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Home My WebLink AboutNCG160239_2024 DMR_20240729 (2) Pace Analytical Services,LLC ace. 106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 May 16, 2024 Bruce Menke Delta Companies Inc. 114 Silver Springs Road Cape Girardeau, MO 63702 RE: Project: DENTON LIQUID TERMINAL 5/4/24 Pace Project No.: 92729341 Dear Bruce Menke: Enclosed are the analytical results for sample(s)received by the laboratory on May 07,2024. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual,where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services-Asheville • Pace Analytical Services-Charlotte If you have any questions concerning this report,please feel free to contact me. Sincerely, -cda2 Kayla Holliday kayla.holliday@pacelabs.com 803-227-2706 Project Manager Enclosures �� , • a REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, { ,� without the written consent of Pace Analytical Services,LLC. Page 1 of 12 Pace Analytical Services,LLC ace® 106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 CERTIFICATIONS Project: DENTON LIQUID TERMINAL 5/4/24 Pace Project No.: 92729341 Pace Analytical Services Charlotte South Carolina Laboratory ID:99006 South Carolina Certification#:99006001 9800 Kincey Ave.Ste 100, Huntersville,NC 28078 South Carolina Drinking Water Cert.#:99006003 North Carolina Drinking Water Certification#:37706 Florida/NELAP Certification#:E87627 North Carolina Field Services Certification#:5342 Kentucky UST Certification#:84 North Carolina Wastewater Certification#:12 Louisiana DoH Drinking Water#:LA029 South Carolina Laboratory ID:99006 VirginiaNELAP Certification#:460221 Pace Analytical Services Asheville 2225 Riverside Drive,Asheville,NC 28804 South Carolina Laboratory ID:99030 Florida/NELAP Certification#:E87648 South Carolina Certification#:99030001 North Carolina Drinking Water Certification#:37712 VirginiaNELAP Certification#:460222 North Carolina Wastewater Certification#:40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,LLC. Page 2 of 12 Pace Analytical Services,LLC ace® 106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 SAMPLE SUMMARY Project: DENTON LIQUID TERMINAL 5/4/24 Pace Project No.: 92729341 Lab ID Sample ID Matrix Date Collected Date Received 92729341001 OUTFALL#2 Water 05/04/24 12:30 05/07/24 12:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,LLC. Page 3 of 12 Pace Analytical Services,LLC ace. 106 Vantage Point Drive West Columbia,SC 29172 (603)791-9700 SAMPLE ANALYTE COUNT Project: DENTON LIQUID TERMINAL 5/4/24 Pace Project No.: 92729341 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92729341001 OUTFALL#2 EPA 1664B SAP1 1 PASI-C SM 2540D-2015 CMW1 1 PASI-A PAS I-A=Pace Analytical Services-Asheville PASI-C=Pace Analytical Services-Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,LLC. Page 4 of 12 Pace Analytical Services,LLC 106 Vantage Point Drive ( Pace. West Columbia,SC 29172 (803)791-9700 ANALYTICAL RESULTS Project: DENTON LIQUID TERMINAL 5/4/24 Pace Project No.: 92729341 Sample: OUTFALL#2 Lab ID: 92729341001 Collected: 05/04/24 12:30 Received: 05/07/24 12:20 Matrix:Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM,Oil and Grease Analytical Method:EPA 1664E Pace Analytical Services-Charlotte Oil and Grease ND mg/L 4.9 1 05/16/24 11:31 2540D Total Suspended Solids Analytical Method:SM 2540D-2015 Pace Analytical Services-Asheville Total Suspended Solids ND mglL 9.5 1 05/09/24 12:17 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:05/16/2024 10:02 PM without the written consent of Pace Analytical Services,LLC. Page 5 of 12 Pace Analytical Services,LLC ace® 106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 QUALITY CONTROL DATA Project: DENTON LIQUID TERMINAL 5/4/24 Pace Project No.: 92729341 QC Batch: 854880 Analysis Method: EPA 1664B QC Batch Method: EPA 1664E Analysis Description: 1664 HEM,Oil and Grease Laboratory: Pace Analytical Services-Charlotte Associated Lab Samples: 92729341001 METHOD BLANK: 4410917 Matrix: Water Associated Lab Samples: 92729341001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Oil and Grease mg/L ND 5.0 05/16/24 11:28 LABORATORY CONTROL SAMPLE: 4410918 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers Oil and Grease mg/L 40 32.1 80 78-114 MATRIX SPIKE SAMPLE: 4410919 35877610001 Spike MS MS %Rec Parameter Units Result Conc. Result %Rec Limits Qualifiers Oil and Grease mg/L 1.1U 38.5 32.0 82 78-114 SAMPLE DUPLICATE: 4410920 50372461002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Oil and Grease mg/L <4.8 ND 30 Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:05/16/2024 10:02 PM without the written consent of Pace Analytical Services,LLC. Page 6 of 12 Pace Analytical Services,LLC ace® 106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 QUALITY CONTROL DATA Project: DENTON LIQUID TERMINAL 5/4/24 Pace Project No.: 92729341 QC Batch: 853034 Analysis Method: SM 2540D-2015 QC Batch Method: SM 2540D-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services-Asheville Associated Lab Samples: 92729341001 METHOD BLANK: 4402079 Matrix: Water Associated Lab Samples: 92729341001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 05/09/24 12:14 LABORATORY CONTROL SAMPLE: 4402080 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers Total Suspended Solids mg/L 250 246 98 90-110 SAMPLE DUPLICATE: 4403421 92728826001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Suspended Solids mg/L 232 236 2 25 SAMPLE DUPLICATE: 4403422 92728826003 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Suspended Solids mg/L 3160 3070 3 25 Results presented on this page are In the units indicated by the"Units"column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:05/16/2024 10:02 PM without the written consent of Pace Analytical Services,LLC. Page 7 of 12 Pace Analytical Services,LLC ace® 106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 QUALIFIERS Project: DENTON LIQUID TERMINAL 5/4/24 Pace Project No.: 92729341 DEFINITIONS DF-Dilution Factor,if reported,represents the factor applied to the reported data due to dilution of the sample aliquot. ND-Not Detected at or above adjusted reporting limit. TNTC-Too Numerous To Count J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL-Adjusted Method Detection Limit. PQL-Practical Quantitation Limit. RL-Reporting Limit-The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S-Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is a combined concentration. Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values. LCS(D)-Laboratory Control Sample(Duplicate) MS(D)-Matrix Spike(Duplicate) DUP-Sample Duplicate RPD-Relative Percent Difference NC-Not Calculable. SG-Silica Gel-Clean-Up U-Indicates the compound was analyzed for,but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting.Therefore,calculated parameters that are typically reported as "Total"may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes. TNI-The NELAC Institute. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:05/16/2024 10:02 PM without the written consent of Pace Analytical Services,LLC. Page 8 of 12 Pace Analytical Services,LLC ace® 106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: DENTON LIQUID TERMINAL 5/4/24 Pace Project No.: 92729341 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92729341001 OUTFALL#2 EPA 1664B 854880 92729341001 OUTFALL#2 SM 2540D-2015 853034 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:05/16/2024 10:02 PM without the written consent of Pace Analytical Services,LLC. Page 9 of 12 DC# Tit(e: ENV-FRM-HUNT-0083 v04_Sample Condition Upon Receipt - ace Effective Date:4/26/2024 10:14:05 AM Laboratory receiving samples: Asheville❑ Eden❑ Greenwood 0 Huntersville,FRaleighD Mechanicsville❑ AtlantaD Kernersvillef Sample Condition Client Nam ■ aO# : 927A9n/� 1 Upon Receipt . e ti (z=z, ( � 2. ,,_ lrt,rc�,isco!ct#' w L Sit Courier: ❑Fed Ex ❑USPS ❑Client 11111111 1111111111 1111 ❑ Commercial ❑Pace �'p.605 ❑Other: 92729341 Custody Seal Present? ❑Yes --'n No Seals Intact? ❑Yes. ❑Nor'�N/A _» Date/Initials Person Examining Contents ~ 4 . 1-�. i Packing Material' p Bubble Wrap 0 Bubble Bags ❑None 0 Other Biological TissueE g n? T et �-�f ❑Yes ❑No L1 N/A hermo IR Gun ID C) l Type of Ice: .-21—get 0 0 None Correction Factor: Cooler Temp: -'•' Add/Subtract('C) (` Temp should be above freezing to 6°C '� ❑Samples out of temp criteria.Samples on ice,cooling,process Cooler Temp Corrected ("C): ) has begun USDA Regulated Soil(Q N/A,water sample) Did samples originate in uarantine zone within the United States:CA,NY,or SC Did samples originate from a foreign source(internationally; (check maps)?❑Yes„AO Including Hawaii and Puerto Rico)?❑Yes „<lErilo Comments/Discrepancy: Chain of Custody Present? es 0 No D N/A 1. • Samples Arrived within Hold Time? ,®Y s 0 No ❑N/A 2, Short Hold Time Analysis(<72 hr.)? ❑Yes —121'No ❑N/A 3. Rush Turn Around Time Requested? ❑Yes 0-No ❑N/A 4. Sufficient Volume? I]Yes ' ❑No ❑N/A 5. Correct Containers Used? {, D�Yes ❑No O N/A 6. -Pace Containers Used? ;i:J Yes ❑No ❑N/A Containers Intact? es ❑No ❑N/A 7. Dissolved analysis:Samples Field Filtered? ❑Yes' ❑No 711.17,17A 8. Sample Labels Match COC? Aces ❑No ON/A 9. - -Includes Date/lime/ID/Analysis Matrix:__ -"\1 _ Headspace in VOA Vials(>5-6mm)? ❑Yes 0 No ..-fl NJA 10. Trip Blank Present? ❑Yes ❑'No /❑N/A 11. Trip Blank Custody Seals Present? ❑yes ❑No ❑N/A COMMENTS/SAMPLE DISCREPANCY ' Field Data Required? ❑Yes ❑No Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Date/Time: Project Manager SCURF Review: bate: Project Manager SRF Review: Date: Page 10 of 12 Qualtrax ID:69614 Paae 1 of 2 DC# Title: ENV-FRM-HUN1-0083 v04_Sample Condition Upon Receipt /lice • A,•'-:s : ..”.. Effective Date:4/26/2024 10:14:05 AM • 'Check mark top half of box if pH and/or dechlorination Is verified and within the Wa# ' 92729341 acceptance range for preservation samples. Project.I Exceptions:VOA,Coliform,TOC,Oil and Grease,ORO/8C15(water)DOC,11.Hg PM: KH1 Due Date: 05/21/24 "Bottom half of box is to list number of bottles CLIENT: WC-Reeves "Check all unpreserved Nitrates for chlorine Laboratory Receiving Location:Asheville C EdenD Greenwood❑ Huntersvil RaleighLt mecnantcsvllieu AtlantaLJ Kernersvilleu Client Profile Number Notes _ �, 1 Y r a �, N Z Za ? a M �Zry co bj "2 $ v v ' ;Zs' v u ? a x = 8 7, 1 v z a a .. E -1 i a 1 'is E l a v io - Z V 14 Z 4 : N NY n 3 , . LL. V t�. .cE tV Z S .- i a a dN NV3 5 a ? , d 11 viA cg J a __, Ec;. o E: E E E 1 _, 4 p O > a; a , gi o' J aE .' fi A F E L bt V E E. V J J J a J E E JE Jin O o 0 ^ ^ S. _ 5 c = o' E E E E E E 0 c o 0� n .. nv .o o a p o.+ ,I., v ,V .. ,y17O3 h' y N $ S O h in a = Y � ani - , N a � > >or a a v , N .ymymm " m 0 I •4 9Oa ammo. rmomm at m RI m 3 4 o 0 > t > v°i gi m .., cc 1 \ \ \\\ \\\,\\ „ . \\ 2 \ \ 1 3 \ \\A 5 4 \\ \ \ ' , 6 \ \ Ilk \} \\ 9 \ _ , \\A 10 \ 11 \ \,\\\. �\ 12 \ \ \ \ pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative Lot ff adjusted added Note:Whenever there is a discrepancy affecting North Carolina compiiancesarnples,a copy of this form will be sent to the North Carolina DENR Certification Office(I.e. Out of hold,incorrect preservative,out of temp,incorrect containers. Qualtrax ID: 69614 Page 11 of 12 Paae2of2 -- 12 nldwes ii Z G}o 31.abed Jig; -:: Jo)puepluapl a�ucwiojuoo•uou uapeniata1d ,r. 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