WQ0000601_GW Monitoring_20101221

SUBMIT FORM ON YELLOW PAPER ONLY
a
?R QUALITY MONITORING:
REPORT FORM
Facility Name: CSX Transportation - Hamlet Wastewater Treatment Facility
Permit Name (if different):
Facility Address: 173 CSX Dnve
Hamlet (51,4m) NC 28345
County Richmond
act Person: Mike Gregory Telephone#:, 910.205.6379
Location/Site Name: See location map No. of wells to be sampled: 8
L ID NUMBER (from Permit): MW-1 Date sample collected:
Depth: 53_75 ft, Well Diameter: 4.0 in.
h to Water Level 82546: ft. below measuring point Screened Interval: ft. to ft.
;udng Point is ft. above land surface Relative M.P. Elevation: ft.
ne of water Pumped/bailed before sampling: gallons
Aes for metals were collected unfiltered: ❑ YES ❑ NO and field aeWif.d- fl vcc r-1 .,.,
ate sample analyzed:
Laboratory Name:
\RAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NOJ as N ooe15
mg/L
Colifarm: MF Fecal 31616
/100ml-
Nitrate (NO,) as N 00620
mg/L
Coliform: MF Total 31504
/100ml-
Phosphorus: Total as P 00665
mg/L
(N.I.: Use MPN meWd for Ng* rabid sample.)
Orthophosphate 70507
mg/L
solved Solids:TOtal 70300
mg/L
AI -Aluminum otlos
mg/L
PH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC 00680
mg/L
Ca - Calcium oosts
mg/L
Chloride oo94o
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 111a42
mg/L
Phenol 32730
ug/L
Fe - Iron 01045
ug/L
Sulfate oos45
mg/L
Hg - Mercury 71900
ug/L
:cificConductance oows
µMhos
K- Potassium oog37
mg/L
Total Ammonia oosto
(Al
mg/L
Mg - Magnesium o0927
m /L
rda Ni"gen: NH,aa N; A anla Nisogen, T.Wl),
9
Mn- Manganese 01055
ug/L
TKN as N ooszs
mg/L
Ni - Nickel 01067
ug/L
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs:
Cad A. Gerhardstein, Env. 8 Sust. Systems
Pemlitree(dr Auth.t Agent)Name and Tdle- Please print ortype
GW-59 Rev. 2/2olo
?RMIT Number: -
Expiration Date: 7/31/2017
)n-Discharge W00000601
UIC
)DES
Other
'PE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon
❑ Remediation: Infiltration Gallery
❑ Spray Field
❑ Remediation:
❑ Rotary Distributor
❑ Land Application of Sludge
❑ Water Source Heat Pump
N Other: Monitoring wells
FIELD ANALYSES: WAS
PH 00400:_ units Temp. 00oio: eC DRY at
Spec. Cond. 00094: µMhos time of
Odor 000ss: samplin
check
Appearance here:r
J
Certification No.
Pb - Lead atasl ug/L
Zn - Zinc 01092mg/L
Other (Speci fy CCoorppouunds and Concentration
�
eUll rrUU eSS;nD l
JJ
ORGANICS: (by GC, G , PLC)
m
z
N
o
(Specify test and. method #.. LAB REPOR=.
Lab Report Attached? Cl Yes(l) ❑ No(o)
VOC 78732: ,method #
m
method #
method #
method #
Effluent Total
VOC Removal%
1
v

SUBMIT FORM ON YELLOW PAPER ONLY
SR QUALITY MONITORING:
REPORTFORM
Name: CSX Transportation - Hamlet Wastewater Treatment Facility
Name (if different):
Address: 173 CSX Drive
Hamlet
NC
County Richmond
act Person: Mike Gregory Telephone#: [phone]
Location/Site Name: See location map No- of wells to be .6379 d: 6
FLING INFORMATION - rmm Pemvt
LID NUMBER (from Permit): MW-2 - Date sample collected: 11/1/2010
Depth: 41.4e g, Well Diameter: 4.0 in.
h to Water Level 82546:36.0 ft. below measuring point Screened Interval: ft to ft.
wring Point is ft. above land surface Relative M.P. Elevation: ft,
ne of water pumped/bailed before sampling: 7.0 gallons
.re.......--'-'-----
gte sample analyzed: 1112-srtot0 Laboratory Name: TesfAmerica
iRAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
CODoo3a5 mg/L Nitrite (NOO as N oo615
Coliform: IMF Fecal 31616 /100
mL Nitrate (NO3) as N 00620 1,3
Coliform: MF Total 31504 /100mL
(Note: Use MPN Mftd kr NpNy Nrbld samples)
solved Solids:Total 70300 71
mg/L
PH (Lab) OD403 -
units
TOC o06eo 1.7
mg/L
Chloride oo940.
mg/L
Arsenic 01002 <0.05
ug/L
Grease and Oils ooss2
.. 11
Phenol 32730
ug/L
Sulfate costs
mg/L
is Conductance 000gs
µMhos
Total Ammonia oosm
mg/L
(Aa=rda Nitrogen; NHsas N: Ammonla Mtrogen, TM)
TKN as N oo625
mg/L
For RemediatiomSystems Only (Attach Lab
Carl A. Gerhardstein, AVP, Env &Bust. Systems
Perminee (orAalhorized Agent) Name and Title- Please print cr type
GW-59 Rev. 2/2010
mg/L
mg/L
Phosphorus: Total as P 00665
mg/L
Orthophosphate 70507
mg/L
AI -Aluminum ollos
mg/L
Be - Barium o1007 0.0062
ug/L
Ca - Calcium oo916'
mg/L
Cd - Cadmium oio27 0.0001
-ug1L
Chromium: Total ofo34 <0.05
ug/L
Cu - Copper 01042
mg/L
Fe - Iron o1045 _
ug/L
Hg - Mercury 71900 -
ugIL
Potassium 00937
mg/L
Mg -: Magnesium 00927
mg/L
Mn- Manganese otoss
ug/L
Ni- Nickel 01067
ug/L
Influent Total VOCs:
Number: 'Expiration Date:
harge W00000601 UIC
Other
'PE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑-Remediation: Infiltration Gallery
❑ Spray Field ❑ Remediation:
El Rotary Distributor ❑ Land Application of Sludge
❑ Water Source Heat Pump *Other: m6nitoring wells
FIELD ANALYSES:
PH 00400: 7.01 units Temp. 0ooio: °C
Spec. Cond. 00094: µMhos
Odor oo06s:
Appearance _
Certification No. NCDWQ 269
Pb- Lead most <0.015 ug/L
Zn - Zinc 01092 - mg/L
Other (Specify Compounds and Concentration Units):
ORGANICS: (by GC, GC/MS; HPLC) -
(Specify test and method #- ATTACH LAB REPORT.)
Lab Report Attached] -El Yes (1) ❑ No (a)
VOC 79732: , method #
method #
method #
method #
Total
mg/L
at
of
(i
It

SUBMIT FORM ON YELLOW PAPER ONLY
t-
°R QUALITY MONITORING:
REPORTFORM
FacilityName:. CSX Transportation -Hamlet Wastewater Treatment Facility
Permit Name (if different):
Facility Address: 173 CSX Drive
Hamlet I51°°'1 NC 28345
cc:t. County Richmond
y iEam) 1=ro1
'ontact Person: Mike Gregory Telephone#: [phone]
Nell Location/Site Name: See location map No. of wells to be sampled:.8
LID NUMBER (from Permit): MW-3 Date sample collected: 71l112010
Depth: 45�7o ft, Well Diameter. 4.0
1 to Water Level e2546:39.9 ft. below _ft.
measuring point Screened Interval: ft, to ft.
uring Point is ft. above land surface Relative M.P. Elevation:
ne of water Pumped/bailed before sampling: _ _ gallons ft
sample
COD oo33s
mg1L
Caliform: MF Fecal 31616
/100mL
Caliform: MFTota131504
/100mL
(Note: Use MPN method for NgNy Nre,E samPla)
solved Solids:Total 70300 43
mg/L
PH (Lab) 00403
units
TOC oo6eo <1.0
mg/L
Chloride oos4o
mg/L
Arsenic 01002<0.05
ug/L
Grease and Oils 00652
mg/L
Phenol 32730
uglL
Sulfate. cog"
mg/L
cific Conductance 0009s
µMhos
Total Ammonia o0slo
mg/L
(AmmoNa Maegen: NHras N: Ammonia Namgen. TOW)
TKN as N 00625 mg/L
For Remediation Systems Only (Attach Lab Reports):
Carl A. Gerhardstein, AVP, Env 8 Bust. Systems
Permit... (car Authar¢etl ABanFI Name and Title- Please Print or type
GW-59 Rev. 2/2010
Laboratory Name: TestAmerica
and colloidal concentrations.
Nitrite (NO,) as N costs
mg/L
Nitrate (NO,) as N 00620 1.2
mg/L
Phosphorus: Total as P oosss
mg1L
Orthophosphate 70507
mg/L�
AI - Aluminum Ott05
mglL
Be - Barium ofoo7 0.0094
ug/L
Ca - Calcium 00916
mg/L
Cd - Cadmium 01027 0.0008.
ug/L
Chromium: Total 01034 <0.05
u.g/L
Cu - Copper 01D42
mg/L
Fe- Iron o1045 .
ug/L
Hg- Mercury 71900.
ug/L
K -'Potassium 00937
mg/L
Mg - Magnesium 00927
mg/L
Mn- Manganese at ass
ug/L
Ni - Nickel 01067
ug/L
Influent Total
ERMIT Number: Expiration Date: 7/31/2017
3n-Discharge W00000601 UIC_
DDES Other
(PE OF PERMITTED OPERATION BEING MONITORED
Lagoon ❑ Remediation: Infiltration Gallery
❑ Spray Field ❑ Remediation:
❑ Rotary Distributor ❑ Land Application of Sludge
❑ Water Source Heat Pump IN Other: monitoring Wells
FIELD ANALYSES:
PH oo4o0: 7.53 units Temp, 000to: eC
Spec. Cond. 00094: . ,µMhos
Odor 000as:
Appearance
Certification No. NCDWQ 269
Pb-Lead olosl <0.015 ug/L
Zn - Zinc e1o92 mg/L
Other (Specify Compounds and Concentration Units):
ORGANICS: (by GC, GUMS. HPLC)
(Specify test and method A ATTACH LAB REPORT.)
Lab Report Attached? ❑ Yes (1) ❑ No (0)
VOC 78732: , method #
method #
method #
method #
mg/L Effluent Total VOCs:
VOC Removal k
at
of
10
x

SUBMIT FORM ON YELLOW PAPER ONLY
ER QUALITY MONITORING: DEr>E1 1101 1 ,oFEq11R1 1M11 FNi11 a,11 w11
TNRA 'RESougcEs . • ;
REPORT FORM DIVISION OF WATER,CUgyJy-tNFOHp,�jTiON PROCESSING,UNiT-
..
Name: CSX Transportation - Hamlet Wastewater Treatment Facility
Name (if different):
Address: 173 CSX Drive
Hamlet fsvnnq
28345
cc,yt � -„ County Richmond
act Person: Mike Gregory Telephone#: [phone]
Location/Site Name: See location map - No. of wells to be sampled: 6
L ID NUMBER (from Permit): MW-4
Depth: 47.45 ft,
1 to Water Level 92546:36.3 ft. below measuring point
uring Point is ft. above land surface
ne of water pumped/bailed before sampling:
YES ❑ NO
=RMIT Number:'
Expiration Date: 7/3112017
)n-Discharge W00000601
UIC_
'DES
Other
!PE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon
❑ Remediation: Infiltration Gallery
❑ Spray Field
❑ Remediation:
❑ Rotary Distributor
❑ Land Application of Sludge
❑ Water Source Heat Pump
0 Other. monitoring Wells
Date sample collected: 11/1I2010 FIELD ANALYSES:
Well Diameter. 2.0 in. pH co400: 7.4 units Temp. 000lo: °C
Screened Interval: ft. to _ft. Spec. Cond. Do094: µMhos
Relative M.P. Elevation: ft. Odor a00s5:
s
Appearance
Date sample analyzed: 11/2. zoto
PARAMETERS NOTE. Values should reflect dissolved and colloidal oconentrationsratory Name: esrAmerica
COD oo33s
Coliform: MF Fecal 31616
mg/L
Nitrite (NO2) as N oost5
mg/L
/100mL
Nitrate (NO,) as N 00620 0.64
mg/L
Coliform: MF Total 31504
(Nob: Use MPN m°dwd forEFY brtid —pies)
/100mL
Phosphorus: Total as P oases
mglL
issolved Solids:Total 703oo 43
Orthophosphate 70507
mg/L
PH (Lab) 00403
mg/L.
AI -Aluminum 01105
mg/L
��mg/L
TOC 0osso <1.D
arium0toa7<2.0
uglL
Chloride acsao
mg/L
a -Be
Ca- Calcium 0091e
mg2
Arsenic 01002 <0.05
mg/L
Cd - Cadmium 01027 0.00013
uglL<0.05
Grease and Oils oossz
uglL
Chromium: Total ot034
ug/L
Phenol 32730
mg/L
Cu - Copper otoaz
mg&
Sulfate oos4s
ug/C
Fe -Iron o1045
uglL
pecific Conductance cools
mg
µMhos
Hg - Mercury 71900
uglL
Total Ammonia costo
K - Potassium a0937
mg/L
(Ammonia Ncvgen; NH,,, Nmm A°nia Nitrogen, T°b)
mg/L
Mg -Magnesium 0osz7
mg/L
TKN as N Doses
Mn - Manganese o1o5s
uglL
mg/L
Ni - Nickel 01067
ug/L
For Remedlation Systems Only (Attach Lab Reports): Influent Total
lllll
Cad A. Gerhard Lein, AVP, Env a Bust. Systems
Pefmktee (orAutherized Agent) Name and Title- Please print or type
GW-59 Rev. 2/2010
Certification No. NCDWQ 269
Pb -Lead oto51 <0.015 ug/L
Zn - Zinc 01092 mg/L
Other (Specify Compounds and Concentration Units):
ORGANICS: (by GC, GC/MS, HPLC)
(Specify test and method #. ATTACH LAB REPORT.)
Lab Report Attached? ❑ Yes (1) ❑ No (0)
VOC 78732: , method #
method #
method #
method #
mg/L Effluent Total
VOC
at
of
S

SUBMIT FORM
ONLY
°R QUALITY MONITORING:
REPORTFORM
Facility Name: CSX Transportation - Hamlet Wastewater Treatment Facility
Permit Name (if different):
Facility Address: 173 CSX Drive
Hamlet (s""01I NC 28345
iary� County Richmond
ismfel 14a.)
act Person: Mike Gregory Telephone#: [phone]
Location/Site Name: See location map No. of wells to be sampled: 8
L ID NUMBER (from Permit): MW-5
Depth: 52.92 ft.
h to Water. Level e2546:44.0 ft, below measuring point
luring Point is ft. above land surface
ne of water pumped/bailed before sampling:
:RMIT Number:
Expiration Date: 7/31/2017
m-Discharge W00000601
UIC
'DES
Other
'PE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon
❑ Remediation: Infiltration Gallery
❑ Spray Field
❑.Remediation:
❑ Rotary Distributor
❑ Land Application of Sludge
❑ Water Source Heat Pump
X Other: monitoring wells
Date sample collected: 1111/2010 FIELD ANALYSES:
Well Diameter. 2.0 in. pH oo400: 7.03 units Temp. cooto: °C
Screened Interval:_ft, to ft. Spec. Cond. oaog4: µMhos
Relative M.P. Elevation: ft. Odor 000e5:
s Appearance
its sample analyzed:11r2-moto
Laboratory Name: TestAmerica
tRAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO,) as N 00615
mg/L
Coliform: MF Fecal.31616
/100mL
Nitrate (NO3) as N 00620 1.0
Colifonn: MF Total 31504
(Nola: Use MPN
/100mL
Phosphorus: Total as P 00665'
mg/L
mg/L
esetlwd for NgNy hel id samples)
Orthophosphate 70507
mg/L
solved Solids:Total 7030058
mg/L
AI -Aluminum otlas
In
PH (Lab) 00403
units
Be -Barium 01007 0.019
uglL
TOC 00680 0.94
mg/L
Ca - Calcium ousts
mg/L
Chloride oos4o
mg/L
Cal - Cadmium 01027 0.0001
ug/L
Arsenic otooz <0.05
ug/L
Chromium: Total oto34 <0.05
ug/L
Grease and Oils 06552
mg/L
Cu - Copper oio42
mg/L
g
Phenol 32730
ug/L
Fe-- Iron aimug/L
Sulfate 0e945
mg/L
Hg - Mercury 71900
ug/L
:cific Conductance 00095
µMhos
K- Potassium 00937
mg2
Total Ammonia o0afo
(AmnnNa Niwpen;
mg/L
Mg - Magnesium co927
mg/L
NH,- N; AmmoNa Nihegen. T.w)
Mn - Manganese otoss
ug/L
TKN as N 00625
mg/L
Ni - Nickel 01067
ugfL
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs:
Cad A. Gerhardstein, AVP; Env & Sust. Systems
Permdtee (or Authorized Agent) Name and Title -Please print or type
GW-59 Rev. 2/2010
Certification No. NCDWQ 269
Pb- Lead atosi <0.015 ug/L
Zn - Zinc cio92mg/L
Other (Specify Compounds and Concentration Units):
ORGANICS: (by GC, GC/MS, HPLC)
(Specify: test and method #. ATTACH LAB REPORT.)
Lab Report Attached? ❑ Yes (1) ❑ No (0)
VOC 78732: , method #
method#
method #
method #
mg/L Effluent Total VOCs:
at
of
C

SUBMIT FORM ON YELLOW PAPER ONLY
-R QUALITY MONITORING:
REPORT FORM
Facility Name: CSX Transportation- Hamlet Wastewater Treatment Facility
Permit Name (if different):
=acility Address: 173 CSX Drive
Hamlet (sv°°p NC 28345
County Richmond
act Person: Mike Gregory Telephone#: [phone]
Location/Site Name: See location map No. Of wells to be sampled: 8
L ID NUMBER (from Permit): MW-7 Date sample collected: 11/112010
Depth: 37.18 ft, Well Diameter. 2.0 in.
h to Water Level azs4s:27.9 ft. below measuring point Screened Interval: ft. to It.
Turing Point is ft. above land surface Relative M.P. Elevation: ft.
ne of water Pumped/balled before sampling: gallons
Iles for metals were collected unfiltered; ® YES ❑ NO and field adda;ed r71 vice n .�..
tte, sample analyzed:1112-5molo LaboratoryName: Test America
tRAMETERS NOTE: Values should reflect dissolved and colloidal
• COD ao33s
concentrations.
COliform: MF Fecal 31616
mg/L
Nitrite (NO=) as N oos15
mg/L
/100mL
Nitrate (NO3) as INoaszo 1.9
mglL
Coliform: MF Total 31504
(Nora: Use MPNm°dadrurldgtdyN ldsamples)
/100mL
Phosphorus: Total asp 00665
mg/L
solved So
Orthophosphate 70507
mg/L
mg/L
AI - Aluminumoiios
-
mg/L
PH(Labl004034fi
PH (Lab) 00403
units'
Ba -Barium otoo7 0.0079
ug/L
TOC 0osso 0.85
mg/L
Ca - Calcium 00916 -
mg/L
Chloride oo94o
mg/L
Cd - Cadmium 01027 0.0001
ug/L
Arsenic otoo2 <0.05
ug/L
Chromium: Total 01034 <0.05
uglL
Grease and Oils 00552
mglL
Cu - Copper oio42
mg/L
Phenol3z73o
ug/L
Fe - Iron ofo45
ug/L
Sulfate oo94s
mg/L
Hg -:Mercury 71900
ug/L
:cific Conductance 000ss
µMhos
K - Potassium 00937
Total Ammonia 00610
mg/L
Mg - Magnesium 00927
m9/L
(Am da Nitrogen; NH.as N; Mumma Nlaogee, T-W)
mglL
TKN as N 00625
Mn - Manganese
se o1055
uglL
mg/L
Ni - Nickel 01067
ug/L
For Remedlation Systems Only (Attach Lab Reports): Influent Total
Cad A. Gerhardstein, AVP, Env & Sust. Systems
Permatea (orAuthonxad Agent) Name and Trtle - Please pant or typo
GW-59 Rev. 2/2010
?RMIT Number:
Expiration Date: 7/3112017
)n-Discharge W00000601
UIC
ODES
Other
rPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon
❑ Remediation: Infiltration Gallery
❑ Spray Field
❑ Remediation:
❑ -Rotary Distributor -
❑ Land Application of Sludge
❑ Water Source Heat Pump
0 Other: Monitoring Wells
FIELD ANALYSES: IWAS
PH 00400: 6.75 units Temp. ooaio: °C JDRY at
Spec. Cond. 00094: who,Itime of
Odor 000as: samplin
check
Appearance
here:r
Certification No. NCDWQ 269
Pb -Lead oiosl <0.015 ug/L
Zn - Zinc =92 mg/L
Other (Specify Compounds and Concentration Units):
ORGANICS: (by GC, GC/MS, HPLC)
(Specify test and method #. ATTACH LAB REPORT.)
Lab Report Attached? ❑ Yes (1) ❑ No (0)
VOC 78732: , method #
method #
method #
method .#
Effluent Total
mg/L VOC
rr
1

SUBMIT FORM ON YELLOW PAPER ONLY
ER QUALITY MONITORING:
REPORT FORM
Facility Name: CSX Transportation - Hamlet Wastewater Treatment Facility I
Permit Name (if different): I
eacility Address: 173 CSX Ddve I
Hamlet t5veen 7
28345
NC , _ County Richmond
:ontact person: Mike Gregory I
Telephone#: [phone]
Vell Leoation/Site Name: See location map -
No. of wells to be sampled- 8
AMPLING INFORMATION 1. p n
VELL ID NUMBER (from Permit): MW-8
Date sample collected: n/v2o1oa1Vz32ata
Vell Depth: 57.18 ft-
lepth to Water Level 62546:43.7 below Well Diameter. 2.0 In.
ft. ow measuring point Screened Interval: ft. to ft.
1easuring Point is ft. above land surface
Plume of water Pumpedibailed before sampling: gallons
M.P. Elevation: ft.
amples for metale 000re...,ue........._�..__ _
"• „o"„H,c eua,yze0: nrz-Y 010 a11/242010 Laboratory Name: TestAmedra kRAMETERS NOTE: Values should reflect dissolved
m
COD o0335
and colloidal concentrations.
COffOrM: MF Fecal 31616�mg�
Nitrite (NO2) as N 0ost5 "
mg/L
-/100ml_
Coliform: MFTotal atso4/100mL
Nitrate (NOS) as N oo620 10.5 (2 samples)
mg/L
(Nate Use NPN me.atl for NpNy lw.Itl samplec)
Phosphorus: Total as P 00665
mg/L
solved Solids:Total 70300 150
2
Orthophosphate 7aso7
mg/L
PH (Lab) 00403�
units
TOC ooseo 1=mg/L
Chloride oosao
mg/L
Arsenic 01002 <0.05
ug/L
Grease and Oils 00552-mg/L
Phenol 32730
ug/L
Sulfate oo945-_mg/L
fic Conductance 00095�-1Mhos
Total Ammonia oaslomglL
mm
(Ammonia NitaOan; NHN:sas Ammonln -Ni.oOan. Tetaq
TKN as N 00625
Systems Only (Attach lab Reports):
Carl A. Geardstein, AVP, Env & Sust. Systems
Permittea (rhorAumorizetl Agent) Nam. and Title -Please print or type
GW-59 Rev. 212010
AI - Aluminumollos
mg/L
Ba - Barium 01007 0.057
ug/L
Ca- Calcium oo916
mg2
Cd - Cadmium 01027 0.0004
ug/L
Chromium: Total oio34 <o.o5
ug/L
Cu- Copper oic42
mg/L
Fe- Iron a1o45ug/L
Hg - Mercury 71900-ug/L
K- Potassium oo937
mg/L
Mg - Magnesium 00927
mg/L
Mn- Manganese atos5
ug/L
Ni- Nickel01067
ug/L
Influent Total VOCs:
Number: Expiration Date:
harge W00000601 UIC
(PE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
❑ Spray Field ❑ Remediation:
❑ Rotary Distributor ❑ Land Application of Sludge
❑ Water Source Heat Pump 0 Other: MonitOring Wells
FIELD ANALYSES:
PH 00400: 7.07 units Temp. 000lo: eC
Spec. Cond. aa094: ILMhos
Odor 00085:
Appearance
Certification No. NCDWO 269
Pb-Lead oiosi <0.015 ug/L
Zn - Zinc olo92 mg/L
Other (Specify Compounds and Concentration Units):
ORGANICS: (by GC, GC/MS, HPLC)
(Specify test and method #. ATTACH LAB REPORT.)
Lab Report Attached? ❑ Yes (1) ❑ No (0)
VOC 78732: , method #
method #
method #
method #
Effluent Total VOCs:
VOC Removal%
at
of

GW-59A COMPLIANCE REPORT FORM Permit # W0000061
` (Submit one each monitoring period with GTV-59 forms) GW-59A 12/8/2003
]
Enter date monitoring results were due. (12/28/2010) Will this monitoring report (GW-59 and GW-59A) be
submitted after the established due date?
YES
NO
2
Was any required information missing on the GW-59 report forms?
YES
NO
IF the answerto question 1 or2 is 'YES", list in the space provided below the well identification'number(s) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
identification plate, area overgrown, etc.)? Ifthe answer is "Yes", contact the Regional Ojr1ce forguidance.
YES
NO
4
Are any monitored constituents equal to or above the established standards?
YES
NO
If the answer to question 4 is "NO , skip to section B.
If the answer to question 4 is "YES" list the affected wells individually with constituents) and concentration(s)
exceeding standards in the space provided below.
MIN-8, the sample collected on 11-01-10, NOa as N was 11 mg/I. The MW-8 was resampled .
on 11/23 and the result was 10 mg/I. The average between the samples is 10.5 mg/I, but the
max concentration is 10.0 mg/I. oThis is upgradient of the treatment plant and holding pond
and so a corrective action wa? mplemented because CSX cannot the
control groundwater
in that well.
$
For the constituents identified in question 4 above, have standards been exceeded previously for the
same
YES
NO
constituent(s) in the same well(s) in the last two years?
if the answer to question 5 is "NO" skip to section 8.
If the answer to question 5 is "YES" list in the space provided below, each well with constituent(s) exceeding
standards, concentration(s) reported, and sample collection date for each
occurrence (for the last two years).
For Nitrogen, Nitrate Total 4/30/09 —12.93 Mg/L.7/7/09 —13 mg/L;
11/10/09 —12.6 mg/L; 11/25/08 —10.4 mg/L
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
YES
NO
It the answer is "YES" a groundwater qualify problem may be occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELYFOR GUIDANCE. If the answerfs "NO" monitoring wells maybe improperly
located,, contact the Regional Office.
Is the permittee implementing previously approved actions required, by the Division involving this
groundwater quality problem?
YES
NO
If the answer to question 7 is -YES-, describe those actions in the space provided below.
If the answer to question 7 is "NO", contact the Regional Office within 90 days; an evaluation may be
required to determine the impact the waste disposal system is having at the review and compliance
boundaries surrounding this facibty. Failure to do so may subfect the pennittee to a Notice of Violation
Tines, andforpenalbes.
8
The person completing this portion (GW-59A) of the monitoring report should sign below and submit this
form with G W-59 forms for required wells to the address the top
provided at of the current G W-59 form.
I
hereby acknowledge that the above information was evaluated and the information submitted in this
report
(Compli nce Repo M ) is true and complete to the best of my knowledge.
Signature of Pe tt ' oroz Agent) ate

_
aoure txx z_
RAILROAD
TRACKS
�P �
SGALE
y
0 1000,
N
vl
J1
N
FIGURE 1. SITE MAP
itN°TF: A/l 3 51TFS ARE //VCoRo,,,,pATEJ)
p�RMIT WQO000bo/
E�END
COMPLIANCE DOGUVDARI
-' _ -- REVIEW DouNPJ(,vy
PRoPJERTy :GouNORR:
NON/TOR DELLS
t

TestAmedca
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Job Number: 680-62704-1
Job Description: CSX Hamlet, NC WWTP
For:
ARCADIS U.S., Inc. -
801 Corporate Center Drive
- Suite 300
Raleigh, NC 27607-5073
Attention: Mr. Alan Pinnix
AP�10,,;M,,,:
KB&�s�
P.J. Meager I
I19 101227 PM
Kathryn Smith
Project Manager I
[e-mail]
11 /09/2010
cc: Mr. Mike Gregory
LWON-EN V0000038652//Project-9522202
The test results in this report meet NELAP requirements for parameters for which accreditation is required or available.
Any exceptions to the NELAP requirements are noted. Results pertain only to samples listed in this report. This report
may not be reproduced, :except in full, without the written approval of the laboratory. Questions should be directed to the
person who signed this report.
Savannah Certifications and ID #s: A21-A: 0899.01; AL: 41450; ARDEQ: 88-0692; ARDOH; CA: 03217CA; CO; CT:
PH0161; DE; FL: E87052; GA: 803; Guam; HI; IL: 200022; IN; IA: 353; KS: E-10322; KY EPPC: 90084; KY UST; LA
DEQ: 30690; LA DHH: LA080008; ME: 2008022; MD: 250; MA: M-GA006; MI: 9925; MS; NFESC: 249; NV: GA00006;
NJ: GA769; NM; NY: 10842; NC DWQ:269; NC DHHS: 13701; PA: 68-00474; PR: GA00006; RI: LA000244; SC:
98001001; TN: TN0296; TX: T104704185; USEPA: GA00006; VT:VT-87052; VA: 00302; WA; WV DEP: 094; WV
DHHR: 9950 C; WI DNR: 999819810; WY/EPAR8: 8TMS-Q
TestAmerlca Laboratories, Inc
TestAmN ACC,, Savannah 5102 LaRoche Avenue, Savannah, GA 31404 1EOR„r Ao�y
Tel [phone] Fax [phone] www_teatarredrainc,com �a6 -"'
Page 1 of 27

CASE NARRATIVE
Client: ARCADIS U.S., Inc.
Project: CSX Hamlet, NC WWTP
Report Number: 680-62704-1
With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no
problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control
limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of
the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples,
the reporting limits are adjusted relative to the dilution required.
Calculations are performed before rounding to avoid round -off errors in calculated results.
All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the
individual sections below.
RECEIPT
The samples were received on 11/02/2010; the samples arrived In good condition, properly preserved and on Ice. The temperature of the
coolers at receipt was.1.4 C.
Note: All samples which require thermal preservation are considered acceptable if the arrival temperature is within .2-C of the required
temperature or method specified range. For samples with a specified temperature of 4 C, samples with a temperature ranging from just
above freezing temperature of water to 6 C shall be acceptable. Samples that are hand delivered immediately following collection may
not meet these criteria, however they will be deemed acceptable according to NELAC standards, if there is evidence that the chilling
process has begun, such as arrival on ice, etc.
Samples MW-2 (680-62704-1), MW-3 (680-62704-2), MW-4 (680-62704-3), MW-5 (680-62704-4), MW-7 (680-62704.5) and MW-8
(680-62704-6) were analyzed for total metals (ICPMS) in accordance with EPA Method 200.8. The samples were prepared on 1110212010
and analyzed on 11105/2010.
No difficulties were encountered during the metals analyses.
All quality control parameters were within the acceptance limits.
TOTAL DISSOLVED SOLIDS _
Samples MW-2 (680-62704-1), MW-3 (680-62704-2), MW-4 (68062704-3), MW-5 (680-62704-4), MW-7 (680-62704-5) and MW-8
(680627046) were analyzed for total dissolved solids in accordance with SM20 2540C. The samples were analyzed on 11102/2010.
No difficulties were encountered during the TDS analyses..
All quality control parameters were within the acceptance limits.
NITRATE -NITRITE AS NITROGEN
Samples MW-2 (68062704-1), MW-3 (68062704-2), MW-4 (68062704-3). MW-5 (68062704-4), MW-7 (68062704-5) and MW-8
(680627046) were analyzed for nitrate -nitrite as nitrogen in accordance with EPA Method 353.2. The samples were analyzed on
11/0212010.
Samples MW-2 (68062704-1)[5X] and MW-8 (680627046)[10X] required dilution prior to analysis. The reporting limits have been
adjusted accordingly.
No difficulties were encountered during the nitrate -nitrite analyses.
All quality control parameters were within the acceptance limits..
TOTAL ORGANIC CARBON
Samples MW-2 (68062704-1), MW-3 (68062704-2), MW-4 (68062704-3), MW-5 (68062704-4), MW-7 (680-62704-5) and MW-8
(680627046) were analyzed for total organic carbon in accordance with SM 5310B. The samples were analyzed on 11/06/2010.
No difficulties were encountered during the TOC analyses.
All quality control parameters were within the acceptance limits.
Page 2 of 27

METHOD SUMMARY
Client: ARCADIS U.S., Inc.
Job Number.. 680-62704-1
Description
Lab Location
Method Preparation Method
Matrix Water
Metals (ICP/MS)
TAL SAV
EPA 200.8
Preparation, Total Metals
TAL SAV
EPA 200.8
Nitrogen, Nitrate -Nitrite
TAL SAV
MCAW W 353.2
Solids, Total Dissolved (TDS)
TAL SAV
SM SM 2540C
Organic Carbon, Total (TOC)r
TAL SAV
SM SM 5310B
Lab References:
TAL SAV = TestAmedca Savannah
Method References:
EPA = US Environmental Protection Agency
MCAWW = "Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March 1983 And Subsequent Revisions.
SM = "Standard. Methods For The Examination Of Water And Wastewater",
G
TestAmerica Savannah
Page 3 of 27

METHOD/ANALYST SUMMARY
Client: ARCADIS U.S., Inc.
Job Number. 680-627041
Method _
Analvst
Analyst ID
EPA 200.8
Robertson, Bryn
BR
MCAWW 353.2
Ross, Jon
JR
SM SM 2540C
Robinson, Tiffany
TR
SM SM 5310B
Holmes, Tinita
TH
TestAmerica Savannah
Page 4 of 27

% y
SAMPLE SUMMARY
Client: ARCADIS U.S., Inc.
680-62704-1
MW-2
Water
680-62704-2
MW-3
Water
680-62704-3
MAN-4
Water
• 680-627044
MW-5
Water
680-62704-5
MW-7
Water
.680-62704-6
MW-8
Water
e
TestAmerica Savannah
Date/Tlme
Sampled
11/01/2010 1545
11/01/2010 1605
11/01/2010 1510
11/01/2010 1620
11/01/20101450
11/01/2010 1430
Job Number: 680-62704-1
Date/Time
Received
11/02/2010 0935
11/02/2010 0935
11/02/2010 0935
11/02/2010 0935
11/02/2010 0935
11/02/2010 0935
Page 5 of 27

L !
Analytical Data
Client: ARCADIS
U:S., Inc.
Job Number. 680-62704-1
Client SamplelD:
MW-2
Lab Sample ID:
680-62704-1
Client Matrix
Water
Date Sampled: 11/01/2010 1545
Date Received: 11/02/2010 0935
200.8 Metals (ICP/MS)
Method:
200.8
Analysis Batch: 680-185270
- -
Instrument ID:
ICPMSB
Preparation:
200.8
Prep Batch: 680-184861
Lab File ID:,
184861.chr
Dilution:.
1.0
Initial Weight/Volume: 50 mL
Date Analyzed:
11/05/2010 1140
_
Final WeighWolume:. 250 mL
Date Prepared:
11/02/2010 1558
Analyte
Result (mg/L)
Qualifier
MOL
RL
Arsenic
0.050 -
U
0.0013
0.050
Barium
0.0062
J
0.0014
2.0
Cadmium
0.00014
J
0.00013
0.0018
Chromium
0.050
U
0.0025
0.050
Lead
0.015
U
0.00050
0.015
TestAmerlcaSavannah Page 6 of 27

Analytical Data
Client: ARCADIS
U.S., Inc.
Job Number: 680-62704-1
Client Sample ID:
MW.9
Lab Sample ID:
680-62704-2
Date Sampled: 11/01/2010 1605
Client Matrix -
Water
Date Received: 11/02/2010 0935
200.8 Metals (ICPIMS)
Method:
200.8
Analysis Batch: 680-185270
Instrument ID: ICPMSB
Preparation:
200.8
Prep Batch: 680-184861
Lab File ID: 184861.chr
Dilution:
1.0
-
Initial WeighWolume: 50 mL
Date Analyzed:
11/05/2010 1202
Final WeighWolume: 250 mL
Date Prepared:
11/02/2010 1558
Arsenic
Barium
Cadmium
Chromium
Lead
Result (mg/L)
Qualifier
:MDL
RL
0.050
U
0.0013
0.050
0.0094
J
0.0014
2.0
0.00077
J
0.00013
0.0018
0.050
U
0.0025
0.050
0.015
U
'0.00050
0.015
TestAmerlea Savannah Page 7 of 27

V l
Client: ARCADIS U.S., Inc.
Analytical Data
Job Number: 680-627041
Client Sample ID:
MW-4
Lab Sample ID:
680-627043
Client Matrix
Water
Date Sampled: 11/01/2010 1510
Date Received: 11/02/2010 0935
200.8 Metals (ICP/MS)
Method:
200.8
Analysis Batch: 680-185270
Instrument ID: ICPMSB
Preparation:
200.8
Prep Batch: 680-184861
Lab File ID:,' 184861.chr
Dilution: -
1.0
Date Analyzed:
11/05/2010 1209
Initial Weight(Volume: 50 mL
Dale Prepared:
11/02/2010 1558
Final WeighWolume: 250 mL
Barium
Cadmium
Chromium
Lead
Result (mg/L)
Qualifier
MDL
RL
0.050
U
0.0013
0.050
2.0
U
0.0014
2.0
0.0013
J
0.00013
0.0018 -
0.050 -
U
0.0025
0.050
0.015
U
0.00050
0.015
7estAmerlca Savannah Page 8 of 27

Analytical Data
Client: ARCADIS U.S., Inc. Job Number: 680-62704-1
Client Sample ID: MW-5
Lab Sample ID:
680-62704-4
Date Sampled: 11/0112010 1626
Client Matrix:
Water
Date Received: 11/02/2010 0935
200.8 Metals (ICPIMS)
'
Method:
200.8
Analysis Batch: 680-185270 -
Instrument ID: ICPMSB
Preparation:
200:8
Prep.Balch: 680-184861
Lab File ID: 184861.chr
Dilution:
1.0
Initial WeighWolume: 50 mL
Date Analyzed:
11/05/2010 � 1216
Final WeighWolume: 250 mL
Date Prepared:
11/02/2010 1558
Arsenio
Barium
Cadmium
Chromium
Lead
Result (mg/L)
Qualifier
.MDL
RL
0.050
U
0.0013
0.050
0.019
J
0.0014
2.0
0.00013
J
0.00013
0.0018
0.050
U
0.0025
0.050.
0.015
U
0.00050
0.015
TestAmericaSavannah Page 9 of 27

Analytical Data
Client: ARCADIS
U.S., Inc.
Job Number: 680-62704-1
Client Sample ID:
MW-7
Lab Sample ID:
660-62704-5
Date Sampled: 11/01/2010 1450
Client Matrbc
Water
Date Received: 11/0212010 0935
200.8 Metals (ICPIMS)
Method:
200.8
Analysis Batch: 680-185270
Instrument ID:
ICPMSB
Preparation:
200.8
Prep Batch: 680-184861
Lab File ID:
184861.chr
Dilution:
1.0
Initial Weight/Volume:
50 mL
Date Analyzed:
11/05120101223
Final Weight/Volume:
250 mL
Date Prepared:
11/02/2010 1558
'
Analyte
Result (mg/L)
Qualifier
MDL
RL
Arsenic
0.050
U
0.0013
0.050
Barium
0.0079
J
0.0014
2.0
Cadmium
0.0010
J
0.00013
0.0018
Chromium
0.050
U
0.0025
0.050
Lead
0.015
U.
0.00050
0.015
TestAmerica Savannah Page 10 of 27

Analytical Data
Client: ARCADIS
U.S., Inc.
Job Number: 680-62704-1
Client Sample ID:
MW-8
Lab Sample ID:
680-62704-6
Client Matrix:
Water
Date Sampled: 11/01/2010 1430
Date Received: 11/02/2010 0935
200.8 Metals (ICP/MS).
Method:
200.8
Analysis Barth: 680-185270
Instrument ID: ICPMSB
Preparation:
200.8 ,
.Prep Balch: 680-184861
Lab, File ID: 184861.chr
Dilution:
1.0
Initial Weightrolume: 50 mL
Date Analyzed:
11/05/2010 1230
Date Prepared:
11/02/2010 1558
Final Weight&olume: 250 mL
Barium
Cadmium
Chromium
Lead'
Result (mg/L)
Qualifier
MDL -
RL
0.050
U -
0.0013
0.050
0.057
J
0.0014
2.0
0.00042
J
0.00013
0.0018
0.050
U
0:0025
0.050
0.015
U
0.00050
0.015
TestAmerica Savannah Page 11 of 27

Analytical Data
Client: ARCADIS U.S., Inc.
Job Number. 680-62704-1
General chemistry
Client Sample ID: 11 W-2 '
Lab Sample ID: 68"2704.1
Client Matrix: Water Date Sampled: 11/01/2010 1545
Date Received: 11/02/2010 0935
Analyte Result
Qual Units MDL
RL
Nitrate as N 1.3
oil
Method
Analysis Batch: 680-185035
mg/L 0.050
Date Analyzed: 11/02/2010 1604
0.25
5.0
353.2
Total Organic Carbon 1.7
" Analysis Batch: 680.185388
mg/L 0.50
Date Analyzed: 11/06/20102107
1.0
1.0
SM 53108
Malyte Result
Qual Units RL
RL
Total Dissolved Solids 71 -
DiI
Method
Analysis Batch: 680-184875
mg/L 5.0'
Date Analyzed: 11/02/2010 1804
5.0
1.0
SM 2540C
TestAmerlca Savannah
Page 12 of 27

Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 680-62704-1 ,
General Chemistry
Client Sample ID: MW-3
Lab Sample ID: 680-62704-2
Client Matrix: Water
Date Sampled: 11/01/2010 1605
Date Received: 11/02/2010 0935 a
Analyte Result
Nitrate as N
Qua[ Units MDL
RL
Dil Method
1.2
Analysis Batch: 680-185035
mg1L 0.010
Date Analyzed: 11/02/2010 1554
. 0.050
1.0 353 2
Total Organic Carbon 1.0
U mg/L 0.50
1.0,
Analysis Batch: 680-185388
Date Analyzed: 11/06/2010 2121
1.0 SM 53106
- Analyte Result
Total Dissolved Solids
Qual Units RL
RL
DII Method
43
Analysis Batch: 680d84875
mglL 5.0
Date Analyzed: 11/02/2010 1804
5.0
1.0 SM 2540C
n
TestAmeriea Savannah Page 13 of 27

Analytical Data
Client: ARCADIS U.S., Inc.
Jab Number. 680-62704-1
General Chemistry
Client Sample ID: Myy.4
.Lab Sample ID: 680-62704-3
Client Matrix Water Date Sampled: ,11/01/2010 1510
Date Received: 11/02/2010 0935
Analyte Result
Nitrate as N
dual Units MDL
RL
Dill
Method
0
Analysis Batch: 680-185035
mg/L 0.010
Date Analyzed: 11/02/20101556
0.050
1.0
353.2
Total Organic Carbon 1.0
.
Analysis: Batch: 680-185388
Date Analyzed: 11 0612010 2135 50
1.0
1.0
SM 53106
4nalyte Result
total Dissolved Solids
Dual Units RL
RL
oil
Method
43
Analysis Batch: 680-184875
mg/L 5.0
Date Analyzed: 11/02/2010 1804
5.0
1.0
SM 2540C
TestAmariea Savannah Page 14 of 27

Client: ARCADIS U.S., Inc. Analytical Data
Job Number. 680-62704-1
General Chemistry
Client Sample to:
Mw-5
Lab Sample ID:
680-62704-4
Client Matrix:
Water
Analyte
Nitrate as N
Result
Qua] Units MDL
1.0
Analysis Balch: 680-185035
mg/L 0.01(
Date Analyzed: 11/02/20101557
Total Organic Carbon 0.94
Analysis Batch: 680-185388
bate Analyzed: 1106/2010223550
Ana[yte Result
Total Dlssolved Solids
Qua[ Units RL
58
Analysis Batch: 680-184875
Date Analyzed: 1r1 O2/2010 1804 0
Dale Sampled: 11/01/2010 1620
Date Received: 11/02/2010 0935
RL Dil Method
0.050 1.0 353.2
1.0 1.0 SM 53103
RL. Dil Method
To 1 n `ene �e.nr
TesfAmerlca Savannah
Page 15 of 27

I
Analytical Data
Client: ARCADIS U.S., Inc. Jab Number: 680-62704-1
General Chemistry
Client Sample ID: MW-7
Lab Sample ID: 680-627045 Client Matrix: Water Date Sampled: 11/01/2010 1450
Date Received: 11/02/2010 0935
Analyte Result
Qua[ Units MDL
RL
Dil
Method
Nitrate as N 1.9
mg/L 0.010
0.050
1.0
353.2
Analysis Batch: 680-185035
Date Analyzed: l l/02/2010 1558
Total Organic Carbon 0.85
J mg/L 0.50
1.0
Analysis Batch: 680-185388
Date Analyzed: 11/06/2010 2319
1.0
SM 53108
-
Analyte Result
Total Dissolved Solids
Qua] Units RL
RL
Dl
Method
46
Analysis Batch: 680-184875
mg/L 5.0
Date Analyzed: 11102/20101804
5.0 ,.
1.0
SM 2540C
TestAmerica Savannah Page 16 of 27

I
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 680-62704-1
_
General chemistry -
CllentSampleim MW-8
Lab Sample ID: 680-62704-6
Client Matrix: Water
-
Date Sampled: 11/01/2010 1430
.Date Received: 11/02/2010 0935
Analyte Result
Nitrate as N
Qual Units MDL
RL
Dil Method
11
Analysis Batch: 680-185035
mg/L 1.0.10
Date Analyzed: 11/02/2010 1612
0.50
10 353.2
Total Organic Carbon 1.5
Analysis Batch: 680-185388
mg/L 0.50
Date Analyzed: 11/0612010 2335 .
1.0
1.0 SM 53108
TotaAnall Di Result
T
Total ssolved Solids 150
Qual Units RL
RL
Dil Method
Analysis Batch: 680-184875
mg/L 6.0
Date Analyzed: 11102/20101804
5.0
1.0 SM'2540C
t
TestAmerica Savannah Page 17 of 27

Client ARCADIS U.S., Inc.
Metals
General Chemistry
TastAmerlta Savannah
DATA REPORTING QUALIFIERS
Job Number. 680-627041
U Indicates the analyte was analyzed for but not detected.
J Result is less than the RL but greater than or equal to the
MDL and the concentration is an approximate value.
U Indicates the analyte was analyzed for but not detected.
J Result is less than the RL but greater than or equal to the
MDL and the concentration is an approximate value.
Page 18 of 27

Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number. 68D-62704-1
Method. Blank - Batch: 680-184861
Method: 200.8
"
Preparation: 200.8
'Lab Sample ID:
Client Matrix: .
MB 680-184861113-A Analysis Batch: 680-185270
Water
Instrument ID: ICPMSB
Dilution:
Prep Batch: 680-184861
1.0
Lb File I
aD: 184861.chr
Date Analyzed:
Units: mg/L
11/05/2010 1001
Initial WeightlVolume: 50 mL
Date Prepared:
11/02/2010 1558
Final Weight/Volume: 250 mL
Analyte
Result
Qua[
MDL
RL
Arsenic
Barium
0.050
U
0.0013
0.050
Cadmium
2
U
0.0014
2.0
Chromium
.0018
U
0.00013
0.0018
Lead
0.001
U
0.0025
0.050
0.015
U
0.00050
0.015
Lab Control Sample -Batch: 680-184861
Method: 200.8
Preparation: 200.8
Lab Sample ID:
LCS 680-184861/14-A
Analysis Batch: 680-185270
Client Matrix:
Water
Prep Batch: 680-184861
Instrument ID: ICPMSB
Dilution:
1.0
Lab File ID: 184861.chr
.Dale Analyzed:
11/05/2010 1008
Units: mglL
Initial Weight/Volume: 50
mL
Date Prepared:
11/02/2010 1558
Final Weight/Volume: 250
mL
Analyte
Spike Amount
Result
Rec. -
Umit
Arsenic
Qua[
Barium
0.100
0.105
105
85 - 115
Cadmium
0.100
0.106
106 -
85 - 115 J
Chromium
0.0500
0.0514
103
85-115
'Lead
0100
0.108
108
85 -115
0.0500
0.0549
110
85-115
TestAmerica Savannah Page 19 of 27

Client: ARCADIS U.S., Inc.
Matrix Spike/
Matrix Spike Duplicate Recovery Report - Batch: 680-184861
MS Lab Sample ID: 680-62704-1
Client Matrix: Water
Dilution:
1.0
.Date Analyzed:
11/05/2010 1148
Date Prepared:
11/02/2010 1558
MSD Lab Sample ID:
680-62704-1
Client Matrbc
Water
.Dilution:
1.0 .
Date Analyzed:
11/05/2010 1155
Data Prepared:
11/02/2010 1558
Analyte
Arsenic
Barium
Cadmium
Chromium
Lead
Analysis Batch: - 680-185270
Prep Batch: 680-184861
Analysis Batch: 680-185270
Prep Batch: 680-184861
%Rea
MS
MSD
Limit
102
100
75 -125
103
104
75 -125
100
98
75 -125
103
101
75-125
106
104
75 - 125
Quality Control Results
Job Number. 680-62704-1
Method: 200.8
Preparation: 200.8
Instrument ID: ICPMSB
Lab File. ID: 184861.chr
Initial WeighWolume: 50 mL
Final WeighWolume: 250 mL
Instrument ID: ICPMSB.
Lab File to:. ' 184861.chr
Initial WeighWolume: 50 mL
Final WeighWolume: 250 mL
RPD RPD Limit MS Qua] MSD Qual
2 20
1 20
J
J
1 20
1 20
2 20
TestAmertca Savannah
Page 20 of 27
a

Client ARCADIS U.S., Inc.
Method Blank -Batch: 680-185035
Lab Sample ID: MB 680-185035/13 Analysis Batch: 680-185035
-Client Mabix: Water Prep Batch: WA
Dilution: 1.0 Units: mg/L
Date Analyzed: 11/02/2010 1548
Date Prepared: N/A
Analyle Result
Nitrate as N 0.050
Lab Control Sample - Batch: 680.185035
Lab Sample ID:
LCS 680-185035/14 Analysis Batch: 680-185035
--Client Matrix:
Water Prep Batch: N/A
Dilution:
1.0 'Units: mg[L
Date Analyzed:
11/02/2010 1549
Date Prepared: WA
Analyte Spike Amount Result
Nitrate as N0.500
0.501
Matrix Spike/
Matrix Spike Duplicate Recovery Report - Batch: 680.185035
MS Lab Sample ID: 680-62704-1
Client Matrix:
Water
Dilution:
5.0
Date Analyzed:
11/02/2010. 1607
Date Prepared:
NIA
MSD Lab Sample ID: 680-62704-1
Client Matrix:
Water
Dilution:
5.0
Date Analyzed:
11/02/2010 1610
Date Prepared:
N/A
Analyte
Nitrate as N
Analysis Barth: 680-186035
Prep Batch: WA
Analysis Batch: 680-185035
Prep Batch: N/A
% Rec,
MS MSD
94 94
Limit
Quality Control Results
Job Number. 680-62704-1
Method: 353.2
Preparation: N/A
Instrument 10: Latchat2
Lab File ID: OM-1 1-2-201015-21-37.OM
Initial WeighWolume: 2 mL
Final WeighWolume: 2 mL
Qual MDL
RL
U 0.010
0.050
Method: 353.2
Preparation: WA
Instrument ID: Latchat 2
Lab.File ID; OM 11-2-2010_15.21-37.OM
Initial Weight/Volume:2
mL
Final Weight/Volume: 2
mL '
% Rec. Limit Qua]
100
Method: 353.2
Preparation: N/A
Instrument ID: Latchat 2
Lab File ID: OM_11-2-2010 15-21-37.Ot
InitialWeighWolume: 10 mL
Final WeighWolume: 10 mL
Instrument ID: Latchat2
Lab File ID: OM 11-2-2010_15-21-37.OM
Initial Weight/Volume: 10 mL
Final Weight/Volume: 10 mL
RPD RPD Limit Ms Qual MSD Qual
0
TestAmedca Savannah Page 21 of 27

i
Client:, ARCADIS U.S., Inc.
Method Blank - Batch: 680-184875
Lab Sample ID:
MB 680-18487511
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
11/02/2010 1804
Date Prepared:
NIA
Analysis Batch: 680-184875
Prep Batch: WA
Units: mg&
Quality Control Results
Job Number: 680-62704-1
Method: SM 2540C
Preparation: WA
Instrument ID: No Equipment Assigned
Lab File ID: N/A
Initial WeighWolume: 100 mL
Final Weight/Volume: 100 mL
Analyte Result
Qual RL RL
Total Dissolved Solids 5.0
5.0 5.0
Lab Control Sample/
Lab Control Sample Duplicate Recovery Report - Batch: 680.184875 Method: 2'
Preparationon : N//AA
LCS Lab Sample ID: LCS 680-18487512 Analysis Batch: 680-184875
Client Matrix: Water Instrument ID: No Equipment Assigned
Prep Batch: WA Dilution: 1.0 Lab File ID: N/A
Units: mg/L
Date Analyzed: 11/02/2010 1804. Initial WeighWolume: 100 mL
Date Prepared: N/A Final WeighWolume: 100 mL
LCSD Lab Sample ID: LCSD 680-18487513 Analysis Batch: 680-184875
Client'Matdx: Water Instrument ID: No Equipment Assigned
Prep Batch: N/A Lab File ID: WA
Dilution: 1.0 Units: mg/L
-Date Analyzed: 11/02/2010 1804 Initial WeighWolume: 100 mL
Date Prepared: WA Final WeighWolume: 100 mL
%Rec
Analyte LCS LCSD Limit RPD RPD Limit LCS Qua] LCSD Qual
Total Dissolved Solids 98 101 80 - 120 3
25
Duplicate - Batch: 680-184876
Method: SM 2640C
Preparation: N/A
Lab Sample ID: 680-62704-1 Analysis Batch: 680-184875
Client Matrix.-" Water InstrumentID: No Equipment Assigned
Prep Batch: N/A Lab File,ID: , N/A
Dilution: 1.0 Units: mg/L
Date Analyzed: 11/0212010 1804 Initial WeighWolume: 100 mL
Date Prepared: WA Final WeighWolume: 100 mL
Analyte Sample Result/Qual Result
RPD Limit Qual
Total Dissolved Solids 71
74.0 4 25
TestAmerlcaSavannah Page 22 of 27

Client. ARCADIS U.S., Inc.
Method Blank - Batch: 680.186388
Quality Control Results
Job Number: 680-62704-1
Method: SM 5310B
Preparation: WA
Lab Sample ID: MB 680-18538812
Analysis Batch: 680-185388
Client Matrix: Water
Prep Batch: N/A
Instrument ID: TOC3
Dilution: 1.0
Units: mg/L
Lab File ID: TOC110610.bd
Date Analyzed: 11/06/2010 1412
Initial WeighWolume: 25 mL
Date Prepared: WA
Final WeighWolume: 25 mL
Analyte
Total Organic Carbon -
- Result Qua]
MDL RL
1.0 U
0.50 1.0
Method Blank - Batch: 680-t85388
-
Method: SM 5310B
Preparation: N/A
Lab Sample ID: MB 680-185388133
Analysis Batch: 680-185388
Client Matrix: Water
'Prep Batch: N/A
Instrument ID: TOC3
Dilution: 1.0
Units: mglL
Lab File ID: TOC110610.txt
Date Analyzed: 11/06/2010 2204
Initial WeighWolume: 25 mL
Date Prepared: WA
Final WeighWolume: 25 mL
Analyte
TotalOmani�r a,.,.,
Result Qua[
_
MDL RL
1.0 U
1.0
TestAmerica Savannah Page 23 of 27

L
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 680-62704-1
Lab Control Sample - Batch: 680-185388
Method: SM 5310B
Preparation: NIA
Lab Sample ID: LCS 680-185388/4
Analysis Batch:
680-185388
Instrument ID: TOC3
Client Matrix: Water
Dilution: 1.0
Prep Batch: WA
Lab File ID: TOC110610.txt
Date Analyzed: 11/06/2010 1442
Units: mg/L
Initial WeighWolume: 25 mL
Dale Prepared: WA
Final WeighWolume: 25 mL
Analyte
Spike Amount
Result
%Rea Limit Oual
Total Organic Carbon
20.0
20.0
100
80 - 120
Lab Control Sample - Batch: 680-186388
Method: SM 5310E
Preparation: NIA
Lab Sample ID: LCS 680-185388134
Analysis Batch: 680-185388
Instrument ID: TOC3
Client Matrix: Water
Dilution:
Prep Balch: WA
Lab File ID: TOC110610.tM
1
Date Analyzed: 11/06/2010 2220
Units:' mg/L
Initial WeighWolume: 25 mL
Date Prepared: WA
Final WeighWolume: 25 mL
Analyte
Spike Amount
Result
%oRec. Limit Qual
Total Organic Carbon `
20.0
19.8
gg ,
80 -120
Matrix Spike/
Matrix Spike Duplicate Recovery Report- Batch: 680-185388
Method: SM 5310B
Preparation: N/A
MS Lab Sample ID: 680-62704-4
Analysis Batch: 680-185388
Instrument ID: TOC3
Client Matrix: Water
Dilution:
Prep Batch: WA
Lab File ID: TOC110610.txt
1.0
Date. Analyzed: 11/06/2010 2251
Initial WeighWolume: 25 mL
Date Prepared: NIA
Final WeighWolume: 25 mL
MSD Lab Sample ID: 680-62704-4
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
11/06/2010 2304
Date Prepared:
WA
Analyte
Total Organic Carbon
Analysis Batch: 680-185388
Prep Batch: WA
. %Rec.
MS MSD Umit
99 97 80 -120
Instrument ID: TOC3
Lab. File ID: TOC110610.txt
Initial Weight/Volume: 25 mL
Final WeighWolume: 25 mL
RPD RPD. Limit MS Qua] MSD Qual
1 25
TestAmerica Savannah Page 24 of 27

Client ARCADIS U.S., Inc.
Duplicate -Batch: 680-185388
Lab Sample ID:
680-62625=F-9 DU
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
11/O6/2010 1819
'Date Prepared:
WA
Analyte
Total Organic Carbon
Analysis Batch: 680-185388
Prep Batch: WA
Units: mg& -
Sample ResultlQual
7.5
Quality Control Results
Job Number: 680-62704-1
Method: SM 5310B
Preparation: N/A
Instrument ID: TOC3
Lab File ID: TOC110610.bd
Initial WelghWolume: 25 mL
Final WeighWolume: 25 mL
Result RPD Limit Qual
7.43 0.6 25
TestAmerlca Savannah
Page 25 of 27

TRANSPORTA770N
TAL-6006 0907 t
T PROJECT INFORMATION
/TostAmerlca Savannah-51021.aeoC: a Avenue, 5annnah, GA 31404 P: B12-354.7858 F: 912-352-0165 COCK
CHAIN OF O TeslAmedca North Canton- 4101 Shu0ot Drive NW,North Croton, OH 44720 P:33OA97.9396 F:330.497-0772 SHIPMENT INFORMATION
CUSTODY 0 TestAmerica Tampa- 6712 Benjamin Road, Sulte Its, Tampa, FL 33634 P:813.885-7427 Fd813.885-7049
❑TBSrAmadca Pensacola-3355MCLemore Drlve.Ponsacale,FL32514 P;650-474-1001 F85GA78-2671 Shipment Method: �^'
❑TOStAmedra BUUaID'IOHUOMOOd Ddve,SultotOB,Ambamt.NY14228 P:716.691-2600 F:716.961-7991 eJ
❑70SIAmerlca Chicago -2417 Bond Slreel, University Park, IL 60466 P:798.534-520D F:708-534.5211 W'Pmenl Tracking No:
Prof. slate (slate of Origin) CONSULTANT INFORMATION Project l:
PO . — ce n A%C IO2.037.
Z Ha 1 11- maB r a C t4� 1: a PM: At _
iumaround Time:
❑ Standard 6.13 Days
r— sv4a]c.
Preservative
nL Kwlr.i
C Z
❑ 1 Day Rush
Codes:
3 - Sulfuric Acid
Note
•
❑' 2 Day Rush
�,�S5��Specity Or Days
ID(i/Siandard
O = No Preservatives
4 e Sodium Thiosullate
Pres.
❑ 3 Day Rush
14 Days
1 = Hydrochloric Acid
5 = Sodium Hydroxicle
Code
LKJ Other
2 - Nitric Acid
6 = Other
Deliverables:
❑ Other Deliv:
CSXT Standard (Level
ll)
Matrix Codes;
SO =Soil LIO =Liquid
W
Level III
❑ EDD Required, Format:
GW = Gmundwater
SL=Sludge
ID
Level IV
WOW c Waste Water
01=Oil
SW a"Surface Water
SOL=Other Solid
N
SAMPLE INFORMATION
o,
h
Irt
Containers
Sample Identification
Sam to
Collection
Filtered
T e
Matrix
-P
N
Number&
Type
Date
Time
Sampler
YoOr
cc
Code
U
.f
or
w—.:?
�-3
am
�SYr
T
1
0a
e
60S
/Siv
D7-
nr
iV
Al
&'b
is
/6
DT-
Al
-,,,,G
lyS-o
PIT
Al
G,"
Hecelved By:
-1 -2ota / Ba
DaterTMa: RaceHed BY:
Daterrime: I Rar hi R.
o 9 ) _ice —1
6
METHODS FOR ANALYSIS
Gu
X
I X
b<
6-wxxxx
�wxx><u
DatarTlme:
Data711me:
Daterlune:
Cr c%,J I p
e Lob Remarks' LAB USE: C ffcy mount Custody Seal B LAB I
❑Y s ❑N e a
0 INVOICE MUST BE SUB7ATTTED TO CSXT WITH ORIGINAL COG
- fao?'7

Login Sample Receipt Check List
Client: ARCADIS U.S., Inc.
Login Number. 62704
Creator. Daughtry, Beth
List Number. 1
Question
Radioactivity either was not measured or, if measured, is at or below
background
The coolers custody seal, if present, is intact
The cooler or samples do not appear to have been compromised or
tampered with.
Samples were received on ice.
Cooler Temperature is acceptable.
Cooler Temperature is recorded.
COC is present.
COC is filled out in ink and legible,
COC is filled out with all pertinent information.
Is the Field Sampler's name present on COC?
There are no discrepancies between the sample IDS on the containers and
the COC.
Samples are received within Holding Time.
Sample containers have legible labels.
Containers are not broken or leaking.
Sample collection date/fimes are provided.
Appropriate sample containers are used.
Sample bottles are completely filled.
Sample preservation Verified '
There is sufficient vol. for all requested analyses, Ind. any requested
MS/MSDs
VOA sample vials do not have headspace or bubble is <6mm (1/4') in
diameter.
If necessary, staff have been informed of any short hold time or quick TAT
needs
Multiphasic samples are not present.
Samples do not require splitting or compositing.
TestAmerica Savannah
T/F/NA
N/A
True
True
True
True
True
True
True
True
False
True
True
True
True
True
True
True
True
True
N/A
True
N/A
N/A
Job Number. 680-62704-1
List Source: TestAmedca Savannah
Page 27 of 27

TestAmedca
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Job Number: 680-63468-1
Job Description: CSX Hamlet, NC WWTP
For:
ARCADIS U.S., Inc.
801 Corporate Center Drive
Suite 300
Raleigh, NC 27607-5073 .
Attention: Mr. Alan Pinnix
Lr yj/�
PpprneE lxnluu.
IVj�AI �U1Y�./
th
¢. 'smtm
PmlMe u .I
i1M29199�9 PM
Kathryn Smith
Project Manager I
[e-mail]
11 /30/2010
cc: Mr. Mike Gregory
LW ON-ENV0000038652//Project-9522202
The test results in this report meet NELAP requirements for parameters for which accreditation is required or available.
Any exceptions to the NELAP requirements are noted. Results pertain only to samples listed in this report. This report
may not be reproduced, except in full, without the written approval of the laboratory. Questions should be directed to the
person who signed this report.
Savannah Certifications and ID #s: A2LA: 0399.01; AL: 41460; ARDEQ: 88-0692; ARDOH; CA: 03217CA; CO; CT:
PH0161; DE; FL: E87052; GA: 803; Guam; HI; IL: 200022; IN; IA: 353; KS: E-10322; KY EPPC: 90084; KY UST; LA
DEQ: 30690; LA DHH: LA080008; ME: 2008022; MD: 250; MA: M-GA006; MI: 9925: MS; NFESC: 249; NV: GA00006;
NJ: GA769; NM; NY: 10842; NC DWQ: 269; NC DHHS: 13701; PA: 68-00474; PR: GA00006; RI: LA000244; SC:
98001001; TN: TN0296; TX: T104704185; USEPA: GA00006; VT: VT-87052; VA: 00302; WA; WV DEP: 094; WV
DHHR: 9950 C; WI DNR: 999819810; WY/EPAR8: 8TMS-Q
TestAmerica laboratories, Inc. �x Accoy
tEo o*y
TestAmerica Savannah 5102 LaRoche Avenue, Savannah, GA 31404
Tel [phone] Fax [phone]. www.testamedcainc.com
Page 1 of 11

Job Narrative
680-63468-1
Comments
No additional comments.
Receipt
All samples were received in good condition within temperature requirements.
General Chemistry
Method(s) 353.2: Due to the high concentration of nitrate, the matrix spike / matrix spike duplicate (MS/MSD) for batch 187296 could not
be evaluated for accuracy and precision. The associated laboratory control sample (LCS) met acceptance criteria.
No other analytical or quality Issues were noted.
Page 2 of 11

t
i
METHOD SUMMARY
Client: ARCADIS U.S., Inc.
Job Number 680-63468-1
YIVY
Matrix Water
Nitrogen, Nitrate -Nitrite TAL SAV MCAWW 353.2
Lab References:
TAL SAV = TestAmerica Savannah
Method References:
MCAWW = "Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March 1983 And Subsequent Revisions.
TestAmedca Savannah Page 3 of 11

METHOD/ANALYST SUMMARY
Client: ARCADIS U.S., Inc.
Job Number. 680-63468-1
Method Analvat .
Analyst ID
MCAWW 353.2 Ross,Jon
JR
TestAmeriea Savannah
Page 4 of 11

SAMPLE SUMMARY
Client ARCADIS U.S., Inc.
Job Number. 680-63468-1
Lab Sample ID Client Sample ID Date/rime Date/rlme
Client Matrix Sampled Received
680-63468-1 MW4 Water 11/23/2010 1500 11/24/2010 0938
TestAmerlca Savannah Page 5 of 11

Analytical Data
Client ARCADIS U.S., Inc.
Job Number. 680-63468-1 "
General Chemistry '
Client sample ID:
MW-8
Lab Sample ID:
680-63468-1
Client Matrix:
Water
as
ttesult Qual Units MDL
10 mg/L 0.10
Analysis Batch:680-187296 Date Analyzed: 11/24/2010 1649
Date Sampled: 11/23/2010 1506
Date Received: 11/24/2010 0938
oil Method
7estAmerlea savannah Page 6 of 11

DATA REPORTING QUALIFIERS
Client: ARCADIS U.S., Inc.
Lab Section Qualifier Descrt lion
General Chemistry
TestAmerIca Savannah
Job Number. 68463468-1
U Indicates the analyte was analyzed for but not detected.
4 MS, MSD: The analyte present in the original sample is 4
times greater than the matrix spike concentration; therefore,
control limits are not applicable.
Page 7 of 11

Quality Control Results'
Client ARCADIS U.S., Inc.
Job Number. 680-63468-1
Method Blank - Batch: 680-187296
Method: 353.2
Preparation: NIA
.Lab Sample ID: MB 680-187296/1 Analysis Batch: 680-187296
Client Matrix: Water Instrument ID: Latchat 2
Prep Batch: WA Dilution: 1.0 Units: mg/L Lab File ID: - OM_11-24-2010 15-49.41.Oh
'
-Date Analyzed: 11/24/2010 1616 Initial WeighWolume: 2 mL
Date Prepared: WA Final WeighWolume: 2 mL
Analyte
Result
Qua[
MDL
RC
Nitrate as N
Nitrate Nitrite as N
0.0500050
U
0.010
0,050
Nitrite as N
.
U
0.010
0.050
0.050
U
0.010
0.050
Lab Control Sample. Batch: 680-187296
Method: 363.2
Preparation: NIA
Lab Sample ID: LCS 680-18729612
Analysis Batch: 680-187296
Client Matrix: Water
Instrument ID: Latchat P
Dilution: 1.0
Prep Batch: WA
Lab File ID: OM_11-24-201015-4g-01.O&
Date Analyzed: 11/24/2010,1617
Units: mglL
Initial WeighWolume: 2
_
mL
Date Prepared: N/A
Final WeighWolume: 2
mL
Analyte
Spike Amount
Result
%Rea.
Limit
Nitrate as N
Oual
Nitrate Nitrate as N
0.00
0.49
100
Nitrite as N
1.00
0.996 ,
100
90 - 110
-
0.500
0.497
99
90 - 110
TestAmerlca Savannah Page 8 of 11

Client ARCADIS U.S., Inc.
Matrix Spike/
Matrix Spike Duplicate Recovery Report - Batch: 600.187298
Quality Control Results
Job Number: 680-63468-1
Method: 363.2
Preparation: WA
MS Lab Sample ID:
Client Matrix:
680-63468-1
Water
Analysis Batch:
680-187296
Instrument ID: Latchat 2
Dilution:
ip
Prep Batch: WA
'�
Lab File ID: OM_11-24-2010_15-49-01.0
Date Analyzed:
11/24/2010 1652
Initial WeighWolume: 10 mL
Date Prepared:
N/A
Final WeighWolume: 10 mL
MSD Lab Sample ID:
Client Matrix:
680-63468-1
Water
Analysis Batch:
680-187296
Instrument ID: Latchat 2
Dilution: -
10
Prep Batch: N/A
Lab File ID: OM_111-24-2010 154941.oh
Date Analyzed:
11/24/2010 1654
Initial WeighWolume: 10 mL
Date Prepared:
N/A
Final WeighWolume: 10 mL
Analyte
%Rec.
MS MSD
Limit
RPD RPD Limit MS Qual MSD Qua]
Nitrate as N
74 67
Nitrate Nitrite as N
87 84
0 4 4
Nitrite as N
90 - 110
0 10 4 4
100' 101
90 - 110
1 10
Duplicate - Batch: 680.187296
Method: 353.2
Preparation: N/A
Lab Sample ID: 680-63184-A-8
Client Matrix Water
DU
Analysis Batch: 680.187296
Instrument ID: Lafchat 2
Dilution: 1.0
Prep Batch: WA
Units: mglL
Lab File ID: OM_11-24-2010_154941.OA
Date Analyzed: 11/24/2010 1638
Initial WeighWolume: 2 mL
Date Prepared: WA
Final WeighWolume: 2 mL
Analyte
Sample Result/Quai
Result
RPD Limit 'Qual '
Nitrate as N
0:050 U
:, 0.050
NC U
7estAmerica Savannah Page 9 0£ 11 ,_

ro
a
w
m
CHAIN OF
TRANSPORTATION CUSTODY
TAL-6006 0907
CSXT PROJECT INFORMATION
CSXT Project Number:
CS%T Project No": ��
CSXT Cooled: -
". � ^ fl S
Tumeround Time: ❑ Standard 6.13 Days
❑ 1 Day Rush ,/Specify N Days
❑ 2 Day Rush 1L1 Standard 14 Days
❑ 3 Day Rush `FgOther
LABORATORY INFORMATION COC #
❑TestAmerlce Savanosh-5102LaRocke0.venue.Savannah.0A31404 P:912-354-7858 P,912-3524165 - ..
EIT-StAnerica North Canlon•4101 Shuael Drive NW, North Canton. ON 44720 P;330-497-9396 F;330-497-0772 SHIPMENT INFORMATION
❑TBSIAmeflca Tampa -671.2 Benjamin Road, Suite 100. Tampa, R. 33034 P:813-885-7427 F:813-885-7049
❑TeslAmerica Pensacola- 3355 Mctemore Drive, Pensacola. FL 32514 P:B50.474.1001 F.850-478.2671 Shlpmenl Method; r e-rJ �x
OTestgmerlca Buffalo - 10 Na7eMood Drive. Suite 106. Amhorst, NY 1422E P.716-691-2600 F:716-961.7991
❑TestAmedca Chlezgo-2417eond Slraet, University Park, IL60466 P:708.534-5203 F;708-534-5211 Shipment Tmckinq �Na:
Prol, State (State of Origin) 47 Y773 QY
" CONSULTANT INFORMATION Pr actY:
Pro) Clry; Co _ - NC O 6 % d0 • 9 d0 e
w4 12 nWe!9r
a PM:
LtS /4' n N i
Add as: I Email: ,fit
LWON: I far /r • C 1Dr• 300 :nri Ca h,
6VI/ ' (.A C'ty. B1ata, zip Phone: t Fax
Preservative Codes: 3.= Sulfuric Acid Note aa►QF-T COMMENTS LAB USE
0 = No Preservatives 4 - Sodium Thlosulfale Pres. METHODS FOR ANALYSIS
1 = Hydrochloric ACid 5 = Sodium Hydmxicle Code
2 = Nitric Acid 6 = Other
Dellverables: ❑ Other Deliv;
CSXT Standard (Level 11)
LJ Level III ❑ EDD Required, Format:
❑ Level IV
SAMPLE INFORMATION
Matrix Codes: SO = Soil LIO = Liquid—
GW = Groundwater SL = Sludge
W W = Waste Water 01= Oil -
SW - Surface Water SOL = Other Solid M
'
Containers
Sample ldentltiwtion Number8
Type
Sam le Collection Filtered T e Matrix
Date Time Sampler Y or N C°rep Code
or Grab
11-2 -le ISbd J7>F Al 6-,6 Cw
Relin lied By:
2V
Date/Tlme:
—os—to Z196o
R¢ceNed B ; -'
Y
Date/Time:
Comments 6 Special Analytical Requirements:
,
�O(
R gaished By,
Dale/Time: I
Received By: 'DateMme:
Relinquished By:.
no" By tory:
ORIGINAL—RETURNTOLABORATORY WITH SAMPLE!,
AMPLE
DaterRme:
Dal end:
/Lob
O a ��
,
Received By-. Y'
Rem rks�
Q
""u"'no
LAB USE: Custody Imad
❑Yes ❑No
Custody Seat N
N
LAB Log Number
N
MUST BE suemN 1 EO TO CSXT WITH ORIGINAL COC

L
Login Sample Receipt Check List
Client: ARCADIS U.S., Inc.
Login Number. 63468
Creator. Kicklighter, Marilyn
List Number. 1
T/F/NA
Radioactivity either was not measured or, if measured, is at or below
N/A
background
The coolers custody seal, if present, is intact.
The cooler or samples do not appear to have been compromised or
True
True
tampered with.
,
Samples were received on ice.
Cooler Temperature is acceptable.
True
Cooler Temperature is recorded.
True
COC is present.
True
COC Is filled out in ink and legible.,
True
COC is filled out with all pertinent information.
True
Is the Field Samplers name present on COC?
True
There are no discrepancies between the sample IDs on the containers and
N/A
True
the COC.
Samples are received within Holding Time.
Sample containers have legible labels.
True
Containers are not brokenor leaking.
True
Sample collection date/times are provided.
True
Appropriate sample containers are used.
True
Sample bottles are completely filled.
True
Sample Preservation Verified
True
There is sufficient vol. for all requested analyses, Ind. any requested
True
True
MS/MSDs.
VOA sample vials do not have headspaoe or bubble is <6mm (1/4') to
N/A
diameter.
If necessary, staff have been informed of any short hold time or quick TAT
True
needs
Multiphasic samples are not present.
Samples do not require splitting or compositing.
N/A
N/A
TestAmerlea Savannah
Job Number. 680-63468-1
List Source: TestAmedca Savannah
Page 11 of 11

TestAme(ica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Job Number: 680-63014-1
Job Description: CSX Hamlet, NC WWTP Monthly
For:
CSX Transportation
173 CSX Drive .
Hamlet, NC 28345
Attention: Mr. Mike Gregory
LoAq& &"i4l
Kathryn Smith
Project Manager I
kathye.,[e-mail]
11/22/2010
cc: Mr. Alan Pinnix
LWON-ENV0000052320; Project No.: R000011790
x ftrn SimO,
MmjMMan I
H=010105PM
The test results in this report meet NELAP requirements for parameters for which accreditation is required or available.
Any exceptions to the NELAP requirements are noted. Results pertain'only to samples listed in this report. This report
may not,be reproduced, except in full, without the written approval of the laboratory. Questions should be directed to the
person who signed this report.
Savannah Certifications and ID #s: A2LA: 0399.01; AL: 41450; ARDEQ: 88-0692; ARDOH; CA: 03217CA; CO; CT:
PH0161; DE; FL: E87052; GA: 803; Guam; HI; IL: 200022; IN; IA: 353; KS: E-10322; KY EPPC: 90084; KY UST; LA
DEQ: 30690; LA DHH: LA080008; ME: 2008022; MD: 250; MA: M-GA006; MI: 9925; MS; NFESC: 249; NV: GA00006;
NJ: GA769; NM; NY: 10842; NC DWQ: 269; NC DHHS: 13701; PA: 68-00474; PR: GA00006; RI: LA000244; SC:
98001001; TN: TN0296; TX: T104704185; USEPA: GA00006; VT: VT-87052; VA: 00302; WA; WV DEP: 094; WV
DHHR: 9950 C; WI DNR: 999819810; WYlEPAR8: 8TMS-Q
TestAmerica Laboratories, Inc.
TestAmerica Savannah 5102 LaRoche Avenue, Savannah, GA 31404
Tel [phone] Fax [phone] +wwaw.testannerioainc corn
Page 1 of 18.
1N A000,
lFpOJQ"��+ O'ry

Job Narrative
680-63014.1
Comments
No additional comments
Receipt
All samples were received In good condition within temperature requirements.
Metals
No analytical or quality Issues were noted.
General Chemistry
Method(s) 1664A: Insufficient sample volume was provided to perform batch matrix spike/matrix spike duplicate(MS/MSD), associated
with batch 186139. The laboratorycontrol sample (LCS) was performed In duplicate to provide precision data for this batch.
No other analytical or quality Issues were noted.
Page 2 of 18

METHOD SUMMARY
Client: CSX Transportation
"
Job Number. 680-63014-1
Description
Lab Location
Method
Preoaratlon Method
Matrix Water
Metals.(ICP/MS)
TAL SAV
EPA 200.8
Preparation, Total Metals
TAL SAV
EPA 200.8
HEM and SGT-HEM
TAL SAV
1664A 1664A
,_ HEM and SGT-HEM (Aqueous)
TAL SAV
"
1664A 1664A
Nitrogen, Nitrate-Nihite
TAL SAV
MCAW W 353.2
Solids, Total Dissolved (TDS)
TAL SAV
SM SM 2540C
Organic Carbon, Total (TOC)
TAL SAV
SM SM 53108
" Lab References:
-
TAL SAV = TestAmedca Savannah
Method References:
1664A = EPA-821-98-002
EPA = US Environmental Protection Agency
MCAW W = "Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March 1983 And Subsequent Revisions.
SM = "Standard Methods.For The Examination Of Water And Wastewater',
TestAmedca Savannah
Page 3 of 18

METHOD/ANALYST SUMMARY
Client: CSX Transportation
Job Number. 680-63014-1
EPA 200.8
nna� s[
Robertson, Bryn
1664A 1664A
BR
Samuel, Sarita
MCAWW 353.2
SS
Ross, Jon
SM SM 2540C
JR
Robinson, Tiffany
SM SM.5310B
TR
Holmes, Tinita
TH
8
TestAmerica Savannah
Page 4 of 18

SAMPLE SUMMARY
Client: CSX Transportation
Job Number. 680-63014-1
Lab SaDate/Time Date rimemple ID Client Sample ID Client Matrix Sampled Received
680-63014-1 Effluent Water 11/09/2010 0915 11/10/2010 1021
TestAmedca Savannah Page 5 of 18

Client: CSX Transportation
Analytical Data
Job Number: 680-63014-1
Client Sample ID:
Effluent
Lab Sample ID:
680-63014-1
Client Matrix:
Water
Date Sampled: 11/09/2010 0915
Date Received: 11/10/2010 1021
200.8 Metals (ICP/MS)
Method:
200.8
Analysis Batch: 680-186535
Instrument ID: ICPMSB
Preparation:
200.8,
Prep Batch: 680-186172
Lab File ID: 186172.chr
Dilution:
1.0
Initial WelghWolume: 50 mL
Date Analyzed:
11/17/2010 1459
Final WeighWolume: 250 mL
Date Prepared:
11/15/2010 1624
Analyte
Result (mg(L)
Qualifier
MDL RL
Arsenic
Badum
0.0033
J
0.0013 _ 0.050
Cadmium
0.022
J
6.0014 2.0
Chromium
0.0018
U
0.00013 0.0018
Lead
0.050
U
0.0025 0.050
0.00052
J.
0.00050 0.015
TestAmedca Savannah. Page 6 of 18

Analytical Data
Client: CSX Transportation
General Chemistry
Job Number. 680-63014-1
Client Sample ID: Effluent
Lab Sample ID: - 680-63014-1
Date Sampled:
11/09/2010 0915
Client Matrix:. Water
Date Received: 11/10/2010 1021
Analyte Result
Dual Units MDL
RL
oil
Method
HEM (Oil & Grease) 5.0
- U mg/L 1.4
5.0
1.0
1664A
Analysis Batch: 680-186265
Date Analyzed: 11/16/2010 1350
Prep Batch: 680-186139
Date Prepared: 11/15/2010 1700
,
Nitrate as N 0.040
1 mg/L 0.010,.
0.050
1.0
353,2
Analysis Batch: 680-185777
Date Analyzed: 11/10/2010 1358
Total Organic Carbon i t
mg/L 0.50
1.0
1.0
SM 5310B
Analysis Batch: 680-186726
Date Analyzed: 11/19/20101813
-
Analyte Result
Dual Units RL
RL
Dil
Method
Total Dissolved Solids 100
- mg/L 5.0
- 5.0
1.0
SM 2540C
Analysis, Batch: 680-185803
Date Analyzed: 11110/20101717
--
TestAmerica Savannah Page 7 of 18

Client: CSX Transportation
Lab
Metals
General Chemistry
TestAmerica Savannah
DATA REPORTING QUALIFIERS
Job Number: 680-63014-1
U Indicates the analyte was analyzed for but not detected.
J Result is less than -the RL but greater than or equal to the
MDL and the concentration is an approximate value.
Indicates the, analyte was analyzed for but,not detected.
J Result is less than the RL but greater than or equal to the
MDL and the concentration is an approximate value.
Page 8 of 18

Client: CSX Transportation
Quality Control Results
Job Number: 680-63014-1
Method Blank -Batch: 680.186172
Method: 200.8
Preparation: 200.8
Lab Sample ID:
MB 680-186172/16-A
Analysis Batch: 680-166535
Instrument ID: ICPMSB
Client Matrix:
Water
Prep Batch: 680-186172
Lab File ID: 186172.chr
Dilution:
1.0
Units: mg/L
Initial WeighWolume: 50 mL
.Date Analyzed:
11/17/2010 1438
-
Final WeighWolume: 250' mL '
Date Prepared:
11/15/2010 1624-
Analyte
Result
Dual
MDL RL
Arsenic
0.050
U
- 0.0013 0.050
Barium
2.0
U
0.0014 2.0
Cadmium
0.0018
U
0.00013 0.0018
Chromium
0.050
U
0.0025 0.050
Lead
0.015
U
0.00050 0.015
Lab Control Sample - Batch: 680.186172
Method: 200.8
Preparation: 200.8
Lab Sample ID:
LCS 680-186172117-A
Analysis Batch: 680-186535
Instrument ID: ICPMSB
Client Matrix:
Water
. Prep Batch: 680-186172
Lab File ID: 186172.chr
Dilution:
1.0
Units: mg/L
Initial WeighWolume: 50 mL
Date Analyzed:
11/17/2010 1445
Final WeighWolume: ' 250 mL '
Date Prepared:
11/15/2010 1624
Analyte
Spike Amount Result
%Rec.
Limit Qua]
Arsenic
0.100 0.0988,
99
85-115
Barium
0.100 0.0957
96
85-115 J
Cadmium
0.0500 0.0478
96
85 - 115
Chromium
0.100 0.100
100
85 - 115
Lead
0:0500 0.0491
98
85 - 115
TestAmerlca Savannah Page 9 of 18

.Client: CSX Transportation
Matrix Spike/
Matrix Spike Duplidate Recovery Report - Batch: 680-186172
MS Lab Sam is ID•
P 680-63014-1 Analysis Batch: 680-186535
Client Matrix: Water Prep Batch: 680-186172
Dilutfpo: 1.0
Date Analyzed: _ 11/17/2010 1521
Date Prepared: 11/15/2010 1624
•MSD Lab Sample 10:, 680-63014-1 Analysis Batch: 680-186535
Client Matrix: Water Prep Batch: 680-186172
Dilution: 1.0 ` -
Date Analyzed: '11/17/2010 1528
Date Prepared: 11/15/2010 1624
Analyte
Arsenic
Barium
Cadmium
Chromium
Lead
%Rec.
MS,
MSD
Limit
108
103
75 - 125
101
104
75 - 125
99
102
75 - 125
110
104
75 - 125
101
104
75-125
TestAmorica'Savannah Page 10 of 18
Quality Control Results
Jab Number. 680-63014-1
Method: 200.8
Preparation: 200.8
Instrument ID: ICPMSB
Lab File ID: 186172.chr
Initial WeighWolume: 50 mL
Final Weight/Volume: 250 mL
Instrument ID:. ICPMSB
Lab File ID: 186172.chr
Initial WeighWolume: 50 mL
Final WeighWolume: 250 mL
RPD RPD Limit MS Qual MSD Qua[
5 20
3 20
J
J
2 20
6 20
4 20

Client: CSX Transportation
Method Blank - Batch: 680-186139
Lab Sample ID:
MB 680-186139121-A
Client. Matrix:
Water '
Dilution:,
1.0
Date Analyzed:
11/16/2010 1350
Date Prepared:.
11/15/2010 1700
Analyte
Quality Control Results
Job Number. 680-63014-1
Method: 1664A
Preparation: 1664A
Analysis Batch: 680-186265 Instrument ID: No Equipment Assigned
Prep Batch: 680-186139 Lab File ID: N/A '
Units: mg/L Initial WeightlVolume: 500 mL
Final Weight/Volume: 500 mL
Result Qual MDL RL
HEM (Oil & Grease)
-5.0
Lab Control'Sampie/
Lab Control Sample Duplicate Recovery Report'-. Batch: 680-186139
LCS Lab Sample ID: LCS 680-186139/22-A
Analysis Batch: 680-186265
Client Matrix: Water
Prep Batch: 680-186139
Dilution: 1.0
Units: mg/L '
Date Analyzed: 11/16/2010 1350
Date Prepared: 11/15/2010 1700
U 1.4 5.0
Method: 1664A
Preparation: 1664A
Instrument ID: No Equipment Assigned
Lab File ID: N/A
Initial Weight/Volume: 500 mL
Final WeighWolume: 500 mL
LCSD Lab Sample ID:
LCSD 680-186139/23-A
Analysis Batch: 680-186265
Instrument ID:. No Equipment Assigned
Client Matrix:
Water
Prep Batch: 680-186139
Lab File ID: N/A
Dilution:
1.0
'Units: mg/L
'Initial WeighWolume: 500 mL
Date Analyzed:
11/16/2010 1350
Final WelghWolume: 500 mL
Date. Prepared:
11/15/2010 1700
% Rec
Analyte
LCS LCSD Limit
RPD RPD Limit LCS Qual LCSD Qua[
HEM (Oil & Grease) 98 96 78 - 114 2 18
TestAmerica Savannah Page 11 of 18

Quality Control Results
Client:.. CSX Transportation
Job Number: 680-63014-T
Method Blank - Batch:. 680.185777
Method: 353.2
Preparation: N/A
- Lab Sample ID: MB 680-18577711 Analysis Batch: 680-185777
Client Matrix: Water Instrument ID: Latchat 2
Prep Batch: N/A Dilution: 1.0 Lab File ID: OM 11-10-2010 13-20-38.Oh
: Units: mg/L — —
Date Analyzed: 11/10/2010 1347 - Initial WelghWolume: 2 mL
Date Prepared: N/A Final WelghWolume: 2 mL
Analyte Result
Qual - MDL RL
Nitrate as N - -
0.050 U 0.010 0.0!
Lab Control Sample - Batch: 680-185777
Method: 353.2
Preparation: N/A
Lab Sample ID: LCS 680-18577712 Analysis Batch: 680-185777
Client Matrix: Water Instrument ID:, Latchat2
Prep Batch: N/A LabFile ID: : OM .
Dilution: 1.0 Units: mg/L —11-10-201013-20-38.OA
-
Date Analyzed: 11/10/2010 1348 Initial WelghWolume: 2 mL
Date Prepared: N/A FinalWeighWolume: 2 mL
Analyte
Spike Amount
Nitrate as N 0.500
Matrix Spike/
Matrix Spike Duplicate Recovery Report - Batch: 680-185777
MS Lab Sam n le to:
Result % Rec. Limit
0.496 99
Method: 353.2
Preparation: N/A
Qual
- - P
Client.. Matrix:
fi60-62999-M-1 MS
Water
Analysis Batch: 680-185777
Instrument lD: Latchat 2
Dilution:
1.0
Prep Batch: N/A
Lab File ID: - OM_1110-2010_13-20-38.0
Date Analyzed:
11/10/2010 1351
Initial Weight/Valume: 10 mL
Date Prepared:
N/A
Final Weight/Volume: 10 mL
.. -_
MSD Lab Sample to:
680-62999-M-1 MSD
Analysis Batch: 680-165777
-
Client Matrix:
Water
Prep N/A
Instrument ID: Latchat2
Dilution:
1.0
Lab File ID: OM_11-10-2010-13-20-38.OA
Date Analyzed:
11/10/2010 1352
Initial WeighWolumei 10 mL
Date Prepared:
N/A
Final Weight/Volume: 10 mL
Analyte
Nitrate asN
TestAmedca Savannah.
MS MSD Limit RPD RPD Limit MS Qual MSD Qual
101 10 p1
Page 12 of 18

Client:CSX Transportation
Duplicate -:Batch: 680.185777
Lab Sample ID:
680-63013-0-1 DU
Analysis Batch: 680-185777
Client Matrix:
Water
Prep Batch: NIA
Dilution:
5.0
Units:' mg/L
Date Analyzed:
11/10/2010 1448
Date Prepared:'
NIA
Analyte Sample Result/Qua[
Nitrate as N 0.40
0
TestAmerica Savannah. Page 13 of 18
Quality Control Results
Jab Number. 680-63014-1
Method:353.2
Preparation: N/A
InstrumentlD: Latchat2
Lab File 10: OM_11-10-2010_14-35-01.0h
.Initial WeighWalume: 2 mL
Final WeighWolume: 2 mL
Result ROD Limit
0.407 2
Qual

Client: CSX Transportation
Method Blank -Batch: 680.185803
Lab Sample ID:
MB 680-185803/1
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:.
11/10/2010 1717
Date Prepared:
N/A
Analysis Batch: 680-185803
Prep Batch: WA
Units: mg/L .
Analyte Result
Qua[
Total Dissolved Solids 5.0 U
Lab Control Sample/
Lab Control Sample Duplicate Recovery Report,- Batch: 680.185803
Quality Control Results
Job Number: 680-63014-1
Method: SM 2540C
Preparation: N/A
Instrument ID: No Equipment Assigned
Lab File ID: N/A
Initial.WeighWolume: 100 mL
Final Weight/Volume: 100 mL
RL RL
5.0 a n
Method: SM 2540C
Preparation: N/A
LCS Lab Sample ID:
Client Matrix:
LCS 680-185803/2
Water
Analysis Batch:
680-185803
Instrument ID: No Equipment Assigned
Dilution:
1,p
Prep Batch: WA
Lab File ID: N/A
Date Analyzed:
11/10/2010 1717
Units: mg/L
Initial WeighWolume: 100 mL
Date Prepared:
N/A
Final Weight/Volume: 100 mL
LCSD Lab Sample ID:
LCSD 680-185803/3
Analysis Batch:
680-185803
Instrument ID:
Client Matrix:
Water
Prep Batch: N/A
No Equipment Assigned
Dilution:
1.0
Units: mg/L
Lab File ID: N/A
Date Analyzed:
11/10@010 1717
Initial WeighWmL
100 m
Date Prepared:
N/A
Final WeighWolume: 100. mL "
° Rec
Analyte
LCS LCSD
Limit
RPD RPD Limit LCS Thal LCSD qua]
Total Dissolved Solids
106 105
80 120
-
2 25
Duplicate - Batch: 680.185803
Lab Sample ID:
680-62999-E-1 DU
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
11/10/2010 1717
Date Prepared:
N/A
Analyte
Total Dissolved Solids
Analysis Batch: 680-185803
Prep. Batch: N/A
Units: mg/L
Sample Resull/Qual
25
TestAmedca Savannah Page 14 of 18
Result
Methcd: •SM 2540C
Preparation: N/A
Instrument ID: No Equipment Assigned
Lab File ID: N/A
Initial WeighWolume: 100 mL
Final Weight/Volume: 100 mL
RPD Limit
4 25
Qual

Client: CSX Transportation
Method Blank - Batch: 680-186726
Lab Sample ID: MB 680-186726/24
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 11/19/2010 1611
Date Prepared: N/A
Analysis Batch: 680-186726
Prep Balch: NIA
Units: mg/L
Quality Control Results
Job Number: 680-63014-1
Method: SM 5310B
Preparation: N/A
Instrument ID: TOC3
Lab. File, ID: TOC111910.txt
Initial WelghWolume: 25 mL
Final WelghWolume: 25 mL
Analyte
Result
Qual MDL RL
Total Organic Carbon
1.0
lJ 0.50. 1.0
- Lab Control Sample - Batch: 680-186726
,
Method: SM 5310B
Preparation: N/A
Lab Sample ID: LCS 680-186726125
Analysis Batch: 680-186726
Instrument ID: TOC3
Client Matrix: Water
Prep Batch: WA .
Lab File ID: TOC111910.bd
Dilution: 1.0
Units: mg/L
Initial Weight/Volume: 25 mL
Date Analyzed: 11/19/2010 1628
Final WeighWolume: 25 mL
Date Prepared: N/A
Analyte
Spike Amount Result
% Rec. Limit Qua]
Total Organic Carbon
20.0 20.2
101 80 - 120
Matrix Spike/
Method: SM 53108
Matrix Spike Duplicate Recovery Report - Batch: 680-186726
Preparation: N/A
MS Lab Sample ID: 460-19785-A-1 MS
Analysts Batch: 680-186726
Instrument ID: TOC3
Client Matrix: Water
Prep Batch: NIA
Lab File ID: TOC111910Jxt
Dilution: 1.0
Initial Weight/Volume: 25 mL
Date Analyzed: 11/19/2010 1659
Final WeighWolume: 25 mL
Date Prepared: NIA
MSD Lab Sample 10: 460-19785-A-1 MSD
Analysis Batch: 680-186726
Instrument ID: TOC3
Client Matrix: Water
Prep Batch: N/A
Lab File ID: TOC111910.txt
Dilution: 1.0
Initial WelghWolume: 25 mL
Date. Analyzed: 11/19/2010 1711
Final Weight/Volume: 25 mL
Date Prepared: N/A
° Rec.
Analyte
MS MSD .Limit
RPD RPD Limit MS Qual - MSD Qual
Total Organic Carbon
98 98 80-120
0 25
r
TestAmedw Savannah
Page 15 of 18

Client: CSX Transportation
Quality Control Results
Job Number: 680-63014-1
Duplicate -Batch: 680.186726 Method: SM 5310B
Preparation: N/A
Lab Sample ID: 680-63051-B-2 DU Analysis Batch: 680-186726 Instrument ID: TOC3
Client Matrix: Water Prep Balch: N/A Lab File ID: TOC111910.txt
Dilution: 1.0 Units: mg/L. Initial WeighWolume: 25 mL
Date Analyzed: 11/19/2010 195o Final WeighWolume: 25 mL
Date Prepared: N/A
Analyte Sample Result/Qua] Result RPD Limit
Total Organic Carbon 1.2 1.23 0.3 25
TestAmerica savannah Page 16 of 18
Qual

LABORATORY INFORMATION -
CHAIN OF
CSX
OonumarlceS......h-5102Laaaehe Nrenhe.Savannah.Gg37g09 P:912-354.7858 F:912-352-0165
OT"oknedca
COC#
TRNdSPORTATION CUSTODY
North came; -41015hulel Drive NW, North Canton, ON 44720 P:330-497-9396 F:330-4970772 SHIPMENT INFORMATION
OTesumerica Tampa- 6712 GI Rod. Suite 100. Tampa, EL33634- P:613.865-1427
F:813-68.
❑ TesOLncrlca Pensacola • 3355 McLemme Drive. Pensacola, FL 57049
32514 p; 850.479.1001 F: B50-178-70
Shipmone Method:
❑ TeslNnerica Bnpalo -10 Nalelaoad Drive Suite 106. Amherst, NY 14226 P:716.691-2600 F 716.961-7991 ❑ TeslAmerica Chicago -207 Send Slreel. Unfversily Park, IL 60466
ShiPmenl Tracking
CSXT PROJECT INFORMATION
P:708d34-5200 P.708.534-5211
Prof, Stale (State of Origin)
too:
CSXT Protect Number:
CONSULTANT INFORMATION
Project Y:
CS%T'Projecl Nama:
PI City.* Company:
l b
PM:
v� 1 II__
' 'i biI b%r �-
r 2 6j Address
CSXT on
Ctact: _
/ ("
-
'Mys
"
LWON: G n City. Stale, Zip:
— !L
Email:
Turnaround Time: ❑ Standard6
Phone: Fax:
❑ t Day Rush SoecgyI pays
❑
Preservative Codes: 3=Sulfuric Acid Note..
COMMENTS U
0-No Preserva0vos 4- SodiumThiosulfaie
2 Day Push landard W Days
❑ 3 Day
P7e5. METHODS FOR
1 = Hydrochloric Acid 5 = Sodium Hydroxide
ANALYSIS
Rush ❑ Other
Code
2=Nitric Acid 6=Other
li
Deverabies: ❑ Other Deliv:
❑ CSXT Standard (Level 1p
Matrix Coder. - SO Sail LIO=Liquid
GW=Gmundwaler Q
❑ Level IN ❑ EDO Required, Formal:
SL=Sludge
n1
l V
rq ❑ Level lv �
W W = Waste Water 01= Oil
m SAMPLE. INFORMATION
SW = Surface Water SOL = Other Solid
Containers
C Sample Identification Number &
Sam le Collection Pillared T Q
e Matrix
Type
Dale Time Sampler Y or N Comp Code
F
or Grab
or
n t:cc•c.
s 13 cd G,,p 2 0•
- MC-
-`I-�o 9:I [2 N
� r
Relinquished By: Da1e717me:
Race'
Relinquished By:
y: DalolTlmo:
0
Comments & Special Analytical Requirem
Dale7Tlma:
Relinquished 8y:
eceNed By: Date7Rme:
/ r9O — / �Q/�
0 (�
Dale(Rme: -
Received By:
('Q
Rani d By Laboratory- Da
�
Dnta771rne:
Lab Remarks:
/, p
ORIGINAL -RETURN TO LAB TORY WITH
'1 IABU
O� �-! Custody Imam
❑No
Custody Seal N LAB Log Number
SANPL
-+1"es
p ,r
(GI

v
Login Sample Receipt Check List
Client: CSX Transportation
Login Number: 63014
Creator. Swafford, Frances
List Number: 1
Radioactivity eitherwas not measured or, if measured, Is at or below
background
The coolers custody seal, if present; is Intact.
The cooler or samples do not appear to have been compromised or
tampered with.
Samples were received on ice.
Cooler Temperature Is acceptable.
Cooler Temperature is recorded.
COC Is present.
COC Is Filled out In Ink and legible.
COC is filled out with all pertinent Information.
Is the field Samplers name present on COC?
There are no discrepancies between the sample Me on the containers and
the COC.
Samples are received within. Holding Time.
Sample containers have legible labels.
Containers are not broken or leaking.
Sample collection date/times are provided.
Appropriate sample containers are used.
Sample bottles are completely filled.
Sample Preservation Verified
There is sufficient vol. for all requested analyses, Ind. any requested
MS/MSDs
VOA sample vials do not have headspace or bubble is <6mm (1/4°) In
diameter. ' ,
'If necessary, staffhave been informed of any shorthold Ilme or quick TAT
needs
Multiphasic samples are not present.
Samples do not require splitting or compositing.
T/F/NA
N/A
True
True
True
True
True
True
True
True
False
True
True
True
True
True
True
True
True
True
N/A
True
N/A
N/A
TestAmerica Savannah
Page 18 of 18
Job Number. 680-63014-1
List Source: TBstAmerica Savannah

CoS�
TRANSPORTATfoN
Jerry L. Cato REM
Supervisor Environmental Control
North Carolina Department
Of Natural Resources
Attn: Information Processing, Unit
Division Water Quality
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
Dear Sir or Madam:
500 Water Street - J275
Jacksonville, FL 32202
((9 fi) 359-3457
(FAX) [phone]
August.24, 2010
File. 9613703
RECEIVE®
AUG 3 1 2010
DENR-FAYEffENLLE REGIONAL OFnCE
Permit No. W00000601 Richmond County
CSX Transportation. Inc. (CSXT) Hamlet NC
Attached in triplicate, is the second triennial 2010 Ground Water Monitoring Well
Analyses, Form GW-59A and Attachment A - WWTF discharge reports, as specified by
Condition 4 of the referenced permit: Due to the drought conditions at this location, monitoring
well No. 1, and No; 3 did not have enough water to collect a sample.
If you have any questions or comments, please contact me at (904) 359,3457,
Sincerely,
Jerry L. Cato
Enclosures
c`
J

ATTACHMENT A — LIMITATIONS AND MONITORING REQUIREMENTS
PPI 001 —W WTF Effluent
Permit Number: W00000601 Version: 3.0
EFFLUENT CHARACTERISTICS
- EFFLUENT LIMITS
MONITORINGREQUIREMENTS
Parameter Description — Parameter Code
Monthly Average
Weekly Average
Daily Maximum
Monitoring Frequency
Sample Type
Flow, in conduit or thru treatment plant —50050
1.0
mgd
b, 0039
ry cjs
Continuous
Recorder
Solids, Total Dissolved— 180 Deg.C— 70300
95
mg/L
3 X year
Grab
pH — 00400
..to
S U
3 X year
Grab
Carbon, Total Organic (TOC) — 00680 -
8.7
mg/L
3Xyear
Grab
Nitrogen, Nitrate Total (as N) — 00620
0.046
mg/L
3Xyear
GrabBarium,
Total (as Be) —01007
0.016
mg/L
3Xyear
Grab
Cadmium, 'I'atal(as Cd)-01027
_
<0.00
mg/L
3Xyear
Grab
Chromium, Total (as Cr) — 01034
< 0 . 01
mg/L
3Xyear
Grab
[.zad,Total (as Ph) —OIOSI
<0.01
mg/L
3Xyear
Grab
Arsenic, Total (as As) —01002
<0.02
mg/L
3Xyear
Grab
3 X year monitoring shall be conducted in March, July and November.
Additional monitoring performed April 2010
W00000601 Version 3A Attachment A Page 1 of 1

Test meka
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Job Number: 680-57105-1
Job Description: CSX Hamlet,, NC WWTP April2010
For:
CSX Transportation
500 Water Street
Jacksonville, FL 32202
Attention: Mr. Mike Gregory
AGGrm'e0lvreleue.
U Uf Vw l PmI�I Menegerl
5I19IN1U 3:@PM
Kathryn Smith
Project Manager I
[e-mail]
05/19/2010
cc: Mr. Jerry Cato
Mr. Alan Pinnix
L W O N-E N V0000027258//Project-R000011790
The test results In this report meet NELAP requirements for parameters for which accreditation is required or available.
Any exceptions to the NELAP requirements are noted. Results pertain only to samples listed in this report. This report
may not be,reproduced, except In full, without the written approval of the laboratory. Questions should be directed.to the
person who signed this report.
Savannah Certifications and ID #s: A21-A: 0399.01; AL: 41450; ARDEQ: 88-0692; ARDOH; CA: 03217CA; CO; CT:
PH0161; DE; FL: E87052; GA: 803; Guam; HI; IL: 200022; IN; IA: 353; KS: E710322; KY EPPC: 90084; KY UST; LA
DEQ: 30690; LA DHH: LA080008; ME: 2008022; MD: 250; MA: M-GA006; MI: 9925; MS; NFESC: 249; NV: GA00006;
NJ: GA769; NM; NY: 10842; NC DWQ: 269; NC DHHS: 13701; PA: 68-00474; PR: GA00006; RI: LA000244; SC:
98001001; TN: TN0296; TX: T104704185; USEPA: GA00006; VT: VT-87052; VA: 00302; WA; WV DEP: 094; WV
DHHR: 9950 C; WI DNR: 999819810; WY/EPAR8: 8TMS-Q
TestAmerica Laboratories, Inc.
TestAmedca Savannah 5102 LaRoche Avenue, Savannah, GA 31404 Wo�•t„ o�,
Tel [phone] Fax [phone] w Aestamedcainc com et =
Page 1 of 17

Job Narrative
680.57105.1
Comments
No additional comments.
Receipt
All samples were received In good condition within temperature requirements
Metals
No analytical or quality issues were noted.
General Chemistry . `
Method(s) 353.2 The matrix spike / matrix spike duplicate (MS/MSC) recoveries for batch 167428 were outside control limits. The
associated laboratory control sample (LCS) recovery met acceptance criteria.
No other analytical or quality issues were noted.
Page 2 of 17

METHOD SUMMARY
Client: CSX Transportation
Job Number. 680-57105-1
Description
Lab Location
Method Preparation Method
Matrix Water
Metals (ICP)
TAL SAV
40CFR136A 200.7 Rev 4.4
Preparation, Total Metals
TAL SAV
EPA 200.7
HEM and SGT-HEM
TAL SAV
1664A 1664A
HEM and SGT-HEM (Aqueous)
TAL SAV
1664A 1664A
Nitrogen, Nitrate -Nitrite
TAL SAV
MCAWW 353.2
Solids, Total Dissolved (TDS)
TAL SAV
SM SM 2540C
Organic Carbon, Total (TOC)
TAL SAV
SM, SM 5310B
Lab References:
TAIL SAV = TestAmedca Savannah
Method References:
1664A = EPA-821-9M02
40CFR136A = "Methods for Organic Chemical Analysis of Municipal Industrial Wastewater', 40CFR, Part 136, Appendix A,
October 26, 1984 and subsequent revisions.'
EPA = US Environmental Protection Agency
MCAW W = "Methods For Chemical Analysis Of Water And Wastes", EPA-60014-79-020, March 1983 And Subsequent Revisions.
Stet = "Standard Methods For The Examination Of Water And Wastewater",
TestAmerica Savannah
Page 3 of 17

METHOD/ANALYST SUMMARY
Client: CSX Transportation
Job Number. 680-57105-1
Method - Analyst — _ AnalvstlD
40CFR136A 200.7Rev4A Bland, Brian BCB
1664A 1664A Samuel, Sarita
SS
MCAWW 353.2 Ross,Jon JR
SM SM 2540C Jackson, Michelle S MSJ
SM SM 5310E Blackshear, Kim
KB
TestAmerica Savannah
Page 4 of 17

SAMPLE SUMMARY
Client: CSX7ransportation
Jab Number: 680-57105-1
_ Date/Time Daterrime
Lab Sample ID Client Sample ID Client Matrix Sampled Received
680-57105-1 Effluent Water + 04/27/2010 0925 04/2812010 1010
TestAmerica Savannah
s
Page 5 of 17

Analytical Data
Client: CSX Transportation Job Number: 680-57105-1
Client Sample ID:, Effluent
Lab Sample ID:
680-57105-1
Date Sampled: 04/27/2010 0925
Client Matrix:
Water
Date Received: 04/28/2010 1010
200.7 Rev 4.4 Metals (ICP)
Method:
200.7 Rev 4.4
Analysis Batch: 680-167268
Instrument ID: - ICPD
Preparation:
200.7
Prep Batch: 680.167027
Lab File ID: N/A
Dilution:
1.0
- Initial WeighWolume: 50 mL
Date Analyzed:
04/29/20101923
Final WeighWolume: 50 mL
Date Prepared: 04/28/2010 1426
Analyte
Result(mg/L)
Qualifier
MDL
RL
Arsenio
0.020
U
0.0046
0.020
Badum
0.016
0.0023
0.010
Cadmium
0.0050
U
0.0020
0.0050
Chromium
0.010
U
0.0012
0.010
Lead
0.010
U
0.0040
0.010
TestAmerica Savannah Page 6 of 17

Client: CSX Transportation
General Chemistry
Analytical Data
Jab Number: 680-57105-1
Client Sample ID: Effluent
Lab Sample ID: 680-57105-1
Date Sampled:
04/27/20100925
Client Matrix: Water
Date Received: 04/28/2010 1010
Analyte Result
Dual Units MDL
- RL
oil
Method -
HEM (Oil & Grease) 5.0
U mg/L 1.4
5.0
1.0
1664A
Analysis Batch: 680-167326
Date Analyzed: 05/03/2010 1330
Prep Batch:.680-167318 .
Date Prepared: 05/02/2010 0935
Nitrate as N 0.046
J mg/L 0.010
0.050
1.0
353.2
Analysis Batch: 680-167428
Date Analyzed: 04/29/2010 0907
Total Organic Carbon 8.7
mg/L 10.50
1.0
1.0
S_ M 5310E
Analysis Batch: 680.167632
Date Analyzed: 05/04/2010 1302
Analyte Result
t
Oual Units RL
RL
Dil
Method
Total Dissolved Solids 95
mg/L 5.0
5.0
1.0
SM 2540C
Analysis Balch: 680-167386
Date Analyzed: 05/03/2010 1259
TestAmerica Savannah Page 7 of 17

DATA REPORTING QUALIFIERS
Client: CSX Transportation
Job Number: 680-57105-1
Lab Section Qualifier Description
Metals
U Indicates the analyte was analyzed for but not detected.
General Chemistry
TestAmedca.Savannah
U Indicates the analyte was analyzed for but not detected.
F MS or MSD exceeds the control limits
J Result is less than the RL but greater than or equal to the
MDL and the concentration is an approximate value.
Page 8 of 17

Quality Control Results
Client: CSX Transportation Job Number. 680-57105-1
Method Blank - Batch: 680-167027
Method: 200:7 Rev 4.4
,Preparation: 200.7
Lab Sample ID:
MB 680-167027/7-A Analysis Batch: 680-167268
Instrument ID: ICPD
Client Matrix:
Water Prep Batch: 680.167027
Lab File ID: N/A
Dilution:
1.0 Units: mg/L
Initial Weight/Volume: 50 mL
Date Analyzed:
, 04/29/2010 1816
Final Weight/Volume: 50 mL
Date Prepared:
04/28/2010 1426
Analyte Result Qual MDL RL
Arsenic
0.020
U
0.0046
0.020
Barium
0.010
U,
-
0.0023
0.010
Cadmium
0.0050
U
0.0020
0.0050
Chromium
0.010.
U
0.0012
0.010
Lead
-
0.010
U
0.0040
0.010
Lab Control Sample - Batch: 680-167027
Method: 200.7 Rev 4.4
Preparation: 200.7
Lab Sample ID:
LCS 680-167027/8-A
Analysis Batch: 680-167268
Instrument ID: ICPD
Client Matrix:
Water
Prep. Batch: 680-167027
Lab File ID: N/A
Dilution:
1.0
Units: mg/L
Initial WelghWolume: 50'
mL '
Date Analyzed:
04/29/2010 1821
Final WeighWolume: 50
mL
Date Prepared:
04/28/2010 1426
Analyte
Spike Amount
Result
% Rec.
Limit
Qual
Arsenic
2.00
1.94
97
85 - 115.
Barium
2.00
2.05
103
85-115
Cadmium
_
0.0500
0.0502
100
85 - 115
Chromium
0.200
0.204
102
85 - 115
Lead
0.500
0.500
100
85-115
TestAmerica Savannah Page 9 of 17

Quality Control Results
Client: CSX Transportation Job Number. 680-57105-1
Matrix Spike/
Matrix Spike Duplicate Recovery Report - Batch: 680.167027
Method:200.7 Rev 4.4
Preparation: 200.7
MS Lab Sample ID:
680-57056-B-1-B MS
AnalysisBatch: 680-167268
Instrument ID: ICPD
-
Client Matrix:
Water
Prep Batch: 680-167027
Lab File ID: NIA
Dilution:
1.0
Initial Weight/Volume:
50 mL
Date Analyzed:
04129/20101842
Final WeighWolume:
50 mL
Date Prepared:
04/28/2010 1426
MSD Lab Sample ID:
680.57056-B-1 C MSD
Analysis Batch: 680-167268
Instrument ID: ICPD
Client Matrix:
Water _
Prep Batch:' 680-167027
- Lab File 10: NIA
Dilution:
1.0
Initial WelghtlVolume:
50 mL
Date Analyzed:
04/2912010: 1847
Final WelghWolume:
50 mL -
Date Prepared:
04/28/2010 1426
•
Analyte
Arsenic
Barium
Cadmium
Chromium
Lead
% Rec
MS MSD
98 97
103 102
102 100
162 101
101 99
Limit RPD RPD Limit MS Dual MSD Qual
75 - 125
1
20
75 - 125
1
20
75 - 125
2
20
75 - 125
1
20
75 - 125
1'
20
TestAmerica Savannah Page 10 of 17

Quality Control Results
Client CSX Transportation
Job Number" 680-57105-1
Method Blank - Batch: 680.167318 -
Method: 1664A
Preparation: 1664A
Lab Sample ID: M8 680-167318/19-A
Analysis. Batch: 680-167326
Instrument ID: No Equipment Assigned
Client'Matrix: Water
Prep Batch: 680-167318
Lab File ID: N/A
Dilution: 1.0
Units: mg/L
Initial WeighWolume: 500 mL
Date Analyzed: 05/03/2010 1330
Final Weight/Volume: 500 mL
Date Prepared: 05/02/2010 0935
`
Analyte
Result Qual
MDL RL "
'HEM (Oil & Grease)
5.0 U
1.4 5.0
Lab Control Sample/
Method: 1664A
Lab Control Sample Duplicate Recovery
Report - Batch: 880-167318
Preparation: 1664A
LCS Lab Sample ID:
LCS 680-167318/20-A
Analysis Batch: 680-167325
Instrument ID: No Equipment Assigned
Client Matrix:
Water
Prep Batch: 680-167318
Lab File ID: N/A
Dilution:
1.0
Units: mg/L,
Initial WelghWolume: 500 mL
Date Analyzed:
05/03/2010 1330
Final WeighWolume: 500 mL
Date Prepared:
05/0212010 0935 '
LCSD Lab Sample 10:
LCSD 680-167318/21-A
Analysis Batch: 680-167326
- Instrument ID: No Equipment Assigned
Client Matrix:
Water
.Prep Batch: 680-167318
Lab File ID: N/A
Dilutor:
1.0 '-
Units: mg/L
Initial WelghWolume: 500 mL
Date Analyzed:
05/03/20101330
Final WelghWolume: 500 mL
Date Prepared:
05/0212010 0935
% Rec.
Analyte
LCS LCSD Limit
RPD RPD Limit LCS Qual LCSD Qual
HEM (Oil & Grease) 90 93 78 -114 4 18
TestAmerica Savannah Page 11 of 17

Client: CSX Transportation
Method Blank -Batch: 680.167428
Lab Sample ID: MB 680-167428/1
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 05/03/2010 1601
Date Prepared: N/A
Analyte
Nitrate as N
Lab Control Sample - Batch: 680-167428
Lab Sample ID:
LCS 680-167428/2
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
05/03/2010 1601
Date Prepared:
N/A
Analyte
Analysis Batch: 680-167428
Prep Batch: NIA
Units: mg/L
Result
0.050
Analysis Batch: 680-167428
Prep Batch: N/A
Units: mg/L
Spike Amount Result
Nitrate as N
1.00 0.995
Matrix Spike/
Matrix Spike Duplicate Recovery Report - Batch: 680-167428
MS Lab Sample ID:
680.57044-G-1 MS
Analysis. Batch: 680-167428
Client Matrix:
Water
Prep Batch:. NIA
Dilution:
1.0
Date Analyzed:
04/24/2010 1419
Date Prepared:
N/A
MSD Lab Sample ID:
680-57044-G-1 MSD
Analysis Batch: 680-167428
Client Matrix:
Water
Prep Batch: N/A
Dilution:
1.0
Date Analyzed:
04/24/2010 1419
Date Prepared:
NIA
%ReC
Analyte MS MSD Limit
Nitrate as N 17 - 17 90 - I to
TestAmerica Savannah Page 12 of 17
Quality Control Results
Job Number. 680-57105-1
Method: 353.2
Preparation: N/A
Instrument ID: KONELAB2
Lab File ID: NIA
Initial Weight/Volume: 2 mL
Final WeighWolume: 2 mL
Qual MDL RL
U 0.010 0.050
Method: 353.2
Preparation: NIA
Instrument ID:: KONELAB2
Lab File ID: N/A
Initial WeighWolume: 2 mL .
Final WeighWolume: 2 mL
%-Rec. Limit Qual
100 90 - 110
Method: 353.2
Preparation: N/A
Instrument ID: , KONELAB2
Lab File ID: N/A
Initial WeighWolume: 2 mL
Final WeighWolume: 2 mL
Instrument ID: KONELAB2
Lab File ID: N/A
Initial WeighWolume: 2 mL
Final WeighWolume: 2 mL
RPD RPD Limit MS Qua[ MSD Qual
1 10 F ' F

. r.
Client: CSX Transportation
Method.Blank- Batch: 680.167386
Lab Sample ID: MB 680-167386/1
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 05/0312010 1259
Date Prepared: N/A
Analysis Batch: 680-167386
Prep Batch: N/A
Units: mg/L
Analyte
Result
Total Dissolved Solids
5.0
Lab Control Sample/
Lab Control Sample Duplicate Recovery Report - Batch: 680.167386
LCS Lab Sample ID:
LCS 680-167386/2
Analysis Batch: 680-167386
Client Matrix:
Water
Prep Batch: N/A
Dilution:
1.0
Units: mg/L
.Date Analyzed:
05103/2010 1259
Date Prepared:
N/A
LCSD Lab Sample ID:
LCSD 680-167386/3
Analysis Batch: 680-167386
Client Matrix:
Water
Prep Batch: N/A
Dilution:.
1.0
Units: mg/L
Date Analyzed:
05/03/2010 1259
Date Prepared:
N/A
Analyte .
TotalDissolved Solids
Duplicate - Batch: 680-167386
Lab Sample ID:
680-57144-B-2 DU
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
05/03/2010 1259
Date Prepared:
N/A
Analyte
Total Dissolved Solids
TestAmerida Savannah
% Rao
LCS LCSD
85 86
Limit
80 - 120
Analysis Batch: 680-167386
Prep Batch: N/A
Units: mg/L
Sample Result/Qual
810
Page'13 of 17
Quality Control Results'
Job Number: 680-57,105-1
Method: SM.2540C
Preparation: N/A
Instrument ID:, No Equipment Assigned.
Lab File ID: N/A
Initial Weight/Volume: 100 mL
Final Weight/Volume: 100 mL
Qual RL RL
U° - - 5.0 5.0
Method: SM 2540C
Preparation: N/A
Instrument ID: No Equipment Assigned
Lab File ID: N/A
Initial WeighWolume: 100 mL
Final Weight/Volume: 100 mL
InsWment ID: No Equipment Assigned
Lab File ID: N/A
Initial WeighWolume: 100 mL
Final WeighWolume: 100 mL
RPD RPD Limit LCS Qual LCSD Qual
1 25
Method: SM 2540C
Preparation: N/A
Instrument ID: No Equipment Assigned
Lab File ID: N/A
Initial WeighWolume: 100 mL
Final Weight/Volume: 100 ml-
Result RPD Limit Qual
802 0 25

Client: CSX Transportation
Method Blank -Batch: 680-167632
Lab Sample JD:
MB 680-167632112
Client Matrix:
Water '
Dilution:
1.0
Date Analyzed:
05/04/2010 1101
Date Prepared:
N/A
Analyte
Total Organic Carbon
'tab ControlSample.- Batch: 680.167632
Lab Sample ID:
LCS 680-167632/4
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
05/04/2010 1132
Date Prepared:
N/A
Analysis Batch: 680-167632
Prep Batch: N/A
Units: mg/L
Quality Control Results
Job Number. 680r57105-1
Method: SM 5310B
Preparation: NIA
Instrument ID: TOC3
Lab File ID: T00050410.15(t
Initial WeighWolume: 25 mL
Final WeighWolume: 25 mL
Result Qual MDL
1.0 U 0.50
Analysis Batch: 680-167632
Prep Batch: N/A
Units: mg/L
Method: SM5310B
Preparation: NIA
RL
Instrument ID: TOC3
Lab File ID: ''T00050410.bd
Initial WelghWolume: 25 mL
Final WeighWolume: , 25 mL
Analyte
Spike Amount
Result
' % Rec. Limit
Total Organic Carbon
'20.0
19.0
95 80 - 120
.Matrix Spike/
.Method: SM 5310B'
Matrix Spike Duplicate Recovery Report -
Batch: 680-167632
Preparation: 'N/A
MS Lab Sample ID:
680-57105-1
Analysis Batch:
680-167632
-Instrument ID: TOC3
-' Client Matrix:
Water
Prep Batch: N/A
Lab File ID: ,T00050410.txt
Dilution:
1.0
Initial WeighWolume: 25 mL
Date Analyzed:
05/04/2010 1319
Final WeighWolume: 25 mL.
Date. Prepared:
N/A
MSD Lab Sample 10:
680-57105-1
Analysis Batch:
680-167632
Instrument ID;' TOC3
Client Matrix:
Water
Prep Batch: N/A
Lab File ID:. T06050410.b¢
Dilution:
1.0
Initial Weight/Volume: 25 mL
Date Analyzed: -
05/04/2010 1332
'Final WeighttVolume: 25 mL
Date Prepared:
N/A
Qual
% Rec.
Analyte MS MSD Limit RPD RPD Limit MS Qual MSD. Qual
Total Organic Carbon 99 97 80-120 1 25
TestAmerica Savannah Page 14 of 17

Client: CSX Transportation
Duplicate - Batch: 680-167632
Lab Sample ID:
680-57237-B-5 DU
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
05/04/2010 1815
Date Prepared:
N/A
Analyte
Total Organic Carbon
Quality Control Results
Job Number: 680-57105-1
Method: SM 5310B
Preparation: NIA
Analysis Batch: 680-167632 Instrument ID: TOC3
Prep Batch: N/A Lab File ID: T00050410.bt
Units: mg/L Initial WeightA/olume: 25 mL
Final WeighWolume: 25 mL
Sample ResultlQual Result RPD Limit Qual
0.76 J 0.T72 1 25 J
TestAmerica Savannah Page 15 0£ 17

ro
w
W
Ia
on
of
O
Fh
r
CHAIN OF
TRANSPORTATION CUSTODY -
LABORATORY INFORMATION
CCC #
❑ TeslAmerica Savannah- 5102 LaRoche Avenue: Savannah, GA 31404 P:912.354-7858 F:912-352.0165
11ITeslAmerica North Canton-4101 Snuffer Drive NW. north Canton. OR 44720 P:330-497-9398 F:330-497.0772
OTeslAmda Tampa -6712 Benjamin Road, Suite 100. Tampa. FL 33534 P:813-885-7427 F.813-685.7049
OTeslAm .0 Pensacola -3355 MCLemom Drve. Pensacola. FL 32514 P:850474-1001 F: 850.478R671
OTestAmedca Buflalo- 10 Hazelwood Drive, Suite 106, Amherst. NY 14228 P:7164i91-2600 i:716-951-7991
❑ TestAmerica Chicago - 2417 Bond Street. University Park. It. 60466 P.708-534-5200 R 708.534-5211
SHIPMENT INFORMATION
Shipment Method:
_
Sryjpment Tracking No:
CSXT PROJECT INFORMATION Prof. State (State of Origin)
CONSULTANT INFORMATION Ploject C:
CSXT Project Number: Prof. City:
Company: PM:�
CSXT Project Name: I Q b n
r
Address. Email
CSXT ContM -� LYJON: /'
City. Slate, Dp: Phone: - I=
Turnaround Time: ❑ Standard 6.13 Days
❑ 1 Day Rush -, -Specify k Days
❑ 2 Day Rush "rudard 14 Days
❑ 3 Day Rush ❑ Other
Preservative Codes: 3 = Sulfuric Acid Note a*
0 = No Preservatives 4 - Sodium Thlosulfate Pres:
1 ='Hydrochloric Acid 5 = Sodium Hydroxide Code
2 = Nitric Acid 6 = Other
COMMENTS
LAB USE
-METHODS
FOR
ANALYSIS
� i
L
0
�
Q;
n,^l
1
V!
,(
J
'
Q
(`+�
Deliverables: ❑ Other Deliv:
❑ CSXT Standard (Level 11)
❑ Level III ❑ EDD Required. Formal:
El Level IV
Matrix Codes: SO = Soil LIO = Liquid
GW = Groundwater SL = Sludge
W W = Waste Water 01= Oil
Surface Water SOL=Other 5cffd
SAMPLE. INFORMATION -
Sample Identification
Containers
Sam le Collection
Filtered
Type
Matrix
Number&
Type
Dale
Time
Sampler
YorN
Comp
or
Coda
Y5dtlrcj r/ .
oo4f
� -Ia
is
6,2
O
oc a cC
j2r"I
µ2710
ZSr,
Q
(16:1,4"2F E
OC Ns I
2 -ro
925
C4Z
IV
-
; R c
SooPLss
-2 -
7,25
fr W CQ
z�SD 11
-2 : ID
�5
GJQ
AN(
fr
( rM•I
-27-1
25
C�
a
ci
Relinquished By:
DateRma:
Rec y:
Da ens:
-.�_ _ D d
Communes & Special Analytical Requirements:
•rp y1,1
(� ' IP O -
Relinquished By:
DataMmus:
Receive By:
Detomme:
Relinquished By:
OaleMme:
Received By:
OateMme:
rR�ceived ey Labors ry; n
- \
'p'a}}zelTlmeq f
y• u I �-
Leb Remarks: - - _
LAB USE: Custody Inlact
❑Yes ❑ No
Custody seal a
q
LAB�Lo�ulDhei n �.
A- U 1
UHIUINAL— REJURN TO LABORATORY VMH SAMPLES 'INVOICE MUST BE SUBMITTED TO CSXT WFrH ORIGINAL COG TAL-6006(0509)
T

Login Sample Receipt Check List
Client: CSX Transportation
Login Number: 57105
Creator. Daughtry, Beth ..
List Number: 1
question T / F/ NA ' Comment
Radioactivity, either was not measured or, if measured, is at or below
N/A
background
The cooler's custody seal, if present, is Intact.
True
The cooler or samples do not appear to have been compromised or
True
tampered with.
Samples were received on Ice. ...
True
Cooler Temperature Is acceptable.
True
Cooler Temperature Is recorded.
True
COC is present.
True
COC is filled out in Ink and legible.
True
COC. is filled out with all pertinent information.
True
There are no discrepancies between the sample IDs on the containers and
Two
the COC.
Samples are received within Holding Time.
True
Sample containers have legible labels.
True
Containers are not broken or leaking.
True
Sample collection date/times are provided.
True
Appropriate sample containers are used.
True
Sample bottles are completely filled.
True '
There Is sufficient vol. for all requested analyses, Incl. any requested
True
MS/MSDs
VOA sample vials do not have headspace or bubble is <6mm (1/4") In
N/A
diameter.
If necessary, staff have been informed of any short hold time or quick TAT
True
needs
Multiphasic samples are not present.
N/A
Samples do not require splitting or compositing
NIA
Is the Field Sampler's name present on COC?
False
Sample Preservation Verified
True
Job Number: 680-57105-1
List Source: TestAmerica Savannah
TestAmerica Savannah
Page 17 of 17

ATTACHMENT A — LIMITATIONS AND MONITORING REQUIREMENTS
PPI 001— W WTF Effluent
EFFLUENT CHARACTERISTICS
Parameter Description — Parameter Code
Flow, in conduit or thru treatment plant —50050
Solids. Total Dissolved-180 Deg.C— 70300
pH — 00400
Carbon, Total Organic (TOC) — 00680
Nitrogen, Nitrate Total (as N) —00620
Barium, Total (as Be) —01007
Cadmium, Total (as Cd)-01027
Chromium, Total (as Cr) — 01034
Lead, Total (as Ph) — 01051
Arsenic, Total (as As) —01002
EFFLUENT. LIMITS
Monthly Average Weekly Average
1.0 1 mgd
3 X year monitoring shall be conducted in March, July and November.
Additional monitoring performed May 2010
Permit Number: WQ0000601
Version: 3.0
MONITORING REQUIREMENTS
Daily Maximum
Monitoring Frequency
Sample Type
t5.03 i(o
t+,
Continuous
Recorder
95
mg/L
3Xyear
Grab
S tJ
3 X year
Grab
12
mg/L
3 X year
Grab
0.13
mg/L
3 X year
Grab
0.023
mg/L
3Xyear
Gmb
<0.00
mg/L
3Xyear
Grab
<0. 01
mg/L
3 X year
Grab
<0.01
mg/L
3Xyear
Grab
<0 002
mg/L
3Xyear
Grab
W00000601 Version 3.0 Attachment A
Page 1 of l

TeStAme lca
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Job Number: 680-58078-1
Job Description: CSX Hamlet, NC WWTP Monthly
For:
CSX Transportation
500 Water Street
Jacksonville, FL 32202
Attention: Mr. Mike Gregory
AP�effvrYe.
IteOvyn SirvN
Pm7eq M 62T201f13:45 P
1<5 PM
Kathryn Smith
Project Manager I
[e-mail]
06/22/2010
cc: Mr. Jerry Cato
Mr. Alan Pinnix
LWO N-E N V0000027258//Project-R000011790
The test results in this report meet NELAP requirements for parameters for which accreditation. is required or available.
Any exceptions to the NELAP requirements are noted. Results pertain only to samples listed in this report. This report
may not be reproduced, except in full, without the written approval of the laboratory. Questions should be directed to the
person who signed this report. I
Savannah Certifications and ID #s: A2LA: 0399.01; AL: 41450; ARDEQ: 88-0692; ARDOH; CA: 03217CA; CO; CT:,
PH0161; DE; FL: E87052; GA: 803; Guam; HI; IL: 200022; IN; IA: 353; KS: E-10322; KY EPPC:'90084; KY UST; LA
DEQ: 30690; LA DHH: tA080008; ME: 2008022; MD: 250; MA: M-GA006; MI: 9925; MS; NFESC: 249; NV: GA00006;
NJ: GA769; NM; NY: 10842; NC DWQ: 269; NC DHHS: 13701; PA: 68-00474; PR: GA00006; RI: LA000244; SC:
98001601; TN: TN0296; TX: T104704185; USEPA: GA00006; VT: VT-87052; VA: 00302; WA; WV DEP: 094; WV
DHHR: 9950 C; WI DNR: 999819810; WY/EPAR8: 8TMS-Q
TestAmerica Laboratories, Inc. Eo ACC"
TesfAmerica Savannah 5102 LaRoche Avenue, Savannah, GA 31404 ���Cr_ • �e,.,� *o�,
Tel (912}3547858 Fax [phone] Avow testamericainc com E e�PW
Page 1 of 18 lid

Job Narrative
680-58078-1
Comments
No additional comments.
Receipt
All samples were received in good condition,within temperature requirements.
Metals
No analytical or quality issues were noted.
General Chemistry
No analytical or quality issues were noted.
Page of 18

METHOD SUMMARY
Client: CSX Transportation
Job Number..680-58078-1.
Description Lab Location Method Preparation Method
Matrix: Water
Metals (ICP) -
TAL SAV
40CFRI36A 200.7 Rev 4.4
Preparation, Total Metals
TAL SAV
EPA 200.7
HEM and SGT-HEM
TAL SAV
1664A 1664A
HEM and SGT-HEM (Aqueous)
TAL SAV
1664A 1664A
Nitrogen, Nitrate -Nitrite
TAL SAV
MCAW W 353.2
Solids, Total Dissolved (TDS)
TAL SAV
SM SM 2540C
Organic Carbon, Total (TOC)
TAL SAV
SM SM 5310B
Lab References:
TAL, SAV = TestAmerica Savannah '
Method References:
1664A = EPA-821-98-002
40CFR136A = "Methods for Organic Chemical, Analysis of Municipal Industrial Wastewater% 40CFR, Part 136, Appendix A,
October 26, 1984 and subsequent revisions.
EPA = US Environmental Protection Agency
MCAW W = "Methods For Chemical Analysis Of Water And Wastes", EPA-60014-79-020, March 1983 And Subsequent Revisions.
SM = "Standard Methods For The Examination Of Water And Wastewater,
TestAmerica Savannah
Page 3 of 18

Client: CSX Transportation
METHOD/ANALYST SUMMARY
Job Number: 680-58078-1
Method - Analyst Analyst ID
40CFR136A."200.7Rev 4.4 Bland, Brian BCB
1664A 1664A Samuel, Santa SS
MCAWW 353.2 Ross, Jon JR .
SM SM 2540C Robinson, Tiffany TR
SM SM 53100 Blackshear, Kim - KB
r
k
TestAmerica Savannah
a
Page 4 of 18

SAMPLE SUMMARY
Client: CSX Transportation Job Number: 680-58078-1
Date/Time Daterrime
Lab Sample ID Client Sample ID Client -Matrix Sampled Received
680-58078-1 Water Sample Water 05/27/2010 0930 05/28/2010 1010
TestAmerica Savannah
e
Page 5 of 18

a
Analytical Data
Client: CSX Transportation
Job Number: 680-58078-1
Client Sample. ID:
Water Sample
Lab Sample'ID:
680-58078-1
Date Sampled: 05/27/2010 0930
Client Matrix:
Water
Date Received: 05/28/2010 1010'
200.7 Rev 4.4 Metals (ICP)
Method: .:
200.7 Rev 4.4
Analysis Batch: 680-170814
Instrument ID:
ICPD
Preparation:
200.7
Prep Batch: 680-170556
tab File ID:
170556.chr
Dilution:
1.0
Initial Weight/Volume:
50 mL
Date Analyzed:
06/08/2010 0018,
Final Weight/Volume:
50 mt.
Date Prepared:
06/04/2010 0850
Analyte
Result (mg/L)
Qualifier
MDL
RL.
Arsenic
0.020
U
0.0046
0.020
Barium
6.023
_
0.0023
0.010
Cadmium
0.0050
U
0.0020
0.0050
Chromium
0.010
U
0.0012
0.010
Lead
0.010
U
0.0040
0.010
TestAmerica Savannah Page 6 of 18

Analytical Data
Client CSX Transportation - Job Number. 680-58078-1
General Chemistry
Client Sample ID: Water Sample
Lab Sample ID: 680.58078-1 - .Date Sampled: 05/27/2010 0930
Client Matrix: Water D t R
a e ecerved: 05/28/2010 1010
Analyte . Result
Qual Units MDL
RL
oil
Method
HEM (Oil & Grease)- 5.0
U mg/L. 1.4
5.0
1.0
1664A
Analysis Batch: 680-170282
Date Analyzed: 06/02/2010 0000
Prep Batch: 680-170250
Date Prepared: 06/01/2010 1705
Nitrate as N 0.13
mg/L 0.010
0.050
1.0
, 353.2
Analysis Batch: 680-170222
Date Analyzed: 05/28/20101612
Total Organic Carbon 12
mg/L 0.50
1.0
1.0
SM 5310B
Analysis Batch: 680-171156
Date Analyzed: 06/09/2010 1339
Analyte - Result
Qual Units RL
RL
Dil
Method
Total Dissolved Solids 95
mg/L 5.0 -
5.0
1.0
SM2540C
Analysis Batch: 680-170253
Date Analyzed: 06/01/2010 1453
t
TestAmerlca Savannah Page 7 of 18

DATA REPORTING QUALIFIERS
Client: CSX Transportation
Lab Section Qualifier Description. -
Metals
General Chemistry
TestAnierica Savannah
Job Number: 680-58078A
U Indicates the analyte was analyzed for,but not detected.
U Indicates4he analyte was analyzed for but not detected.
4 MS, MSD: The analyte present in the original sample is 4 times
greater"than the matrix spike: concentration; therefore, control
limits are'notapplicable.
J Result is less than the RL but greater than or equal to the MDL
and the concentration is an approximate value.
n
Page 8 of 18

Client: CSX Transportation
Method Blank- Batch: 680-170556
Lab Sample ID:
MB 680-170556/21-A
Analysis Batch: 680-170814
Client Matrix:
Water
Prep Batch: 680-170556
Dilution:
1.0
Units: 'mg/L
Date Analyzed:'
06/07/2010 2318
Date Prepared:
06/04/2010 0850
Analyte
Result
Arsenic
-
- 0.020 '
Barium
0.010
Cadmium
0.0050
Chromium
0.010
Lead
0.010
Lab Control Sample- Batch: 680-170556
'
Lab Sample ID:
LCS 680-170556122-A
Analysis Batch: 680-170814
Client. Matrix:
Water
Prep Batch: 680-170556
Dilutlon,
1.0
Units: mg/L
Date Analyzed:
06/07/2010 2323 "
Date Prepared:
06/04/2010 0850-
Analyte
Spike Amount Result
Arsenic4
2.00 2.06
Barium
2.00 2.08
_
Cadmium
0.0500 0.0499
Chromium
0.200 0.206
Lead
0.500. 0.518
Quality Control Results
Job Number: 680-58018-1
Method: 200.7 Rev 4.4
Preparation: 200.7
Instrument ID: ICPD
Lab File ID: 170556.chr
Initial WelghWolume: 50 mt.
Final WeighWolume: 50 mL
f
Qual
MDL -
RL '
U
- 0.0046
0.020
U ;"
0.0023
0.010
U.
0.0020
0.0050
U
0.0012
0.010
U
0.0040
0.010�
Method: 200.7 Rev 4.4
Preparation: 200.7
Instrument ID: ICPD
-
LabFlle ID: 170556.chr
Initial WeighWolume: 50r
mL
Final WeighWolume: 50
mL,
% Rec. Limit "
Quay. ,
103
85-115
104
85-115
'
100
85-115
103
85 - 115
104
85 - 1.15
TestAmerlca Savannah Page 9 of 18

Client: CSX Transportation
Matrix Spike/
Matrix Spike Duplicate Recovery Report - Batch: 680-170556
MS Lab Sample ID:
680-58078-1
Analysis Batch: 680-170814
Client Matrix:
Water
Prep Batch: 680-170556
Dilution:
1.0
}
Date Analyzed:
06/0812010 0034
Date. Prepared:
06/04/2010 0850
MSD. Lab Sample ID:
680 58078-1. -
Analysis Batch. 680-170814
Client Matrix:
Water
Prep Batch: 680-170556
Dilution:
1.0
,
Date Analyzed:
06/0812010 0039 -
Date Prepared:.
06/04/2010 0850
% Rec.
Analyte MS MSD Limit
Quality Control Results
Job Number. 680-59078-1
Method::200.7 Rev 4.4
Preparation: 200.7 ..
Instrument ID: ICPD
Lab File ID: 170556.chr
Initial Weight/Volume: 50mL
Final Weight/Volume: 50 mL
Instrument ID: ICPD
Lab File ID: 170556.chr
Initial Weight/Volume: 50 mL
Final Weight/Volume: 50 mL
RPD RPD Limit MS Qua] MSD Qual
Arsenic.
105
106
75-125.
0
20
Barium
106
105
75 - 125
0
20
Cadmium.
102
101
75-125
0
20
Chromium
105
105
75 -125
0
20
Lead
105
106
75 -125
1
20
t
TestAmerica Savannah'. Page 10 of 18

f
Client: CSX Transportation
Method Blank -Batch: 680.170250
Lab Sample -ID:, MIS 680-170250/21-A
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 06/02/2010 0000
Date Prepared: 06/01/2010 1705
Analysis Batch: 680-170282
Prep Batch: 680-170250
Units: mg/L
Quality Control Results
Job Number: 680-58078-1
Method: 1664A-
Preparation: 1664A
InstrumentID: No Equipment Assigned
Lab File 10: , N/A
Initial Weight/Volume: 500 mL
Final WeighWolume: 500 mL
Analyte - Result Qual MDL RL
HEM.(Oil.& Grease) 5.0 ll . 1.4 5:0 ,
Lab ControlSample/ Method: 1664A -
Lab Control Sample Duplicate Recovery Report - Batch: 680-170250 Preparation:1664A
LCS Lab Sample ID:
LCS 680-170250/22-A
Analysis Batch: 680-170282
Instrument ID:, No Equipment Assigned
Client Matrix:
Water
Prep Batch: 680-170260
Lab File ID: N/A
Dilution:
1.0
Units: mg/L
Initial Weight/Volume: 500 mL '
Date Analyzed:
06/02/2010 0000
Final WeighWolume: 500 mL '
Date Prepared:
06/01/2010 1705
-
LCSD Lab Sample ID:
LCSD 680-170250/23-A
Analysis Batch: 680-170282
Instrument ID: No Equipment Assigned
Client Matrix:
Water
Prep Batch: 680-170250
'Lab File ID: N/A.. ,
Dilution:
1.0
Units: mg/L -
Initial Weight/Volume: 500 mL '
Date Analyzed:
06/02/2010 0000
Final WelghWolume: 500, mL
Date Prepared:
06/01/2010 1705,
% Rec.
Analyte
LCS, LCSD Limit
RPD RPD Limit LCS Qual LCSD Dual
HEM (Oil & Grease) 100 99 78 - 114 1 18
TestAmerica: Savannah
Page 11 of 18
9

Quality Control Results
Client: CSX Transportation Job Number: 680-58078-1
Method Blank —Batch: 680-170222
Method:353.2
Preparation: N/A
Lab Sample ID:
MB 680-17022211
Analysis Batch: 680-170222
InstrumentID: Latchat 2
Client Matrix:
Water
Prep Batch: WA
Lab File ID: N/A
Dilution:
1.0
Units: mg/L
Initial Weight/Volume: 7
mL
Date Analyzed:
05/28/2010 1612
Final WeighWolume: 7
mL
Date. Prepared:
N/A
Analyte
Result Qua[
MDL
RL
Nitrate as N
0.050 U
0.010
0'.0!
Lab Control Sample - Batch: 680-170222.
Method: 353.2
-�
Preparation: NIA
Lab Sample ID:
LCS 680-170299/9
Analysis Batch: 680-170222
Instrument 10: Latchat 2
Client Matrix:
Water
Prep Batch: N/A
Lab File 10: N/A
Dilution:
1.0
Units: mg/L
Initial Weight/Volume: 7
mL
Date Analyzed:
05128/20101612
Final Weight/Volume: 7
mL
Date Prepared: NIA
Analyte
Spike Amount Result % Rec. Limit Qual
Nitrate as N
0.500 0.501
100 90 - 110 -
Matrix Spike/
Method: 30.2
Matrix Spike Duplicate Recovery Report - Batch: 680.170222
Preparation: -N/A
MS Lab Sample ID:
680-58064-E-1 MS'
Analysis,Batch: 680-170222
instrument ID: Latchat 2
Client Matrix:
Water
Prep Batch: N/A
Lab File ID: N/A
Dilution:
5.0
Initial WeighWolume: 25 mL
Date Analyzed:
05/28/2010 1612
Final Weightolume: 25 mL
Date Prepared:
N/A
MSD Lab Sample 10:
680-58064-E-1 MSD
Analysis Batch: 680-170222
Instrument ID: Latchat 2
Client Matrix:
Water
Prep Batch: N/A
Lab File ID: NIA
Dilution:
5.0
Initial WelghWolume: '25 mL
Date Analyzed:
05/28/2010 1612
Final WeighWolume:. 25 mL
Date Prepared:
N/A
Analyte
MS
% Rec.
MSD
Limit
RPD RPD Limit MS Qual MSD Qual
Nitrate as N
104
105
90 - 110
0 10 4 4
TestAmerica Savannah Page 12 of 1S

Client: CSX Transportation
Duplicate -Batch: 680-170222
Lab Sample ID:
680-58072-G-3 DU
Client Matrix:
Water
Dilution:
4.0
Date Analyzed:
05/28/2010 1612
Date Prepared:
NIA
Analyte
Nitrate as N
Analysis Batch: 680-170222
Prep Batch: N/A
Units: mglL
Sample ResultlQual
0.20 U
Result
0.20
Quality Control Results
Job Number. 680-58078-1
Method: 363.2
Preparation: N/A
Instrument ID: Latchat 2
Lab File ID: NIA
Initial WelghWolume: 7 mL
Final WelghWolume: 7 mL
RPD .Limit
NC 10
Qual
U
TestAmericaSavannah Page 13 of 18
t

Client: CSX Transportation
Method Blank- Batch: 680.170253
Lab Sample ID: MB 680-17025311
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 06/01/2010 1453
Date Prepared: NIA
Analysis Batch: 680-170253
Prep Batch: N/A
Units: mg/L
Quality Control Results
Job Number. 680-58078-1
Method: SM 2540C
Preparation: N/A
Instrument ID: No Equipment Assigned
Lab File ID: N/A
Initial WeightArolume: 100 mL
Final WeighWolume: 100 mL
Analyte Result Qual RL RL
Total Dissolved Solids 5.0 U 5.0 5.0
Lab ControlSample/ - Method: SM 2540C
Lab Control Sample Duplicate Recovery Report - Batch: 680-170253 Preparation: N/A
LCS Lab Sample ID: LCS 680-170253/2
Client Matrix:
Water
Dilution:
1.0•
Date Analyzed:
06/0112010 1453
Date Prepared:
N/A
c
LCSD Lab Sample ID:
LCSD 680-170253/3
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
06/01/2010 1453
Date Prepared:
N/A '
Analyte
Total Dissolved Solids
Duplicate - Batch: 680-170253
Lab Sample ID:
680-58081-F-1 DU
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
06/01/2010 1453
Date Prepared:
N/A
Analyte
Total Dissolved Solids
Analysis Batch: 680-170253 Instrument ID: No Equipment Assigned
Prep Batch: N/A Lab File ID: N/A
Units: mg/L Initial WeighWolume: 100 mL
.Final Weight/Volume: 100 mL
Analysis Batch: 680-170253 Instrument ID: No Equipment Assigned
Prep Batch: N/A Lab File ID: NIA
Units: mg/L Initial Weight/Volume: 100 mL
Final WeighWolume: 100 mL
% Rec.
LCS LCSD Limit RPD RPD Limit LCS Dual LCSD Qual
101 99 80 - 120 2
Analysis Batch: 680-170253
Prep Batch: N/A
Units: mg/L
Sample Result/Qual Result
100 107
25
Method: SM 2540C
Preparation: N/A
Instrument ID: No Equipment Assigned
Lab File ID: N/A
Initial WeighWolume: 100 mL
Final WeighWolume: 100 mL
RPD Limit Qual
3 25
TestAmerica Savannah Page 14 of 18

Client CSX Transportation
Method Blank - Batch: 680.171156
Lab Sample ID:
MB 680-17115612.
Analysis Batch: 680-171156
Client Matrix`
Water
Prep Batch:. N/A
Dilution:
1.0
Units:, mg/L
Date Analyzed:
06/09/2010 1056
Date Prepared:
N/A •
Analyte Result
Total Organic Carbon 1.0
Lab Control Sample - Batch: 680-171156
Lab Sample ID:
LCS 680-17115614
Analysis Batch: 680-171156.
Client Matrix:
Water
Prep Batch: NIA
Dilution:
1.0
Units: mg/L
Date Analyzed:
06/09/2010 1129
Dale Prepared:
N/A -
Analyte Spike Amount Result
Total Organic Carbon 20.0 19.4
Matrix Spike/
Matrix Spike Duplicate Recovery Report - Batch: 680.171156
Quality Control Results
Job Number: 680-58078-1
Method: SM 5310B
Preparation: N/A
Instrument ID: T003
Lab File ID: T00060910.ixt
Initial Weight/Volume: 25 mL
Final Weight/Volume: 25 mL
Qual MDL RL
U 0.50 1.0
Method: SM 5310B
Preparation: N/A
Instrument ID: TOC3
Lab File ID: T00060910.bd
Initial Weight/Volume: 25 mL
Final Weight/Volume: 25 mL
%Rec. Limit
97 80 - 120
Method: SM 5310B"
Preparation: N/A
Qual
MS Lab Sample ID:
680-58093-I-4 MS
Analysis Batch:
680-171156
Instrument ID: TOC3,
Client Matrix:
Water
Prep Batch: WA
Lab File ID: T00060910.txt
Dilution:
1.0
Initial WeighWolume: 25 mL
Date Analyzed:
06/0912010 1628
Final WeighWolume: 25 mL
Date Prepared:
N/A
MSD Lab Sample ID:
680-58093-I-4 MSD
Analysis Batch:
680-171156
Instrument ID: TOC3
Client Matrix:
Water
Prep Batch: N/A
Lab File ID: T00060910.txt
Dilution:
1.0
Initial Weight/Volume: 25 mL
Dale Analyzed:
06/09/2010 1641
Final Welght/Volume: 25 mL
Date Prepared:
N/A -
,
% Rec.
Analyte
MS MSD
Limit
RPD RPD Limit MS Qual MSD Qual
Total Organic Carbon
98 97
80 - 120
1 25
TestAmerica. Savannah Page 15 of 18

Client: CSX Transportation
Duplicate.- Batch: 650-171156
Lab Sample ID:
680-58091-A-2 DU
Analysis Batch: 680-171156
Client Matrix:
Water
Prep Batch: N/A '
Dilution:
1.0
Units: mg/L
Date Analyzed:
06/09/2010 1451
Date Prepared:
N/A
Analyte
Sample Result/Qual Result
Total Organic Carbon
0.86 J 0.868
Quality Control Results
Job. Number: 680-58078-1
Method: SM 5310B
Preparation: N/A
Instrument ID: TOC3 .-
Lab File ID: T00060910:bd
Initial WeighWolume: 25 mL
Final Weight/Volume: 25 mL
RPD , Limit Qual
1 25 J
TestAmerica Savannah . Page 16 of 18

ha
W
m
,f
LABORATORY INFORMATION
UVL' IF
CHAIN OF
pTestAmerid Savannah-S1o2 LaRoche Avehue. Savannah. GA 31404 P:912.354.785B F:912-352.0165
OrestAmerea Norm Canton -4101 Shuifel Drive NW. North Canton, OH 44720 P:330-497.93S6 R230-497-0772
Road, Suite 100. Tampa, FL 33634:P:e13.885.7427 F:813-885-7049
SHIPMENT INFORMATION
Shipment Method: -
CUSTODY
pTes"erin Tampa -6712Benjamin
preslAmerim Pensacola - 3355 MCLemare Olive, Pensacola, R. 32614 P:850-474-1001 F.850-478.2671
ShlpmemTraddrig No:
TRANSPORTAYLON
[3TMtAmwim Buffalo - to Hamlwood Ddve, Suite 106, Amherst. NY 14220 P:716.691-2600 F:71"61-7991
pT,,lAmenra Chicago -2417 Bond Street. UaNdiniy Park IL 6040 P:700.534-5200 F. 708-534-5211
Fro]. State (state of Ori9m)
CSXT PROJECT INFORMATION .G
COLTANT INFORMATION Project C
CONSULTANT
CSXT Project Number: _ n Proj. City:
G fz E
Company: ". PM:
Address: Email
CS%T Protect Nama:
Zo if 0
LWON: -- /"r City, State, ZIP: Phone: Fan
CSXT Contact: / —
- r lD
(
Turnaround Time: ❑Standard 6r13 Days Preservative Codes: 3=Suiluric Acid' Note COMMENTS LAB USE
El Day Rush S ecily # Days 0 = No Preservatives 4 . Sodium Thiosullale Pros. METHODS FOR ANALYSIS
❑ 2 Day Rush Standard 14 Days 1 = Hydrochloric Acid 5 = Sodium Hydroxide Code ,
❑ 3 Day Rush ❑ Other 2 = Nitric Acid 6 = Other
Deliverable$: ❑ Osier Deli,: Matrix Codes: SO=Soil . LIO=Liquid
' v
❑ CSXT Standard (Level II) GW =Groundwater SL = Studge J M 1-
❑ Level 111 ❑ EDD Required, Format: W W = Waste Wald OI = Oil
❑ Level IV SW=Surface Waler SOL=Other Solid 1-9
-
SAMPLE INFORMATION
Containers Sle Collection Filtered T e Matrix ^1
r V
Sample Identification Number & Dale Time Sampler Y or N CORor Grab Code
Type
1 55DIVE d
5 on
-2 ' a
36.
2
Nltn/
soo 1
S �'r�10
30
3
o; I e St
DOM
CwA-
M.
zSDWin
z7,o
.'3�
R
S
d 7
&Z.
DateTms:
Comments & Special Analytical Requirements:
Relinquished By:
DaleTma:
Race' a
S - 1-1 o
Temp 15.-Z
`Ce. '�,d
Date7Rme:
calved By:
DataMme:
Relinquished By:
ReOnquishetl By:
Data7Tlme:
Re®Ned By:
DatwT=w..
ce+vetl y bor
Date/Timep:
Leb Remarks:
LAB.USE: Custody Imam Custody Seal9 LAB urPber ��
❑Yes ❑No $1
n
• U' a �I V
-
INVOICE MUST BE SUBMITTED TO CSXT WITH ORIGINAL COO TAL-6006(0509)
ORIGINAL- RETURN TO LABOSKTORY IyITH SAMPLES

Login Sample Receipt Check List
Client: CSX Transportation
Login Number: 58078
Creator: Daughtry, Beth
List Number: 1
Radioactivity either was not measured or, if measured, is at or below
background
The coolers custody seal, if present, is Intact.
The cooler or samples do not appear to have been compromised or,
tampered with. -
_ Samples were received on Ice.
Cooler Temperature is acceptable.
Cooler Temperature is recorded.
COG is present.
COG is filled out In ink and legible.
COG is filled out with all pertinent Information.
There are no discrepancies between the sample IDs on the containers and
the COG.
Samples are received within Holding Time.
Sample containers have legible labels.
Containers are not broken or leaking.
Sample collection date/limes are provided.
Appropriate sample containers are used.
Sample bottles arecompletely filled.
There Is sufficient vol. for all requested analyses, Ind. any requested
MS/MSDs
VOA sample vials do not have headspace or bubble is <6mm (1/4") in
diameter.
If necessary, staff have been informed of any short hold time or quick TAT
needs
Multiphasic samples are not present.
Samples do not require splitting or compositing.
Is the Field Sampler's name present on COG?
Sample Preservation Verified
T/F/NA Comment
N/A
True
True
False
N/A
True
True
True
True
True
True
True
True
True
True
True
True
N/A
True
NIA
N/A
False
True
15.2'
Job Number. 680-58078-1 '
List Source: TestAmerica Savannah
TestAmerica Savannah
Page 18 0£ 18

GW-59A COiMPLLANCE REPORT FORM Permit # LJ d6�
(Submit one each ntoniroring period with GIV--59 forms.)
I
Enter date monitoring results were due: 110 Will this monitoring report (GW59 and GW-59A)
be submitted after the established. due date?
YES
NO
X
2
Was any required information missing on the GW-59 report forms?
IF the answer to question 1 or 2 is °YES ;list in the space provided below the wellidentification cation number(s) and
YES
NO
explain the problems encountered in obtaining the required information.
Mon;}pr:t.� wells A( tf3
yD were cQr(, CL sa.�,61e Wc. nr,r
I (1 r 1 v)
GCve VO OW Wc. l'cv Ievelo
3identification
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
plate, area overgrown, etc.)? ff1he answer is "Yes",
YES
NO
contact the Regional Ofcefor guidance.
FT4�"een
4
Are any monitored constituents equal to or above the established standards? -
YES
O
If the answer to question 4 is °NO , skip to section S.
If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentretion(s)
exceeding standards in the space provided below:
j,
For the constituents Identified In question 4 above, have standards been exceeded previously for the
YES
NO
same constituent(s) In the same well(s) in the last two years?
If the answer to question 5 is 'NO", skip to section a.
If the answer to question 51s "YES" list in the space provided below, each well wilh constiluent(s) exceeding
standards, concentration(s) reported, and sample collection date for
each occurrence (for the last two years).
6
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
YES
NO
If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL.
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer Is "NO" monitoring wells maybe Improperly
located; contact the Regional Office.
7
Is the permittee implementing previously approved actions required by the Division involving this
groundwater quality problem?
YES
NO
If the answer to question 7 is "YES", describe those actions in the space provided below.
If the answer to question 7Is contact the Regional Office wlth/n 90 days* an evaluation maybe
required to determine the impact the waste disposal system Is having at the review and compliance
boundaries surrounding this facility. Failure to do so may subiect the permfttee to a Notice of Violation
lines, and/oroenalties.
g
The person completing this poet/on (G W-59A) of the monitoring report should sign below and submit this
form with GW59 forms for required wells to the address
provided at the top of the current G W-59 form.
I -hereby acknowledge tha! above )nfonnation was evaluated and:tfiWhiforrnatton submittedan thi
rep'ort(Co�tance 59A}is;trueand.cornplete�tothebestof,mryknowleilge���„^^f
gnature a ee (orAUtFrorlzed Agent) Mats
GW-59A 12/8f2003

SUBMIT FORM ON
Facility Name CSX Transportation - Hamlet Wastewater Treatment Facility
Facilly, Address 173 CSX Drive
Hamlet, NC 28345 County Richmond
Contact Person: MIKE GREGORY Telephone #: [phone]
Well Location/Sity Name: see location map No. of Wells to be Sampled: 8
Well Identification Number (From Permit): MW-1 For Groundwater Treatment
Systems
Well Depth 53.75 ft. .Well Diameter. 4.0 in. Check One:
Screened Interval: ft. to ft OInfluent(98)
Depth to Water Level ft. below measuring point. © Effluent (99)
Measuring point (M.P.) is: ft. above land surface Relative M.P. Elevation in ft...
Gallons of water Pumped/balled —before sampling: Date Sample Collected
Field Analysis: pH Specific Conductance uMhos
Temp. ° C Odor Appearance
PAPER
PERMIT #.
Non -Discharge
NPDES
EXPIRATION DATE: November 30, 2009
WQ0000601 UIC
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
Spray Field Remediation:
Rotary Distributor Land Application of Sludge
X Other Monitoring Well
NOTE* Values should reflect dissolved and collaidal concentrations
Date Sample Analyzed
Laboratory Name:
Certification No.
PARAMETERS: (Samples for metals were collected unfiltered YES
COD
_X NO and
field acidified
YES NO)
Coliform: MF Fecal
mg/I
/ 100MI
Nitrite (NO2) as N
Nitrate (NO3) as N
mg/l
Ni - Nickel
mg/I
Coliform: MF Total
(Note: Use MPN method for highly turbid
/ 100m1
Phosphorus: Total as P
mg/I
mg/I
Pb -Lead
Zn -Zinc
mg/I
samples)
Dissolved Solids Total mg/I
Orthophosphate
AI -Aluminum
mg/I
Ammonia Nitrogen
mg/I
PH (when analyzed)
units
Be - B
Barium
mg/1
mg/I
Other (Specify Comp ounds and conceritration units)
TOC
Chloride
mg/l
Ca -Calcium
mg/1
mg/I
Arsenic
mg/I
Cd - Cadmium
mg/I
Grease and Oils O�°b�
mg/I
Chromium: Total
mgA
/R+
Phenol " ` L:
mg/I
Cu- Copper
mg/I
Sulfate ZOf
mg/I
mgd
Fe - Iron
Hg - Mercury
m9d
ORGANICS: (GC, GC/MS, HPLC)
Specific Conductaflerettalio ;
Mhos
K- Potassium
mg/I
(Specify test and method #. Attach lab report)
Tdtal Ammonia rocb
ni..
4ra
Mg -Magnesium
mg/I
Report Attached? Yes No_(0)
TKN as N ,rf� <
—mg/I
mg/l
Mn -Manganese
m 9/I
_(1)
VOC : method # _
mg/l
VOC : method # =
VOC :method#=
'i
r •
..
..
Carl A. Gerhardstein,
• VP Environmental Systems
GW-59 Rev. 03/2000
Ferm/�h
gent�me and Title -Please print or type r
-

FORM ON YELLOW
ONLY
Facility Name Hamlet Wastewater TreatmentFacility
Facility Address CSX Transporta0on. BOX 191A Highway 177N
Hamlet. NC 28345 County Richmond
Contact Person: M. L. GREGORY [phone]
Well Location/Sity Name. Location Map Attached
Well Identification Number. MW-2
Well Depth: 41.48 ft. Well Diameter: 4.0 in.
Screened Interval ft. To ft
Depth to Water Level 36.3 ft. below measuring point
Measuring point Is ft. above land surface
Gallons of water pumped/bailed'before sampling:
Field Analysis pH 5.47 Specific Conductance _ 5.1 uMhos
Temp. _eC Odor Appearance
Grountlwater Treatment Systems
❑Q Influent (98)
Effluent (99)
PERMIT M EXPIRATION DATE July 31. 2014
Non -Discharge W00000601 UIC
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
Spray Field Remediation
_ Rotary, Distributor Land Application of Sludge
X Other Moniterina wau
PARAMETERS: (Samples for metals were collected unfiltered _X_ YES NO
CO mg/l
Coliform: MF Fecal / 100ml
Coliform: MF Total / 100ml
(Note: Use MPN method for highly turbid samples)
Dissolved Solids Total
pH (when analyzed)
TOC
49. mg/I
units
Chloride -
mg4
Arsenic <0.02
moll
Grease and Oils
mg/I
Phenol
mg/I
Sulfate 1 a
mg/I
Specific Conductance
Mhos
Total AmmoniA
mg/I
TKN as N fir—
Information Prn,--,_
mgll
NOTE Values should reflect dissolved and collaidal concentrations
Date Sample Collected 07/08/10
Laboratory Name
Certification No.
and field acidified _X_ YES
NO-2 as N
mg/I
NO_3 as N
1.6
mg/I
Phosphorus: Total as P
mg/l
Orthophosphate
mg/I
AI - Aluminum
mg/I
Ba-Barium
<0.0073
mg/I
Ca - Calcium
mg/I
Cd -Cadmium
<0.005
mg/I
Chromium: Total
<0.0017
mg/I
Cu - Copper
Fe - Iron
Hg - Mercury _
K - Potassium _
Mg - Magnesium
Mn - Manganese
Date Sample Analyzed 07/21/10
NO)
Ni - Nickel
mg/1
Pb - Lead <0.004
mg/I
Zn -Zinc
mgll
Ammonia Nitrogen
mg/I
Other (Specify Compounds and concentration
units).
ORGANICS: (GC, GC/MS, HPLC)
(Specify test and method If. Attach lab report.)
Report Attached? Yes—(1) No_(0)
VOC : method#=
VOC : method#=

SUBMIT FORM ON
ONLY
Facility Name . Hamlet Wastewater Treatment Facility
Facilty Address CSX Transportation Box 191A.Highway 177N
Hamlet, NC 28345 County Richmond
Contact Person: M. L. GREGORY [phone]
Well Location/SityName: Location Map Attached
Well Identification Number.. � MW-3 For Gm=heeter Trwiment Systems
Well Depth: _" 45.70 fit. Well Diameter. , 4.0 'in, cnea oee:
Screened Interval It. To fL' Influent (98)
Depth to Water Level fL below measuring point ® Effluent (99j
Measuring point is ft. above land surface
Gallons of water Pumpediballed before sampling:
Field Analysis pH. " Specific Conductance — uMhos
Temp. C Odor Appearance
PARAMETERS:
PERMIT #: EXPIRATION
Non -Discharge W00000601 u1C
NPDES "
TYPE OF PERMITTED OPERATION BEING MONITORED
(Samples for metals were collected unfiltered _X_ YES NO
CO
I mg/l
Conform: ME Fecal
/ 100m1
Coliform: MF Total
/ 100ml
(Note: Use MPN method for highly turbid samples)
Dissolved Solids Total
mg/I
PH (when analyzed)
units
TOC-
mg/l
Chloride
mg/I
Arsenic -
__,.
Grease and Oils
mgll
Phenol
mg/I
Sulfate
mgll
Specific Conductance
Mhos
Total Ammonia `
mg/l
TKNas N ".
moll:
NO-2 as N
NO-3 as N
Phosphorus: Total as P
Orthophosphate
AI - Aluminum
Ba - Barium
Ca - Calcium
Cd - Cadmium
Chromium: Total
Cu - Copper
Fe - Iron
Hg - Mercury _
K - Potassium
Mg - Magnesium
Mn - Manganese
2009-
Lagoon Remediation: Infiltration Gallery
Spray Field - Remediation
Rotary Distributor 'land "Application of Sludge
X Other "Monitoring Well ` , .
NOTE Values should reflect dissolvedand colldidal concentrations .
Date Sample Collected Date Sample Analyzed
Laboratory Name
Certification No.
and field acidified X_ YES NO)
mg/l Ni -Nickel mg/I
mg/I Pb -Lead mg/l
mg/I Zn-Zinc
mg/l Ammonia Nitrogen mg/I
mg/I Other (Specify Compounds and concentration units)
mg/l
mg/1
moll
mg/l ORGANICS: (GC, GC/MS, HPLC)
mg/I (Specify test and method #. Attach lab report.)
mgll Report Attached?Yes_0) No" (0)
mgll' VOC method #_
mgll VOC : method # =

Facility Name 'Hamlet Wastewater Treatment Facility -
Facilty Address _CSX Transportation Box 191A Highway MN
Hamlet, NC 28345 • County Richmond
Contact Person: M. L. GREGORY 1(910)582-4901
Well Location/Site Name: Location Map Attached
Well Identification Number. MW=4 - Far Grwnd� Treahnen( syst m
Well Depth: 47.45 ft. Well Diameter: 2.0 in: cb x01m:
Screened Interval - % To, ft. - — ® Influent (9fl),
Depth to Water Level 36.5 it below measuring point [] Effluent (99)
Measuring point is - fL above land surface
Gallons of water Pumpedibailed before sampling:
Field Analysis pH 6.18 Specific Conductance 0.0 ' uMhos
TemP• _ eC Odor Appearance
PARAMETERS -
PERMIT #: - - - EXPIRATION I
Non -Discharge W00000601 UIC
NPDEs
TYPE OF PERMITTED OPERATION BEING MONITORED
(Samples for metals were collected unfiltered _X_ YES NO
CO
mg/I
Coliform: MF Fecal
/ looml
Coliform: MF Total
/loom[
(Note: Use MPN method for highly turbid samples)
Dissolved Solids Total 36.
moil
PH (when analyzed)
- units
TOC, 1.
mgn•
Chloride-' _
-. -mg/l
Arsenic <0:02
ing/l
Grease and Oils
mg/i,
Phenol
mg/l
Sulfate
moll
Specific Conductance
Mhos
s
Total Ammonia
TKN as N'
mail
2014'
Lagoon Remediation: Infiltration Gallery
Spray Field Remediatiob
Rotary Distributor Land` Application of Sludge
X Other Monitoring, Well
NOTE Values should reflect dissolved and collaidal concentrations
Date Sample Collected 07/08/10 Date Sample Analyzed 07/21/10
Laboratory Name TestAmerica Laboratories 1NC
Certification No. 269
and field acidified _X_ YES' NO)
NO-2 as N
moll
Ni - Nickel
NO 3 as N
0.33
moll
Pb - Lead < 0.01
mg/l
Phosphorus: Total as P
mg/1
Zn =Zinc
mg/I
Orthophosphate
mg/1
Ammonia Nitrogen
mg/l
AI -Aluminum
moll-
mg/k
"Other (Specify Compounds and concentration.
Be - Barium
<0.01
- mg/l
units)
Ca -Calcium --
-
-, moll
Cd - Cadmium-'
<0.005
moll
..
Chromium: Total
•<0,01.
- mg/i
Cu - Copper
mg/1
Fe -Iron
Hg'- Mercury
In
ORGANICS: (GC, GC/MS, HPLC)
K-,Potassium
mg/1
(Specify test and method #. Attach lab report)
Mg - Magnesium
moll
Report Attached? 'Yes _([) No_(o)
Mn.-Manganese
mg/1
VOC method #
:
mg/I
VOC :method # _
rn
VOC method#

YELLOW
ONLY
. Facility Name Hamlet Wastewater Treatment Facility
Facilty Address CSX Transportation Box 191AHighway 177N '
Hamlet, NC 28345 County Richmond
Contact Person: ML. GREGORY ' (910)582-901
Well Locatiort/Sity Name: Location Map Attached
Well Identification Number: MW-5,
Well Depth: 52.92 fL Well Diameter.- 2.0 in. c"ecko-`
_Screened Interval - ft. To ft. Influent (98)
Depth to Water Level 43.7 tL below measuring point ® Effluent (99)
Measuring point is - ft. above land surface
Gallons of water pumpedibailed before sampling:
Field. Analysis. pH 5.39 Specific Conductance 1a,1 uMhos
Temp. _°C Odor Appearance
PERMIT M ` EXPIRATION DATE July 31, 2014
Non -Discharge WO000�_ UIC
NPDES
TYPE OF PERMITTED OPERATION BEINGMONITORED
Lagoon _ Remediation: infiltration Gallery
Spray Field Remediation _
_ Rotary Distributor _ Land Application of Sludge
X Other Monitoring Well
PARAMETERS: (Samples for metals were collected unfrlter id X_ YES
NO
CO,
Coliform: MF Fecal
mg/l
/ 100ml
Coliform: MF Total
/ t00m1
(Note: Use MPN method for highly turbid samples)
Dissolved Solids Total 54;
mg/l
PH .(when analyzed)
units
TOC 0.6
mg/I
Chloride -
mgll
Arsenic <0.02
mg/I
Grease and Oils
mg/I
Phenol
mg/l
Sulfate
mg/1
Specific Conductance
mhos
Total Ammonia
mg/I
TKN as N
mall
NOTE Values should reflect dissolved and collaidal concentrations
Date Sample Collected 07/08/10 Date Sample Analyzed 07/21/10
Laboratory Name' TestAmerica Laboratories,.INC
Certification No. 269
and field acidified _X YES NO)
NO_2 as N
mg/l,
NO-3 as N 0.74
mg/I
Phosphorus: Total as P
mg/1
Orthophosphate
mg/1
AI -Aluminum
mg/1
Ba - Barium .0.02
mg/I.
Ca - Calcium.
_ mg/I
Cd - Cadmium' _ <0.005
mg/1-
Chromium: Total <0.01
mg/I
Cu - Copper
mg/I
Fe - Iron
mg/I
Hg -Mercury
K - Potassium
—mg/1
mg/1
Mg - Magnesium
-mg/1
Mn - Manganese _
NI - Nickel mg/I
Pb - Lead 20.01 mg/1
Zn-Zinc mg/1
Ammonia Nitrogen mg/1
Other. (Specify Compounds and concentration units)
ORGANICS: (GC, GC/MS, HPLC),
(Specify test and method #. Attach lab report.)
Report Attached? Yes_(1) No_(0)
VOC method #=
VOC Method it=

ON
Facility Name Hamlet Wastewater Treatment Facility
FaciltyAddress CSX Transportation 'Box191A Htghway 177N
Hamlet, NC 28345 4 County Richmond
Contact Person: M. L. GREGORY [phone]
Well Location/Sity Name: Location Map Attached
Well Identification Number: MW-7 ' Fercr°wdW,ra,TreaManisy :
Well Depth: 37.18 fL Well Diameter: -2.0; in. cn�a�:
Screened Interval ft. To fL- 9 -Influent (98)
Depth to Water Level 32.1 f . below measuring point Effluent (99)
Measuring, point is tL above land. surface
Gallons of water Pumpedibailed before sampling:
Field Analysis pH 5.35 Specific Conductance 90, Sl uMhos
Temp. _ °C Odor Appearance
PARAMETERS -
PERMIT M EXPIRATION DA
Non -Discharge W00000601 UIC
NPDES —
TYPE OF PERMITTED OPERATION BEING MONITORED
(Samples for metals. were, collected unfiltered _X YES NO
CO
mg/1
Coliform: MF Fecal
/ 100ml
Coliform: MF Total
/ 100m1
(Note: Use MPN method forhighly. turbid samples)
Dissolved Solids Total 71.
mg/1
PH (when analyzed)
units
TOC 1.1.
mg/I
Chloride - - -
Arsenic <0.02
_mg/I
Grease and Oils
mg/l
Phenol
mg/I
Sulfate
ing/1
Specific Conductance
Mhos
Total Ammonia _
mg/I
TKN as N
mg/I
NO-2 as N
NO 3 as N'
1.8
Lagoon'
Spray Field
Rotary Distributor _
X Other Monitorinq. Well -
Remediation:.Intiitration Gallery
Remediation
Land Application of Sludge
NOTE Values should reflect dissolved and collaidal concentrations
Date Sample Collected 07/08/10 Date Sample Analyzed 07/21/10
Laboratory Name
'Certification No.
and field acidified _X_' YES NO)
Phosphorus: Total as P
mg/I
Orthophosphate
mgll
A] -Aluminum
mg/I
Ba -Barium 0:018 �
-
Ca - Calciummg/I
—mg/I
Cd = Cadmium - <0,005
mg/I
Chromium: Total <0.01
mg(I
Cu - Copper
Fe. -Iron
—mg/I
mg/1
Hg - Mercury
mg/I
K - Potassium
mg/I
Mg - Magnesium
mg/1
Mn - Manganese
mnil
NI - Nickel
mg/I
Pb -Lead <0.01
mg/I
Zn -Zinc
mgll
Ammonia Nitrogen
mg/I
Other (Specify Compounds and concentration
units)
ORGANICS: (GC, GC/MS, HPLC)
.(Specify test and method #. Attach lab report)
Report Attached?Yes_(1) No_(oy
VOC method#= '
VOC ; method 9 = .

FORM
Facility Name Hamlet Wastewater Treatment Facility
Facilly Address CSX Transportation Box 191A Highwav 177N
Hamlet, NC 28345 County Richmond
Contact Person: M. L. GREGORY [phone]
Well Locauumo ty Name. Location Map Attached
Well Identification Number. MW-8 F rGmundw-W Treypnentsy,,=
Well Depth: _ 57.18_ fL Well Diameter: 2.0 in. � �e
Screened Interval ft. To _ft. Influent (98)
Depth to Water Level 44.6 fL below measuring point Effluent (99)
Measuring point is fL above land surface
Gallons of water Pumpedibailed before sampling:
Field Analysis pH 5.4 Specific Conductance _ ,(, uMhos
Temp. _ 0C Odor Appearance
PARAMETERS: (Samples for metals were collected unfiltered YES
CO
Coliform: MF Fecal
/ 100ml
Coliform: MF Total
I 1100ml
(Note: Use MPN method for highly turbid samples)
Dissolved Solids Total 130.
moil
pH (when analyzed)
units
TOC 1.2.
moil
Chloride
moil
Arsenic <0.02
moll
Grease and Oils
moil
Phenol
mg/I
Sulfate
moil
Specific Conductance
Mhos
Total Ammonia
moil
TKN as N
.„_rl
PERMIT #: EXPIRATION DATE July 31, 2014
Non -Discharge WQ0000601 UIC
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
Spray Field Remediation
_ Rotary Distributor Land Application of Sludge
X Other Monitorina Well
Tre
NOTE Values should reflect dissolved and collaidal concentrations
Date Sample Collected 07/08/10 Date Sample Analyzed 07/21/10
Laboratory Name TestAmerica Laboratories INC
Certification No. egg
and field acidified _X_ YES NO)
NO-2 as N
moll
NO-3 as N 9.7
mg/I
Phosphorus: Total as P
moll
Orthophosphate
mg/I
AI -Aluminum
moll
Ba - Barium 0.037
mg/I
Ca- Calcium
moll
Cd- Cadmium <0.005
moil
Chromium: Total <0.01
moll
Cu - Copper
Fe - Iron _
Hg - Mercury _
K - Potassium
Mg - Magnesium
Mn : Manganese
Ni - Nickel moll
Pb - Lead <0.01 moll
Zn - Zinc mg/I
Ammonia Nitrogen moil
Other (Specify Compounds and concentration units)
ORGANICS: (GC, GC/MS, HPLC)
(Specify test and method #. Attach lab report.)
Report Attached? Yes _(1) No_(0)
VOC : method#=
VOC : method # _

Test—Ame ica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Job Number: 680-59248-1
Job Description: CSX Hamlet, NC WWTP
For.
ARCADIS U.S., Inc. -
801 Corporate Center Drive
Suite 300
Raleigh, NC 27607-5073'
Attention: Mr. Alan Pinnix
)21R0100:]5PN
Kathryn Smith
Project Manager I
[e-mail]
07/21/2010
cc: Mr, Jerry Cato
Mr. Mike,Gregary
LWON-EN V0000038652UProject-9522202
The test results in this report meet NELAP requirements for parameters for which accreditation is required or available.
Any exceptions to the NELAP requirements are noted. Results pertain only. to samples listed in this report. This report
may not be reproduced, except In full, without the written approval of the laboratory. Questions should be directed to the
person who signed this report.
Savannah Certifications and ID #s: A2LA: 0399.01; AL; 41450; ARDEQ: 88-0692; ARDOH; CA: 03217CA; CO; CT:
PH0161; DE; FL: E87052; GA: 803; Guam; HI; IL: 200022; IN; IA: 353; KS: E-10322; KY EPPC: 90084; KY UST; LA
DEQ: 30690; LA DHH: LA080008; ME: 2008022; MD: 260; MA: M-GA006; MI: 9925; MS; NFESC: 249; NV: GA00006;
NJ: GA769; NM; NY: 10842; NC DWQ: 269; NC DHHS: 13701; PA: 66-00474; PR: GA00006; RI: LA000244; SC:
98001001; TN: TN0296; TX: T104704185; USEPA: GA00006; VT: VT-87052: VA: 00302; WA; WV DEP: 094; WV
DHHR: 9950 C; WI DNR: 999819810; WY/EPAR8: BTMS-Q
TestAmerlca Laboratorles, Inc
N ACCO
TestAmedca Savannah 5102 LaRoche Avenue, Savannah, GA 31404 pa
Tel [phone] Fax [phone] ma .teslamericainG�II1
Page 1 of 25

Job Narrative
680-59248.1
Comments
No additional comments.
Receipt
Al samples were received in good condition within temperature requirements.
Metals
No analytical or quality issues were noted.
General Chemistry
No analytical or quality issues were noted.
Page 2 of 25

a
METHOD SUMMARY
Client: ARCADIS U.S., Inc.
Job Number.. 680-59248-1
Description Lab Location Method Preparation Method
Matrix Water
Metals (ICP)
TAL SAV
40GFR136A 200.7 Rev 4.4
Preparation, Total Metals.
TAL SAV
EPA200.7
Nitrogen, Nitrate -Nitrite
- TAL SAV
MCAW W 353.2 '
Solids, Total Dissolved (TDS)
TAL SAV
SM SM 2540C
Organic Carbon, Total (TOC)
TAL SAV
SM SM 5310B
Lab References:
TAL SAV = TestAmerica Savannah
Method References: -
40CFR136A - "Methods for Organic Chemical Analysis of Municipal Industrial Wastewater", 40CFR, Part 136, Appendix A,
October 26, 1984 and subsequent revisions.
EPA= US Environmental Protection Agency
MCAW W = "Methods For Chemical Analysis Of Water And Wastes', EPA-60014-79-020, March 1983 And Subsequent Revisions.
SM = "Standard Methods For The Examination Of Water And Wastewater",
TestAmerica Savannah
a
Page 3 of 25

METHOD/ANALYST SUMMARY
Client: ARCADIS U.S., Inc.
Job Number: 680-59248-1
Method Anal st Anal st ID
40CFR136A 200.7 Rev 4.4 Stand, Brian BCS
MCAWW 353.2 Ross,Jon JR
SM SM 2540C Robinson, Tiffany TR
SM SM 53108 Blackshear, Kim KB
TestAmerica Savannah
Page 4 of 25

SAMPLE SUMMARY
Client ARCADIS U.S., Inc.
Job Number. 680-59248-1
Lab Sample ID
Client Sample ID
Client Matrix
DateMme
DaterrimeSampled
Received
680-59248=1
MW-8
Water
07/08/2010 1130
07/09/2010 0928
680-59248-2
MW-7
Water
07/0812010 1230
07/0912010 0928 '
680-59248.3
MW-4
Water
07/08I2010 1320
07/0912010 0928
680-59248-4
MW-5
Water
07108/2010 1415
07/09/2010 0928
680-59248-5
MW-2-
Water
07/0812010 1515
07/09/2010 0928
TestAmerica Savannah
Page 5 of 25

Client: ARCADIS U.S., Inc.
Client Sample ID: MW-8
Analytical.Data
Job Number. 680-59248-1
Lab Sample 10:
680-59248.1
Date Sampled: 07/08/2010 1130
Client Matrix:
Water
Date Received: 07/09/2010 0928
200.7 Rev 4.4 Metals (ICP)
Method:
200.7 Rev 4.4
Analysis Batch: 680-174850
Instrument ID: ICPD
Preparation:
200.7
Prep Batch: 080-174707
Lab File 10: 072010.chr
Dilution: ,
1.0.
-
Initial WeighllVolume: 50 mL
Date Analyzed:
07/21/2010 0238
Final WelghtNolume: 50 mL
Date Prepared:
07/2012010 1120
Analyte -__.
_
_ Result (uglL)
Qualifier
MOL RL
Arsenic
..
20
Barium,
37
2.3 10
Cadmium
5.0
U,
2.0 5.0
Chromium'
.- 10
U
12 10
Lead
10
U -
4.0 10
TestAmericaSavannah . Page 6 of 25

Client: ARCADIS U.S., Inc.
Client Sample ID: MW7 l%
Analytical Data
Job Number. 680-59248-1
Lab Sample 10:
680-59248.2
Client Matrix:
Water
Date Sampled: 07/08I2010 1230
Date Received: 07/09/2010 0928
200.7 Rev 4.4 Metals (ICP)
,
Method:
200.7 Rev 4.4
Analysis Batch: 680-174850
Instrument ID: ICPD
Preparation:
200.7
Prep Batch: 680-174707
Lab File 1D: 072010.chr
Dilution:
1.0
Initial WeighWolume: 50 mL
Date Analyzed-
07/21/2010 0305.
Date Prepared:
07/20/2010 1120
Final Weight/Volume: 50 mL
Analyte
Result(ug/L)
Qualifier
MOL_ RL
Arsenic
�•',.J.9`-
-
20
U—
4.6 20
Barium
.
-
2.3 10
Cadmium
Chromium
.9. ,"�`^
5. 0
U
"
2.0 5.0
Lead
10
U
1.2 1p
.-
10
U
4.0• 10
t
7estAmerica Savannah Page 7 of 25

Client: ARCADIS U.S., Inc.
Client SamplelD: MW-4'/
Analytical Data
Job Number. 680-59248-1
Lab Sample ID:
680-59248-3
Client Matrix:
Water
Date Sampled: 07/08/2010 1320
- Date Received: 07/09/2010 0928
200.7 Rev 4.4 Metals (ICP)
Method:
200.7 Rev 4.4
Analysis Batch: 680-174850
Instrument 10: ICPD
Preparation:
200.7
Prep Batch: 680-174707
Lab File ID: 072010.chr
Dilution:
1.0
Date Analyzed:
07/21/2010 0310
Initial WeighWolume: 50 mL
Date Prepared:
07/20/2010 1120
Final Weight/Volume: 50 mL
—..__ 1uul�)
Qualifier
MDL
RL
Arsenic
.:, J. ec^ 20 .
U
4.6
20
Barium
, 10
U
2.3
10
Cadmium
5.0
U
2.0
5.0
Chromium
'" 10
U
Lead
•, . D'
1.2
10
10
U
4.0
10
TestAmerica Savannah Page a of 25

Client ARCADIS U.S., Inc.
Client Sample ID: MW-5 •/
Analytical Data
Job Number. 68059248-1
Lab Sample ID:
680-59248-4
Client Matrix:
Water
Date Sampled: 07l08/2010 1415
Date Received: 07/09/2010 0928
200.7 Rev 4.4 Metals (ICP)
Method:
200.7 Rev 4.4
Analysis Batch: 680-174850
Instrument ID: ICPD
Preparation:
200.7
Prep Batch: 680-174707
Lab He ID: 072010.chr
Dilution:
1.0
Initial WeighWolume: 50 mL
Date Analyzed:
07/21/2010 0315
Final WelghWolume: 50 mL
Dale Prepared:
07/20/2010 1120
Arsenio
Barium
Cadmium
Chromium
Lead
Result (ug/L)
Qualifier
MDL
_
20
2.3
5.0
U
2.0
1.
10
U
1.2
10
U
4.0
10
5.0
10
10
TestAmerica Savannah Page 9 ,o£ 25

Analytical Data
Client: ARCADIS
U.S., Inc.
Jab Number. 680-59248-1
Client Sample ID;
MW-2
Lab Semple ID:
680-59248-5
Client Matrix:
Water
-
Date Sampled: 07/08/2010 1515
'Date
Received: 07/09/2010 0928
•
200.7 Rev 4.4 Metals (ICP)
Method:
200.7 Rev 4.4
Analysis Batch: 680-174850
Instmment l0:
ICPD
Preparation:
200.7
Prep Batch: 686-174707
Lab File ID:
d72010.chr
Dilution:
1.0
Initial WeighWolume:
50 mL
Date Analyzed:
07/21/2010 0331'
Final WeighWolume:
50 mL
Date Prepared:
07/20/2010 1120
,
Analyte
Result (ug/L)
Qualifier
MDL
RL -
Arsenic
„ ,.
20 -
U
4.6.—._�—�
Badum�
O.
7.3 .
J
2.3
10
Cadmium
{p. 70.
5.0
U
2.0
5.0
Chromium
.; )7.->
1.7
J
1.2
10
Lead
4.0
10
9
TestAmerica Savannah Page 10 of 25

Analytical Data
Client:, ARCADIS U.S., Inc. Job Number. 680.59248-1
General Chemistry
client Sample in: MW8
Lab Sample ID: 680-59248.1 Client Matrix: Water .Date Sampled: 07/08/2010 1130
-
Date Received: 07/09/2010 0928
Analyte Result
Nitrate as N 9.7
_ Qual Units MDL
RL
DII
Method
Analysis Batch: 680-173990
_mg/L 0.10
Date Analyzed: 07/09/2010 1745
0.50
'10
353.2 i
Total Organic Carbon . 1.2
mg/L 0.50
1.0
Analysis Batch: 680-174825
Date Analyzed: 07120/20101630
1.0
SM 5310B
Analyte Result
Total Dissolved Solids 130
Qua] units
�
mg/L RL.
RL. _
Dil
Method
Analysis Batch: 880-173876
5:0
Date Analyzed:•07/12I20101522
5.0
1.0
SM 2540C •
a
TestAmerica Savannah Page 11 0£ 25

Analytical Data
Client ARCADIS U.S., Inc. Job Number. 680-59248-1
/ General Chemistry
Client Sample ID: MW-7.; /
Lab Sample 10: 660-59248.2
Client Matrix: Water Date Sampled: 07108/2010 1230
Date Received: 07/09/2010 0928
Analyte Result
Nitrate as N
Qual Units
— - MDL •
RL
Oil
Method
1.8
Analysis Batch: 680-173990
m9/L 0.010 ~
Date Analyzed: 07/09@010 1736 -
_
Total Organic Carbon 1.1'
mg/L 0.50
Analysis Batch:,680-174825
Date Analyzed: 07/20/2010 1644
1.0'
1.0
SM 5310B
Analyte Result
To--
tal D6llssed Solids
Oual Units RL
RL
DII
Method
71
Analysis Batch: 680-173876
_
mg/L 5.0 •----
Date Analyzed: 07/12/2010 1522
5.0
1il
2540C�
TestAmerica savannah Page 12 of 25

Analytical Data
Client: ARCADIS U.S., Inc. Job Number. 680-59248-1
General Chemistry "
Client Sample ID: MW-4/t" ,
Lab Sample -ID: 680-59248.3, Date Sampled: 07/08/2010 1320
Client Matrix: Water
mnaiyre Result
T
Dual Units MDL
Nitrate es N 0.33-
'� mg/L 0.011
Analysis Batch: 680-173990
Date Analyzed: 07/09/2010 1737
Total Organic Carbon _ 1.0
U mg/L 0.60
Analysis Batch: 680-174825
Date Analyzed; 07/20/2010 1658
Analyte Result
Dual ' Units RL
Total Dissolved Solids 36
mg/L 5.0
Analysis Batch: 680.173876
Date Analyzed: 07112/2010 1522
Date Received: 07/09/2010 0928
RL DII Method
1.0 1.0 SM 53108
RL _ DII Method
SA 1.0 SM 25dOC
TestAmerlca Savannah Page 13 of 25

Analytical Data
Client ARCADIS U.S., Inc. Job Number. 680-59248-1
General Chemistry
Client Sample to:
MW-5 •:'
_
Lab Sample ID:
680.59248.4
Client Matrix:
Water
Date Sampled:
07/06/2010 1415
Date Received:
07/09/2010 0928
Analyte
Result
_-173990
Dual Units MDL
RL
DII
Method
Nitrate as N
0.74
_
mg/L 0.016
_
0.050
1.0
353.2
Analysis Batch: 680
Date Analyzed: 07/09/2010 1738
Total Organic Carbon 0.67
J mg/L 0.50
1.0
1.0
SM 5310B
Analysis Batch: 680-174825
Date Analyzed: 07/20/2010 1715
Analyte
_Result
Dual Units RL
RL
Dil
Method
Total Dissolved Solids 54
mglL •5.0
5.0
- 1.0
SM 2540C
.Analysis Batch: 680-173876
Date Analyzed: 07/12I2010 1522 -
TestAmerlcaSavannah Page 14 of 25

Analytical Data
Client ARCADIS U.S., Inc. Job Number: 680-59248-1
General Chemistry
-
Client Sample ID: MW-2
Lab Sample ID: 680-59248-5
Date Sampled: 07108/2010 1515'
Client Matrix: Water
Date Received: 07109/2010 0928
Analyte Result
Qual Units MDL
RL
Dii Method
Nitrate as N 1.6
mg/L 0.010
0.050
_
1.0 353.2
- Analysis Batch: 680-173990
Date Analyzed: 0710912010 1742
Total Organic Carbon 2.0
mg/L 0.50
1.0
1.0 SM 5310B
Analysis Balch: 680-174825
Dale Analyzed: 07/20/2010 1800
Analyte Result
Qua[ Units RL
RL
DII Method
TotalDised Solids 49----
mg/L S.
5.0
_
'�- 1SM 2540C
:0
Analysis Batch: 680-173876
Date Analyzed: 07/12/2010 1522
TestAmerica Savannah Page 15 of 25

C
s
DATA REPORTING QUALIFIERS
Client: ARCADIS U.S., Inc.
Lab Section Qualifier Description
Metals
General Chemistry
TestAmedca Savannah
Job Number. 680-59248-1.
U Indicates the analyte was analyzed for but not detected.
J Result is less than the RL but greater than or equal to the
MDL and the concentration Is an approximate value.
U indicates the analyte was analyzed for but not detected.
J Result is less than the RL but greater than or equal to the
MDL and the concentration 'is -an approximate value.
Page 16 of 25

Quality Control Results
Client: ARCADIS U.S., Ina
-
Job,Number: 680=59248-1
Method Blank
-Batch: 680.174707
Method: 200.7 Rev 4.4
Preparation:, 200.7.
Lab Sample ID:
MS 680-174707125-A
Analysis Batch:
680-174850
Instrument ID: ICPD
Client Matrix:
Water
Prep Batch: 680-174707
Lab File ID: 072010.chr
Dilution:
1.0
Units: ug/L
Inldal.WeighWolume: 50 mL
Date Analyzed:.
07/21/2010 0227
Final WeightMolume: 50 mL
Date Prepared:
07/20/2010 1120
-
Analyte
Result
Qual
MDL RL
Arsenic
20
U
4.6 20
Barium
-
10
U
2.3 10
Cadmium
5.0
U
'
2.0 5.0
Chromium
10
U
1.2 10
Lead
10
U
4.0 10
Lab Control Sample - Batch: 680.174707
Method: 200.1 Rev 4.4
-
Preparation: 200.7
Lab Sample 10:
LCS 680-174707/26-A
Analysis Batch:
680-174850
Instrument ID: ICPD
Client Matrix:
Water ..
Prep Batch: 680-174707
Lab File ID: 072010.chr
Dilution:
1.0
Units: ug/L
Initial WelghWolume: 50 mL
Date Analyzed:
07/21/2010 0233 .
Final WelghWolume: 50 mL
Date Prepared:
07/20/2010 1120
'
Anaiyte
Spike Amount
Result
%Rea
Urnit Qua[ -
Arsenic
2000
1960
98
85 - 115
Barium
2000
2030
102
85,115
Cadmium
50.0
50.1
100
85-115
Chromium
-
200
202
101
85-115
Lead
500.
499
100
85- 115
TestAmedca Savannah Page 17 of 25

Quality Control Results
Client: ARCADIS U.S., Inc.. Job Number. 680-59248-1
Matrix splkel
Method: 200.7 Rev 4.4
Matrix Spike DuplicateRecovery Report -
Batch: 680.174707
Preparation: 200.7
MS Lab Sample ID:
680-59248-1
Analysis Batch:
680-174850
Instrument 10: ICPD
Client Matrix:
Water
Prep Batch: 680-174707
Lab File 10: 072010.chr
Dilution:
1.0
Initial Weight/Volume: 50 mL
Date Analyzed:
07/21/2010 0254 ,
Final WelghWolume: 50 mL
Date Prepared:
07/20/2010 1120
,
MSD Lab Sample ID:
680 59248-1
Analysis Batch..
680-174850
Instrument ID: ICPD
Client Matrix:
Water
Prep Batch: 680-174707
Lab File ID: 072010.chr
'Dilution:
1.0
Initial Weight/Volume: 50 mL
Date Analyzed:
07/21120100259
Final WelghWolumet 50 mL
Date Prepared:
07120/2010 1120
..
%Rec
Analyte
-
MS MSD
Limit
RPD
RPD Limit MS Qual :MSD Qual
Arsenio -_
94 103
75-125
v 9
20
Barium
96 106
75 -125
9
20
'Cadmium
95 103
75-125
9
20
Chromium
,. - -
98 105
75-125'
8
20
Lead
95 103
75 -125
9
20
TestAmerlca Savannah Page 18 of 25

Client: ARCADIS U.S., Inc.
Method Blank -Batch: 680.173990
Lab Sample ID:
MB 680-17399011
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
07/0912010 1711
Date Prepared:
NIA
Analysis Batch: 680-173990
Prep Batch: WA
Units: mg/L
Quality Control Results
Job Number: 680-59248-1
Method: 353.2
Preparation: NIA
InstrumentlD: Latchat2
Lab File ID: N/A
Initial WelghWolume: 7 mL
Final WelghWolume: 7 mL
Analyte
Result
Qual MDL
RL
Nitmte as N
0.050
U 0.010
0.050
Lab Control Sample - Batch: 680-173990
Method: 353.2
Preparation: NIA
Lab Sample ID: LCS 680-17399012
Analysis Batch: 680-173990
Instrument ID: Latchat 2
Client Matrix: Water
Prep Batch: NIA
_ Lab File ID: N/A
Dilution: 1.0
Units: mg/L
Initial Welghtolume: 7
mL
Date Analyzed: 07/0912010 1712
Final WelghWolume: 7
mL
Date Prepared: NIA
Analyte
Spike Amount Result
% Rec. Limit
Qual
Nitrate as Ny
0.500 0.481
96
Matrix Spike/
Method: 353.2
Matrix Spike Duplicate Recovery Report- Batch: 680.173990
Preparation: N/A
MS Lab Sample ID: 680-59236-G-1 MS
Analysis Batch: 660-173960
Instrument ID: Latchat 2
Client Matrix: Water
Prep Batch: NIA
Lab File ID: NIA
Dilution: 1.0
Initial WelghWolume: 25 mL
Date Analyzed: 07/09/2010 1720
Final WelghWolume: ' 25 mL
Date Prepared: NIA
,
MSD Lab Sample ID: 660-59236-G-1 MSD
Analysis Batch: 680-173990
Instrument ID: Latchat 2
Client Matrix: Water
Prep Batch: N/A
Lab File ID: 'N/A -
Dilution: 1.0
IniOai WelghWolume: 25
mL
Date Analyzed: 07109/2010 1721
Final Weight/Volume: 25
mL
Date Prepared: NIA ,
Analyte
Nitrate as
a
% Rec.
MS 'MSD Limit RPD RPD Unit MS Qual MSD Qual
96
TostAmerica Savannah Page 19 of 25

Client: ARCADIS U.S., Inc.
Duplicate -Batch; 680.173990
Lab Sample ID:
680-59248-1
Client Matrix:
Water
Dilution:
10
Date Analyzed:
07/09/2010 1747
Date Prepared:
N/A
Analyte
Analysis Batch: 680-173990
Prep Batch: NIA
Units: mg/L
Sample Result/Cual Result
Quality Control Results
Job Number: 680-59248-1
Method: 353.2
Preparation: NIA
Instrument ID: Latchat 2
Lab File 10: N/A
InitialWeight/Volume: 7 mL
Final WeightA/olume: 7 mL
RPD Limit Dual
Nitrate as 9.7 9.64 0
TestAmerica Savannah Page 20 of 25

r =y
Client: ARCADIS U.S., Inc:
Method Blank -Batch: 680.173876.
Lab Sample ID:
MB 680-173876/1
Analysis Batch:.680-173876
Client Matrix:
Water
Prep Batch: NIA
Dilution:
1.0
Units: mg/L
Date Analyzed:
07/12/2010 1522
'
Date Prepared:
WA
Quality Control Results
Job Number: 680-59248-1
Method: SM 2540C
Preparation: NIA
Insbumant ID: No Equipment Assigned
Lab File ID: NIA
Initial WeighWolume: 100 mL
Final Weight/Volume: 100 mL
Analyte
Result
Dual RL RL
Total Dissolved Solids
5.0
U 5.0 5.0
Lab Control Sample/
Method: SM 2540C
Lab Control Sample Duplicate Recovery Report - Batch: 680-173876
Preparation: N/A
LCS Lab Sample ID:
LCS 660-173876/2
Analysis Balch: 880.173876
Instrument ID: No. Equipment Assigned
Client Matrix:
Water
Prep Batch: NIA
Lab File ID: NIA
Dilution:
1.0
Units: mg/L
Initial WeighWolume: 100 mL
Date Analyzed:
07/12120101522 -
Final WeighWolume: 100 mL
Date Prepared:
N/A
,
LCSD Lab Sample 10:
LCSD 680-173876/3
Analysis Batch: 680-173876
Instrument ID: No Equipment Assigned
Client Matrix:
Water
Prep. Batch: N/A
Lab File ID: N/A
Dilution:
1.0
Units: mg/L
Initial Weightolume: 100 mL
Date Analyzed:
07/12I2010 1522
Final Weight/Volume: 100 mL
Date Prepared:
N/A
'
a ec
Analyle
LCS LCSD Limit
RPD RPD Limit LCS Qual LCSD Qual
Total Dissolved Solids 107 102 80 -120 5 25
Duplicate -Batch: 680.173876 Method: SM 2540C
Preparation: N/A.
Lab Semple ID: 680-59260-A-1 OU Analysis Batch: 680-173876 Instrument IO: No Equipment Assigned
Client Matrix: Water Prep Balch: N/A Lab File ID: N/A
Dilution: 1.0 Units: mg/L Initial Weight/Volume: 5 mL
Date Analyzed: 07112/2010 1522 Final WeighWolume: 100 mL
Date Prepared: WA
Analyte Sample Result/Qual Result RPD Limit Qual
Total Dissolved Solids 9000 8440 . 7 25
TestAmerica Savannah Page 21 of 25

i
Quality Control Results
Client ARCADIS U.S., Inc. Job Number: 680-59248-1
Method Blank - Batch: 680.174825
Method: SM 5310B
Preparation: NIA
Lab Sample ID: MB 680-174825/6
Analysis Batch:.
880-174825
Instrument'ID: TOC3
Client Matrix: Water
Prep Batch: N/A
Lab File ID: T00072010.bat
Dilution: 1.0
Units: mg/L
Initial WeightA7olume: 25 mL ,
Date Analyzed: 07/2012010 1127
Final Weightolume: 25 mL
Date Prepared: N/A
Analyte
Result
Qual MDL RL
�..
Total Organic Carbon
1.0
U - 0.50 1.0
Lab Control Sample - Batch: 680.174826
Method: SM 5310B
Preparation: NIA
i
Lab Sample ID: LCS 680-174825113
Analysis Batch:
680-174825
Instrument ID: TOC3.
Client Matrix: Water
Prep Batch:.NlA
Lab File ID: T00072010.txt
Dilution: 1.0
Units: mg/L
Initial WeighWolume: 25 ML
Date Analyzed: 07120120101316
Final WeighWolume: 25 mL
Date Prepared: N/A
Analyte
Spike Amount
Result !
% Rec. Limit Qual:
Total Organic Carbon
20.0
19.6 �.^
98 80-120
Matrix, Spike/
Method: SM 5310B
Matrix Spike Duplicate Recovery Report - Batch: 680.174825
Preparation: NIA
MS Lab Sample ID: 6B0-59331-J4 MS
Analysis Batch:
680-174825
Instrument ID: TOC3
Client Matrix: Water
Prep Batch: N/A
Lab File 10: T00072010.bct
Dilution: 1.0
Initial WelghWolume: 25 mL
Date Analyzed: 07/20/2010 1900
Final Weight/Volume: 25 mL
Date Prepared: N/A ,
MSO Lab Sample 10: 680.59331-J4 MSD
Analysis Batch:
680-174825
Instrument ID: TOC3
Client Matrix: Water
Prep Batch: N/A
Lab File ID: T00072010axt
_
-Dilution: 1.0
IniOal WeighWolume: 25 mL
Date Analyzed: 072012010 1912
Final WeighWolume: 25 mL
Date Prepared: N/A
'/yea.
Analyte
MS MSD
Limit
RPD RPD Limit MS Qual MSD Qual .
TotalorganicCarbon-.__�V____....—.--
0F`99
_----80-120
-2".
TestAmerica Savannah Page 22 of 25

i !1
Client: ARCADIS U.S., Inc.
Duplicate- Batch: 680.174825
Lab Sample ID:
68M93334-1 OU
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
07/20/2010 1547
Date Prepared:
N/A
Analyte
Total Organic Carbon
Analysls Batch: 680-174825
Prep Batch: N/A
Units: mg/L
Sample Result/Oual
1.0 -- U
Quality Control Results
Job Number: 680-59248-1
Method: SM 53108
Preparation: N/A
Instrument ID: TOC3
Lab File ID: T00072010.bd
Initial WeighWolume: 25 mL
Final WeightlVolums: 25 mL
Result RPD Limit Oual
1.0 NC 25 U
TestAmerica Savannah Page 23 of 25

ro
W
N
N
A
0
M
N
N
CHAIN OF
TRANSPORTATION CUSTODY
TAL-6DC6 11907
LABORATORY INFORMATION
COC # '
TmLAmMu Sawm2b - 5102 LaRad a Avenue. Sava .ah. GA31404 P.912.354-7858. F:912.352-0165
❑TeWmuiq Nonh Canton- 41m Shuffel Drive NW.Nodh Canton.ON44720 P.330.497-9396 F.330497.0772
O Tesmmuira Tampa-6712 oeryamin Road. Soda 1DD. TIMPa.R33634 P.813-885-7427 F:813-885-7049
OTesLkmuimPen.cola-3355Mci..MDrive.Pen N.FL32514 P.850474-1001 F.&S"?8.2671
OTceUmulca Buffalo- 10Nazet ood Drive.S.Ro 106.Amhast. NY Mil P.716-6912600 F.71G951.7991
OTeslAme,iea Chicago-2417eond Suca.Bnk.raity Pak ILB0466 P..708-534.5200 RNE1,534.5211
SHIPMENTINFORMATION
SNpmenlMeNotl:FEDFX
Shpmenl Tracking No'
87N o-(o3 3217
CSXT PROJECT INFORMATION Pre!. SUM laws of Origin) AIG
�I ``t7
ac�1 n
CSXT Project Number: gr3q- LD% Plal•Cay. Q�
Pro eq k•
CONSULTANT INFORMATION I
NC�OZ'po3-1, ooio. 0000l
Company: AWAM
PAL Alcurt I'irviI
CSXT Project Name. 11_lwle\- W1:�-P �r�7 p:.
CSXT Contact: 1' W� i�) vll l ."ONeW 3 62— MLA
[
Aodressp A� Ce itle r,�Rly Dr. 5-I �r."raw APIa'IYL,4Arc i$-vs,.e4V
.Stal(e7.VZIp: I.Y �� , NI.CC wIG01 ICVJw, Frond: qIq-�Gt1-12$'�FdY
JTCOMMENTS
Turnaround Time: ❑ Standard 6.13 Days
❑ 1 Day Rush �,Specify 4 Days
❑1
2 Day Rush 9 Standard 14 Days
❑ 3 Day Rush ❑ Omer
Preservative Codes: 3=Sulfuric Acid Noteaa ZI
0 = No Preservadves 4 = Sodium Thiosulfnle Pres.
1 = Hydrochloric Acid 5 = Sodium Hydroxide Code
2 - Nitric Acid 6 - Other
I
I O
3
LAB USE
METHODS
FOR
ANALYSIS
O
-
J
O
N
In
ti
d
-
t1DD�xeeTliverables: ❑ Other DeM:
YY CSXT Standard (Laval ll)
❑ Level III ❑ EDD Required Formal:
El IV
Matrix Codes: SO=Soil LID Liquid
GW =Groundwater SL= Sludge
WIN = Waste Water Of = Oil
SW=Surface Water SOL=Other Solid
r
8
aA
SAMPLE INFORMATION _
Sample Identification
Containers
Sam le
Collection
Filtered
Type
IMaIrpi
_?
Number 8
Type
Date
Time
Sampler
Y orN
Comp
or Grab
Code
W-
y
-710110
1130
DT
N
Cara6
GlW
X
X
L -
1230
w -
Lt
132o
X
`C
if1s15
X
Rel'mquishetl B
Da ime
x o 1730
Recdivdd By.
Dame:
Comments & Special Analytical Requirements:
Regori As,3,;,,CJjCr, 4.1 Pb.
Ter19.
a•b
Relinquished BY
Dat
Received By:
Dnml7ime:
RegnquiWaetl eY•
DafeYTune:
Received SY•
Dal�me:
ived B Labomtor :
nnirium _ncn mumrevnv ev .� �..�.«
Datel(lfine (�
Lan Remarks:
-
LAD USE: Gus" InWq
Custody Seal N
If
LAB L umper
Ip
INYUIUE MUST BE SUBMITTED TO CSXT WITH ORIGINAL COO

Client: ARCADIS U.S., Inc.
Login Number:.59248
Creator: Daughtry, Beth
List Number. 1
Question
Login Sample Receipt Check List
T/ F/ NA Comment
Radioactivity either was not measured or, if measured. Is at or below
N/A
background ,
The cooler's custody seal, if present, is Intact.
True
The cooler or samples do not appear to have been compromised or
True
tampered with.
Samples werereceived on Ice.
True
Cooler Temperature Is acceptable.
True
Cooler Temperature is recorded.
True
COC is present.
True
COC is filled out In ink and legible.
True
COC is filled out with all pertinent information.
True
Is the Feld Sampler's name present on COC?
False.
There are no discrepancies between the sample IDs on the containers and
True
the COC.
Samples are received within Holding Time.
True
Sample containers have legible labels.
True
Containers are not broken or leaking.
True
Sample collection date/times are provided.
True
Appropriate sample containers are used.
True
Sample bottles are completely filled:
True
Sample Preservation Verified
True
There Is sufficient vol. for all requested analyses, Incl. any requested
True
MS/MSDs
VOA sample vials do not have headspace or bubble is <6mm (1/4') In
N/A
diameter.
If necessary, staff have been informed of any short hold time or quick TAT
Two
needs •
Multiphasic samples are not present.
N/A
Samples do not require splitting or compositing.
N/A
TestAmerica Savannah
Page 25 of 25
Job Number. 680-59248-1
List Source: TestAmerica Savannah

CSx
TRANSPORTATION
Jerry L. Cato REM
Supervisor Environmental Control
North Carolina Department
Of Natural Resources
Attn: Information Processing Unit
Division Water Quality
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
Dear Sir or Madam:
April 22, 2010
File. 9613703
Permit No. W00000601 Richmond County
CSX Transportation Inc (CSXT) Hamlet NC
500 Water Street - J275
Jacksonville, FL 32202
(PAX)
(904) 2455--2�
RECEIVE®
E ,Xf 0 3 2018
DERR-FAYEMLLE REGIGMI-OFME
Attached in triplicate, is the first triennial 2010 Ground Water Monitoring Well
Analyses, Form GW-59A and Attachment A - WWTF discharge reports, as specified by
Condition 4 of the referenced permit. Due to the drought conditions at this location, monitoring
well No. 2, No. 3, No. 7, and No. 8 did not have enough water to collect a sample.
If you have any questions or comments, please contact me at [phone].
Enclosures
Sincerely,
Jerry L. Cato RECEIVIED
APR 2 7 2010
Information Processing Unit
DWQ/BOG

GW-59A COMPLIANCE REPORT FORM Permit # LJQ �lOt1�t1�
•�. (Submit one each monitoring period with GIV 59 forms.)
1
Enter date monitoring results were due. - O Will this monitoring report (GW-59 and GW-59A)
YES
NO
be submitted after the established due date?
I
v
2
Was any required Information missing on the GW-59 report forms?
YES
NO
IF the answer to question 1 or 2 is "YES, list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
YES
NO
Identification plate, area overgrown, etc.)? If the answer is "Yes". contact the Regional Ofce for guidance.
V101,
4
Are any monitored constituents equal to or above the established standards?
YES
NO
If the answer to question 4 is "NO", skip to section B.
If the answer to quest/on 4 /s "YES" list the affected wells individually with constituents) and concentration(s)
exceeding standards in the space provided below:
5
For the constituents identified in question 4 above, have standards been exceeded previously for the
YES
NO
same constltuent(s) In the same well(s) in the last two years?
1f the answer to question 5Is "NO" skip to section 8.
If the answer to question 5Is "YES'; list in the space provided below, each well with constituent(s) exceeding
standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years).
6
Are the monitoring wells listed in section 5located at or beyond the review boundary?
YES
NO
If the answer Is "YES'; a groundwater qualify problem maybe occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer Is "NO'; monitoring wells maybe Improperly
located; contact the Regional Office.
7
Is the permittee implementing previously approved actions required by the Division involving this
YES
NO
groundwater quality problem?
11 the answer to question 7 is "YES" describe those actions in the space provided below.
-- - -1f
the answer -to question-7-15 "NO", contactthe'Renional Ofilce,wlthln 90 days: ah eyaluatlari n1aVba-"-
—
—
repuired to determine the,Impact the waste disposal system Is having at the review and compliance
boundaries surrounding this facility. Failure to do so may subject the Permittee to a Notice of Violation
fines. and/orpenalties.
g
The person completing this portion (GW--59A) of the monitoring report should sign below and submit this
form with GW-59 forms for required wells to the address provided at the top of the current G W-59 form.
I
hereby acknowledge that the above Informaflon was evaluated and the1nformation sub--Hed n this'
report
(Compliance Report W 59A) Is_ true and complete to therbest o'f my knowledge'r ,z"�s
1`1
lO
Signature I
f Permittee (or Authoriz Agent) loate
CW-59A 12/8/2003

SUBMIT FORM
Y
Facility Name CSX
Facilty Address 1731
Contact Person: MIKE GREGORY
Well Location/Sity Name: see location
- Hamlet Wastewater Treatment
County Richmond
:phone #: [phone]
of Wells to be Sampled: 8
Well Identification Number (From Permit): MW-1 i Systems
Well Depth 53.75 ft. Well Diameter. in. Check One: 0 Influent (98)
Screened Interval: ft. to ft. f 0 Effluent (99)
Depth to Water Level .E(o . a R below measuring point. I
Measuring point (M.P.) Is: ft. above land surfs111 Relative M.P. Elevation in ft.: _
Gallons of water pumped/bailed before sampling: Date Sample Collected
Field Analysis: pH s .13 Specific Conductance !I )A a, uMhos
Temp. ° C Odor j Appearance
PARAMETERS: (Samples for metals were colle
COD
md1l
Coliform: MF Fecal
/ 10dn
Coliform: MF Total
/ 1 q( n
(Note: Use MPN method for highly turbid samples)
Dissolved Solids Total
5 3 mgA
pH (when analyzed)
unit:
TOC
< mgA
Chloride
mgA
Arsenic
'L G.oQ mgA
Grease and Oils
mgA
Phenol
mgA
Sulfate
mgA
Specific Conductance
Mho
Total Ammonia
mgA
TKN as N
mgA
i
unfiltered X_ YES
NT NATURAL RESOURCES, I
OUN0INATER SECTION �
c
-PERMIT #: EXPIRATION DATE: November 30; 2889
Non -Discharge W00000601 UIC
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
Spray Field Remediation:
Rotary Distributor Land Application of Sludge
X Other Monitoring WeII
NOTE: Values should reflect dissolved and collaidal concentrations
Date Sample Analyzed
Laboratory Name:_
Certification No.
NO and field acidified X_YES NO)
Nitrite (NO2) as N a , 3
mgA
Nitrate (NO3) as N
mgA
Phosphorus: Total as P
mgA
Orthophosphate
mgA
At - Aluminum
mgA
Ba - Badum
mgA
Ca - Calcium
mgA
Coll Cadmium
mgA
Chromium%Total .gin „� 0.00)3
mgA
Cu - Copper'
mgA
Fe - Iron 02 -71
mgA
Hg - Mercury C�'o` mgA
K - Potassium �O ��
mgA
Mg Mg -Magnesium 9�
mgA
Mn - Manganese fly
mgA
Cad A. Gerhardstein,
GW-59 Rev. 0312000 1
v
Signature of rmittee (or Authorized
Ni - Nickel mgA
Pb - Lead < O 0 1 mgA
Zn - Zinc mgA
Ammonia Nitrogen mgA
Other (Specify Compounds and concentration units)
ORGANICS: (GC, GC/MS, HPLC)
(Specify test and method #. Attach lab report)
Report Attached? Yes_(1) No_(0)
VOC : method # =
VOC : method # =
VOC : method # =
nental Systems '
Title - Please print or type

YELLOW PAPER ONLY
1UAL1,1 r MUNI I UKINU
IORTT
' t
3... `n �- ... nf2N��•
Facility Name
Facilty Address
Contact Person: M. L. G
Well Location/Sity Name:
Wastewater Treatment Facility
ansportation, Box 191A Highway 177N
NC 28345 (County Richmond
REGORY [phone]
Location Mao Attached
Well Identification Number: MW-2
Well Depth: 41.48 ft. Well Diameter
Screened Interval ft. To ft.
Depth to Water Level ft. below measuri
Measuring point is ft. above land sur
Gallons of water pumped/bailed before sampling:
Field Analysis pH Specific Conduct
Temp. aC Odor _
Far GrowAirater Treatment Systems
cnearone:
4_0 in.
® Influent (98)
point. ® Effluent(99)
PARAMETERS: (Samples for metals were collebtei
CO
mg/I
Coliform: MF Fecal
/ 100m1
Coliform: MF Total
/ 100ml
(Note: Use MPN method for highly turbid samples)
Dissolved Solids Total
mg`t/I
pH (when analyzed)
units
TOC
miil/I `
Chloride
mg/I
Arsenic
mill
Grease and Oils
m611
Phenol
mill
Sulfate
mg/l
Specific Conductance
Mho:
Total Ammonia
mill
TKN as N
mg/l
uMhos
` - Phnn�ai r04ow
PERMIT M EXPIRATION DATE July 31, 201+
Non -Discharge ` - W00000601 _ UIC
NPDES
Lagoon Remediation: Infiltration Gallery
Spray Field Remediation
_ Rotary Distributor Land Application of Sludge
X Other Monitorina Well A r v .. _ cam,.. 1- k, K.. _
NOTE Values should reflect dissolved and collaidal concentrations
Date Sample Collected WA
Laboratory Name
Certification No.
Date Sample Analyzed
unfiltered X_ YES NO and field acidified _X YES NO)
NO_2 as N
mg/I
NO_3 as N
mg/I
Phosphorus: Total as P
mg/l
Orthophosphat
mg/I
AI -Aluminum
mg/I
Ba - Barium
mg/I
Ca - Calcium
mg/l
Cd - Cadmium
mg/I
Chromium: Total
mg/I
Cu - Copper
mg/I
Fe - Iron
mg/1
Hg - Mercury
mg/I
K - Potassium
mg/I
Mg -Magnesium
mg/I
Mn - Manganese
-mg/I
Ni - Nickel
mg/I
Pb -Lead
mg/I
Zn - Zinc
mg/I
Ammonia Nitrogen
mg/I
Other (Specify Compounds and
concentration units)
ORGANICS: (GC, GC/MS, HPLC)
(Specify test and method #. Attach lab report)
Report Attached?Yes_(1) No_(0)
VOC : method#=
VOC : method#=
Carl A. Gerhardstein, Director Environmental Systems
aillee (or AuthorizedA epA Name and Title - Please print or type
GW-59 Rev. 4/98 j Signature of Rtrmittee (or Authorized

Facility Name
Facility Address
Contact Person: M. L. G
Well Location/Sity Name:
SUBMIT FORM ON YELLOW PAPER ONLY
y7 ` `. • DIVISION OF -WATER QUALITY
LITY MONITORING
--v� '� ^-a F, v• ZF ` rg >i-.�k ,<. GROUNDWATEl� SECTION PERMITS.
IT-TORM P,O Box 2ifi87
Rale16h, NC 27611 7687 ` I
PERMITM EXPIRATION DATE Novi Nan -Discharge W00000601 UIC
Wastewater Treatment Facility I
ans ortation, Box 191A Highway 177N
, NC 28345 County Richmond NPDES
REGORY [phone] I TYPE OF PERMITTED OPERATION BEING MONITORED
Location
Well Identification Number:
MWJ
For Gmu ler Treatment Systems
Well Depth: 45.70
ft. Well Diameter. 4.0 in.
Check one:
Screened Interval
ft. To ft.I
OInfluent(98)
Depth to Water Level
ft. below measuring point
® Effluent (99)
Measuring point is
ft. above land surface
Gallons of water pumpedibailed before sampling:
Field Analysis pH
Specific Conductance
uMhos
Temp.
eC Odor � j Appearance
PARAMETERS: (Samples for metals were collebte
CO
m§ll
Coliform: MF Fecal
1100ml
Colifonn: MF Total
1100ml
(Note: Use MPN method for highly turbid samples)
Dissolved Solids Total
mg/l
pH (when analyzed)
units
TOC
moll
Chloride
mg/I
Arsenic
moll
Grease and Oils
mg/l
Phenol
moll
Sulfate
myll
Specific Conductance
Mhot
Total Ammonia
mg/l
TKN as N
moil
Lagoon Remediation: Infiltration Gallery
Spray Field Remediation
Rotary Distributor Land Application of Sludge
X Other Monitoring WellSc,� . rt -
NOTE Values should reflect dissolved and collaidal concentrations
Date Sample Collected NI4 Date Sample Analyzed
Laboratory Name
Certification No.
unfiltered X YES NO and field acidified X_ YES NO)
NO_2 as N
mg/I
Ni - Nickel
mg/I
NO_3 as N
mg/I
Pb - Lead
mg/l.
Phosphorus: Total as P
mgn
Zn - Zinc
mg/I
Orthophosphat
mgn
Ammonia Nitrogen
mg/I
AI -Aluminum
mg/I
Other (Specify Compounds and concentration
units)
Ba - Barium
mg/l
Ca - Calcium
mg/I
Cd - Cadmium
mg/l
Chromium: Total
mg/l
Cu - Copper
mg/I
Fe - Iron
mg/I
ORGANICS: (GC, GC/MS, HPLC)
Hg - Mercury
mg/I
(Specify test and method M Attach lab report)
K - Potassium
mg/I
Report Attached? Yes_(1) No_(0)
Mg - Magnesium
mg/I
VOC : method # =
Mn - Manganese
mg/I
VOC : method # =
VOC : method # =
Carl A. Gerhardstein, Director Environmental:Systems
ittee or Authorized PpNnt) Name and Title - Please print or type
GW-59 Rev. 4198

SUBMIT FORM ON YELLOW PAPER ONLY
A. 4
Facility Name
Facility, Address
Contact Person: M. L. G
Well Location/Site Name:
OAL' ITY MONITO RING.
ORT FORM 4`
a ,
Location
Attached
Well Identification Number. MW-4
Well Depth: 47.45 ft. Well Diameter
Screened Interval ft. To ft.
Depth to Water Level fl below measuri
Measuring point is It. above land sui
Gallons of water pumpedibailed before sampling
Field Analysis pHSpecifrcConducl
Temp. e C Odor
(Samples for metals were
CO
Coliform: MF Fecal
Coliform: MF Total
(Note: Use MPN method for highly turbid samples)
Dissolved Solids Total
.58
pH (when analyzed)
TOC
n(,3
Chloride
Arsenic
< 0.0 rot
Grease and Oils
Phennl
Sulfate
Specific Conductance
Total Ammonia
TKN as N
I
Richmond
For Grou,:vater Treatment Systems
Cneac ore: ..
20 in.
❑D Influent (98)
point ❑® Effluent (99)
e
se 35.9 uMhos
Appearance
td unfiltered X YES
PI
PERMIT #: EXPIRATION DATE July 31. 20W Ll
Non -Discharge W00000601 UIC
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
Spray Field Remediation
Rotary Distributor Land Application of Sludge
X Other Monitoring Well
NOTE Values should reflect dissolved and collaidal concentrations
Date Sample Collected Date Sample Analyzed
Laboratory Name TestAmerica Laboratories, INC
Certification No. 269
NO and field acidified _X_ YES NO)
NO-2 as N
(. 3
mg/I
NO_3 as N
mg/I
Phosphorus: Total as P
mg/I
Orthophosphat
mg)I
Al - Aluminum
mg/I
Ba - Barium
< O.0 l
mg/I
Ca - Calcium
mg/l
Cd - Cadmium
0.00 s
mg/l
Chromium: Total
0.048
mg/I
Cu - Copper
mg/I
Fe - Iron
mg/I
Hg - Mercury
mg/I
:K - Potassium
mg/I
Mg -Magnesium
mg/I
Mn - Manganese
mg/I
Ni - Nickel mg/I
Pb - Lead 4 0.0 1 mg/I
Zn - Zinc mg/I
Ammonia Nitrogen mg/I
Other (Specify Compounds and concentration units)
ORGANICS: (GC, GCIMS, HPLC)
(Specify test and method #. Attach lab report)
Report Attached? Yes_(1) Nc_(0)
VOC : method # =
VOC : method # =
VOC : method # =
Carl A. Gerhardstein, Director Environmental Systems
P trr< ig�(or Authorized Agent) Name and Tit e - Please
or type
GW-59 Rev. 4/98
Signature

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING
DIVISION OF WATER QUALITY
o- :GROUNDWATER
60.MPLIANCE REPORT FORMx
SECTION PERMITS AND CO(YIP,LIANCE UNIT
.°P
O Box 27yt17 M
27611 7687 ' Phone (9`79)733-3221,
rER
FACILITY INFORMATION
)acility
EXPIRATION DATE July3l.20f4 1'l
Facility Name Hamlet Wastewater Treatment
WQ0000601 UIC
FaciltyAddress CSX Transportation, Box 191A Highway 177N
Hamlet, NC 28345 County Richmond
Contact Person: M. L. GREGORY (910)582�901
TYPE OF PERMITTED OPERATION BEING MONITORED
Well LocatioNSity Name: Location Map Attached
lagoon Remediation: Infiltration Gallery
Spray Field Remediation
Rotary Larid Application of Sludge
Well Identification Number. MWS For Groundwater rreatmwtSystem
Chea 0m.
Distributor
Well Depth: 52.92 fL Well Diamete¢ 2.0 in. - -
X Other Monitoring Well
Screened Interval ft. To ft Olnfluent(98)
—
Depth to Water Level a. �i 9 It.below measuring point © Effluent (99)
NOTE Values should reflect dissolved and collaidal concentrations
Measuring point is ft. above land surface
Gallons of water pumpedibailed before sampling:
Date Sample Collected Date Sample Analyzed
Field Analysis pH t� -3 l Specific Conductance l l . (, uMhos
Laboratory Name TestAmedca Laboratories, INC
Temp. °e✓ Odor f Appearance
Certification No. 269
PARAMETERS: (Samples for metals were collgcted unfiltered X_ YES NO and field acidified X_ YES NO)
CO
mg/I
Coliform: MF Fecal
/ 100m1
Colifonn: MF Total
/ 100ml
(Note: Use MPN method for highly turbid samples)
Dissolved Solids Total 80
}g/I
pH (when analyzed)
units
roc p. L9
mgn
Chloride
trig/I
Arsenic Co,Ga.
nign
Grease and Oils
rog/I
Phenol
trig/l
Sulfate
mg/I
Specific Conductance
Mho:
Total Ammonia
nqg/l
TKN as N
mg/I
NO_2 as N
1. -1 mgll
NO_3 as N -
mg/l
Phosphorus: Total as P
mg/I
Orthophosphat
mg/I
AI -Aluminum
mg/l
Be - Barium
<0•0al mg/l
Ca - Calcium
mgn
Cd- Cadmium
.4O.005 mg/l
Chromium: Total
0.0111 mg/l
Cu -'Copper
mgll
Fe - Iron
mgll
Hg - Mercury _
mgll
K - Potassium
mgll
Mg -Magnesium
mg/l
Mn - Manganese
mgll
Pr'eKla. Ge.c3 4� Cad A.
0.039 "A/ Ly Pe ittee(o
<().0l "I Q (3adI;va:' o.oat.�ISt 'm'-
GW-59 Rev. 4/98 'Y (24Z`Pn: �m '� G -p � 5 'h`0�,� Signature of
(or
Ni - Nickel mg/I
Pb - Lead eQ-OI mg/I
Zn - Zino mg/l
Ammonia Nitrogen mg/I
Other (Specify Compounds and concentration units)
ORGANICS: (GC, GC/MS, HPLC)
(Specify test and method #. Attach lab reporL)
Report Attached?Yes_(1) No—(0)
VOC : method # _
VOC : method # _
VOC : method # _
Director Environmental Systems
igentphlame and Title - Please print or type
51

SUBMIT FORM ON YELLOW PAPER ONLY
l
GROUNDWATER -QUALITY MONITOF ING
DIVISION OF WATER QUALITY '-
pr �. > '"x ``,GROUNDWATER
COMPLIANCE REPORT FORM ' 4 fie:ii
SECTION PERMITSrANDCOMPLIANCE UNIT
Box z7se7
{
Raleigh, NC27M 17687 ,' `Phone [phone]-
rER
FACILITY INFORMATION
Facility Name Hamlet Wastewater Treatment Facility
EXPIRATION DATE November 30, 2009
Facilty Address CSX Trans ortation, Box 191A ighwa 177N
WQ0000601 UIC
Hamlet, NC 28345 County Richmond
NPDES
Contact Person: M. L. GREGORY (910)582449D1
TYPE OF PERMITTED OPERATION BEING MONITORED
Well LocatioNSity Name: Location Map Ataphed
_ Lagoon Remediation: Infiltration Gallery
_ Spray Field _ Remediation
Well Identification Number: MW-7 For Gmundwater Treatment Systems
checkom:
Well Depth: 37.18 ft Well Diameter: 2.0 in.
Rotary. Distributor _ Land Application of Sludge
Screened Interval ft.To ft. Influent (98)
X Other Monitorin Well no S *4.1rea-
Depth to Water Level ft below measuring point ❑D Effluent (99)
Measuring point is ft above land surface
NOTE Values should reflect dissolved and collaidal concentrations
Gallons of water pumped/bailed before sampling
Date Sample Collected /f fl Date Sample Analyzed
Field Analysis pH Specific Conductimce uMhos
Laboratory Name
Temp. °C Odor 1 Appearance
T
Certification No.
PARAMETERS: (Samples for metals were collected unfiltered X_ YES
NO and field acidified X YES NO)
CO
mg/l
NO-2 as N
mg/I
Ni - Nickel
mg/I
Coliform: MF Fecal
/,100ml
NO_3 as N
mg/I
Pb - Lead
mg/I
Coliform: MF Total
/ 40ml
Phosphorus: Total as P
mg/I
Zn - Zinc
mg/I
(Note: Use MPN method for highly turbid samples)
i
Orthophosphat
mg/I
Ammonia Nitrogen
mg/I
Dissolved Solids Total
mil
AI - Aluminum
mg/l
Other (Specify Compounds and concentration
units)
pH (when analyzed)
units
Ba - Barium
mg/I
TOC
mg/I
Ca - Calcium
mg/I
Chloride
mgll
Cd - Cadmium
mg/l
Arsenic
mg/l
Chromium: Total
mg/I
Grease and Oils
mgll
Cu - Copper
mg/I
Phenol
mg/I
Fe - Iron
mgll
ORGANICS: (GC, GC/MS, HPLC)
Sulfate
mg/l
Hg - Mercury
mg/1
(Specify test and method #. Attach lab report)
Specific Conductance
9hos
K - Potassium
mg/l
Report Attached? Yes_(1) No_(0)
Total Ammonia
n1gill
Mg - Magnesium
mg/l
VOC : method # =
TKN as N
mgll
Mn - Manganese
mgll
VOC : method # =
i
VOC : method # =
i Carl A. Gerhardstein, Director Environmental Systems
PGQnittee (or Authorized Agent) a and TiBe - Please print or type
I�M\h
GW-59 Rev. 4/98 ti Signature of F rmittee (or Authorized Agen
V

YELLOW PAPER
t
ING z• ,,,
�4n4
Facility Name Hamlet Wastewater Treatment Facility
Facilty Address CSX Transportation, Box 191A Highway 177N
Hamlet, NC 28345 County Richmond
Contact Person: M. L. G
Well Location/Sity Name:
Well Identification Number. MW-8 Chra o:wler Tmtmwt systems
Well Depth: 57.18 tL Well Diamete : 2.0 in, cnea ore
Screened Interval ft To ft. ❑m Influent (98)
Depth to Water Level ft below measuring point ® Effluent (99)
Measuring point is fL above land surface
Gallons of water pumpedibailed before sampling'.
Field Analysis pH Specific Conductance uMhos
Temp. °C Odor d Appearance
PARAMETERS: (Samples for metals were c,
CO
Coliform: MF Fecal /'
Colifonn: MF Total /'
(Note: Use MPN method for highly turbid samples)
Dissolved Solids Total
PH (when analyzed)
TOC
Chloride
Arsenic
Grease and Oils
Phenol
Sulfate
Specific Conductance
Total Ammonia
TKN as N
RMITS,AND 5gTP IANCE:UNIT
+ Phone: [phone]
PERMIT M EXPIRATION DATE July 31, 2014
Non -Discharge WQ0000601 UIC
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
Spray Field Remediation
Rotary Distributor Land Application of Sludge
X Other Monitoring Well J, q An Sc mil. 4cVeA
NOTE Values should reflect dissolved and collaidal concentrations
Date Sample Collected Date Sample Analyzed
Laboratory Name TestAmerica Laboratories, INC
Certification No. 269 -
unfiltered X YES . NO and field acidified _X YES NO)
NO_2 as N
mg/I
NO_3 as N
mg/l
Phosphorus: Total as P
mg/I
Orthophosphat
mg/I
Al -Aluminum
mg/I
Ba - Barium
mg/I
Ca - Calcium
mg/l
Cd - Cadmium
mg/I
Chromium: Total
mg/I
Cu - Copper
mg/I
Fe - Iron
mg/I
Hg - Mercury
mgll
K - Potassium
mgll
Mg - Magnesium
mgll
Mn - Manganese
mgll
Ni - Nickel
mg/I
Pb - Lead
mg/I
Zn -Zinc
mg/1
Ammonia Nitrogen
mg/1
Other (Specify Compounds and
concentration units)
ORGANICS: (GC, GC/MS, HPLC)
(Specify test and method #. Attach lab report)
Report Attached? Yes (1) Nc_(0)
VOC method#=
VOC : method#=
VOC : method#=
4 - Cad A. Gerhardstein, Director Environmental Systems
P ' ee(orAuthorizedme andTiitle- Pleaseprintortype
s �.
GW-59 Rev. 4198 Signature of I
rmittee (or Authorized Age )

tt
Test menca
THE LEADER IN ENVIRONMENTAL TESTING
To
-` A I r LLERcG10NALOFfiCE
ANALYTICAL REPORT
Job Number: 680-56229-1
Job Description: CSX Hamlet, NC WWTP
For:
ARCADIS U.S., Inc.
801 Corporate Center Drive
Suite 300
Raleigh, NC 27607-5073
Attention: Mr. Alan Pinnix
Lo'-*V'� &Vt 1-h
Kathryn Smith
Project Manager I
[e-mail]
03/31/2010
cc: Mr. Jerry Cato
Mr. Mike Gregory
Aplr Ia mleae.
mffi" SmiN
PmleeMa W.I
=Ja010427PM
LW ON-ENV0000038652//Project-9522202
s for
ich
accreditation is required or available.
The test
resultss in this report meet ELAP to the NELAP requirements a el n t d tResults s for rperta pertain only ohsamples listed in this report. This report
Any pt n approval of the laboratory. Questions should be directed to the
may not reproduced, except in full, without the writte
person who signed this report.
Savannah Certifications and ID #s: A2LA: 0399.01; AL: 41450; ARDEQ: 88-0692; ARDOH; CA: 03217CA; CO; CT:
PH0161; DE; FL: E87052; GA: 803; Guam; HI; IL: 200022; IN; IA: 353, KS: E-10322; KY EPPC: 90084; KY UST; LA
NJ- GA769; NM; NY: 10842; NC DWQ: 269; NC DHHS S 3 01; PA: 68-0047I4; PR: GA00 06ERL LA000244; SC:006;
1; T C; N0296- TX: T10 0 7 4185; USERS BTM 0006; VT. VT 87052; VA: 00302; WA; WV DEP: 094; WV
DHHR:
¢"qR
N, ACCOHOTestAmerica Laboratories, Inc. g
TestAmerica Savannah 5102 LaRoche Avenue, Savannah, GA 31404
Tel [phone] Fax [phone] ODN testamericainc com
Page 1 of 11

METHOD SUMMARY.
Client: ARCADIS U.S., Inc.
Job Number: 680-56229-1
Description Lab Location Method Preparation Method
Matrix Water
Metals (ICP)
Preparation, Total Metals
Lab References:
TAL SAV = TestAmerica Savannah
Method References:
TAL SAV 40CFR136A 200.7 Rev 4.4
TAL SAV EPA 200.7
40CFR136A = "Methods for Organic Chemical Analysis of Municipal Industrial Wastewater, 40CFR, Part 136, Appendix A,
October 26, 1984 and subsequent revisions.
EPA = US Environmental Protection Agency
TestAmedca Savannah
Page 3 of 11

r
METHOD/ANALYST SUMMARY
Client: ARCADIS U.S., Inc.
Job Number: 680-56229-1
Method Analyst Analyst ID
40CFR136A 200.7 Rev 4.4 Bland, Brian
TestAmedca Savannah
BCB
Page 4 of 11

SAMPLE SUMMARY
Client: ARCADIS U.S., Inc.
Job Number: 680-56229-1
Date/Time Date/Time
Lab Sample ID Client Sample ID Client Matrix Sampled Received
680-56229-1 MW-5 Water 03/26/2010 1435 03/27/2010 0849
Te9tAmerica Savannah
Page 5 of 11

P, r
Client: ARCADIS U.S., Inc.
Client Sample ID: MW-5
Lab Sample ID: 680-56229-1
Client Matrix: Water
Analytical Data
Job Number: .680-56229-1
Date Sampled: 03/26/2010 1435
Date Received: 03/27/2010 0849
200.7 Rev 4.4 Metals (ICP)
Method:
200.7 Rev 4.4
Analysis Batch: 680-164574
Instrument ID:
ICPD
Preparation:
200.7
Prep Batch: 680-164291
Lab File ID:
N/A
Dilution:
1.0
Initial WeightNolume:
50 mL
Date Analyzed:
03/31/20100543
Final WeighWolume:
50 mL.
Date Prepared:
03/2912010. 1144
Analyte
Result (ug/L)
Qualifier
MDL
RL
Arsenic
20 -
U
4.6 -
20
Barium
20
2.3
10
Cadmium
5.0
U
2.0
5.0
Chromium
29
1.2
10
Lead
10
'U
4.0
10
TestAmerica Savannah Page 6 of 11

DATA REPORTING QUALIFIERS
Client: ARCADIS U.S., Inc.
Lab Section. Qualifier Description
Metals
TestAmerica Savannah
Job Number: 680-56229-1
Indicates the analyte was analyzed for but not detected.
Page 7 of 11

Client: ARCADIS U.S., Inc.
Quality Control Results
Job Number: 680-56229-1
Method. Blank -Batch: 680.164291
Method: 200.7 Rev 4.4
Preparation: 200.7
Lab Sample ID:
MB 680-164291/13-A
Analysis Batch: 680-164574
Instrument ID: ICPD
Client Matrix:
Water
Prep Batch: 680-164291
Lab File ID: NIA
Dilution:
1.0
Units: ug/L
Initial Weight/Volume: 50
mL
Date Analyzed:
03/31/2010 0353
Final WelghWolume: 50
mL
Date Prepared:
03/29/2010 1144
Analyte
Result
Qual
MDL
RL
Arsenic
20
U
4.6
20
Barium
10
U
2.3
10
Cadmium
5.0
U
2.0
5.0
Chromium
10
U
12
10
Lead
10
U
4.0
10
Lab Control Sample - Batch: 680-164291
Method: 200.7 Rev 4.4
Preparation: 200.7
Lab Sample ID:
LCS 680-164291114-A
Analysis Batch: 680-164574
Instrument ID: ICPD
Client Matrix:
Water
Prep Batch: 680-164291
Lab File ID: NIA
Dilution:
1.0
Units: ug/L
Initial Weight/Volume: 50
mL
Date Analyzed:
03/31/2010 0358
Final Weight/Volume: 50
mL
Date Prepared:
03/29/2010 1144
Analyte
Spike Amount Result
% Rec. Limit
Qual
Arsenic
2000
1960
98
85-115
Barium
2000
2060
103
85 - 115
Cadmium
50.0
49.2
98
85-115
Chromium
200
204
102
85 - 115
Lead
500
501
100
85-115
Calculations are performed before rounding to avoid round -off errors in calculated results.
TestAmerica:Savannah Page 8 of 11

Client: ARCADIS U.S., Inc.
Matrix Spike/
Matrix Spike Duplicate Recovery Report - Batch: 680.164291
MS Lab Sample ID: 680-56229-1
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
03/31/2010 0548
Date Prepared:
03/29/2010 1144
MSD Lab Sample ID:
680-56229-1
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
03/31/2010 0553
Date Prepared:
03/29/2010 1144
Analysis Batch: 680-164574
Prep Batch: 680-164291
Analysis Batch: 680-164574
Prep Batch: 680-164291
Quality Control Results
Job Number: 680-56229-1
Method: 200.7 Rev 4.4
Preparation: 200.7
Instrument ID: ICPD
Lab File ID: WA -
Initial Weight/Volume: 50 mL
Final Weight/Volume: 50 mL
Instrument ID:. ICPD
Lab File ID: WA
Initial Weight/Volume: 50 mL
Final WeighWolume: 50 mL
Analyte
MS
% Rec.
MSD
Limit
RPD
RPD.Limit
Arsenic
93
97
75-125
5
20
Barium
97
101
75-125
5
20
Cadmium
92
97
75-125
5
20
Chromium
99
104
75-125
4
20
Lead
95
98
75 - 125
4
20
Calculations are performed before rounding to avoid round -off errors In calculated results.
TestAmerica Savannah Page 9 of 11
MS Qual MSD Qual

CHAIN OF
TRANSPORTATION CUSTODY
TNSPORATI
TRA
LABORATORY INFORMATION
COC #
%TestAmerica Savannah- 5102 LaRoche Avenue. Savannah. GA 31404. P: 912.354-7858 F:912-352.0165
eslArman North Canton- 4101 Shutfel Drive MY. North Canton, ON 44720 P:330.497-9396 F:330-497-0772
Q Testnmerin Tampa -6712 Benjamin Rod, Suite 100. Tampa. FL 33634 P:813.885.7427 F:813.885.7049
QTestAmalica Pensacola• 3355 McLemore Drive. Pensacola. FL 32514 P:850.4744001'F:85OA78-2671
QTe4tAmeriea BuNalo- Westwood Drive, Suite 106.'Amhcrsl, NY 14228 P:716691.2600 F:716.961-7991
QTestAmariw Chicago- 2417 Bond Street. University Park. It. 60466 P.708534.5200 F. 708534.5211
SHIPMENT INFORMATION
Shipment Melhoct
ShipmentTrecking No:
CSXT PROJECT INFORMATION Prof. State (State of Origin) N.
CONSULTANT INFORMATION Project 4.
CSXT Project Number: 7�u.� �^ Proj.City:
CSXT Project Name: 1 , ^\..--�
ijawleT Vv _
CSXT Contact LWON: p
ij IDI.
Company:p1Z
Address: mail:
l t� ( { CU
CEN. Slate, Zip: 1-e - 1L Phone: ` 5 F ><
CA Iv
Turnaround Time: ❑ Standard 6.13 Days
❑ 1 Day Rush Specify N Days .
❑ 2 Day Rush Standard 14 Days
❑ 3 Day Rush Other
Preservative Codes: 3 = Sulfuric Acid Not A
0 = No Preservatives 4 = Sodium Thiosulfate Pres.
1 = Hydrochloric Acid 5 = Sodium Hydroxide Code
2 = Nitric Acid 6 = Other
'COMMENTS
LAB USE
METHODS
FOR
ANALYSIS
p
Sl
D liverables: ❑ Other Deliv:
CSXT Standard (Level 11)
Level III ElW EDD Required. Format:
❑ Level IV
Matrix Codes: SO=Soil LID=Liquid
GW = Groundwater SL- Sludge
W = Waste Water 01 = Oil
SW=Sudace Water SOL=Other Solid
SAMPLE INFORMATION
Sample Identification
Containers
Sam le
Collection
Filtered
Type
Matrix
NuT ber&
Type
Date
Time
Sampler
Y or N
Comp
or Grab
Code
�—
Relirmi had e :
p
oat Rme:
t e
Received Sr.DateRmo:
Comments & Special Analytical Requirements:
ReOnquished By:
Date7Time:
Received By:
Date/Time:
Resnquished By:
DateTme:
Received By:
Dnle7Tlme:
Received By Laboralo
Dale7Tt e:
Lab Remarks:
LAB USE: Custody Intact
Dyes ❑No
un.nire eu ieT ne el IRMITTFn
Cuslody Seat
N
Tn CAYT WITH ORIGINAI
LAB Log Number
0
Mr.
ORIGINAL- RETURN TO LABORATORY WITH SAMPLES

Login Sample Receipt Check List
Client: ARCADIS U.S., Inc.
Login Number: 56229
Creator: Conner, Keaton
List Number: 1
Job Number: 680-56229-1
List Source: TestAmerica Savannah
Question
T / F/ NA Comment
Radioactivity either was not measured or, if measured, is at or below
True
background
The cooler's custody seal, if present, is Intact
True
The cooler or samples do not appear tohave been compromised or
True
tampered with.
-
Samples were received on ice.
Two
Cooler Temperature is acceptable.
True
Cooler Temperature is recorded.
True
COC is present.
True
COC is filled out in ink and legible.
True
COC is filled out with all pertinent information.
True
There are no discrepancies between the sample IDs on the containers and
True
the COC.
Samples are received within Holding Time.
True
Sample containers have legible labels.
True
Containers are not broken or leaking.
True
Sample collection date/times are provided.
True
Appropriate sample containers are used.
True
Sample bottles are completely filled.
True
There is sufficient vol. for all requested analyses, incl. any requested
True
MS/MSDs
VOA sample vials do not have headspace or bubble is <6mm (114") in
N/A
diameter.
If necessary, staff have been informed of any short hold time or quick TAT
True
needs
Multiphasic samples are not present.
True
Samples do not require splitting or compositing.
True
Is the Field Sampler's name present on COC?
N/A
Sample preservation Verified
N/A
TestAmerica Savannah
Page 11 of 11

COC #
LABORATORY INFORMATION
TesWnedwSavanmh-5102 LaRocheAvenue. Sarahnah. GA 31404-P:912-354-7858 F:912-352-0165
SHIPMENT INFORMATION
CHAIN OF
11Amenta North Onion -4101 Shuful Drive MY. North Canton, OH44720 P:330-497.9396 F:330-497-0772
6712 Benjamin Road. Suite too; Tampa. FL 33634 P.813-085.7427 F:813-885-7049
shipment McOwtl: r
CUSTODY
0TestAmerica-fampa-
Pensacola. FL32614 P: 850474•t00t'F:8 F:716-261-
❑TestAm¢dca Peffalo-a•33551004 P: 716.691•Zfi00 F: 71fi-961.7991
Shipmen1TreckOg NOT: {
TRANSPORTATION
TAL.6006 0907
od"e, suit
❑ TestPrAenw 8uilalo • 10 Hauiaood Drive, Suite 106:'Amheml NY 14228
Chiu9o-2417 Bond Street. llniversily Park. IL 60466 P;M'534.5200 F:708-534.5211
❑TestAm4dw
Project d: A (/ . D o J
Prof. Slate (State of Origin) 11, CONSULTANT INFORMATION
ti
l`R.i
CSXT PROJECT INFORMATION
PM.
Company:
Pro}' City. _L '� S
CSXT Project Number.
5�y 92
( Adtlress:
J
Email: 1
l ` e
i
CS%T Prolecl Name: 1 ���
T'
c •
Phone: F
_
LWON: y CBX Stele, Zip:1�. AG
1
l
CS1CT contact: �
,�, U a —CT
� COMME'.
Turnaround Time: ❑Standard 6.73 Days
PreservativeNo t
Codes: 3 =Sulfuric Acid METHODS FOR ANALYSIS
Pres.
❑ Rush Specify q Days _,_
0 = No Preservatives 4 = Sodium Thiosulfate
1 Day
❑ Rush Standard 14 Days
1 = Hydrochloric Acid 5 = Sodium Hydroxide Code
2 Day
2 = Nitric Acid 6 = Other
❑ 3 Day Rush Other
LIO =Liquid L
D liverables: ❑ Other Deliv:
Matrix Codes: SO =Soil
v
SL=Sludge [�
GIN =Groundwater 4
CSXT Standard (Level 11)
❑ EDD Required, Format:
W W = Waste Water 01=Oil
y
Level 111
SW=Surface Water SOL=Other Solid
u]
m
❑ Level IV
_
F+
SAMPLE INFORMATION
Containers
Sam Ie Collection Filtered Type Matrix
o
0
Sample Identification Number&
Date Time Sampler Y or N orGmh Code
M
Type
a._1_'
c1: N tg ��
By" Daunts:
By: DalaTima:
By: __ _._
n,rem�= Lab Remarks: (ABUSE:
f'1..
68�..%zzY
Intact Custody Seal 0 LAB Log Number
a If
IBMITTED TO CSXT WITH ORIGINAL COC
14

r _. 1
Client: ARCADIS U.S., Inc.
Login Number: 56229
.Creator. Conner, Keaton
List Number: 1
Question
Login Sample Receipt Check List
T / F/ NA Comment
Radioactivity either was not measured or, if measured, is at or below
True
background
The cooler's custody seal, if present, is Intact.
True
The cooler or samples do not appear to have been compromised or
True
tampered with.
Samples were received on Ice.
True
Cooler Temperature Is acceptable.
True
Cooler Temperature Is recorded.
True
COC is present.
True
COC Is filled out In ink and legible.
True
COC Is filled out with all pertinent information.
True
There are no discrepancies between the sample IDs on the containers and
True
the COC.
Samples are received within Holding Time.
True
Sample containers have legible labels.
True
Containers are not broken or leaking.
True
Sample collectiondate/times are provided.
True
Appropriate sample containers are used.
True
Sample bottles are completely filled.
True
There is sufficient vol. for all requested analyses. Inc]. any requested
True
MS/MSDs
VOA sample vials do not have headspace or bubble is <6mm (114") In
N/A
diameter.
If necessary, staff have been informed of any short hold time or quick TAT
True
needs
Mulfiphasic samples are not present.
True
Samples do not require splitting or compositing.
True
Is the Field Sampler's name present on COC?
NIA
Sample Preservation Verified
N/A
Job Number: 68056229-1
Llst'Source: TestAmerica Savannah
TestAmerica Savannah
Page 11 of 11

Im
TRANSPORTATION
Jerry L. Cato REM
Supervisor Environmental Control
North Carolina Department
Of Natural Resources
Attn: Information Processing Unit
Division Water Quality
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
Dear Sir or Madam:
JAN 2.2 2010
OENR- FAYEMLLE REGIONAL
January 11, 2010
File. 9613703
L
r�
" G
Permit No. WO00G0604 Richmond Country
CSX Transportation, Inc. (CSXT)Hamlet `NC
Please find Attachment A in triplicate, which is the third triennial_ 2009 Monitoring
Report for the WWTP discharge. Flow and Nitrogen, Nitrate Total (as N) for Attachment A, are
being sent under separate cover due -to our contract lab was not able to run the Nitrogen, Nitrate
Total prior to the 2009 holidays and vacation time.
If you have any questions or comments, please contact.me at [phone].
Sincerely,
Jerry L. Cato
Enclosures
RECEIVED/DENR/DWQ
Aquifer Protection Section
JAN 15 2010

ATTACHMENT q — LTATIONS AND MONITORING REQUIRE Permit Number: W
00000601 Version; 3.0 '
PPI 001— W WTF Effluent
EFFLUENT CHARACTERISTICS
Parameter Descriptiou — parameter Code
H
OW. conduit or thru treatment Plant — 501050
Total Dissolved — I So Deg.0 — 70300400
TotalOrganic (TOC)— 00680
rogen. Nitrate Total (as N) — 00620
Barium, Total (as Ba) — 01007
Cadmium. Total (as Cd) — 01027
Chromium. Total (as Cr) — 01034
LCad, Total (as Pb) — 0105I
Arsenic, Total (as As) — 01002
EFFLUENT LIMITS
Monthly Average Weekly Average
1.0 I mgd 0, O ,O
na
3 X year monitoring shall be conducted in March. July and November.
W'Q0000601 Version 3.0
Daily Maximum
.0u75 ms�
j.)
L
MONITORING REQUIREMENTR,Fequency
Frequency
Sample Type
uous
Recorder
ear
Grab
ear
Grab'.
ear
Grab
ear
Grab
ear
Grabear
Grabar
Grabar
Grabar
Grab
Attachment A

TestAmenca \\
THE: LEADER IN ENVIRONMENTAL TESTING —_
ANALYTICAL REPORT
Job Number: 680-52940=1
Job Description: CSX Hamlet, NC.WWTP Monthly
For:
CSX Transportation
500 Water Street
Jacksonville, FL 32202
Attention: Mr. Mike Gregory
�1,J 1 PPPm+eG laireVaee.
�/ `�) Pmietl Menial l
1228/1WBfU:12 AAI ,
Kathryn Smith
Project Manager I
:[e-mail]
12/29/2009
cc: Mr. Jerry Cato
Mr. Alan Pinnix
L W ON -EN V0000027258HProject-R000011790
The test results in this report meet NELAP requirements for parameters foc which accreditation is required or available.
Any exceptions to the NELAP requirements are noted. Results pertain only to samples listed in this report. This report
may not be reproduced, except in full, without the written approval of the laboratory. Questions should be directed to the
person who signed this report.
`Savannah Certifications and;ID #s: A2LA: 0399.01; AL: 41450; ARDEQ: 88-0692; ARDOH; CA:,03217CA; CO; CT: -
PH0161; DE; FL: E87052; GA:'803' Guam; HI; IL: 200022; IN; IA: 353; KS: E-10322; KY EPPC: 90084; KY UST; LA
DEQ: 30690; LA DHH: LA080008; ME; 2008022; MD: 250;"MA: M-GA006;'MI: 9925; MS; N#ESC: 249; NV: GA00006;
NJ: GA769; NM; NY: 10842; NC DWQ: 269; NC DHHS:13701; PA: 68-00474; PR: GA00006;•RI: 'LA000244; SC:
98601001; TN: TN0296; TX T104704185; USEPA: GA00006; VT: VT-87052;.VA: 00302; WA; WV DER 094; WV
DHHR: 9950 C; WI DNR: 999819810; WY/EPAR8: 8TMS-Q
TestAmerica Laboratories, Inc.
TestAmerica Savannah 5102 LaRoche Avenue. Savannah, GA 31404
Tel [phone] Fax [phone] ww Aestamericainc.com
C 1N ACCCgO
E ti
c
-Page 1 of 19

Job Narrative
68052940-1
Comments
No additional comments
Receipt
All samples were received in good condition within temperature requirements
Metals
No analytical or quality issues were noted.
General Chemistry
No analytical or quality issues were noted.
Page 2 of 19

METHOD SUMMARY
Client: CSX Transportation
Job Number. 680-52940-1
Description
Lab Location
Method
Preparation Method
Matrix . Water
Metals (ICP)
TAL SAV
40CFR136A 200.7
Rev 4.4
Sample Filtration, Feld
TAL SAV
FIELD _FLTRD
Preparation, Total Metals
TAL SAV
EPA 200.7
' Preparation, Total Recoverable Metals
TAL SAV
EPA 200.7
Nitrogen, Nitrate -Nitrite
TAL PEN
MCAM 353.2
Solids, Total.Dissolved (TDS)
TAL SAV
SM SM 2540C
Organic Carbon, Total (TOC)
TAL SAV
SM SM 5310B
Lab References:
TAL PEN = TestAmerica Pensacola
TAL SAV = TestAmedca Savannah
Method References:
40CFR136A = "Methods for Organic Chemical Analysis of Municipal Industrial Wastewater", 40CFR, Part 136, Appendix A,
October 26, 1984 and subsequent revisions.
EPA = US Environmental Protection Agency
MCAW W = "Methods For Chemical Analysis Of Water And Wastes";'EPA-60014-79-020, March 1983 And Subsequent Revisions.
SM = "Standard Methods For The Examination Of Water And Wastewatef',
TestAmerica Savannah
Page.3 of 19

r
METHOD/ANALYST SUMMARY
Client: CSXTransportaton
Job Number. 560-52940-1
Method Analvst Analyst ID
40CFR136A 200.7 Rev 4.4 Bland, Brian BCB
MCAWW 353.2 Gimlin, Wendy WG
SM SM 2540C Jackson, Michelle S MSJ
SM SM 5310B Blackshear, Kim KB
TestAmerlca Savannah
Page 4 of 19

SAMPLE SUMMARY
Client: CSX Transportation
Job Number. 680-52940-1
DaterTime DateTme
Lab Sample ID Client Sample ID Client Matrix- Sampled Received
680-52940-1 WWiP Semple Water 11123120091000 11/24/20091020
TestAmerica Savannah
Page 5 of 19

Analytical Data
Client: CSX Transportation
Client Sample to: W WTP Sample
Lab Sample ID: 680-52940-1.
Client Matrix: Water
Job Number. 680-5294D-1
Date Sampled: 11/23/2009 1000
Date Received: 11/24/2009 1020
200.7 Rev 4.4 Metals (ICP)
Method:
200.7 Rev 4.4
Analysis Batch: 680-.154811
Instrument ID:
ICPD
Preparation:
200.7
Prep Batch: 680-154566
Lab File ID:
WA
Dilution:
1.0
Initial Weight/Volume:
50 mL
Date Analyzed:
11/27/2009 1314
Final Weight/Volume:
50 mL
Date Prepared:
11/2512009 0838
Analyte
Result (ug/L)
Qualifier
MDL
RL
Arsenic
20
U
4.6
20
Barium
18
2.3
10
Cadmium
- 5.0
U
2.0
5.0
Chromium
10
u
1.2
10
Lead
10
U
4.0
10
200.7 Rev 4.4 Metals (ICP)-otssoived
Method:
200.7 Rev 4.4
Analysis Batch: 680-154811
Instrument ID:
ICPD
Preparation:
200.7
Prep Batch: 680-154562
Lab. File ID:
NIA
Dilution:
1.0
Initial Weight/Volume:
50 mL
Dale Analyzed:
11127/20091055
Final Weight/Volume:
50 mL
Date Prepared:
11/25/2009 0821
Analyle
Result (ug/L)
Qualifier
MDL
RL
Arsenic
20
U
10
20
Barium
19
2.0
10
Cadmium
5.0
U
2.0
5.0
Chromium
10
U
2.0
10
Lead
10
U
3.4
10
TestAmarlca Savannah Page 6 of 19

Analytical Data
Client: CSX Transportation Job Number. 680-52940-1
General Chemistry -
CllentSamplelD: WWTP Sample .
Lab Sample ID: 680-52940rf - Date Sampled: 11/23/2009 1000
Client Matrix: Water ' Date Received: 11/24/2009 1020
Analyte Result Oual Units MDL ' RL Oil Method
Nitrate as N . 1.2 mg/L 0.030 0.050 1.0 •353.2
Analysis Balch: 400-101232 Date Analyzed: 12/21/2009 1230 _
Total Organic Carbon 9.5 mg/L 0.50 -1.0 1.0 SM 5310B
Analysis Balch: 680-155262 Date Analyzed: 12102/2009 1340 .
Analyte Result Oual Units RL. RL Dil ' Method
Total Dissolved Solids 120 mg/L 5.0 5.0 1.0 70 2540C
Analysis Batch: 680-154506 Date Analyzed: 11/24120091347
n
TestAmerlca Savannah Page 7 of 19

DATA REPORTING QUALIFIERS
Client: CSXTransportabon
Lab Section Qualifier Description
Metals
General Chemistry
TestAmerica Savannah
Job Number. 680-52940-1
U Indicates the analyte was analyzed for but not detected.
U Indicates the analyte was analyzed for but not detected.
Page 8 of 19

Client: CSXTransportabon
MethodBlank-Batch: 680-154562
Lab Sample ID:
MB 680-154562/4-A
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
11/272009 1019
Date Prepared:
11/25/2009 0821
Analysis Batch: 680-154811 ,
Prep Balch:, 680.154562
Units: ug/L
Quality Control Results
Job Number. 680-52940-1
Method: 200:7 Rev 4A
Preparation: 200.7
Total Recoverable
Instrument ID: ICP/AES - D
Lab File ID: NIA
Initial WeighWolume: 50 mL
Final WeighWolume: 50 mL
F
Analyle Result Qual MDL RL
Arsenic
20 -
U
10
20
Barium
10
U
2.0
10
Cadmium
5.0
U
2.0
5.0
Chromium
10
U
2.0
10
Lead
10
U
3.4
10
Lab Control Sample -Batch: 680.164562
-
Method: 200.7 Rev 4A
Preparation: 200.7
Total Recoverable
Lab Sample ID:
,LCS 680-16456215-A
Analysis Batch: 680-154811
Instrument ID: ICP/AES -
D
Client Matrix:
Water
_
Prep Batch: 680-154562
Lab File ID: WA
Dilution:
1.0
Units: ug/L
Initial WeighWolume: 50
mL
Date Analyzed:
11/27/2009 1024
Final WeighWolume: 50
mL
Dale Prepared: 11125/2009 0821
Analyte Spike Amount Result % Rec. Limit Qual
Arsenic
2000
2090
105
B5 - 115
Barium
2000
2110
105
85- 115
Cadmium
50.0
53.3
107
85-115
Chromium
200
209
105
85-115
Lead
500
521
104
85-115
Calculations are performed before rounding to avoid round -off errors in calculated results.
TestAmerlea Savannah Page 9 of 19

s
Client: CSX Transportation
Matrix Spike/
Matrix Spike Duplicate Recovery Report - Batch: 680.164562
MS Lab Sample ID:
680-52907-C-1-B MS
Analysis Batch: 680-154811
Client Matrix:
Water
Prep Batch: 680-154562
Dilution:
1.0
Date Analyzed:
1127/2009 1045
Date Prepared:
11/2512009 0821
MSD Lab Sample ID:
680-52907-C-1-C MSD
Analysis Balch: 680-154811
Client Matrix:
Water
Prep Batch: 680-154562
Dilution:
1.0
Date Analyzed:
11/27/2009 1050
Date Prepared:
1125/2009 0821
Quality Control Results
Job Number. 680-52940-1
Method:.200.7 Rev 4.4
Preparation: 200.7
Total Recoverable
Instrument ID: ICP/AES - D
Lab File ID: WA
Initial Weightolume: 50 mL
Final WeighWolume: 50 mL
Instrument ID: ICP/AES -D
Lab File ID: N/A
Initial Weight/Volume: 50 mL
Final WeighWolume: 50 mL
Analyte
MS
% Rec.
MSD
Limit
RPD
RPD Limit
Arsenic
107
107
75-125
0
20
Barium
107
107
75 - 125
0
20
Cadmium
106
106
75-125
0
20
Chromium
106
105
75-125
0
20
Lead
106
104
75-125
2
20
Calculations are performed before rounding to avoid round -off errors In calculated results.
TestAmerlca Savannah Page 10 of 19
MS Oust MSD Quai

Client: CSX Transportation
Method Blank - Batch:630-154566 '
Lab Sample ID:
MB 680-154566/11-A
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
11/2712009 1259
Date Prepared:
11/252009 0838 -
Analysis Batch: '680-154811
Prep Batch: 680-154566
Units: ug/L
Quality -Control Results
Job Number.. 68D-52940-1
Method: 200.7 Rev 4.4
Preparation: 200.7 -
'Instrument ID: ICP/AES - D
Lab File ID: N/A
Initial Weight/Volume: - 50 mL
Final WeighWolume: 50 mL
Analyte
Result
i
Qual
MDL
RL
Arsenic
20
U:-
4.6
20
Barium
10
U
2.3'
10
Cadmium
5.0
U
2.0
5.0
Chromium
.10
U
_
1.2
10
Lead
10
U
4.0• -
10
Lab Control Sample -Batch: 680.164666
Method: 200.7 Rev 4A
,
Preparation: 200.7
Lab Sample ID:
LCS 680-164566/12-A
Analysis Batch:
680-154811
Instrument ID: ICP/AES - D
Client Matrix:
Water
Prep Batch: 680-154566
Lab File ID: WA
,
Dilution:
1.0
Units: ug/L
Initial Weight/Volume: 50
'mL
Date Analyzed:
11127/2009 1304
Final Weight/Volume: 50
mL
Date Prepared:
11125/2009 0838
Analyte
Spike Amount
Result
% Rec. Limit
Qual-
Arsenic
-
2060
2080
104
85-115
Barium
_
2000
2140
107
. 85-115
Cadmium
50.0
54.3
109
85-115
Chromium
200
210
105
85-115
Lead
500
524
105
- 85-115
Calculations are performed before rounding to avoidround-ofGenors,V calculated results.
TestAmerica Savannah Page 11 of 19

Client CSX Transportation
Matrix Spike/
Matrix Spike Duplicate Recovery Report - Batch: 680-154566
MS Lab Sample ID:
680-52894-F-1-B MS
Analysis Batch: 680-154811
Client Matrix:
Water
Prep Batch: 680-154566
Dilution:
1.0
Date Analyzed:
11/27/2009 1418
Date Prepared:
11/2512009 0838
MSD Lab Sample ID:
680.52894-F-1-C MSD
Analysis Batch: 680-154811
Client Matrix:
Water
Prep Batch: 680-154566
Dilution:
1.0
Date Analyzed:
11/27/2009 1423
Date Prepared:
11/2512009 0838
% Rec.
Quality Control Results
Job Number. 680-52940-1
Method: 200.7 Rev 4.4
Preparation: 200.7
Instrument ID: ICP/AES - D
Lab File ID: NIA
Initial WeighWolume: 50 mL
Final WeighWolume: 50 mL
Instrument ID: ICP/AES - D
Lab File ID: N/A
Initial WeighWolume: 50 mL
Final WeighWolume: 50 mL
Analyte MS MSD Limit RPD RPD Limit
Arsenic
107
106
75 - 125
1
20
Badum
110
110
75 - 125
1
20
Cadmium
112
111
75 - 125
0
20
Chromium
108
107
75 -125
1
20
Lead
107
107
75 -125
0
20
Calculations are performed before rounding to avoid round -off errors in calculated results,
TestAmerlea Savannah Page 12 of 19
MS Qual MSD Qua[
e

Client: CSX Transportation
Method Blank -Batch: 40D-101232
Lab Sample ID;
. MB 400-10123211
Client Matrix:
Water
Dilution:1.0
Date Analyzed:
12/21/2009 1230
Date Prepared:
WA
Analysis Batch: 400-101232
Prep Balch: N/A '
Units: mg/L _
Quality Codtrol Results
Job Number. 680-52940-1
Method: 353.2'
Preparation: NIA
Instrument ID: Lachat 1
Lab File ID: N/A
Initial Weight/Volume: 1.0 mL
Final Weight/Volume:' ' 1.0 mL
Analyte
Result -Qual
. MDL RL
Nitrate as N
0.050 ` U
'0.030 0.050
Lab Control Sample • Batch: 400-101232
Method: 353.2
'
Preparation: N/A
Lab Sample ID:
LCS 400-10123212
Analysis Batch: 400-101232
Instrument ID: ' Lachat 1
Client Matrix:
Water
Prep Batch: N/A -
Lab File ID: ` WA
Dilution:
1,0
Units: mg/L
Initial WeighWolume:, 1.0 mL "
Date Analyzed:
12/21/2009 1230
Final WeighWolume: 10 mL
Date Prepared: N/A
Analyte, Spike Amount Result '%Rec. Limit Qual
Nitrate Nitrite as N 0.500 0.515 103 90 - 110
Calculations are performed before rounding to avoid round -off errors in calculated results.
TestAmerlca Savannah :Page 3.3 of 3.9

Client: CSX Transportation
Method Blank -Batch: 680.164506
Lab Sample ID: MB 680-164506/1
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 11/24/2009 1347
Date Prepared: N/A
Analysis Batch: 680-154506
Prep Batch: NIA
Units: mg1L
Quality Control Results
Job Number. 680-52940-1
Method: SM 2540C
Preparation: N/A
InstrumentID: No Equipment Assigned
Lab File ID: N/A
IniOal WeighWolume: 100 mL
Final WeighWolume: 100 mL
Analyte
Result Qual
RL
RL
Total Dissolved Solids
5.0 U
5.0
5.0
Lab Control Sample/
Method: SM 2640C
Lab Control Sample Duplicate Recovery Report - Batch: 680.154506
Preparation: NIA
LCS Lab Sample ID: LCS 680-154506/2
Analysis Batch: 680-154506
Instrument ID: No Equipment Assigned
Client Matrix: Water
Prep Batch: NIA
Lab File ID: NIA
Dilution: 1.0
Units: mg/L
Initial Weight/Volume:
100 mL
Date Analyzed: 11/2412009 1347
Final WeighWolume:
100 mL
Date Prepared: WA
LCSD Lab Sample ID: LCSD 680-IWO613
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
11/2412009 1347
Date Prepared:
N/A
Analyte
Total Dissolved Solids
Analysis Batch: 680-154506
Prep Batch: NIA
Units: mg/L
% R c
LCS LCSD Limit
Instrument ID: No Equipment Assigned
Lab File ID: N/A
Initial Weight/Volume: 100 mL
Final WeighWolume: 100 mL
RPD RPD Limit LCS Qual LCSD Qual
81 85 80 -120 5 25
Calculations are performed before rounding to avoid round -off errors In calculated results.
TestAmerleaSavannah Page 14 of 19

Client CSX Transportation
Duplicate - Batch: 680-164606
Lab Sample ID:
680-52940.1
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
1.1/24/2009 1347-
Date Prepared:
N/A
Analyte
Total Dissolved Solids
0
Quality Control Results
Job Number. 680-52940-1
Method: SM 2640C"
Preparation: N/A
Analysis Balch: 680-154506 Instrument ID: No Equipment Assigned
Prep Batch: N/A Lab File ID: WA -
Units: mg/L Inftial WeighWalume: - 100 mL -
Final WeighWolume: 100 mL
Sample Result/Qual Result RPD Limit Qual
120 118 3 25
Calculations are performed before rounding to avoid round -off errors in calculated results.
TestAmerica Savannah Page 15 of 19

Client CSX Transportation
Method Blank -Batch: 680-155262
Lab Sample ID:
MB 680-155262/2
Analysis Batch: 680-155262
Client Matrix:
Water
Prep Batch: N/A
Dilution:
1.0
Units: mglL
Date Analyzed:
12/02/2009 1243
Date Prepared:
N/A
Analyte Result
Total Oraanic Carbon 1.0
Lab Control Sample - Batch: 680.155262
Lab Sample ID:
LCS 680-15526214
Analysis Batch: 680-155262
Client Matrix:
Water
Prep Batch: N/A
Dilution:
1.0
Units: mg/L
Date Analyzed:
12/02/2009 1317
Date Prepared:
WA
Analyte Spike Amount Result
Total Organic Carbon 20.0 19.1
Matrix Spike/
Matrix Spike Duplicate Recovery Report - Batch: 680.155262
MS Lab Sample ID: 680-52940-1
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:"
12/02/2009 1357
Date Prepared:
N/A
MSD Lab Sample ID: 680-52940-1
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
12/02/2009 1413
Dale Prepared:
NIA
Analyte
Total Organic
Analysis Batch: 680-155262
Prep Batch: WA
Analysis Batch: 680-155262
Prep Batch: N/A
Quality Control Results
Job Number. 680-52940-1
Method: SM 5310B
Preparation: NIA
Instrument ID: Total Organic Carbon Analyze
Lab File ID: N/A
Initial Weight/Volume: 25 mL
Final Weight/Volume: 25 mL
Qual MDL RL
U 0.50 1.0
Method: SM 5310B
Preparation: NIA
Instrument ID: Total Organic Carbon Analyze
Lab File ID: N/A
Initial WeighWolume: 25 mL
Final Weight/Volume: 25 mL
%Rec. Limit Qual
95 80 - 120
Method: SM 5310B
Preparation: N/A
Instrument ID: Total Organic Carbon
Lab File ID: N/A
Initial Weight/Volume: 25 mL
Final WeighWolume: 25 mL
Instrument ID: Total Organic Carbon Analyze
Lab File ID: WA
Initial WeighWolume: 25 mL
Final WeighWolume: 25 mL
°/sec
MS MSD Limit RPD RPD Limit
95 91 Bo - 120 2 25
Calculations are performed before rounding to avoid round -off errors in calculated results.
TestAmerlca Savannah Page 16 of 19
MS Qual MSD Qual

LABORATORY INFORMATION
C_OC N
4 35430.4 F:912-952-M65
❑Taulancelot North anton-4
CHAIN OF
HShueAwnue. W.North. anion. 4720
I]Tesmmeraa North Canton-4lm Shull4l Drive raY, None Camon, OH 44720 P:33a-997-9398 F:330-/97-0772.
❑TestAmelira Tampa- 6712 Benjamin And. Suite IGO, Tampa, R-33634 P:8134185-7427 F:813-685.7049
SHIPMENT INFORMATION
Shlpmem Method:
CUSTODY
❑79s1ArneritaPermcala-3355McLemoreorira.Pere wt&FL32514. P-850-474-1001 F:850-478.2671
2� �y
❑ TeWoerin Sulfate- 10 Hazelwood Brin. Sage In, Amherst. NY 14228 P:716E91-2600 F:716.961-7991
Shipment Trucking No:
'
p reauuntilo, Chlow -2417 Bond Street UMwmsiy Park, A. GMS P:709-534.5200 F. 708-534-5211
CSXT PROJ14CT INFORMATION Pro" smto lSlale of Drgln)
CONSULTANT INFORMATION Project a"
CSXT Project Number: �- /1 1'� Prof. City;
F�
Company: PM:
CSxT Project Name: —
FA- I
Address: Emmt
CSXT Conumt
/c— C
Ciy. Stale, Lp: - Phonex: : Fa
TumeroundTime: ❑ Standard 6-13 Days
"Preservative Codes: 3 = Sulfuric Acid Note ar
3
COMMENTS
LAB USE
❑ 1 Day Rush d Days
0 = No Preservatives 4 = Sodium Thiosulfate Pres.
METHODS
FOR ANALYSIS
,--,/aoecif
❑ 2 Day Rush hT Standard 14 Days
1 = Hydrochloric Acid 5 = Sodium Hydroxide Code
❑ 3 Day Rush ❑ Other
2 = Nitric Add 6 = Other
�1
d
Deliverables: ❑ Other Doliv:
Matrix Codes: SO Soil LID = Liquid
❑ csxrstandard(Love] 11)
❑ Level lit ❑ EDD Required, Formal:
GW=Groundwater SL=Sludge
W W = Waste Water CI = Oil
Q
M
Level IV
SW=Surface Water SOL=01her Solid
SAMPLE INFORMATION
�
Containers
a
Collection
Filtered
T e
Matrix
Number&
Date
Time
Sampler
YorN
Comp
Code
Sample ldentifitalion
Type
or Grab
rk On"
oa -'X
z a9
000(11
0
C l -QSSo I=d a
g
2 9
0°O
�3 e
3
t41 1 c
Raerpuithed BY:
Dale/Rmo:
Re - B
Dflle7rime:
gam,
CmSFpa•l"raV gOE.�MARK9
ReOnquislRd By:
Data7Tima:
cebepay:
Relinquished By:
De[erRme:
Receke.M BY
Deteziane:
Received By Labor8lory.
Dated-rme:
Lab Remarks:
LABUSE: Custodylntact
Custody Seals
LAB og mbar_
❑Yes ❑No
0
a
aNvntnF MII-ST RF SI IRMrrWD
TO CSXT WITH ORIGINAL
COC TAL-6003(0509)
ORIGINAL - RETURN TO LABOKAI URI'

Login Sample Receipt Check List
Client: CSX Transportation
Login Number: 62940
Creator: Daughtry, Bath
List Number. 1
Question
T I F/ NA Comment
Radioactivity either was not measured or, if measured, is at or below
NIA
background
The coolers custody seal, If present, is intact.
True
The cooler or samples do not appear to have been compromised or
True
tampered.with.
Samples were received on ice.
True
Cooler Temperature is acceptable.
True
Cooler Temperature is recorded.
True
COC is present.
True
COC Is filled out in ink and legible.
True
COC is filled out with all pertinent information.
True
There are no discrepancies between the sample Do on the containers and
True
the COC.
Samples are received within Holding Time.
True
Sample containers have legible labels.
True
Containers are not broken or leaking.
True
Sample collection date/limes are provided.
True
Appropriate sample containers are used.
True
Sample bottles are completely filled.
True
There is sufficient vol. for all requested analyses, inch any requested
True
MS/MSDs
VOA sample vials do not have headspace or bubble is <6mm (1/4") in
N/A
diameter.
If necessary, staff have been informed of any short hold time or quick TAT
True
needs
Multiphasic samples are not present.
N/A
Samples do not require splitting or compositing.
N/A
Is the Field Samplers name present on COC?
False
Sample Preservation Verified
True
Job Number. 680-52940-1
List Source: TestAmerica Savannah
TestAmerica Savannah
Page 18 of 19

Login Sample Receipt Check List
Client: CSX Transportation
Login Number: 52940
Creator: Chas, Vanda
List Number. 1
Radioactivity either was not measured or, if measured, is at or below
background _
The cooler's custody seal, if present, is intact.
The cooler or samples do not appear to have been compromised or
tampered with.
Samples were received on lee.
Cooler Temperature is acceptable:
Cooler Temperature is recorded.
COC is present.
COC is filled out in Ink and legible.
COC is filled out with all pertinent information.
There areno discrepancies between the sample Me on the containers. and
the COC.
Samples are received within Holding Time.
Sample containers'have legible labels.
Containers are not broken or leaking.
Sample collectiondate/fimes are provided.
Appropriate sample containers are used.
Sample bottles are completely filled.
There is sufficient vol. for all requested analyses, Incl. any requested
MS/MSDs
VOA sample vials do not have headspace or bubble is <6mm (1/4") in
diameter. '
If necessary, staff have been informed of any short hold time or quick TAT
needs
Multiphasic samples. are not present.
Samples do not require splitting or compositing.
Is the Feld Samplers name present on COC?
Sample Preservation.Vedfied
T/F/NA
WA
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
N/A
True
True
True
True
True
Comment
0.0°C
Job Number 680-52940-1
List Source: TestAmerica Pensacola
List Creation: 12119109 02:26 PM
TestAmerlca Savannah
Page 19 of 19

TestAmedca
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Job Number: 680-52940-1 .
Job Description: CSX Hamlet, NC WWTP Monthly
` For:
CSX Transportation
500 Water Street
Jacksonville, FL 32202
Attention: Mr. Mike Gregory ,
�Y1/�-I, lr1 NaN,M6miN
IM IMM.1l
fY182pCB i61i AM
Kathryn Smith
Project Manager I
[e-mail]
12/29/2009
cc: Mr. Jerry Cato
Mr. Alan Pinnix
L W O N-E N V0000027258//Project-R000011790
The test results in this report meet NELAP requirements for parameters for which accreditation is required or available.
Any exceptions to the NELAP requirements are noted. Results pertain only to samples listed in this report. This report
may not be reproduced, except in full, without the written approval of the laboratory. Questions should be directed to the
person who signed this report.
Savannah Certifications and ID #s: A21-A: 0399.01; AL: 41450; ARDEQ: 88-0692; ARDOH; CA: 03217CA; CO; CT:
PHO161; DE; FL: E87052; GA: 803; Guam; HI; IL: 200022; IN; IA: 353; KS: E-10322; KY EPPC: 90084; KY UST; LA
DEQ: 30690; LA DHH: LA080008; ME: 2008022; MD: 250; MA: M-GA006; MI: 9925; MS; NFESC: 249; NV: GAOOOOL:
NJ: GA769; NM; NY: 10842; NC DWQ: 269; NC DHHS: 13701; PA: 68-00474; PR: GA00006; RI: LA000244; SC:
98001001; TN: TN0296; TX: T104704185; USEPA: GA00006; VT: VT-87052; VA: 00302; WA; WV DEP: 094; WV
DHHR: 9950 C; WI DNR: 999819810; WY/EPAR8: 8TMS-Q
TestAmerica Laboratories, Inc. C,e Acecgo
TestAmerica Savannah 6102 LaRoche Avenue, Savannah, GA 31404 d�E
W
Tel [phone] Fax [phone] ywnv.testamericainc com
R
Page 1 of 19

Job Narrative
680-62940.1
Comments
No additional comments
Receipt
All samples were received in good condition within temperature requirements
Metals
No analytical or quality issues were noted.
General Chemistry
No analytical or quality issues were noted.
Page 2 of 19

METHOD SUMMARY
Client: CSXTransportation
Job Number.. 680-52940-1
Description
Lab Location
Method
Preparation Method
Matrix Water
"
Metals (ICP)
TAL SAV
40CFR136A 200.7 Rev 4.4 "
Sample Filtration, Feld
TAL SAV
FIELD_FLTRD
Preparation, Total Metals
TAL SAV
EPA 200.7
. Preparation, Total Recoverable Metals
TAL SAV
-EPA 200.7 ..
Nitrogen, Nitrate-Nddte
TAL PEN
MCAWW 353.2
. -
Solids, Total Dissolved (TDS)
TAL SAV
SM SM 2540C
Organic Carbon, Total (TOC)
TAL SAV
SM SM 5310B
'
Lab References: -
TAL PEN = TestAmerica Pensacola
TAL SAV = TestAmerica Savannah
Method References: -
40CFR136A = "Methods for Organic Chemical Analysis of Municipal Industrial Wastewater', 40CFR, Part 136,.Appendix A,
October 26, 1984 and subsequent revisions.
EPA = US Environmental Protection Agency
MCAWW = "Methods For Chemical Analysis Of Water And Wastes", EPA-600/4.79-020, March 1983 And Subsequent Revisions.
SM = "Standard Methods For The Examination Of Water And Wastewater",
b
TestAmerlea Savannah
a
Page 3 of 19

METHOD/ANALYST SUMMARY
Client: CSX Transportation
Job Number. 680-52940-1
Method Analvst Analyst ID
40CFR136A 200.7 Rev 4.4 Bland, Brian BCB
MCAWW 353.2 Gimlin, Wendy WG
SM SM 2540C Jackson, Michelle S MSJ
SM SM 5310B Blackshear, Kim KB
TestAmerlea Savannah
e
Page 4 of 19

SAMPLE SUMMARY
Client: CSX Transportation Job Number. 68D-52940-1
Datelrime DateTme
Lab Sample ID Client Sample ID Client Matrix Sampled Received
680-52940-1 WWTP Sample , _ Water 11/23/2009 1000 11/24/2009 1020
TestAmerica Savannah
J
Page 5 of 19

9
Client: CSX Transportation
Client Sample ID: W WTP Sample.
Analytical Data
Job Number: 680-52940-1
Lab Sample ID: 680-52940-1 Date Sampled: 11/23/2009 1000
Client Matrix: Water Dale Received: 11/24/2009 1020
200.7 Rev 4.4 Metals (ICP)
Method:
200.7 Rev 4.4
Analysis Balch: 680-154811
Instrument ID:
ICPD
Preparation:
200.7
Prep Batch: 680-154566
Lab File ID:
N/A
Dilution:
1.0
Initial Weight/Volume:
50 mL -
Date Analyzed:
11/27/2009 1314
Final WeighWolume:
50 mL
Date Prepared:
11/2512009 0838
Analyte
Result (ug/L)
Qualifier
MDL
RL
Arsenic
20
U
4.6
20
Barium
18
2.3
10
Cadmium
5.0
U
2.0
5.0
Chromium
10
U
1.2
10
Lead
10 _
U
4.0
10
200.7 Rev 4.4 Metals (ICP)-Dlssolved
Method:
200.7 Rev 4.4
Analysis Batch: 680-164811
Instrument ID:
ICPD
Preparation:
200.7
Prep Batch: 68D-154562
Lab File ID:
WA
Dilution:
1.0
Initial Weight/Volume:
50 mL
Date Analyzed:
11127/2009 1055
Final WeighWolume:
50 mL
Date Prepared:
11/2512009 0821
Analyte
Result (ug1L)
Qualifier
MDL
RL
Arsenic
20
U
10
20
Barium
19
2.0
10
Cadmium
5.0
U
2.0
5.0
Chromium
10
U
2.0
10
Lead
10
U
3.4
10
TestAmeriea Savannah Page 6 of 19

a
Client: CSX.Transportation
Client Sample ID:
Lab Sample ID:
Client Matrix:
W WTP Sample
General Chemistry
Analytical Data
Job Number. 660-52940-1
Date Sampled: 11/23/2009 1000
Date Received: 11124/2009 1020
Analyte Result Dual Units -MDL RL Dil Method
Nitrate as N 1.2 - mg/L , 0.030 0.050 - 1.0 353.2
Analysis Batch: 400-101232 Date Analyzed: 12/21/20091230 _
Total Organic Carbon 9.5 mg/L 0.50 1.0 1.0 SM5310B
Analysis Batch: 680455262 Date Analyzed: 12/02/2009 1340 '
680-52940-1
Water
Analyte, Result Qua[ Units - RL RL Dil Method
Total Dissolved Solids 120 mg/L 5.0 5.0 1.0 SM 2640C
Analysis Batch: 680-154506 Date Analyzed: 11/24/2009 1347
TestAmerica Savannah . Page 7 of 19

DATA REPORTING QUALIFIERS
Client: CSX Transportation
Lab Section Qualifier Description
Metals
General Chemistry
TestAmerlca Savannah
Job Number. 680-52940-1
Indicates the analyte was analyzed for but not detected.
Indicates the analyte was analyzed for but not detected.
Page 8 of 19

Client: CSX Transportation
Method Blank -Batch: 680-164662
Lab Sample ID:
MB 680-154562/4-A
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
11/27/2009 1019
Date Prepared:
11/25/2009 0821
Analysts Batch: 680-154811
Prep Batch: 680-154562
Units: ug/L _
Quality Control Results
Job Number. 680-52940-1
Method: 200.7 Rev 4A
Preparation: 200.7
Total Recoverable
Instrument ID: ICP/AES - D
Lab File ID: N/A
Initial WeighWolume: 50 mL
Final Weight/Volume: 50 mL
Analyte Result Dual MDL RL
Arsenic
20
U
10
20
Barium
10
U
_
2.0
'10
Cadmium
5.0
U
2.0
5.0
Chromium
10
U
2.0
10
Lead
10
U
3.4
-10
Lab Control Sample - Batch: 680-164662
Method: 200.7 Rev 4.4
Preparation: 200.7
..
,,
Total Recoverable
^
Lab Sample ID:
LCS 680-15456215-A
Analysis Batch:
680-154811
Instrument ID: ICP/AES - D
Client Matrix:
Water
Prep Batch: 680-154562
Lab File ID: N/A
Dilution:
1.0
Units: -ug/L
Inhial Weight/Volume:
50 mL
Date Analyzed:
11/27/2009 1024
Final Weight/Volume:
50 mL
Date Prepared:
11/25/2009 0821'
Analyte
Spike Amount
Result
% Rem Limit
Qual
Arsenic
2000
2090
105.
85-115
Barium
2000
2110
105
85-115
Cadmium
50.0
53.3
107
85 -115
Chromium
200
209
105
85 -115
Lead
500
521
104
85-115
Calculations are performed before rounding to avoid round -off errors in calculated results.;
TestAmedca Savannah Page 9 of-19

Client CSX Transportation
Matrix Spike/
Matrix Spike Duplicate Recovery Report- Batch: 680-164662
MS Lab Sample ID:
680-52907-C-1-13 MS
Analysis Batch: 680-154811
Client Matrix:
Water
Prep Batch: 680-1 W62
Dilution:
1.0
Date Analyzed:
11/27/2009 1045
Date Prepared:
1125/2009 0821
MSD Lab Sample ID:
680.52907-C-1-C MSD
Analysis Batch: 680-154811
Client Matrix:
Water
Prep Batch: 680-164562
Dilution:
1.0
Date Analyzed:
1127/2009 1050
Dale Prepared:
11/25/2009 0821
Analyte
% Rec.
MS MSD Limit
Quality Control Results
Job Number. 680-52940-1
Method: 200.7 Rev 4.4
Preparation: 200.7
Total Recoverable
Instrument ID: ICP/AES - D
Lab File ID: N/A
Initial WeighWolume: 50 mL
Final WeighWolume: 50 mL
Instrument ID: ICP/AES - D
Lab File ID: N/A
Initial WeighWolume: 50 mL
Final WeighWolume: 50 mL
RPD RPD Limit MS Qual MSD Qual
Arsenic
107
107
75-125
0
20
Barium
107
107
75-125
0
20
Cadmium
106
106
75 - 125
0
20
Chromium
106
105
75 - 125
0
20
' Lead
106
104
75 -125
2
20
Calculations are performed before rounding to avoid round -off errors in calculated results.
TestAmerica Savannah Page 10 of 19

Client: CSX Transportation -
Method Blank - Batch: 680-164566
Lab Sample ID:
• MB 680-154566111-A
Client Matrix:
Water
Dilution:
1.0 - -
Dale Analyzed:
11/27/2009 1259
Date Prepared:
11/252009 0838
Analyle
Arsenic
Barium
Cadmium
Chromium
Lead
Lab Control Sample - Batch: 680-164566
Lab Sample ID:
LCS 680-154666/12-A
Client Matrix:
Water
Dilution: '
1.0 -
Date Analyzed:
11/272009 1304
Date Prepared:
. 11/252009 0838
Analyte
Analysis Batch: 680-154811
Prep Batch: 680-154566
Units: ug/L
Result
20
10
5.0
10
10
Analysis. Batch: 680-154811
Prep Batch: 680-154566
Units: ug/L
Quality Control Results
Job Number. 68D-52940-1
Method: 200.7 Rev 4A
Preparation: 200.7
Instrument ID: :ICP/AES - D
Lab File ID: WA
Initial Weight/Volume:• 50 mL
Final WeighWolume: 50 mL .
Dual
MDL
RL
U
4.6
20
U
2.3
10
U
2.0:.
5.0
U
1.2
10
U
4.0
10
Method: 200.7 Rev 4A
Preparation: 200.7
Instrument ID: ICP/AES -D
Lab File ID: N/A
Initial WeighWolume:
50 * mL
Final WeighWolume:
50 mL
Spike Amount Result % Rec. Limit
Arsenic
2000
2080
104
85 - 115
Barium
2000
2140
107
85--115
Cadmium
50.0
54.3
109
85.-115
Chromium
200
210
105
85-115
Lead
500
524
105
85-115
Calculations are performed before rounding to avoid round -off errors In calculated results.
TestAmerlea Savannah Page 11 of 19
Qual

Client: CSX Transportation
Matrix Spike/
Matrix Spike Duplicate Recovery Report- Batch: 680.154566
MS Lab Sample ID:
680-52894-F-1-B MS
Analysis Batch: 680-154811
Client Matrix:
Water
Prep Batch: 680-154566
Dilution:
1.0
-
Date Analyzed:
11/27/2009 1418
Date Prepared:
11125/2009 0838
MSD Lab Sample ID:
680-52894-F-1-C MSD
Analysis Batch: 680-154811
Client Matrix:
Water
Prep Batch: 680-154566
Dilution:
1.0
Date Analyzed:
11/2712009 1423
Date Prepared:
11/25/2009 0838
Analyte
% Rec.
MS MSD Limit
Quality Control Results
Job Number. 680-52940-1
Method: 200.7 Rev 4.4
Preparation: 200.7
Instrument ID: ICP/AES -D
Lab File ID: WA
Initial WeighWolume: 50 mL
Final WeighWolume: 50 mL
Instrument ID: ICPIAES - D
Lab File ID: WA
Initial Weight/Volume: 50 mL
Final WeighWolume: 50 mL
RPD RPD Limit MS Qual MSD Qual
Arsenic
107
106
75 - 125
1
20
Barium .
110
110
75 - 125
1
20
Cadmium
112
111
75 - 125
0
20
Chromium
108
107
75-125
1
20
Lead
107
107
75 -125
0
20
Calculations are performed before rounding to avoid round -off errors in calculated results.
TestAmerlca Savannah Page 12 of 19

Quality Control Results
Client: CSX Transportation Job Number. 680-52940-1
Method Blank- Batch: 400.101232
Method:353.2
`
Preparation: NIA
Lab Sample ID:
MB 400-10123211
Analysis Batch: 400-101232
Instrument ID: Lachat 1
Client Matrix:
Water
Prep Batch: WA -
Lab File ID: N/A
Dilution: ,
1.0 - -
Units: mg/L
Initial WeighWolume: 1.0
mL
Date Analyzed:
12/21/2009 1230
Final WelghtfVolume: 1.0
mL '
Date Prepared:
WA
Analyte
Result Qual
MDL
RL
Nitrate asN ,
0.050 U
_ 0.030 0.050
Lab Control Sample - Batch: 400-101232
.
- Method: 353.2
--'
Preparation: NIA
Lab Sample ID:
LCS 400-101232/2 - -
Analysis Batch: 400-101232
Instrument ID: Lachat 1
Client Matrix:
Water -
Prep Batch: N/A
Lab File ID: WA
Dilution:
1.0 . ,
Units: mg/L
Initial Weight/Volume: 1.0
mL '
Dale Analyzed:
12/21/2009 1230
Final WeighWolume: 10
mL
Date Prepared: WA
Analyte Spike Amount Result %Rea Limit • Qual
Nitrate Nitrite as N 0.500 0.515 103 90 - 110
Calculations are performed before rounding to avoid round -off errors in calculated results.
TeatAmerlca Savannah Page 13 of 19

Client: CSX Transportation
Method Blank - Batch: 680-IW06
Lab Sample ID:
MB 680-154506/1
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
11/24/2009 1347
Date Prepared:
WA
Analysis Batch: 680-154606
Prep Batch: N/A
Units: mg/L
Quality Control'Results
Job Number. 68D-52940-1
Method: SM 2540C
Preparation: N/A
Instrument ID: No Equipment Assigned
Lab File ID: WA
Initial Weight/Volume: 100 mL
Final WeighWalume: 100 mL
Analyte
Result Qual
RL
RL
Total Dissolved Solids
5.0 U
5.0
5.0
Lab Control Sample/
Method: SM 2640C
Lab Control Sample Duplicate Recovery Report -Batch: 680-164506
Preparation: WA
LCS Lab Sample ID: LCS 680-154506/2
Analysis Batch: 680-154506
Instrument ID: No Equipment Assigned
Client Matdx: Water
Prep Batch: N/A
Lab File ID: N/A
Dilution: 1.0
Units: mg/L
Initial Weight/Volume:
100 mL
Date Analyzed: 11/24/2009 1347
Final Weight/Volume:
100 mL
Date Prepared: WA
LCSD Lab Sample ID: LCSD 680-154506/3 Analysis Batch: 680-154506
Client Matrix: Water Prep Batch: NIA
Dilution: 1.0 Units: mg/L
Date Analyzed: 11/24/2009 1347
Dale Prepared: N/A
Analyte
°Rec.
LCS LCSD Limit
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial Weight/Volume: 100 mL
Final Weight/Volume: 100 mL
RPD RPD Limit LCS Qual LCSD Qual
Total Dissolved Solids 81 85 80 - 120 5 25
Calculations are performed before rounding to avoid round -off errors in calculated results.
TestAmerlca Savannah Page 14 of 19

Quality Control Results
Client CSX Transportation Job Number. 680-52940-1
Duplicate - Batch: 680-154606
Method: SM 2640C
- Preparation: N/A
Lab Sample ID: 680-52940-1
- Analysis.Batch: 680-154506
InstrumentID: No Equipment Assigned
Client Matrix: Water
Prep Batch: NIA
'Lab File ID: N/A
DiluBon: 1.0
Units: mg/L
Initial WeightlVolume: 100 mL
Date Analyzed: 11/24/2009 1347
Final WeighWolume: 100 mL ."
Date Prepared: N/A
Analyte
Sample Result/Qual - Result
RPD. Limit Qual
Total Dissolved Solids
120 118
3 25
Calculations are performed before rounding to avoid round -off errors in calculated results:
TestAmerlce Savannah Page 15 of 19

Client: CSX Transportation
Method Blank - Batch: 680-155262
Lab Sample ID:
MB 680-15526212
Analysis Batch: 680-155262
Client Matrix:
Water
Prep Batch: WA
Dilution:
1.0
Units: mglL-
Date Analyzed:
12/02/2009 1243
Date Prepared:
NIA
Analyte Result
Total Organic Carbon
Lab Control Sample - Batch: 680.155262
Lab Sample ID:
LCS 680-15526214
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
1210212009 1317
Date Prepared:
N/A
Analyte
1.0
Analysis Batch: 680-155262
Prep Batch: NIA
Units: mg/L
Spike Amount Result
Total Organic Carbon 20.0 19.1
Matrix Spike/
Matrix Spike Duplicate Recovery Report - Batch: 680-155262
MS Lab Sample ID:
680-52940-1 Analysis Balch: 680-155262
Client Matrix:
Water Prep Batch: N/A
Dilution:
1.0
Date Analyzed:
12/02/2009 1357
Date Prepared:
N/A -
Quality Control Results
Job Number. 680-52940-1
Method: SM 5310B
Preparation: NIA
InstrumenllD: Total Organic Carbon Analyze
Lab File ID: N/A
Initial WeighWolume: 25 mL
Final WeighWolume: 25 mL
Qual MDL RL
U 0.50 1.0
Method: SM 6310B
Preparation: N/A
Instrument ID: Total Organic Carbon Analyze
Lab File ID: NIA
Initial Weight/Volume: 25 mL
Final WeighWolume: 25 mL
% Rec. Limit Qual
95 80 -120
Method: SM 5310B
Preparation: NIA
Instrument ID: Total Organic Carbon
Lab File ID: N/A
Initial WeighWolume: 25 mL
Final WeighWolume: 25 mL
MSD Lab Sample ID:
680-52940-1
Analysis Batch: 680-155262
Instrument ID: Total Organic Carbon Analyze
Client Matrix:
Water
Prep Batch: N/A
Lab File ID: NIA
Dilution:
1.0
Initial WeighWolume: 25 mL
Date Analyzed:
12/02/2009 1413
Final WeighWolume: 25 mL
Date Prepared:
WA
% Rec.
Analyte
MS MSD Limit
RPD RPD Limit MS Qua[ MSD Qual
Total Organic Carbon 95 91 80 - 120 2 25
Calculations are performed before rounding to avoid round -off errors in calculated results.
TestAmerlce Savannah Page 16 0£ 19