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Home My WebLink AboutWQ0003698_Monitoring - 07-2024_20240823Monitoring Report Submittal Permit Number#* Name of Facility:* Month:* July Report Information Type * GW-59 WQ0003698 Corpening Creek WWTP Year:* 2024 Upload Document* Signed Package--8.23.24.pdf PDF Only 1.65M B Please upload one PDF containing all applicable monitoring reports (i.e., NDMR, NDAR-1, NDAR-2, NDMLR, GW-59). Confirmation Email Address: * thorton@marionnc.org Name of Submitter: * tim horton Signature: rtk i1;Af ;A, Date of submittal: 8/23/2024 This will be filled in automatically Initial Review Reviewer: Wanda.Gerald Is the project number correct?* W00003698 Is the monitoring report accepted?* Yes NO Regional Office* Asheville Reviewer: _anonymous Review Date: 8/26/2024 GW-59A COMPLIANCE REPORT 'IFORM Permit # 1�o ,000-3 (o9 (Submit one each monitori period with GW-59 forms.) 1 Enter date monitoring results were due. 1-tl aZ ill this monitoring report (Gut-59 and GIN-59A) YES NO be submitted after the established due date. X 2 Was any required information missing on the GW-59 repor orms? YES NN IF the answer to question 9 or 2 is "YES", list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenanc identification plate, area overgrown, etc.)? If the answer is "Ir (damaged casing, unlocked or missing cap, missing contact the Regional Office for guidance. YES NO 4 Are any monitored constituents equal to or above the Ile' tablished standards? YES NO If the answer to question 4 is "NO", skip to section 8. If the answer to question 4 is "YES" list the affected well individually with constituent(s) and concentration(s) exceeding standards in the space provided below. 5 For the constituents identified in question 4 above, haute same constituent(s) in the same well(s) in the last two standards been exceeded previously for the ears? YES NO If the answer to question 5 is NO", skip to section 8. If the answer to question 5 is "YES". list in the space pit standards, concentration(s) reported, and sample collection vided below, each well with constituent(s) exceeding date for each occurrence (for the last two years). I� 6 Are the monitoring wells listed in section 5 located at Ili beyond the review boundary? YES NO X, If the answer is "YES", a groundwater quality problem: rIIay be occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer'is "NO". monitoring wells may be improperly located; contact the Regional COffice. Q2 10naL C'S l [C'2�Cc5v� 7 Is the permittee implementing previously approved actibns required by the Division involving this YES NO groundwater quality problem? If the answer to question 7 is "YES", describe those action's'in the space provided below. If the answer to question 7 is "NO" contact the Rectional Office within 90 days; an evaluation may be re uired to determine theimjpactthe waste dis osa/ s° stem is having at the review and compliance boundaries surrounding this facility, Failure to do so'' av sub"ect the permittee to a Notice of Violation fines, and/or penalties. e it o Vkl ` vim- t t G '� Co ex" g The person completing this portion (G W-59A) of the monitoring form with G W-59 forms for required wells to the address report should sign below and submit this provided at the top of the current GW-59 form. I hereby acknowledge that,the above information.was - aivated-and,the information,submitted: in this report (Compliance Re ort_GW 59A is true and com 1 e to the best of m knowled e, L Signatur f Permittee (or A on ed Agent) i ate I GW-59A 12/8/2003 Question #4 LAB DATA WHICH EXCEEDS PERMIT DATE MONITORING WELL # PARAMETE REPORTED DATA 7/12/2024 1 pH 71 5.8 Iron 11 396 ug/L 2 pH 11 6.4 Ammonia 5.7 mg/L Iron 11 42,100 ug/L Manganes 1,230 ug/L 3 pH 5 Cobalt 3.1 ug/L Iron 438 ug/L Manganes 96.7 ug/L 4 pH 4.9 Cobalt !1 3.0 ug/L Manganesg 131 ug/L QUESTION #5 LAB DATA WHICH EXCEEDS PERMIT FOR LAST 2 PREVIOUS YEARS 1 pH 5.9 II 2 Ammonia 5.4 mg/, Iron 27,100ug L Manganese 1,250 ug L pH 6.4 I1 3 Cobalt 2.5 ugh Manganese 98.5 ug% pH 5.1 1I 4 Manganese 1 86 ug/jL pH 1 4.9111 1 pH 5.9 1 2 Ammonia 5.9 mg%t Cobalt 1.1 ugly Iron 50,400 qg/L Manganese 1,310 ug/, L 3 pH 5.2 I 1 Cobalt 2.2 ug 4 Manganese 70.6 u9A 4 IpH 1 5 ',� Cobalt 3.3 ug%L Manganese 1 126 ug% . 1 pH 5.9 ;� 2 pH 6.4 !� Ammonia 5.6 mg%L Iron 42,200 ug/L Manganese 1,530 ug L 3 pH 5.11 Cobalt 2.8 ug/I* Iron 478 ug%- Manganese 85.8 ug/JL 4 pH 5 I,I Cobalt 3.0 ug%I, Manganese 1 124 ug% t2'f20�r3 1 pH 5.6 Iron 464 ugv 2 pH 6.411 Ammonia 4.2 mg% Iron 123, 900 l g/L Manganese 1,490 ug�L 3 pH 5.2 11 Page 1 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM Please Print Clearly or Type Facility Name: Corpening Creek WWTP--City of Marion Permit Name (if different): Facility Address: Marion NC 28752 Marion (Street) NC 28752 County McDowell act Person: Tim Horton Telephone#: (828) 652-8843 Location/Site Name: Monitoring Well #1 R No. of wells to be sampled: 4 ILLID NUMBER (from Permit): Monitoring Well #1 R II Depth: 62.62 ft. )th to Water Level 82546: 25.85 ft. below measuring point asuring Point is 1.5 ft. above land surface ume of water pumped/bailed before sampling: 4.7 nples for metals were collected unfiltered: ❑■ YES ❑ PERMIT Number: Expiration Date: Non -Discharge WQ0003698 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑ Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: Date sample collected: 7/12/24 Well Diameter: 2 in. Screened Interval: 55 ft. to 65 ft. Relative M.P. Elevation: ft. gallons NO and field acidified: ❑ YES ❑ NO FIELD ANALYSES: pH 00400: 5.8 units Spec. Cond. 00094: Odor 00085: Appearance sample analyzed: 7/12-26/24 Laboratory Name: Pace Analytical AMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 0.0019 mg/L Pb - Lead olo51 /1-00m L- Coliform: MF Total 31504 /100mL (Note: Use MPN method for highly turbid samples) solved Solids:Total 70300 mg/L pH (Lab) 00403 units TOC 00680 mg/L Chloride 00940 mg/L Arsenic 01002 ug/L Grease and Oils 00552 mg/L Phenol 32730 ug/L Sulfate 00945 mg/L acific Conductance 00095 µMhos Total Ammonia 00610 <0.10 mg/L (Ammonia Nitrogen; NHaas N; Ammonia Nitrogen, Total) TKN as N 00625 <0.50 mg/L Phosphorus: Total as P 00665 mg/L Orthophosphate 70507 0.014 mg/L Al - Aluminum oil o5 mg/L Ba - Barium 01007 35.2 ug/L Ca - Calcium oo916 mg/L Cd - Cadmium 01027 <0.10 ug/L Chromium: Total 01034 ug/L Cu - Copper 01042 mg/L Fe - Iron 01045 396 ug/L Hg - Mercury 71900 ug/L K - Potassium 00937 mg/L Mg - Magnesium 00927 mg/L Mn - Manganese 01055 10.0 ug/L Ni - Nickel 01067 ug/L If WELL WAS Temp. 000lo: 21.2 oC DRY at µMhos time of sampling, None check Clear here: ❑ Certification No. 12, 40, 12710 ug/L Other (Specify Compounds and Concentration Units): Boron: <50 ug/L Cobalt: <1 ug/L ORGANICS: (by GC, GC/MS, HPLC) (Specify test and method #. ATTACH LAB REPORT.) Lab Report Attached? ❑ Yes (1) ❑■ No (0) VOC 7873 method # method # method # method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Signature of Permittee (or GW-59 Rev.05-02-2017 SUBMIT FORM ON YELLOW PAPER ONLY . • S GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM PERMIT Number: Expiration Date: FACILITY INFORMATION Please Print Clearly or Type Facility Name: Corpening Creek WWTP--City of Marion Non -Discharge WQ0003698 UIC Permit Name (if different): NPDES Other Facility Address: Marion NC 28752 TYPE OF PERMITTED OPERATION BEING MONITORED Marion tStreet) NC 28752 County McDowell ❑ Lagoon ❑ Remediation: Infiltration Gallery (city) (State) (zip) ❑ Spray Field ❑ Remediation: Contact Person: Tim Horton Telephone#: (828) 652-8843 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Monitoring Well #2 No. of wells to be sampled: 4 ❑ Water Source Heat Pump ❑ Other: from Pemtit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): Monitoring Well #2 Date sample collected: 7/12/24 FIELD ANALYSES: WAS Well Depth: 38.02 ft. Well Diameter: 2 in. pH 00400: 6.4 units Temp. 000lo: 20.9 °C DRY at Depth to Water Level 82546:18.38 ft. below measuring point Screened Interval: 30 ft. to 40 ft. Spec. Cond. 00094: µ Mhos time of sampling, Measuring Point is 0.22 ft. above land surface Relative M.P. Elevation: ft. Odor 00085: None check Volume of water pumped/bailed before sampling: 0.63 gallons Appearance Clear here: ❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: X YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 7/12/-26/24 Laboratory Name: Pace Analytical Certification No. 12, 40, 12710 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 0.0099 mg/L Pb - Lead o1o51 ug/L Coli omi-MF-F-ecaa r1 OpmL—_Ntir-atT (h7O-)-as N _oo-s2a_U.-02/L _- - Zn Zinc o lv9- — - mg/ Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 0.023 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 mg/L Al -Aluminum 01105 mg/L Boron: 47.5ug/L pH (Lab) 00403 units Ba - Barium 01007 56.8 ug/L Cobalt: 0.69ug/L TOC 00680 mg/L Ca - Calcium 00916 mg/L Chloride 00940 mg/L Cd - Cadmium 01027 <0.10 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 42,100 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑■ Yes (1) ❑■ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00810 5.7 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3asN; Ammonia Nitrogen, Total) Mn - Manganese 01055 1,230 ug/L method # TKN as N 00625 6.8 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Tim Horton WWTP Superintendent Permittee (or Authorized Agent) Name and Title - Please print or type GW-59 Rev.05-02-2017 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM PERMIT Number: Expiration Date: FACILITY INFORMATION Please Print Clearly or Type Facility Name: Corpening Creek WWTP--City of Marion Non -Discharge WQ0003698 UIC Permit Name (if different): NPDES Other Facility Address: Marion NC 28752 TYPE OF PERMITTED OPERATION BEING MONITORED Marion (Streetj NC 28752 County McDowell ❑ Lagoon ❑ Remediation: Infiltration Gallery (City) (Slate) (zip) ❑ Spray Field El Remediation: Contact Person: Tim Horton Telephone#: (828) 652-8843 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Monitoring Well # 3 No. of wells to be sampled: 4 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPUNG INFORMATION If WELL WELL ID NUMBER (from Permit): Monitoring Well #3 Date sample collected: 7/12124 FIELD ANALYSES: WAS Well Depth: 50.02 ft. Well Diameter: 2 in. pH 0040o: 5.0 units Temp. 000lo: 19.3 °C DRY at Depth to Water Level 82546: 34.07 ft. below measuring point Screened Interval: 30 ft. to 40 ft. Spec. Cond. 00094: µMhos time of sampling, Measuring Point is 1.09 ft. above land surface Relative M.P. Elevation: ft. Odor 000m: None check Volume of water pumped/bailed before sampling: 3.7 gallons Appearance Clear here: ❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: H YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 7/12-26/24 Laboratory Name: Pace Analytical Certification No. 12, 40, 12710 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (11i as N 00515 0.0018 mg/L Pb - Lead o1o51 ug/L — -- .four;=M1F eca 4-00mL_.___ , t ra e--, . 3..as-,-00s2o_- --8-.6 -_-..---- —mg/L - n- Inc oT65------ mg/L----- Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 <0.050 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 mg/L Al -Aluminum o1105 mg/L Boron: <50 ug/L pH (Lab) 00403 units Ba - Barium 01007 405 uglL Cobalt: 3.1 ug/L TOC 00680 mg/L Ca - Calcium oo916 mg/L Chloride 00940 mg/L Cd - Cadmium 01027 0.54 uglL Arsenic 01002 ug/L Chromium: Total 01034 uglL Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, Ill Phenol 32730 ull Fe - Iron 01045 438 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ul lL Lab Report Attached? ❑ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3asN; Ammonia Nitrogen, Total) Mn - Manganese 01055 96.7 ul lL method # TKN as N 00625 <0.50 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal GW-59 Rev.05-02-2017 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM e FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: Facility Name: Corpening Creek WWTP--City of Marion Non -Discharge WQ0003698 UIC Permit Name (if different): NPDES Other Facility Address: Marion NC 28752 TYPE OF PERMITTED OPERATION BEING MONITORED Marion (Street) NC 28752 County McDowell ❑ Lagoon ❑ Remediation: Infiltration Gallery (City) (State) (Zp) ❑ Spray Field ❑Remediation: Contact Person: Tim Horton Telephone#: (828) 652-8843 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Monitoring Well #4 No. of wells to be sampled: 4 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): Monitoring Well #4 Date sample collected: 7/12/24 FIELD ANALYSES: WAS Well Depth: 35.37 ft. Well Diameter: 2 in. pH 00400: 5.9 units Temp. 00010: 23.0 °C DRY at Depth to Water Level 82546: 20.82 ft. below measuring point Screened Interval: 18.5 ft. to 33 ft. Spec. Cond. 00094: µMhos time sampling, Measuring Point is 0.51 ft. above land surface Relative M.P. Elevation: ft. Odor 00085: None check Volume of water pumped/bailed before sampling: 0.63 gallons Appearance Clear here: ❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑■ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 7112-26124 Laboratory Name: Pace Analytical Certification No. 12,40, 12710 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 <0.020 mg/L Pb - Lead 01051 ug/L . o t orm�--— -eca _3a:6-16 /100mla Nitr-ate-(NO3)-as-N=00620---- ---mg/L----- Coliform: MF Total 31504 1100mL Phosphorus: Total as P 00665 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 <0.50 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 mg/L Al -Aluminum o1105 mg/L Boron: <50 ug/L pH (Lab) 00403 units Ba - Barium 01007 144 ug/L Cobalt: 3.Oug/L TOC 00680 mg/L Ca - Calcium 00916 mg/L Chloride 00940 mg/L Cd - Cadmium 01027 0.11 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 109 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑■ No (0) Specific Conductance o0095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total) Mn - Manganese o1055 131 ug/L method # TKN as N 00625 <0.50 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% GW-59 Rev.05-02-2017 ace° Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 August 20, 2024 Mr. Tim Horton City of Marion 3982 NC Hwy 226 South Marion, NC 28752 RE: Project: Monitoring Wells Pace Project No.: 92741682 Dear Mr. Horton: Enclosed are the analytical results for sample(s) received by the�laboratory on July 12, 2024. The results relate only to the samples included in this report. Results reported herein conform fo the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise n ted in the body of the report. The test results provided in this final report were generated by • Pace Analytical Services -Asheville • Pace Analytical Services - Charlotte • Pace Analytical Services - Ormond Beach Report revised to remove VOCs JWB 8/20/24 If you have any questions concerning this report, please feel Sincerely, Jonathan W Biddix jonathan.biddix@pacelabs.com 704-977-0978 Project Manager Enclosures REPORT OF This report shall not t without the written consent of the following laboratories within the Pace Network: contact me. ANALYSIS luced, except in full, Analytical Services, LLC. Page 1 of 27 �Yace" SAMPLE SUMMARY Project: Pace Project No.: Monitoring Wells 92741682 Lab ID Sample ID Matrix Date Collected Date Received 92741682001 MW-1 R Water 07/12/24 11:45 07/12/24 17:02 92741682002 MW-2 Water 07/12/2413:15 07/12/2417:02 92741682003 MW-3 Water 07/12/2415:15 07/12/2417:02 92741682004 MW-4 Water 07/12/2412:30 07/12/2417:02 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 REPORT OF LABO TORY ANALYSIS This report shall not be ri produced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 27 ace° Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Monitoring Wells Pace Project No.: 92741682 Sample: MWAR Parameters Lab ID: 92741682001 Collected: Results Units PQL I 07/12/24 11:45 MDL DF Received: 07/12/24 17:02 Matrix: Water Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlott Performed by PACE 1 07/29/24 16:18 Collected By Mattew 1 07/29/24 16:18 Reusch Collected Date 7/12/24 1 07/29/24 16:18 Collected Time 11:45 1 07/29/24 16:18 pH 5.8 Std. Units 1 07/29/24 16:18 Temperature 21.2 deg C 1 07/29/24 16:18 Static Water Level 25.85 feet 1 07/29/24 16:18 Specific Conductance 21.5 umhos/cm 1 07/29/24 16:18 Oxygen, Dissolved 6.9 mg/L 1 07/29/24 16:18 7782-44-7 Total Well Depth 62.62 feet 1 07/29/24 16:18 Turbidity 9.9 NTU 1 07/29/24 16:18 Odor ND 1 07/29/24 16:18 Appearance CLEAR 1 07/29/24 16:18 200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 Pace Analytical S,-rvices - Ormond each Boron Iron 200.8 MET ICPMS Barium Cadmium Cobalt Manganese 4500H+ pH, Electrometric pH at 25 Degrees C 300.0 IC Anions 28 Days Bromide Chloride Fluoride Sulfate 350.1 Ammonia Nitrogen, Ammonia Date: 08/20/2024 10:53 AM ND ug/L 50.01 12.4 1 07/23/24 09:40 07/23/24 22:41 7440-42-8 396 ug/L 40.0 25.0 1 07/23/24 09:40 07/23/24 22:41 7439-89-6 Analytical Method: EPA 200.8 Preparation Method: EPA 200.8 Pace Analytical Services - Ormond !,Beach 35.2 ug/L 1.0 ! 0.50 1 07/23/24 09:40 07/24/24 16:06 7440-39-3 ND ug/L 0.10', 0.067 1 07/23/24 09:40 07/24/24 16:06 7440-43-9 ND ug/L 1.0' 0.24 1 07/23/24 09:40 07/24/24 16:06 7440-48-4 10.0 ug/L 1.0' 0.29 1 07/23/24 09:40 07/24/24 16:06 7439-96-5 Analytical Method: SM 4500-H+B- 0 1 Pace Analytical Services - Asheville' 6.2 Std. Units 0.10 0.10 1 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services - Asheville ND mg/L 0.10 0.060 1 ND mg/L 1.0 0.60 1 0.060J mg/L 0.101'i 0.050 1 0.68J mg/L 1.0 0.50 1 Analytical Method: EPA 350.1 Rev 2 0 1993 Pace Analytical Services - Asheville ND mg/L 0.10 0.031 1 REPORT OF LABORATORYI ANALYSIS This report shall not b reproduced, except in full, without the written consent of 3ace Analytical Services, LLC. 07/19/24 12:39 07/15/24 00:57 24959-67-9 07/15/24 00:57 16887-00-6 07/15/24 00:57 16984-48-8 07/15/24 00:57 14808-79-8 07/26/2417:59 7664-41-7 H3 Page 5 of 27 �ace- ANAL Project:. Monitoring Wells Pace Project No.: 92741682 - RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: MW-2 Parameters Lab ID: 92741682002 Collecte Results Units PQL 07/12/24 13:15 MDL DF Received: 07/12/24 17:02 Matrix: Water Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlott, Performed by PACE 1 07/29/24 16:21 Collected By Mattew 1 07/29/24 16:21 Reusch Collected Date 7/12/24 1 1 07/29/24 16:21 Collected Time 12:54 1 07/29/24 16:21 pH 6.4 Std. Units 1 07/29/24 16:21 Temperature 20.9 deg C 1 07/29/24 16:21 Static Water Level 18.38 feet 1 07/29/24 16:21 Specific Conductance 418.4 umhos/cm 1 07/29/24 16:21 Oxygen, Dissolved 1.1 mg/L 1 07/29/24 16:21 7782-44-7 Total Well Depth 38.02 feet 1 07/29/24 16:21 Turbidity 5.3 NTU 1 07/29/24 16:21 Odor ND 1 07/29/24 16:21 Appearance CLEAR 1 07/29/24 16:21 200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 Pace Analytical Services - Ormond: each Boron Iron 200.8 MET ICPMS Barium Cadmium Cobalt Manganese 4500H+ pH, Electrometric pH at 25 Degrees C 300.0 IC Anions 28 Days Bromide Chloride Fluoride Sulfate 350.1 Ammonia Nitrogen, Ammonia Date: 08/20/2024 10:53 AM 47.5J ug/L 50.0 12.4 1 07/23/24 09:40 07/23/24 22:45 7440-42-8 42100 ug/L 80.0 50.0 2 07/23/24 09:40 07/24/24 19:54 7439-89-6 Analytical Method: EPA 200.8 Preparation Method: EPA 200.8 Pace Analytical Services - Ormond each 56.8 ug/L 1.0 0.50 1 07/23/24 09:40 07/24/24 16:17 7440-39-3 ND ug/L 0.10', 0.067 1 07/23/24 09:40 07/24/24 16:17 7440-43-9 0.69J ug/L 1.01 0.24 1 07/23/24 09:40 07/24/24 16:17 7440-48-4 1230 ug/L 5.0 1.5 5 07/23/24 09:40 07/26/24 14:58 7439-96-5 Analytical Method: SM 4500-H+B-2 0 1 Pace Analytical Services - Asheville i 6.6 Std. Units 0.101 0.10 1 Analytical Method: EPA 300.0 Rev 2I.1 1993 Pace Analytical Services - Asheville) 0.078J mg/L 0.101 0.060 1 2.1 mg/L 1.0 !, 0.60 1 0.075.1 mg/L 0.10', 0.050 1 0.591 mg/L 1.0I 0.50 1 Analytical Method: EPA 350.1 Rev 2 0 1993 Pace Analytical Services - Asheville 5.7 mg/L 0.101 0.031 1 REPORT OF LABORATORYII ANALYSIS This report shall not b� r produced, except in full, without the written consent of ace Analytical Services, LLC. 07/19/2412:47 H3 07/15/24 01:12 24959-67-9 07/15/24 01:12 16887-00-6 07/15/24 01:12 16984-48-8 07/15/24 01:12 14808-79-8 07/26/24 18:01 7664-41-7 Page 7 of 27 ace" Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANAL Project: Monitoring Wells Pace Project No.: 92741682 . RESULTS Sample: MW-3 Parameters Lab ID: 92741682003 Collect° Results Units PQL : 07/12/24 15:15 Received: MDL DF Prepared 07/12/24 17:02 Matrix: Water Analyzed CAS No. Qua] Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by PACE 1 07/29/24 16:24 Collected By Mattew 1 07/29/24 16:24 Reusch Collected Date 7112124 1 07/29/24 16:24 Collected Time 15:15 1 07/29/24 16:24 pH 5.0 Std. Units 1 07/29/24 16:24 Temperature 19.3 deg C 1 07/29/24 16:24 Static Water Level 34.07 feet 1 07/29/24 16:24 Specific Conductance 119.0 umhos/cm 1 07/29/24 16:24 Oxygen, Dissolved 5.8 mg/L 1 07/29/24 16:24 7782-44-7 Total Well Depth 50.02 feet 1 07/29/24 16:24 Turbidity 9.9 NTU 1 07/29/24 16:24 Odor ND 1 07/29/24 16:24 Appearance Clear 1 07/29/24 16:24 200.7 MET ICP Analytical Method: EPA 200.7 PrepE ration Method: EPA 200.7 Pace Analytical Services - Ormond,i E each Boron Iron 200.8 MET ICPMS Barium Cadmium Cobalt Manganese 4500H+ pH, Electrometric pH at 25 Degrees C 300.0 IC Anions 28 Days Bromide Chloride Fluoride Sulfate 350.1 Ammonia Nitrogen, Ammonia Date: 08/20/2024 10:53 AM ND ug/L 50.0I 12.4 1 07/24/24 09:48 07/25/24 03:31 7440-42-8 438 ug/L 40.0 j 25.0 1 07/24/24 09:48 07/25/24 03:31 7439-89-6 Analytical Method: EPA 200.8 Pre ration Method: EPA 200.8 Pace Analytical Services - Ormond! Beach 405 ug/L 1.0I 0.50 1 07/24/24 09:47 07/26/24 00:22 7440-39-3 0.54 ug/L 0.101 0.067 1 07/24/24 09:47 07/26/24 00:22 7440-43-9 3.1 ug/L 1.0 0.24 1 07/24/24 09:47 07/26/24 00:22 7440-48-4 96.7 ug/L 1.0 0.29 1 07/24/24 09:47 07/26/24 00:22 7439-96-5 Analytical Method: SM 4500-H+B-2011 Pace Analytical Services - Asheville) 5.3 Std. Units 0.4! 12 0.10 1 Analytical Method: EPA 300.0 Rev 1 1993 Pace Analytical Services -Asheville 0.13 mg/L 0.101 0.060 1 7.3 mg/L 1.01 0.60 1 ND mg/L 0.101 0.050 1 ND mg/L 1.0 0.50 1 Analytical Method: EPA 350.1 Rev 2 0 1993 Pace Analytical Services - Asheville ND mg/L 0.4 0.031 1 REPORT OF LABORATORY ANALYSIS This report shall not b I produced, except in full, without the written consent of lace Analytical Services, LLC. 07/19/24 13:01 07/15/24 01:27 24959-67-9 07/15/24 01:27 16887-00-6 07/15/24 01:27 16984-48-8 07/15/24 01:27 14808-79-8 07/26/2418:05 7664-41-7 H3 Page 9 of 27 ace° Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANAL' L RESULTS Project: Monitoring Wells Pace Project No.: 92741682 Sample: MW-4 Lab ID: 92741682004 Collect 07/12/24 12:30 Received: 07/12/24 17:02 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by PACE 1 07/29/24 16:27 Collected By Matthew 1 07/29/24 16:27 Reusch Collected Date 7/12/24 j 1 07/29/24 16:27 Collected Time 12:08 1 07/29/24 16:27 pH 4.9 Std. Units 1 07/29/24 16:27 Temperature 23.0 deg C 1 07/29/24 16:27 Static Water Level 20.82 feet 1 07/29/24 16:27 Specific Conductance 70.2 umhos/cm 1 07/29/24 16:27 Oxygen, Dissolved 2.0 mg/L 1 07/29/24 16:27 7782-44-7 Total Well Depth 35.37 feet 1 07/29/24 16:27 Turbidity 3.4 NTU 1 07/29/24 16:27 Odor ND 1 07/29/24 16:27 Appearance Clear 1 07/29/24 16:27 200.7 MET ICP Analytical Method: EPA 200.7 PrepE ration Method: EPA 200.7 Pace Analytical Services - Ormond each Boron Iron 200.8 MET ICPMS Barium Cadmium Cobalt Manganese 4500H+ pH, Electrometric pH at 25 Degrees C 300.0 IC Anions 28 Days Bromide Chloride Fluoride Sulfate 350.1 Ammonia Nitrogen, Ammonia Date: 08/20/2024 10:53 AM ND ug/L 50.01 12.4 1 07/24/24 09:48 07/25/24 03:34 7440-42-8 109 ug/L 40.0; 25.0 1 07/24/24 09:48 07/25/24 03:34 7439-89-6 Analytical Method: EPA 200.8 Prep ration Method: EPA 200.8 Pace Analytical Services - Ormond E each 144 ug/L 1.01 0.50 1 07/24/24 09:47 07/26/24 00:27 7440-39-3 0.11 ug/L 0.10i 0.067 1 07/24/24 09:47 07/26/24 00:27 7440-43-9 3.0 ug/L 1.01 0.24 1 07/24/24 09:47 07/26/24 00:27 7440-48-4 131 ug/L 1.01 0.29 1 07/24/24 09:47 07/26/24 00:27 7439-96-5 Analytical Method: SM 4500-H+B-2 11 Pace Analytical Services - Asheville 5.2 Std. Units 0.10� 0.10 1 Analytical Method: EPA 300.0 Rev ,21 1993 Pace Analytical Services -Asheville 0.19 mg/L 0.10 0.060 1 2.3 mg/L 1.0 0.60 1 ND mg/L 0.10 0.050 1 ND mg/L 1.0 0.50 1 Analytical Method: EPA 350.1 Rev 12 01993 Pace Analytical Services -Asheville 11 ND mg/L 0.10I 0.031 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of�Pace Analytical Services, LLC. 07/19/24 12:43 07/15/24 01:42 24959-67-9 07/15/24 01:42 16887-00-6 07/15/24 01:42 16984-48-8 07/15/24 01:42 14808-79-8 07/26/2418:06 7664-41-7 H3 Page 11 of 27 Pace Analytical Services, LLC 2225 Riverside Dr. ace® Asheville, NC 28804 (828)254-7176 QUALITY CO TROL DATA Project: Monitoring Wells Pace Project No.: 92741682 QC Batch: 1028302 Analysis Metl-II0 EPA 200.7 QC Batch Method: EPA200.7 Analysis Desdri tion: 200.7 MET Laboratory: Pace Analytical Services -Ormond Beach Associated Lab Samples: 92741682001, 92741682002 I METHOD BLANK: 5651585 i Matrix: I i Vater Associated Lab Samples: 92741682001, 92741682002 1 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Boron ug/L ND 50.0 12.4 07/23/24 20:55 Iron ug/L ND 1 40.0 25.0 07/23/24 20:55 LABORATORY CONTROL SAMPLE: 5651586 1GS Spike L LCS %Rec Parameter Units Conc. Re ult % Rec Limits Qualifiers Boron ug/L 1250 1240 99 85-115 Iron ug/L 2500 2540 102 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 5651587 5651588 MS MSD' 35891259001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Boron ug/L 70.7 1250 125i0 1320 1360 100 104 70-130 3 20 Iron ug/L 26.8J 2500 2500 2550 2650 101 105 70-130 4 20 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 5651589 5651590 MS MSD 11 35893228004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Boron ug/L 13AJ 1250 1256 1270 1280 100 101 70-130 1 20 Iron ug/L 434 2500 2500 3000 3040 103 104 70-130 1 20 Results presented on this page are in the units indicated by the "Units" 1.1umn except where an alternate unit is presented to the right of the result. REPORT OF LABIRATORY ANALYSIS i This report shall not be r produced, except in full, Date: 08/20/2024 10:53 AM without the written consent off ace Analytical Services, LLC. Page 13 of 2, �Yaceo QUALITY CC, Project: Monitoring Wells Pace Project No.: 92741682 L DATA QC Batch: 1028303 Analysis Method: EPA 200.8 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QC Batch Method: EPA 200.8 Analysis Desdr ption: 200.8 MET Laboratory: Pace Analytical Services - Ormond Beach Associated Lab Samples: 92741682001, 92741682002 METHOD BLANK: 5651591 Matrix: Aater Associated Lab Samples: 92741682001, 92741682002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Barium ug/L ND 1.0 0.50 07/24/2413:55 Cadmium ug/L ND 0.10 0.067 07/24/2413:55 Cobalt ug/L ND 1.0 0.24 07/24/2413:55 Manganese ug/L ND 1.0 0.29 07/24/2413:55 LABORATORY CONTROL SAMPLE: 5651592 Spike L�S LCS % Rec Parameter Units Conc. Rie�ult % Rec Limits Qualifiers Barium ug/L 50 46.2 92 85-115 Cadmium ug/L 5 5.1 102 85-115 Cobalt ug/L 50 48.3 97 85-115 Manganese ug/L 50 47.5 95 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 5651593 lil 5651594 MS MSD 35892652002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua[ Barium ug/L 10.9 50 50 76.9 58.8 132 96 70-130 27 20 M1,R1 Cadmium ug/L 0.067U 5 5 4.6 4.7 92 94 70-130 2 20 Cobalt ug/L 0.24U 50 5,0 46.0 47.0 92 94 70-130 2 20 Manganese ug/L 14.2 50 50 64.8 59.6 101 91 70-130 8 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not b II eproduced, except in full, Date: 08/20/2024 10:53 AM without the written consent of Pace Analytical Services, LLC. Page 15 of 27 �YaGV° QUALITY Project: Monitoring Wells Pace Project No.: 92741682 QC Batch: 869359 Analysis ME QC Batch Method: SM 4500-H+B-2011 Analysis De Laboratory: Associated Lab Samples: 92741682001, 92741682002, 92741682003, SAMPLE DUPLICATE: 4480883 92741646001 Parameter Units Result pH at 25 Degrees C Std. Units 6.9 SAMPLE DUPLICATE: 4480884 Parameter pH at 25 Degrees C Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 DATA SM 4500-H+B-2011 Lion: 4500H+B pH Pace Analytical Services - Asheville 1682004 Dup Max Result RPD RPD Qualifiers 6.9 0 10 H3 92741646002 Dup Max Units Result Result RPD RPD Qualifiers Std. Units 6.8 6.9 1 10 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 08/20/2024 10:53 AM REPORT OF LAB �2ATORY ANALYSIS This report shall not bei r produced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 27 Pace Analytical Services, LLC 2225 Riverside Dr. ace® Asheville, NC 28804 (828)254-7176 QUALITY CC I ITROL DATA Project: Monitoring Wells Pace Project No.: 92741682 QC Batch: 870767 Analysis Mettib EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Desri tion: 350.1 Ammonia Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92741682001, 92741682002, 92741682003, 927 1682004 III METHOD BLANK: 4487533 Matrix: ater Associated Lab Samples: 92741682001, 92741682002, 92741682003, 9 7 1682004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Ammonia mg/L ND 0.10 0.031 07/26/24 17:22 LABORATORY CONTROL SAMPLE: 4487534 Spike L �S LCS %Rec Parameter Units Conc. R�! uIt % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 5.3 105 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4487535 II 4487536 MS MSD 92742858001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Ammonia mg/L 26.0 5 5 31.5 31.6 110 112 90-110 0 10 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4487537 4487538 MS MSD I 92742858002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua[ Nitrogen, Ammonia mg/L 27.0 5 5 31.9 31.9 98 99 90-110 0 10 i I Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LAB �� RATORY ANALYSIS This report shall not b r produced, except in full, )ate: 08/20/2024 10:53 AM without the written consent of ace Analytical Services, LLC. Page 19 of 27 Pace Analytical Services, LLC 2225 Riverside Dr. ace® Asheville, NC 28804 (828)254-7176 QUALITY CO TROL DATA Project: Monitoring Wells Pace Project No.: 92741682 QC Batch: 868003 Analysis Meth o EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Desc i tion: 353.2 Nitrate + Nitrite, Unpres. Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92741682001, 92741682002, 92741682003, 92j/ 1682004 METHOD BLANK: 4474376 Matrix: U ter Associated Lab Samples: 92741682001,92741682002,92741682003,927,tl682OO4 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Nitrate mg/L ND 0.020 0.0039 07/13/24 02:27 Nitrogen, Nitrite mg/L 0.0012J 0.020 0.0012 07/13/24 02:27 LABORATORY CONTROL SAMPLE: 4474377 Spike S LCS % Rec Parameter Units Conc. Re ult % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 1.5 1.4 96 90-110 Nitrogen, Nitrite mg/L 1 1.0 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4474378 4474379 MS MSD 92741472001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD 2.4 2.4 102 100 90-110 1 RPD Qual 10 Nitrogen, Nitrate mg/L 0.84 1.5 1.5 Nitrogen, Nitrite mg/L 0.39 1 1.5 1.5 110 109 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4474380 4474381 MS MSD 92741682001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. I Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 0.052 1.5 1.5 1.5 1.5 98 98 90-110 0 10 Nitrogen, Nitrite mg/L 0.00191 1 1 1.0 1.0 103 102 90-110 1 I i i 10 Results resented on this page are in the units indicated b the "Units" p P 9 Y to umn except where an alternate unit is presented to the right of the result. REPORT OF LA1301 ZATORY ANALYSIS This report shall not bel I r produced, except in full, Date: 08/20/2024 10:53 AM without the written consent of ace Analytical Services, LLC. Page 21 of 2' �Yace" Project: Monitoring Wells Pace Project No.: 92741682 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the re ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limil MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets proje bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and he LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 C Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. 'Total' may vary slightly from the sum of the reported component par, Pace Analytical is TNI accredited. Contact your Pace PM for the curre TNI - The NELAC Institute. ANALYTE QUALIFIERS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 data due to dilution of the sample aliquot. below the adjusted reporting limit. requirements for quantitative data with known precision and using Method 8270. The result for each analyte is been used to calculate % recovery and RPD values. 4 for the analysis of Acrolein and Acrylonitrile by EPA using Method 8270. The result reported for calculated parameters that are typically reported as list of accredited analytes. B Analyte was detected in the associated method blank. it H3 Sample was received or analysis requested beyond the rileII ognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch acceptil based on laboratory control sample (LCS) recovery. R1 RPD value was outside control limits. REPORT OF TORY ANALYSIS This report shall not bejreproduced, except in full, Date; 08/20/202410:53 AM without the written consent of (Pace Analytical Services, LLC. Page 23 of 27 I!Vace "';-1-itle: ENV-1FRM-HUN1-0083 V05 Condition Upon Receipt Effective Date: 05/24/2024 Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville [ SampleClient Name: Upon Receipt t Ult- Courier: ❑Fed Ex LQUPs ❑USPs ❑ Commercial ❑Pace ❑Other: Custody Seal Present? Yes No Seals Intact? [ Packing Material: [:]Bubble, Wrap QBubble Bags Jh Thermometer: (' ❑IRGun ID: � tX Type of Ice: Correction Factor: Cooler Temp: f c/1� _ Add/Subtract(T) I1 f t- Cooler Temp Corrected (° USDA.Regulated Soil (( N/A, water sample) Did samples originate ina quarantine zone within the United States: CA; Raleigh❑ Mechanicsville❑ AtlantaM.. Kernar- fivar-1 Project # W0## 92?41682 QCIienE ,y�, 92141682 . ❑XJ No N/A. Date/Initials Person Examining Contents: El Other Biological Tissue..Frozen? i LJ []Yes ❑No 'V_J4N/A []Blue ❑None Temp should be above freezing to 6'C 05amples out.of temp criteria. Sampleson ice, cooling process has begun Did samples originate -from a foreign source (internationally, including Hawaii and Puerto Rico)? QYes []No Chain of Custody Present? es QNC ❑N/A 1. Samples Arrived within Hold Time? 9y6_1__13N( ON/A 2. Short Hold Time Analysis (<72 hr.)? QYes IN ❑N/A 3. Rush Turn. Around Time Requested? QYes ti i ❑N/A 4. Sufficient Volume? es N ❑N/A 5. Correct Containers Used? es ONd -Pace Containers Used? e N ON/A ON/q 6. Containers Intact? C YYes ONo ❑N/A 7. Dissolved analysis: Samples. Field Filtered? es ON ON/A 8. Sample Labels Match 000? ON Includes Date/Time/ID/Analysis Matrix: ❑N/A 9. Headspace in VOA Vials (>5-6mm)? QYes ON `b4JA 10. Trip Blank Present? QYes ON Trip Blank Custody Seals Present? []Yes ON 'PkN/A N/A 11. COMMENTS/SAMPLE-DISCREPANCY I Field Data Required? [:]Yes ❑No I I i Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION i i I Person contacted: Date/Time: Project Manager SCURF Review: Project Manager SRF Review:. Date: Date: Qualtrax ID: 69614 Page 1 of 2 Page 25 of 27 a n r'4, A z7 a� V 0 3 3' c Cb 0 _ 00 N gD.M D l N o - b oo n S V^ T! 3 < O a to m n O % • X a S d .t sC1' b D 3 3 tra n iGf •-� m. o C•°. o 2., m D I o y n _ ° o A N C » x O r p u e o n 0 3 'a ;t ° 0 r O wco. O 00. >. CA tt a! .... o c w c Ol a .. - ........ i "••-• 9 CD a 0 � N N g � F n ? to o — rt � a: o to 0 I to n o 200:8 Metals 8 3 360.0 IC Anions 28 Days 3 i 350.1 Ammonia 3 ?� 351.2TotalKJeldahl Nitrogen c a V 353:2Nitrogen, NO2/NO3unpres N. to 4500H+ pH, Electrometric n vCi z 0 V. N X 62008 MSV 3 ° m o SM4500P-E, Phosphate, Ortho ' n D: x -� 7• O w ,a. 2 o o 0 7 m - lab Use only; � v 7 ti w 3 �..v 22 @ 3 e^ n t r (Y ZN2, G71 En` x c s 3 = 3 "w ' orpyi � °a v n m Vi 9' ��— CL X s + 3 3° o 3 0. z �•`8. V -- �s• 3 n: ° w Preservation non-conformance idemitfed for —— — --_. 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