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WQ0005910_Monitoring - 03-2024_20240702
Monitoring Report Submittal Permit Number#* Name of Facility:* Month: * March Report Information Type * Revised - GW-59 Confirmation Email Address: Name of Submitter: * Signature: Date of submittal: Initial Review WQ0005910 Avoca LLC Year:* 2024 Upload Document* Avoca LLC March 2024 GW-59 (Revised).pdf 3.08MB PDF Only Please upload one PDF containing all applicable monitoring reports (i.e., NDMR, NDAR-1, NDAR-2, NDMLR, GW-59). brian.conner@ashland.com Brian M. Conner fftt;ew 6W C Ca rt Reviewer: Wanda.Gerald 7/2/2024 This will be filled in automatically Is the project number correct?* WQ0005910 Is the monitoring report accepted?* Yes No Regional Office* Washington Reviewer: _anonymous Review Date: 7/3/2024 GW-59A COMPLIANCE, REPORT FORM Permit # W tG Ooo 5ct l (Submit one each uinnitoring period with GIV-59 forms.) I Enter date monitoring results were due. ( LA ISO]) Will this monitoring report (GW-59 and GW-59A) YF.S NO be submitted after the established due date? \7 2 Was any required information missing on the GW-59 report forms? YES NO IF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. V 3 Arc any of the mouito• wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES NO identification plate, area overgrown, etc.)? If the answer is "Yes", contact the Regional Office forguidance. 4 Are any monitored constituents equal to or above the established standards? YES NO If the answer to question 4 is 'NO", skip to section 8. If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s) exceeding standards in the space provided below: PtVV% . o•n 1 a. - N`e.) \ % -1 • S� w%y 1 \.- -CoS- JAW(b - 510 rr.y11-- N& W 1 \ - to too r" k l -- 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO same constituent(s) in the same well(s) in the last two years? If the answer to question 5 is "NO", skip to section 8. If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding standards, concentrations) reported, and sample collecttionD at for each occurrence (for the last two years). \111S�13- 1000 %%hS11.1 to40 \�171VI2i .-130 \O.-11 Lol'L1, ►1-qb '1t\�1 �,'a - tilb0 'i11p1,L7-- '1'LO 74-b -1 •31S01Z2- t%•S 3libl�l - to-1 O 311oix1- tot o Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES NO If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. if the answer is "NO", monitoring wells may be improperly located; contact the Regional Office. 7 Is the permittee implementing previously approved actions required by the Division involving this YES NO groundwater quality problem? If the answer to question 7 is "YES", describe those actions in the space provided below. If the answer to question 7 is "NO", contact the Regional Office within 90 days; an evaluation maV be required to determine the impact the waste disposal system is having at the review and compliance boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation, fines, and/or penalties. S The person completing this portion (GW-59A) of the monitoring report should sign below and submit this form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form. I hereby acknowledge that the above information was evaluated and the information submitted in this report (Compliance Report GW-59A) is true and complete to the best of my knowledge. Signature of Nermittee (or Authorized Agent) Date GW-59A 12/8/2003 SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 91M07-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: -2Lk Facility Name: Avoca LLC Non -Discharge W00005910 UIC Permit Name (if different): NPDES Other Facility Address: g�� IAvotu f7a✓Iv1 91 TYPE OF PERMITTED OPERATION BEING MONITORED rfY W.`� (Street) 1 ct S-1 County Bertie ❑ Lagoon ❑ Remediation: Infiltration Gallery (CO) (State) (zip) N Spray Field ❑Remediation: Contact Person: Brian Conner Telephone#: 252-482-2133 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name:AVOca LLC No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: (from Permit) SAMPLING INFORMATION r WELL ID NUMBER (from Permit): tv%w Date sample collected: 3-20-ZIA FIELD ANALYSES: If WELL WAS Well Depth: 21--I ft. Well Diameter: 2 in. pH ooaoo:14-Z7units Temp. 00010: fib• I °C DRY at Depth to Water Level 82546: $.7 ft. below measuring point Screened Interval: I S ft. to 22 ft. Spec. Cond. 000sa: µMhos time ofsampling, Measuring Point is 2 ft. above land surface Relative M.P. Elevation: ft. Odor o0085: N ov�� check Volume of water pumped/bailed before sampling: 5 gallons ��,// Appearance C 1e0.✓ here:❑ Samples for metals were collected unfiltered: ES ❑ NO and field acidified: DYES ❑ NO LABORATORY INFORMATION Date sample analyzed: 3 1 I IAL4 LaboratoryName: �q.,� �74. I`�i t?"tv�OC��(�; La.� Certification No. PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead o1o51 ug/L Coliform: MF Fecal 31616 /100mL Nitrate (NO3) as N 00620 40.04 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 Q . la mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 LiLA D mg/L Al - Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC oo68o -.: I$ mg/L Ca - Calcium oo916 ?jl_ S�I l mg/L Chloride 00940 3LA mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #./iTTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? Yes (1) ❑ No (0) peciffc Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 .O�i mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3as N; Ammonia Nitrogen, Total) Mn - Manganese o1055 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only - •Total• • I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete. and that the laboratory analytical data was produced using approved methods of analysis by a DWR-certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. _Bann,j6 L• jyv !P kOAk 'Mar • Permittee (or Authorized Ape t) Name and Title - Please print or type Siqnature of Permittee (or Authorized Agent) (Date) GW-59 Rev.3-1-2016 SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: .. INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: Facility Name: Avoca LLC Non -Discharge WQ0005910 UIC Permit Name (if different): NPDES Other Facility Address: %A i kW O (.a Cu✓w4 Qj - TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery Mery . x (Street) N L 2-1ct S—j County Bertie (City (state) (zip) N Spray Field El Remediation: Contact Person: Brian Conner Telephone#: 252-482-2133 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name -Avoca LLC No. of wells to be sampled: 6 ❑Water Source Heat Pump El Other: (from Permit) SAMPLING INFORMATION WELL ID NUMBER (from Permit): ��'-7 Date sample collected: 317.�,�� FIELD ANALYSES: If WELL WAS Well Depth: V Urmft. Well Diameter: 2.. in. pH oo400:9.00units Temp. 00010: 1 (�) °C DRY at Depth to Water Level 82546: —1 -Ci ft. below measuring point Screened Interval: S::ft. to ft. Spec. Cond. 00094: µMhos time of Measuring Point is 2. ft. above land surface Relative M.P. Elevation: ft. Odor oo085: N ohe' sampling, check Volume of water pumped/bailed before sampling: 5 gallons Appearance C.ar- �e here:❑ Samples for metals were collected unfiltered: YES ❑ _/ NO and field acidified: L`s YES ❑ NO LABORATORY INFORMATION Date sample analyzed: Laboratory Name: �oLy ,70.v�� i�sYv���r: ca Certification No. PARAMETERS NOTE: Values should reflect dissolved and colloidal concentration COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead olo51 ug/L Coliform: MF Fecal 31616 /100mL Nitrate (NO3) as N 00620 k - 0 3 mg/L Zn -Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0• Q q mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 12� mg/L Al -Aluminum oilo5 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 3.�2, mg/L Ca - Calcium 00916 -1.'-l'1Q mg/L Chloride oo94o 32 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron o1045 ug/L (Specify test and method #. TTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? VYes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 < C . CA mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen: NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% L-k-1 S 2%1 Permittee (or Authorized Agent) Name and Title - Please print orrype Siqnature of Permittee (or Au GW-59 Rev.3-1-2016 (Date) SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: I0-3►- 2Li Facility Name: Avoca LLC Non -Discharge WQ0005910 UIC Permit Name (if different): NPDES Other Facility Address: �� A �v0 cn � aevv+, 9a • TYPE OF PERMITTED OPERATION BEING MONITORED M ��_U `I (Street) (.1 12.71 Si County Bertie � ❑ Lagoon ❑ Remediation: Infiltration Gallery ( 1ty) (State) (Zip) Spray Field ❑Remediation: Contact Person: Brian Conner Telephone#: 252-482-2133 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name:Avoca LLC No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: (from Permit) SAMPLING INFORMATION WELL ID NUMBER (from Permit): �V� Date sample collected: 3 I �q 1 ��{ FIELD ANALYSES: If WELL WAS Well Depth: ts ft. Well Diameter: 2 in. pH 00400: (#-JLI units Temp. 00010: \\o-ob °C DRY at Depth to Water Level 82546: Cv• $ ft. below measuring point Screened Interval: 3 ft. to ft. Spec. Cond. 00094: µMhos time of sampling, Measuring Point is 2 ft. above land surface Relative M.P. Elevation: ft. Odor 00085: N 4r\2. check Volume of water pumped/bailed before sampling: gallons Appearance C_Xe_C .f here:❑ � Samples for metals were collected unfiltered: YES [I NO and field acidified: d,� YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 3 2\ 2L 1 ^ Laboratory Name: Wta•j �d•v>>i 1 ry �,v Certification No.� PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead o1o51 ug/L Coliform: MF Fecal 31616 /100mL Nitrate (NO3) as N 00620 , C)-j mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 3 . Ly 3 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 SCO mg/L Al - Aluminum o11o5 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 l3 •� mg/L Ca - Calcium 00916 �(o. S$ mg/L Chloride 00940 ZZ mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total o1o34 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #�4TTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 ©��i mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% GW-59 Rev.3-1-2016 SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: LO 3k '4 Facility Name: Avoca LLC Non -Discharge WQ0005910 UIC Permit Name (if different): NPDES Other Facility Address: 06%Ak P! VQCa r—atvw► 9,A • TYPE OF PERMITTED OPERATION BEING MONITORED (Street) N Bertie L 2�i9C�7 County ❑Lagoon El Remediation: Infiltration Gallery Icily) (state) (zip) ❑■ Spray Field ❑ Remediation: Contact Person: Brian Conner Telephone#: 252-482-2133 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name:Avoca LLC No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: (from Permit) SAMPLING INFORMATION A Q A WELL ID NUMBER (from Permit): t'kv — _l Date sample collected: 3'xo FIELD ANALYSES: If WELL WAS Well Depth: 22•$ft. Well Diameter: 2 in. pH 00400:5 A`i units Temp. 00010: °C DRY at Depth to Water Level 82546: ft. below measuring point Screened Interval:ft. to Z3 ft. Spec. Cond. 00094: µMhos time ofsampling, Measuring Point is Z, ft. above land surface Relative M.P. Elevation: ft. Odor 00085: N OVQ.. check Volume of water pumped/bailed before sampling: S gallons Appearance dam- here:❑ Samples for metals were collected unfiltered: VYES ❑ NO and field acidified: �ES ❑ NO LABORATORY INFORMATION 11 Date sample analyzed: 3j'�t2�E �1�� eL� LaboratoryName: l�alyaoin�C �irw� ��c�c i Certification No. `� PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N o0615 mg/L Pb - Lead o1051 ug/L Coliform: MF Fecal 31616 /100mL Nitrate (NO3) as N 00620 I-SZ mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 • 1 i mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 2 D mg/L AI - Aluminum o1105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 41.00 mg/L Ca - Calcium 00916 S • l 2 Z- mg/L Chloride 00940 3 l mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. 97TACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? Yes (1) ❑ No (0) pecific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia o0610 L 0 .out mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen: NH3asN: Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% L- jvy- , Yko^k r zed Agentl Name and Title - Please print or _` S--L. GW-59 Rev.3-1-2016 SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: Facility Name: Avoca LLC Non -Discharge WQ0005910 UIC NPDES Other Permit Name (if different): Facility Address: ObL{\ k'-rain �esrw► t� �� • TYPE OF PERMITTED OPERATION BEING MONITORED \ (Street) 2^'�gCJ Coun ty Bertie ❑Lagoon ❑Remediation: Infiltration Gallery (City (state) (Zip) 0 Spray Field ❑Remediation: Contact Person: Brian Conner Telephone#: 252-482-2133 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name:Avoca LLC No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: (from Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): Date sample collected: 3X7.0A-aLA FIELD ANALYSES: WAS Well Depth: 2O ft. Well Diameter: Z in. pH 00400:3.losunits Temp. 000lo: \0 0-I °C DRY at Depth to Water Level 825a6: p a.� ft. below measuring point Screened Interval: 7j ft. to 2-�ft. Spec. Cond. 000sa: µMhos time of sampling, Measuring Point is �. ft. above land surface Relative M.P. Elevation: ft. Odor o0065: �1 Oh2. check Volume of water pumped/bailed before sampling: gallons ,,,__ Appearance C-V-on - here:❑ Samples for metals were collected unfiltered: YES ❑ NO and field acidified: EKES ❑ NO LABORATORY INFORMATION -3� t 0 Date sample analyzed: 1\ `'lam - �l\1� 1`-E Laboratory Name: WU.'f ���� I(�y�rl,�(T;�\ Certification No. PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N oo615 mg/L Pb - Lead o1o51 ug/L Coliform: MF Fecal 31616 /100mL Nitrate (NO3) as N 00620 C4 , a w mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 3s L mg/L Al - Aluminum o1105 mg/L pH (Lab) oo403 units Ba - Barium 01007 ug/L TOC oo680 k •s o mg/L Ca - Calcium 00916 Z� .�-E�3 mg/L Chloride 00940 y� mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total oio34 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 TACH LAB REPORT.) ug/L (Specify test and methoVes Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? (1) ❑ No (0) pecific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 Q . o u mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 Ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% I certify that. to the best of my knowledge and belief, the information submitted in this report is true, accurate. and complete. and that the laboratory analytical data was produced using approved methods of analysis by a DWR-certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. a vhv e-\ _L- 1 v\ ? l,W k ittee (or Authorized Agent) game and Title - Please print or GW-59 Rev.3-1-2016 Signature of Permittee (or Authorized Agent) -\ S-21 (Date) SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: Facility Name: Avoca LLC Non -Discharge WQ0005910 UIC Permit Name (if different): NPDES Other c� Facility Address: �� >PrVO cc� �av .�. �cl • TYPE OF PERMITTED OPERATION BEING MONITORED •. (street) N 2:1ClS-1 County Bertie ❑ Lagoon ❑ Remediation: Infiltration Gallery (dty) (State) (zip) X Spray Field ❑Remediation: Contact Person: Brian Conner Telephone#: 252-482-2133 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name:Avoca LLC No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: (from Permit) SAMPLING INFORMATION �AA ''��11 WELL ID NUMBER (from Permit): MW " Date sample collected: 31'29 k -a%4 FIELD ANALYSES: If WELL WAS Well Depth: 2.0 ft. Well Diameter: 2 in. pH oo400:(o.s4 units Temp. 00010: 16.2°C DRY at Depth to Water Level 62546: 12• 00 ft. below measuring point Screened Interval: 3 ft. to Z.Oft. Spec. Cond. 00094: µMhos time ofsampling, Measuring Point is Z ft. above land surface Relative M.P. Elevation: ft. Odor 00085: m av1$. check Volume of water pumped/bailed before sampling: Jr Samples for metals were collected unfiltered: ES El gallons --// NO and field acidified: DYES ❑ NO Appearance \Ct�y• here: LABORATORY INFORMATION .//�� Date sample analyzed: 1,\2\' a%A 1k10jr1%4 LaboratoryName: (w)Q,,A 00'Vy�- 1� g-ANV• - co-k Certification No. ,Q PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N oo615 mg/L Pb - Lead olo51 ug/L Coliform: MF Fecal 31616 /100ml- Nitrate (NO3) as N 00620 , Q (p mg/L Zn -Zinc 01092 mg/L Coliform: MF Total 31504 /100ml- Phosphorus: Total as P 00665 Q, 39 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total70300 �0Q mg/L Al -Aluminum oilo5 mg/L PH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 \ O . O O mg/L Ca - Calcium 00916 1-7 • 0 t•{ mg/L Chloride 00940 2-06 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total olo34 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L TTACH LAB REPORT.) (Specify test and methoVyes Sulfate 00945 mg/L Hg - Mercury 7190o ug/L Lab Report Attached? (1) ❑ No (0) pecific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 -I.Goo mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Scwnv,k L--��Ch p\aAk �Au,r Permittee (or Authorized Agent) Name and Ttle - Please print or type i �• 71 Signature of Permittee (or Authofized,.Agent) Lk_X 5-2y GW-59 Rev.3-1-2016 Waypointo ANALYTICAL 114 OAKMONT DRIVE GREENVILLE, NC 27858 AVOCA, LLC (WASTEWATER) MR. BRIAN CONNER P.O. BOX 129 MERRY HILL, NC 27957 Effluent PARAMETERS Drinking Water IDt 37715 Wastewater IDs 10 PHONE (252) 756-6208 FAX (252) 756-0633 ID#: 132 DATE COLLECTED: 03/20/24 DATE REPORTED : 04/10/24 REVIEWED BY: Well N5 Well N7 Well N8 Well N9 Analysis Method Date Analyst Code BOD, nigh r 297 Total Suspended Residue, mg/I 45 Anunonia Nitrogen as N, mg/I 0.06 0.09 <0.04 0.49 Ammonia Nitrogen as N, mg/I Total Igeldahl Nitrogen as N,mg/I 11.25 Nitrate+Nitrite as N, mg/1 (talc) 0.09 Nitrate Nitrogen as N, mg/l 0.07 <0.04 1.03 0.07 Nitrite Nitrogen as N, mg/I 0.02 Total Phosphorus as P, mg/1 19.45 0.06 0.09 3.63 Total Organic Carbon, mg/1 2.78 3.42 13.78 Chloride, mg/l 82 34 32 22 Total Dissolved Residue, nlg/l 1400 440 120 590 Calcium, ug/I 3954 31571 7479 16589 IVlagnesium, ug/l 2011 Sodium, ug/l 189890 Sodium Adsorption Ratio (talc) 19.4 Total Nitrogen, mg/I (talc) 11.34 All QC requirements were not met: r Replicate varied by more than 30%. 03/20/24 KJD 521OB-16 03/21/24 AMC 254OD-15 03/28/24 HMM 350.1 R2-93 <0.04 04/02/24 IIMM 350.1 112-93 03/27/24 HMM 351.2 R2-93 353.2 R2-93 1.52 03/21/24 TRJ 353.2 R2-93 03/20/24 TRJ 353.2 112-93 0.11 03/27/24 HMNI 365.4-74 < 1.00 04/04/24 BLV 531OC-14 31 03/22/24 KJD 4500CLB-11 280 03/21/24 BNC D5907-13 51122 03/25/24 MTM EPA200.7 03/28/24 MTM EPA200.7 03/25/24 MTM EPA200.7 Waypoint,o ANALYTICAL 114 OAKMONT DRIVE GREENVILLE, NC 27858 AVOCA, LLC (WASTEWATER) MR. BRIAN CONNER P.O. BOX 129 MERRY HILL, NC 27957 Well #10 Well #11 PARAMETERS Drinking Hater IDS 37715 Wastewater IDS 30 PHONE (252) 756-6208 FAX (252) 756-0633 ID#: 132 DATE COLLECTED: 03/20/24 DATE REPORTED : 04/10/24 REVIEWED BY: Analysis Method Date Analyst Code Ammonia Nitrogen as N, mg/1 0.06 7.58 03/28/24 HNIM 350.1 R2-93 Nitrate Nitrogen as N, mg/1 9.06 0.06 03/21/24 TRJ 353.2 R2-93 Total Phosphorus as P, mg/1 0.15 0.39 03/27/24 HNIM 365.4-74 Total Organic Carbon, mg/1 1.50 10.00 04/05/24 BLV 531OC-14 Chloride, mg/1 47 28 03/22/24 KJD 4500CLB-11 Total Dissolved Residue, mg/1 350 660 03/21/24 BNC D5907-13 Calcium, 11g/1 28483 17048 03/25/24 MTM EPA200.7 All QC requirements were not mat: r Replicate varied by more than 30%. S7 � w -3a � a FW co Q 0-(U 0 � n w o o D wn 0 Q N n � w w 3 w -o =i ro tD b cb 0) c6G) c o CD CD Q :, t?►o!za D D C G C C Q rn U7 C � C tit �� oo tit J � cn �� Fn N �w H�o i m m � C O w _'2 ni z fi7 G) G) N N p� w oo n LA 3 D D D w m rn m w oy i 33 m TOTAL CHLORINE, mgA Li U U U C7 m OR ug/I AT COLLECTION < m < m < z c n 0o J+ r fl1 TEMPERATURE,IC 0 0 0 0 < X i"J ATCOLLECTION tin o O tzn #OFCONTAINERS 00 ;r $OD > ro S 1J •;r, r.:':i � + -' � Ai111110111a Nitro. 0ro TKN 0 tl C f ; Nilrate+Nitrate 0 Di Nitrate ro m m m - '<s Nitrite a ro IS J s;; s<- ;:€ ��`;� ; ; ;z T. Phosphorus 'ti ToC n ro JCS C mmv- << << Bromide G7 ' a', TDS Metals > SAR Total Nitrogen � D =b cn z PARAMETERS/TESTS Y o n o 0 r U) m m � G7 �o 0 -n c� w r y m m OT, �z m m m n 0 c: -u z i z o to 0 z �o N C-) m m n m �G "'i to o v g c� m o m m m m c 3m 00 o �' o _ _ Z -< m :zm CS) D N = Z Z p ZZcn W o z mm m :30 Z O O D o z z a' y N �n n ;z D Z O m a 0, r'a SG Orlando, FL t t The iestilts set forth herein ate provided by SGS North Ainedea Ilie. e-Hardcopy 2.0 AWomaled Report j Technical Report for Waypoint Analytical AVOCA LLC; Merg Hill, NC 132 SGS Job Number- FC14615 Sampling Date: 03/20/24 Report to: Environment 1, Inc PO Box 7085 Greenville, NC 27835 abaynor@wpacolp. com TTN: Ann Brown Total number of pages in report: 15 'rest results contained within Uds data package meet (lie requirements of die National Environmental Laboratory Accreditation Program and/or state specific certification programs as applicable unless noted In the narrative, connuents or footnotes. Norm Farmer Technical Director Client Service contact: Dwayne Foster 407-425-6700 Certifications: FL(@83510), LA(03051), 1(S(E-10327), NC(573), NJ(FL002), NY(12022), SC(96038001) DoD ELAP(ANAR L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68.03573), VA(460I77), AL, AK, AR, CT, IA, KY, MA, MI. MS, NO, NH, NV, OK, OR, IL, UT, VT, WA, WI, WV This report shall not be reproduced, except In Its entirely, without the written approval of SGS. Test results relate array to samples anai}ted. SGS Nordt Arnerica Inc. • 4405 Vineland Road - Suite C-15 - Orlando, FL 32811 • tel. 407-425.6700 SGS is the sole oultioniy for audwrizlug edlfs or modltha(tons to this (IOCUtnent Please share your idols about Unauthortred modification ofthis report is strictly prohibited ho\\ we can serve you better at Review stand.0 d icrins nt iltt]1 //AVSR Sg5 CUm/en/Ilin1S-and-WndltlA)nS Ell,% US CustomcrC'arc iisgs cote 1 of 16 FC14616 Sections: Fable of Contents Section1: Sample Summary..............................1.................................................................... 3 Section2: Summary of Hits.................................................................................................... 4 Section3: Sample Results....................................................................................................... 5 3.1: FC 14615-1. EFFLUENT.............................................................................................. 6 3.2: FC 14615 2: WELL 5................................................................................................... 7 3.3: FC14615-3: WELL 7.................................................................................................... 8 3,4: FC14615-4: WELL 8.................................................................................................... 9 3.---,: FC14615-5: WELL 9.................................................................................................... 10 3.6: FC14615-6: WELL 10.................................................................................................. 11 3.7: FC14615-7: WELL 11................................................................................................. 12 Section4: Misc. Forms............................................................................................................ 13 4.1: Chain of Custody............................................................................... 14 2of15 FC 14615 SGS Nm•t11 America Inc. Sample Summary Waypoint Analytical AVOCA LLC; Merry Hill, NC Project No: 132 Job No: FC14615 Sample Collected Matrix Client Number Date Time By Received Code Type Sample ID FC14615-1 f 03/20/24 10:05 RB 04/06/24 AQ Water FC14615-2 03/20/24 10:30 RB 04/06/24 AQ Water FC14615-3 03/20/24 11:45 RB 04/06/24 AQ Water FC14615-4 03/20/24 11:20 RB 04/06/24 AQ Water FC14615-5 03/20/24 10:45 RB 04/06/24 AQ Water FC14615-6 03/20/24 11:35 RB 04/06/24 AQ Water FC14615-7 03/20/24 09:55 RB 04/06/24 AQ Water EFFLUENT CIA ICI WELL 7 WELL 8 WELL 9 WELL 10 WELL II AM 3of15 FC14616 Summary of Hits Job Number: FC14615 Account: Waypoint Analytical Project: AVOCA LLC; Merty Hill, NC Collected: 03/20/24 Lab Sample ID Client Sample ID Result/ Analyte Qua[ RL MDL Units Method Page I of 1 IM FC14615-1 EFFLUENT Bromide 21.5 5.0 mg/l EPA 300/SW846 9056A FC14615-2 WELL 5 Bromide 5.4 2.5 mg/l EPA 300/SW846 9056A FC14615-3 WBLL 7 Bromide 12.3 0.50 mg/l EPA 300/SW846 9056A FC14615-4 WELL 8 Bromide 6.2 2.5 mg/l EPA 300/SW846 9056A k' FC14615-5 WELL 4 No hits reported in this sample. I FC14615-6 WELL 10 E No hits reported in this sample. i FC14615-7 WELL 11 Bromide 9.1 2.5 mg/l EPA 300/SW846 9056A ' 4of15 FC14616 Orlando, FL Sample Results Report of Analysis -_- I 5 of 15 FC14616 SGS North America Inc. Report of Analysis ;lient Sample ID: EFFLUENT ,ab Sample ID: FC14615-1 Date Sampled: 03/20/24 datrix: AQ - Water Date Received: 04/06/24 Percent Solids: n/a 'roject: AVOCA LLC; Merry Hill, NC Page 1 of 1 P General Chemistry Analyte Result RL Units DF Analyzed By Method Bromide 21.5 5.0 mg/l 10 04/06/24 21:38 GN EPA 3001SW846 9056A RL = Reporting Limit Is 6of16 --- - FGI M6 SGS Nortli America Inc. Report of Analysis CIient Sample ID: WELL 5 Lab Sample ID: FC14615-2 Date Sampled: 03/20/24 Matrix: AQ - Water Date Received: 04/06/24 Percent Solids: n/a Project: AVOCA LLC; Merry Hill, NC Page 1 of 1 N General Chemistry Analyte Result RL Units DF Analyzed By Method Bromide 5.4 2.5 mg/l 5 04/06/24 22:42 CN EPA 360MV846 9056A RL = Reporting Limit 7of15 S I C14615 SGS North America Inc. Report of Analysis Client Sample ID: WELL 7 Lab Sample ID: FC14615-3 Date Sampled: 03/20/24 Matrix: AQ - Water Date Received: 04/06/24 Percent Solids: n/a Project: AVOCA LLC; Merry Hilt, NC Page 1 of 1 w General Chemistry Analyte Result RL Units DF Analyzed By Method Bromide 1.213 0.50 mg/l 1 04/07/24 00:27 GN EPA 3001SW840 9050A RL = Reporting Limit 19" I Bof15 Fc14ets SGS North America Inc. Report of Analysis Client Sample ID: WELL 8 Lab Sample ID: FC14615-4 Date Sampled, 03/20/24 Matrix: AQ - Water Date Received: 04/06/24 Percent Solids. u/a Project: AVOCA LLC; Mercy Hill, NC Page 1 of 1 General Chemistry Analyte Result RL Units Dr Analyzed By Method Bromide 6.2 2.5 mg/l 5 04/07/24 00:49 GN EPA 3001SWtt40 9056A RL = Reporting Limit M." 9of15 FC 14015 SGS Nortit America Inc. Report of Analysis Client Sample ID: WELL 9 Lab Sample ID: FC14015-5 Date Sampled: 03/20/24 Matrix: AQ - Water Date Received: 04/06/24 Percent Solids: n/a Project: AVOCA LLC; Meiiy Hill, NC Page 1 of 1 General Chemistry Analyte Result RL Units DF Analyzed By Method Bromide < 0.50 0.50 mg/l 1 04/07/24 01:10 GN EPA 300/sW840 9050A RL = Reporting Limit 10 of 15 FC14616 SGS Nordi America Inc. Report of Analysis ;Bent Sample ID: WELL 10 ,ab Sample ID: FC14615-0 Date Sampled: 03/20/24 Matrix: AQ - Water Date Received: 04/06/24 Percent Solids: n/a Toject: AVOCA LLC; Merry Hill, NC Page 1 of 1 General Chemistry Analyte Result RL [snits DF Analyzed By Method Bromide < 0.50 0.50 Ing/I 1 04/07/24 01:31 GN EPA 300/SW846 9056A RL = Reporting Limit In, 11 of 15 - bba FC 14616 SGS Nordi America Inc. Report of Analysis Client Sample ID: WELL 11 Lab Sample ID: FC14615-7 Date Sampled: 03/20/24 Matrix: AQ - Water Date Received: 04/06/24 Percent Solids, n/a Project: AVOCA LLC; Meny Hill, NC General Chemistry Analyte Result RL Units DID Bromide 9.1 2.5 mg/I 5 RL = Reporting Limit Page 1 of 1 P Analyzed By Method 04/07/24 01:52 GN EPA 300/SW846 9056A In ' 12 of 15 FC14M r 1 i Orlando, FL Misc. Forms Custody Documents and Other Forms Includes die following where applicable: • Chain of Custody �i - 13 of 15 FC14615 WAypoint© CHAIN OF CUSTODY RECORD ji,/ WoypohuAnolyttinl-CreenvillN° �� �� at j 45Pnge of — ,vww 1VaypulnlAnalylie,l Coln Phone(252) 7566208• ru(252) 7560633 CLIENT: t32 Week•15 VOCA, LT.0 (WASTEWATER) IR. BRIAN CONNBR .0. BOX 129 rERRY HILL NC 27957 �52)492.2133 COLLECTION Ij CHLORINE ❑ UV ❑ NONE -- CHLORINE CHECK (LAO) aoSmgA.•Yes (vf or No lM N n/ n V ' pHCHECK(SU)(LABJ P P P P P P P P P P r P P CONIAINERTYPE,PIG A A C C C A A C C A AlA A A CHEMICALPRESERVATION A•NONE D NACH B•t410, E-HCL C HSO, F-ZINGACETATEMA01t G NANOSULFA3E ` tz z C� SAVPLELOCATION DATE Effluent § 3 I C ( ! j � i 4 # CSPS9RGATlOk ❑ WASFEVIATFAQ(AOESJ ❑ DfiI1,WGWATF.A � DtvRA;IY ❑ SOUDWASTESECRON Well15 Z 3-30 ]{ t03a Ib i O FF hi 9 weu17 3 3-ao4q INN 1$ f c t ( a ^ � � � WeD15 � 3•aax! fid0 16,8 � ; t i ��r,,�' t 'rVe11 19 1-30.14 10`\S 15,E #� 1 L� }� T i i t Well 910 3 do 4,1 1j3S III 4 l I i'`z-CHAIN OFCUSTODY(SEAL) MAINTAINED DORING IPtAENTfOEUVERY l r't Y N SAMMS COLLECTED BY SUBBED TO SGS (� &usPLESRECErlEotNtAeAr_j_,2 _°C BAT�`k COW(ENTS, SAMPLES RECEIVEDON ICE NO We11111 7 3�•?'( 495� 152 g `% 11IM& MENr R£L1VQ(r5tiE00Y(SG}(SAVPLERJ DATURNf s•aa a4 4l'l5' RECEIVED BY(w � RE(L 6 (SKL) r( AlE/R4 09 D Y(M) CUT 4E 31)" 03 0 OBY ) �OAT57M -YLf 20 EGG : 4 6 ay q 15 fu,T V ; ' " PLEASE RFAD fnstrucgons for completing this form on the reverse side. 3 a1Q 1 Sampler must place a'C' forcomposite sample ora'G' for F0111— i Grab sample lnthe btocksabove for each parameter requested FC14615: Crain of Custody Page 1 of Z 1Aof15 FC 14615 3CS - Orlando Sample Receipt Summary Jab Number fc14615 Client: WAYPOINT Project: AVOCA, LLC (WASTEWATER) Date f Time Received: 4/6/2024 9 150o AM Delivery Method' FEDEX Alrbill A's• 712766968304 Cooler Temps (Raw Measured) IC: Cooler 1 (3 2). Cooler Temps (Corrected)1C, Cooler 1 (4 2). Cooler IInformation Y or N SamnleInformation Y or N NIA 1 Custody Seals Present © ❑ 1 Sample labels present on bottles © ❑ 2 Custody Seals Intact to ❑ 2 Samples presented property ® ❑ 3 Temp criteria achieved W Cl 3 Sufllclent volume/containers recYd for analysis ® ❑ 4 Cooler temp verification IR Gun 4 Condition of sample Intact 5 Cooler media Ice (Bag) 5 Sample recv d velbin HT ❑e 0 Trip Wank Information Y or N (JjA 6 DalesMmesltDs on COG match sample label 10 ❑ 1 VOCs have headspac@ El ❑ Q 1 Trip Blank present 1 cooler 8 Bottles received forrinspeafied tests ❑ 10 2 Trip Blank listed COG ❑ El R) 9 Compostbng instfuctlons clear (] ❑ W or S N/A 19 Voa Sort KIWJars received past 48hrs? ❑ ❑ fid 3 Type of TO Received D ❑ (] 1t.16 Bonds Jar Received? ❑ ❑ 12 Residual Chlonne Present? ❑ ❑ Gil Min Infonnall4n Number of Encores 25 Gram 5 Gram Numberol Lab Filtered bielals Test Slrp Lot #a pH 0-3 220422 p" 10.12 Other JSpeaty) pH„-1 0- 120 222221 Residual Chlorine Test Strip Lot 0 Comments Sample Receipt Summary 112723 EK Teehmc+an ZANEB Date 4/6/2024 12 29 30 PM Reviewer Dale FC14615: Chain of Cl.Jstody Page 2 of 2 ij��`` ' 15oF15 _ iG 1 F014616