WQ0000485_Monitoring - 07-2024_20240823

Monitoring Report Submittal
Permit Number#* WQ0000485
Name of Facility:* Darling Ingredients Rose Hill
Month: * July Year: * 2024
Report Information
Type* Upload Document*
GW-59 scan 2024-07 GW-59 3.74MB
Grou ndwaterComplianceReportForm-WQ0000485
- DIRH.pdf
PDF Only
Please upload one PDF containing all applicable monitoring reports
(i.e., NDMR, NDAR-1, NDAR-2, NDMLR, GW-59).
Confirmation Email Address: * [e-mail]
Name of Submitter: * Corey Lanier
Signature:
Date of submittal: 8/23/2024
This will be filled in automatically
Initial Review

Reviewer: Wanda.Gerald
Is the project number correct?* WQ0000485
Is the monitoring report accepted?* Yes NO
Regional Office* Wilmington
Reviewer: _anonymous
Review Date: 8/26/2024

DARLING
INGREDIENTS
August 21, 2024
Division of Water Resources
Attn: Information Processing Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Re: Ground Water Quality Monitoring Report (GWQMR)
Darling Ingredients — Rose Hill
Permit WQ0000485
To whom it may concern,
Please find enclosed the Groundwater Quality Monitoring Compliance Report for
Surface Irrigation for the month of July 2024 for our Rose Hill Division.
Should you require any additional information or wish to discuss this matter,
please feel free to contact me at 910.289.2083 x 25119.
Sincerely,
0--r- ;A
Thomas Tyner
General Manager
cc: DI Regional Corporate Office
tws - BIOEKERGY - SERVICES

GW-59A COMPLIANCE REPORT FORM Permit# W00000485
(Submit one each monitoring period with GW-59 forms.)
1
Enter date monitoring results were due. (0813112024) WIII this monitoring report (GW-59 and GW-59A)
be submitted after the established due date?
No
2
Was any required information missing on the GW-59 report forms?
No
IF the answer to question 1 or 2 is 'YES", list in the space provided below the well identification number(s) and explain the
problems encountered in obtaining the required information.
MW-8A was damaged by farm equipment and is scheduled to be closed and replaced by Register Well Co, INC; moving the
replacement well 10' due North per DEQ direction-
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing identification
plate, area overgrown, etc.)? Jf the answer is "Yes ", contact the Regional Office for guidance.
No
4
Are any monitored constituents equal to or above the established standards?
YES
Ifthe answer to question 4 is "NO° skip to section 8.
If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s) exceeding
standards in the space provided below:
SEE ATTACHED GROUNDWATER MONITORING WELL 2 YR EXCEEDANCE HISTORY REPORT
5
For the constituents identified in question 4 above, have standards been exceeded previously for the same
constituent(s) in the same well(s) in the last two years?
YES
If the answer to question 5 is 'NO" skip to section 8
lithe answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding standards,
concentration(s) reported, and sample collection date for each occurrence (for the last two years).
SEE ATTACHED GROUNDWATER MONITORING WELL 2 YR EXCEEDANCE HISTORY REPORT
6
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
YES
If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE
IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly located; contact the
Regional Office.
7
Is the perrnittee implementing previously approved actions required by the Division involving this groundwater quality
problem?
YES
If the answer to question 7 is "YES" describe those actions in the space provided below.
If the answer to question 7 is "NO", contact the Regional Office within 90 da s: an evaluation may be
required to determine the impact the waste disposal system is having at the review and compliance
boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation,
fleas, andhor allies.
Additional monitoring was performed to identify constituents of TOC in MW No.9. The facility has been
communicating with Mr. Geoff Kegley in the Wilmington Regional Office.
8
The person completing this portion (GW59A) of the monitoring report should sign below and submit this form with
G W-59 forms for required wells to the address provided at the top of the current G W-59 form.
I hereby acknowledge that the above information was evaluated and the information submitted in this report
(Compliance Report GW-59A) is true and complete to the best of my knowledge.
.4
z4a 'il/23 2
gnature of Perm e r Authorized Agent Date
GW-59A 12/8i2003

Darling Ingredients - Rose Hill (WQ0000485) Groundwater Monitoring Well 2 Year Exceedance History Report
TDS 500
8A
10A
11A
14A
July-24
733
946
571
1430
March-24
795
1420
November-23
793
1010
July-23
816
1270
March-23
804
1310
1310
November-22
833
944
944
July-22
772
1280
1280
pH 6.5-8.5
1
2
7A
8A
9
10A
11A
I 12B
13A
14A
July-24
5.00
6.40
5.00
4.40
4.90
3.90
4.60
5.00
5.90
4.80
March-24
5.20
5.00
4.80
5.80
3.82
4.80
4.60
4.80
5.30
November-23
5.20
3.66
4.60
5.90
3.55
4.70
3.91
4.70
5.10
July-23
5.20
1 5.50
5.30 1
5.10
1 6.30
3.70
5.40
4.60
4.70
1 4.70
March-23
6.40
6.30
3.86
4.50
4.10
4.50
4.20
4.80
5.00
November-22
5.60
3.86
4.20
6.00
1 3.67
4.10
3.70
4.40
4.70
July-22
6.40
5.10
5.30
1 4.20
4.60
4.00
5.10
4.90
TOC 10
9
July-24
27.2
March-24
39.1
November-23
30.6
July-23
46.9
March-23
33
November-22
27.6
July-22
45.1
Chloride 250
10A
14A
July-24
309
368
March-24
305
375
November-23
322
316
July-23
337
1 361
March-23
350
November-22
305
350
July-22
261
356
Sulfate 250
14A
July-24
325
March-24
494
November-23
July-23
357
March-23
375
November-22
July-22
287

SUBMIT FORM ON YELLOW PAPER ONLY
■ 0MITIrsIDEPARTMENT
OF ENVIRONMENT 8, NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING:
DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
0
1617 MAIL SERVICE CENTER, RALEIGH, INC 27699-1617 Phone: [phone]
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: WQ0000485 Expiration Date: 3/31/2025
Facility Name:
Darling Ingredients - Rose Hill
Non -Discharge UIC
NPDES Other
Permit Name (if different):
Facility Address:
469 Yellow Cut Rd
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
Rose Hill, NC 28458 County Duplin
., (State)
(zip)
X Spray Field ❑ Remediation:
Contact Person. Corey Lanier
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name
No. of wells to be sampled: 11
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): Ill
Date sample collected: 7/5/2024
FIELD ANALYSES:
WAS
Well Depth: 12.46 ft.
Well Diameter: 2 in.
pH4500HB 5.00 units Temp. 000lo: 23.9 °G
DRY at
Depth to Water Level 82546: 7.0
Screened Interval: 12.46 ft. to 2.46 ft. Spec. Cond. 00094: µMhos
time of
Measuring Point is 1.17 ft. above land surface
Relative M.P. Elevation: ft.
Odor 00085: N/D
sampling,
check
Volume of water pumped/bailed before sampling:
5.0
gallons
Appearance Clear
here
El
Samples for metals were collected unfiltered:
X YES ❑ NO and field acidified: X YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: 07/05/2024-07/18/2024
Laboratory Name Environmental Chemists, Inc. Certification No. DWQ#94
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615 <0.02
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 <1.0
/100mL
Nitrate (NO3) as N 00620 0.23
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665 <0.04
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 115.00
mg/L
Al -Aluminum 01105
mg/L Sodium 9.03 m /L
pH (Lab) 00403 5.00
units
Ba - Barium 01007
ug/L
TOC 00680 0.9
mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 5
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 48
mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? 0 Yes (0) ❑ No (0)
pecific Conductance 00095
µMhos
K - Potassium 00937
mg/L VOC 78732: method # SM 6200C
Total Ammonia 00610 <0.2
mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese 01056
ug/L method #
TKN as N 00625 <0.5
mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs
Thomas Tyner - General Manager
Permittee (or Authorized Aqent) Name and Title - Please print or tvpe
Effluent.. •
?te, and that the laboratory analytical data was
�s lbllity of fines and imprisonment for knowing
00,0WOR.'', . 1
mg/L VOC Removal%
(Date
GW-59 Rev.8/2013

SUBMIT FORM ON YELLOW PAPER ONLY
i
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING:
DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: WQ0000485 Expiration Date: 3/31/2025
Facility Name:
Darling Ingredients
- Rose Hill
Non -Discharge UIC
NPDES Other
Permit Name (if different):
Facility Address:
469 Yellow Cut Rd.
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
Rose Hill, NC 28458 County Duplin
(city) (State)
_ii ..
X Spray Field ❑ Remediation:
Contact Person: Corey Lanier
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name
No. of wells to be sampled: 11
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-2
Date sample collected: 7/5/2024
FIELD ANALYSES:
WAS
Well Depth: 31.00 ft.
Well Diameter: 2 in.
pH4500HB 6.40 units Temp. 000lo: 21.4 oC
DRY at
Depth to Water Level 82546: 15.7 ft. below measuring point
Screened Interval: 30.15 ft. to 20.15ft. Spec. Cond. 00094: µMhos
time of
Measuring Point is 3 ft. above land surface
Relative M.P. Elevation: ft.
Odor 00085: N/D
sampling,
check
Volume of water pumped/bailed before sampling:
5.0
gallons
Appearance Clear
here:
Samples for metals were collected unfiltered:
X YES ❑
NO and field acidified X YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: 07/05/2024-07/18/2024
Laboratory Name: Environmental Chemists, Inc. Certification No. DWQ#94
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615 <0.02
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 <1.0
/100mL
Nitrate (NO3) as N 00620 0.34
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL Phosphorus: Total as P 00665 0.09
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids -.Total 70300 241.00
mg/L
Al -Aluminum oilo5
mg/L Sodium 12.6 m /L
pH (Lab) 00403 6.40
units
Ba - Barium 01007
ug/L
TOC 00660 1.3
mg/L
Ca - Calcium oo916
mg/L
Chloride 00940 13
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 25
mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? 0 Yes (0) ❑ No (0)
pecific Conductance 00095
µMhos
K - Potassium 00937
mg/L VOC 76732: method # SM 6200C
Total Ammonia 00610 <0.2
mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH3as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L method #
TKN as N 00625 <0.5
mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
Thomas Tyner - General Manager
Permittee (or Authorized Anent) Name and Title - Please print or type
(or Authorized Anent)
Z3 �
(Date)
GW-59 Rev.8/2013

SUBMIT FORM ON YELLOW PAPER ONLY
■
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING:
DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
o
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION
Please Print CleaHyorType
PERMIT Number: WQ0000485 Expiration Date: 3/31/2025
Facility Name:
Darling Ingredients
- Rose Hill
Non -Discharge UIC
NPDES Other
Permit Name (if different):
Facility Address:
469
Yellow Cut Rd.
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
Rose Hill NC 28458 County
Duplin
(City) (State)
X Spray Field ❑ Remediation:
Contact Person: Corey Lanier
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name
No. of wells to be sampled: 11
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-4
Date sample collected:
7/5/2024 FIELD ANALYSES:
WAS
Well Depth: 28.93 ft.
Well Diameter:
2 in. pH4500HB 6.60 units Temp. 000lo: 14.4 oC
DRY at
Depth to Water Level 82546: 8.7 ft. below measuring point
Screened Interval:
28.93 ft. to 18.93 ft. Spec. Cond. 00094: µMhos
time of
Measuring Point is 3 ft. above land surface
Relative M.P. Elevation:
ft. Odor 00085: N/D
sampling,
check
Volume of water pumped/bailed before sampling:
5.0
gallons
Appearance Clear
here:
Samples for metals were collected unfiltered:
X YES ❑ NO and field acidified: X YES ❑ NO
LABORATORY INFORMATION
Date sample analvzed: 07/05/2024-07/18/2024
Laboratory Name:
Environmental Chemists, Inc. Certification No. DWQ#94
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615
<0 02 mg/L Pb - Lead o1o51 ug/L
Coliform: MF Fecal 31616 <1
/100mL
Nitrate (NO3) as N 00620
0.02 mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665
0.17 mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 236.00
mg/L
Al -Aluminum 01105
mg/L Sodium 9.16 m /L
pH (Lab) 00403 6.60
units
Ba - Barium 01007
ug/L
TOC 00680 <0.5
mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 <5.0
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 <5.0
mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? E Yes (0) ❑ No (0)
pecific Conductance 00095
µMhos
K - Potassium 00937
mg/L VOC 78732: method # SM 6200C
Total Ammonia 00610 <0.2
mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L method #
TKN as N 00625 <0.5
mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOC& mg/L Effluent Total VOCs: mg/L VOC Removal%
Thomas Tyner - General Manager
Permittee (or Authorized Aqent) Name and Title - Please print or type
Siq ture of PernnitWe (or Authorized Aqent)
'Y/ 2 3/ ZD
(Date)
GW-59 Rev.8/2013

• •
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING:
DIVISION OF WATER RESOURCES -INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
• • •
•
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: W00000485 Expiration Date: 3/31/2G25
Facility Name:
Darling Ingredients - Rose Hill
Non -Discharge UIC
Permit Name (if different):
NPDES Other
Facility Address:
469 Yellow Cut Rd.
TYPE OF PERMITTED OPERATION BEING MONITORED
Rose Hill NC 28458
County Duplin
❑ Lagoon ❑ Remediation: Infiltration Gallery
(City) (81.1=)
X Spray Field ❑ Remediation:
Contact Person: Corey Lanier
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:
_
No. of wells to be sampled: 11
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-7A
Date sample collected: 7/5/2024
FIELD ANALYSES:
WAS
Well Depth: 16 ft.
Well Diameter: 2 in.
pH4500HB 5.00 units Temp. 000lo: 15.8 oC
DRY at
Depth to Water Level 82546: 5.2 ft. below measuring point
Screened Interval: 16 ft, to
6 ft. Spec. Cond. 00094: µMhos
time of
Measuring Point is 2.42 ft. above land surface
Relative M.P. Elevation: ft.
Odor 00085: N/D
sampling,
check
Volume of water pumped/bailed before sampling:
5.0
gallons
Appearance Clear/Tan
here:
Samples for metals were collected unfiltered:
X YES ❑
NO and field acidified: X YES ElNO
LABORATORY INFORMATION
Date sample analyzed:_ 07/05/2024-07/18/2024
Laboratory Name: _ Environmental Chemists, Inc. Certification No. DWQ#94
PARAMETERS NOTE: Values should reflect
dissolved and
colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N oo615 <0.02
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 <1
/100mL
Nitrate (NO3) as N 00620 <0.02
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL Phosphorus: Total as P 00665 0.08
mg/L
(Note: Use MPN method For highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
)issolved Solids:Total 70300 122.00
mg/L
Al - Aluminum o11o5
mg/L Sodium 24.4 mg/L
pH (Lab) 00403 5.00
units
Ba - Barium 01007
ug/L
TOC 00680 0.7
mg/L
Ca - Calcium oo916
mg/L
Chloride oog4o 83
mg/L
Cd - Cadmium 01027.
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 26
mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? N Yes (0) ❑ No (0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L VOC 78732: method # SM 6200C
Total Ammonia 00610 <0.2
mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L , method #
TKN as N 00625 <0_5
mg/L
Ni - Nickel 01067.
ug/L method #
For Remediation Systems Only (Attach Lab Reports)- Influent I otaI VOCs: mg/L Emuent 1 otml VUC:s:
mgn. ❑tuL, rcenrl
1 Cerlify Thai. 10 the Lest of my knmvledge and ballet. the In;omlall ion submitted in Ihis raport is true. accurate and Complete, and Ih"t the lahoralwy onalylical dale was produced using approved melho6 or analysiv. ya;:
DWR-cerf[Fred lagdral8ry I am aware that there am 5igndicdnt penallies for subrliIting false Informal Ion. Including the posmbility or fines and impriwurnonl forW"ing Violations:
Thomas Tyner - General Manager
Permittee (or Authorized Agent) Name and Title - Please print or type
Agent)
(Date)

DEPARTMENT OF ENVIRONMENT d NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING:
DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION
Please Print Clearty or Type
PERMIT Number: WQ0000485 Expiration Date: 3/31/2025
Facility Name:
Darling Ingredients - Rose Hill
Non -Discharge UIC
NPDES Other
Permit Name (if different):
Facility Address:
469 Yellow Cut Rd.
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
Rose Hill, NC 28458 County Duplin
(City) SUS
(zip)
X Spray Field ❑ Remediation:
Contact Person: Corey Lanier
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Field 5 -damaged by
farm eaui / to replace No. of wells to be sampled: 11
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit):
MW-8A
Date sample collected: 7/5/2024
FIELD ANALYSES:
WAS
Well Depth: 16 ft.
Well Diameter: 2 in.
pH4500HB 4.40 units Temp. 000lo: 24.9 °C
DRY at
Depth to Water Level 62546: 7.5 ft. below measuring point
Screened Interval: 16 ft. to
6 ft. Spec. Cond. 00094: µMhos
time of
sampling,
Measuring Point is 2.5 ft. above land
surface
Relative M.P. Elevation: ft.
Odor 00085: N/D
cheek
Volume of water pumped/bailed before Sam
0_ 5.0
gallons
Appearance Clear/Tan
Samples for metals were collected unfiltered:
X YES L
NO and field acidified: X YES NO
El -
LABORATORY INFORMATION
Date sample analyzed: 07/05/2024-07/18/2024
Laboratory Name: Environmental Chemists, Inc. Certification No. DWQ#94
PARAMETERS NOTE: Values should reflect dissolved and
colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N oo615 0.02
mg/L Pb - Lead o1o51 ug/L
Coliform: MF Fecal 31616 <1.0
/100mL
Nitrate (NO3) as N 00620 1.33
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL Phosphorus: Total as P 00665 0.29
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 733.00
mg/L
Al - Aluminum 01105
mg/L Sodium 2.87 mg/L
pH (Lab) 00403 4.40
units
Ba - Barium 01007
ug/L
TOC 00680 0.80
mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 7
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 22
mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? E Yes (0) ❑ No (0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L VOC 76732: method # SM 6200C
Total Ammonia oo6lo <0.2
mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L , method #
TKN as N 00625 0.5
mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent I otal VUUS. mglL Emi uenr Toral vut.s rrigrL V V� r1C111UV0J 10
Thomas Tyner - General Manager
Permittee (or Authorized Agent) Name and Title - Please print or type

DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING:
�1617
DIVISION OF WATER RESOURCES -INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: WQ0000485 Expiration Date: 3/31/2025
Facility Name:
Darling Ingredients - Rose Hill
Non -Discharge UIC
NPDES Other
Permit Name (if different):
Facility Address:
469 Yellow Cut Rd.
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
Rose Hill, NC 28458 County Duplin
(City) (State)
(zip)
X Spray Field ❑ Remediation:
Contact Person: Corey Lanier
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:
No. of wells to be sampled: 11
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-9
Date sample collected: 7/5/2024
FIELD ANALYSES:
WAS
Well Depth: 13.73 ft.
Well Diameter: 2 in.
pH4500HB 5.90 units Temp. 000lo: 22.3 oC
DRY at
Depth to Water Level 82546: 8.3 ft. below measuring point Screened Interval: 13.73 ft. to
3.73 ft. Spec. Cond. 00094: _tMhos
time of
sampling,
Measuring Point is 3.80 ft. above land surface
Relative M.P. Elevation: ft.
Odor 00085: N/D
check
Volume of water pumped/bailed before sampling:
5.0
gallons
Appearance Tan
here:
Samples for metals were collected unfiltered:
X YES ❑ NO and field acidified: X YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed. 07/05/2024-07/18/2024
Laboratory Name: Environmental Chemists, Inc. Certification No. DWQ#94
PARAMETERS NOTE: Values should reflect
dissolved
and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N oo615 0.12
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 <1.0
/100mL
Nitrate (NO3) as N 00620 0.16
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665 0.28
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units)-
issolved Solids:Total 70300 309.00
mg/L
Al - Aluminum 01105
mg/L Sodium 9.32 mg/L
pH (Lab) 00403 5.90
units
Ba - Barium 01007
ug/L
TOC 00680 27.2
mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 28
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 18
mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? ■ Yes (0) ❑ No (0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L VOC 78732: method # SM 6200C
Total Ammonia 00610 <0.2
mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH3as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L , method #
TKN as N 00625 1.6
mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent -total VOUs: mg1L Lttluent I otaI vuus: mgrL vv►. mernvvat7o
Thomas Tyner - General Manager
Permittee (or Authorized Agent) Name and Title - Please print or type

DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING:
DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: WQ0000485 Expiration Date: 3/31/2025
Facility Name:
Darling Ingredients - Rose Hill
Non -Discharge UIC
NPDES Other
Permit Name (if different):
Facility Address:
469 Yellow Cut Rd.
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
Bose Hill, NC 28458 County Duplin
(City)
X Spray Field ❑ Remediation-
Contact Person: Corey Lanier
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:
No. of wells to be sampled: 11
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-10A
Date sample collected: 7/5/2024
FIELD ANALYSES:
WAS
Well Depth: 16 ft.
Well Diameter: 2 in.
pH4500HB 3.90 units Temp. 000lc 24N °C I
DRY at
Depth to Water Level 82546: 6.7 ft. below measuring
point
Screened Interval: 16 ft. to
6 ft. Spec. Cond. 00094: µMhos
time of
sampling,
Measuring Point is 3 ft. above land surface
Relative M.P. Elevation: ft.
Odor 00035: N/D
check
Volume of water pumped/bailed before sampling:
5.0
gallons
Appearance Clear/Tan
here:
Samples for metals were collected unfiltered:
X YES ❑
NO and field acidified: X YES ElNO
LABORATORY INFORMATION
Date sample analyzed: 07/05/2024-07/18/2024
Laboratory Name: Environmental Chemists, Inc. Certification No. DWQ#94
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615 <0.02
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 <1
/100mL
Nitrate (NO3) as N 00620 0.05
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL Phosphorus: Total as P 00665 0.26
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 946.00
mg/L
At -Aluminum olim
mg/L Sodium 120 m /L
pH (Lab) 00403 3.90
units
Ba - Barium 01007
ug/L
TOC 00630 3.8
mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 309
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 141
mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? Yes (0) ❑ No(0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L VOC 79732: method # SM 6200C
Total Ammonia 00610 0.40
mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH3as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L , method #
TKN as N 00625 0.90
mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): influent Total VOCs:
Thomas Tvner - General
Permittee (or Authorized Agent) Name and Title - Please print or type
mg/L Lttluent I otal VUL:s:
Authorized Agent)
Z
mglL vvt- memoval'7n
(Date)

❑EPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING:
DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: WQ0000485 Expiration Date. 3/31/2025
Facility Name.
Darling Ingredients
- Rose Hill
Non -Discharge UIC
NPDES Other
Permit Name (if different):
Facility Address:
469 Yellow Cut Rd.
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
Rose Hill, NC 28458 County Du lin
(stse)
oF'
X Spray Field ❑ Remediation:
Contact Person: Corey Lanier
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name.
No. of wells to be sampled: 11
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-11A
Date sample collected. 7/5/2024
FIELD ANALYSES:
WAS
Well Depth: 16 ft.
Well Diameter: 2 in.
pH4500HB 4.60 units Temp. 000lc 24.6 oC
DRY at
Depth to Water Level 82546: 9.3
Screened Interval: 16 ft. to
6 ft. Spec. Cond. 00094: µMhos
time of
Measuring Point is 3.3 ft. above land surface
Relative M.P. Elevation: ft.
Odor 00085: N/D
sampling,
check
Volume of water pumped/bailed before sampling:
5.0
gallons
Appearance Clear
here:
Samples for metals were collected unfiltered:
X YES ❑ NO and field acidified: X YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: 07/0512024-07/18/2024
Laboratory Name: Environmental Chemists. Inc. Certification No. DWQ#94
PARAMETERS NOTE: Values should reflect
dissolved
and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615 <0.02
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 <1.0
/100mL
Nitrate (NO3) as N 00620 0.1
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665 0.29
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 571.00
mg/L
Al - Aluminum 01105
mg/L Sodium 73.1 mg/L
pH (Lab) 00403 4.60
units
Ba - Barium 01007
ug/L
TOC 00680 2.50
mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 140
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
uglL
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 158.0
mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? M Yes (0) ❑ No (0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L VOC 78732: method # SM 6200C
Total Ammonia 00610 <0.2
mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; N1­13as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L , method #
TKN as N 00625 <0.50
mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VUC:S: mg1L t"went [oral vuL s: rrigiL VUtr MuniuVdi.n
Permittee (or Authorized Agent) Name and Title - Please print or type

DEPARTMENT OF ENVIRONMENT E NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING:
_
DIVI5IDN OF WATER RESOURCES - INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: WQ0000485 Expiration Date 3/31/2025
Facility Name:
Darling Ingredients
- Rose Hill
Non -Discharge UIC
NI'DES Other
Permit Name (if different):
Facility Address:
469 Yellow Cut Rd.
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
Rose Hill, NC 28458 County Duplin
(city) (State)
(zip)
X Spray Field ❑ Remediation:
Contact Person: Corey Lanier
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:
No. of wells to be sampled: 11
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-12B
Date sample collected: 7/5/2024
FIELD ANALYSES:
WAS
Well Depth: 16 ft.
Well Diameter: 2 in.
pH4500HB: 5.00 units Temp. 000lo: 25.2 uC
DRY at
Depth to Water Level 82546: 7.8 ft. below measuring point
Screened Interval: 20 ft. to
10 ft. Spec. Cond. 00094: µMhos
time of
Measuring Point is 3 ft. above land surface
Relative M.P. Elevation: ft.
Odor 00085: N/D
sampling,
check
Volume of water pumped/bailed before sampling:
6.0
gallons
Appearance Clear
here:
Samples for metals were collected unfiltered:
X YES
NO and field acidified: X YES Lj NO
LABORATORY INFORMATION
Date sample analyzed: 07/05/2024-07/18/2024
Laboratory Name: Environmental Chemists, Inc. Certification No. DWQ#94
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615 <0.02
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 <1
/100mL
Nitrate (NO3) as N 00620 0.08
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL Phosphorus: Total as P 00665 0.62
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 428.00
mg/L
Al - Aluminum oil o5
mg/L Sodium 43.7 m /L
pH (Lab) 00403 5.00
units
Ba - Barium 01007
ug/L
TOC 00680 1.50
mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 108
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 124
mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? 0 Yes (0) ❑ No (0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L VOC 78732: method # SM 6200C
Total Ammonia o0810 <0.2
mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L , method #
TKN as N 00625 <0.5
mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs. mg/L Effluent Z otai VOGs:
mg/L VUG KemOVal7o
{ certify Thal to the best of my knowledge and belief- the information submitted in this report is true accurate and complete- and that the laboratory analytical data was produced using approved methods of analysis by a
D'NR-certified laboratory I am aware that there are significant penalliea for submitling. false information. IncluRing the possiWily of fines and imprisonment for knowmn violations
Thomas Tyner - General Manager
Pennittee (or Authorized Agent) Name and Title - Please print or type
Agent)
(Date)

DEPARTMENT OF ENVIRONMENT 8. NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING:
_
DIVISION OF WATER RESOURCES -INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: W00000485 Expiration Date: 3/31/2025
Facility Name:
Darling Ingredients - Rose Hill
Non -Discharge UIC
NPOES Other
Permit Name (if different):
Facility Address:
469 Yellow Cut Rd.
TYPE OF PERMITTED OPERATION BEING MONITORED
Rose Hill NC 2W&
County Duplin
❑ Lagoon ❑ Remediation: Infiltration Gallery
(city) (sloe.)
X Spray Field ❑ Remediation:
Contact Person: Corey Lanier
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:
No. of wells to be sampled: 11
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-13A
Date sample collected: 7/5/2024
FIELD ANALYSES:
WAS
Well Depth: 16 ft.
Well Diameter: 2 in.
pH4500HB 5.90 units Temp. 000lo: 26.5 oC
DRY at
Depth to Water Level 82546: 8.6 ft. below measuring point
Screened Interval: 16 ft. to
6 ft. Spec. Cond. 00094: µMhos
time of
Measuring Point is 3 ft. above land surface
Relative M.P. Elevation: ft.
Odor 00085: N/D
sampling,
check
Volume of water um ed/bailed before sampling:
p p p
5.0
gallons
A
Appearance Clear
here:
Samples for metals were collected unfiltered:
X YES Lj
NO and field acidified: X YES NO
LABORATORY INFORMATION
Date sample analyzed: 07/05/2024-07/18/2024
Laboratory Name: Environmental Chemists, Inc. Certification No. DWQ#94
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N oo615 0.03
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 <1
/100mL
Nitrate (NO3) as N 00620. <0.02
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL Phosphorus:
Total as P 00665 0.10
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 41.00
mg/L
Al - Aluminum ollo5
mg/L Sodium 4.97 mg/L
pH (Lab) 00403 5.90
units
Ba - Barium 01007
ug/L
TOC oo68o <0.5
mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 <5
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
uglL
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 5.00
mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? 0 Yes (0) ❑ No (0)
pecific Conductance 00095
µMhos
K - Potassium 00937
mg/L VOC 78732: method # SM 6200C
Total Ammonia 000lo <0 20
mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; N%as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L method #
TKN as N 00625 <0.50
mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent T otal VOGs: mg/L Ettluent iota[ vuus PITS vest, removal io
Thomas Tyner - General Manager
Pennittee (or Authorized Agent) Name and Title - Please print or type

M
PEPARTMENT OF ENVIRONMENT 3 NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING:
a 8
0
131VISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1611 MAIL SERVICE CENTER, RALEIGH, NC 276994617 Phone: [phone]
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: WQ0000485 Expiration Date 3/31/2025
Facility Name-
Darling Ingredients - Rose Hill
Non -Discharge UIC
Permit Name (if different):
NPDES Other
Facility Address:
469 Yellow Cut Rd.
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
Rose Hill, NC 28458 County DUDIIn
airy, (811W
X Spray Field ❑ Remediation:
Contact Person- Corey Lanier
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:
No. of wells to be sampled: 11
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit):
MW-14A
Date sample collected: 7/5/2024
FIELD ANALYSES:
WAS
Well Depth: 16 ft.
Well Diameter: 2 in.
pH4500HB 4.80 units Temp. 000lc 25.6 oC
DRY at
Depth to Water Level 82546: 7.3 ft. below
measuring point
Screened Interval: 10 ft. to
2.5 ft. Spec. Cond. 00094: µMhos
time of
Measuring Point is 3 ft. above land surface
Relative M.P Elevation: ft.
Odor 000m: N/D
sampling,
check
Volume of water pumped/bailed before sampling:
5.0
gallons
Appearance Clear /Tan
here:
Samples for metals were collected unfiltered:
X YES ❑
NO and field acidified: X YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: 07/0512024-07/18/2024
Laboratory Name: Environmental Chemists, Inc. Certification No DWQ#94
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615 <0.02
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 <1.0
/100mL
Nitrate (NO3) as N 00620 1.47
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL Phosphorus: Total as P 00665 0.05
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
)issolved Solids:Total 70300 1430.00
mg/L
Al - Aluminum ol1o5
mg/L Sodium 325 mg/L
pH (Lab) 00403 4.80
units
Ba - Barium 01007
ug/L
TOC 00680 4.50
mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 368
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 325
mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? ■ Yes (0) ❑ No(0)
Specific Conductance 00095
JiMhas
K - Potassium 00937
mg/L VOC 78732: method # SM 6200C
Total Ammonia 00610 <0.20
mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L , method #
TKN as N 00625 0.60
mg/L
Ni - Nickel o1o67
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mglL Effluent Total VOU$: mgn- vVU Kemoval to
Thomas Tyner - General Manager
Permittee (or Authorized Agent) Name and Title - Please print or type

envirochem
L�---
ANALYTICAL S CONSULTING CHEMISTS
Environmental Chemists, Inc.
6602 Windmill Way, Wilmington, NC 28405 • 910.392.0223 Lab o 910.392.4424 Fax
710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax
255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax
[e-mail]
Darling Ingredients - Rose Hill
Post Office Box 1026
Rose Hill NC 28458
Attention:
Revised Report: Aug 20, 2024
Original Report Date: Jul 18, 2024
Reportt 2024-15321
Customer ID: 08100027
Project ID: July - Monitoring Wells
Lab ID Sample ID:
Collect DateITime Matrix Sampled by
24-37727 Site: MW-1
7/5/2024
10:55 AM Water jcb/envirochem
Test
Method
Results Date Analyzed
Color
Color
Clear
07/05/2024
Depth to water, ft.
Depth to Water. Ft
7.0 feet
07/05/2024
Sodium
EPA 200.7. Rev 4A.1994
9.03 mg/L
07/11/2024
Sulfate
EPA 300.0. Rev. 2.1. 1993
48 mg/L
07/08/2024
Ammonia Nitrogen
EPA 350.1, Rev. 2.0, 1993
< 0.2 mg/L
07/08/2024
Gallons bailed before sampling
Gallons Bailed before sampling
5.0 gallons
07/05/2024
Odor
Quardative
N/D
07/05/2024
Total Dissolved Solids (TDS)
SM 2540 C-2015
115 mg/L
07/08/2024
Temperature
SM 2550 B-2010
23.9 C
07/05/2024
pH
SM 4500 H 8-2011
5.0 units
07/05/2024
Total Phosphorus
SM 4500 P (F-H)•2011
< 0.04 mg/L
07/11/2024
Total Organic Carbon (TOC)
SM 6310 B-2014
0.9 mg/L
07/09/2024
Fecal Coliform
SM 9222 D-2015 MF
<1 Colonies/100mL
07/05/2024
Chloride
SM4500 a E-2011
5 mg/L
07/08/2024
Nitrate Nitrogen (Calc)
Nitrite Nitrogen
EPA 353.2, Rev. 2.0. 1993
< 0.02 mg/L
07/05/2024
Nitrate+Nitrite-Nitrogen
EPA 353.2, Rev. 2.0. 1993
0.23 mg/L
07110/2024
Nitrate Nitrogen
Subtraction Method
0.23 mg1L
07/05/2024
Total Nitrogen (Calc)
Total Kjeldahl Nitrogen (TKN)
EPA 351.2, Rev. 2.0,1993
< 0.5 mg/L
07/11/2024
Total Nitrogen
Total Nitrogen
<0.5 mg/L
07/18/2024
Reporttk; 2024.15321 �— Page 1 of 11

F"007
envirochem
ANALYTICAL & CONSULTING CHEMISTS
Darling Ingredients - Rose Hill
Post Office Box 1026
Rose Hill NC 28458
Attention:
Lab ID Sample ID:
24-37728 Site: MW-2
Test
Color
Depth to water, fL
Sodium
Sulfate
Ammonia Nitrogen
Gallons bailed before sampling
Odor
Total Dissolved Solids (TDS)
Temperature
pH
Total Phosphorus
Total Organic Carbon (TOC)
Fecal Coliform
Chloride
Nitrate Nitrogen (Cale)
Nitrite Nitrogen
Ndrate+Nib ite-Nitrogen
Nitrate Nitrogen
Total Nitrogen (Cale)
Total Kjeldahl Nitrogen (TKN)
Total Nitrogen
Environmental Chemists, Inc.
6602 Windmill Way, Wilmington, NC 28405 • 910.392.0223 Lab * 910.392.4424 Fax
710 Bowsertown Road, Manteo, NC 27954 - 252A73.5702 Lab/Fax
255-A Wilmington Highway, Jacksonville, NC 28540 a 910.347.5843 Lab/Fax
info@environmentalchemistLCom
Revised Report: Aug 20, 2024
Original Report Date: Jul 18, 2024
Report 0: 2024-15321
Customer ID: 08100027
Project ID: July - Monitoring Wells
Collect DateMme Matrix
7/5/2024 10:35 AM Water
Method
Color
Depth to water, Ft,
EPA 200.7, Rev 4.4, 1994
EPA 300.0, Rev_ 2.1.1993
EPA 350.1, Rev. 2.0,1993
Galom Bailed before samprmg
Qualitative
SM 2540 C-2015
SM 2550 8-2010
SM 4500 H B-2011
SM 4500 P (F-Fij 2011
SM 5310 B-2014
SM 9222 D-2016 MF
SM4500 Cl E-2011
EPA 353.2, Rev. 2.0,1993
EPA 353.2, Rev. 2.0, 1993
Subtraction Method
EPA 351.2, Rev. 2.0.1993
Total Nitrogen
Results
Sampled by
jcb/envirochem
Date Analyzed
Clear
07/05/2024
15.7 feet
07/05/2024
12.6 mg/L
07/11/2024
25 mg/L
07/08/2024
< 0.2 mg/L
07/08/2024
5.0 gallons
07/05/2024
N/D
07/05/2024
241 mg/L
07/08/2024
21.4 C
07/05/2024
6.4 units
07/05/2024
0.09 mg/L
07/11/2024
1.3 mg/L
07/09/2024
<1 Colonies/100mL 07/05/2024
13 mg/L
07/08/2024
< 0.02 mg/L
07/05/2024
0.34 mg/L
07/10/2024
0.34 mg/L
07/05/2024
< 0.5 mglL 07/11/2024
<0.5 mg/L 07/18/2024
Report M: 2024-15321 Page 2 of 111

envirochem
ANALYTICAL & CONSULTING CHEMISTS
Darling Ingredients - Rose Hill
Post Office Box 1026
Rose Hill NC 28458
Attention:
Lab ID Sample ID:
24-37729 Site: MW4
Test
Color
Depth to water, ft.
Sodium
Sulfate
Ammonia Nitrogen
Gallons bailed before sampling
Odor
Total Dissolved Solids (TDS)
Temperature
PH
Total Phosphorus
Total Organic Carbon (TOC)
Fecal Coliform
Chloride
Nitrate Nitrogen (Cale)
Nitrite Nitrogen
Nitrate+Nitrite-Nitrogen
Nitrate Nitrogen
Total Nitrogen (Cale)
Total Kieldahl Nitrogen (TKN)
Total Nitrogen
Environmental Chemists, Inc
6602 Windmill Way, Wilmington, NC 28405 - 910.392.0223 Lab • 910.392.4424 Fax
710 Bowsertown Road, Manteo, NC 27954 a 252.473.5702 Lab/Fax
255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax
[e-mail]
Revised Report: Aug 20, 2024
Original Report Date: Jul 18, 2024
Report 0: 2024-15321
Customer ID: 08100027
Project ID: July - Monitoring Wells
Collect Date/Time Matrix
7/5/2024 10:20 AM Water
Method
Color
Depth to Water, FL
EPA 200.7. Rev 4.4. 1004
EPA 300.0, Rev, 2.1, 1093
EPA 350.1, Rev. 2.0, 1903
Gallons Bailed before sampling
Qualitative
SM 2540 C-2015
SM 2550 B-2010
SM 4500 H B-2011
SM 4500 P (F•H)•2011
SM 6310 B-2014
SM 9222 D-2015 MF
SM4500 Cl E-2011
EPA 353.2. Rev. 2.0, 1093
EPA 353.2. Rev, 2.0, 1993
Subtraction Method
EPA 361.2, Rev_ 2.0, 1993
Total Nitrogen
Results
Sampled by
jcb/envirochem
Date Analyzed
Clear
07/05/2024
8.7 feet
07/05/2024
9.16 mg/L
07/11/2024
<5 mg1L
07/08/2024
< 0.2 mg/L
07/08/2024
5.0 gallons
07/05/2024
N/D
07/0512024
236 mg/L
07/08/2024
23.0 C
07/05/2024
6.6 units
07/05/2024
0.17 mg/L
07/11/2024
<0.5 mg/L
07/09/2024
<1 Colonies/100ml- 07/05/2024
< 5 mg/L
07/08/2024
< 0.02 mg/L
07/05/2024
0.02 mg/L
07/10/2024
0.02 mg/L
07/05/2024
< 0.5 mg/L 07/1112024
<0.5 mg/L 07/18/2024
Report k: 2024.15321 Page 3 of 11

F-' '-- - � - 17, Environmental Chemists, Inc.
'nvirochem 1 6602 Windmill Way, Wilmington, NC 28405 ■ 910.392.0223 Lab - 910.392.4424 Fax
710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax
255-A Wilmington Highway, Jacksonville, NC 28540 - 910.347.5843 Lab/Fax
ANALYTICAL & CONSULTING CHEMISTS [e-mail]
Darling Ingredients - Rose Hill
Post Office Box 1026
Rose Hill NC 28458
Attention:
Lab ID Sample ID:
24-37730 Site: MW-7A
Test
Color
Depth to water, ft.
Sodium
Sulfate
Ammonia Nitrogen
Gallons bailed before sampling
Odor
Total Dissolved Solids (TDS)
Temperature
pH
Total Phosphorus
Total Organic Carbon (TOG)
Fecal Coliform
Chloride
Nitrate Nitrogen (Calc)
Nitrite Nitrogen
Nitrate+Nitrite-Nitrogen
Nitrate Nitrogen
Total Nitrogen (Calc)
Total Kjeldahl Nitrogen (TKN)
Total Nitrogen
Revised Report: Aug 20, 2024
Original Report Date: Jul 18, 2024
Report S: 2024-15321
Customer ID: 08100027
Project ID: July - Monitoring Wells
Collect DatelTime Matrix
7/5/2024 11:30 AM Water
Method
Color
Depth to Water. Ft.
EPA 2001, Rev 4.4, 1994
EPA 300.0, Rev, 2.1, 1093
EPA 350.1. Rev. 2.0, 1993
Gallons Bailed before sampling
Qualitative
SM 2540 C-2015
SM 2560 S-2010
SM 4500 H B-2011
SM 4500 P (F-Hj 2011
SM 5310 B-2014
SM 9222 D-2015 MF
SM4500 Cl E-2011
EPA 353.2, Rev. 2.0,1993
EPA 353.2, Rev. 2.0,19M
Subtraction Method
EPA 351.2. Rev_ 2.0. 1993
Total Nitrogen
Results
Sampled by
jcb/envirochem
Date Analyzed
Clear/ran
07/05/2024
6.7 feet
07/05/2024
32.5 mg/L
07/11/2024
15 mg/L
07/08/2024
< 0.2 mg/L
07/08/2024
5.0 gallons
07/05/2024
N/D
07/05/2024
339 mg/L
07/08/2024
25.2 C
07/05/2024
3.6 units
07/05/2024
0.16 mg/L
07/11/2024
1.0 mg/L
07/09/2024
<1 Colonies/100ml- 07/05/2024
104 mg/L
07/08/2024
< 0.02 mg/L
07/06/2024
0.02 mg/L
07/10/2024
0.02 mg/L
07/05/2024
< 0.5 mg/L 07/11/2024
<0.5 mg/L 07/18/2024
Report f_ 2024-15321 Pape 4 of 11

F"P,P, -- 77 Environmental Chemists, Inc.
envirochem 6602 Windmill Way, Wilmington, NC 28405 • 910.392.0223 Lab • 910.392.4424 Fax
kL 710 Bowsertown Road, Manteo, NC 27954 • 252.473,5702 Lab/Fax
255-A Wilmington Highway, Jacksonville, NC 28540 • 910.3475843 Lab/Fax
ANALYTICAL & CONSULTING CHEMISTS [e-mail]
Darling Ingredients - Rose Hill
Post Office Box 1026
Rose Hill NC 28458
Attention:
Revised Report: Aug 20, 2024
Original Report Date: Jul 18, 2024
Report #: 2024-15321
Customer ID: 08100027
Project ID: July - Monitoring Wells
Lab ID Sample ID:
Collect Datelrime Matrix Sampled by
24-37731 Site: MW-8A
7/5/2024
11:45 AM Water jcb/envirochem
Test
Method
Results Date Analyzed
Color
Color
Clear/Tan
07/05/2024
Depth to water, ft.
Depth to water, Ft
7.5 feet
07/05/2024
Sodium
EPA200.7. Rev 4.4, 1994
2.87 mg/L
07/11/2024
Sulfate
EPA 300.0. Rev. 2.1, 1993
22 mg/L
07/08/2024
Ammonia Nitrogen
EPA 350.1. Rev. 2.0, 103
< 0.2 mg/L
07/08/2024
Gallons bailed before sampling
Gelb% Bailed before sampling
5.0 gallons
07/05/2024
Odor
Qualitative
N/D
07/05/2024
Total Dissolved Solids (TDS)
SM 2540 C-2015
733 mg/L
07/08/2024
Temperature
SM 2550 B-2010
24.9 C
07105/2024
pH
SM4500 H B-2011
4.4 units
07/05/2024
Total Phosphorus
SM4500 P (F-H}-2011
0.29 mg/L
07/11/2024
Total Organic Carbon (TOC)
SM 5310 B-2014
0.8 mg/L
07/08/2024
Fecal Coliform
SM 9222 D-2015 MF
<1 Colonies/100mL
07/05/2024
Chloride
SM4500 Cl E-2011
7 mg/L
07/08/2024
Nitrate Nitrogen (Cale)
Nitrite Nitrogen
EPA 353.2, Rev_ 20, 1993
0.02 mg/L
07105/2024
Nitrate+Nitrite-Nitrogen
EPA 353.2, Rev. 2.0,1993
1.35 mg/L
07/10/2024
Nitrate Nitrogen
Subtraction Method
1.33 mg/L
07/05/2024
Total Nitrogen (Cate)
Total Kjeldahl Nitrogen (TKN)
EPA 351.2. Rev. 2.0.1993
0.5 mg/L
07/11/2024
Total Nitrogen
Total Nitrogen
1.8 mg/L
07/18/2024
Report #:: 2024.15321 Page 5 of 11

ANALYTICAL & CONSULTING CHEMISTS
Environmental Chemists, Inc.
6602 Windmill Way, Wilmington, NC 28405 a 910.392.0223 Lab a 910.392.4424 Fax
710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax
255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax
info@environmentalchemistacom
Darling Ingredients - Rose Hill Revised Report: Aug 20, 2024
Post Office Box 1026 Original Report Date: Jul 18, 2024
Rose Hill NC 28458 Report 0: 2024-15321
Attention: Customer ID: 08100027
Project ID: July - Monitoring Wells
Lab ID Sample ID:
24-37732 Site: MW-9
Test
Collect Datefrime
7/5/2024 10:35 AM
Method
Matrix Sampled by
Water jcb/envirochem
Results Date Analyzed
Color
color
Tan
07/05/2024
Depth to water, ft.
Depth to water. Ft.
8.3 feet
07/05/2024
Sodium
EPA200.7. Rev 4.4. 1904
9.32 mg/L
07/11/2024
Sulfate
EPA 300.0. Rev. 2.1.1993
18 mg/L
07/08/2024
Ammonia Nitrogen
EPA 350.1. Rev. 2.0,1993
< 0.2 mg/L
07/08/2024
Gallons bailed before sampling
Gallons Bailed tpforesampling
5.0 gallons
07/05/2024
Odor
Qualitative
N/D
07/05/2024
Total Dissolved Solids (TDS)
SM 2540 C-2015
309 mg/L
07/08/2024
Temperature
SM 2550 B-2010
22.3 C
07/05/2024
pH
SM 4509 H B-2011
5.9 units
07/05/2024
Total Phosphorus
SM 4500 P {F-H}2011
0.28 mg/L
07/11/2024
Total Organic Carbon (TOC)
SM 5310 B-2014
27.2 mg/L
07109/2024
Fecal COliform
SM 9222 D-2015 MF
<1 Colonies/100ml-
07/05/2024
Chloride
SM4500 Cl E-2011
28 mg/L
07/08/2024
Nitrate Nitrogen (Cale)
Nitrite Nitrogen
EPA 353.2. Rev. 2.0,1993
0.12 mg/L
07/05/2024
Nitrate+Nitrite-Nitrogen
EPA 353.2. Rev. 2.0,1993
0.28 mg/L
07/10/2024
Nitrate Nitrogen
Subtraction Method
0.16 mg/L
07/05/2024
Total Nitrogen (Cale)
Total Kjeldahl Nitrogen (TKN)
EPA 3512. Rev. 2.0,1993
1.6 mg/L
07/11/2024
Total Nitrogen
Total "fin
1.9 mg/L
07/18/2024
Report*; 2024 -1 5321 Page 6 of 11

ANALYTICAL & CONSULTING CHEMISTS
Darling Ingredients - Rose Hill
Post Office Box 1026
Rose Hill NC 28458
Attention:
Environmental Chemists, Inc.
6W2 Windmill Way, Wilmington, NC 28405 . 910.392.0223 Lab • 910.392.4424 Fax
710 Bowsertown Road, Manteo, NC 27954 ■ 252.4733702 Lab/Fax
255-A Wilmington Highway, Jacksonville, NC 28540 a 910.347.5843 Lab/Fax
info@environtnentalchemismcom
Revised Report: Aug 20, 2024
Original Report Date: Jul 18, 2024
Report #: 2024-15321
Customer ID: 08100027
Project ID: July - Monitoring Wells
Lab ID Sample ID:
24-37733 Site: MW-10A
Test
Collect Datelrme
7/5/2024 10:00 AM
Method
Matrix Sampled by
Water jcb/envirochem
Results Date Analyzed
Color
color
Clear/Tan
07/05/2024
Depth to water, ft.
Depth to water, Ft,
6.7 feet
07/05/2024
Sodium
EPA 200.7, Rev 4A, 1994
120 mg/L
07/11/2024
Sulfate
EPA 300.0, Rev. Z1.1993
141 mg/L
07/09/2024
Ammonia Nitrogen
EPA 350.1. Rev. 2.0.1993
0.4 mg/L
07/08/2024
Gallons bailed before sampling
Gallons Baled before sampling
5.0 gallons
07105/2024
Odor
Qualitative
N/D
07/05/2024
Total Dissolved Solids (TDS)
SM 2540 C-2015
946 mg/L
07/08/2024
Temperature
SM 2550 B-2010
24.8 C
07/06/2024
pH
SM 45N H B-2011
3.9 units
07/05/2024
Total Phosphors
SM 4500 P (F-H)-2011
0.26 mg/L
07/11/2024
Total Organic Carbon (TOC)
SM 5310 B-2014
3.8 mg/L
07/08/2024
Fecal Coliform
SM 9222 D-2015 MF
<1 Colonies/100ml-
07/05/2024
Chloride
SM4500 G E 2011
309 mg/L
07/08/2024
Nitrate Nitrogen (Calc)
Nitrite Nitrogen
EPA 363.2, Rev. 2.0, 1993
< 0.02 mg/L
07/05/2024
Nitrate+Nitrite-Nitrogen
EPA 353.2, Rev. 2.0,1993
0.05 mg/L
07/10/2024
Nitrate Nitrogen
Subtra don Method
0.05 mg/L
07/05/2024
Total Nitrogen (Calc)
Total Kjeldahl Nitrogen (TKN)
EPA 351,2. Rev. 2.0,1993
0.9 mg/L
07/11/2024
Total Nitrogen
Total NWopen
1.0 mg/L
07/18/2024
Report #.,- 2024-15321 Page 7 of 11

Eenvirochem
ANALYTICAL & CONSULTING CHEMISTS
Darling Ingredients - Rose Hill
Post Office Box 1026
Rose Hill NC 28458
Attention:
Lab ID Sample ID:
24-37734 Site: MW-11A
Test
Color
Depth to water, ft.
Sodium
Sulfate
Ammonia Nitrogen
Gallons bailed before sampling
Odor
Total Dissolved Solids (TDS)
Temperature
pH
Total Phosphorus
Total Organic Carbon (TOC)
Fecal Coliform
Chloride
Nitrate Nitrogen {Cate
Nitrite Nitrogen
Nitrate+Nib ite-Nitrogen
Nitrate Nitrogen
Total Nitrogen (Cale)
Total Kjeldahl Nitrogen (TKN)
Total Nitrogen
Environmental Chemists, Inc.
6602 Windmill Way, Wilmington, NC 28405 • 910392.0223 Lab • 910.392.4424 Fax
710 Bowsertown Road, Manteo, NC 27954 + 252.473.5702 Lab/Fax
255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax
info@environmentalchemist&com
Revised Report: Aug 20, 2024
Original Report Date: Jul 18, 2024
Report #: 2024-15321
Customer ID: 08100027
Project ID: July - Monitoring Wells
Collect Date/Time Matrix
7/5/2024 9:45 AM Water
Method
Color
Depth to water. Ft
EPA 200.7. Rev 4.4, 1994
EPA 300.0, Rev. 21,1993
EPA 350.1, Rev. 2-0,1993
Gallons Bailed before sampling
Qualitative
SM 2540 C-2015
SM 2550 $-2010
SM 4500 H B-2011
SM 4500 P (F-li)4011
SM 5310 B-2014
SM 9222 D-2015 MF
SM4500 Cl E-2011
a
EPA 353.2, Rev. 2.0, 1993
EPA 353.2, Rev- 2.0, 1993
Subtraction Method
EPA351,2, I(ev. P-0,1993
Total Nltrogen
Results
Sampled by
jcb/envirochem
Date Analyzed
Clear
07/05/2024
9.3 feet
07/05/2024
73.1 mg/L
07/11/2024
158 mg/L
07/09/2024
< 0.2 mg/L
07/08/2024
5.Ogallons
07/05/2024
WD
07/05/2024
571 mg/L
07/08/2024
24.6 C
07/05/2024
4.6 units
07/05/2024
0.29 mg/L
07/11/2024
2.5 mg/L
07/08/2024
<1 Colonies/100mi- 07/05/2024
140 mg/L
07/08/2024
< 0.02 mg/L
07/05/2024
0.10 mg/L
07/10/2024
0.10 mg/L
07/05/2024
< 0.5 mg/L 07/11/2024
<0.5 mg/L 07/18/2024
Report lt_ 2024-15321 Page a of 11

[,envihroehem
ANALYTICAL & CONSULTING CHEMISTS
Darling Ingredients - Rose Hill
Post Office Box 1026
Rose Hill NC 28458
Attention:
Lab ID Sample ID:
24-37735 Site: MW-12B
Test
Color
Depth to water, ft.
Sodium
Sulfate
Ammonia Nitrogen
Gallons bailed before sampling
Odor
Total Dissolved Solids (TDS)
Temperature
pH
Total Phosphorus
Total Organic Carbon (TOG)
Fecal Coliform
Chloride
Nitrate Nitrogen (Calc)
Nitrite Nitrogen
Nitrate+N itrite-Nitrogen
Nitrate Nitrogen
Total Nitrogen (Calc)
Total Kjeldahl Nitrogen (TKN)
Total Nitrogen
Environmental Chemists, Inc.
6602 Windmill Way, Wilmington, NC 28405 • 910.392.0223 Lab • 910.392.4424 Fax
710 Bowsertown Road, Manteo, NC 27954 ° 252.473.5702 Lab/Fax
255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax
info@environmentalchemistscom
Revised Report: Aug 20, 2024
Original Report Date: Jul 18, 2024
Report 0: 2024-15321
Customer ID: 08100027
Project ID: July - Monitoring Wells
Collect Date/Time Matrix
7/5/2024 9:30 AM Water
Method
Color
Depth to Water, Ft.
EPA 200.7, Rev 4.4. 1094
EPA 300.0, Rev_ 2.1,1993
EPA 350.1, Rev_ 2..0, 1993
Gdons BaW before sampling
Qualitative
SM 2540 C-2015
SM 2550 B-2010
SM 4500 H B-2011
SM 4500 P (F-HY2011
SM 5310 8.2014
SM 9222 D-2015 MF
SM4500 CI E-2011
EPA 353.2, Rev, 2.0,1993
EPA 353.2, Rev. 2.0,1093
SubirwIlon Method
EPA 351.2, Rev. 20. 1993
Total Nitrogen
Results
Sampled by
jcb/envirochem
Date Analysed
Clear
07/05/2024
7.8 feet
07/05/2024
43.7 mg/L
07/11/2024
124 mg/L
07/09/2024
< 0.2 mg/L
07/08/2024
5.0 gallons
07/05/2024
N/D
07/05/2024
428 mg/L
07/08/2024
25.2 C
07/05/2024
5.0 units
07/05/2024
0.62 mg/L
07/11/2024
1.5 mg/L
07/08/2024
<1 Colonies/100ml-
07/05/2024
108 mg/L
07/08/2024
< 0.02 mg/L
07/05/2024
0.08 mg/L
07/10/2024
0.08 mg/L
07/05/2024
< 0.5 mg/L 07/11/2024
<0.5 mg/L 07/18/2024
Report*7 2024-15321 Page 9 of 11�

�k st LI 1►1'sU J r-Il jl-'A;ti
ANALYTICAL & CONSULTING CHEMISTS
Darling Ingredients - Rose Hill
Post Office Box 1026
Rose Hill NC 28458
Attention:
Environmental Chemists, Inc.
6602 Windmill Way, Wilmington, NC 28405 • 910.392.0223 Lab ■ 910.392.4424 Fax
710 Bowsertown Road, Manteo, NC 27954 0 252.473.5702 Lab/Fax
255-A Wilmington Highway, Jacksonville, NC 28540 + 910.347.5843 Lab/Fax
[e-mail]
Revised Report: Aug 20, 2024
Original Report Date: Jul 18, 2024
Report 0: 2024-15321
Customer ID: 08100027
Project ID: July - Monitoring Wells
Lab ID Sample ID: Collect DatelTime Matrix Sampled by
24-37736 Site: MW-13A 7/5/2024 9:15 AM Water jcb/envirochem
Test Method Results Date Analyzed
Color
Color
Clear
07/05/2024
Depth to water, ft.
Depth to water. Ft.
8.6 feet
07/05/2024
Sodium
EPA 200.7.Rev 4A,19N
4.97mg/L
07/11/2024
Sulfate
EPA 300.0, Rev. 2.1, 1993
5 mg/L
07/08/2024
Ammonia Nitrogen
EPA 350.1, Rev. 2.0, 1993
< 0.2 mg/L
07/08/2024
Gallons bailed before sampling
Gallons Bailed before sampling
5.0 gallons
07105/2024
Odor
Qualitative
N/D
07/05/2024
Total Dissolved Solids (TDS)
SM 2540 C-2015
41 mg/L
07/08/2024
Temperature
SM 2550 B-2010
26.5 C
07/05/2024
pH
SM 4500 H B-2011
5.9 units
07/05/2024
Total Phosphorus
SM 4500 P (F-H)-2011
0.10 mg/L
07111 /2024
Total Organic Carbon (TOC)
SM 5310 B-2014
<0.5 mg/L
07/08/2024
Fecal Coliform
SM 9222 D-2015 MF
<1 Colonies/100mL 07105/2024
Chloride
SM4500 Ci E-2011
< 5 mg/L
07/08/2024
Nitrate Nitrogen (Cale)
Nitrite Nitrogen
EPA 353.2, Rev- 2.0,1993
0.03 mg/L
07/05/2024
Nitmte+Nitrite-Nitrogen
EPA 353.2, Rev. 2.0,1993
0.03 mg/L
07/10/2024
Nitrate Nitrogen
Subtraction Method
<0.02 mg/L
07/05/2024
Total Nitrogen (Cale)
Total Kjeldahl Nitrogen (TKN)
EPA 351.2. Rev. 2.0,1903
< 0.5 mg/L
07/11/2-024
Total Nitrogen
Total Nitrogen
<0.5 mg/L
07/18/2024
Report*: 2024-15321 Page 10 of 11

envirochem
tsu
ANALYTICAL & CONSULTING CHEMISTS
Environmental Chemists, Inc.
6602 Windmill Way, Wilmington, NC 28405 - 910.392.0223 Lab - 910.392.4424 Fax
710 Bowsertown Road, Manteo, NC 27954 - 252.473,5702 Lab/Fax
255-A Wilmington Highway, Jacksonville, NC 28540 - 910.347.5843 Lab/Fax
[e-mail]
Darling Ingredients - Rose Hill
Post Office Box 1026
Rose Hill NC 28458
Attention:
Lab ID Sample ID:
24-37737 Site: MW-14A
Test
Revised Report: Aug 20, 2024
Original Report Date: Jul 18, 2024
Report #: 2024-15321
Customer ID: 08100027
Project ID: July - Monitoring Wells
Collect Date/Time Matrix Sampled by
7/5/2024 11:15 AM Water jcb/envirochem
Method Results Date Analyzed
Color
Color
Clear/Tan
07/05/2024
Depth to water, {t,
Depth to water, Ft
7.3 feet
07/05/2024
Sodium
EPA200.7, Rev 4.4. 1904
125 mg/L
07/11/2024
Sulfate
EPA 300.0, Rev. 2.1, 1993
325 mg/L
07/09/2024
Ammonia Nitrogen
EPA 350.1. Rev. 2.0, 1993
< 0.2 mg/L
07/08/2024
Gallons bailed before sampling
Gallons Bailed before sampling
5.0 gallons
07/05/2024
Odor
Qualitative
N/D
07/05/2024
Total Dissolved Solids (TDS)
SM 25U C-2015
1430 mg/L
07/08/2024
Temperature
SM 2550 EI-2010
25.6 C
07/05/2024
PH
SM 45M H B-2011
4.8 units
07/05/2024
Total Phosphorus
SM4500 P (F-H)-2011
0.05 mg/L
07/11/2024
Total Organic Carbon (TOC)
SM 5310 0-2014
4.5 mg/L
07/08/2024
Fecal CoNform
SM 9222 0-2015 MF
<1 Colonies/100ml-
07/05/2024
Chloride
SM4500 Cl E-2011
363 mg/L
07/08/2024
Nitrate Nitrogen (Calc)
Nitrite Nitrogen
EPA 353.2. Rev: 2,0,1993
< 0.02 mg/L
07/05/2024
Nitrate+Nitrite-Nitrogen
EPA 353.2. Rev, 2.0, 1993
1.47 mg/L
07/10/2024
Nitrate Nitrogen
subtraction Method
1.47 mg/L
07/05/2024
Total Nitrogen (Calc)
Total Kjeldahl Nitrogen (TKN)
EPA 3512. Rev. 2.0,1993
0.6 mg/L
07/11/2024
Total Nitrogen
Total Nitrogen
2.1 mg/L
07/18/2024
Comment: AMENDED 8/20/24 to
report Odor.
TM
Reviewed by:
4_.L7
Report V: 2024-15321 Page 11011

Dale:
Analyst: _ Jay Baker
Ccnlr1caIIon q 94
Facility Name: r I I' tr1
r--
Permit It; LAN Fl �.>✓
pH
Reference Minhnd: SMd50D H+A _WlI I Iwwnemcm In fiTA RA221 • rtnS94C
CalibFation Time
Cal Bufrer0 0 s u I Cal Buffer 10.0 s.u-
I Check Buller 7 0 s u
Comments ~
-1:30
4,QL () 10,c)( ('
-7roz (14)
-pri csoc+c ourirr mustreaa wnnin Y'ti.l pii uniLS of ine t U[W s Irue value.
4 su buffer Lodlr Ricca 1304N51 Exo OU25 7 su buffer Loan: j} 10 su buffer Lath
Sample location
p
Sample Collection
Time •
Sample Analysis
Ti •
pH Result
s.0
►Post -analysis Duffer
Check value s u
Commenta/Data Qualifiers
O
p55
5 M
(�V•12
1p
c�3s
,�
10
07-
Pt1(30
30
3 a3 t
S+
Post analysis bui%r check iS required when performing analyses at multiple sampling locations mid must be within* D I units onhe buffer's true value
All pH values in pH units (I e . s u.). Record all data to the nearest 0.01 s-u. and report to the nearest 0.1 s u
Total Residual Chlorine (TRC)
Reference Method: S1.14W Cl•G301 I: Ilach g 157 HR- I PION" P.rrin IhniIr■1.ir r PIhne[I in HAC t7 1Cl')AV'3aana1
Daily Check
Standard Result
Post -analysis
d k S Checi.
(aiirn analyzing
Time check Sampl
Standard e
Location
Sample
Collection
n
Sample
Analysis
Result
Comments/Data Qiialiftcrs
pg/L or mg/L
atmult{ lesiles)
Analyzed
Time
Time
pg& or mg/L
i n�_ uauy Ulcer: JrarlaRM true vaiue pg/L or mg/L acceptance range )igiL or mVL GELSTDS IIACII A003B
Check standards must recover Within t 10% of the check standard's true value
Annual Calibration Cure Verification Date. _ 1U25/23 1DEM (Free) 230901 Exp. Date:1001/24 Y
Reagent Blank Value ,- (When applicable. Analyze and document a reagent blank when standards• sample dilutions or PT Samples are prepared)
Dissolved Oxygen (DO)
Re! rpw rr Mr Mier SILL dSnn n r .In I ir.e.,.m...e in VC Von in '11111 ilinACK
Calibration/
Verification
Time
Calibration variable
Meter reading
ur %efficiency -
ali cr calibration
• Post -analysis calibration
veriffcation (whoa necessary)
Comments
Temp
°C
Barometric
pressure
mmHg
Salinity
ppt
Theoretical
Value mg/L
Calculated
Value mg/L
Use (his row when performing it sedlicalinn Instead of
Sample Location
Sample Collection
Time
•Sample Analysis
Time
DO reading
m
Comments/Data Qtialifrers
• When periorming analyses at muitipic tocattoris, the mcler must be recalibraled at each site before analysis or a pos(-analysis calibration venfiralron must be performed.
• If sample is mcasuted directly in the stream and/or onsue, only time analyzed %%cold be recorded with a note that they are measured in situ or immediately
Temperature
R►rn.nr� IL1wii.evi SM 25S1i B-20tn I......•. Ana in CTA Q A 77 r ref19:1119
Sample Location
Sample
Collection
Time
*Sample
Analysis
Time
Temperature
°C
Comments/Data Qualifiers
loss
5S
p
23 . t
N
(035
1 D35
21.y
M�4
1020
102D
Z •C_
Mw1A
63o
li 3a
zs-Z
rr auei:per rs mca,umu uuecrev in me stream oi>svor on site onl) tlme'analy zrd anu d be rer.orded, widl a note li al they are mrasurrd m situ or enuludiarcly
Annual Verification Date 1111-2 2
Field Personnel Note:
QA.001 12/01/22
Rev 1-2022

Dale:_
Analyst:. —Jay BIkIL
PH
Certification 0 94
Facility Name: Csd_I > C)E
Permits: t LIG
Calibration Time
Cal Buffer 40 s It
11MUCncc Method
I Cal Buffer 10.0 s u
4M4*L; K- Is •':il t
Check Buffer 7.0 s u
Instrumcat ID hiFAKAiZI : KU6795
Comments
(4)
(1
()
*pH check buffer Must wad within r 0.1 pH units orthe buffer's true value
4 su buffer Latilt RuCa l304N61 Esd 910 7 su buffer Lotilk Ricca 1210040 Exn. 1024 10 sir buffer Lotil._ R1CCA 130074 Exn. 1024
Sample location
Sample Collection
Time•
Sample Aralysis
Tom*
pl•1 Result
s u
►Post -analysis Buffer
Check value s.0
Com►mntslData Qualifiers
14,S
I i S
4. a
M v�1
1035
1 o3s
5 9
I) top
v c:� vo
I
tl edit
N W I ( A-
C� Ll 5
q'i ;S
465
i(-1 W 12
30 I
q 3p
tt 5
> r-usr iniaipts wirer cneo: is required mien performing anaFyaes at multiple sampling locations and must be w•Ihm is 0,1 units of the buffer's true value
A II PH values in pH units (i.e , s u.). Record all data to the nearest 0.01 s.u. and repon to the nearest 0 1 s u
Total Residual Chlorine (TRC)
Rerrcnce ivMelhod SM 4500 0-153011 Hach U6711R Pietist circle aDrAicAble MWsod) Insirwritnt ID H A C H CoIarim a r 15 1 MEMO]
Daily Check
Post -analysis
Time check
5atnple
Sample
Sample
TRC Result
Standard Result
µg/L or mglL
hen an lyzSid
(when analyzing
Standard
Analyzed
Locau I$
Collection
Time
Analysis
y
Time
pg/L or mg/L
Comments/Data Qualifiers
at multi a sites
r let-. Uaay I-necu Standard true value _ pg/L or mgli. acceptance range i+g0- or mg/L GEL SIDS HAC'H A0038
Check standards must recover within t10°b of the check standard's true value
Annual Calibration Curve Verification Date 11/25123 IDEXX (ELcg 230901 Exp_ Date:10131/24 IDEXX (Tote)] 230757 Exp. Datc:0$1311.24
Reagent Blank Value _ (When applicable. Analyze and document a reagent blank when standards, sample dilutions or PT Samples ate prepared)
Dissolved Oxygen (DO)
Reference Method.SM 4s00n C 11116 Innn—W In VR1 110411 ?.A III r1Ian"A
Calibration/
Verification
lime
Calibration variable
hicter reading
or % effici9)xw
after calibration
a Post -analysis calibration
verification (when necessary)
Comments
Temp
,C
BarometricSalinity,
Pressure
mmH
pP'
Theoretical
Value mgli.
Calculated
Value mg/L
()sc tills roN when performing a verification instead of
calibration
Sample Location
SampleColieelion
Time
•Sample Analysis
Time
DO reading
m
Comments/Dota Qualifiers
9 When perrorming analyses at multiple locations, the Fnetcr must be recalibroled at each site before analysis or a post -analysis calibration venfieation must be performed
• If sample is measured directly in the stream and/or onsite, only nine analyzed could he recorded rvuh a note Ihat lhey are measured in situ or immediately
Temperature
Reference Method SM 2550 n.inin Fnsrnnnnnr In C-f sae77 r • IeIM inc
Sample Location
Sample
Collection
Time
$Sample
Analysis
Time
Temperature
'C
Comments/Data Qualifiers
M�.18
li4s
114
24°l
VIA WCt
1435
-a.3
W! Pr
1000
loco
2�:R
M W it R
1=I H S
4-S
24:
1�112 f3
el—�v
a3�
Z5.2
n siniipie is ineasurcd directly in ine stream andlar on site, only time zuaty zed Would he recorded, w'nb a note that they are measured in Situ or immediately
Annual Verificatton Date 1-25-23
Field Personnel i\Ole:
QA.001 12/01 /22
Rev I-2022

Date; S ierti0ratioa
Facility Name• _�j c---
Analyst:--_ JAy Baker PermitM. -
pH
Re rerenre. Mo]lvvt CILIJ S,M Ni.14 _->nI 1 I..e.n......... In QTA O All 114154'10e
Calibration Time
Buffer4.0 s u
Cal Buffer 10 0 s u
.�............ ... .........-.�.. .......ter
Check Buller 7 0 s u Comments
1C'al
rn a uncn uuucr mlor reap nluim x u I pit units or Inc callers IRIe value.
4 su buffer Lath Ricca I &NkLLXgMi77 so buffer Lot#/- Ricca 22 1 Qt340 Exp. 10/24 10 su buffer LotB RICCA IMP74 Egp l on -
Sample location
Sample Collection
Time •
Sample Analysis
Timeb
pH Result
s u
►Post-anelysis Buffer
Check value s u
Comrnenrs/Dnta Qualifiers
t
_ . ►5 _
�.1
5.
► Past anaiysls buffer check is required mien performing analyses at multiple sampling locations and must be within A 0.1 units of the WfTer's true value
All pH values in pH units (i.e., s.u.). Record all data to the nearest 0.01 s.0 and report to the nearest 0 1 s Is
Total Residual Chlorine (TRC)
Reference Mcthod' SM 4500 Cl•G2011• !-lath 8167 HR: f Please circle atic Ilcable Met hod I Instrument ID
Daily Check
Standard Result
Post•analysis
Check Sid
(when analyzing
Time check
Standard
Sample
Location
Semple
Collection
Sample
Analysis
TRC Result
Comments/Data Quabftcrs
P&IL or mg/L
at multiple sites
Analyzed
Time
Time
µ11& or mg/L
I RC Daily Check Standard Ime value pg/L or mg/L acceptance range µg/L or mg/L. GEL STDS NACH A0039
Check standards must recover within f 101% of the check standard's true value
Annual Calibration Curve Verification Dale; 11/25/23 IDEXX (Free) 230901 Exp. Date: I(Y3124 a1 7 T24
Reagent Blank Value; (When applicable. Analyze turd document a reagent blank when standards, sample dilutions or PT Samples are prepared)
Dissolved Oxygen (DO)
Reference Method'SM45noflr,-ioib 1ee1--M. v6l DYrftM1)1"Ifin"r.
Calibration/
Verifrcalmn
lam
Calibration variable
Temp Barometric Unruly,
.0 p..0 rc
rnmHe PPi
Meter reading
or 56 efficiency
aflercalibtation
• Post -analysis calibration
verification (when necessary)
Cugnmenis
Theoretical
Value mglL
Calculated
Value mg/L
t se this row when performing a verification instead or
Sample Location
Sample Collection
Time
'Sample Analysis
Time
DO reading
m
Comments/Data Qualifiers
. o.1m perrurming anaryses an multiple locations, Inc meter must be recalibraled at each sue before a•ralysrs or a post -analysts cahbmtron verification must be performed
• If sample is measured duecd) in the scream and'or ortsite, onh time analyzed could be recorded %uh a note that they are measured in situ or immediately
Temperature
Re rereneeMrihed SM'+Sin A-,inIra i—P. r. i in QTAPA971 , W141Qi
Sample UWAinn
Sample
Collection
Time
*Sample
Analysis
Tune
Temperature
"C
Camrnenis/Date Qualifiers
is
Zt 5
"W ky
IVIS
11.W
Z5.6
11 i,rinpic Is measured directly ur the strcam,:ndror al site, only ume.aatal%ZeC nwiluf t v cceorsW. atih a note that Ote) are rienskued in sou or im ncdwlely
Anmwl Verification Date 11-25-23
Field Personnel Note'
QA.001 12MV22
Rev 1-2022

Environmental Chemist, Inc., Wilmington, NC Lab #94
6602 Windmill Way
Wilmington, NC 29405
910,392.0223
Sample Receipt Checklist
Client:
l S
CcY
Date Report Number: _ 3 1-
Receipt of sample:
ECHEM Pickup Client Delivery ❑ JUPS 17 FedEx ❑ Other ❑
❑
YES
113
NO
0 N/A
III Were custody seals present on the cooler?
❑
YES
JE3
NO
I I] N/A
. If custody seals were present, were they intact/unbroken?
,Original temperature upon receipt 'C Corrected temperature upon receipt "C
How temperature taken:
❑ Temperature Blank N Against Bottles
IR Gun ID: Thomas Traceable S/N: 230222540 IR Gun Correction Factor'C: 0.0
®
YES
❑
NO
3. If temperature of cooler exceeded FC, was Project Mgr./CtA notified?
®
YES
❑
NO
4. Were proper custody procedures (relinquished/received) followed?
0
YES
❑
NO
S. Were sample ID's listed on the COC?
10
YES
❑
NO
6. Were samples ID's listed on sample containers?
0
YES
©
NO
7. Were collection date and time listed on the COC?
IT
YES
❑
NO
A. Were tests to be performed listed on the COC?
0
YES
❑
NO
9. Did samples arrive in proper containers for each test?
©
YES
❑
NO
10. Did samples arrive in good condition for each test?
0
YES
❑
NO
11. Was adequate sample volume available?'
®
YES
❑
NO
12. Were samples received within proper holding time for requested tests?
YES
❑
NO
13. Were acid preserved samples received at a pH of <2?
YES
❑
NO
14. Were cyanide samples received at a pH >12?
❑
YES
❑
NO
15. Were sulfide samples received at a pH >97
YES
❑
NO
16. Were NH3/TKN/Phenol received at a chlorine residual of <0.5 m/L7 **
YES
❑
NO
17. Were Sulfide/Cyanide received at a chlorine residual of <0.5 mjL?
❑
YES
❑
NO
18. Were orthophosphate samples filtered in the field within 15 minutes?
" TOC/Volatiles are pH checked at time of analysis and recorded on the benchsheet.
** Bacteria samples are checked for Chlorine at time of analysis and recorded on the benchsheet.
Sample Preservation: (Must be completed for any sample(s) incorrectly preserved or with headspace)
Sample(s) were received incorrectly preserved and were adjusted accordingly
by adding (circle one): H2SO4 HNO3 HCl NaOH
Time of preservation: If more than one preservative is needed, notate in comments below
Note: Notify customer service Immediately for incorrectly preserved samples. Obtain a new sample or
notify the state lab if directed to analyzed by the customer. Who was notified, date and time;
Volatiles Sample(s) were received with headspace
COMMENTS:
DOC. QA.002 Rev 1

W
i
J
Z
W
2
z
0
Z
W
d
' \
N[
fir+
67
y'
J
h
z
1�
le
Q
IL
w
aC
0 = [a ul
a a E
c
O
m
J �
H
3 L
O
cm
z
a
1 V
�
Q
O
�
J
aW
W
0
z
p
i -�
v
z
�
O
a
Z
z
O
o
N
N
�1
U
�
�
U
cn
a
� �
l
c°
u a
10JO') a.
0.
0a0aC9a(7
�mla�uo�
w
a age°
•°
Uc�Uc7Uc7U0UU0
i(D
(D
N atla°duwo
1N \n
1n v
m �
0 0
U O

Q
z
T)
2
W
J
Z
0
z
W
o
o
: V)
J �
N
� U
L
d
o
tm
Z
i
0
i z
p
J
J
v
7
O
a
Li
z
Z
U
o
O
a.
aac
a
v
LU
d)
ac�In-FacLcqa-C�ac)ac9at�ac7ac7
,oullnuo,
w
4 +3
,u UU'
U(7UC9UC7UC7Uc9UC7UC9Ut7
H ailsodwo�
F
E E
D G [�]

In
0
10)
3cm m
N OE'_ �°, E
-dam
0
c O1 'S
� cc11
~ LL O
�a
V
Z
C6F
Vi
W
0
.j
H
z
W
2
Z
0
Z
W
t
3 p
N
u �
C)
�o
�z
i =
:L)
to
I
G
V
i W
J
r -j
V
>
a:
UQJ
uj
i w
M
uj
O
u
Y
r7
C
>
I
U
z
U
z
.r
z
Z_
z
I
U U
o 0
a3NJ.O
a OIHI
Q NOUN
y
IX £ONN
W
LItoSiN
IY.
L l3H
BNON X
v3vwnN C
OI evi
ll8w
aulrol40
W
a (D1Od)
JaLIYJU07 ac9dt7a0CLa
d01CL
a.
1010-
0 CL
W
J
IL gaJrj
Jo UCDL)000UC9UC9UC9UC7UC7L)
allsodwo�
al
E
k
Ia
t
I wi

� N
L
G
U
.E E
5
W
y
?
7
N
H
W
0
U
N Y
11
z
=
0.
_ c
E
s-
e O1 �
II
r
2
z
y
o
0
t-
LL
E
z
OL
O
W
z
z
Y
.� �
Il3H10
d
m
0o
OIHL
Vr
f11
r
HOVN
EONH
Z
Z'
�?, W
►OSiH
G
}
C b
lOH
F.
g
MON65
X
oe
H
y
If
W U
C�
d
W 1139nnN
3
01 an
_U.
0
p
01
�..� =
=p
a
m
-prow
J C1
=
►s
C
10
11
Z
%0
p
J
W
W
`v
Z a
ZG
z
G
a
W
W
W
Q
H
lz O
p }
E
C}
z
�,
U U
z
O O
I x
X
0
Y
CL (DJOd) 4(D0-C91Zt9aoa.o
�suls,uo�
00.aa.o
W
J
4p�
U(9UC7U(jU(iUC7UU'
UC9UC7UC7
yQ apsodwo3
Z"
0
w
edRl
�
09
-3 o G
V a v a (�
wawag
0
z
CL
�)
z
N
W
'
E
a
�_
M
E
01
m
OF
�
0
U
�
a+
C
W
p
m
c
a
o
p
N
M
CLI
ram..
° 0
E
C

N
N
CE
z b � v
0—�
c
co)
m
3 !V
_ "' E
o 0
us CC)
m w O
z
.0
G
LL
Z
V
a
a
d
Z P1
z
o
V) E
o
r
W
ca
DLU
Y
H
V
V
0
d
Z C
0
fll
♦ ♦
V T
=a
Z
`
L.
"J z
ca
du
a
c
z
ZLU
Q
L
a
p
z
z
o
It
W
w
a�
ore
Z"�w
r
w0
a
c�
oc
rJ
0 ae:
U
_
W
2 z
W
F,
In
ad
dr'
O
t
�
S
U
a
7
C
U
�
W
11
0
z
N
}
F
(-
ry
li
_
0
1—
rn
ri
z
U
N
M
z
z
� N
aaluo
11 z
01HI
yv
HOYN
3
EON14
v
11
fO9t H
X
H
?� W
V
e
iv
tiO11
a
dNON
x
II
W aamm
(1
_
QI BVI
C
a�
�fdw
1f
11 supolgO
p
E
a
w
9
U
z
U
U
L
Z
O
O
x
■©
©=
W
a ��'°�a
Jaulolu°�
UO
c7a
c9 a
c� a
c7a
c� a
tea
c�
W
a
Glum
�u UC9UCryUC7UC7UC7UC9UC7UU'
t]c7
H ■ltvodwo�
E
L
a
ro
3
o
p
m
'm
�
r
� a
o
e
V
m
0
E
r�

N
zIm E
,8
Sao N
EL m
M L
ti
�N R
:in
C
ii
O
V C
N
m U �
m
U
z
Emma
!Fn
L
2
W
U
..J
a
z
W
Ls
z
0
a
z
W
0
U)
V
LL
0
z
a
z'
0
V
W
J
J
�au�quo:) a
llnuo
c7 a
c9 a
C7 10-10
CL
a 0-
U a
c9 a.
c7 a
c7
a ao�
t�c7UcDUc�Uc7Uc�c�t�c�c�Uc�UC7
coallsodwo�

An
N
N4
z M E
_
C6s�
fl
on y
if)W
3
U
m
Lo
E
n
I
U)
p
�.
q
O e
J
J
�
Z
1-
E
E
d
c
O
�
d7
r
ai
`
"
t
M
Z
O
>
O
W
U
z0_qq
z
0 0
R_
z
Z
z �i
a z O
'Iv
0
MJ R a
E 11
y
U) z
p
z
11
0
F
w
�m---m----
®--m©----m
.
®-MMM-----
M-M©-M---.
®-©--M©---mm
y
11
[1
LV
Cj
d
W
v3gwnN
f�
`l
U.
3
e
al ev-1
= n
0
to
a
L
a
p
•R
1 V
=
_
II
aupol4O
2
Ci
a
J
U!
yyy�a 119joa) a. cD a. 0 CL CD a. C) (L lula-I M (D 0- Lo a(9
��l Joulqu00
gvjo
•u UCDUC9000CDUC7UC7UU' U(!)0
� sllsadwo�
adRl f
sldwsg
adRl f
sldwsg
V
E
_
S
H
d
Ir
U
p
•Il
'°
II]
a.i
c
m
C�
H
Q
a
)
1 L
E
C
M
+'
C
ar
a
m
yam?
v
`
,
`
d)
3
no
Q
O
.0
N
°
ono
y
coo
M
a
s
....r •
a
s� v
e,
E
3
m
U
m
ix
o?

N
N
Z
C p O
V
E
M V
N A
1.9
m
C
w
V
N LL
I6_
0
Z
U)
TW
i
J
a
z
W
2
Z
0
z
W
0
0
❑
V
LL
Z
a
0
Z
a
Z
v
c�
w
J
yl

N
Y Q
e o u
w r y
c _N
'E1L�
pp Ct
N .�.
c
-a
9c�
c •�
Ny—V,
mo 0
z
o
0 E
�
a �
Z�
#
Z
O
z
N
r
a
R
to
�
U
=o
D
C�
0
.9
d
V =
C
a
a
Z2zLu
Z
Q
ii i
a�d�
ui
o
s
O
V
z
W
U
zmm
o
F'
Z
J
w
a
O
U
aCL
ui 0
M O
Z
C
Z z
W
Ir
41 Q
L
fIJ
L
E
u
O
c�7
°
>
U
z
U
z
N
z
c
Z
` U
L]
Dj
Z
li O
aaHlo
�
m
11 z O11u
�p
X
HOYN
N
IX CONH
X
m
a
11 Lu
r? iL rosxH
X
X
!� 1314
)(
MON
"
S
w aaewnH
�
al evi
r
ylBw
II auN0143
D
ui
o
(9'° d)
wulalu°p
a c9 a c9 0_ c7 a c� a t� a
c� a t� 0- 0 m
a
Wig
M
H
UC7U(7UL7U(7U(9ic!)
9UC7Ui9
all9°dwaa
adRl
aldwag
CL
c
a
�
�
y �
C
�
Or
p f'
C]
m
A
IR
�r
�
C
4«1
«
��
m32
a
LU
_
♦d
..a 3
`
N
c
w
67
L
a
v
I _Amin
m

N
�
Z to
c d In
sA
I
E m
ryMry
N AA
} N m
_ "' r
va
W
i O
a�
� o
o
♦Y
�
a
M
�
z
�
Z
_
Yi
�
Vl
_�
V
LL
o
o
d
3
zCl
J z
o
cc
z
Z F
z
Q
z
IL
Q
W
a
9
Q
U
W ot
Ix
o
W
z
'
z
o
F
2Ix
0 c
r
o.'
4
O
Vcc
W O
0
W
7 0
z Z
W
IL
N
B
N
S
E
W
m
0
IOU
U) w
�
u U)a
z
C
U)
F-
F
Nq
-a
E
O
rR
ri
`C
r1
z
H
U
U
z
v
N
O
ri
0
r U
U
m
z
co
z z
li Q
O
n3ru0
11 Z OINL
X
D]
V1 F HOrll
a
�
CONN
j(
a
11 W
W POSiHLU
X
�(
JEION
j(
MON
:(
L55
11
W H3BWnN
C Gl9Yl
a
II auP0143
p
ki
Q
a (D AD d)
iauleluo0
CL c' Il c7 a O a O a C 4 C9 IL 0 d 0 a c9
J
L gei0
jo
UCiC.)00aC-)00 90000007u
I/l allsodw0D
addl
rldweg
7-
CL
r
Q
O
_:I ti

Lna
cr
s-
CC)
22§
'
■�®
�
� $ §
LU
�L$
2
2
■off
w
O
0 2
z
"W 0
X
0
1."
a .
Z
� .uj
O
�
Lij
U.
2
I
X00
�
f
z
o
■
-j z
Q
is
�
z
§
uj
2
b
Z
k
b-5
r
2
0
a
2
IX J
> k
z z
LLI
�
@
.
2
k
�
�
&
k
�
J
I
$
o
b
�
2
§
a
2
%
2 S§
/ k
/
0
C
Q
/1
2
■
o
w
0)
"
§
d
I
v
z
R
U _
§
Q Q
I
L
O O
VN
1 z
eo
x
�&
�2tONH
mm
4 x
. Q
fw
x
CL
IOH
XI
§
_a
x
W emwm
I CH lei V-1
�r
yi
■ . A3
A
w
IL(E) ©d)
a
o a o a
o
c
o a
0 a
e a
o
a
U
O U D Q
e o o C.)o
o
■ ¥__o
i(D
U
CD
' !
«
«a■
CL
�
b
U
ro
�
&
�
�
\_
�
Ilk,
E
e
$
ƒ
t
0
m
,.
!
�
�
@
§
I
0