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HomeMy WebLinkAboutWQ0014452_2017 Annual Report_20180215Town of Bladenboro, NC RESIDUALS LAND APPLICATION PROGRAM Perffiit No. WQ0014452 2017 ANNUAL REPORT a Town of Bladenboro, NC Residuals Land Application Program 2017 Annual Report TABLE OF CONTENTS 1. Certification Form and Annual Operations Summary 2. Annual Residual Sampling Summary Forms, Residuals Analysis, & SAR Calculation Page 3. Annual Land Application field Summary Forms 4. TCLP Analysis 5. Pathogen ReductionNectgr Attraction Reduction 6. Soil pH & Lime Application Records 7. Soil Analyses ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit #: W00014452 County Bladen Year 2017 Facility Name (as shown on permit) Bladenboro W WTP NPDES No. NCO026352 Land Application Operator, Svnaero Phone# (336) 998-7150 Land application of residuals as allowed by the above permit occurred during the past calendar year? X 'YES NO. NNO, skip Part A, and Part Band proceed to Part C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A —Residuals Application Summary: Total number of application fields in the permit: 4 . Total number of fields utilized for land application • during the year: 2 Total amount of dry tons applied during the. year for all application sites: 25.43 Total number of acres utilized. for land application during the year: 16 Part B — Annual Compliance Statement: Facility was compliant during calendar year 2017 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Quality X YES NO. If no, please provide a written description why the facility was not compliant, the dates,. and explain corrective action taken. 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified is the permit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory resultsare attached. - ' 4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. I 6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading Rates in 15A NCAC 02T .I 105(b) (Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 1 8. All monitoring and reporting requirements in• 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9. All operations' and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at monitoring well or explanations of violations are attached to include appropriate actions and remediatioas. 11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified' in the permit 12. No runoff of residuals from the application 'sites onto adjacent property or nearby surface watershas occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C — Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." ' 2uRA6 P. Mr-Y-I, Z� M -TL Permittee Name and Title (type or print) Signature of Preparer* Date (if different from Permittee) _k'U�on K-1_ JGtCltc>Ut 15^t8 Signature ofPe ri Date SignatMe of Land App rDate (if different from Permittee and Preparer) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006) 2017 ANNUAL OPERATIONS SUMMARY - LAND APPLICATION BLADENBORO,NC BLADENBORO, NC AEROBICALLY DIGESTED LIQUID MONTHNEAR December 2017 YEARLY TOTAL DRY METRIC AMOUNT UNIT DRY TONS UNIT TONS 204,600.00 G 25.43 D 23.06 204,600.00 G 25.43 D 23.06 2/8/2018 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: WQ0014452 Facility Name: BLADENBORO, NC NPDES# : NCO026352 or WQ# (residual only) WWTP Name: BLADENBORO Residuals Analysis Data Product Type AEDLIQ Date Sampled (grab) or 11/13/17 Date Composited Percent Solids 2'. 98 PARAMETERS (mg/kg dry weight) Arsenic 4.02 Cadmium <2 Mercury 0.497 Chromium 84.5 Copper 435 Lead 24.6 Molybdenum <5 Nickel 41.1 Selenium <5 Zinc 556 Total Phosphorus 14300 TKN 42800 Ammonia -Nitrogen 9700 Nitrate and Nitrite 99 Laboratory Waypoint Analytical Virginia Inc. "I certify, under penalty of law, that this'document was prepared under my direction or'supervision in accordance with a system designed to as urg;tjat qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant pea r suboitting false information, including the possibility of fines and imprisonment for knowing violations." Date DENR FORM RSSF (5/2003) Printed: Thursday- February 8 2018 at 16:54:41 for: 2004 01 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: WQ0014452 Facility Name: BLADENBORO, NC NPDES# : NCO026352 or WQ# (residual only) WWTP Name: BLADENBORO Residuals Analysis Data Product Type AEDLIQ Date Sampled (grab) or _ 11/13/17 Date Composited Percent Solids 2.98 PARAMETERS (mg/kg dry weight) Aluminum 7520 Calcium 13600 Magnesium 1590 pH 7.69 Potassium 1800 Sodium 710 "I certify, under designed to significant p n6 Fq Laboratory Waypoint Analytical Virginia Inc. ilty of law, that this document was prepared under my direction or supervision in accordance with a system :hat qualified personnel properly gathered and evaluated the information submitted. I am aware that there are for sub/nitting false information, including the possibility of fines and imprisonment for knowing violations." NR - Data Not Reported or Data Not Required Date DENR FORM RSSF-B (7/2002) Printed: Thursday - February 8. 2018 at 16:55:05 for: 2004 01 Page: 1 of 2 Report Number: 17-318-0203 Account Number: 46437 Send To: Synagro Central LLC/ Bladenboro Marshal Puryear 284 Boger Road Mocksville , NC 27028 Lab Number: 57101 Sample Id : bladenboro wwtp Waypoint. (D ANALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Project: Bladenboro W WTP REPORT OFANALYSIS Date Sampled: 11/13/2017 11:30:00 Date Received: 11/14/2017 00:00 Date Reported: 11/21/2017 Total Solids 2.98 29800 100.0 JM 11/14/201715:00 SM-2540G Moisture' 97.01 _ .100.0 JM 11/14/201715:00 SM-254OG Total Kjeldahl Nitrogen 428 42800 50.0 R D 11/15/2017 08:30 SM-4500-NH3C-TKN Total Phosphorus 1.43 14300 100 MOS 11/15/2017 15:34 6010C Total Potassium 0.18 1800 100 MOS 11/1612017 12:34 6010C Total Sulfur 0.78 7800 100 MOS 11/15/2017 15:34 6010C Total Calcium 1.36 13600 100 MOS 11/15/2017 15:34 6010C Total Magnesium 0.16 1590 100 MOS 11/15/2017 15:34 6010C Total Sodium 0.07 710 100 MOS 11/15/2017 15:34 6010C Total Iron 14300 100 MOS 11/151201715:34 6010C Total Aluminum 7520 100 MOS 11/16/2017 12:34 6010C Total Manganese 145 5.00 MOS 11/15/2017 15:34 601OC Total Copper 435 5.00 MOS 11/15/2017 15:34 601OC Total Zinc 556 5.00 MOS 11/15/2017 15:34 6010C Ammonia Nitrogen 0.97 9700 50.0 R D 11/15/2017 08:30 SM-4500-NI3C Organic N 3.31- 33100 50.0 11/15/2017 08:30 CALCULATION Nitrate+Nitrite-N 99.0 2.37 MMT 11/16/201714:45 450ONO3F-2011 All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. �« Ourrepons and letters am forthe exclusive and cnnfidenliel use of ourclienfs, and may not be reproduced In whole organ, normay any reference be made to the work, the results, orthe company in any advedising, news release, orotherpublic announcements without obtaining ourpdorwritten authorization. , Pauric McGroary Agronomist Page: 2 of 2 Report Number: 17-318-0203 Account Number: 46437 Send To: Synagro Central LLC/ Bladenboro Marshal Puryear 284 Boger Road Mocksville , NC 27028 Lab Number: 57101 Sample Id : bladenboro wwtp Waypoint.. ANALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 a Fax 804-271-6446 www.waypointanalytical.com Project: Bladenboro W WTP REPORT OFANALYSIS Total Cadmium <2.00 Total Chromium 84.5 Total Nickel 41.1 Total Lead 24.6 Total Arsenic 4.02 Total Mercury 0.497 Total Selenium <5.00 pH ` 7.69 Total Volatile Solids 45.33 _ 453300 Total Molybdenum <5.00 Comments: NC CERT#257, SC CERT#9300 7001 SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES. Date Sampled: 11/13/2017 11:30:00 Date Received: 11/14/2017 00:00 Date Reported: 11/21/2017 2.00 MOS 11/15/201715:34 6010C 5.00 MOS 11/15/201715:34 6010C 5.00 MOS 11/15/201715:34 6010C 5.00 MOS 11/15/201715:34 6010C 3.00 MOS 11/15/201715:34 6010C 0.400 SJB 11/20/201710:51 SW-7471B 5.00 MOS 11115/201715:34 6010C 1.00 R D 11/15/2017 08:30 SW-9045D 100.0 JM 11114/201715:00 SM-2540G 5.00 MOS 11/15/201715:34 6010C All values are on a dry weight basis except as noted by.aster sk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any mfemnce be made to the wodr, the results, or the company in any advertising, news release, or otherpublic announcements without obtaining ourpnor written authodution. Pf« AV Ga°"� Pauric McGroary Agronomist Sodium Absorption Ratio Calculation (SAR) Product Code Product Name Sample Date ReportRange Ratio 2004-01-AEDLIQ-NC BLADENBORO, NC AEROBICALLY - • 11/13/2017 1/112017-12131/2017 0:2644 DIGESTED LIQUID Na mg/I = (Na mg/kg x % Solids) +100 = (710.x 2.9800) + 100 = 21.158 Ca mg/I = (Ca mg/kg x % Solids) + 100 = (13600 x 2.9800) 100 = 405.28 Mg mg/l = (mg mg/kg x % Solids) + 100 = (1690 x 2.9800) + 100 = 47.382 Na meq = Na mg/I + Molec.Wgt.Na = 21.158 + 23 = 0.919913 Ca meq = Ca mg/I + Molec.Wgt.Ca = 405.28 + 20 = 20.264 Mg meq = Mg mg/I--+ Molec.Wgt.Mg = 47.382 + 12 = 3.9485 SAR = Na meq + SgrRoot[0.5 x (Ca meq + Mg meq)] = 0.919913 + SgrRoot[0.5(20.264+3.9485)] = 0.264388 . Printed: 2/8/2018 Page 1 16:56 f� ACILITYNAME: BLADENBORO,NC )WNER: TOWN OF BLADENBORO iITE #: NC BL 00003 FIELD# : BL 00003 0003 3ESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIE LD SUMMARY FORM PREDOMINANT SOIL SERIES: GOLDSBORO PERMIT #: W00014452 ANNUAL DRY TONS APPLIED: 10.02 OPERATOR: TOWN OF BLADENBORO CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 6.10 ACRES PERMUTED: 6.10 Page: 1 Lime Applied Date iLbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) "�" Tons Cond. Precip. cation till- all- Ammonia Nitrate PAN DATE or Solids pet Residual DWet, Dry, Past 24 Method zation zation TKN Nitrogen and (pp m) Crop p Total MONTH Per Acre 1215/17 80,600.00 (G) 13213.115 2.98 1.642 BLAEDL DRY 0-<I/2" SUR 0.5 0.30 42,800.p 9,700.00 p 99.00 p 14879 WHEAT Dec-17 80,600.00 (G) 13,213.115 Total Gallons/Ac: 13,213.11 As Cd Cr Cu Pb Fig Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 49 0.013 0.007 0.277 1.428 0.081 0.002 0.016 0.135 0.016 1.826 46.96 Cumulative lbs/acre 0.139 0.067 3.346 19.126 1.009 0.034 0.167 1.551 0.161 23.164 'emit PAN Limit (lbs/acre) 1st Crop/2nd Crop r "''' J ' M 1 i M t Ill. 136 c'� FD Cumulative Pollutant Loading Rate Limit (lbs/nre) 36.6 34.8 r an 1339.0 267.9 15.0 375.0 89.0 2500.0 ! ! l BLAEDL = BLADENBORO, NC AEROBICALLY DIGESTED LIQUID X a 2 Z15I$ (SIGNATURE OF LAND APPLIER) - DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A=Not Applicable NR=Not Reported or Not Required %=percent p=ppm or mgdrg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ° Application Method: SUR-Surface, INJ -Injection, SURIN -Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2018 FACILITYNAME: BLADENBORO,NC JWNER: TOWN OF BLADENBORO 81TE #: NC BL 00003 I =# : BL 00003 0004 RESIDUAL SOURCE(S) * See list at bottom of report 0 ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: GOLDSBORO PERMIT#: W00014452 OPERATOR: TOWN OF BLADENBORO, ANNUAL DRY TONS APPLIED: 15.41 CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 9.90 ACRES PERMITTED: 9.90 Page: 1 Lime Applied *•* Date Lbs/Ac jallons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (VM (specify) ^/o Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or .MONTH Solids Per Residual 'Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppm) Crop Total Per Acre 12/4/17 124,000.00 (G) 12525.253 2.98 1.556 BLAEDL - DRY 0- 1/2" SUR 0.5 0.30 42,800.p 9,700.00 p 99.00 p 14879 WHEAT Dec-17. 124,000.00 (G) 12,525.253 TOTALS: As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN Annual lbs/acre 46 0.013 0.006 0.263 1.354 0.077 0.002 0.016 0.128 0.016 1.731 44:51 Cumulative lbs/acre 0.300 0.041 2.243 12.215 0.682 0.021 0.102 1.000. 0.113 15.077 t ]r ,emit PAN Limit (lbs/acre) 1st Crop2nd Crop ; t , ,� '( t: t �. ` f l - 136 J FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34 8 1339.0 267.9 ""f a" 'i 15.0 �„ 375.0 89.0 2500.0 DDD BLAEDL = BLADENBORO, NC AEROBICALLY DIGESTED LIQUID x (SIGNATURE OF LAND APPLIER) DATE - "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A=Not Applicable NR=Not Reported or Not Required .%=percent p=ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR- Surface, INJ -Injection, SURIN -Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2018 �� EPR9agN1dENYALiE6a0.+OlAefE5, lN0 hrtalptical fabetatorles November 28, 2017 Chad M. Hayes , Synagro 284 Boger Rd. Mocksville; NC 27028 TEL: (336) 998-7150 FAX: (336) 998-8450 RE: Bladenboro WWTP Dear Chad M. Hayes: Summit Environmental Technologies, Inc. 3310 Win St. Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX.- (330) 253-4489 Websht: httn://www:settekcom Order No.: 17110701 Summit Environmental Technologies, Inc. received 1 sample(s) on 11/14/2017 for the analyses presented in the following report. There were no problems with the analytical events associated with this report unless noted in the Case Narrative. Quality control data is within laboratory defined or method specified acceptance limits except where noted. If you have any questions regarding these tests results, please feel free to call the laboratory.' Sincerely, Jennifer Woolf Project Manager 3310 Win St:, Cuyahoga, Falls, Ohio 44223 Arkansas 88-0735, Califomia 07256CA, Colorado, Comecticut PH-0108, Delaware, Florida NELAC E87688, GeorgiaE87688, Idaho 01100923, Illinois 200061, Indiana C-011-13, Kaasss E-10347, Kennmky (Underground Storage Took) 3, Kentucky 90146, Louisiana 04061, Maryland 339, Miaresota 409711, New Hampshire 2996, New Jersey 011006, New York 11777, North Carolina 39705 and 631, North Dakota R-201, Oklahoma 9940, Oregon OH2O0001, Rhode Island LA000317, South Carolina 92016001, Texas TI047044664 1-5, Utah OH009232011-1, Virginia 00440 and 1591, Washington C991 Page 1 of 36 "y Summit Environmental Technologies, Inc. Case Narrative ui iur 3310 Win St. 1\ RMIRONWENTALTECBNOLOCIES, INC-. CayahogaFalls, Ohio 44223 WO#: 17110701 AnalyBcal Laboratories TEL: (330) 253-8211 FAX: (330),253-4489 Website: haol/www.settekemn Date: 11/2S/2017 CLIENT: Synagro Project: Bladenboro WWTP WorkOrder Narrative: 17110701: This report in its entirety consists of the following documents: Cover Letter, Case Narrative, Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody, Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit Environmental Technologies, Inc., Work Order Number assigned to this report. Summit EnvironmentalTechnologies, Inc., holds the accreditations/certifications listed at the bottom of the cover letter that may or may not pertain to this report. State Certificates and Scopes of Accreditation are attached as applicable. Results provided in this report for any parameter not listed on the Scope of Accreditation should be considered "not certified." The information contained in this analytical report is the sole property of Summit Environmental Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of t� Summit Environmental Technologies, Inc. or the customer for which this report was issued.' The results contained in this report are only representative of the samples received. Conditions can vary at different times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible for use or interpretation of the data included herein. All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as "dry weight" using the "-dry" designation on the reporting units. . This report is believed, to meet all of the requirementsof the accrediting agency, where applicable. Any comments or problems with the analytical events associated with this report are noted below. WorkOrder Comments: 17110701: Sample Receipt Temperature= 5.8°C Analytical Sequence Sample Notes: 17110701-001A SVOC-BNA_TCLP(8270): The BNA 8270 CCV (Batch R77398) exhibited high recoveries for several analytes and low recovery for Surrogate: Phenol-d6; Associated samples are ND for all analytes of interest. 17110701-001a tclp-svoc-epest_tclp(8081): TCLP Pesticide Sample MS and MSD pair exhibited high RPDs for all analytes of interest. Original Page 2 of 36 U I T Smmait Environmental Tec3310 haolWS. Case Narrative 10 win st. MVIRONMENTAL ISCMOLOGI'cS, 19C. Cuyahoga Falls, Ohio 44223 wo#: 17110701 Anaiytica! Laboratories TEL: (330) 253-8211 FAX.. (330) 253-4489 website: huoda� /wv.seaekcom Date: 11/28/2017 CLIENT: Synagro Project: Bladenboro WWTP Analytical Sequence QC Notes: . NM-29700 SVOC-BNA_TCLP(8270): The BNA TCLP Method Blank (Batch 29700) exhibited high recovery for Surrogate: Nitrobenzene-d5; the MB is ND for all analytes of interest. LCS-29700 SVOC-BNA_TCLP(8270): The BNA TCLP LCS (Batch 29700) exhibited low recovery for Phenol-d6; All analytes of interest exhibited recoveries within acceptance limits. 17110701-00IAMS SVOC-BNA TCLP(8270): The BNA TCLP Sample MS exhibited low recovery for Phenol-d6; All analytes of interest exhibited recoveries within acceptance limits. 17110701-OOIAMSD SVOC-BNA_TCLP(8270): MSD not reported due to Internal Standard failing Original Page 3 of 36 � w Summir Environmental Technologies, In Qualifiers and Acronyms 3310 /owms ` ENVIROMMENTALTECHUCLOCIZ5, INC. Cuyahoga Falls, Ohio 4422 WO#: 17110701 Analytical I aborstorfes TEL: (330) 253-8211 FAX.- (330) 253-445 • Website: hup.-lAvlvtv.settek.co. Date:. 11/28/2017 These commonly used Qualifiers and Acronyms may or may not be present in this report. Qualifiers •- " U The compound was analyzed for but was not detected. J The reported value is greater than the Method Detection Limit but less than the Reporting Limit: , H . The hold time for sample preparation and/or analysis was exceeded. , D The result is reported from a dilution. ' E The result exceeded the linear range of the calibration or is estimated due to interference. MC The result is below the Minimum Compound Limit. - * The result exceeds the Regulatory Limit or Maximum Contamination Limit. in Manual integration was used to determine the area response. - ' it • Manual integration in which peak was deleted N The result is presumptive based on a Mass Spectral library search assuming a 1:1 response. P The second column confirmation exceeded 25% difference. C The result has been confirmed by GC/MS. X The result was not confirmed when GC/MS Analysis was performed B/MB+ The analyte was detected in the associated blank G The ICB or CCB contained reportable amounts of analyte. - . QC-/+ The CCV recovery failed low (-) or high (+). ' R/QDR The RPD was outside of accepted recovery limits. QL-/+ The LCS or LCSD recovery failed low (-) or high (+). QLR The LCS/LCSD RPD was outside of accepted recovery limits. •, QM-/+ The MS or MSD recovery failed low (-) or high (+). QMR The MS/MSD RPD was outside of accepted recovery limits. ., _ QV-/+ The ICV recovery failed low (-) or lrigh (+). - ° • S '� The spike result was outside of accepted recovery limits.. . Z Deviation; A deviation from the method was performed; Please refer to the Case Narrative for additional information Acronyms ND Not Detected RL Reporting Limit QC Quality Control MDL Method Detection Limit MB Method Blank LOD Level of Detection _ LCS Laboratory Control Sample LOQ Level ofQuanfitation ' LCSD Laboratory Control Sample Duplicate PQL Practical Quantitation Limit QCS Quality Control Sample CRQL Contract Required Quantitation Limit DUP Duplicate PL Permit Limit . MS Matrix Spike - RegLvl Regulatory Limit ' MSD Matra Spike Duplicate MCL Maximum Contamination Limit ' RPD Relative Percent Different MinCL Min m= Compound Limit ' ICV Initial Calibration Verification RA Reanalysis ICB Initial Calibration Blank RE Reextraction CCV Continuing Calibration Verification TIC Tentatively Identified Compound CCB Continuing Calibration Blank RT Retention Time _ RLC . Reporting Limit Check CF Calibration Factor DF ' Dilution Factor RF Response Factor This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting.. Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this list or for additional information regarding the use of these Qualifiers on reported data. �) Original Page 4 of 36 Sronmit Environmental Technologies,Inc. WOrkorder 3310 Win St. RIVIRONMENTAL TECHNOLOGIES, INC. Cuyahoga Falls, Ohio 44223 Sample Summary Analytical laboratories TEL: (330) 253-8211 FAX. • (330) 253-4489, WO#: 17110701 Websile: hu .-IA lv.seuekcom 28-Nov-17 CLIENT: Synagro Project: Bladenboro WWTP Lab SampleID Client Sample D) Tag No Date Collected Date Received Matrix 17110701.001 Bladenboro W WiP 11/13=17 11:30:00 AM 11/14=17 10:00:00 AM Sludge Page 5 of 36 �8 > � -, �� sam+rEnvironmental Teehnar10WinStInc. 3310 Win St. Analytical Report ENVIRONMENTAL TECHNOLOGIES, IPiC. Cuyahoga Falls, Ohio 44213 (basereport) /rrelytical Laboratories TEL: (330) 253-8211 FAX.-. (330) 253-4489 WO#: 17110701 Website: htta://www.settekeom Date Reported: 11/28/2017 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 11/13/2017 11:30:00 AM Lab ID: 17110701-OOIA Project: Bladenboro WWTP Client Sample ID Bladenboro W WTP Analyses Result RL Qual Units DF . Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW7470A SW7470A Analyst ALJ ' . TCLP MERCURY ANALYSIS (SW1311/7470) TCLP Mercury NO 0.00200 mg/L 1 11/16/2017 5:05:00 PM TCLP METALS, VOC, BNA, PEST,.HERBSOLID SW6010C SW3010A Analyst KMS TCLP METALS ANALYSIS (SW131116010) TCLP Arsenic(As) ND 0.500 mg/L 1 11/16/2017 5:29:25 PM TCLP Badum(Ba) - ND 5.00 mg/L 1 11/16/2017 5:29:25 PM TCLP Cadmium(Cd) ND 0.1.00 mg/L 1 11/16/2017 5:29:25 PM - TCLP Chromium(Cr) - ND 0.200 mg/L 1 11/16/2017 5:29:25 PM _ TCLP Lead(Pb) - ND 0.500 mg/L 1 11/16120175:29:25 PM - TCLP Seler ium(Se) ND 0.0500 mg/L 1 11/16/2017 5:29:25 PM TCLP Silver(Ag) ND 0.500 mg/L 1 11/16/2017 5:29:25 PM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8270C SW3510C , Analyst: BJH TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270) 1,4-Dichlorobenzene , ND 0.0800 mg/L 2 11/17/2017 2:47:00 AM 2,4,5-Tiichlorophenol ND 0.200 QC+ mgtL 2 11117120172:47:OOAM 2,4,6-Trichlorophenol ND 0.200 QC+ mg/L 2 11/17/20172:47:OOAM ' 2,4-Dinitrotoluene ND 0.100 QC+ ingil- 2 1 Ill 7/20172:47:00 AM Cresols, Total - ND 4.00 mg/L 2 11/17120172:47:00AM Hexachlorc-1,3-butadiene ND 0.100 mg/L 2 11/17120172:47:00'AM Hexachlorpbenzene ND 0.100 mg/L 2 11/17/20172:47:00AM Hexachloroethane ND 0.0800 mglL 2 11/17/20172:47:OOAM Nitrobenzene ND 0.0800 mg/L 2 11/17/20172:47:OOAM Pentachlorophenol • ND 0:200 mg/L 2" 11/17120172:47:OOAM Pyridine ND 0.200 mg/L 2 11/17/20172:47:OOAM Sum 2-Fluorophenol 57.3 10-109 %Rec 2 11/17/20172:47:OOAM Sum Phenol-d6 60.2 10-109 %Rec 2 11/17/20172:47:00AM Surr Nitrobenzene-d5 95.5 '19-120 %Rec 2 11/17/20172:47:OOAM Surr:2,4,6-Tdbromophenol 60.3 10 -120 %Rec 2 11/17/2017 2:47:00 AM Surr: 2-Fluorobiphenyl 74.0 22 - 117 %Rec 2 11/17/2017 2:47:00 AM Surf: p-Terphenyl-d14 88.4 34 -116 %Rec 2 11/172017 2:47:00 AM QualiSers• " Value exceeds Maximum Contaminant Level. E Value above quantitation range H Holding times for preparation or analysis exceeded M 'Manuel Integration used to detemilne area response / MC Value is below Minimum Compound Limit. N Tentatively identified compounds ND Not Detected 0 • RSD is greater than RSDIimit ' P Second column confirmation exceeds PL Permit Limit I Original R RPD outside accepted recovery limits RL Reporting Detection Limit Page 6 of 36 Summit Environmental Technologies, Ina - Analytical Report 3310 Win St. RiVIROWENTAL TECHNOLOGIES, IxR Cuyahoga Falls, Ohio 44223 (basereport) Analyffcaf Lahorarorjes TEL. (330) 253-8211 FAX.-. (330) 253-4489 WO#:17110701 Websile: h ry.-IAnmvsettekcom Date Reported: 11/28/2017 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 11AV201711:30:00 AM Lab ED: 17110701-001A Project: Bladenboro WWTP Client Sample lD Bladenboro W WTP Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8270C SW3510C Analyst BJH TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270) _ NOTES: The BNA 8270 CCV (Batch R77398) exhibited high recoveries for several analytes and low recovery for Surrogate: Phenol-d6; Associated samples are ND for all analytes of interest. TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8081A SW3510C Analyst JBN TCLP PESTICIDES ANALYSIS (SW131118081) Chlordane, total ND 0.0100 mg/L 1 11/22/2017 9:53:00 PM Toxaphene -ND - 0.0200 ni 1 11122/20179:53:06 PM Enddn ND 0.00100 QMR mg/L 1 11/22/2017 9:63:00 PM ' {, gamma-BHC ND 0.00100 QMRd mg/L 1 11/22/20179:53:00 PM -` Heptachlor No 0.00100 QMR mg/L 1 11/22/2017 9:53:00 PM Heptachlor epoxide ND 0.00100 QMR mg/L 1 11/22120176:53:00 PM Methoxychlor ND 0.00100 QMR mg/L 1 11/22120179:53:00 PM Sum TCMX 93.3 10 -119 %Rec 1 11/22/2017 9:53:00 PM Sum DCB 85.4 10 -119 %Rec 1 11/22/2017 9:53:00 PM NOTES:. TCLP Pesticide Sample MS and MSD pair exhibited high RPDs forall analytes of interest. TCLP METALS; VOC, BNA, PEST, HERB -SOLID SW8151A SW8151A Analyst: JBN SVOC SW-846: 8151 HERBICIDES-TCLP _ 2,4-D ND 11.3 d ri 1 11/21/2017 9:23:00 PM 2,4,5-TP ND 11.3 d mg/L 1 11/2112017 9:23:00 PM Sum 2,4-Dichlorophdnylacetic aci 92.0 20 - 140 %Rea 1' 11/21/2017 9:23:00 PM TCLP METALS, VOC, BNA, PEST, HERBSOLID - SW8260B SW1311M Analyst MES TCLP VOLATILES ANALYSIS 1,1-Dichloroethene ND 0.100 mg/L 1 11/16120174:07:00 PM 1,2-Dichloroethane ND 0.100 mg/L 1 11116/20174:07:00 PM MEK ND 2.00 mg/L 1 11116/20174.07:00 PM Benzene ND 0.100 mg/L 1 11/16120174:07:00 PM Carbon tetrachloride , ND 0.100 ri 1 11/16/2617 4:07:00 PM Chlorobenzene - ND 0.100 mg/L 1 11116120174:07:00 PM Qualifiers: " Value exceeds Maximum Contaminant Level. E Value above quantitation range �_-- H Holding times for preparation of analysis exceeded M Manual Integration used to determine area: response 1 ) MC Value is below Minimum Compound Limit. N Tentatively identified compounds \._ 1 ND Not Detected O RSD is greater than RSDlirnit P Second column confirmation exceeds , PL Permit Limit Original' R RPD outside accepted recovery limits RL Reporting Detection Limit , Page 7 of 36 Summit Environmental Technologies, Inc. 3310 Win St. Analytical Report ENVIRONMENTAL TECONO LOCI25, NC. Cuyahoga Falls, Ohio 44223 (basereport) Analytical lshcrafories 'TEL:.. (330) 253-8211 FAX.- (330) 253-4489 WO#: 17110701 Website: htra://ivwrvsenekcom Date Reported- 1128/2017 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 11/13/2017 11:30:00 AM Lab ED: 17110701-001A Project: Bladenboro WWTP Client Sample ID Bladenboro W WTP Analyses Result' ' RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERBSOLID SW8260B SW1311M Analyst MES TCLP VOLATILES ANALYSIS Chloroform ND . 0.100 mg/L 1 11/16/2017 4:07:00 PM Tetrachloroethene ND 0.100 mg/L 1 11/16/20174:07:00 PM Trichlorcethene ND 0.100 mg/L 1 1.1/16/20174:07:00 PM Vinyl chloride ND 0.200 mglL 1 11/16/2017 4:07:00 PM Sum 4-Bromofluorobenzene 104 70-130 %Rec 1 11/1612017 4:07:00 PM Surr: Dibromofluoromethane 94.0 70 -130 %Rec 1 11/16/2017 4:07:00 PM Surr. Toluene-d8 95.3 70 - 130 %Rec 1 11/16/2017 4:07:00 PM - RCISOLID-W/IGNITABILITY1030 SW9014 Analyst MS / REACTIVE CYANIDE (9014/7.3.3.2)SOLID l J� Cyanide, Reactive ND 0.500 mg/Kg 1 11/21/2017 RCI-SOLID-W/ IGNITABILITY1030 SW1030 Analyst AJT IGNITABILITY OF SOLIDS (SW-846: 1030) Ignitability non-flammable 1 11/16/2017 10:00:00 AM RCISOLID-W/ IGNITABILITY1030 SW9045D Analyst: DHC PH (SW9045D) pH 7.0 s.u.@19.0C 1 11/14120172:64:00 PM RCISOLID-W/IGNITABILITY1030 SW9034 Analyst: MS REACTIVE SULFIDE (9034)17.3.4.2 Sulfide, Reactive _ 30.0 25.0 mg/Kg 1 11/21/2017 12:35:00 PM Qualifiers: " Value exceeds Maximum Contaminant Level. .E Value above quantitation range , H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response MC Value is below Minimum Compound Limit. N, Tentatively identified compounds ._ ND Not Detected O RSD is greater than RSDlimit - P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit Page 8 of 36 ms"MmIst 9amnrilEnvironmental TeahnalainSt. 33I0Win St. QC SUMMARY REPORT tr;vlNVMn4NMAL I LCHNOLUr11bS, INC. Analyltcal Laborraroriea Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 17110701 Websile: hawlAvrvw..rettelccom 28-Nov-17 Client: Synagro Project: Bladenboro WWTP BatchID: 29666 Sample ID mb-29666=10 SampType: MBLK TestCode: tclp-voc-mstr Units: mg/L Prep Date: 11/15/2017 RunNo: 77399 "lient ID: PBS Batch to: 29666 TeslNo: SW8260B SW1311M Analysis Date: 1111612017 SegNo: 1324639 4nalyle Result PQL SPK value SPK Ref Val %REC LowLimit HlghUrnit RPD Ref Val %RPD RPDLimil Qual 1,1-Dichloroethene ND 0.100 1,2-Dichloroelhane ND 0.100 MEK ND .2.00 Benzene ND 0.100 Carbon tetrachloride ND 0.100 Chlorobenzene ND 0.100 Chloroform ND 0.100 Tetrachloroethene ND 0.100 Trichloroethene ND 0.100 Vinyl chloride ND 0.200 Surr: 4-Bromofluorobe6zene 526 Surr: Dibromofluoromethane _ 471 Surr: Toluene-d8 483 500.0 105 70 130, 500.0 94.2 70 130 500.0 96.7 70 130 Sample ID Ics 20ppb 4059 SampType: LCS TestCode: tclp-voc-mstr Units: mglL Prep Date: RunNo: 77399 "lient ID: LCSS Batch ID: 29666 TestNo: SW8260B SW1311M Aralysis Date: 11/1612017 SegNo: 1324659 4nalyte Result PQL SPK value SPK Ref Val %REC LowLimit HighUrnit ' RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 0.0227 0.0100 0.0200 0 114 79.4 131 1,2-Dichloroethane 0.0230 0.0100 0.0200 0 115 73.6 137 MEK 0.0995 0.0506 0.100 0 99.5 55.1 163 Benzene 0.0215 0.0100 0.0200 0 107 73.1 132 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected Q RSD is greater than RSDlimit .Original P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Page 9 of 36 a � IT t� SnmmirEar,.aan,eatarTeehaafaWinSInc. 3310Win St., QC SUMMARY REPORT eKVIKIINrA9NIALrecewoLVOLS.,.ANC. Cuyahoga Falls, Ohio44223 AnsiyUcal taboratorfes ,. TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 17110701 ' Website: hoo:Oww v.seeekcom 28-Not-17 Client: Synagro - Project: Bladenboro WWTP BatchED: 29666 Sample ID Ics 20ppb 4059 SampType: LCS TestCode: tclp-voc-mstr Onils: mg/L Prep Date: - RunNo: 77399 Client ID: LCSS Batch ID: 29666 TestNo: SW8260B SW1311M Analysis Date: 11/16/2017 SegNo: 1324659 Analyte .. Result PQL SPK value SPK Ref Val %REC LowUmit HIghLlmit RPD Ref Val %RPD RPDLImlt Qual carbon tetrachloride 0.0192 0.0100 0.0200 0 96.2 63.7 139 Chlorobenzene. - 0.0195 0.0100 0,0200 0 97.4 - 72.3 139 Chloroform '• 0.0208 -0.0100 0.0200 0 104 79.3 129 Tetrachloroelhene _ 0.0218 Ao100 O.D200 0 109 56.2 187 Trichloroethene 0.0206 0.0100- 0.0200 0 103 64.1 138 Vinyl chloride 0.0209 " 0.0100 0.0200 0 104 22.1 147 Surr: 4-Bromofluorobenzene 52.3 50.00 105 80.4 126 Surr: Dibromofluoromethane 45.0 50.00 90.0 70.3 125 . Surr: Toluene -dB 49.7 50.00 ,. 99.4 82 117 Sample ID Icsd 20ppb 4059 SampType: LCSD TestCode: tclp-voc-mstr Units: mg/L Prep.Date: RunNo: 77399 Client ID: LCSS02 'Batch ID: 29666 TestNo: SW8260B SW1311M Analysis Dale: 11/1612017 SegNo: 1324660 ' Analyte Result PQL SPK value SPK Ref Val %REC LowLlmit HighUmit RPD Ref Val %RPD RPDLimit Qual i,i-ulcmoroemene u.u224 0.01uu 0.0200 0 112 79.4 131 0.0227 1.64 25 1,2-Dichloroethahe _ 0.0228 0.0100 0.0200 .0 114 73.6 137 0.0230 0.960 25- - MEK 0.0968 0.0500 • 0.100 .. 0 , 96.8. - 55.1 163 0.0995 2.82 25 Benzene 0.0208 0.0100, 0.0200 0 104 - 73.1 132 0.021 5' 2.88 25 Carbon tetrachloride 0.0196. 0.0100 0.0200 - 0 _ 98.2 63.7 139 0.0192 2.11 25 Chlorobenzene 0.0191 0.0100 0.0200 0 95.6 72.3 139 '0.0195 1:92 25 Chloroform - 0.0197 0.0100 0.0200 0 98.4 79.3 129 0.0208 5.29 25 Tetrachloroethene 0:0225 0.0100 0.0200 0- -112 56.2 187 0.0218 3.02 25 - Qualifiers: • Value exceeds Maximum Contaminant Level. B ' Analyte detected in the associated Melhod Blank E Value above quantitation range - H Holding times for preparation or analysis exceeded . J- Analyte detected below quantitation limits M Manual Integration used to determine ` MC . Value is below MinimumCom oundLimit.. P ND Not Detected O RSDis greater than RSDlimit Original ' P Second column confirmation exceeds 'PL Permit Limit _ R RPD outside accepted recovery limits Page 10 of 36 1 � � UIT Summit Environmental Technologies, Inc.ffIS 3310 Wirs S<. QC SUMMARY REPORT L1VIRU1NIabN I Al. I LGi14UWQuL5INC. Arialyifeal tabolotorles Cuyahoga Falls, Ohio 44223 TEL:_ (330) 253-8211 FAX.- (330) 253-4489 - WO#: 17110701 ' Website: hawlAnnv.settelr.eom 28 Not,17 Client: Synagro Project: Bladenboro WWTP BatchlD: 29666 Sample ID Icsd 20ppb 4059 SampType: LCSD TestCode: tclp-voc-mstr _Units: mg/L Prep Date: RunNo: 77399 :lient to: LCSS02 Batch ID: 29666 TestNo: SW8260B SW1311M . Analysis Date: 11/16/2017 SegNo: 1324660 lnalyte Result PQL SPK value SPK Ref Val %REC Lowlimit Hlght-lmit RPD Ref Val %RPD RPDLlmit Qual inchloroethene - 0.0204 0.0100-0.0200 0 102 64.1 138 0.0206 1.02 25 Vinyl chloride 0.0196 0.0100 0.0200 0 98.0 22.1 147 0.0209 6.32 25 Sun: 4-13romofluorobenzene 52.2 50.00 104 80.4 - 126 - 0 25 Sutr: Dibromofluoromethane 45.5 50.00 90.9, 70.3 125 0 '25 Surr: Toluene-d8, 49.6 " 50.00 - 99.2 82 117 0 25 Qualifiers: • Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value. above quantitation range H Holding times for: preparation or analysis exceeded I Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below. Minimum Compound Limit. ND Not Detected - 0 RSD is greater than RSDlimit Original P Second column confirmation exceeds PL Permit Limit - R RPD outside accepted recovery limits ' Page 11 of 36 u i� Win St. Inc. vd 3BammhEnvironmental Technologies, QC SUMMARY REPORT LRWINrrdtlAMAL. I WHH0LVG11:S,1NQ Cuyahoga Falls, Ohio 44223 Anatyllcal Laboratories TEL: (330) 253-8211 FAX:: (330) 253-4489 WO#: 17110701 Webstte: humMvinvaettekcom 28-Nov-17 Client: Synagro - Project: Bladenboro WWTP BatchID: 29690 Sample ID MB-29690 SampType: MBLK TestCode: MTL-TCLP-7( Units: mg1L Prep Date: 11116/2DI7 RunNo: 77394 client ID: PBS Batch ID: 29690 TestNo: SW6010C SW3010A Analysis Date: 11116/2017 SegNo: 1324512 Malyte Result PQL SPK value SPK Ref Val %REC LowLimit Hlghl-imit RPD Ref Val %uRPD RPDUmlt Qual TCLP Arsenic(As) ND 0.500 TCLP Barium(Ba) ND 5.00 TCLP Cadmium(Cci) ND 0.100 TCLP Chromium(Cr) ND 0.200 TCLP Lead(Pb) ND 0.500 TCLP Selenium(Se) ND 0.0500 TCLP Silver(Ag) ND 0.500 Sample ID LCS-29690 SampType: LCS TestCode: MTL-TCLP-7( Units: mg/L Prep Date: 11/1612017 RunNo: 77394 client ID: LCSS .Batch ID: 29690 TestNo; SW6010C SW3010A Analysis Dale: 11/1612017 SegNo: 1324613 Malyte Result PQL SPK value SPK Ref Val %REC LowLlmit HighLimit RPD Ref Val %RPD RPDUmit Dual TCLP Arsenic(As) 1.93 0.500 2.000 0 96.4 80 120 TCLP Barium(Ba) ND 5.00 2.000 0 - 99.1 80 120 TCLP Cadmlum(Cd) 1.83 0.100 2.000 0 91.5 80 120 TCLP Chromium(Cr) 2.01 0.200 2.000 0 100 80 120 TCLP Lead(Pb) - 1.98 0.500 2.000 0 99.0 80- 120 TCLP Selenium(Se) 2.00 0.0500 2.000 0 100 80 - 120 TCLP Silver(Ag) 2.03 0.500 2.000, 0 101 80 120 Qualifiers: • Value exceeds Maximum Contaminant Level. H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. P Second column confirmation exceeds B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range M Manual Integration used to determine 0 RSD is greater than RSDhrmt R RPD outside accepted recovery limits Original Page 12 of 36 fn u l� Inc Smm�,tEmirnamemarTea331010 Win SShaarWt. . QC SUMMARY REPORT W4V1KV,NlnhN I Al. 1 bCHFI0 G1tS, INC. Cuyahoga Falls, Ohio 44223 - Analytleal Laboratories TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 17110701 Webslte: ham:/Fvwwseuekcom 28 Now17 Client: Synagro Project: Bladenboro WWTP BatchID: 29690 Sample ID 17110703-001AMS SampType: MS TestCode: MTL-TCLP-7( Units: mg/L Prep Date: 11/1612017 RunNo: 77394 Client ID: BatchQC Balch ID: 29690 TestNo: SW6010C SW301 DA Analysis Date: 1111612017 SegNo: 1324517 Analyte' Result PQL SPK value SPK Ref Val %REC LowLimit HlghLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsemc(As) 2.11 0.500 2.000 0.04748 103 70 130 TCLP Barium(Ba) ND 5.00 2.000 0.5291 92.7 70 130 TCLP Cadmium(Cd) 1.83 0.100 2.000 0.0005364 91.7 70 130 TCLP Chromium(Cr) 1.93 0.200 2.000 0.004083 96.3 70 130 TCLP Lead(Pb) 1.81 0.500 2.000 0.0D4672 90.4 70 130 TCLP Selenium(Se) 2.17 0.0500 2.000 0 109 70 130 TCLP Silver(Ag) 2.08 0.50D 2.000 0 104 70 130 Sample ID 17110703-OD1AMSD SampType: MSD TestCode: MTL-TCLP-7(, Units: mg/L Prep Date: 1111612017 RunNo: 77394 Client ID: BatchQC Batch ID: 29690 TestNo: SW6010C SW301 DA Analysis Date: 1111612017 SegNo: 1324518 4nalyte Result PQL SPK value SPK Ref Val %REC LowLimitt HighLimit RPD Ref Val %RPD RPDLimit Quay TCLP Arsenic(As) 2.12 0,500 2.000 0.04748 103 70 130 2.108 0.318 20 TCLP Barium(Ba) ND 5.00 2.000 0.5291 92.1 70 130 0 0 20 TCLP Cadm1um(Cd) 1.82 0.100 2.000 0.0005364 91.0 70 130 1.834 0.716 20 TCLP Chromium(Cr) 1.92 0.200 2.000 0.004083 95.7 70 130 1.930 0.646 20 TCLP Lead(Pb) 1.81 0.500 2.000 0.004672 90.5 70 130 1.813 0.0748 20 TCLP Selenium(Se) 2.16 0.0500 2.000 0 108 70 130 2.171 0.715 20 TCLP Silver(Ag) 2.06 0.500 2.000 0 103 70 130 2.084 0.944 20 Qualifiers: ' Value exceeds Maximum Contaminant Level. H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. P Second column confirmation exceeds B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range M Manual Integration used to determine O RSD is greater than RSDlimit R RPD outside accepted recovery limits Original Page 13 of 36 En uur 33Win SSamnr,Env;.anneata,Teahnar10WinSt. . QC SUMMARY REPORT trGVlagVtlrrlaN l F4 t tunNUL4Q1b S, lRC. Cuyahoga Falls, Ohio 44223 �ittaryffcal [at1af910!!e6 TEL: (330) 253.8111'FAX.• (330) 253-4489 WO#: 17110701 Websuei httn://www..seuekcom 28-Nou17 Client: Synagro Project: Bladenboro WWTP BatchID: 29690 Sample ID MB-29684 SampType: MBLK TestCode: MTL-TCLP-7( Units: mglL Prep Date: 11/16/2017 _ RunNo: 77394 Client ID: PBS Batch ID: 29690 TestNo:, SW6010C SW3010A Analysis Date: 11/16/2017 SegNo: 1324523 Analyte Result PQL. SPK value SPK Ref VaI %REC LowLimit HIghLlmit RPD Ref Val %RPD RPDLlmit Qual TCLP Arsenlc(As) ND 0.500 TCLP Barium(Ba) ND 5.00 ' TCLP Cadmlum(Cd) - ND. - 0.100 - TCLP Chromium(Cr) ND 0.200 TCLP Lead(Pla) ND 0.500 TCLP Selenlum(Se) ND 0.0500 TCLP Silver(Ag) ND 0.500 Qualifiers: " Value exceeds Maximum Contaminant Level. H.. _Holding times for preparation or arialysis exceeded MC Value is below Minimum Compound Limit. P Second column confirmation exceeds B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit ' E Value above quantitation range M Manual Integration used to determine O RSD is greater than RSDlimit R RPD outside accepted recovery limits' Original Page 14 of 36 i f l � 3310/0 Win St. Summit Environmental TeehnarWinSInc.91 QC SUMMARY REPORT tr4UNUPJrneNIRL t LU"NuLUCltt:S, 1NC. Cuyahoga Falls, Ohio 44223 WO#: 17110701 Analyitcaf Laboratories TEL: (330) 253-8211 FAX (330) 253-4489 Webslte: haa:/fw m, settek.com 28-Nov-17 Client: Synagro Project: Bladenboro WWTP BatchID:, 29693 Sample ID MS-29693 SampType: MBLK TestCode: HG TCLP(74 Units: PPM Prep Date: 11116/2017 RunNo: 77387 Client ID: PBS Batch ID: 29693 TestNo: SW7470A SW7470A Analysis Date: 1111612017 SegNo: 1324359 ' Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qua[ TCLP Mercury ND 0.00200 Sample ID LCS-29693 SampType: LCS TestCode: HG_TCLP(74 Units: PPM Prep Date: 11116/2017 RunNo: 77387 Client ID: LCSS Batch to: 29693 TestNo: SW7470A SW7470A Analysis Date: 11116/2017 SegNo: 1324360 Analyte Result PQL SPK value SPK Ref Val %REC LowUmit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Mercury, 0.00434 0.00200 0.00400 0 108 80 120 Sample ID 171.10703-001AMS SampType: MS TestCode: HG TCLP(74 Units: PPM Prep Dale:. 11/1612017 RunNo: 77387- Client ID:. BatchQC Batch to: 29693 TestNo: SW7470A SW7470A Analysis Date: 11/1612017 SegNo: 1324363 Analyte . Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDUmit oust TCLP Mercury 0.00402 0.00200 0.00400 0 101 75 125 Sample to 17110703-001AMSD SampType:'MSD TestCode: HG TCLP(74 Units: PPM Prep Date: 11/1612017 RunNo: 77387 Client ID: BatchQC Batch ID: 29693 TestNo: SW7470A SW7470A Analysis Date: 11116/2017 SegNo: 1324364 Analyte Result PQL SPK value SPK Ref Val %REC LowLimil HighLimit RPD Ref Val %RPD RPDUm[t Qual TCLP Mercury 0.00397 0.00200 0.00400 0 99.2 75 125 0.00402 1.25 20 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. 1 Analyte detected below quantitation limits ND Not Detected M O Manual Integration used to determine RSD is greater than RSDImut Original P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Page 15 of 36 1 - r � �� Summit Environmental Technologies, Inc. 3310 Wm &. QC SUMMARY REPORT trMHUInrnbry i Ai. I menaatuarbs,+rac. Cuyahoga Falls, Ohio 44223 AnsiyNcal Laboratories TEL: (330) 253-8211 FAX., (330) 253-4489 WO#: 17110701 Website: httwll wrv..seaelccom 28-Nov-17 Client: Synagro Project: Bladenboro WWTP Bateh D: 29693 Sample ID 17110703-001AMSD SampType: MSD TeslCode: HG TCLP(74 Units:PPM Prep Date: 1111612017 RunNo: 77387 Client ID: BatchQC Batch ID: 29693 TestNo: SW7470A SW7470A Analysis Date: 1111612017 SegNo: 1324364 Analyte Result PQL SPK value SPK Ref Val %REC LowrUmit HlghUrnit RPD Ref Val %RPD RPDLimit Qual Qualifiers: • Value exceeds Maximum Contaminant Level. H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. P Second column confirmation exceeds B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation"range M Manual Integration used to determine O RSD is greater than RSDlimit R RPD outside accepted recovery limits Original Page 16 of 36 6 91 ummur331OinSt. Summit Environmental Technologies, ner QC SUMMARY REPORT emvlRWrtl ldkNltIL IYCHRULVU1�5, itYC. Cuyahoga Falls, Ohio 44223 WO#: 17110701 Analytical Laboratorle5 TEL: (330) 253.8211 FAX.-. (330) 253-4489 Wehsite: htto:/Aviviv..Teltelc.com 28-Nov-17 Client: Synagro Project: Bladenboro WWTP BatchID: 29698 Sample ID mb-29698 SampType: mblk TestCode: tclp-svoc-cpe Units: mg1L Prep Date: 11/1612017 RunNo: 77731 Client ID: PBS Batch ID: 29698 TestNo: SW8081A SW3510C Analysis Dale: 11/2212017 SegNo: 1332175 4alyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLlmil RPD Ref Val %RPD RPDLimit Qual Chlordane, total ND 0.0100 Toxaphene ND 0.0200 Endrin ND 0.00100 d gamma-BHC ND 0.00100 Heptachlor ND 0.00100 Heptachlor epoxide ND 0.00100 Methoxychlor NO 0.00100 Sum: TCMX 16.6 20.00 83.2 10 119 Surr: DCB 17.9 20.00 89.7 10 119 Sample ID Ics-29698 SampType: Ics TestCode: tclp-svoc-cpe Units: mglL Prep Date: 11/1612017 RunNo: 77731 Client ID: LCSS Batch ID: 29698 TestNo: SW8081A SW3510C Analysis Date: 11/2212017 SegNo: 1332176 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLlmit RPD Ref Val %RPD RPDLimit Qua] Endrin 0.00874 0.00100 0.0100 0 87.4 20 157 gamma-BHC 0.00804 0.00100 0.0100 0 80.4 22 137 Heptachlor 0.00843 0.00100 0.0100 0 84.3 24 121 Heptachlor epoxide 0.00869 0.00100 0.0100 .0 86.9 27 152 Methoxychlor 0.00836 0.00100 0.0100 0 83.6 10 199 Surr: TCMX 13.4 20.00 66.9 10 119 Surr: DCB 13.4 20.00 67.2 10 119 Qualifiers: • Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantilation range H Holding times for preparation or analysis exceeded I Analyte detected below quantilation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit.. ND Not Detected O RSD is greater than RSDlimit Original P Second column confirmation exceeds _ PL Permit Limit R RPD outside accepted recovery limits Page 17 of 36 n1suMMIT Summit Enviromuen[al Technologies, Inc. 3310 Win St QC SUMMARY REPORT WAVIaV'NMUN IRL I LCHNVIRCH.b.S" Ma, Cuyahoga Falls, Ohio 44223 WOS: 17110701 Artaryilcal Laboralories TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: hup.*lApww.seaefccom 28-Not 17 Client: Synagro Project: Bladenboro WWTP BatchID: 29698 Sample ID 17110701-001ams SampType: has TestCode: tclp-svoc-cpe Units: mg/L Prep Date: 11/1612017 RunNo: 77731 Client ID: Bladenboro WWTP Batch ID: 29698 TeslNo: SW8081A SW3510C Analysis Date: 1112212017 SegNo: 1332177 Analyte . Result PQL SPK value SPK Ref Val %REC LowLlmit HighLimit RPD Ref Val %RPD RPDLimit Qual Endrin 0.00419 0.00100 0.0100 0 41.9 20 157 QMR gamma-BHC 0.00502 0.00100 0.0100 0 50.2 22 137 QMR Heptachlor 0.00509 0.00100 0.0100 0 50.9 24 121 QMR Heptachlorepoxide 0.00440 0.00100 0.0100 0 44.0 27 - 152 QMR Methoxychlor 0.00502 0.00100 0.0100 0 50.2 10 199 QMR Sur: TCMX 8.04 20.00 40.2 10 119 Sum: DCB 8.54 20.00 42.7 10 119 Sample ID 17110701-001amsd SampType: msd TestCode: telp-svoc-cpe. Units: mglL Prep Date: 1111612017 RunNo: 77731 Client ID: Bladenboro WWTP Batch ID: 29698 TestNo: SW8081A-SW3510C Analysis Dale: 11122f2017 SegNo: 1332178 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit oust Endrin 0.00953 0.00100 0.0100 gamma-BHC 0.00988 0.00100 0.0100 Heptachlor 0.0105 0.00100 0.0100 Heptachlor epoxide 0.00968 0.00100 0.0100 Methoxychlor 0.0119 0.00100 0.0100 •- Sur: TCMX , 17.4 20.00 Sum: DCB 17.5 20.00 NOTES: The TCLP Pesticide Sample MS and MSD pair exhibited high RPDs for all analytes of Interest. Qualifiers: • Value exceeds Maximum Contaminant Level. H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. P Second column confirmation exceeds 0 95.3 20 157 0.00419 77.9 0 98.8 22 137 0.00502 65.2 0 105 24 121 _ 0.00509 69.3 0 96.8 27 152 0.00440 - 75.1 0 119 10 199 0.00502 81.4 86.9 10 119 0 87.7 10 119 0 B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range M Manual Integration used to determine O RSD is greater than RSDlimit R RPD outside accepted recovery limits 30 R 30 R 3D R 30 R 30 R Original Page 18 of 36 Bunvnil Environmental Technologies,QC 3310t. /0 Win SSt. SUMMARY REPORT trsvlarJN rn uN l Al. t LCHUL) LUU14: S, Mc. Analytical Gabartalories Cuyahoga Fails, Ohio 44223 TEL: (330) 253-8211 FAX. (330) 253-4489 WO#: 17110701 - Webslle: hup.,lAnvivaettekcam 28-Nov-17 Client: Synagro Project: Bladenboro Wl TP BatchED: 29700 Sample ID MB-29700 SampType: MBLK TestCode: SVOC-BNA T Units: mg1L 'Prep Date: 11116/2017 RunNo: 77398 Client to: PBS Batch ID: 29700 TestNo: SW8270C SW3510C Analysis Date'. 1111712017 SegNo: 1324620 Analyte - Result PQL SPK value SPK Ref Val %REC Lowl-imit HlghLimit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene ND 0.0400 2,4,5-Trichlorophenol ND 0.100 2,4,6-Trichloropheno_I - ND 0.100 2,4 Dinitrotoluene.. ND. - 0.0200 o-Cresol ND 0.100 m/p-Cresol(s), ND 0.100 Cresols, Total ND 2.00 Hexachloro-1,3-butadiene ND 0,00800 Hexachlorobenzene ND 0.0200 Hexachloroelhane ND 0.6400 Nitrobenzene ND 0.0400 Pentachlorophenol - ND 0.100 Pyridine 'ND 0.100 Surr: 2-Fluorophen ol 0.825 Surr: Phenol-d6 0.836 Surr: Nitrobenzene-d5 1.22 Surr: 2,4,6-Tribromophenol 0.838 Surr: 2-Fluorobiphenyl 0.930 Surr: p-Terphenyl-d14 _ Qualifiers: • Value exceeds Maximmn Contaminant Level. H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. P ' Second column confirmation exceeds 1.000 82.5 10 109 ,. 1.000 83.6 10 109 1.000 122 19 120 1.000 - 83.8 10 120 1.000 93.0 22 117 1.000 -111 34 - 116 - B Analyte detected in the associated Method Blank E Value above quantitation range J . Analyte detected below quantitation limits M Manual Integration used to determine ND Not Detected - 0 RSDJs greater than RSDlimit PL Permit Limit R RPD outside accepted recovery limits QC+ QC+ QC+ 6 Original Page 19 of 36, rya U M MIT Summit Ersvironmenta[Technolo0 Inc.WinSr QC.SUMMARYREPORT trIVIKULN rAIIN I AL 14UHNULOU11:5, INC, Cuyahoga Falls, Ohio 44223 ` " - WO#: 17110701 1lnalyll:=I tabarslafteo TEL: (330) 2S3-8211 FAX. • (330) 253-4489 Websue: hum-11 viv.settekaam 28-Nov-17 Client: Synagro Project: Bladenboro WWTP BatchED: 29700 Sample ID LCS-29700 SampType: LCS TestCode: SVOC-BNA T Units: mglL Prep Date: 1111612017 - RunNo: 77398 ' Client to: LCSS Balch to: 29700 TeslNo: SW8270C SW3510C Analysis Date: 1111712017 SegNo: 1324621 Analyte Result PQL SPK value SPK Ref Val %REC LowLlmit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.619 0.0400 0.8000 0 77.4 19.1 126 2,4,5-Trichlorophenol 0.768 0.100. 0.8000 0 96.0 11.7. - 151 2,4,6-Trichlorophenol 0.741 0.100 0.8000 0 92.6 12.4 150 2,4-Dinitrotoluene - 0.777 0.6200 - ' 0.8000 0 97.1 20:6 140 o-Cresol 0.661 0.100 0.8000 0 82.6 13.8 137 mlp-Cresol(s) 0.674' 0.100 0.8000 0 84.2 10 134 Cresols, Total . ND 2.00 1,600 ' 0 83A 10 129 Hexachloro-1,3-butadiene 6.626 0.00800 0.8000- 0 78.2 14.7 137 Hexachlorobenzene 0.640 0.0200 0.8000 0 80.0 12 139 Hexachloroethane 0.606 0.0400 0.8000 0 75.8 14.8 132 Nitrobenzene 0.726 ' 0.0400 0.8000 0 ' 90.8 15.6 138 Pentachlorophenol - 0.755 0.100 0.8000 - 0 94.4 10 156 Pyridine 0.121 0.100 0.8000 0 15.1 - 1 130 Burr: 2-Fluorophenol _ 0.651 1.000 65.1 10 147 Surf: Phenol-d6 0.0316 1.000 3.16 10 140 Suir: Nitrobenzene-d5 1.02 1.000 102 10 169 Burr: 2,4,6-Tdbromophenol - 0.718 1.000 71.8 10 185 Surr: 2-Fluorobiphenyl 0.806 1.000 80.6 10 169 Surr: p-Terpherryld14 - 0.968 - 1.000 96.8 10 179 Qualifiers: ° Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank H Holding times for preparation or analysis exceeded 1 'Analytedetected below quantitationlimits - MC Value is below Minimum Compound Limit. ND Not Detected P Second column confirmation exceeds PL Permit Limit. - E Value above quantitation range M Manual Integration used to determine 0 RSD is greater than RSDlimit R RPD outside accepted recovery limits QC+. QC+ QC+ In S Original Page 20 of 36 �� 331010 Win sr. suaanirEavi.aameararTeahaarWinSInc.fn QC SUMMARY REPORT LNInHUNUMN IAL I W"rlUt Gn;S, INC. Cuyahoga Falls, Ohio 44223 Aaalyftral Laboralarles TEL: (330) 253-8211 FAX.- (330) 253-4489 Wolf: 17110701 Webstle: hap://wlny.sellelccom 28 Nov-17 Client: Synagro Project: Bladenboro WWTP BatchlD: 29700 Sample ID 17110701-D01AMS SampType: MS TeslCode: SVOC-BNA T Units: mg/L Prep Date: 11/1612017 RunNo: 77398 Client ID: Bladenboro WWTP Batch ID: 29700 TestNo: SW8270C SW3510C Analysis Date: 11/1712017 SegNo: 1324622 Analyte Result PQL SPK value SPK Ref Val %REC LowLlmit HIghLlmil RPD Ref Val %RPD RPDLImit Coal 1,4-Dichlorobenzene 0.674 0.0800 0.8000 0 84.3 15.2 124 2,4,5-Trichlorophenol 0.838 0.200 0.8000 0 105 30.6 152 QC+ 2,4,6-Trichlorophenot 0.768 0.200 0.8000 0 96.0 27.6 150 QC+ 2,4-Dinitrotoluene 0.856 _ 0.0400 0.8000 0 107 58 _ 141 QC+ o-Cresol 0.708 - 0.200 0.8000 0 88.4 26.9 132 m/p-Cresol(s) 0,729 0.200 0.8000 0 91.2 27.4 134 Cresols, Total NO 4.00 1.600 0 89.8 27.6 132 ' Hexachloro-1,3-butadiene 0.658 - 0.0160 0,8000 0 _ 82.2 -5.3 156 Hexachlorobenzene 0.6B1 0.0400 0.8000 0 85.2 54.3 142 Hexachloroethane 0,680 0.0800 0.8000 0 85.1 1.92 131 Nitrobenzene - 0.762 - 0.0800 0.8000 0 95.2 21 135 In Pentachlorophenol 0.934 0.200 0.8000 0 117 47.4 134 Pyridine NO 0.200 0.8000 0 15.2 -10.3 64.2 Surr: 2-Fluorophenol 0.696 1.000 69.6 9.77 146 Surr: Phenol-d6 0.0356 1.000 3.56 20.7 130 S Surr: Nitrobenzene-d5 1.15 1.000 115 13.9 156 _ Surr: 2,4,6-Tdbromophenol 0.849 1.000 84.9 27.3 183 Surr: 2-Fluorobiphenyl 0.887 1.000 88.7 21.4 153 Surr: p-Terphenyl-d14 1.07 1.000 107 54.8 154 NOTES: The BNA TCLP Sample MS exhibited low recovery for Phenol-d6; All analytes of interest exhibited recoveries within acceptance limits. Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected O RSD is greater than RSDlimit Original P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Page 21 of 36 u lirrn s SunvnifErsvhanmersralTeahr3310Wirs SY.en& 3310 QC SUMMARY REPORT tr4vIHU1NN1kN IAL I hCHNUWCnES, tNc. Anarytfcal tabornforles Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX: (330) 253-4489 WO#: 17110701 ' Website: hap:/Avtnv sehekcom 28-Nov-17 Client: Synagro Project: Bladenboro VFWI? BatehID: 29708 Sample ID mb-29708 SampType: mblk TestCode: telp-svoc-her Units: mg/L Prep Date: 11/1612017 RunNo: 77587 Client ID: PBS Batch ID: 29708 TestNo: SW8151A SW8151A Analysts Date: 11/2112017 SegNo: 1328684 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HlghLimil RPD Ref Val %RPD RPDUmlt Qual 2,4-U ND 1.00 0 0 d 2,4,5-TP ND 0.500 0 0 d Surr: DCAA 423 500.0 84.6 20 140 Sample ID Ics-29708 SampType: Ics TestCode: tclp-svoc-her Units: mg/L Prep Date: 1111612017 RunNo: 77587 Client ID: LCSS Batch ID: 29708 TestNo: SW8151A SW8151A Analysis Date: 11121/2017 SegNo: 1328695 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 2,4-D ND 1.00 2,4,5-TP ND 0.500 Surr. CCAA 511 Qualifiers: • Value exceeds Maximum Contaminant Level. . H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. P Second column confirmation exceeds 0.500 0 97.1 62.6 0.500 0 84.9 52.5 500.0 102 20 B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit 125 128 140 E Value above quantitation range M Manual Integration used to determine O RSD is greater than RSDlimit R RPD outside accepted recovery limits Original Page 22 of 36 frSMMU Summit Environmental. Technologies, Inc. 'QC SUMMARY REPORT IT 3310 Win St. eraviKUWr1 ery iAu hCMgULOCn:s, tne. Cuyahoga Falls, Ohio 44223 Analyllcal taboretories TEL: (330) 253-8211 FIX.- (330) 253-4489 WO#: 17110701 - Website: htt�://www.seuelccmn 28-Nov-17 Client: Synagro Project: Bladenboro WWTP BatchID: 29708 Sample ID 17110656.006ams "SampType: ms - TestCode: tclp-svoc-her Units: mglL Prep Date: 1111612017 RunNo: 77567 Client ID: BatchQC Batch ID: 29708 TestNo: SW8151A SW8151A Analysis Dale: 11/2112017 SegNo: 1328685 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HlghLimit RPD Ref Val %RPD RPDLimit Qual t,v-u NU 11.3 0.500 0 103 37 105 - 2,4,5-TP ND 11.3 0.500 0 90.5 36 106 - Surr:2,4-Dlchlorophenylacelcacid 544 500.0 109 20 .- 140 Sample ID 17110656-006amsd SampType: msd TestCode: telp-svoc-her Units: mg/L ' Prep Date: 11116/2017 RunNo: 77587 Client ID: BatchQC Batch ID: 29708 TestNo: SW8151A SW8151A Analysis Date: 11121/2017 SegNo: 1328686 Analyte - Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLlmit RPD Ref Val %RPD RPDLimit Qual 2,4-D. ND 11.3 - 0.500 0 87.8 37 105 0 0 30 2,4,5,TP ND 11.3 0.500 0 77.9 38 106 0 0. 30 'Surr: 2,4-Dichlorophenylacetic acid 472 600.0 94.3 20 140 0 30 Qualifiers: • Value exceeds Maximum Contaminant Level. B . Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded •J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected Q RSD is Original p greater than RSDlimil P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits - Page 23 of 36 AgEm Ill' 1 ly Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT trevlHUNrOMAL rtiMNOLGCnt3, a'1C, rinalylical Laboralorieo Cuyahoga Falls, Ohio 44223fn TEL: (330) 253-8211 FAX (330) 253-4489 WO#: 17110701 Webshe: hay.,1Aovw.seaek.com/Avtvw.seuek.com 28-Nov-17 Client: Synagro Project: Bladenboro WWTP BatchID: R77252 'ample ID LCS-R77252 SampType: LCS TestCode: pH O11(9045 Units: s.u.@20.3C Prep Date: RunNo: 77252 :lient to: LCSW Batch ID: R77252 TestNo: SW9045D Analysis Date: 11/1412017 SegNo: 1322134 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imil HighLimit RPD Ref Val %RPD RPDLImit Qua[ pH 7.0 7.0 0 100 90 110 Sample ID 17110691-001ADUP SampType: DUP TestCode: pH 011(9045 Units: s.u.@20.4C Prep Date: RunNo: 77252 :;lient ID: BatchQC Batch ID: R77252 TestNo: SW9045D Analysis Date: 11/14/2017 SegNo: 1322136 4nalyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual pH 5.9 Qualifiers: " Value exceeds Maximum Contaminant Level. H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit, P Second column confirmation exceeds 0 0 B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit 5.9 0 10 E Value above quantitation range M Manual Integration used to determine O RSD is greater than RSDlimit R RPD outside accepted recovery limits Original Page 24 of 36 p" f�. I'G�''?7� 33/0 Win St. Summit Environmental Technologies, St.FE QC SUMMARY RL' PORT crcv IHU w rm u n l AL r LCHNO LU 011:5, m¢6. Cuyahoga Falls, Ohio 44223 WO#: 17110701 Analytical Laboratories TEL: (330) 253-8211 FAX:: (330) 253-4489 Website: huy.,1AvrnP.se1tekcom 28-Nov-17 Client: Synagro Project: Bladenboro WWTP BatchED: R77351 Sample ID 17110701-001ADUP SampType: DUP TestCode: Ignitahility_S Units: Prep Date: RunNo: 77351 ,lient ID: Bladenboro WWTP Batch to: R77351 TestNo: SW1b30 Analysis Dale: 11/1612017 SegNo: 1323859 4nalyte Result PQL SPK value SPK Ref Val %REC LowLimit HlghLimit RPD Ref Val %RPD RPDLimit Qual Ignitability non-flammable 0 0 20 Sample ID 17110701-001ATRIP SampType: DUP TestCode: Ignitability_S Units: Prep Date: RunNo: 77351 ,lient ID: Bladenboro WWTP Batch ID: R77351 TestNo: SW1030 Analysis Dale: 11/1612017 SegNo: 1323860 4nalyte - Result PQL SPK value SPK Ref Val %REC LowUrnit HighLlmit RPD Ref Val %RPD RPDLimit Qual Ignitability non-flammable 0 0 20 Sample ID 17110779-001ADUP SampType: DUP TestCode: Ignitability_S Units: Prep Date: RunNo: 77351 :lient ID: BatchQC Batch ID: R77351 TestNo: SW1030 Analysis Date: 11/16/2017 SegNo: 1323862 " 4nalyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimlt RPD Ref Val %RPD RPDLimit Qual gn0aon0y non-mammaole o 0 20 Sample ID 17110779-001ATRIP SampType: DUP TestCode: Ignitability_S Units: Prep Date: RunNo: 77351 Client ID: BatchQC Batch ID: R77351 TestNo: SW1030 Analysis Date: 11/16/2017 SegNo: 1323863 Analyle Result PQL SPK value SPK Ref Val %REC LowLimit HighUmit RPD Ref Val %RPD RPDLimit oust Ignitability non-flammable 0 0 20 Qualifiers: ° Value exceeds Maximum Contaminant Level. H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. P Second column confirmation exceeds B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range M Manual Integration used to determine O RSD is greater than RSDlimit R RPD outside accepted recovery limits Original Page 25 of 36 SUMMIT SnmmitEnvirmmnenalTechnologies, WinSIna 331010 Win St. QC SUMMARY REPORT trAVINUNrneN IAL I WHNULQUTSs, INC. Analytical Laborasarfa5 Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX.. (330) 253-4489 WO#: 17110701 Website: hay.,1 ww.seaekcom '28 Nov-17 Client: Synagro " Project: Bladenboro WWTP BatchID: R77351 Sample ID 17110779-001ATRIP 'SampType: DUP TestCodes Ignitability_S Units: Prep Date: RunNo: 77351 Client ID: Batch= Batch ID: R77351 TestNo: SW103D Analysis Date: 1111612017 SegNo: 1323863 Analyte Result, PQL "SPK value SPK Ref Val %REC LowLlmit HlghUrnit RPD Ref Val %RPD RPDLimit Qtial Qualifiers: • Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank H Holding times for preparation or analysis exceeded "J Analyte detected below quantimtion limits MC Value is below Minimum Compound Limit. ND Not Detected ' P Second column confirmation exceeds PL Permit Limit E Value above quantitation range M Manual Integration used to determine - 0 RSD is greater than RSDlimit R RPD outside accepted recovery limits Original - Page 26 of 36 s u m"I N T Summit Environmental Technologies, St. 3310 l0 Win St. QC SUMMARY REPORT tsVIRVNrmeNUtl. rtcHNV LS7G1tt5, JNC, AnalyUcaf Lobarnforlos Cuyahoga Falls, Ohio 44223 TEL: (330) 253.8211 FAX: (330) 253-4489 WO#: 17110701 Website: hity.-Mvinvsetrelccom 28-Nou17 Client: Synagro Project: Bladenboro WWTP BatchED: R77544 Sample ID MB.R77544 SampType: MBLK TestCode: Sulfide,React Units: mg/Kg Prep Date: RunNo: 77544 Client ID: PBS Batch ID: R77544 TestNo: SW9034 Analysts Date: 1112112017 SegNo: 1327622 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual iulfitle, Reactive ND 25.0 Sample ID LCS-R77544 SampType: LCS TestCode: Sulfide,React Units: mg/Kg Prep Date: RunNo: 77544 Client ID: LCSS Batch ID: R77544 TestNo: SW9034 Analysis Date: 1112112017 SegNo: 1327623 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual iulfitle, Reactive 4560 25.0 4800 0 95.0 85 130115 Sample ID 17110481-001AMS SampType: MS TestCode: Sulfide,React Units: mglKg Prep Date: RunNo: 77544 Client ID: BatchQC Batch ID: R77544 TestNo: SW9034 Analysis Date: 11/2112017 SegNo: 1327625 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual iulfide, Reactive 4470 25.0 4800 0 93.1 SD 120 Sample ID 17110481-001AMSD SampType: MSD TestCode: Sulfide,React Units: mg/Kg Prep Date: RunNo: 77544 Client ID: BatchQC Batch ID: R77544 TestNo: SW9034 Analysis Date: 11/2112017 SegNo: 1327626 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive 4510 25.0 4800 0 . 94.0 80 120 4470 0.891 30 Qualifiers: • Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded I Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected O RSD is greater than RSDlimit Original P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Page 27 of 36 r� tRI sa,,,a;lEnvironmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT cravIaUTunCNia4 t t:CMULUOLS,aG Cuyahoga Falls, Ohio 44223 WO#: 17110701 Analytdcal Laboralcries TEL: (330) 253-8211 FAX.- (330) 253-4489 Websile: hUR.-Mvinv.sellekcon, 28-NoY 17 Client: Synagro Project: Bladenboro WWTP BatchID: R77544 Sample ID 17110481-001AMSD SampType: MSD TestCode: Sulfide,React Units: mg/Kg Prep Date: RunNo: 77544 Client ID: BatchQC Batch ID: R77544 TestNo: SW9034 Analysis Dale: 11/2112017 SegNo: 1327626 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLlmit RPD Ref Val %RPD RPDUrrdt Qual Qualifiers: • Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation mnge H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected 0 RSD is Original p greater than RSDlimit P Second column confirmation exceeds - PL Pormit Limit R RPD outside accepted recovery limits Page 28 of 36 Ef LT, Surmnit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY ^LoRl crcvlHVNrakNlAL t LCHNat.0a6.5, P;C Cuyahoga Falls, Ohio 44223 Anatyfl:cal taboralwlec TEL: (330) 2S3-8211 FAX.- (330) 253-4489 WO#: 17110701 Website: hun.,114,mv.seaekeom 28-Nov-17 Client: Synagro Project: Bladenboro WWTP BatchID: R77599 Sample ID MB-R77599 SampType: MBLK TestCode: Cyanide,Rea Units: mg]Kg Prep Dale: RunNo: 77599 Client ID: PBS Batch to: R77599 TestNo: SW9014 Analysis Date: 11/21/2017 SegNo: 1328886 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual ;yanide, Reactive ND 0.500 Sample ID LCS-R77599 SampType: LCS TestCode: Cyanide,Rea Units: mglKg Prep Date: RunNo: 77599 Client ID: LCSS Batch ID: R77599 TestNo: SW9014 Analysis Date: 11/21/2017 SegNo: 1328887 Analyte Result. POL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual ;yanide, Reactive 1.03 0.500 1.000 0 103 85 110 Sample ID 17110481.001AMS SampType: MS TestCode: Cyanide,Rea Units: mglKg Prep Date: RunNo: 77599 Client to: BatchQC Batch ID: R77599 TestNo: SW9014 Analysis Dale: 11/21/2017 SegNo: 1328889 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual :yamde, Reactive 0.973 0.500 1.000 0 97.3 81.6 122 Sample ID 17110481-001AMSD SampType: INSD TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 77599 Client ID: BatchQC Batch ID: R77599 TestNo: SW9014 Analysis Date: 1112112017 SegNo: 1328890 Analyte Result PQL SPK value SPK Ref Val %REC LowUndt HighLimit RPD Ref Val %RPD RPDLimit Qual yanide, Reactive 0.973 0.500 1.000 0 97.3 81.6 122. 0.9730 0 5 Qualifiers: ° Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected O RSD is greater than RSDlimit Original P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Page 29 of 36 \ � r [,1� surdrd 33/0WWInin St. Svmmtt Envirottmen[al Technologies, Inc.rn QC SUMMARY REPORT trMHUMA rN W. t br:HW000IL5, RIG Analyn=l Labaraforleo TEL:.(330) Cuyahoga Falls, Ohio 44223 253-8211 FAX. (330) 253-4489 V✓0#: 17110701 Website: ht1P.-1A rvtv.se[lekcom 28-Nov-17 Client: Synagro Project: Bladenboro WWTP BatchID: R77599 Sample ID 17110481-001AMSD SampType: MSD TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 77599 Client ID: BatchQC Batch ID: R77599 TeslNo: SW9014 Analysis Dale: 11/21/2017 SegNo: 1328890 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HlghUmit RPD Ref Val %RPD RPDLimit oust Qualifiers: • Value exceeds Maximum Contaminant Level, B Analyte detected in the associated Method Blank H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits MC Value is below Minimum Compound Limit. ND Not Detected P Second column confirmation exceeds PL Permit Limit E Value above quantitationrange M Manual Integration used to determine Q RSD is greater than RSDlimit R RPD outside accepted recovery limits Original Page 30 of 36 Page 31 of 36 CID M N 0 O N M N a) SOP: Sample Receipt rn to Revision:13 m C. fL Effective Date: 07/17/17 Figure 1— Summit Environmental Technologies, Inc. Cooler Receipt Form, Page 7 Initials of person lnspeciing cooler earl samples:' Client: r/ �'�` D Order Number, I —2 �( 0] a I Date Recemad: -1 - / cr-/T a ReceYi,ed: (000 Date cooler(B) opened and samples Inspected: I Lt Number of Cool-mMoxes: M NIA Shlpper, di PS DHL Atoms US Postal Walk-in Pickup Other. Packaging: Peanuts B ISMS Paper Foam None Other. TapeonwaW_rlbor. /'� N WA Custody Seals intact Y N QA C•0.0 in glesfe 0 N . WA ice_Blue lw resenl bsenl matted WA Cooler Temperalum IR Gun #16020 Sag CFI°C Temp: S,S-O WA Ratrological Tesfsglnstnmentsedatpd5127• Y N Nr _ (seepage2forscanresurs) Use shear par sample. If sample IS> 100 cpm, the Radiological SafetyOffleer must be notified Immediately. PO-C filled out property L:P N WA Samples in separate bags Y N - WA Sample containers intact* D N WA 'If na, list broken samplo(a Sample laber(s) complete (to; date, eta) Y N NIA Label(s) agree with CO•C Y N WA Correct containers used YO N WA Suisnnt sample received 0 WA /N� Sufficient sample for OC Y NIA Samples received wit" holding time (Y N WA RDonny 40rnL vials=maln bubbles•' •°Samples Y N WA with bubbles SSmm are acceptable. Indicate bubble size Was client contacted about samples Y N Will client sand new Samples Y N Logged Page 10 of 12 North Carolina WastewaterlGroundwater Laboratory Certification Certified Paramete76 Listing L-aO Nama. SLwar Eq'HroArrlenlor-roehn=g es lnn Cedlf[mle Numirci. 531 Address: 3310 Win Slrect --EReplim Dale. 111 Pi.01T' Cuyahoga Fall., OH 44223- Expiration 7atu. 92.3f12097 Dote Cf Last Amerdment: Ell, W120 r [no eoyr.m•-a=b6mate'7. havingduly met:Fu roqui-ampn:a$15ANGAG 21-.7206,Is burrcyeo•tlfcd rc11k. Ile parsrneMsils.ad DDIVA CERTIFIED PARAMETERS 11ORGANIC FHp6PWAYE ORTHC Boo S W-846 0056 A (Aqucoue) SM 521 1) B•2001 iAgjetus) SW646905G A (Non-Aqueousl CHI ORI()E _ PHOSPHORL:S, TOTAL SW345 9056 P. (AJuaoutl EPA nC 7 Rev 44(1994) (Acueous) SW -MU 9056 A (Non -Aqueous) 5 W-846 (i070 D (Aquecus) GO0 - 9W-mu SDtO D(Non.Aqueous; Ski 5220 C- 397 ±Aq jeous) F.EEIOJ=_ DISSOLVED 180 O rLLORfr)E 3M 2540 0.199' (Acueoas) CPA 300 0• Rev : 1• 1993 (Aqueous) RESIOJ=. SUSPENDED SVV-846 gG.96 A :Aluenus} SM KAD D-199' (.AcueoJS) SW-84390AF A ;Nnn-AgUeauS) SILICA IGNITA.6ILIT'i - EPA2C0-7•ReV 4.4. IS841AqueaLA7 SW-846 10m (Nor Aqueous) S W-946 6010 D (Agaaaus I INORGANIC PHENOLS S W-S46 6010 D (Non,Aqueous; EPA L20 1• Rev ' 078 IAQjtcLS) SULFATE NITROGEN. NITRATE EPA NO.D. Rev. 2.1. 1G03 (Aqueous) EPA 300 0. Ruv. 2 1 • ; S931A i2mus) SW-840 S050 A (Aqueous) SVJ-845 9056 A ;Aqueuu5; 9W.R46 A0 61 A (Non-Aqueaus) SW-045 0056 A:Non,Aquerus) 9ULPIOF NITROGEN. NITRITE 5W-046 0034 (Aqueous) I:FA 300 0. Rev. 2 1 :993 (Agjeolls) S W-846 0084 (Non-Ageeouy; 9W-045 905E A ;Aqueous; RIETAL SVV-843 905E A ;Na1-A.queoue) TCLP METALS N17RQmEN. NOS ^ NO2 ' 31*440 1311 (Aqueaus) F.PA3000 R,v.21 19931Agacvuu; AL IWINL'M SW-946 9C5E A ;ASueoms: FPA. 900 7, Rev. 4.4 1994 (P.yuruus) SVd4e6 DL'Sti A ;NL••1-Aquaaus) SW.049 6013 D rkwou5) NI'; HOO(:.L. I0-AL KJELDAHL S'N-849 b013 D (Nan-AgLeuuM SM 4500 No,g 9-' 907 (GM 4500 NH3 D-I D07) (Aqueous) EPA 200.8, Rev. 9.4 1994 (Aqueous) OIL 8 GREASE SIN 046 6021) R (AquewE) CPA 11104 Rev B-;Acuepu$) S'N•84660205(Nan-Ayoeousj 9w-848 9071 F. {Nno-Aquenus) ANTIMONY PH EPA 200.7• Rev. 4.4 1994 (Aqueous) SW-846 904E E•;Non-Aqueous) S'N-04E 601;1 D (Aqunrn.$) Tres u.»Sc;?r rrc. 25raiamne; Manaweptaoa valiyasa.ra-pe p-aq:em Sae OFappM0. rr-ll de'a=y per enesanlbr:matt-al;nn Fr•idmrAarc e_.q:Port1- in lEA nCAC2h.0BU. (v (� (D W A O co 0) North Carolina Wastewater/Groundwater Laboratory Certification CerNfied Parameters Listing Lab• Narrz. Surmi: Fmironi -mtal TeChraloDees Inc. Address: 231a Wm Str=el Cuyahoga -ally. CH 4422i- lne 2:a'e named IM 2t0ry h.uine 4U} mul the rMuirpr is of 1bA N::AC:2H)dW.0'10TP7yaadBled to•Ce mBsaah-raaM ellhe pa3no%ri lw.w babw. CERTIFIED PARAMETERS SW-84E 6010 D (Von-Aq,+ecue) EPA 2W.8, Rev, 54, 1994 (Aqueousl SW-946 6020 B (Aqueoua; SLV-94C 6020 B (Ncr•AuuaoL�) ARSEN C FPA Inn 7, Rev. 4A. 1094 (Aquauas) 5L4.646 5210 Or(AgLeau4) SLY-150 8010 D (Ncn-AquaOLs) LPA 200 8, 9ev. 5.4, 1994 (Aqueous) SW-846 6020 B (Aqueousl SW-540 G720 6 (Hon-AgveoUs) BARIUM EPA 2007. Rev 4.4. 1994 Aquenl,$) SW-80 6010 D (Aqueousl SW-846 6010 D (Nor -Aqueous} EPA 200.3. Rev. 5.4, 1994'AgUQou.1) SVJ-846 W2C E ;Aqueous! SW-846602C S'Non-Aqueous) BERYLLILM EPA 200.$.Rev. 5A. 1934 ;Aquecus) .i W-845 602C E {Aqueous; SW-S46602C S;Nq Aquecus) BURUN EPA 200.61 Rev'. 5 4 1994 {AgjeC6.9) S1N-845 6020 E ;Aqueous; SLV-845 6020 0:Non•A.queousS CADMIUTA EOAi00 Y. Rev 44.1994iAq.,QC.S) SVJ.848 % C. :AgUfauSi SW-S4S BU70 C jNcnAquequs) EbA 20u e, Rev 5.4. 1994 (Aq.acsl SW 84& 6020 9 fAqucaus; SYd•046 U020 a (Nnn-Aqueo05) CALCIU%I EPA 200.7. Rev. 4.4. '9241Aqu=n.$) SW-346 6010 D {Aqueous} S•M-3+66010 D INcrinNucous) CI IROMIUh4 TOTAL EPA200.7, P,ev. 4.4, 1994 (Aquuuus) S W-346 6010 D iAq.reau s) S W-B4fi 6010 0 (Non-Aqueousl EPA.200.8, Rev. 5.4, 1994 (Aqueous) SW B46 602D 8 (Aqu: We) $W-846 60200 (Non-A4Leous) COBALT EPA 20.7. Rev 4.4. IS94 (Aqueous) Svy-346 601C r3 (Agjwua) SW-840 en1C n (NnnagLeousl EPA 2LO.e. Rev 5 4.1994 (Aqueous) SIV!•iti 802D B (Aquooue) SW-846 602C 13 (Hai-Aaueouei COPPER EPA.2 OJ- ROv. 4.4 1994 ;Aqueous) SW446 GO'" D (Aqueous) SW-846 60-2 D (Nnn-ACLEOUS) EPAXO.5. R=_v. 5.4. 199A (Aqueous) 6W-646 6WU B 1A6UeCU8) SW-846 6020 B (Non Aqucousi IRON EPA 2Ce.7. f iev. 4.4. 1994 ;Aq ue Sus) SW-246 60' 7 D fgquaous) SW-246 = 3 D fNo:l-AuLeaus) LEAD EPA 2C0.7. Rev. 4-d. 1954 (Aqueous) SW d46 6C10 D fAgneousl SW 846 6013 0 (Non Aal..ous) EPA2C0& Rev 53 1594 {Agveousl SW-646 6023 B ;Aqueous) SWd46 6023 B ;No,+ Aqueous; MAGNFSII•;IJ Carif+cale Nu7,be• 631 Effective Dole 1f1)2017 EBoiraticr. Date: 12f3fy2017 Date o1 Last Armndmen:' WI W2017 Iris Cer4tealal•C.cuirc�rrtair{j�oa'.•a' a::BF-tdb� 4ualtyai;ct ante pmGram,use of aup!oved Md:"o4obgy ei-j 1s-adoy pe&r-iwoow9%awlloq eame eE Ltmtoree are Subjec. xr:lua pwal( vx d!nr dvm:tiG::allon fo• mlrlGLCm as Se19' :. 15f, NCA� 2H.CEo:, North Caroliiia Wasti water/Groundwater Laboratory Certification Certified Parameters Listing Lab News Summit Environmen:et Tecnnologle5111C. Acdre99: 3310 Win SUM..t Cuy211a97. Falls, 0?1 44?23. P:e ate+r nsroR1 NScre:oq, naWt9 tluy n el I::e m,;aur,:n,::. d l-A N('Af aFpsOq, �s heres/<'enifie:'nr Na measuremant aft Parenns;'3 fis>=d 1e4+r. EPA?00 7, Rev. 4.4, 1994 iAqueous; -RW-UP 5011) D (Aqueousl SUC-a40 •301D D (Ncr-Aqueous) MANUANEEE EPA.200.7 Rey 4,4,'994fAgteous) SW'-D40 6010 0 (Aqueous) Sw-840 6010 D Mar•Aqueou+) EPA 20f. A Rev 5.4. ' 934 CAqueous) SW-346 6:21T 0 (Aqueous; SW-9461iU;N 9:Nor,Aqusous) NERCl1RY EDA?45 1. Rcv. 3.C, 1094 CAqueous) SW-346 7470 A :Aqueous; SW345 747: B :Ncrl-A.queousl EPA t 531 E (Aqueous) M(71 V51DENU4 FPA 2D07, Rev. 4.4. 1994 CAgoeous) SW445601C C:Agt'cqus; SYJ-a15 GWC C :Non Aqueous) EPA 2:0.8 Ro 5.4. -W4 CAgjaoI;S) SW-W 602C B {lwueous) S'PJ-E4.3 6C2C B (Non -Aqueous) NICaF1 5'uV.84%i 6C+C D :No"A.queous) EPA 20U.6. Rev 5.4, 1994 (Ag1EeUR)' SU'1.845 5C25 9 (Agjeouo ) SW546 SU22 3 M3n-ACUeo:s) PO i AESIUM C'A 20D 7. Rep 4.4, 1304 (Aqutc.$) S'rl-840 W1.1 I iAnl.F Vs) S'N-845 El M 'I (Nlr-Jlqueq.I8) SELENIUM SYJ•S46 bQl J -1 iNun-Aqunojs) LPA 200 0, Rov. 5.4, '.9D4 (Aqueous) G'N-846 6020 3 SAquccus) CERTIFIED PARAMETERS S47-646 6U'LU B (Non -Aqueous) SILVER EPA 20.7, Rcv. 4.4 1004 (Acucous) SW-640 601110 (Aqusaus) 5W-6400010 D Wqn-AqueaV5' EPA 2C0.8. R=_v. 5.4 1994 (Acueous} SW84660 AR(AquP.nus1 SW.846 G020 B(Non•Aqueous) SOUIUM EPA 2C0.7. Rev. 4.4 19a4 (Aoueo.lol. 6W6466010 D (Aqueo.ls] 6WLE46 6012 D (Non-Aqutaos; STRONTIUM EPA 2C0?, Rdv. 4.4 1S94 (Agoau.-sl SW-2466U 17 D (AgU8Ou4) SW-E46 601 J D (Non-AaLeous; EPA 200.6. Roo. 6.4 1994 (Aqueous) SW-E46 602D B tAquaoua) $W,,466023 E (Non-Aquecus) THALLIUM FPA 200 7, Rex 44 1494 (Aguen.as) SW-846 60101)(ACne,)Us] SW-e46 601 J D (Non -Aqueous; EPA -ICU U. ttw b.4 1544 CAgueo.ls) SW-E46602J 9 (Aqucnus) GW246 602) B (Non-Aquccus) TIN EPA 200 7, Rea 4.4 1994 (Aqueous) S W246 601:1 D (Aquama) SAr246 6010 D (Non•Aqueous) VANADIUM EPA 200 5, Rev 5.4 1994 (Aaueaasl SW-546 602) B (Agl••eous) SVJ-50 602D B (Non•A•wecus) ZI•VO Certif we NUm:er: 031 Fff,' .rlve NIP, 111120/7 Explratior :lwF, 19:310.117 Date of Last Amendment- 9A91401t T'ia tl1r19[at!pl gd?SI"dI111nMf.ffa'arr.Pn!.:nle4}it1=s3V4rKe naaraM, gsE et xa::a'2tl mENOEao9i,alJ sah518[Eory pe'Orrtalcea^Eva4•a:cn sar[155.Lam•a:ar ssarE so".;e¢Ic q7n Fera�:R£antlrn•aa;E^iL'xlim fnr PlrtrimS eL+se: W.111 • °A NOW. N111N..7 North Carolina Wastewater/Groundwater Laboratory Certification Codified Parameters Listing Lab Narra: Summi; Envhonmeval Tedlnalogiea Ix. Address 3310win Street Cnyahop Falls, Ott 44223- T•e aoeve n�rmJ r�L.anLrrta�i la ilnly rol:•t^n lr..7iin�nnraa.n :SF Nf,.AC .N Iwm SlrerFCY Lenlflay'rp: IfP mAF.:'YI-"�'�: nrll'F nAIArrINiY.rV Iti:I.fI IY:INI SW-846 6310 0 (Non -Aqueous) EPA 200.6, Rev. 5.4 1294 (Ag4e0VS) SYJ-M 5 902CI B (Aqueous) EV1-8466020 B(Non-Apueouai ORGANIC TCLP ORGANICS SW-8461311 iAq.leu. ) ,AWORBABLE ORGANIC HALIDES EPA 1650, Rev. C, 1997 (Aqueous) BAe6 NEVI HA-m mo. ORGANICS EPA 826 (Aaucous) .SW9466270 D (Aqueous) 3W-04Gb270 D (Non-AqueoVS) 01ILQRI VATED ACID HFRP.ICIDFR SW-84G 8151 A (Asuan.Is7. SW-640 8151 A (Nan AgjeoLS) CHLORINATED PHENOLICS EPA 1BE$ Rev. A 1 U67 (Apcovoj EXTRACTABLE PETROLEUM HYDROCARBONS MADEP. rdsq 20L'4, Rev. 1.1 :Aqueous) NONHA,LOGCNAI'CD VOLATILE. OR:ANIC.S SkV•846 EWE C (AgLuo4s) PESTICIDES, 0RGA.NOCHLORINE EFA 608 �,AgLEOLS) S1'Y•CJ68081 B(Acueoosf SVV-VG 8G81 6 (Non AaUCoua1 PO.-YCHLORINATED 6,Pi-ENYLS (P03s! . EPA 008 (Aqueous) a^W-846 8082 A (Ruucuusl ' SW-P46 8087 A (Non-Aelleo,S) PIIR(i=AXLE QRGANICS EPA ti24.AqueOus) SW 84G6260 B'AuLcousl SLV 8488260 B (Aon,AqueDus) TOTAL ORGANIC rIAL10ES _ — CERTIFIED PARAMETERS SV!-84d 9U2L• B!Ag3ecusl IPh U hStL RANGE, ORGANICS SX-846 8818 C'Aqueous; S W-648 8012 O ;Nor•A.quewsl 7PFi GASOLIAERANGE, GR3ANICS Sif!-&58 8010 C :Aqueuux;• SV!-H40 801 E C ;Nur-Ayueoux) VOLATILE FETROLEUM HYDROCARBONS t.4ADEP May 2004, Rev. 1.1 (Agjamsj Certificate NLmbcr: 631 Effective Dam- 111/2017 Fxpim ion Ode 12C1r2017 Date of Las! Amendment 9t 912017 m1s renlrL^9l:er'equrux-mwwj.ror.'Hear;eplkle gl.alp•xssl'ra"orppp. ise ete_prW.dmellxxdoap era sel 5ari•)pertnmarc+A^.nual:mil•:n R'-...--y Ixhnclu:n•Saio CullrCl uoevl pP.rRdieS 6rffiftlPC.P.n'le3ao'ro!l:'•'dG11an5 59 9P.1-wh in l5A v:4 JH nm, ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Town of Bladenboro WQ Permit Number: W00014452 r WWTPName: BladenboroWWTP NPDESNumber: NC0026352 Monitoring Period: From OU01/2017 To 12/31/2017 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106)- Please indicate level achieved and alternative performed: Class A: Alt. I/A (time/temp) Alt. 4/D (No Prior Test) Alt. 2B (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 5/Process to Further Reduce Pathogens _ ,Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only). indicate "Process to Further Reduce Pathogens": Compost _ Heat Drying _ Heat Treatment _ Thermophilic Beta Ray _ Gamma Ray — Pasteurization — Class B: Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting _ Aerobic Digestion Anaerobic Digestion at appitcame to arernanve periormea ku ass A or umss ticom iere me InHowing monnorm t ama: Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units dences Analysis Fecal 2xl0 to the 6 MPN MPN/g Coliform power per gram of total solids 67600 110000 145000 CFU/g 0 Once a grab 9222D - CFU year MF 1000 MPN per gram of MPN/g total solids (dryweight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) ' lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: Option/Alt. 1 Option/Alt. 2 Option/Alt. 3 Option/Alt. 4 (VS reduction) (40-day bench) (30-day bench) (Spec. 02 uptake) Option/Alt. 5 Option/Mt. 6 Option/Alt 7 Option/Alt. 8 (14-Day Aerobic) (A1kStabthzation) (Drying —Stable) (Drying —Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) _ (Incorporation) X No vector attraction reductionalternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met I am aware that there are significant. penalties for false certification including fine and imprisonment." A/ L, 3n ktz=r� D �C Todd LWaftftAftAirckor t' Pr Lland�i[le (type or print _ Lan ie Q applicably pr' 6WYa?6re ofPreparer* Date Signature of Land Applier (if applicable) Date *Prepares is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) Cameron Testing Services, Inc. Laboratory Report NO OENR#554 NCPHHS#37799 Glrenf' Synagro C3S Prod 171930 US EPA #NC01918 ro�ect t Bladenboro �L2ebb Ot�orry ' Yes ! - 0M_ * Sample Information _ Sam�led'S1 C. Hayes x� bate,; "11/13/173iecelvgd j G. Cameron 1 date' 11/13/17 Analyses and Results 171930 01 a Sludge Gr •- Fec:Colifcrrn-S • <125000 cWts 125000 11/14/17 ERP 9222D-MF r b <67600 OFUfg 676.00 ' C <125000 CFUfg 125000 d <92600 MID 92600 e <145000 CFU/g, 145000 ' f <122000 CFUfg 122000 9 <116000 cFU19 116000 Geomean <110000 LL� rf 1 171930 01 a sludge or TS (e/u) 2.84% 0.01 11/14/17 ERP 2540 G -TS b 5.29% o.0f C 2.30% 0.01 d 3.66% 0.01 e 2.87% 0.01 f 2.830W 0.01 g 2.86% 0.01 .. - Report ReviewY12Q� Project Manager .210. S. Steele Ste. 914-2084240 Sanford NC 27330 chds& merentesting,com 219S.Steele str. Cameron Testing Services, Inc. Chain of Custody Sanford, NC 27330 Phone: 919-208.4240 NC WW(GW Cent. 9654 NC PHHS cent #37799 US EPA NC01918 Page of t C m an _p tvIF • �, f 5 gadstclty; rSta�e' Z(p)-T5 $ R2 rq Y 9 Email I Phone• <� 1t Notes Cha es s na ro.com _ Y °Q Y 9 919-799-0766�- �a -. FCTSaIab tlSe,OnL vht�u'r " SamP.le emPr p C .r: 1 t i tr+5`3'r a f)'=il S T �'�iiF' tr`k'.$•3y'ki;�z:'",+,�ixs Pro) :i' q 7 l U rover ore " tf , . o;4ViN C�-0 ce�]»e..n-ere.r 0. ed 284 Boger Rd. Mocksville, NC 27028 Bladenboro �rColleeted��Name: CIAJ 14 � Signature: {h�,Jn'Itl]9 r�ti I-Z.+. _.t:7`>'.+i,,Idx '; I,.�..r; v wSam a Info at(on ,,_rz.:z:l:] Pvr ..r ..vl_ s 4 'Numberroflbottles v I n ' R uestetl;Anaiysts` _ ? a44ij, r,l Sample ID _ o. x Z E N .`J � o m m IU ci , o R y ,! ° (7 o i i '° `m E d H .I $o m o I r ° Preservatives (U)np(esenved H(C)J' rill `(S 1 , 3 H2(S)04iIH(N)g3 ,(Na)7hmsulfate Na(0)N{),I1rD� S+�rt`t,a,l+ '�Olher(X),Indlcate' N`� p5a 1b1i ��y( 4iW •1' til d`3,y�J ]# I 1 iTs-- _ I i I I . ,n�... .. J _•� l ] 1 �jtY K y.. t: -J •... .. fYt %S I j.Vi ,t , JI `Ij Rush work will require prior approval. Additional charges will apply 1 ) Agricultural Lime Application Log Year: 2017 Project: Town of Bladenboro Field (state -county -site -field code) Soil pH Lime Requirement, (from soil analysis) Tons/Acre Applied Date Applied NC-BL-03-03 6.6 1 0.0 NC-BL-03-04 6.0 0.0 Page 1 of 2 '- Report Number: 18-033-0519 Account Number:46437 Send To: Synagro Central LLC/ Bladenboro Marshal Puryear 284 Boger Road Mocksville NC 27028 j Waypoint_ ANALYTICAL "Every acre ... Everyyear."rxr 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 p Fax 804.271.6446 www.waypointanalytical.com Grower: Bladenboro Farm ID/Name: Bladenboro SOIL ANALYSIS REPORT AnalyticalMethod(s): Mehlich3 SMPBufferpH LossOnlgnition WaterpH Date Received: 02/02/2018 Date Of Analysis: 0210512018 Date Of Report: 02/07/2018 OM WN ENR- Phosphorus Potassium Magnesium Calcium Sodium pH Acidity C.E.0 Sample ID Field ID Lab Number Rate Soil Class Ibs1A M3 ppm Rate ppm Rate ppm Rate K ppm Rate M 9 ppm Rate Ca ppm Rate Na ppm Rate Soil PH Buffer Index H meq/106g meq/100g 3 01196 2.0 L 84 285 VH NC=237 66 M NC=34 70 M 672 H 12 VL 6.6 0.3 4.5 MIN 4 1 01197 2.5 L 94 226 VH NC=188 89 M NC=46 54 M 542 M 19 VL 6.0 0.6 4.1 MIN Percent Base Saturation Nitrate Sulfur Zinc Manganese Iron Copper Boron Soluble salts Sample FieID ID e K % Mg % Ca % No % H % NO3 N ppm Rate S ppm Rate Zn ppm Rate Mn ppm Rate Fe ppm Rate Cu ppm - Rate B ppm Rate SS ms/cm Rate 3 3.8 13.0 74.7 1.2 6.7 9 VL NC=19 12.0 VH NC=300.0 5 L NC=31 256 VH 7.3 VH NC=365.0 0.5 L 0.12 VL 4 5.6 1 11.0 1 66.1 1 2.0 14.6 17 M NC=35 9.4 VH 1 NC=235.0 6 L NC=38 245 VH 6.1 VH NC=305.0 0.5 L 0.11 VL Values on this report represent the plant available nutrients in the soil. Rating after each value: VL (Very Low), L (Low), M (Medium), H (High), VH (Very High). ENR- Estimated Nitrogen Release.. C.E.C. - Calton Exchange Capacity. Explanation of symbols: % (percent), ppm (parts per million), Ibs/A This report applies to sample(s) tested. Samples are retaineda (pounds per acre), ms/cm(milli-mhos per centimeter),meq/t00g maximum ofthirty days after testing. by. Ppuric m°�� (milli -equivalent per 100 grams). Conversions: ppm x 2= Ibs/A, Soluble Salts ms/cm x 640 = ppm. Analysis prepared by. WaypointAnaly(Ical Nrginie, Inc. Pauric McGroary . j Page 2 of 2 Report Number: 18-033-0519 Account Number:46437 Send To: Synagro Central LLC/ Bladenboro Marshal Puryear 284 Boger Road Mocksville NC 27028 Date Received: 02/02/2018 Date Of Report: 02/07/2018 7621 Whitepine Road, Richmond, VA 23237 Waypoi ■■M■ t Main 804-743-9401 a Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com "Every acre...Everyyear.",v Grower: Bladenboro Farm ID/Name: Bladenboro SOIL FERTILITY RECOMMENDATIONS Nitrogen Phosphate Potash Magnesium Sulfur Zinc Manganese Iron Copper Boron FFiemldp7ID Intended Crop Yield Goal Lime N P205 K20 Mg S Zn Mn Fe Cu B TonslA Ib/A IbIA Ib/A Ib/A Ib/A Ib/A Ib/A lb/A. IbIA Ib/A 3 Adjust pH to 6.0 0 0.0 0 3 0 4 Adjust pH to 6.0 0 1 0.0 11 3 0 Comments: Sample(s) : 4 Crop: Adjust pH to 6.0 Apply required magnesium with magnesium oxide, Epsom Salts, K-Mag or Sul-PO-Mag. 'The recommendations are based on research data and experience, but NO GUARANTEE or WARRANTY expressed or Implied, concerning crop performance is made." Our reports and letters are for the exclusive and confidential use of our clients„ and may not be reproduced In whole or part, nor may any reference be made to the Pod. me 600" work,lhe results, or the company in any advertising, news release, or other public anouncements without obtaining our prior written authorization. Copy right 1977. Paul McGroary