NC0087629_Renewal Application_20160202

PAT MCCRORY
DONALD R. VAN DER VAART
Water Resources S. JAY ZIMMERMAN
ENVIRONMENTAL QUALITY 1)Ii-cctor
February 2, 2016
Ethan Caldwell
NCDOT
1558 Mail Service Center
Raleigh, NC 27699
Subject: Acknowledgement of Permit Renewal
Application No.NC0087629
Asphalt Testing Site No. 6-48
Chatham County
Dear Permittee:
The Water Quality Permitting Section has received your permit renewal application on January 2,
2016. A member of the NPDES Unit will review your application. They will contact you if additional
information is required to complete your permit renewal. Per G.S. 150B-3 your current permit does not
expire until permit decision on the application is made. Continuation of the current permit is contingent on
timely and sufficient application for renewal of the current permit. Please respond in a timely manner to
requests for additional information necessary to complete the permit application.
If you have any additional questions concerning renewal of the subject permit, please contact Derek
Denard at 919-807-6307 or [e-mail].
Sincerely,
W rew Ttieo2O-rot,
Wren Thedford
Wastewater Branch
cc: Central Files
NPDES
Raleigh Regional Office
State of North Carolina I Environmental Quality I Water Resources
1617 Mail Service Center I Raleigh,North Carolina 27699-1617
919-807-6300

NPDES PERMIT APPLICATION - SHORT FORM C - GW
For discharges associated with groundwater treatment facilities.
Mail the complete application to:
N. C. Department of Environment and Natural Resources
Division of Water Quality / NPDES Unit
1617 Mail Service Center, Raleigh, NC 27699-1617
NPDES Permit Number NC0087629
If you are completing this form in computer use the TAB key or the up - down arrows to move from one
field to the next. To check the boxes, click your mouse on top of the box. Otherwise,please print or type.
1. Contact Information:
Owner Name NC Department of Transportation c/o Ethan Caldwell
Facility Name Asphalt Testing Site No. 6-48
Mailing Address Roadside Environmental Unit, 1558 Mail Service Center
City Raleigh
State / Zip Code NC/27699 •
Telephone Number [phone]
Fax Number ( )
e-mail Address ejcaldwellO)ncdot.gov
RECEIVED/NCDEQ/DWR
FEB 0 2 2016
2. Location of facility producing discharge:
Water Quality
Check here if same as above ❑ Permitting Section
Street Address or State Road 240 Sugar Lake Rd.
City Pittsboro
State / Zip Code NC /27312
County Chatham
3. Operator Information:
Name of the firm, consultant or other entity that operates the facility. (Note that this is not referring to the
Operator in Responsible Charge or ORC)
Name Hart and Hickman, PC c/o Jeff Albano
Mailing Address 2923 S. Tryon St Suite 100
City Charlotte
State / Zip Code NC/ 28203
Telephone Number [phone]
Fax Number ( )
4. Ownership Status:
Federal ❑ State ® Private El Public 0
Page I of 3 C-GW 03/05

•
NPDES PERMIT APPLICATION - SHORT FORM C - GW
For discharges associated with groundwater treatment facilities.
5. Products recovered:
Gasoline ❑ Diesel fuel ❑ Solvents ® Other
6. Number of separate discharge points: 1
Outfall Identification number(s) Outfall 001
7. Frequency of discharge: Continuous ® Intermittent ❑
If intermittent:
Days per week discharge occurs: Duration:
8. Treatment System Design flow 0.0144 MGD
9. Name of receiving stream(s) (Provide a map showing the exact location of each outfall, including
latitude and longitude):
unnamed tributary to the Haw River [stream segment 16-(36.7)]
10. Please list all additives to the treatment system, including chemicals or nutrients, that have
the potential to be discharged.
none RECEIVED/NCDEQ/DWR
FEB 0 2 2016
Water Quality
Permitting Section
11. Is this facility located on Indian country? (check one)
Yes ❑ No ❑
12. Additional Information
All applicants (including renewals):
• A USGS topographical map (or copy of the relevant portion) which shows all outfalls
> A summary of the most recent analytical results (effluent data, if available) containing the
maximum values for each chemical detected
NEW Applicants only:
• Engineering Alternative Analysis
• Description of remediation treatment system components, capacities, and removal efficiency
for detected compounds.
.. If the treatment system will discharge to a storm sewer, written approval from the
municipality responsible for the sewer.
• A list of any chemicals found in detectable amounts at the site, with the maximum observed
concentration reported for each chemical (the most recent sample must be collected less
than one year prior to the date of this application)
• For petroleum-contaminated sites-Analyses for Volatile Organic Compounds (VOC) should
be performed. Analyses for any fuel additives likely to be present at the site and for phenol
and lead should also be performed.
> For sites contaminated with solvents or other contaminants - EPA Method 624/625
analysis should be performed.
Page 2 of 3 C-GW 03/05

NPDES PERMIT APPLICATION - SHORT FORM C - GW
For discharges associated with groundwater treatment facilities.
13. Applicant Certification
I certify that I am familiar with the information contained in the application and that to the
best of my knowledge and belief such information is true, complete, and accurate.
Ethan J Caldwell Environmental Operations Engineer Ill
Printed name of Person Signing Title
/ (7 C//J'2 c l C
Signature of Applicant Date
North Carolina General Statute 143-215.6 (b)(2) provides that: Any person who knowingly makes any false
statement representation, or certification in any application, record, report, plan, or other document files or
required to be maintained under Article 21 or regulations of the Environmental Management Commission
implementing that Article, or who falsifies, tampers with, or knowingly renders inaccurate any recording or
monitoring device or method required to be operated or maintained under Article 21 or regulations of the
Environmental Management Commission implementing that Article, shall be guilty of a misdemeanor punishable
by a fine not to exceed $25,000, or by imprisonment not to exceed six months, or by both. (18 U.S.C. Section
1001 provides a punishment by a fine of not more than $25,000 or imprisonment not more than 5 years, or both,
for a similar offense.)
RECEIVED/NCDEQ/DWR
FEB 0 2 2016
Water Quality
Permitting Section
Page 3 of 3 C-GW 03/05

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NCDOT / REU Facility
Asphalt Test Site #6-48 Location
State Grid/Ouad: E22 N E/Merry Oaks,NC SU4-Hasin: 03-06-04 not to scale
Permitted Flow: 0.0144MCiD Stream Class- WS-TV;NSW
Droinage Basin: Cape Fear River Basin HUC: 03030002 0 1 N NOT:0*72-M.N
Receivine Stream: UT to Haw River[Stream Segment 16-(36.7))

•
EFFLUENT
NPDES PERMIT NO. NC0087629 DISCHARGE NO.001 MONTH DECEMBER YEAR 2015
FACILITY NAME NCDOT ASPHALT SITE No. 6-48 CLASS I COUNTY CHATHAM
CERTIFIED LABORATORY (I)Shealy Environmental Services. Inc. CERTIFICATION NO. #329
(list additional laboratories on the backside/page 2 of this form)
OPER. IN RESP. CHARGE(ORC)Jeffrev A Leaver GRADE 1 CERTIFICATION NO. PC-991234
PERSON(S)COLLECTING SAMPLES Jeffrey Leaver, Aaron H Hill ORC PHONE[phone]
CHECK BOX IF ORC HAS CHANGED C=J NO FLOW I DISCHARGE FRO\I SITE 0
Mail ORIGINAL and ONE COPY to:
ATTN:CENTRAL FILES x ?`/(- iii'..42 t.'�-L-.. I
DIVISION OF WATER QUALITY
1 j1, I 1 I �.
(617 X1:111,SERVICE CENTER DATE
BY THIS" IGN, 'l' E,1 CYRTIFV THAT THIS REPORT N
RALEIGH, NC' 27699-1617 ACCLR. TE AND COMPLETE TO TIIE BEST OF MV KNOWLEDGE.
m 50050 78371 J 34501 006011 C'0665 TIIP3B 34506 34496 I
E FLOW ` y v
Ti o i-" u EFF1 j c - u o c r
d c
� o c ✓ INF 0 ` n x
r o- a L Ot OvmC O = O O O= m r 0 } IJH O L 7 d c O u
m Q ru - q O ,y t O
'IRS HRS Y/B/N MCD ug/L ug/1, mg/L mg/L P/F ug/I. uo/I `
1 0.002
22 0.002
3 1430 0 Y 0.0021 -
0.0021 4 -
5 0.0021
6, 0.002I
7 1420 1 Y 0.0019 <0.5 <0.5 0.11' 0.016 PASS <0.5 <0.5
8 _ 0.0019
9
0.0019 -
(0, 0.0019
0.0019 1
12 0.0019
13 0.00(9
14 0.0019 - - - --
15 0.0019 -
16 1500' 0.5 Y 0.001 RECEIUED�CD:aIDWR
17, 0.001
16
18 ' 0.001
FEB 0 2 2
19 0.001
20 0.001 Wati f Clualjty
21 0.001 'f'.• ion
22 1300 0.5 Y 0
23 0
24 0
25 0 _ .
26 0
27 0 -
28 0
29 1600 1,Y . 0.0021
30 0.0021 -
31 0.0021
AVERAGE 0.0012<0.5 <0.5 0.11 0.016 PASS <0.5 <0.5
MAXIMUM 0.0021 <0.5 <0.5 0.11 0.016 PASS <0.5 <0.5
11INIMUM 0 <0.5 <0.5 0.11 0.016 PASS <0.5 <0.5
('amp.(C)/Grab(C) MFG G C G G G C
atonthly I.imit 0.0144 4.1 none 5.5 2 P,;F none none
DWQ Form MR-I,1 (11/04)

I
Effluent Toxicity Report Form - Chronic Pass/Fail and Acute LC50 Date: 12/10/15
Facility: NCDOT-PITTSBORO NPDES#: NC0087629 Pipet!: 001 County: CHATHAM '
Laborato Performin61
g PACE ANALYTICAL
X / Comments:
S':n.y!$ e o% Operator in9Responsible Charge
X . Wim, Ute..
Sig -t re of)Laboratory Supervisor
PASSED: -4.59% Reduction
Work Order: 92277814 Environmental Sciences Branch
MAIL ORIGINAL TO: Div. of Water Quality
N.C. DENR
1621 Mail Service Center
Raleigh, North Carolina 27699-1621
North Carolina Ceriodaphnia
Chronic Pass/Fail Reproduction Toxicity Test
Chronic Test Results
Calculated t = -0.830
CONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 Tabular t = 2.508
Reduction = -4.59
^
# Young Produced 20 32 30 26 24 29 28 27 28 24 29 30 Mortality Avg.Reprod.
0.00 27.25
Adult (L)ive (D)ead L IL L L L L L L L L L L Control Control
k
18.33 28.50
r Effluent %: 90% Treatment 2 Treatment 2
TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 Control CV ~
12.133% PASS FAIL
# Young Produced - 18 33 31 28 32 28 31 28 30 27 25 31 % control orgs X
producing 3rd
Adult (L)ive (D)ead D L L L L L L L L L L L ! brood Check One
100%
i
1st sample 1st sample 2nd sample Complete This For Either Test
PH Test Start Date: 12/02/15
Control 7.84 7.82 7.65 8.04 8.25 8.00 Collection (Start) Date
1Treatment 2 7.86 7.87 7.93 8.69 8.23 8.20 Sample T: 12/01/15 Sample 2: 12/03/15
P Type/Duration
s
s s Grab Comp. Duration D 1st in
t e t e t e
I S S
a n a n a n Sample 1 X hrs L A
r d r d r d AU
M
t t t Sample 2 X hrs T P P
1st sample 1st sample 2nd sample P P
D.O.
Control 7. 90 7.51 7.85 7.92 7.76 7.30 Hardness(mg/1) 47
Treatment 2 7.80 7.60 7.59 7.03 7.67 7.23 Spec. Cond. (µmhos) 268 452 455
Chlorine(mg/1) <0.1 <0.1
• LC50/Acute Toxicity Test Sample temp. at receipt(°C) 2.7 5.6
(Mortality expressed as %, combining replicates) I
Note: Please
% % % % % Concentration Complete This
% % % % % % % % % % Mortality Section Also
start/end start/end
LC50 = % Method of Determination '
95% Confidence Limits Moving Average Probit Control
% -- % Spearman Karber - Other
High
Conc.
PH D.O.
Organism Tested: Ceriodaphnia dubia Duration(hrs) : I
Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41)

SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Hart & Hickman, PC
2923 South Tryon Street
Suite 100
Charlotte, NC 28203
Attention: Jeff Albano
Project Name:NCDOT
Lot Number:QL09014
Date Completed:12/22/2015
RECEIVED/NCDEQIDWR
FEB 0 2 2016
Water Quality
Permitting Section
A
Nisreen Saikaly
Project Manager
LABORATORY
NANAITATION
BUREAUCCRED. .-•-
0)
ACCR�DITfD,s �� ::
This report shall not be reproduced,except in its entirety.without the written approval of Shealy Environmental Services, Inc.
The following non-paginated documents are considered part of this report:Chain of Custody Record and Sample Receipt Checklist.
Shealy Environmental Services.Inc Page: 1 of 30
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SHEALY ENVIRONMENTAL SERVICES, INC.
SC DHEC No: 32010 NELAC No:E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Hart & Hickman, PC
Lot Number: QL09014
This Report of Analysis contains the analytical result(s)for the sample(s)listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt,sample analysis,and data review have been performed in accordance with the most current approved NELAC standards,the
Shealy Environmental Services, Inc. ("Shealy")Quality Assurance Management Plan(QAMP),standard operating procedures(SOPs),and Shealy
policies.Any exceptions to the NELAC standards,the QAMP,SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page.
Shealy Environmental Services.Inc. Page: 2 of 30
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SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Hart & Hickman, PC
Lot Number: QL09014
Sample Number Sample ID Matrix Date Sampled Date Received
001 TRIP BLANK Aqueous 12/07/2015 12/09/2015
002 INF-120715 Aqueous 12/07/2015 1540 12/09/2015
003 PRECARBON-120715 Aqueous 12/07/20151528 12/09/2015
004 MID-CARBON-120715 Aqueous 12/07/20151520 12/09/2015
005 EFF-120715 Aqueous 12/07/20151510 12/09/2015
(5 samples)
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SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Hart & Hickman, PC
Lot Number: QL09014
Sample Sample ID Matrix Parameter Method Result Q Units Page
001 TRIP BLANK Aqueous Chloroform 8260B 0.23 BJ ug/L 5
002 INF-120715 Aqueous Acetone 8260B 2.3 J ug/L 7
002 INF-120715 Aqueous 1,1-Dichloroethane 8260B 2.0 ug/L 7
002 INF-120715 Aqueous 1,1-Dichloroethene 8260B 5.8 ug/L 7
002 INF-120715 Aqueous cis-1.2-Dichloroethene 8260B 36 ug/L 7
002 INF-120715 Aqueous Tetrachloroethene 8260B 2.0 ug/L 7
002 INF-120715 Aqueous 1,1,1-Trichloroethane 8260B 0.90 ug/L 7
002 INF-120715 Aqueous Trichloroethene 8260B 54 ug/L 8
002 INF-120715 Aqueous Vinyl chloride 8260B 1.3 ug/L 8
003 PRECARBON-120715 Aqueous Acetone 8260B 6.7 J ug/L 9
003 PRECARBON-120715 Aqueous cis-1,2-Dichloroethene 82608 0.66 ug/L 9
003 PRECARBON-120715 Aqueous Trichloroethene 8260B 0.56 ug/L 10
004 MID-CARBON-120715 Aqueous Acetone 8260B 2.4 J ug/L 11
005 EFF-120715 Aqueous Nitrate-Nitrite-N 353.2 0.11 B mg/L 13
005 EFF-120715 Aqueous Phosphorus 365.1 0.016 mg/L 13
005 EFF-120715 Aqueous TKN 351.2 0.19 B mg/L 13
005 EFF-120715 Aqueous Acetone 8260B 2.4 J ug/L 14
(17 detections)
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Volatile Organic Compounds by GC/MS
Client:Hart& Hickman, PC Laboratory ID:QL09014-001
Description:TRIP BLANK Matrix:Aqueous
Date Sampled:12/07/2015
Date Received:12/09/2015
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260B 1 12/17/20151027 SES 92442
CAS Analytical
Parameter Number Method Result Q PQL MDL Units Run
Acetone 67-64-1 8260B ND 10 1.7 ug/L 1
Benzene 71-43-2 8260B ND 0.50 0.20 ug/L 1
Bromodichloromethane 75-27-4 8260B ND 0.50 0.24 ug/L 1
Bromoform 75-25-2 8260B ND 0.50 0.31 ug/L 1
Bromomethane(Methyl bromide) 74-83-9 8260B ND 0.50 0.27 ug/L 1
2-Butanone(MEK) 78-93-3 8260B ND 10 1.6 ug/L 1
Carbon disulfide 75-15-0 8260B ND 0.50 0.17 ug/L 1
Carbon tetrachloride 56-23-5 8260B ND 0.50 0.21 ug/L 1
Chlorobenzene 108-90-7 8260B ND 0.50 0.16 ug/L 1
Chloroethane 75-00-3 8260B ND 0.50 0.34 ug/L 1
Chloroform 67-66-3 82606 0.23 BJ 0.50 0.20 ug/L 1
Chloromethane(Methyl chloride) 74-87-3 8260B ND 0.50 0.35 ug/L 1
Cyclohexane 110-82-7 8260B ND 0.50 0.24 ug/L 1
1,2-Dibromo-3-chloropropane(DBCP) 96-12-8 82608 ND 0.50 0.36 ug/L 1
Dibromochloromethane 124-48-1 8260B ND 0.50 0.18 ug/L 1
1,2-Dibromoethane(EDB) 106-93-4 8260B ND 0.50 0.23 ug/L 1
1,3-Dichlorobenzene 541-73-1 8260B ND 0.50 0.23 ug/L 1
1,2-Dichlorobenzene 95-50-1 8260B ND 0.50 0.19 ug/L 1
1,4-Dichlorobenzene 106-46-7 8260B ND 0.50 0.18 ug/L 1
Dichlorodifluoromethane 75-71-8 8260B ND 0.50 0.26 ug/L 1
1,1-Dichloroethane 75-34-3 8260B ND 0.50 0.21 ug/L 1
1,2-Dichloroethane 107-06-2 8260B ND 0.50 0.13 ug/L 1
trans-1,2-Dichloroethene 156-60-5 8260B ND 0.50 0.24 ug/L 1
1,1-Dichloroethene 75-35-4 8260B ND 0.50 0.18 ug/L 1
cis-1,2-Dichloroethene 156-59-2 8260B ND 0.50 0.21 ug/L 1
1,2-Dichloropropane 78-87-5 82608 ND 0.50 0.24 ug/L 1
trans-1,3-Dichloropropene 10061-02-6 8260B ND 0.50 0.19 ug/L 1
cis-1,3-Dichloropropene 10061-01-5 8260B ND 0.50 0.21 ug/L 1
Ethylbenzene 100-41-4 8260B ND 0.50 0.19 ug/L 1
2-Hexanone 591-78-6 8260B ND 10 0.40 ug/L 1
lsopropylbenzene 98-82-8 8260B ND 0.50 0.13 ug/L 1
Methyl acetate 79-20-9 8260B ND 1.0 0.24 ug/L 1
Methyl tertiary butyl ether(MTBE) 1634-04-4 8260B ND 0.50 0.18 ug/L 1
4-Methyl-2-pentanone 108-10-1 8260B ND 10 0.38 ug/L 1
Methylcyclohexane 108-87-2 8260B ND 5.0 0.14 ug/L 1
Methylene chloride 75-09-2 8260B ND 0.50 0.20 ug/L 1
Styrene 100-42-5 8260B ND 0.50 0.18 ug/L 1
1,1,2,2-Tetrachloroethane 79-34-5 82606 ND 0.50 0.23 ug/L 1
Tetrachloroethene 127-18-4 8260B ND 0.50 0.24 ug/L 1
Toluene 108-88-3 8260B ND 0.50 0.23 ug/L 1
1,1,2-Trichloro-1,2,2-Trifluoroethane 76-13-1 82606 ND 0.50 0.23 ug/L 1
1,2,4-Trichlorobenzene 120-82-1 82606 ND 0.50 0.15 ug/L 1
1,1,1-Trichloroethane 71-55-6 8260B ND 0.50 0.37 ug/L 1
1,1,2-Trichloroethane 79-00-5 8260B ND 0.50 0.27 ug/L 1
POI_=Practical quantitation limit B=Detected in the method blank E=Quantitation of compound exceeded the calibration range H=Out of holding time
ND=Not detected at or above the MDL J=Estimated result<PQL and>MDL P=The RPD between two GC columns exceeds 40% N=Recovery is out of criteria
Where applicable,all soil sample analysis are reported on a dry weight basis unless flagged with a"W'
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Volatile Organic Compounds by GC/MS
Client:Hart&Hickman,PC Laboratory ID QL09014-001
Description:TRIP BLANK Matrix:Aqueous
Date Sampled:12/07/2015
Date Received:12/09/2015
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 50308 8260B 1 12/17/20151027 SES 92442
CAS Analytical
Parameter Number Method Result Q PQL MDL Units Run
Trichloroethene 79-01-6 82608 ND 0.50 0.27 ug/L 1
Trichlorofluoromethane 75-69-4 8260B ND 0.50 0.20 ug/L 1
Vinyl chloride 75-01-4 8260B ND 0.50 0.21 ug/L 1
Xylenes(total) 1330-20-7 8260B ND 0.50 0.32 ug/L 1
Run 1 Acceptance
Surrogate Q %Recovery Limits
1,2-Dichloroethane-d4 97 70-130
Bromofluorobenzene 101 70-130
Toluene-d8 103 70-130
PQL=Practical quantitation limit B=Detected in the method blank E=Quantitation of compound exceeded the calibration range H=Out of holding lime
ND=Not detected at or above the MDL J=Estimated result<PQL and>MDL P=The RPD between two GC columns exceeds 40% N=Recovery is out of criteria
Where applicable,all soil sample analysis are reported on a dry weight basis unless flagged with a"W'
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Volatile Organic Compounds by GC/MS
Client:Hart&Hickman,PC Laboratory ID:QL09014-002
Description:INF-120715 Matrix:Aqueous
Date Sampled:12/07/2015 1540
Date Received:12/09/2015
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260B 1 12/17/20151159 SES 92442
CAS Analytical
Parameter Number Method Result Q PQL MDL Units Run
Acetone 67-64-1 8260B 2.3 J 10 1.7 ug/L 1
Benzene 71-43-2 8260B ND 0.50 0.20 ug/L 1
Bromodichloromethane 75-27-4 8260B ND 0.50 0.24 ug/L 1
Bromoform 75-25-2 8260B ND 0.50 0.31 ug/L 1
Bromomethane(Methyl bromide) 74-83-9 8260B ND 0.50 0.27 ug/L 1
2-Butanone(MEK) 78-93-3 8260B ND 10 1.6 ug/L 1
Carbon disulfide 75-15-0 8260B ND 0.50 0.17 ug/L 1
Carbon tetrachloride 56-23-5 82606 ND 0.50 0.21 ug/L 1
Chlorobenzene 108-90-7 8260B ND 0.50 0.16 ug/L 1
Chloroethane 75-00-3 8260B ND 0.50 0.34 ug/L 1
Chloroform 67-66-3 8260B ND 0.50 0.20 ug/L 1
Chloromethane(Methyl chloride) 74-87-3 82606 ND 0.50 0.35 ug/L 1
Cyclohexane 110-82-7 82606 ND 0.50 0.24 ug/L 1
1,2-Dibromo-3-chloropropane(DBCP) 96-12-8 82608 ND 0.50 0.36 ug/L 1
Dibromochloromethane 124-48-1 8260B ND 0.50 0.18 ug/L 1
1,2-Dibromoethane(EDB) 106-93-4 8260B ND 0.50 0.23 ug/L 1
1,3-Dichlorobenzene 541-73-1 82606 ND 0.50 0.23 ug/L 1
1,2-Dichlorobenzene 95-50-1 82606 ND 0.50 0.19 ug/L 1
1,4-Dichlorobenzene 106-46-7 82606 ND 0.50 0.18 ug/L 1
Dichlorodifluoromethane 75-71-8 82606 ND 0.50 0.26 ug/L 1
1,1-Dichloroethane 75-34-3 8260B 2.0 0.50 0.21 ug/L 1
1,2-Dichloroethane 107-06-2 8260B ND 0.50 0.13 ug/L 1
trans-1,2-Dichloroethene 156-60-5 8260B ND 0.50 0.24 ug/L 1
1,1-Dichloroethene 75-35-4 8260B 5.8 0.50 0.18 ug/L 1
cis-1,2-Dichloroethene 156-59-2 8260B 36 0.50 0.21 ug/L 1
1,2-Dichloropropane 78-87-5 8260B ND 0.50 0.24 ug/L 1
trans-1,3-Dichloropropene 10061-02-6 8260B ND 0.50 0.19 ug/L 1
cis-1,3-Dichloropropene 10061-01-5 82608 ND 0.50 0.21 ug/L 1
Ethylbenzene 100-41-4 82608 ND 0.50 0.19 ug/L 1
2-Hexanone 591-78-6 8260B ND 10 0.40 ug/L 1
Isopropylbenzene 98-82-8 8260B ND 0.50 0.13 ug/L 1
Methyl acetate 79-20-9 8260B ND 1.0 0.24 ug/L 1
Methyl tertiary butyl ether(MTBE) 1634-04-4 82606 ND 0.50 0.18 ug/L 1
4-Methyl-2-pentanone 108-10-1 8260B ND 10 0.38 ug/L 1
Methylcyclohexane 108-87-2 8260B ND 5.0 0.14 ug/L 1
Methylene chloride 75-09-2 8260B ND 0.50 0.20 ug/L 1
Styrene 100-42-5 8260B ND 0.50 0.18 ug/L 1
1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 0.50 0.23 ug/L 1
Tetrachloroethene 127-18-4 8260B 2.0 0.50 0.24 ug/L 1
Toluene 108-88-3 82608 ND 0.50 0.23 ug/L 1
1,1,2-Trichloro-1,2,2-Trifluoroethane 76-13-1 8260B ND 0.50 0.23 ug/L 1
1,2,4-Trichlorobenzene 120-82-1 8260B ND 0.50 0.15 ug/L 1
1,1,1-Trichloroethane 71-55-6 8260B 0.90 0.50 0.37 ug/L 1
1,1,2-Trichloroethane 79-00-5 82606 ND 0.50 0.27 ug/L 1
POI_=Practical quantitation limit B=Detected in the method blank E=Quantitation of compound exceeded the calibration range H=Out of holding time
ND=Not detected at or above the MDL J=Estimated result<POL and>MDL P=The RPD between two GC columns exceeds 40% N=Recovery is out of criteria
Where applicable,all soil sample analysis are reported on a dry weight basis unless flagged with a"W'
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Volatile Organic Compounds by GC/MS
Client:Hart&Hickman,PC Laboratory ID:QL09014-002
Description:INF-120715 Matrix:Aqueous
Date Sampled:12/07/2015 1540
Date Received:12/09/2015
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260B 1 12/17/20151159 SES 92442
CAS Analytical
Parameter Number Method Result Q PQL MDL Units Run
Trichloroethene 79-01-6 8260B 54 0.50 0.27 ug/L 1
Trichlorofluoromethane 75-69-4 8260B ND 0.50 0.20 ug/L 1
Vinyl chloride 75-01-4 8260B 1.3 0.50 0.21 ug/L 1
Xylenes(total) 1330-20-7 8260B ND 0.50 0.32 ug/L 1
Run 1 Acceptance
Surrogate Q %Recovery Limits
1,2-Dichloroethane-d4 98 70-130
Bromofluorobenzene 101 70-130
Toluene-d8 103 70-130
PQL=Practical quantitation limit B=Detected in the method blank E=Quantitation of compound exceeded the calibration range H=Out of holding time
ND=Not detected at or above the MDL J=Estimated result<PQL and>MDL P=The RPD between two GC columns exceeds 40% N=Recovery is out of criteria
Where applicable,all soil sample analysis are reported on a dry weight basis unless flagged with a"W'
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Volatile Organic Compounds by GC/MS
Client:Hart&Hickman,PC Laboratory ID:QL09014-003
Description:PRECARBON-120715 Matrix:Aqueous
Date Sampled:12/07/2015 1528
Date Received:12/09/2015
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 82608 1 12/17/20151222 SES 92442
CAS Analytical
Parameter Number Method Result Q PQL MDL Units Run
Acetone 67-64-1 8260B 6.7 J 10 1.7 ug/L 1
Benzene 71-43-2 8260B ND 0.50 0.20 ug/L 1
Bromodichloromethane 75-27-4 82608 ND 0.50 0.24 ug/L 1
Bromoform 75-25-2 8260B ND 0.50 0.31 ug/L 1
Bromomethane(Methyl bromide) 74-83-9 82608 ND 0.50 0.27 ug/L 1
2-Butanone(MEK) 78-93-3 82608 ND 10 1.6 ug/L 1
Carbon disulfide 75-15-0 82608 ND 0.50 0.17 ug/L 1
Carbon tetrachloride 56-23-5 8260B ND 0.50 0.21 ug/L 1
Chlorobenzene 108-90-7 8260B ND 0.50 0.16 ug/L 1
Chloroethane 75-00-3 8260B ND 0.50 0.34 ug/L 1
Chloroform 67-66-3 82608 ND 0.50 0.20 ug/L 1
Chloromethane(Methyl chloride) 74-87-3 82608 ND 0.50 0.35 ug/L 1
Cyclohexane 110-82-7 82608 ND 0.50 0.24 ug/L 1
1,2-Dibromo-3-chloropropane(DBCP) 96-12-8 8260B ND 0.50 0.36 ug/L 1
Dibromochloromethane 124-48-1 8260B ND 0.50 0.18 ug/L 1
1,2-Dibromoethane(EDB) 106-93-4 8260B ND 0.50 0.23 ug/L 1
1,3-Dichlorobenzene 541-73-1 8260B ND 0.50 0.23 ug/L 1
1,2-Dichlorobenzene 95-50-1 8260B ND 0.50 0.19 ug/L 1
1,4-Dichlorobenzene 106-46-7 82608 ND 0.50 0.18 ug/L 1
Dichlorodifluoromethane 75-71-8 8260B ND 0.50 0.26 ug/L 1
1,1-Dichloroethane 75-34-3 8260B ND 0.50 0.21 ug/L 1
1,2-Dichloroethane 107-06-2 8260B ND 0.50 0.13 ug/L 1
trans-1,2-Dichloroethene 156-60-5 8260B ND 0.50 0.24 ug/L 1
1,1-Dichloroethene 75-35-4 8260B ND 0.50 0.18 ug/L 1
cis-1,2-Dichloroethene 156-59-2 8260B 0.66 0.50 0.21 ug/L 1
1,2-Dichloropropane 78-87-5 8260B ND 0.50 0.24 ug/L 1
trans-1,3-Dichloropropene 10061-02-6 8260B ND 0.50 0.19 ug/L 1
cis-1,3-Dichloropropene 10061-01-5 8260B ND 0.50 0.21 ug/L 1
Ethylbenzene 100-41-4 82608 ND 0.50 0.19 ug/L 1
2-Hexanone 591-78-6 82608 ND 10 0.40 ug/L 1
Isopropylbenzene 98-82-8 8260B ND 0.50 0.13 ug/L 1
Methyl acetate 79-20-9 8260B ND 1.0 0.24 ug/L 1
Methyl tertiary butyl ether(MTBE) 1634-04-4 8260B ND 0.50 0.18 ug/L 1
4-Methyl-2-pentanone 108-10-1 8260B ND 10 0.38 ug/L 1
Methylcyclohexane 108-87-2 8260B ND 5.0 0.14 ug/L 1
Methylene chloride 75-09-2 8260B ND 0.50 0.20 ug/L 1
Styrene 100-42-5 8260B ND 0.50 0.18 ug/L 1
1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 0.50 0.23 ug/L 1
Tetrachloroethene 127-18-4 8260B ND 0.50 0.24 ug/L 1
Toluene 108-88-3 8260B ND 0.50 0.23 ug/L 1
1,1,2-Trichloro-1,2,2-Trifluoroethane 76-13-1 82608 ND 0.50 0.23 ug/L 1
1,2,4-Trichlorobenzene 120-82-1 82608 ND 0.50 0.15 ug/L 1
1,1,1-Trichloroethane 71-55-6 8260B ND 0.50 0.37 ug/L 1
1,1,2-Trichloroethane 79-00-5 8260B ND 0.50 0.27 ug/L 1
PQL=Practical quantitation limit B=Detected in the method blank E=Quantitation of compound exceeded the calibration range H=Out of holding time
ND=Not detected at or above the MDL J=Estimated result<PQL and>MDL P=The RPD between two GC columns exceeds 40% N=Recovery is out of criteria
Where applicable,all soil sample analysis are reported on a dry weight basis unless flagged with a"W'
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Volatile Organic Compounds by GC/MS
Client:Hart&Hickman,PC Laboratory ID:QL09014-003
Description:PRECARBON-120715 Matrix:Aqueous
Date Sampled:12/07/2015 1528
Date Received:12/09/2015
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260B 1 12/17/20151222 SES 92442
CAS Analytical
Parameter Number Method Result Q PQL MDL Units Run
Trichloroethene 79-01-6 8260B 0.56 0.50 0.27 ug/L 1
Trichlorofluoromethane 75-69-4 8260B ND 0.50 0.20 ug/L 1
Vinyl chloride 75-01-4 82608 ND 0.50 0.21 ug/L 1
Xylenes(total) 1330-20-7 8260B ND 0.50 0.32 ug/L 1
Run 1 Acceptance
Surrogate Q %Recovery Limits
1,2-Dichloroethane-d4 98 70-130
Bromofluorobenzene 99 70-130
Toluene-d8 103 70-130
PQL=Practical quantitation limit B=Detected in the method blank E=Quantitation of compound exceeded the calibration range H=Out of holding time
ND=Not detected at or above the MDL J=Estimated result<PQL and>MDL P=The RPD between two GC columns exceeds 40% N=Recovery is out of criteria
Where applicable,all soil sample analysis are reported on a dry weight basis unless flagged with a''W'
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Volatile Organic Compounds by GC/MS
Client:Hart&Hickman,PC Laboratory ID:QL09014-004
Description:MID-CARBON-120715 Matrix:Aqueous
Date Sampled:12/07/2015 1520
Date Received:12/09/2015
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 50308 8260B 1 12/17/20151245 SES 92442
CAS Analytical
Parameter Number Method Result Q PQL MDL Units Run
Acetone 67-64-1 8260B 2.4 J 10 1.7 ug/L 1
Benzene 71-43-2 8260B ND 0.50 0.20 ug/L 1
Bromodichloromethane 75-27-4 8260B ND 0.50 0.24 ug/L 1
Bromoform 75-25-2 8260B ND 0.50 0.31 ug/L 1
Bromomethane(Methyl bromide) 74-83-9 8260B ND 0.50 0.27 ug/L 1
2-Butanone(MEK) 78-93-3 8260B ND 10 1.6 ug/L 1
Carbon disulfide 75-15-0 8260B ND 0.50 0.17 ug/L 1
Carbon tetrachloride 56-23-5 8260B ND 0.50 0.21 ug/L 1
Chlorobenzene 108-90-7 8260B ND 0.50 0.16 ug/L 1
Chloroethane 75-00-3 8260B ND 0.50 0.34 ug/L 1
Chloroform 67-66-3 8260B ND 0.50 0.20 ug/L 1
Chloromethane(Methyl chloride) 74-87-3 82608 ND 0.50 0.35 ug/L 1
Cyclohexane 110-82-7 8260B ND 0.50 0.24 ug/L 1
1,2-Dibromo-3-chloropropane(DBCP) 96-12-8 8260B ND 0.50 0.36 ug/L 1
Dibromochloromethane 124-48-1 8260B ND 0.50 0.18 ug/L 1
1,2-Dibromoethane(EDB) 106-93-4 8260B ND 0.50 0.23 ug/L 1
1,3-Dichlorobenzene 541-73-1 8260B ND 0.50 0.23 ug/L 1
1,2-Dichlorobenzene 95-50-1 8260B ND 0.50 0.19 ug/L 1
1,4-Dichlorobenzene 106-46-7 82608 ND 0.50 0.18 ug/L 1
Dichlorodifluoromethane 75-71-8 8260B ND 0.50 0.26 ug/L 1
1,1-Dichloroethane 75-34-3 8260B ND 0.50 0.21 ug/L 1
1,2-Dichloroethane 107-06-2 8260B ND 0.50 0.13 ug/L 1
trans-1,2-Dichloroethene 156-60-5 8260B ND 0.50 0.24 ug/L 1
1,1-Dichloroethene 75-35-4 82608 ND 0.50 0.18 ug/L 1
cis-1,2-Dichloroethene 156-59-2 8260B ND 0.50 0.21 ug/L 1
1,2-Dichloropropane 78-87-5 82608 ND 0.50 0.24 ug/L 1
trans-1,3-Dichloropropene 10061-02-6 8260B ND 0.50 0.19 ug/L 1
cis-1,3-Dichloropropene 10061-01-5 8260B ND 0.50 0.21 ug/L 1
Ethylbenzene 100-41-4 8260B ND 0.50 0.19 ug/L 1
2-Hexanone 591-78-6 8260B ND 10 0.40 ug/L 1
Isopropylbenzene 98-82-8 82608 ND 0.50 0.13 ug/L 1
Methyl acetate 79-20-9 8260B ND 1.0 0.24 ug/L 1
Methyl tertiary butyl ether(MTBE) 1634-04-4 8260B ND 0.50 0.18 ug/L 1
4-Methyl-2-pentanone 108-10-1 82608 ND 10 0.38 ug/L 1
Methylcyclohexane 108-87-2 8260B ND 5.0 0.14 ug/L 1
Methylene chloride 75-09-2 8260B ND 0.50 0.20 ug/L 1
Styrene 100-42-5 8260B ND 0.50 0.18 ug/L 1
1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 0.50 0.23 ug/L 1
Tetrachloroethene 127-18-4 82608 ND 0.50 0.24 ug/L 1
Toluene 108-88-3 8260B ND 0.50 0.23 ug/L 1
1,1,2-Trichloro-1,2,2-Trifluoroethane 76-13-1 8260B ND 0.50 0.23 ug/L 1
1,2,4-Trichlorobenzene 120-82-1 8260B ND 0.50 0.15 ug/L 1
1,1,1-Trichloroethane 71-55-6 82608 ND 0.50 0.37 ug/L 1
1,1,2-Trichloroethane 79-00-5 8260B ND 0.50 0.27 ug/L 1
PQL=Practical quantitation limit B=Detected in the method blank E=Quantitation of compound exceeded the calibration range H=Out of holding time
ND=Not detected at or above the MDL J=Estimated result<PQL and>MDL P=The RPD between two GC columns exceeds 40% N=Recovery is out of criteria
Where applicable,all soil sample analysis are reported on a dry weight basis unless flagged with a"W'
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Volatile Organic Compounds by GC/MS
Client:Hart&Hickman,PC Laboratory ID:QL09014-004
Description:MID-CARBON-120715 Matrix:Aqueous
Date Sampled:12/07/2015 1520
Date Received:12/09/2015
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260B 1 12/17/20151245 SES 92442
CAS Analytical
Parameter Number Method Result Q PQL MDL Units Run
Trichloroethene 79-01-6 8260B ND 0.50 0.27 ug/L 1
Trichlorofluoromethane 75-69-4 8260B ND 0.50 0.20 ug/L 1
Vinyl chloride 75-01-4 8260B ND 0.50 0.21 ug/L 1
Xylenes(total) 1330-20-7 8260B ND 0.50 0.32 ug/L 1
Run 1 Acceptance
Surrogate Q %Recovery Limits
1,2-Dichloroethane-d4 97 70-130
Bromofluorobenzene 99 70-130
Toluene-d8 103 70-130
PQL=Practical quantitation limit B=Detected in the method blank E=Quantitation of compound exceeded the calibration range H=Out of holding time
ND=Not detected at or above the MDL J=Estimated result<PQL and>MDL P=The RPD between two GC columns exceeds 40% N=Recovery is out of criteria
Where applicable,all soil sample analysis are reported on a dry weight basis unless flagged with a"W'
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Inorganic non-metals
Client:Hart&Hickman,PC Laboratory ID:QL09014-005
Description:EFF-120715 Matrix:Aqueous
Date Sampled:12/07/2015 1510
Date Received:12/09/2015
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Nitrate-Nitr)353.2 1 12/11/2015 2320 HMA 92003
1 (Phosphorus)365.1 1 12/22/2015 1006 BWS 12/21/2015 1509 92743
1 351.4 (TKN)351.2 1 12/18/2015 1231 BWS 12/17/2015 1039 92504
CAS Analytical
Parameter Number Method Result Q PQL MDL Units Run
Nitrate-Nitrite-N 353.2 0.11 B 0.020 0.0013 mg/L 1
Phosphorus 7723-14-0 365.1 0.016 0.010 0.0087 mg/L 1
TKN 351.2 0.19 B 0.10 0.042 mg/L 1
PQL=Practical quantitation limit B=Detected in the method blank E=Quantitation of compound exceeded the calibration range H=Out of holding time
ND=Not detected at or above the MDL J=Estimated result<PQL and>MDL P=The RPD between two GC columns exceeds 40% N=Recovery is out of criteria
Where applicable,all soil sample analysis are reported on a dry weight basis unless flagged with a"W'
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Volatile Organic Compounds by GC/MS
Client:Hart&Hickman,PC Laboratory ID:QL09014-005 .
Description:EFF-120715 Matrix:Aqueous
Date Sampled:12/07/2015 1 510
Date Received:12/09/2015
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260B 1 12/17/20151308 SES 92442
CAS Analytical
Parameter Number Method Result Q PQL MDL Units Run
Acetone 67-64-1 8260B 2.4 J 10 1.7 ug/L 1
Benzene 71-43-2 8260B ND 0.50 0.20 ug/L 1
Bromodichloromethane 75-27-4 8260B ND 0.50 0.24 ug/L 1
Bromoform 75-25-2 8260B ND 0.50 0.31 ug/L 1
Bromomethane(Methyl bromide) 74-83-9 82608 ND 0.50 0.27 ug/L 1
2-Butanone(MEK) 78-93-3 8260B ND 10 1.6 ug/L 1
Carbon disulfide 75-15-0 8260B ND 0.50 0.17 ug/L 1
Carbon tetrachloride 56-23-5 8260B ND 0.50 0.21 ug/L 1
Chlorobenzene 108-90-7 82608 ND 0.50 0.16 ug/L 1
Chloroethane 75-00-3 8260B ND 0.50 0.34 ug/L 1
Chloroform 67-66-3 82608 ND 0.50 0.20 ug/L 1
Chloromethane(Methyl chloride) 74-87-3 82606 ND 0.50 0.35 ug/L 1
Cyclohexane 110-82-7 82608 ND 0.50 0.24 ug/L • 1
1,2-Dibromo-3-chloropropane(DBCP) 96-12-8 8260B ND 0.50 0.36 ug/L 1
Dibromochloromethane 124-48-1 8260B ND 0.50 0.18 ug/L 1
1,2-Dibromoethane(EDB) 106-93-4 82608 ND 0.50 0.23 ug/L 1
1,3-Dichlorobenzene 541-73-1 82608 ND 0.50 0.23 ug/L 1
1,2-Dichlorobenzene 95-50-1 8260B ND 0.50 0.19 ug/L 1
1,4-Dichlorobenzene 106-46-7 8260B ND 0.50 0.18 ug/L 1
Dichlorodifluoromethane 75-71-8 8260B ND 0.50 0.26 ug/L 1
1,1-Dichloroethane 75-34-3 8260B ND 0.50 0.21 ug/L 1
1,2-Dichloroethane 107-06-2 82608 ND 0.50 0.13 ug/L 1
trans-1,2-Dichloroethene 156-60-5 8260B ND 0.50 0.24 ug/L 1
1,1-Dichloroethene 75-35-4 8260B ND 0.50 0.18 ug/L 1
cis-1,2-Dichloroethene 156-59-2 8260B ND 0.50 0.21 ug/L 1
1,2-Dichloropropane 78-87-5 8260B ND 0.50 0.24 ug/L 1
trans-1,3-Dichloropropene 10061-02-6 8260B ND 0.50 0.19 ug/L 1
cis-1,3-Dichloropropene 10061-01-5 8260B ND 0.50 0.21 ug/L 1
Ethylbenzene 100-41-4 8260B ND 0.50 0.19 ug/L 1
2-Hexanone 591-78-6 82608 ND 10 0.40 ug/L 1
Isopropylbenzene 98-82-8 8260B ND 0.50 0.13 ug/L 1
Methyl acetate 79-20-9 82608 ND 1.0 0.24 ug/L 1
Methyl tertiary butyl ether(MTBE) 1634-04-4 82608 ND 0.50 0.18 ug/L 1
4-Methyl-2-pentanone 108-10-1 8260B ND 10 0.38 ug/L 1
Methylcyclohexane 108-87-2 8260B ND 5.0 0.14 ug/L 1
Methylene chloride 75-09-2 8260B ND 0.50 0.20 ug/L 1
Styrene 100-42-5 8260B ND 0.50 0.18 ug/L 1
1,1,2,2-Tetrachloroethane 79-34-5 8260B ND 0.50 0.23 ug/L 1
Tetrachloroethene 127-18-4 8260B ND 0.50 0.24 ug/L 1
Toluene 108-88-3 8260B ND 0.50 0.23 ug/L 1
1,1,2-Trichloro-1,2,2-Trifluoroethane 76-13-1 8260B ND 0.50 0.23 ug/L 1
1,2,4-Trichlorobenzene 120-82-1 8260B ND 0.50 0.15 ug/L 1
1,1,1-Trichloroethane 71-55-6 82606 ND 0.50 0.37 ug/L 1
1,1,2-Trichloroethane 79-00-5 8260B ND 0.50 0.27 ug/L 1
PQL=Practical quantitation limit B=Detected in the method blank E=Quantitation of compound exceeded the calibration range H=Out of holding time
ND=Not detected at or above the MDL J=Estimated result<PQL and>MDL P=The RPD between two GC columns exceeds 40% N=Recovery is out of criteria
Where applicable,all soil sample analysis are reported on a dry weight basis unless flagged with a"W'
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Volatile Organic Compounds by GC/MS
Client:Hart&Hickman,PC Laboratory ID:QL09014-005
Description:EFF-120715 Matrix:Aqueous
Date Sampled:12/07/2015 1510
Date Received:12/09/2015
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260B 1 12/17/20151308 SES 92442
CAS Analytical
Parameter Number Method Result Q PQL MDL Units Run
Trichloroethene 79-01-6 8260B ND 0.50 0.27 ug/L 1
Trichlorofluoromethane 75-69-4 8260B ND 0.50 0.20 ug/L 1
Vinyl chloride 75-01-4 8260B ND 0.50 0.21 ug/L 1
Xylenes(total) 1330-20-7 82606 ND 0.50 0.32 ug/L 1
Run 1 Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4 99 70-130
Bromofluorobenzene 101 70-130
Toluene-d8 103 70-130
PQL=Practical quantitation limit B=Detected in the method blank E=Quantitation of compound exceeded the calibration range H=Out of holding time
ND=Not detected at or above the MDL J=Estimated result<PQL and>MDL P=The RPD between two GC columns exceeds 40% N=Recovery is out of criteria
Where applicable,all soil sample analysis are reported on a dry weight basis unless flagged with a"W'
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QC Summary
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Inorganic non-metals - MB
Sample ID: QQ92003-001 Matrix: Aqueous
Batch:92003
Analytical Method: 353.2
Parameter Result Q Dil PQL MDL Units Analysis Date
Nitrate-Nitrite-N 0.0076 J 1 0.020 0.0013 mg/L 12/11/2015 2315
PQL=Practical quantitation limit P=The RPD between two GC columns exceeds 40% N=Recovery is out of criteria
ND=Not detected at or above the MDL J=Estimated result<PQL and>MDL +=RPD is out of criteria
Where applicable,all soil sample analysis are reported on a dry weight basis unless flagged with a"W'
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
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Inorganic non-metals - LCS
Sample ID: QQ92003-002 Matrix: Aqueous
Batch:92003
Analytical Method: 353.2
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil %Rec Limit Analysis Date
Nitrate-Nitrite-N 0.80 0.74 1 92 90-110 12/11/2015 2316
PDL=Practical quantitation limit P=The RPD between two GC columns exceeds 40% N=Recovery is out of criteria
ND=Not detected at or above the MDL J=Estimated result<PQL and>MDL +=RPD is out of criteria
Where applicable,all soil sample analysis are reported on a dry weight basis unless flagged with a"W'
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
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Inorganic non-metals - MB
Sample ID: QQ92504-001 Matrix: Aqueous
Batch:92504 Prep Method: 351.4
Analytical Method: 351.2 Prep Date: 12/17/2015 1039
Parameter Result Q Dil PQL MDL Units Analysis Date
TKN 0.069 J 1 0.10 0.042 mg/L 12/18/2015 1158
PQL=Practical quantitation limit P=The RPD between two GC columns exceeds 40% N=Recovery is out of criteria
ND=Not detected at or above the MDL J=Estimated result<PQL and>MDL .=RPD is out of criteria
Where applicable,all soil sample analysis are reported on a dry weight basis unless flagged with a"W'
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
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Inorganic non-metals - LCS
Sample ID: QQ92504-002 Matrix: Aqueous
Batch:92504 Prep Method: 351.4
Analytical Method: 351.2 Prep Date: 12/17/2015 1039
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil %Rec Limit Analysis Date
TKN 2.0 2.0 1 101 90-110 12/18/20151158
POL=Practical quantitation limit P=The RPD between two GC columns exceeds 40% N=Recovery is out of criteria
ND=Not detected at or above the MDL J=Estimated result<PCL and>MDL +=RPD is out of criteria
Where applicable,all soil sample analysis are reported on a dry weight basis unless flagged with a"W'
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
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Inorganic non-metals - MB
Sample ID: 0092743-001 Matrix: Aqueous
Batch:92743 Prep Method: 365.1
Analytical Method: 365.1 Prep Date: 12/21/2015 1509
Parameter Result Q Di! PQL MDL Units Analysis Date
Phosphorus ND 1 0.010 0.0087 mg/L 12/22/20151006
PQL=Practical quantitation limit P=The RPD between two GC columns exceeds 40% N=Recovery is out of criteria
ND=Not detected at or above the MDL J=Estimated result v POI_and-MDL +=RPD is out of criteria
Where applicable.all soil sample analysis are reported on a dry weight basis unless flagged with a"W'
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
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Inorganic non-metals - LCS
Sample ID: CQ92743-002 Matrix: Aqueous
Batch:92743 Prep Method: 365.1
Analytical Method: 365.1 Prep Date: 12/21/2015 1509
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q DII %Rec Limit Analysis Date
Phosphorus 0.25 0.22 1 90 90-110 12/22/20151006
Poi_.Practical quantitation limit P=The RPD between two GC columns exceeds 40% N=Recovery is out of criteria
ND=Not detected at or above the MDL J=Estimated result<PQL and>MDL *=RPD is out of criteria
Where applicable,all soil sample analysis are reported on a dry weight basis unless flagged with a"N!'
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
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Volatile Organic Compounds by GC/MS - MB
Sample ID: QQ92442-001 Matrix: Aqueous
Batch:92442 Prep Method: 5030B
Analytical Method: 8260B
Parameter Result Q Dil PQL MDL Units Analysis Date
Acetone ND 1 10 1.7 ug/L 12/17/2015 0959
Benzene ND 1 0.50 0.20 ug/L 12/17/2015 0959
Bromodichloromethane ND 1 0.50 0.24 ug/L 12/17/2015 0959
Bromoform ND 1 0.50 0.31 ug/L 12/17/2015 0959
Bromomethane(Methyl bromide) ND 1 0.50 0.27 ug/L 12/17/2015 0959
2-Butanone(MEK) ND 1 10 1.6 ug/L 12/17/2015 0959
Carbon disulfide ND 1 0.50 0.17 ug/L 12/17/2015 0959
Carbon tetrachloride ND 1 0.50 0.21 ug/L 12/17/2015 0959
Chlorobenzene ND 1 0.50 0.16 ug/L 12/17/2015 0959
Chloroethane ND 1 0.50 0.34 ug/L 12/17/2015 0959
Chloroform 0.25 J 1 0.50 0.20 ug/L 12/17/2015 0959
Chloromethane(Methyl chloride) ND 1 0.50 0.35 ug/L 12/17/2015 0959
Cyclohexane ND 1 0.50 0.24 ug/L 12/17/2015 0959
1,2-Dibromo-3-chloropropane(DBCP) ND 1 0.50 0.36 ug/L 12/17/2015 0959
Dibromochloromethane ND 1 0.50 0.18 ug/L 12/17/2015 0959
1,2-Dibromoethane(EDB) ND 1 0.50 0.23 ug/L 12/17/2015 0959
1,2-Dichlorobenzene ND 1 0.50 0.19 ug/L 12/17/2015 0959
1,3-Dichlorobenzene ND 1 0.50 0.23 ug/L 12/17/20150959
1,4-Dichlorobenzene ND 1 0.50 0.18 ug/L 12/17/20150959
Dichlorodifluoromethane ND 1 0.50 0.26 ug/L 12/17/2015 0959
1,1-Dichloroethane ND 1 0.50 0.21 ug/L 12/17/20150959
1,2-Dichloroethane ND 1 0.50 0.13 ug/L 12/17/20150959
trans-1,2-Dichloroethene ND 1 0.50 0.24 ug/L 12/17/20150959
cis-1,2-Dichloroethene ND 1 0.50 0.21 ug/L 12/17/20150959
1,1-Dichloroethene ND 1 0.50 0.18 ug/L 12/17/20150959
1,2-Dichloropropane ND 1 0.50 0.24 ug/L 12/17/20150959
cis-1,3-Dichloropropene ND 1 0.50 0.21 ug/L 12/17/20150959
trans-1,3-Dichloropropene ND 1 0.50 0.19 ug/L 12/17/2015 0959
Ethylbenzene ND 1 0.50 0.19 ug/L 12/17/2015 0959
2-Hexanone ND 1 10 0.40 ug/L 12/17/2015 0959
lsopropylbenzene ND 1 0.50 0.13 ug/L 12/17/2015 0959
Methyl acetate ND 1 1.0 0.24 ug/L 12/17/2015 0959
Methyl tertiary butyl ether(MTBE) ND 1 0.50 0.18 ug/L 12/17/2015 0959
4-Methyl-2-pentanone ND 1 10 0.38 ug/L 12/17/2015 0959
Methylcyclohexane ND 1 5.0 0.14 ug/L 12/17/2015 0959
Methylene chloride ND 1 0.50 0.20 ug/L 12/17/2015 0959
Styrene ND 1 0.50 0.18 ug/L 12/17/2015 0959
1,1,2,2-Tetrachloroethane ND 1 0.50 0.23 ug/L . 12/17/20150959
Tetrachloroethene ND 1 0.50 0.24 ug/L 12/17/2015 0959
Toluene ND 1 0.50 0.23 ug/L 12/17/2015 0959
1,1,2-Trichloro-1,2,2-Trifluoroethane ND 1 0.50 0.23 ug/L 12/17/20150959
1,2,4-Trichlorobenzene 0.26 J 1 0.50 0.15 ug/L 12/17/2015 0959
1,1,1-Trichloroethane ND 1 0.50 0.37 ug/L 12/17/2015 0959
1,1,2-Trichloroethane ND 1 0.50 0.27 ug/L 12/17/2015 0959
PQL=Practical quantitation limit P=The RPD between two GC columns exceeds 40% N=Recovery is out of criteria
ND=Not detected at or above the MDL J=Estimated result<PQL and>MDL +=RPD is out of criteria
Where applicable,all soil sample analysis are reported on a dry weight basis unless flagged with a"W'
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
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Volatile Organic Compounds by GC/MS - MB •
Sample ID: QQ92442-001 Matrix: Aqueous
Batch:92442 Prep Method: 5030B
Analytical Method: 8260B
Parameter Result Q Oil PQL MDL Units Analysis Date
Trichloroethene ND 1 0.50 0.27 ug/L 12/17/2015 0959
Trichlorofluoromethane ND 1 0.50 0.20 ug/L 12/17/2015 0959
Vinyl chloride ND 1 0.50 0.21 ug/L 12/17/2015 0959
Xylenes(total) ND 1 0.50 0.32 ug/L 12/17/2015 0959
Surrogate Q % Rec Acceptance Limit
Bromofluorobenzene 100 70-130
1,2-Dichloroethane-d4 97 70-130
Toluene-d8 104 70-130
PQL=Practical quantitation limit P=The RPD between two GC columns exceeds 40% N=Recovery is out of criteria
ND=Not detected al or above the MDL J=Estimated result=PQL and>MDL +=RPD is out of criteria
Where applicable.all soil sample analysis are reported on a dry weight basis unless flagged with a"W'
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
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Volatile Organic Compounds by GC/MS - LCS
Sample ID: QQ92442-002 Matrix: Aqueous
Batch:92442 Prep Method: 5030B
Analytical Method: 82606
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q Dil %Rec Limit Analysis Date
Acetone 100 98 1 98 60-140 12/17/2015 0906
Benzene 50 55 1 110 70-130 12/17/2015 0906
Bromodichloromethane 50 56 1 111 70-130 12/17/2015 0906
Bromoform 50 52 1 104 70-130 12/17/2015 0906
Bromomethane(Methyl bromide) 50 48 1 96 60-140 12/17/2015 0906
2-Butanone(MEK) 100 100 1 104 60-140 12/17/2015 0906
Carbon disulfide 50 47 1 93 60-140 12/17/2015 0906
Carbon tetrachloride 50 47 1 94 70-130 12/17/2015 0906
Chlorobenzene 50 55 1 109 70-130 12/17/2015 0906
Chloroethane 50 49 1 97 60-140 12/17/2015 0906
Chloroform 50 47 1 93 70-130 12/17/2015 0906
Chloromethane(Methyl chloride) 50 55 1 110 20-158 12/17/2015 0906
Cyclohexane 50 46 1 92 70-130 12/17/2015 0906
1,2-Dibromo-3-chloropropane(DBCP) 50 54 1 108 70-130 12/17/2015 0906
Dibromochloromethane 50 60 1 120 70-130 12/17/2015 0906
1,2-Dibromoethane(EDB) 50 55 1 111 70-130 12/17/2015 0906
1,2-Dichlorobenzene 50 53 1 106 70-130 12/17/2015 0906
1,3-Dichlorobenzene 50 54 1 108 70-130 12/17/20150906
1,4-Dichlorobenzene 50 52 1 105 70-130 12/17/20150906
Dichlorodifluoromethane 50 57 1 114 60-140 12/17/2015 0906
1,1-Dichloroethane 50 52 1 104 70-130 12/17/20150906
1,2-Dichloroethane 50 54 1 107 70-130 12/17/20150906
trans-1,2-Dichloroethene 50 52 1 105 70-130 12/17/20150906
cis-1,2-Dichloroethene 50 53 1 106 70-130 12/17/20150906
1,1-Dichloroethene 50 48 1 96 70-130 12/17/20150906
1,2-Dichloropropane 50 56 1 113 70-130 12/17/20150906
cis-1,3-Dichloropropene 50 59 1 117 70-130 12/17/2015 0906
trans-1,3-Dichloropropene 50 58 1 116 70-130 12/17/20150906
Ethylbenzene 50 57 1 113 70-130 12/17/2015 0906
2-Hexanone 100 120 1 117 60-140 12/17/2015 0906
Isopropylbenzene 50 56 1 111 70-130 12/17/2015 0906
Methyl acetate 50 60 1 119 60-140 12/17/2015 0906
Methyl tertiary butyl ether(MTBE) 50 53 1 106 70-130 • 12/17/2015 0906
4-Methyl-2-pentanone 100 110 1 112 60-140 12/17/2015 0906
Methylcyclohexane 50 48 1 97 70-130 12/17/2015 0906
Methylene chloride 50 48 1 96 70-130 12/17/2015 0906
Styrene 50 57 1 115 70-130 12/17/2015 0906
1,1,2,2-Tetrachloroethane 50 55 1 110 70-130 12/17/20150906
Tetrachloroethene 50 55 1 109 70-130 12/17/2015 0906
Toluene 50 56 1 112 70-130 12/17/2015 0906
1,1,2-Trichloro-1,2,2-Trifluoroethane 50 40 1 80 70-130 12/17/20150906
1,2,4-Trichlorobenzene 50 58 1 116 70-130 12/17/2015 0906
1,1,1-Trichloroethane 50 51 1 103 70-130 12/17/20150906
1,1,2-Trichloroethane 50 57 1 114 70-130 12/17/20150906
PQL=Practical quantitation limit P=The RPD between two GC columns exceeds 40% N=Recovery is out of criteria
ND=Not detected at or above the MDL J=Estimated result<PQL and>MDL a=RPD is out of criteria
Where applicable,all soil sample analysis are reported on a dry weight basis unless flagged with a"W'
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
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Volatile Organic Compounds by GC/MS - LCS
Sample ID: QQ92442-002 Matrix: Aqueous
Batch:92442 Prep Method: 5030B
Analytical Method: 8260B
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q DII % Rec Limit Analysis Date
Trichloroethene 50 56 1 112 70-130 12/17/2015 0906
Trichlorofluoromethane 50 49 1 98 60-140 12/17/2015 0906
Vinyl chloride 50 50 1 100 60-140 12/17/2015 0906
Xylenes(total) 100 110 1 112 70-130 12/17/2015 0906
Acceptance
Surrogate Q % Rec Limit
Bromofluorobenzene 97 70-130
1,2-Dichloroethane-d4 90 70-130
Toluene-d8 101 70-130
PQL=Practical quantitation limit P=The RPD between two GC columns exceeds 40% N=Recovery is out of criteria
ND=Not detected at or above the MDL J=Estimated result<PQL and>MDL *=RPD is out of criteria
Where applicable.all soil sample analysis are reported on a dry weight basis unless flagged with a"W'
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
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•
Volatile Organic Compounds by GC/MS - Duplicate
Sample ID: QL09014-002DU Matrix: Aqueous
Batch:92442 Prep Method: 5030B
Analytical Method: 8260B
Sample
Amount Result % RPD
Parameter (ug/L) (ug/L) Q DiI %RPD Limit Analysis Date
Acetone 2.3 4.4 + 1 63 20 12/17120151807
Benzene ND ND 1 0.00 20 12/17/20151807
Bromodichloromethane ND ND 1 0.00 20 12/17/20151807
Bromoform ND ND 1 0.00 20 12/17/20151807
Bromomethane(Methyl bromide) ND ND 1 0.00 20 12/17/2015 1807
2-Butanone(MEK) ND ND 1 0.00 20 12/17/2015 1807
Carbon disulfide ND ND 1 0.00 20 12/17/2015 1807
Carbon tetrachloride ND ND 1 0.00 20 12/17/2015 1807
Chlorobenzene ND ND 1 0.00 20 12/17/20151807
Chloroethane ND ND 1 0.00 20 12/17/20151807
Chloroform ND ND 1 0.00 20 12/17/20151807
Chloromethane(Methyl chloride) ND ND 1 0.00 20 12/17/2015 1807
Cyclohexane ND ND 1 0.00 20 12/17/20151807
1,2-Dibromo-3-chloropropane(DBCP) ND ND 1 0.00 20 12/17/2015 1807
Dibromochloromethane ND ND 1 0.00 20 12/17/20151807
1,2-Dibromoethane(EDB) ND ND 1 0.00 20 12/17/2015 1807
1,3-Dichlorobenzene ND ND 1 0.00 20 12/17/20151807
1,2-Dichlorobenzene ND ND 1 0.00 20 12/17/20151807
1,4-Dichlorobenzene ND ND 1 0.00 20 12/17/20151807
Dichlorodifluoromethane ND ND 1 0.00 20 12/17/20151807
1,1-Dichloroethane 2.0 1.8 1 8.8 20 12/17/20151807
1,2-Dichloroethane ND ND 1 0.00 20 12/17/20151807
trans-1,2-Dichloroethene ND ND 1 0.00 20 12/17/20151807
1,1-Dichloroethene 5.8 5.0 1 14 20 12/17/20151807
cis-1,2-Dichloroethene 36 32 1 11 20 12/17/20151807
1,2-Dichloropropane ND ND 1 0.00 20 12/17/20151807
trans-1,3-Dichloropropene ND ND 1 0.00 20 12/17/20151807
cis-1,3-Dichloropropene ND ND 1 0.00 20 12/17/20151807
Ethylbenzene ND ND 1 0.00 20 12/17/20151807
2-Hexanone ND ND 1 0.00 20 12/17/20151807
Isopropylbenzene ND ND 1 0.00 20 12/17/20151807
Methyl acetate ND ND 1 0.00 20 12/17/2015 1807
Methyl tertiary butyl ether(MTBE) ND ND 1 0.00 20 12/17/2015 1807
4-Methyl-2-pentanone ND ND 1 0.00 20 12/17/20151807
Methylcyclohexane ND ND 1 0.00 20 12/17/20151807
Methylene chloride ND ND 1 0.00 20 12/17/2015 1807
Styrene ND ND 1 0.00 20 12/17/20151807
1,1,2,2-Tetrachloroethane ND ND 1 0.00 20 12/17/20151807
Tetrachloroethene 2.0 1.8 1 13 20 12/17/20151807
Toluene ND ND 1 0.00 20 12/17/20151807
1,1,2-Trichloro-1,2,2-Trifluoroethane ND ND 1 0.00 20 12/17/20151807
1,2,4-Trichlorobenzene ND ND 1 0.00 20 12/17/20151807
1,1,1-Trichloroethane 0.90 0.82 1 9.2 20 12/17/20151807
1,1,2-Trichloroethane ND ND 1 0.00 20 12/17/20151807
PQL=Practical quantitation limit P=The RPD between two GC columns exceeds 40% N=Recovery is out of criteria
ND=Not detected at or above the MDL J=Estimated result<PQL and>MDL +=RPD is out of criteria
Where applicable,all soil sample analysis are reported on a dry weight basis unless flagged with a"W"
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
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Volatile Organic Compounds by GC/MS - Duplicate
Sample ID: QL09014-002DU Matrix: Aqueous
Batch:92442 Prep Method: 5030B
Analytical Method: 8260B
Sample
Amount Result % RPD
Parameter (ug/L) (ug/L) Q Dil % RPD Limit Analysis Date
Trichloroethene 54 48 1 11 20 12/17/20151807
Trichlorofluoromethane ND ND 1 0.00 20 12/17/20151807
Vinyl chloride 1.3 1.2 1 13 20 12/17/2015 1807
Xylenes(total) ND ND 1 0.00 20 12/17/2015 1807
Acceptance
Surrogate Q °/U Rec Limit
1,2-Dichloroethane-d4 97 70-130
Bromofluorobenzene 100 70-130
Toluene-d8 103 70-130
PQL=Practical quantitation limit P=The RPD between two GC columns exceeds 40% N=Recovery is out of criteria
ND=Not detected at or above the MDL J=Estimated result<PQL and>MDL +=RPD is out of criteria
Where applicable,all soil sample analysis are reported on a dry weight basis unless flagged with a"W'
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
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Volatile Organic Compounds by GC/MS - MS
Sample ID: QL09014-003MS Matrix: Aqueous
Batch:92442 Prep Method: 5030B
Analytical Method: 8260B
Sample Spike
Amount Amount Result % Rec
Parameter (ug/L) (ug/L) (ug/L) Q Oil %Rec Limit Analysis Date
Acetone 6.7 100 92 1 85 60-140 12/17/20151830
Benzene ND 50 55 1 111 70-130 12/17/20151830
Bromodichloromethane ND 50 54 1 107 70-130 12/17/20151830
Bromoform ND 50 47 1 94 70-130 12/17/20151830
Bromomethane(Methyl bromide) ND 50 50 1 99 60-140 12/17/2015 1830
2-Butanone(MEK) ND 100 97 1 97 60-140 12/17/2015 1830
Carbon disulfide ND 50 50 1 101 60-140 12/17/2015 1830
Carbon tetrachloride ND 50 51 1 103 70-130 12/17/2015 1830
Chlorobenzene ND 50 53 1 106 70-130 12/17/20151830
Chloroethane ND 50 52 1 105 60-140 12/17/20151830
Chloroform ND 50 46 1 92 70-130 12/17/20151830
Chloromethane(Methyl chloride) ND 50 60 1 121 20-158 12/17/2015 1830
Cyclohexane ND 50 54 1 108 70-130 12/17/20151830
1,2-Dibromo-3-chloropropane(DBCP) ND 50 49 1 98 70-130 12/17/2015 1830
Dibromochloromethane ND 50 55 1 111 70-130 12/17/20151830
1,2-Dibromoethane(EDB) ND 50 51 1 102 70-130 12/17/2015 1830
1,3-Dichlorobenzene ND 50 51 1 103 70-130 12/17/20151830
1,2-Dichlorobenzene ND 50 50 1 100 70-130 12/17/20151830
1,4-Dichlorobenzene ND 50 50 1 99 70-130 12/17/20151830
Dichlorodifluoromethane ND 50 64 1 127 60-140 12/17/20151830
1,1-Dichloroethane ND 50 53 1 106 70-130 12/17/20151830
1,2-Dichloroethane ND 50 50 1 101 70-130 12/17/20151830
trans-1,2-Dichloroethene ND 50 54 1 109 70-130 12/17/20151830
1,1-Dichloroethene ND 50 53 1 107 70-130 12/17/20151830
cis-1,2-Dichloroethene 0.66 50 53 1 106 70-130 12/17/20151830
1,2-Dichloropropane ND 50 55 1 110 70-130 12/17/20151830
trans-1,3-Dichloropropene ND 50 52 1 105 70-130 12/17/20151830
cis-1,3-Dichloropropene ND 50 54 1 107 70-130 12/17/20151830
Ethylbenzene ND 50 56 1 112 70-130 12/17/20151830
2-Hexanone ND 100 110 1 112 60-140 12/17/20151830
lsopropylbenzene ND 50 56 1 112 70-130 12/17/20151830
Methyl acetate ND 50 50 1 100 15-128 12/17/2015 1830
Methyl tertiary butyl ether(MTBE) ND 50 50 1 100 70-130 12/17/2015 1830
4-Methyl-2-pentanone ND 100 110 1 106 60-140 12/17/20151830
Methylcyclohexane ND 50 55 1 110 70-130 12/17/20151830
Methylene chloride ND 50 47 1 94 70-130 12/17/2015 1830
Styrene ND 50 55 1 110 70-130 12/17/20151830
1,1,2,2-Tetrachloroethane ND 50 51 1 102 70-130 12/17/20151830
Tetrachloroethene ND 50 57 1 114 70-130 12/17/20151830
Toluene ND 50 56 1 113 70-130 12/17/20151830
1,1,2-Trichloro-1,2,2-Trifluoroethane ND 50 47 1 93 70-130 12/17/20151830
1,2,4-Trichlorobenzene ND 50 51 1 102 70-130 12/17/20151830
1,1,1-Trichloroethane ND 50 55 1 110 70-130 12/17/20151830
1,1,2-Trichloroethane ND 50 53 1 107 70-130 12/17/20151830
PQL=Practical quantitation limit P=The RPD between two GC columns exceeds 40% N=Recovery is out of criteria
ND=Not detected at or above the MDL J=Estimated result=PQL and>MDL =RPD is out of criteria
Where applicable,all soil sample analysis are reported on a dry weight basis unless flagged with a"W'
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
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Volatile Organic Compounds by GC/MS - MS
Sample ID: QL09014-003MS Matrix: Aqueous
Batch:92442 Prep Method: 5030B
Analytical Method: 8260B
Sample Spike
Amount Amount Result % Rec
Parameter (ug/L) (ug/L) (ug/L) Q Dil %Rec Limit Analysis Date
Trichloroethene 0.56 50 58 1 115 70-130 12/17/20151830
Trichlorofluoromethane ND 50 51 1 103 60-140 12/17/20151830
Vinyl chloride ND 50 55 1 110 60-140 12/17/2015 1830
Xylenes(total) ND 100 110 1 110 70-130 12/17/2015 1830
Acceptance
Surrogate Q % Rec Limit
1.2-Dichloroethane-d4 97 70-130
Bromofluorobenzene 101 70-130
Toluene-d8 105 70-130
POL=Practical quantitation limit P=The RPD between two GC columns exceeds 40% N=Recovery is out of criteria
ND=Not detected at or above the MDL J=Estimated result<PQL and>MDL +=RPD is out of criteria
Where applicable,all soil sample analysis are reported on a dry weight basis unless flagged with a"W'
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
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Chain of Custody
and
Miscellaneous Documents
Shealy Environmental Services,Inc.
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.shealylab.corn

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07, ' MINI ' m
b 73______ -
3
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Urn Adound Mar Ancpcfrers Imo,rro?Wolof rewired kr awake LATA Sewole Disposal Pweb:e Naiad ICer.ratzhiur •• OC Rooturorwas i'lpoo4',4 CP
t J St.1111011:, 0 Rush mpecito D P=.?bil 0^Near n 5110:00f 4 Leif UVreNtwe n PanlAuLe ESki kr•.1.1 L.-Poison r.11virclas
1.fleikilashed b•i idisorzeA,, - } r'ne 1.n•Cekfla tot •Da4. , rano
il, 111J i 11:1 0
F.47,...,-."2--- (...: i 74 thr Z
2 freer:v.:alma, Cale Mrra i.Re:104d by Chin Tone 0
3.Firekquerrytta by Otte Tim 1 nicaima/by - Date nine
t.Arkiraashei or iDet , i ctr 4 Lebomk,-y•scwwour Sy ..4 (.4rte i i nine
c GhtE)e 1WV IS :US) l -n-e4-1-3-aU4PfdAIL . -2r_ iallAs : 10_30
Note:All sampies are rotaineci kr rour lieffitS frorr:receipt LAG Lem ONLY
unioss ether grrangainanta arm madc, rissaw nil k.,,radr) Pi..), Plc !ce rack j claearliula I
rarritouliort;kiklitE A YFli MN'Ream co ileinaloy mu:smnriate P,;NK-FrediDireia Cop/ Dert.cpben!Nurnoar F-A13 mow Culle.1.W.0 i-K114 i
i

SHEALY ENVIRONMENTAL SERVICES, INC.
s'K'sir Fa:irocra_vul Fcnicct.:r.:. Pace 1 rJ I
Uttrn:w.N.,enbc::kME'.1(ISC-7 tteplaoes(Air)9.21,1.1
Frr o ive nue:alae n 5
Sample Receipt Checklist(SRC)__�
Clic:N: 11,A17—"V 4 tP.Y_rlik tJ Cuolet Inspected byvdate: Ane 1 1 `V15._Lot#: LO 3 O Ir{ _. ..._
Mains of receipt: C 51.51 D Client FT UPS 2 FadF.r El (Mee.
Yes B No / 1.Wcrc custody scalsYprescnl or.:he exult.
_Yes Nc LI _ Ni leg ! 2. If culstody Feels were present,were they intact and unbroken?
pll strip 11): 15 — 1 0 a C'.!strip ID.
Cooler TiDfO iggitril tc:nperatcre upon:eceipt!Derived(corrected)temperature upon receipt:
)i.M1I ). _ ' I.(, °C of f r ''C. i I `{.
Mcihnd:LPem rerature Blank ❑Against Bottles IR Gun ID: L, , IR Gun Correction actor: O °C
Methcdofcoo'int: [/'WerTce ❑ Blue Ice El Dry Lc ❑ Near
I if tereperatum of any cooler exceeded 6.0°C,was Project Manager notified' PM
Yrs (]1 No[ �l .v notified by SRC,planet, note(circ:e one),ocher: .
(Fur eouiers received via commercial courier, PMs are to be notified
immediately.)
YesdNo C NA El4. 11 19u uaninerciul courier's packing slip attached to this form?
Y^s L� Nn❑ 5. Were Epp:melody (rel:nttui:; li dh xcivexl) fuulluYeeel?
Yes 1Z' No❑ NA 0 5a Were samples relinquished by client to commercial courier?
' YmNe El G. Were sample IDs listed on the COC?
Yes E.,/ Nc U 7. Were sample IDs listed VII all sample cunluinere1
Yes 7 No❑ _ K. Was collection date&time listed on the CCK'?
_Yes g� NeC I _ 9. Was collection date&time listed on ell sample contair.ers?
Yes ( No ID10.Did all container label information(Ii),date,t:n►e)agree with the COC?
Ycs [ . Ne❑ 11. Were tests to be performed listed or.the COC?
Yes _ a[-1 Nf 12. Did al:samples arrive in the proper containers for each test?
Ycs No0 ` 13. Did all containers arrive good condition(unbroken,lids on,etc.)?
Yes E :n No❑ 14. Was adequate sample voieme available?
Yes [Z. .U 15- Were al samples rorcivcd within y_the holding time or 48 hours,whichever
cornea first?
Yes U No 4. 16. Were any sunrple s cunluinu�missing?
Yes 0 No�/1� 17. Were there any excess samples not listed on CDC'"
Yes ❑,,NO F2T NA❑ I S. Were bubbles present>"pec-size"(!4"or emm in diameter):n any VOA vials?
Yes 0 No❑ NA 19. Were ail matulsfO&GIHEM/nutrient elm:plies received rel a pH of e2?
Yes U No 0 _ NA 20. Were all cyanide andtor sul de samples received at a pH>:2?
Yep u Nol=1 N;( 21. Were a]applicable N11311'KN/cyaride'phennl(0)_2tng,7-)ramplea free of
_ residual rhlorFne?
Yes ❑ No D NA 22. Were collection temperatures documented on the CCC for NC samp:es?
Yee 0 No❑ A�/23.W.rcc;ical reinurks/reque is(i.e.rrceesleJ dilutione,MS-hMSD t:oig:wlions,
I - etc...)correctly transcribed from the COC into the comarei,t section iii LIMS?
Yes [ No l7oaL 24.Wus the queer number used.akcn from the eoulainer:abel?
Sample Preservation (Must be completed for any sample(s)incorrectly preserved cr with headspace.)
Sa:nplr.(s) were received incorrectly preserved and were adjusted
accordingly in sample receiving with (H2SO4,11NO3,HC1,NaOH)using SR# -
Sa:nple(s) , -_ _ were received with bubbles>6 mm in diameter.
Sample(s) were received with TRC-•0.2 mg/L(If 421 is No)
SC Drinking Water Project Samples)pfd verified to be:;2 by Date
Sa:nple(s) were not received at a pH of-e2 and were adjusted accordingly using SR#
Sample labels applied by:_,__ ___,,,____ Verified bye __ _ ___ _ Dare: ./_
Comment:
Shealy Environmental Services.Inc.
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.shealylab.com

Effluent Toxicity Report Form - Chronic Pass/Fail and Acute LC50 Date: 12/10/15
Facility: NCDOT-PITTSBORO NPDES#: NC0087629 Pipe#: 001 County: CHATHAM
Laboratory Performing Test: PACE ANALYTICAL
n Comments: __
X
Sig ture oaf Ope attorr�in Responsible Charge _
3 X • V�/� 1�lVit
Sig t re of Laboratory=Supervisor * PASSED: -4.59% Reduction *
t MOM 1\ 4k5/122641=Mil
f Work Order: 92277814 Environmental Sciences Branch
MAIL ORIGINAL TO: Div. of Water Quality
t N.C. DENR
F 1621 Mail Service Center
p Raleigh, North Carolina 27699-1621
North Carolina Ceriodaphnia
Chronic Pass/Fail Reproduction Toxicity Test Chronic Test Results
Calculated t = -0.830
Tabular t = 2.508
CONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 % Reduction = -4.59
% Mortality Avg.Reprod.
# Young Produced 20 32 30 26 24 29 28 27 28 24 29 30
0.00 27.25
Control Control
Adult (L)ive (D)ead L L L L L L L L L L L L
8.33 28.50
Treatment 2 Treatment 2
Effluent %: 90%
TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 Control CV
fl
12.133% PASS FAIL
,
# Young Produced 18 33 31 28 32 28 31 28 30 27 25 31 % control orgs X
producing 3rd
brood Check One
j Adult (L) ive (D)ead D L L L L L L L L L L L 100%
1st sample 1st sample 2nd sample Complete This For Either Test
pH Test Start Date: 12/02/15
Control 7.84 7.82 7.65 8.04 8.25 8.00 Collection (Start) Date
Sample 1: 12/01/15 Sample 2: 12/03/15
Treatment 2 7.86 7.87 7.93 8.69 8.23 8.20 Sample Type/Duration 2nd
1st P/F
s s s Grab Comp. Duration D
t e t e t e I S S
a n a n a n Sample 1 X hrs L A A
✓ d r d r d U M M
t t t Sample 2 X hrs T P P
1st sample 1st sample 2nd sample
D.O. Hardness(mg/1) 47
Control 7.90 7.51 7.85 7.92 7.76 7.30
Spec. Cond. (µmhos) 268 452 455
Treatment 2 7.80 7.60 7.59 7.03 7.67 7.23
Chlorine(mg/1) <0.1 <0.1
LC50/Acute Toxicity Test Sample temp. at receipt(°C) 2.7 5.6
(Mortality expressed as %, combining replicates)
- Note: Please
% % % % % % % °% % % Concentration Complete This
Section Also
% % % % % % % % % % Mortality
start/end start/end
LC50 = % Method of Determination Control
95% Confidence Limits Moving Average Probit
% -- % Spearman Karber _ Other - High
Conc.
pH D.O.
Organism Tested: Ceriodaphnia dubia Duration(hrs) :
Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41)

1 Effluent Toxicity Statistical Results - Chronic Pass/Fail Date: 12/10/15
I Facility: NCDOT-PITTSBORO NPDES#: NC0087629 Pipe#: 001 County:CHATHAM
Laboratory Performing Test: PACE ANALYTICAL
Reduction: -4.59$ CONTROL 90% Effluent
# Replicates 12 12
i
0 Female Live 12 11
Adult Male 0 0
F Adult Dead 0 1
E
Adult Mortality 0.00% 8.33%
# Neonates 327 342
IMean # Neonates 27.250 28.500
E Standard Deviation 3.306 4.034
1
F Coefficient of Variation 12.1330
Fisher's Exact Test
A = 12 B = 12 a = 12 b = 11
a/A = 1.00 b/B = 0.92
Success is: survival
Critical b value = 8
11 > 8
The test concludes that the proportion of survival is not
significantly different for the control and the effluent groups.
Test Passes!
SHAPIRO-WILK'S TEST FOR NORMAL DISTRIBUTION OF DATA
ORDERED OBSERVATIONS
i Group Neonates Centered i Group Neonates Centered
1 E 18 -10.5000 13 C 28 0.7500
2 C 20 -7.2500 14 E 30 1.5000
3 E 25 -3 .5000 15 C 29 1.7500
4 C 24 -3.2500 16 C 29 1.7500
5 C 24 -3.2500 17 E 31 2.5000
6 E 27 -1.5000 18 E 31 2.5000
7 C 26 -1.2500 19 E 31 2.5000
8 E 28 -0.5000 20 C 30 2.7500
9 E 28 -0.5000 21 C 30 2.7500
10 E 28 -0.5000 22 E 32 3.5000
11 C 27 -0.2500 23 E 33 4.5000
12 C 28 0.7500 24 C 32 4.7500

6
SHAPIRO-WILK'S TEST FOR NORMAL DISTRIBUTION OF DATA (cont.)
COEFFICIENTS AND DIFFERENCES
i x(n-i-1) x(i) a(i) x(n-i-1) - x(i)
1 4.7500 -10.5000 0.4493 15.2500
2 4.5000 -7.2500 0.3098 11.7500
3 3.5000 -3.5000 0.2554 7.0000
V 4 2.7500 -3.2500 0.2145 6.0000
5 2.7500 -3.2500 0.1807 6.0000
6 2.5000 -1.5000 0.1512 4.0000
7 2.5000 -1.2500 0.1245 3.7500
p 8 2.5000 -0.5000 0.0997 3.0000
9 1.7500 -0.5000 0.0764 2.2500
10 1.7500 -0.5000 0.0539 2.2500
11 1.5000
-0.2500 0.0321 1.7500
12 0.7500 0.7500 0.0107 0.0000
1
1
W = X 268.0129
i 299.2500
Calculated W = 0.896 Critical W = 0.884
0.896 0.884
The reproduction data is normally distributed
evaluated at a 99% confidence interval.
Test Passes!
F test for Homogeneity of Variance
Effluent variance 16.2727
F = = = 1.49
Control variance 10.9318
Numerator degrees of freedom: 11 Denominator degrees of freedom: 11
Critical F = 5.32
1.49 s 5.32 =► The Test PASSES, the variances of the two groups
are significantly the same, homogeneous.

EQUAL VARIANCE t TEST
27.3 - 28.5
t = = -0.830
1.506
Degrees of freedom = 22
Critical t = 2.508
-0.830 < 2.508
Test passed. There is not a significant difference in reproduction
between the Control and the effluent evaluated at a 99% confidence interval.
P
}
Chronic Test PASSES

Ceriodaphnia dubia Chronic Pass/Fail Test
Days Fed By Time
Client: W,
-0C)-k- -F1-n- iDeo NPDES#:NC 0 ?"15-A"i'r%'?(11
Culture Transfer(Date/Time): 1;.--i- / 14-49 Organism Born(Date/Time): ,a`�.-1`j /%v.D,Ae Day OtAge of Organism: '.,1 n Time Fed(Culture): Organism Source: a t
Dilution Water Batch: 4 G Temp.Dilution Water: 7 `S Randomized: V Incubator: `� c Day 24 -,--T-
Start
T
Start Date: 12-ZS-( Day lc Time: O Analyst: Day 3 8, i 1 O5
151 Transfer Date:12"4- 6 Time: ` Analyst: ¶ Day 4 )4i
2"a Transfer Date: - Time: 1 k l Analyst:
Ending Date: ;. Time: y Analyst: i— Reviewed by: , � Day 5 Day 6 3i ,c--)to
--)to
Replicate
1 2 1 3 4 5 6 7 8 9 1 10 11 12 Collection(Start)Date:
Day2 0 0 0 0 0 0 0 0 0 0 0 0
Adult:Live,Dead L L L L L L _ L L L L L L 1St Sample: -1 -I S
Control Day 5 (r, `± 5 7/10 'C , ( 5' `�- `6/[(--) 2nd Sample: /oC" 3- }5
Adult:Live,Dead L.., L— L L L 1.-- Lr L 1_ C__. L_ Z.__
Day 7 Cog 101 14 lo[2 !o/i 1 3/w i- to,//a 0,/;r,3 5{/;3 Ali 1 c1./(.� '2
Adult:Live,Dead 1___ 11 L. j,. L--- L. L - /r L. ) f.
_ J (,/
.
Total Li 12,-).- 3 D K _ -4i `-0)-5Z) 0,-7.9--1 , _7) ---AQ01 ?5-c.) Grab Composite Duration
Replicate
1 2 3 4 5 6 7 8 9 10 11 12 Sample
Day 2 0 0 0 0 0 0 0 0 0 0 0 0 god
Adult:Live,Dead L L L L L L L L L L L L Sample V
Effluent Day 5 q '-I- ' (a nci -R-/j1 (3 5 S j S `4--
�fa��o Adult:Live,Dead . L.- L L L__- (; 1.— c.-- (.i C_ 1 c----Day 7 \\ ,p11& 9/,,if, 104 io/ /i /./4 /O/i iv/i'2 1113 /i
4-
Adult:Live,Dead 2.-
Total 1 0ID -)•\ ?..-A oL ;` ,`6 .,--7e,,,\ ')`' `.'D .---i- ,-.,6- •,?j\
pH I Start End Start End I Start End Control 1"Sample 12"a Sample
- it
u� � ,Control _� � ---q-.159., -- _(0°j ,`).ti 1Q k.d Hardness a 1,
Treatment - •,i� •�7-1- " .cy ' '.Loci, ,. .. (m_/L) E ; ,, ,
DO I Start End Start End Start End Conductivity
Control �- .S 1 .`s j -4, 2 -,�-Lo .�c7 Chlorine ;
Treatment c
m 2 �*~
Control Start End Start End Start End Sample Temp. t k
2 - co
. . h14cz
Treatment 4.,"9' 2Z,4:, 2 g 2 2 124-,, . , 24,CpH 100% Mg1 ,Of --4" -I- p��
U t
�.�. _�::«.�..,__._a . s:4.., ..�.__,

Document Name: Date Revised:June 12.2015
Bioassay Chain of Custody Page 1 of 1
rf A 7 Document Number: Issuing Authority.
acef nal lcc l F-RAI--CS-007-rev.02 Pace Carolinas Quality Office
Bioassay Chain of Custody Form
Facility Name: fNL' °7/ Pi 4-s( re)
Address: Pi G. / 4,Z,14"s..- P.O. Box:
2A 23 c1i /CYU Phone#:_("?
(S)-e-d„ ( 0 C L 1I c 4-l-4 Al(-- Contact: Z-- a
County: NPDES permit#: N L-O O t'`J G2`i pipe: O 0
% Effluent Dilution (IWC): Plant Flow: NI/A--
Select Test Method:
C.dubia Pass/Fail Chronic 600CPFCNC 0 P.promelas Pass/Fail Acute 600A PFPpr
❑ C.dubia Full Range Chronic 600C FRCNC ❑ P,promelas Full Range Acute 600A FRPpr
0 C.dubia Pass/Fail Acute 600A PFCdu ❑ P.promelas Full Range Chronic 821C FRPpr
0 M.bahia Pass/Fail Acute 600A PFMba
Sample Collector: Print I ick.v
Signature )
Sample Type:
Composite
Date Started Time: AM or PM
Date EndedTime: AM or PM
Samples per Hr: �#Hrs: S
Grab
Date: /Z -i -I Time: Q tic 3r PM
Sample Volume: 2,1+s Chilled during Collection? es or No
Method of Transportation to the Lab:
Chain of Custod Release
Relin• ish;d By Date Time Received By Date Time
19-'1-LC 1v>VO )
Comments:
For Pace Anal pica I Ise Only
Pace Work Order Number:""- iZZ "N01 y
Receiving Temperature: '), - J 1,c Received By: �2. ,
Pace Analytical Services, Inc.Address:6701 Conference Dr.,Raleigh,NC 27607 Phone:[phone]

Document Name' Date Revised:June 12,2015
)5(7 Boassay Chain of Custody Page 1 of 1
- e.`/IaI )Cr3J Document Number. Issuing Authority:
F-RAL-CS-007.rev.02 Pace Carolinas Quality Office
Bioassay Chain of Custody Form
Facility Name: G D o"r /p, ‘)c-to
Address: /.1��� (�/,� P.O. Box:
g 2S3 S - I RYvov Phone# : (��� Wj7 `/ 62.3
SfS2 /o o LLe-r to Contact: �v„.,0
County : G(Ao NPDES permit#: .^IG oo $762.-it pipe: CIO
% Effluent Dilution (IWC): 71-1/,4 Plant Flow: 11/ ,%
Select Test Method:
C.dubia Pass/Fail Chronic 600CPFCNC 0 P.promelas Pass/Fail Acute 600A PFPpr
❑ C.dubia Full Range Chronic 600C FRCNC 0 P.promelas Full Range Acute 600A FRPpr
❑ C.dubia Pass/Fail Acute 600A PFCdu ❑ P.promelas Full Range Chronic 821C FRPpr
❑ M.bahia Pass/Fail Acute 600A PFMba
Sample Collector: Print '7 n v,3 h i l l
Signature c—C'
Sample Type:
Composite
Date Started Time: At/1 or PM
Date Ended Time: AM� or PM
Samples per Hr: #Hrs:
Grab
Date: /2-3-(S Time: f q LiD AM or&
Sample Volume: (61'5 Chilled during Collection? 9or No
Method of Trans•ortation to the Lab:
Chain of Custody Release
Relinquished By Date Time Received By Date Time
0 TN:4 —
Comments:
For Pace Analytical, Inc. Use Only
Pace Work Order Number: . n
Receiving Temperature: Received By: 11—V
Pace Analytical Services, Inc.Address:6701 Conference Dr.,Raleigh, NC 27607 Phone:[phone]

hart '' hi
� ckman
SMARTER ENVIRONMENTAL SOLUTIONS
Sent Via Fed Ex
February 1, 2016
.41 Ith
NC DEQ ��rneRs�rtt
Division of Water Quality and Natural Resources
Division of Water Quality/NPDES UNIT
1617 Mail Service Center
Raleigh, NC 27699-1617
RE: National Pollution Discharge Elimination System Permit NC0087629 Renewal Application
Discharge 001
NCDOT Asphalt Testing Site No. 6-48 RECEIVEDINCDEQ/DWR
240 Sugar Lake Road, Pittsboro, North Carolina
H&H Job No. DOT-515 FEB 0 2 2016
Water Quality
Dear Sir or Madam: Permitting Section
On behalf of the North Carolina Department of Transportation, please find the attached NPDES
Permit Application - Short Form C — GW for renewal of the referenced National Pollution
Discharge Elimination System Permit. There are no proposed changes to the treatment system or
discharge limits. Based on the ongoing monitoring results, the system discharge is in
compliance. Should you have any questions or need additional information, please do not
hesitate to call us at [phone].
Respectfully,
Hart& Hickman, PC
Af-L-111-
Jeff Albano, PG Matt Bramblett, PE
Project Geologist Principal
Attachments:
2923 South Tryon Street,Suite 100 3334 Hillsborough Street
Charlotte,NC 28203 Raleigh, NC 27607 www.harthickman.com
704.586.0007 main 919.847.4241 main