WQ0002503_Monitoring - 03-2024_20240501

Monitoring Report Submittal
.....................................................
Permit Number#* WQ0002503
Name of Facility:* Frit Car, Inc.
Month: * March
Report Information
Type *
NDMR, NDAR-1, NDAR-2, NDMLR
Confirmation Email Address: * [e-mail]
Name of Submitter: * Connie Pettis
Signature:
Year:* 2024
Upload Document*
NDMR NDAR LAB MARCH 2024.pdf
PDF Only
5.66MB
Please upload one PDF containing all applicable monitoring reports
(i.e., NDMR, NDAR-1, NDAR-2, NDMLR, GW-59).
Date of submittal: 5/1/2024
This will be filled in automatically
Initial Review
Reviewer: Wanda.Gerald

Is the project number correct?* W00002503
Is the monitoring report accepted?* Yes NO
Regional Office* Washington
Reviewer: _anonymous
Review Date: 5/13/2024

FORM: NDAR-1 08-11 NON -DISCHARGE APPLICATION REPORT (NDAR-1) Page of�
Permit • 0111 1
• Craven
Month:1
irrigation
• occur--

FORM: NDAR-1 08-11 NON -DISCHARGE APPLICATION REPORT (NDAR-1) Page 9, of a
Did the application rates exceed the limits in Attachment B of your permit?
Were adequate measures taken to prevent effluent ponding in or runoff from the sites?
Was a suitable vegetative cover maintained on all sites as specified in your permit?
Were all setbacks listed in your permit maintained for every application to each permitted site?
Were all freeboards maintained in accordance with the specified freeboard heights in your permit?
Compliant ❑ Non -Compliant
❑� Compliant ❑ Non -Compliant
❑✓ Compliant ❑ Non -Compliant
❑� Compliant ❑ Non -Compliant
❑� Compliant ❑ Non -Compliant
If the facility is non -compliant, please explain in the space below the reason(s) the facility was not in compliance. Provide in your explanation the date(s) of the non-compliance and describe the corrective
action(s) taken. Attach additional sheets if necessary.
Operator in Responsible Charge (ORC) Certification
Permittee Certification
ORC: Jacob Kazdan
Permittee:
Frit Car, Inc.
Certification No.: 26718
Signing Official: Michael Newby
Grade: Phone Number: 585-773-0914
Signing Official's Title: Senior Vice President
Has the ORC changed since the previous NDAR-1? ❑ Yes 0 No
Phone Numbe . 251-867-7752 Permit Exp.: 2/28/29
Z,_
4/29/24
4 2 / 9/24
gnature Date
Signmr-r-J,
Date
By th' ture, I certify that this report is accurrate and complete to the best of my knowledge.
I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance
with a system designed to assure that all qualified personnel properly gathered and evaluated the information submitted. Based on my
inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the
information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations.
Mail Original and Two Copies to:
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, North Carolina 27699-1617

FORM: NDMR 07-13 NON -DISCHARGE MONITORING REPORT (NDMR) Page)of )
Permit No.: W00002503
Facility Name: Frit Car, Inc.
County: Craven
Month: March
Year: 2024
PPI:
Flow Measuring Point: ❑ Influent ❑ Effluent ❑ No flow generated
Parameter Monitoring Point: ❑ Influent ❑ Effluent ❑ Groundwater Lowering ❑ Surface Water
Parameter Code -►
50050
00400
00945
00310
00940
C0665
00610
00680
00660
00929
70300
C0530
01045
00625
00620
00600
U
0
C
O
U
a
0
3
to
O
N
o
a O
v
o
a
M
p
E
E
O
c
A C
0
N
o
m
r
0
a
E
a
N
ONE Q
~
O
Q
v
c
=
.0
R
-
a> 0)
Y
mZ
o
F
N
_~N`
(Z 0)O
z
24-hr
hrs
GPD
su
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L 1
mg/L
mg/L
mg/L
mg/L
1
07:00
8
0
31.3
283
6260
902
37200
66300
1700
70.8
2
3
4
07:00
8
5
07:00
8
120
7
6 1
07:00
8
7
07:00
8
8
07:00
8
9
10
11
07:00
8
121
07:00
8
13
07:00
8
14
07:00
8
15
07:00
8
150
7.1
16
17
181
07:00
19
07:00
8
400
7.1
20
07:00
8
21
07:00
8
22
07:00
8
0
23
24
25
07:00
8
26
07:00
8
0
27
07:00
8
28
07:00
8
0
29
07:00
8
0
7.1
30
31
Average:
84
31.30
283.00
#REF!
90.20
137,200,00
66,300.00
1,700.00
70.80
Daily Maximum:
400
#REF!
31.30
283.00
#REF!
90.20
37,200.00
66,300.00
1.700.00
70.80
Daily Minimum:
0
#REF!
31.30
283.00
#REF!
90.20
37,200.00
66,300.00
1,700.00
70.80
Sampling Type:
Monthly Avg. Limit:
Daily Limit:
Sample Frequency:

FORM: NDMR 07-13 NON -DISCHARGE MONITORING REPORT (NDMR) Page ` of
Permit No.: W00002503
Facility Name: Frit Car, Inc.
County: Craven
Month: March
Year: 2024
PPI:
Flow Measuring Point: ❑ Influent 0 Effluent ❑ No Flow generated
Parameter Monitoring Point: ❑ Influent Effluent ❑ Groundwater Lowering ❑ Surface water
Parameter Code 0
50050
01027
01034
01042
01051
01067
01092
32730
>.
Q
Q£
F
O
C
O
E .�.
U
30
LL
N
U
E
M
I_
.0
V
d
Q
U
a
M
"'�
d
Y
Z
v
C
N
N�
c) m
p N
p
a
24-hr
hrs
GPD
mg/L I
mg/L
mg/L
mg/L
I mg/L
mg/L
mg/L
1
07:00
8
0.55
2
3
4
07:00
8
5
07:00
8
6
07:00
8
7
07:00
8
8
07:00
8
9
10
11
12
07:00
8
13
07:00
8
14
07:00
8
15
07:00
8
16
07:00
8
17
18
19
07:00
8
20
07:00
8
21
07:00
8
22
07:00
8
23
07:00
8
24
25
26
07:00
8
27
07:00
8
28
07:00
8
29
07:00
8
30
07:00
8
31
Average:
#DIV/0!
0.55
Daily Maximum:
0
0.55
Daily Minimum:
0
0.55
Sampling Type:
Monthly Avg. Limit:
Daily Limit:
Sample Frequency:

FORM: NDMR 07-13 NON -DISCHARGE MONITORING REPORT (NDMR) Page of �-1)
Sampling Person(s) Certified Laboratories
Name: Danny Hornbeck Name: Pace Analytical
Name: Name:
Does all monitoring data and sampling frequencies meet the requirements in Attachment A of your permit? Q Compliant ❑ Non -Compliant
If the facility is non -compliant, please explain in the space below the reason(s) the facility was not in compliance. Provide in your explanation the date(s) of the non-compliance and describe the corrective
action(s) taken. Attach additional sheets if necessary.
Operator in Responsible Charge (ORC) Certification
Permittee Certification
ORC: Jacob Kazdan
Permittee: Frit Car, Inc.
Certification No.: 26718
Signing Official: Michael Newby
Grade: SI Phone Number: 252-638-2675
Signing Official's Title: Senior Vice President
Has the ORC changed since the previous NDMR? 2 Yes ❑ No
Phone Number: 251-867-7752 Permit Expiration: 2/28/2029
4/29/2024
4/29/2024
Signature Date
Signature Date
By this signature, I certify that this report is accurrate and complete to the best of my knowledge.
I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in
accordance with a system designed to assure that all qualified personnel properly gathered and evaluated the information
submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for
gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am
aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for
knowing violations.
Mail Original and Two Copies to:
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, North Carolina 27699-1617

(� aceAnalytical
4.
ANALYTICAL REPORT
April 25, 2024
Frit Car Inc.
Sample Delivery Group
Samples Received:
Project Number:
Description:
L1725772
04/15/2024
Bridgeton Facility Monthly
Report To: Connie Pettis
2012 US Hwy 17N
New Bern, NC 28560
Entire Report Reviewed By: 4�a4�
Heather J Wagner
Project Manager
Results relate onty to the items tested or calibrated and are reported as rounded values. This test report shall not be
reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace
Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and
ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided,
and as the samples are received.
t
3
.�
ACCOUNT: PROJECT: SDG: DATEMME: PAGE:

TABLE OF CONTENTS
Cp: Cover Page
Tc: Table of Contents
2
Ss: Sample Summary
3
Cn: Case Narrative
4
Sr: Sample Results
5
EFFLUENT L1725772-01
5
Qc: Quality Control Summary
7
Gravimetric Analysis by Method 2540 C-2011
7
Gravimetric Analysis by Method 2540 D-2015
8
Wet Chemistry by Method 300.0
9
Wet Chemistry by Method 350.1
11
Wet Chemistry by Method 351.2
12
Wet Chemistry by Method 365.4
14
Wet Chemistry by Method 420.4
15
Wet Chemistry by Method 4500H+ B-2011
16
Wet Chemistry by Method 5310 B-2014
17
Metals (ICP) by Method 200.7
18
GI: Glossary of Terms
20
Al: Accreditations & Locations
21
Sc: Sample Chain of Custody
22
FS
[Cn
E
FQ-c
[GI
E
FC
ACCOUNT: PROJECT: SDG: DATE/TIME:
PAGE:

SAMPLE SUMMARY
EFFLUENT L1725772-01 WW
Collected by
Kazdan
Collected date/time
04/12/2409:06
Received date/time
04115/2412:15
[CP
Method
Batch
Dilution
Preparation
Analysis
Analyst
Location
date/time
date/time
E
Gravimetric Analysis by Method 2540 C-2011
WG2268321
1
04/16/24 22:16
04/17/2412:05
DLS
Mt. Juliet, TN
Gravimetric Analysis by Method 2540 D-2015
WG2269989
1
04/19/2410:15
04119/2413:51
DLS
Mt. Juliet, TN
Wet Chemistry by Method 300.0
WG2272238
1
04/24/24 04:43
04/24/24 04:43
DLH
Mt. Juliet, TN
Wet Chemistry by Method 300.0
WG2272238
5
04/24/24 05:32
04/24/24 05:32
DLH
Mt. Juliet, TN
Wet Chemistry by Method 350.1
WG2270729
200
04/20/2414:25
04/20/2414:25
BMD
Mt. Juliet, TN
rCn
Wet Chemistry by Method 351.2
WG2269220
10
04/17/2417:29
04/19/24 01:02
LDT
Mt. Juliet, TN
Wet Chemistry by Method 365.4
WG2269789
2000
04/1712417:29
04/18/2416:37
JAS
Mt. Juliet, TN
Wet Chemistry by Method 420.4
WG2270390
1
04/19/2416:25
04/22/2412:17
JAS
Mt. Juliet, TN
Fr
Wet Chemistry by Method 4500H+ B-2011
WG2268107
1
04116/2419:20
04/16/2419:20
KRB
Mt. Juliet, TN
Wet Chemistry by Method 5310 B-2014
WG2268284
5
04/17/24 01:32
04/17/24 01:32
ASH
Mt. Juliet, TN
C
F
Metals (ICP) by Method 200.7
WG2269011
50
04/18/24 06:49
04/19/2411:22
JTM
Mt. Juliet, TN
ACCOUNT: PROJECT: SDG:
DAT E/T M E: PAGE:

CASE NARRATIVE
All sample aliquots were received at the correct temperature, in the proper containers, with the
C
appropriate preservatives, and within method specified holding times, unless qualified or notated within
the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples E
have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative, a non-conformance form r
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my SS
knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory, and no information or data have been
knowingly withheld that would affect the quality of the data.
E
PC
4�jj rGl
Heather J Wagner
Project Manager AI
EC
Sample Delivery Group (SDG) Narrative
The following analysis were performed from an unpreserved, insufficiently or inadequately preserved sample.
Lab Sample ID Project Sample ID Method
L1725772-01 EFFLUENT 200.7. 351.2, 350.1, 365.4, 420.4
ACCOUNT: PROJECT: SDG:
DATE/TIME: PAGE:

EFFLUENT
SAMPLE RESULTS - 01
Collected date/time: 04/12/24 09:06
L1725772
Gravimetric Analysis by Method 2540 C-2011
Result Qualifier
RDL
Dilution
Analysis
Batch
Analyte ug/l
ug/l
date / time
Dissolved Solids 66300000
1000000
1
04/17/202412:05
WG2268321
Gravimetric Analysis by Method 2540 D-2015
Result Qualifier
RDL
Dilution
Analysis
Batch
Analyte ugfl
ug/l
date / time
Suspended Solids 1700000
125000
1
04/19/202413:51
WG2269989
Wet Chemistry by Method 300.0
Result Qualifier
RDL
Dilution
Analysis
Batch
Analyte ug/I
ug/I
date / time
Chloride 283000
5000
5
04/24/2024 05:32
WG2272238
Sulfate 31300
5000
1
04/24/2024 04:43
WG2272238
Wet Chemistry by Method 350.1
Result Qualifier
RDL
Dilution
Analysis
Batch
Analyte ug/l
ug/I
date / time
Ammonia Nitrogen 51600
50000
200
04/20/202414:25
WG2270729
Wet Chemistry by Method 351.2
Result Qualifier
RDL
Dilution
Analysis
Batch
Analyte ug/I
ug/I
date / time
Kjeldahl Nitrogen, TKN 70800
2500
10
04/19/2024 01:02
WG2269220
Sample Narrative:
L1725772-01 WG2269220: Dilution due to matrix interference
Wet Chemistry by Method 365.4
Result Qualifier
RDL
Dilution
Analysis
Batch
Analyte ug/I
ug/I
date / time
Phosphorus,Total 6260000
200000
2000
04PB/202416:37
WG2269789
Wet Chemistry by Method 420.4
Result Qualifier
RDL
Dilution
Analysis
Batch
Analyte ug/l
ugh
date / time
Total Phenol by 4AAP ND
40.0
1
04/22/202412:17
WG2270390
Wet Chemistry by Method 4500H+ B-2011
Result Qualifier Dilution Analysis Batch
Analyte su date / time
pH 6.41 1-3 1 04/16/202419:20 WG2268107
Sample Narrative:
L1725772-01 WG2268107: 6.41 at 18.1C
Wet Chemistry by Method 5310 B-2014
Result Qualifier RDL Dilution Analysis Batch
Analyte ug/I ug/I date / time
TOC (Total Organic Carbon) 90200 5000 5 04/17/2024 01:32 WG2268284
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

EFFLUENT SAMPLE RESULTS - 01
Collected date/time: 04/12/24 09:06 L1725772
Metals (ICP) by Method 200.7
Result
Qualifier RDL
Dilution
Analysis
Analyte
ug/1
ug/I
date / time
Cadmium
ND
100
50
04/19/202411:22
Chromium
ND
500
50
04/19/202411:22
Copper
ND
500
50
04/19/202411:22
Iron
ND
5000
50
04/19/202411:22
Lead
ND
250
50
04/19/202411:22
Nickel
550
500
50
04/19/202411:22
Sodium
37200000
50000
50
04/19/202411:22
Zinc
ND
2500
50
04/19/202411:22
Batch
WG2269011
WG2269011
WG2269011
WG2269011
WG2269011
WG2269011
WG2269011
WG2269011
ACCOUNT: PROJECT: SDG: DATE/TIME:
PAGE:

WG2268321 QUALITY CONTROL SUMMARY
Gravimetric Analysis by Method 2540 C-2011
L1725772-01
Method Blank (MB)
(MB) R4059799-1 04/17/2412:05
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/I ug/I ug/l
Dissolved Solids U 10000 10000
L1725314-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1725314-01 04/17/2412:05 • (DUP) R4059799-3 04/17/2412:05
Original Result DUP Result Dilution DUP RPD
DUP Qualifier DUP RPD
Limits
Analyte ug/I ug/I %
%
Dissolved Solids 281000 299000 1 6.21
10
L1726004-20 Original Sample (OS) • Duplicate (DUP)
(OS) L1726004-20 04/17/2412:05 • (DUP) R4059799-4 04/17/2412:05
Original Result DUP Result Dilution DUP RPD
DUP Qualifier DUP RPD
Limits
Analyte ug/I ug/I %
%
Dissolved Solids 352000 368000 1 4.44
10
Laboratory Control Sample (LCS)
(LCS) R4059799-2 04/17/2412:05
Spike Amount LCS Result LCS Rec. Rec. Limits
LCS Qualifier
Analyte ug/I ug/I % %
Dissolved Solids 8800000 8440000 95.9 85.0-115
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

WG2269989
Gravimetric Analysis by Method 2540 D-2015
Method Blank (MB)
(MB) R4061103-1 04/19/2413:51
MB Result
Analyte ug/I
Suspended Solids U
MB Qualifier MB MOIL MB RDL
ug/I ug/1
2500 2500
L1725711-01 Original Sample (OS) • Duplicate (DUP)
QUALITY CONTROL SUMMARY
L1725772-01
(OS) L1725711-01 04/19/2413:51 • (DUP) R4061103-3 04/19/2413:51
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/I ug/1 °i %
Suspended Solids 15600 16800 1 7.41 10
L1725926-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1725926-01 04/19/2413:51 • (DUP) R4061103-4 04/19/2413:51
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/I %
Suspended Solids 9000 9600 1 6.45 10
Laboratory Control Sample (LCS)
(LCS) R4061103-2 04/19/2413:51
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte ugh ug/I % %
Suspended Solids 773000 752000 97.3 85.0-115
ACCOUNTPROJECT: SDG:
DATE/TIME:
PAGE:

WG2272238 QUALITY CONTROL SUMMARY
Wet Chemistry by Method 300.0
L1725772-01
Method Blank (MB)
(MB) R4061911-1 04/23/24 23:00
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/I ugll ug/I
Chloride U 379 1000
Sulfate U 594 5000
L1723817-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1723817-01 04/23/24 23:57 • (DUP) R4061911-3 04/24/24 00:13
Original Result DUP Result Dilution DUP RPD
DUP Qualifier DUP RPD
Limits
Analyte ug/I ug/I %
%
Chloride 8480 8450 1 0.329
15
Sulfate 8390 8410 1 0.261
15
L1726004-21 Original Sample (OS) • Duplicate (DUP)
(OS) L1726004-21 04/24/24 07:07 • (DUP) R4061911-6 04/24/24 07:23
Original Result DUP Result Dilution DUP RPD
DUP Qualifier DUP RPD
Limits
Analyte ug/I ug/I %
%
Chloride 7990 7980 1 0.125
15
Sulfate ND ND 1 3.81
15
Laboratory Control Sample (LCS)
(LCS) R4061911-2 04/23/24 23:16
Spike Amount LCS Result LCS Rec. Rec. Limits
LCS Qualifier
Analyte ug/I ug/I % %
Chloride 40000 39400 98.4 90.0-110
Sulfate 40000 40800 102 90.0-110
L1723817-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1723817-01 04/23/24 23:57 • (MS) R4061911-4 04/24/24 00:29 • (MSD) R4061911-5 04/24/24 00:45
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
RPD Limits
Analyte ug/I
Ug/I
ug/I
ug/I
%
%
%
%
%
Chloride 40000
8480
44500
45000
90.1
91.4
1 80.0-120
1.09
15
Sulfate 40000
8390
46100
46200
94.2
94.6
1 80.0-120
0.374
15
ACCOUNT: PROJECT: SDG:
DATE/TIME:
PAGE:

WG2272238
Wet Chemistry by Method 300.0
L17260O4-21 Original Sample (OS) - Matrix Spike (MS)
QUALITY CONTROL SUMMARY
L1725772-01
(OS) L1726004-21 04/24/24 07:07 - (MS) R4061911-7 04/24/24 07:39
Spike Amount
Original Result
MS Result
MS Rec.
Dilution Rec. Limits
Analyte ug/I
ug/1
ug/l
%
%
Chloride 40000
7990
43700
89.2
1 80.0-120
Sulfate 40000
ND
40100
92.7
1 80.0-120
MS Qualifier
ACCOUNT: PROJECT: SDG:
DATE/TIME:
PAGE:

WG2270729
Wet Chemistry by Method 350.1
Method Blank (MB)
(MB) R4060595-1 04/20/2413:41
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/I ug/I ug/I
Ammonia Nitrogen U 117 250
L1725549-09 Original Sample (OS) • Duplicate (DUP)
QUALITY CONTROL SUMMARY
L1725772-01
(OS) L1725549-09 04/20/2413:53 • (DUP) R4060595-5 04/20/2413:55
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/I ug/l % %
Ammonia Nitrogen 1570 1570 1 0.0638 10
L1725549-11 Original Sample (OS) • Duplicate (DUP)
(OS) L1725549-11 04/20/2414:04 • (DUP) R4060595-7 04/20/2414:05
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/I ug/I % 1/1
Ammonia Nitrogen ND ND 1 0.000 10
Laboratory Control Sample (LCS)
(LCS) R4060595-2 04/20/2413:43
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte ug/I ug/I % %
Ammonia Nitrogen 7500 7570 101 90.0-110
L1725549-08 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1725549-08 04120/2413:49 • (MS) R4060595-3 04/20/2413:50 • (MSD) R4060595-4 04/20/2413:52
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/I ugA ug/I ug/I % % % % %
Ammonia Nitrogen 5000 2360 7490 7410 102 101 1 90.0-110 1.02 10
L1725549-10 Original Sample (OS) • Matrix Spike (MS)
(OS) L1725549-10 04/20/2414:01 • (MS) R4060595-6 04/20/2414:02
Spike Amount Original Result MS Result MS Rec. Dilution Rec. Limits MS Qualifier
Analyte ug/I ug/I ug/I % %
Ammonia Nitrogen 5000 ND 5600 107 1 90.0-110
ACCOUNT: PROJECT: SDG:
DATE/TIME:
PAGE:

WG2269220
Wet Chemistry by Method 351.2
Method Blank (MB)
(MB) R4059550-1 04/19/24 00:28
MB Result
Analyte ug/I
Kjeldahl Nitrogen, TKN U
MB Qualifier M8 MDL MB RDL
ug/I ug/I
140 250
L1726260-01 Original Sample (OS) • Duplicate (DUP)
QUALITY CONTROL SUMMARY
L1725772-01
(OS) L1726260-01 04/19/24 00:48 • (DUP) R4059550-6 04/19/24 00:49
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/I % %
Kjeldahl Nitrogen, TKN 583 656 1 11.8 20
L1726260-02 Original Sample (OS) • Duplicate (DUP)
(OS) L1726260-02 04/19/24 00:51 • (DUP) R4059550-7 04/19/24 00:52
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ugll ug/I % %
Kjeldahl Nitrogen, TKN 378 399 1 5.41 20
Laboratory Control Sample (LCS)
(LCS) R4059550-2 04/19/24 00:29
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte ug/I ug/I % %
Kjeldahl Nitrogen, TKN 12300 13100 107 80.0-120
L1726072-02 Original Sample (OS) • Matrix Spike (MS)
(OS) L1726072-02 04/19/24 00:32 • (MS) R4059550-3 04/19/24 00:33
Spike Amount Original Result MS Result MS Rec. Dilution Rec. Limits MS Qualifier
Analyte ug/I ug/l ug/I % %
Kjeldahl Nitrogen, TKN 5000 463 5700 105 1 90.0-110
L1726107-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1726107-01 04/19/24 00:38 • (MS) R4059550-4 04/19/24 00:39 • (MSD) R4059550-5 04/19/24 00:43
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/I ug/l ug/I ug/I % % % °6 %
Kjeldahl Nitrogen, TKN 5000 ND 3820 3970 76.4 79.4 1 90.0-110 iE 3.85 20
ACCOUNT: PROJECT: SDG:
DATE/TIME:
PAGE:

WG2269220 QUALITY CONTROL SUMMARY
Wet Chemistry by Method 351.2 L1725772-01
L17261O7-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1726107-01 04/19/24 00:38 • (MS) R4059550-4 04/19/24 00.39 • (MSD) R4059550-5 04/19/24 00:43
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/1 ug/I ug/I ug/I % % % % %
Sample Narrative:
MS: Spike failure due to matrix interference
MSD: Spike failure due to matrix interference
ACCOUNT: PROJECT: SDG:
DATE/TIME:
PAGE:

WG2269789
Wet Chemistry by Method 365.4
Method Blank (MB)
(MB) R4059426-1 04/18/2415:30
M8 Result MB Qualifier MB MDL MB RDL
Analyte ug/1 ugA ug/1
Phosphorus,Total 47.8 J 35.0 100
L1726260-02 Original Sample (OS) • Duplicate (DUP)
QUALITY CONTROL SUMMARY
L1725772-01
(OS) L1726260-02 04/18/2415:46 • (DUP) R4059426-5 04/18/2415:47
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/1 ugA % %
Phosphorus,Total 180 107 1 50.9 P1 20
Laboratory Control Sample (LCS)
(LCS) R4059426-2 04/18/2415:32
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte ug/1 ug/I % %
Phosphorus,Total 1810 1760 97.5 85.0-115
ACCOUNT: PROJECT: SDG:
DATE/TIME:
PAGE:

WG2270390
Wet Chemistry by Method 420.4
Method Blank (MB)
(MB) R4060417-1 04/22/2411:54
MB Result
Analyte ug/I
Total Phenol by 4AAP U
MB Qualifier MB MDL MB RDL
ug/I ug/I
8.30 40.0
L1722581-02 Original Sample (OS) • Duplicate (DUP)
QUALITY CONTROL SUMMARY
L1725772-01
(OS) L1722581-02 04/22/2411:55 • (DUP) R4060417-3 04/22/2411:56
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/I ug/I % %
Total Phenol by 4AAP ND ND 1 0.000 20
L1725449-02 Original Sample (OS) • Duplicate (DUP)
(OS) L1725449-02 04/22/2412:13 • (DUP) R4060417-6 04/22/2412:13
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/I ug/I % %
Total Phenol by 4AAP ND ND 1 0.000 20
Laboratory Control Sample (LCS)
(LCS) R4060417-2 04/22/2411:55
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte ug/I ug/I % %
Total Phenol by 4AAP 1000 996 99.6 90.0-110
L1723620-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1723620-02 04/22/2411:57 • (MS) R4060417-4 04/22/24 11:58 • (MSD) R4060417-5 04/22/2411:59
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/I ug/I ug/I ug/I % % % % %
Total Phenol by 4AAP 1000 309 1340 1170 103 86.1 1 90.0-110 13.5 20
ACCOUNT: PROJECT: SDG:
DATE/TIME:
PAGE:

WG2268107
QUALITY CONTROL SUMMARY
Wet Chemistry by Method 4500H+ B-2011
L1725772-01
L1724446-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1724446-01 04/16/2419:20 • (DUP) R4058491-2 04/16/2419:20
E
Original Result DUP Result Dilution DUP RPD
DUP Oualifier DUP RPD
Limits
Analyte su su %
%
pH 7.49 7.49 1 0.000
1
Fs
Sample Narrative:
OS: 7.49 at 18.6C
Fn
DUP: 7.49 at 18.1C
E
L1725931-04 Original Sample (OS) • Duplicate (DUP)
(OS) L1725931-04 04/16/2419:20 • (DUP) R4058491-3 04/16/2419:20
Original Result DUP Result Dilution DUP RPD
DUP Qualifier DUP RPD
Limits
Analyte su su %
%
FG1
pH 7.97 7.99 1 0.251
1
E
Sample Narrative:
OS: 7.97 at 18.9C
DUP: 7.99 at 18.9C
E
Laboratory Control Sample (LCS)
(LCS) R4058491-1 04/16/2419:20
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte su su % %
pH 10.0 10.0 100 99.0-101
Sample Narrative:
LCS:10.01 at19.8C
ACCOUNT: PROJECT: SDG:
DATE/TIME:
PAGE:

WG2268284
Wet Chemistry by Method 5310 B-2014
Method Blank (MB)
(MB) R4058567-2 04/16/2417:51
MB Result
Analyte ug/I
TOC (Total Organic Carbon) U
MB Qualifier MB MDL MB RDL
ug/I ug/l
102 1000
L1725871-01 Original Sample (OS) - Duplicate (DUP)
QUALITY CONTROL SUMMARY
L1725772-01
(OS) L1725871-01 04/16/2418:51 - (DUP) R4058567-3 04/16/2419:11
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/I ug/I % %
TOC (Total Organic Carbon) 3450 3480 1 0.779 20
L1724967-01 Original Sample (OS) - Duplicate (DUP)
(OS) L1724967-01 04/16/24 23:29 - (DUP) R4058567-6 04/16/24 23:48
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/I ug/I % %
TOC (Total Organic Carbon) 1850 1840 1 0.433 20
Laboratory Control Sample (LCS)
(LCS) R4058567-1 04/16/2417:34
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte ug/I ug/l % %
TOC (Total Organic Carbon) 25000 24100 96.5 85.0-115
L1725871-02 Original Sample (OS) - Matrix Spike (MS) - Matrix Spike Duplicate (MSD)
(05) L1725871-02 04/16/2419:30 - (MS) R4058567-4 04/16/2419:54 - (MSD) R4058567-5 04/16/24 20:17
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/I ug/I ug/I ug/I % % % % %
TOC (Total Organic Carbon) 25000 3580 28200 28800 98.3 101 1 85.0-115 2.07 20
L1724967-02 Original Sample (OS) - Matrix Spike (MS) - Matrix Spike Duplicate (MSD)
(0,S) L1724967-02 04/17/24 00:07 • (MS) R4058567-7 04/17/24 00:28 - (MSD) R4058567-8 04/17/24 00:50
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/I ug/I ug/I % % %
TOC (Total Organic Carbon) 25000 1800 26500 26800 98.6 100 1 85.0-115 1.31 20
ACCOUNT: PROJECT: SDG:
DATE/TIME:
PAGE:

WG2269011
Metals (ICP) by Method 200.7
Method Blank (MB)
(MB) R4059584-1 04/18/24 22:32
M8 Result
MB Qualifier MB MDL
MB RDL
Analyte ug/I
ug/I
ug/I
Cadmium U
0.552
2.00
Chromium U
1.63
10.0
Copper U
2.26
10.0
Iron U
20.5
100
Lead U
2.27
5.00
Nickel U
1.82
10.0
Sodium U
444
1000
Zinc U
5.78
50.0
Laboratory Control Sample (LCS)
QUALITY CONTROL SUMMARY
L1725772-01
(LCS) R4059584-2 04/18/24 22:34
Spike Amount
LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
Analyte ug/I
ug/I
%
%
Cadmium 1000
995
99.5
85.0-115
Chromium 1000
1000
100
85.0-115
Copper 1000
996
99.6
85.0-115
Iron 10000
9970
99.7
85.0-115
Lead 1000
979
97.9
85.0-115
Nickel 1000
975
97.5
85.0-115
Sodium 10000
10000
100
85.0-115
Zinc 1000
1010
101
85.0-115
L1726111-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1726111-01 04/18/24 22:35 • (MS) R4059584-4 04/18/24 22:39 • (MSD) R4059584-5 04/18/24 22:41
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Dilution Rec. Limits
Analyte
ug/I
ug/I
ug/l
ug/l
%
%
%
Cadmium
1000
ND
1010
1020
101
102
1 70.0-130
Chromium
1000
ND
1030
1030
103
103
1 70.0-130
Copper
1000
ND
1000
1020
100
102
1 70.0-130
Iron
10000
ND
10000
10200
100
102
1 70.0-130
Lead
1000
ND
1020
1030
102
103
1 70.0-130
Nickel
1000
ND
1030
1040
103
104
1 70.0-130
Sodium
10000
27900
37900
37700
99.4
97.6
1 70.0-130
Zinc
1000
ND
1060
1050
106
105
1 70.0-130
MS Qualifier MSD Qualifier RPD
RPD Limits
1.04
20
0.142
20
1.75
20
1.96
20
1.15
20
0.569
20
0.464
20
0.361
20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

WG2269011 QUALITY CONTROL SUMMARY
Metals (ICP) by Method 200.7 L1725772-01
L1726165-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1726165-01 04/18/24 22:42 • (MS) R4059584-6 04/18/24 22:44 • (MSD) R4059584-7 04/18/24 22:46
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
ug/I
ug/I
ug/l
ugA
%
/°
Cadmium
1000
ND
1040
1010
104
101
Chromium
1000
ND
1030
1000
103
100
Copper
1000
ND
993
982
99.3
98.2
Iron
10000
ND
10200
10100
102
101
Lead
1000
ND
1040
1020
104
102
Nickel
1000
12.5
1070
1050
106
104
Sodium
10000
190000
206000
198000
155
76.5
Zinc
1000
ND
1070
1050
107
105
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
RPD Limits
1 70.0-130
2.91
20
1 70.0-130
2.76
20
1 70.0-130
1.11
20
1 70.0-130
1.37
20
1 70.0-130
2.44
20
1 70.0-130
1.71
20
1 70.0-130
V 3.92
20
1 70.0-130
2.41
20
ACCOUNT: PROJECT: SDG:
DATE/TIME:
PAGE:

GLOSSARY OF TERMS
Guide to Reading and Understanding Your Laboratory Report
The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not
intended as a comprehensive explanation, and if you have additional questions please contact your project representative.
Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name,
Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On -Site Data, Sampling Collection Dates/Times, and
Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received.
Abbreviations and Definitions
MDL
Method Detection Limit.
ND
Not detected at the Reporting Limit (or MDL where applicable).
RDL
Reported Detection Limit.
Rec.
Recovery.
RPD
Relative Percent Difference.
SDG
Sample Delivery Group.
U
Not detected at the Reporting Limit (or MDL where applicable).
Analyte
The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes
reported.
If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the
Dilution
standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the
laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the
result reported has already been corrected for this factor.
These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal
Limits
for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or
duplicated within these ranges.
Original Sample
The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control
sample. The Original Sample may not be included within the reported SDG.
This column provides a letter and/or number designation that corresponds to additional information concerning the result
Qualifier
reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and
potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable.
The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was
no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL"
Result
(Below Detectable Levels). The information in the results column should always be accompanied by either an MDL
(Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect
or report for this analyte.
Uncertainty
(Radiochemistry)
Confidence level of 2 sigma.
A brief discussion about the included sample results, including a discussion of any non -conformances to protocol
Case Narrative (Cn)
observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.
Quality Control
This section of the report includes the results of the laboratory quality control analyses required by procedure or
Summary (Qc)
analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not
being performed on your samples typically, but on laboratory generated material.
This is the document created in the field when your samples were initially collected. This is used to verify the time and
Sample Chain of
date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This
Custody (Sc)
chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the
samples from the time of collection until delivery to the laboratory for analysis.
This section of your report will provide the results of all testing performed on your samples. These results are provided
Sample Results (Sr)
by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for
each sample will provide the name and method number for the analysis reported.
Sample Summary (Ss)
This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and
times of preparation and/or analysis.
Qualifier
Description
J
The identification of the analyte is acceptable; the reported value is an estimate.
J6
The sample matrix Interfered with the ability to make any accurate determination; spike value is low.
P1
RPD value not applicable for sample concentrations less than 5 times the reporting limit.
T8
Sample(s) received past/too close to holding time expiration.
v
The sample concentration is too high to evaluate accurate spike recoveries.
ACCOUNT: PROJECT: SDG:
DATE/TIME: PAGE:

ACCREDITATIONS & LOCATIONS
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Alabama
40660
Nebraska
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Alaska
17-026
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TN000032021-1
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AZ0612
New Hampshire
2975
Arkansas
88-0469
New Jersey—NELAP
TN002
California
2932
New Mexico'
TN00003
Colorado
TN00003
New York
11742
Connecticut
PH-0197
North Carolina
Env375
Florida
E87487
North Carolina
DW21704
Georgia
NELAP
North Carolina'
41
Georgia'
923
North Dakota
R-140
Idaho
TN00003
Ohio—VAP
CL0069
Illinois
200008
Oklahoma
9915
Indiana
C-TN-01
Oregon
TN200002
Iowa
364
Pennsylvania
68-02979
Kansas
E-10277
Rhode Island
LAO00356
Kentucky '6
KY90010
South Carolina
84004002
Kentucky a
16
South Dakota
n/a
Louisiana
A130792
Tennessee"
2006
Louisiana
LA018
Texas
T104704245-20-18
Maine
TN00003
Texas'
LAB0152
Maryland
324
Utah
TN000032021-11
Massachusetts
M-TNO03
Vermont
VT2006
Michigan
9958
Virginia
110033
Minnesota
047-999-395
Washington
C847
Mississippi
TN00003
West Virginia
233
Missouri
340
Wisconsin
998093910
Montana
CERT0086
Wyoming
A21-A
A21-A — ISO17025
1461.01
AIHA-LAP,LLC EMLAP
100789
QLA — ISO 17025 6
1461.02
DOD
1461.01
Canada
1461.01
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P33045-00234
EPA—Crypto
TN00003
' Drinking Water Z Underground Storage Tanks 3 Aquatic Toxicity "Chemical/Microbiological 6 Mold 6 Wastewater n/a Accreditation not applicable
Not all certifications held by the laboratory are applicable to the results reported in the attached report.
' Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical.
ACCOUNT: PROJECT: SDG'
PAGE:

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