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WQ0032016_Groundwater Monitoring Report March 2024_20240418
(:_W-59A COM.PUAiNCE REPORT FORM Perinit # WQ0032016 (,SUb"lit arse ouch njoniruring perm,! with Go—.59 ?n",.j - j Enter date monitoring results were due, (4 3012024 ) Will this monitoring report (GW-59 and GW-59A) YES NO be submitted after the established due date? X Was any required information missing on the GW-59 report forms? YES NO IF the answer to question 1 or 2 is "YES'; list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. I i Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing; cap, missing � YES NO identification plate, area overgrown, etc.)? !!'the a nswf-,p is "Yes conrricl the Regionril Djrrce for guidance. j 4 Are any monitored constituents equal to or above the established standards? YEg NO If the answer to question 4 is "NO", skip to section 6, If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s) exceeding standards in the space provided below. 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO some constituents) in the saute well(s) in the last two years? tf the answer fo question 5 is 'NO", skip to section $. if the answer to question 5 is "YE5', list in the space provided below, each well with constituent(s) exceeding standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years). MW-1: pH 6.44; Fe 0.39 MW-2: pH 5.52; Fe 0.487 MW-3: Fe 16.8 Mn 0.58 b Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES NO If the answer is "YES', a groundwater quality problem maybe occurring, CONTACT THE REGIONAL OFFICE IMMEDiATELYFOR GUIDANCE, if the answer is "NO", monitoring welts maybe improperly located; contact the Regional Office. 7 is the permittee implementing previously approved actions required by the Division involving this yES w'O groundwater quality problem? If the answer to question 7 is "YFS", describe those actions in the space provided below. If the answer to question 7 is "NO", contact the -ReWonal Office within 90 days: an evalrratinn m. v hm 8 tines and/or >Je.rtalties. t he person completing this portion (GW--59A) of the monitoring report should sign below and submit this form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form. l hereby acknowledge that the above information was evaluated and the information submitted in this report (Compliance Report OW-59A) is. true and complete to the best of my knowledge. Signature of Permittee (or Authorized GVV-59.1 1 V912003 Date SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: s . DEPARTMENT OF ENVIRONMENTAL QUALITY - INV. OF WATER RESOURCES INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617MAIL SERVICE CENTER, RALEIGH,NC27699.1617 FACILITY INFORMATION Please Print Cleady or Type PERMIT Number: Expiration Date: 6130/2028 Facility Name: Rose Hill Plantation Development, LLC Nan -Discharge UIC NPDES Other W00032016 Permit Name (if different): Facility Address: 3041 New Leicester Highway TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery Leicester NC 28748 County Buncombe ❑ Spray Field ❑ Remediation: Contact Person: Bob Barr Telephone#: (828) 251-1900 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Ste Name: Well # 1(MW A on GW-1b) No. of wells to be sampled: 3 ❑ Water Source Heat Pump X Other: Surface Irrigation from Permily SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): Well # 1 Upgradient Date sample collected: 3/25/2024 FIELD ANALYSES: WAS Well Depth: 69 ft. Well Diameter: 2 in. pH 004o0: 6.44 units Temp. 00010 15.2 °C DRY at Depth to Water Level 02546: 41.83 p ft. below measuring paint Screened Interval: 49 ft, to 69 ft. Spec. Cond. 000s4: 51.5 I Imhos time of Measuring Point is 2.5 ft. above land surface Relative M.P. Elevation: ft. Odor ono85: None sampling, check Volume of water pumpedlbailed before sampling: gallons Appearance Clear here:❑ Samples for metals were collected unfiltered: ❑■ YES ❑ NO and field acidified: 0 YES ❑ NO LABORATORY INFORMATION Date sample analyzed 415l2024 Laboratory Name: Pace Analytical Certification No. 40 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD o0335 mg1L Nitrite (NO2) as N o0615 <0.020 mglL Pb - Lead o1o51 <5.0 ug1L Coliform: MF Fecal 3161s <1 1100mL Nitrate (NO.) as N 0062o c0.020 mglL Zn -.Zinc olo92 c10.0 mg1L Coliform: MF Total 31504 1100mL Phosphorus: Total as P oo665 0.085 mglL (vole: use MPN method for highly turbid Samples) Orthophosphate 70507 mg1L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 47.0 mglL AI - Aluminum olim mglL PH (Lab) 00403 units Ba - Barium 01007 19.2 uglL TOC 00680 <1-0 mglL Ca - Calcium 00916 mg1L Chloride 00940 <1.0 mg1L Cd - Cadmium 01027 uglL Arsenic 01002 <10.0 uglL Chromium: Total 01034 <5.0 uglL Grease and Oils 00552 mglL Cu - Capper 01042 <5.0 mglL ORGANICS: (by GC, GCIMS, HPLC) Phenol 32730 ug1L Fe - Iran 01045 390 uglL (Specify test and method #. ATTACH LAB REPORT,) Sulfate o0945 mglL Hg - Mercury 719GO uglL Lab Report Attached? ❑ Yes (1) ❑■ No (0) Specific Conductance ❑sass µMhos K - Potassium 00937 mglL VOC 7B73 method # SM 6200B Total Ammonia 0061a <0.10 mglL Mg - Magnesium 00927 mglL method # (Ammonia Nitrogen: N113as N: Ammonia Nitrogen, Tolal} Mn - Manganese o1o55 9.7 g uglL .method # TKN as N 00625 mglL Ni - Nickel 01067 ug1L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mglL Effluent Total VOCs: mglL VOC Removal% GVV-59 Rev.05-07-2018 SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENTAL. QUALITY- DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 6130/2028 Facility Name: Rose Hill Plantation Development, LLG Mon -Discharge UIC NPDES Other WQ0032016 Permit Name (if different): Facility Address: 3041 New Leicester Highway TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery Leicester NC 28748 County Buncombe ❑ Spray Field ❑ Remediation: Contact Person: Bob Barr Telephone#: (628) 251-1900 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Well # 2(MW B on GW-1 b) No. of wells to be sampled: 3 ❑ Water Source Heat Pump 0 Other: Surface Irrigation (fmm Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): Well # 2 downgradient Date sample collected: 3/25/2024 FIELD ANALYSES: WAS Well Depth: 30 ft, Well Diameter: 2 in. pH 00400: 5.52 units Temp. 000lo: 11.7 °C DRY at Depth to Water Level 82546:12.04 ft. below measuring point Screened Interval: 10 ft. to 30 ft. Spec. Canal. oaa94: 34.4 µMhos time of sampling,chock Measuring Point is 2.5 ft. above land surface Relative M.P. Elevation: ft. Odor o0D85: None Volume of water pumped/bailed before sampling: gallons Appearance Clear here:❑ Samples for metals were collected unfiltered: 0 YES ❑ NO and field acidified: 0 YES ❑ NO LABORATORY INFORMATION Date sample analyzed:41512024 Laboratory Name: Pace Analytical Certification No. 40 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 <0,020 mg/L Pb -Lead uimi <5.0 ug1L Coliform: MF Fecal 31616 <1,0 1100ml- Nitrate (NO,) as N 00620 0.4C mg/L 7n -Zinc 01092 <10.0 mg/L Collforrn: MF Total 31504 1100mL Phosphorus: Total as P oo665 <0.050 mg/L (Note: use MPN method for highly turbid Samples) Orthophosphate 70507 mg1L Other (Specify Compounds and Concentration Units): issolved Solids:Total 703oo 30.0 mg1L Al - Aluminum a11o5 mglL PH (Lab) 004D3 units Ba - Barium a10o7 26.5 ug1L TOC 00680 <1.0 mg]L Ca - Calcium 00916 mg/L Chloride 00940 4.6 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 <10.0 ug/L Chromium: Total 01034 <5.0 ug/L Grease and Oils 00552 mg/L Cu -Capper 01042 <5.0 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 487 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑■ No (0) Specific Conductance 00095 )LMhes K - Potassium 00937 mg/L VOC 7873 method # SM 6200B Total Ammonia 00610 <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen, NH3asN: Ammonia Nitrogen. Total( Mn -Manganese 01055 5.3 ug1L ,method # TKN as N 00625 mglL Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Permittee (or Authorized Agent) Name and Title - Please print or type Signature of Permittee (or Authorized Agenq (Date) GVV-59 Rev_ 06-07-2018 SUBMIT FORM ON YELLOW PAPER ONLY • DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NO 27699-1617 FACILITY INFORMATION Please Print C)ear(y or Type PERMIT Number: Expiration Date: 613012,028 Facility Name: Rose Hill Plantation Development, LLC Non -Discharge UIC Permit Name (if different): NPDES Other WQ0032016 Facility Address: 3041 New Leicester Highway TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery Leicester NC 28748 County Buncombe ❑ Spray Field ❑ Remediation: Contact Person: Bob Barr Telephone#: (828) 251-1900 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Well # 3 No. of wells to be sampled: 3 ❑ Water Source Heat Pump ❑■ Other: Surface Irrigation from Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): Well 4 3 Date sample collected: 3/25/2024 FIELD ANALYSES: WAS Well Depth: 14 ft, Well Diameter. 2 in. pH 00400: 6.86 units Temp. 00010: 7.6 °C DRY at Depth to Water Level azsae: 4.25 ft. below measuring point Screened Interval: 4 ft. to 14 ft. Spec. Cond. 00094: 108.0 }Mhos time ofsampling, Measuring Pofnt is 0 ft. above land surface Relative M.P. Elevation: ft. Odor 00085: None check Volume of water pumped/bailed before sampling: gallons Appearance Clear here,❑ Samples for metals were collected unfiltered: ❑■ YES ❑ NO and field acidified: 0 YES ❑ NO LABORATORY INFORMATION Date sample analyzed:4/512024 Laboratory Name: Pace Analytical Certification No. 40 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 0,029 mg/L Pb -Lead oio51 <5.0 ug/L Coliform: MF Fecal 31616 <1.0 /100mL Nitrate (NO3) as N 00620 <0,020 mg/L Zn -Zinc 01092 <10.0 mg/L Coliform: IMF Total 31504 M00mL Phosphorus: Total as P oo865 0.062 mglL (Note: use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 67.0 mg/L Al - Aluminum 011c5 mg1L PH (Lab) 00403 units Ba - Barium a1aa7 15.0 ug1L TOC Gesso <1.0 mg/L Ca - Calcium oasis mg/L Chloride 00940 4.6 mg/L Cd - Cadmium 01027 ug1L Arsenic 01002 <10.0 ug/L Chromium: Total 01034 <5.0 ug1L Grease and Oils 00552 mg1L Cu - Capper 01042 <5-0 mglL ORGANICS: (by GC, GCIMS, HPLC) Phenol 32730 ug1L Fe - Iron 01045 16800 uglL (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mglL Hg - Mercury 71900 uglt_ Lab Report Attached? ❑ Yes (1) 0 No (0) Specific Conductance oo095 µMhos K - Potassium 00937 mg/L VOC 7873 method # SM 6200E Total Ammonia 00610 <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen, NH, as N. Ammonia Nitrogen, Tolal) Mn - Manganese oims 580 g uglL ,method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Permittee (or Authorized Agent) Name and Title - Please print or type Signature of Permittee (or Authorized Agent) (Date) GW-59 Rev.06-07-2018 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 April 05, 2024 Kimber Reese RPB Systems Inc. P.O. Box 1325 Asheville, NC 28802 RE: Project: Rose Hill MW Pace Project No.: 92721035 Dear Kimber Reese: Enclosed are the analytical results for sample(s) received by the laboratory on March 25, 2024. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, (Z/� ` - Lord Patton lorri.patton@pacelabs.com 828-417-6055 Project Manager Enclosures cc: Mr. Robert Barr, RPB Systems Inc. Ms. Liz Barr, RPB Systems Inc. Lorri Patton REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 28 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Rose Hill MW Pace Project No.: 92721035 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 CERTIFICATIONS South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 VirginiaNELAP Certification #: 460221 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 VirginiaNELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 28 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 SAMPLE ANALYTE COUNT Project: Pace Project No.: Rose Hill MW 92721035 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92721035001 MW-1 EPA 200.7 Rev 4.4 1994 SBW 8 PASI-A SM 2540C-2015 JMH1 1 PASI-A SM 9222D-2015 YEG 1 PASI-A EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A EPA 353.2 Rev 2.0 1993 KDF1 2 PASI-A EPA 365.1 Rev 2.0 1993 Zip 1 PASI-A SM 4500-CI-E-2011 MMA 1 PASI-A SM 5310B-2014 MJP 1 PASI-A 92721035002 MW-2 EPA 200.7 Rev 4.4 1994 SBW 8 PASI-A SM 2540C-2015 JMH1 1 PASI-A SM 9222D-2015 YEG 1 PASI-A EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A EPA 353.2 Rev 2.0 1993 KDF1 2 PASI-A EPA 365.1 Rev 2.0 1993 Zip 1 PASI-A SM 4500-CI-E-2011 MMA 1 PASI-A SM 5310B-2014 MJP 1 PASI-A 92721035003 MW-31B EPA 200.7 Rev 4.4 1994 SBW 8 PASI-A SM 2540C-2015 JMH1 1 PASI-A SM 9222D-2015 YEG 1 PASI-A EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A EPA 353.2 Rev 2.0 1993 KDF1 2 PASI-A EPA 365.1 Rev 2.0 1993 Zip 1 PASI-A SM 4500-CI-E-2011 MMA 1 PASI-A SM 5310B-2014 MJP 1 PASI-A PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 28 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Rose Hill MW Pace Project No.: 92721035 Sample: MWA Lab ID: 92721035001 Collected: 03/25/24 14:15 Received: 03/25/24 16:15 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 03/26/24 09:56 Collected By Mark 1 03/26/24 09:56 Swann Collected Date 3/25124 1 03/26/24 09:56 Collected Time 14:15 1 03/26/24 09:56 pH 6.44 Std. Units 1 03/26/24 09:56 Temperature 15.2 deg C 1 03/26/24 09:56 Static Water Level 41.83 feet 1 03/26/24 09:56 Specific Conductance 51.5 umhos/cm 1 03/26/24 09:56 Oxygen, Dissolved 5.99 mg/L 1 03/26/24 09:56 7782-44-7 REDOX 93.1 my 1 03/26/24 09:56 Turbidity 8.45 NTU 1 03/26/24 09:56 Odor No Odor 1 03/26/24 09:56 Appearance Clear 1 03/26/24 09:56 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services -Asheville Arsenic ND ug/L 10.0 1 03/27/2413:30 03/29/2415:41 7440-38-2 Barium 19.2 ug/L 5.0 1 03/27/2413:30 03/29/2415:41 7440-39-3 Chromium ND ug/L 5.0 1 03/27/2413:30 03/29/2415:41 7440-47-3 Copper ND ug/L 5.0 1 03/27/2413:30 03/29/2415:41 7440-50-8 Iron 390 ug/L 50.0 1 03/27/2413:30 03/29/2415:41 7439-89-6 Lead ND ug/L 5.0 1 03/27/2413:30 03/29/2415:41 7439-92-1 Manganese 9.7 ug/L 5.0 1 03/27/2413:30 03/29/2415:41 7439-96-5 Zinc ND ug/L 10.0 1 03/27/2413:30 03/29/2415:41 7440-66-6 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids 47.0 mg/L 25.0 1 03/29/24 13:06 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services -Asheville Fecal Coliforms ND CFU/100 mL 1.0 1 03/25/24 16:44 03/26/24 15:49 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 1 04/05/24 13:16 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate ND mg/L 0.020 1 03/26/24 13:23 14797-55-8 Nitrogen, Nitrite ND mg/L 0.020 1 03/26/24 13:23 14797-65-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/05/2024 05:40 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 28 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Rose Hill MW Pace Project No.: 92721035 Sample: MWA Lab ID: 92721035001 Collected: 03/25/24 14:15 Received: 03/25/24 16:15 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus 0.085 mg/L 0.050 1 04/04/24 23:40 04/05/24 11:41 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride ND mg/L 1.0 1 04/03/24 21:23 16887-00-6 531013 TOC Analytical Method: SM 531 OB-2014 Pace Analytical Services -Asheville Total Organic Carbon ND mg/L 1.0 1 04/03/24 20:19 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/05/2024 05:40 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 28 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Rose Hill MW Pace Project No.: 92721035 Sample: MW-2 Lab ID: 92721035002 Collected: 03/25/24 12:55 Received: 03/25/24 16:15 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 03/26/24 10:03 Collected By Mark 1 03/26/24 10:03 Swann Collected Date 3/25124 1 03/26/24 10:03 Collected Time 12:55 1 03/26/24 10:03 pH 5.52 Std. Units 1 03/26/24 10:03 Temperature 11.7 deg C 1 03/26/24 10:03 Static Water Level 12.04 feet 1 03/26/24 10:03 Specific Conductance 34.4 umhos/cm 1 03/26/24 10:03 Oxygen, Dissolved 7.07 mg/L 1 03/26/24 10:03 7782-44-7 REDOX 87.9 my 1 03/26/24 10:03 Turbidity 19.25 NTU 1 03/26/24 10:03 Odor No Odor 1 03/26/24 10:03 Appearance Clear 1 03/26/24 10:03 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services -Asheville Arsenic ND ug/L 10.0 1 03/27/2413:30 03/29/2415:43 7440-38-2 Barium 26.5 ug/L 5.0 1 03/27/2413:30 03/29/2415:43 7440-39-3 Chromium ND ug/L 5.0 1 03/27/2413:30 03/29/2415:43 7440-47-3 Copper ND ug/L 5.0 1 03/27/2413:30 03/29/2415:43 7440-50-8 Iron 487 ug/L 50.0 1 03/27/2413:30 03/29/2415:43 7439-89-6 Lead ND ug/L 5.0 1 03/27/2413:30 03/29/2415:43 7439-92-1 Manganese 5.3 ug/L 5.0 1 03/27/2413:30 03/29/2415:43 7439-96-5 Zinc ND ug/L 10.0 1 03/27/2413:30 03/29/2415:43 7440-66-6 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids 30.0 mg/L 25.0 1 03/29/24 13:06 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services -Asheville Fecal Coliforms ND CFU/100 mL 1.3 1.3 03/25/24 16:44 03/26/24 15:49 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 1 04/05/24 13:18 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 0.40 mg/L 0.020 1 03/26/24 13:22 14797-55-8 Nitrogen, Nitrite ND mg/L 0.020 1 03/26/24 13:22 14797-65-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/05/2024 05:40 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 28 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Rose Hill MW Pace Project No.: 92721035 Sample: MW-2 Lab ID: 92721035002 Collected: 03/25/24 12:55 Received: 03/25/24 16:15 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus ND mg/L 0.050 1 04/04/24 23:40 04/05/24 11:43 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 4.6 mg/L 1.0 1 04/03/24 21:26 16887-00-6 531013 TOC Analytical Method: SM 531 OB-2014 Pace Analytical Services -Asheville Total Organic Carbon ND mg/L 1.0 1 04/03/24 20:38 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/05/2024 05:40 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 28 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Rose Hill MW Pace Project No.: 92721035 Sample: MW-313 Lab ID: 92721035003 Collected: 03/25/24 10:15 Received: 03/25/24 16:15 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 03/26/24 10:18 Collected By Mark 1 03/26/24 10:18 Swann Collected Date 3/25124 1 03/26/24 10:18 Collected Time 10:15 1 03/26/24 10:18 pH 6.86 Std. Units 1 03/26/24 10:18 Temperature 7.6 deg C 1 03/26/24 10:18 Static Water Level 4.25 feet 1 03/26/24 10:18 Specific Conductance 108.0 umhos/cm 1 03/26/24 10:18 Oxygen, Dissolved 0.50 mg/L 1 03/26/24 10:18 7782-44-7 REDOX 13.7 my 1 03/26/24 10:18 Turbidity 2.69 NTU 1 03/26/24 10:18 Odor No Odor 1 03/26/24 10:18 Appearance Clear 1 03/26/24 10:18 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services -Asheville Arsenic ND ug/L 10.0 1 03/27/2413:30 03/29/2415:46 7440-38-2 Barium 15.0 ug/L 5.0 1 03/27/2413:30 03/29/2415:46 7440-39-3 Chromium ND ug/L 5.0 1 03/27/2413:30 03/29/2415:46 7440-47-3 Copper ND ug/L 5.0 1 03/27/2413:30 03/29/2415:46 7440-50-8 Iron 16800 ug/L 50.0 1 03/27/2413:30 03/29/2415:46 7439-89-6 Lead ND ug/L 5.0 1 03/27/2413:30 03/29/2415:46 7439-92-1 Manganese 580 ug/L 5.0 1 03/27/2413:30 03/29/2415:46 7439-96-5 Zinc ND ug/L 10.0 1 03/27/2413:30 03/29/2415:46 7440-66-6 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids 67.0 mg/L 25.0 1 03/29/24 13:07 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services -Asheville Fecal Coliforms ND CFU/100 mL 1.0 1 03/25/24 16:44 03/26/24 15:49 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 1 04/05/24 13:19 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate ND mg/L 0.020 1 03/26/24 13:17 14797-55-8 Nitrogen, Nitrite 0.029 mg/L 0.020 1 03/26/24 13:17 14797-65-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/05/2024 05:40 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 28 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Rose Hill MW Pace Project No.: 92721035 Sample: MW-313 Lab ID: 92721035003 Collected: 03/25/24 10:15 Received: 03/25/24 16:15 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus 0.62 mg/L 0.050 1 04/04/24 23:40 04/05/24 11:44 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 4.6 mg/L 1.0 1 04/03/24 21:26 16887-00-6 531013 TOC Analytical Method: SM 531 OB-2014 Pace Analytical Services -Asheville Total Organic Carbon ND mg/L 1.0 1 04/03/24 20:54 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/05/2024 05:40 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 28 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Rose Hill MW Pace Project No.: 92721035 QC Batch: 842098 Analysis Method: EPA 200.7 Rev 4.4 1994 QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92721035001, 92721035002, 92721035003 METHOD BLANK: 4349117 Matrix: Water Associated Lab Samples: 92721035001, 92721035002, 92721035003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Arsenic ug/L ND 10.0 03/29/2414:35 Barium ug/L ND 5.0 03/29/2414:35 Chromium ug/L ND 5.0 03/29/2414:35 Copper ug/L ND 5.0 03/29/2414:35 Iron ug/L ND 50.0 03/29/2414:35 Lead ug/L ND 5.0 03/29/2414:35 Manganese ug/L ND 5.0 03/29/2414:35 Zinc ug/L ND 10.0 03/29/2414:35 LABORATORY CONTROL SAMPLE: 4349118 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic ug/L 500 497 99 85-115 Barium ug/L 500 488 98 85-115 Chromium ug/L 500 508 102 85-115 Copper ug/L 500 500 100 85-115 Iron ug/L 5000 4860 97 85-115 Lead ug/L 500 498 100 85-115 Manganese ug/L 500 490 98 85-115 Zinc ug/L 500 502 100 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4349119 4349120 MS MSD 92721331010 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Arsenic ug/L ND 500 500 527 505 105 101 70-130 4 Barium ug/L 123 500 500 658 642 107 104 70-130 3 Chromium ug/L 29.6 500 500 559 537 106 102 70-130 4 Copper ug/L 62.8 500 500 602 575 108 102 70-130 5 Iron ug/L 32000 5000 5000 39400 39200 149 144 70-130 1 M1 Lead ug/L 8.4 500 500 517 494 102 97 70-130 5 Manganese ug/L 87.9 500 500 603 588 103 100 70-130 3 Zinc ug/L 350 500 500 857 836 101 97 70-130 2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/05/2024 05:40 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 28 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Rose Hill MW Pace Project No.: 92721035 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4349121 4349122 MS MSD 92721331011 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Arsenic ug/L ND 500 500 512 515 102 103 70-130 1 Barium ug/L 38.5 500 500 531 529 99 98 70-130 0 Chromium ug/L 2.OJ 500 500 503 508 100 101 70-130 1 Copper ug/L 161 500 500 677 674 103 103 70-130 0 Iron ug/L 69.7 5000 5000 5020 5000 99 99 70-130 1 Lead ug/L ND 500 500 490 493 98 99 70-130 1 Manganese ug/L 8.4 500 500 498 493 98 97 70-130 1 Zinc ug/L 17.0 500 500 506 509 98 98 70-130 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/05/2024 05:40 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 28 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Rose Hill MW Pace Project No.: 92721035 QC Batch: 842600 Analysis Method: SM 2540C-2015 QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92721035001, 92721035002, 92721035003 METHOD BLANK: 4351836 Matrix: Water Associated Lab Samples: 92721035001, 92721035002, 92721035003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Dissolved Solids mg/L ND 25.0 03/29/24 13:04 LABORATORY CONTROL SAMPLE: 4351837 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Dissolved Solids mg/L 250 262 105 90-110 SAMPLE DUPLICATE: 4351838 92720833002 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 348 343 1 SAMPLE DUPLICATE: 4351839 92721035001 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 47.0 45.0 4 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/05/2024 05:40 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 28 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Rose Hill MW Pace Project No.: 92721035 QC Batch: 841956 Analysis Method: SM 9222D-2015 QC Batch Method: SM 9222D-2015 Analysis Description: 9222D Fecal Coliform(MF) -AVL Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92721035001, 92721035002, 92721035003 METHOD BLANK: 4348551 Matrix: Water Associated Lab Samples: 92721035001, 92721035002, 92721035003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Fecal Coliforms CFU/100 mL ND 1.0 03/26/24 15:49 SAMPLE DUPLICATE: 4348552 Parameter Fecal Coliforms 92720857005 Dup Units Result Result RPD Qualifiers CFU/100 mL 116 115 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/05/2024 05:40 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 28 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Rose Hill MW Pace Project No.: 92721035 QC Batch: 844394 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92721035001, 92721035002, 92721035003 METHOD BLANK: 4360905 Matrix: Water Associated Lab Samples: 92721035001, 92721035002, 92721035003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Ammonia mg/L ND 0.10 04/05/24 12:45 LABORATORY CONTROL SAMPLE: 4360906 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 5.0 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4360907 4360908 MS MSD 92722322006 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L 0.14 5 5 5.3 5.3 104 104 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4360909 4360910 MS MSD 92722322007 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L ND 5 5 5.0 5.0 101 101 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/05/2024 05:40 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 28 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Rose Hill MW Pace Project No.: 92721035 QC Batch: 841743 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92721035001, 92721035002, 92721035003 METHOD BLANK: 4347328 Matrix: Water Associated Lab Samples: 92721035001, 92721035002, 92721035003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L ND 0.020 03/26/24 13:07 Nitrogen, Nitrite mg/L ND 0.020 03/26/24 13:07 LABORATORY CONTROL SAMPLE: 4347329 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 1.5 1.6 105 90-110 Nitrogen, Nitrite mg/L 1 0.99 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4347330 4347331 MS MSD 92720967001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L 1.5 1.5 1.5 3.1 3.7 105 145 90-110 18 Nitrogen, Nitrite mg/L 0.034 1 1 1.1 1.1 104 106 90-110 3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/05/2024 05:40 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 28 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Rose Hill MW Pace Project No.: 92721035 QC Batch: 844502 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92721035001, 92721035002, 92721035003 METHOD BLANK: 4361668 Matrix: Water Associated Lab Samples: 92721035001, 92721035002, 92721035003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Phosphorus mg/L ND 0.050 04/05/2411:32 LABORATORY CONTROL SAMPLE: 4361669 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phosphorus mg/L 2.5 2.5 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4361670 4361671 MS MSD 92721057001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 0.20 2.5 2.5 2.8 2.7 103 101 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4361672 4361673 MS MSD 92721057002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L ND 2.5 2.5 2.6 2.6 103 102 90-110 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/05/2024 05:40 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 28 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Rose Hill MW Pace Project No.: 92721035 QC Batch: 844117 Analysis Method: SM 4500-CI-E-2011 QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92721035001, 92721035002, 92721035003 METHOD BLANK: 4359627 Matrix: Water Associated Lab Samples: 92721035001, 92721035002, 92721035003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 04/03/24 21:01 LABORATORY CONTROL SAMPLE: 4359628 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 20.5 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4359629 4359630 MS MSD 92721796001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 4.4 10 10 14.9 14.9 105 105 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4359631 4359632 MS MSD 92721796002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 7.2 10 10 18.0 17.9 108 106 90-110 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/05/2024 05:40 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 28 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Rose Hill MW Pace Project No.: 92721035 QC Batch: 844093 Analysis Method: SM 531 OB-2014 QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92721035001, 92721035002, 92721035003 METHOD BLANK: 4359397 Matrix: Water Associated Lab Samples: 92721035001, 92721035002, 92721035003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Organic Carbon mg/L ND 1.0 04/03/24 18:09 LABORATORY CONTROL SAMPLE: 4359398 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Organic Carbon mg/L 25 24.1 96 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4359399 4359400 MS MSD 92721320001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Total Organic Carbon mg/L 5.5 25 25 30.0 30.4 98 100 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4359401 4359402 MS MSD 92721320002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Total Organic Carbon mg/L 4.5 25 25 29.3 29.6 99 100 90-110 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/05/2024 05:40 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 28 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALIFIERS Project: Rose Hill MW Pace Project No.: 92721035 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/05/2024 05:40 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 28 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Rose Hill MW 92721035 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92721035001 MW-1 92721035002 MW-2 92721035003 MW-3B 92721035001 MW-1 EPA 200.7 Rev 4.4 1994 842098 EPA 200.7 Rev 4.4 1994 842230 92721035002 MW-2 EPA 200.7 Rev 4.4 1994 842098 EPA 200.7 Rev 4.4 1994 842230 92721035003 MW-3B EPA 200.7 Rev 4.4 1994 842098 EPA 200.7 Rev 4.4 1994 842230 92721035001 MW-1 SM 2540C-2015 842600 92721035002 MW-2 SM 2540C-2015 842600 92721035003 MW-3B SM 2540C-2015 842600 92721035001 MW-1 SM 9222D-2015 841956 SM 9222D-2015 841957 92721035002 MW-2 SM 9222D-2015 841956 SM 9222D-2015 841957 92721035003 MW-3B SM 9222D-2015 841956 SM 9222D-2015 841957 92721035001 MW-1 EPA 350.1 Rev 2.0 1993 844394 92721035002 MW-2 EPA 350.1 Rev 2.0 1993 844394 92721035003 MW-3B EPA 350.1 Rev 2.0 1993 844394 92721035001 MW-1 EPA 353.2 Rev 2.0 1993 841743 92721035002 MW-2 EPA 353.2 Rev 2.0 1993 841743 92721035003 MW-3B EPA 353.2 Rev 2.0 1993 841743 92721035001 MW-1 EPA 365.1 Rev 2.0 1993 844502 EPA 365.1 Rev 2.0 1993 844655 92721035002 MW-2 EPA 365.1 Rev 2.0 1993 844502 EPA 365.1 Rev 2.0 1993 844655 92721035003 MW-3B EPA 365.1 Rev 2.0 1993 844502 EPA 365.1 Rev 2.0 1993 844655 92721035001 MW-1 SM 4500-CI-E-2011 844117 92721035002 MW-2 SM 4500-CI-E-2011 844117 92721035003 MW-3B SM 4500-CI-E-2011 844117 92721035001 MW-1 SM 5310B-2014 844093 92721035002 MW-2 SM 5310B-2014 844093 92721035003 MW-3B SM 5310B-2014 844093 Date: 04/05/2024 05:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 28 DC# Title: ENV-FRM-HUN1-0083 v03_Sample Condition Upon Receipt ' --Pace Effective Date: 12/01/2023 Laboratory a eiving samples: Asheville N Eden[] Greenwood ❑ Huntersville ❑ Raleigh❑ Client Name: Mechanicsville❑Atlanta❑ Kernersviilel—I • Project h: Wn# ' 927I 2103 III IIII II 1i�Mi�i��� Courier: Fed [x [-]UPS- ❑U5P5 ❑Client II � ll� 11 ill 1 El commercial Wace ❑Other: 92721035 Custody Sea I Present? ❑Yes VNo Seals Intact? Packing Material: ❑Bubble Wrap ubble Bags Th ter• ❑Yes ❑No O /A .ci2 t f Date/Initials Person Examining Contents: ❑None ❑ Other ermome ❑ qIR Gun ID: %r[,� Type of Ice: �4�lel -�� Correct ion factor:. Cooler Temp: Add/Subtract (°C) n CoolerTernp Corrected ('C): USDA Regulated Soil �j N/A, water sample) Did samples origin, a in a quarantine zone within the United States: CA, NY, or SC ❑Blue El None Biological Tissue Frozen? Dyes ❑No VN/A Temp should be above freezing to 6°C ❑Samples out of temp criteria. Samples on ice, cooling process has begun Did samples originate from a foreign source (internationally, [check maps)? LJYes LJNo _ rnuuueng nawdn dim ruii w MWI u r as L—J,MU Comments/Discrepancy: Chain of Custody present? AYes ❑No ❑N/A 1. Samples Arrived within Hold Time? Yes []No ❑N/A 2. Short Hold Time Analysis (<72 hr.)? Yes ❑No []N/A 3. Rush Turn Around Time Requested? ❑Yes ❑No /A 4. Sufficient Volume? yes ❑Na ❑N/A 5. Correct Containers Used? -Pace Containers Used? [ i+es Yes ❑No ❑No ❑N/A ❑N/A 6. Containers Intact?1es ❑No ❑N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes ❑No N/A 8, Sample Labels Match COO -Includes Date/Time/ID/Analysis Matrix: Yes J' ❑No ❑N/A 4. Headspace in VC)A Vials (>5-6mm)? ❑Yes ❑No ❑N/A 10. Trip 81a n k Present? Trip Blank Custody Seals Present? ❑Yes ❑Yes ❑No ❑No ❑N/A ❑N/A 11. COMMENT(S/SAMPLE DISCREPANCY +�Z — i/l nfi►'Yl�er Es U(lfCca,f�7 �_1� ',-Q, �_(_�� CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Lot ID of soffit containers: Date/ Firne: Date: Date: t•two uata nequlrear L1res L1rvo Page 21 of 28 OUaltrax ID- 69614 Paae 1 of 2 c A K y N ❑ Q O d `� $ ♦1 u b N C W m C N C F-` it C 0 ry ro N = i➢ ° Z u v ¢ o 3 o N ny�rlVl 3 Cb o n a N� o CO _ w 3 A @ ,01. . n 73 C re p c S f, o ca A N R o d F M d 3 x a n ~ 0 aw i � _ 'm el 3 3 3 3' 3- ra G1 N i r u a m n w x m o _W E . 0 r. m o 4 -�n C� N cw C V {4 z m n V • 4 m c o 3 mcr 00 m C - 1 F FE 1753 A a �' A v UD m �0 o s nJ A n m 3 N 3 z 3 n '2 ; ° v^i T n n 5t n < 3 Om 3 0 _ a 3 3 3 3 3 70 - yh\ `,\lC� n m sr f �' m C _ cj Q e H J Fr fG H Z v r+ S `^ X X X 2001 MET ICP a 3 X X X m 2540C Total Dissolved Solids d350.1 m X X Ammonia; 365.1 Phosphorus,X tr o a,ti351.2 Total`0 Total Kleldahl Nilrogen; TotalX d X X e Nitrogen Calc y'' m _ a X -X- 353:2 Nitrogen, NO2IN03 unpres - N: N w rn _ " X X X 4500 Chloride a m m � 0 y v Z X X X 53106 TpC a @ ; rp1 \ n 2 n n o X X X L/1 � d 62pOB MSV m � 5 a o 0 X X X MBIQ 9222D Fecal Coliforrn AVL N c _ a 2 D QQ m n� 3 -AL Lab Use Onlya d w g W m No w v � age SrC Q N 3 m m00 Vya Ln N ev N'sN — w r Page 22 of 28 - Preservation nanKonfannance identified far n sample. o DC# Title: ENV-FRM-HUN1-0083 v03 - Sarni}le Condition Upon Receipt ace Effective Date: 12/01/2023 *Check mark top half of box if pH and/or dechlorination is verified and Project tl WOE: 92721035 within the acceptance range for preservation samples. PM: LJP Due Date: 04/08/24 Exceptions: VOA, Coliform,TOC, oil and Grease, DRO/8015 (water) DOC, LLFIg CLIENT: 93-RPB **Bottom half of box is to list number of bottles **"Check all unpreserved Nitrates for chlorine a z V a) 2 H w ¢ z 'O W H m a a 'D 61 4f a a ? -p w a u N V A N V v = a rn o z r m u d a r=, N F sl = O CV a C m U z i' 40 e p, N v a — a N V1 n C _ N V S n v O n V n. 0 N �% Q Z cl V Q z Q m a z _' ICI d Q Z ? d m z '-' Y l7 R m I Q Z u N N 1 Q ? u M v O ra i d n C 3 z of } C Q ro Z7 N m 11 _ E a) — V a J E N d a tb U '«+ m d JCC G N rnm a as U fa ci* J C3 1! r tv a m a u .� T a H 7 ry M tom V m a fn y a a rn a J E CI H m a m - m a J Ul N a Q m :. ro n J E ul .Nj tr a M N 3 1=L l7 a`f 1] E Q a1 — r-I a M U Q i a' i Q N = rl Z •+ U Q QI A ¢ J in N 7 m W Q N Z y n E a rl v1 + Q Q E 4 J in N Uf m l7 ¢ 2 iir n E Q D d m 0 n U Q O J Cl 2 M C7 O z Q p 7 O V i- a, t7 7 04 C 7 Q O O 7 rn l7 7 a fry T Q O O ? m c7 ❑ C 7 " a a �fl j r. a Y y^. .. a rr1 .... X C7 ._ ? Q. .� M N r-1 F w a V) A. .y ui n N F: N a Lon, ? V re CL inin in N 1< 4 1 o d .G in n try 7 7 ¢ V J v, 1 It 3N\� a s r; 7 a 9 11 12 - PH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative Lot 11 adjusted I added Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DENR Certification Office (i e. out of hold, incorrect preservative, out or temp, incorrect containers. Page 23 of 28 r)iinitrny In- fQF1A Pace 2 of 2 Hate —Issued:! November 27, 2018 P I Document Name: Field data Sheet ag litv /11w: of _f utwtersville Quial F Issuif[gAtithoxity, Face Document Number: F-CAR-FLD-00I-tev,02 office Field Data Shed project MfM �s Location: Naxxte and Affiliation (S=plLr(s): Field Data Sheet Review: Na-vae and Affiliation (fit$peCtOr)' Dat e, -BY: we11 n�fornuon wa ID: Well Locked- Y /140) WeM Diameter: Construction: (kD/Steel/Stainless Steel) ',7 Total Well Depth: Multi Factor'—LL6 —L nadiu9/12)2 x 3,14 X.7,481 gallons Static witer LeveL--ti --b ft- Casing Volume: Height o . f _ Water CDlu nui- ft Cal 3 Volumes: gallons Pump Intake- )-y StaTt: Finish,�_I�o purge Fate:_L�11, " Date Puj�ged-_��J Total Volume Purged- ----- purging Method.. L "—J Time Collected—_L+ 4 —, 6rnq 0M Sampling I EquipimentUse& Instrument ID; Bottk,.Type preservation Analysis Required kv Field 4_ea,9ureMe_At8L0_bserya6Dw sample Temp, �q !S')- Time: I Turbidity (ntu): Time: Dins Oxy (mWL). Time, Fe 2-� mg/L:- 4- Res, Cl (Mg/L)&tg/L),_AZI �_Tirne: Specific Cond. (us): Time: It, Odor:Y� Sample pH,_(s.u'). Time: Lc A- ime- ReDox (InV) Time: _J Appearance: ReDox (EH value),,YSI ProPlus +200mV Other. Time'. a�RGerjeraWe.ather Observations: fv,',j' /a;'O" -4-� CT) WindI!_"!:_(mPh) (sunny/cloudyftainy) Temp.— Sampler Signature: ate, L/ Time Temp. Diss Oxy. Spec, Cond, pH ReDox TuxbiditY Voluine Volume removed i ter Water level (ft) level (,) Other Other Purged �C) (MZ/L) (US) (MV) (rLt") S onst , (gallons/ (g onst . 4-1- I A-, 33 6 6 Lea r T 7�7' 1 4—J Page 24 of 28 �06 Document Name: Field data Sheet Date Issued: March'.8; 209' Page. I of Ar7d1y11Ct?I Issubig Authority: Pace Jimitersville Quality i Document Nc�ntiber: F-CAR-PLD-0f]I-revA3 Office Field Data Sheet Client; Locatiow oie- >/ Name and Affiliation (Sainpler(s); /"�? r 1 ✓ J Name and Affiliation (Inspector): Well Information Information Well ID:.I c,� - ' Well Diameter: Total Well Depth: ft Static Water Level: ft Height of Water Colurr m �7, �T G ft Well Locked: Data. Sheet Review: n Date: 01 a4 Construction: /Steel/Stab less Steel) Multi Factor*. -f /di [' (Radius/12)2 x 3.14 x 7 48] Casing Volume: gallons Cal. 3 Volumes: 3. Y gallons Pump intake: V_ ' l� -- ft By: b6C L )�tUv► Purge Infornation. t — Date Purgedj: / �' / Start:-., % ' Pialisllc 1� ,Iurge Rate: J-� ,M r� �y�h Purging Methe ci: �c 1, y •�r, , t Total Volume Purged: ?_ ? (ga.iloits./ la) sampliug_Information / Date Collected;_/ `/._.._ ! _ }} Title Collected: ( � E (ant/pin) Sampling Equipment Used: Pa .i 3t� !�, t Instrument ID:,f = 7 �` , ��� ' ' `> Bottle Type A1, L� Field Measurements/Observations Preservation 85/ IFS L L Analysis Required P Hai t -„ l Stk.Mple Temp (°C): 1117 Turbidity (,ntu): / 9, / j_ Tune: Diss Oxy (mg/L.): t: �7 Time: 4 J , Fe 2+ mg/L: /Vq Time: Specific Cozad. (6): 3 Tire: } a Res. Cl (mg/L)/(gg/L): 41" 'rime: AQ Sample pH. (s.u.): 5" , S Time: 1 1 • � Odar:__ �° .. � Time: � �.. � �_ ReDox (mV): .�1 Time,. 4''A Appearance: C «u.~ Tittle: / • ;' ReDox(il35ca1t )ixSl.i'_rQP-lus.+20[1t1W�1-? )._ [?titer: a i ✓A /OTime: General/WeatherObservations: (sunny/cloudy/rainy) Temp.. (°F) Wind"If (niph) Sampler Signature"Date: t �` Stabilization Test Vo ume Time Temp,Spec, Diss Oxy. Cond. pH (s.u.) ReDox Turbidity remove Water Other Purged o (C) (mg/I.) (mV) (n#u) (gallons/ tls level (ft) (us) L Page 25 of 28 I3pGUziienk:Name: Field Datzk Sheet N7 umenk. lssiied h MC4$; 201 Ng — of — °Doc�,MNoibet: 1sspe►ng.AnHibrity F CAR FI.D-M.rev.Oa Pace Hume sgfle Quality Office Ctienf: Projec-t.,. 1 ' - Well 10:. _ __ KevieWed-Gate-and-By: -1 _ 5tabiliiation lest Weil Diameter 1 1.2 1.625 2 3 6 3 .Mul plr-ahon D,D408 DA..030 0,1630 0.3670 0,.6530 1.46$0 2.6106 Time Temp. a .6 aiss Spec. pH (s.u.) Renax {mv) Turbidity Volume Removed (gall©�s/ cal N. drde.one 1l1(ater level � Othercond., -- ------- J � �� c, of � b -) ` f`LP � � Lj �- e �'}�� �__ � • .� � U / � a l 3 � J : � � ,fit � .� % `! �% � J. � •i:-..2X Page 26 of 28 ;A t L. Date Issued: November 27, 2018 Document Name: Field data Sheet Pave: 1 of _ Document Number: F-CARFLD-001-rev.02 Issseing Authority: Pace fi Office Field Data Sheet Client: as Location_ : 41 % >- A I 1 Project Name and Affiliation (Sampler(s): A"I s r 1 < Field Data Sheet Review: Name and Affiliation (Inspector):�� .� By: Date: '7 Well Information Well ID:is �`� Well Locked: / NO) Well Diameter: Construction: (V(,/Steel/Stainless Steel) Total Well Depth: ft Multi Factor*:. �r r(Radius/12)2 x3.14 x 7.48] Static Water Level: ' W ft Casing Volume: 1,a" �� gallons Height of Water Column: IJ 7ft Cal.. 3 Volumes; 7�'gallons Pump Intake: ?, t r ft Prur a Tnformatio -- -- ----- Date Purged:_ / y Start: ` Finish: 14i 1 G' Purge Rate: �' '�� •^ purging Method:. Total Volume Purged: �___� -_ _ (gallons/rzris SaMling_Lnformation r Date Collected: / "/ t` w Time Collected: Oz.prn) sampling Equipment Used: � 1, 1 � Instrument ID: Bottle Type Preservation Analysis Required ! LY1 J 3 t,•• r � 1 a � �15 � } Field Measuremtents Observations 1 '' G 1 Time: i Sar>Ltple Temp. (C): Time: f Turbidity (niu):, Diss Oxy (mg/L): �' Time: r r Fe 2+rng/L: `t' '-'�-- - Time: j v " Time: Specific Cond. (ttS � i i �� Res. Cl (mg/L)/(µ$/L):�t°'•i Time: i� Sample pH (s.u.): /rA Time; '' � '� Odor_ Tune: ' ReDox (mV): `Time: " Appearance: C,L:. A. ;t Time: v jr ReDox (EH value):YSI ProPlus +200mV � � � � Other. Time: � Genera]VWeatherObservations: t L vn �• �� 1 s_ 1; P (sunny/cloudy/rainy) Temp`' —; C?) Wind'+_ (mph) Sampler Signature: /1. lf� .: Date: 3 '" ,L " e4 IMN 14n" Tncf Time PlYr ed g Temp. °C ( ) Diss Oxy. (m /L) g Spec. Cond. (uS) pH (s.u,) ReDox (mV) Turbidity (ntu} VolumeWater removed (gallons/ nls) level (ft) Other C1+y.J _7 6�1J• i J �11, 'ate 7 V J, NIP 4 y A Page 27 of 28 E)4cuuient Narite• 064mertt Issued., Marc[486 201t. Field DMAShut Page! aft. Ddc theM Ntiut( er: lssuein �.uthiirilyt l BAR-FLD pol, ev.6 FACe Hamer mie Quality office 3 y'i— • y se Gtient: +� Locatiorr JI0 s Z. l c. Project: WeII ID: '_ t3 , -tevi-ewe€ -pate and By: �J Stabill2stionTest 1tFall biarnetex MfsI44cat on Factor* 1 �_8 1.2 Q.091 '01630 0.3670 0..6530 1,4630 3 2.6100 Time Temp. a Diss Oxy. Spec. Cord.. phi (;s.u.) ReDQX (M.V) Turbidity Volume Removed (gailvns/ /l }, [%W-ater level Other (us) circle one Page 28 of 28