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WQ0000601_GW Monitoring_20081219
GW-59A COMPLIANCE REPORT FORM Permit # -?a- (Submit one each monitoring period with GR=59 jorni.c) date monitoring results were due. Fr' Will this monitoring report (GW-59 and GIN-59A) YES bmitted after the established due data? NO X y required Information missing on the C�4'-59 report forms? N y� t� �-y — Yit✓1,� IYES NO answer to question 1 or 2 is "YES", list in the space provided below the well identification the problems encountered in obtaining the required information. numbers nd l� 1Ssj,,,Q s,`cQ,e —DfRAYEMLLEREGIDNALOMCI rAreany �on 5 2Ni of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES ation plate, area overgrown, etc.)? /jthe answer is "y'es", contact theRegional Officejorguidance. NO monitored constituents equal to or above the established standards? YES O If the answer tb question 4 is NO", skip to section B. If the answer to question 4 !s "YES"list the affected wells individually with conslituent(s) and concentration(s) exceeding standards in the space provided below. r-1 d 0 same constituent(s) in the same well(s) In the last two years? Ir the answer to question 5 is "NO'; skip to section 8. If the answer to question 51s "YES" list in the space provided below, each well with constituent(s) exceeding standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years). at or beyond the review it the answer Is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAi OFFICE IMMEDIATELY FOR GUIDANCE. If the answer /s "NO", monitoring wells may be Improperly located; contact the Regional Office. Is the permittee impl groundwater quality If the answer to question 7 is "YES , describe those actions in the space If the answer to question 7 is 'WO'; contact the Reolonal Office wifl ine person form with G report Plating this portion (GW-59A) of the monitoring report s forms for required wells to the address provided at the "ECEIVE0 DEC 2 9 200E form. that the above Information was evaluated afid the Informatloh stib altidd ln:thia ;i'? J/ 7 --59A) Is true and complete to'the bast of my knowledge.`'- U. ";. "?r? .i4 NO GW-59A 12/8/2093 YELLOW 'OMPLIANCE`REPORT FORM Facility Name ' CSX Transportation - Hamlet Wastewater Treatment Facility Facilty Address 173 CSX Drive Hamlet, NC 28345 County Richmond Contact Person: MIKE GREGORY Telephone #: (910) 205-6379 Well Location/Sity Name: see location map No. of Wells to be Sampled: 8 Well Identification Number (From Permit): MW-1 t-or urounawater Treatment Well Depth 53.75 ft. Well DiameterSystems: 4.0 in. Check One: Screened Interval: ft• to ft ® Influent (98) Depth to Water Level 47. 22 ft. below measuring point. ® Effluent (99) Measuring point (M.P.) is: ft. above land surface Relative M.P. Elevation in ft.: Gallons of water pumpedibailed before sampling: 9.9 Date Sample Collected 11/25/08 Field Analysis: pH 5.4 Specific Conductance - uMhos Temp. ° C Odor Appearance PARAMETERS: (Samples for metals were collected unfiltered X YES COD mg/I Coliform: MF Fecal / 1100ml Coliform: MF Total / 100ml (Note: Use MPN method for highly turbid samples) Dissolved Solids Total 41. mg/I pH (when analyzed) units TOC _ 1.04 mgq Chloride mg/I Arsenic <0.005 mg/I Grease and Oils mg/I R&CPe' Phenol /rz �r„gq Sulfate gA Specific Conductance _Mhos Total Ammonia Inforr,7 t p� mg/I TKN as N DWn ocessOG. ing�nit-mgq GW-59 Rev. 0312000 SERVICE CENTER-•(, NC 27688-7636 Phona: (919)733J221 PERMIT M EXPIRATION DATE: November 30, 2009 Non -Discharge W00000601 UIC NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remedialion: Infiltration Gallery _ Spray Field Remediation: Rotary Distributor Land Application of Sludge X Other Monhoring Well NOTE: Values should reflect dissolved and collaidal concentrations Date Sample Analyzed 12/03/08 Laboratory Name: Certification No. NO and field acidified _X_ YES Nitrite (NO2) as N mg Nitrate (NO3) as N 1.44 mgq Phosphorus: Total as P mg/I Orthophosphate mg/I Al - Aluminum mgq Ba - Barium <0.01 mgA Ca - Calcium mg1l Cd - Cadmium <0.001 mg/l Chromium: Total <0.005 mgA ENVIRONMENT 1. INC NO) mg/I <0.005 mg/1 mgA Ammonia Nitrogen mgq Other (Specify Compounds and concentration units) Ni- Nickel Pb - Lead Zn -Zinc Cu - Copper mg/I Fe - Iron mg/I ORGANICS: (GC, GC/MS, HPLC) Hg -Mercury mgA (Specify test and method #. Attach lab report.) K- Potassium mgq Report Attached?Yes_(1) No_(0) Mg - Magnesium mgA VOC : method # = Mn - Manganese mgA VOC : method # = vnr a.en m. �ernamstem„ uuector Lnvvonmenlal --Please print or type A. DATE SUBMIT FORM ON YELL ONLY GROUNDWATER QUALITY MONITORING:'- COMPLIANCE: REPORT. FORM Facility Name Hamlet Wastewater Treatment Facility Facilty Address CSX Transportation, Box 191A Highway 177N Hamlet, NC 28345 County Richmond Contact Person: M. L. GREGORY (910)582-4901 Well Location/SityName: Location Map Attached Well Identification Number: MW-2 Fom undweterTeaMenlSysemss Well Depth: 41.48 fL Well Diameter: 4.0 In. one: Screened Interval ft. To It. 9 Influent(98) Depth to Water Level 33.6 ft. below measuring point. © Effluent (99) Measuring point is ft. above land surface Gallons of water pumped/bailed before sampling: 13.8 Field Analysis .pH 4.8 Specific Conductance uMhos Temp. °C Odor Appearance (Samples for metals were collected unfiltered X YES CO mg/I Coliform: MF Fecal / 100ml Colifomt: MF Total / 100ml (Note: Use MPN method for highly turbid samples) Dissolved Solids Total 77. mg/I pH (when analyzed) units TOC 2.9 mg/I Chloride mg/I Arsenic <0.005 mg/I Grease and Oils mg/1 Phenol I Sulfate /i Specific Conductance —HL • Mhos Total Ammonia 00ing/I TKN as N Information a ro ees' DWO/BOG � u 9l I'll NO-2 as N NO 3 as N Phosphorus: Total as P Orthophosphate Al -Aluminum Ba - Barium )WATER SECTION PERMITS AND COMPLIANCE UN i 27687' NC 2761,1-,7687 _ Plione:.. (919)7334221- PERMIT #: EXPIRATION DATE November 30, 2009 Non -Discharge W00000601 UIC NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon _ Spray Field _ _ Rotary Distributor •X Other Monitorina Well Remediation: Infiltration Gallery Remediation Land Application of Sludge NOTE Values should reflect dissolved and collaidal concentrations Date Sample Collected 11/25/08 Date Sample Analyzed 12/03/08 Laboratory Name ENVIRONMENT 1, INC Certification No. 10 NO and field acidified _X_ YES NO) 0.012 mg/I mg/I Ammonia Nitrogen mg/I mgll Other (Specify Compounds and concentration units) mg/I NI -Nickel mg/I mg/1 'Ph - Lead <0.005 mg/I mgfi Zn-Zinc Ca - Calcium mg/I Cd- Cadmium <0.001 mg/I Chromium: Total <0.005 mg/I Cu.- Copper mg/1 Fe - Iron mg/1 Hg - Mercury mg/1 K - Potassium mg/1 Mg - Magnesium mg/1 Mn - Manganese mail ORGANICS: (GC, GC/MS, HPLC) (Specify test and method #. Attach lab report.) Report Attached? Yes_(1) No_(0) VOC : method # = VOC : method # = VOC Cad A. Gerhardrtein, Director Environmental - Please print method # = GW-59 Rev. 4/98 Sigature 8 SUBMIT FORM ON YELLOW PAPER ONLY COMPLIANCE REPORT -FORM FACILITY INFORMATION Facility Name Hamlet Wastewater Treatment Facility Facilty Address CSX Transportation, Box 191A Highway 177N Hamlet, NC 28345 County Richmond Contact Person: M. L. GREGORY (910)582-4901 Well Location/Sity Name: Location Map Attached Well Identification Number: MW3 For Groundwater Treatment Systems Check One: Well Depth: 45.70 ft. Well Diameter: 4.0 in. Screened Interval ft. To ft. ®Influent (98) Depth to Water Level 36.8 ft. below measuring point ❑® Effluent (99) Measuring point is ft. above land surface Gallons of water pumpediballed before sampling: 1.1.7 Field Analysis pH 4.9 Specific Conductance uMhos Temp. eC Odor Appearance PARAMETERS: (Samples for metals were collected unfiltered _X_ YES I. SECTION - PERMITS AND COMPLIANCE UNI' 11-768T: - Phone:, (919)7333221 PERMIT #: EXPIRATION DATE November 30, 2009 Non -Discharge WQ0000601 UIC NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Spray Field Rotary Distributor _ X Other Monitoring Well Remediation: Infiltration Gallery Remediation Land Application of Sludge NOTE Values should reflect dissolved and collaidal concentrations Date Sample Collected 11/25/08 Date Sample Analyzed 12/03/08 Laboratory Name ENVIRONMENT 1, INC Certification No. 10 NO and geld acidified _X_ YES NO) CO mg/l NO_2 as N mg/I Coliform: MF Fecal / 100ml NO-3 as N 1.49 mg/l Coliform: MF Total / 100ml Phosphorus: Total as P mg/l (Note: Use MPN method for highly turbid samples) Orthophosphate mg/I Dissolved Solids Total 43. mg/I AI -Aluminum mg/1 pH (when analyzed) units Ba - Barium <0.01 mg/l TOC <1. mg/l Ca - Calcium mg/1 Chloride mg/l Cd -.Cadmium <0.001 mg/l Arsenic <0.005 mg/l Chromium: Total <0.005 mg/I Grease and Oils mgll Cu - Copper mg/I Phenol mail Fe - Iron mg/ l 6� Sulfate 6ti f Ar� figll Hg - Mercury mg/I Specific Conductance Total Ammonia g 1Nho� {j��,,11 K - Potassium Mg - Magnesium mg/I mg/1 TKN as N Inro�mari �19,11 Mn - Manganese mg/I NI - Nickel mg/l Pb - Lead <0.005 mg/l Zn -Zinc mg/l Ammonia Nitrogen mg/I Other (Specify Compounds and concentration units) ORGANICS: (GC, GC/MS, HPLC) (Specify test and method #. Attach lab report.) Report Attached? Yes_(1) No(0) VOC : method # = VOC : method # = VOC : method # = A. Gerhardstein Director Environmental e.{er AutWjWl cent) Name and Title - or GW-59 Rev. 4/98 Signature of Pq rfTi iitee (or FORM ON YELLOW PAPER ONLY ROUNDWATER QUALITY MONITORING: • -'-""" -' """ GROUNDWATERSECTION. PERMITSANDCOMPLIANCEVh QMP,LIANCEREPORT' FORM, . _ P.O. Box 27697., . . Ralelgh;.NC27611-7687 Phone: (919)733-3221 Facility Name Hamlet Wastewater Treatment Facility FaciltyAddress CSX Transportation, Box 191A Highway 177N Hamlet, NC 28345 County Richmond Contact Person: M. L. GREGORY (910)582-4901 Well Location/Site Name: Location Map Attached Well Identification Number: MWd For omund"ter Treatment Systems Chen One: Well Depth: 47.45 ft. Well Diameter: 2.0 In. Screened Interval ft. To ft. ® Influent(98) Depth to Water Level 32.9 tL below. measuring point. ❑m Effluent (99) Measuring point is ft. above land surface Gallons of water pumped/bailed before sampling: 7.2 Field Analysis pH 6.1 Specific. Conductance uMhos Temp. ° C Odor Appearance PARAMETERS: (Samples for metals were collected unfiltered _X_ YES CO mg/l Coliform: MF Fecal / 100ml Colifonn: MF Total / loom[ (Note: Use MPN method for highly turbid samples) Dissolved Solids Total 90. mg/l pH (when analyzed) units TOC 1.27 mg/I Chloride mg/l Arsenic <0.005 mg/l Grease and Oils mgll Phenol mgll Sulfate /ire._ _mg/1 Specific Conductance vos Total Ammonia9 911 TKN as IN _ om _` .-m911 NO 2 as N NO_3 as N Phosphorus: Total as P Orthophosphate At -Aluminum PERMIT #: EXPIRATION DATE November 30, 2009 Non -Discharge WC10000601 UIC NPDES TYPE OF PERMITTED OPERATION BEING MONITORED _ Lagoon Remediation: Infiltration Gallery Spray Field _ Remediaton Rotary Distributor _ Land Application of Sludge X Other Monitoring Well NOTE Values should reflect dissolved and collaidal concentrations Date Sample Collected 10/01/08 Date Sample Analyzed 10/07/08 Laboratory Name ENVIRONMENT 1, INC Certification No. 10 - NO and field acidified _X_ YES NO) 1.58 mg/l N[ -Nickel mg/l mg/l Pb - Lead <0.005 mg/1 mgll Zn - Zinc mg/I mg/I Ammonia Nitrogen mgfl mg11 Other (Specify Compounds and concentration units) Ba - Barium <0.01 mgn Ca - Calcium mg/l Cd- Cadmium <0.001 mg/I Chromium: Total Cu -Copper Fe - Iron Hg -Mercury _ K - Potassium _ Mg -Magnesium Mn - Manganese <0.005 mg/I ORGANICS: (GC, GC/MS, HPLC) (Specify test and method #. Attach lab report) Report Attached? Yes_(1) No_(0) VOC : method # = VOC : method # = vnc : method # = I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory anyalytical data was I produced using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. Cad A. Gefhardstein, Director Environmental and Title - Please print or type GW-59 Rev. 4198 Signature of rmi ee (or Authorized Agent) DATE SUBMIT FORM ON YELLI UNDWATER QUALITY MONITORING: PLIANCE-REPORT FORM - Facility Name Hamlet Wastewater Treatment Facility Facilty Address CSX Transportation, Box 191A Highway 177N Hamlet, NC 28345 County Richmond Contact Person: M. L. GREGORY (910)582-4901 Well Location/Sity Name: Location Map Attached Well Identification Number: MW-5 For Groundwater Treatment Systems Check One: Well Depth: 52.92 ' ft. Well Diameter: 2.0 in. Screened Interval ft. To ft. ® Influent (98) Depth to Water Level 40.5 It. below measuring point. ® Effluent (99) Measuring point is ft. above land surface Gallons of water pumped/bailed before sampling: 6. Field Analysis pH 5.2 Specific Conductance uMhos Temp. ° C Odor Appearance SECTION - PERMITS AND COMPLIANCE UNIT 17687. Phone: (919)733-3221 - PERMIT #: EXPIRATION DATE November 30, 2009 Non -Discharge W00000601 UIC NPDES TYPE OF PERMITTED OPERATION BEING MONITORED _ Lagoon _ Remediation: Infiltration Gallery _ Spray Field _ Remediation Rotary Distributor _ Land Application of Sludge X Other Monitoring Well NOTE Values should reflect dissolved and collaidal concentrations Date Sample Collected Laboratory Name Certification No. 11/25/08 Date Sample Analyzed 12/03/08 ENVIRONMENT 1, INC 10 PARAMETERS: (Samples for metals were collected unfiltered _X_ YES NO and field acidified _X_ YES NO) CO mgn Coliform: MF Fecal / loom] Colifonn: MF Total / t00ml (Note: Use MPN method for highly turbid samples) Dissolved Solids Total 83. mg/I pH (when analyzed) units TOC 1.12 mg/l Chloride rng/I Arsenic , <0.005 mgll Grease and Oils mgll Phenol mg/I Sulfate mg/I' Specific Conductance hos Total Ammonia kLf g�N/ITKN j as N In��._ '§l1 NO 2 as N NO-3 as N Phosphorus: Total as P Orthophosphate AI - Aluminum 0.98 mg/I NI - Nickel mg/I mg/I Pb - Lead <0.005 mg/I mg/l Zn - Zinc mg/I mg/I Ammonia Nitrogen mgn mg/l Other (Specify Compounds and concentration units) Ba - Barium 0.031 mgll Ca - Calcium mg/I Cd- Cadmium <0.001 mg/l Chromium: Total <0.005 mg/l Cu - Copper mg/I Fe -Iron mgll Hg _ Mercury mg/I K - Potassium Mg - Magnesium Mn -Manganese _ Carl A. mg/I ORGANICS: (GC, GC/MS, HPLC) (Specify test and method #. Attach lab report.) Report Attached? Yes_(]) No_(0) VOC : method # = VOC : method # = VOC : method.#= Environmental or GW-59 Rev. 4/98 ON YELLOW COMPLIANCE REPORT FORM_ Facility Name Hamlet Wastewater Treatment Facility Facilty Address CSX Transportation Box 191A Highway 177N Hamlet, NC 28345 County Richmond Contact Person: M. L. GREGORY (910)582-4901 Well Location/Sity Name: Location Map Attached Well Identification Number: MW-6 F.=n Nater Treatment systems Chetl One: Well Depth: 48.35 tL Well Diameter: 2.0 In. Screened Interval ft. To ft.0 Influent(98) Depth to Water Level 38.4 ft. below measuring point. Effluent (99) Measuring point is ft. above land surface Gallons of water pumpediballed before sampling: 4.5, Field Analysis pH 4.9 Specific Conductance uMhos Temp. e C Odor Appearance PARAMETERS: (Samples for metals were collected unfiltered _X_ YES CO mg/l Coliforrn: MF Fecal 1100ml Colifonn: MF Total / 100ml (Note: Use MPN method for highly turbid samples) Dissolved Solids Total mg/I pH (when analyzed) units TOC <1. mg/I Chloride mg/I Arsenic <0.005 mg/l Grease and Oils mg/I Phenol mg/I Sulfate mg/I Specific Conductance A' Total Ammonia /� �_ 01 TKN as N gl PERMIT #: Non -Discharge NPDES 4 - PERMITS AND COMPLIANCE UN Phone: (919)733-3221 EXPIRATION DATE November 30, 2009 WQOGO0601 UIC TYPE OF PERMITTED OPERATION BEING MONITORED _ Lagoon _ Remediation: Infiltration Gallery _ Spray Field Remediation Rotary Distributor _ Land Application of Sludge X Other Monitoring Well NOTE Values should reflect dissolved and collaidal concentrations Date Sample. Collected 11/25/08 Date Sample Analyzed 12/03/08 Laboratory Name ENVIRONMENT 1, INC Certification No. 10 NO and field acidified _X_ YES NO) NO_2 as N mg/I NO-3 as N 1.52 mg/l Phosphorus: Total as P mg/I Orthophosphate mg/l At -Aluminum mg/l Be - Barium 0.019 mg/l Ca - Calcium mg/l Cd- Cadmium <0.001 mg/I Chromium: Total 0.017 mg/l Cu - Copper mg/I Fe - Iron mg/1 Hg -'Mercury mg/I K - Potassium mg/l Mg - Magnesium mg/i Mn - Manganese mg/I NI - Nickel mgn Pb - Lead <0.005 mgp Zn - Zinc mg/I Ammonia Nitrogen mg/I Other (Specify Compounds and concentration units) ORGANICS: (GC, GC/MS, HPLC) (Specify. test and method #. Attach lab report.) Report Attached? Yes_(1) No_(0) VOC : method # = VOC : method # = VOC : method # = Cad A. Gerhardsleln, Director Environmental Systems Pe (o u o t) Name a d Title - Please print or type GW-59 Rev. 4/98 3 g4ture ofPeViittee (or Authorized ON YELLOW PAPER ONLY IDWATER QUALITY MONITORING: IANCE REPORT FORM, , Facility Name Hamlet Wastewater Treatment Facility Facilty Address CSX Transportation, Box 191A Highway 177N Hamlet, NC 28345 County Richmond Contact Person: M. L. GREGORY (910)582-4901 Well Location/S[ty Name: Location Map Attached Well Identification Number: MW-7 ForGrounewaler Treatment Systems cherxone: Well Depth: 37.18 ft. Well Diameter: 2.0 In. Screened Interval ft. To ft. ©Influent (98) Depth to Water Level 29.2 ft. below measuring point. ❑❑ Effluent (99) Measuring point is fL above land surface Gallons of water pumpediballed before sampling: 3.9 Field Analysis pH 4.7 Specific Conductance uMhos Temp. e C Odor Appearance (Samples for metals were collected unfiltered _X_ YES CO mg/l Coliform: MF Fecal / looml Colifonn: MF Total / loom[ (Note: Use MPN method. for highly turbid samples) Dissolved Solids Total 54. mg/I pH (when analyzed) units TOC 1.79 mg/I Chloride mg/i Arsenic <0.005 mg/l Grease and Oils mgll Phenol ri _ Sulfate 1 1 mg/I Specific Conductance 01 Total Ammonia 2 ling/l TKN as N °roma,,, � D mall • yr r/�n, cn �vnu, , - )WATER SECTION - PERMITS AND COMPLIANCE UNIT 127687 - NC'27611-7687 Phone: (919)733-3221 - PERMIT #: EXPIRATION DATE November 30, 2009 Non -Discharge WC10000601 UIC NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Spray Field Rotary Distributor _ X Other Monitoring Well Remediation: Infiltration Gallery Remediation Land Application of Sludge NOTE Values should reflect dissolved and collaidal concentrations Date Sample Collected 11/25/08 Date Sample Analyzed 12/03/08 Laboratory Name ENVIRONMENT 1, INC Certification No. 10 NO and field acidified _X_ YES NO) NO_2 as N mg/I NO_3 as N 2.21 mg/I Phosphorus: Total as P mg/I Orthophosphate mg/I AI - Alum[num mg/l Ba - Barium 0.024 mg/l Ca - Calcium mg/I Cd- Cadmium <0.001 mg/I Chromium: Total 0.014 mg/I Cu - Copper mg/I Fe - Iron mg/I Hg - Mercury -mg/I K - Potassium mg/I Mg - Magnesium mg/I Mn - Manganese mg/i Cad A. Gerhardstein, NI - Nickel mg/I Pb - Lead <0.005 mg/I Zn -Zinc mg/l Ammonia Nitrogen mg/I Other (Specify Compounds and concentration -units) ORGANICS: (GC, GC/MS, HPLC) (Specify test and method #. Attach lab report.) Report Attached?Yes_(1) No_(0) VOC : method # = VOC : method # = VOC : method # = ctor Environmental Systems Name anfl Title - Please print or GW-59 Rev. 4/98 SrgnaTure ofPeryrStre (or ON YELLOW 3ROUNDWATER QUALITY MONITORING: OMPLIANCE REPORT FORM - Facility Name Hamlet Wastewater Treatment Facility Facilty Address CSX Transportation Box 191A Highway 177N Hamlet, NC 28345 County Richmond Contact Person: M. L. GREGORY (910)582-4901 Well Locatlon/Sity Name: Location Map Attached Well Identification Number: MW-8 Far Gmun:vater Treatment Systems Chea One: Well Depth: 57.18 fL Well Diameter: 2.0 In. Screened Interval ft. To ft. ❑o Influent(98) Depth to Water Level 41.2 ft. below measuring point. ❑n Effluent (99) Measuring point is ft. above land surface Gallons of water pumped/bailed before sampling: 72 Field Analysis pH 5.2 Specific Conductance uMhos Temp. e C Odor Appearance PARAMETERS: (Samples for metals were collected unfiltered _X_ YES CO mg/I Collfonn: MF Fecal / 10om1 Colifonn: MF Total / loom[ (Note: Use MPN method for highly turbid samples) Dissolved Solids Total 125. mg/I pH (when analyzed) TOC Chloride Arsenic Grease and Oils Phenol Sulfate Specific Conductance Total Ammonia TKN as N units 1.6 Mgt[ mg/l Unit UNDWATER SECTION -PERMITS AND COMPLIANCE Uh Box 27687' gh, NC'-27(11-768T _ Phone:: (919)733.3221 PERMIT #: EXPIRATION DATE November 30, 2009 Non -Discharge W00000601 UIC NPDES TYPE OF PERMITTED OPERATION BEING MONITORED _ Lagoon _ Remediation: Infiltration Gallery _ Spray Field _ Remediation Rotary Distributor _ Land Application of Sludge X Other Monitoring Well NOTE Values should reflect dissolved and collaidal concentrations Date Sample Collected, 11/25/08 Date Sample Analyzed 12/03/08 Laboratory Name ENVIRONMENT 1, INC Certification No. 10 NO and field acidified _X_ YES NO) NO-2 as N mg/I NO-3 as N 10.4 mg/I Phosphorus: Total as P mg/l Orthophosphate mg/I At - Aluminum mg/I Ba - Barium 0.046 mg/I Ca - Calcium mg/I Cd-Cadmium <OA01 mg/l Chromium: Total 0.014 mg/I Cu -Copper Fe - Iron Hg Mercury _ K - Potassium _ Mg - Magnesium Mn - Manganese NI - Nickel mgll Pb - Lead <0.005 mg/I Zn - Zinc mg/I Ammonia Nitrogen mg/I Other (Specify Compounds and concentration units) ORGANICS: (GC, GC/MS, HPLC) (Specify test and method #. Attach lab report.) Report Attached? Yes _(1) Nc_(0) VOC : method # = VOC : method # = VOC : method # = Can A. Gerhardstein, Director Environmental Name and Title - Please print GW-59 Rev. 4198 tgnalure of erm oroAulloonz�gln) DATE EnMOmmomq alp hmppQEUd CSX TRANSPORTATION (HAMLET) MIRE GREGORY 173 CSX DRIVE DATE COLLECTED: 11/25/08 HAMLET ,NC 28345 DATE REPORTED : 12/09/08 REVIEWED BY: MW-1 MW-2 MW-3 MW-4 MW-5 Analysis Method PARAMETERS Date Analyst Code PH (fleld measurement), Units 5.4 4.8 4.9 5.9 5.2 11/25/OS RJH SM4500HB Nitrate Nitrogen, mgll 1.44 1.73 1.49 1.58 0.98 11/26/08 ANO EPA353.2 Total Organic Carbon, mg/l 1.04 2.90 <1.00 1.39 1.12 11/26/08 SEJ SM531UC Total Dissolved Residue, mg/l 41 77 43 66 83 11/28/08 TRB SM2540C Arsenic, ug/l <0.005 <0.005 <0.005 <0.005 <0.005 12/02/08 CMF SM3113B Barium, ug/l <0.010 0.012 <0.010 <0.010 0.031 12/03/08 LFJ EPA200.7 Cadmium, ug/l <0.001 <0.001 <O.601 <0.001 <0.001 12/01/09 CMF SM3113B Total Chromium, ug/l <0.005 <0.005 <0.005 <0.005 <0.005 12/03/08 LFJ EPA200.7 Lead, ugh <0.005 <0.005 <O.005 <0.005 <0.005 12/03/08 CMF SW113B Static Water Level, feet 47.82 33.68 36.80 32.93 40.58 11/25/08 RJH Water Balled, Gals. 9.9 13.8 11.7 7.2 6.0 11/25/08 RJH CSX TRANSPORTATION (HAMLET) MIKE GREGORY 173 CSX DRIVE HAMLET ,NC 28345 ID#: 4 DATE COLLECTED: 11/25/08 DATE .REPORTED : 12/09/08 REVIEWED BY: 4 MW-6 MW-7 MW-8 Analysts. Method PARAMETERS Date Analyst Code PH (field measurement), Units 4.9 4.7 5.2 11MI08 RJH SM4500HB Nitrate Nitrogen, mg)l 1.52 2.21 10.40 11/26/08 ANO EPA353.2 Total Organic Carbon, mgll <1.00 1.79 1.60 11/26/08 SEJ SM5310C Total Dissolved Residue, mg/l Missing 54 125 11/28/08 TRB SM2540C Arsenic, ugA <0.005 <0.005 <0.005 12/02/03 CMF SM3113B 0.019 0.024 0.046 12/03/08 LFJ EPA200.7 Barium, ug/l <0.001 <0.001 <0.001 12/01/08 CMF SM3113B Cadmium, u9/1 0.017 0.014 0.014 12/03/08 LFJ EPA200.7 Total Chromium, ug/i <0.005 <O.005 <0.005 12/03/08 CMF SM3113B Lead, ug/l Static Water Level, feet 38.44 29.29 41.21 11/25/08 RJH Water Bailed, Gals. _ 4.5 39 7.2 11/25/08 RJH 1, 111c. CHAIN OF CUSTODY RECORD P.CJTioR=:085, 114 Oakmont Dr. Page 1 of 1 ircenvme, Ni- Lima DISINFIXTION CHLORINE NEUTHALIZEDATCOLLECTION 'hone (252) 756-6208 ^Fax (252) 756-0633 I—�, I p CHLORINE �LI)C1VT; 4 Week: 46 �a UV / pHCHECK(LAB) P P P P - P CONTAINERTYPE, PIG CSX TRANSPORTATION (11A]MILET) - 13 NONE MIKE GREGORY 173 CSX DRIVE , A A C A A CHFSAICALPRESERVATION HAMLET NC 28345 A -NONE D-NAOH - (910) 205-6379 E ,L Z Z Z m w B-HNCs E-HCL u� Ft 0a; F ¢ µi C-H,SO, F-ZJNCACEfATE COLLECTION o g a. U m 'd G-NATHIOSULFATE . Cp c a SANIPLELOCATION DATE TIME R ¢�' alwa i t Yp f l 1 o 5 CLASSOCATION WASTEWATER(NPDES) DRINKINGWATFA DW(YGW MW-2 5 MW-3 ��� 5 MW4 lZD�•J f' t9 5 Raw ,. MW-5 �� C) ) � 5 SOLIDWASIESEC110N 'd - MW-6 , 1 J 5 5 , CHAIN OF CUSTODY MAINTAINED MW-7 W 'Y DURING SliieMENT/DELIVERY N MW-8 11 5 SAMPLESCOLLECTE BY: ( P. SAMPIL-SRECEI DIN AT_(3 °C DATERIME COMMENTS: L ( c5 ,{P, EUNOUI 1 - BY (SIG.) (SAMPLER) REC Y (S I�DATWME RELINQUISHEDBY SIG.) DATE/fW1E RECENED G.) DA7FJIIME ^ S' C RELINQUISHED BY (SIG.) DATEITIME RECEIVED BY(SIG) DATE/RNE Instructions for completing this form are on the reverse side. Sampler must place a V for composite sample or a"G" for No- 174000 Grab sample in the blocks above for each parameter requested. FORM Q5 CSX QA/QC DATA SUMMARY FACILITY: Hamlet SAMPLE DATE: 11/25/08 SAMPLE LOCATION: Monitoring Wells PARAMETER: Nitrate Nitrogen Duplicates RPD = 3.1 % (acceptable value is < 14.75%) Quality Control Standard Recovery =105.0 % (acceptable value is 85-115%) Blank Value = 0.00 mg/1 PARAMETER: Total Organic Carbon Duplicates RPD = 0.0 % (acceptable value is <10:841/6) Quality Control Standard Recovery = 97.3 (acceptable value is 85-115%) Blank Value= 0.00 mg/1 PARAMETER: Total Dissolved Residue Duplicates RPD = 0.7% (acceptable value is <6.15%) *Quality Control Standard Recovery =102.6% (acceptable value is 90-100%) Blank Value =1.5 mg/l * Value reported for required quarterly QC standard. RPD (Relative Percent Difference) Quality control data for individual metals analyses is attached on the following pages. ICP Ongoing Quality Control —_. Second Source Digested LCS 0.0000 4.8000 _ 19 - _--Value Result, u91L Sequence# 461.9 ?Q. %R--y 92 A—ptnnce +/• 15% I PasslF-0 LxJ U __.. _._�......_. _. " Spike R1te, Sequence# %Recev �, . Aceptance +/-20%(WW) :PeeelFell Di d'Matrix Saika � 6 22 97 +I.30%(DW) LLx, U Spike Lug3 _ _—_._ Bottle M Sampla Nana LSX —. 441 :Client ID 0 4 'Sample Result, Ug1L Sequence # . :Lacetian Code W03 �I �y�,r......,__... 'Date 11/25/2008 Digasled Matrix Spike DR J vy� -- -- 'Spike Reeulb, u91L Sequence # ' % Recevery I :PasslFag 1 500"i`:'yy`rR.nv�- 479.7 23 T 96 _ LXJ U _ RPD �Aoceptance QO% PesalFw CrW :Digested Method Blank Value Result, uglL Sequence# .. RL Acceptance Pass/Fall 0_0000 5.0 <= RL i LU U Second Source Digested LCS ec Value Petd%ug1L _ SequenceR %Recoveryr Acraptance PasNFail ' 500 459.9 20 92 M-15% Lx, U _ _..__ .... .. Spike Resups,_._.. ua/L . ..._P— Sequence# %Ra=ary +620%.(WM PMGIFaq Oi ested Matrix Spike H _ i Lx, U ' Spike Amount u94 p 500 Betts# ;Sample Name._... 441 sCliant ID # 4 _. . .._ -Sample Resua, 6S.4 Sequence # ILoceSon Cade W03 0.4___. :Date 11/25/2008 , Dpeslad Matrix spike DUp_._ _,: Results, ugA. Sequence# %Re rY Pass/Fail ' 5500 43 ,,.:; 479.3 23 96 L%J U RPD Acceptance QO'Y PasWFa)I 1 LX_) U TEST: _1:5-' GRAPHITE FURNACE - INITIAL & ONGOING QUALITY CONTROL Date of Analysis: 12/ 2 / 08 Analyst Initials: Value, ug/l Result, u8/1 Sequence # R Acceptance Pass ---Fall Blank Check 0.0 Value, ug/I `B' i°3o Result, ugA Sequence # % Recovery Acceptance Pass —Fail Initial Calibration Verification 2 .D Value, ug/I ( 26 i7 Result, ug/I g Sequence # l0 % Recovery 10 Acceptance cep Pass- Fail Detection Limit Standard S O Value, ugil tt. 7 l Value, ugll 77 Value, ug/l Value, ug/I Value, ug/1 Initial Calibration Levels 6 O S-U ( /0. 0 ) 257v ; 0,0 Value, ugA Result, unce # RL Acceptance Pass --Fail Digested Method BlanWAd /!-7 0.0 `0.43 27 S <RL W,g !/-7f Value, ug/IrResuug/l Sequence # % Recovery Acceptance Pass --Fail LCS Second Source mid -point) Digested Spike Amount dg/I 2 D 2,7 Z P esult, ugll Sequence# q / %Recovery ±15% Acceptance ( '� Pass ---Fail Matrix Spike Z( so) ±20%Sample Name: #1Client ID# �-1 Result, ugA SegZ�ce # Location Code: Iro 6 r !_� Date: It-2-4 Digested MS Spike Amount, ug/I Spike Result, ug/I Sequence # %Recovery Acceptance Pass ---Fail I Duplicate #1 ( Zf0 23 703/ g RPD +20% Acceptance Pas�Fail Spike Duplicate Results_ I L I RPD <20% ( ) Value, ugfl ug/I Sequence # RL Acceptance < RL Pass --Fail DDiGested Method Blank 0.0 Value, ugn , ug/I Sequence # % Recovery Acceptance Pass --Fail LCS Second Source mid -Point) fiigestzd Spike Amount ugll tResult, Result, ug/ISequence# % Recovery +IS% Acceptance Pass —Fail (_, �� ±20% Matrix Spike (� Sample Name: #2 Client lD# Sample Result, ug/I Sequence # Location Code: Date: Digested MS Spike Amount; ug/I Spike Result, ug/I Sequence # % Recovery Acceptance Pass-( Fail Duplicate 01 ( ( RPD — Acceptance Pass ---Fail Spike Duplicate Results RPD <20% Value, ugn Result, ug/I Sequence # RL Acceptance Pass --Fail Digested Method Blank 0.0 Value, ug/I Result, ug/I Sequence # % Recovery < RL Acceptance Pass ---Fail LCS (Second Source mid- pint) Digested Spike Amount, ug/l ) ( ( Spike Result, ug/l Sequence # % Recovery ±IS% Acceptance ( ( ) L) —Fail Matrix Spike U �_) �� �_� ±20% ( Sample Name: #3 Client ID# Sample Result, ug/I Sequence # Location Code: Date: Digested MS Spike Amount, ugn Spike Result, ug11 Sequence # % Recovery AcceQtance Pass —Fail Du licate#1 RPD +200/0 Acceptance Pass —Fail Spike Duplicate Results RPD <20% TEST: GRAPHITE FURNACE - INITIAL & ONGOING QUALITY CONTROL Date of Analysis: _L/_j/ OSf Analyst Initials: ��d Blank Check Value, ug/1 0.0 Result, ug/1 —O.It5' Sequence # RL Acceptance Pass --Fail ( <RL Initial Calibration Verification Value, ug/l ( zS.o Result, ug/1 ZS,Zt Sequence# $ % Recovery 1,( Acceptance +100/0 Pass —Fail Detection Limit Standard Value, ug/1 Result, ug/l Sequence # % Recovery ( 9 S Acceptance +10% Pass --Fail Initial Calibration Levels ValueO, ug/l O, Value, ug/1 f 0 Value, ug/l (/0.6 Value, ug/1 Zf.0 Value, ug/1 ( SO.O Value, ug/l Result, ug/l Sequence # RL Acceptance Pass ---Fail Digested Method Blank W1A //'78 0.0 -0. rS7 3V < RL wge 10r Value, ug/l Result, ug/l Sequence # % Recovery Acceptance Pass --Fail LCS (Second Source mid -point) ( 2f D 2 3. sf)S 9 y ±15% �( Digested Spike Amount, ug/l Spike Result, ugfl SeiWuence # % Recovery `tl Acceptance Pass --Fail Matrix Spike Zf,O y2.P ( ) ( ) +2Q% Lf:5,L—) Sample Name: #t c 7)z yY41 Client ID# t/ Sample Result, ug/l Sequence # Location Code:. w4% ( 0• +60) ( -5 6 ) Date: //- 3 Digested MS Spike Amount, ug/l Spike Result, ug/l Sequence %Recovery Acceptance Pass --Fail LDu licate #1 2%p 24 0( 8 gC +200/. RPD Acceptance -- PaFail Spike Du licate Results i RPD <20% (ss Value, ug/l Result, ug/l Sequence # RL Acceptance Pass --Fail Divested Method Blank 0.0 ( <RL Value, ug/l Result, ug/l Sequence # % Recovery Acceptance Pass --Fail LCS Second Source mid -point) +15% Digested i Nlatriz Spike Spike Amount, ug/l (_� Sample Name: Spike Result, ug/1 ( ) Sequence # !_� %Recovery (_� Acceptance ±20% Pass —Fail #2 Client ID# Sample Result, ug/l Sequence # Location Code: Date: Digested MS Duplicate #1 Spike Amount, ug/I ( Spike Result, ug/l Sequence # ( % Recovery Acceptance +20% Pass —Fail ) RPD Acceptance Pass —Fail Spike Duplicate Results RPD <20% ) ( ) Value, ug/l Result, ug/l Sequence # RL Acceptance Pass --Fail Digested Method Blank 0.0 < RL ( Value, ug/l Result, ug/l Sequence # % Recovery Acceptance Pass ---Fail LCS (Second Source mid -point) +15% Digested Matrix Spike Spike Amount, ug/l (_� Spike Result, ug/l L� Sequence # O % Recovery �� Acceptance ±20% Pass ---Fail Sample Name: #3 Client ID# — Sample Result, ug/l Sequence # Location Code: Date. Digested MS Duplicate #I Spike Amount, ug/l Spike Result, ug/I Sequence # % Recovery Acceptance Pass --Fail +20% RPD Acceptance 'Pass ---Fail Spike Duplicate Results RPD <20% TEST:( GRAPHITE FURNACE - INITIAL & ONGOING QUALITY CONTROL Date of Analysis: j/ / / O$ Analyst Initials: ate/ Value, ug/l Result, ug/l Sequence # RL Acceptance Pass --Fail Blank Check 0.0 70•17' g- ( <RL ( Value, ug/l Result, ug/l Sequence # % Recovery Acceptance Pass ---Fail Initial Calibration Verification 0 Z. Syz Value, ug/l Result ug/I Sequ nce # % Recovery Acceptance Pa--Fail Detection Limit Standard I , 0 !, 0!6 101 +10%a Value, ug/l Value, ug/l Value, ug/l Value, ug/l Value, ugA Initial Calibration Levels 0.0 t, 0 Z -SU 5'.6 — Value, ug/I Result, ug/l Sequence # RL Acceptance Pass --Fail Digested Method Blank wrn //-78 0.0 �D, /7L T 3 1 <RL ) We- //-Ar Value, ugn Result, ug/l Sequence # % Recovery Acceptance Pass ---Fail LCS (Second Source mid -point) 2 • SD (z- y4s - 3 `1 !00 +15% ( � Digested Spike Amount, ug/l Spike Result, ug/l Sequence # % Recovery Acceptance Pass —Fail Matrix Spike ( Z .0 ) ( 2. i`/Z) ( � ) l( / 0 ) +20% (��) Sample Name: #1 Client ID# y Sample Result, ug/l Sequence # Location Code: tvo6 ( D•/��) ( 3f ) Date: / - Digested MS Spike Amount, ug/l Spike Result, ug/l Sequence # %Recovery Acceptance Pass ---Fail +20o/a I Duplicate #; 2•SU 2.d0 ? !/Z RPD Acceptance P�-Fail Spike Duplicate Results 2 RPD <�0% � Value, ug/l Result, ug/l Sequence # RL Acceptance Pass ---Fail Digested Method Blank ( 0.0 1 <RL 1 I'LCS (Second Source mid -point) Value, ug/l Result, ug/l Sequence # ( %Recovery Acceptance +15% Pass —Fail Digested ' i Matrix Spike Spike Amount, ug/l (� Sample Name: Spike Result, ug/l (_� Sequence # �� % Recovery ( ) Acceptance ±200/a Pass --Fail #2 Client 1D# Sample Result, ugn Sequence # Location Code: Date: Digested MS I Spike Amount ug/l Spike Result, ug/l Sequence # % Recovery Acceptance Pass --Fail Duplicate #1 ( _+20% ( RPD Acceptance Pass —Fail Spike Duplicate Results RPD <L0% ( ) Value, ug/l Result, ug/l Sequence # RL Acceptance Pass —Fail Digested Method Blank ( O.o ___) ( < RL I LCS Second Source mid -point) Value, ug/l Result, ug/l ( Sequence # % Recovery Acceptance +15% Pass —Fail ( ( ) Digested Spike Amount, ug/l Spike Result, ug/l Sequence # % Recovery Acceptance Pass --Fail Matrix Spike (__) �) �_� �� ±20% Sample Name: i� 4 Client ID# Sample Result, ug/l Sequence # Location Code: U (� Date: Digested MS Duplicate #1 Spike Amount, ug(l Spike Result, ug/l Sequence # % Recovery Acceptance +20% Pass --Fail ( ( RPD Acceptance Pass --Fail Spike Duplicate Results RPD <20°/u ( ) ( ) 11/06/2008 13:56 9102056330 CSX ENV HAMLET PAGE 01110 oEmpo Trod C6S TPANSFORTATIO14 (HAMLET) MIRE GREOORY 173 CSX DRIVE RM-EtET ,NC 28345 MW-4 Analysis Method PARAMETERS Date Analyst Code PH (field measurement),. Units 6.1 10/0l/08 RM SM45001M Nitrate Nttrogen, mgn 1.51 10/03/09 ANO EPA353.1 Total Organic Carbon, mgll 1.27 10/06108 SEi SM5310C . Total Dissotvea Residue, nlgn 90 10/06/08 TRB SM2540C Arsenic, ugn <0.005 10/07/08 CMF EPA200.8 Barium, ug/1 <0.010 10/07/08 CDIB EPA200.8 CadmiuN, ugll <0,001 '10/07i08 CMF EPA200.8 Total Chromium, u0/1 <0.005 10107/OS CD1F EPA200.8 Lead, ug/l <9.005 10/07/08 CM XPA200.8 Statte Water Level, feet 31.20 10/01i08 RJH Water Bailed, Gals. 7.8 10/01/08 RJH ID#c 4 DATE COLLECTED: 10/01/08 DETE REPORTED : 10/13/08 REVIEWED HY• Laboratory Analyses — Environmental Consultants EDvi!ronment i, in¢ P.O. Box O95, ) t4Oakmont Dr. rreeov)0e NC 27858 CHAIN OF CUSTODY RECORD Page 1 of 1 hone (252) '756-6208 • Fax (252) 756-0633. CLIENT: 4 Week:2 CSX THANs"GRTA 7GN *LkMLE1) 2MKE GFEGORY PRWE YHAARE t• NC 28345 (9Y0) 205.6379 . COLLECTION DISINFECI•ION CHLOi2INE UV �•J NONE CHLORNENEUIRALIZEDATCOLLECTION pH CHECK LAB) P P P P P OJNTPNERTYPE,PIG A A C A A CHEMICALPRESEWATION A -NONE D-N40H B•HNOs E-HCL C-H,80, F-ZNCACETATE G-NATFBOSILFATE z z R� � 9 z g� a w g o 3� iB z V O- w F ri Q n a a w SA44PLPLOCADON DATE TIME NW-4 1b 01 d f CLASSIFICATION: . C� WASTPRATER(NPDES) DRINKMGWATER tTMGIN SOUDWASTESECTION CHAIN OF CUSTODY MAWTAINEO DURIN MENTIDEUVERY Y N SAMPLES0011LECT BY: (P rd} SAMPLES RECEIVEDIN A7 � ' � °C 8Y{SIG.J(SaMPLH� RELNOUISHEDBY SIG) RELILd.KSHED BY{SIG.) DATE1T7tAE RECE BY{ DATHNME O^AENTS` DATEMNE REGEIVEDBY() DATEf ME DA E RECEIVEDBY{SIG) DATENME Instructions for completing this farm are an the reverse side. Sampler must place a`O' for composlfe sampla ore "G" for P 9 _ .... .. . . . , Alo 1RRAAR ■ y D 11/06/2008 13:56 9102056380 CSX ENV HAMLET PAGE 03/10 CSX QA/QC DATA SUMMARY FACILITY: Hamlet SAMPLE DATE: 10/01/08 SAMPLE LOCATION: Monitoring Well 94 PARAMETER: Nitrate Nitrogen Duplicates RPD =1.2 % (acceptable value is < 14.75%) Quality Control Standard Recovery =105.0 % (acceptable value is 85-115%) Blank Value = 0.00 mg/1 PARAMETER: Total Organic Carbon Duplicates RFD — 0.0 % (acceptable value is <10.84%) Quality Control Standard Recovery =101.8 (acceptable value is 85-115%) Blank Value = 0.00 mg/l PARAMETER: Total Dissolved Residue Duplicates RPD =1.5% (acceptable value is <6.15%) *Quality Control Standard Recovery = 96.6 % (acceptable value is 90400%) Blank Value = 4.0 mg/1 * Value reported for required quarterly QC standard. RFD (Relative Percent Difference) Quality control data for individual metals analyses is attached on the following pages. 11/06/2008 13:56 9102856380 CSX ENV HAMLET PAGE 04110 IC P[mS INITIAL QU,&LITY CONTROL hate ofAna][ysis: P / '?- 1 C28' $lank Check: Analyst Initials: oniL Aa Value, ug/1 Result, ug/1 File . RL Acceptance Pass —Fail 0.0 <RL Al Value,ug/ Result ut/1 File# RL Acceptance? L ()•�� — AS Value, ug/l Result, ug11 File 0 RL Acceptance lass —Fa] B a Value, ug/l Result, ugA File # RL Acceptance Pass ---Pat 1160 10 <RL P— r)-3}3e 'Value, ugh Result,ug/l File# RL Acceptance Pass —Pail 0.0 :SFL . r U ) Ca Value, ug/l Result, ugfl File # RL Acceptance asl - -Fail1 0.0 _ Cd Value, ug/1 Result, ugll _ File # RL Acceptance Pass --Fail 0.0 el. ova 116d ! <RL LtTL) CO Value, ug/1 Result, uy'l File it RL Acceptance pass -Fail L d� ) Cr Value, ug/1 Result, ugll File ,# RL Acceptance ass-- ail 0.0 0. U 3 1/60 t <RL LPL] Cll Value, up/1 Result, ug/l File # RL Acceptance pass —Fail j L 00 — H Value, ug/l Result, ug/l File # RL Acceptance , pass --Fail g 00 <RL L lr l- Value, ug/l Result, ug/l File # RL Acceptance ass --pail 0.0 ( <RL LL-) Mg Value, ug/1 Result, ugA i File # RL Acceptance Pass --Fail ( 0.0—) <ItI r r ) Mn Value, ug/l Result, ug/l File # RL Acceptance ass... Fail 0.0 <RL M0 Value, ugA Result, ugA Filet,' RL Acceptance Pass --- Fail ' ( 0.0 ) �RL I L1L� Ni Value, ugA Result, ugA File # RL Acceptance Pass ---Fail ( 0,0 1 <RL L J L—) Pb Value, ug/1 Result, ugA Pile # RL Acceptance ass-- ai ( 0.0 ) as 9' LGU 4 _<RL Sb Value, ugA Result, ug/1 File # RL Acceptance Pass --Fail 1 0.0 1 ) <RL L—I-LJ - Se Value, ug/l Result, ug/l File # RL Acceptance Pass --Fail 0,0 —<RL f ZL—) Sri Value, ug/l Result, ug/l File # RI: Acceptance Pass —Fail 0.0 <RL L ) ( ) TI Value, ug" Result, ug/l . File # RL Acceptance a 1.( aill ! V Value, ug/I Result, ug/l File # RL Acceptance Pass--- Fail ( 0.0 Zl1 Value, ugA Result, ugA File # RL Acceptance ass --'-Fail ( 0.0 ) ( <RL LLf� U Value, USA Result, ug/I Pile # RL Acceptance Pass--- Fail ART, f ) ( ) 11/66/2008 13:56 9102056380 CSX ENV HAMLET PAGE 05/10 IC?/mS MTTAL QUALM CONTROL 'Date of Analysis: • L! % l""e ,Second Source Verification (ICE: Analyst Initials ��� /� g Value, ue _ Result, ugA File # %Recovery Acceptance -1-10% Pass ---Fail Al Value, ug/l Result, ug/I File # % Recovery Acceptance +l0% ass —Fail L) ( ) AS Value, ug/1 • Result, ugA y3.8N8 File # /161 %Recovery 16 Acceptance +10% pass —Fain LPL Ba Value, ug/1 Qaa . tiesnit, ug/1 tfle. q7.o File # 11 1 %Recovery gN Acceptance +_10%. ass... ail e Value, ugA Result, u8/1 File # ' % Recovery AcceptancePass•--Fa' +l0% ( I i Ca Value, ug/I Result, ug/I File # %Recovery Acceptance ±10% pass --Fail Cd Value,ug/l U Result,U911 Y�,3t�1 File llG/ %Recovery 9 f Acceptance =1.0% Pass --Fail f1 Co Value, ug/l Result, ug/I File # Recovery Acceptance +10% Pass —Fa' L I 1 Cr Value, u8/1 Result, ug/l y7 76S' File # /l - %Recovery 4 Acceptance ±lo% Pass —Fail Cn -Lie. Value, ug/I Result, u54 . File # %Recovery Acceptance t_10% ass ---Fail L )J 1 H, 9Value, ug/: Result, ug/1 File # - - %Recovery Acceptance +10% ass ---Fail . L LL1 i Value, uO Result, ug.4 File # "A Recovery Acceptance +10% --Fail L1L._Z Mg Value, uO Result, ug/l File # a/°Recovery Acceptance +10% Pass --Fail L, LL-) mn Value, uVI Result, u01 Fite # %Recovery Acceptance +10% Pass ---Fail L�1 0 Value, ug/1 Result, ugll ) File # % Recovery Acceptance +IQ% ass -•-Fail L 1/ I Ni Valuc, ug/l Result, ug/l Filo # %Rceovory Aooeptanoo +_10% Pass —Fail L—.L ) Pb Value, ug/1 Result, ugl) File # %Recovery Acceptance . Pass --Fail Sb Value,ug/1 Result, ug/l File# %Recovery Acceptance +10% a -- i Se Value, ug/1 Result, ugA File # %Recovery' cceptance A +_10°ie Pans-- fll L_LL__� Sn Value, uejl Result, ugA pile # %Recovery Acceptance +10% ass --Fail L-LC_) TI Value, ug/l Result,ug/1 File %Recovery ( Acceptance +10% Pass ---Fail L__1L_� V Valfug(I Result, ugN File # %Recovery Acceptance +10% ass --,Fail L 1 C ] Zn Value, Result; U.0 File # °io Recovery Acceptance ass ... Fail Value, ugA I Result, ug/I File 9 I %Recovery Acceptance I nn. ass --Fail 11/06/2008 13:56 9102056380 CSX ENV HAMLET PAGE 06/10 ZCPIMS INITIAL QUALITY CONTROL ))ate ol'Analysis Detection Limit Standard: Analyst Initials! X. d Value, ug/I Result, ug/1 File # %Recovery Acceptance : Pass ---Fail Al Value, ug!1 Result, awl File # %Recovery Acceptance ass--- F ' ( +25% L_U....1 As Value, ug,A Result, ug/) File # %Recovery Acceptance ass--- ai z o I.SGf 11Gt R3 +25yo �1 Ba Value, ugh , Result,ug[l - File %Recovery Acceptance Pass ---Fail 1L_f= ( - o ) 1.1g8 r[�� -T1 +25% Be Value, ugil Result, ugll File # % Recovery Acceptance Pass ---Fail ( ) +25% r ) ( ) Ca Value, ug/I Result, ugll File # '/o Recovery Acceptance Pass --Fail { ) ) +25% Cd Value,ugrl Result,ug/I File A! %Recovery Acceptance Pass ---Fail { 4?_ ) 9, 7c12 116 3 13 +_25% ( ( ) co Value, ugA Result, ug/1 File # %Recovery Acceptance ass --Fail . ( —) +25% ( ) ( ) ; Cr Value, ug/I Result, ug/1 File '11G31 %Recovery Acceptance Pass •-,Fail ( 2.0 ) 2 . lod +25% Cu Value,ug/1 Result,ug/I File %Recovery Acceptance Pass --Fail ( ) +25% L__ L_ 1 Rg Value, ugA Result, UgA File# %Recovery Acceptance ass --Fail 1 ) +25°% (.—) L—) K value, ugA Result,ug/l File# %Recovery Acceptance Pass —Fat ( ) +25% L) I ) g Value, Ud11 Result, ugA File # %Recovery Acceptance ass --Pail ( ) ) +25% Value,ug/I Result,ug/I File# %Recovery Acceptance Pass --Fail +25% f 1 lit) Value, ug/I Result, ug/1 File # %Recovery Acceptance ( ) ( ) +25% { ) ( ) 1\ 11i Value, usA Result,ug/I File# %Recovery Acceptance pass --Fail { )L +25% L_____) Pb Value,ug/1' Result,ug/I File# %Recovery Acceptance Pass--- Fail Sb Value, ug/I Result, uw] Pile # %Recovery Acceptance Pass ---Fail ( ) ( •+25% J 1 L_� Se Value,ug/I Result,ug!I File# %Recovery Acceptance Pass ---Pail ( ) +25% 1L1 Sn Value, ug/J Result, cgll File # Recovery Acceptance Pass ---Fail { )C +_25% x1 Value, Uel Result,ugll File %Recovery Acceptance Pass--- Fail ( ) ( +25% (—) ( ) V Value,ugll Result,ug,'1 File %Recovery Acceptance Pass --- Fail ) ( +25% I L( ) r/- n /J Value, ug/l Result, kiwi File # %Recovery Acceptance Pass ---Fail ( ) +25% " ( ) U Value, ug/) Result, ugn File # % Recovery Acceptance . Pass ---Fail ( ) ___) ±25% E= 11/06/2008 13:56 9102056380 CSX ENV HAMLET PAGE 07/10 ICPIMS ' INITIAL QUALITY CONTROL Date of Analysis: la ! 7 Lb— Analyst Initials: GmG Interference Check Standard "A": Ag Result,ug/1 _ v. 11 S ) File# 1169 RL 5.0 ug/i Acceptance <RL Pass— ' • 6s'�., •cy r rZ.9 'v. K,w TV __�, Result, ug/1 Yr ': rv':.:5�."'. w.,i4� — v�'sCnad3)xfSa.^4 File #' 1( 14°ice �.•��y���.1yyI--M�W1. 1..I R RL sUg1 q VA 1 JUr..GFIi•�-t'�:I••~�PI: Acceptancem 9L ,��lai`:r _ L'''• i i P — ail A S B2 Result, ugh O,ku7 File 1( 1G I ) RL •10u9/1 Acceptance• gtL Pass— ' C Result, ugn V.03.5 File /(_ ILA ) RL 1-oug/1 • Acceptance QtL ass-- a'l Ca .:nr-i:r•.r.y .Resultugh ( p. 36 $r •) � x-y R, 1.0 ug/l ..,`ur:i?r Acceptance :5n . •i. : ISJ— S ,n File I(^ i L 5 ) Cd Co Result, ug(1 ( O. Y s:- File #, ( 1 r 6y ) RL low Acceptance -StL, pass --- Fall Cl Result, ug/1 File # RL 20.7/c Acceptance Pass— ail Cu Result, ugh ( y, 11 3 ) File # !( 1 G9 ) RL 10 ug/l Acceptance <RL Pass ---Fail g Result, ugil ( O. a41 ) File # ( IlC9 ) RL 0.2ugl1 Acceptance <RL ass —Fail (✓f ( ') Y�• 9.1 � "'°_aa�''r, � I^L^ e., u't'.{'�s `" I'.'°�"°'"'�Cm�m'£ Nil ? '"^`t�'as;ta � I lG—'— i'7,aa"P' E•°"am tea. w � a '•ems ".� b,:'f i'i!jSJT"M rAi�iS av ^r .uc z..:x • �: •i3P,�.,.i3aj'rtiu�.�IxC'fb' .',S.�ra:. ;P:•.^n 'caAa' kxli"suS. r z :: , i i1 . 21.t .�....r� `.. q.�. `��...�Ja•-L'e•.i-e:a.:, 'l a�UaFe�Y. yY�"' y'Z4p "k. [•!•p'a'..A Mn Result, ug/l ( !f, G 3 , ) File H ( ![G�/ ) RL 1c ugn Acceptance :5RL Pass —Fail f ) mo Ni w` s Result, ug/1 File # ( !. 4 3v ) , tt /G9) b RL l0 u2A 2 Acceptance <_RL Yar?''4 rvt• `t ass --Fail PbResult, JC ugh ( o. 227 ) Pile # ( r/L9) XL sugh Acceptance QtL- s--Fai f �CL---) �+� Result:ug/l File.0 RL Acceptance Paste Se Result, uo ( p, 211 ) File.4 1( /Vq--) RL lougil Acceptance <RL Pass --Fa' J ✓�( �' Reault,ug/l �. ) File# . ( !./C• 9) RL 100 ugtl Acceptance <_RT, Pass ---Fail x+� Result, ugA File k Ljl�f RL Acceptance 'RL — ai . v Result, ug/1 ( - 0, 00 Z ) File # (,1G i) RL 40 ug/1 Acceptance f L Pass --Fail f n Result, ug/1 File 4 P.L Acceptance Pass-- Fail 11/06/2008 13:56 9102056380 CSX ENV HAMLET PAGE 08/10 ICP/MS INITIAL QUALITY CONTROL Date of'Analysis, Interference Check Standard "A-•$": Analyst Initials: Gam,✓ Ag Value Result ugh File %Recovery Acceptance Pass —Fail (2Dtip�1) ( ZO,f�)lUI ) ±20% AS Value Result, ugA File # %u Recovery Acceptance gae »- s' (20 ng/l)' ( o. mo3/I ) ±2054. C C(� Value Result, ug/l File # % Recovery Acceptance Pass -.Fail (20 ug/1) ( Z 1, G 53) ( 117.0 ) ( t o & ) +20%• j --I-L-� Co Va_ve Result, ug/1 File # % Recovery Acceptance Pass —Fail (20 ug4) 1176 ) ! U 9 . ±20% Cr Value Result, ug/l File # % Recovery Acceptance Pass --Fail (20 ugQ) ( 3 f, dGa ) 11 76 ( / / ) ±20% (- i( 1 Cu Value• Result, us/1 File # % Recovery Acceptance Pass ail (2o ugfi) ( Z :• 9/,t) (. 11 }D ) ( (! D ) ±,,20% Mn .Value Resole ug/l Pile # % Recovery Acceptance Pass —Fail (20 Vol) (_ Z (. p° 5) ( 1170 a ) ( toy ) +_20% L -4 ( j NJ Velue Result, ug/l File 6 %Recovery Acceptance Pa -Fail (20 ugfl) f Z Z. ?8 8') ( 1 I �'O } ( 112 ) ±20% r/-n Value Result,ug/1 File# %Recovery Acceptance Pass - a7 .0 (20 ugA) U. 77i ( 117 6 } ( /Gy ) ±20% 11/06/2008 13:56 9102856380 CSX ENV HAMLET PAGE 09/10 ICP/W ONGOVG QUALITY CONTROL Date of Analysis: !a / 7' /- o� Analyst Initials:. i ' Di eatedlfethodBlmk /P-3 Yaluy UgQ 0.0 acmu'ugA' /03 l FileP 1/91.f ' RL Acceptance Pass--Fai <RI seooddswrcoDi wtedLcS (0 3 Value, nga 2S•d Result,ugfl z 4Fo Toe /I $� %Recover 9 a( Ataofance' pass—Fei +13% Digested Matrix Spike Splice Amouo4ng11 , ( zS a Sxnplc Name: G5>( .i!/P Spike Rew1r, •Jl ( � 3. -UT Semple )R.wx.gA ( U, 123 ) File # r /10 ) %Recovery C 9 ) - A=mtence ±20%(WW) ±30%(DUI) Pass—Fti1 C-�"U r:lc rr r 6 %l fi Client M# N Loc4mCode: wou seraph Result, ugA FRO # Dde: /D - / Digested MS Da Beata lfl Spice Amoent, uSA , d I Spike PeUR, Uol.- ZNe! File# l f 8V %Recovery q Aceeotmee + -S Foss —Fail '. Acceptaace Pass—Fai S ike D�.t licate Results RPD C10% / ! Digested Wth9d Bluk Yalue,ug0 0.0 I Result,ug/1 D. 371 Foe# 8 RL I o Aeeaotmeo Pass —Fail <RL . Second Scarce Di cd LC9. 1D3 Yalue,vgA Rees:+, u#1 'L �. .�S� Fib# h %acoovcry 9a Aoeeotmea • +fi% Pea Fail Digested Matsiv, SA. Spilce,Amowa, ugJl (. Z �� /1 1 Sample Name: GSX Spike ResuU,v ( 2%z07 ] Sample Rt4,okugA ( 7-dG9 ) Sample ReTsuo ( 2. ti ] File# (,• //9b 1. F:fe't` ( i-L-r-0 File# ( ! 1 4( ) %Recovery ( $!/ ) (m2iltaace pass. -Fail L-i-t—, ±20V.Cw !) ±30%(DW) . Clientm.' !/ Location Code: bye 4 Detc: /D -/ Digested rYlS Du Gvate Rl 8p0ee Amount, ugA (7c Spit R.wR, ug4 237 File/ 11 v? °h Rerovery p m � pis—Fal S c Duplicate Recallsl) RPD Acuptwom RPD <20% Pau -•Fail C Di ested Method Bleak/D' Vatnc, uy9 0.0 Reran, UPI ©, dd`% FRO v3 P.L I Acecotallee Pass—Fml � <aL Second Source Di tAcdLCS value, UO isid ) Rauh, ug'1 -e, . ; 3 File# 195 % ? aRecovery tmce pans• --Pail ✓f +15-A DigWedMaldz SPike Spin Amount, uZA ( '2� Y', I/ Sample Name: C fY8 Spike Result, ugA ( ^l'Z.dVB ) Sample Rasul u9A ( v,oy5 ] Samylo Resokug/l ( D• vY ) FRO ( /I E,Y ) %Recovery ( 9Z ,j Ameutmee PM.--Fas1 +20Yo(Ww) ±30%(DW) J'ale A� (!gG File# ( l!`/( ') Client ID# Hf location Coda: I. v y Date: Id --I Dig,ated MS Du llaate kl Spike Amon.} ugA '2 0 - Spice Rttult,ugj 7. Irq a File - Y %Recovery ( Q Z Acmunce Pass —Fail . L 0% S eDu licale Results Rp� Acceptance RPD<20% Pass---Fa11 C Digested Method Blau$/0-3 Veluc, u8A 0.0 Resukugfl -^o.d4Z File# f!Y RL A¢e,�Wice Pass —Fail <RL Seomd Source bi e¢ed LCS (d�� YaW<,ugl t0 Result, up/1 23 73� ,File# 11 H5" °/a aeoovcry A=mtmee pas --Fail Digeslcd Mataz Spice Splice Amouol, USA Sample Name: Spike & ll. uSA r SampleRmXugA SzvepleResult,ugil File # r:/e � Filed %Recovery Aceeatmce Fass.-Fail L'(� ±�O./.(wvr) ±30%(DV)) Cliaut,ID9 y Locadas Cede•. Date: Po_ Digested MS I)U licatefil Spike gmouy1�1g11 2 S' Spice Rewlt,ugA Z I , File# 119 %Recovery Sr7 Aco"Unce Pas —Fail +20% S 1ka lA1 licats Ran17t9 RPD ( Aamoma RPD <20•!° I Pass —Fail 11/06/2008 13:55 9102056380 CSX ENV HAMLET PACE 10/10 ICPIW - ONGOING Qr)ASd.TX CONTROL Date ofAugysis: 10/ 7/•6rg Analystbitials: . ,m,,e 6 ' Di eiod Moil od Blade// va1ae,up/1 0.0 Rcsalt, vsA d. 1Sf! Foie# 1183 RL 1r Ao°eetmcg Pam —Fail <RL Sewed Source A' .ed LCS Vatic, Uj�i 7 i0 Resale wo 23 4D Fib )I !r %Recovery Acce Aonce• +15% Fass—Faa Digestea Vatrix Space Spike Amauut, me ( 2 S�•D� SampleNeme: Spike Result, ueJ1 � C Z i BO ) Semple Resu(t,ugll Samyk Result ag/1 (. a, rr3 t File ( u88 ) !•Nca+^ Fiie# Wit %Recovery ( �fS ] Ace ce ±20%(WW) ±30°.b(DW) paso—Fa L_�L, - Client II7# H Location Code: I;,,oaf Date: 10- DigestedMS Iicete0l Splice Amawt, ugll 2SrU Spike Result, vifl" 2 !a i3! File# 1 S %Recovery Accevimee Foss —Fail '. +20% RPA Spike DuplicatcXt=alts r Acceptance RPD<10°h Pau--Fu7 Digested Method Blank. Value,ugn 0.0 Result, up/1 Filo# RL Accanhnce Pass —Fail <RL Sccoud Soveee 'sated LCS Value,usa Result, ug/1 EBB %Recovery AcceMsece pus —Fail • +150,6 Digested Motaix, Spike Spike Amount, ugq ( ) .Sample Name: Spika ResuNuVl ( 1 Sample Result, ugll Sample Result 167 ( ) File ( ). 9/.Recovery ( ) Aeeeoteuce pass —Fall Lj C—) ±20%Mw) +30%(DW) pp rrrm/+- File # ( ) Client 1D# (,ucelioat Code: bate' Digested Me Dmlicale#1 SpikeAmoant, me Space Result ugR File# %Reeoveay Aeeeotmce + 0% Fass--Ful ' ' S ike Do LealeRaeolts RPD Aeccptauce RFD<20% Pans --Fait Ai °d Method Hlaak Value, ugl 0.0 Resultugfl File ( RL ( .Aectoemce Pass ---Fail <RL Second S.=.Di tstedLC5 Value, ugn R=Nug/1 File °k Reemary Acee±w, Pass —Fail ) +15% Digested Mullis Spike Spike Axaoaat me Sample Neme: Spikc Resultup/I Sample Resin; up/1 Sample Raw%uWl File# �� / art' File# . oh Recovery Actmtaeee Pass --Fail L.-) L..) tyo%(WW) ±30°/a(DW) Cheat 1D4 LamtiaLiAde: Date• agested S licale#1 eAauouut, agd Spikz Resukvgfl File# °ib Recovery ) Aceeotsnce Pass —Fail .+20% ' S' cDu iwte Resuts RFD A=ptance RPDe20% Peat Ful Digested Method Alank Veluqug7 0.0 ResuR, ug/1 File# RL Acceptance Pass—Faa <RL • Second Souse Di estad LCS Value, usa Result, upll i Pile# 4'°Rocovery Ac000aaoe Pass--paa +15% Digested Metric: Space Spike Amount, ugA ( ) SomAoName:, Spaw Resvlt,ug+lc f _ 1 Saoaple Result,ugA ( ) Sample RssvltvpJl File# ( ) %Recovery ( ) Aaoeotanm pas&—Ful L.:)'L-) ±20%(P1W) 430%(DW) • ha1m7F� File# ( ) C1;eot11]# [.oeaiioo Code: Da . Digested MS Du Iawte#1 Spaca Amount, agll Space Resvttue •Filth! %Izeeovery Be Paas—Fai] + Ya S ace Duplicate Results RFD Acmep * e RPD <20°/a pass. -.Fail 11/06/2008 13:50 9102056380 CSX ENV HAMLET PACE 01/07 [Erpw rnrmmi@2 ale b(owmW911@0 CSX TRAIISPORTATION (RPIM ST) MIKE MGORY 173 CSX DRIVE HAMLET ,NC 28345 PARAMETERS Nitrate Nitrogen, m9/1 Total Organic Carbon, ug/l Total pissolved Resldae, mgn Arsenic, mgA Sarum, mg/t Cadmium, mgfl Total Cbromium, mg/l Lead, mg/l FpAF. Am*sls Method Date Analyst Code 1.08 10[01/08 ANO EPA353.2. 10.49 10/06/08 SEJ SM5310C 112 10/06/08 TRB SM2540C 0.006 10l13/08 CMS SM3113B 0.022 10/03/08 LPJ EPA200.7 *0,001 10/09/08 CMP $N131130 <0.005 10/10/08 LFJ EPA200.7 <0.005 10/08108 CMF SM3113B ID#: 4 B DATIi COLLECTED: 09/29/08 DAT7; REPORTED IO/15/OB R]MIEWED BY: A- - a LeboratoryAna.Wes — Environmental Consultants . r m N m R4 w J F a 2 z W UX) U m M M u� N m m t+i ti Cn1i11Dr3a1ent 1, Inc. P.O. B07¢7US3-T)4 Oakmont Dr. Grecnvi lie, NC 279SR CHAIN OF CUSTODY RECORD Page I of 1 Phone (252) 756-6208 • Fax {252} 756-0633 llNINFEC11ON CHLORINE NEt1TRNJZED ATCOLtEC1I0N CHLORINE CH / `P y pHCHECK&M CLIErgm 4B Week: 40 ElUV CSXTRANSPORTATION(HAMLET) f—i P P P CONTiINERTYFE.PIG MI,$E GREGORY NONE L.J 173 CS%DRIVE FIA1.ii.ETNC29345 .. ❑ A C A A CHENIICALPRESERVAT04 A•NONE D-NAOH (910)205-6379 E LLr zz N B-HNO, E•HCL u7 ;0 C•HSD, F•ZINCACETATE COLLECTION 03 ¢ , o ¢ o y z 00 H a rK i G-NA71-1109J1-FRTE SAMPLELOCATIDN DATE TINE DAY q 9.fi0 4 �s `-•,� CLASSIFICATION: WASTEWATER{NPDES) DRINKNGINATER I� DWQ+GW SCLLDWASTESECMN CHAIN OFCUSTDDY MAINTAINED DURING SHIPMENTIDELIVERY N SAMPLES ODLLECTED BY {Please Pdnq L- .r v SAMPLES RECEIVED INLABAT 1. 7 'C R U H BY(SIG.) PLEB) DATE/TME RE BY G. D.ATSTNE COryMEW& 7/4mn I I EL ISHEDBY( ) DAT&RIVIF RECEIVED BY a) TEIRME RRMIIISHEDBY(SIG) DATE/RME RECEIVEDBY(IG.) DATE TIME Instrucfions for completing this form arson the reverse side. Sampler must place a'G forcompodle sample ora'G" for Na 16 8 7 2 6 ....... Grab sample in the blocks above for each parameter requested. 11/06/2008 13:50 9102056380 CSX ENV HAMLET PAGE 03/07 CSX QA/QC DATA SUMMARY FACILITY: Ilaralet SAMPLE DATE: 09/29/08 SAMPLE LOCATION: DAF PARAMETER: Nitrate Nitrogen Duplicates RIM = 2.4 % (acceptable value is < 14.75%) Quality Control Standard Recovery = 106.0 % (acceptable value is 85-115%) Blank Value = 0.00 mg/I PARAMETER, Total Organic Carbon Duplicates RPD = 0.0 % (acceptable value is <10,84%) Quality Control Standard Recovery = 101.8% (acceptable value is 85-115%) Blank Value = 0.00 mg/1 PARAMETER: Total Dissolved Residue Duplicates RPD =1.5 % (acceptable value Is <6.15%) *Quality Control Standard Recovery = 96.6 % (acceptable value is 90-100%) Blank Value = 4.0 mg/l * Value reported for required quarterly QC standard. RPD (Relative Percent Difference) Quality control data for individual metals analyses is attached on the following pages. 11/06/2008 13:50 9102056380 CSX ENV HAMLET PAGE 04/07 TEST: A GRAPIUME FURNACE - INITIAL & ONGOING QUALITY CONTROL Date of Analysis: /0 l £C / 08 Analyst Initials: Blank Check Value, ugq ( 0.0 ) Result, Egli - S x- Sequence# G RL 'r Acc lance Pass —Fail < RL Initial Calibration Verification Value, ugg -7. d Result, ugq zY, T Sequence # / % Recovery Acceptance -10% PasfFail Detection Limit Standard Value, ug/l S-U Result, ug/l ,,?70 Sequence # % Recovery If Acceptance +10% P�-Fail Initial Calibration Levels Value, ug/l d.O Value, ug/1 t d Value, ug/l Id.d Value, ug/l 2 i G Value, ugll 54.d Digested Method 131ank f' Result, ug/l /, /�0 Sequence # 3y RL' Acceptance < R1', Pass --Fail . LCS (Second Source mid- =-v'0.0 Result, ug/i aS--� Sequence # 3� % Recovery /417/ Acceptance ±15% Pass —Fail Digested Spike Amount, ug/1 Matrix Spike zf:P Spike Result, ugq ( as 77) Sequence# ( 3q ) %Recovery °� Acceptance Pass —Fail +20% Sequence# Sample Name: #1 /'b.11ovin /ds Client ID# 8s3 Location Code: 6' Sample Result, ug/l (8,�y2� Date: - To Uigested MS Spike Amount, ugll D liCate;fl (zS-G Spike Result, ugJl zS:L Sequence # t!d %Recovery !v3 Acceptance Pass --Fail +20% RPD . S ike Du licate Results 2 Acceptance RPD QO% Pasail —' Di ested Method Blank Value, ugq ( 0.0 1 Result, ug/l, Sequence # RL Acceptance <RL Pass --pail Value, ug/1 LCS Second Source mid -point) Digested Spike Amount, ug/1 Matrix Spike L___) Result, ug/1 Sequence # % Recovery Spike Result, ug/l Sequence # % Recovery Acceptance ±15010 Acceptance Pass--Fhil Pass ---Fail ±20% Sample Name: lit Client ID# Sample Result, ug/l Sequence # Location Code: Date: Digested MS Duplicate Spike Amount, ug/l ( Spike Result, ugtl Sequence # % Recovery Acceptance Pass ---Fail ( ) +20% RPD 'Acceptance Pass --Fail Spike Duplicate Results RPD <20% Value, ug/l Result, uEA Sequence # RL Acceptance Pass —Fail Di ested Method Blank 0 <RL Value, ug/I Result, ug/I Sequence # ' % Recovery Acceptance pass --Fail LCS Second Source mid -point) ( ) ±15% ( ) Digested Spike Amount, ug/l Spike Result, ag/I Sequence # % Recovery _Accel3ance Pass -•-Fail ±20% Matrix Spike �� () (�_� (� U LSe Sample Name: #3 Client [D# Sample Result ug/l Location Code: Date: Digested MS Duplicate 01 Spike Amount, ug/l Spike Result, ugA ! Sequence # % Recovery Acceptance t20°A Pass ---Fail RPD Acceptanca Fass--Fail Spike Duplicate Results RFD QD% 11/06/2008 13:50 9102056380 CSX ENV HAMLET PAGE 05/07 TEST: CW GRA.PEUTE FURNACE - INITIAL & ONGOING QUALITY CONTROL Date of Analysis: to / 'I / Atlalyst Initials: C Value, ug/l Blank Check 0.0 Result, no -0•oal Sequence # 5- RL 1 Ac xptance Pass- --Fail ) <RL Value, ug/l initial Calibration Verification i 2,Sv Result, ug/l zc.5? Sequence # a %Recovery 10S Acceptance +10% Pass --Fail Detection Limit Standard i Value, ug/l 1, a Result, ug/l Sequence # %Recovery Acceptance F10% Pass ---Fail Initial Calibration Levels Value, ug/1 ( o •V Value, ugA /• o Value, ug/1 z. f Value, ug/l 4 o Value, ug/l r Digested Method Blank R/I !e-� Value, ug/I 0.0 Result, upll -O, 06 Sequence # RL 1 Acceptance < RL Pass --Fail 44 &-c . LCS (Second Source mid -point Value, ug/l 2. so Result. ug/) 2, s-no Sequence # 7� °/a Recovery /4c Acceptance ±I 5% Pass ... Fail (✓f Digested Matrix Spike Spike Amount, ug/l 2,Sd Spike Result, ug/l tYN Sequence # ( u z ) % Recovery / z .Acceptance Pass --Fail (_j (__) ±200/0 SampleName: Client ID# Ps-? Sample Result, ug/l Sequence # Location Code: E -o.n// ( h'1 ) Date: 9-36 . Digested MS Duplicate #1 Spike A punt, ug/l . 5` Spike Result, ugA z-Lo Sequence # S % Recovery o �q Acceptance Pass ---Fail + 0% . RPD Acceptance Pass --Fail Spike Duplicate Results z RPD <20% Value, ugA Result, ug/t Sequence # RL Acceptance Pass --Fail Digested Method Blank 0 <RL Value,ug/I RasultugA Sequence# %Recovery Acceptance Pass —Fail LCS Second Source mid- Dint +15% -Digested Matrix Spike Spike Amount, ugn (, Spike Result, uga �� Sequence # (_� % Recovery �� Acceptance Pass —Fail L) C—) ±20% Samplo Name: #2 Client ID# Sample Result, ug/l Sequence # Location Code: Date: Digested MS Spike Amount, ug/l Spike Result, u_M Sequence # % Recovery Acceptance Pass ---Fail +20% Du licate#1 1( RPD Acceptance Pass --Fail S ika Duplicate Results Value, ugh Result, ugq Sequence # RL Acceptance Pass ---Fail Digested Method Blank 0. <RL LCS (Second Source mid- oint Value, ug/1 Result, ug/l Sequence # % Recovery Acceptance +15% Pass ---Fall ( ) Digested Spike Amount, ugA Spike Result, ugA i Sequence # % Recovery Acceptance Pass --Fail Matrix Spike �� [�� i �� (_ ) ±20Y° U C-) Sample Name; #3 Client ID# Sample Result, ug/l Sequence # Location Code: Date: Digested MS Spike Amount, ug/l Spike Result, ug/l Sequence # % Recovery Acceptance Pass --Fail Duplicate 9 1 +20% RPD Acceptance Pass --Fail Spike Du licate Results RPD <20% 11/06/2008 13:50 9102056380 CSX ENV HAMLET PAGE 06/07 TEST: /IS GItAI'IRTE FURNACE - INITIAL & ONGOING QUALITY CONTROL Date of Analysis: %D / 17 / GS Analyst Initials: G�.l Value, ug/1 Result, ug/1 Sequence # Rl, Acceptance Pass ---Fail Blank Check ( 0.0 ) -a-v6rr lv 5' <RL Value, ug/1 Result, ugn Sequence # % Recovery Acceptance Pass ---Fail j Initial Calibration Verification zS.O 2 Z RG +10% Value, ug/I Result, ugA Sequence # % Recovery Acceptance Press ---Fa l ' Limit Standard Detection L S, a ,. ;: 7 Y S ) +10% Value, ug/I Value, u I Value, ug/I Value, ugll Value, u$9 Initial Calibration Levels I ( G- O Srd za-d I (5 6,d Value, ug/I Result, ug/I Sequence # RL Acceptance Pass --Fail Digested Method Blank PzOldi6 0.0 O,7G4 to ) r <RL t--Y ) Qo /d-G Value,ug/I Result,ug/I Sequence# %Recovery Acceptance Pass --Fail LCS Second Source mid -point) (Z f-O Z!0 z !I /d'o Digested ' Spike Amount, uel Spike Result, ugA E Sequence # % Recovery Acce nce Pass —Fail Matrix Spike Zr,o [ 7 t%I I ( 13 l /r0 +20% L�U) Sample Namoe: � #1 f'41"amvL M Client ID# .¢ s-? Sample Result, U&I , Sequence # Location Date: -f-30 Digested MS Spike Amount, ug/I Spike Result, uel I Sequence it % Recovery Acceptance Pass ---Fall I Duplicate #1 ( 2 r'.d V— -.12) ! �/ (US +_20"/0 (�; Acceptance - FailRPD Spike Duplicate Results RPD <00/6 Value, ugll Result, ug/I • Sequence # RL. Acceptance Pass --Fail Dipested Method Blank 0.0 <RL ) ) i j LCS (Second Source midpoint) Value, g/l Result, ug/I Sequence # % Recovery Acceptance +15% Pass ---Fail Digested Spike Amount, ugA Spike Result, ug/1 Sequence # % Recovery Acceptance Pass --Fail Matrix Spike () U_U Sample Name: I p2 Client ID# Sample Result, ugA Sequence # Location Code: U UU Date: Digested MS Duplicate 9 1 Spike Amount, 119/1 1 Spike Result, ug/1 Sequence # %Recovery -Ay&aWa Pass ---Fail RPD Acceptance Pass --Fail Spike Duplicate Results RPD <20% ) ( ) Value, ugh Result, ugA Sequence# RL Acceptance Pass ---Fail Di estedMethodBlank 0.0 eRL ) LCS Second Source mid -point) Value, u9/1 Result, ug9 ) Sequence # ( ) % Recovery 1 Acceptance +15°!0 Pass ---Fail ( ) Digested Spike Amount, us/1 Spike Result, ug/I Sequence # % Recovery Acceptance Pass ---Fail Matrix Spike Sample Name: #3 Client ID# _ Sample Result, ug/I Sequence # ' Location Code: Date: Digested MS Dt Spike Amount, ug/1 Spike Result, ug/l _L Sequence # L %Recovery Acceptance Pass ---Fail d RPD Acceptance Pass ---Fail Spike Duplicate Results ( ) RPD QO% ( ) ( ) d71 d'JI L0/40 3ltld 13lWVH Na %SJ BBE950ZBL6 05=ES B08L/90/ii 11/06/2003 13:53 9102056380 CSX ENV HAMLET PAGE 01/02 GREENV.ILLE, N.C. 27835-7085- 756-0633 CBS WRAr18PDRTATION (HAMr.6T) MITE GREGORY 173 CSX DRSVE HAMLET ,NC 28345 DAF Analysis Wthod PARAMETERS Date Analyst Cade Nitrate Nitrogen, mgA 0.87 10/27/05 TWA EPA353.2 Total Organic Carbon, mgfl 13.16 10/20/08 SET SA45310C Total Dissolved Residue, mgA 14 10/16/08 THE SM2540C Arsenic, mg/1 0.005 10/24/08 CMF SM3113D Barium, mg/l 0.024 10/20/03 LPJ EPA200.7 Cadmium, mgll <0.001 10/21/08 CMF SM3113D Total Chromium, mgfl <0.005 10/20/08 LFJ EPA200,7 Lead, mgA . <0.005 10/20108 CN7 M, 113B ID$: 4 B DATE COLLECTED! 10/15/08 DATE REPORTED : 10/27/08 REVIEWED EY: OL Laboratory Analyses — Environmental Consultants R m m N m m N m Fnviroamen( 1, Inc It 4 Oakmont Dr. r.,PP�,.anP n1c��usa CHAIN OF CUSTODY RECORD Page I of I ----------------------- 131S(NYISCT10N CHLORINENEUTRALIZEDATCOLLECTION Planne. (252)756-67A8 - Fax (252)756-06.13 CITLURINE CLIENT: a 13 Reek: 44 UII pH CHECK (LAB) P P P P CONTAINERTYPEXIS CSX TRANSPORTATION (ELA6ILM NONE AnIKE GREGORY 173 CSX DRIVE - A A CHEMICALPBESERVATION BAN= NC 28345 — - - A C A -NONE D-NACH Z05•6379 w z z 9(91U) , - z � B -HNO, E•HCL �o �m z 0•H7S0, F-ZINCACETATE COLLECTIGN O F i�O- a El F � a m o „ N G-NATHfOSULFM- SMdFLELOCATKJN DATE TIME DAF b $ a 4 "< CLASSIFICATION WASTEWATER(NPDES) ORWINGWATER DWMW SOLIDWASTESECTION - CHAIN OF GUSTODYMAINTAINED DURING Sf ktJENT1DELIVERY V N SAMPLES COLLECTED BY: (fleasePretl) ! DS SAMPLES RECEIVEO IN LABAT-0 RF1J DBY(SI6.) LER) DATEITINIE RECEI BY, G DATEMME C0MMENTS: RELIT ISHEDBY(W.) E RECEIVED (SIGs) 0ATF151ME RELWUISHEDBV(SIC,) 09-OTIME RECEIVED BY (SIG.) DA711 E Instructions for compleling [his form are on the reverse sde. Sampler must place a-C" for composite sample or a V (ot N e j 7 4 1 1 U Fonra ns Grab :ample in the blocks above for each Qarameler requested. V 1 FFA'f -�VDTRANSPORTATION 2QOB SIXI Water Street - ]275 Jacksonville. FL 32202 EREC0IALOFACE)359-3457 Jerry LCatoREM,t (FAX) 904) 359-3457 ` Supervisor Environmental Control August 19, 2008 File. 9613703 North Carolina Department Of Natural Resources Attn: Information Processing Unit Division Water Quality 1617 Mail Service Center Raleigh, North Carolina 27699-1617 Dear Sir or Madam: Permit No. W00000601 Richmond County CSX Transportation Inc (CSXT) Hamlet NC Attached in triplicate, is the second triennial 2008 Ground Water Monitoring Well Analyses, as specified by Condition 4 of the referenced permit. On August 19, 2008, at 10:30 am, I notified Ms: Joan Snyder (910-433-3333) Division of Water Quality concerning our groundwater monitoring results. Laboratory analyses showed Monitoring Well # 7, had a Chromium result of 0.085 mg/L, which exceeded the groundwater quality standard of 0.05 mg/L. The pH results, for MW2, MW3, MW4, MW5, MW7 and MW8 are all below the standard of 6.5 SU. Due to the dry conditions at this facility, Monitoring Well # 1 and Monitoring Well # 6 did not have samples pulled for analyses. If you have any questions or comments, please contact me at (904) 359-3457. 'ato Enclosures RECEIVED AUG 2 2 2008 Information Processing Unit DWQIBOG Ci W-59A COMPLIANCE REPORT FORM Permit # Cc) n aoiCYiG O / • (Submit one each monitoring period with GIK59 forms.) I Enter date monitoring results were due. (R-,W-OR) Will this monitoring report (GW-59 and GW-59A) YES NO be submitted after the established due date? i Was any required information missing on the CW-59 report forms? YES NO V IF the answer to question f or 2 is 'YES", list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. 3 Are any or the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES NO identification plate, area overgrown, etc.)? Ifthe answer is "Yes", contact the Regional bfcejorguidance. V 4 Are any monitored constituents equal to or above the established standards? YES NO If the answer to question 4 is NO', skip to section B. If the answer to question 4Is "YES"list the affected wells individually with constituent(s) and concentration(s) exceeding standards in the space provided below: Alum5er 7 1 C�Myniom U.085 fhy/L 5 For the constituents identified In question 4 above, have standards been exceeded previously for the YES NO same constituent(s) In the same well(s) In the last two years? ✓ If the answer to question 5 is "NO", skip to section 8. If the answer to question 51s "YES", list In the space provided below, each well with constituent(s) exceeding standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years). Nvrn4r. 71 Chvcm,'vm D.�lli1 rn7/L 3-34-0T I Are the monitoring wells listed in section 5located at or beyond the review boundary? YES NO If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells maybe Improperly located; contact the Regional Office. 7 Is the permittee implementing previously approved actions required by the Division involving this YES NO groundwater quality problem? If the answer to question 7 is "YES", describe those actions in the space provided below. If the answer to question 7 is "NO", contact the Regional Office within 90 days: an evaluation may be required to determine the Impact the waste disposal system is having at the review and compliance boundaries surrounding this facility. Failure to do so may sublect the permittee to a Notice of Violation fines, and/orpenalties. g The person completing this portion (GW-59A) of the monitoring report should sign below and submit this form with GW-59 forms for required wells to the address provided at the fop of the current GW-59 form. I hereby acknowledge that the atic ve Informeilon was evildated and tk-eelaformaifon submittea�th)s � report ( GW-59A) the of pile it is.true and comphito to best rtiy know eq ignature of rmittee ( Authorized Agent) Dale CW-i9,\ 121ROW NuHMIT FORM ON AONITORING77 ONLY Facility. Name CSX Transportation - Hamlet Wastewater Treatment Facility Facilty Address 173 CSX Drive Hamlet, NC 2i - County Richmond Contact Person: MIKE GREGORY Telephone #: (910) 205-6379 Well Location/Sity Name: see location map No. of Wells to be Sampled: 8 Well Identification Number (From Permit): MW-1 SysFor teGroundwater Treatment Well Depth 53:75 ft. Well Diameter. 4.0 in. ms Check One: Influent (98) Screened Interval: ft. to ft. Depth to Water Level ft. below measuring point. =+ Effluent (99) Measuring point (M.P.) is: _ fL above land sum,,, Relative M.P. Elevation in ft.: Gallons of water pumped/bailed before sampling: Date Sample Collected Field Analysis: pH Specific Conductance uMhos Temp. _ ° C Odor Appearance PARAMETERS: (Samples for metals were collected unfiltered _X_ YES COD mgn Coliform: MF Fecal / loom[ Coliform: MF Total / 100ml (Note: Use MPN method for highly turbid samples) Dissolved Solids Total mgn PH (when analyzed) units TOC mg/I Chloride mgn Arsenic m9 A Grease and Oils Phenol Sulfate Specific Conductance Total Ammonia _ TKN as N GW-59 Rev. 03/2000 mgn mgA mall Mhos mail mgA PERMIT #: EXPIRATION DATE: November 30, 2009 Non -Discharge WO0000601 UIC NPDES TYPE OF PERMITTED OPERATION BEING MONITORED i Lagoon Remediation: Infiltration Gallery f Spray Field Remediation: Rotary Distributor Land Application of Sludge X Other Monitoring Well NOTE: Values should reflect dissolved and collaidal concentrations Date Sample Analyzed Laboratory Name: ENVIRONMENT 1, INC Certification No. in — NO and field acidified _X_ YES NO) Nitrite (NO2) as N mgA Nitrate (NO3) as N mgA Phosphorus: Total as P mgn Orthophosphate mgn At - Aluminum mg/I Ba - Barium mg/I Ca - Calcium %—g Cd - Cadmium 08 mgn Chromium: Total b �� P� Cu -Copper _mgA tocess mgA Fe -Iron �ole�vl 3BmgA Hg - Mercury mgn K - Potassium mgn Mg - Magnesium mgA Mn - Manganese mgn A. Gerhanlstin, Director N[ - Nickel mgn Pb - Lead mgA Zn - Zinc mgA Ammonia Nitrogen mgA Other (Specify Compounds and concentration units) ORGANICS: (GC, GC/MS, HPLC) (Specify test and method#. Attach lab report) Report Attached? Yes_([) No_(0) VOC method # = VOL; method#= VOC method # = ironmental Systems and Title - Please or Agent) DATE SUBMIT FORM ON YELLOW ONLY BRING 1, c. F i C Facility Name Hamlet Wastewater Treatment Facility Facility Address CSX Transportation, Box 191A Highway 177N _ Hamlet, NC 28345 County Richmond Contact Person: M. L. GREGORY (910)582.4901 Well Location/S)ty Name: Location Map Attached Well Identification Number: MW-6 Well Depth: 48.35 ft. Well Diameter: 2.0 in. Screened Interval ft To . Depth to Water Level _ft. ft. below measuring point Measuring point is ft above land surface Gallons of water pumped/bailed before sampling: Field Analysis pH Specific Conductance T PARAMETERS: For Groundwater Treatment Systems Check One: ti Influent (98) ® Effluent (99) uMhos emp. C Odor Appearance PERMIT M EXPIRATION DATE November 30, 2009 Non -Discharge Wg0000601 UIC-------- NPDES _ — -- TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon _ Spray Field _ _ Rotary Distributor _ X Other Monitoring Well Remediation: Infiltration Gallery Remed)ation Land Application of Sludge NOTE Values should reflect dissolved and collaidal. concentrations Date Sample Collected Date Sample Analyzed Laboratory Name ENVIRONMENT 1, INC Certification No. 10 (Samples for metals werecollected unfiltered,_)_ YES NO and field acidified _X_ YES CO mg/I Coliforrn: MF Fecal / loom, Coliforrn: MF Total / loom[ (Note: Use MPN method for highly turbid samples) Dissolved Solids Total mgfl pH (when analyzed) units TOC __.. Chloride Arsenic mg/I Grease and Oils mg/I Phenol _ mg/I Sulfate mg/1 Specific Conductance Mhos Total Ammonia mg/I TKN as N mg/l NO-2 as N -NO 3 as N Phosphorus: Total as P Orthophosphate At - Aluminum Ba - Barium Ca -Calcium IRV Cd- Cadmium t Chromium: Total—�� Cu - Copper Fe - Iron Hg - Mercury K - Potassium Mg - Magnesium _ Mn -Manganese mg/I mg/1 NO) Ni - Nickel mg/I Pb - Lead mg/I Zn - Zinc mg/l Ammonia Nitrogen mg/I Other (Specify Compounds and concentration units) ORGANICS: (GC, GC/MS, HPLC) (Specify test and method #. Attach lab report) Report Attached?Yes_(,) No_(0) VOC : method # = VOC : method # _ Cad A. Gerhardstein, Ditector Environmental and Title - GW-69 Rev. 4/98 igna ure 'ootttee (or print or 1 ON YELLOW PAPER ONLY Facility Name Hamlet Wastewater Treatment Facility Facilty Address CSX Transportation, Box 191A Highway 177N Hamlet, NC 28345 County Richmond Contact Person: M. L. GREGORY (910)582139 Well Location/Sity Name: Location Map Attached Well Identification Number: MW-8 Well Depth: 57.18 fL Well Diameter: 2.0 in. Screened Interval ft To ft. Depth to Water Level 45.9 ft below measuring point Measuring point is tt above land surface Gallons of water Pumpedibailed before sampling: Field Analysis pH 5.4 Specific Conductance uMhos Temp. _ eC Odor Appearance For Groundwater Treatment systems Check One: Influent(98) 0 Etfluent(99) 5.4 PARAMETERS: (Samples for metals were collected unfiltered _X_ YES CO mg/I Coliform: MF Fecal / 100ml Colifonn: MF Total / 100ml (Note: Use MPN method for highly turbid samples) Dissolved Solids Total 130. mg/I PH (when analyzed) I units TOC 2.12 mg/I. Chloride mg/I Arsenic <0.005 mg/I Grease and Oils mg/I Phenol mg/I Sulfate mg/I Specific Conductance Mhos Total Ammonia mg/I TKN as N _ mg/1 PERMIT M EXPIRATION DATE November Non -Discharge W00000601 UIC NPDES -- TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon _ Spray Field _ Rotary Distributor _ % Other _Monitoring Well Remediation: Infiltration Gallery Remediation Land Application of Sludge NOTE Values should reflect dissolved and collaidal concentrations Date Sample Collected 07/09/08 Date Sample Analyzed 07/14/08 Laboratory Name ENVIRONMENT 1, INC Certification No. 10 NO and field acidified _X_ YES NO) NO-2 as N mgll NO-3 as N 9.96 mg/I Phosphorus: Total as P mg/I Orthophosphate mg/I AI - Aluminum mg/I Ba - Barium 0.048 mg/I Ca - Calcium mg/I Cd - Cadmium <0.001 mg/I Chromium: Total 0.031 mg/I Cu - Copper mg/l Fe -Iron mg/I Hg - Mercury mg/I K - Potassium mg/I Mg - Magnesium mg/I Mn - Manganese marl t, Unfit lnfotmaltoO\NQJ5O9 G Ni - Nickel mg/I Pb - Lead <0.005 mg/I Zn - Zinc mg/I Ammonia Nitrogen mg/I Other (Specify Compounds and concentraflon units) ORGANICS: (GC, GC/MS, HPLC) (Specify test and method#. Attach lab report) Report Attached? Yes_(1) No_(0) VOC : method # _ VOC : method # _ VOC : method # _ SUBMIT FOF (Q.UALITY-MONITORINGe,' EPORTFORM Facility Name Hamlet Wastewater Treatment Facility Facilty Address CSX Transportation Box 191A Highway 177N Hamlet, NC 28345 County Richmond Contact Person: M. L. GREGORY (910)582-4901 Well Location/Sity Name: Location Map Attached ON YELLOW Well Identification Number: MW-7 For Groundwater Treatmem Sy,,,m, Well Depth:_ 37.18 —ft. Well Diameter: 2.0 in Check One: Screened Interval ft. To ft ® Influent (98) Depth to Water Level 33.1 ft below measuring point ® Effluent (99) Measuring point is ft above land surface Gallons of water pumped/bailed before sampling: 1.5 Field Analysis pH 5. Specific Conductance uMhos Temp. ° C Odor Appearance PARAMETERS: (Samples for metals were collected unfiltered _X YES CO mg/I Colifonn: MF Fecal / 100ml Colifonn: MF Total /100ml (Note: Use MPN method for highly turbid samples) Dissolved Solids Total 62. moll pH (when analyzed) units TOC 2.41 moll Chloride mg/I Arsenic <0.005 mg/I Grease and Oils mg/I Phenol mg/l Sulfate mg/I Specific Conductance Mhos Total Ammonia mg/I TKN as N .....rr IntotmatioDW�BOssin9 Unit G Ca - Calcium ONLY PERMIT #: EXPIRATION DATE November 30, 2009 Non -Discharge W00000601 UIC NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon _ Spray Field _ _ Rotary Distributor _ O Other Monitoring Well Remediation: Infiltration Gallery Remediation Land Application of Sludge NOTE Values should reflect dissolved and collaidal concentrations Date Sample Collected 07/09/08 Date Sample Analyzed 07/14/08 Laboratory Name ENVIRONMENT 1, INC Certification No. 10 NO and field acidified _X YES NO) 2.07 NO 2 as N NO-3 as N Phosphorus: Total as P Orthophosphate At - Alunimum mg/I Ba - Barium 0.029 moll mg/I Ni - Nickel mg/I mg/I Pb - Lead <0 005 moil Cd -Cadmium <0.001 moll Chromium: Total 0.085 mg/I Cu - Copper - mnn Fe - Iron Hg -Mercury _ K - Potassium Mg - Magnesium Mn - Manganese moil moll Zn -Zinc moll Ammonia Nitrogen moll Other (Specify Compounds and concentration units) ORGANICS: (GC, GC/MS, HPLC) (Specify test and method N. Attach lab report) Report Attached? Yes_(1) No_(0) VOC : method # = VOC :method#= VOC : method#= SUBMIT FORM ON YE JALITY•.MONITORING ; )RTFORM Facility Name Hamlet Wastewater Treatment Facility Facilty Address C3X Transportation, Box '191A Highway 177N Hamlet, NC 28345 County Richmond Contact Person: M. L. GREGORY (910)582-4901 Well Location/Sity Name: Location Map Attached Well Identification Number; MW-5 For Gm,ndvmter Treatment Systems Well Depth:__ 52.92 ft. Well Diameter: 2.0 in. cne�ona. Screened Interval ft To ft ❑-� Influent(98) Depth to Water Level 43.2 ft below measuring point c� Effluent (99) Measuring point is ft above land surface Gallons of water pumped/bailed before sampling: 4.5 Field Analysis pH 5.2 Specific Conductance uMhos Temp. °C Odor Appearance PARAMETERS: (Samples for metals were collected unfiltered _X_ YES CO mg/I Colifonn: MF Fecal / 100ml Coliform: MF Total / 100ml (Note: Use MP N method for highly turbid samples) Dissolved Solids Total pH (when analyzed) TOC Chloride 60. mgfl units mg/I mg/I Arsenic _ <0.005 mg/I Grease and Oils mg/I Phenol mg/I Sulfate mg/I Specific Conductance Mhos Total Ammonia mg/1 TKN as N . Ml PERMIT#: EXPIRATION DATE November 30, 2009� Non -Discharge WQ0000601 UIC NPDES i TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field Remediation Rotary Distributor Land Application of Sludge X Other Monitoring Well NOTE Values should reflect dissolved and collaidal concentrations Date Sample Collected 07/09/08 Date Sample Analyzed 07/14/08 Laboratory Name ENVIRONMENT 1, INC Certification No. 10 NO and fieldacidified_X_YES NO) NO-2 as N mg/l NO-3 as N 0.83 myfl Phosphorus: Total as P mg/l Orthophosphate mg/I Al -Aluminum mg/i Ba - Barium 0.037 mg/I Ca - Calcium mg/I Cd - Cadmium <0.001 mg/( Chromium: Total <0.005_ mg/I Cu - Copper Fe - Iron Hg - Mercury _ K - Potassium Mg - Magnesium Mn - Manganese Ni - Nickel mg/I Pb - Lead <0.005 mg/I Zn - Zinc mg/1 Ammonia Nitrogen mg/I Other (Specify Compounds and concentration units) ORGANICS: (GC, GC/MS, HPLC) (Specify test and method #. Attach lab report.) Report Attached? Yes (1) No_(0) VOC : method # = VOC : method # = RECE�� 4 �E Carl A. Gerhardstein, Director Environmental Systems V Per' ter A Agent) Name and Title - Please print or Noe GW-59 Rev. 4/98 AUG 2 2 7M information Processing Unit DWOIBOG ti SUBMIT YELLOW PAPER ONLY Facility Name Facilty Address WILIAL1.1,T .MV NI I ORING::'_ PORT.FORM12 rY M � Hamlet Wastewater Treatment Facility _ CSX Transportation, Box 191A Highway 177N Hamlet, NC 28345 County Richmond Contact Person: M. L. G^ Well Location/Site Name: Well Identification Number: MW-4 " cn%r G. ,ater Treatment systems Well Depth:_ 47.45 ft. Well Diameter: 2.0 in. exone: Screened Interval ft To ft. 0 Influent(98) Depth to Water Level 36.5 ft below measuring point 5 Effluent (99) Measuring point is ft above land surface Gallons of water pumped/bailed before sampling: 4.8 Field Analysis pH 6. Specific Conductance uMhos Temp. °C Odor Appearance PARAMETERS: (Samples for metals were collected unfiltered _X_ YES CO mg/I Colifonn: MF Fecal / 100ml Coliform: MF Total / 100ml (Note: Use MPN method for highly turbid samples) Dissolved Solids Total pH (when analyzed) TOC Chloride 81. mg/l units 1.95 mg/I Arsenic <0.005 - mg/I Grease and Oils mg/l Phenol mg/I Sulfate mg/I Specific Conductance Mhos Total Ammonia mg/1 TKN as N IntormahpWagp� in9 Unit PERMIT M EXPIRATION DATE November 30. 2009 Non -Discharge WQ0000601 UIC NPDES -- TYPE OF PERMITTED OPERATION BEING MONITORED _ Lagoon Remediation: Infiltration Gallery Spray Field Remediation _ _ Rotary Distributor Land Application of Sludge X Other Monitoring Well NOTE Values should reflect dissolved and collaidal concentrations Date Sample Collected 07/09/08 Date Sample Analyzed 07/14/08 Laboratory Name ENVIRONMENT 1, INC Certification No. 10 NO and field acidified _X_ YES NO) NO-2 as N mg/l NO-3 as N 2.4 mg/I Phosphorus: Total as P mg/l Orthophosphate mg/l Al -Aluminum mg/I Ba - Barium <0.01 mg/I Ca - Calcium mg/l Cd - Cadmium <0.001 mg/I Chromium: Total <0.005 mg/I Cu -Copper _ Fe - Iron Hg - Mercury mg/1 K - Potassium mg/i Mg - Magnesium mg/l Mn - Manganese mg/1 Ni - Nickel mg/I Pb - Lead <0.005 mg/I Zn -Zinc mg/I Ammonia Nitrogen mg/l Other (Specify Compounds and concentration units) ORGANICS: (GC, GC/MS, HPLC). (Specify test and method A Attach lab report) Report Attached?Yes_(1) Nc_(0) VOC : method # = VOC : method # = VOC : method # = SUBMIT FORM ON YELL PAPER MONITORING- 2M Facility Name Hamlet Wastewater Treatment Facility Facility Address CSX Transportation, Box 191A Highway 177N Hamlet, NC 28345 _ County Richmond Contact Person: M. L. GREGORY (910)582-4901 Well Location/Sity Name: Location Map Attached Well Identification Number: MW-3For Gmondwater Treatment Systems Well Depth:__ 45.70 ft. Well Diameter: 4.0 in, check one: Screened Interval ft To ft. Influent(98) Depth to Water Level 40.8 ft below measuring point. Effluent (99) Measuring point is ft above land surface Gallons of water pumpedibailed before sampling: 3.9 Field Analysis pH 5.8 Specific Conductance uMhos Temp. _ ° C Odor Appearance PERMIT M EXPIRATION DATE November 30, 2009 Non -Discharge W00000601 UIC NPDES - TYPE OF PERMITTED OPERATION BEING MONITORED I Lagoon Remediation: Infiltration Gallery Spray, Field Remediation Rotary Distributor Land Application of Sludge R Other Monitoring Well NOTE Values should reflect dissolved and collaidal concentrations Date Sample Collected 07/09/08 Date Sample Analyzed 07/14/08 Laboratory Name ENVIRONMENT 1, INC Certification No. 10 PARAMETERS: (Samples for metals were collected unfiltered _X_ YES NO and field acidified _X_ YES CO NO) mg/I100ml Coliform: MF Fecal / Coliform: MF Total / 100ml (Note: Use MPN method for highly turbid samples) Dissolved Solids Total 43. mg/I pH (when analyzed) units TOC 1.33 mg/I Chloride mg/l Arsenic _ <0.005 mg/I Grease and Oils mg/1 Phenol mg/I Sulfate - mg/1 Specific Conductance Mhos Total Ammonia mg/I TKN as N .....rr GW-59 Rev. 4/98 RECENE,U AUG 2 2 JQU InfonnaboOnwQIoress BOGin9 Unit NO_2 as N mg/l NO-3 as N 1.77 Phosphorus: Total as P —mg/I mg/I Orthophosphate mg/I AI -Aluminum mg8 Ba - Barium 0.011 m911 Ca - Calcium mg/I Cd-Cadmium <0.001 mg/l Chromium: Total <0.005 mg/1 Cu -Copper mg/I Fe -Iron mg/1 Hg - Mercuy mg/1 K - Potassium m9/1 Mg - Magnesium mg/l Mn - Manganese mg/I Ni - Nickel mg/I Pb - Lead <0.005 mg/I Zn - Zinc —mg/I Ammonia Nitrogen mg/l Other (Specify Compounds and concentration units) ORGANICS: (GC, GC/MS, HPLC) (Specify test and method #. Attach lab report) Report Attached?Yes_(1) Nc_(0) VOC : method # = VOC : method # _ can A. GerhardStein, Director Environmental and Title - / DATE SUBMIT FORM ON YELLOW PAPER Facility Name Hamlet Wastewater Treatment Facility Facilty Address CSX Transportation, Box 191A Highway 177N Hamlet, NC 28345 County Richmond Contact Person: M. L. GREGORY (910)582-4901 Well Location/Sity Name: Location Map Attached Well Identification Number: MW-2 rorcmwavater 7reahnenl Well Depth: 41.48 ft. Well Diameter: 4.0 .in. rhack One. Screened Interval ft. To _ft. ® Influent(98) Depth to Water Level 36.5 ft. below measuring point. 0 Effluent (99) Measuring point is ft. above land surface Gallons of water pumped/bailed before sampling: 7.8 Field Analysis pH 5.2 Specific Conductance uMhos Temp. - C Odor Appearance PARAMETERS: (Samples for metals were collected unfiltered _X YES CO mg/I CoIifonn: MF Fecal / 100m1 Coliform: MF Total / 100ml (Note: Use MPN method for highly turbid samples) Dissolved Solids Total 103. mg/I pH (when analyzed) units TOC 3.31 mg/I Chloride mg/I Arsenic <0.005 mg/I Grease and Oils mg/I Phenol mg/I Sulfate mg/I Specific Conductance Mhos Total Ammonia mg/I TKN as N __11 In(ormaGoOn'�gOGin9 Unit sync: PERMIT #: EXPIRATION DATE November 30, 2009 Non -Discharge W00000601 UIC NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery _ Spray Field � Remediation _ Rotary Distributor Land Application of Sludge X Other. Monitoring Well NOTE Values should reflect dissolved and collaidal concentrations Date Sample Collected 07/09/08 Date Sample Analyzed 07/14/08 Laboratory" Name ENVIRONMENT 1, INC Certification No. - NO and field acidified _X_ YES NO) NO-2 as N mg/I NO-3 as N 3.19 mg/I Phosphorus: Total as P mg/l Orthophosphate mg/I AI - Aluminum mg/I Ba - Barium <0.01 Ca - Calciummg/I —mg/I Cd- Cadmium <0.001 mg/I Chromium: Total <0.005 mg/I Cu - Copper Fe - Iron Hg -Mercury K -,Potassium Mg - Magnesium Mn - Manganese mg/I mg/I mg/I Ni - Nickel mg/I Pb - Lead <0.005 mg/I Zn - Zinc mg/I Ammonia Nitrogen mg/I Other (Specify Compounds and concentration units) ORGANICS: (GC, GC/MS, HPLC) (Specify test and method A Attach lab report) Report Attached? Yes_(1) No_(0) VOC : method # = VOC : method # = VOC : method # = DATE , IDO: 4 CSX TRANSPORTATION -(HAMLET) MIKE GREGORY 173 C8X DRIVE DATE COLLECTED: 07/09/08 HAMLET. ,NC 28345 DATE'REPORTED : 07/21/08 REVIEWED BY. MW-1 MW-2 MW-3 MW4 MW-5 Analysis Method • PARAMETERS Date Analyst Code i PH (field measurement), Units Missing 5.2 5.8 6.0 5.2 07/09/08 RJH SM450ORB Nitrate Nitrogen, mg/l Missing 3.19 1.77 2.40 0.83 07/11/08 TWA EPA353.2 Total Organic Carbon, mg/1 Missing 3.31 1.33 1.95 2.30 07/10/08 SEJ SM5310C . Total Dissolved Residue, mg/1 Missing 103 43 81 60 07/10/08 TRB SM2540C Arsenic, ug/l Missing <0.605 <0.005 <0.005 <0.005 07/15/08 CMF SM3113B Barium, no Missing <0.010 0.011 <0.010 0.037 07/14/08 LFJ EPA200.7 Cadmium, no Missing <0.001 <0.001 <0.001 <0.001 07/14/08 CMF SM3113B Total Chromium, ug/1 Missing <0.005 <0.005 <0.005 <0.005 07/14/08 LPJ EPA200.7 Lead, ug/l Missing <0.005 <0.005 <0.005 <0.005 07/17/08 CMF SM3113B Static Water Level, feet Missing 36.56 40.83 36.50 43.21 07/09/08 RJH Water Balled, Gals. basing 7.8 3.9 4.8 4.5 07/09/08 RJH [EM09 9M@0 alp DIM@Up@T(Iq@d CSX TRANSPORTATI MIXE GRHGORY 173 C8X DRIVE HAMLET ,NC 28345 (HAMLET) ID#: 4 DATE COLLECTED: 07/09/08 DATE REPORTED : 07/21/08 RHVImnm BY.4 KI - MW-6 MW-7 MW-8 Analysts Method PARAMETERS Date Analyst Code PH (Held measurement), Units Missing 5.0 5.4 07/09108 RM SM4500HB Nitrate Nitrogen, mg/l Missing 2.07 9.96 07/11/08 TWA EPA353.2 Total Organic Carbon, mg/l Missing 2.41 2.12 07/10/08 SEJ SM5310C Total Dissolved Residue, mg/l Missing 62 130 07/10/08 TRB SM2540C Arsenic, ug/1 Mussing <0.005 <0.005 07/15/09 CMF SM3113B Barium, ug/l Missing 0.029 0.048 .07/14/08 LFJ EPA200.7 Cadmium, ug/i raging <0.001 <0.001 07/14/08 CMF SM3113H Total Chromium, ugd Missing 0.085 0.031 07/14/09 LFJ EPA200.7 Lead, ug/l Mis8h:g <0.005 <0.005 07/17/08 CMF SM3113B StaticWater Level, feet Missing 33.12 45.98 07/09/08 RJH Water Bailed, Gals. Mussing" 1.5 5.4 07/09/08 RJH Sz. ��t}. 'ar t4� "- i �ai7Afdi ,anai Shp �nvrrb men atGAAsv)t � t �3`i� - s.z; } ca �� e,43 11/06/2008 13:46 ' 9102056380 CSX ENV HAMLET PAGE 01/07 [ 1@wW1@H@)1W alp EinupopO CSX TRANSPORTATION WMLET) MIHS GREGORY 173 CSX DRIVE HAMLET ,NC 28345 ID#-. 4 B DATE•j,.CO1.LE0ED TBD. 08/�26 J�,08 DATE REPORTa 09/05/OB REVIEWED BY: AAF Analysis Method PARAMEURS Date Analyst Code Nitrate Nitrogen, mg/l 0.15 oa/27/08 TWA EFA333.2 Total Organic Carbon, mgll 24.24 08/29/08 SFJ SW310C Total Dissolved Residue, mgll 223 09/02/08 TRB SM?540C Arsenic, mg.0 0.006 09/03108 CMF SM3113B Barium, mg•.q 0.022 08/28/08 LFJ EPA209.7 Cadmium, mgn <0.001 09104/08 CAW SM31130 Total Chromium, mgtl a0.005 09/28/08 LFJ EPA200.7 Lead, mg/l <0.005 OS/28108 ClY1F _ SM3113B Laboratory' Analyses = Environrr)ental Consultants i EnvLbnment 1, Inc. CHAIN OF CUSTODY RECORD P.O. Boz 7085, 114 Oakmont Dr. Pab 1 of 1 Greenville, NC 27958 CHLORINE NEIITAALVt�DAT COlLEC710N r �ISINFECTIOCt Phone (252) 756-6208 •Fax (252)756-0633 I - CHLORINE CLIENT: 46 W �. pHCHECK"B) UV CSX TRANSPORTA77ON(EfAMR) P P P NONE g OONTAINERNPE, PlG WKE GREGORY A CHEMICALPRESERVAMN 173 CSX DRIVE A C A HAMLET NC 25345 A -NONE D-NAOH E (910) 205-6379 u� B • HNII, E-HCL - ¢ 4 F•711,I0ACETATE ' ;OI.LECTION U rn :3 _ G-NATH1OSlRFATE tz F a SMWLE UrATION IIPdE a CLASSIFICATION: u?ATE DAF 3Q 4 2fp b - WAMMMER(NI'OESi DMGW LDR14KINGWATER SO LID WASTE SECTION GHAIN O� CUSTODY MAINTAINE0 URING V N SAMPLES COLLECTSDBN, nECEIVED Irstract ons for completing this form are on the reverse side. SAMI'LESRECEIVEDPJLABATO�to _'C COMMENTS: sampler must place a'V for composite sample are `G" far o 2 0 0 r:,an c rnnla in the blacks above for each parameter requested. n X rn =C b� r D CD N 1 m J 11/06/2008 13:46 9102056380 CSX ENV HAMLET PAGE 03107 CSX QA/QC DATA, SUMMARY FACILITY: Iiamlet SAMPLE DATE: 08/26/08 SAMPLE LOCATION: DAF PARAMETER: Nitrate Nitrogen Duplicates RPD = 0.0 % (acceptable value is < 14.75%) Quality Control Standard Recovery =105.0 % (acceptable value is 85-115%) Blank Value = 0.00 mg/1 . PARAMETER: Total Organic Carbon Duplicates RPD = 2.6 % (acceptable value is <10.84%) Quality Control Standard Recovery=101.1% (acceptable value is 85-115%) Blank Value = 0.00 mg/1 PARAMETER: Total Dissolved Residue Duplicates RPD =1.8 % (acceptable value is <6.15%) *Quality Control Standard Recovery — 96.6 % (acceptable value is 90-100%) Blank Value = 7.0 mg/1 * Value reported for required quarterly QC standard. RPD (Relative Percent Difference) Quality control data for individual metals analyses is attached on the following pages. 11/06/2008 13:46 9102056380 CSX ENV HAMLET PAGE 04/07 Bottle# Semple Name 47 oltentlDB Looelion Code ICP Ongoing Quality Control 1000 . t it092 I qu.6ce C 461 11/06/2008 13:46 9102056380 CSX ENV HAMLET PAC£ 05/07 TEST: Js -- --- GRAPHITE FURNACE - INITIAL & ONGOING QUALITY CONTROL Date of Analysis. �% / ? / �S Analyst Initials: cm6 Blank Check Value, ug/I 0.0 Result, ue/i 0.7/ Sequence # '^ RL 5' Acceptance Pass ---Fail idl ) <RL initial Calibration Verification Value, ug/I ZSa Result, ug/I PY Sequence # g % Recovery ( 99 Acceptance .+10'/c Pass --Fall Detection Limit Standard Value, ug/I S.0 Result ugA N.l6.2 Sequence # 7- %Recovery q9 Acceptance ±10% Pass Fail f ) Initial Calibration Levels Value, ugn a, 0 Value, ug/I. S• o Value, ug/1 -(-La .a Value, ug4 z r,9 Value, ug/l Value,ugn Result Sequence RL Acceptance Pass --Fail Di ested Method Blank P--lP 0. -d.y�G �a 9� <RL dr- p_Zp Value, ugl. Result, ug/l Sequence # %Recovery Acceptance Pass —Fail LCS Second Source mid -point) yr, a ZG.Za // /as- 4-15% ---f Digested Spike Amount, ug/I Spike Result, ugll Sequence # % Recovery Acceplanc- Pass --Fail ±20% Matrix Spike 75.0 ' Z( RG�/) ( l3 ) I( u ) �✓j'�) Sample Nam.te: #t Ts.i /2ne�'�o y7� • Client ID# 13o I Sample Result, ug/l Sequence # Location Code: Si/z Date: 9-75' Digested MS Spike Amount, ug/l Spike Result, ug/I Sequence # % Recovery Acceptance Pass --Fail I Duplicate 41 ( 7f xG 9 / N /08. ±20% --r( ) RPD Acceptance Pass —Fail Spike Duplicate Results 7 ) RPD QO% Value, ug/1 Result, ug/l Sequence # RL Acceptance Pass --Fail D�ested Method Blank ( 0.0 ) <RL ( ) LCS Second Source mid- int Value, ugq ( Result, ug/I Sequence # %Recovery Acceptance +15% Pass --Fail Digested Spike Amoum ug/1 Spike Result, ug/I Sequence # % Recovery Acceptance Pass —Fail Matrix Spike ±20% f Sample Name: #2 Client IW Sample Result, ug/1' Sequence # Location Code: Date: Digested MS Spike Amount,ug/I Spike Result,ug/I Sequence #, %Recovery Acceptance Pass --Fail Duplicate 41 ) +20% RPD Acceptance Pass --Fail Spike Duplicate Results ( RPD QD% ) Value, ug/I Result, ug/1 Sequence# RL Acceptance Pass --Fail Digested Method Blank ! 0.0 ( ( <RL Value, ugll Result, ug/1 Sequence # % Recovery Acceptance Pass ---Fail LCS Second 5ouroe mid- Dint +IS% ( ) Digested Spike Amount, ug/1 Spike Result, ug/l Sequence# %Recovery Acceptance Pass --Fail Matrix Spike U (� ( 1 C� ±20% U ( ) Sample Name: I93 Client ID# Sample Result, ug/1 Sequence # Location Code: Date: Digested MS Spike Amount, ug/I Spike Result, ug/I Sequence # % Recovery Acceptance Pass ---Fail Du licate#1 +20% RPD Acceptance Pass —Fail Spike Duplicate Results RPD <20% 11/06/2006 13:46 9102056380 CSX ENV HAMLET PAGE 06/07 TEST: CW GRAPHITE FURNACE - INITIAL & ONGOING QUALITY CONTROL Date of Analysis: �1�1 Analyst Initials: G'lrf _ Blank Check Value, ugn 0 Result, ug/l —O-Dir `Sequence # RL 1 Acceptance Pass .-Fail <RL Initial CalbrationVerifcation Value, ugn 7,i0 Result, ug/l .-)if Sequence # � % Recovery it Acceptance ±101/. Pass --Fail Detection Limit Standard Value, ugA !.6 Result, Udl I•� Sequence # % Recovery /C� Acceptance +10% Pass-yFail "( Initial Calibration Levels Value, ug/I O Value, ug/l 1• d Value, ugA 2 Value, ug/l u Value, ug/l Value, ug/l Result, ug/l Sequence # RL Acceptance Pass ---Fail Digested Method Blank Mew { _ Q O 1 � A.GS y `I I ) < RL ) Qtd g,-pd Value, ugn Result, ugA Sequence # % Recovery Acceptance Pass --Fail LCS Second Source mid -point) ( sp .?7 /O lug +15% ✓f Digested Spike Amount, ug/l Spike Result, ugn Sequence # % Recovery Acceptance Pass-- Fail ±20% Matrix Spike •Z, sti Z ) ( RO ( ) Sample Name: #1 (� %nr %Jital /!C•Q ! �"� Client ID# / 30l Sample Result, ugA Sequence # , Location Code: sT/ z ( q 071) ( I! ) Date: B=Zr ' Digested MS Spike Amount, ug/l Spike Result, ugn Sequence# %Recovery Acceptance Pass ---Fail LDu licato#1 ( 'z iD /ac' ±20% RPD L Acceptance Passs---Fail Spike Duplicate Results RPD-20% ' `. ) Value, ug/1 Result, ugA Sequence # RL Acceptance Pass --Fail Digested Metbod Blank mo <RL j Value,ug/1 Result,ug/l Sequence,# %Recovery Acceptance Pass —Fail LCS Second Source mid- pint +15/0 Digested Spike Amount, ug/l Spike Result, ug/l Sequence # % Recovery Acceptance Pass --Fail Matrix Spike ±20% L) Sample Name: Client IDN Sample Result, ug/l Sequence if Location Code: Date: Digested MS' Spike Amount, ug/l Spike Result, ug/1 Sequence # °/a Recovery Acceptance Pass ---Fall Du licate#I _+20% ( ) RPD Acceptance Pass — Fail Spike Duplicate Results RPD Q0%a L—) Value, ujo Result, ugA Sequence # RL Acceptance Pass ---Fail Digested Method Blank 0.0 ) <RL Value, ugn Result, ug/l Sequence # % Recovery Acceptance Pass ---Fail LCS Second Source mid -point) Digested Matrix Spike Spike Amami. ug/l (!� Spike Result, ugA �� Sequence # C ] % Recovery (� Accentance Pass ---Fail (__) ±20% Sample Name: #3 Client ID# Sample Result, ug/l Sequence # Location Code: Date: ' Digested MS Spike Amount ug/l Sp(ke Result, ugA Sequence # % Recovery Acce to ce Pass ---Fail +20% D licate#1 ) RPD Acceptance Pass --Fail Spike Duplicate Results 11/06/2008 13:46 9102056390 CSX ENV HAMLET PAGE 07107 TEST: GRAPHITE FURNACE - INIM41 & ONGOING QUALITY CONTROL Date of Analysis: Analyst Initials: cmf Value, ug/1 Result, ugll Sequence # RL Accc tq ancc Pass —Fail Blank Check .0 —0./03 6 9 <RL Value, ugA Result, ugil Seqce # uen % Recovery Acceptance Pass ---Fail Initial Calibration Verification zr.O ayq $ /oo ±10% • Value, ug/1 Result, ug/1 Sequence # % Recovery Acceptance Pass —Fail Dctwion Limit Standard S.o '* 9 ±10% Value, ug/1 Value, ug/1 Value, ug/1 Value, ugn Value, ug/l Initial Calibration Levels d, o S, 6 f MA I r -1 Su•d Digested Method Blank 9,-79 Value, ugn ( 0.0 ) Result, ug/1 ( o.d Sequence # -3 RL i Acceptance <RL Pass --Fail aG g-a8 LCS Second Source mid -point) Value, ugN , ( S.O Result, ug/1 Z .B l Sequence # cl % Recovery ` r Acceptance ±1501. Pass ---Fail ' ( ✓ ,( ) Digested Matrix Spike Spike Amount, ug/l ( g S O) Spike Result, ugh ( '2 y, Sequence # ( �i ) _ '/° Recovery ( 9 7 ) Acceptance Pass --Fail (=�L-) ±20% Sample Name: Client ID# /3L/ • Sample Result, ug/1 Seq cc # I ' Location Code: T>12 Date: - Z f —AJ/ s` Digested MS Du licate#1 Spike Amount, ug/l aS.d Spike Result, ug/l 2y,n1 Sequence # % Recovery 9 Acceptance +20% Pass --Fail �( ) RPD Acceptance P� -Fail Spike Duplicate Results RPD <20% Value, ugtl Result, ugn Sequence # RL Acceptance Pass ---Fail ` Di ested Metbod Blank ( <RL ( ) Value, ug/l Result, ug/l Sequence # %Recovery Acceptance Pass --Fail LCS (Second Source mid -point) +15% Digested Spike Amount, ug/1 Spike Result, ug/1 Sequence # % Recovery' Acceptance Pass --Fail ±203/9 Matrix Spike (�� (�� �� ( ) L_) ( ) Sample Name: #2 Client ID# Sample Result, ug/1 Sequence # Location Code: Date: Digested MS Spike Amount, ug/l Spike Resell, ug/l Sequence # % Recovery Acceptance Pass ... Fail Duplicate#1 ( ( +20% • RPD Acceptance Pass --Fail S ike Du licate Results r PD < nc/a (_ ) Value, ug/l Result, ug/l Sequence # RL Acceptance Pass ---Fail Digested Method Blank 0.0 ( ( <RL Value, ug/1 Result, ug/1 Sequence # % Recovery Acceptance Pass ---Fail LCS Second Source mid - point) +15% ( Digested Matrix Spike , Spike Amount, ug/l ( Spike Result' ug/l Sequence # % Recovery Acceptance Pass -,-Fail U ( ) ±20% • Sample Name: , #3 Client 1D9 Sample.Result, ug/l Sequence # Location Code: Date: Digested MS Spike Amount, uo Spike Result, ug/l Sequence # % Recovery -A cc Pass --Fail Du licate#1 +20% ( ) RPD Acceptance Pass ---Fail Spike Duplicate Results RPD <20% 11/06/2008 13:43 9102056380 CSX ENV HAMLET PAGE 01/06 ID#: 4 B CSX TRANSPORTATION (HAMLET) MIRE GREGORY 173 CSX DRIVE DATE COLLECTBO�,�9i7�%23� HAMLET ,NC 28345 DATE REPORTED : 0810 08 REVIEWED BY: "All Analys)s Method PARAMSTERS Date Analyst Code Nitrate Nitrogen, mg/l 0.25 07/25/08 TWA EPA353.2 Total Organic Carbon, mg/I 3050 07/28/08 SEJ SY15310C Total Disoolvod Rosidaa, mgA 211 07/28/08 TRB SNU540C Arsenic, mg/I o.oll 01/31/D8 CMF SNO113B Barium, mg/l 0.021 07/30/08 LFJ EFA200.7 Cadmium, mgA <0.001 08/06/08 ChD? SN13113B Total Chromiran, wg/l <0.006 07/30/08 LFJ EPA200.7 Lead, mgll <0,005 05/01/08 CNF SWI13B ,;.>: �.. '"•"• %tatidrato'ry'Anafyses,`-, Enuirdnsliantril'Gor(sufienfs,�:'''' ..,. , . i,C� � • <n , Inc. c,114 Oakmont Dr. NC 27858 CHAIN OF CUSTODY RECORD Page I of 1 .... (252) 756.6208 • Fax (252) 756.0633 CLIENT: 4E Week: 31 CSX TRANSPORTATION WAhII.ET) MIKE GREGORY 173 CSX DRIVE E1bILET NC 28345 (910) 205.637Y CTI COLLEON DISINFECrION CHLORINE 1N NONE U CHLORINE NEUTRALIZEDATCOLLECMN � py CHECK (LAB) p p p p CONTPINERTVPE,RG A C A A CHEMCA.LPRESERVATION ' A -NONE D-NAOH B-HNO E-HCL - N C-KSO, F-ZIW ACETATE G-NATHIOSULFATE a ui a�6 o rho g�g m ¢ z y G ,� SAMPLELOCATION DATE TIME DAF !9 / 4 CL SSIRCATION: WASTEWATER(NPDq DRINKING WATER DLWklib'! ' SCUD YVASTE SECTION - - CHAIN OF CUSTODY MAINTAINED DURING SHIPMENTIDELIVERY N SAMPLES COLLECTED BY: (PI a Pri115 SAMPLES RECEIVED84LABAT „I"�Z.°C T031 B'f(SIG. PL£R) DATEgM 2 RECEIVED (S DATSMME Z f / COMMENTS: CUISHEDBY(SIG.) ATERME RECErZFBY( IG DA[EfnME REONOUISHEDBY(SIG) DATEfIME RECEIVED Of (Sri) DATEIOME - rse side. Sampler must place a"C-for composlie sample ora'G' for Instructions for completing this form are on She roveJ o170222 n_. k .... kin IM 4J..�Le e6nen In. neeb mn &.r row,e I.H D A 11/06/2008 13:43 9102056380 CSX ENV HAMLET PAGE 03106 CSX Q.A,/QC DATA SUMMARY FACILITX: hamlet SAMPLE DATE: 07/23/08 SAMPLE LOCATION: DAF PARAMETER: Nitrate Nitrogen Duplicates RPD =1.2 % (acceptable value is < 14.75%) Quality Control Standard Recovery =108.0 % (acceptable value is 85-1150/9) Blank Value = 0.00 mg/1 PAPUMETER: Total Organic Carbon Duplicates RFD = 2.0 % (acceptable value is <10,84%) Quality Control Standard Recovery= 101.1% (acceptable value is 85-1150/6) Blank Value= 0.00 mgll PARAMETER: Total Dissolved Residue Duplicates RPD = 0.7 % (acceptable value is <6.15%) *Quality Control Standard Recovery = 96.6 % (acceptable value is 90-100%) Blank Value � 4.0 tngll Value reported for required quarterly QC standard. RPD (Relative Percent Difference) Quality control data for individual metals analyses Is attached on the following pages. n 11/06/2008 13:43 9102056380 CSX ENV HAMLET PAGE 04105 ICP Ongoing Quality Control eolAneysis. 7/30/200a Anad;t anti 1F7 I algeelc BIvNe I eua esu ,u , quen4l i. .enua �pesiffea ' 0.0000 t,3000 2 t0, _=RL ,(X1 ;6`awadS"cume OlOesteSCC$�" _._.__._Value ";"Reaull; ulyL'"-SeduZiSF@i 1 eta Recovery"_._ �CieG1a75E--� 600 473.6 3 95 +1-15°b (_X_) U ._._..__.«..—_._ ._.— :f.. ........... T._.,-._.......__.. .. 9pOce Resulta�. �xted Ma ike u I I Sequena # %Recovery H-2D%(WW1 :Passffaii 'SPYce-74nounl, 463.7 ....__... 5 ... 91 .. _ �0%low) _�( XJ..C>_ 500 i aoile Y Sample Name TARBORD _ _ _ _ 522 Client to it 304 Sem �Resul UD& , Sepumtce0 Laalbn Code. E HIM 9.DI 4 Data 7/24/2008 .._—.. .. aced >;a OMsTrCr-b'iup, - .. Spke Amnl.wugrL Opa(e nesutte, ugl Bvquanavx �6-}iosovery IPecwFau ' wo ! z°iP.- r �P 483.1, 6 95 (X 1 U 0.0000 0.6000 2 5 i « RL wand 56urce DtBesi-ed'LCS...-'9c4uEKenrT%Rwwary �A"�"aFa'rice— _ L..._.— 3 $Pike Reeulte,'-' --- Acecpianee etedMaaie9lke uP)L i SequenWY %RecoveryN-20%MM ;1 5 96 +}30%low) LI _ .._ ..__._ ._.._ OoltleS jeempk Nmne TARODRD � ,_ ...___._.__..7 522 ICl WY 304 Sam la SaqusrcsY 1 ILOiDnion Code 7/24/2008 _.,. 3.61 4_�„_ ale salad Maba 8Pkeke �� _..._.:.._. _ _ _.____. _ _..___ i SPU Amquro, uglL; �3DIIre Reside• u9)L _ _° 3equenmX 95 Recovery .. 11/06/2000 13:43 9102656300 l9( E1N HAMLET PA(3E 05/06 GRAPHITE FURNACE -INITIAL & ONGOING QUALITY CONTROL Date of Anlalyeim 7 /�L/ o fY� Analyst Ioitlela: �.•.e..a>^ Value, uyl Rwu14.9/1 Sequenced RL Aea-seas Pecs--pail Blank Check <RLncv ] Vvluq ug/1 Rwu14 VY/I Svqumcvtl %0.ecOvery Aca-spmnca ➢ass —.Pall snialvl CaliLratlan Vvificntiem Value, vg/I Reau1L up/1 Saqumm M %Recovery Accsptvnee Pasa-�Feil Datectlm Limit Sundard .O 4.1 'I. 9 +1O% Vulue,ug/1 Value, u3/ a Veluq ug/1 Value, a9fI Value, ug/1 inkier Ca1Rre[ivn 1-avers O• T.O (Y, e, 2f 4 Vvlue,uyl Revulq ug Sequenwb RL Acceptance Pee —Fail DI csted MCNoa Dtank I11 O Ti <RL - G^j-� VoluG UP/1 Rpaul4 ug/I Sequen®b ^/. Reevvary Aeeeplance Pass —Fail LCS See sM Source mle- elm -O O ! aV + Digested Slut. Amoum. nWl Saq/u3 b % Rere aeeenta Le Pea' —pin, Mona. Spike ( 7-O 30% smnPla Nome, 3-zZ a, IYI I.ocmicm Co4e ems: E^ Sa2p/Gf lull. Dete- i dY . Digested MS Spikes Amoun4 up/1 Sp kv Result. uzA Sequence b %Rcwwry Aceevionic e Paq—Pall Du tleatabl b 2O P$ ' O%. R D Acceptance Pms---Fail s iko Du Ilcem Resvin P RPD QO% Vvluq u3b Result. u0/1 Sequenen Y RL Atocp ari.. Pass --Pall Di cared Meauki Dlenk <RL Value, up/ Resulq.'/1 I Sequence 0 ACCaptmsee Pws—Fall I_LCi 6 f6econd Souses mid. In +IS% ' Ur3aated Spike Amoun4 uF/1 Spike RvaulL uw. Saquenoab %Recovery at Pa -Full 11.11. Spike f )I ( ) C 1 ( ) }20% f C_) Semple Nome: p2 Cllen[1Db i Samplu Rapulq uRll Svquvrcvtl Lomtim Cvdc ( ] ( ] Ate: DlgesW MS ' DV lieale l/I SDIka Ameun4 uP/1 .pits Result. no Segarneeb %RWOwry velars peas —Fail RPD Ac"cepPi. pass --Fail 3 ike Duplimty 0.ou1Ls RPD Q0%O?'v Value, u3A Result. ug/1 Sequma b RL Pass —Fail DI arced Mttbad Blank <RL Velu4 uP/1 "Gaup. u RecovM Aee6pmn[e Pass --ERR LCS Second svurca mix- OlnI e +'15% p Ream Spike Amvunq v I .pike Reau14.,I ao-vi ve N %Raevwry A.Cenma n Paso --Fell Mmrix Spike ( l ( 1 ( 1 ( 1 =20% C� (_) .emple Neme: N3 C l� .vpla Rosull-ug/1 Scquvpca m [ucafieatian case• ( ] i r I Dam: Dlbassed MS SDikc Ameunt. ug/( SplkO Result. ue/I sCOuonCO p W. RecOwry Accaemnae Pa66--Pall Du liwee Ml + RPD , Accepmn Pvai—Evil Spike Oa ❑cam Rwuln rRPD QO% TEST- A6 GRAPIHTE FURNAC]Z- INITIAL & ONGOlNU QUALITY CCINTROL Date ofAnalycia:�/�/08' Analyst Initials: � via ug/1 Reeuli. up/I SvqumaM M1L Aecmo Pav-..pall Olenk Cheek (—P.R C S <R�n Valve, ugA Ruul4u 1 SequenwY %RecovM Aeeeplvntt Paaa--Fail Initial Celibrailan Verificot on 2 ,o zY. t - Value, up/1 Rwul4 ug/1 6equmeea %R4CZvery A Pnm—Foil Dvtttclen Limis 6mndvd f-A. 7 9 Ipunks Value, up/I. Velue„ulyl Value, uWl Veluc,ual Vglua, uR/1 Initial Celibsatlm C S.a I!✓.[� 2 So.o Values. ug/1 Reault�p/I Seq RL ACcc ncc Pans —Fail Di cvlvd MCNod Blank - O i �Qm S yGv?a Value. uw- Reaul[. uWl SequmceY very ACcep(ence Paaa—Foil LC. Second 5ewee mkf- oral t0 (G( ♦15^0 p Recv Spike Amours , US/1 Sp ka Raaulq .0Sequa e b % Reeowry - n`P_am�---Fni j Mmrix SDlke ( ( IIY. xGI ( 13 1 L Y7 Sample NNUC "I T i! — S7a Cllenl IDM I I S.W. Resin; Jill Sequence 0 L Ion Cade: W — ( —0. 7f,c Dam. 7-3 V.Swted MS Spike Amoum, uw] . Spike Reaul4 ugb Sequen¢ N %Recovery AW...S, Paas—Fell Dc Ilwm dl s.p z i, za` 9 (iPD Amepun—A P:� Fall .,am Du Ileaty Resuks d RPD Qo% Vglue,"C Reeula, UVI Soil no. "I RL Ae.epeone. Paea—Pall pl lamd MaUaa Rlank ... <RL Value. W. Raaul4 upJ1 9equeneeM %RCcovory Acceptance Poia—FYI Seeand Sours mid- aim - +I S% _LC9 OigcaRa .pike Amoum, n2l/I SpIkR Rc6ulk uP/I BcqueneeY ( ) %Rttowry ( 1 .dS -s-e. Paea—Pail Mmin SPikv ( ] ( l "±2(Ai r U Sample Name, Y2 e11en11DN Sample Result u3/1 SequenceM i-oo.oOn Cotlo: I ( ] ( l Dnf Dlgea[ca Spike Amoun4vlyl Sp ke FtneuR, uP/I .aquenevN %Recovery Aaevlencv Pus--Feil 01 Rcam Yl Du RPD p Paea—Fail R vulu Spike Du Ikvm a RPp 40%M% a.0 Value, uWi HcniH,uyl Sequenm. RL anCo. Paso —Pa Di sited Method Blank L VYIUe, uW. Rcpula, ug/I Season N Ye Recovery toneo Pa96—Fall ,Les semna source mte- ine % D"ovee Spika Amount ug/1 Spikes Resin;-uV1 Sol,mceY ( ] %Recovery"" ( ] u P.. Pall Meni a Spike ( ) ( ) % U 3 6ompMName: N3 tA�mncc Ckanl ION Sample Reaol4 ug/1 6equmce N Lucatlgn Co..!— [ ] ( ] oat p Seated MS Spika Amoum. UO Spike Re.u14 u8/1 Sequence p % R.—r,lanee paaa•—Fail Du Ii.. MI % RPp paaa--PullS ike psi lieute Rmulta 4.% 11/06/2008 13:43 9102056380 CSX ENV HAMLET PACE 06/06 TEST: Ct � GRAPHITE FURNACE - INITIAL & ONGOING QUALITY CONTROL Date of Analysis: •L f_jL! 0 8 Analyst Initials: G. l- Value, ug/l Result, ugA Sequence # RL Acceptance Pas5 ... Fail Blank Check 0.0 (-D, sl s ! _<RL ) Value, ugA Result, ug/l Sequence # %Recovery Acceptance Pass --Fail Initial Calibration Verification 7" o 2.703 Value, ug/l Result, ugA Sequence # a R overy Acceptance P�Fail Detection Limit Standard !.0 I. CS t � � S +10% Value, ugA Value, ug/l Value, ugA Value, u9.7 Value, ugA initial Calibration Levels 01D t. Value, ugA Result, ugA Sequence # RL Acceptance Pass —Fail Di esled Method Blank We 730 ( 0.0 <RL ) 0,4 3D • LCS_ Second Source mid -point) Value, ug/1 _re2 Result, ug/l Z.?,o Sequence # o/a Recovery /!O Acceptance +15% Pm --Fall .Ji ) i. Digested Matrix Spike Spike Amount, ug/l Z, yu Spike Result, ugA 2( GyS) Sequence 0 ( ! Z ) % Recovery /d r Acceptance Pass —Fail ±200/0 #1 Sample Name: re-. 0 s�z Client ID# 'e'oy Location Code: Sample Result, ug/I ,pas Sequence it Date: 7-21e Digested MS I Duplicate 91 Spike Amount, ugA 2 ( .5V Spike Result, ugA a,CF3 Sequence # 1 %Recovery 103 Acceptance Pass ---Fail If +20% RPD Acceptance Pail Spike Duplicate Results RPD QO% -- Vakie, u2A Result, ugA Sequence # RL Acceptance Pass ---Fail Digested Method Blank <RL Value, ugA Result, ugA Sequence#' %Recovery Acceptance Pass --Fail LCS (Second Source mid -point +15% Uigestad Matrix Spike Spike Amount, ugA Spike Result, ug/l Sequence # % Recovery Acceptance ±20% Pass —Fail C—) (_) Sample Name: #2 Client JD/1 Sample Result, ug/1 Sequence # Location Code: Date: Digested MS Spike Amount, ugA Spike Result, ug/l Sequence # % Recovery Acceptance past --Fail Du licate#I ( +20% RPD .Acceptance Pass ---Fail Spike Duplicate Results RPD <20% ) Value, ug/1 Result, ug/I Sequenced RL Acceptance Pass ---Fail Digested Method Blank ! 0.0 <RL I Value, ug/l Result, ugA Sequence # % Recovery Acceptance ,Pass ---Fail i LCS Second Source mid -point ( +150/ ( ( ) Digested Matrix Spike Spike- Amount, ug/i Spike Result, ugA Sequence ii a/a Recovery Aeceytaoce Pass --Fail Sample Name: #3 Clioni ID# - Sample Result, ugA Sequenced Location Code: Sequence # Di gesled MS Date: Spike Amount, ug/l Spike Result, ugA % Recovery Qecainance Pass --Fail Duplicate #1 ( +200/. RPD Acceptance Pass ---Fail Spike Duplicate Results RPD 1<20% Envirv,---.71j, Inc. P.O. Box 7085, 114 Oakmont Dr. Greenville, NC 27858 CHAIN OF CUSTODY RECORD Page 1 of 1 r DRIVE OAY ON HAMLET NC 2045 ■ • ©©®©©■®■■■■■■■■■ • ■ NOW • �� 1 =MGM � � on NOMINEE ow b ".4 La wa on a W. y� 11 ■MINWWWu> w ■■■■MINE■ ' =1`f MMEEMIN MME■EMMM■■E .�•.. •• 1 ' ■■■■■MEM■■MEEE■■NE■E■ NNO■EEIN■EEnMEMM�MMNME r Instructions for completing this form are on the reverse side. Sampler must place a "C" forcomposite sample or a "G" for FOAM 05 Grab sample in the blocks above for each parameter requested. N ° 169998 CSX QA/QC DATA SUMMARY, FACILITY: Hamlet SAMPLE DATE: 07/09/08 SAMPLE LOCATION: DAF PARAMETER: Nitrate Nitrogen Duplicates RPD = 0.0 % (acceptable value is < 14.75%) Quality Control Standard Recovery =104.0 % (acceptable value is 85-115%) Blank Value = 0.00 mg/1 PARAMETER: Total Organic Carbon Duplicates RPD = 09 % (acceptable value is <IU4%) Quality Control Standard Recovery= 98.6% (acceptable value is 85-115%) Blank Value = 0.00 mg/l PARAMETER: Total Dissolved Residue Duplicates RPD = 2.0 % (acceptable value is <6.15%) *Quality Control Standard Recovery = 96.6. % (acceptable value is 90-100%) Blank Value = 0.0 mg/1 * Value reported for required quarterly QC standard. RPD (Relative Percent Difference) Quality control data for individual metals analyses is attached on the following pages. wi— Ongoing Qualfty Control ate of Analysis 7/14/2008 Analinn Initials LIFT aw Digested Method Stank Value RewulL ug/L Sequence 0 RL Acceptance Pass/Fal 0.0000 7.5000 34 10 c RL _xj 'Sewnd Source Digested LC3F Value ReveL ugg- SequenceW Recovery Acceptance Pais! 500 479.8 35 96 -/.16% UU Upme Kasults._—_Acceptance Bested MabrbK Was uWL Sequence# % Recovery 4/- 20 % MM TaBsilal SpIko Amount, ugA 5.20.5 93 +1- 30%.(D)9 LXJ 500 some IF S=pW Name MnWCN 286 !Cllwt 10 0 169 'Sample Result, UgJL ence Iocailon Coda WL17 57 . 31 --38 ...... i. Data 7/9/2008 Bested Moorbt Spike Dup ug/L Spike Results, ugA. Sequence 0 Recmrery PWBJFW 500 017 502.5 40 89 LX-) I— RPD Acceptance <20% Pass) 'Digested Method Blank Value Resul% upt 0.0000 1.2000 Sequence 0 i 34 RL 5.0 Acceptance <o RL Pass/Fail LX-) Li Second Scarce Digested LCS Value RewAL ug/L Sequence N % Recovery Acceptance Pass/Fall 500 485.7 35 97 +1-15% LX-) U — ---------- vpwmaura.. F -Add-wwg�e— —.- ... also Matfix Spike uwL S, equence # % Racmuiry 20 % ANW) Posaffiall Spike Amourl. ugA 480.8 39 96 +1- 30% (13vi) LYJ U BM...... Boggs 0 Sample Name wilwom 286 :Cgerd too 169 :Sample Res?3 U91 Sequenceif Location Coda WL17 1.4 38 Date WW20178 ug/L �p�,a R till. Sequonce# %Raccreery .'Pass/Fag 5w 463 40 93 LX-) L-) I iP� nce,4,2,0%, Pass/Fag TEST: CW GRAPHITE FURNACE - INITIAL & ONGOING QUALITY CONTROL Date of Analysis: 7 / /y/D8' Analyst Initials: sy,G Value, ug/1 Result, ug/l Sequence # RL Acceptance Pass --Fail Blank Check • 0.0 o,OG2 .ram 1 <RL Value, ug/1 Result, ug/l Sequence # %Recovery Acceptance Pass ---Fail Initial Calibration Verification Z. f3/ lol +10% ( Value; ug/l Result, ug/l Sequence # %Recovery Acceptance Pass- -Fail Detection Limit Standard /.O /, orb l//7 ±10% Value, ug/l Value, ug/l Value, ug/I Value, ug/1 Value, ug1l Initial Calibration Levels d• /% 1, D Z• S SO Value, ug/l Result, ug/l Sequence # RL Acceptance Pass --Fail Digested Method Blank Win.4 (--Q.0 —O• /Bo I ) <RL y��Q(� p y LCS Second Source mid- pint Value, ug/l Z SO Result, ug/l Z•?8a Sequence # �y % Recovery qS Acceptance +15% Pas�ail ) Digested Matrix Spike Spike Amount, ug/l 2.5-P ,Spike Result, ug/1 z•F B7 Sequence # • % Reco ery 95 Acceptance ±20% Pass ---Fail #1 Sample Name: LUr4 ion ZPG Client 1D# i 6 y Sample Result, ug/l Sequence # Location Code: wG/7 Date: A-9 —0•0 / Digested MS I Du licate #I Spike Amount, ug/l d Spike Result, ug/1 Yo Sequence # % Recovery 94; 1 Acceptance +20% Pass --Fail ) RPD Acceptance Pass ---Fail Spike Duplicate Results ( / I RPD Q0% r Value, ug/l Result, ug/l Sequence # RL Acceptance Pass ---Fail Digested Method Blank 0.0 <RL ( I_LCS Value, ug/I .Result, ug/l Sequence # % Recovery Acceptance Pass ---Fail Second Source mid -point) +15% Digested Spike Amount, ug1l Spike Result, ug/l Sequence # %Recovery Acceptance Pass --Fail Matrix Spike �) Sample Name: C_� L� �� ±20% (_) C—) #2 Client ID# Sample Result, ug/l Sequence # Location Code: Date: Digested MS Spike Amount, ug/l Spike Result, ug/1 Sequence # % Recovery Acceptance Pass ---Fail +20% Duplicate 01 ) RPD Acceptance Pass —Fail Spike Duplicate Results RPD <20% Value, ug/1 Result, ug/l Sequence # RL Acceptance Pass --Fail Di ested Method Blank ( 0-0 1 ) I <RL LCS (Second Source mid -point) Value, ug/1 Result, ug/l Sequence # %Recovery Acceptance +15% Pass --Fail Digested Matrix Spike Spike Amount, ug/1 Spike Result, ug/l Sequence # % Recovery Acceptance Pass --Fail C__) C_) +20% Sample Name: #3 Client ID# Sample Result, ug/l Sequence # Location Code: - Date: Digested MS Du licate #I Spike Amount, ug/l Spike Result, ug/l ) Sequence # % Recovery Acceptance Pass ---Fail +20% RPD Acceptance Pass --Fail Spike Duplicate Results RPD Q0% r TEST: Pi GRAPHITE FURNACE - INITIAL & ONGOING QUALITY CONTROL Date of Analysis: 7 / / -9' / 41 g Analyst Initials: c�W Blank Check Value, ug/1 ( 0.0 ) Result, u 1 —a. IP Sequence # G RL f Acceptance Pass ---Fail _<RL InitialCalibrationVerification Value, ug/1 Z .O Result, ug/1 z2.L2 Seque�tce # %� % Recovery Yd ) Acceptance +10% Pass ---Fail Detection Limit Standard Value, ug/I S. d Result, ug/I S / 361,97 Sequence # % Recovery Acceptance +10% Pass ---Fail Initial Calibration Levels Value, ug/l Value, ugA .O Value, ug/1 /O.O Value, ug/l J:d Value, ug/l sa Value, ug/1 Result, ugtl Sequence # RL Acceptance Pass --Fail Digested Method Blank U*a 7-// 0.0 -O."/ '/O ) <RL u/QG ,z-#/ Value, ug/l Result, ug/1 Sequence # % Recovery Acceptance Pass --Fail LCS (Second Source mid -point) z S,O) 2 3. Y8 W f`/ +15% ( vT Digested Spike Amount, ug/1 Spike Result, ug/1 Sequence # % Recovery Acceptance Pass --Fail Matrix Spike 25 D ' . ( 2z l4) ( y3 ) -TO ±20% ( � Sample Name: #1 W,_. wt 2'K Client ID# /G3 Sample Result, ug/1 Sequence # Location Code: trLh `O•zZ ( t/Z ) Date:. ;x- 5 Digested MS Spike Amount, ug/I Spike Result,ug/1 Sequence # %Recovery Acceptance Pass --- Fail Du licate#I ZSU 36 /Gr! 9Z ( ) _+20% RPD Acceptance Pasail Spike Duplicate Results (. z RPD Q0% Value, ug/1 Result, ug/l Sequence # RL Acceptance Pass ---Fail Digested Method Blank ( 0.0 ) ) I <RL Value, ug/l Result, ug/1 Sequence # % Recovery Acceptance Pass --Fail LCS Second Source mid -point) +15% Digested Spike Amount, ug/1 Spike Result, ug/l Sequence # % Recovery Acceptance Pass —Fail ±20% Matrix Spike (_) Sample Name: #2 Client 1D# Sample Result, ug/l Sequence # Location Code: Date: Digested MS Spike Amount, ug/1 Spike Result, ug/1 Sequence # % Recovery Acceptance Pass ---Fail +20% Duplicate #I ( RPD Acceptance Pass --Fail Spike Duplicate Results RPD <20% ) Value, ug/1 . Result, ug/1 Sequence # RL Acceptance Pass ---Fail Digested Method Blank ( 0.0 ___) < RL ( ) ( ) LCS Second Source mid -point) Value, ug/l Result, ug/l Sequence # % Recovery ( Acceptance +15% Pass ---Fail ( ( ) Digested Matrix Spike Spike Amount, ug/) Spike Result, ug/l Sequence # % Recovery Acceptance Pass --Fail C—) (_•) ±20% Sample Name: #3 Client ID# _ Sample Result, ug/l Sequence # Location Code: Date: Digested MS Du licate 01 Spike Amount, ug/1 Spike Result, ug/I Sequence # % Recovery Acceptance Pass --Fail _+20% RPD Acceptance Pass --Fail Spike Duplicate Results RPD G?0% ( ) TEST: GRAPHITE FURNACE - INITIAL & ONGOING QUALITY CONTROL Date of Analysis: Analyst Initials: G',;,! Value, ug/I Result, ug/l Sequence # RL Acceptance Pass ---Fail Blank Check ( 0.0 1 —0.3Y10 e S' <RL Value, ug/1 Result, ug/l Sequence # 0/Y Recovery Acceptance Pass --Fail Initial Calibration Verification n' 0 Z 3 OZ S q2 ±10v ✓S( Value, ug1l Result, ug/1 Sequence # %Recovery Acceptahce Pass- Fail r Detection Limit Standard (. , 0 Z/Z) +10% Value, ug/1 Value, ug/l Value, ug, Value, ug/l Value, ug/l Initial Calibration Levels ( D• U 4%D . /0:0 Zf Sod Digested Method Blank '//i -// Value, ug/l 0.0 Result, ug/l D.lv Sequence # �'if ) RL .-4" Acceptance <RL Pass ---Fail LCS Second"S rcemid-point) Value, ug/I ZSD Result, ugn Z30b seauen e # � % Recovery q2 Acceptance +_I5% Pass —Fail (� Digested Matrix Spike Spike Amount, ug/1 Z.Try Spike Result, ug/l zS• r —7 Sequence # % Recovery 103 ) Acceptance +20% Pass ---Fail ( ( ) Sample Name: #� w,- fo„ 7eS Client ID# /69 Location Code: WG/7 Sample Result, ug/l —D, 531 Sequence # Date: Digested MS Duplicate 41 u licate#I Spike Amount, ug/l �SI� Spike Result, ug/l Sequence # ,Z9 % Recovery Lo/ Acceptance Pass ---Fail ) +20% RPD Acceptance -,,,Fail Spike Duplicate Results ( a ) RPD <20% Value, ug/I Result, ug/l Sequence # RL Acceptance Pass ---Fail U� igested Method Blank 0:0 ) ) < RL LCS (Second Source mid -point) Value, ug/1 Result, ug/I ) Sequence# %Recovery Acceptance +15%. Pass ---Fail ) Digested Matrix Spike Spike Amount, ug/l Spike Result, ug/l Sequence # % Recovery Acceptance ±20% Pass —Fail (_) (_) Sample Name: #2 Client ID# Sample Result, ug/l Sequence # Location Code: Date: Digested MS Du licate#1 Spike Amount, ug/l ( ) Spike Result, ug/l Sequence # % Recovery Acceptance Pass ---Fail ( ±20% RPD Acceptance Pass --Fail Spike Duplicate Results I RPD <20% ) (_) Digested Method Blank Value, ug/l 0.0 _-) Result, ug/l Sequence # RL ) Acceptance <RL Pass ---Fail ) ( LCS (Second Source mid -point) Value, ug/l Result, ug/l Sequence # ) % Recovery Acceptance +15% Pass --Fail ( ) Digested Matrix Spike Spike Amount, ugn Spike Result, ug/l Sequence # % Recovery Acceptance Pass ---Fail Lj (_) ±20% Sample Name: #3 Client ID# Sample Result, ug/l Sequence # Location Code: Date: Digested MS Du licate#1 Spike Amount; ug/1 Spike Result, ug/l Sequence # °/n Recovery Acceptance +20% Pass ---Fail RPD Acceptance Pass --Fail Spike Duplicate Results RPD Q0% ( GW-59A COMPLIANCE REPORT FORM Permit # L4-)Q 0000 GO a• (Snbmtr one each monitoring eriod with GW 59 forms.) • fin. 1 �•,•r, _._ „,�nuunny resuiis were aue. t -t-,.rx-u61 Will this monitoring report (GW-59 and GW-59A) and be submitted after the established due date? YES NO X Was any required information missing on the GW-59 report forms? YES IF the answer to question f or 2 is "YES , list in the space provided below the well identification and explain the problems encountered in obtaining the required information. P3Arc any of the monitor wells In need of repair or maintenance (damaged casing, unlocked ormissing cap, missing dentification plate, area overgrown, etc.)? /'the answer is "Yes", contact the Regional 0jr1ce forguidance. YES NO V q 1 Are any monitored constituents equal to or above the established standards? Y S NO If the answer to question 4 Is ONO", skip to section R. If the answer to question 4 is "YES'Ilist the affected wells individually with constituent(s) and concentration(s) exceeding standards in the space provided below. r1 � ��wC�ru..aiuw.- ICr taw h:c�j�n.iuVh- o.�oa "�► L lnwLl: mtU3M - Q•d0� it�`1_ Mw l�rovn��ri-0•o�y"r Yv1W C _ 0= o L Wtw 8: No-� �sN - (o.jy„, 5 For theconstituents identified in question 4 above, hift standards been exceeded previously for the YES NO same constituent(s) in the same well(s) In the last two years? If the answer to question 5 is `NO, skip to section B. -- I "v. ur urr uYuuc i/,VI,VQVVGIVIY, ca n wen wen cunsuruengs/ exceeamg standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years). Thw V : No-3 as N r t0.48 vj/L ) ll-I' -01 -- `A Uj 8 NO_ as N) la.ct� Y.,IJL Are the monitoring wells listed In section 5located at or beyond the review boundary? YES II — drib war Is -rea", a groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO" monlioring wells may be Improperly located; contact the Regional Office. 7 Is the permittee Implementing previously approved actions required by the Division involving this YES NO groundwater quality problem? x If the answer to question 7is "YES; describe those actions in the space provided below. If the answer to question 7 is "N6" contact the Renlonal Office within 90 days• an evaluation may be re ulred to determine the Impact the waste disposal sitstem iew and com /!ante boundaries surroundingthis facility. Failure to do 'ect t o / f Violation fines. and/or aenalties. RE V E" D El MAY 0 6 2008 7ENR-FA 2 s 7008 AY 1E(TENLLEREGIONALOpryCE informati n Proc !ssing Unit WO/6 G g The person completing this portion.(GW--59A) of the monitoring report should sign below and submit this form with G W-59 forms for required wells to the address provided at the top of the current GW-59 form. I hereby acknowledge that the above Infgrmaf(oti was evaluated grid the Infomiaf(oii sutimlttea ....: f report (Compliance Report yn.thls' GW-59A) Is true and complete;to°the. best of rtiykngwlbdge Signature of Pennittee(or Authorized Agent) I Date GW-59:% im-nni SUBMIT FORM ON YELLI GROUNDWATER QUALITY MONITORING COMPLIANCE REPORT b^ FACILITY INFORMATION Facility Name CSX Transportation - Hamlet Wastewater Treatment Facility Facilty Address 173 CSX Drive Hamlet, NC 28345 County Richmond Contact Person: MIKE GREGORY Telephone tk (910) 2 55-6379 Well Location/Sity Name: see location map No. of Wells to be Sampled: 8 Well Identification Number (From Permit): MW-1 For Groundwater Treatment Systems Well Depth 53.75 ft. Well Diameter. 4.0 in. Check One: Screened Interval: ft. to ft. ® Influent (98) Depth to Water Level ft. below measuring point. ❑O Effluent (99) Measuring point (M.P.) is: ft. above land surface Relative M.P. Eievation in ft.: Gallons of water pumped/bailed before sampling: Date Sample Collected Field Analysis: pH Specific Conductance uMhos Temp. ° C Odor Appearance PAPER MAICBERVICE CENTER ".. -. '- ilGH NC 27699;, - Phone: (919)73"221 PERMIT #: EXPIRATION DATE: November 30, 2009 Non -Discharge WQ0000601 UIC NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field .Remediation: Rotary Distributor Land Application of Sludge X Other Monitoring Well NOTE: Values should reflect dissolved and collaidal co trations Date Sample Analyzed -#/Alew .54tw J 1 , Laboratory Name: ENVIRO ENT 1, INC Certification No. 10 PARAMETERS: (Samples for metals were collected.unfiltered X YES NO and field acidified X_ YES NO) COD mgA Coliform: MF Fecal / 100ml Coliform: MF Total / 100ml (Note: Use MPN method for highly turbid samples) . Dissolved Solids Total mgA PH (when analyzed) _ units TOC mgA Chloride mgA Arsenic mgA Grease and Oils R �� Phenol I/� a`mgfl Sulfate /i 2 q ���� I Specific Conduct eanc nro�o/o (Qn�_Mhos Total Ammonia Pr mgA TKN as N giB�6srnglr . mg/l '�+r— GW-59 Rev. 0312000 Nitrite (NO2) as N Nitrate (NO3) as N Phosphorus: Total as P Orthophosphate Al - Aluminum Be - Barium _ Ca - Calcium _ Cd- Cadmium _ Chromium: Total _ Cu - Copper Fe - Iron Hg - Mercury K- Potassium _ Mg - Magnesium _ Mn - Manganese mgA mgA mgA mgA mgA mgA mgA Ni- Nickel Pb - Lead Zn - Zinc Ammonia Nitrogen Other (Specify Compounds mqA mqA maA mgA concentration units) mgA ORGANICS: (GC, GC/MS, HPLC) mgA (Specify test and method #. Attach lab report) mgA Report Attached?Yes_(1) No_(0) mgA VOC ; method # = mgA VOC : method # = VOC : method # = Cad A. Gerhardstein, Director Environmental Systems Fittee.(or Auth5o¢ed Agent) Name and Title - Please print or type Signature of Pennittee (or Authorized SUBMIT FORM ON YELLOW PAPER ONLY k1l 10-11 %AUHL1 I T '1111UNI I;4LJKII4k3: E.REPORT FORM.` aILI Facility Name Hamlet Wastewater Treatment Facili FaciltyAddress CSX Transportation, Box 191A Highway 177N Hamlet, NC 28345 County Richmond Contact Person: M. L. GREGORY (910)582-4901 Well Location/Sity Name: Location Map Attached Well Identification Number: ,- MW-2 For GmtmdwaterTmtment Systems Check One: Well Depth: 41.48 ft., Well Diameter. 4.0 in. Screened Interval: ft -To ft. ® Influent (98) Depth to Water Level 3I.4'1 ft below measuring. point ®Effluent (99) Measuring point is - ft. above land surface Gallons of water pumped/bailed before sampling: Field Analysis: pH- S, It Specific Conductance uMhos Temp. e C Odor Appearance 7 , Phone: (919)7,333221,,.,I PERMIT #: EXPIRATION DATE: November 30, 2009 Non -Discharge WQ0000601 UIC NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field Remediation _ Rota_ry.Distributor Land Application of Sludge x Other Monitorina Well NOTE Values should reflect dissolved and collaidal concentrations Date Sample Collected c 9 Date Sample Analyzed Laboratory'Name ENVIRONMENT 1, INC Certification No. 10 PARAMETERS: (Samples for metals were collected unfiltered _X_ YES NO and field acidified _X_ YES NO) COD mg/I Colifonn: MF Fecal / 100m1 Coliform: MF Total /100m1 (Note: Use MPN method for highly turbid samples) Dissolved Solids Total 1 Orl mg/1 pH (when analyzed) units TOC A. U mg/l Chloride mall Arsenic < O. o0 5 mg/1 Grease and Oils mg/1 Phenol /1 mgl[ Sulfate mgll Specific Conductance Total Ammonia Or, rho Mgt] TKN as N NO-2 as N mg/I NO_3 as N /.3 mg/I Phosphorus: Total as P mg/I Orthophosphate mg/1 At - Aluminum mg/1 Be - Barium < Ox ( mg/I Ca - Calcium mg/1 Cd - Cadmium 40,001 mg/I Chromium: Total .4 e _ oo S mg/1 Cu - Copper mg/1 Fe - Iron mg/I Hg - Mercury ' mgll K - Potassium mg/l Mg - Magnesium mg/l Mn - Manganese mg/l Ni - Nickel mg/I Pb -Lead 47.005 mg/I Zn - Zinc mg/I Ammonia Nitrogen mg/1 Other (Specify Compounds and concentration units) ORGANICS: (GC, GCIMS, HPLC) (Specify test and method #. Attach lab report) Report Attached? Yes=(1) Nc_(0) VOC - : method#= VOC method # = VOC : method # Carl A. Gerhardstein, Director Environmental Systems Permittee (or Aut4a&Lzed Agent) Name and Title -.Please print or type GW-59 Rev. 4198 of Pennittee (or Authorized DATE SUBMIT FORM ON YELLOW PAPER ONLY orc, �.eu„u �•r. rrwm 1:vrcu�u ' � •, ' REPORT FORM. Facility Name Hamlet Wastewater Treatment Facility FaciltyAddress CSX Transportation, Box 191A Highway 177N Hamlet, NC 28345 County Richmond Contact Person: M. L. GREGORY (910)582-4901 Well Location/Sity Name: Location Map Attached Check Well Identification Number: MW-3 CunMaerTreeMent Systems nr orre: Well Depth: 45.70 ft. Well Diameter: 4.0 in. Screened Interval: ft.To ft 0 Influent (98) Depth to Water Level _ 64 ft below measuring point ® Effluent (99) Measuring point is ft above land surface Gallons of water pumpedibailed before sampling: Field Analysis: pH S- Specific Conductance j09 uMhos Temp. °C Odor Appearance PARAMETERS: (Samples for metals were collected unfiltered _X YES COD Mgt[ Coliform: MF Fecal / loom[ Colifonn: MF Total f loom[ (Note: Use MPN method for highly turbid samples) Dissolved Solids Total 9 (e mgfl PH (when analyzed) units TOC (. mg/i Chloride mg/I Arsenic < O.00 S mg/l Grease and Oils mgll Phenol mgll Sulfate mgll Specific Conductance Mhos Total Ammonia mgll TKN as,N mall • DIVISION OF.WATER QUALITY ' � - - GROUNDWATER SECTION PERMITS AND COMPLIANCE UNIT • PO Box2mu ' ,- r, Ralelgh, NC.27611 70 ' .Phone; (919)733.1221 PERMIT #: EXPIRATION DATE: November 30, 2009 Non -Discharge W00000601 UIC NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field Remediation _ Rotary Distributor Land Application of Sludge X Other -Monitoring Well NOTE Values should reflect dissolved and�collaic(1a co�ncepta atlor s Date Sample Collected 9 2LJoY Date Sam le(grrdlTej0,$ Laboratory Name ENVIRON E(�( 44(( Certification No. 10 Infou"AtiOR-Processin I Int+ v buffs NO and field acidified _X YES NO) NO_2 as N mg/l NO_3 as N mg/l Phosphorus: Total as P mg/I Orthophosphate mg/l Al -Aluminum mail Ba - Barium O-C)/P mgfl Ca - Calcium mail Cd - Cadmium 4- 6.00 1 mg/l Chromium: Total O.O,aa Mgt[ Cu - Copper mall Fe - Iron mgll Hg - Mercury Mgt[ K - Potassium mgll Mg - Magnesium Mn - Manganese Carl A. Gerhardstein, Director Ni - Nickel m9/1 Pb - Lead 4-0. 00 S mg/I Zn =Zinc mg/I Ammon[a Nitrogen mg/l Other (Specify Compounds and concentration units) ORGANICS: (GC, GC/MS, HPLC) (Specify test and method #. Attach lab report.) Report Attached?Yes_([) No_(0) VOC : method#= mail VOC : method#= VOC : method#= PermiBee (or Authorized Agent) Name and TiUe - Please print or type 72.wlurirf% ll xotzx •5/�22/0 8 —1 GW-59 Rev. 4/98 Signature of Pennittee (or Authorized Agent) PAPER ONLY GROUNDWATER QUALITY-MONITORING.,!"u COMPLIANCE REPORT FORM , FACILITY INFORMATION Facility Name Hamlet Wastewater Treatment Facility Facilty, Address CSX Transportation, Box 191A Highway 177N Hamlet, NC 28345 County Richmond Contact Person: M. L. GREGORY (910)582-4901 Well Location/Site Name: Location Map Attached Well Identification Number: MW-4 For Grwndw ter Tmt..tl Che& Ore: Well Depth: 47.45 ft. Well Diameter: 2.0 in. Screened Interval: ft. . To ft. ® Influent (98) Depth to Water Level -At y ft below measuring point I ❑�' Effluent (99) Measuring point is _ ft. above land surface Gallons of water pumped/bailed before sampling: _ Field Analysis: pH (a _ Specific Conductance Temp. — e C Odor PERMIT M EXPIRATION DATE: November 30, 2009 Non -Discharge WQ0000601 UIC NPDES Lagoon Remediation: Infiltration Gallery Spray Field Remediation _ Rotary Distributor Land Application of Sludge . X Other Monitoring Well NOTE Values should reflect dissolved and collaidal concentrations 4. j _ Date Sample Collected 3 o Date Sample Analyzed �(o ( uMhos Laboa4ratory Name ENVIRONMENT 1, INC Appearance I Certification No. 10 PARAMETERS: (Samples for metals were collected unfiltered _X YES NO and field acidified _X_ YES NO) COD mgn Coliform: MF Fecal / 100ml Colifonn: MF Total / 100ml (Note: Use MPN method for highly.turbid samples) Dissolved Solids Total 10 i3 mg/I pH (when analyzed) units TOC 1.31 mg/I Chloride mgn Arsenic <O-ooS mg/l Grease and Oils mg/I Phenol mg/I Sulfate mg/I Specific Conductance Mhos Total -Ammonia _mg/1 TKN as N mg/1 GW-59 Rev. 4198 NO-2 as N mg/I NO-3 as N QA Q mg/l Phosphorus: Total as P mg/I Orthophosphate mg/I Al - Aluminum mg/l. Be - Barium G O , O ( mg/I Ca - Calcium , mg/I Cd- Cadmium 6,00a mg/l Chromium: Total O-d 3t3 mg/l Cu - Copper mg/I Fe - Iron mg/I Hg - Mercury mgll K - Potassium mg/I Mg - Magnesium mg/I Mn - Manganese mg/I A. Ni - Nickel mg/I Pb - Lead C O.005 mg/I Zn -Zinc mg/I Ammonia Nitrogen 1\ /� mg/I Other (Specify Compo�Tn- s; and once- eennutLi units) DD 2 to �008 ORGANICS: (GC, GC/MS, HPLC) (Specify test and method #. Attach lab report) Report Attached? Yes=(1) No_(0) VOC o method # = VOC method # = VOC method # _ Title - Please print or type tl-�-- - ----- DATE ' r� SUBMIT FORM ON YELLOW PAPER ONLY OUNDWATER QUALITY MONITORING => MPLIANCE:REPORT FORM, Facility Name Hamlet Wastewater Treatment Facility Facility Address CSX Transportation, Box 191A Highway 177N Hamlet, NC 28345 County Richmond Contact Person: M. L. GREGORY (910)582-4901 Well LocationlSity Name: Location Map Attached Well Identification Number: MW5 For Groundwater Treatment Systems Check One: Well Depth: 52.92 ft. Well Diameter: 2.0 in. Screened Interval: ft. To ft ®Influent(98) Depth to Water Level 31.52 ft.below measuring point ❑O Effluent(99) Measuring point is ft. above land surface Gallons of water pumpedibailed before sampling: 4-2 Field Analysis: pH . i. 6 Specific Conductance ) y J uMhos Temp. ° C Odor Appearance PARAMETERS: (Samples for metals were collected unfiltered _X_ YES COD mg/I Colifonn: MF Fecal / 100ml Colifonn: MF Total / 100ml (Note: Use MPN method for highly turbid samples) Dissolved Solids Total 10 mg/I pH (when analyzed) units TOC mg/l Chloride mg/l Arsenic t 0 - 00 mg/I Grease and Oils mg/l Phenol mg/I Sulfate mg/I Specific Conductance Mhos Total Ammonia mg/I TKN as N mg/I Phone: (919)7333221, PERMIT #: EXPIRATION DATE: November 30. 2009 Non -Discharge W00000601 _ UIC NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field Remediation Rotary Distributor Land Application of Sludge X Other Monitoring Well_ — NOTE Values should reflect dissolved and collaidal concentrations Date Sample Collected 3/ 24 O? Date Sample Analyzed Laboratory Name ENVIRONMENT 1, INC Certification No. 10 NO and field acidified _X_ YES NO) NO_2 as N mg/I NO_3 as N 1.11i mg/l _ Phosphorus: Total as P mg/l Orthophosphate mgll AI -Aluminum mg/I Ba-Barium �_o�S. mg/l Ca - Calcium mgn Coll - Cadmium < O- Oo ( mg/I Chromium: Total < o. no A, mg/I Cu - Copper mg/I Fe - Iron mg/I Hg - Mercury mg/1 K - Potassium mg/1 Mg - Magnesium mgll Mn - Manganese mg/I Ni - Nickel Pb - Lead 6.oi: a mg/l Zn - Zinc mg/I Ammonia Nitrogen mg/1 Other (Specify Com�.psound�s-eand concentration units) EIvED HY' 9 �-011)Tg ormation Processing •t ORGANICS: (GC, GC/ LCf (Specify test and method #. Attach lab report) Report Attached? Yes_(1) No_(0) VOC : method#= VOC : method # = VOC : method#= Cad A. Gerhardstein, Director Environmental Systems ` PermiO a (orr Authorized Agent) Name and Title - Please print or type 71:de I" /r • %-t4rv— GW-59 Rev. 4198 Signature of Permittee (or Authorized Agen � � DATE w FORM ON YELLOW PAPER ONLY Facility Name Hamlet Wastewater Treatment Facility Facilty Address CSX Transportation, Box 191A Highway 177N Hamlet, NC 28345 County Richmond Contact Person: M. L. GREGORY (910)582-4901 Well Location/Sity Name: Location Map Attached Well Identification Number:- MW-6 - Well Depth: 48.35 ft. Well Diameter: 2.0 in. Screened Interval: ft. To ft. Depth to Water Level ft below measuring point Measuring point is ft above land surface Gallons of water pumpediballed before sampling: Field Analysis: pH Specific Conductance uMhos Temp. °C Odor Appearance Far Giomd WTMe ere Systems Check One: fa Influent(98) Effluent (99) ERMITS AND COMPLIANCE Phone:. (919)7334221; ,a PERMIT #: EXPIRATION DATE: November 30, 2009 Non -Discharge WQ0000601 UIC _ NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Spray Field Rotary Distributor X Other Monitorim i Well Remediation: Infiltration Gallery Remediation Land Application of Sludge NOTE Values should reflect drisssolved and c I/IpidcYl�conceotrations Date Sample Collected /yd Date Sqfnple Analyzed Laboratory Name ENVIRONMENT 1, INC Certification No. 10 - PARAMETERS: (Samples for metals were collected unfiltered X YES NO and field acidified _X YES COD mg/I Colifonm: MF Fecal /loom[ Col(fonn: MF Total 11oom1 (Note: Use MPN method for highly turbid samples) Dissolved Solids Total pH (when analyzed) TOC Chloride Arsenic Grease and Oils Phenol Sulfate Specific Conductance Total Ammonia TKN as N _ mg11 units mgll NO-2 as N mg/l NO-3 as N mg/I Phosphorus: Total as P mg/I Orthophosphate mgn At - Aluminum mg/I Ba - Barium Ca - Calcium Cd-Cadmium Chromium: Total Cu -Copper Fe - Iron Hg -Mercury _ K - Potassium Mg - Magnesium Mn - Manganese Ni - Nickel NO) mg/I Pb - Lead mg/I Zn -Zinc m9/1 Ammonia Nitrogen- mg/I Other (Specify Compodnds and�on'centration units) mg/l mgn Z008 Mgt[ nformation IycLessln riigll D W Z 9Unit mgll ORGANICS: (GC, GCIMS, HPLC) mg/I (Specify test and method #. Attach lab report) mgll Report Attached?Yes_(1) No_(0) mg/I VOC : method#= mg/I VOC : method # = Director Environmental Permittee (or Authorized Agent) Name and Title - Please print or type Y ll. JZaollw ,t/ s/zz/o8 GW-59 Rev. 4/98 Signature of Permittee (or SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATERQUALITYMONITORING r • UIVWIUnUrwA1=KyUAU1T s ti GROUNDWATER SECTION PERMITS AND COMPIL jANCE UNIT COMPLIANCE REPORT FORM , • P.O.Box 278e7 Raleigh NC27811-7687o' Phone: {918)733-3221 Facility Name Hamlet Wastewater Treatment Facility Facilty Address CSX Transportation, Box 191A Highway 177N Hamlet, NC 28345 County Richmond Contact Person: M. L. GREGORY (910)582-4901 _ Well Location/Sity Name: Location Map Attached _ Well Identification Number: MW-7 For Ground"terTrealment Systems Cheri One: Well Depth: 37.18 ft. Well Diameter: 2.0 in. Screened Interval: ft. To • ft. ® Influent(98) Depth to Water Level 33.5d ft below measuring point 0 Effluent (99) Measuring point is ft above land surface Gallons of water pumpediballed before sampling: 1. T Field Analysis: pH 5.3 Specific Conductance uMhos Temp. ° C Odor Appearance PARAMETERS: (Samples for metals were collected unfiltered X YES COD mgll _ Colifonn: MF Fecal / 100ml Colifonn: MF Total / 100ml (Note: Use MPN method for highly turbid samples) Dissolved Solids Total .mg/i pH (when analyzed) units TOC 3 . i 3 mg/l Chloride mg/l Arsenic <O. Oo S mg/I Grease and Oils mgll Phenol mg/1 Sulfate mgll Specific Conductance Mhos Total Ammonia rtigll TKN as N - _- _-__mg/1 PERMIT #: EXPIRATION DATE: November 30, 2009 Non -Discharge W00000601 UIC NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery Spray Field Remediation Rotary Distributor Land Application of Sludge X Other Monitorina Well NOTE Values should reflect dissolved and collaidal concentrations Date Sample Collected 3 2v oil Date Sample Analyzed Laboratory Name , ENVIRONMENT 1, INC Certification No. 10 NO and field acidified X YES NO) NO_2 as N mg/I NO_3 as N a.' mg/l Phosphorus: Total as P mg/l Orthophosphate mg/l AI -Aluminum mg/l Ba-Barium 0.0` 9 mg/l Ca - Calcium ing/l Cd - Cadmium 6.00 mg/I Chromium: Total (h. 'f 18 mg/l Cu -Copper mg/I Fe - Iron mg/I Hg - Mercury mg/I K - Potassium mgll Mg - Magnesium mg/l Mn - Manganese mg/I Ni - Nickel Pb - Lead in, 00 S, mg/l Zn - Zinc mg/l Ammonia Nitrogen mgll Other (Specify Compounds and concentration units) r I Il2- Information ORGANICS: (GC, GG S �PLOpnit (Specify test and method #. Attach lab report) Report Attached? Yes_(1) No_(0) VOC : method#= VOC : method # = VOC : method # = Cad A. Gerhardstein, Director Environmental Systems Perminee (or Authorized Agent) Name and Titlee-- Please print or type A 1� /� ky, �J. GW-59 Rev. 4/98 Signature of Permiltee (or SUBMIT FORM ON YELLOW PAPER (GROUNDWATER QUALITY MONITORING COMPLIANCE REPORT FORM ` FACILITY INFORMATION Facility Name Hamlet Wastewater Treatment Facility Facility Address CSX Transportation, Box 191A Highway 177N Hamlet, NC 28345 County Richmond Contact Person: M. L. GREGORY (910)582-4901 Well Location/Sity Name: Location Map Attached Welildentification Number: MW-8 ForcmmdxeterTea1mn1 systems 'Well Depth: 57.18 ft Well Diameter: 2.0 in. Check One: Screened Interval: ft. To ft ® Influent (98) Depth. to Water Level LA-1,03 fL below measuring point ® Effluent (99) Measuring point is fL above land surface Gallons of water pumped/balled before sampling: 11.5 Field Analysis: pH s-�( Specific Conductance aaS uMhos Temp. e C Odor Appearance: Ft SECTION PERMITS AND COMPLIANCE.UNITI c 11 7697; �. - Phone:' (919)733-3nl yj x _ PERMIT #: EXPIRATION DATE: November 30, 2009 Non -Discharge WQD000601 UIC NPDES TYPE OF PERMITTED OPERATION BEING MONITORED Lagoon Remediation: Infiltration Gallery _ Spray Field Remediation Rotary Distributor Land Application of Sludge X Other Monitoring Well NOTE Values should reflect dissolved and collaidal, concentrations Date Sample Collected 3 z4 ob Date Sample Analyzed Laboratory Name ENVIRONMENT 1, INC Certification No. 10 PARAMETERS: (Samples for metals were collected unfiltered X YES NO and field acidified X_ YES NO) COD mg/l Coliform: MF Fecal / 1ooml Coliform: MF Total / loom] (Note: Use MPN method for highly turbid samples) Dissolved Solids Total mg/I pH (when analyzed) units TOC (, y mg/l Chloride mg/l Arsenic c 0, 00 9, mg/I _ Grease and Oils mg/l Phenol mgll Sulfate mg/l Specific Conductance Mho; Total Ammonia mg/1 TKN as N mg/l NO-2 as N mg/l NO-3 as N 10. Sii mgf1 Phosphorus: Total as P mg/l Orthophosphate mg/I At -Aluminum mg/I Be - Barium 0.053 mg/I Ca -Calcium mg/I Cd - Cadmium 0.00) mg/l Chromium: Total O- p 7 mg/I Cu - Copper mg/I Fe - Iron mg/I Hg - Mercury mg/l K - Potassium mg/l Mg - Magnesium mg/l Mn - Manganese mg/l Ni - Nickel mg/l Pb - Lead t O -pp S mg/I Zn -Zinc mg/i Ammonia Nitrogen mg/I Other (Specify Compounds and,concentrationunits) `i g noa i nfnrmnfinn Processing-LIM! DWO/BOG ORGANICS: (GC, GC/MS, HPLC) (Specify test and method #. Attach lab report) Report Attached? Yes _(1) No" (0) VOC : method #= VOC : method#= VOC : method#= Cad A. Gerhardstein, Director Environmental Systems Permittee (or Authorized Agent) Name and Title - Please printor type GW-59 Rev. 4198 Signature of Pennitlee (or Authorized Agent) UAlt