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WQ0000957_GW Monitoring_20160405
NO, April 5, 2016 VALLEY PROTEINS , INC. Department of Environment & Natural Resources Division of Water Resources — Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: Valley Proteins, Inc. — Wadesboro Division, Permit #WQ0000957 Enclosed please find the Quarterly Monitoring Wells Report for our Wadesboro, North Carolina Division. If you require any additional information or wish to discuss the information in this report, please feel free to call me at (704) 694-3701. Sincerely, Chris Bivans General Manager P.O. Box 718 Wadesboro, NC 28170 704-694-3701 Fax:704-694-6145 www.valleyproteins.com �y � RECEIVED DEQ/DWR APR 12 Z016 WQROS FAYETTEVILLE REGIONAL OFFICE Creating Renewable Resources Built on Tradition SUBMIT FORM ON YELLOW PAPER ONI Y DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES. GROUNDWATER QUALITY MONITORING: IVISIONOFWATERQUALlfY-INFORMATtONPROCESSINGUNIT % COMPLIANCE REPORT FORM -617,MAIL, SERVICE.CENTER;;RALEIGH,'NC 2769.91617 ; Phone, (919}733 3221.,' FACILITY INFORMATION Please Print Clearfy or Type PERMIT Number: Expiration Date: 06/30/2018 Facility Name: Valley Proteins Non -Discharge W00000957 UIC Permit Name (if different): NPDES Other Facility Address: 656 Little Duncan Road TYPE OF PERMITTED OPERATION BEING MONITORED e Su nt; Wadesboro NC 28170 County Anson ❑ Lagoon ❑ Remediation: Infiltration Gallery ,t�fe, t_.p, fC❑ Spray Field ❑ Remediation: Contact Person: Chris Bivans Telephone#: 704-694-3701 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Behind Field #9 No. of wells to be sampled: 8 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW#1 Date sample collected: 03/16/16 FIELD ANALYSES: WAS Well Depth: 33 ft. Well Diameter: 2 in. pH 7.5 units Temp. 14.8 °C DRY at Depth to Water Level: 24.8 ft. below measuring point Screened Interval: ft. to ft. Spec. Cond. µMhos time of sampling,check Measuring Point is ft. above land surface Relative M.P. Elevation: ft. Odor No Odor Volume of water pumped/bailed before sampling: 12.0 gallons Appearance Clear here: ❑ Samples for metals were collected unfiltered: DYES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 03/16/16 - 03/22/16 Laboratory Name: PACE Analytical Certification No. PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD mg/I Nitrite (NOZ) as N mg/I Pb - Lead mg/I Coliform: MF Fecal <1 /loom[ Nitrate (NO3) as N 14.7 mg/I Zn -Zinc mg/I Coliform: MF Total /100ml Phosphorus: Total as P mg/I (Note: Use MPN method for highly turbid samples) Orthophosphate mg/I Other (Specify Compounds and Concentration Units): Dissolved Solids: Total 928 mg/I Al - Aluminum mg/I pH (when analyzed) 7.5 units Ba - Barium mg/I TOC 41.8 mg/I Ca - Calcium mg/I Chloride 359 mg/I Cd - Cadmium mg/I Arsenic mg/I Chromium: Total mg/I Grease and Oils mg/I Cu - Copper mg/I ORGANICS: (by GC, GC/MS, HPLC) Phenol mg/I Fe - Iron mg/I (Specify test and method #. ATTACH LAB REPORT.) Sulfate 31.2 mg/I Hg - Mercury mg/I ReportAttached? ❑ Yes (1) ❑ No (0) Specific Conductance µMhos K - Potassium mg/I VOC method # Total Ammonia <•10 mg/I Mg - Magnesium mg/I method # (Ammonia Nitrogen; N%as N; Ammonia Nitrogen, Total) Mn - Manganese mg/I , method # TKN as N mg/I Ni - Nickel mg/I method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% GW-59 Rev.1/2007 w ."_ l X!;a'ceAna1Xica1" (wawpacelabs.com ANALYTICAL RESULTS Project: SPRAYFIELD WELLS Pace Project No.: 92290350 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: MW-1 Parameters Lab ID: 92290350001 Collected: 03/16/16 10:05 Results Units Report Limit DF Received: 03/16/16 14:50 Matrix: Water Prepared Analyzed CAS No. Qua] MBIO 9222D Fecal Coliform CHT Analytical Method: SM 9222D Fecal Col]forms ND CFU/100 mL 1.0 1 03/16/16 15:37 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 928 mg/L 50.0 1 03/18/16 12:17 4500H+ pH, Electrometric Analytical Method: SM 4500-1-1+13 pH at 25 Degrees C 7.5 Std. Units 1.0 1 03/22/16 14:25 H6 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Sulfate 31.2 mg/L 2.0 1 03/17/1618:47 14808-79-8 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia ND mg/L 0.10 1 03/20/16 12:53 7664-41-7 353.2 Nitrogen, NO2/NO3 pres. Analytical Method: EPA 353.2 Nitrogen, NO2 plus NO3 14.7 mg/L 0.10 5 03/18/16 15:35 4500 Chloride Analytical Method: SM 4500-CI-E Chloride 359 mg/L 100 100 03/18/16 21:45 16887-00-6 5310E TOC Analytical Method: SM 5310B Total Organic Carbon 41.8 mg/L 1.0 1 03/19/16 16:25 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/23/2016 02:01 PM without the written consent of Pace Analytical Services, Inc.. Page 3 of 25 G$ RfiBf�'FICal 't)&um6tNaine: Pield:Da#a Sl eet Document Issued: April 6, 2015 No l of Dgeumei►h_Numlier: " F CtTI2-pLb OA2-red:QO Issuing AutHority: Pace Huntersbifl Qdality Office r t k�ieId.DaEa Sheet Client: Vaal wm�_ Location: iJI� PS O N L, !• Project Name/#: • rX Name and Afiliation (Sampler(s): Name and A.filiation (Inspector): k) I Well Information Well ID: _ -V bj r i Well Diameter: a Total Well Depth: 33.p ft Static Water Level: Well Locked: ciii) NO Constrdction; (&D Steel Stainless Steel Mu1.ti Factor*: 0 ,! b3 [(Radius/12)2 x 3.14 x 7.481 Casing Volume: gallons Height of Water Column: CaL 3 volumes: f �• O gallons Purge Information Date Purged: 15_ b_ Start Timer 4.5- _ Finish• I1:1 % Purge Rate �El /r - -- Purging Method: `13c+Total volume Purged: gallons Sampling Information ! • Date Collected: Time Collected am pm Sampling Equipment Used: % -v Bottle Type Preservation Analysis Required a: �2 /-5-00 n C sP—� 11Sh-� Na..SG14f _ '7-• A•vnma�vt. Field Measurements/Observations Sample Temp (°C): ) y • j Time: !O : o S Sample pH (s.u.): Time: ! o. o S Specific Cond. (6): ) Time: ReDox (mV): '+ Time: Odor: N ON E Time: P iD5 •GeneraMeather Observations Turbidity (ntu): f" Time: Diss Oxy (mg/L): — Time: -' Res. Cl (mg/4 Time: Other• Time.• Appearance: Cf ew v rh 1v �' fnl i wps 53z� 10 �p�. S i, h n Sampler Signature/Date: Stabilization Test MACE 03)l 6 il6 Time Purged pH (s.u.) Spec. Cond. (us) ReDox (mV) Turbidity (ntu) Diss Oxy. (mg/L) Temp. (°C) Volume R ove Other I. , 03--- t ID SUBMIT FORM ON YELLOW PAPER ONLY EPARTMENT OF ENVIRONMENT'& NATURAL RESOURCES, GROUNDWATER QUALITY MONITORING: �16117 IVISION,oFWATE.RQUALITY.-INFORMATIONPROCESSINGUNIT COMPLIANCE REPORT FORM MAIL SERVICE' CENTER,,RALEIGH,'NC27699;1617 .Phone::(919):733 3221- 3 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 06/30/2018 Facility Name: Valley Proteins Non -Discharge WQ0000957 UIC Permit Name (if different): NPDES Other Facility Address: 656 Little Duncan Road TYPE OF PERMITTED OPERATION BEING MONITORED Wadesboro """"' NC . 28170 County Anson ❑ Lagoon ❑ Remediation: Infiltration Gallery ='> 1 Spray Field ❑ Remediation: Contact Person: Chris Bivans Telephone#: 704-694-3701 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Behind Field #4 No. of wells to be sampled: 8 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW#2 Date sample collected: 03/16/16 FIELD ANALYSES: WAS Well Depth: 30 ft. Well Diameter: 2 in. pH 7.3 units Temp. 14.3 eC DRY at Depth to Water Level: 28.19 ft. below measuring point Screened Interval: ft. to ft. Spec. Cond. µMhos time of sampling, Measuring Point is ft. above land surface Relative M.P. Elevation: ft. Odor No Odor check Volume of water pumped/bailed before sampling: 15.25 gallons Appearance Clear here: ❑ Samples for metals were collected unfiltered: ❑YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 03/16/16 - 03/22/16 Laboratory Name: PACE Analytical Certification No. PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD mg/I Nitrite (NO2) as N mg/I Pb - Lead mg/I Coliform: MF Fecal <1 /100ml Nitrate (NO3) as N 10.4 mg/I Zn - Zinc mg/I Coliform: MF Total /100ml Phosphorus: Total as P mg/I (Note: Use MPN method for highly turbid samples) Orthophosphate mg/I Other (Specify Compounds and Concentration Units): Dissolved Solids: Total 1340 mg/i Al - Aluminum mg/I pH (when analyzed) 7.3 units Ba - Barium mg/I TOC 1.1 mg/I Ca - Calcium mg/I Chloride 403 mg/I Cd - Cadmium mg/I Arsenic mg/I Chromium: Total mg/I Grease and Oils mg/I Cu - Copper mg/I ORGANICS: (by GC, GC/MS, HPLC) Phenol mg/I Fe - Iron mg/I (Specify test and method #. ATTACH LAB REPORT.) Sulfate 8.6 mg/I Hg - Mercury mg/I ReportAttached? ❑ Yes (1) ❑ No (0) Specific Conductance µMhos K - Potassium mg/I VOC method # Total Ammonia <.10 mg/I Mg - Magnesium mg/I method # (Ammonia Nitrogen; N%as N; Ammonia Nitrogen, Total) Mn - Manganese mg/I , method # TKN as N mg/I Ni - Nickel mg/I method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Chris Bivans (General Manager) Permittee (or Authorized Agent) Name and Title - Please print or type GW-59 Rev.1/2007 fJ 5 � aceAnalytical / www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: SPRAYFIELD WELLS Pace Project No.: 92290350 Sample: MW-2 Lab ID: 92290360002 Collected: 03/16/16 09:30 Received: 03/16/16 14:50 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual MBIO 9222D Fecal Coliform CHT Analytical Method: SM 9222D Fecal Coliforms ND CFU/100 mL 1.0 1 03/16/16 15:37 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 1340 mg/L 250 1 03/16/16 22:12 4500H+ pH, Electrometric Analytical Method: SM 4500-H+B pH at 25 Degrees C 7.3 Std. Units 1.0 1 03/22/16 14:25 H6 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Sulfate 8.6 mg/L 2.0 1 03/17/1619:00 14808-79-8 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia ND mg/L 0.10 1 03/20/16 12:57 7664-41-7 353.2 Nitrogen, N021NO3 pres. Analytical Method: EPA 353.2 Nitrogen, NO2 plus NO3 10.4 mg/L 0.060 3 03/18/16 15:36 4500 Chloride Analytical Method: SM 4500-CI-E Chloride 403 mg/L 150 150 03/18/16 21:46 16887-00-6 5310B TOC Analytical Method: SM 5310B Total Organic Carbon 1.1 mg/L 1.0 1 03/19/16 16:39 7440-44-0 Date: 03/23/2016 02:01 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 25 V cZGBii3Jj+ilCc7i V bocumenklVame: ' Ffe1d Data;Sleet. Document Issue& APH16, 2615 Pa a 1_ of Do¢uiiierij Plumber: IssuingAutliorily: F-CAR=PtD 0pl=rev.OD Pace Huntecsil, e, QualityOffice PeldData Sheet. Client: v u I P� S Location: A b e� a> N t' Project Name/#: Name and Afiliation (Sampler(s):_ TJ( 7P- lid Name and Afiliation (Inspector)-'1 + Well Information Well ID: Well Locked: rYES NO Well Diameter: < : ConstracixPV tee! Stainless Steel Total Well Dept�i�p a ft'Multi Factor*: r(Ra&us/12)2 x 3.14 x 7.48] Static Wafter Level:. $ ft Casing No lume: gallons Height of Water Column: �2g' tq ft Cal. 3 Volumes: 13, gallons Purge Information Date Purged: a- /�/(_ Start Time: S� Finish: 10 N thPurge Rate: / - Purging Meod: �7 y T t iy- K Total Volume Purged: / 5' a S� gallons Sampling Information f Date Collected: Ca ! Time Collected: DI 3 v G—m) pm Sampling Equipment Used: k4, -e r Bottle Type Preservation Analysis Required •3g61,4UVA A-Cii0 C� ��ab`t}:, 2•'% 1�6�t�w.11 l��sn L itl0�1� nt& L� c� Nll ipSlP��i � Field Measurements/Observations Sample Temp (°C): 114, 3 Time: 07 3 O Sample pH (s.u.): 7,0 Time- 093 D Specific Cond. (uS): 19 9 O Time: 09 3 0 ReDox (mV): Time: _ -- Odor; Ni)N9- Time: 09 3 0 General/Weather Observations Sampler Signature/Date: Stabilization Test Turbidity (ntu): Time: Diss Oxy (mg/L): Time: Res. CI (mg/L): ' Time: Other: Appearance: __C,) e e.,, Ali~• Time: Time Purged- pH (s.u.) Spec. Cond. (us) ReDox (mV) Turbidity (ntu) Diss Oxy. tmg/L) Temp. (°C) Volume Removed AS Other SUBMIT FORM ON YELLOW PAPER nNl Y GROUNDWATER QUALITY MONITORING: DEPARTMENT OF ENVIRONMENT 8, NATURAL RESOURCES ' • • :;. IVISIONt7WATERQUALITY-1NEORMATIONPROGE5SINGt1N1T x COMPLIANCE REPORT FORM fiil MAIL SERVICEECEN7ER, RALEIGH,'NC 27699.46i7, P"R 49,19),443422! •" r FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 06/30/2018 Facility Name: Valley Proteins Non -Discharge WQ0000957 UIC Permit Name (if different): NPDES Other Facility Address: 656 Little Duncan Road TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery Wadesboro NC 28170 County Anson 0 Spray Field ❑ Remediation: Contact Person: Chris Bivans Telephone#: 704-694-3701 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Behind Field #1 No. of wells to be sampled: 8 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW#3 Date sample collected: 03/16/16 FIELD ANALYSES: WAS Well Depth: 29.2 ft. Well Diameter: 4 in. pH 7.2 units Temp. 14.3 °C DRY at Depth to Water Level: 28.19 ft. below measuring point Screened Interval: ft. to ft. Spec. Cond. µMhos time of Measuring Point is ft. above land surface Relative M.P. Elevation: ft. Odor No Odor sampling,check Volume of water pumped/bailed before sampling: 19•0 gallons Appearance Clear here: ❑ Samples for metals were collected unfiltered: DYES ❑ NO and field acidified: ❑ YES ❑ NO LA13 RATORY INFORMATION Date sample analyzed: 03/16/16 - 03/22/16 Laboratory Name: PACE Analytical Certification No. PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD mg/l Nitrite (NO2) as N mg/I Pb - Lead mg/I Coliform: MF Fecal <1 /100ml Nitrate (NO3) as N 3.9 mg/1 Zn - Zinc mg/I Coliform: MFTotal. A00ml Phosphorus: Total as P mg/I (Note: Use MPN method for highly turbid samples) Orthophosphate mg/I Other (Specify Compounds and Concentration Units): Dissolved Solids: Total 1050 mg/I AI - Aluminum mg/I pH (when analyzed) 7.2 units Ba - Barium mg/I TOC 1.3 mg/I Ca - Calcium mg/I Chloride 321 mg/I Cd - Cadmium mg/I Arsenic mg/I Chromium: Total mg/I Grease and Oils mg/I Cu - Copper mg/I ORGANICS: (by GC, GC/MS, HPLC) Phenol mg/I Fe - Iron mg/I (Specify test and method #. ATTACH LAB REPORT.) Sulfate: 173 mg/I Hg - Mercury mg/I Report Attached? ❑ Yes (1) ❑ No (0) Specific Conductance µMhos K - Potassium mg/I VOC method # Total Ammonia <.10 mg/I Mg - Magnesium mg/I method # (Ammonia Nitrogen; NH,as N; Ammonia Nitrogen, Total) Mn- Manganese mg/I , method # TKN as N mg/I Ni - Nickel mg/I method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Chris Bivans (General Manager) Permiftee (or Authorized Agent) Name and Title - Please print or type GW-59 Rev.1/2007 R c.� 1 11�aceAnalXicalo / www.pacelabs.com i ANALYTICAL RESULTS Project: SPRAYFIELD WELLS Pace Project No.: 92290350 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: MW-3 Parameters Lab ID: 92290350003 Collected: 03/16/16 08:55 Results Units Report Limit DF Received: 03/1.6/16 14:50 Matrix: Water Prepared Analyzed CAS No. Qual MBIO 9222D Fecal Coliform CHT Analytical Method: SM 9222D Fecal Coliforms ND CFU/100 mL 1.0 1 03/16/16 15:37 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 1050 mg/L 50.0 1 03/16/16 22:09 4500H+ pH, Electrometric Analytical Method: SM 4500-H+B pH at 25 Degrees C 7.2 Std. Units 1.0 1 03/22/16 14:25 H6 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Sulfate 173 mg/L 40.0 20 03/18/1611:31 14808-79-8 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia ND mg/L 0.10 1 03/20/16 12:59 7664-41-7 353.2 Nitrogen, NO2/NO3 pres. Analytical Method: EPA 353.2 Nitrogen, NO2 plus NO3 3.9 mg/L 0.020 1 03/18/16 14:31 4500 Chloride Analytical Method: SM 4500-CI-E Chloride 321 mg/L 150 150 03/18/16 21:47 16887-00-6 5310B TOC Analytical Method: SM 5310B Total Organic Carbon 1.3 mg/L 1.0 1 03/19/16 16:54 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/23/2016 02:01 PM without the written consent of Pace Analytical Services, Inc.. Page 5 of 25 1)0t=rLt Naive: Field Docuirient Isgued; April 6, 2015 ge i of D Issuing Authority; Pace Hntd,,,iU, QUOR Office Fkld.Data Sheet Client: ProjectName/#: Location: . NameandAffiliation Nample (s). Name and Afiliation (Inspector): - Well Information Well 11): W Well Diameter: L4 '2 7 Total Well. Depth: 9- ft Static water Level. t Height of Water Column: 9, S 2 Well Locked: (Ei) NO Cons4dai6m, �0 Steel Stainless Steel Multi Factor*: 0 .bs3 r(RadiU8/12)2x3.14x7.481 Casing Volume: I gallons Cal. 3 Volumes: _ 32 gallons Purge Information Date Purged--PfYAi 14 1-1-fP Start Time: C90D Finish: 091 S 3 Purge Rate: Purging Method: otal Volume Purged: b'-Nallons SmR%n-K Information D . ate Collected: Ofl Time Collected: 0'9515 am pm Sampling Equipment Used: Bottle Type Preservation Analysis Required 0AIE W War, 4-b `77 Arnram, o-,ij-A- Field Measurements/Observations Sample Temp CC):— 1'4-3 Time: 0255 Turbidity (utu): Time - Sample pH (s.u-.)- Time: . o-255 Diss Oxy (mg/L).— Time: Specific Cond. (6): Time: 0-655 Res. a (mg/L): Time. ReDox (mV): Time: - Other: Time: Odor: Time: b'855 Appearance: elee, -GeneraJ8VLeather Observations M.W.- 3 70o1F Sampler Signature/Date: Stabilization Test ce. - -03/1 & // & Time Purged pH (s.u.) Spec.Cond. (us) ReDox (MV) Turbidity (ntu) Diss Oxy. (mg/L) Temp. (0Q volume Re oved Other L232 Ore, ( SUBMIT FORM ON YELLOW PAPER ONLY ROUNDWATER QUALITY MONITORING: OMPLIANCE REPORT FORM 'acility Name: Valley Proteins 'ermit Name (if different): acility Address: 656 Little Duncan Road Wadesboro Please Print Clearly or Type 28170 County Anson act Person: Chris Bivans Telephone#: 704-694-3701 Location/Site Name: Behind Pond #1 No. of wells to be sampled: 8 L ID NUMBER (from Permit): MW#5 Depth: 29.2 ft. h to Water Level: 23.79 ft. below measuring point wring Point is ft. above land surface ne of water pumped/bailed before sampling: 12.0 gallon Date sample collected: 03/16/16 Well Diameter: 2 in. Screened Interval: ft. Relative M.P. Elevation: UNIT,x PERMIT Number: Expiration Date: 06/30/2018 Non -Discharge WQ0000957 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery fc❑ Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: to _ft. ft. FIELD ANALYSES: pH 7.2 units Spec. Cond. _ Odor No Odor Appearance Clear Temp. 12.8 eC DRY at µMhos time of Iples for metals were collected unfiltered: ❑YES ❑ NO and field acidified: ❑ YES ❑ NO ORATORY INFORMATION sample analyzed: 03/16/16 - 03/22/16 Laboratory Name: PACE Analytical Certification No. lAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD mg/I Nitrite (NOZ) as N mg/I Pb - Lead mg/1 Coliform: MF Fecal <1 /100ml Nitrate (NO3) as N <,020 mg/I Zn - Zinc mg/I Coliform: MF Total /100ml Phosphorus: Total as P mg/l (Note: Use MPN method for highly turbid samples) Orthophosphate mg/I Other (Specify Compounds and Concentration Units): Dissolved Solids: Total 1700 mg/I AI - Aluminum mg/l pH (when analyzed) 7.2 units Ba - Barium mg/I TOC 2.3 mg/I Ca - Calcium mg/1 Chloride 366 mg/l Cd - Cadmium mg/I Arsenic mg/I Chromium: Total mg/l Grease and Oils mg/I Cu - Copper mg/I ORGANICS: (by GC, GC/MS, HPLC) Phenol mg/I Fe - Iron mg/I (Specify test and method #. ATTACH LAB REPORT.) Sulfate 39.2 mg/I Hg - Mercury mg/I Report Attached? ❑ Yes (1) ❑ No (0) Specific Conductance µMhos K - Potassium mg/I VOC , method # Total Ammonia <.10 mg/I Mg - Magnesium mg/I (Ammonia Nitrogen; NH3as N; Ammonia Nitrogen, Total) Mn - Manganese mg/I TKN as N mg/1 Ni - Nickel mg/I method # method # method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Chris Bivans (General Manager) Permittee (or Authorized Aqent) Name and Title - Please print or type GW-59 Rev.1/2007 Siqnature J aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: SPRAYFIELD WELLS Pace Project No.: 92290350 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: MW-5 Parameters Lab ID: 92290350004 Collected: 03/16/16 08:15 Results Units Report Limit DF Received: 03/16/16 14:50 Matrix: Water Prepared Analyzed CAS No. Qua[ MBIO 9222D Fecal Coliform CHT Analytical Method: SM 9222D Fecal Coliforms ND CFU/100 mL 1.0 1 03/16116 15:37 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 1700 mg/L 250 1 03/16/16 22:09 4500H+ pH, Electrometric Analytical Method: SM 4500-H+B pH at 25 Degrees C 7.2 Std. Units 1.0 1 03/22/16 14:25 H6 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Sulfate 39.2 mg/L 2.0 1 03/17/1619:27 14808-79-8 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia ND mg/L 0.10 1 03/20/16 13:00 7664-41-7 353.2 Nitrogen, NO2/NO3 pres. Analytical Method: EPA 353.2 Nitrogen, NO2 plus NO3 ND mg/L 0.020 1 03/18/16 14:32 4500 Chloride Analytical Method: SM 4500-CI-E Chloride 366 mg/L 20.0 20 03/18/16 21:47 16887-00-6 5310E TOC Analytical Method: SM 5310B Total Organic Carbon 2.3 mg/L 1.0 1 03/19/16 17:07 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/23/2016 02:01 PM without the written consent of Pace Analytical Services, Inc.. Page 6 of 25 J a ' Well Locked: YES)NO Construction: - � Steel . Stainless Steel Multi Factor': O• f 6 . (!"(Radius/12)2 x 3.14 x 7.48] Casing Volume: .9 , gallons Cal. 3 Volumes: 1 gallons Purge Information Date Purged: '3 / 1 L/ `1 Start Time: b 6.1 to Finish Q Li5' Purge Rate: -►� Purging Method: Q) CA114 Total Volume Purged: gallons Sarngling Information Date Collected: {� 1 f_r ! i{� Time Collected ©� 5r pm Sampling Equipment Used: Bottle Type f t �c?i ly'�Gs71a l7ociinient iVaine: Fiel i•pAtd:Sh` Docunientlssued: April 6, 2015 Fake l of . Doctirilentl�itiaitie; F-CAR-HLD-0U1=rev.00 IsstiYgAtitHority.: Pace Hunteisvinl Qua UtV office F161d. Data: Sheet Client: htviS Location: w.ACAPSE C��6.NL Project Name/#: L.0 Name and Afiliation (Sampler(s): Name and Affiliation (inspector):' _ J Well Information Wel11D: Well Diameter: an Total Well Depth: °�� ' ft Static Water Level: Height of Water Column: 3 9 ft Analysis Required a as�►�jr-sa0A,ONG 7-1 474149ni�;L Field Measurements/Observations Preservation Sample Temp CC): /a . S Time: n73 , l 5 Sample pH (s.u.): • 5 Time: 02 :15 Specific Cond. (uS): ti Time: O8 i 5 ReDox (mV): Turbidity (ntu): Time: Diss Oxy (mg/L): �` " Time: — Res. Cl (mg/L): .'Time' Other: Time: Irl— Odor,- IVflnti- Time: 68:15 Appearance: clgra.,r General/Weather Observations Imr�t-S So°E E�1�rp5 5fi�l� ��i,N� /i n e MP '— Sampler Signature/Date: Stabilization Test Time: '"' Time Purged pH (s.u.) Spec. Cond. (US) ReDox (mV) Turbidity (ntu) Diss Oxy. (mg/L) Temp. (°C) IY- 3 Volume Removed Other 5 E8 SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENT 8 NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: IVIStONOFWAT k66ALITYINFORMATiONPRQGESSINGUNIT W . ,. COMPLIANCE REPORT FORM 617MAI SERVMECENTER; RALEIGH.INC 27549x[517 Flirrne (s19j 733 322t ; K M FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 06/30/2018 Facility Name: Valley Proteins Non -Discharge W00000957 UIC Permit Name (if different): NPDES Other Facility Address: 656 Little Duncan Road TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery Wadesboro ;3nv' NC 28170 County Anson 0 Spray Field ❑ Remediation: Contact Person: Chris Bivans Telephone#: 704-694-3701 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Behind Field #20 No. of wells to be sampled: 8 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW#6 Date sample collected: 03/16/16 FIELD ANALYSES: WAS Well Depth: 45 ft. Well Diameter: 2 in. pH 7.1 units Temp. 14.7 °C DRY at Depth to Water Level: 39.55 ft. below measuring point Screened Interval: ft. to ft. Spec. Cond. µMhos time of sampling, Measuring Point is ft. above land surface Relative M.P. Elevation: ft. Odor No Odor check Volume of water pumped/bailed before sampling: 10.54 gallons Appearance . Light gray here: ❑ Samples for metals were collected unfiltered: DYES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 03/16/16 - 03/22/16 Laboratory Name: PACE Analytical Certification No. PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD mg/1 Nitrite (NO2) as N mg/1 Pb - Lead mg/I Coliform: MF Fecal <1 /100ml Nitrate (NO3) as N <.020 mg/1 Zn - Zinc mg/I Coliform: MF Total /100ml Phosphorus: Total as P mg/I (Note: Use MPN method for highly turbid samples) Orthophosphate mg/I Other (Specify Compounds and Concentration Units): Dissolved Solids: Total 154 mg/I Al - Aluminum mg/I pH (when analyzed) 7.1 units Ba - Barium mg/1 TOC <1 mg/I Ca - Calcium mg/I Chloride 11.9 mg/I Cd - Cadmium mg/I Arsenic mg/1 Chromium: Total mg/I Grease and Oils mg/1 Cu - Copper mg/1 ORGANICS: (by GC, GC/MS, HPLC) Phenol mg/I Fe - Iron mg/I (Specify test and method #. ATTACH LAB REPORT.) Sulfate 5.2 mg/I Hg - Mercury mg/I Report Attached? ❑ Yes (1) ❑ No (0) Specific Conductance µMhos K - Potassium mg/I VOC method # Total Ammonia <• 10 mg/I Mg - Magnesium mg/1 method # (Ammonia Nitrogen; NH,as N; Ammonia Nitrogen, Total). Mn -Manganese mg/1 ,method # TKN as N mg/I Ni - Nickel mg/I method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% GW-59 Rev.1/2007 aceAnalXical y www.pacelabs.com ANALYTICAL RESULTS Project: SPRAYFIELD WELLS Pace Project No.: 92290350 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: MW-6 Parameters Lab ID: 92290350006 Collected: 03/16/16 11:45 Results Units Report Limit DF Received: 03/16/16 14:50 Matrix: Water Prepared Analyzed CAS No. Qual MBIO 9222D Fecal Coliform CHT Analytical Method: SM 9222D Fecal Coliforms NO CFU/100 mL 1.0 1 03/16/16 17:42 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 154 mg/L 25.0 1 03/16/16 22:10 4500H+ pH, Electrometric Analytical Method: SM 4500-H+B pH at 25 Degrees C 7.1 Std. Units 1.0 1 03/22/16 14:25 H6 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Sulfate 5.2 mg/L 2.0 1 03/17/1619:41 14808-79-8 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia NO mg/L 0.10 1 03/20/16 13:02 7664-41-7 363.2 Nitrogen, NO2/NO3 pres. Analytical Method: EPA 353.2 Nitrogen, NO2 plus NO3 NO mg/L 0.020 1 03/18/16 14:35 4500 Chloride Analytical Method: SM 4500-CI-E Chloride 11.9 mg/L 1.0 1 03/18/16 20:44 16887-00-6 5310B TOC Analytical Method: SM 5310B Total Organic Carbon ND mg/L 1.0 1 03/19/16 17:21 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/23/2016 02:01 PM without the written consent of Pace Analytical Services, Inc.. Page 7 of 25 5 'Documlent`Nainei Documeni Issued Aprit 6, 2015 c�lr81�r9&fj+'F!w Fieldbata'She2t i age 1 of Docta6nt Nifi itid: P-CAR- liD 9jll:rev.00 Issuing * tliority: Pace 14unteisville Quali Office `r�OL� p 11?�S _ Held Data.Sheet 1F Client: _ N 'i4'1 Location: eA) A, � eS,��+ U N c, Project Name/#: p Name and Afiliation (Sample'r(s): -T-U.• 0- PACE Name and Affiliation (Inspector):- N I Well Information Well ID: If AW tv Well Diameter: TotaI WelI Depth: ,qqI 9q ft Static Water Level: Height of Water Column, S5 ft Well Locked: �S, NO Construction: Steel Stainless Steel Multi Factor*: a ,1(a 3 ["(Radius/12)2 x 3.14 x 7.461 Casing .VoIume: gallons Cal. 3 Volumes: Q, � gallons Purge Information Date Purged; Start Time:. i3 ) (O Finish: 1102 Purge Rate N Purging Method: 134 t le-� Total VoIuine Purged: U S gallons Sampling Information J Date Collected: 0 3Ga ! i l� O Time Collected: 1 , ys am pm Sampling Equipment Used: 13 ci. i -ei- Bottle Type 7-4 Preservation ghat �. v Now. �ra�50!2 rt�•-svlf Field MeasurementslObservations Sample Temp (°C): I'-± Time: Sample pH (s.u.): Time: Specific Cond. (uS): (0 Time: I L49 ReDox (mV): Time: Odor: loumv— Time: lt•- 4.5, Generalf Weather Observations 11i1. i. 1, ra - -:76 S tt h N Sampler Signature/Date: Stabilization Test Analysis Required 'TZJ ri Turbidity (ntu): Time. Diss Oxy (mg/L): Time: Res. CI (mg/L): Time: Other: �' Time: '~ Appearance: Time Purged pH (s.u.) Spec. Cond. (us) ReDox (mV) Turbidity (ntu) Diss Oxy. (mg/l.) Temp. (°C) Volume Removed Other 6 ;k --� -- --, f SUBMIT FORM ON YELLOW PAPER ONLY UNDWATER QUALITY MONITORING: PLIANCE REPORT FORM ACILITY INFORMATION Please Print Clearly or Type acility Name: Valley Proteins ermit Name (if different): acility Address: 656 Little Duncan Road Wadesboro NC 28170 County Anson act Person: Chris Bivans Location/Site Name: Behind Field #19 L ID NUMBER (from Permit): MW#7 Depth: 52 ft. n to Water Level: 36.73 ft. below measuring point Telephone#: 704-6 94-3701 No. of wells to be sampled: 8 Date sample collected: 03/16/16 Well Diameter: 2 in. Screened Interval: ft. & NATURAL RESOURCES IN 6RMAT16N PROCESSG'_UNIT PERMIT Number: Non -Discharge W00000957 NPDES to _ft. wring Point is ft. above land surface Relative M.P. Elevation: ft. ne of water pumped/bailed before sampling: 11.0 gallons )les for metals were collected unfiltered: DYES ❑ NO and field acidified: ❑ YES ❑ NI Expiration Date: UIC Other 'PE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑fc Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: FIELD ANALYSES: pH 7.1 units Spec. Cond. _ Odor No Odor WELL Temp. 14.7 °C DRY at uMhos I time of Appearance Turbid here: sample analyzed: 03/16/16 - 03/22/16 Laboratory Name: PACE Analytical Certification No. tAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD mg/I Nitrite (NO2) as N mg/1 Pb - Lead mg/1 Coliform: MF Fecal <1 /100ml Nitrate (NO3) as N <• 12 mg/l Zn - Zinc mg/I Coliform: MF Total /100ml Phosphorus: Total as P mg/I (Note: Use MPN method for highly turbid samples) Orthophosphate mg/I Other (Specify Compounds and Concentration Units): Dissolved Solids: Total 311 mg/I Al - Aluminum mg/I pH (when analyzed) 7.6 units Ba - Barium mg/I TOC <1 mg/1 Ca - Calcium mg/1 Chloride 30.4 mg/I Cd - Cadmium mg/I Arsenic mg/I Chromium: Total mg/I Grease and Oils mg/l Cu - Copper mg/I ORGANICS: (by GC, GC/MS, HPLC) Phenol mg/1 Fe - Iron mg/1 (Specify test and method #. ATTACH LAB REPORT.) Sulfate 7.0 mg/I Hg - Mercury mg/I Report Attached? ❑ Yes (1) ❑ No (0) Specific Conductance µMhos K - Potassium mg/I VOC method # Total Ammonia 10 mg/I Mg - Magnesium mg/I method # (Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total). Mn - Manganese mg/I , method # TKN as N mg/I Ni - Nickel mg/I method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% GW-59 Rev.1/2007 %r_ aceAnalXical www.pacelabs.com ANALYTICAL RESULTS Project: SPRAYFIELD WELLS Pace Project No.: 92290350 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: MW-7 Lab ID: 92290350006 Collected: 03/16/16 12:45 Received: 03/16/16 14:50 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[ MBIO 9222D Fecal Coliform CHT Analytical Method: SM 9222D Fecal Coliforms ND CFU/100 mL 1.0 1 03/16/16 17:42 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 311 mg/L 25.0 1 03/16/16 22:10 4500H+ pH, Electrometric Analytical Method: SM 4500-H+B pH at 25 Degrees C 7.6 Std. Units 1.0 1 03/22/16 14:25 H6 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Sulfate 7.0 mg/L 2.0 1 03/17/1619:55 14808-79-8 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia ND mg/L 0.10 1 03/20/16 13:03 7664-41-7 353.2 Nitrogen, NO2/NO3 pres. Analytical Method: EPA 353.2 Nitrogen, NO2 plus NO3 0.12 mg/L 0.020 1 03/18/16 14:36 4500 Chloride Analytical Method: SM 4500-CI-E Chloride 30.4 mg/L 1.0 1 03/18/16 20:45 16887-00-6 5310B TOC Analytical Method: SM 5310B Total Organic Carbon ND mg/L 1.0 1 03/19/16 17:33 7440-44-0 Date: 03/23/2016 02:01 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 25 7 , Issued: �!e�nafyFr�af°' c-kepm-'-ri u uUA-wxu Pace Hunteisi i& Qtiali Offi Fiteld.Dafi Sheet Client: 1 &kkn Location:.- W 4dpProject Name/#: S ra..'► \C� Name and Afiliation (Sampler(s):_ Name and Afiliation (Inspector): N 1 pr Well Information Well ID: _ i111,J—� Well Diameter: a `) Total Weil Depth: 5 3 . ;? 3 Static Water Level:: ft Height of Water Column: ft Well Locked: NO Construction: PV Steel Stainless Steel Multi Factor*: I fo 3 [(Radius/12)2 x 3.14 x 7.48I Casing Volume: © gallons Cal. 3 Volumes: gallons Purge Information Date Purged: /�6 Start Time: 1'Z : Q Finish 1:: 31 Purge Rate• N/ 6- Purging Method: Total Volume Purged: 1 0 info, gallons Sampling Information Date Collected: 3 f Time Collected: ra am Sampling Equipment Used: 1)ci r Bottle Type Preservation Analysis Required. NoaC c , su/ fie` N �/U�al 7— W/plf 4,*8 1- Xsb, - ,r H+vt~ni Field Measurements/Observations Sample Temp (°C): (5- 57 Time: 1 a4 5 Sample pH (s.u.): 3 —Time: 1,245 Specific Cond. (us): 5 Time: I a`E5 ReDox (mV): Time: — Odor: NDA Time: 0-4 5 General/Weather Observations ►'Avs-_ ° t �rcx 5;fiD to Sampler Signature/Date: Stabilization Test Turbidity (ntu): Time• Diss O m L xy ( g/ ): _~Time: Res. CI (mg/L): Time: Other: — ' Time: Appearance: -T.a6tb Time Purged p5 (s u) Spec. Cond. (us) ReDox (mV) Turbidity (ntu) Diss Oxy. (mg/L) Temp (0Q Volume Removed �tA(S Other SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: mDEPARTMENT OF ENVIRONMENT &;NATURAL RESOURCES' VISION OR,WATER'QUALITY-INFORMATION PROCESSINGUNIT COMPLIANCE REPORT FORM 6 7 MAIL SERVICE CENTER;,RALEIGH, NC 27699,1S17 , phone (919).733.3221 ,} ' FACILITY INFORMATION Please Print clearly or Type PERMIT Number: Expiration Date: 06/30/2018 Facility Name: Valley Proteins Non -Discharge WQ0000957 UIC Permit Name (if different): NPDES Other Facility Address: 656 Little Duncan Road TYPE OF PERMITTED OPERATION BEING MONITORED El Lagoon El Remediation: Infiltration Gallery Wadesboro icu" '' NC 28170 County Anson ;cty) 'S`�f ' !'ri ❑fc Spray Field ❑ Remediation: Contact Person: Chris Bivans Telephone#: 704-694-3701 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Behind Field #16 No. of wells to be sampled: 8 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW#8 Date sample collected: 03/16/16 FIELD ANALYSES: WAS Well Depth: 30 ft. Well Diameter: 2 in. pH 7.1 units Temp. 14.7 °C DRY at Depth to Water Level: 28.24 ft. below measuring point Screened Interval: ft. to ft. Spec. Cond. µMhos time of sampling,check Measuring Point is ft. above land surface Relative M.P. Elevation: ft. Odor No Odor Volume of water pumped/bailed before sampling: 13.0 gallons Appearance Clear here: ElSamples for metals were collected unfiltered: DYES El NO and field acidified: ❑ YES El NO LABORATORY INFORMATION Date sample analyzed: 03/16/16 - 03/22/16 LaboratoryName: PACE Analytical Certification No. PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD mg/I Nitrite (NO2) as N mg/I Pb - Lead mg/I Coliform: MF Fecal <1 /loom[ Nitrate (NO3) as N <,020 mg/I Zn - Zinc mg/I Coliform: MF Total /100ml Phosphorus: Total as P mg/I (Note: Use MPN method for highly turbid samples) Orthophosphate mg/I Other (Specify Compounds and Concentration Units): Dissolved Solids: Total 434 mg/I Al - Aluminum mg/I pH (when analyzed) 7.4 units Ba - Barium mg/I TOC <1 mg/I Ca - Calcium mg/l Chloride 108 mg/l Cd - Cadmium mg/I Arsenic mg/I Chromium: Total mg/I Grease and Oils mg/I Cu - Copper mg/I ORGANICS: (by GC, GC/MS, HPLC) Phenol mg/I Fe - Iron mg/I (Specify test and method #. ATTACH LAB REPORT.) Sulfate 8.6 mg/I Hg - Mercury mg/I Report Attached? ❑ Yes (1) ❑ No (0) Specific Conductance µMhos K - Potassium mg/I VOC method # Total Ammonia <• 10 mg/I Mg - Magnesium mg/I method # (Ammonia Nitrogen; N113as N; Ammonia Nitrogen, Total) Mn -Manganese mg/I ,method # TKN as N mg/I Ni - Nickel mg/I method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% GW-59 Rev.1/2007 ,-r Tr, /5a'ceAnalytical" www.pacelabs.com i? ANALYTICAL RESULTS Project: SPRAYFIELD WELLS Pace Project No.: 92290350 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: MW-8 Parameters Lab ID: 92290350007 Collected: 03/16/16 10:40 Results Units Report Limit DF Received: 03/16/16 14:50 Matrix: Water Prepared Analyzed CAS No. Qual MBIO 9222D Fecal Coliform CHT Analytical Method: SM 9222D Fecal Coliforms ND CFU/100 mL 1.0 1 03/16/16 17:42 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 434 mg/L 25.0 1 03/16/16 22:10 4500H+ pH, Electrometric Analytical Method: SM 4500-H+B pH at 25 Degrees C 7.4 Std. Units 1.0 1 03/22/16 14:25 H6 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Sulfate 8.6 mg/L 2.0 1 03/17/16 20:08 14808-79-8 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia ND mg/L 0.10 1 03/20/16 13:05 7664-41-7 353.2 Nitrogen, N021NO3 pres. Analytical Method: EPA 353.2 Nitrogen, NO2 plus NO3 NO mg/L 0.020 1 03/18/16 14:39 4500 Chloride Analytical Method: SM 4500-CI-E Chloride 108 mg/L 10.0 10 03/18/16 21:48 16887-00-6 5310E TOC Analytical Method: SM 5310B Total Organic Carbon ND mg/L 1.0 1 03/19/16 18:12 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/23/2016 02:01 PM without the written consent of Pace Analytical Services, Inc.. Page 9 of 25 tiGBl;f[ir?/yllEr�i� Document IVamei Field DaWSheet ., Document Issued: April 6, 2015 Pao 10f Doc*ntNuriib, ' F-CAIt-110-001-rev.00 Iss!lmgAutiiority: Pace Hunteirsviile Q'qafity Office Client: Name and Affiliation (Samvler(s): Name and Affiliation (Inspector):- N 1 Well Information Well ID: Well Diameter: 'off Total Well Depth:. of ft Static Water Level: 5 . ft 2 Height of Water Column —A ft Project Name/#: Well Locked: NO Construction: &Vr%, Steel Stainless Steel Multi Factor*: 0-(6 ` ['(Radius/12)2 x 3.14 x 7.481 Casing Volume: u' to gallons Cal. 3 Volumes: J3 8 gallons forge .Information Date Purged: D� / 1 S /q } (0 Start Time: _ l 113S Finish: 1; : 0 2— Purge Rate: Al % - Purging Method- l �"r Total Volume Purged: /3. 0 P% goon, Sampling Information J j Date Collected: 0 3 I 6 I Time Collected: 10 ' `-t © a� pm Sampling Equipment Used: 6G { Bottle Type Preservation Analysis Required _ ` drnI- deA- �Lirxr 4CI D. ?� oZ--av► C /1/-BN19 iti rps/pd 44B Field Measurements/Observations Sample Temp CC): ►5 S Time: i b . O Sample pH (s.u.): tv • c� Time: 102140 Specific Cond. (6): % 3 Time: D : 4 0 ReDox (mV): "' Time: r Odor' nJ 0 %NE Time: ( 61 Sampler Signature/Date: Stabilization Test Turbidity (ntu): Time Diss Oxy (mg/L): r Time: Res. CI (mg/L): ' Time: Other: Time: Appearance: G? rau- P WIKJS .S-fv/0,.pk g a�fl�li� Time Purged pH (s.u.) Spec. Cond. (US) ReDox (mV) Turbidity (ntu} Diss Oxy. (mg/l.) Temp. (°C) Volume Removed gals . Other 11,4(0 �, a --- --- �-- 5 �• -- :o� _O G5a -- _. — 1G.� 13,0 — ---� SUIRMIT FnRM ON YFI I OW PAPFR nNl V GROUNDWATER QUALITY MONITORING: DEPARTMENT OF ENVIRONMENT & NATURAL -RESOURCES.,. IVISIONOFWATERQUALITY-INFORMATIONPROCESSING.UNIT COMPLIANCE REPORT FORM 617MAILSERVI6E.6ENTER.RALEIGH,:NC127699=161T Phone.(919)7333221. ,Y " FACILITY INFORMATION Please Print CleaAyorType PERMIT Number: Expiration Date: 06/30/2018 Facility Name: Valley Proteins Non -Discharge WQ0000957 UIC Permit Name (if different): NPDES Other Facility Address: 656 Little Duncan Road TYPE OF PERMITTED OPERATION BEING MONITORED Wadesboro ;Suet; NC 28170 County Anson ❑ Lagoon ❑ Remediation: Infiltration Gallery (S(3rP.i i-T::1 ❑>'c Spray Field ❑ Remediation: Contact Person: Chris Bivans Telephone#: 704-694-3701 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Behind Field #14 No. of wells to be sampled: 8 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW#9 Date sample collected: 03/16/16 FIELD ANALYSES: WAS Well Depth: 29 ft. Well Diameter: 2 in. pH 7.1 units Temp. 14.7 eC DRY at Depth to Water Level: 21.45 ft. below measuring point Screened Interval: ft. to ft. Spec. Cond. µMhos time of Measuring Point is ft. above land surface Relative M.P. Elevation: ft. Odor No Odor sampling,check Volume of water pumped/bailed before sampling: 10.5 gallons Appearance Clear here: ❑ Samples for metals were collected unfiltered: El YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 03/16/16 - 03/22/16 Laboratory Name: PACE Analytical Certification No. PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD mg/I Nitrite (NO2) as N mg/I Pb - Lead mg/I Coliform: MF Fecal <1 /loom[ Nitrate (NO3) as N <,45 mg/I Zn - Zinc mg/I Coliform: MF Total /loom[ Phosphorus: Total as P mg/I (Note: Use MPN method for highly turbid samples) Orthophosphate mg/I Other (Specify Compounds and Concentration Units): Dissolved Solids: Total 972 mg/I Al - Aluminum mg/I pH (when analyzed) 7.3 units Ba - Barium mg/I TOG <1 mg/1 Ca - Calcium mg/1 Chloride 381 mg/I Cd - Cadmium mg/I Arsenic mg/1 Chromium: Total mg/l Grease and Oils mg/I Cu - Copper mg/I ORGANICS: (by GC, GC/MS, HPLC) Phenol mg/I Fe - Iron mg/I (Specify test and method #. ATTACH LAB REPORT.) Sulfate 26.7 mg/I Hg - Mercury mg/1 Report Attached? ❑ Yes (1) ❑ No (0) Specific Conductance µMhos K - Potassium mg/I VOC method # Total Ammonia <• 10 mg/I Mg - Magnesium mg/I method # (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn -Manganese mg/I ,method TKN as N mg/I Ni - Nickel mg/I method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Chris Bivans (General Manager) Permittee (or Authorized Aqent) Name and Title - Please print or type GW-59 Rev.1/2007 Ah I_' aceAnalytical www.pacelabsxam ANALYTICAL RESULTS Project: SPRAYFIELD WELLS Pace Project No.: 92290350 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: MW-9 Lab ID: 92290350008 Collected: 03/16/16 11:10 Received: 03/16/16 14:50 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[ MBIO 9222D Fecal Coliform CHT Analytical Method: SM 9222D Fecal Coliforms ND CFU/100 mL 1.0 1 03/16/16 17:42 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 972 mg/L 50.0 1 03/16/16 22:11 4500H+ pH, Electrometric Analytical Method: SM 4500-H+B pH at 25 Degrees C 7.3 Std. Units 1.0 1 03/22/16 14:25 H6 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Sulfate 26.7 mg/L 2.0 1 03/18/16 07:27 14808-79-8 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia ND mg/L 0.10 1 03/20/16 13:06 7664-41-7 353.2 Nitrogen, NO2/NO3 pres. Analytical Method: EPA 353.2 Nitrogen, NO2 plus NO3 0.45 mg/L 0.020 1 03/18/16 14:41 4500 Chloride Analytical Method: SM 4500-CI-E Chloride 381 mg/L 15.0 15 03/18/16 21:49 16887-00-6 5310B TOC Analytical Method: SM 5310B Total Organic Carbon ND mg/L 1.0 1 03/19/16 18:24 7440-44-0 Date: 03/23/2016 02:01 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 25 t� i• A rrce.4n�lytical" Issued: ee 1 df 1 Field.Data Sheet Client: -).ei.VI Location: c{es' lo0c79.,. n! � Project Name/#: $0 Name and Afiliation (Sampler(s): Name and AfiIiaiion (Inspector):- N% Well Information Well ID: M ldi' at Well Diameter: a �� Total Well Depth: a9. a ft Static Water Level: ft Well Locked: <aD NO Constructi6(!f:�Steel Stainless Steel Multi Factor'; l.1 33 r(Radius/12)2 x 3.14 x 7.48] Casing Volume: 3, S— goons Height of Water Column: a 1 q S ft' CaL 3 Volumes: - /0.5 gallons Pur a Information Date Purged n.3 / /5 / !(a StartTime: /F:/S N/A - Purge Rate: Purging Method: 3 CE Total Volume Purged: / 0• 67'� gallons Sampling Information Date Collected: 3 Time Collected.—ZL—OL—CQ m P Sampling Equipment Used: Bai f-e Bottle Type Preservation Analysis required Aids "�Cl P G -aSo�rQ / /-s /-4asMI— Nc�n�E l , sal 71s _ °�'�L'a /7/pNlq� �i%rls ;O r Ca �On T. Field Measurements/Observations Sample Temp (°C): -- Tune: 1/,/C)` Sample pH (s.u.): Time: Specific Cond. (uS): ! 6 ry Time• ReDox (mV): Time: Odor: Time: Turbidity (ntu): Time: —y Diss Oxy (mg/L): Time; Res. Cl (mg/L): Time: -- _ Time: Appearance; le ,.-- Other: q Sampler Signature/Date: Stabilization Test Time Purged PH (s.u.} Spec. Cond. (US) ReDox (mV) Turbidity (ntu) Diss Oxy. (mg/t) Temp. (°C} Volume Removed Other /-2:37- -7.o I365- 18/ ---- -- /,3 lZ a t 3 /-aceAnalytical o vyt.U111C111 IVQ111C, vv�uii,c�i� i��v,x-u. iy. Lucv1v ondition Upon Receipt(SCUR) Page 1 of 2 Document No.: Issuing Authority: F-CHR•CS-003-rev.18 Pace Huntersvilie Quality Office Page 2 of 2 for internal Use ONLY • Client Name: �r' t Project#: WO#:92290350 Courier: ❑Fed Ex ❑UPS ❑USPS ❑Client 1111111111111111111111❑ Commercial ❑Pace []Other: 92290350 Custody Seal Present? ❑Yes QNo'- Seals intact? [Dyes--- ❑No Date/initials Person Examining Contents:;-) I (�? t : • f"?,• c Packing Material: []Bubble Wrap ]Bubble Bags ❑None ❑Other: Thermometer: ❑ T,1505 ❑ ; -", ' Type of Ice: OWet`_-❑Blue ❑gone ❑SRmples on ice, cooling process has begun Correction Factor: OVC Cooler Temp Corrected (°C): Biological Tissue Frozen? []Yes ❑No '(]NIA Temp should be above freezing to 6°C USDA Regulated Soil (❑,NIA; water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally, MYes MNo-•- '— includine Hawaii and Puerto RlcaP r1Yes BIND -- COMMENTS: Chain of Custody Present? Dyes • []No ❑N/A 1. Chain of Custody Filled Out? DYes'"' ❑No ❑N/A 2. Chain of Custody Relinquished? DYes" [--]No ❑N/A 3. Sampler Name and/or Signature on COC? DYes s ❑No ❑N/A 4. Samples Arrived within Hold Time? ❑Yes []No ❑N/A 5, Short Hold Time Analysis (<72 hr.)? Dyes QNO ~ ❑N/A 6. Rush Turn Around Time Requested? DYes []NO ❑N/A 7, Sufficient Volume? DYes•` [:]No [I N/A 8. Correct Containers Used? ❑Yasr []No ❑N/A 9. -Pace Containers Used? DYes'- []No ❑N/A Containers Intact? Yes.--- []NO ❑N/A 10. Filtered Volume Received for Dissolved Tests? []Yes []No ❑N/A• 11. Note if sediment is visible in the dissolved container Sample Labels Match COC? DYes ❑No ❑N/A 12. -includes Date/iime/ID/Anal sis Matrix: 1 i - I All containers needing acid/base preservation have been 13. checked? [jYes • " [:]No ❑N/A All. containers needing preservation are found to be in compliance with EPA recommendation? (HNO3, HZSO4, HCI<2; NaOH >9 Sulfide, NaOH>32 Cyanide) E1Yes' ❑No ❑N/A Exceptions: VOA, Caliform, TOC, Oil and Grease, DRO/8015 (water) DOC,LLHg []Yes []NO ON/A— Samples checked for dechlorination [ti7Yes—• [--]No ❑N/A 14. Headspace in VOA Vials (>5-6mm)? []Yes ❑No—C1N!A 15. Trip Blank Present? []Yes []No ❑NIA 16. Trip Blank Custody Seals Present? []Yes []No []NIA' Pace Trip Blank Lot P (if purchased): CLIENTNOTIFiCATION/RESOLUTION Field Data Required? []Yes []No Person Contacted: Date/Time: Comments/Resolution Project Manager SCURF Review: j._tt. Date: is Project Manager SRF Review: ?-• �� Date: Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the.North Carolina DEHNR Certification Office (i.e. .Out of hold, Incorrect preservative, out of temp, incorrect containers) Page 24 of 25 e PaceAnalytrcal www.pacelalis.com Section A Required Client Information: Company: f l I 1! 'i Address: Due DatelTAT: Section B Required Project Information: CHAIN -OF -CUSTODY / Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section C Invoice li formallon: Al!enlion: Company Name: Section D Matrix Codes RoquirndClient lnfum:alrnn r_,nLklx r rant - a COLLECTED Drinking Water DW U Oz Water WT 'Nasle%%'ater %,Vm/ o U o crll,trrs:rE COMPOSITE — � Product P SIIAM ENDIGRA3 w SoiliSelid SL SAMPLE ID Oil OL r9 �; O U IX Wipe WP (A-Z. 0-9 / ;) Air AR W ❑ "`� a Z Sample IDs MUST BE UNIQUE Tissue TS G a 1-- Other OT X w w G g ~ t- a a " w G DATE TIME DATE TIME 2 Lti - Lw T i i9 31' - C a Peal;'-t> 6 % LU`— Gva — — 3//6 S C a A4 Gu- `> _ _ ` 1 /,_ 111rr - Page: oa REGULATORY AGENCY NPDES GROUND WATER DRINKING WATER UST RCRA OTHER .I�G7l�ij "��♦�'n`(�C1Y') Site Location / l _ _ STATE:s Requested Analysis Filtered (YIN) 2 , Preservatives } _ LO N 0 -.► - tU iq C D V1,Z O in Ka T lO U O C x z z O Pace Project No.! Lab J.D. ( ) ! s Xy .A` A ' YI I I I I I co I ADDITIONAL COMMENTS RELINQU�IS� D�BY / AFFILIATIItON / DATE TIME ACCEPTED BY / AFFILIATION DATE TIME SAMPLE CONDITIONS i 1°/ V- t; t 7:. ` — SAMPLER NAME AND SIGNATURE PRINT Name of SAMPLER: rf SIGNATURE of SAMPLER: 'Important Neer By signing Ill's IMm yno arc accoplirg Pace:: NET 30 day pny—nl I.,mS and agmeinp to late chanluS e1 1 5%1,er month fo ry i—i,:-not Raid 30 dory•;, l O r Z oUZ urZ d _� 2 d 7 �U— J l�° lL• ~ c F-ALL-Q-020rev.07. 15-May-2007 GW-59A COMPLIANCE REPORT FORM Permit # WQ0000957 (Submit one each monitoring period with GW 59 forms.) 1 Enter date monitoring results were due. ( 4/30/2016 ) Will this monitoring report (GW-59 and GW-59A) YES O` be submitted after the established due date? 2 Was any required Information missing on the GW-59 report forms? YES NO IF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES NO identification plate, area overgrown, etc.)af the answer is "YES", contact to Regional Office for guidance 4 Are any monitoring constituents equal to or above the established standards? (YE91 NO If the answer to question 4 is "NO", skip to section 8. If the answer to question 4 is "YES'list the affected wells individually with constituents(s) and concentration(s) exceeding standards in the space provided below: MW# 1, 2, 3, 5 and 9 exceed ground water standards for Total Dissolved Solids. MW# 1, 2, 3, 5 and 9 exceed for chlorides. MW#1 and #2 exceed for nitrate. 5 For the same constituents identified in question 4 above, have standards been exceeded previously for the YES NO same constituents s in the same wells s in the last two ears? If the answer to question 5 is "NO", skip to section 8. If the answer to question 5 is "YES"Dist in the space provided below, each well with constituent(s) exceeding standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years). See Report enclosed. 6 Are the monitoring wells listed in section 5 located at or beyond the review boundary? E NO If the answer is "YES", a groundwater quality problem may be occuring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly located; contact the Regional Office 7 Is the permittee implementing previously approved actions required by the Division involving this (YESNO groundwater quality problem? If the answer to question 7 is "YES", describe those actions in the space provided below. If the answer to question 7 is "NO'tontact the Regional Office within 90 days: an evaluation may be required to determine the impact the waste disposal system is having at the review and compliance boundaries surrounding this facility. Failure to do so may subject the permitteeg to a Notice of Violation fines, andfor penalties. Piezometers were placed in the irrigation fields to determine water quality . Total Dissolved Solids and Chlorides are naturally high in this area. Sprinkler heads were purposely capped off near monitoring well #1 as instructed by Jim Barber (Division of Water Resources) to see If the nitrate level will change in the well. Results for nitrates include nitrite due to lab. 8 The Person completing this portion (GW-59A) of the monitoring report should sign below and submit this form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form. I hereby acknowledge that the above information was evaluated and the information submitted in this report (Compliance Report GW-59A) is true and complete to the best of my knowledge. '. Signature of Permittee (or Authorized Agent) M to GW-59A 12/8/2003