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HomeMy WebLinkAboutWI0500181_Inspection Letter_2100 Dimmocks Mill Rd-FINAL June 25, 2024 Mr. William L. Dyson 2100 Dimmocks Mill Road Hillsborough, NC 27278 Subject: Geothermal Well Renewal Permit # WI0500181 Summary of Inspection and Sampling on March 14, 2024 Mr. Dyson: In support of your request for renewal of the above-referenced geothermal well permit, Tyler Clark from the Division of Water Resources Performed an inspection and collected samples from the well influent and effluent on March 14, 2024. The permittee, William Dyson, was present during the inspection, and identified the location of the well. The well is used for geothermal heat exchange and water supply. During the inspection, the geothermal system was in operation. The well and exposed well piping was covered with a fiberglass rock and was in good condition, with no leaks observed. The wellhead appeared to be secure. No well identification plate was observed. The influent and effluent piping was not labeled, but the inspector labeled them in the field prior to taking photographs (Attachment 1). Influent (W1-I) and effluent (W1-E) water samples were collected from the sample ports at the well head. Both sample ports were disinfected with a 70% isopropyl solution prior to sampling. Samples were collected directly from the sample ports following disinfection. Groundwater quality (temperature, pH, dissolved oxygen, conductivity, and salinity) was measured in the field. The measurements are relatively similar between the well effluent and the system discharge. Samples were delivered to the Division of Water Resources Laboratory on March 14, 2024. Laboratory analytical results were returned on February 13, 2024 (Attachment 3). Concentrations of the constituents analyzed were below the North Carolina Groundwater Standards (NCAC 15A.02L). The concentration of the constituents analyzed were relatively similar between the influent and effluent samples. The concentration values for arsenic were slightly over half the North Carolina Groundwater Standards (NCAC 15A.02L). The 2L limit is 10 mg/L and your well showed 5.6 and 6 mg/L for both the effluent and influent samples. Arsenic is a naturally occurring element and is well-known to occur in elevated levels in Orange County. Neither the field measurements nor the laboratory results suggest a concern regarding groundwater quality. Based on the inspection of the well head, and the laboratory analytical results for the samples collected, the continued use of the well for geothermal heat exchange and consumption is appropriate. DocuSign Envelope ID: D6C40437-BE6D-4CBB-9B53-EEE75CD3BE66 William L. Dyson, WI0500181 June 26,2024 Page 2 of 2 We appreciate your assistance during the inspection, and if you have any questions regarding this report or its conclusions, please contact Michael Hall at (919) 791-4237 or via email at michael.hall@deq.nc.gov. Sincerely, Michael Hall, Regional Supervisor Water Quality Regional Operations Section Raleigh Regional Office Division of Water Resources, NCDEQ Enclosure Attachment 1 – Photograph Attachment 2 – Laboratory Analytical Reports cc: Laserfiche Attachment 1: Well Head details DocuSign Envelope ID: D6C40437-BE6D-4CBB-9B53-EEE75CD3BE66 PO Number # Loc. Descr.:2100 DIMMOCK MLL ROAD Loc. Type:Influent Collector:T CLARK Collect Date:03/14/2024 Collect Time:10:20 Date Received:03/14/2024 Time Received:13:30 Location ID:WI0500181_1 County:Orange Region:Raleigh Labworks LoginID TASCENZO1Sample Matrix:GROUNDWATER Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results VisitID Sample Depth RROReport To NEURiver Basin 05/06/2024 Emergency COC Yes/No Sample ID:AD17880 5/6/24Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. Hand DeliveredDelivery Method ROUTINEPriority AD17880 Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by LAB MSWIFT°CSample temperature at receipt by lab 3/14/241.7 MIC SM 9222 D-1997 JJURGEVICHCFU/100mlB2Coliform, MF Fecal in liquid 3/14/2411 SM 9222 B-1997 JJURGEVICHCFU/100mlB2Coliform, MF Total in liquid 3/14/2411 NUT EPA 353.2 REV 2 ALWILLIAMSmg/L as NUNO2+NO3 as N in liquidE701177 4/3/240.03 0.03 WET EPA 300.0 rev2.1 ALWILLIAMSmg/LUBromide24959-67-9 3/19/240.4 0.4 EPA 300.0 rev2.1 ALWILLIAMSmg/LChloride16887-00-6 3/19/2412.7 EPA 300.0 rev2.1 ALWILLIAMSmg/LFluoride16984-48-8 3/19/240.4 0.53 EPA 300.0 rev2.1 ALWILLIAMSmg/LPSulfate14808-79-8 3/19/2410110 SM 2540 C-1997 ALWILLIAMSmg/LTotal Dissolved Solids in liquid 3/19/2412283 MET EPA 200.7 Rev4.4 JJURGEVICHug/LAl by ICP7429-90-5 3/25/245069 EPA 200.8 Rev5.4 JJURGEVICHug/LAs by ICPMS7440-38-2 3/25/242.0 5.6 EPA 200.7 Rev4.4 JJURGEVICHmg/LPCa by ICP7440-70-2 3/25/241.0 67 EPA 200.8 Rev5.4 JJURGEVICHug/LUCr by ICPMS7440-47-3 3/25/245.0 5.0 EPA 200.8 Rev5.4 JJURGEVICHug/LCu by ICPMS7440-50-8 3/25/242.0 7.1 EPA 200.7 Rev4.4 JJURGEVICHug/LUFe by ICP7439-89-6 3/25/245050 SM 2340B-1997 JJURGEVICHmg/LHardness by Calculation 4/3/241.0 180 EPA 200.7 Rev4.4 JJURGEVICHmg/LK by ICP7440-09-7 3/25/240.10 0.56 EPA 200.7 Rev4.4 JJURGEVICHmg/LMg by ICP7439-95-4 3/25/240.10 2.7 EPA 200.7 Rev4.4 JJURGEVICHug/LUMn by ICP7439-96-5 3/25/241010 EPA 200.7 Rev4.4 JJURGEVICHmg/LNa by ICP7440-23-5 3/25/240.10 21 EPA 200.8 Rev5.4 JJURGEVICHug/LUNi by ICPMS7440-02-0 3/25/242.0 2.0 EPA 200.8 Rev5.4 JJURGEVICHug/LUPb by ICPMS7439-92-1 3/25/242.0 2.0 EPA 200.8 Rev5.4 JJURGEVICHug/LPZn by ICPMS7440-66-6 3/25/24100640 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. DocuSign Envelope ID: D6C40437-BE6D-4CBB-9B53-EEE75CD3BE66 AD17880Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by MIC:Total Coliform-B2-Counts from all filters = 0. MIC:Fecal Coliform-B2-Counts from all filters = 0. Sample Comments NCDEQ-WSS-Chemistry Lab Data Qualifiers A1 The reported value is an average, where at least one result is qualified with a “U”. The PQL is used for the qualified result(S) to calculate the average. B1 Coliform-Countable membranes with less than 20 colonies. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B2 Coliform-Counts from all filters were zero. B3 Coliform-Countable membranes with more than 60 or 80 colonies. The value reported is calculated using the count from the smallest volume filtered and reported as a greater than ">" value. B4 Coliform-Filters have counts of both >60 or 80 and <20. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B5 Coliform-Too many colonies were present; too numerous to count (TNTC). TNTC is generally defined as >150 colonies. B6 Coliform-Estimated Value. Blank contamination evident. B7 Coliform-Many non-coliform or non-enterococcus colonies or interfering non-coliform or non-enterococcus growth present. In this competitive situation, the reported value may under-represent actual density. BB1 MPN-No wells or tubes gave a positive reaction. Value based upon the appropriate MPN Index and reported as a less than “<” value. BB2 MPN-All wells or tubes gave positive reactions. Value based upon the MPN Index and reported as a greater than “>” value. C Total residual chlorine was present in sample upon receipt in the laboratory; value is estimated. G1 BOD-The dissolved oxygen (DO) depletion of the dilution water blank exceeded 0.2 mg/L. G2 BOD-The bacterial seed controls did not meet the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G3 BOD-No sample dilution met the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G4 BOD-Evidence of toxicity. This is generally characterized by a significant increase in the BOD value as the sample concentration decreases. The reported value is calculated from the highest dilution representing the maximum loading potential and G5 BOD-The glucose/ glutamic acid standard exceeded the range of 198 ± 30.5 mg/L. G7 BOD-Less than 1 mg/L DO remained for all dilutions set. The reported value is an estimated greater than value and is calculated for the dilution using the least amount of sample. G8 BOD-Oxygen usage is less than 2 mg/L for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. G9 BOD-The DO depletion of the dilution water blank produced a negative value. J1 Surrogate recovery limits have been exceeded. J10 Unidentified peak; estimated value. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. DocuSign Envelope ID: D6C40437-BE6D-4CBB-9B53-EEE75CD3BE66 AD17880Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by J11 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when J12 The calibration verification did not meet the calibration acceptance criterion for field parameters. J2 The reported value failed to meet the established quality control criteria for either precision or accuracy. J3 The sample matrix interfered with the ability to make any accurate determination. J4 The data is questionable because of improper laboratory or field protocols (e.g., composite sample was collected instead of grab, plastic instead of glass container, the sample's extraction batch did not include a LCS/MS/MSD, etc.). J5 Temperature limits exceeded (samples frozen or >6°C) during transport or not verifiable (e.g., no temperature blank provided): non-reportable for NPDES compliance monitoring. J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. J7 This qualifier is used to identify analyte concentration exceeding the upper calibration range of the analytical instrument/method. The reported value should be considered estimated. J8 Temperature limits exceeded (samples frozen or >6ºC) during storage, the data may not be accurate. J9 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. M Sample and duplicate results are "out of control". The sample is non-homogenous (e.g., VOA soil). The reported value is the lower value of duplicate analyses of a sample. N1 Presumptive evidence and estimated value. The component has been tentatively identified base on mass spectral library. N2 There is an indication that the analyte is present, but quality control requirements for confirmation were not met (i.e., presence of analyte was not confirmed by alternate procedures). N3 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. This code is not routinely N4 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when an MDL has not N5 The component has been tentatively identified based on a retention time standard. P Elevated PQL* due to matrix interference and/or sample dilution. Q1 Holding time exceeded prior to receipt by lab. Q2 Holding time exceeded following receipt by lab. S Not enough sample provided to prepare and/or analyze a method-required matrix spike (MS) and/or matrix spike duplicate (MSD). U Indicates that the analyte was analyzed for but not detected above the reported practical quantitation limit*. The number value reported with the "U" qualifier is equal to the laboratory's practical quantitation limit*. U, J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. UU Indicates that the analyte was not detected by a screen analysis. The number value was determined by a one-point estimation at the PQL. V Indicates the analyte was detected in both the sample and the associated method blank. Note: The value in the blank shall not be subtracted from the associated samples. X1 Sample not screened for this compound. X2 Sampled, but analysis lost or not performed-field error. X3 Sampled, but analysis lost or not performed-lab error. Y Elevated PQL* due to insufficient sample size. Z1 Inability to analyze the sample. Z2 Questions concerning data reliability. J13 Standards used for this analyte are from an uncertified source. These are the only standards currently available for the analyte. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 3 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. DocuSign Envelope ID: D6C40437-BE6D-4CBB-9B53-EEE75CD3BE66 PO Number # Loc. Descr.:2100 DIMMOCKS MILL ROAD Loc. Type:Effluent Collector:T CLARK Collect Date:03/14/2024 Collect Time:10:10 Date Received:03/14/2024 Time Received:13:30 Location ID:WI0500181_E County:Orange Region:Raleigh Labworks LoginID TASCENZO1Sample Matrix:GROUNDWATER Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results VisitID Sample Depth RROReport To NEURiver Basin 05/06/2024 Emergency COC Yes/No Sample ID:AD17881 5/6/24Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. Hand DeliveredDelivery Method ROUTINEPriority AD17881 Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by LAB MSWIFT°CSample temperature at receipt by lab 3/14/241.7 MIC SM 9222 D-1997 JJURGEVICHCFU/100mlB2Coliform, MF Fecal in liquid 3/14/2411 SM 9222 B-1997 JJURGEVICHCFU/100mlB2Coliform, MF Total in liquid 3/14/2411 NUT EPA 353.2 REV 2 ALWILLIAMSmg/L as NUNO2+NO3 as N in liquidE701177 4/3/240.03 0.03 WET EPA 300.0 rev2.1 ALWILLIAMSmg/LUBromide24959-67-9 3/19/240.4 0.4 EPA 300.0 rev2.1 ALWILLIAMSmg/LChloride16887-00-6 3/19/2412.7 EPA 300.0 rev2.1 ALWILLIAMSmg/LFluoride16984-48-8 3/19/240.4 0.62 EPA 300.0 rev2.1 ALWILLIAMSmg/LPSulfate14808-79-8 3/19/2410130 SM 2540 C-1997 ALWILLIAMSmg/LTotal Dissolved Solids in liquid 3/19/2412315 MET EPA 200.7 Rev4.4 JJURGEVICHug/LAl by ICP7429-90-5 3/25/245073 EPA 200.8 Rev5.4 JJURGEVICHug/LAs by ICPMS7440-38-2 3/25/242.0 6.0 EPA 200.7 Rev4.4 JJURGEVICHmg/LPCa by ICP7440-70-2 3/25/241.0 74 EPA 200.8 Rev5.4 JJURGEVICHug/LUCr by ICPMS7440-47-3 3/25/245.0 5.0 EPA 200.8 Rev5.4 JJURGEVICHug/LCu by ICPMS7440-50-8 3/25/242.0 8.5 EPA 200.7 Rev4.4 JJURGEVICHug/LUFe by ICP7439-89-6 3/25/245050 SM 2340B-1997 JJURGEVICHmg/LHardness by Calculation 4/3/241.0 190 EPA 200.7 Rev4.4 JJURGEVICHmg/LK by ICP7440-09-7 3/25/240.10 0.57 EPA 200.7 Rev4.4 JJURGEVICHmg/LMg by ICP7439-95-4 3/25/240.10 2.3 EPA 200.7 Rev4.4 JJURGEVICHug/LUMn by ICP7439-96-5 3/25/241010 EPA 200.7 Rev4.4 JJURGEVICHmg/LNa by ICP7440-23-5 3/25/240.10 22 EPA 200.8 Rev5.4 JJURGEVICHug/LUNi by ICPMS7440-02-0 3/25/242.0 2.0 EPA 200.8 Rev5.4 JJURGEVICHug/LUPb by ICPMS7439-92-1 3/25/242.0 2.0 EPA 200.8 Rev5.4 JJURGEVICHug/LPZn by ICPMS7440-66-6 3/25/24100690 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. DocuSign Envelope ID: D6C40437-BE6D-4CBB-9B53-EEE75CD3BE66 AD17881Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by MIC:Total Coliform-B2-Counts from all filters = 0. MIC:Fecal Coliform-B2-Counts from all filters = 0. Sample Comments NCDEQ-WSS-Chemistry Lab Data Qualifiers A1 The reported value is an average, where at least one result is qualified with a “U”. The PQL is used for the qualified result(S) to calculate the average. B1 Coliform-Countable membranes with less than 20 colonies. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B2 Coliform-Counts from all filters were zero. B3 Coliform-Countable membranes with more than 60 or 80 colonies. The value reported is calculated using the count from the smallest volume filtered and reported as a greater than ">" value. B4 Coliform-Filters have counts of both >60 or 80 and <20. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B5 Coliform-Too many colonies were present; too numerous to count (TNTC). TNTC is generally defined as >150 colonies. B6 Coliform-Estimated Value. Blank contamination evident. B7 Coliform-Many non-coliform or non-enterococcus colonies or interfering non-coliform or non-enterococcus growth present. In this competitive situation, the reported value may under-represent actual density. BB1 MPN-No wells or tubes gave a positive reaction. Value based upon the appropriate MPN Index and reported as a less than “<” value. BB2 MPN-All wells or tubes gave positive reactions. Value based upon the MPN Index and reported as a greater than “>” value. C Total residual chlorine was present in sample upon receipt in the laboratory; value is estimated. G1 BOD-The dissolved oxygen (DO) depletion of the dilution water blank exceeded 0.2 mg/L. G2 BOD-The bacterial seed controls did not meet the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G3 BOD-No sample dilution met the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G4 BOD-Evidence of toxicity. This is generally characterized by a significant increase in the BOD value as the sample concentration decreases. The reported value is calculated from the highest dilution representing the maximum loading potential and G5 BOD-The glucose/ glutamic acid standard exceeded the range of 198 ± 30.5 mg/L. G7 BOD-Less than 1 mg/L DO remained for all dilutions set. The reported value is an estimated greater than value and is calculated for the dilution using the least amount of sample. G8 BOD-Oxygen usage is less than 2 mg/L for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. G9 BOD-The DO depletion of the dilution water blank produced a negative value. J1 Surrogate recovery limits have been exceeded. J10 Unidentified peak; estimated value. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. DocuSign Envelope ID: D6C40437-BE6D-4CBB-9B53-EEE75CD3BE66 AD17881Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by J11 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when J12 The calibration verification did not meet the calibration acceptance criterion for field parameters. J2 The reported value failed to meet the established quality control criteria for either precision or accuracy. J3 The sample matrix interfered with the ability to make any accurate determination. J4 The data is questionable because of improper laboratory or field protocols (e.g., composite sample was collected instead of grab, plastic instead of glass container, the sample's extraction batch did not include a LCS/MS/MSD, etc.). J5 Temperature limits exceeded (samples frozen or >6°C) during transport or not verifiable (e.g., no temperature blank provided): non-reportable for NPDES compliance monitoring. J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. J7 This qualifier is used to identify analyte concentration exceeding the upper calibration range of the analytical instrument/method. The reported value should be considered estimated. J8 Temperature limits exceeded (samples frozen or >6ºC) during storage, the data may not be accurate. J9 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. M Sample and duplicate results are "out of control". The sample is non-homogenous (e.g., VOA soil). The reported value is the lower value of duplicate analyses of a sample. N1 Presumptive evidence and estimated value. The component has been tentatively identified base on mass spectral library. N2 There is an indication that the analyte is present, but quality control requirements for confirmation were not met (i.e., presence of analyte was not confirmed by alternate procedures). N3 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. This code is not routinely N4 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when an MDL has not N5 The component has been tentatively identified based on a retention time standard. P Elevated PQL* due to matrix interference and/or sample dilution. Q1 Holding time exceeded prior to receipt by lab. Q2 Holding time exceeded following receipt by lab. S Not enough sample provided to prepare and/or analyze a method-required matrix spike (MS) and/or matrix spike duplicate (MSD). U Indicates that the analyte was analyzed for but not detected above the reported practical quantitation limit*. The number value reported with the "U" qualifier is equal to the laboratory's practical quantitation limit*. U, J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. UU Indicates that the analyte was not detected by a screen analysis. The number value was determined by a one-point estimation at the PQL. V Indicates the analyte was detected in both the sample and the associated method blank. Note: The value in the blank shall not be subtracted from the associated samples. X1 Sample not screened for this compound. X2 Sampled, but analysis lost or not performed-field error. X3 Sampled, but analysis lost or not performed-lab error. Y Elevated PQL* due to insufficient sample size. Z1 Inability to analyze the sample. Z2 Questions concerning data reliability. J13 Standards used for this analyte are from an uncertified source. These are the only standards currently available for the analyte. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 3 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. DocuSign Envelope ID: D6C40437-BE6D-4CBB-9B53-EEE75CD3BE66