WQ0005910_Monitoring - 07-2024_20240827

Monitoring Report Submittal
Permit Number#*
Name of Facility:*
Month:* July
Report Information
Type *
Revised - GW-59
Confirmation Email Address:
Name of Submitter: *
Signature:
Date of submittal:
Initial Review
WQ0005910
Avoca LLC
Year:* 2024
Upload Document*
Avoca LLC July 2024 GW-59 Forms.pdf 3.85MB
PDF Only
Please upload one PDF containing all applicable monitoring reports
(i.e., NDMR, NDAR-1, NDAR-2, NDMLR, GW-59).
[e-mail]
Brian M. Conner
ffee;e r 6W C Cart
Reviewer: Wanda.Gerald
8/27/2024
This will be filled in automatically

Is the project number correct?* WQ0005910
Is the monitoring report accepted?* Yes No
Regional Office* Washington
Reviewer: _anonymous
Review Date: 8/28/2024

GW-59A COMPLIANCE REPORT FORM Permit # WQ 000G°i %
(Submit pile each monitoring perind ndth GIV-99furms.)
1
Enter date monitoring results were due. { Will this monitoring report (GW-59 and GW-59A)
YES
NO
be submitted after the established due date?
2
Was any required informatian missing on the GNV-59 report fornis?
YES
NO
IF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells ill lieed of repair or maintenance (daniaged casing, unlocked or missing cap, missing
YTS
NO
identification plate, area overgrown, etc.)? If the answeris "Yes", Contact the Regloi?(ilOffce.fol-gllidclilee.
4
Are any monitored constituents equal to or above the established standards?
YES
NO
If the answer to question 4 is 'NO", skip to section B.
If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s)
exceeding standards in the space provided below.
61 tv
IDS-m,4G:: nnwlt 7-1100
1Aw Rh = S-10
5
For the constituents identified in question 4 above, have standards been exceeded previously for the
YES
NO
same constituent(s) in the same well(s) in the last two years?
If the answer to question 5 is "NO", skip to section 8.
If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding
standards, concentration(s) reported, nd sample collection date for each occurrence (for the last two years).
/
312WAIA-1.Sdb 3114+1'1="1.'14 3I?.1117.-A-Seto 0*0 3I'M-13 — ke 10
twAV212:10-tu +4I1s1v+-Woo %\1,1�b%V4-'13a
�It►1JL3-to.11b -t12ojg2=171.RW `Ilttl�3-bBo -{110�11-'120
6
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
YES
NO
If the answerls "YES", a groundwater quality problem maybe occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly
located; contact the Regional Office.
/
7
is the permittee implementing previously approved actions required by the Division involving this
TES
NO
groundwater quality problem?
If the answer to question 7 is "YES", describe those actions in the space provided below.
If the answer to question 7 is "NO", contact the Regional Office within 90 daVs; an evaluation maV be
required to determine the impact the waste disposal system is having at the review and compliance
boundaries surrounding this facIRIV. Failure to do so may subject the permittee to a Notice of Violation,
fines, and/or penalties.
g
The person completing this portion (GW-59A) of the monitoring report should sign below and submit this
form with GW-59 forms for required wells to the address provided at the fop of the current GW-59 form.
l hereby acknowledge that the above information was evaluated and the information submitted in this
report (Compliance Report GW-59A) is true and complete to the best of my knowledge.
t 1
--r
Signature of Perinittee (or Authorized Agent) Date
GW-59A 121812003

SUBMIT FORM ON YELLOW PAPER ONLY
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
�•
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
,
1617 MAIL SERVICE CENTER, RALEIGH, NC27699-1617 Phone:[phone]
FACILITY INFORMATION Please Print Clearly or Type
PERMIT Number: Expiration Date;
Facility Name: Avoca LLG
Non -Discharge WQ0005910 UIC
Permit Name (if different):
NPDES Other
Facility Address: Y � fRQac%TYPE
OF PERMITTED OPERATION BEING MONITORED
V_V'v -J'. ` (sireez} 2r1<i
County Berne
❑ Lagoon ❑Remediation: Infiltration Gallery
(MY) (seater cz`a)
❑■ Spray Field ❑ Remediation:
Contact Person: Brian Conner
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:Avoca LLC
No. of wells to be sampled: 8
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
WELL ID NUMBER (from Permit): V1} ' S
Date sample collected: ~{ 3[7 �-�
FIELD ANALYSES:
If WELL
WAS
Well Depth: -2kIft.
Well Diameter: 2 in.
pH o0400:� units Temp. 0001G: Zw °C
DRY at
Depth to Water Level 82545: _ft. below measuring point
Screened interval: - ft. to '14 ft.
Spec. Cond, 000s4: ;i Mhos
time of
sampling,
Measuring Point is Z ft. above land surface_
Relative M.P. Elevation: ft.
Odor ocom: tj Dyne.
check
Volume of water pumped/bai[ed before sampling: is
gallons
Appearance C V-eL4r
here:
Samples for metals were collected unfiltered: YES ❑
��``
NO and field acidified:'* ES ❑ NO
El
LABORATORY INFORMATION
Date sample analyzed: —[ L3tA -3'Li — $1-2 12LI
LaboratoryName: Why �0 �r1�i
"��10��y� �a 1 Certification No. 1 O
PARAMETERS NOTE: Values should reflect dissolved and
colloidal concentrations.
COD 00335 mg/L
Nitrite (NO2) as N 00615
mg/L
Pb - Lead o1051 ug/L
Coliform: MF Fecal 31616 /100mL
Nitrate (NO3) as N 00620 • 0 3
mg/L
Zn - Zinc 01092 mg/L
Co[iform: MF Total 31504 /100mL Phosphorus: Total as P 00665 4 Q . 02
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L
Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 tiJ5 D mg/L
Al - Aluminum 01 u
mg/L
pH (Lab) oo4o3 units
Ba - Barium o#ow
ug/L
TOC 0068o 2 .3 mg/L
Ca - Calcium 00916 32 ,
mg/L
Chloride 00940 �2._ mg/L
Cd - Cadmium o1027
ug/L
Arsenic 01002 ug/L
Chromium: Total 01034
ug/L
Grease and Oils oo552 mg/L
Cu - Copper 01042
mg/L
ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
Fe - Iron 01045
ug/L
TTACH LAB REPORT,)
(Specify test and methoV'Yes
Sulfate 00945 mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? (1) ❑ No (0)
pecific Conductance 00095 µMhos
K - Potassium C0937
mg/L
VOC 7873 method #
Total Ammonia oo610 Q •O mg/L
Mg - Magnesium oo927
mg/L
method #
[Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug1L
method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
.3%M tNGVl
Permittee for Authorized Agent) Name and Title - Please p ' t or type
7/Z
GW-59 Rev.3-1-2016

SUBMIT FORM ON YELLOW PAPER ONLY
DEPARTMENT OF ENVIRONMENTAL QUALMY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFOf7I69ATIONPROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC27699-1617 Phone:919-8g7-6306
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date:
Facility Name: Avoca LLC
Non -Discharge W00005914 UIC
NPDES Other
Permit Name (if different):
Facility Address:yp rrdf+M
-Roar\
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
(Street)
°Lv'V A. t 21q!; County Bertie
( yl (State?
(Zip}
X Spray Field ❑Remediation:
Contact Person: Brian Conner
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:Avoca LLC
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
WELL ID NUMBER (from Permit), W "'�
1
Date sample collected: � l 1So y 2�
FIELD ANALYSES.
If WELL
WAS
Well Depth: ft.
Well Diameter: 2. in.
pH 00400:5 -Co units Temp. 00010:2q M oC
DRY at
Depth to Water Level 82546: 1 l.s ft, below measuring point
Screened Interval: ft. to
�� ft. Spec. Cond. 00os4: µ Mhos
time of
sampling,
Measuring Point is Z ft. above land surface
Relative M.P. Elevation: ft.
Odor Boom: N fl­%2.
check
Volume of water pumped/balled before sampling:
e
J
gallons
Appearance C yeeor"
here:❑
Samples for metals were collected unfiltered: ES ❑
NO and field acidified: 2 YES ❑ NO
LABORATORY INFORMATION
Date sample 21nalyzed:—11%tt2--1 N2I2y
LaboratoryName: Wgm g2o'�'nA
(NnOA zceLk Certification No.
PARAMETERS NOTE: Values should reflect
dissolved and
colloidal concentrations. I
COD 00335
mg/L
Nitrite (NO2) as N C0615
mg/L Pb - Lead oio51 ug/L
Coliform: MF Fecal 31616
1100ML
Nitrate (NO3) as N co62o ��(�
mg/L Zn - Zinc 01092 mg/L
CoIifcrm: MF Total 31504
/100mL Phosphorus: Total as P 00665 L, Q,02.
mg/L
(Note: use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved SoIids:Total 7o3oo 1 % D
mg/L
A] -Aluminum ciio5
mg/L
pH (Lab) 00403
units
Ba - Barium C1007
ug/L
TOC 00680 .2 n 3
mg/L
Ca - Calcium cosi s 10 . Ly
mg/L
Chloride 00940 Z7j
mg/L
Cd - Cadmium cio27
ug/L
Arsenic oi=
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug1L
Fe - Iron 01045
ug/L
TACH LAB REPORT.)
(Specify test and methoVes
Sulfate C0945
mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? (1) ❑ No (0)
pecific Conductance coo95
µMhos
K - Potassium a0937
mg/L VOC 7873 method #
Total Ammonia o0610 < O, OIL
mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NFiyas N; Ammonia Nitrogen, Total)
Mn - Manganese o1055
ug/L
method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
Sw'­+ _�•4 4%dn - plank
Permittee (or Authorized Agent) Name and Ttle - Pleas rant or type
(Date)
GW-59 Rev.3-1-2016

SUBMIT FORM ON YELLOW PAPER ONLY
DEPARTMENT OF ENVIRONMENTAL QUALITY - AIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
, , ,
,
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617MAIL SERVICi=CENTER, RALEIGH,NC27699-1617 Phone.[phone]
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date:
Facility Name: Avoca LLC
Nan -Discharge WQ0005910 UIC
NPDES Other
Permit Name (if different):
`Q Facility Address: 8 � VOCCA;
i�
er+r�19%061A
TYPE OF PERMITTED OPERATION BEING MONITORED
El Lagoon ❑ Remediation: Infiltration Gallery
�a(�r --k(street) 2��'l5 County Bertie
(my) (st3tet
(zlp�
❑■ Spray Field ❑ Remediation:
Contact Person: Brian Conner
Telephone#: [phone]
❑ Rotary Distributor © Land Application of Sludge
Well Location/Site Name:Avoca LLC
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
WELL ID NUMBER (from Permit): �j' ^
Date sample collected: �30�2�{
FIELD ANALYSES:
If WELL
WAS
Well Depth: ktft.
Well Diameter: Z in.
pH 00400: to." units Temp. 000io:2-J.t0 °C
DRY at
Depth to Water Level 62546: (Q.� ft. below measuring point
Screened interval: 3 fit. to
o,
t1
ft. Spec. Cond. 00094: uMhos
time ofsampling,
Measuring Point is ft. above land surface
Relative M.P. Elevation: fit.
Odor o0065: V D r�
check
Volume of water pumped/bailed before sampling:
gallons
Appearance C�(&,r•
here:❑
Samples for metals were collected unfiltered: RYES ❑
NO and field acidified: &2"Y"ES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: -1 3 —
Laboratory Name: �avr Qp�r�}
QS
1
�y�`i C4 l Certification No. 0
PARAMETERS NOTE: Values should reflect
dissolved and
colloidal concentrations.
COD C0335
mg/L
Nitrite (NO2) as N oos15
mg/L Pb - Lead o1o51 ug/L
Coliform: MF Fecal 31616
1100mL
Nitrate (NO3) as N 00620 _ % X O
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Tot21 31504
1100mL Phosphorus: Total as P oos65 U . Olp
mg1L
(Note: Use MPN method for highly turbid Samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 7mco 5-7y
mg/L
Al -Aluminum of 1as
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC oosao
mg/L
Ca - Calcium 00916 �(. 32.
mg/L
Chloride 00940 12. •S
mg/L
Cd - Cadmium 01027
ug1L
Arsenic 01002
ug/L
Chromium: Total 0:034
ug1L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iran 01045
ug/L
(Specify test and method #. 9rTTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? Yes (I) ❑ No (0)
pecific Conductance 00095
p.Mhos
K - Potassium 00937
mg/L VOC 7673 method #
Total Ammonia cosio 2- •LAQ
mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH3as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
uglL
, method #
TKN as N o0625
mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
_Z�uhrn , urnLIn - a
Permittee (or Authoriz d Agent) Name
GW-59 Rev, 3-1-2016
or type
Signature of Permittee

SUBMIT FORM ON YELLOW PAPER ONLY
DEPARTMENT OF ENVIRONMENTAL QUAL17Y - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
, ,
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
7B17MA[LSERVICE CENTER, RALEIGH,NC27699-4617 Phone,919-8D7-6306
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date:
Facility Name: Avoca LLC
Non -Discharge WQ0005910 UIC
NPDES Other
Permit Name (if different):
-4 Facility Address: 0<ra t—a--Vyl
rr��
plow{
TYPE OF PERMITTED OPERATION BEING MONITORED
El Lagoon ❑Remediation: Infiltration Gallery
{Street} B ertl e
County
( y; (state)
(Zip)
0 Spray Field Remediation:
Contact Person: Brian Conner
Telephone-#: 252-482-2133
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:Avoca LLC
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
WELL 1D NUMBER (from Permit): M� —
11
Date sample collected: �301 Z; -�
FIELD ANALYSES:
If WELL
WAS
Well Depth: ZZlbft.
Well Diameter: Z in.
pH 0040o:(0.11 units Temp. 00010:-zCA °C
DRY at
Depth to Water Level 82546: V3 ft. below measuring
paint
Screened Interval: 1 O ft. to Z3 ft. Spec. Cond. 00094: Mhos
time ofsampling,
Measuring Point is 2 ft. above land surface
Relative M.P. Elevation: ft.
Odor coo85: �i'�2,
check
Volume of water pumped/bailed before sampling:
gallons
Appearance C keeL�
here:❑
Samples for metals were collected unfiltered: ES ElNO
and field acidified: R// ES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: —[ �'3�,'��{ — �l1'Z�2�
Laboratory Name: ��Oa"^k
�ky��C"t.1
I Certification No.
PARAMETERS NOTE: Values should reflect
dissolved and
colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N ooei5
mg/L Pb - Lead oiosi uglL
Coliform: MF Fecal 3i6is
110OmL
Nitrate (NO3) as N 00620 ?� ` ��
mglL Zn - Zinc 01092 mglL
Coliform: MFTotal 3i5o4
/100mL Phosphorus: Total as P oo665
mglL
(Note: LJseMPN method for high lyturbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Tetal 70300 G�
mg/L
Al - Aluminum 01105
mg/L
pH (Lab) 00403
units
Ba - Barium 01C07
ug1L
TOC o0sso L 1 . ID
mg/L
Ca - Calcium 00916 Lj(p -(0
mg/L
Chloride 0094C Z"i •ra
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
uglL
Chromium: Total 01034
ug/L
Grease and Oils o0552
mg/L
Cu - Copper 01042
mglL ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
uglL (Specify test and method #. AJ,TACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900
uglL Lab Report Attached? Yes (1) ❑ No (0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mglL VOC 7873 method #
Total Ammonia 00610 4— Q . Q2,
mg/L
Mg - Magnesium 00B27
mglL method #
(Ammonia Nitrogen: NH,as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug1L method #
TKN as N 00625
mg/L
Ni - Nickel 01067
uglL method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
5e1L'" 1 M'mt -- `P\OaN Pa r
Permittee (or Authorized Aqerit) Name and Title - Please ifMint or
GW-59 Rev.3-1-2016
Signature of Permittee for Authorized Agent)

SUBMIT FORM ON YELLOW PAPER ONLY
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:JOE
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC27699-151T Phone.,919-807-6306
FACILITY INFORMATION Please Print Clearly orType
PERMIT Number: Expiration Date: fl-3 -2.Lf
Facility Name: Avoca LLC
Non -Discharge WQ0005910 UIC
NPDES Other
Permit Name (if different):
Facility Address: ` vflCCt �d✓w1Oad
TYPE OF PERMITTED OPERATION BEING MONITORED
;ss eeu 2�� 5
Count y Bertie
0 Lagoon ❑Remediation: Infiltration Gallery
(MY) (State) (zip)
0 Spray Field ❑Remediation:
Contact Person: Brian Conner
Telephone* 252-452-2133
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:Avoca LLC
No. of wells to be sampled: 5
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION c-�
WELL ID NUMBER (from Permit): [�i�W I0
Date sample collected: 'i \3012LA
FIELD ANALYSES:
If WELL
WAS
Well Depth: 20 ft.
Well Diameter: 2. in.
pH 00400:3.1 units Temp. COD 10:T6.(0 oC
DRY at
Depth to Water Level 82546:! ft. below measuring point
Screened Interval: 7j ft.
to loft. Spec. Cond. 00094: µ
time ofMhos sampling,
Measuring Point is 2. ft. above Iand surface
Relative M.P. Elevation:
ft.
Odor 000m: iy riyte. _
check
Volume of water pumped/bailed before sampling. 6
gallons
Appearance Cl ow-
here:❑
Samples for metals were collected unfiltered: 2YES ❑
NO and field acidified: &?*YES
❑ NO
LABORATORY INFORMATION
Date sample analyzed: llsik'214~ c6laI2,4
Laboratory Name:
l
Certification No. 1
PARAMETERS NOTE: Values should reflect dissolved and
colloidal concentrations.
COD 00335 mg/L
Nitrite (NO2) as N oos15
mg/L Pb - Lead o1051 ug1L
Coiiform: MF Fecal 31616 1100ml-
Nitrate (NO3) as N 00620 Ci2J >� mg/L Zn - Zinc 01092 mg1L
Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 7j�Q mg/L
Al -Aluminum oiim
mg/L
PH (Lab) 00403 units
Ba - Barium 01007
ug/L
TOC oossc ,2Co mg/L
Ca - CaIcium oo9i6 mg/1-
Chloride 00940 '� mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002 ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552 mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
ire - iron 01045
ug/L (Specify test and method #. 5TACH LAB REPORT.)
Sulfate 00945 mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? Yes (1) ❑ No (0)
pecific Conductance 00095 uMhos
K - Potassium 00937
mg/L VOC 7873 method #
Total Ammonia 00610 < Q , O Z mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH,as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs:
and that the laboratory analytical data
ility of fines and imprisonment for knc
M 7 rr
Permittee (or Authcrize Aqent) Name and Title - Please 'nt or type
mg/L VOC Removal%
Vz7
(Date)
GW-59 Rev.3-1-2016

SUBMIT FORM ON YELLOW PAPER ONLY
a .
DEPARTMENT OF ENVIRONMENTAL QUALITY -DIY. OF WATER. RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617MAIL SERVICE CENTER, RALEIGH,NC276991617 Phone.,919-807-630fi
FACILITY INFORMATION Please Prinfclearly orType
PERMIT Number: Expiration Date:
Facility Name: Avoca LLC
Non -Discharge WQ0005910 UIC
Permit Name (if different):
NPDES Other
Facility Address:yOCGI rr{�l�rrv� RQA�
TYPE OF PERMITTED OPERATION BEING MONITORED
2_19 5
County Bertle
❑ Lagoon ❑Remediation: Infiltration Gallery
( y) (State) (zip)
0 Spray Field ❑Remediation:
Contact Person: Brian Conner
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:AVoca LLC
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
WELL [D NUMBER (from Permit): MW —
Date sample collected: S 3012.4
FIELD ANALYSES:
If WELL
WAS
Well Depth: 20 ft.
Well Diameter: 2 in.
pH co400:(o4t units Temp. cool o: 2 P °C
DRY at
Depth to Water Level 82546: i?-, 00 ft. below measuring point
Screened Interval: ��ft. to 2d ft. Spec. Cond. 00094: µ Mhos
time of
sampling,
Measuring Point is 2 ft. above Iand surface
Relative M.P. Elevation: ft.
Odor 00085: N one-
check
Volume of water pumped/bailed before sampling: S
gallons ��
Appearance C.'leAr
here:❑
Samples for metals were collected unfiltered: YES ElNO
and field acidified: L_�I'YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: — C010JILI
LaboratoryName: LgLy po rti�
�r1[A
rr
�uT ,CGS [ Certification No. Q
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead of osi ug1L
Coliform: MF Fecal 31616 /100mL
Nitrate (NO3) as N 00620 D
mg/L Zn -Zino 01092 mg1L
Coliform: MF Total 31504 1100mL Phosphorus: Total as P 00655 , s4
mg1L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 7o5o7
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 k j Q n mg1L
Al - Aluminum o11o5
mg1L
PH (Lab) 00403 units
Ba - Barium 01007
ug1L
TOC o065o �{ .S~j mg/L
Ca - Calcium 00916 Z�
mg1L
Chloride 00940 mg/L
Cd - Cadmium 01027
ug1L
Arsenic 01002 ug/L
Chromium: Total 01034
ug1L
Grease and Oils 00552 mg/1-
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug1L
Fe - Iron 01045
ug1L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? Yes (1) ❑ No (0)
Specific Conductance 00095 }LNlhos
K - Potassium 00937
mg/L VOC 7873 method #
Total Ammonia 00610 �l .�� mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug1L
method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VCCs: mg/L VOC Removal%
i 4-CCn- t r.
Permittee (or Authorize Agent) Name and Title - Piease Mt or type
�� '
Signature of Permittee {or AutP
°lz7 Z
(date)
GW-59 Rev.3-1-2016

(2)
WayPAoint.
NALYTICAL
8/19/2024
Avoca, LLC
Brian Conner
P.O. Box 129
Merry Hill, NC, 27957
Ref: Analytical Testing
Lab Report Number: 24-213-0603
Client Project Description: 132 - AVOCA, LLC
Effluent & Wells
114 Oakmont Drive, Greenville, NC 27858
Main 252.756.6208 0 Fax [phone]
www.waypointanalytical.com
Dear Brian Conner:
Waypoint Analytical Carolina (Greenville) received sample(s) on 7/31/2024 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021).
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
�9 �4�
Ron Boquist
General Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
NC DHHS DW Cert# 3771S
NC DEQ W W Cert# 10
NC DEQ W W Satellite Cert# 610
Page 1 of 8

114 Oakmont Drive, Greenville, NC 27858
• (2)
Waypoint, Main 252.756.62081 Fax [phone]
ANALYTICAL www.waypointanalytical.com
Sample Summary Table
Report Number: 24-213-0603
Client Project Description: 132 - AVOCA, LLC
Effluent & Wells
Lab No
Client Sample ID
Matrix
Date Collected
Date Received
Method
Lab ID
72686
Effluent
Aqueous
07/30/2024 14:00
07/31/2024
72686
Effluent
Aqueous
07/30/2024 14:00
07/31/2024
300.0
WP CNC
72687
Well #5
Aqueous
07/30/2024 14:35
07/31/2024
72687
Well #5
Aqueous
07/30/2024 14:35
07/31/2024
300.0
WP CNC
72688
Well #7
Aqueous
07/30/2024 15:45
07/31/2024
72688
Well #7
Aqueous
07/30/2024 15:45
07/31/2024
300.0
WP CNC
72689
Well #8
Aqueous
07/30/2024 15:15
07/31/2024
72689
Well #8
Aqueous
07/30/2024 15:15
07/31/2024
300.0
WP CNC
72690
Well #9
Aqueous
07/30/2024 14:55
07/31/2024
72690
Well #9
Aqueous
07/30/2024 14:55
07/31/2024
300.0
WP CNC
72691
Well #10
Aqueous
07/30/2024 15:30
07/31/2024
72691
Well #10
Aqueous
07/30/2024 15:30
07/31/2024
300.0
WP CNC
72692
Well #11
Aqueous
07/30/2024 14:20
07/31/2024
72692
Well #11
Aqueous
07/30/2024 14:20
07/31/2024
300.0
WP CNC
WP CNC - Charlotte, NC: Waypoint Analytical - Charlotte, Charlotte, NC
Page 2 of 8

s
114 Oakmont Drive, Greenville, NC 27858
Waypipint.Main 252.756.6208 ° Fax [phone]
AYTICAL www.waypointanalytical.com
08604
Avoca, LLC
Brian Conner Project 132 - AVOCA, LLC
P.O. Box 129 Information : EfFluent & Wells
Merry Hill , NC 27957
Report Date: 08/19/2024
Report Number : 24-213-0603 REPOR T OF A NA L YSIS Received : 07/31/2024
Lab No : 72686 Matrvx: Aqueous
Sample ID : Effluent Sampled: 7/30/2024 14.00
Test
Results
Units
MQL
DF Date / Time
By
Analytical
Analyzed
Method
Nitrite (NO2-N)
0.02
mg/L
0.02
1 07/31/21 16:18
KID
353.2
Nitrate (NO3-N)
<0.020
mg/L
0.020
1 07/31/21 16:18
]RF
EPA-353.2
Ammonia Nitrogen
<0.02
mg/L
0.02
1 OR/06/24 16:29
HMM
350.1
Biochemical Oxygen Demand (5-day)
4500
mg/L
2C00
1 07/31/24 09:18
AAM
5210E-2016
Bromide
74.8
mg/L
0.500
5 08/14/24 15:36
ND[
300.0
Chloride
115
mg/L
5.00
1 08/09/2-109:30
BNC
4500-CI-B
Nitrate+Nitrite-N
0.03
mg/L
0.02
1 O8/01/2412:07
353.2
Total Dissolved Solids
1700
mg/L
50
1 08/06/24 10:38
HMV
254OC-2015
Total Suspended Solids
230
mg/L
62,5
1 08/01/24 10:00
BLV
2540D-2015
Total Kieldahi Nitrogen
11.87
mg/L
2.00
10 08/08/24 15:46
HMM
EPA-351.2
Total Nitrogen
11.9
mg/L
0.020
1 08/01/24 12:07
CALCULATION
Phosphorus
2.98
mg/L
0.02
1 08/08/2414:19
HMM
365.4
Calcium
5.65
mg/L
0.500
1 08/05/2417:48
MTM
EPA-200.7
Magnesium
1.93
mg/L
0.500
1 08/O5/2417:48
MTM
EPA-200.7
Sodium
218
mg/L
2.50
1 08/05/2417:48
MTM
EPA-200.7
Sodium Absorption Ratio
0.638
Ratio
0.100
1 08/05/24 17:48
CALCULATION
Qualifiers/ DF Dilution Factor L Limit Exceeded
Definitions MQI Method Quantitation Limit
Page 3 of 8

Waypointo
ANALYTICAL
08604
Avoca, LLC
114 Oakmont Drive, Greenville, NC 27858
Main 252.756.6208 1 Fax [phone]
www,waypointanalytical.com
Brian Conner Project 132 - AVOCA, LLC
P.O. Box 129 Information : Effluent & Wells
Merry Hill , NC 27957
Report Date:08/19/2024
Report Number : 24-213-0603
REPORT OFANAL YSTS
Received : 07/31/2021
Lab No : 72687
Matrix: Aqueous
Sample ID : Well #5
Sampled: 7/30/2024 14:35
Test
Flesul[s
Units
MQL
DF Date / Time By Analytical
Analyzed Method
Nitrate (NO3-N)
0.030
mg/L
0.020
1 07/31/24 16:26 JRF EPA-353,2
Ammonia Nitrogen
0.06
mg/L
0.02
1 08/06/24 16:06 HMM 350.1
Bromide
10.9
mg/L
0.100
1 08/1412413:57 NDL 300.0
Chloride
32.0
mg/L
2.00
1 08/09/24 09:30 BNC 4500-CI-B
Total Dissolved Solids
550
mg/L
25
1 08/06/24 10:38 HMV 2540C-2015
Phosphorus
<0.02
mg/L
0.02
1 08/08/2414:21 HMM 365.4
TOC
2.31
mg/L
1.00
1 08/12/24 12:22 BLV 531OC-2014
Calcium
32.1
mg/L
0.500
1 08/05/2417:52 MTM EPA-200.7
Lab No : 72688
Matrix: Aqueous
Sample ID : Well #7
Sampled: 7/30/2024 15:45
Test
Results
Units
MQL
DF Date I Time By Analytical
Analyzed Method
Nitrate (NO3-N)
0.760
mg/L
0.040
107/31/24 16:25 JRF EPA-353.2
Ammonia Nitrogen
<0.02
mg/L
0.02
1 08/06/24 13:57 HMM 350.1
Bromide
8.27
mg/L
0.100
1 08/14/2414:09 NDL 300.0
Chloride
23.0
mg/L
2.00
1 08/09/24 09:30 BNC 4500-Ct-B
Total Dissolved Solids
180
mg/L
13
1 08/06/24 10:38 HMV 2540C-2015
Phosphorus
<0.02
mg/L
0,02
1 08/08/2410:53 HMM 365.4
TOC
2.73
mg/L
1.00
1 08/12/24 12:22 BLV 531OC-2011
Calcium
10.6
nag/L
0.500
1 08/05/2417:57 MTM EPA-200,7
Qualifiers/ DF Dilution Factor
L
Limit Exceeded
Definitions MQL Method Quantitation
Limit
Page 4 of 8

Waypointo
ANALYTICAL
08601
Avoca, Lt.0
114 Oakmont Drive, Greenville, NC 27858
Main 252.756.G708 0 Fax 252.756,0633
www.w,iypointanalytical.com
Brian Canner Project 132 - AVOCA, LLC
P.O. Box 129 Information : Effluent & Wells
Merry Hill , NC 27957
Report Date ; OB/19/2024
Report Number : 24-213-0603
REPORTOFANACYSIS
Received : 07/31/2024
Lab No : 72689
Matrix: Aqueous
Sample ID : Well #8
Sampled: 7/30/2024 15.15
Test
Results
Units
MQL
DF Date 1 Time By Analytical
Analyzed Method
Nitrate (NO3-N)
0.110
mg/L
0.040
1 07/31/24 16:23 JRF EPA-353.2
Ammonia Nitrogen
2.46
mg/L
0.02
1 08/06/24 13:59 HMM 350.1
Bromide
5.82
mg/L
0.100
1 08/14/2414:22 NDL 300.0
Chloride
12.5
m9/L
1.00
1 0B/09/24 09:30 BNC 4500-Cl-B
Total Dissolved Solids
570
mg/L
25
1 08/06/24 10:38 HMV 2.54OC-2015
Phosphorus
6.06
mg/1-
0.02
1 08/08/2410;55 HMM 365.4
TOC
1.40
mg/L
1.00
1 08/12/2412:22 BLV 5310C-2014
Calcium
9.32
mg/L
0.500
1 08/05/2418:01 MTM EPA-200.7
Lab No : 72690
Matrix: Aqueous
Sample ID : Well #9
Sampled: 7/30/2024 14:55
Test
Results
Units
Mal-
DF Date / Time By Analytical
Analyzed Method
Nitrate (NO3-N)
3.07
mg/L
0.080
1 07/31/24 16:22 JRF EPA-353.2
Ammonia Nitrogen
<0.02
mg/L
0.02
1 08/06/24 13:03 HMM 350.1
Bromide
<0.100
rng/L
0.100
1 08/14/2414:31 NDL 300.0
Chloride
27.5
mg/L
1.00
1 08/09/24 09:30 BNC 4500-CI-B
Total Dissolved Solids
270
ntg/L
25
1 08/06/24 10:38 HMV 254OC-2015
Phosphorus
<0.02
mg/L
0.02
1 08/08/2414:16 HMM 365.4
TOC
<1.00
mg/L
1.00
1 08/12/2412:22 Bi_V 531OC-2011
Calcium
46.6
mg/L
0.500
1 08/05/2418:05 MTM EPA-200.7
Qualifiers/ DF Dilution Factor L Limit Exceeded
Definitions MQL Method Quantitation Limit
Page 5 at 8

Waypoeinto
ANALYTICAL
08604
Avoca, LLC
114 Oakmont Drive, Greenville, NC 27858
Main 252.756.6208 9 Fax [phone]
www.waypointanalytical.com
Brian Conner Project 132 - AVOCA, LLC
P.O. Box 129 Information : Effluent & Wells
Merry Hill, NC 27957
Report Number: 24-213-0603
REPORT OFANAL YSIS
Report Date; 08/19/202-4
Received : 07/31/2024
Lab No : 72691
Matrix: Aqueous
Sample ID : Well #10
Sampled: 7/30/2024
15:30
Test
Results
Units
MQL
DF Date I Time By
Analytical
Analyzed
Method
Nitrate (NO3-N)
9.31
mg/L
0.400
1 07/31/24 16:20 JRF
EPA-353.2
Ammonia Nitrogen
<0.02
mg/L
0.02
1 08/06/24 16:21 HMM
350.1
Bromide
<0.100
mg/L
0.100
1 08/14/2414:46 NDL
300.0
Chloride
71.0
mg/L
1.00
1 08/09/24 69:30 BNC
4500-CI-B
Total Dissolved Solids
380
mg/L
25
1 08/06/24 10:38 HMV
254OC-2015
Phosphorus
0.05
mg/L
0.02
1 08/08/24 14:37 HMM
365.4
TOC
1.26
mg/L
1.00
1 08/12/2412:22 BLV
5310C-2014
Calcium
26.6
mg/L
0.500
1 08/05/2418:09 MTM
EPA-200.7
Lab No : 72692
Matrix: Aqueous
Sample ID: Well #11
Sampled: 7/30/2024 14:20
Test
Results
Units
MQL
DF Date / Time By
Analytical
Analyzed
Method
Nitrate (NO3-N)
0.080
mg/L
0.040
1 07/31/24 16:14 JRF
EPA-353.2
Ammonia Nitrogen
7.81
mg/L
0.02
1 08/06/24 16:27 HMM
350.1
Bromide
9.66
mg/L
0.100
1 08/14/2414:59 NDL
300.0
Chloride
27.0
mg/L
2.00
1 08/09/24 09:30 BNC
4500-CI-8
Total Dissolved Solids
1100
mg/L
25
1 08/06/24 10:38 HMV
2540C-2015
Phosphorus
0.54
mg/L
0.02
1 08/08/2414:44 HMM
365.4
TOC
9.57
mg/L
1.00
1 08112/2412.22 BLV
531OC-2014
Calcium
27.0
mg/L
0.500
1 08/05/2418:13 MTM
EPA-200.7
Qualifiers/ DF
Dilution Factor
L
Limit Exceeded
Definitions MQL
Method Quantitation Limit
Page 6 of 8

(D
Waypoint.
ANALYTICAL
114 Oakmont drive, Greenville, NC 27858
Main 252.756.6208 ° Fax [phone]a3
www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 08604
Customer Name: Avoca, LLC
Report Number: 24-213-0603
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
1.5c oakton
Shipping container/cooler uncompromised?
0 Yes
No
Number of coolers/boxes received
F1
Custody seals intact on shipping container/cooler?
0 Yes
0 No
0 Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
0 Yes
0 No
COC agrees with sample label(s)?
a Yes
0 No
COC properly completed
Yes
0 No
Samples in proper containers?
0 Yes
0 No
Sample containers intact?
0 Yes
0 No
Sufficient sample volume for indicated test(s)?
0 Yes
0 No
All samples received within holding time?
0 Yes
0 No
Cooler temperature in compliance?
0 Yes
0 No
0 Not Present
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
0 NIA
Water - VOA vials free of headspace
0 Yes
0 No
0 NIA
Trip Blanks received with VOAs
0 Yes
0 No
Ce) NIA
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
© NIA
High concentration container (48 hr) f Low concentration Encore samplers (48 hr)
High concentration pre -weighed (methanol -14 d) J Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included?
0 Yes
* No
Comments: ,Clt�did not collect Well #4
Signature: l intlA�man Date & Time: 07/31/2024 12:16:20
Page 7 of 8

e
palsenbai aalaweied yoea ao; anoge ssloolq aul uj aldwes gej0 sa wao
a01 u9, a so aidwes apsod won lo) .0„ e aoeld lsnw saldweS ap+s asaanai aUl uo uaao� sil 6ul#aldwoo �o suni;ins st�1 CiV38 3SV31d
3wul31bQ
(91S) A0 MA13O3d
3vqu)avo
(JIS) A8 C13HS1MNFGH
3NlUalvo
(US) AS fl3A Cd
3vivalv(]
( ) 81 cgreu
3wW31.tlo
i 03AI,13 b
_9,51 Ibc nF
3+Vi IJ31dQ
(EmdwbS) (01S) A8 o3HSInONr@U
ON 53 301 NO C13A13038 S31dNVS
1 S.MMOO
�- Ld8t�1 NI 03N333d S31dMS
C3
(wud OId)
A9 031O311oo S31dWtlS
N I J
1 P[, .tt
AIOA113Q ANM S Mi8n(]
fl3Nl�fit�lt/N1('1tf3S)1.001S(lO �fl NVHHfl
G
'T'°t
of
0 1 � IT7 N
NOLLO3S 3.LS'dM anOS
'
L
L '
ht C�
G# 111)
"
G
°� ��
SsSti
M�-c� �.
�;� u�.►1
M�raMa �
'`
G
}+
S�SL
�-cZ- L
La IW 1t
tf3lt/M JNIHNIE�o �
aIp
(S30dN)8aVM31SVM
;�
L
_ -
rh II3r►1
N011VOHISSM
4
3u011
1J3
3Ld-lnSoIHi vN - J
H0VN/31V130t/ ON IZ ` 3 °oS`H - O
13H-3 `ONI4-8 m
�
HOVN-4 3NON-V ran
m
O sn
n
0
o
c m
� 3
z
3va
ado
NMY00131dWdS
NQI1 O3 i"10O
££IZ-Ur (ZSZ)
VV
V
N0Il'dM3S3bd1V01Y13H3
LSSLZ 3N 7'11H .�?R1311�
:)NON
6Z1 X08 'O'd
Z[ hL�lOO1rIV1?]8'2121
(313(.LVh1H,I,SV,11) O7'I `V;�dAV
9!d'3dAL83NfViNO0
d d d d d i
,£ct £c D71 VOCAV v£t
j :)TI VOOAtI
rossv � ii �I(j� �1�1 (jll �� � i � �[ �� I
£OS�tZ :r I i�j Jf j!; !.1 J f
hn
=INPi0-lHJ
ltCl[EXEINIS[Q
�, N3(1'I3
££-9(�-95L (%Si,) al':! �SOZ9-95L (Z9D'Us'4d
Mu) 11:Ji�A 1,'LI,�iI,E(,[I1{L'M M,tt N
I;SSCi 31V'�Il��staaxJ
IO ILJML]jtF () 1711
(8dl) (n S) ?103HO Hd
iN) ON JO LkI SOA - llBw 5 0>
(20 NO3HO3NIbOlHO
la 1 a<,rd al�tn�aaa� - 1ratl+tl�'uV au�c►c�.te,�
M10,M d AuvjL,31A_, .:I" a.LIVH3 0jureM