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HomeMy WebLinkAboutWQ0035207_More Information Received_20240403Initial Review Reviewer nathaniel.thorn burg Is this submittal an application? (Excluding additional information.) * Yes No If not an application what is the submittal type?* Annual Report Residual Annual Report Additional Information Other Permit Number (IR) * W00035207 Applicant/Permittee Synagro Central, LLC Email Notifications Does this need review by the hydrogeologist? * Yes No Regional Office CO Reviewer Admin Reviewer Submittal Form Project Contact Information Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence. Name* Adam Brigman Email Address* abrigman@synagro.com Project Information ......................... Application/Document Type* New (Fee Required) Modification - Major (Fee Required) Renewal with Major Modification (Fee Required) Annual Report Additional Information Other Phone Number* 17046504341 Modification - Minor Renewal GW-59, NDMR, NDMLR, NDAR-1, N DAR-2 Residual Annual Report Change of Ownership We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type:* Wastewater Irrigation High -Rate Infiltration Other Wastewater Reclaimed Water Closed -Loop Recycle Residuals Single -Family Residence Wastewater Other Irrigation Permit Number:* WQ0035207 Has Current Existing permit number Applicant/Permittee Address* 284 Boger Rd. Mocksville NC 27028 Facility Name* Synagro Central Class A Residuals Program Please provide comments/notes on your current submittal below. Attached is the Additional Information requested regarding the permit Modification for WQ0035207. At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here. (Application Form, Engineering Plans, Specifications, Calculations, Etc.) Synagro Class A WQ0035207 2023 MOD ADD INFO.pdf 12.82MB Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger than upload limit. * By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Mail payment to: NCDEQ — Division of Water Resources Attn: Non -Discharge Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Signature f Submission Date 4/3/2024 April 1, 2024 NCDENR-DEQ Division of Water Resources Land Application Permitting and Compliance Unit Aquifer Protection Section 1636 Mail Service Center Raleigh, NC 27699-1636 ATTENTION: Mr. Nathaniel Thornburg REFERENCE: Application No. WQ0035207 Permit Modification — Additional Information Synagro LLC DCAR Dear Mr. Thornburg: Regarding the additional information request of March 4, 2024 for the modification request of the Synagro LLC Permit No. WQ0035207, please see the following response. • The discrepancy in the request to increase the Siler City Dry Tonnage to 1,000 Dry Tons from 250 Dry Tons, was a typo. It is correct Siler City is currently permitted for 125 Dry Tons. • Regarding the marketability stamen for the Kerr Lake WTP was revised for clarification and is attached below. • Regarding the Spill Control Plan issues, the Spill Control plan has been updated to ensure all contact information for the regional offices are including in a more efficient manner. • Regarding the missing pages of the RSC form for both sources, it was a scanning error, so those missing pages are attached. • Regarding the Siler City WTP SAR and PAN calculations that was a typo in the RSC form my calculations were the same. Those calculations are attached as well. Along with a updated RSC page 4. • Regarding the TCLP results being three years old, the plant experienced some issues with the lab when Synagro requested a new TCLP. Therefore, I used the 2020 results from the previous sample that was taken that was used for the different contractors permit to land apply there material. They state their processes have not changed and that the material is the same as this previous sample. In the permit with Granville Farms where the Kerr Lake WTP is a source, the TCLP is needed once per permit cycle so that is why the latest one took was 2020 as well. • Regarding the sampling plan for the Kerr Lake WTP, it has been updated to represent the Kerr Lake WTP. Regarding the TCLP sampling frequency, with the material being consistent and the previous permitted cycle for their land application was once per cycle I requested once per cycle. 284 Boger Road, Mocksville, NC 27028 • Phone: (704) 650-4341 Wonzaidg, +l If you require additional information or have further questions, please contact me at (704) 650-4341 or ABril?man&synagro.com. Thank you in advance for the timely and efficient review of this modification application. Sincerely, zl�4- Adam Brigman 284 Boger Road, Mocksville, NC 27028 • Phone: (704) 650-4341 DCAR Marketability Statement Kerr Lake Water Treatment Plant Residuals will be given to local farmers for crop or grass production. Synagro will land apply material for the local farmers who choose to receive residuals. The spreaders will be able to spread the material in an even and consistent manner. The material is going to be land applied on fields that have grass growing on them that are going to either be grazed or cut for hay for animal feed some fields may be in row crop production and rates will be determined by RYE for the crop that is going to be grown for animal consumption. An estimated 1,000 dry tons will be land applied from the Kerr Lake Water Treatment Plant. SPILL RESPONSE PLAN PROJECT: SYNAGRO CENTRAL Permit W00035207 IN THE UNLIKELY EVENT OF A SPILL THE FOLLOWING ACTIONS SHALL BE TAKEN IMMEDIATELY: 1. MANAGEMENT OF SPILL CLEAN-UP ACTIVITIES: The Operations Manager shall take immediate charge and initiate clean-up activities. Synagro labor and equipment is to be utilized. In the event additional labor and equipment is required, assistance may be requested from the Town of Pittsboro, City of Dunn, Town of Franklin, Brunswick County NC, City of Reidsville, Piedmont Regional Water Authority, Town of Mooresville, The City of Durham, The City of Greensboro, Town of Mooresville, City of Charlotte, International Textile Group, Town of Albemarle, or the NC Department of Transportation, and other private contractors as necessary. 2. HALT THE SOURCE OF THE SPILL: Such as a ruptured container or damaged transport unit. 3. CONTAIN THE SPILL: Form a barrier. Sufficient quantities of straw shall be used for such purposes. Earthen barriers may be constructed to augment the straw bale containment area of the spill. The Operations Manager or the person in charge on the spill site will advise the clean-up personnel where to get the straw, lime, and other items necessary to complete the clean-up operation, i.e., local farmers, farm supply centers, nurseries, etc. 4. CLEAN-UP: Employ front-end loaders, vacuum equipment, sludge application vehicles, and/or local septic tank service to remove as much of the spilled material as possible. Straw and/or sand should be scattered in the spill area to soak up the remaining material. The straw- and sand -soaked material will be collected and removed to a disposal area approved by representatives of the state regulatory agency. 5. FINAL CLEAN-UP: Employ rotary brush sweeper if needed, and apply lime to the spill area upon the approval of the clean-up efforts by the state regulatory representative. If the event occurs on private property, the clean-up will be completed to the satisfaction of the property owner and state regulatory representatives. The ultimate goal will be to restore the spill area to its original condition if possible. 6. NOTIFICATION: As soon as possible after the spill occurs, the Synagro Operations Manager or assistant will notify the Synagro Central office, and they will then be responsible for notifying other key Synagro personnel. 7. REPORTING: Synagro Central personnel will notify the Raleigh regional office of the NCDEQ by telephone for the Pittsboro WTP, Durham WTP's, Kerr Lake WTP, Siler City WTP. The Asheville regional office at for the town of Franklin, SJWD WTP, The Wilmington Regional office for Brunswick NW WTP, the Winston Salem Regional office for the City of Reidsville WTP, City of Greensboro, The City of Graham, International Textile Group, and Piedmont Regional WTP, the Mooresville Regional office for The City of Albemarle Tuckertown WTP, Town of Mooresville WTP, and City of Charlotte Lee S. Dukes WTP the Fayetteville Regional Office for the Dunn WTP. This will be done as soon as possible, but not more than 24 hours after, or on the next working day following the occurrence. The Operations Manager shall provide a written report within 48 hours of the spill to the Technical Services Manager. The report shall list all relative information and actions taken. Synagro Central personnel will file a written report to the Raleigh, Asheville, Wilmington, Mooresville, Winston Salem, or Fayetteville Regional office of the NCDENR within 5 days of the occurrence. For after hours reporting the Division's emergency number shall be called to report all incidences (800-662-7956 or 800-858-0368 or 919-733-3300) Asheville Regional Office 828-296-4500 Mooresville Re Tonal Office 704-235-2100 Winston-Salem Regional Office 336-776-9800 Raleigh Regional Office 919-791-4200 Fayetteville Regional Office 910-433-3300 Wilmington Regional Office 910-796-7215 Washington Regional Office 252-946-6481 Division of Water Resources State of North Carolina Department of Environmental Quality Division of Water Resources RESIDUALS SOURCE CERTIFICATION FORM: RSC 06-16 L RESIDUALS SOURCE -GENERATING FACILITY INFORMATION (See Instruction B.): 1. Facility Name: Siler City Water Treatment Plant 2. Facility permit holder is: ❑ Federal, ❑ State, 0 Local Government, or ❑ Private. Facility permit issued by: Div. of Water Resources, ❑ Div. of Environmental Health, or ❑ Other (explain: ). 3. Facility contact person and title: Chris McCorq_uodale Utilities Director Complete mailing address: 311 N 2nd Ave City: Siler City Telephone number: (919)-742-4731 State: NC Zip: 27344 E-mail address: cmccorquodale@silercity.org 4. Facility physical address: 950 Water Plant Rd. City: Siler Qy State: NC Zip: 27344- Coordinates: Latitude: 3'S°45' 39" Longitude: 79° 27' 43" Datum: NAD83 Level of accuracy: Seconds Method of measurement. MAP 5. Purpose of the facility: treatment of municipal wastewater, ❑'; treatment of 100% domestic wastewater, treatment of potable water, [] treatment of 100% industrial wastewater, ❑, treatment of industrial wastewater mixed with domestic wastewater, (approximate percentages:.-. % industrial and %domestic) ❑ other (explain: ). 6. Does the facility have an approved pretreatment program: ® Yes ❑ No 7. Facility permitted/design flow: 4_0 MGD and facility average daily flow: 1_7MGD 8. Average amount of residuals being generated at this facility est 1,000 dry tons per year. 9. Specify the following regarding treatment and storage volumes available at the facility: Type and volume of residuals treatment: Water Treatment Process Type and volume of residuals storage (i.e., outside of residuals treatment units): 1 lagoon estimated '/z million gallons cap. U. RESIDUALS QUALITY INFORMATION (See Instruction C.)! Specify if residuals are regulated under: Q 40 CFR Part 503 or', 40 CFR Part 257. Note: Only residuals that are generated during domestic/municipal wastewater treatment processes are regulated under 40 CFR Part 503, otherwise, the residuals are regulated under 40 CFR Part 257. 2. Specify if residuals are defined under 15A NCAC 02T.1102(61 as: Biological Non -Biological Note: Biological residuals are residuals that have been generated during the treatment of domestic wastewater, animal processing wastewater, or the biological treatment of industrial wastewater (biological treatment is a system that utilizes biological processes including lagoons, activated sludge systems, extended aeration systems, and fixed film systems). FORM: RSC 06-16 Page 1 of 5 3. Hazardous Waste Determination: Complete the following to demonstrate that the residuals are non -hazardous under RCRA: (Note - this item does not have to be completed for facilities that are less than 0.5 MGD in design flow that treat 100% non -municipal, domestic wastewater only) a. Are the residuals listed in 40 CFR §261.31-§261.33: ❑ yes no. If yes, list the number(s): b. Specify whether or not the residuals exhibit any of the characteristics defined by 40 CFR §261.21- 261.24: ❑ yes 0. no. Fill in the following tables with the results of the latest toxicity characteristic leaching procedure (TCLP) analysis as well as those for corrosivity, ignitability, and reactivity: Laboratory: Summit Environmental and Date of analysis: 2/10/2023 Passed corrosivity test: ® yes ❑ no. pH: s.u. (2 < pH < 12.5) Passed ignitability test: ® yes ❑ no. Flashpoint: >140 OF (> 140°F) Passed reactivity test: Eyes Ono. HCN: ND mg/kg (<250) & H2S: ND mg/kg (<500) TCLP Parameter Limit (Mg/0 Result img/V TCLP Parameter Limit (mg/V Result (Mg/0 Arsenic 5.0 ND Hexachlorobenzene 0.13 ND Barium 100.0 ND Hexachloro-1,3-Butadiene 0.5 ND Benzene 0.5 ND Hexachloroethane 3.0 ND Cadmium 1.0 ND Lead 5.0 ND Carbon Tetrachloride 0.5 ND Lindane 0.4 ND Chlordane 0.03 ND Mercury 0.2 ND Chlorobenzene 100.0 ND Methoxychlor 10.0 ND Chloroform 6.0 ND Methyl Ethyl Ketone 200.0 ND Chromium 5.0 ND Nitrobenzene 2.0 ND m-Cresol 200.0 ND Pentachlorophenol 100.0 ND o-Cresol 200.0 ND Pyridine 5.0 ND p-Cresol 200.0 ND Selenium 1.0 ND Cresol 200.0 ND Silver 5.0 ND 2,4-D 10.0 ND Tetrachloroethylene 0.7 ND 1,4-Dichlorobenzene 7.5 ND Toxaphene 0.5 ND 1,2-Dichloroethane 0.5 ND Trichloroethylene 0.5 ND 1, 1 -Dichloroethylene 0.7 ND 2,4,5-Trichlorophenol 400.0 ND 2,4-Dinitrotoluene 0.13 ND 2,4,6-Trichlorophenol 2.0 ND Endrin 0.02 ND 2,4,5-TP (Silvex) 1.0 ND Heptachlor and its Hydroxide 0.008 ND Vinyl Chloride 0.2 ND FORM: RSC 06-16 Page 2 of 5 4. Metals Determination: Complete one of the following tables (i.e., as applicable) to demonstrate that the residuals do not violate the ceiling concentrations for metals regulated under 15A NCAC 02T .1105. a. For Distribution/Land Application: Fill in the following table with the results of the latest analyses (i.e., on a dry weight basis) for the following metal parameters: Laboratory: Meritech, Inc and Date of analysis: 12/23/22 Parameter Ceiling Concentration Limits (ClassA & ClassB) (mg/kg) Monthly Average Concentration Limits (Class A Only) (mg/kg) Result (mg/kg) .Arsenic 75 41 <8.2 Cadmium 85 39 1,64 Copper 4,300 1,500 19.8 Lead 840 300 10.2 Mercury 57 17 <0.164 Molybdenum 75 n/a <4.1 Nickel 420 420 8.61 Selenium 100 100 <8.2 Zinc 7,500 2,800 49.3 b. For Surface Disposal Unit (landfill): Fill in the following table with the results of the latest analyses (i.e., on a dry weight basis) for the following metal parameters: Laboratory. and Date of analysis:. .: Distance from Disposal Unit to Boundary to Closest Property Line (meters, check one) Arsenic (mg/kg) Chromium (mg4g) Nickel (mg/kg) ]' > 0 but < 25 30 200 210 p; > 25 but < 50 34 220 240 > 50 but < 75 39 260 270 ]' > 75 but < 100 46 300 320 > 100 but < 125 53 360 390 > 125 62 450 420 Result (mg/kg) FORM: RSC 06-16 Page 3 of 5 5. Nutrient/Micronutrient Determination: Complete the following: a. Total solids: 0.61 %. b. Fill in the following table with the results of the latest analyses (i.e., on a dry weight basis) for the following nutrient and micronutrient parameters: Laboratory: Meritech Inc and Date of analysis: 12/23/2022 Parameter Result (mg/kg) Aluminum 109,000 Ammonia -Nitrogen <1640 Calcium 1,950 Magnesium 1,180 Nitrate -Nitrite Nitrogen <1640 pH (Standard Unit) 6.3 Phosphorus 1,430 Potassium 751 Sodium 815 Total Kjeldahl Nitrogen 6,960 c. Using the results listed in Item II. 5b. above, calculate the sodium adsorption ration (SAR): 1.41 [Note: If residuals contain SAR of 10 or higher, the applicant shall obtain recommendations from the local Cooperative Extension Office, the Department of Agriculture and Consumer Services, the Natural Resource Conservation Service, a North Carolina Licensed Soil Scientist, or an agronomist, prior to land application of residuals. The recommendations shall address the sodium application rate, soil amendments (e.g., gypsum, etc.), or a mechanism for maintaining site integrity and conditions conducive to crop growth]. d. Specify the mineralization rate to be used in calculating the plant available nitrogen (PAN) of the residuals: 40 %. This rate is a (check one): 0 default value, or ❑ actually established. If the residuals are not generated from the treatment of municipal or domestic wastewater, explain or provide technical justification as to why the selected default value is appropriate to be applied to these residuals: Water Treatment Process e. Calculate the PAN for the residuals (i.e., on a dry weight basis) and fill the results in the following table: Application Method First (111) Year PAN Five -Year Maximum Adjusted PAN (mg1kg) (mg/kg) Surface 4,588 5,733 Injection/Incorporation 5,408 6,553 6. Other Pollutants Determination: Specify whether or not there are any other pollutants of concern in the residuals and provide the results of the latest analyses: None FORM: RSC 06-16 Page 4 of 5 7. Pathogen Reduction: Per 15A NCAC 02T.1106, specify how residuals will meet the pathogen reduction requirements: a. For Distribution/Land Application of Class A or Eauivalent: A fecal coliform density that is demonstrated to be less than 1,000 MPN per gram of total dry solids, or A salmonella sp. density that is demonstration to be less than 3 MPN per 4 grams of total dry solids. AND one of the followings (except for non -biological residuals): Alternative 1 [15A NCAC 02T.1106(b)(3)(A)] - Time/Temperature Compliance. [] Alternative 2 [15A NCAC 02T.I 106(b)(3)(B)] - Alkaline Treatment. Alternative 3 [15A NCAC 02T.I 106(b)(3)(C)] - Prior Testing for Enteric Virus/Viable Helminth Ova. [] Alternative 4 [15A NCAC 02T.I 106(b)(3)(D)] - No Prior Testing for Enteric Virus/Viable Hehninth Ova. [J Alternative 5 [15A NCAC 02T.I 106(b)(3)(E)-(K)] - Process to Further Reduce Pathogens (PFRP). Specify one: composting, [] heat drying, 0' heat treatment, thermophilic aerobic digestion,'; beta ray irradiation, ]�! gamma ray irradiation, or [ pasteurization. b. For Land Application of Class B: EJ Alternative 1 [15A NCAC 02T. I 106(c)(1)] - Fecal Coliform Density Demonstration. Alternative 2 [15A NCAC 02T.I 106(c)(2)] - Process to Significantly Reduce Pathogens (PSRP). Specify one: 0 aerobic digestion, El air drying, 0 anaerobic digestion, 0- composting, or [J. lime stabilization. c. For Surface Disposal: Select One of the Class A or Equivalent Pathogen Reduction Alternatives in Item 11. 7a. above. Select One of the Class B or Equivalent Pathogen Reduction Alternatives in Item 11. 7b. above. Exempt -If Daily Cover Alternative is chosen in Item 11.8. below [15A NCAC 02T.1106(a)(2)]. Not Applicable - Non -Biological Residuals with NO Domestic Wastewater Contribution, 8. Vector Attraction Reduction (VAR): Per 15A NCAC 02T.1107, specify how residuals will meet the VAR requirements: El Alternative 1 [15A NCAC 02T.1107(a)(1)] - 38% Volatile Solids Reduction (Aerobic/Anaerobic Digestion). 0 Alternative 2 [15A NCAC 02T.I 107(a)(2)] - 40-Day Bench Scale Test (Anaerobic Digestion). Alternative 3 [15A NCAC 02T.I 107(a)(3)] - 30-Day Bench Scale Test (Aerobic Digestion). C3 Alternative 4 [15A NCAC 02T.I 107(a)(4)] - Specific Oxygen Uptake Rate Test (Aerobic Digestion). Alternative 5 [15A NCAC 02T.I 107(a)(5)] - 14-Day Aerobic Processes. [] Alternative 6 [15A NCAC 02T.I 107(a)(6)] - Alkaline Stabilization. Alternative 7 [15A NCAC 02T. 1 107(a)(7)] - Drying of Stabilized Residuals. 0! Alternative 8 [iSA NCAC 02T.1107(a)(8)] - Drying ofUnstabilized Residuals. (, Alternative 9 [15A NCAC 02T. I 107(a)(9)] - Injection. Alternative 10 [15A NCAC 02T.1107(a)(10)] - Incorporation. E Alternative for Surface Disposal Units Only - Soil/Other Material Cover [15A NCAC 02T.I 107(b)(2)]. _I Not Applicable - Non -Biological Residuals with NO Domestic Wastewater Contribution. Note: For animal processing residuals, only alternatives 9 or 10 may be chosen due to the nuisance conditions that typically occur when these residuals are applied and left on the land surface. FORM: RSC 06-16 Page 5 of 5 5. Nutrient/Micronutrient Determination: Complete the following: a. Total solids: 3.44 %. b. Fill in the following table with the results of the latest analyses (i.e., on a dry weight basis) for the following nutrient and micronutrient parameters: Laboratory: Waypoint Anal 'cal and Date of analysis: 3/14/2023 Parameter Result (mg/kg) Aluminum 11,300 Ammonia -Nitrogen 3,760 Calcium 1,490 Magnesium 921 Nitrate -Nitrite Nitrogen <147 pH (Standard Unit) 6•8 Phosphorus 1,960 Potassium 453 Sodium 1,010 Total Kjeldahl Nitrogen 26,200 c. Using the results listed in Item II. 5b. above, calculate the sodium adsorption ration (SAR): 1.41 [Note: If residuals contain SAR of 10 or higher, the applicant shall obtain recommendations from the local Cooperative Extension Office, the Department of Agriculture and Consumer Services, the Natural Resource Conservation Service, a North Carolina Licensed Soil Scientist, or an agronomist, prior to land application of residuals. The recommendations shall address the sodium application rate, soil amendments (e.g., gypsum, etc.), or a mechanism for maintaining site integrity and conditions conducive to crop growth]. d. Specify the mineralization rate to be used in calculating the plant available nitrogen (PAN) of the residuals: 40 %. This rate is a (check one):; default value, or 0 actually established. If the residuals are not generated from the treatment of municipal or domestic wastewater, explain or provide technical justification as to why the selected default value is appropriate to be applied to these residuals: Water Treatment Process e. Calculate the PAN for the residuals (i.e., on a dry weight basis) and fill the results in the following table: Application Method First (ls� Year PAN Five -Year Maximum Adjusted PAN (mg/kg) (mg/kg) Surface 11,003 15,834 Injection/Incorporation 12,883 17,714 6. Other Pollutants Determination: Specify whether or not there are any other pollutants of concern in the residuals and provide the results of the latest analyses: None FORM: RSC 06-16 Page 4 of 5 »we •\om6¥ `79«79 c»c»9 kkkk = 3 & g $ m S S k k k k k a n# o \ / / m -- I k k k k c @ E S @ % / . 2\ 2\ k £ 9 n m m 2£ o e J e« \.. $ 7 7 £ ® o ® I © ° _ � k \2 < ) k G co/ c L 22m7 2. co � \ r . . e 0 o w o \ % / ® kC \/ 3) >� / S CD / / c E W) m 0 — Q \� 2 r Cl) ± a I O e $ \ @ z z e > o 2 o r % co U m 68 3=—w &§ » » = 4 k \o \t tCD\\/ / / $ $ ^ 2 � 2 � / 7 M �� �kk\ CO ¢ c 2 § u Project: Sodium Absorption Ratio Calculation (SAR) % Solids 3.44 Na (mg/kg) 1010.00 Ca (mg/kg) 1490.00 Mg (mg/kg) 921.00 Na (mg/L) Ca (mg/L) Mg (mg/L) Na (meq) Ca (meq) Mg (meq) t+IUIIAE LEGEND Fill in this area with data from the analysis sheets These areas are calculated automatically I - Residual Source Volume (Dry Tons) Proportion (dec. %) Source 1 1000 1.00 Source 2 0 0.00 Source 3 0 0.00 Source 4 0 0.00 Total 1000 1.0 Parameters I Source 1 Source 2 Source 3 Source 4 Min. Rate 0.40 0.00 0.00 0.00 H 6.8 0 0 0 % Solids 3.44 0 0 0 Arsenic 14.7 0 0 0 Cadmium 6.26 0 0 0 Chromium 14.4 0 0 0 Copper 15.6 0 0 0 Lead 8.82 0 0 0 Mercury 4.74 0 0 0 Molybdenum 7.35 0 0 0 Nickel 33.2 0 0 0 Selenium 14.7 0 0 0 Zinc 36.8 0 0 0 Aluminum 11300 0 0 0 Ammonia-N 3760 0 0 0 Calcium 1490 0 0 0 Magnesium 921 0 0 0 NO2-NO3-N 147 0 0 0 Phosphorus 1960 0 0 0 Potassium 453 0 0 0 Sodium 1010 0 0 0 TKN 26200 0 0 0 Analysis ID Siler City WTP 2023 N&M Analysis Date Mar-23 Parameters Original Source (Ibs/DT) Source 1 Source 2 Source 3 Source 4 Arsenic 0.029 0.000 0 0 Cadmium 0.013 0.000 0 0 Chromium 0.029 0.000 0 0 Copper 0.031 0.000 0 0 Lead 0.018 0.000 0 0 Mercury 0.009 0.000 0 0 Molybdenum 0.015 0.000 0 0 Nickel 0.066 0.000 0 0 Selenium 0.029 0.000 0 0 Zinc 0.074 0.000 0 0 Ammonia-N 7.520 0.000 0 0 Calcium 2.980 0.000 0 0 Magnesium 1.842 0.000 0 0 NO2-NO3-N 0.294 0.000 0 0 Phosphorus 3.920 0.000 0 0 Potassium 0.906 0.000 0 0 Sodium 2.020 0.000 0 0 TKN 52.400 0.000 1 0 0 Permit Holder Modification Application Aug. 2005 Permit #WQ0035207 Weighted Average Calculations • ... . . I �1 1 11 • •II I •I• .:I III 1111 1 III III 1 III I III III •III I III III oa .1 1 11 1111 •III III 1 III I III III as ® III ao III 1 III 1 III .:1 1 11 I III 1 III II II III 00 •1 II Eff- 111 1111 1 111 ••I II III 1 III 1 III • 1• III •III •III 11 111 1 III 1 III •.1 11 III 1 III 1 /11 •I • 11 I III 1 III I I •/ 1 1/ 1 III I III II II III 1 III 1 111 • ... . MENE / 1 I III 1 11/0 I III I I M. 1 111 1 1110 1111 I I 1 1110 1 1/1 0 I I1/ 1 1 I III 1111 I I11 1 11• I III 1 III 1 11/ /IIIN 1 1.. 1 111 1 111 1 III perew-M 0 I III 1111 1111 1 1 1 111 I III E 1 III / 1110 I III E I III W-7-TIM 0 FITITITIN 0 FITITII 1 111 1 I11 1 1I1 1 111 � 1 111 I / III 1 111 NO I I III I 1 111 I I I11 I I 1 111 1 III 1111 III /III I III 1111 Weighted Ave. 0.40 6.80 3.44 14.70 6.26 14.40 15.60 8.82 4.74 7.35 33.20 14.70 36.80 11300.00 3760.00 1490.00 921.00 147.00 1960.00 453.00 1010.00 26200.00 Weighted Ave. (Ibs/DT) 0.029 0.013 0.029 0.031 0.018 0.009 0.015 0.066 0.029 0.074 7.520 2.980 1.842 0.294 3.920 0.906 2020. 52.400 Residuals Sampling Plan Synagro Residuals Land Application for WQ0035207 Kerr Lake Water Treatment Plant Nutrients and Metals Analysis Sampling Point: Storage Tank • Sampling Frequency: Quarterly • Sample Type: Composite • Lab: Waypoint Analytical Pathogen Reduction (Not Required) Vector Attraction Reduction (Not Required) TCLP • Sampling Point: Storage Tank Sampling Frequency: Once per Permit • Sample Type: Composite • Lab: Summit Environmental Labs