NC0024392_Draft Review_20151009

DUKEDuke Energy
"2 ENERGY. McGuire Nuclear Station
` " 12700 Hagers Ferry Road
Huntersville,NC 28078
December 7, 2015
Mr. Jeff Poupart, Chief
Water Quality Permitting Section
NC DEQ Division of Water Resources
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
Subject: McGuire Nuclear Station RECEIVED/DENROWR
NPDES Permit No. NCO024392
Mecklenburg County DEC
• 9 2015
Certified Mail: 7010 2780 0000 7412 4397 Water Quality
Permitting Seatlon
Dear Mr. Poupart:
On June 3, 2015, the Division provided a draft NPDES permit for our review. In a letter to the
Division dated June 29, 2015, Duke Energy expressed concerns about several aspects of the
draft permit which included Thallium monitoring and effluent limitations.
As discussed with Division staff, additional.monitoring for Thallium has been conducted on both
the surface waters in the vicinity of the McGuire cooling water intake and the cooling water
discharge (Outfall 001). Intake samples were conducted as grab samples. Effluent samples
were initially sampled as grab samples (first two sampling events) but were sampled as
composite following consultation with the Division. All samples except one were split with a
certified external laboratory. A sampling location map and analytical results from both Duke
Energy and Pace Laboratory are included as enclosures. Table 1 is a summary of the analytical
results from the sampling activities.
Table 1 - McGuire Nuclear Station Thallium Analyses
Duke Laboratory Results Pace-Laboratory Results
Sample Report # Intake a- Sample Discharge, Sample: Intake Sample:. Discharge.. Sample
Date Result Type Result Type - Result -Type Result Type .
(ug/I) - (ugly) - (ug/0 ((g/0_"'' .
10/19/15 J15100454 <0.2 Grab <0.2 Grab <0.1 Grab <0.1 Grab
10/23/15 J15100546 <0.2 Grab <0.2 Grab
10/30/15 J15100693 <0 2 Grab <0.2 Composite <0.1 Grab <0.1 Composite
11/02/15 J15110007 <0 2 _ Grab <0.2 Composite <0.1 ' Grab <0.1 Composite
11/06/15 J15110120 <0.2 Grab <0.2 Composite <0.1 Grab <0.1 Composite
11/09/15 J15110147 <0.2 Grab <0.2 Composite <0.1 Grab <0.1 Composite
. - - - .._-
11/13/15 J15110283 <0.2 Grab <0.2 ; Composite <0.1 Grab Composite
- _ -
11/16h5 J15110284 <0.2 Grab <0.2_ Composite <0.1 Grab <0.1 Composite
11/20/15 J15110416 <6.2 j Grab _ <0'2j <0.1 Grab <0.1 Composite
- - - - - - - -
11/23/15 J15110441 <b Grab <0.2 Composite <0.1 Grab <0.1 i Composite
Based on these Thallium analytical results, we respectfully request that the proposed monitoring
and effluent limitations for Thallium be removed from the proposed permit. If the Division
believes that monitoring and/or an effluent limit for Thallium is necessary, Duke Energy would

appreciate the opportunity to meet with you and other appropriate staff to discuss this matter in
greater detail.
If you have any questions or wish to discuss this matter, please do not hesitate to contact Mr.
John Williamson, McGuire Nuclear Station Environmental Coordinator at [phone].
I certify, under penalty of law, that this document and all attachments were prepared under my
direct supervision in accordance with a system designed to assure that qualified personnel
properly gather and evaluate the information submitted. Based upon my inquiry of the person or
persons who manage the system, or those persons directly responsible for gathering the
information, the information submitted is, to the best of my knowledge and belief, true, accurate,
and complete. 1 am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations.
Sincerely,
:�tAo
i
Steven D. Capps
Duke Energy, McGuire Nuclear Station
Site Vice President
Enclosures
McGuire Thallium Sampling Location Map
Duke Energy and Pace Laboratory Analytical Reports
cc: Ms. Teresa Rodriguez, Environmental Engineer, NC DEQ DWR
Mr. John Williamson, Environmental Coordinator, McGuire Nuclear Station
Mr. Don Safrit, Senior Environmental Specialist, Permitting and Compliance, Carolinas

1
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��DUKE Analytical Laboratory APagtical of 17
ENERGY.
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex-MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Order Number: J15100454
Project Name: MCGUIRE-
Customer Name(s): BILL FORIS,JOSH QUINN
RECEIVEDIDENRIDWR
Customer Address: 13225 Hagers Ferry Rd
Mail Code: MG01CH DEC 0 9 2015
Huntersville,NC 28078-8985
Water Qual'
Lab Contact. Mary Ann Ogle Phone: [phone] Permitting`^""'On
/ Digitally signed by Mary
n„ 7rj OS Ann Ogle
Report Authorized By: /V/ Date.2015 70.28 13.50.59 Date: 10/28/2015
(Signature) ✓ oaoo
Mary Ann Ogle
Program Comments:
Please contact the Program Manager(Mary Ann Ogle)with any questions regarding this report.
Data Flags&Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis(sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative.An estimation of
the uncertainty of measurement for the results In the report is available upon request. This report shall not be reproduced,except
In full,without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions.The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package,Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets,Reports&
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody(COC)
Certification:
The Analytical Laboratory holds the following State Certifications: North Carolina(DENR)Certificate#248,South Carolina
(DHEC)Laboratory ID#99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Analytical Lab
Sample ID's & Descriptions: Page 2 of 17
Collection
Sample ID Plant/Station Date and Time Collected By Sample Description
2015034071 MCGUIRE 19-Oct-15 10.30 AM DAVID HORNE MNS Intake 0.3 M
2015034072 MCGUIRE 19-Oct-15 9:03 AM DAVID HORNE MNS Discharge(001)0.3 M
2 Total Samples
RECEIVEDIDENRIDWR
DEC 0 9 2015
Water Quaft
Permitting section

Analytical Lab
Page 3 of 17
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals F,/] Yes ❑ No
and analyses(compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes 0 No
All laboratory QA/QC requirements are acceptable. ❑� Yes F�'No
Report Sections Included:
W]Job Summary Report ❑d Sub-contracted Laboratory Results
Sample Identification ❑ Customer Specific Data Sheets,Reports,&Documentation
91 Technical Validation of Data Package ❑ Customer Database Entries
EV6 Analytical Laboratory Certificate of Analysis 91 Chain of Custody
❑Analytical Laboratory QC Report ❑ Electronic Data Deliverable(EDD)Sent Separatel
RECEIVEDIDENRIDWR
Reviewed By: Mary Ann Ogle Date: 10/28/2015 DEC 0 9 2015
Water Quality
Permitting Sectlon

Analytical Lab
Certificate of Laboratory Analysis Page 4 of 17
This report shall not be reproduced, except in full.
Order#A 5100454
Site: MNS Intake 0.3 M Sample#: 2015034071
Collection Date: 19-Oct-15,10:30 AM Matrix: NPDES
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
TOTAL RECOVERABLE METALS BY ICP-MS
Thallium(TI)Low Level <0.2 ug/L 0.2 1 EPA 200.8 10/20/2015 15:42 JAHERMA
METALS ANALYSIS BY VENDOR LAB-(Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Analytical Lab
Certificate of Laboratory Analysis Page 5 of 17
This report shall not be reproduced, except in full.
Order#A 5100454
Site: MNS Discharge(001)0.3 M Sample#: 2015034072
Collection Date: 19-Oct-15 9:03 AM Matrix: NPDES
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
TOTAL RECOVERABLE METALS BY ICP-MS
Thallium(TI)Low Level <0.2 ug/L 0.2 1 EPA 200.8 10/20/2015 16:03 JAHERMA
METALS ANALYSIS BY VENDOR LAB-fAnalysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Analytical Lab
Certificate of Laboratory Analysis Page 6 of 17
This report shall not be reproduced, except in full.
Order#A 5100454
Level II QC Summary
Q15100348 IMS_TRM TOTAL RECOVERABLE METALS BV ICP-MS
Blank #I
Parameter Measured Final Units- Dil RDL Relative Concentration Qualifier
Thallium(TI)Low Level 0.0039 0.0039 ug/L 1 0.2 <1/2 RDL
LCS #1
Parameter Measured Final Units: Dil Soike %Recovery LCL UCL Qualifier
Thallium(TI)Low Level 49.6 496 ug/L 1 50 99.2 85 115
MS #1 Parent Sample: J15100454 -- 2015034071
Parameter Measured Final Uni s: Dil Soike %Recovery LCL UCL Qualifier
Thallium(TI)Low Level 49.3 49.3 ug/L 1 50 98.5 70 130
MSD #1 Parent Sample: J15100454 -- 2015034071
Parameter Measured Final Units: Dil Soike %Recovery LCL UCL RPD Qualifier
Thallium(TI)Low Level 481 48.1 ug/L 1 50 96.1 70 130 2.47
1

Papna�VtWIftl tervices,Inc.
® ��Q�(i�c ,, . Suite loo
aceAnalytical Huntersville,NC 28078
wwwpacelabs.com [phone]
October 26, 2015
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
RE: Project: J15100454
Pace Project No.: 92272359
Dear Program Manager:
' Enclosed are the analytical results for sample(s) received by the laboratory on October 19, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
3
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Rodney Wike,Duke Energy
pccr
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc. Page 1 of 10
geORAtpQ,

Pa$nalyKtl�aFrabervlces,Inc.
® ��Q�(igc�� e Suite 100
aceAnalytical Huntersville,NC 28078
www pacefabs com [phone]
CERTIFICATIONS
Project, J15100454
Pace Project No.: 92272359
Minnesota Certification IDs
1700 Elm Street SE Suite 200,Minneapolis,MN 55414 Minnesota Certification#:027-053-137
A21-A Certification#:2926.01 Mississippi Certification#:Pace
Alaska Certification#:UST-078 Montana Certification#:MT0092
Alaska Certification#MN00064 Nevada Certification#:MN 00064
Alabama Certification#40770 Nebraska Certification#:Pace
Arizona Certification#:AZ-0014 New Jersey Certification#.MN-002
Arkansas Certification#:88-0680 New York Certification#:11647
California Certification#:01155CA North Carolina Certification#:530
Colorado Certification#Pace North Carolina State Public Health M 27700
Connecticut Certification#:PH-0256 North Dakota Certification#:R-036
EPA Region 8 Certification#:8TMS-L Ohio EPA#:4150
Florida/NELAP Certification#-E87605 Ohio VAP Certification#•CL101
Guam Certification#:14-008r Oklahoma Certification#•9507
Georgia Certification M 959 Oregon Certification#:MN200001
Georgia EPD M Pace Oregon Certification#:MN300001
Idaho Certification#:MN00064 Pennsylvania Certification M 68-00563
Hawaii Certification#MN00064 Puerto Rico Certification
Illinois Certification#:200011 Saipan(CNMI)*MP0003
Indiana Certification#C-MN-01 South Carolina#•74003001
Iowa Certification M 368 Texas Certification#.T104704192
Kansas Certification#:E-10167 Tennessee Certification#:02818
Kentucky Dept of Envi.Protection-DW#90062 Utah Certification#:MN000642013-4
Kentucky Dept of Envi.Protection-WW#:90062 Virginia DGS Certification#:251
Louisiana DEQ Certification#•3086 Washington Certification#:C486
Louisiana DHH#:LA140001 West Virginia Certification M 382
Maine Certification#:2013011 West Virginia DHHR#:9952C
Maryland Certification#:322 Wisconsin Certification#:999407970
Michigan DEPH Certification#:9909
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc. Page 2 of 10

Pamalyyti�aFrabervices,Inc.
® ��Q�;,4,,P . Suite 100
aceAnalytical Hunlersville,NC 28076
wwwpacelabs.com [phone]
SAMPLE ANALYTE COUNT
Project J15100454
Pace Project No.: 92272359
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92272359001 2015034071 EPA 200.8 TT3 1 PASI-M
92272359002 2015034072 EPA 200.8 TT3 1 PASI-M
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc. Page 3 of 10

Par A tl�aF�abervlces,Inc.
® 096 �I�b�l fr Suite 100
aceAnalytical y Huntersville,NC 28078
wwwpacelabs com [phone]
ANALYTICAL RESULTS
Project J15100454
Pace Project No.: 92272359
Sample: 2015034071 Lab ID: 92272359001 Collected: 10/19/15 1030 Received- 10/19/15 12:44 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
200.8 MET ICPMS Analytical Method:EPA 200 8 Preparation Method-EPA 200.8
Thallium ND ug/L 0.10 1 10/22/15 08 24 10/22/15 16:20 7440-28-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date-10/26/2015 02:46 PM without the written consent of Pace Analytical Services,Inc Page 4 of 10

Parr tl�aFEabervlces,Inc.
aceAnalytical® � ��`unters�e Suite 100
Huntersville,NC 28078
wwwpacelabs oom [phone]
ANALYTICAL RESULTS
Project J15100454
Pace Project No.. 92272359
Sample: 2015034072 Lab ID: 92272359002 Collected: 10/19/15 0903 Received. 10/19/15 12:44 Matrix. Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
200.8 MET ICPMS Analytical Method.EPA 200.8 Preparation Method.EPA 200.8
Thallium ND ug/L 0.10 1 10/22/15 08:24 10/22/15 16.36 7440-28-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:10/26/2015 02 46 PM without the written consent of Pace Analytical Services,Inc. Page 5 of 10

Pa�nal tl�el Labervices,Inc.
e fQ$Q�Ffli�4yy e. Suite 100
acmnalytical y Huntersville,NC 28078
www.pacefabs.com [phone]
QUALITY CONTROL DATA
Project J15100454
Pace Project No.: 92272359
QC Batch- MPRP/58932 Analysis Method- EPA 200.8
QC Batch Method. EPA 200.8 Analysis Description: 200.8 MET
Associated Lab Samples: 92272359001,92272359002
METHOD BLANK: 2113306 Matrix: Water
Associated Lab Samples: 92272359001,92272359002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Thallium ug/L ND 0.10 10/22/1516.04
LABORATORY CONTROL SAMPLE: 2113307
Spike LCS LCS %Rec
Parameter Units Conc Result %Rec Limits Qualifiers
Thallium ug/L 80 910 114 85-115
MATRIX SPIKE&MATRIX SPIKE DUPLICATE. 2113308 2113309
MS MSD
92272359001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Thallium ug/L ND 80 80 92.5 91.6 116 114 70-130 1
Results presented on this page are in the units Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date.10/26/2015 02:46 PM without the written consent of Pace Analytical Services,Inc.. Page 6 of 10

Pa�nal tWifribervices,Inc.
® op�g�,5%yf�1'e Suite 100
(�55'ceAnalytical y Huntersville,NC 28078
www pacelabs com [phone]
QUALIFIERS
Project: J15100454
Pace Project No.. 92272359
DEFINITIONS
DF-Dilution Factor,if reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit.
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL-Practical Quantitation Limit.
RL-Reporting Limit
S-Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is
a combined concentration
Consistent with EPA guidelines,unrounded data are displayed and havebeenused to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate `
RPD-Relative Percent Difference
NC-Not Calculable
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for,but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether,Styrene,and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute.
LABORATORIES
PASI-M Pace Analytical Services-Minneapolis
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:10/26/2015 02:46 PM without the written consent of Pace Analytical Services,Inc. Page 7 of 10

PamA tl�aF�abervlces,Inc.
® og$ q fli C&� ye. Suite 100
acmnalytical y Huntersville,NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project. J15100454
Pace Project No.. 92272359
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92272359001 2015034071 EPA 200.8 MPRP/58932 EPA 200.8 ICPM/27096
92272359002 2015034072 EPA 200.8 MPRP/58932 EPA 200.8 ICPM/27096
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:10/26/2015 02:46 PM without the written consent of Pace Analytical Services,Inc. Page 8 of 10

,P"weArralytical' Sample Condition Upon Receipt(SCUR Pa e'1 of 2*
Document Number: - Issuing Authoritynalytical Lab
F-CHR-CS-003-rev.16 . Pace Huntersville Qua ®fly 17
Client Name: Oil V\'e V 'Page 2 of 2 is for Internal Use Only l
Courter: _❑ Fed E)❑ UPC], USP❑ lierfl Commerci� Pac Other ` �" �t' �'
O tlorialr _ .;aYa•_ .'
x
Proji?Due`Date :,ti<:x
Custody Seal on Cooler/Box Present: yes ❑ no Seals Intact: yea ❑ no
-
Packing Material: ❑ Bubble Wrap ❑ Bubble BagsJQ None Other
Thermometer Used:IR Gun .T1402 Typ/e of Ice: Ve Blue-- None Samples on ice,cooling process has begun
Temp Correction Factor. T1402 No Correction
•C Biological Tissue Is frozen:,,Yes,No r Date and Initials q}.pers4�exa Hing i
Corrected Cooler Temp:: contents: J �('
Temp should be above freezing to 6°C -- Comments:,
Chain of Custody Present: a31 ONO ❑NIA 1. i
Chain of Custody Filled Out: res ONo ON/A 2.
Chain of Custody Relinquished: Idyes,ONo ON/A 3.
Sampler Name&Signature on COC: Yes ONo ONIA 4:
Samples Arrived within Hold Time: 9411 ONo ❑N/A 5.
Short Hold Time Analysis <72hr): DYes No ❑N/A 6. } }
Rush Turn Around Time Requested: OYes No ❑NIA 7: i
Sufficient Volume: j6Yes []No ONlA
i
Correct•Containers Used: )dYes',❑No ON/A g.
-Pace Containers Used: .ClYes ONo ON/A a
Containers Intact: Yes, ONo ON/A 10.
Filtered volume received for Dissolved tests es DNo ❑NIA 11.
Sample Labels match COC: RrYes ONo ON/A 12.
-Includes date/time/ID/Analysis Matrix:
All containers needing preservation have been checked.
Yes ONo ❑N!A 13.
K
All containers needing preservation are found to be In J�Yes ONo ❑NIA
compliance with EPA recommendation.
exceptions- VOA, oolilorm,TOC,O&G,WI-DRO(water) Oyes vfto
Samples checked for dechlorination: es ONo ON/A 14.
Headspace in VOA Vials(>6mm): 'DYes ❑NoA 15.
Trip Blank Present: OYes ONo N!A 16.
Trip Blank Custody Seals Present DYes ONo ONIA
Pace Trip Blank Lot#(if purchased):
Client Notification/Resolution: Field Data Required? Y 1 N
Person Contacted: Datelrime:
Comments/Resolution:
SCURF Review: Date: Jn /° r WO# -. 92272359.:
92272,359
/
SRF Review: Date:
Note: Whenever there isa discrepancy affecting North Carolina compliance 1111111111
samples,a copy of this form will be sent to the North Carolina DEHNR
Certification Office(Le out of hold,incorrect preservative,out of temp, 9227235e
incorrect containers) —

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Container Type NAPE F
Sample Description or ID
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LAB U31!ONLY collection Information
Location 9 Depth -4
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Date 1 Time Signature
MNS Intake 0.3 rn toliq1tii j0 c, eDAv.i) /6aggl
51n7 MNS Discharge(001) 0.3 m, X,
"A
0
0
0
0
0
0
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Relinquished By "7
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l�DUKE Analytical Laboratory Page 1 of 17
V ENERGY,,
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex-MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Order Number: J15100693
Project Name: MCGUIRE-
Customer Name(s), BILL FORIS,JOSH QUINN
Customer Address: 13225.Hagers Ferry Rd
Mail Code: MG01CH
Huntersville,NC 28078-8985
Lab Contact: Mary Ann Ogle Phone: [phone]
/� Digitally signed by Mary
yy� (9S("—AnnOgle
Report Authorized By: / / Date:2015.11.0911:27:10 Date: 11/9/2015
(Signature) ✓ soo
Mary Ann Ogle
Program Comments:
Please contact the Program Manager(Mary Ann Ogle)with any questions regarding this report.
Data Flags&Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis(sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative.An estimation of
the uncertainty of measurement for the results in the report Is available upon request.This report shall not be reproduced,except
in full,without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions.The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package,Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports&
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody(COC)
Certification:
The Analytical Laboratory holds the following State Certifications: North Carolina(DENR)Certificate#248,South Carolina
(DHEC)Laboratory ID#99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

r
Sample ID's & Descriptions: Page 2 of 17
Collection
Sample ID Plant/Station Date and Time Collected By Sample Description
2015035208 MCGUIRE 30-Oct-15 9:05 AM G.LONG MNS Intake 10M
2015035209 MCGUIRE 30-Oct-15 1008 AM G.LONG MNS Discharge(001)0.3 M
2 Total Samples

Page 3 of 17
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals ❑� Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. Yes ❑ No
All laboratory QA/QC requirements are acceptable. ❑v Yes ❑ No
Report Sections Included:
sel Job Summary Report ❑ Sub-contracted Laboratory Results
D Sample Identification ❑ Customer Specific Data Sheets,Reports,&Documentation
0lTechnical Validation of Data Package ❑ Customer Database Entries
Analytical Laboratory Certificate of Analysis ❑ Chain of Custody
❑Analytical Laboratory QC Report ❑ Electronic Data Deliverable(EDD)Sent Separatel
Reviewed By: Date, 11/9/2015

Certificate of Laboratory Analysis Page 4 of 17
This report shall not be reproduced, except in full.
Order#J15100693
Site: MNS Intake 10M Sample#: 2015035208
Collection Date: 30-Oct-15 9:05 AM Matrix: NPDES
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
TOTAL RECOVERABLE METALS BY ICP-MS
Thallium(TI)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/03/2015 04:48 JAHERMA
METALS ANALYSIS BY VENDOR LAB-(Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 5 of 17
This report shall not be reproduced, except in full.
Order#J15100693
Site: MNS Discharge(001)0.3 M Sample#: 2015035209
Collection Date: 30-Oct-15 10:08 AM Matrix. NPDES
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
TOTAL RECOVERABLE METALS BY ICP-MS
Thallium(TI)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/03/2015 04:27 JAHERMA
METALS ANALYSIS BY VENDOR LAB-(Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 6 of 17
This report shall not be reproduced, except in full.
Order#J15100693
Level II QC Summary
Q15110013 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank #1
Parameter Measured Final Units- Dil RDL Relative Concentration Qualifier
Thallium(TI)Low Level -0.0403 -0.0403 ug/L 1 02 <1/2 RDL -
LCS #1
Parameter Measured Final Units: Dil Sgike %Recovery LCL UCL Qualifier
Thallium(TI)Low Level 52.8 528 ug/L 1 50 106 85 115 -
MS #1 Parent Sample: J15100693 -- 2015035209
Parameter Measured Final Units: Dil Spike %Recovery LCL UCL Qualifier
Thallium(TI)Low Level 54.9 54.9 ug/L 1 50 110 70 130
MSD #1 Parent Sample: J15100693 -- 2015035209
Parameter Measured Final Units: Dil Spike %Recovery LCL UCL RPD Qualifier
Thallium(TI)Low Level 52.1 52.1 ug/L 1 50 104 70 130 524 -

Pace Analytical Services,Inc.
aceAnalytical o ��� '9 �e Suite 078
loo
Huntersville,NC 28078
www pacelabs com [phone]
November 06, 2015
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
RE: Project: J15100693
Pace Project No.: 92274191
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on October 30, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
r
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Rodney Wike,Duke Energy
pCCRF�i
REPORT OF LABORATORY ANALYSIS
r This report shall not be reproduced,except in full,
Qy
without the written consent of Pace Analytical Services,Inc Page 1 of 10
OBORA�

i Pace Analytical Services,Inc.
® 10$P g,gc8ty 0e Suite100
aceAnalytical Huntersville,NC 28078
www.pacelabs.com [phone]
CERTIFICATIONS
Project- J15100693
Pace Project No.. 92274191
Minnesota Certification IDs
1700 Elm Street SE Suite 200,Minneapolis,MN 55414 Minnesota Certification#.027-053-137
A21-A Certification#:2926.01 Mississippi Certification#:'Pace
Alaska Certification#:UST-078 Montana Certification#:MT0092
Alaska Certification#MN00064 Nevada Certification#:MN 00064
Alabama Certification#40770 Nebraska Certification#:Pace
Arizona Certification#:AZ-0014 New Jersey Certification#-MN-002
Arkansas Certification#-88-0680 New York Certification#:11647
California Certification#:01155CA North Carolina Certification#•530
Colorado Certification#Pace North Carolina State Public Health#:27700
Connecticut Certification#:PH-0256 North Dakota Certification#:R-036
EPA Region 8 Certification#:8TMS-L Ohio EPA#:4150
Florida/NELAP Certification# E87605 Ohio VAP Certification# CL101
Guam Certification#:14-008r Oklahoma Certification#.9507
Georgia Certification#:959 Oregon Certification#.MN200001
Georgia EPD#:Pace Oregon Certification#:MN300001
Idaho Certification#:MN00064 Pennsylvania Certification#•68-00563
Hawaii Certification#MN00064 Puerto Rico Certification
Illinois Certification#:200011 Saipan(CNMI)#:MP0003
Indiana Certification#C-MN-01 South Carolina#:74003001
Iowa Certification#.368 Texas Certification#:T104704192
Kansas Certification#.E-10167 Tennessee Certification#:02818
Kentucky Dept of Envi.Protection-DW#90062 Utah Certification#:MN000642013-4
Kentucky Dept of Envi.Protection-WW#:90062 Virginia DGS Certification#:251
Louisiana DEQ Certification#:3086 Washington Certification#:C486
Louisiana DHH#•LA140001 West Virginia Certification#•382
Maine Certification#:2013011 West Virginia DHHR#•9952C
Maryland Certification#:322 Wisconsin Certification#:999407970
Michigan DEPH Certification#:9909
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc.. Page 2 of 10

Pace Analytical Services,Inc.
e vgQ�(i�c�� ye. Suite 100
aceAnalytical Hunterswlle,NC 28078
www.pacelabs.com [phone]
SAMPLE ANALYTE COUNT
Project J15100693
Pace Project No.: 92274191
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92274191001 2015035208 EPA 200.8 TT3 1 PASI-M
92274191002 2015035209 EPA 200.8 TT3 1 PASI-M
RECEIVED/DENR/DWR
DEC 0 8 2015
Water Quality
Permitting Section
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc. Page 3 of 10

Pace Analytical Services,Inc.
® 095 'Bc8yfje Suite 100
aceAnalytical 9 Huntersville,NC 28078
www.pacela6scom [phone]
ANALYTICAL RESULTS
Project- J15100693
Pace Project No. 92274191
Sample: 2015035208 Lab ID: 92274191001 Collected: 10/30/15 09 05 Received- 10/30/15 14:38 Matrix- Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
200.8 MET ICPMS Analytical Method:EPA 200.8 Preparation Method:EPA 200.8
Thallium ND ug/L 0.10 1 -11/05/1511,42 11/06/1501:08 7440-28-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/06/2015 11:38 AM without the written consent of Pace Analytical Services,Inc. Page 4 of 10

Pace Analytical Services,Inc.
Q n ® 09Q9Kliicgy ye. Suite 100
an A! alytical �J Hunterswlle,NC 28078
www pacelabs com [phone]
ANALYTICAL RESULTS
Project. J15100693
Pace Project No.. 92274191
Sample: 2015035209 Lab ID: 92274191002 Collected, 10/30/15 10 08 Received: 10/30/15 14:38 Matrix Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
200.8 MET ICPMS Analytical Method:EPA 200.8 Preparation Method:EPA 200.8
Thallium ND ug/L 0.10 1 11/05/15 11.42 11/06/15 01.11 7440-28-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date.11/06/2015 11:38 AM without the written consent of Pace Analytical Services,Inc. Page 5 of 10

Pace Analytical Services,Inc.
(�15ceAnalytical® �$���i�ter�e Suite100
Hunterswlle,NC 28078078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: J15100693
Pace Project No.: 92274191
QC Batch- MPRP/59365 Analysis Method- EPA 200 8
QC Batch Method: EPA 200.8 Analysis Description: 200.8 MET
Associated Lab Samples: 92274191001,92274191002
METHOD BLANK: 2126108 Matrix- Water
Associated Lab Samples: 92274191001,92274191002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Thallium ug/L ND 0.10 11/06/15 00:36
LABORATORY CONTROL SAMPLE- 2126109
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Thallium ug/L 80 88.9 111 85-115
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2126110 2126111
MS MSD
92274246001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc Conc Result Result %Rec %Rec Limits RPD Qual
Thallium ug/L ND 80 80 88.4 91.2 111 114 70-130 3
Results presented on this page are in the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/06/2015 11:38 AM without the written consent of Pace Analytical Services,Inc Page 6 of 10

Pace Analytical Services,Inc.
o 0988 li�c&yfte Suite 100
(�Ia'neAnalytical 9 Huntersville,NC 28078
www.pacelabs com [phone]
QUALIFIERS
Project. J15100693
Pace Project No.: 92274191
DEFINITIONS
DF-Dilution Factor,if reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL-Practical Quantitation Limit.
RL-Reporting Limit.
S-Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is
a combined concentration.
Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-'Indicates the compound was analyzed for,but not detected.
Acid preservation may not be appropriate for 2 Chloroethylwnyl ether,Styrene,and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute.
LABORATORIES
PASI-M Pace Analytical Services-Minneapolis
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/06/2015 11:38 AM without the wntten consent of Pace Analytical Seances,Inc.. Page 7 of 10

Pace Analytical Services,Inc.
e 0$0�♦Sli�c&fte Suite 100
acmnalXical 9 Hunterswlle,NC 28078
www pacefabs com [phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J15100693
Pace Project No. 92274191
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92274191001 2015035208 EPA 200.8 MPRP/59365 EPA 200.8 ICPM/27338
92274191002 2015035209 EPA 200.8 MPRP/59365 EPA 200.8 ICPM/27338
f
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/06/2015 11:38 AM without the written consent of Pace Analytical Services,Inc. Page 8 of 10

Arl
KceAltalytrcol' Sample Condition U on^Recei t SCUR Pagel of 2" k
Document Number: Issuing Authority:
F-CHR-CS-003-rev.16 Pace Huntersville Quafl mad 17�
Client Name: C� Page 2 of 2 Is for Internal Use Only
Courier: ❑ Fed E>❑ UPC] USP❑ ClierOCo mercies ace Othertioiiah' •t=�"' ��-Y� " ''
Pj(oPM'LA'iDate
Custody Seal on Cooler/Box Present: Elyes � no Seals intact: El,-yes Elno
Packing Material: ❑ Bubble Wrap ❑ Bubble Bags None ❑ Other
Thermometer Used:IR Gun 1402 Type of Ic We Blue, None Samples on'ice,cooling process has begun
Temp Correction Factor T1402 o Correction j
p - Is T - V �Date,and Initials of son examining�
_Corrected Cooler Tem G! �C Biological Tissue is Frozen: Yes No Ad
contents: (7C!/ 1,..
Temp should be above freezing to 6°C Comments:,
Chain of Custody Present:, 0 es [IN. ON/A 1: s
Chain of Custody Filled Out: Yes 9No ❑NIA 2.
Chain of Custody Relinquished: es 0 N ❑NIA 3.
Sampler Name&Signature on COC: OJ es ONo ON/A 4. t
Samples Arrived within Hold Time: OYe ONo O - 5.
Short Hold Time Analysis <72hr: ❑Yes o /A 6. ' !
- i
Rush Turn Around Time Requested: ❑Yes O o ONIA 7. ; t
Sufficient Volume: Yes. QN.o ❑NIA 8.
Correct Containers Used: Yes;[]No ❑ IA 9.
-Pace Containers Used: Oyeso ❑NIA
r
Containers Intact: 1z Yes ONO ❑NfA 10.
Filtered volume received for Dissolved tests ❑Yes ONO 0 0/01
Sample Labels match COC: Yes ONO ❑NIA 12.
-Includes date/time/ID/Analysis Matrix:
All containers needing preservation have been checked. ❑ es No ❑WA 13.
All containers needing preservation are found to be in p es ❑No ❑NIA `
compliance with EPA recommendation.
exceptions* VOA, coliform,TOC,O&G,WI-DRO(water) ❑Yes
Samples checked for dechlorination: OYes ONO NIA 4•
Heads ace in VOA Vials >6mm : ❑Yes ONO NIA 15.
Trip Blank Present: ❑Yes ❑No A 16.
Trip Blank Custody Seals Present ❑Yes ONO ❑�tl
Pace Trip Blank Lot#(if urchased):
Client Notification/Resolution: Field Data Required? Y I N
Person Contacted: Date rime:
Comments/Resolution: ® `o
11l a -274191
SCURF Review: Date: IV3V IS
SRF Review: Date: I / 8227418!1
Note: Whenever there is a discrepancy affecting North Carolina compliance
samples,a copy of this form will be sent to the North Carolina DEHNR Hanum—
Certification Office(Le out of hold,incorrect preservative,out of temp,
(if no label available)
Incorrect containers)

O
16
'U5 ODY ==CORD AND:.?:,1.'!$i�= .'
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y YW CeYGe (BJgY.y Tree) ;Oroer tl /p trix-NPDES �iiip1iO,o„•,b�.. Nc_ SC— Pae_7—o1._-1_ DISTRIBUTION
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chain of Custody a n.r..mr.,rL G MY$ ;fatltl•e By' �/� Daa 6 ORIGINAL to LAB,COPY to CLIENT
sample 400 (ror)ars.sa . Fu• Dl„- . SAMPLE PROGRAM
_.___.—_.—._._._._._-._.:.-._.__ ._--._._-._.5��•.L°�?•.3a0"___._.-__._.: C~4 Wd NPOES
I }U: O4.k Water_ UST.— { �"``T.?P,'f'• =r r ' 3s+•'_+'u•1.:•
n..,c Norman Thallium xo-ays»w -.Fx"' RCRA Waa1•_ )-�A'•� „�� n-r ^ /�r��
1 -..1� tn1 aa s Cae1«T•31c1.._._.. ='4+,.w. .'u-_ ..`��,`OR
ca•c Bill Foris/Josh Quinn s.o Yo ®#rp■' 7��� _.._.._.._.._.___.. _.__.._.._.._.._.._—._.._.._._.._.._.._._.._.._.._.._._.._._.._._.._.._.._. `
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ContainerTypo NOPE
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LAB USE oYL I Location 9 Depth Cdbctionlnlc m tion ¢ S o
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t'
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14 Days .
I Date rime Accepted Daterrims / _
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NNFNr
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' Page 17 of 17
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' S
4016 Analytical Laboratory Page 1 of 17
ENERGY,
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex- MG03A2
Phone:[phone] Fax: [phone]
Order Summary Report
Order Number: J15110007
Project Name: MCGUIRE-
Customer Name(s): BILL FORIS,JOSH QUINN
Customer Address: 13225 Hagers Ferry Rd
Mail Code: MG01CH
Huntersville,NC 28078-8985
Lab Contact- Mary Ann Ogle Phone- 980-875-5274
t,��� Digitally signed by Mary
Ann Ogle
Report Authorized By: / Date.
2015.11 0912.10.51 Date: 11/9/2015
(Signature) -05'00'
Mary Ann Ogle
Program Comments:
Please contact the Program Manager(Mary Ann Ogle)with any questions regarding this report.
Data Flags&Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis(sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
Included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described In this narrative.An estimation of
the uncertainty of measurement for the results in the report is available upon request.This report shall not be reproduced,except
in full,without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions.The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package,Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports&
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody(COC)
Certification:
The Analytical Laboratory holds the following State Certifications: North Carolina (DENR)Certificate#248,South Carolina
(DHEC)Laboratory ID#99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's $ Descriptions: Page 2 of 17
Collection
Sample ID Plant/Station Date and Time Collected By Sample Description
2015035287 MCGUIRE 02-Nov-15 8:07 AM G.LONG MNS Intake 10M
2015035288 MCGUIRE 02-Nov-15 9:04 AM G.LONG MNS Discharge(001)0.3 M
2 Total Samples

Page 3 of 17
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals 0 Yes F1 No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. F-1 Yes No
All laboratory QA/QC requirements are acceptable. Yes No
Report Sections Included:
Job Summary Report ❑ Sub-contracted Laboratory Results
Sample Identification ❑ Customer Specific Data Sheets,Reports,&Documentation
❑Technical Validation of Data Package ❑ Customer Database Entries
❑Analytical Laboratory Certificate of Analysis Chain of Custody
❑Analytical Laboratory QC Report Electronic Data Deliverable(EDD)Sent Separatel
Reviewed By Date: 11/9/2015

Certificate of Laboratory Analysis Page 4 of 17
This report shall not be reproduced, except in full.
Order#J15110007
Site: MNS Intake 10M Sample#: 2015035287
Collection Date: 02-Nov-15 8:07 AM Matrix: NPDES
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
TOTAL RECOVERABLE METALS BY ICP-MS
Thallium(TI)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/03/2015 16:57 JAHERMA
METALS ANALYSIS BY VENDOR LAB-(Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 5 of 17
This report shall not be reproduced, except in full.
Order#A 5110007
Site: MINIS Discharge(001)0.3 M Sample#: 2015035288
Collection Date: 02-Nov-15 9:04 AM Matrix: NPDES
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
TOTAL RECOVERABLE METALS BY ICP-MS
Thallium(TI)Low Level <0.2 ug/L 02 1 EPA 200.8 11/03/2015 16.36 JAHERMA
METALS ANALYSIS BY VENDOR LAB-(Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 6 of 17
This report shall not be reproduced, except in full.
Order#A 5110007
Level II QC Summary
Q15110040 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank #1
Parameter Measured Final Units• Dil RDL Relative Concentration Qualifier
Thallium(TI)Low Level -00171 -00171 ug/L 1 0.2 <1/2 RDL
LCS #1
Parameter Measured Final Units: Dil Soike %Recovery LCL UCL Qualifier
Thallium(TI)Low Level 51 51 ug/L 1 50 102 85 115 -
MS #1 Parent Sample: J15110007 -- 2015035288
Parameter Measured Final Units: Dil Soike %Recovery LCL UCL Qualifier
Thalhum(TI)Low Level 51.3 51.3 ug/L 1 50 102 70 130
MSD #1 Parent Sample: J15110007 -- 2015035288
Parameter Measured Final Units: Dil Spike %Recovery LCL UCL RPD Qualifier
Thallium(TI)Low Level 517 51.7 ug/L 1 50 103 70 130 0.681

i Pace Analytical Services,Inc.
aceAnalytical® ���1K9ter�re Suite 100
Huntersville,NC 28078
www.pacelabs.com [phone]
November 06, 2015
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
RE: Project: NORMAN THALLIUM
Pace Project No.: 92274246
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on November 02, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Rodney Wilke,Duke Energy
V,P,cc O
REPORT OF LABORATORY ANALYSIS
%t This report shall not be reproduced,except in full,
!q without the written consent of Pace Analytical Services,Inc Page 1 of 10
BORA

Pace Analytical Services,Inc.
laneAnalytical' 9 �� 18tervire Swte
Huntersville,NC 28078078
www.pacelabs.com [phone]
CERTIFICATIONS
Project NORMAN THALLIUM
Pace Protect No.: 92274246
Minnesota Certification IDs
1700 Elm Street SE Suite 200,Minneapolis,MN 55414 Minnesota Certification#:027-053-137
A21-A Certification#:2926.01 Mississippi Certification#:Pace
Alaska Certification#:UST-078 Montana Certification#.MT0092
Alaska Certification#MN00064 Nevada Certification#:MN 00064
Alabama Certification#40770 Nebraska Certification#-Pace
Arizona Certification#-AZ-0014 New Jersey Certification#:MN-002
Arkansas Certification#.88-0680 New York Certification#:11647
California Certification#.01155C North Carolina Certification#:530
Colorado Certification#Pace North Carolina State Public Health#:27700
Connecticut Certification#:PH-0256 North Dakota Certification#•R-036
EPA Region 8 Certification#:8TMS-L Ohio EPA#:4150
Florida/NELAP Certification#:E87605 Ohio VAP Certification#:CL101
Guam Certification#•14-008r Oklahoma Certification#•9507
Georgia Certification#.959 Oregon Certification#:MN200001
Georgia EPD#-Pace Oregon Certification#:MN300001
Idaho Certification#:MN00064 Pennsylvania Certification#:68-00563
Hawaii Certification#MN00064 Puerto Rico Certification
Illinois Certification#:200011 Saipan(CNMI)#:MP0003
Indiana Certification#C-MN-01 South Carolina#:74003001
Iowa Certification#:368 Texas Certification#:T104704192
Kansas Certification#:E-10167 Tennessee Certification#-02818
Kentucky Dept of Envi.Protection-DW#90062 Utah Certification#:MN000642013-4
Kentucky Dept of Envi.Protection-WW#:90062 Virginia DGS Certification#•251
Louisiana DEQ Certification#:3086 Washington Certification#•C486
Louisiana DHH4'LA140001 West Virginia Certification# 382
Maine Certification#-2013011 West Virginia DHHR#•9952C
Maryland Certification#:322 Wisconsin Certification#:999407970
Michigan DEPH Certification#:9909
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Seances,Inc. Page 2 of 10

Pace Analytical Services,Inc.
® Ya5eiy 0�1!e Suite 100
aceAnalytical Huntersville,NC 28078
www pacalabacom [phone]
SAMPLE ANALYTE COUNT
Project NORMAN THALLIUM
Pace Project No.. 92274246
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92274246001 2015035287 EPA 200.8 TT3 1 PASI-M
92274246002 2015035288 EPA 200 8 TT3 1 PASI-M
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc.. Page 3 of 10

Pace Analytical Services,Inc.
aceAnalyticai® 0960inffte Suite 100
Huntersville,NC 28076
wwwpacelabacom [phone]
ANALYTICAL RESULTS
Project- NORMAN THALLIUM
Pace Project No 92274246
Sample: 2015035287 Lab ID: 92274246001 Collected. 11/02/150807 Received- 11/02/1511:15 Matrix.Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No Qua]
200.8 MET ICPMS Analytical Method:EPA 200.8 Preparation Method:EPA 200.8
Thallium ND ug/L 0.10 1 11/05/15 11:42 11/06/15 00:48 7440-28-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/06/2015 11:37 AM without the written consent of Pace Analytical Services,Inc. Page 4 of 10

Pace Analytical Services,Inc.
® 0969I1iiiw�re. Suite 100
aceAnalXical Hunterswlle,NC 28078
www.pacelabs com [phone]
ANALYTICAL RESULTS
Project: NORMAN THALLIUM
Pace Project No.. 92274246
Sample: 2015035288 Lab ID: 92274246002 Collected, 11/02/1509:04 Received: 11/02/1511:15 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No Qua[
200.8 MET ICPMS Analytical Method.EPA 200.8 Preparation Method:EPA 200.8
Thallium ND ug/L 0.10 1 11/05/15 11 42 11/06/15 01.06 7440-28-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/06/2015 11:37 AM without the written consent of Pace Analytical Services,Inc Page 5 of 10

Pace Analytical Services,Inc.
aceAna/ytical® 0980inyfre Suite 100
Huntersville,NC 28078
wwwpacelabs.com [phone]
QUALITY CONTROL DATA
Project NORMAN THALLIUM
Pace Project No.. 92274246
QC Batch: MPRP/59365 Analysis Method: EPA 200 8
QC Batch Method: EPA 200.8 Analysis Description: 200.8 MET
Associated Lab Samples: 92274246001,92274246002
METHOD BLANK: 2126108 Matrix: Water
Associated Lab Samples. 92274246001,92274246002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Thallium ug/L ND 0 10 11/06/15 00:36
LABORATORY CONTROL SAMPLE: 2126109
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Thallium ug/L 80 88.9 111 85-115
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2126110 2126111
MS MSD
92274246001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc Result Result %Rec %Rec Limits RPD Qual
Thallium ug/L ND 80 80 88.4 91.2 111 114 70-130 3
Results presented on this page are in the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/06/2015 11:37 AM without the written consent of Pace Analytical Services,Inc Page 6 of 10

Pace Analytical Services,Inc.
® 0$Q9Klinffte Suite 100
aceAnalytica! Huntersville,NC 28078
www.pacelabs.com [phone]
QUALIFIERS
Project- NORMAN THALLIUM
Pace Project No.- 92274246
DEFINITIONS
DF-Dilution Factor,if reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit.
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL-Practical Quantitation Limit.
RL-Reporting Limit.
S-Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is
a combined concentration.
Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for,but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether,Styrene,and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 toir the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270 The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited Contact your Pace PM for the current list of accredited analytes
TNI-The NELAC Institute.
LABORATORIES
PASI-M Pace Analytical Services-Minneapolis
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/06/2015 11:37 AM without the written consent of Pace Analytical Services,Inc. Page 7 of 10"

Pace Analytical Services,Inc.
® i e Suite 100
aceAnalytical ����
Huntersville,NC 28076
www.pacefabs.com [phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project NORMAN THALLIUM
Pace Project No' 92274246
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92274246001 2015035287 EPA 200.8 MPRP/59365 EPA 200.8 ICPM/27338
92274246002 2015035288 EPA 200.8 MPRP/59365 EPA 200.8 ICPM/27338
'i
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date'11/06/2015 11:37 AM without the written consent of Pace Analytical Services,Inc. Page 8 of 10

uocumenrName: vuUunicin 1.RV10VM. --Y ,V _
Sample Condition U on Receipt SCUR Pae 1 of 2*
Analytical Issuing Authoritx k
Document Number: 9 a f 17
F-CHR-CS-003-rev.16 Pace Huntersville Qua it f � i
Client Name. Page 2 of 2 is for Internal Use Only
Courier: ❑ Fed E)❑ UPC] USP❑ Clier❑ CommeOO Pace Other
/ Pro DIie;YDatehx
Custody Seal on Cooter/Box Present:�0 yes ❑ no Seals intact: (� yes ❑ no
Packing Material: ❑ Bubble Wrap ❑ Bubble Bags k]."'None _ Other
Thermometer Used:IR Gun T1402 Type of Ice: /6t/ Blue None Samples on ice,cooling process has begun t
l� .
Temp Correction Factor T1402 No Correction
,1 �� Date and Initials of person examining
Corrected Cooler Temp:: U -C Biological Tissue Is'Frozen:,Yes N�0 -contents:
Temp should_be above freezing to 6°C Comments:
k
Chain of Custody Present: Yes ONO ❑NIA 1.
Chain of Custody Filled Out: Yes ONO ❑N/A 2. ;
Chain of Custody Relinquished: Yes ONO ❑NIA 3,.'—
Sampler
:Sampler Name&Signature on COC: Pies,.ONO ❑NIA 4.
Samples Arrived within Hold Time: Yes ONO ❑NIA 5.
Short Hold Time Analysis(<72hr): Dyes do ON/A 6. r
Rush Turn Around Time Requested: ❑Yes lallo 0N/A 7.
/ .
Sufficient Volume: P es ONO ❑N/A 8.
f i
Correct Containers Used: PYes
ONO ❑NIA 9. '
-Pace Containers Used: 4es ONO ❑NIA
Containers-intact: pYes ❑No ❑NIA 10.
Filtered volume received for Dissolved tests i Yes ONO ❑N/A 11.
Sample Labels match COC: Yes ONO ONIA V.
-Includes date/time/ID/Analysis Matrix:
Ali containers needing preservation have been checked. Yes ONO ❑N/A 13.
All containers needing preservation are found to be in Yes ONO ❑NIA
compliance with EPA recommendation. j
exceptions: VOA, oolifonn.TOC,O&G,WI.ORO(water) Dyes JZNo
Sam les checked for dechlorination: Qxes []No ❑NIA 14. '
Headspace in VOA Vials(>6mm): ❑Yes ONo _,ON/A 15.
Trip Blank Present: Dyes ONO JIZI N/A 16.
Trip Blank Custody Seals Present Dyes ONO '}l�/A
Pace Trip Blank Lot# ifpurchased):
Client Notification/Resolution: Field Data Required? Y 1 N
Person Contacted: Date/Time:
Comments/Resolution:
SCURF Review: oats: rr�y I' WI ; 92274246
SRF Review: Date HEED
Note: Whenever there is a discrepancy affecting North Carolina compliance I� II�UI I II�I'�I'II�II•
samples,a copy of this form will be sent to the North Carolina DEHNR 922742.46
Certification Office(i.e out of hold,Incorrect preservative,out of temp,
incorrect containers)
Pana Q of�n

- -- Duke Energy - -Dote Er;e.yr nno+vo�teea�to.r--, r AIV i+eon Use On
wvicee.rooan(aaav r•v» :Order NC_ sc_ Page ol_t_ DISTRIBUTION
Analytical Laboratory ,avn.,j-Fw,y AC ..1 ORIGINAL 1.LAB•COPY to CLIENT
Chain of Custody 6 n...r.var.■.c.mon By O•ba Ti.. SAMPLE PROGRAM
` G C�y -X
_
Sample Log o,yy� ow-\ :J '1 G—d waw._ NPOES _ t
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? n•mc Norman Thallium ++u� �w�� coni«T•m S __.._.._.._._.RA w��..—_._._._._.._....._.._._.._
Fu lo: 1�
Bill Foris/Josh Quinn teoarywv P@#-1 19 5040 Filtration(0.45 um) 1 Unfiltered I b
MCO. Praa«a 8L"EGNa..r.c..�r. I J
ME' J
PresOrvativC
P,q.e ux c: MG°oOr I rtainor Volum.(mL) Soo N
lg0.1 �_
.,.neer Lax.Norman MNS Container Typo HOPE] I
`c
Sample Description or ID w,." . ,..,. E o
Lae uta aur• ' Location 8 Depth Collectron Inromutlon
Lab 10 I Dace lime I -F' ,
16150 3S V& MNS Intake tom 0&7 X yt I
yd MNS Discharge(001) 0.3,m X
0
I .
I I
0
0
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�:u.r�.n .to a•m .arc E,--
.Reil OatdTime AompteA By: Date/Time
J U A..•.,1,,' /'^ _r C ,e A_� ,Requested Turnaround Total
F2 I
11 L.l U- ZS 7- ,f��r1 N/✓ I ! .J (J 'T - _
14 Days
Oam/TI= Accepted By:
'7 Days—X -
e SeaVLoekW BY Date?Ime SadedM1Opar,sd By BY
Detsrtime -
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-
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O

Pa�naxl tWiftlbervlces,Inc.
® � �L�li��t✓ e Swte100
(�55'neAnalytical y Huntersville,NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project J15110120
Pace Project No.. 92275203
QC Batch- MPRP/59450 Analysis Method: EPA 200 8
QC Batch Method: EPA 200.8 Analysis Description. 200.8 MET
Associated Lab Samples: 92275203001,92275203002
METHOD BLANK: 2130040 Matrix: Water
Associated Lab Samples: 92275203001,92275203002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Thallium ug/L ND 010 11/11/1516:17
LABORATORY CONTROL SAMPLE: 2130041
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Thallium ug/L 80 872 109 85-115
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2130042 2130043
MS MSD
92274835001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Thallium ug/L ND 80 80 87.2 89.5 109 112 70-130 3
MATRIX SPIKE SAMPLE: 2130044
92274840002 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Thallium ug/L ND 80 88.5 111 70-130
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/12/2015 01:21 PM without the written consent of Pace Analytical Services,Inc. Page 6 of 10

Pae tl i ervices,Inc.
® �naRV�aFLaSb
aceAnalytica! o$��'�swfte. Suite 100
Huntersville,NC 28078
www.pacelabs.corn [phone]
QUALIFIERS
Project- J15110120
Pace Project No.: 92275203
DEFINITIONS
DF-Dilution Factor,if reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL-Practical Quantitation Limit.
RL-Reporting Limit.
S-Surrogate
1,2-Diphenylhydrazme decomposes to and cannot be separated from Azobenzene using Method 8270 The result for each analyte is
a combined concentration.
Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for,but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether,Styrene,and Vinyl chloride
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated_from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute
LABORATORIES
PASI-M Pace Analytical Services-Minneapolis
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/12/2015 01:21 PM without the written consent of Pace Analytical Services,Inc. Page 7 of 10

Pa�nal �if el tervlces,Inc.
®
13969 TYf`i'e. Suite 100
aceAnalXical 9 Huntersvdle,NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project- J15110120
Pace Project No: 92275203
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92275203001 2015035750 EPA 200.8 MPRP/59450 EPA 200.8 ICPM/27451
92275203002 2015035752 EPA 200 8 MPRP/59450 EPA 200.8 ICPM/27451
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/12/2015 01:21 PM without the written consent of Pace Analytical Services,Inc. Page 8 of 10

// J . • - Document Number:, rssuuiy Muu,vilLy•
( F-CHR-CS-003-rev.16 ' Pace Huntersville Quafit Office.
na ytical Lab
Page 15 of 17
Cl lent Name:
Page 2 of 2 Is for Internal Use Only
Fed E�❑ UP USP❑ Clie Commerci❑ Pace Other ,O tiohal�
Courier: ❑ ❑ PCo. '<:
Custody Seal on CoolerlBox Present: ❑ yes 0 no Seals intact: ❑ yes ❑ no °' ;:r?;:`.;,,ca• :::
Pro .Name:;
Packing Material: E] Bubble Wrap ❑ Bubble Bags ElNon El Other
Fe5tBlue NoneSamples on Ice,cooling process has begun
Thermometer Used:IR Gun T1402 Type of Ice:
Temp Correction Factor T1402 No Correction CNIA
Oateand Initialsf pe o1r a mining•CBiological Tissue is Frozen: Yes No contents:_- -- / ;
Corrected Cooler Temp.:
Temp should be above freezing to 6°C Comments:
r
Chain of Custody Present: 9x No ❑NrA 1.
i
Chain of Custody Filled Out: es No ❑NIA 2.
Chain of Custody Relinquished: es No ❑NlA 3.
Sam ler Name&Signature on COC: 5Y e No ONlA 4.,
Samples Arrived within Hold Time: Yes ONO NIA 5.,
Short Hold Time Analysis 472hr): Dyes-0 o N/A 6.
Rush Turn Around Time Requested: _ ❑Yes o ❑NIA 7.
Sufficient Volume: des No ❑NrA 8:
Correct Containers Used: Cayes' ONO ❑N/A 9.
-Pace Containers Used: res ONO ❑N/A _
Containers Intact: es ❑No ❑NIA
❑Yes•❑No
Filtered volume received.for Dissolved tests
❑ /A 11.
(Sample Labels match COC: es ONO ❑NIA 12.
,
-Includes dateltime/ID/Analysis Matrix:
All containers needing preservation have been checked. ❑No ❑N/A 13.
All containers needing preservation are found to be In es ❑No ❑NIA
scompliance with EPA recommendation.
exceptions- VOA, coliform,TO 08 G,Wl•DRO(water) ❑Yes
Samples checked for dechlorination: []Yes ONO rA 14.OYes C01 No 6NHeads ace in VOA Vials(>6mm):
I 15.
Trip Blank Present: ❑Yes ONO NrA 16.
Trip Blank Custody Seals Present ❑Yes ONO NIA
!Pace Trip Blank Lot# if purchased:
Field Data Required? Y ! N
Client Notification/Resolution:
Person Contacted: Datefl ime:
Comments/Resolution: sd�
Date: 11� is f/11® ° o��oaged227520
SCURF RevleW:
k
1 �S clin North Carolina compliance ILO Ill�I I�1(I I I I I I I III. _
Note: Whenever there Is a discrepancy affe g ;n-
samples,a copy of this form will be sent to the North Carolina DEHNR 922176203,-
Certification
22767.03
Certification Office(I.e out of hold,incorrect preservative,out of temp, tit no label available)
incorrect containers)
Page 9 of 10

t
ti __ _ _ CD
CHAIN OF CUSTODY RECORD 0
AND ANALYSIS RE_QU_F_S_T FORM rn
puke Energy M----- l Leaoretory ---V~ •—__•—� AM � Ux
J o Duke Energy y Metrlx-NPD£S e,y,Y,.,.,... NC_ SC_ ` 'Page•.t—.o1—1,_ DISTRIBUTION a
9y Y.0[.e.Yoow(o�+.`o—M :O.dern /�.Q%2Q+ ORIGINAL to LAB.COPYtOCLIENT
U[O Analytical 1.81501`310ry .J'a9 M.0Y•F`^V an -�
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—
Q�P..Har Yom+ Nomwn Thallium em+essMo �l -1 cea..T—P19ZF.
_._.. _.—____.�__.--_-_—•_--..__..__ .—___._..__.
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Container Volume(mL)
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MNS Discharge(007) 0.3 m ��I O X
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•Analytical Lab ,
Page 17-of 17
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Lab
DUKE Analytical Laboratory Analytical
of 17
ENERGY.
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex- MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Order Number: J15110147
Project Name, MCGUIRE-
Customer Name(s): BILL FORIS,JOSH QUINN
Customer Address. 13225 Hagers Ferry Rd
Mail Code: MG01CH
Huntersville,NC 28078-8985
Lab Contact Mary Ann Ogle Phone: [phone]
Digitally signed by Mary
Report Authorized B J6 © �—Ann Ogle 11/18/2015
By: Date:201511.1815:01:47 Date:
(Signature) -05,00 RECEIVEDIDENRIDWR
Mary Ann Ogle
Program Comments: DEC 0 9 2015
Please contact the Program Manager(Mary Ann Ogle)with any questions regarding this report. Water Qua*
Permitting Section
Data Flags&Calculations:
Any analytical tests or Individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis(sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative.An estimation of
the uncertainty of measurement for the results in the report is available upon request.This report shall not be reproduced, except
in full,without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions.The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package,Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports&
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody(COC)
Certification:
The Analytical Laboratory holds the following State Certifications: North Carolina(DENR)Certificate#248,South Carolina
(DHEC)Laboratory ID#99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Analytical Lab
Sample ID's $ Descriptions: Page 2 of 17
Collection
Sample ID Plant/Station Date and Time Collected By Sample Description
2015035883 MCGUIRE 09-Nov-15 9:00 AM G.LONG MNS Intake 10M
2015035884 MCGUIRE 09-Nov-15 10:00 AM G.LONG MNS Discharge(001)0.3 M
2 Total Samples

Analytical Lab
Page 3 of 17
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals W Yes ❑ No
and analyses(compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑v Yes ❑ No
All laboratory QA/QC requirements are acceptable. 0 Yes ❑ No
Report Sections Included:
❑d Job Summary Report Sub-contracted Laboratory Results
Sample Identification ❑ Customer Specific Data Sheets,Reports,&Documentation
0 Technical Validation of Data Package ❑ Customer Database Entries
❑� Analytical Laboratory Certificate of Analysis R] Chain of Custody
❑Analytical Laboratory QC Report ❑ Electronic Data Deliverable(EDD)Sent Separate[
Reviewed By- Mary Ann Ogle Date: 11/18/2015

Analytical Lab
Certificate of Laboratory Analysis Page 4 of 17
This report shall not be reproduced, except in full.
Order#A 5110147
Site: MNS Intake 10M Sample#: 2015035883
Collection Date: 09-Nov-15 9:00 AM Matrix: NPDES
Analyte Result Units Qualifiers RDL DF Method Analysis Daterrime Analyst
TOTAL RECOVERABLE METALS BY ICP-MS
Thallium(TI)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/16/2015 21:38 JAHERMA
METALS ANALYSIS BY VENDOR LAB-(Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Analytical Lab
Certificate of Laboratory Analysis Page 5 of 17
This report shall not be reproduced, except in full.
Order#A 5110147
Site: MNS Discharge(001)0.3 M Sample#: 2015035884
Collection Date: 09-Nov-15 10:00 AM Matrix: NPDES
Analyte Result Units Qualifiers RDL DF Method Analysis Daterrime Analyst
TOTAL RECOVERABLE METALS BY ICP-MS
Thallium(TI)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/16/2015 21:17 JAHERMA
METALS ANALYSIS BY VENDOR LAB-(Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Analytical Lab
Certificate of Laboratory Analysis Page 6 of 17
This report shall not be reproduced, except in full.
Order#A 5110147
Level 11 QC Summary
Q15110183 1MS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank #1
Parameter Measured Final Units- Dil RDL Relative Concentration Qualifier
Thallium(TI)Low Level -0.052 -0.052 ug/L 1 02 <1/2 RDL -
LCS #1
Parameter Measured Final Units- Dil 5pM %Recovery LCL UCL Qualifier
Thallium(TI)Low Level 48.5 48.5 ug/L 1 50 96.9 85 115 -
MS #1 Parent Sample: J15110147 -- 2015035884
Parameter Measured Final Units: Dil SRike %Recovery LCL UCL Qualifier
Thallium(TI)Low Level 48.4 48.4 ug/L 1 50 96.6 70 130 -
MSD #1 Parent Sample: J15110147 -- 2015035884
Parameter Measured Final Units: Dil Saike %Recovery LCL UCL RPD Qualifier
Thallium(TI)Low Level 50.5 50.5 ug/L 1 50 101 70 130 4.43 -

Pa�n8lytWIfel bervlces,Inc.
® ��Q�(i9 ,p. Suite 100
(�Ilacl
AnalXical Huntersville,NC 28078
wwwpacelabs com [phone]
November 16, 2015
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
RE: Project: J15110147
Pace Project No.: 92275330
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on November 09, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Rodney Wike,Duke Energy
pCCRFO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc. Page 1 of 10
B�RA�

Pa�nalytl�alFEabervlces,Inc.
® �(aQ�ia4 e. Suite 100
aceAnalytical Huntersvdle,NC 28078
www.pacelabs corn [phone]
CERTIFICATIONS
Project: J15110147
Pace Project No 92275330
Minnesota Certification IDs
1700 Elm Street SE Suite 200,Minneapolis,MN 55414 Minnesota Certification#:027-053-137
A21-A Certification#:2926.01 Mississippi Certification#:Pace
Alaska Certification#:UST-078 Montana Certification#•MT0092
Alaska Certification#MN00064 Nevada Certification#:MN_00064
Alabama Certification#40770 Nebraska Certification#:Pace
Arizona Certification#•AZ-0014 New Jersey Certification#:MN-002
Arkansas Certification#.88-0680 New York Certification#: 11647
California Certification#.011 55C North Carolina Certification#:530
Colorado Certification#Pace North Carolina State Public Health#•27700
Connecticut Certification#:PH-0256 North Dakota Certification#:R-036
EPA Region 8 Certification#:8TMS-L Ohio EPA#.4150
Florida/NELAP Certification#:E87605 Ohio VAP Certification#:CL101
Guam Certification#•14-008r Oklahoma Certification#:9507
Georgia Certification#.959 Oregon Certification#.MN200001
Georgia EPD#.Pace Oregon Certification# MN300001
Idaho Certification#:MN00064 Pennsylvania Certification#:68-00563
Hawaii Certification#MN00064 Puerto Rico Certification
Illinois Certification#:200011 Saipan(CNMI)#:MP0003
Indiana Certification#C-MN-01 South Carolina#.74003001
Iowa Certification#:368 Texas Certification#:T104704192
Kansas Certification#:E-10167 Tennessee Certification#:02818
Kentucky Dept of Envi.Protection-DW#90062 Utah Certification#.MN000642013-4
Kentucky Dept of Envi.Protection-WW#:90062 Virginia DGS Certification#:251
Louisiana DEQ Certification#:3086 Washington Certification#:C486
Louisiana DHH#:LA140001 West Virginia Certification# 382
Maine Certification#:2013011 West Virginia DHHR#:9952C
Maryland Certification#:322 Wisconsin Certification#:999407970
Michigan DEPH Certification#:9909
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc Page 2 of 10

Pamal tWifEl bervlces,Inc.
aceAnalytical �� �i4r�re Sude 100
Huntersvdle,NC 28078
www.pmlabs.com [phone]
SAMPLE ANALYTE COUNT
Project J15110147
Pace Project No.: 92275330
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92275330001 2015035883 EPA 200.8 RJS 1 PASI-M
92275330002 2015035884 EPA 200 8 RJS 1 PASI-M
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc. Page 3 of 10

Pa�nal tvtlftl bervices,Inc.
® 19����i�6�>+'fy'e. Suite 100
aceAnalytical 9 Huntersville,NC 28078
www.pacelabs.com [phone]
ANALYTICAL RESULTS
Project J15110147
Pace Project No.. 92275330
Sample: 2015035883 Lab ID: 92275330001 Collected- 11/09/150900 Received- 11/0911511-38 Matnx• Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
200.8 MET ICPMS Analytical Method:EPA 200.8 Preparation Method:EPA 200.8
Thallium ND ug/L 0.10 1 11/11/151505 11/13/1512:20 7440-28-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/16/2015 03:40 PM without the written consent of Pace Analytical Services,Inc. Page 4 of 10

Pa�nal tl�aF�Bbervlces,Inc.
® ofiPiiv to Suite100
aceAnalytical Huntersville,NC 28078
www.pacelabs.com [phone]
ANALYTICAL RESULTS
Project- J15110147
Pace Project No.: 92275330
Sample: 2015035884 Lab ID: 92275330002 Collected- 11/09/15 1000 Received. 11/09/15 11.38 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
200.8 MET ICPMS Analytical Method:EPA 200.8 Preparation Method:EPA 200.8
Thallium ND ug/L 0.10 1 11/11/15 1505 11/13/15 12 02 7440-28-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/16/2015 03:40 PM without the written consent of Pace Analytical Services,Inc. Page 5 of 10

Pam tl�aF�abervices,Inc.
® a v ii a a"1e. Suite 100
aceAnalyticai Huntersville,NC 28078
www pacelabs com [phone]
QUALITY CONTROL DATA
Project. J15110147
Pace Protect No.: 92275330
QC Batch- MPRP/59524 Analysis Method: EPA 200 8
QC Batch Method. EPA 200.8 Analysis Description. 200.8 MET
Associated Lab Samples- 92275330001,92275330002
METHOD BLANK: 2132045 Matrix: Water
Associated Lab Samples: 92275330001,92275330002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Thallium ug/L ND 0.10 11/13/1511:52
LABORATORY CONTROL SAMPLE: 2132046
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Thallium ug/L 80 837 105 85-115
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2132047 2132048
MS MSD
92275330001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Thallium ug/L ND 80 80 88.1 88.8 110 111 70-130 1
MATRIX SPIKE SAMPLE: 2132049
92275282005 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Thallium ug/L ND 80 83.9 105 70-130
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/16/2016 03:40 PM without the written consent of Pace Analytical Services,Inc. Page 6 of 10

Parr tI�2Frabervices,Inc.
O 19�Q�KIi�c��.Q . Suite 100
aceAnalXical Huntersvdle,NC 28078
www.pacelabs.com [phone]
QUALIFIERS
Project. J15110147
Pace Project No.: 92275330
DEFINITIONS
DF-Dilution Factor,if reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
NO-Not Detected at or above adjusted reporting limit.
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL-Practical Quantitation Limit.
RL-Reporting Limit.
S-Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is
a combined concentration.
Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for,but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether,Styrene,and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute.
LABORATORIES
PASI-M Pace Analytical Services-Minneapolis
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date.11/16/2015 03:40 PM without the written consent of Pace Analytical Services,Inc. Page 7 of 10

Pa���mtalfEl tervlces,Inc.
® ��QFfli�c�� Suite 100
aceAnalytical y Huntersville,NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project- J15110147
Pace Project No.: 92275330
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92275330001 2015035883 EPA 200.8 MPRP/59524 EPA 200.8 ICPM/27463
92275330002 2015035884 EPA 200.8 MPRP/59524 EPA 200.8 ICPM/27463
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/16/2015 03:40 PM without the written consent of Pace Analytical Services,Inc. Page 8 of 10

uocument rvame: vuaui�ioi�t r`VVIJ�u , -, -
Sam le Condition U on Recei t SCUR Pa e 1 of 2`
Analytical Issuing Authority:Anaiytical Lab j
Document Number: of i7
F-CHR-CS-003-tel'
Pace Huntersville Quali iFic�e ;
*.Page 2 of 2 Is for Internal Use only' {
Client Name:
❑ Clier❑��no
merci❑
a Other
Courter: ❑ Fed E�❑
UPC] USP p�pj� DU2iDStel; +'�'�s i
Custody Seal on Cooter/Box Present: ❑ yes Seals intact: El yes ❑ no
Packing Material: ❑ Bubble Wrap ❑ Bubble Bags None Other — f
Thermometer Used:-IR Gun 1402 Type of Ice:
Blue None Samples on Ice,cooling process has begun
f
Temp Correction Factor T1 No Correction Date and Initial��pf pars n examining
.0 Biological Tissue is Frozen: .Yes,No . (A
Corrected Cooler Temp.: Comments:
Temp should be above freezing to 6"C
Chain of Custod Present:
Yes ❑ ❑N1A 1.
_
Chain of Custodyea ❑ o ON1A 2.
Filled Out: ?
Chairi of custody Relin wished:
es No ❑N!A 3. t
Sampler Name&Signature on COC:
es ONO ❑NIA 4.
Sam les Arrived'wittiin Hold Time:
'Yes ONO NIA 5. i
A '•
Short Hold Time Analysis <72hr: Dyes 1:3 o 6: ;
Rush Turn Around Time Re uested:
Dyes o 0N1A 7. i
es ❑ ❑NIA 8.
Sufficient Volume:
es 11 NO ❑ A 9. {
Correct Containers Used:
-Pace Containers Used:
Dyes L�fl DWA
Cont—­
es ONO ❑NIX
Containers Intact:
Filtered volume received for Dissolved tests
❑Yes Ido, ❑ !A 11•
es ONO ❑NIA 12.
Sample Labels match COC: A
-Includes date/time/tD/Anal sis Matrix:
All containers needing preservation have been checked. �UyesNo ❑N1A 13.
All containers needing preservation are found to be in No ❑NIA
compliance with EPA recommendation.
No
exceptions: VOA, coliform,TOC,O&G,WI-DRO(water) Dyes _
Samples checked for dechlorination:
❑Yes
'ONO A 1
Headspace in VOA Vials(>6mm
Dyes ONO IA 15.
Dyes ONO QN16.
Trip Blank Present:
/
ONO ❑jN1
Trip Blank Custody Seals Present Dyes ;
Pace Trip Blank.Lot# if purchased):
Field Data Required? Y / N
Client Notification!Resolution:
Date/Time: •
Person Contacted: '—
i Comments/Resolution:
Date: // /5 W® 0 922 '5330
SCURF Review: EE]
ff
Date: Ir+lo�l II
SRF Review:
Note: Whenever there is a discrepancy affecting North Carolina compliance
samples,a copy of this form will be sent to the North Carolina DEHNR 82275330
Certification Office(i.e out of hold,Incorrect preservative,out of temp,
incorrect containers)

i O
FIZZ l
n,( CHAIN OF CUSTODY•RECORD AND ANALYSIS REQUEST FORM m
�,•-:-"-•-•-•-•-•---•-•----- puke Enegy Malytleal Laeoreroy-, r• ._._..�.___.__'. — rdy
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mrd Analytical Laboratory .m•wow.F—,Ae '��/.d�!/ y-�'�e�""'+`^ NC� Sc_' 'Page-101�t_ DISTRIBUTION
Analytical
crba curio r a w.�...or K a ravn o��rm�a ORIGINAL 10 LAB,COPY to CLIENT
sampe Les P�anstas 1—.; �t.'9B�tl ar G J �" sAuvl.E PROGRAM
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La
DUKE Analytical Laboratory Analytical
of 17
ENERGY.
i 13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex-MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Order Number: J15110283
Project Name: MCGUIRE-
Customer Name(s): BILL FORTS,JOSH QUINN
Customer Address 13225 Hagers Ferry Rd
Mail Code- MG01CH
Huntersville,INC 28078-8985
Lab Contact: Mary Ann Ogle Phone: [phone]
/ Digitally signed by Mary Ann
Report Authorized By: ✓ Date-2015 11.30 1130 00 Date: 11/3012015
(Signature) (/ -05,00,
Mary Ann Ogle
Program Comments:
Please contact the Program Manager(Mary Ann Ogle)with any questions regarding this report.
Data Flags&Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier Indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis(sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative.An estimation of
the uncertainty of measurement for the results in the report is available upon request.This report shall not be reproduced,except
in full,without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions.The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identirication, Technical Validation of Data Package,Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets,Reports&
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody(COC)
Certification:
The Analytical Laboratory holds the following State Certifications: North Carolina(DENR)Certificate#248,South Carolina
(DHEC)Laboratory ID#99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Analytical Lab
Sample ID's & Descriptions: Page 2 of 17
Collection
Sample ID Plant/Station Date and Time Collected By Sample Description
2015036392 MCGUIRE 13-Nov-15 9:07 AM G.LONG MNS Intake 10M
2015036393 MCGUIRE 13-Nov-15 9:35 AM G.LONG MNS Discharge(001)0 3 M
2 Total Samples

Analytical Lab
Page 3 of 17
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals ❑- Yes ❑ No
and analyses(compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑� Yes ❑ No
All laboratory QA/QC requirements are acceptable. Fv—i Yes ❑ No
Report Sections Included:
0 Job Summary Report Sub-contracted Laboratory Results
Sample Identification ❑ Customer Specific Data Sheets,Reports,&Documentation
Technical Validation of Data Package ❑ Customer Database Entries
❑� Analytical Laboratory Certificate of Analysis Chain of Custody
❑Analytical Laboratory QC Report ❑ Electronic Data Deliverable(EDD)Sent Separatel
Reviewed By. Mary Ann Ogle Date: 11/30/2015

Analytical Lab
Certificate of Laboratory Analysis Page 4 of 17
This report shall not be reproduced, except in full.
Order#A 5110283
Site: MNS Intake 10M Sample#: 2015036392
Collection Date: 13-Nov-15 9:07 AM Matrix: NPDES
Analyte Result Units Qualifiers RDL DF Method Analysis Daterrime Analyst
TOTAL RECOVERABLE METALS BY ICP-MS
Thallium(TI)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/17/2015 19:47 JAHERMA
METALS ANALYSIS BY VENDOR LAB-(Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Analytical Lab
Certificate of Laboratory Analysis Page 5 of 17
This report shall not be reproduced, except in full.
Order#J15110283
Site: MNS Discharge(001)0.3 M Sample#: 2015036393
Collection Date: 13-Nov-15 9:35 AM Matrix- NPDES
Analyte Result Units Qualiflers RDL DF Method Analysis Daterrime Analyst
TOTAL RECOVERABLE METALS BY ICP-MS
Thallium(TI)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/17/2015 1926 JAHERMA
METALS ANALYSIS BY VENDOR LAB-(Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Analytical Lab
Certificate of Laboratory Analysis Page 6 of 17
This report shall not be reproduced, except in full.
Order#A 5110283
Level II QC Summary
Q15110299 IMS_TRM TOTAL RECOVERABLE METALS BV ICP-MS
Blank #1
Parameter Measured Final Units: Dil RDL Relative Concentration Qualifier
Thallium(TI)Low Level 00051 0.0051 ug/L 1 0.2 <1/2 RDL
LCS #1
Parameter Measured Final Units: Dil Soike %Recovery LCL UCL Qualifier
Thallium(TI)Low Level 48.8 488 ug/L 1 50 97.6 85 115 -
MS #1 Parent Sample: J15110283 -- 2015036393
Parameter Measured Final Uni s: Dil SSoike %Recovery LCL UCL Qualifier
Thallium(TI)Low Level 49 49 ug/L 1 50 97.8 70 130
MSD #I Parent Sample: J15110283 -- 2015036393
Parameter Measured Final Units: Dil Soike %Recovery LCL UCL RPD Qualifier
Thallium(TI)Low Level 486 48.6 ug/L 1 50 97.1 70 130 0.718 -

PanelytWifel bervlces,Inc.
® ��Q�Ci94p;. Suite 100
acmnalXical Huntersvwlle,NC 28078
wwwpacelabs.00m [phone]
November 24, 2015
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
RE: Project: J15110283
Pace Project No.: 92276408
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on November 17, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Rodney Wike,Duke Energy
pCCR�
REPORT OF LABORATORY ANALYSIS
<. 3 This report shall not be reproduced,except in full,
�q without the written consent of Pace Analytical Services,Inc. Page 1 of 10
e�RA�

Pa�nalytl�2Frabervlces,Inc.
® ��Q�Cigc���e Suite 100
(�55'cmnalytical Huntersville,NC 28078
www pacelabs com [phone]
CERTIFICATIONS
Project J15110283
Pace Project No.: 92276408
Minnesota Certification IDs
1700 Elm Street SE Suite 200,Minneapolis,MN 55414 Minnesota Certification#:027-053-137
A21-A Certification#:2926.01 Mississippi Certification#:Pace
Alaska Certification#:UST-078 Montana Certification#.MT0092
Alaska Certification#MN00064 Nevada Certification#:MN 00064
Alabama Certification#40770 Nebraska Certification#:Pace
Arizona Certification#:AZ-0014 New Jersey Certification#:MN-002
Arkansas Certification#:88-0680 New York Certification#. 11647
California Certification#:01155CA North Carolina Certification#:530
Colorado Certification#Pace North Carolina State Public Health#•27700
Connecticut Certification#:PH-0256 North Dakota Certification#:R-036
EPA Region 8 Certification#:8TMS-L Ohio EPA#:4150
Florida/NELAP Certification# E87605 Ohio VAP Certification#:CL101
Guam Certification#:14-008r Oklahoma Certification#:9507
Georgia Certification#:959 Oregon Certification#.MN200001
Georgia EPD M Pace Oregon Certification#.MN300001
Idaho Certification#:MN00064 Pennsylvania Certification#:68-00563
Hawaii Certification#MN00064 Puerto Rico Certification
Illinois Certification#:200011, Saipan(CNMI)#:MP0003
Indiana Certification#C-MN-01 South Carolina#:74003001
Iowa Certification#:368 Texas Certification#:T104704192
Kansas Certification#:E-10167 Tennessee Certification#-02818
Kentucky Dept of Envi.Protection-DW#90062 Utah Certification#:MN000642013-4
Kentucky Dept of Envi.Protection-WW#:90062 Virginia DGS Certification#.251
Louisiana DEQ Certification#:3086 Washington Certification#:C486
Louisiana DHH#:LA140001 West Virginia Certification#:382
Maine Certification#:2013011 West Virginia DHHR#:9952C
Maryland Certification#.322 Wisconsin Certification#:999407970
Michigan DEPH Certification#:9909
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc Page 2 of 10

pa�nal tlfrabervices,Inc.
aceAnalytical® ���Hunter�e Suite 100
8078
Huntersvdie,NC 26078
www.pace/abacom [phone]
SAMPLE ANALYTE COUNT
Protect: J15110283
Pace Project No.: 92276408
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92276408001 2015036392 EPA 200.8 TT3 1 PASI-M
92276408002 2015036393 EPA 200.8 TT3 1 PASI-M
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc. Page 3 of 10

Parr tl�aF�abervlces,Inc.
® 086p'6`8t~ffe Suite 100
aceAnalytical Huntersville,NC 28078
www pacelabs com [phone]
ANALYTICAL RESULTS
Project. J15110283
Pace Project No.: 92276408
Sample: 2015036392 Lab ID: 92276408001 Collected. 11/13/150907 Received- 11/17/1514:20 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
200.8 MET ICPMS Analytical Method:EPA 200.8 Preparation Method:EPA 200.8
Thallium ND ug/L 0.10 1 11/19/151620 11/20/1512.02 7440-28-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date-11/24/2015 05.08 PM without the written consent of Pace Analytical Services,Inc. Page 4 of 10

PasnaT tWifel bervices,Inc.
® Ig$Q�FfIi;y� e. Suite 100
acmnalXical y Huntersville,NC 28078
www.pacelabs com [phone]
ANALYTICAL RESULTS
Project: J15110283
Pace Project No.: 92276408
Sample: 2015036393 Lab ID: 92276408002 Collected: 11/13/150935 Received: 11/17/1514:20 Matrix, Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
200.8 MET ICPMS Analytical Method:EPA 200.8 Preparation Method:EPA 200.8
Thallium ND ug/L 0.10 1 11/19/1516:20 11/20/1512.04 7440-28-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/24/2015 05:08 PM without the written consent of Pace Analytical Services,Inc. Page 5 of 10

Parraa x tI�BFrabervlces,Inc.
® 0$Q K�iQvfte Suite 100
aceAnalytical Huntersville,NC 28078
xww.pacelabs.com [phone]
QUALITY CONTROL DATA
Project J15110283
Pace Project No.. 92276408
QC Batch. MPRP/59792 Analysis Method EPA 200.8
QC Batch Method EPA 200.8 Analysis Description' 200.8 MET
Associated Lab Samples: 92276408001,92276408002
METHOD BLANK: 2139583 Matrix. Water
Associated Lab Samples, 92276408001,92276408002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Thallium ug/L ND 0.10 11/20/1510:50
LABORATORY CONTROL SAMPLE: 2139584
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Thallium ug/L 80 89.2 112 85-115
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2139585 2139586
MS MSD ,
92276507001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Thallium ug/L ND 80 80 87.8 87.0 110 109 70-130 1
MATRIX SPIKE SAMPLE. 2139587
92276513003 Spike MS MS %Rec -
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Thallium ug/L ND 80 856 107 70-130
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/24/2015 05:08 PM without the wntten consent of Pace Analytical Services,Inc. Page 6 of 10

Par A tl�aFtabervlces,Inc.
® �Rg�,,i&I;e. Suite 100
aceAnalytical y Huntersville,NC 28078
www.pacelabs com [phone]
QUALIFIERS
Project, J15110283
Pace Project No.. 92276408
DEFINITIONS
DF-Dilution Factor,if reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit.
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL-Practical Quantitation Limit.
RL-Reporting Limit.
S-Surrogate
1,2-Diphenylhydrazine'decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is
a combined concentration
Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for,but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether,Styrene,and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamme decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute
LABORATORIES
PAST-M Pace Analytical Services-Minneapolis
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/24/2015 05:08 PM without the written consent of Pace Analytical Services,Inc. Page 7 of 10

Pamnal tWIftlbervlces,Inc.
® ��Q9♦fl %Y to Suite 100
aceAnaIXical Huntersville,NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J15110283
Pace Project No- 92276408
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92276408001 2015036392 EPA 200.8 MPRP/59792 EPA 200.8 ICPM/27599
92276408002 2015036393 EPA 200.8 MPRP/59792 EPA 200.8 ICPM/27599
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/2412015 05:08 PM without the written consent of Pace Analytical Services,Inc. Page 8 of 10

uocumen
Sample Condition Upon Recei t SCUR vu�u_Ir�CIf�Page 1 of 2*
� Analytical La f
�7f,�Alr�1/ytlCal Document Number: Issuing Authority:
F-CHR-CS-003-rev.16 Pace Huntersville Quality Office
i
Client Dame: Otet JjQ- �, j !,Page-2 of 2 is for Internal Use Only;
Couiler: ❑ FedE)0 UP❑ USP❑ Clier❑ComerciEl P Other
P..rojDue:D,ate;f#r<< ar
Custody Seal on Cooler/Box Present: El yes ❑ no Seals intact: Elyes El no
h
Packing Material: ❑ Bubble Wrap- ❑ Bubble Bags one ❑ Other
Thermometer Used:IR Gun (fT 4131 Type of Ice: �t� Blue None [],Smples on Ice,cooling pjocess has begun
Temp Correction Factor 11402 No Correction
Date and Initials ofRRarson ex mining
__
Biological Tissue is Frozen: Yes N. N/
Corrected Cooler Temp.: contents:
C 1_S
Temp should be above freezing to 6°C -Comments:
Chain of Custody Present: ices ONO .❑NIA 1.
Chain of CustodyFilled Out: Yes No ON/A 2.' I
Chain of Custody Relinquished: fd es No ❑N/A 3. '
Sampler Name&Signature on COC: Yes ONO ❑NIA 4.
t
Samples Arrived within Hold Time: Yes ONO JINZA 5.
Short Hold Time Analysis <72hr: ❑Yes ONO JONIA 6.
Rush Turn Around Time Requested: Dyes No ❑wA 7.
i
Sufficient Volume: w es gNo ❑NIA $,
i
Correct Containers Used: Des ONO NIA 9. }
'
-Pace Containers Used: Oyes P Ito"'❑N/A � '
Containers Intact: C es 0 N ❑NIA
Filtered volume received for Dissolved tests Dyes ONO ❑ /A 11.
Sample Labels match COC: OYes ❑No ❑NIA 12.
-Includes date/time/ID/Analysis Matrix:
All containers needing preservation have been checked. ❑Y ��No ❑NIA 13.
All containemneeding preservation are found to-be in yes ONO ❑N/A
compliance with EPA recommendation.
exceptions: VOA, coliform,TOC,O&G,WI-DRO(water) Dyes 06-, i
Samples checked for dechlorination: Dyes ONO I NIA 14.
Heads ace in VOA Vials(>6mm): Dyes ONO 09/'A 15.
Trip Blank Present: Dyes ONO QN A 16.
Trip Blank Custody Seals Present Dyes ON OWK
Pace Trip Blank Lot#(if purchased):
Client Notification/Resolution: Field Data Required? Y / N
Person Contacted: DatefTime:
Comments/Resolution:
SCURF Review: Date: it IIS ® 92276'408
SRF Review: Date: ►t ! t� (I II' III(II I I I I II I I ISI
Note: Whenever there Is a discrepancy affecting North Carolina compliance 82276408
samples,a copy of this form will be sent to the North Carolina DEHNR {
Certification Office(Le out of hold,incorrect preservative,out of temp, (if no label available)
incorrect containers)
Page 9 of 10'

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DUKE Analytical Lab
Analytical Laboratory Page 1 of 17
ENERGY.
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex- MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Order Number: J15110284
Project Name: MCGUIRE-
Customer Name(s): BILL FORIS,JOSH QUINN
Customer Address: 13225 Hagers Ferry Rd
Mail Code. MG01CH
Huntersville,NC 28078-8985
Lab Contact: Mary Ann Ogle Phone: [phone]
© / Digitally signed by Mary Ann
� Ogle
Report Authorized By: / I Date:2015.11.3011.37:07 Date: 11/30/2015
(Signature) - l -05'00'
Mary Ann Ogle
Program Comments:
Please contact the Program Manager(Mary Ann Ogle)with any questions regarding this report.
Data Flags&Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis(sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative.An estimation of
the uncertainty of measurement for the results in the report is available upon request.This report shall not be reproduced,except
in full,without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions.The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package,Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports&
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody(COC)
Certification:
The Analytical Laboratory holds the following State Certifications: North Carolina(DENR)Certificate#248,South Carolina
(DHEC)Laboratory ID#99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Analytical Lab
Sample ID's & Descriptions: Page 2 of 17
Collection
FSample ID Plant/Station Date and Time Collected By Sample Description
2015036394 MCGUIRE 16-Nov-15 10:06 AM G.LONG MNS Intake 10M
2015036395 MCGUIRE 16-Nov-15 9'07 AM G.LONG MNS Discharge(001)0.3 M
2 Total Samples

Analytical Lab
Page 3 of 17
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals 0 Yes ❑ No
and analyses(compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑� Yes ❑ No
All laboratory QA/QC requirements are acceptable. 0 Yes ❑ No
Report Sections Included:
EVI Job Summary Report 0 Sub-contracted Laboratory Results
Sample Identification ❑ Customer Specific Data Sheets,Reports,&Documentation
❑� Technical Validation of Data Package ❑ Customer Database Entries
❑� Analytical Laboratory Certificate of Analysis R] Chain of Custody
❑Analytical Laboratory QC Report ❑ Electronic Data Deliverable(EDD)Sent Separatel
Reviewed By: Mary Ann Ogle Date: 11/30/2015

Analytical Lab
Certificate of Laboratory Analysis Page 4 of 17
This report shall not be reproduced, except in full.
Order#J15110284
Site: MNS Intake 10M Sample#: 2015036394
Collection Date: 16-Nov-15 10:06 AM Matrix: NPDES
Analyte Result Units Qualifiers RDL DF Method Analysis Daterrime Analyst
TOTAL RECOVERABLE METALS BY ICP-MS
Thallium(TI)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/17/2015 19:54 JAHERMA
METALS ANALYSIS BY VENDOR LAB-(Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Analytical Lab
Certificate of Laboratory Analysis Page 5 of 17
This report shall not be reproduced, except in full.
Order#J15110284
Site: MNS Discharge(001)0.3 M Sample#: 2015036395
Collection Date: 16-Nov-15 9:07 AM Matrix: NPDES
Analyte I Result Units Qualifiers RDL DF Method Analysis Daterrime Analyst
TOTAL RECOVERABLE METALS BY ICP-MS
Thallium(TI)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/17/2015 20.01 JAHERMA
METALS ANALYSIS BY VENDOR LAB-(Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Analytical Lab
Certificate of Laboratory Analysis Page 6 of 17
This report shall not be reproduced, except in full.
Order#J15110284
Level II QC Summary
Q15110299 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank #1
Parameter Measured Final Units: Dil RDL Relative Concentration Qualifier
Thallium(TI)Low Level 0.0051 0.0051 ug/L 1 0.2 <1/2 RDL
LCS #1
Parameter Measured Final Units: Dil Saike %Recovery LCL UCL Qualifier
Thallium(TI)Low Level 488 488 ug/L 1 50 976 85 115
MS #1 Parent Sample: J15110283 -- 2015036393
Parameter Measured Final Units: Dil Soike %Recovery LCL UCL Qualifier
Thallium(TI)Low Level 49 49 ug/L 1 50 97.8 70 130
MSD #1 Parent Sample: J15110283 -- 2015036393
Parameter Measured Final Units: Dil Soike %Recovery LCL UCL RPD Qualifier
Thallium(TI)Low Level 48.6 486 ug/L 1 50 97.1 70 130 0.718

Pa�nal �afeabervlces,Inc.
aceAnalytical ��� �94re. Suite 100
Huntersville,NC 28078
wwwpacelabs,com [phone]
November 23, 2015
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
RE: Project: J15110284
Pace Project No.: 92276412
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on November 17, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Rodney Wike,Duke Energy
ESQ pCc ft,-
_ Fa REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
!q �� without the written consent of Pace Analytical Services,Inc. Page 1 of 10
BORA(4

Pa�nal mtlfE8bervices,Inc.
® ��Q�Ciac�� �e Suite 100
acmnalytical Huntersville,NC 28078
wwwpacelabs com [phone]
CERTIFICATIONS
Project J15110284
Pace Project No, 92276412
Minnesota Certification IDs
1700 Elm Street SE Suite 200,Minneapolis,MN 55414 Minnesota Certification#:027-053-137
A21-A Certification#:2926.01 Mississippi Certification#:Pace
Alaska Certification#:UST-078 Montana Certification#:MT0092
Alaska Certification#MN00064 Nevada Certification#:MN 00064
Alabama Certification#40770 Nebraska Certification#:Pace
Arizona Certification#.AZ-0014 New Jersey Certification#:MN-002
Arkansas Certification# 88-0680 New York Certification#- 11647
California Certification#:011 65C North Carolina Certification#:530
Colorado Certification#Pace North Carolina State Public Health#.27700
Connecticut Certification#:PH-0256 North Dakota Certification#:R-036
EPA Region 8 Certification#:8TMS-L Ohio EPA#:4150
Florida/NELAP Certification#:E87605 Ohio VAP Certification#:CLI 01
Guam Certification#:14-008r Oklahoma Certification#:9507
Georgia Certification#:959 Oregon Certification#.MN200001
Georgia EPD#:Pace Oregon Certification# MN300001
Idaho Certification#.MN00064 Pennsylvania Certification#-68-00563
Hawaii Certification#MN00064 Puerto Rico Certification
Illinois Certification M 200011 Saipan(CNMI)#:MP0003
Indiana Certification#C-MN-01 South Carolina#:74003001
Iowa Certification*368 Texas Certification#:T104704192
Kansas Certification#.E-10167 Tennessee Certification#.02818
Kentucky Dept of Envi.Protection-DW#90062 Utah Certification#:MN000642013-4
Kentucky Dept of Envi.Protection-WW#:90062 Virginia DGS Certification M 251
Louisiana DEQ Certification#:3086 Washington Certification#:C486
Louisiana DHH#:LA140001 West Virginia Certification#:382
Maine Certification#•2013011 West Virginia DHHR#:9952C
Maryland Certification#:322 Wisconsin Certification#:999407970
Michigan DEPH Certification#•9909
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc.. Page 2 of 10

Parn�yW�talfraServlces,Inc.
® IgaVA . Suite 100
aceAnalytical Huntersville,NC 28078
wmpace/abs.com [phone]
SAMPLE ANALYTE COUNT
Project J15110284
Pace Project No.- 92276412
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92276412001 2015036394 EPA 200.8 RJS 1 PASI-M
92276412002 2015036395 EPA 200.8 RJS 1 PASI-M
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc. Page 3 of 10

Paw A t1�8fr8bervlces,Inc.
(� ' ® 098�f'yfy�re. Suite 100
acmnalytical y Huntersville,NC 28078
wwwpace/abs com [phone]
ANALYTICAL RESULTS
Project J15110284
Pace Project No.. 92276412
Sample: 2015036394 Lab ID: 92276412001 Collected- 11/16/15 1006 Received- 11/17/15 14:20 Matrix, Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No Qual
200.8 MET ICPMS Analytical Method:EPA 200.8 Preparation Method.EPA 200.8
Thallium ND ug/L 0.10 1 11/19/1516:31 11/21/1501:43 7440-28-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/23/2015 01:27 PM without the written consent of Pace Analytical Services,Inc. Page 4 of 10

Pa�nai tifcabervlces,Inc.
0q�
® 'jc8yf . Suite 100
aceAnalXical y Huntersvdle,NC 28078
www.pacelabs.com [phone]
ANALYTICAL RESULTS
Project- J15110284
Pace Project No.: 92276412
Sample: 2015036395 Lab ID: 92276412002 Collected, 11/16/15 09:07 Received- 11/17/15 14 20 Matrix. Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
200.8 MET ICPMS Analytical Method:EPA 200.8 Preparation Method EPA 200.8
Thallium ND ug/L 0.10 1 11/19/15 1631 11/21/15 01:24 7440-28-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date.11/23/2015 01:27 PM without the written consent of Pace Analytical Services,Inc. Page 5 of 10

Panal ti�aFrabervlces,Inc.
��O�filigc�f.�e Suite 100
aceAnalytical 9 Huntersville,NC 28078
www.pzicelabs.com [phone]
QUALITY CONTROL DATA
Project J15110284
Pace Project No.. 92276412
QC Batch- MPRP/59801 Analysis Method: EPA 200.8
QC Batch Method. EPA 200.8 Analysis Description. 200 8 MET
Associated Lab Samples- 92276412001,92276412002
METHOD BLANK: 2139956 Matrix: Water
Associated Lab Samples: 92276412001,92276412002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Thallium ug/L ND 0.10 11/21/15 01:15
LABORATORY CONTROL SAMPLE: 2139957
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Thallium ug/L 80 78.3 98 85-115
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2139958 2139959
MS MSD
92276412001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Thallium ug/L ND 80 80 76.5 80.5 96 101 70-130 5
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/23/2015 01:27 PM without the written consent of Pace Analytical Services,Inc Page 6 of 10

® Pan �tglfElbervlces,Inc.
01 SAM. Suite 100
eAnalyticalHuntersville,NC 28078
www.pacelabs.com [phone]ac
QUALIFIERS
Project, J15110284
Pace Project No.. 92276412
DEFINITIONS
DF-Dilution Factor,If reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit.
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit
PQL-Practical Quantitation Limit.
RL-Reporting Limit.
S-Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270 The result for each analyte is
a combined concentration.
Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for,but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvtnyl ether,Styrene,and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute.
LABORATORIES
PASI-M Pace Analytical Services-Minneapolis
i
i
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full.
Date:11/23/2015 01:27 PM without the written consent of Pace Analytical Services,Inc. Page 7 of 10

Pawal tWIfEl bervlces,Inc.
0 �gpt,,�a4 .�e Suite 100
aceAnalytical Hunterswlle,NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project J15110284
Pace Project No.. 92276412
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92276412001 2015036394 EPA 200.8 MPRP/59801 EPA 200.8 ICPM/27608
92276412002 2015036395 EPA 200.8 MPRP/59801 EPA 200.8 ICPM/27608
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/23/2015 01:27 PM without the written consent of Pace Analytical Services,Inc. Page 8 of 10

uocument IVame: 6ut;u111C11t r\OVIZiCU. MCIy IU,
'
Sample Condition U on Receipt SCUR Pae 1 of 2" Analytical La
�_ Vce
A/l��lyticalDocument Number: Issuing Authority: ° ,
F!�-,CHR-CS-003-rev.16 Pace Huntersville QualityOffice
Client fume. I `^ I�� �n��'/� 'Page 2 of 2 Is for Internal Use Only
Courier: ❑ Fed E>❑ UPC] USP❑ Clie CommerciQ lf§
r❑ P�� Other
/ Proj :Diie;pate;;' .;-t=
Custody Seal on Cooler/Box Present: ❑ yes .❑ no - Seals intact: ❑ yes ❑ no
Packing Material: ❑ Bubble Wrap ❑ Bubble-Bags ❑�-N_one ❑ Other
Thermometer Used:IR Gun T.1(1402* Type of Ice: Vy6t Blue None ❑ S' amples on ice,cooling process has begun
Temp Corre`ctlon Factor T140a No Correction
Blolo ical Tissue is Frozen: Yes No N/ � Date and Initials of person examining
Corrected Cooler Temp.: L 'C g � contents: 1. 17"0
Temp should be above freezing to 6°C Comments:
Chain of CustodyPresent: ❑ es ❑No ❑N/A 1.
Chain of Custody ❑Filled Out: es_ ❑No ❑N/A 2.
Chain of Custody Relinquished: ❑ es No ❑N/A 3.
Sampler Name&Si nature on COC: DYes ONo ❑N/A 4.
Samples Arrived within Hold Time: nYe, ❑No ❑N/A 5.
Short Hold Time Analysis(<72hr): ❑Yes Qo NIA 6. :
Rush Turn Around Time Requested: ❑Yes ❑ o ❑WA 7. ;
E
Sufficient Volume: 1!14 ❑No ❑N/A $,
Corfect•Containers Used: 'Yes ❑NNoo ❑N/A 9. °
❑Yes or�O ❑NrA
-Pace Containers Used:
s
1
Containers Intact: Yes ❑No ❑N/A 1
' 4
Filtered volume received for Dissolved tests ❑Yes ❑No ❑NIA 11.
Sample Labels match COC: / Yes ❑No ❑N/A 12.
-Includes date/time/ID/Analysis Matrix:
All containers needing preservation have been checked. s QNo ❑NIA 13.
All containers needing preservation are found to be in ❑Yes ❑No (IN/A
compliance with EPA recommendation.
exceptions: VOA, coliform,TOC,ORG,Wi-DRO(water) ❑Yes 9
Samples checked for dechlorination: ❑Yes ❑No QN/A 14.
Heads ace in VOA Vials >6mm): Oyes ❑No ❑ /A 15.
Trip Blank Present: ❑Yes ❑No ❑N/A 16.
Trip Blank Custody Seals Present ❑Yes ❑No 9'I
Pace Trip Blank Lot#(if purchased):
Client Notification/Resolution: Field Data Required? Y / N
Person Contacted: Datefrime:
Comments/Resolution: p
SCURF Review: Date: ?� q
SRF Review: Date: ft tS't' j 12 '
Note:'Whenever there Is discrepancy affecting Noith Carollna compliance
samples,a copy of this form will be sent to the North Carolina DEHNR 92276412
1 1�Il�JI
Certification Office(i.e out of hold,incorrect preservative,out of temp,
incorrect containers) _
Page 9 of 10

CHAIN OF CUSTODY RECORD AND ANALYSIS REOUEST FORA!
Duke Energy _ ----Enasr un.iyncai ioeoDuke .at«y— --------- ------- _hui—cv I.,b'oro use Only
sm e�rooa.x is wa 740) ; ;Order rf%�,, dx Matrix-NPDES ,,,wiO1y„rw, NC— sG_ i Page 1—Ot_+- DISTRIBUTION
Analytical Laboratory 131*11.p. MRd i /-51 d'
Cham of custody 8 N••�+••�s+N•C.�n ito97•a ay Daa a T 1 ORIGINAL to LAB.COPY t0 CLIENT
sample tug t>se sn.a.s ra SAMPtE PROGRAM
Groudwater NPDES—x—
_.-----•-•-•-•-•-•- •-- --- �, ��g� -- .1 D•:•w:gWet.
Rcruwe�a— Usr_
srar.a NaM. Norman Thallium arii�te '-• -
_cpoIa.T—p(C)._ 10/29!2015
R.e Bill Foris/Josh Quinn W $®to-®
ttration(OAS um);r time a -„�^ b Uttered - b
e,we.w taw; rnC00 ft—BL AKEGN ^•.o cwwrr
?.+SOO Preservative
k..y MGO2A3 _—-- •�'ner Volume(ml-) S00
w.eoar• Lake Nom ; s,.,— MNS Container Type HDPE
sample Description or ID
PLLstomer to eamptefe nff approprwife non^ £` c
-- shxhd
Ma UGi ONI.y— collection kdOrt S— A
Location 1t- Depth t, 5
tab lD Date I Time
� MNS Intake 10m l lltl, I u X
MNS Discharge(001) 0.3 m x r+
I I D
a..
0
I I 0
I I ! I D
io 0
I I 0
D
D
I i D
le I I D
is I 0
Total o I 0 0' o D 2 0 0 0 0 0 0 ! 0 o z
-J
Ree y Date/time ACCepteO Date Ime, 11�1-13 C o Requested Turnaround Total 2
162)
Relirpu Dalarrimo Dote mo ' c
���7 � �d '�,•/ r �/��ff", t'�I /'i jS !�1 a1,�,� c� to Days
/ l c
R ngeiened D."rne A«eeoo�ttaa,66ey: l �/- Datertlrne 9=
7Cays_ X
SeeVLoekM By Onte/time Sealea/l,.ock GWS By Date/rlme �_y /"`-•,!
o to w
t j •OthCr__ n
A00 Cost Will Apply .�• O N
r
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e Analytical Lab
Page 17 of 17
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i
La
DUKE Analytical Laboratory Analytical
of 17
till)ENERGY.
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex- MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Order Number: J15110416
Project Name: MCGUIRE-
Customer Name(s): Josh Quinn
Customer Address 13225 Hagers Ferry Rd
Mail Code: MG01CH
Huntersville,NC 28078-8985
Lab Contact: Mary Ann Ogle Phone: [phone]
� / Digitally signed by Mary
S Ann Ogle
Report Authorized By: / / Date:2015.12.02 12:28:47 Date: 12/2/2015
(Signature) ✓✓ -05,00,
Mary Ann Ogle
Program Comments:
Please contact the Program Manager(Mary Ann Ogle)with any questions regarding this report.
Data Flags&Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis(sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis Is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative.An estimation of
the uncertainty of measurement for the results in the report is available upon request.This report shall not be reproduced,except
in full,without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions.The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package,Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports&
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody(COC)
Certification:
The Analytical Laboratory holds the following State Certifications: North Carolina(DENR)Certificate#248,South Carolina
(DHEC)Laboratory ID#99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

.t
Lab
(�DUKE Analytical Laboratory Analytical
of 17
ENERGY.
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex-MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Order Number: J15110416
Project Name: MCGUIRE-
Customer Name(s): Josh Quinn
Customer Address: 13225 Hagers Ferry Rd
Mail Code: MG01CH
Huntersvllle,NC 28078-8985
Lab Contact. Mary Ann Ogle Phone- 980-875-5274
/ Digitally signed by Mary Ann Ogle
Report Authorized By: Date-2015.12.02 12:28:47 Date: 12/2/2015
(Signature) (� ✓✓✓ -05,00,
Mary Ann Ogle
Program Comments:
Please contact the Program Manager(Mary Ann Ogle)with any questions regarding this report.
Data Flags&Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier Indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis(sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as Information only. Certified vendor results can be found In the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative.An estimation of
the uncertainty of measurement for the results in the report is available upon request.This report shall not be reproduced,except
in full,without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions.The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package,Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports&
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody(COC)
Certification:
The Analytical Laboratory holds the following State Certifications: North Carolina(DENR)Certificate#248, South Carolina
(DHEC)Laboratory ID#99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Analytical Lab
Sample ID's $ Descriptions: Page 2 of 17
Collection
FSample ID Plant/Station Date and Time Collected By Sample Description
2015036967 MCGUIRE 20-Nov-15 8.25 AM G.LONG MINIS Intake 10M
2015036968 MCGUIRE 20-Nov-15 9:02 AM G.LONG MNS Discharge(001)0.3 M
2 Total Samples

Analytical Lab
Page 3 of 17
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals ❑/ Yes ❑ No
and analyses(compliance programs and procedures).
All Results are less than the laboratory reporting limits. F,-/] Yes ❑ No
All laboratory QA/QC requirements are acceptable.
Yes ❑ No
Report Sections Included:
91 Job Summary Report Subcontracted Laboratory Results
Sample Identification ❑ Customer Specific Data Sheets,Reports,&Documentation
❑Technical Validation of Data Package ❑ customer Database Entries
Analytical Laboratory Certificate of Analysis Chain of Custody
❑Analytical Laboratory QC Report ❑ Electronic Data Deliverable(EDD)Sent Separatel
Reviewed By: Mary Ann Ogle Date: 12/2/2015

Analytical Lab
Certificate of Laboratory Analysis Page 4 of 17
This report shall not be reproduced, except in full.
Order#J15110416
Site: MNS Intake 10M Sample#: 2015036967
Collection Date: 20-Nov-15 8:25 AM Matrix: NPDES
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
TOTAL RECOVERABLE METALS BY ICP-MS
Thallium(TI)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/25/2015 15:30 MHALL3
METALS ANALYSIS BY VENDOR LAB-(Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Analytical Lab
Certificate of Laboratory Analysis Page 5 of 17
This report shall not be reproduced, except in full.
Order#J15110416
Site: MNS Discharge(001)0.3 M Sample#: 2015036968
Collection Date: 20-Nov-15 9:02 AM Matrix: NPDES
Analyte Result Units Qualifiers RDL DF Method Analysis Daterrime Analyst
TOTAL RECOVERABLE METALS BY ICP-MS
Thallium(TI)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/25/2015 15:09 MHALL3
METALS ANALYSIS BY VENDOR LAB-(Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Analytical Lab
Certificate of Laboratory Analysis Page 6 of 17
This report shall not be reproduced, except in full.
Order#J15110416
Level II QC Summary
Q15110428 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank #I
Parameter Measured Final Units: Dil RDL Relative Concentration Qualifier
Thallium(TI)Low Level -0.0287 -0.0287 ug/L 1 0.2 <1/2 RDL
LCS #1
Parameter Measured Final Units- Dil Spike %Recovery LCL UCL Qualifier
Thallium(TI)Low Level 49 49 ug/L 1 50 98 85 115 -
MS #1 Parent Sample: JI 5110416 -- 2015036968
Parameter Measured Final Units ail Spike %Recovery LCL UCL Qualifier
Thallium(TI)Low Level 48.8 48.8 ug/L 1 50 97.5 70 130 -
MSD #1 Parent Sample: JI 5110416 -- 2015036968
Parameter Measured Final Units: Dil Spike %Recovery LCL UCL RPD Qualifier
Thallium(TI)Low Level 48.7 48.7 ug/L 1 50 97.3 70 130 0.226

Pa�naTyyt1�8f�8dervices,Inc.
ga(f�;a9 ;. Suite 100
aceAnalyticalj �yJHunterswlle,NC 28078
www.pacelabs com [phone]
December 01, 2015
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
RE: Project: J15110416
Pace Project No.: 92277157
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on November 20, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
(::�- - � -—
Chris Bishop for
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Rodney Wike,Duke Energy
pccgF��
r c REPORT OF LABORATORY ANALYSIS
x�
This report shall not be reproduced,except in full,
gepRA��
without the written consent of Pace Analytical Services,Inc. Pagel of 10

Parr tI�2Fr&bervlces,Inc.
0 W��'ki&p. Suite 100
aceAnalytical
Huntersville,NC 28078
www.pacelabs com [phone]
CERTIFICATIONS
Project: J15110416
Pace Project No.: 92277157
Minnesota Certification IDs
1700 Elm Street SE Suite 200,Minneapolis,MN 55414 Minnesota Certification#:027-053-137
A21-A Certification#:2926.01 Mississippi Certification#:Pace
Alaska Certification#:UST-078 Montana Certification#:MT0092
Alaska Certification#MN00064 Nevada Certification#:MN 00064
Alabama Certification#40770 Nebraska Certification*'Pace
Arizona Certification#:AZ-0014 New Jersey Certification#•MN-002
Arkansas Certification#.88-0680 New York Certification#:11647
California Certification#:01155CA North Carolina Certification#:530
Colorado Certification#Pace North Carolina State Public Health#:27700
Connecticut Certification#:PH-0256 North Dakota Certification#:R-036
EPA Region 8 Certification#:8TMS-L Ohio EPA*4150
Florida/NELAP Certification#:E87605 Ohio VAP Certification#•CL101
Guam Certification#.14-008r Oklahoma Certification#:9507
Georgia Certification#:959 Oregon Certification#.MN200001
Georgia EPD#:Pace Oregon Certification#.MN300001
Idaho Certification#:MN00064 Pennsylvania Certification#:68-00563
Hawaii Certification#MN00064 Puerto Rico Certification
Illinois Certification#:200011 Saipan(CNMI)#:MP0003
Indiana Certification#C-MN-01 South Carolina#:74003001
Iowa Certification#:368 Texas Certification#:T104704192
Kansas Certification#:E-10167 Tennessee Certification#:02818
Kentucky Dept of Envi.Protection-DW#90062 Utah Certification#:MN000642013-4
Kentucky Dept of Envi.Protection-WW#:90062 Virginia DGS Certification#:251
Louisiana DEQ Certification#:3086 Washington Certification#.C486
Louisiana DHH#-LA140001 West Virginia Certification#:382
Maine Certification#:2013011 West Virginia DHHR#:9952C
Maryland Certification#:322 Wisconsin Certification#:999407970
Michigan DEPH Certification#:9909
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc. Page 2 of 10

ParalytWIFrabervlces,Inc.
® �$gg,;a�,.;. Suite 100
acmnalytical Huntersville,NC 28078
wmpacefabs com [phone]
SAMPLE ANALYTE COUNT
Project J15110416
Pace Project No.. 92277157
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92277157001 2015036967 EPA 200.8 TT3 1 PASI-M
92277157002 2015036968 EPA 200.8 TT3 1 PASI-M
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Seances,Inc. Page 3 of 10

Parr ti�aFrabervlces,Inc.
0 �lQ�Kli acfj;e. Suite 100
acmnalytical Huntersville,NC 28078
www.pacelabs.com [phone]
ANALYTICAL RESULTS
Project J15110416
Pace Project No: 92277157
Sample: 2015036967 Lab ID: 92277157001 Collected: 11/20/150825 Received. 11/20/1514.45 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
200.8 MET ICPMS Analytical Method:EPA 200.8 Preparation Method.EPA 200.8
Thallium ND ug/L 0.10 1 11/24/15 10:10 11/24/15 2020 7440-28-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full.
Date 12/0112015 11:04 AM without the written consent of Pace Analytical Services,Inc Page 4 of 10

Pa�nal tl�aFtabervlces,Inc.
aceAnalytical® � ��Hunter.�e Suite
Huntersville,NC 28078
www.pacelabs.com [phone]
ANALYTICAL RESULTS
Project J15110416
Pace Project No.. 92277157
Sample: 2015036968 Lab ID: 92277157002 Collected, 11/20/15 09:02 Received- 11/20/15 14.45 Matrix-Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
200.8 MET ICPMS Analytical Method:EPA 200 8 Preparation Method:EPA 200.8
Thallium ND ug/L 010 1 11/24/151010 11/24/1520:37 7440-28-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:12/01/2015 11:04 AM without the written consent of Pace Analytical Services,Inc. Page 5 of 10

i Pa�naT tWiftl bervlces,Inc.
e 0�Q�Kti�rp. Suite 100
aceAnalytical y Huntersville,NC 28078
www pacelabs com [phone]
QUALITY CONTROL DATA
Project J15110416
Pace Project No.: 92277157
QC Batch: MPRP/59896 Analysis Method: EPA 200 8
QC Batch Method EPA 200.8 Analysis Description- 200.8 MET
Associated Lab Samples: 92277157001,92277157002
METHOD BLANK: 2142955 Matrix: Water
Associated Lab Samples: 92277157001,92277157002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Thallium ug/L ND 0.10 11/24/15 20.09
LABORATORY CONTROL SAMPLE: 2142956
Spike LCS LCS %Rec
Parameter Units Conc Result %Rec Limits Qualifiers
Thallium ug/L 80 86.6 108 85-115
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2142957 2142958
MS MSD
92277157001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Thallium ug/L ND 80 80 88.0 88.7 110 111 70-130 1
Results presented on this page are in the units Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:12/01/2015 11:04 AM without the written consent of Pace Analytical Services,Inc. Page 6 of 10

Pa�nal �if�l tervlces,Inc.
acmnalXical® ��� Huntet'f`lle Suite 100
078
Huntersville,NC 28078
www.pacelabs.com [phone]
QUALIFIERS
Project: J15110416
Pace Project No.: 92277157
DEFINITIONS
DF-Dilution Factor,if reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit.
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL-Practical Quantitation Limit.
RL-Reporting Limit
S-Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is
a combined concentration.
Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for,but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether,Styrene,and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270 The result reported for
each analyte is a combined concentration
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute.
LABORATORIES
PASI-M Pace Analytical Services-Minneapolis
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:12/01/2015 11:04 AM without the written consent of Pace Analytical Services,Inc Page 7 of 10

Pa�nal atifri bervices,Inc.
® ��Q�Kli a4 �re Suite 100
acmnalXical Huntersvdle,NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project J15110416
Pace Project No.. 92277157
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92277157001 2015036967 EPA 200.8 MPRP/59896 EPA 200.8 ICPM/27653
92277157002 2015036968 EPA 200.8 MPRP/59896 EPA 200.8 ICPM/27653
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:12/01/2015 11:04 AM without the written consent of Pace Analytical Services,Inc. Page 8 of 10

Document Name: Document Revised: Nove s oP 15
aceMalytica!° Sample Condltion U on Recei t SCUR -Pa e-1 of 2* ;
Document Number: Issuing Authority:
F-CHR-CS-003-rev.16A = Pace Huntersville Quality Office
Client fume: vJU`:K 0 *Page 2 of 21s for Internal Use Only
Courier: ❑ Fed E>❑ UP❑ USP[] ClierComnerci� Pace Other
. O`tlona/-�•��•;.-<',;:��::,s'�Y''� ,
CustodySeal on Cooler/Box Present:
❑ yes� no Seals Intact: ❑ yes ❑ no
Packing Material: ❑ Bubble Wrap ❑ Bubble Bags Qf None❑ -OtherT
Thermometer Used:IR•Gun T1505 Type of Ice: Wet Blue No� ❑ Samples on Ice,cooling process has begun .
Temp Correction Factor No Correction
Biolo ical•Tissue is Frozen: Yes No N/A Date an nitiats.Qf p r n examining
'orrected Cooler Temp.: 'C g Conten V 11
Temp should be above freezing to 6°C Comments:
,hain of Custody Present: (ayes ONO- ON/A' 1.' ,
,hain of Custody Filled Out: - j2Yes ❑No ❑N/A 2,'
'hain of Custody Relinquished: 9)Kes ONO ❑N/A 3.
Sam ler Name&Si nafure on COC: es ONO ❑NIA 4.
Sam les Arrived within Hold-Time: 0< ONO ❑NIA S.
Short Hold Time Analysis' (<72hr): Dyes 1311 o" 0,N/A 6.- ;
tush Turn Around Time Requested: byes &4o' ❑NiA 7,
Sufficient Volume: ries .❑No ❑N/A 8.
:orrect Containers Used: 134es ONO ON/A g,. -
-Pace Containers Used: ❑Yes ❑N /❑N/A -
:ontainers Intact: B�Yes ONO ❑N/A 10.
iltered volume received for Dissolved tests ❑Yes ❑No" N/A 11.
ample Labels match COC: -JffYes ONO ❑NIA 12.
-Includes date/time/ID/Analysis Matrix:
II containers needing preservation have been checked. '
k7Yes ONO ❑NiA 13.
II containers needing preservation are found to be In ONO ❑NIA
)mpliance with EPA recommendation.
:captions: VOA, coliform,70C,0&G,WI-ilRO(water) ❑Yes ONO
am les checked for dechlorination: OYes ONO ❑ A 14.
Bads ace in VOA Vials >6mm : ❑Yes ONO a 15.
rip Blank Present: ❑Yes ONaNIA 16.
rip Blank Custody Seals Present ❑Yes ONO ❑NIA
ace Trip Blank Lot# Ifpurchased):
------------
lient Notification/Resolution: Field Data Required? Y I N
Person Contacted: Date/Time:
Comments/Resolution:
CURF Review: Date: It/719� �® 0 92277157-
e ..
SRF Rview: Date: H Z//�
Jote: Whenever there is a discrepancy affecting Notch Carolina compliance
samples,a copy of this form will be-sent to the North Carolina DEHNR
Certification Office(i.e out of hold,incorrect preservative,out of temp, 92277157 Page 9 of 10
Incorrect containers) -

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DUKE Analytical Lab
ENERGY, Analytical Laboratory Page 1 of 17
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex- MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Order Number: J15110441
Project Name: MCGUIRE-
Customer Name(s): BILL FORIS,JOSH QUINN
Customer Address: 13225 Hagers Ferry Rd
Mail Code- MG01CH
Huntersville,NC 28078-8985
Lab Contact: Mary Ann Ogle Phone: [phone]
/ Digitally signed by Mary
Ann Ogle
Report Authorized By: ��/ / Date:2015.12.0410:41:42 pate: 12/4/2015
(Signature) (/ ✓✓✓ -05'00'
Mary Ann Ogle
Program Comments:
Please contact the Program Manager(Mary Ann Ogle)with any questions regarding this report.
Data Flags&Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis(sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative.An estimation of
the uncertainty of measurement for the results in the report is available upon request.This report shall not be reproduced, except
in full,without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions.The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package,Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports&
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody(COC)
Certification:
The Analytical Laboratory holds the following State Certifications: North Carolina(DENR)Certificate#248, South Carolina
(DHEC)Laboratory ID#99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Analytical Lab
Sample ID's & Descriptions: Page 2 of 17
Collection
FSample ID Plant/Station Date and Time Collected By Sample Description
2015037088 MCGUIRE 23-Nov-15 10:40 AM Josh Quinn MNS Intake 10M
2015037089 MCGUIRE 23-Nov-15 11:30 AM Josh Quinn MINIS Discharge(001)0.3 M
2 Total Samples

Analytical Lab
Page 3 of 17
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals ❑v Yes ❑ No
and analyses(compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes F,/� No
All laboratory QA/QC requirements are acceptable.
0 Yes ❑ No
Report Sections Included:
O Job Summary Report Sub-contracted Laboratory Results
Y]Sample Identification ❑ Customer Specific Data Sheets,Reports,&Documentation
RI Technical Validation of Data Package ❑ Customer Database Entries
RJ Analytical Laboratory Certificate of Analysis ❑ Chain of Custody
❑Analytical Laboratory QC Report ❑ Electronic Data Deliverable(EDD)Sent Separatel
Reviewed By. Mary Ann Ogle Date- 12/4/2015

Analytical Lab
Certificate of Laboratory Analysis Page 4 of 17
This report shall not be reproduced, except in full.
Order#J15110441
Site: MNS Intake 10M Sample#: 2015037088
Collection Date: 23-Nov-15 10:40 AM Matrix: NPDES
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
TOTAL RECOVERABLE METALS BY ICP-MS
Thallium(TI)Low Level <0.2 ug/L 0.2 1 EPA 200 8 11/25/2015 16 33 MHALL3
METALS ANALYSIS BY VENDOR LAB-(Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Analytical Lab
Certificate of Laboratory Analysis Page 5 of 17
This report shall not be reproduced, except in full.
Order#A 5110441
Site: MNS Discharge(001)0.3 M Sample#: 2015037089
Collection Date: 23-Nov-15 11:30 AM Matrix: NPDES
Analyte Result Units Qualifiers RDL DF Method Analysis Daterrime Analyst
TOTAL RECOVERABLE METALS BY ICP-MS
Thallium(TI)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/25/2015 16:12 MHALL3
METALS ANALYSIS BY VENDOR LAB-(Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Analytical Lab
Certificate of Laboratory Analysis Page 6 of 17
This report shall not be reproduced, except in full.
Order#J15110441
Level II QC Summary
Q15110456 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank #1
Parameter Measured Final Units: Dil RDL Relative Concentration Qualifier
Thallium(TI)Low Level -0.0311 -0.0311 ug/L 1 0.2 <1/2 RDL
LCS #1
Parameter Measured Final Units: Dil Soike %Recovery LCL UCL Qualifier
Thallium(TI)Low Level 49.4 49.4 ug/L 1 50 98.8 85 115
MS #1 Parent Sample: J15110441 -- 2015037089
Parameter Measured Final Units Dil Soike %Recovery LCL UCL Qualifier
Thallium(TI)Low Level 49.7 49.7 ug/L. 1 50 99.4 70 130
MSD #1 Parent Sample: J15110441 -- 2015037089
Parameter Measured Final Units: Dil Soike %Recovery LCL UCL RPD Qualifier
Thallium(TI)Low Level 48.6 48.6 ug/L 1 50 97.2 70 130 2.22 -

Pa�nal �if ri tervlces,Inc.
aceAnalytical® ���Hunter�e Suite 100
078
Huntersville,NC 28078
wKw.pacelabs.com [phone]
December 03, 2015
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
RE: Project: J15110441
Pace Project No.: 92277438
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on November 24, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
-K—
Kevin
{K-Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Rodney Wike,Duke Energy
pCCRF��
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
gepRplp
without the written consent of Pace Analytical Services,Inc, Page 1 of 10

Pa�nalyKtlxBFeebervlces,Inc.
® IgaPa Y� - Suite 100
acmnalytical Huntersville,NC 28078
www.pacelabs.com [phone]
CERTIFICATIONS
Project J15110441
Pace Project No.: 92277438
Minnesota Certification IDs
1700 Elm Street SE Suite 200,Minneapolis,MN 55414 Minnesota Certification#:027-053-137
A21-A Certification#:2926.01 Mississippi Certification#.Pace
Alaska Certification#:UST-078 Montana Certification#:MT0092
Alaska Certification#MN00064 Nevada Certification#:MN 00064
Alabama Certification#40770 Nebraska Certification#•Pace
Arizona Certification#:AZ-0014 New Jersey Certification#'MN-002
Arkansas Certification#:88-0680 New York Certification#:11647
California Certification#•01155C North Carolina Certification#:530
Colorado Certification#Pace North Carolina State Public Health#:27700
Connecticut Certification#•PH-0256 North Dakota Certification#:R-036
EPA Region 8 Certification#:8TMS-L Ohio EPA*4150
Florida/NELAP Certification#:E87605 Ohio VAP Certification#:CL101
Guam Certification#:14-008r Oklahoma Certification#.9507
Georgia Certification#:959 Oregon Certification# MN200001
Georgia EPD#:Pace Oregon Certification# MN300001
Idaho Certification#.MN00064 Pennsylvania Certification#:68-00563
Hawaii Certification#MN00064 Puerto Rico Certification
Illinois Certification#:200011 Saipan(CNMI)#:MP0003
Indiana Certification#C-MN-01 South Carolina#:74003001
Iowa Certification#:368 Texas Certification#:T104704192
Kansas Certification# E-10167 Tennessee Certification#:02818
Kentucky Dept of Envi.Protection-DW#90062 Utah Certification#:MN000642013-4
Kentucky Dept of Envi.Protection-WW#:90062 Virginia DGS Certification#.251
Louisiana DEQ Certification#:3086 Washington Certification#:C486
Louisiana DHH#:LA140001 West Virginia Certification#•382
Maine Certification#•2013011 West Virginia DHHR#•9952C
Maryland Certification#:322 Wisconsin Certification#:999407970
Michigan DEPH Certification#:9909
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc.. Page 2 of 10

Pa�nal ginat1F&bervlces,Inc.
aceAnalytical ���Hunter fte Surte 100
Hunterswlle,NC 28078
www pacelabs com [phone]
SAMPLE ANALYTE COUNT
Project: J15110441
Pace Project No. 92277438
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92277438001 2015037088 EPA 200.8 RJS 1 PASI-M
92277438002 2015037089 EPA 200 8 RJS 1 PASI-M
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc. Page 3 of 10

Pa�nalq2FEabervlces,Inc.
® O$Q�Kligc M-- Suite 100
aceAnalytical y Huntersville,NC 28078
—pacelabaoom [phone]
ANALYTICAL RESULTS
Project: J15110441
Pace Protect No.: 92277438
Sample: 2015037088 Lab ID: 92277438001 Collected, 11/23/1510:40 Received: 11124/15 13 45 Matrix, Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[
200.8 MET ICPMS Analytical Method-EPA 200 8 Preparation Method.EPA 200.8
Thallium ND ug/L 010 1 12/02/15 1040 12/02/15 23 32 7440-28-0
t
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date.12/03/2015 04.27 PM without the written consent of Pace Analytical Services,Inc. Page 4 of 10

Pam A ti�a��abervlces,Inc.
t.100
acmnalXical® ����Hunter~vire Sui28078
Huntersville,NC 28078
www.pacelabs com [phone]
ANALYTICAL RESULTS
Project J15110441
Pace Project No.: 92277438 ,
Sample: 2015037089 Lab ID: 92277438002 Collected: 11/23/15 11:30 Received- 11/24/15 1345 Matrix Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
200.8 MET ICPMS Analytical Method:EPA 200.8 Preparation Method:EPA 200.8
Thallium ND ug/L 0.10 1 12/02/15 10:40 12/02/15 23.37 7440-28-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date.12/03/2015 04:27 PM without the written consent of Pace Analytical Services,Inc. Page 5 of 10

Pa�nal tWifel bervices,Inc.
® �,pv,ia4, . Suite 100
1�5acl
Analytical tJ Huntersville,NC 28078
wwwpacefabs com [phone]
QUALITY CONTROL DATA
Project- J15110441
Pace Project No.. 92277438
QC Batch- MPRP/60028 Analysis Method: EPA 200 8
QC Batch Method. EPA 200.8 Analysis Description 200.8 MET
Associated Lab Samples: 92277438001,92277438002
METHOD BLANK: 2147104 Matrix: Water
Associated Lab Samples: 92277438001,92277438002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Thallium ug/L ND 0.10 12/02/15 23:28
LABORATORY CONTROL SAMPLE: 2147105 a
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Thallium ug/L 80 785 98 85-115
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2147106 2147107
MS MSD
92277715001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc Conc. Result Result %Rec %Rec Limits RPD Qual
Thallium ug/L 0.028J 80 80 82.6 80.4 103 100 70-130 3
Results presented on this page are in the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:12/03/2015 04:27 PM without the written consent of Pace Analytical Services,Inc. Page 6 of 10

Pa�nal tl�if tl tervlces,Inc.
100
5. acieAnalytical ' e Suite 078
Huntersville,NC 26078
wwwpacelabs com [phone]
QUALIFIERS
Project- J15110441
Pace Project No.. 92277438
DEFINITIONS
DF-Dilution Factor,if reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL-Practical Quantitation Limit.
RL-Reporting Limit.
S-Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270 The result for each analyte is
a combined concentration.
Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for,but not detected
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether,Styrene,and Vinyl chloride
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260. -
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamme using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute.
LABORATORIES
PASI-M Pace Analytical Services-Minneapolis
REPORT OF LABORATORY ANALYSIS
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Date:12/03/2015 04:27 PM without the written consent of Pace Analytical Services,Inc Page 7 of 10

Pae tl 1 ervlces,Inc.
® ulna i�aF�a
aceAnalytical �$��Hunter P. Suite 100
Huntersville,NC 28078
—pacela6scom [phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project J15110441
Pace Project No.: 92277438
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92277438001 2015037088 EPA 200.8 MPRP/60028 EPA 200.8 ICPM/27731
92277438002 2015037089 EPA 200.8 MPRP/60028 EPA 200.8 ICPM/27731
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:12/03/2015 04:27 PM without the written consent of Pace Analytical Services,Inc. Page 8 of 10

Document Name: Document Revised: Noveml)Kal�AflLlfb
Y. aceAnalytic�a!' Sample Condition Upon Receipt SCUR Pae 1 of 2* Page 15 of 17
Document Number: ., Issuing Authority:
F-CHR-CS-003-rev.16.1, Pace Huntersville.Qualit Office {
lent name. Page 2 of 2 is for Internal Use Only i
ourier: ❑ Fed E>❑ UPC] USP[] Cller❑ CQmrnercIQ ac Other
Pr.`a b o Ce x
ustody Seal on Cooler/Box Present: ❑ yes no Seals intact:. yes ❑ no
acking Material: ❑ Bubble Wrap- ❑ Bubble Bags [3'.None❑ .Other
iermometer Used:IR Gun r160,6,/ Type of Ice: N et -Bltle, None samples on ice,cooling process h'as begun ;
)mp Correction Factor No Correction
It I
Biolo ical Tissue is Frozen: Yes Date and Initials of person examinin
orrected Cooler Temp.: G� 'C g contents:, % P •/!-�I'
:mp should be above freezing to 8°C Comments:
lain of Custody Present: ❑ es ❑No ❑NIA 1.•
iain of Custody Filled Out: es No ❑NIA 2. {
lain of Custody Relinquished; Of,. Oyo ❑N/A 3.-
tm ler Name&Signature on COC: Dv s ❑No -NiA 4.
im les Arrived within Hold.Time: res ❑No, ON/A'
5.
sort Hold Time Analysis(<72hr): ❑Yes ❑ o ❑NIA 6.-
• ' 3
i
rsh Turn Around Time Requested: Oyes b�o ❑wA 7.
ifficlent Volume: ❑ es ❑No ,❑WA 8.
rrrect Containers Used: 01es ❑r. ON1A
NIA 9. '
-Pace Containers Used: ❑Yes
intainers•Intact: ❑Yes ❑No ❑NIA 10.
tered volume received for Dissolved tests OYejATNo OWK 11.
mple Labels match COC: - Y's /❑No ❑NIA 12. 4
-Includes dateltimellD/Analysis Matrix: w I/
,onlalners needing preservation have been checked. QY-es�'I No ❑NIA 13.
containers needing preservation are found'to be in yes
0 ❑NIA
npllancewith EPA.recommendation.
3piions: VOA, coliform,TOC,0&G,Wi-DRO(water) ❑Yes 120-0
,
m les checked for dechlorination: ❑Yes ❑No ErNA4,14.
ads ace in VOA Vials >6mm : ❑Yes []No 17KIA,15.
Blank Present: ❑Yes ❑No NiA 8.
i Blank Custody Seals Present ❑Yes ❑No IINIA
±e Trip Blank Lot# if purchased):
ent Notification/Resolution: Field Data Required? Y / N
Person'Contacted: Datefrime:
omments7 Resolution:
URF Review: Date: tl�2 1' Wt.- 92.277 /03 `
SRF Review: •' Date: III 2 t — �II���� �i�� I�� I��I �I III•
rte: Whenever there Is a discrepancy affecting North Carolina compliance
samples,a copy of this form wfll be sent to the North Carolina DEHNR 82277438 ,
Certification Office(i.e out of bold,Incorrect preservative,out of temp, ratr no taoel avaual)le) Page 9 of 10
incorrect containers) g

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r I Duke Energy Did a Erorgy AnatyCcai 4+horaicry_._ _ Ahs-'ticat(aAorSl.lllae
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Analytical Laboratory--._ ----------
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Cnotn of Custody 6 h.waay n.c,tarn - (>aN a rrm ORIGINAL to LAB,COPY to CLIENT
.T�; Semple Lop pal a7ssaas a arssmrr F.c t, I i-7 - 1 S (.�LrO SAMPLE PROGRAM
Ground waw_ NPDES-%_.
c Cu -._.-•_ •_._._.- - '-------- _ Fnorr•e: J, o-"water
UST ti• y ..:r,r-;,-s«
v.at-.— Norman Thallium f�m�pl� �<?:4•�. _
Q - )ssxt I Y'YYhi I RCRA Wash— l,5`w•>... -a-t�' ., `J:<:A'_..;YL:!..-"yi
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Sample Description or ID ;j
MauSE oagY Coliecdon lnforfnaon
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Location✓ Depth o t
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i7�•1SG .T; MNS Intake tom 1('j•�'._1 r :�(�
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