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Home My WebLink AboutWQ0034987_2015 Annual Report_20160215rr t a' ��d Murphy -Brown LLC PO Drawer856 2822 Hwy. 24 West Warsaw, NC 28398 T& 910-293-3434 Fax 910-293-6957 February 15, 2016 North Carolina Department of Environment and Natural Resources Division of Water Quality Aquifer Protection Section Land Application Unit 1636 Mail Service Center Raleigh, NC 2769901636�� To Whom It May Concern: , Q IVP _� Q SZ� ?OJs �i Enclosed you will find the 201 Annual Reporting Forms as required by Permit WQ0034397 (Murphy -Brown Bladen/Scotland Residuals Program). The attachments are NGUN� submitted in the following order: FORMIACF FORM;PVRF Murphy -Brown did not conducted land application on any sites in 2015. Due to no activity, samples were not taken in 2015. The application field AMMON2 received lime in 2015 per soil test recommendations. Please feel free to contact me for both Permittee and preparer inquiries at kraiewesterbeelda MlUhybrownllc com or (910) 293 5330. A11111L)AL LAl\LA rJALA1lU1V L;J& 11P11:A11Ur4 FURNI WQ leermit#: W00034397 County: Facility Name (as shown on permit): Bladen/Scotland Year: 2015 Bladen/Scotland Residuals Land_ Application Operator: Murphy -Brown Phone: 910 293 5330 Land application of residuals as allowed by the permit occurred during the past calendar year? ❑ Yes v❑ No - If No, slip Part A, and Part B and proceed to Part C. Also, If residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A- Residuals Application Summary: Total number of application fields in the ennit: Total number of fields utilized for land application during the year: Total amount of dry tons applied during the year for all application sites: Total number of acres utilizes for land application during the year: Part 16_- Annual Compiance Statement: Facility was compliant during calendar year with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Resources. ❑ Yes ❑ No If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken_ 1) Only residuals approved for this permit were applied to the permitted sites. 2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading Rates in 15A NCAC 02T A 105(b) (applicable to 40 CFR Part 503 regulated facilities). 7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8) All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Resources. 10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as specified in the permit. 12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13) All buffer requirements as specified on the permit were maintained during each application of residuals. Part C - Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Kraig Westerbeek, VP Permittee Name and Title (type or print) Vignature of Pe ittee Date CL 1. -ISO Signature of Preparer* Date Signature of Land Applier Date (if different from Permittee) (if different from Permittee and Preparer) * Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T A 102 (26) DENR FORM ACF (12/2006) �..... vr..-.�n...v...,:... ru�yi Y�%-A V1c H1 inixt,11VA1(L"uu11V1N PVA1Yt(UL1'ltules) Faca'lity Name: Murphy -Brown Bladen/Scotland Residuals Program WWTP Name: Monntering Period: From Jan. 2015 To WQ Permit Number: NPDES Number: Dec. 2015 Patkagen Reduction (15A NCAC MAW W - Please indicate level achieved and alternative Class A: I Alt A (timeltem Alt B (Alk Tre_ atment)❑' Alt C (Prior Teshn = ..),'_:p .p Alt l) (No Prior Test) ❑ . Prods to.Ftuther Reduce Pathogengs_ p a _- If applicable to alternative erformed, Class A o ).iadfeate."Process to Further RedacePatho Post Com ❑: Heat Dr1'tng ❑ . .Heat Treatment: ❑ Thermophthc ❑ Beta Ray ❑ .GammaRa . ❑ . Pasteurization .❑ ::..:.....;:. . Class B Alt (1) Fecal Densi : ❑ Ali.' (2) Process to Signific4ntly ReducePatho ens. p If applicable to alternative performed (Class B only) indicate `'Process to Significantly Rsdace Pathogens": Lime Stabilization ❑ Air,Drymg ..21, . Com ostin ` ❑ Aerobic Digestion El Anaerobic Di estion ❑ If a 6cable p to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level Pathogen Density Num er o Frequency Sample Analyti in Sludge Mean axim Units of Analysis Type Tech- de nioue' e 2 x 10 to the MPN 6th power per gam of Fecal Colifonn total solids CFU 1000 mpn per gam oftotal solid (dry weight) Salmonella bacteria 3 WN per 4 grams (in lieu of fecal total solid (dry coliform) weight) Vector Attraction Reduction (15A 1NUAU U2T .1107) -Please indicate alternative performed: Alt I (VS reduction) ❑ Alt. 2 (40-day bench) ❑, JAIt. 3 (30-day bench) ❑ JAR. 4 (Spec. OZ uptake) ❑ Alt. 5 (14-Day Aerobic) ❑ JAR. 6 (AUc Stabilization ❑ JAIt 7 (Drying - Stable) [3Alt. 8 (Drying - Unstable) ❑ Alt. 9 (Injection) ❑ jAlt. 10 (Incorporation) [3 INo vector attraction reduction alternatives were.performed ❑ CEK11kJLUAIWN Sl'ATEMENT (please check the appropriate statement) 0 "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." ❑ " I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note N you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met I am aware that there are significant penalties for false certification including fine and imprisonment." Kraig Westerbeek, 4P Preparer� e and Title (type or print) Land Applier Name and Title (if applicable)(type or print) er Date Signature of Land Applier (if applicable) Date in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM PVRF 02T (12/2006) _ Environmental %-/'hemists, Inc. d0 19 6602 Windmill Way, Wilmington, NC 28405 • 910.392.0223 lab ^ 910.392.4424 Fax 710 Bowsertown Road, Nlanteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, INC 28540 • 910.347.5843 Lab/rax ANALYTICAL & CONSULTING CHEMISTS inlinirenvironmdulalchemislseotu Smithfield Hog Productions - Warsaw Date of Report: Jan 20, 2017 Post Office Box 856 Customer PO M Warsaw NC 28398 Customer ID: 08110011 Attention: Kraig Westerbeek Report M 201&18897 Project ID: Lab ID Sample ID: Collect Date/Time Matrix Sampled by 16-45295 Site: #3 12/30/2016 11:30 AM Solid/Sludge Client Test Method Results Date Analyzed Chlordane SW 846 Method80B1B/3510 <0.02mg/L 01/04/2017 Endrin SW 846 Method 8081B13510 <0.0005 mg/L 01/04/2017 Heptachlor SWS46 Method 8081BI3510 <0.0005mg/L 01/04/2017 Heptachlor epoxide SW 846 Method 8081B/3510 <0.0005 mg/L 01/04/2017 Lindane SW846Method 8081B/3510 <0.0005mg/L 01/04/2017 Methoxychlor SW 846 Method8081B/3510 <0.0005mg/L 01/04/2017 Toxaphene SW 846 Method 80818/3510 <0.05 mg/L 01/04/2017 1,4-Dichlorobenzene (TCLP) SW 846 method 827013510 <0.050 mg/L 01/04/2017 2,4,5-Trichlorophenol(TCLP) SW 846 method8270/3510 <0.050mg/L 01/04/2017 2,4,6-Trichlorophenol(TCLP) SWS46 method 8270/3510 <0.050mgtL 01/04/2017 2,4-Dinitrotoluene(TCLP) SW845method 8270/3510 <0.050mg/L 01/04/2017 Cresol (TCLP) SW 846 method 827013510 <0.050 mg/L 01/04/2017 Hexachloro-1,3-butadiene (TCLP) SW 846 method 8270/3510 <0.050 mg/L 01104/201.7 Hexachlorobenzene(TCLP) SW 846 method827013510 <0.050mg/L 0110412017 Hexachloroethane(TCLP) SW 848 method827013510 <0.050mg/L 01/04/2017 m + p-Cresol (TCLP) SW 846 method 6270/3510 <0.050 mg/L 01/04/2017 Nitrobenzene (TCLP) SW 846 method8270/3510 .<0.050mg/L 01/04/2017 o-Cresol(TCLP) SW 846 method827013510 <0.050mg/L 01/04/2017 Pentachlorophenol(TCLP) SW 846 method8270/3510 <0.250mg/L 01/04/2017 Pyridine (TCLP) SW 846 Method 827013510 <0.050mg/L 01/04/2017 2,4,5-TP SW846Method 8151A <0.003mg/L 01/05/2017 2,4-D SW846 Method 8151A <0.003mg/L 01/05/2017 , 1,1-Dichloroethylene SW846 Method 826015030 <0.01mg/L 01/10/2017 1,2-Dichloroethane SW846 Method 826015030 <0.01 mg/L 01/10/2017 Benzene SW846 Method 8260/6030 <0.01mg/L 01/10/2017 Carbon Tetrachloride SW846 Method 826015030 <0.01 mg/L 01/10/2017 Report #:: 2016-18897 Page 1 of 3 n A �. Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 24405 • 910.392.0223 Lab • 910.392.4424 Fax 0 71011owsertown Road, 1vlanteo, NC 27954 ' 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 ' 910.347.5843 Lab/Fos ANALYTICAL & CONSULTING CHEMISTS inlix<oenvironmentDtchemists.com Smithfield Hog Productions - Warsaw Date of Report: Jan 20, 2017 Post Office Box 856 Customer PO M Warsaw NC 28398 Customer ID: 08110011 Attention: Kraig Westerbeek Report M 2016-18897 Project ID: Chlorobenzene SW846 Method 8260/5030 <0.01 mg/L 01/10/2017 Chloroform SW846 Method826015030 <0.01mg/L 01/10/2017 Methyl ethyl ketone SW846 Method 8260/5030 <0.05 mg/L 01/10/2017 Tetrachloroethylene SW848Method 626016030 <0.01mg1L 01/10/2017 Trichloroethylene SW846 Method 826015030 <0.01mg/L 01/10/2017 Vinyl Chloride SW846 Method8260/5030 <0.01 mg/L 01/10/2017 RCI Ignitability EPA1030 <0.8mm/sec 01/17/2017 Cyanide EPA335.4 <0.063mg/kg 01/05/2017 Sulfide SM 4500 S D <0.127 mg/kg 01/09/2017 pH SW 846 Method 9045D 7.31 units 01/10/2017 Sludge Residuals Aluminum EPA200.7 102mg/kg 01/04/2017 Arsenic EPA200.7 <3.21 mg/kg 01/04/2017 Cadmium EPA200.7 <3.21 mg/kg 01/04/2017 Calcium EPA200.7 3760mg/kg 01104/2017 Chromium EPA200.7 <3.21mg/kg 01/04/2017 Copper EPA200.7 37.9mg/kg 01/04/2017 Lead EPA200.7 <3.21 mg/kg 01/04/2017 Magnesium EPA200.7 575mg/kg 01/04/2017 Molybdenum EPA200.7 <3.21 mg/kg 01/05/2017 Nickel EPA2001 <3.21 mg/kg 01/04/2017 Potassium EPA200.7 424mg/kg 01/04/2017 Selenium EPA200.7 <3.21 mg/kg 01/04/2017 Sodium EPA200.7 165mg/kg 01/04/2017 Zinc EPA200.7 99.9mg/kg 01/0412017 Nitrate+Nitrite-Nitrogen EPA353.2 23.3mg/kg 01/12/2017 Total Solids (%) SM2540B 31.1 % 01/05/2017 Ammonia Nitrogen SM4500NH3 C <0.3mg/kg 01/09/2017 Total Kjeldahl Nitrogen (TKN) SM4500 Drg B 3420 mg/kg 01/09/2017 Report #:: 2D16.18897 Page 2 of 3 A4 • S.Yax�i4�up%u.0 Environmental �liemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 • 9lo.392.0223 Lab • 910.392.4424 Fax 710 13owsertown Road, blanteo, NC 27954 • LS2.473 57U2 Lab/Pas 255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lib/Fox ANALYTICAL & CONSULTING CHEMISTS inliwPenvironmem:dchemistsanu Smithfield Hog Productions - Warsaw Date of Report: Jan 20, 2017 Post Office Box 856 Customer PO #: Warsaw NC 28398 Customer ID: 08110011 Attention: Kraig Westerbeek Report#: 2016-18897 Project ID: Total Phosphorus SM4500PF 1530mg/kg 01/10/2017 Mercury SWa467471B <0.061 mg/kg 01/03/2017 TCLP Metals Arsenic EPA200.7 <1.Omg/L 01/06/2017 Barium EPA200.7 <1.Omg/L 01/06/2017 Cadmium EPA200.7 <1.Omg/L 01/06/2017 Chromium EPA200.7 <1.0mg/L 01/06/2017 Lead EPA200.7 <1.Omg/L 01/06/2017 Selenium EPA200.7 <1.Omg/L 01/06/2017 Silver EPA200.7 <1.Omg/L 01/06/2017 Mercury EPA245.1 <0.0020mg/L 01/05/2017 Comment: Sludge residuals, exce t pH, reported on a dry weight basis. pH reported on an as received basis. w Revieed by: T 0 0 Report it.: 201 B-18B97 Page 3 of 3 C C e A Analytical & Consulting Chemists ENVIRONMENTAL CHEMISTS, INC NCDENR: DWQ CERTIFICATION 0 94 NCDHHS: DLS.CERTIFICATION # 37729 Cnl i cr Tri 1kt Auln ^UA1L1 ^I 6602 Windmill Way Wilmington, NC 28406 OFFICE: 910-392-0223 FAX 910-392-4424 info@em4ronmentalchemiss.eom I v1v reeve+ vngUv Vr' wWoI VNi Client: Smithfield Hog Production-Wlamaw PROJECT NAME: 5 • Se TC L P ' REPORT NO: 16�— ADDRESS: G PJox S 5(, CONTACT NAME: PO NO: REPORT TO: Kraig Westerbeek PHONEIFAX: COPY TO: ,v.ove 11 email: I<'LJC6 / S amp ed EY. Sample Identification Collection y r .r Iwr"c 1. g; c u 1 , ram: B, = a i = mnueni, = c �' t e m g = tmuent, W PRESERVATION = Well, ST = Stream, SO = Soil, SL = Sludge, Other: ANALYSIS REQUESTED Data Time Temp z c c �w Residuals 'J 55 �5L X Full TCLP, P.Ci, Nutrients/metals C G P G G C P G G C P G G C P G G C P G G C P G G C P G G C P G G Transfer Relinquished By: Date/Time Received By: Daterrime t. a. Temperature when Received: Delivered By: �� ___...p._ ....y....a.,.... o fi Received By. Date: i Zt3a{ co _ 1 If Time: ll,n_4— 7. t Environmental4-,hemists, Inc. 4 O 6602 Windmill N+ay, Wilmington, NC 28405 ' 910.392.0223 Lab ` 910.392.4424 Fax - - 710 Bowsertown Road, Manteo, NC 279,94 • 292.473.5702 Lab/Fax sM - 255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Far ANALYTICAL & CONSULTING CHEMISTS info(a em inn7nentalchemismeom Smithfield Hog Productions- Warsaw Date of Report: Jan 20, 2017 Post Office Box 856 Customer PO #: Warsaw - NC 28398 Customer ID: 08110011 Attention: Kraig Westerbeek Report #: 2016-18898 Project ID: Lab ID Sample ID: Collect Date/Time Matrix Sampled by 1645296 Site: #4 12/30/2016 12:15 PM Water Client Test Method Results Date Total Solids (%) SM 2540 B <0.1 % 01/05/2017 Chlordane SW 846 Method8081B13510 <0.02mg/L 01/04/2017 Endrin SW 846 Method 8081813510 <0.0005mg/L 01/04/2017 Heptachlor SW 846 Method 8081 B13510 <0.0005mg/L 01/04/2017 Heptachlor epoxide SW 846 Method8081B/3510 <0.0005mg/L 01104/2017 Lindane SW 846 Method80818/3510 <0.0005mg/L 01/04/2017 r Methoxychlor SW 846 Method 8081B/3510 <0.0005mg/L 01/04/2017 Toxaphene SW 846 Method 80818/3510 <0.05 mg/L 01/04/2017 1,4-Dichlorobenzene(TCLP) SW846 method 827013510 <0.050mg/L 01/0412017 2,4,5-Trichiorophenol (TCLP) SW 846 method8270/3510 <0.050mg/L 01/0412017 2,4,6-Trichlorophenol(TCLP) SW846method 8270/3510 <0.050mg/L 01/04/2017 2,4-Dinitrotoluene (TCLP) • SW 846 method 8270/3510 <0.050 mg/L 01/04/2017 Cresol (TCLP) SW 046 method 827013510 <0.050mg/L 01/04/2017 Hexachioro-1,3-butadiene(TCLP) SW 846 method827013510 <0.050mg/L 01/04/2017 Hexachlorobenzene(TCLP) SW846 method 8270/3510 <0.050mg/L 01/04/2017 Hexachloroethane(TCLP) SW 846 method827o13510 <0.050mg/L 01/04/201T m-Cresol(TCLP) SW 846 method 827013510 <0.050mg/L 01/04/2017 Nitrobenzene (TCLP) SW 845 method 827013510 <0.050mg/L 01/04/2017 o-Cresol(TCLP) SW 846 method 827013510 <0.050mg/L 01/04/2017 p-Cresol(TCLP) SW 846 method 827013510 <0.050mg/L 01104/2017 Pentachlorophenol(TCLP) SW 846 method 827013510 <0.250mg/L 01/04/2017 Pyridine (TCLP) SW 846 method8270/3510 <0.050mg/L 01/04/2017 2,4,5-TP SW846 Method 81 51A <0.003mg/L 01/05/2017 2,4-D SW845Method B151A <0.003mg/L 01/05/2017 1,1-Dichloroethylene SW846 Method 826015030 <0.01 mg/L 01/11/2017 1,2-Dichloroethane SWMMethod a26o/5030 <0.01mg/L 01/11/2017 Report #:: 2016.18898 Page 1 of 3 Environmental Chemists, Inc. ` a a u willh-1 6b02 Windmill Way. Wilmington, NC 23405 • 910.392.0223 lab - 910.392.4424 Fax 710 Bowsertown Road, 1.1anteo, NC 27954 ^ 252.473.5702 Lib/Fax sM - 255-A Wilmington Highn'a}; Jacksonville, NC 28540 910.347.5843 Lab/Fax ANALYTICAL & CONSULTING CHEMISTS in lii/menvironmenndchcnlists.conl Smithfield Hog Productions -Warsaw Date of Report: Jan 20, 2017 Post Office Box 856 Customer PO #: Warsaw NC 28398 Customer ID: 08110011 Attention: Kraig Westerbeek Report #: 2016-18898 Project ID: Benzene SW846 Method 8260/5030 <0.01mg/L 01/11/2017 Carbon Tetrachloride SW046 Method 6260/5030 <0.01 mg/L 01/11/2017 Chlorobenzene SW846 Method 826015030 <0:01mg/L 01/11/2017 Chloroform SWO46 Method 8260/5030 <0.01mg/L 01/11/2017 Methyl ethyl ketone SW846 Method 8260/5030 <0.05mg/L 01/11/2017 Tetrachloroethylene SW846 Method 82601503D <0.01mg/L 01/11/2017 Trichloroethylene SW846 Method 826015030 <0.01 mg/L 01/11/2017 Vinyl Chloride SW846 Method 8260/5030 <0.01 mg/L 01/11/2017 RCI Cyanide EPA335.4 <0.013mg/L 01/05/2017 Sulfide SM 4500 S D <0.025 mg/L 01/09/2017 Analyzed outside of holding time. Ignitability SW 846 method 1010 >212 °F 01/12/2017 Sludge Residuals Aluminum EPA200.7 1390mg/L 01/05/2017 Arsenic EPA200.7 <10.Omg/L 01/05/2017 Cadmium EPA200.7 <10.0mg/L 01/05/2017 Calcium EPA2D0.7 65600mg/L 01/10/2017 Chromium EPA200.7 <10.0mg/L 01/05/2017 Copper EPA200.7 699mg/L 01/05/2017 Lead EPA200.7 <10.0mg/L 01/05/2017 Magnesium EPA200.7 34300mg/L 01/1012017 Molybdenum EPA200.7 <10.Omg/L 01105/2017 Nickel EPA200.7 24.Omg/L 01/05/2017 Potassium EPA200.7 116000mg/L 01/10/2017 Selenium EPA200.7 <10.Omg/L 01/05/2017 Sodium EPA200.7 49900mg/L 01/10/2017 Zinc EPA200.7 1620mg/L 01/05/2017 Mercury EPA245.1 <0.200mg/L 01/05/2017 Ammonia Nitrogen EPA350.1 107000mg/L 01/05/2017 Report # : 2016-18a98 Page 2 of 3 Environmental�hemists, Inc. 6602 Windmill Way, Wilmington, NC 254t15 - 910.392.0223 Lab • 910.392.4424 Fax 710 Uowsertown Road, Mantco, NC 27954 • 152.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28-940 • 910 347.5843 Lab/Pas i ANALYTICAL & CONSULTING CHEMISTS infix<uenvronmentakhemislscom Smithfield Hog Productions -Warsaw Date of Report: Jan 20, 2017- Post Office Box 856 Customer PO #: Warsaw NC 28398 Customer ID: 08110011 Attention: Kraig Westerbeek Report #: 2016-18898 Project ID: Total Kjeldahl Nitrogen (TKN) EPA351.2 118000mg/L 01/09/2017 Nitrate+Nitrite-Nitrogen EPA353.2 82.8mg1L 01/12/2017 pH SM 4500 H B 7.31 units 01/10/2017 Total Phosphorus SM4600PF 101000mg1L 01/10/2017 TCLP Metals Arsenic EPA200.7 <1.0mg1L 01/10/2017 Barium EPA200.7 <1.0mg1L 01/10/2017 Cadmium EPA200.7 <1.0mg1L 01/10/2017 Chromium EPA200.7 <1.0mg/L 01/10/2017 Lead EPA200.7 <1.0mg/L 01/1012017 Selenium EPA200.7 <1.0mg/L 01/10/2017 Silver EPA200.7 <1.Omg/L 01/10/2017 Mercury EPA245.1 0.0024mg/L 01/05/2017 Comment: Sludge residuals, except reported on a dry weight basis. pH reported on an as received basis. Reviewed by - Report #:: 2016-18898' Page 3 of 3 C C • i , Analytical & Consulting Chemists ENVIRON ENTAL.CHEMISTS, INC NCDENR: DWO CERTIFICATION d 94 NCDHHS: DLS CERTIFICATION B 37729 PlTI k L'nTF/10., ak.FT � 6602 Windmill Way Wilmington, NC 28406 OFFICE: 910-392-0223 FAX 910-392.4424 info@envimnmentalchemists.com vke i-uvw vnlYnY Vf VVAf VVI Client: Smithfield HoI Production -Warsaw PROJECT NAME: Res. So/- TC L P REPORT NO: ADDRESS: FIG (3 ox ? 5 (� CONTACT NAME: PO NO: f aW tic %Sr3`j REPORT TO: Kraig Westerbeek PHONEIFAX. COPY TO: en -� �o✓ email: gILje,S!c@Sw,` �. e Sample Identification Collection ' i m u @ _ `" — i = mnuent, s = t E e M o m _ = vmuent, W PRESERVATIOtd = Well, ST tream, SO = Soil, SL = Sludge, Other: ANALYSIS REQUESTED Date Time Tem Residuals r� �7llt� rJ: f5 55° c P S'IX Full TCLP, RCL Nutrients/metals C G P G G C P G G C P G G C P G G C P G G C P G G C P , G C G P G G Transfer Relinquished By: Date/Time Received By: DaterTime 1. 2. Temperature when"celved: aeccntoA. ••=i=�• mesample K u eat: Delivered By: 1 Received By: �/� Date: r 3 r( Time: t(T Comments:_ TURNA OUND: a) Environmental %lhemists, Inc. 6602 Windmill Wav, Wilmington, NC 28405 . 910.392.0223 Lab a 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 ° 910.347.5843 Lab/Fax ANALYTICAL & CONSULTING CHEMISTS info«oenvironmlent0lchenlists.eoul Smithfield Hog Productions - Warsaw Date of Report: Jan 20, 2017 Post Office Box 856 Customer PO M Warsaw NC 28398 Customer ID: 08110011 Attention: Kraig Westerbeek Report M 2016-'18895 Project ID: Lab ID Sample ID: Collect Date/Time Matrix Sampled by 16-45293 Site: #1 12/29/2016 8:00 AM Water Client Test Method Total Solids (%) SM 2540 B Chlordane SW 846 Method 808113/3510 Endrin SW 848 Method 6081BI3510 Heptachlor SW 646 Method 80B1 B13510 Heptachlor epoxide SW 846 Method 8081 B13510 Lindane SW 846 Method 8081 B/3510 Methoxychlor SW 846 Method 8081 B/3510 Toxaphene SW 846 Method 8081 B/3510 1,4-Dichicrobenzene(TCLP) SW 846 method 8270/3510 2,4,5-Trichlorophenol (TCLP) SW 846 method 8270/3510 2,4,6-Trichlorophenol (TCLP) SW 846 method 8270/3510 2,4-Dinitrotoluene (TCLP) SW 846 method 8270/3510 Cresol (TCLP) SW 846 method 8270/3510 Hexachloro-1,3-butadiene(TCLP) SW 84B method 8270/3510 Hexachlorobenzene (TCLP) SW 846 method 8270/3510 Hexachloroethane(TCLP) SW 848 method 827013510 m-Cresol (TCLP) SW 846 method 8270/3510 Nitrobenzene (TCLP) SW 646 method 827013510 O-Cresol (TCLP) SW 846 method 827013510 p-Cresol (TCLP) SW 846 method 827013510 Pentachlorophencl(TCLP) SW 846 method 827013510 Pyridine (TCLP) SW 846 method 8270/3510 2,4,5-TP SW846 Method 8151A 2,4-D SW846 Method 8151A 1,1-Dichloroethylene SW846 Method 826015030 1,2-Dichloroethane SW846Method B260/5030 Results Date <0.1 % 01/05/2017 <0.02mg/L 01/04/2017 <0.0005 mg/L 01104/2017 <0.0005mg/L 01/04/2017 <0.0005mg/L 01/04/2017 <0.0005mg/L 01/04/2017 <0.0005mg/L 01/04/2017 <0.05 mg/L 01/04/2017 <0.050mg/L 01/04/2017 <0.050mg/L 01/04/2017 <0.050mg/L 01/04/2017 <0.050mg/L 01/04/2017 - <0.050mg/L 01/04/2017 <0.050mg/L 01/04/2017' <0.050mg/L 01/04/2017 <0.050mg/L 01/04/2017 <0.050mg/L 01/04/2017 <0.050mg/L 01/04/2017 <0.050mg/L 01/64/2017 <0.050mg/L 01/04/2017 <0.250mg/L 01/04/2017 <0.050mg/L 01/04/2017 <0.003 mg/L 01/05/2017 <0.003mg/L 01/05/2017 <0.01 mg/L 01/10/2017 <0.01 mg/L 01/10/2017 Report #:: 2016-18885 Page 1 of 3 s : Environmental Chemists Inc. A A A 6602 Windmill Way, Wilmington. NC 2R405 • 910.392.022J Lab - 910.392.4424 Fax sn 710 Botvsertown Road, Manteo, NC 27954 , 252.473.5702 Lab/Fax %ft255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax ANALYTICAL & CONSULTING CHEMISTS inlitla'tinvironmentalchemisu.cum Smithfield Hog Productions -Warsaw Date of Report: Jan 20, 2017 Post Office Box 856 Customer PO #: Warsaw NC 28398 Customer ID: 08110011 Attention: Kraig Westerbeek Report #: 2016-18895 Project ID: Benzene SW846 Method 826015030 <0.01mg/L 01/10/2017 Carbon Tetrachloride SW848 Method8260/5030 <0.01mg/L 01110/2017 Chlorohenzene SW846 Method 826015030 <0.01mg/L 01/10/2017 Chloroform SW846 Method 828015030 <0.01mg/L 01/10/2017 Methyl ethyl ketone SW848 Method 8260/5030 <0.05 mg/L 01/10/2017 Tetrachloreethylene SW846 Method 826015030 <0.01mg/L 01/10/2017 Trichloroethylene SW046 Method 826015030 <0.01 mg/L 01/10/2017 Vinyl Chloride SW846 Method B26015030 <0.01 mg/L 01/10/2017 RCI Cyanide EPA335.4 <0.005mg/L 01/05/2017 Sulfide SM 4500 S o <0.01 mg/L 01109/2017 Analyzed outside of holding time. Ignitability SW 846 method 1010 >212 °F 01/12/2017 Sludge Residuals Aluminum EPA200.7 99.0mg/L 01/05/2017 Arsenic EPA200.7 <10.Omg/L 01/05/2017 Cadmium EPA200.7 <10.Omg/L 01/05/2017 Calcium EPA200.7 58000mg/L 01/06/2017 Chromium EPA200.7 <10.Omg/L 01/05/2017 Copper EPA200.7 11.0mg/L 01/05/2017 Lead EPA200.7 <10.Omg/L 01/05/2017 Magnesium EPA200.7 4900mg/L 01/06/2017 Molybdenum EPA200.7 <10mg/L 01/05/2017 Nickel EPA200.7 <10mg/L 01/05/2017 Potassium EPA200.7 24100mg/L 01/06/2017 Selenium EPA200.7 <10.Omg/L 01/05/2017 Sodium EPA200.7 26400mg/L 01/06/2017 Zinc EPA200.7 117mg/L 01/05/2017 Mercury EPA245.1 <0.200mg/L 01/05/2017 Ammonia Nitrogen EPA350.1 342mg/L 01/04/2017 Report #:: 2016-18885 Page 2 of 3 :x Environmental Chemists, Inc. �4 6602 Windmill Way, Wilmington, NC 24405 4 910.392A223 Lab ` 910.392.4424 Fax 710 Bowsertown Road, Nlanteo, NC 27954 ' 252.473.5702 Lab/Fax sw. SS -A Wilmington Highway, Jacksonville, NC 28540 ` 910.147S843 lLab/Fax ANALYTICAL & CONSULTING CHEMISTS infotmeuvironntenlnlchemists.cOm Smithfield Hog Productions - Warsaw Date of Report: Jan 20, 2017 Post Office Box 856 Customer PO #: Warsaw NC 28398 Customer ID: 08110011 Attention: Kraig Westerbeek Report #: 2016-18895 Project ID: Total Kjeldahl Nitrogen (TKN) EPA351.2 3460mg/L 01/09/2017 Nitrate+Nitrite-Nitrogen EPA353.2 1680mg/L 01/12/2017 pH SM4500He 7.80units 01/10/2017 Total Phosphorus SM 4500 P F 1790 mg/L 01/09/2017 TCLP Metals Arsenic EPA200.7 <1.Omg/L 01/10/2017 Barium EPA200.7 <1.Omg/L 01/10/2017 Cadmium EPA200.7 <1.Omg/L 01/10/2017 Chromium EPA200.7 <1.Omg/L 01110/2017 Lead EPA200.7 <1.Omg/L 01/10/2017 Selenium EPA200.7 <1.Omg/L 01/10/2017 Silver EPA200.7 <1.Omg/L 01/10/2017 Mercury EPA245.1 <0.0020mg/L 01/05/2017 Comment: Sludge residuals, except pH, reported on a dry weight basis. pH reported on an as received basis Reviewed by: 0 Report#:: 201648895 Page 3 of 3 C C � cry ♦ e �r c a r Analytical & Consulting Chemists ENVIRONMENTAL CHEMISTS, INC NCDENR: OWO CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION it 37729 CtII 1 PrTInki AMIN f'WAIKI nc rr ICTnnw 6602 windmill Way Wilmington, NC 28405 OFFICE: 910.392-0223 FAX 910.392-4424 Info@anvitonmentatchemists.com Client: Smithfield Hiog Production -Warsaw PROJECT NAME: es. 5bk . -I-e p REPORT NO: r✓t: ' (P►' f ADDRESS: Pa g o l( 15 C CONTACT NAME: PO NO: ' C'V-sc'o REPORT TO: Kraig Westerbeek PHONEIFAX: COPY TO: A " tie email: aampleo t5v: QARAn. c rin=. , Sam P le identification Collection a 1t - 2 g 2 E' u` m _ 2 t' -c d I - ii-DUGM, 2 —°� E c - ° m m ¢muent, vv PRESERVATION =wen, S I = Stream, SO = Soil, SL = Sludge, Other: ANALYSIS REQUESTED Date Time Tem i o so o w Residuals 1 4 AA �5b C P �L41 t{ X Full TCLP, RCI, Nutrients(metals G C P G G C P G G C P- G G C P G G C P G G C P G G C P G G C P G G Transfer Relinquished By: DatelTime Received By: Datel7ime 1. 2. TP_moaratnrn whc.'P... iv.A.. ------- 7. _ Delivered 'x � � Environmental �liemists, Ia' - 0* e B ® 6W2 Windmill Wav, Wilmington, NC 29405 • 910.392.0223 Lab • 910.392.4424 Fax 710 6otvsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilnington Highway, Jacksonville, NC 25540 a 910.3475843 Lab/Fax ANALYTICAL.& CONSULTING CHEMISTS inlbrn cnvironntenlukhcntists.coiu ' i Smithfield Hog Productions - Warsaw Date of Report: Jan 20, 2017 Post Office Box 856 Customer PO #: Warsaw NC 28398 Customer ID: 08110011 Attention: Kraig Westerbeek Report#: 2016-18896 Project ID: Lab ID Sample ID: Collect Date/Time Matrix Sampled by 1645294 Site: #2 12/30/2016 9:15 AM Water Client Test I Method Total Solids (%) SM 2540 B Chlordane SW 846 Method 8081 B/3510 Endrin SW 846 Method 8081 B/3510 Heptachlor SW 846 Method 8081 B/3510 Heptachlor epoxide SW 046 Method 8081 B1351 0 Lindane SW 846 Method 8081 B13510 Methoxichlor SW 846 Method 8081 B/3510 Toxaphene SW 048 Method 8081 B/3510 1,4-Dichlorobenzene (TCLP) SW 846 method 8270/3510 2,4,5-Trichlorophenol(TCLP) SW 846 method 8270/3510 2,4,6-Trichlorophenol(TCLP) SW 846 method 827013510 2,4-Dinitrotoluene (TCLP) SW 846 method 827013510 Cresol (TCLP) SW 846 method 8270/3510 Hexachloro-1,3-butadiene (TCLP) SW 848 method 8270/3510 Hexachlorobenzene(TCLP) SW 846 method 8270/3510 Hexachloroethane (TCLP) SW 846 method 8270/3510 m-Cresol (TCLP) SW 846 method 827013510 Nitrobenzene (TCLP) SW 846 method 8270/3510 o-Cresol (TCLP) SW 846 method 8270/3610 p-Cresol (TCLP) SW 846 method 827013510 Pentachlorophenol(TCLP) SW 846 method 8270/3510 Pyrldlne`(TCLP) SW846 method 8270/3510 - 2,4,5-TP SW846 Method 8151A 2,4-D SW846 Method 8151A 1,1-Dichloroethylene SW846 Method8280/5030 1,2-Dichloroethane SW846 Method8260/5030 Results Date <0.1 % 01/05/2017 <0.02 mg/L 01/04/2017 <0.0005mg/L 01/04/2017 <0.0005mg/L 01/04/2017 <0:0005mg/L 01/04/2017 <0.0005mg/L 01/04/2017 <0.0005mg/L 01/04/2017 <0.05 mg/L 01104/2017 <0.050mg/L 01/04/2017 <0.050 mg/L 01/04/2017 <0.050mg/L 01/04/2017 <0.050mg/L 01/04/2017 <0.050mg/L 01/04/2017 <0.050mg/L 01/04/2017 <0.050mg/L 01/04/2017 <0.050 mg/L 01/04/2017 <0.050 mg/L 01/04/2017 <0.050 mg/L 0110412017 <0.050mg/L 01/04/2017 <0.050mg/L 01/04/2017 <0.250 mg/L 01/04/2017 <0.050 mg/L 01/04/2017 <0.003mg/L', 01/05/2017 <0.003mg/L 01/05/2017 <0.01 mg/L 01/10/2017 <0.01 mg/L 01/10/2017 Report#:t 2016-18888 Pagel of Environmental Chemists, Inc. ar. 4 b6(12 Windmill Way, Wilminghm, NC 28405 • 910.392.0223 Lab • 910.392.4424 Fax 710 Bowserhncn Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax z :SIA. 255-A Wilmington Highway, Jacksonville, NC 28940 ^ 910.347.5843 Lab/Fax ANALYTICAL 8 CONSULTING CHEMISTS' inlb(a cnvironmcntalchemists.cons Smithfield Hog Productions • Warsaw Date of Report: Jan 20, 2017 Post Office Box 856 Customer PO #: Warsaw NC 28398 Customer ID: 08110011 Attention: Kraig Westerbeek Report #: 2016-18896 Project ID: Benzene SW846 Method8260/5030 <0.01 mg/L 01/1012017 Carbon Tetrachloride SW646 Method 8260/5030 <0.01 mg/L 01/10/2017 Chlorobenzene SW848 Method 8260/5030 <0.01mg/L 01/10/2017 Chloroform SW846 Method8260/5030 <0.01mg/L 01/10/2017 Methyl ethyl ketone SW846 Method 8260/6030 <0.05 mg/L 01110/2017 Tetrachloroethylene SW846 Method826015030 <0.01mg/L 01/10/2017 Trichloroethylene SW846 Method8260/6030 <0.01mgIL 01/10/2017 Vinyl Chloride SWO46 Method 826015030 <0.01mg/L 01/10/2017 RCI Cyanide EPA335.4 <0.005mg/L 01/05/2017 Sulfide SM4500SD <0.01mg/L 01/09/2017 Analyzed outside of holding time. Ignitability SW 846 method 1010 >212°F 01/12/2017 Sludge Residuals Aluminum EPA200.7 106mg/L 01/05/2017 Arsenic EPA200.7 <10.Omg/L 01105/2017 Cadmium EPA200.7 <10.Omg/L 01/05/2017 Calcium EPA200.7 57400mg/L 01/0612017 Chromium EPA200.7 <10.Omg/L 01/05/2017 Copper EPA200.7 10.0mg/L 01/05/2017 Lead EPA200.7 <10.0mgIL 01/05/2017 Magnesium EPA200.7 4900mg/L 01/06/2017 Molybdenum EPA200.7 <10.Omg/L 01/05/2017 Nickel EPA200.7 <10.Omg/L 01105/2017 Potassium EPA200.7 23300mg/L 01/06/2017 Selenium EPA200.7 <10.Omg/L 01/05/2017 Sodium EPA200.7 25800mg/L 01/06/2017 Zinc EPA200.7 122mg/L 01/05/2017 Mercury EPA245.1 <0.200mg/L 01/05/2017 Ammonia Nitrogen EPA350.1 157mg/L 01/04/2017 Report #:: 2016-18896 Page 2 of 3 s � Environmental ti hemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 • 910.392.0223 Lab - 910 392.442d Fax 710 Bowsertuwn Road, Manteu, NC 27954 • 252.473 5702 Lab/Fax SM 255-A Wilmington Flighwav, Jacksonville, NC 28540 9711.347.5843 Lib/Fay ANALYTICAL & CONSULTING CHEMISTS iinlii(n;eaviro0nlantalchem isti.00111 Smithfield Hog Productions - Warsaw Date of Report: Jan 20, 2017 Post Office Box 856 Customer PO #: Warsaw NC 28398 Customer ID: 08110011 Attention: Kraig Westerbeek Report #: 2016-18896 Project ID: Total Kjeldahl Nitrogen (TKN) EPA351.2 3490mg/L 01/09/2017 Nitrate+Nitrite-Nitrogen EPA353.2 2630mg/L 01/13/2017 pH SM 4500 H B 7.80 units 01/10/2017 Total Phosphorus SM 4500 P F 1680 mg1L 01/09/2017 TCLP Metals Arsenic EPA200.7 <1 Om IL 01/10/2017 g Barium EPA200.7 <1.Omg/L 01110/2017 Cadmium EPA200.7 <1.0mg/L 01/1012017 Chromium EPA200.7 <1.0mg/L 01110/2017 Lead EPAzo0.7 <1.Omg/L 01/10/2017 Selenium EPA200.7 <1.0mg/L 01/10/2017 Silver EPA200.7 <1.Omg/L 01/1012017 Mercury EPA24st <0.0020mg/L 01/05/2017 Comment: Sludge residuals, exceptp, reported on a dry weight basis. pH reported on an as received basis Reviewed by: Report #:: 2016-10896 Page 3 of 3 �,r I'M r � I r +r vot* Y . .Analytical & Consulting Chemists a C C ENVIRONMENTAL CHEMISTS, INC NCDENR: DWQ CERTIFICATION 0 94 NCDHHS: DLS CERTIFICATION # 37729 Cnl 1 ru-rir d AAIn ru Aim ne rr'�csr�nv $602 Windmill Way Wilmington, NC 28405 OFFICE: 910392-0223 FAX 910-392-4424 info&nvironmentalchemists.com Client: Smithfield Hog Production -Warsaw PROJECT NAIVE: Res. So! . I L L P REPORT NO: 14 076 ADDRESS: 76 Box S 5'r. CONTACT NAIVE: PO NO: VS-1 NC aS;3 !? REPORT TO: Kraig Westerbeek PHONEIFAX: COPY TO: A M I w o JC email: 1LtJcS�crbea (c®s iC ; e Sarnn[L-rl Rv- Sample Identification p Collection a a N ti -- -.-. _ E° _ =... _ a _.. - ....._...., = Ja a E - g �.....�.., PRESERlfATION VA I avi6 0L = 3IuU u' utner: ANALYSIS REQUESTED Date Time Temp" z v _ "_ ^o = o= a o w c Residuals CD SJ C P 5S tiSL Y> Full:TCLP, RCI, Nutrients/metals I a9►I 915 G G C P G G C P G G C P G G C P G G C P G G C P G G C P G G C P i G G Transfer Relinquished By: Datertlme Received By: Daterl ime t. 2. . v.vp... urm.c rrnm. Delivered By-._ Time: i b 05 V�