NC0020605_Renewal (Application)_20240402 (2)

ROY COOPER
Governor
ELIZABETH S. BISER
Secretary
RICHARD E. ROGERS, JR.
Director
Troy Lewis
Town of Tarboro
PO Box 220
Tarboro, NC 27886-0220
Subject: Permit Renewal
Application No. NCO020605
Tarboro WWTP
Edgecombe County
Dear Applicant:
NORTH CAROLINA
Environmental Quality
April 02, 2024
The Water Quality Permitting Section acknowledges the April 2, 2024 receipt of your permit renewal application and
supporting documentation. Your application will be assigned to a permit writer within the Section's NPDES WW permitting
branch. Per G.S. 150E-3 your current permit does not expire until permit decision on the application is made.
Continuation of the current permit is contingent on timely and sufficient application for renewal of the current permit. The
permit writer will contact you if additional information is required to complete your permit renewal. Please respond in a
timely manner to requests for additional information necessary to allow a complete review of the application and renewal
of the permit.
Information regarding the status of your renewal application can be found online using the Department of Environmental
Quality's Environmental Application Tracker at:
https://www.deg.nc.gov/permits-rules/environmental-application-tracker
If you have any additional questions about the permit, please contact the primary reviewer of the application using the
links available within the Application Tracker.
Sincerely
i
Cynthia Demery
Administrative Assistant
Water Quality Permitting Section
ec: WQPS Laserfiche File w/application
North Carolina Department of Environmental Quality I Division of Water Resources
4AMRaklgh Regional Office 1 3800 Barrett Drive I Raleigh. North Carohm 27609
919.791.4200

Town of Tarboro
500 N Main Street, PO Box 220, Tarboro, NC 27886 (P) 252.641.4200 (F) 252.641.4286
May 15, 2019
NC DEQ
Division of Water Quality, NPDES Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Re: NPDES Permit Renewal Application
Permit No. NCO020605
Dear Application Reviewer:
RECEIVED
ArK 02 Z024
NCDEQ/DWR/NPDES
The letter is to confirm that The Wooten Company is the Town of Tarboro's Authorized
Representative in preparing the NPDES Permit Renewal Application.
I certify under penalty of law that this document and all attachments were prepared under
my direction and supervision in accordance with a system designed to assure that
qualified personnel properly gather and evaluated the information submitted. Based on
my inquiry of the person or persons who manage the system or those persons directly
responsible for gathering the information, the information is, to the best and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting
false information, including the possibility of fine and imprisonment for knowing
violations.
If you need additional information, please contact me at [phone].
Sincerely,
JTroy R. Lewis
Town Manager

Application for Renewal of
NPDES Permit No. NCO020605
Town of Tarboro, North Carolina
March 2024
Prepared by:
The Wooten Company
301 West 14th Street
Greenville, North Carolina 27834
[phone]

EPA Identification Number
NPDES Permit Number
Facility Name
Form Approved 03/05/19
110022546146
NCO020605
Tarboro WWTP
OMB No.2040-0004
Form
U.S. Environmental Protection Agency
2A=EPA
vo
Application for NPDES Permit to Discharge Wastewater
NPDES
NEW AND EXISTING PUBLICLY OWNED TREAT ENT WORKS
SECTION•N
INFORMATION FOR r
Facility name
1.1
Town of Tarboro Wastewater Treatment Plant
Mailing address (street or P.O. box) 0 �1 24
P.O. Box 220
City or town
State g v' C
-WP/N
0
r
Tarboro
NC
PID
€
Contact name (first and last)
Title
Phone number
Email address
Troy R. Lewis
Town Manager
[phone]
[e-mail]
Location address (street, route number, or other specific identifier) ❑ Same as mailing address
U-
Service Road off 268/Highway 64 Junction
City or town
State
ZIP code
Tarboro
NC
27886
1.2
Is this application for a facility that has yet to commence discharge?
❑ Yes 4 See instructions on data submission ❑ No
requirements for new dischargers.
1.3
Is applicant different from entity listed under Item 1.1 above?
❑ Yes No 4 SKIP to Item 1.4.
Applicant name
C
Applicant address (street or P.O. box)
0
A
City or town
State
ZIP code
c
w
Contact name (first and last)
Title
Phone number
Email address
n
c-
a
1.4
Is the applicant the facility's owner, operator, or both? (Check only one response.)
❑ Owner ❑ Operator 0 Both
1.5
To which entity should the NPDES permitting authority send correspondence? (Check only one response.)
❑ Facility ❑ Applicant 0 Facility and applicant
(they are one and the same)
1.6
Indicate below any existing environmental permits. (Check all that apply and print or type the corresponding permit
y
number for each.
Existing Environmental Permits
IL
0 NPDES (discharges to surface
❑ RCRA (hazardous waste)
❑ UIC (underground injection
c
water)
control)
E
NCO020605
❑ PSD (air emissions)
❑ Nonattainment program (CAA)
❑ NESHAPs (CAA)
c
W
C1
❑ Ocean dumping (MPRSA)
❑ Dredge or fill (CWA Section
❑r Other (specify)
)
w
WQ0003047
S
EPA Form 3510-2A (Revised 3-19) Page 1

EPA Identification Number
NPDES Permit Number
Facility Name
Form Approved 03/05/19
110022546146
NCO020605
Tarboro WWTP
OMB No. 2040-0004
1.7
Provide the collections stem information requested below for the treatment works.
Municipality
Population
Collection System Type
Status
Served
Served
indicatepercentage)Ownership
Town of Tarboro
10,569
100 % separate sanitary sewer
0 Own I]Maintain
Z%
combined storm and sanitary sewer
❑ Own ❑ Maintain
❑ Unknown
❑ Own ❑ Maintain
100 % separate sanitary sewer
❑ Own 0 Maintain
O
Edgecombe Co.
WSD no. 6
1,246
% combined storm and sanitary sewer
❑ Own ❑ Maintain
0
( Town of
❑ Unknown
❑ Own ❑ Maintain
100 % separate sanitary sewer
❑ Own I] Maintain
ao
Edgecombe CO.
WSD No.S
270
/o ° combined storm and sanitary sewer
❑ Own ❑ Maintain
16
❑ Unknown
❑ Own ❑ Maintain
d%
separate sanitary sewer ❑ Own ❑ Maintain
N%
combined storm and sanitary sewer ❑ Own ❑ Maintain
c
1
❑ Unknown ❑ Own ❑ Maintain
Total
;
Population
12,085
c�
Served
Separate Sanitary Sewer System Combined Storm and
Sanitary Sewer
Total percentage of each type of
100 % °
�°
sewer line in miles
z'
1.8
Is the treatment works located in Indian Country?
c
o
❑ Yes 0 No
CU
1.9
Does the facility discharge to a receiving water that flows through Indian Country?
❑ Yes 0 No
1.10
Provide design and actual flow rates in the designated spaces.
Design Flow Rate
5.0 mgd
r
Annual Average Flow Rates Actual
a
Two Years Ago
Last Year
This Year
c
1.537 mgd
1.529 mgd
1.529 mgd
_0
Maximum Daily Flow Rates Actual
Two Years Ago
Last Year
This Year
3.197 mgd
5.599 mgd
5.599 mgd
H
1.11
Provide the total number of effluent discharge points to waters of the United States by type.
Total Number of Effluent Discharge Points b T e
o CL
Combined Sewer
Constructed
rn F
Treated Effluent
Untreated Effluent
Overflows
Bypasses
Emergency
s
Overflows
_A
G
1
0
0
0
0
EPA Form 3510-2A (Revised 3-19) Page 2

EPA Identification Number
NPDES Permit Number
Facility Name
Form Approved 03105119
110022546146
NCO020605
Tarboro WWTP
OMB No. 2040-0004
Outfalls Other Than to Waters of the United States
1.12
Does the POTW discharge wastewater to basins, ponds, or other surface impoundments that do not have outlets for
discharge to waters of the United States?
❑ Yes ❑✓ No -+ SKIP to Item 1.14.
1.13
Provide the location of each surface impoundment and associated discharge information in the table below.
Surface Im oundment Location and Dischar a Data
Average Daily Volume
Continuous or Intermittent
Location
Discharged to Surface
(check one)
Impoundment
❑ Continuous
gpd
❑ Intermittent
❑ Continuous
gpd
❑ Intermittent
❑ Continuous
gpd
y
❑ Intermittent
1.14
Is wastewater applied to land?
2
❑ Yes 0 No 4 SKIP to Item 1.16.
c
1.15
Provide the land application site and discharge data requested below.
y
Land Application Site and Discharge Data
o
Continuous or
0
Location
Size
Average Daily Volume
Intermittent
Applied
check one
cc
acres
d
gpd
❑ Continuous
o
❑ Intermittent
El Continuous
o
acres
gp d
❑ Intermittent
0T
acres
gpd
❑ Continuous
❑ Intermittent
1.16
Is effluent transported to another facility for treatment prior to discharge?
o
❑ Yes ❑✓ No + SKIP to Item 1.21.
1.17
Describe the means by which the effluent is transported (e.g., tank truck, pipe).
1.18
Is the effluent transported by a party other than the applicant?
❑ Yes ❑ No -* SKIP to Item 1.20.
1.19
Provide information on the transporter below.
Trans otter Data
Entity name
Mailing address (street or P.O. box)
City or town
State
ZIP code
Contact name (first and last)
Title
Phone number
Email address
EPA Form 3510-2A (Revised 3-19) Page 3

EPA Identification Number
NPDES Permit Number
Facility Name
Form Approved 03/05/19
110022546146
NCO020605
Tarboro W WTP
OMB No. 2040-0004
1.20
In the table below, indicate the name, address, contact information, NPDES number, and average daily flow rate of the
receiving facility.
Receiving F cility Data
-0
Facility name
Mailing address (street or P.O. box)
d
3
City or town
State
ZIP code
0
Contact name (first and last)
Title
0
d
Phone number
Email address
0
NPDES number of receiving facility (if any) ❑ None
Average daily flow rate mgd
fA
1.21
Is the wastewater disposed of in a manner other than those already mentioned in Items 1.14 through 1.21 that do not
`0
have outlets to waters of the United States (e.g., underground percolation, underground injection)?
d
21
❑ Yes ❑ No 4 SKIP to Item 1.23.
0
1.22
Provide information in the table below on these other disposal methods.
Information on Other Disposal
Methods
o
Disposal
Location of
Size of
Annual Average
Continuous or Intermittent
Method
Disposal Site
Disposal Site
Daily Discharge
(check one)
R
Description
Volume
4!
acres
gpd
❑ Continuous
0
❑ Intermittent
acres
❑ Continuous
gpd
❑ Intermittent
acres
gpd
❑ Continuous
❑ Intermittent
1.23
Do you intend to request or renew one or more of the variances authorized at 40 CFR 122.21(n)? (Check all that apply.
Consult with your NPDES permitting authority to determine what information needs to be submitted and when.)
3
❑ Discharges into marine waters (CWA ❑ Water quality related effluent limitation (CWA Section
Section 301(h)) 302(b)(2))
0 Not applicable
1.24
Are any operational or maintenance aspects (related to wastewater treatment and effluent quality) of the treatment works
the responsibility of a contractor?
❑ Yes 0 No +SKIP to Section 2.
1.25
Provide location and contact information for each contractor in addition to a description of the contractor's operational
and maintenance responsibilities.
Contractor Information
Contractor 1
Contractor 2
Contractor 3
c
Contractor name
(company name
Mailing address
c
street or P.O. box
S
City, state, and ZIP
R
code
cContact
name (first and
c�
last
Phone number
Email address
Operational and
maintenance
responsibilities of
contractor
EPA Form 3510-2A (Revised 3-19) Page 4

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
110022546146 NCO020605 Tarboro WWTP OMB No.2040-0004
SECTIONDD• •- • 1
o Outfalls to Waters of the United States
r-
2.1
Does the treatment works have a design flow greater than or equal to 0.1 mgd?
o
❑✓ Yes ❑ No 4 SKIP to Section 3.
0
2.2
Provide the treatment works' current average daily volume of inflow
Average Daily Volume of Inflow and Infiltration
and infiltration.
135,000 gpd
Indicate the steps the facility is taking to minimize inflow and infiltration.
CThe
Town has budgeted $100,000 for sewer line and manhole rehabilitation and replacement.
0
0
t
2.3
Have you attached a topographic map to this application that contains all the required information? (See instructions for
CL
specific requirements.)
C
0
0
CL
❑✓ Yes ❑ No
E
2.4
Have you attached a process flow diagram or schematic to this application that contains all the required information?
16
c
(See instructions for specific requirements.)
rn
o
❑✓ Yes ❑ No
2.5
Are improvements to the facility scheduled?
❑ Yes ❑✓ No 4 SKIP to Section 3.
Briefly list and describe the scheduled improvements.
=
0
_
d
E
d
Q
2.
E
w
0
H
d
3.
a
m
4.
U )
2.6
Provide scheduled or actual dates of completion for improvements.
Scheduled
or Actual Dates of Completion for Improvements
E
d
Scheduled
Affected
Begin
End
Begin
Attainment of
>
0
Improvement
Outfalls
(list
Construction
Construction
Discharge
Operational
Level
E
(from above)
number)
)
(MM/DD/YYYY)
(MM/DD/YYYY)
(MM/DDIYYYY)
MMIDD
d
d
s
2.
3.
4.
2.7
Have appropriate permits/clearances concerning other federal/state requirements been obtained? Briefly explain your
response.
❑ Yes ❑ No ❑ None required or applicable
Explanation:
EPA Form 3510-2A (Revised 3-19) Page 5

EPA Identification Number NPDES Permit Number
Facility Name Form Approved 03/05/19
110022546146 NCO020605
Tarboro WWTP OMB No. 2040-0004
SECTION••
3.1
• ON
Provide the following information for each outfall. (Attach additional sheets if you have more than three outfalls.)
Outfall Number 001
Outfall Number
Outfall Number
State
NC
y
County
Edgecombe
3
o
City or town
Tarboro
0
Distance from shore
N/A ft.
a
d
Depth below surface
N/A ft.
0
Average daily flow rate
1.966 mgd
mgd
mgd
Latitude
35° 57 58" N
o°
I
Longitude
77P V 15" W
3.2
Do any of the outfalls described under Item 3.1 have seasonal or periodic discharges?
o
❑ Yes 0 No 4 SKIP to Item 3.4.
d
3.3
If so, provide the following information for each applicable outfall.
s
y
Outfall Number
Outfall Number
Outfall Number
0
Number of times per year
°
discharge occurs
a
Average duration of each
`0
discharge (specify units
cAverage
flow of each
mgd
mgd
mgd
discharge
�o
in
Months in which discharge
occurs
3.4
Are any of the outfalls listed under Item 3.1 equipped with a diffuser?
❑ Yes ❑ No + SKIP to Item 3.6.
3.5
Briefly describe the diffuser type at each applicable outfall.
Outfall Number
Outfall Number
Outfall Number
a�
N
7
o vi
3 6
Does the treatment works discharge or plan to discharge wastewater to waters of the United States from one or more
0 �
discharge points?
r
0 Yes ❑ No 4SKIP to Section 6.
EPA Form 3510-2A (Revised 3-19) Page 6

EPA Identification Number
NPDES Permit Number
Facility Name
Form Approved 03/05/19
110022546146
NCO020605
Tarboro WWTP
OMB No. 2040-0004
3.7
Provide the receiving water and related information if known for each outfall.
Outfall Number 001
Outfall Number
Outfall Number
Receiving water name
Tar River
Name of watershed, river,
Lower Tar
c
or stream system
a-
z
U.S. Soil Conservation
m
Service 14-digit watershed
03020103010020
c
code
Name of state
Tar -Pamlico
3
IM
management/river basin
U.S. Geological Survey
8-digit hydrologic
03020103
W
cataloging unit code
Critical low flow (acute)
N/A cfs
cfs
cfs
Critical low flow (chronic)
N/A cfs
cfs
cfs
Total hardness at critical
mg/L of
N/A
mg/L of
mg/L of
low flow
CaCO3
CaCO3
CaCO3
3.8
Provide the following information
describing the treatment pr vided for discharges from each outfall.
Outfall Number 001
Outfall Number
Outfall Number
Highest Level of
121 Primary
❑ Primary
❑ Primary
Treatment (check all that
❑ Equivalent to
❑ Equivalent to
❑ Equivalent to
apply per outfall)
secondary
secondary
secondary
El Secondary
❑ Secondary
❑ Secondary
El Advanced
❑ Advanced
❑ Advanced
❑ Other (specify)
❑ Other (specify)
❑ Other (specify)
c
0
Q.
Design Removal Rates by
Outfall
d
BOD5 or CBOD5
95+ %
e
d
E
w
TSS
85 %
%
%
H
❑ Not applicable
❑ Not applicable
❑ Not applicable
Phosphorus
80 %
%
%
❑ Not applicable
❑ Not applicable
❑ Not applicable
Nitrogen
75 %
%
%
Other (specify)
❑ Not applicable
❑ Not applicable
❑ Not applicable
EPA Form 3510-2A (Revised 3-19) Page 7

EPA Identification Number
NPDES Permit Number
Facility Name
Form Approved 03/05/19
110022546146
NCO020605
Tarboro WWTP
OMB No.2040-0004
3.9
Describe the type of disinfection used for the effluent from each outfall in the table below. If disinfection varies by
season, describe below.
-a
Chlorine Gas
m
C
c
c
0
c
Outfall Number 001
Outfall Number
Outfall Number
0
Disinfection type
Chlorine Gas
d
0
Seasons used
All
d
E
Dechlorination used?
❑ Not applicable
❑ Not applicable
❑ Not applicable
0 Yes
❑ Yes
❑ Yes
❑ No
❑ No
❑ No
3.10
Have you completed monitoring for all Table A parameters and attached the results to the application package?
0 Yes ❑ No
3.11
Have you conducted any WET tests during the 4.5 years prior to the date of the application on any of the facility's
discharges or on any receiving water near the discharge points?
0 Yes ❑ No 4 SKIP to Item 3.13.
3.12
Indicate the number of acute and chronic WET tests conducted since the last permit reissuance of the facility's
discharges by outfall number or of the receiving water near the discharge points.
Outfall Number 001
Outfall Number
Outfall Number
Acute
Chronic
Acute
Chronic
Acute
Chronic
Number of tests of discharge
N/A
25
water
Number of tests of receiving
N/A
N/A
water
3.13
Does the treatment works have a design flow greater than or equal to 0.1 mgd?
0 Yes ❑ No 4 SKIP to Item 3.16.
cc
w
c
3.14
Does the POTW use chlorine for disinfection, use chlorine elsewhere in the treatment process, or otherwise have
reasonable potential to discharge chlorine in its effluent?
✓❑ Yes 4 Complete Table B, including chlorine. ❑ No 4 Complete Table B, omitting chlorine.
Z
3.15
Have you completed monitoring for all applicable Table B pollutants and attached the results to this application
package?
IR
uw
0 Yes ❑ No
3.16
Does one or more of the following conditions apply?
• The facility has a design flow greater than or equal to 1 mgd.
• The POTW has an approved pretreatment program or is required to develop such a program.
• The NPDES permitting authority has informed the POTW that it must sample for the parameters in Table C, must
sample other additional parameters (Table D), or submit the results of WET tests for acute or chronic toxicity for
each of its discharge outfalls (Table E).
0 Yes 4 Complete Tables C, D, and E as ❑ No 4 SKIP to Section 4.
applicable.
3.17
Have you completed monitoring for all applicable Table C pollutants and attached the results to this application
package?
0 Yes ❑ No
3.18
Have you completed monitoring for all applicable Table D pollutants required by your NPDES permitting authority and
attached the results to this application package?
❑ Yes 0 No additional sampling required by NPDES
permitting authority.
EPA Form 3510-2A (Revised 3-19) Page 8

EPA Identification Number
NPDES Permit Number
Facility Name
Form Approved 03/05/19
110022546146
NCO020605
Tarboro WWTP
OMB No. 2040-0004
3.19
Has the POTW conducted either (1) minimum of four quarterly WET tests for one year preceding this permit application
or (2) at least four annual WET tests in the past 4.5 years?
❑ Yes ❑ No + Complete tests and Table E and SKIP to
Item 3.26.
3.20
Have you previously submitted the results of the above tests to your NPDES permitting authority?
❑ Yes ❑ No + Provide results in Table E and SKIP to
Item 3.26.
3.21
Indicate the dates the data were submitted to our NPDES permitting authority and provide a summary of the results.
Date(s) Submitted
Summary of Results
MM/DD
See Attached (Toxicity Testing)
c
c
0
w
3.22
Regardless of how you provided your WET testing data to the NPDES permitting authority, did any of the tests result in
o
toxicity?
0'
w
❑ Yes ❑✓ No + SKIP to Item 3.26.
3.23
Describe the cause(s) of the toxicity:
c
m
W
3.24
Has the treatment works conducted a toxicity reduction evaluation?
❑ Yes ❑ No 4 SKIP to Item 3.26.
3.25
Provide details of any toxicity reduction evaluations conducted.
3.26
Have you completed Table E for all applicable outfalls and attached the results to the application package?
❑ Yes ❑ Not applicable because previously submitted
information to the NPDES permittinq authority.
SECTION•
DISCHARGES AND HAZARDOUS WASTES (40
Does the POTW receive discharges from SIUs or NSCIUs?
4.1
❑✓ Yes ❑ No + SKIP to Item 4.7.
m
4.2
Indicate the number of SIUs and NSCIUs that discharge to the POTW.
A
Number of SIUs
Number of NSCIUs
3
0
3
70
4.3
Does the POTW have an approved pretreatment program?
R
A
_
✓ Yes ❑ No
❑
4.4
Have you submitted either of the following to the NPDES permitting authority that contains information substantially
0
identical to that required in Table F: (1) a pretreatment program annual report submitted within one year of the
CM
application or (2) a pretreatment program?
L
H
0 Yes ❑ No + SKIP to Item 4.6.
a
4.5
Identify the title and date of the annual report or pretreatment program referenced in Item 4.4. SKIP to Item 4.7.
,a
3
Pretreatment Annual Report 02/21/2024
4.6
Have you completed and attached Table F to this application package?
El Yes ❑ No
EPA Form 3510-2A (Revised 3-19) Page 9

EPA Identification Number
NPDES Permit Number
Facility Name
Form Approved 03/05/19
110022546146
NCO020605
Tarboro WWTP
OMB No. 2040-0004
4.7
Does the POTW receive, or has it been notified that it will receive, by truck, rail, or dedicated pipe, any wastes that are
regulated as RCRA hazardous wastes pursuant to 40 CFR 261?
❑ Yes ❑ No 4 SKIP to Item 4.9.
4.8
If yes, provide the follo ing information:
Annual
Hazardous Waste
Waste Transport Method
Amount of
Units
Number
(check all that apply)
Waste
Received
❑ Truck ❑ Rail
❑ Dedicated pipe ❑ Other (specify)
0
U
❑ Truck ❑ Rail
3
❑ Dedicated pipe ❑ Other (specify)
U)
0
N
❑ Truck ❑ Rail
cc
_
-o
❑ Dedicated pipe ❑ Other (specify)
U)
d
R
4.9
Does the POTW receive, or has it been notified that it will receive, wastewaters that originate from remedial activities,
including those undertaken pursuant to CERCLA and Sections 3004(7) or 3008(h) of RCRA?
Mn
0
❑ Yes ❑ No 4 SKIP to Section 5.
�
Z
4.10
Does the POTW receive (or expect to receive) less than 15 kilograms per month of non -acute hazardous wastes as
specified in 40 CFR 261.30(d) and 261.33(e)?
❑ Yes -* SKIP to Section 5. ❑ No
4.11
Have you reported the following information in an attachment to this application: identification and description of the
site(s) or facility(ies) at which the wastewater originates; the identities of the wastewater's hazardous constituents; and
the extent of treatment, if any, the wastewater receives or will receive before entering the POTW?
❑ Yes ❑ No
SECTION•
OVERFLOWS (40
E
5.1
Does the treatment works have a combined sewer system?
`a
❑ Yes 0 No 4SKIP to Section 6.
5.2
Have you attached a CSO system map to this application? (See instructions for map requirements.)
Q
❑ Yes ❑ No
R
M
5.3
Have you attached a CSO system diagram to this application? (See instructions for diagram requirements.)
0
�
❑ Yes ❑ No
EPA Form 3510-2A (Revised 3-19) Page 10

EPA Identification Number
NPDES Permit Number
Facility Name
Form Approved 03105/19
110022546146
NCO020605
Tarboro WWTP
OMB No. 2040-0004
5.4
For each CSO outfall, provide the following information. Attach
additional sheets as necessary.)
CSO Outfall Number
CSO Outfall Number
CSO Outfall Number
City or town
0
w
State and ZIP code
h
c
County
A
i
Latitude
°
°
0
0
co
c�
Longitude
°
Distance from shore
Depth below surface
5.5
Did the POTW monitor any of the following items in the past year for its CSO outfalls?
CSO Outfall Number _
CSO Outfall Number
CSO OutFall Number
Rainfall
❑ Yes ❑ No
❑ Yes ❑ No
❑ Yes ❑ No
rn
c
o
CSO flow volume
❑ Yes ❑ No
❑ Yes ❑ No
❑ Yes ❑ No
0
CSO pollutant
El Yes El No
❑ Yes ❑ No
El Yes ❑No
0
concentrations
dN
Receiving water quality
❑ Yes ❑ No
❑ Yes ❑ No
❑ Yes ❑ No
CSO frequency
❑ Yes ❑ No
❑ Yes ❑ No
❑ Yes ❑ No
Number of storm events
❑ Yes ❑ No
❑ Yes ❑ No
❑ Yes ❑ No
5.6
Provide the following information for each of your CSO outfalls.
CSO Outfall Number _
CSO Outfall Number _
CSO Outfall Number
Number of CSO events in
events
events
events
the past year
A
cAverage
duration per
hours
hours
hours
r
event
❑ Actual or ❑ Estimated
❑ Actual or ❑ Estimated
❑ Actual or ❑ Estimated
4D
w
million gallons
million gallons
million gallons
0
Average volume per event
❑ Actual or ❑ Estimated
❑ Actual or ❑ Estimated
❑ Actual or ❑ Estimated
Minimum rainfall causing
inches of rainfall
inches of rainfall
inches of rainfall
a CSO event in last year
❑ Actual or ❑ Estimated
❑ Actual or ❑ Estimated
❑ Actual or ❑ Estimated
EPA Form 3510-2A (Revised 3-19) Page 11

EPA Identification Number
NPDES Permit Number
Facility Name
Form Approved 03/05/19
110022546146
NC0020605
Tarboro WWTP
OMB No.2040-0004
5.7
Provide the information in the table below for each of your CSO outfalls.
CSO Outfall Number _
CSO Outfall Number
CSO Outfall Number
Receiving water name
Name of watershed/
streams stem
dU.S.
Soil Conservation
❑ Unknown
❑ Unknown
❑ Unknown
3
Service 14-digit
c
watershed code
>
if known
Name of state
management/river basin
caU.S.
Geological Survey
❑ Unknown
❑ Unknown
❑ Unknown
8-Digit Hydrologic Unit
Code if known
Description of known
water quality impacts on
receiving stream by CSO
(see instructions for
examples)
SECTION•
i
In Column 1 below, mark the sections of Form 2A that you have completed and are submitting with your application. For
6.1
each section, specify in Column 2 any attachments that you are enclosing to alert the permitting authority. Note that not
all applicants are required to provide attachments.
Column 1
Column 2
❑ Section 1: Basic Application
❑ w/ variance request(s) ❑ w/ additional attachments
Information for All Applicants
❑ Section 2: Additional
0 w/ topographic map w/ process flow diagram
Information
❑ w/ additional attachments
0 w/ Table A 0 w/ Table D
❑ Section 3: Information on
❑ w/ Table B ❑ w/ Table E
c
Effluent Discharges
E
0 w/ Table C 0 w/ additional attachments
R
Section 4: Industrial
❑ w/ SIU and NSCIU attachments 21 wl Table F
_
Discharges and Hazardous
❑
Wastes
w/ additional attachments
ElSection 5: Combined Sewer
El w/ CSO map E] w/ additional attachments
Overflows
❑ w/ CSO system diagram
❑ Section 6: Checklist and
w/ attachments
A
Certification Statement
Y
6.2
Certification Statement
d
1 certify under penalty of law that this document and all attachments were prepared under my direction or supervision in
accordance with a system designed to assure that qualified personnel properly gather and evaluate the information
submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible
for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and
complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine
and imprisonment for knowing violations.
Name (print or type first and last name)
Official title
p
0.
danq¢ac'
Signatur
Date signed
EPA Form 3510-2A (Revised 3-19) Page 12

Number
110022546146
NPDES Permit Number I Facility
NCO020605 Tarboro WWTP
Outfall Number
001
Form App 3/05/19
OMB No. 2040-0004
Maximum Daily Discharge
Average Daily Discharge
Analytical ML or MDL
Value
Units
Number
Pollutant
Value Units
Methods (Include units)
Samples
Biochemical oxygen demand
o BOD5 or ❑ CBOD5
6.56
mg/L
1.98
mg/L
365
30 R1 ML
❑ MDL
(report one
Fecal coliform
461.10
#/100 mL
23.03
#/100 mL
260
200 2 ML
❑ MDL
Design flow rate
5.599
mgd
2.156
mgd
365
pH (minimum)
6.01
s.0
pH (maximum)
8.94
s.0
Temperature (winter)
23
C
15.98
C
182
Temperature (summer)
28
C
22.95
C
183
Total suspended solids (TSS)
13
mg/L
1.43
mg/L
260
30 2 ML
❑ MDL
1 Sampling shall be conducted according to sufficiently sensitive test procedures (i.e., methods) approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or
required under 40 CFR chapter I, subchapter N or 0. See instructions and 40 CFR 122.21(e)(3).
EPA Form 3510-2A (Revised 3-19) Page 13

-ntification Number NPDES Permit Number Facility Outfall Number
F 110022546146 NC0020605 Tarboro WWTP 001
Form Ar 03/05/19
OMB No. 2040-0004
Maximum Daily Discharge Average Daily Discharge
Analytical
ML or MDL
Value
Units
Value
Units
Numbers
Pollutant
Method'
(include units)
Samples
Ammonia (as N)
5
mg/L
5
mg/L
248
EPA 353.2
9 ❑ MDL
Chlorine
total residual, TRC 2
25
ug/L
22.92
ug/L
156
❑ ML
❑ MDL
Dissolved oxygen
15
mg/L
7.98
mg/L
365
5 El IVIL
❑ MDL
Nitrate/nitrite
19.60
mg/L
13.67
mg/L
51
EPA 353.2
0.1 2 ML
❑ MDL
Kjeldahl nitrogen
9.60
mg/L
1.68
mg/L
52
EPA 351.2
0.5 O ML
❑ MDL
Oil and grease
N/A
N/A
N/A
N/A
N/A
EPA 1664A
5 ❑ MDL
Phosphorus
2.48
mg/L
1.10
mg/L
51
EPA 365.1
0.1 Z ML
❑ MDL
Total dissolved solids
N/A
N/A
N/A
N/A
N/A
❑ ML
❑ MDL
I Sampling shall be conducted according to sufficiently sensitive test procedures (i.e., methods) approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or
required under 40 CFR chapter I, subchapter N or 0. See instructions and 40 CFR 122.21(e)(3).
2 Facilities that do not use chlorine for disinfection, do not use chlorine elsewhere in the treatment process, and have no reasonable potential to discharge chlorine in their effluent are not
required to report data for chlorine.
EPA Form 3510-2A (Revised 3-19) Page 15

This page intentionally left blank.

entification Number NPDES Permit Number Facility Outfall Number
110022546146 NC0020605 Tarboro WWTP 001
6-111129107
Maximum Daily Discharge Average Daily Discharge
Pollutant
Value Units Value Units Number of
Samples
Form Ai 03105119
OMB No. 2040-0004
Analytical ML or MDL
Method' (include units)
Metals, Cyanide, and Total Phenols
Hardness (as CaCO3)
ND
mg/L
ND
mg/L
3
SM 23401B
0.65 El ML
MDL
Antimony, total recoverable
ND
ug/L
ND
ug/L
3
EPA 200.7
5 OML
❑ MDL
Arsenic, total recoverable
5
ug/L
5
ug/L
3
EPA 200.7
5 OML
❑ MDL
Beryllium, total recoverable
ND
ug/L
ND
ug/L
3
EPA 200.7
1 OML
❑ MDL
Cadmium, total recoverable
1
ug/L
1
ug/L
3
EPA 200.7
1 ❑ MDL
Chromium, total recoverable
12
ug/L
7.33
ug/L
3
EPA 200.7
5 0 ML
MDL
Copper, total recoverable
8
ug/L
7.33
ug/L
3
EPA 200.7
5 DML
❑ MDL
Lead, total recoverable
5
ug/L
5
ug/L
3
EPA 200.7
5 OML
❑ MDL
Mercury, total recoverable
1.90
ug/L
1.67
ug/L
3
EPA 1631E
0.5 ❑ MDL
Nickel, total recoverable
10
ug/L
10
ug/L
3
EPA 200.7
10 ❑ MDL
Selenium, total recoverable
10
ug/L
10
ug/L
3
EPA 200.7
10 El ML
MDL
Silver, total recoverable
5
ug/L
5
ug/L
3
EPA 200.7
5 OML
❑ MDL
Thallium, total recoverable
ND
ug/L
ND
ug/L
3
EPA 200.7
10 ❑ MDL
Zinc, total recoverable
29
ug/L
23.22
ug/L
3
EPA 200.7
10 ❑ ML
❑ MDL
Cyanide
0.005
mg/L
0.005
mg/L
3
SM 4500-CN-E
0.005 OML
❑ MDL
Total phenolic compounds
ND
mg/L
ND
mg/L
3
EPA 420.4
0.01 OML
❑ MDL
Volatile Organic Compounds
Acroleln
ND
ug/L
ND
ug/L
3
EPA 624
100 OML
❑ MDL
Acrylonitrile
ND
ug/L
ND
ug/L
3
EPA 624
100 OML
❑ MDL
Benzene
ND
ug/L
ND
ug/L
3
EPA 624
5 OML
❑ MDL
Bromoform
ND
ug/L
ND
ug/L
3
EPA 624
5 0 ML
MDL
EPA Form 3510-2A (Revised 3-19) Page 17

entification Number NPDES Permit Number Facility Outfall Number
110022546146 NC0020605 Tarboro WWTP 001
•• D'•
Maximum Daily Discharge Average Daily Discharge
Pollutant
Value Units Value Units Number of
Samples
Form Al. 03/05/19
OMB No.2040-0004
Analytical ML or MDL
Method' (include units)
Carbon tetrachloride
ND
ug/L
ND
ug/L
3
EPA 624
5 ❑ MDL
Chlorobenzene
ND
ug/L
ND
ug/L
3
EPA 624
5 ❑ MDL
Chlorodibromomethane
ND
ug/L
ND
ug/L
3
EPA 624
5 ❑ MDL
Chloroethane
ND
ug/L
ND
ug/L
3
EPA 624
5 ❑ MDL
2-chloroethylvinyl ether
ND
ug/L
ND
ug/L
3
EPA 624
5 ❑ MDL
Chloroform
ND
ug/L
ND
ug/L
3
EPA 624
5 Cl MDL
Dichlorobromomethane
ND
ug/L
ND
ug/L
3
EPA 624
5 ❑ MDL
1,1-dichloroethane
ND
ug/L
ND
ug/L
3
EPA 624
5 ❑ MDL
1,2-dichloroethane
ND
ug/L
ND
ug/L
3
EPA 624
10 11 ML
MDL
trans-1,2-dichloroethylene
ND
ug/L
ND
ug/L
3
EPA 624
10 ❑ MDL
1,1-dichloroethylene
ND
ug/L
ND
ug/L
3
EPA 624
5 ❑ MDL
1,2-dichloropropane
ND
ug/L
ND
ug/L
3
EPA 624
5 ❑ MDL
1,3-dichloropropylene
ND
ug/L
ND
ug/L
3
EPA 624
5 ❑ MDL
Ethylbenzene
ND
ug/L
ND
ug/L
3
EPA 624
5 ❑ MDL
Methyl bromide
ND
ug/L
ND
ug/L
3
EPA 624
5 ❑ MDL
Methyl chloride
ND
ug/L
ND
ug/L
3
EPA 624
5 ❑ MDL
Methylene chloride
ND
ug/L
ND
ug/L
3
EPA 624
5 ❑ MDL
1,1,2,2-tetrachloroethane
ND
ug/L
ND
ug/L
3
EPA 624
5 ❑MDL
Tetrachloroethylene
ND
ug/L
ND
ug/L
3
EPA 624
5 ❑ MDL
Toluene
ND
ug/L
ND
ug/L
3
EPA 624
5 ❑ MDL
1, 1, 1 -trichloroethane
ND
ug/L
ND
ug/L
3
EPA 624
5 ❑ MDL
1,1,2-trichloroethane
ND
ug/L
ND
ug/L
3
EPA 624
5 ❑ MDL
EPA Form 3510-2A (Revised 3-19) Page 18

entification Number NPDES Permit Number Facility Outfall Number
110022546146 NCO020605 Tarboro WWTP 001
Maximum Daily Discharge Average Daily Discharge
Pollutant
Value Units Value Units Number of
Samples
Form Al 03105119
OMB No. 2040-0004
Analytical ML or MDL
Method' (include units)
Trlchloroethylene
ND
ug/L
ND
ug/L
3
EPA 624
5 OML
❑ MDL
Vinyl chloride
ND
ug/L
ND
ug/L
3
EPA 624
ML
5 0 MDL
Acid -Extractable Compounds
p-chloro-m-cresol
ND
ug/L
ND
ug/L
3
EPA 624
10 0ML
MDL
2-chlorophenol
ND
ug/L
ND
ug/L
3
EPA 624
10 0ML
MDL
2,4-dichlorophenol
ND
ug/L
ND
ug/L
3
EPA 624
10 OML
❑ MDL
2,4-dimethylphenol
ND
ug/L
ND
ug/L
3
EPA 624
10 ❑ MDL
4,6-dinitro-o-cresol
ND
ug/L
ND
ug/L
3
EPA 624
50 ❑ MDL
2,4-dinitrophenol
ND
ug/L
ND
ug/L
3
EPA 624
50 El ML
❑ MDL
2-nitrophenol
ND
ug/L
ND
ug/L
3
EPA 624
10 El ML
❑ MDL
4-nitrophenol
ND
ug/L
ND
ug/L
3
EPA 624
50 El ML
❑ MDL
Pentachlorophenol
ND
ug/L
ND
ug/L
3
EPA 624
50 ❑ MDL
Phenol
ND
ug/L
ND
ug/L
3
EPA 624
10 ❑ MDL
2,4,6-trichlorophenol
ND
ug/L
ND
ug/L
3
EPA 624
10 ❑ MDL
Base -Neutral Compounds
Acenaphthene
ND
ug/L
ND
ug/L
3
EPA 625
6.4 OML
❑ MDL
Acenaphthylene
ND
ug/L
ND
ug/L
3
EPA 625
6.4 ❑ MDL
Anthracene
ND
ug/L
ND
ug/L
3
EPA 625
6.4 ❑ MDL
Benzidine
ND
ug/L
ND
ug/L
3
EPA 625
6.4 0 ML
MDL
Benzo(a)anthracene
ND
ug/L
ND
ug/L
3
EPA 625
6.4 ❑ MDL
Benzo(a)pyrene
ND
ug/L
ND
ug/L
3
EPA 625
6.4 ❑ MDL
3,4-benzofluoranthene
ND
ug/L
ND
ug/L
3
EPA 625
6.4 OML
❑ MDL
EPA Form 3510-2A (Revised 3-19) Page 19

entification Number NPDES Permit Number Facility Outfall Number
110022546146 NCO020605 Tarboro WWTP 001
Maximum Daily Discharge Average Daily Discharge
Pollutant
Value Units Value Units Number of
Saes
Form Al 03/05/19
OMB No. 2040-0004
Analytical ML or MDL
Method' (include units)
Benzo(ghi)perylene
ND
ug/L
ND
ug/L
3
EPA 625
6.4 0 ML
❑ MDL
Benzo(k)fluoranthene
ND
ug/L
ND
ug/L
3
EPA 625
6.4 ❑ML
❑ MDL
Bis (2-chloroethoxy) methane
ND
ug/L
ND
ug/L
3
EPA 625
0 ML
12.8 ❑ MDL
Bis (2-chloroethyl) ether
ND
ug/L
ND
ug/L
3
EPA 625
6.4 0 ML
❑ MDL
Bis (2-chloroisopropyl) ether
ND
ug/L
ND
ug/L
3
EPA 625
6•4 0 ML
❑ MDL
Bis (2-ethylhexyl) phthalate
ND
ug/L
ND
ug/L
3
EPA 625
6.4 0 ML
❑ MDL
4-bromophenyl phenyl ether
ND
ug/L
ND
ug/L
3
EPA 625
6.4 ❑ ML
❑ MDL
Butyl benzyl phthalate
ND
ug/L
ND
ug/L
3
EPA 625
6.4 0 ML
❑ MDL
2-chloronaphthalene
ND
ug/L
ND
ug/L
3
EPA 625
6.4 0 ML
❑ MDL
4-chlorophenyl phenyl ether
ND
ug/L
ND
ug/L
3
EPA 625
6.4 ❑ ML
❑ MDL
Chrysene
ND
ug/L
ND
ug/L
3
EPA 625
6.4 El ML
❑ MDL
di-n-butyl phthalate
ND
ug/L
ND
ug/L
3
EPA 625
6.4 0 ML
❑ MDL
di-n-octyl phthalate
ND
ug/L
ND
ug/L
3
EPA 625
6.4 0 ML
❑ MDL
Dibenzo(a,h)anthracene
ND
ug/L
ND
ug/L
3
EPA 625
6.4 0 ML
❑ MDL
1,2-dichlorobenzene
ND
ug/L
ND
ug/L
3
EPA 625
6.4 ❑ML
❑ MDL
1,3-dichlorobenzene
ND
ug/L
ND
ug/L
3
EPA 625
6.4 0 ML
❑ MDL
1,4-dichlorobenzene
ND
ug/L
ND
ug/L
3
EPA 625
6.4 El ML
❑ MDL
3,3-dichlorobenzidine
ND
ug/L
ND
ug/L
3
EPA 625
6.4 0 ML
❑ MDL
Diethyl phthalate
ND
ug/L
ND
ug/L
3
EPA 625
6.4 11 ML
❑ MDL
Dimethyl phthalate
ND
ug/L
ND
ug/L
3
EPA 625
6.4 0 ML
❑ MDL
2,4-dinitrotoluene
ND
ug/L
ND
ug/L
3
EPA 625
6.4 0 ML
❑ MDL
2,6-dinitrotoluene
ND
ug/L
ND
ug/L
3
EPA 625
6.4 0 ML
❑ MDL
EPA Form 3510-2A (Revised 3-19) Page 20

entification Number NPDES Permit Number Facility Outfall Number
110022546146 NCOO206O5 Tarboro W WTP 001
Maximum Daily Discharge Average Daily Discharge
Pollutant Number of
Value Units Value Units Samples
Form Al 03/05/19
OMB No. 2040-0004
Analytical ML or MDL
Method' (include units)
1,2-diphenylhydrazine
ND
ug/L
ND
ug/L
3
EPA 625
6.4 OML
❑ MDL
Fluoranthene
ND
ug/L
ND
ug/L
3
EPA 625
6.4 DIVIL
❑ MDL
Fluorene
ND
ug/L
ND
ug/L
3
EPA 625
6.4 OML
❑ MDL
Hexachlorobenzene
ND
ug/L
ND
ug/L
3
EPA 625
6.4 OML
❑ MDL
Hexachlorobutadiene
ND
ug/L
ND
ug/L
3
EPA 625
6.4 DIVIL
❑ MDL
Hexachlorocyclo-pentadiene
ND
ug/L
ND
ug/L
3
EPA 625
6.4 ❑ MDL
Hexachloroethane
ND
ug/L
ND
ug/L
3
EPA 625
6.4 0 NIL
❑ MDL
Indeno(1,2,3-cd)pyre ne
ND
ug/L
ND
ug/L
3
EPA 625
6.4 OML
❑ MDL
Isophorone
ND
ug/L
ND
ug/L
3
EPA 625
6.4 ❑ MDL
Naphthalene
ND
ug/L
ND
ug/L
3
EPA 625
6.4 ❑ MDL
Nitrobenzene
ND
ug/L
ND
ug/L
3
EPA 625
6.4 OML
❑ MDL
N-nitrosodi-n-propylamine
ND
ug/L
ND
ug/L
3
EPA 625
6.4 OML
❑ MDL
N-nitrosodimethylamine
ND
ug/L
ND
ug/L
3
EPA 625
6.4 OML
❑ MDL
N-nitrosodiphenylamine
ND
ug/L
ND
ug/L
3
EPA 625
6.4 ❑ MDL
Phenanthrene
ND
ug/L
ND
ug/L
3
EPA 625
6.4 OML
❑ MDL
Pyrene
ND
ug/L
ND
ug/L
3
EPA 625
6.4 OML
❑ MDL
1,2,4-trichlorobenzene
ND
ug/L
ND
ug/L
3
EPA 625
6.4 0 ML
MDL
Sampling shall be conducted according to sufficiently sensitive test procedures (i.e., methods) approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or
required under 40 CFR Chapter I, Subchapter N or 0. See instructions and 40 CFR 122.21(e)(3).
EPA Form 3510-2A (Revised 3-19) Page 21

This page intentionally left blank.

entification Number NPDES Permit Number Facility Outfall Number Form Al 03/05/19
110022546146 NCO020605 Tarboro WWTP 001 OMB No. 2040-0004
LWU IMF
MDail Discharge Average Dail Discharge
Pollutant 7Analytical ML or MDL
(list) Value Units Value Units Numbers Method' (include units)
Samples
0 No additional sampling is required by NPDES permitting authority.
❑ ML
❑ MDL
❑ ML
❑ MDL
❑ ML
❑ MDL
❑ ML
❑ MDL
❑ ML
❑ MDL
❑ ML
❑ MDL
❑ ML
❑ MDL
❑ ML
❑ MDL
❑ ML
❑ MDL
❑ ML
❑ MDL
❑ ML
❑ MDL
❑ ML
❑ MDL
❑ ML
❑ MDL
❑ ML
❑ MDL
❑ ML
❑ MDL
❑ ML
❑ MDL
❑ ML
❑ MDL
Sampling shall be conducted according to sufficiently sensitive test procedures (i.e., methods) approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or required
under 40 CFR chapter I, subchapter N or 0. See instructions and 40 CFR 122.21(e)(3).
EPA Form 3510-2A (Revised 3-19) Page 23

This page intentionally left blank.

_ entification Number NPDES Permit Number Facility Outfall Number Form Af 03/05/19
110022546146 NC0020605 Tarboro WWTP 001 OMB No. 2040-0004
TABLE E. EFFLUENT MONITORING FOR WHOLE EFFLUENT TOXICITY
The table provides response space for one whole effluent toxicity sample. Copy the table to report additional test results.
Test Information
Test Number
Test Number
Test Number
Test species
Age at initiation of test
Outfall number
Date sample collected
Date test started
Duration
Toxicity Test Methods
Test method number
Manual title
Edition number and year of publication
Page number(s)
Sample Type
Check one:
❑ Grab
❑ 24-hour composite
❑ Grab
❑ 24-hour composite
❑ Grab
❑ 24-hour composite
Sample Location
Check one:
❑ Before Disinfection
❑ After Disinfection
❑ After Dechlorination
❑ Before Disinfection
❑ After Disinfection
❑ After Dechlorination
❑ Before disinfection
❑ After disinfection
❑ After dechlorination
Point in Treatment Process
Describe the point in the treatment process
at which the sample was collected for each
test.
Toxicity Type
Indicate for each test whether the test was
performed to asses acute or chronic toxicity,
or both. (Check one response.)
❑ Acute
❑r Chronic
❑ Both
❑ Acute
El Chronic
❑Both
❑ Acute
El Chronic
El Both
EPA Form 3510-2A (Revised 3-19) Page 25

entification Number NPDES Permit Number Facility Outfall Number Form AF 03/05/19
110022546146 NCO020605 Tarboro WWTP 001 OMB No.2040-0004
TABLE E. EFFLUENT MONITORING FOR WHOLE EFFLUENT TOXICITY
e table provides response space for one whole effluent toxicity sample. Copy the table to report additional test results.
Test Number
i
Test Number
Test Number
Test Type
Indicate the type of test performed. (Check one
response.)
❑ Static
❑ Static -renewal
❑ Flow -through
❑ Static
❑ Static -renewal
❑ Flow -through
❑ Static
❑ Static -renewal
❑ Flow -through
Source of Dilution Water
Indicate the source of dilution water. (Check
one response.)
❑ Laboratory water
❑ Receiving water
❑ Laboratory water
❑ Receiving water
❑ Laboratory water
❑ Receiving water
If laboratory water, specify type.
If receiving water, specify source.
Type of Dilution Water
Indicate the type of dilution water. If salt
water, specify "natural' or type of artificial
sea salts or brine used.
❑ Freshwater
❑ Salt water (specify)
❑ Freshwater
El Salt water (specify)
❑ Freshwater
El Salt water (specify)
Percentage Effluent Used
Specify the percentage effluent used for all
concentrations in the test series.
Parameters Tested
Check the parameters tested.
❑ pH
❑ Salinity
❑ Temperature
❑ Ammonia
❑ Dissolved oxygen
❑ pH
❑ Salinity
❑ Temperature
❑ Ammonia
❑ Dissolved oxygen
❑ pH
❑ Salinity
❑ Temperature
❑ Ammonia
❑ Dissolved oxygen
Acute Test Results
Percent survival in 100% effluent
%
%
%
LC50
95% confidence interval
%
%
%
Control percent survival
%
%
%
EPA Form 3510-2A (Revised 3-19) Page 26

_entification Number NPDES Permit Number Facility Outfall Number Form Al 03/05/19
110022546146 NCO020605 Tarboro W WTP 001 OMB No. 2040-0004
TABLE E. EFFLUENT MONITORING FOR WHOLE EFFLUENT TOXICITY
The table provides response space for one whole effluent toxicity sample. Copy the table to report additional test results.
Test Number Test Number Test Number
Acute Test Results Continued
Other (describe)
Chronic Test Results
NOEC
%
%
%
IC25
%
%
%
Control percent survival
%
%
%
Other (describe)
Quality Control/Quality Assurance
Is reference toxicant data available?
❑ Yes
❑ No
❑ Yes
❑ No
❑ Yes
❑ No
Was reference toxicant test within
El Yes
El No
❑Yes
❑ No
ElYes
ElNo
acceptable bounds?
What date was reference toxicant test run
(MM/DDIYYYY)?
Other (describe)
EPA Form 3510-2A (Revised 3-19) Page 27

This page intentionally left blank.

PA Identification Number
110022546146
NPDES Permit Number
NCO020605
Facility Name
Tarboro WWTP
Form Al 103/05/19
OMB No. 2040-0004
INFORMATIONTABLE F. INDUSTRIAL DISCHARGE
Response space is provided for three SIUs. Copy the table to report information for additional SIUs.
SIU 1
SIU 2
SIU 3
Name of SIU
Johnson Controls
Sara Lee Frozen Bakery, LLC
Mayo Knitting Mill, Inc.
Mailing address (street or P.O. box)
3301 Main Street
110 Sara Lee Road
P.O. Box 160
City, state, and ZIP code
Tarboro, NC 27886
Tarboro, NC 27886
Tarboro, NC 27886
Description of all industrial processes that affect
Manufacturing of metal grills for air
Production of consumable basic food and
Knitting, Dyeing, Finsihing, Packaging and
or contribute to the discharge.
conditioning registers
dessert pastries
Shipping of Hosiery
List the principal products and raw materials that
Air Duct Registers
Pound Cake, Muffins, Biscuits, Croissants,
Hosiery
affect or contribute to the SIU's discharge.
Sheet Metal, Paint
Danish, Layer Cakes
Yams, Dyes, Chemicals
Flour, Eggs, Sugar, Spices, Stabilizers,
Colorings, Flavorings
Indicate the average daily volume of wastewater
discharged by the SIU.
40,000 gpd
300,000 gpd
250,000 gpd
How much of the average daily volume is
attributable to process flow?
gpd
gpd
gpd
How much of the average daily volume is
attributable to non -process flow?
1,00o gpd
50,00o gpd
1,00o gpd
Is the SIU subject to local limits?
❑✓ Yes ❑ No
0 Yes ❑ No
✓❑ Yes ❑ No
Is the SIU subject to categorical standards?
2 Yes ❑ No
❑ Yes El No
21 Yes ❑ No
EPA Form 3510-2A (Revised 3-19) Page 29

_PA Identification Number
110022546146
NPDES Permit Number
NC0020605
Facility Name
Tarboro WWTP
Form Al 103/05/19
OMB No. 2040-0004
INFORMATIONTABLE F. INDUSTRIAL DISCHARGE
Response space is provided for three SIUs. Copy the table to report information for additional SIUs.
SIU 1
SIU
SIU _
Under what categories and subcategories is the
SIU subject?
40 CFR 433, subpart A
40 CFR 410, subpart G
Has the POTW experienced problems (e.g.,
upsets, pass -through interferences) in the past 4.5
ears that are attributable to the SIU?
❑ Yes 0 No
❑ Yes No
❑ Yes B No
If yes, describe.
EPA Form 3510-2A (Revised 3-19) Page 30

Topographic Map &
Process Flow Diagram

.� --- 1 � �•,l ••cam •� . � f � f - r h �" /
Golf �� !, • 1/j �;� S `; . �� ,, ` : 1_ rth
r 1✓I -
1 Course r. ! �,.� �� ti ,'� i �✓
f e .`_ mot• •� - w,..'_.�w��.`•i.►' •_
ji-
• f ,. ,��• : �,:� + ,,�.-.� .. ;:r-+ `-_y, � t' t• I % _ , �` •. .. Town-.
VC
Influent Lines ' ;' • ii :-
SewB o I + ' Penn k..•. .
/ 1 e
Tarboro WWTP Discharge 1 �' �� f►
Outfall 00127.9
�►
f 371
lh
_
ILI
Town of Tarboro WWTP N
NPDES Permit No. NC0020605
Non -Discharge Permit No. WQ0002047
USGS Quads:
Tarboro, NC 1981
500, 2OW, Rocky Mount, NC 1985
Scale: __ _ Mr -- I

PO
ae
81
i/ may, • 4 R� *' t��U' e..�
Golf -A
Course ' , q►'VVT WO :•ate :,� , n
51
A,
lie
1
I
+• / • S
.. : o• ^� �8l .:.r' h ,''mow,
10
it
� s'. "`"tea 5 � �l , ► ��,t� ` ..b ..
s
:o dco l
DISCHARGE S
OUTFALL 001 t
WWTP
77.9 h t tl
Town of Tarboro WWTP
NPDES: NC0020605
Non -Discharge: WQ0002047
Permit Renewal
March 2024
I'll
� M $
.e
(1760�
Feet
0 1,000 2,000
» ooten

Headworks
Anaerobic Digesters
Sludge Drying Beds
Aerobic Digesters
Town of Tarboro Wastewater Treatment Plant
Process Flow Diagram
Primary Clarifiers
Aerated Sludge Holding Lagoon
Secondary Clarifiers
Cascade
Aeration

Sludge Management Plan

Sludge Management Plan
Town of Tarboro Wastewater Treatment Plant
NPDES Permit No. NC0020605
Non -Discharge Permit No. WQ0002047
The Town of Tarboro operates a 5.0 mgd modified biological nutrient removal (BNR) plant
which discharges its effluent into the Tar River in the Tar -Pamlico River Basin under NPDES
Permit No. NC0020605. Waste sludge from the primary clarifiers is discharged into two (2)
anaerobic digesters for sludge stabilization while waste activated sludge from the modified BNR
system is pumped to the aerobic sludge digester for stabilization. The anaerobically and
aerobically stabilized sludges are later pumped to the aerated sludge basin for further long term
stabilization and storage prior to disposal by land application. Periodically, supernatant from the
anaerobic digester, aerobic digester, and sludge stabilization/storage basin is withdrawn and
recycled back to the plant headworks for reprocessing. Sludge can also be dewatered using
sludge drying beds prior to disposal by land application.
The stabilized sludge that meets pollutant limits and Class B pathogen reduction and vector
attraction reduction requirements is disposed of in accordance with Non -Discharge Permit No.
WQ0002047. The Class B pathogen reduction requirement is met using Alternative 1 and the
vector attraction reduction requirement is met performing Option 9. Pathogen reduction is
verified through in-house monitoring of fecal coliform bacteria. Sludge is land applied on five
sites (37 fields) totaling 828 acres. The 200 acre Tarboro Farm site is owned by the Town while
the Bourne Farm and Taylor Farm sites are owned by private parties.

Priority Pollutant Analyses

Town of Tarboro
Priority Pollutant Analysis
1/16/2020 4/13/2021 10/13/2022 7/11/2023
METALS (TOTAL RECOVERABLE), CYANIDE, PHENOLS, AND HARDNESS.
ANTIMONY
ug/L
ARSENIC
ug/L
BERYLLIUM
ug/L
CADMIUM
ug/L
CALCIUM
ug/L
8730
7690
11200
11800
CHROMIUM
ug/L
COPPER
ug/L
10.5
11.1
9.3
LEAD
ug/L
MAGNESIUM
ug/L
2240
2250
2750
3500
MERCURY
ng/L
3.74
4.08
1.13
1.02
NICKEL
ug/L
SELENIUM
ug/L
SILVER
ug/L
THALLIUM
ug/L
ZINC
ug/L
20.2
14.2
23.4
25
CYANIDE
mg/L
TOTAL PHENOLIC
COMPOUNDS
mg/L
HARDNESS (as CaCO3)
mg/L
31.00
28.5
39.3
43.8
VOLATILE ORGANIC COMPOUNDS
ACROLEIN
ug/L
ACRYLONITRILE
ug/L
BENZENE
ug/L
BROMOFORM
ug/L
CARBON TETRACHLORIDE
ug/L
CHLOROBENZENE
ug/L
CHLORODIBROMO-
METHANE
ug/L
CHLOROETHANE
ug/L
2-CHLOROETHYLVINYL
ETHER
ug/L

CHLOROFORM
ug/L
DICHLOROBROMO-
METHANE
ug/L
1,1-DICHLOROETHANE
ug/L
1,2-DICHLOROETHANE
ug/L
TRANS-I,2-DICHLORO-
ETHYLENE
ug/L
1,1-DICHLORO-ETHYLENE
ug/L
1,2-DICHLOROPROPANE
ug/L
1,3-DICHLORO-PROPYLENE
ug/L
ETHYLBENZENE
ug/L
METHYL BROMIDE
ug/L
METHYL CHLORIDE
ug/L
METHYLENE CHLORIDE
ug/L
1,1,2,2-TETRA-
CHLOROETHANE
ug/L
TETRACHLORO-ETHYLENE
ug/L
TOLUENE
ug/L
1,1,1-TRICHLOROETHANE
ug/L
1,1,2-TRICHLOROETHANE
ug/L
TRICHLOROETHYLENE
ug/L
VINYL CHLORIDE
ug/L T_
ACID -EXTRACTABLE COMPOUNDS
P-CHLORO-M-CRESOL
ug/L
2-CHLOROPHENOL
ug/L
2,4-DICHLOROPHENOL
ug/L
2,4-DIMETHYLPHENOL
ug/L
4,6-DINITRO-0-CRESOL
ug/L
2,4-DINITROPHENOL
ug/L
2-NITROPHENOL
ug/L
4-NITROPHENOL
ug/L
PENTACHLOROPHENOL
ug/L
PHENOL
ug/L
2,4,6-TRICHLOROPHENOL
ug/L
BASE -NEUTRAL COMPOUNDS
ACENAPHTHENE
ug/L

ACENAPHTHYLENE
ug/L
ANTHRACENE
ug/L
BENZIDINE
ug/L
BENZO(A)ANTHRACENE
ug/L
BENZO(A)PYRENE
ug/L
3,4 BENZO-FLUORANTHENE
ug/L
BENZO(GHI)PERYLENE
ug/L
BENZO(K)
ug/L
FLUORANTHENE
BIS (2-CHLOROETHOXY)
METHANE
ug/L
BIS (2-CHLOROETHYL)-
ETHER
ug/L
BIS (2-CHLOROISO-PROPYL)
ETHER
ug/L
BIS (2-ETHYLHEXYL)
PHTHALATE
ug/L
4-BROMOPHENYL PHENYL
ETHER
ug/L
BUTYL BENZYL PHTHALATE
ug/L
2-CHLORO-NAPHTHALENE
ug/L
4-CHLORPHENYL PHENYL
ETHER
ug/L
CHRYSENE
ug/L
DI-N-BUTYL PHTHALATE
ug/L
DI-N-OCTYL PHTHALATE
ug/L
DIBENZO(A,H) ANTHRACENE
ug/L
1,2-DICHLOROBENZENE
ug/L
1,3-DICHLOROBENZENE
ug/L
1,4-DICHLOROBENZENE
ug/L
3,3-DICHLORO-BENZIDINE
ug/L
DIETHYL PHTHALATE
ug/L
DIMETHYL PHTHALATE
ug/L
2,4-DINITROTOLUENE
ug/L
2,6-DINITROTOLUENE
ug/L
1,2-DIPHENYL-HYDRAZINE
ug/L
FLUORANTHENE
ug/L
FLUORENE
ug/L
HEXACHLOROBENZENE
ug/L

HEXACHLORO-BUTADIENE
ug/L
HEXACHLOROCYCLO-
PENTADIENE
ug/L
HEXACHLOROETHANE
ug/L
INDENO(1,2,3-CD) PYRENE
ug/L
ISOPHORONE
ug/L
NAPHTHALENE
ug/L
NITROBENZENE
ug/L
N-N ITROSO D I-N-
PROPYLAMINE
ug/ L
N-NITROSODI-METHYLAMINE
ug/L
N-NITROSODI-PHENYLAMINE
ug/L
PHENANTHRENE
ug/L
PYRENE
ug/L
1,2,4-TRICHLOROBENZENE
ug/L
NITROBENZENE-D5(s)
37%
75%
98%
96%
2-FLUOROBIPHENYL (S)
33%
63%
71 %
83%
TERPHENYL-D14 (S)
47%
75%
110%
118%
PHENOL-D6 (S)
14%
46%
42%
51 %
2-FLOROPHENOL (S)
20%
63%
55%
65%
2,4,6 TRIBROMOPHENOL
30%
105%
94%
98%
DIBROMOFLUOROMETHANE
(S)
4-BROMOFLUOROBENZENE
99%
102%
99%
100%
TOLUENE-D8 (S)
98%
96%
104%
99%
1,2-DICHLORETHANE-D4 (S)
96%
93%
84%
104%
TOTAL DISSOLVED SOLIDS
mg/L
188
210
317
271
NITROGEN,
KJELDAHL,TOTAL
mg/L
1.2
1
1.5
2.1
NITROGEN, AMMONIA
mg/L
0.13
NITROGEN, TOTAL
mg/L
9.5
9.5
16.6
18.8
NITROGEN, NO2 PLUS NO3
mg/L
8.3
8.5
15.2
16.6
PHOSPHORUS
mg/L
0.57
0.4
1.9
2.1
PHENOL
mg/L

Max Average
0
#DIV/0!
0
#DIV/0!
0
#DIV/0!
0
#DIV/0!
11800
9784
0
#DIV/0!
11.1
9.275
0
#DIV/0!
3500
2604
4.08
2.404
0
#DIV/0!
0
#DIV/0!
0
#DIV/0!
0
#DIV/0!
25
19.14
0
#DIV/0!
0
#DIV/0!
43.8
35.14

r
aceAna1j4ical F
www.0acalabi.com
January 30, 2020
Mr. Mike Allen
Town of Tarboro
506 Dowd Street
PO Box 220
Tarboro, NC 27886
RE: Project: PPA 1/16
Pace Project No.: 92461128
o 2-6
Pace Analytical Services, LLC
9800 Kincey Ave Sulle 100
Hunlersville, NC 28078
(704 )875-9092
Dear Mr. Allen:
Enclosed are the analytical results for sample(s) received by the laboratory on January 16, 2020,
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Chris Derouen
[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 31

aceAnalydicala
www.puolsb:.cam
Project: PPA 1/16
Pace Project No.: 92461128
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Cerlification #. 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NCO30
North Carolina Drinkino Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
VirginiaNELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
VrginiaNELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services. LLC.
Pace Analytical Service*, LLC
9800 Kincey Ave. Suite too
Huntemb Ile, NC 28078
[phone]
Page 2 of 31

Pace Analytical Services, LLC
2ace aljicUI
9800 Kincey Ave Suite too
www.pacoleb:.csm Huntersvi Ile, NC 28078
(704 )875-9092
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
PPA 1/16
92461128
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92461128001
TARBORO VW1 TP EFFLUENT
EPA 1664e
WAM
1
PASI-C
EPA 200.7 Rev 4.4 1994
KQ
15
PASI-A
EPA 1631E
RDT
1
PASI-A
EPA 625.1
Bpi
59
PASI-C
EPA 624.1
SAS
39
PASI-C
SM 2540C-2011
CJL
1
PASI-A
TKN+NO3+NO2 Calculation
EWS
1
PASI-A
EPA 350,1 Rev 2.0 1993
CJH1
1
PASI-A
EPA 351.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 353.2 Rev 2.0 1993
CJH1
1
PASI-A
EPA 365.1 Rev 2.0 1993
NAL
1
PASI-A
EPA420.4 Rev 1.0 1993
DMN
1
PASI-A
SM 4500-CN-E-2011
CJH1
1
PASI-A
92461128002
TARBORO WWTP EFF LLHG BLANK
EPA 1631E
RDT
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 31

aceAnalj tical
www.pac114Ccwm
ANALYTICAL RESULTS
Project: PPA 1/16
Pace Project No.: 92461128
Pace Analytical Services, LLC
9000 Klncey Ave Suite 100
Hunterevllle, NC 28078
(704 )875-9092
sample: TARBORO WWfP Lab ID: 92461128001 Collected: 01/16/20 08:30 Received: 01/16/20 14:45 Matrix: Water
EFFLUENT
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
HEM, Oil and Grease Analytical Method: EPA 1664B
Oil and Grease
ND
mg/L
5.0
1
01/2B20 09:45
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Antimony
ND
ug/L
5.0
1
01/24/20 01:48
01/28/20 01:06 7440-36-0
Arsenic
ND
ug/L
10.0
1
01/2420 01:48
0128120 01:06 7440-38-2
Beryllium
ND
ug/L
1.0
1
01/24/20 01:48
0128/20 01:06 7440-41-7
Cadmium
ND
ug/L
1.0
1
01/2420 01:48
01/28/20 01:06 7440-43-9
Calcium
8730
ug/L
100
1
01/2420 01:48
0128/20 01:06 7440-70-2
Chromium
ND
ug/L
5.0
1
01/2420 01:48
01/28/20 01:06 7440-47-3
Copper
6.4
ug/L
5.0
1
01/24/20 01:48
0128/20 01:06 7440-50-8
Lead
ND
ug/L
5.0
1
01/2420 01:48
0128/20 01:06 7439-92-1
Magnesium
2240
ug/L
100
1
01/2420 01:48
0128/20 01:06 7439-95-4
Nickel
ND
ug/L
5.0
1
01/24/20 01:48
0128/20 01:06 7440-02-0
Selenium
ND
ug/L
10.0
1
0124120 01:48
01/28/20 01:06 7782-49-2
Silver
ND
ug/L
5.0
1
01/2420 01:48
01/2820 01:06 7440-22-4
Thallium
ND
ug/L
10.0
1
01/24/20 01:48
01/2812001:06 7440-28-0
Hardness, Total(SM 2340B)
31000
ug/L
662
1
01/2420 01:48
01/2820 01:06
Zinc
20.2
ug/L
10.0
1
01/2420 01:48
01/2820 01:06 7440-66-6
1631E Mercury,Low Level
Analytical Method: EPA 1631E Preparation Method:
EPA 1631E
Mercury
3.74
ng/L
0.50
1
01/212012:00
0123/2017:12 7439-97-6
625 MSSV
Analytical Method: EPA 625.1 Preparation Method: EPA
625.1
Acenaphthene
ND
ug/L
4.8
1
01/22/2011:57
01/29/2019:49 83-32-9
Acenaphthylene
ND
ug/L
4.8
1
01122/2011:57
0112912019:49 208-96-8
Anthracene
ND
ug/L
4.8
1
01222011:57
01/2912019:49 120-12-7
Benzo(a)anthracene
ND
ug/L
4.8
1
01/22/2011:57
01/29/2019:49 56-55-3
Benzo(a)pyrene
ND
ug/L
4.8
1
01/222011:57
01/2912019:49 50-32-8
Benzo(b)fluoranthene
ND
ug/L
4.8
1
01/222011:57
01/29/2019:49 205-99-2
Benzo(g,h,i)perylene
ND
ug/L
4.8
1
01222011:57
01/2912019:49 191-24-2
Benzo(k)fiuoranthene
ND
ug/L
4.8
1
01/222011:57
01/2912019:49 207-08-9
4-Bromophenylphenyl ether
ND
ug/L
4.6
1
0112220 11:57
01/29/20 19:49 101-55-3
Butylbenzylphthalate
ND
ug/L
4.8
1
01/222011:57
01(29/2019:49 85-68-7
4-Chloro-3-methylphenol
ND
ug/L
4.8
1
01/222011:57
01/29/2019:49 59-50-7
bis(2-Chloroethoxy)methane
ND
ug/L
9.6
1
01/222011:57
01/29/2019:49 111-91-1
bis(2-Chloroethyl) ether
ND
ug/L
4.8
1
01/2220 11:57
01/29/20 19:49 111- 4-4
2-Chloronaphthalene
ND
ug/L
4.8
1
01/22/2011:57
0112912019:49 91-58-7
2-Chlorophenol
ND
ug/L
4.8
1
01222011:57
01/29/2019:49 95-57-8
4-Chlorophenylphenyl ether
ND
ug/L
4.8
1
01/2220 11:57
0129/20 19:49 7005-72-3
Chrysene
ND
ug/L
4.8
1
01222011:57
0112912019:49 218-01-9
Dibenz(a,h)anthracene
ND
ug/L
4.8
1
01222011:57
01/29/2019:49 53-70-3
1,2-Dichlorobenzene
ND
ug/L
4.8
1
01/222011:57
012912019:49 95-50-1
1,3-Dichlorobenzene
ND
ug/L
4.8
1
01/222C 11:57
0129120 19:49 541-73-1
1,4-Dichlorobenzene
ND
ug/L
4.8
1
011222011:57
01/2912019:49 106-46-7
3,3'-Dichlorobenzidine
ND
ug/L
24.0
1
01/22/2011:57
01/29/2019:49 91-94-1
REPORT OF LABORATORY
ANALYSIS
This report shall not
be reproduced, except
in full,
Date: 01/30/2020 04:23 PM
without the written consent of Pace Analytical Services. LLC.
Page 4 of 31

r
Pace Analytical Sorvlces, LLC
17Kincey
aceAnalytic
9800 Ave Suite 100
www.pealeb:.rom
Huntersvi Ile, NC 28078
/
f
(704 )875-9092
ANALYTICAL RESULTS
Project: PPA 1/16
Pace Project No.: 92461128
Sample: TARBORO WWTP
Lab ID: 92461128001 Collected: 01/16/20 08:30
Received: 01/16/20 14:45 Matrix: Water
EFFLUENT
Parameters
Results
Units
Report Limit
DF
Prepared
Analyzed CAS No. Qual
625 MSSV
Analytical Method: EPA625 1
Preparation Method.
EPA625.1
2,4-Dichlorophenol
ND
ug/L
4.8
1
01/22/2011-57
01/29/20 19:49 120-83-2
Diethylphlhalate
NO
ug/L
4.8
1
01/22/201157
01/2912019:49 84-66-2
2,4-Dimethylphenol
NO
ug/L
9.5
1
01122/2011:57
01/29/20 19:49 105-67-9
Dimethylphthalate
NO
ug/L
4.8
1
01/22/20 11:57
01/29/20 19:49 131-11-3
Di-n-butyl phthalate
ND
ug/L
4.8
1
01/22/201157
01/2912019:49 84-74-2
4,6-Dinitro-2-methylphenol
NO
ug/L
19.2
1
01/22/20 11:57
01/29/20 19:49 534-52-1
2,4-Dinitrophenol
NO
ug/L
48.1
1
0112212011:57
01/29/20 19:49 51-28-5
2,4-Dinitrotoluene
NO
ug/L
4.8
1
01122/2011:57
01/29/20 19:49 121-14-2
2,6-Dinitrotoluene
NO
ug/1-
4.8
1
01/2212011.57
01/2912019:49 606-20-2
Di-n-octylphthalate
NO
ug/L
4.8
1
01/22i2011:57
01/29/20 19:49 117-84-0
1,2-Diphenylhydrazine
NO
ug/L
4.8
1
0112212011:57
01/29/20 19:49 122-66-7
bis(2-Ethylhexyl)phthalate
NO
ug/L
4 8
1
01/22/20 11:57
01/29/20 19:49 117-81-7
Fluoranthene
ND
ug/L
4.8
1
01122/2011.57
01129/2019:49 206-44-0
Fluorene
ND
ug/L
4.8
1
01122/2011:57
01/29/20 19:49 86-73-7
lexachlorobenzene
NO
ug1L
4.8
1
01/22/20 11:57
01/29/20 19:49 118-74-1
lexachlorocyclopentadiene
NO
ug/L
9.6
1
01/2212011:57
01/29/20 19:49 77-47-4
lexachloroethane
NO
ug/L
4.8
1
01/22120 11 :57
01/29/20 19:49 67-72-1
Indeno(1,2,3-cd)pyrene
NO
ug/L
4.8
1
01/2212011:57
01/2912019:49 193-39-5
Isophorone
NO
ug/L
9.6
1
01/2212011:57
01/29/20 19:49 78-59-1
Naphthalene
NO
ug/L
4.8
1
01/22/20 11:57
01/29/20 19:49 91-20-3
Nitrobenzene
ND
ug/L
4.8
1
01122/2011:57
01/29/20 19:49 98-95-3
2-Nitrophenol
NO
ug/L
4.8
1
01122/2011.57
01/2912019:49 88-75-5
4-Nitrophenol
NO
ug/L
48.1
1
01/22/20 11:57
01/2912019:49 100-02-7
N-Nitrosodimethylamine
NO
ug/L
4.3
1
01/22/20 11:57
01/29/20 19:49 62-75-9
N-Nitroso-di-n-propylamine
NO
ug/L
4.8
1
01/22/20 11:57
01/29/20 19:49 621-64-7
N-Nitrosodiphenylamine
NO
ug/L
9.6
1
01/22/20 11:57
01/29/20 19:49 86-30-6
Pentachlorophenol
ND
ug/L
9.6
1
01122/2011:57
01/29/2019:49 87-86-5
Phenanthrene
ND
ug/L
4.8
1
01/22/20 11:57
01/29/20 19:49 85-01-8
Phenol
ND
ug1L
4.8
1
0112212011:57
01/29/20 19:49 108-95-2
Pyrene
ND
ug/L
4.8
1
01/22/20 11:57
01/29/20 19:49 129-00-0
2,4,6-Trichlorophenol
ND
ug/L
9.6
1
01122/2011:57
01/29/20 19:49 88-06-2
Surrogates
Nitrobenzene-d5 (S)
37
%
10-120
1
01/22/20 11:57
01/29/20 19:49 4165-60-0
2-Fluorobiphenyl (S)
33
%
15-120
1
01/22/20 11:57
01/29/20 19:49 321-00-8
Terphenyl-d14 (S)
47
%
11-131
1
01/22/20 11:57
01/29/20 19.49 1718-51-0
Phenol-d6 (S)
14
%
10-120
1
01/22/20 11:57
01/29/20 19:49 13127-88-3
2-Flucrophenol (S)
20
%
10-120
1
01/22/20 11 57
01/29/20 19:49 367-12-4
2,4,6-Tribromophenol (S)
30
%
10-137
1
01/22/20 11:57
01/29/20 19:49 118-79-6
624 Volatile Organics
Analytical Method: EPA624 1
Acrolein
NO
ug/L
5.0
1
01/21/2019:29 107-02-8
Acrylonitrile
ND
ug/L
5.0
1
01/21/2019:29 107-13-1
Benzene
ND
ug/L
1.0
1
01/21/2019:29 71-43-2
Bromodichloromethane
ND
ug/L
2.0
1
01/21/2019:29 75-27-4
Bromoform
ND
ug/L
2.0
1
0112112019:29 75-25-2
omomethane
NO
ug/L
2.0
1
01121/2019:29 74-83-9
REPORT
OF LABORATORY ANALYSIS
This report shall not
be reproduced, except in
full,
Date: 01 /30/2020 04:23 PM
without the written consent
of Pace Analytical Services, LLC.
Page 5 of 31

r
aceAnalytical
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ANALYTICAL RESULTS
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntarsvllle, NC 28078
[phone]
Project: PPA 1/16
Pace Project No.: 92461128
Sample: TARBORO WWTP Lab ID: 92461128001 Collected: 01/16/20 08:30 Received: 01/16/20 14:45 Matrix: Water
EFFLUENT
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua!
624 Volatile Organics
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethylvinyl ether
Chloroform
Chloromethane
Di bromochl oro methane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis- 1.3-Dichl oropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachloro-1,3-butadiene
Methylene Chloride
Naphthalene
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluorometha ne
Vinyl chloride
Surrogates
4-Bromofluorobenzene (S)
Toluene -dB (S)
1,2-Dichloroethane-d4 (S)
2540C Total Dissolved Solids
Total Dissolved Solids
Total Nitrogen Calculation
Total Nitrogen
350.1 Ammonia
Nitrogen, Ammonia
Datei 01/30/2020 04:23 PM
Analytical Method: EPA 624.1
ND
ug/L
2.0 1
ND
ug/L
2.0 1
ND
ug/L
2.0 1
ND
ug/L
5.0 1
ND
ug/L
2.0 1
ND
ug/L
20 1
ND
ug/L
20 1
ND
ug/L
2.0 1
ND
ug/L
2.0 1
ND
ug/L
2.0 1
ND
ug/L
20 1
ND
ug/L
2.0 1
ND
ug/L
2.0 1
ND
ug/L
20 1
ND
ug/L
2.0 1
ND
ug/L
2.0 1
ND
ug/L
2.0 1
ND
ug/L
1.0 1
ND
ug/L
50 1
ND
ug/L
2.0
ND
ug/L
5.0
ND
ug/L
2.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
2.0
ND
ug/L
2.0
ND
ug/L
2.0
ND
ug/L
2.0
ND
ug/L
2.0
99
%
70-130
98
%
70-130
96
%
70-130
Analytical Method: SM 2540C-2011
188 mg/L 25.0
Analytical Method: TKN+NO3+NO2 Calculation
9.5 mg1L 0-52
Analytical Method: EPA 350.1 Rev 2.0 1993
ND mg/L 0.10
01121/2019:29 56-23-5
01121 /20 19:29 108-90-7
01/21/20 19:29 75-00-3
01121 /20 19:29 110-75-8
01/21/20 19:29 67-66-3
01/21/20 19:29 74-87-3
01121 /20 19:29 124-48-1
01121/2019:29 95-50-1
01/21/20 19:29 541-73-1
01/21/20 19:29 106-46-7
01/21/20 19:29 75-34-3
01/21/20 19:29 107-06-2
01 /21120 19:29 75-35-4
01 /21120 19:29 156-60-5
01/21/20 19:29 78-87 5
01/21/20 19:29 10061-01-5
01/21/20 19:29 10061-02-6
01 /21120 19:29 100-41-4
01/21/20 19:29 87-68-3
01/21/20 19:29 75-09-2
01/21/20 19:29 91-20-3
01 /21120 19:29 79-34-5
01/21/20 19:29 127-184
01/21/20 19.29 108-88-3
01/21/20 19:29 120-82-1
01/2112019:29 71-55-6
01/21/20 19:29 79-00-5
01/21/20 19:29 79-01-6
01 /21120 1929 75-69-4
01 /21 /20 19.29 75-01-4
0112112019:29 460-00-4
01121/2019:29 2037-26-5
01 /21/20 19:29 17060-07-0
1 01121 /20 00:32
1 01/29/20 14:04
1 01/25/2019:12 7664-41-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC
Page 6 of 31

aceAnalyfical p
j www.pscalabc.com
i
I
Project PPA 1/16
Pace Project No.: 92461128
Sample: TARBORO WWTP
EFFLUENT
Parameters
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total
353.2 Nitrogen, N021NO3 pres.
Nitrogen, NO2 plus NO3
365.1 Phosphorus, Total
Phosphorus
420.4 Phenolics, Total
Phenol
450OCNE Cyanide, Total
Cyanide
Pace Analytical S ervlces, LLC
9800 Kincey Ave SLlte 100
Huntersvitle, NC 20078
[phone]
ANALYTICAL RESULTS
Lab ID: 92461128001 Collected: 01/16/20 08:30 Received: 01/16/20 14:45 Matrix: Water
Results Units Report Limit OF Prepared Analyzed CAS No.
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
1.2 mg/L 0.50 1 01/28/20 11:45 01 /29/20 07:42 7727-37-9
Analytical Method: EPA 353.2 Rev 2.0 1993
8.3 mg/L 0.20 5 01/26/2019:38
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
0.57 mg/L 0,050 1 01/19/201749 01/20/2013:57 7723-14-0
Analytical Method: EPA420.4 Rev 1 0 1993 Preparation Method: EPA420.4 Rev 1-0 1993
NO mg/L 0,020 1 01/20/201010 01/20/2015:08 108-95-2
Analytical Method: SM 4500-CN-E-2011 Preparation Method: SM 4500-CN-E-2011
NO mg/L 0,0080 1 01/191201T30 01120/2000:52 57-12-5
Qual
Sample: TARBORO WWTP EFF Lab 10: 92461128002 Collected: 01/16/20 08:30 Received: 01/16/20 14:45 Matrix: Water
LLHG BLANK
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
1631E Mercury,Low Level Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Mercury ND ng/L 0.50 1 01/21/2012:00 01/2312015:33 7439-97-6
Date: 01/30/2020 04:23 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 31

1�?eAnalytical'
www.pacolobs.com
QUALITY CONTROL DATA
Project: PPA 1/16
Pace Project No.: 92461128
QC Batch: 521729 Analysis Method: EPA 1664B
QC Batch Method: EPA 1664B Analysis Description: 1664 HEM, Oil and Grease
Associated Lab Samples: 92461128001
METHOD BLANK: 2790998 Matrix: Water
Associated Lab Samples: 92461128001
Blank Reporting
Q I'f
Pace Analytical Services, LLC
9000 Kincey Ave. Suite 100
HuntefavIlie, NC 28078
[phone]
Parameter
Units
Result Limit
Analyzed
ua I lers
Oil and Grease
mg/L
ND 5.0
01/28/20 09:45
LABORATORY CONTROL SAMPLE:
2790999
Spike LCS
LCS
% Rec
Parameter
Units
Conc. Result
% Rec
Limits Qualifiers
Oil and Grease
mg/L
40 39.7
99
78-114
MATRIX SPIKE SAMPLE:
2791005
92461058001 Spike
MS
MS %Rec
Parameter
Units
Result Conc.
Result
% Rec Limits Qualifiers
Oil and Grease
mg/L
ND 40
20.1
43 78-114 J(M1)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/30/2020 04:23 PM
without the written consent of Pace Analytical Services, LLC. Page 8 Of 31

2aceAnalj4ical-
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j
QUALITY CONTROL DATA
Project: PPA 1/16
Pace Project No.: 92461128
QC Batch: 521153
Analysis Method:
EPA 200.7 Rev 4.4 1994
QC Batch Method: EPA 200.7 Rev 4.4 1994
Analysis Description:
200.7 MET
Associated Lab Samples: 92461128001
METHOD BLANK: 2788325
Matrix: Water
Associated Lab Samples: 92461128001
Blank Reporting
Parameter
Units
Result Limit
Analyzed
Antimony
ug/L
NO
5.0
01/28/20 00:16
Arsenic
ug/L
ND
10.0
0128120 00:16
Beryllium
ug/L
ND
1.0
01/28/20 00:16
Cadmium
ug/L
ND
1.0
01/2812000:16
Calcium
ug/L
NO
100
01/28/20 00:16
Chromium
ug/L
NO
5.0
01/28/2000:16
Copper
ug/L
NO
5.0
0128/20 00:16
Hardness, Total(SM 2340B)
ug/L
NO
662
0128120 00:16
Lead
ug/L
ND
5.0
0128/20 00:16
Magnesium
ug/L
NO
100
0128/20 00:16
Nickel
ug/L
NO
5.0
0128120 00:16
Selenium
ug/L
NO
10.0
0128/20 00:16
Silver
ug/L
ND
5.0
0128/20 00:16
Thallium
ug/L
ND
10.0
012at20 00:16
Zinc
ug/L
ND
10.0
0128/20 00:16
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
2788326
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
500
457
91
85-115
Arsenic
ug/L
500
435
87
85-115
Beryllium
ug/L
500
504
101
85-115
Cadmium
ug/L
500
471
94
85-115
Calcium
ug/L
5000
5120
102
85-115
Chromium
ug/L
500
507
101
85-115
Copper
ug/L
500
484
97
85-115
Hardness, Total(SM 2340B)
ug/L
33100
32900
99
85-115
Lead
ug/L
500
477
95
85-115
Magnesium
ug/L
5000
4870
97
85-115
Nickel
ug/L
500
480
96
85-115
Selenium
ug/L
500
452
90
85-115
Silver
ug/L
250
242
97
85-115
Thallium
ug/L
500
448
90
85-115
Zinc
ug/L
500
462
92
85-115
Pace Analytical services, LLC
9800 Kinsey Ave, Suite 100
Huntarsvllle, NC 28078
(704)e75-9092
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an altemate unit Is presented to the right or the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /30/2020 04:23 PM without the written consent of Pace Analytical Services, LLC.
Page 10 of 31

aceAnalytical
www.pacllabs.com
Project: PPA 1/16
Pace Project No.: 92461128
QUALITY CONTROL DATA
Pace Analytical S ervlces, LLC
9800 Kincey Ave. Suite 100
Huntersvi/le, NC 28078
(704 )875-9092
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2788327
2788328
MS
MSD
92461003001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Antimony
ug/L
ND
500
500
494
469
99
94
70-130
5
Arsenic
ug/L
ND
500
500
476
452
95
90
70-130
5
Beryllium
ug/L
ND
500
500
522
500
104
100
70-130
4
Cadmium
ug/L
ND
500
500
505
480
101
96
70-130
5
Calcium
ug/L
17100
5000
5000
22200
21100
101
80
70-130
5
Chromium
ug/L
ND
500
500
514
487
103
97
70-130
6
Copper
ug/L
ND
500
500
509
485
102
97
70-130
5
Hardness, Total(SM 23408)
ug/L
53200
33100
33100
86800
82700
101
89
70-130
5
Lead
ug/L
ND
500
500
492
470
98
94
70-130
5
Magnesium
ug/L
2530
5000
5000
7610
7260
102
94
70-130
5
Nickel
ug/L
ND
500
500
497
475
99
95
70-130
5
Selenium
ug/L
ND
500
500
504
477
100
95
70-130
5
Silver
ug/L
ND
250
250
256
242
102
97
70-130
5
Thallium
ug/L
ND
500
500
454
430
91
86
70-130
5
Zinc
ug/L
11.3
5D0
500
488
468
95
91
70-130
4
AATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2788329
2788330
MS
MSD
92461128001
Spike
Spike
MS
MSC
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Antimony
ug/L
ND
500
500
490
492
98
98
70-130
0
Arsenic
ug/L
ND
500
500
477
486
95
96
70-130
2
Beryllium
ug/L
ND
500
500
510
514
102
103
70-130
1
Cadmium
ug/L
ND
500
500
496
500
99
100
70-130
1
Calcium
ug/L
8730
5000
5000
13600
13700
97
100
70-130
1
Chromium
ug/L
ND
500
500
503
510
100
102
70-130
2
Copper
ug/L
6.4
500
500
508
509
100
100
70-130
0
Hardness, Total(SM 2340B)
ug/L
31000
33100
33100
63400
64200
98
100
70-130
1
Lead
uglL
ND
500
500
493
493
98
98
70-130
0
Magnesium
ug/L
2240
500D
5000
7160
7280
98
101
70-130
2
Nickel
ug/L
ND
50D
500
491
494
98
99
70-130
1
Selenium
ug/L
ND
500
500
503
502
100
100
70-130
0
Silver
ug/L
ND
250
250
252
254
100
101
70-130
1
Thallium
ug/L
ND
500
500
465
464
92
92
70-130
0
Zinc
ug/L
20.2
500
500
504
510
97
98
70-130
1
Results presented on this page are in the units Indicated by the "Units" column except where an altemate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/30/2020 04:23 PM without the written consent of Pace Analytical Services, LLC Page 11 of 31

aceAnalytical
www.paalabc.com
QUALITY CONTROL DATA
Project: PPA 1/16
Pace Project No.: 92461128
QC Batch: 520503 Analysis Method. EPA 624.1
QC Batch Method: EPA624.1 Analysis Description: 624 MSV
Associated Lab Samples: 92461128001
Pace Analytical Sorvices, LLC
9800 Kincey Ave. Suite 100
Hunlersville, NC 28078
[phone]
METHOD BLANK: 2785137
Associated Lab Samples: 92461128001
Parameter
Units
Matrix: Water
Blank Reporting
Result Limit
Analyzed Qualifiers
1,1,1-Trichloroethane
ug/L
NO
2.0
01/2112011:45
1.1,2,2-Tetrachloroethane
ug/L
ND
2.0
01/21/20 11:45
1,1,2-Trichloroethane
ug/L
NO
2 0
01/21/20 11:45
1,1-Dichloroethane
ug/L
ND
2.0
01121/2011:45
1,1-Dichloroethene
ug/L
NO
20
01/21/20 11:45
1,2,4-Trichlorobenzene
ug/L
NO
2.0
0112112011:45
1,2-Dichlorobenzene
ug/L
NO
2.0
01121/201145
1,2-Dichloroethane
ug/L
ND
2.0
0112112011:45
1,2-Dichloropropane
ug/L
ND
2.0
01/21/20 11:45
1,3-Dichlorobenzene
ug/L
ND
2.0
01/21/2011A5
1,4-Dichlorobenzene
ug/L
ND
2.0
01/21/20 11:45
2-Chloroethylvinyl ether
ug/L
ND
5.0
01/21/20 11 45
Acrolein
ug/L
ND
5.0
01121/2011:45
Acrylonitrile
ug/L
ND
5.0
01121/2011:45
Benzene
ug/L
ND
1.0
0112112011:45
Bromodichloromethane
ug/L
ND
2.0
01/21/20 11:45
Bromoform
ug/L
ND
2.0
01/21/20 11:45
Bromomethane
uglL
ND
2.0
01/2112011:45
Carbon tetrachloride
ug/L
NO
2.0
01/21/20 11:45
Chlorobenzene
ug/L
NO
2.0
01121/2011:45
Chloroethane
ug/L
NO
2.0
01/21/20 11:45
Chloroform
ug/L
ND
2.0
01/21/20 11:45
Chloromethane
ug/L
ND
2.0
01121/2011:45
cis- 1,3-Dichloropropene
ug/L
ND
2.0
01121/2011:45
Dibromochloromethane
ug/L
NO
2.0
01/21/20 11:45
ug/L
NO
1.0
01/21/20 11:45
Ethylbenzene
ug/L
ND
5.0
01/21/20 11:45
Hexachloro-1,3-butadiene
NO
2.0
01121Y20 11:45
Methylene Chloride
ug/L
ug/L
ND
5.0
0 1121120 11:45
Naphthalene
ug/L
ND
2.0
0 1121120 11:45
Tetrachloroethene
ug/L
ND
1.0
01/2112011:45
Toluene
trans-1,2-Dichloroethene
ug/L
ND
2.0
01/21/20 11:45
trans-1,3-Dichloropropene
ug/L
NO
2.0
01/21/20 11:45
Trichloroethene
ug/L
ND
2.0
01/2112011:45
Trichlorofluoromethane
ug/L
ND
2.0
01/21/20 11:45
ug/L
ND
2.0
01/21/20 11:45
vinyl chloride
%
93
70-130 01/21/20 11:45
1,2-Dichloroethane-d4 (S)
99
70-130
01/21/20 11:45
4-Bromofluorobenzene (S)
%
97
70-130 01/21/20 11:45
Toluene-d8 (S)
%
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /30/2020 04:23 PM without the written consent of Pace Anaiyticai Services, LLC.
Page 12 of 31

aceAnaiytical
www.pacslabt.com
QUALITY CONTROL DATA
Project: PPA 1/16
Pace Project No.: 92461128
LABORATORY CONTROL SAMPLE: 2785138
Parameter
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1,1-Trichloroethane
ug/L
20
14.8
74
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
22A
112
60-140
1,1,2-Tdchloroethane
ug/L
20
18.4
92
70-130
1,1-Dichloroethane
ug/L
20
15.1
75
70-130
1,1-Dichloroethene
ug/L
20
15.6
78
50-150
1,2,4-Trichlorobenzene
ug/L
20
24.3
122
70-130
1,2-Dichlorobenzene
ug/L
20
22.7
113
65-135
1,2-Dichloroethane
ug/L
20
14.9
75
49-155
1,2-Dichloropropane
ug/L
20
18.1
91
35-165
1,3-Dichlorobenzene
ug/L
20
22.6
113
70-130
1,4-Dichlorobenzene
ug/L
20
22.6
113
65-135
2-Chloroethylvinyiether
ug/L
40
36.0
90
1-225
Acrolein
ug/L
100
128
128
60-140
Acrylonitrile
ug/L
100
81.1
81
60-140
Benzene
ug/L
20
16.7
83
65-135
Bromodichloromethane
ug/L
20
17.4
87
65-135
Bromoform
ug/L
20
19.9
99
70-130
Bromomethane
ug/L
20
15.5
77
15-185
Carbon tetrachloride
ug/L
20
16.4
82
70-130
Chlorobenzene
ug/L
20
20.1
100
65-135
Chloroethane
ug/L
20
14.0
70
40-160
Chloroform
ug/L
20
15.5
78
70-135
Chloromethane
ug/L
20
9.9
49
1-205
cis-1,3-Dichloropropene
ug/L
20
18.3
92
25-175
Dibromochloromethane
ug/L
20
21.1
105
70-135
Ethylbenzene
ug/L
20
20.0
100
60-140
Hexachloro-1,3-butadiene
ug/L
20
25.0
125
70-130
Methylene Chloride
ug/L
20
15.6
78
60-140
Naphthalene
ug/L
20
25.1
125
70-130
Tetrachloroethene
ug/L
20
19.1
96
70-130
Toluene
ug/L
20
17.2
86
70-130
trans-1,2-Dichloroethene
ug/L
20
15.7
79
70-130
trans-1,3-Dichloropropene
ug/L
20
17.9
89
50-150
Trichloroethene
ug/L
20
17.4
87
65-135
Trichlorofluoromethane
ug/L
20
13.3
67
50-150
Vinyl chloride
ug/L
20
13.1
65
5-195
1,2-Dichloroethane-d4 (S)
%
95
70-130
4-Bromofluorobenzene (S)
%
96
70-130
Toluene-d8 (S)
%
96
70-130
Pace Analytical Sorvicos, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2785139 2785140
MS MSD
92460563001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
11,1-Trichloroethane ug/L ND 80 80 _ 76.3 76.0 95 95 52-162 0
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shag not be reproduced, except in full,
Date: 01/30/2020 04:23 PM without the written consent of PaceAnalytical Services, LLC Page 13 of 31

Pace Analytical Services, LLC
�;a'ce A nalyfica I 9B00 Kincey Ave Suite 100
www.patala6a.com Huntersvllle, NC 20078
�
!/ (704 )87 5-9092
f
QUALITY CONTROL DATA
Project: PPA 1116
Pace Project No.: 9246112E
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
2785139
2785140
MS
MSD
92460563001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Clual
1,1,2,2-Tetrachloroethane
ug/L
ND
80
80
90.8
89.4
113
112
46-157
2
1,12-Trichloroethane
ug/L
ND
80
80
75.7
77.5
95
97
52-150
2
1,1-Dichloroethane
ug/L
NO
80
80
76.4
76.8
95
96
59-155
1
1,1-Dichloroethene
ug/L
NO
80
80
84.2
81.9
105
102
1-234
3
1,2,4-Tdchlorobenzene
ug/L
ND
80
80
96.1
92.1
120
115
70-130
4
1,2-Dichlorobenzene
ug/L
NO
80
80
94.7
88.3
118
110
18-190
7
1,2-Dichloroethane
ug/L
ND
80
80
72.5
70.0
91
87
49-155
4
1,2-Dichloropropane
ug/L
NO
80
80
84.5
82.6
106
103
1-210
2
1,3-Dichlorobenzene
ug/L
NO
80
80
97.2
91.7
122
115
59-156
6
1,4-Dichlorobenzene
ug/L
NO
80
80
104
103
130
128
18-190
2
2-Chloroethylvinyl ether
ug/L
ND
160
160
ND
NO
0
0
1-305
J(P5)
Acrolein
ug/L
NO
400
400
668
645
167
161
40-160
3 J(MI)
Acrylonitrile
ug/L
ND
400
400
406
382
101
96
40-160
6
Benzene
ug/L
NO
80
80
83.1
79.9
104
100
37-151
4
Bromodichloromethane
ug/L
NO
80
80
78.0
76.6
98
96
35-155
2
omoform
ug/L
ND
80
80
7T6
77.9
97
97
45-169
0
omomethane
ug/L
ND
80
80
53.6
53.1
67
66
1-242
1
Carbon tetrachloride
ug/L
ND
80
80
80.7
77.9
101
97
70-140
4
Chlorobenzene
ug/L
NO
80
80
94.3
92A
118
115
37-160
2
Chloroethane
ug/L
ND
80
80
69.1
72.5
86
91
14-230
5
Chloroform
ug/L
ND
80
80
79.6
75.7
95
91
51-138
5
Chloromethane
ug/L
ND
80
80
49.3
47.5
62
59
1-273
4
cis -1.3-Dichloropropene
ug/L
NO
80
80
78.4
76.8
98
96
1-227
2
Dibromochloromethane
ug/L
ND
80
80
87.9
86.2
110
108
53-149
2
Ethylbenzene
ug/L
NO
80
80
93.3
92.9
117
116
37-162
0
Hexachloro-1,3-butadiene
ug/L
ND
80
80
139
126
174
158
70-130
9 J(M1)
Methylene Chloride
ug/L
NO
80
80
79A
76.0
99
95
1-221
4
Naphthalene
ug/L
ND
80
80
970
89.4
121
112
70-130
8
Tetrachioroethene
ug/L
NO
80
80
91.1
88.9
114
111
64-148
2
Toluene
ug/L
10.5
60
80
8T6
87.9
96
97
47-150
0
trans-1,2-Dichloroethene
ug/L
NO
80
80
78.5
75.2
98
94
54-156
4
trans-1,3-Dichloropropene
ug/L
ND
80
80
74.7
73.7
93
92
17-183
1
Trichloroethene
ug/L
ND
80
80
78.9
81.2
99
102
70-157
3
Trichlorofluoromethane
ug/L
ND
80
80
73.3
71.1
92
89
17-181
3
Vinyl chloride
ug/L
ND
80
80
72.2
70.2
90
88
1-251
3
1,2-Dichloroethane-d4 (S)
%
88
87
70-130
4-Bromofluorobenzene (S)
%
98
98
70-130
Toluene-d8 (S)
%
94
95
70-130
Results presented on this page are In the units Indicated by the "Units" column except wherean alternate unit is presented to the right or the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /30/2020 04:23 PM without the written consent of Pace Analytical Services, LLC
Page 14 of 31

/a'ce A nalj4ical ,f
www.pecolebs.com
QUALITY CONTROL DATA
Project: PPA 1/16
Pace Project No., 92461128
QC Batch. 520690 Analysis Method: EPA 625 1
QC Batch Method: EPA 625.1 Analysis Description: 625 MSS
Associated Lab Samples: 92461128001
METHOD BLANK: 2785923
Associated Lab Samples: 92461128001
Parameter
Units
Matrix: Water
Blank Reporting
Result Limit
Analyzed
1,2-Dichlorobenzene
ug/L
NO
5,0
01/24I2012:22
1,2-Diphenylhydrazine
ug/L
NO
5.0
01/2412012:22
1,3-Dichlorobenzene
ug/L
NO
5.0
0112412012:22
1,4- Diehl orobenzene
ug/L
NO
5 0
01/24/20 12.22
2,4,6-Trichlorophenol
ug/L
ND
10.0
01/24/20 12:22
2,4-Dichlorophenol
ug/L
ND
5.0
01124/2012:22
2,4-Dimethylphenol
ug/L
NO
10.0
01/24/20 12 22
2,4-Dinitrophenol
ug/L
NO
500
01124/20 12:22
2 4-Dinitrotoluene
ug/L
NO
5.0
0124/20 12:22
2,6-Dinitrotoluene
ug/L
ND
5 0
01/24/20 12:22
2-Chloronaphthalene
uglL
ND
5.0
01124/2012:22
2-Chlorophenol
ug/L
ND
5.0
01/24/20 12:22
2-Nitrophenol
ug/L
ND
5.0
012412012:22
3,3'-Dichlorobenzidine
ug/L
NO
25.0
012412012:22
4,6-Dinitro-2-methylphenol
ug/L
ND
200
01/24/20 12:22
4-Bromophenylphenyl ether
ug/L
NO
5.0
0124,120 12:22
4-Chloro-3-methylphenol
ug/L
ND
5.0
0124/2012:22
4-Chlorophenylphenyl ether
ug/L
NO
5.0
0124120 1222
4-Nitrophenol
ug/L
NO
50.0
012412012:22
Acenaphlhene
ug/L
NO
5.0
01/24/2012.22
Acenaphlhylene
ug/L
ND
5.0
01/24/20 12:22
Anthracene
ug/L
NO
5.0
01/24/20 12:22
Benzo(a)anthracene
ug/L
NO
5.0
01/24/20 12:22
Benzo(a)pyrene
ug/L
ND
5.0
01124/2012:22
Benzo(b)fluoranthene
ug/L
ND
5.0
01/24/20 12:22
Benzo(g,h,i)perylene
ug/L
NO
5.0
01124/2012:22
Benzo(b)fluoranthene
ug/L
NO
5.0
0112412012:22
bis(2-Chloroethoxy)methane
ug/L
NO
10.0
012412012:22
bis(2-Chloroethyl) ether
ug/L
NO
5.0
01/24/20 12:22
bis(2-Ethylhexyl)phthalate
ug/L
NO
5.0
0112412012:22
Butylbenzylphthalate
ug/L
ND
5.0
012412012:22
Chrysene
ug/L
ND
5.0
0124/2012:22
Di-n-butylphthalate
uglL
ND
5.0
01/24/20 12:22
Di-n-octylphthalate
ug/L
ND
5.0
01124/2012:22
Dibenz(a,h)anthracene
ug/L
ND
5.0
01/2412012:22
Diethylphthalate
ug/L
NO
5.0
01/24/2012.22
Di methyl phtha late
ug/L
ND
5.0
0124/2012:22
Fluoranthene
ug/L
ND
5.0
0124/2012:22
ug/L
ND
5.0
0124/2012:22
Fluorene
ug/L
ND
5.0
01/24/20 12:22
Hexachlorobenzene
NO
10.0
01/24/20 12,22
Hexachlorocydopentadiene
ug/L
Qualifiers
Pace Analytical Sorvlces, LLC
9000 Kincey Ave Suile 100
Huntersvi Ile, NC 26078
(704 )67 5-9092
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/30/2020 04:23 PM without the written consent of Pace Analytical Services, LLC Page 15 of 31

aceAnalytical'
www.pecolatigsom
t
Project: PPA 1/16
Pace Project No.: 92461128
METHOD BLANK: 2785923
Associated Lab Samples: 92461128001
Parameter
Units
Hexachloroethane
ug/L
Indeno(1,2,3-cd)pyrene
ug/L
Isophorone
ug/L
N-Nitroso-di-n-propyl a mine
ug/L
N-Nitrosodimethylamine
ug/L
N-Nitrosodiphenylamine
ug/L
Naphthalene
ug/L
Nitrobenzene
ug/L
Pentachlorophenol
ug/L
Phenanthrene
ug/L
Phenol
ug/L
Pyrene
ug/L
2,4,6-Tribromophenol (S)
%
2-Fluorobiphenyl (S)
%
2-Fluorophenol (S)
%
Nitrobenzene-d5 (S)
%
Phenol-d6 (S)
%
Terphenyl-d14 (S)
°fie
Pace Analytical Services, LLC
9800 Kincey Ave Suite 100
Hunlersvilie, NC 28078
(704 )87 5-9092
QUALITY CONTROL DATA
Matrix: Water
Blank
Result
Reporting
Limit
Analyzed Qualifiers
NO
5.0
01124/2012:22
NO
5.0
01/24/2012:22
NO,
10.0
01/24/2012:22
ND
5.0
01/2412012:22
ND
5.0
01/2412012:22
NO
10.0
01/24/2012:22
NO
5.0
0112412012:22
NO
5.0
01/2412012:22
NO
10.0
01/2412012:22
NO
5.0
01/2412012:22
NO
5.0
01124/2012:22
NO
5.0
01/24/20 12:22
44
10-137
011241201222
50
15-120
01/24/2012:22
38
10-120
01/24/2012:22
55
10-120
01/24/20 12:22
25
10-120
01124/2012:22
55
11-131
01 /24120 12:22
LABORATORY CONTROL SAMPLE:
2785924
Spike
LCS
LCS
%Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,2-Dichlorobenzene
ug/L
50
32.6
65
B8
32-129
25-150
1,2-Diphenylhydrazine
ug/L
50
44.0
63
1-172
1,3-Dichlorobenzene
ug/L
50
31.7
64
20-124
1,4-Dichlorobenzene
ug/L
50
50
32.0
300
60
37-144
2,4,6-Trichlorophenol
ug/L
50
32.6
65
39-135
2,4-Dichlorophenol
ug/L
50
36.4
73
32-120
2.4-Dimethylphenol
ug/L
250
145
58
1-191
2,4-Dinitrophenol
uglL
50
36.0
72
39-139
2,4-Dinitrotoluene
ug/L
50
35.8
72
50-158
2,6-Dinitrotoluene
ug/L
50
32.7
65
60-120
2-Chloronaphthalene
ug/L
50
34 2
68
23-120
34
2-Chlorophenol
ug/L
50
34 6
69
181
29-1-181
2-Nitrophenol
ug/L
ug/L
100
70.5
73
262
3,3'-Dichlorobenzidine
100
73.2
1-181
4,6-Dinitro-2-methylphenol
ug/L
63
53-127
4-Bromophenylphenyl ether
u9/L
50
31.6
71
22-147
4-Chloro-3-methylphenol
ug/L
100
70-8
65
25-158
4-Chlorophenylphenyl ether
ug/L
50
32.4
33
1-132
4-Nitrophenol
ug/L
250
50
82 8
35.4
71
47-145
Acenaphthene
ug/L
50
38.8
78
33-145
Acenaphthylene
uglL
50
40.3
81
27 133
Anthracene
uglL
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/30/2020 04:23 PM without the written consent of Pace Analytical Services, LLC
Page 16 of 31

l*;a'ceAnalyfical'
www.pecalabi.com
QUALITY CONTROL DATA
Project: PPA 1/16
Pace Project No.: 92461128
Pace Analytical S ervicos, LLC
9800 Kincey Ave. Suite 100
Huntersvitlle, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
Parameter
2785924
Units
Spike
Cone.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Benzo(a)anthracene
ug/L
50
3B.2
76
33-143
Benzo(a)pyrene
ug/L
50
40.3
81
17-163
Benzo(b)tluoranthene
ug/L
50
37.7
75
24-159
Benzo(g,h,i)perylene
ug/L
50
40.6
81
1-219
Benzo(k)fluoranthene
ug/L
50
36.8
74
11-162
bis(2-Chloroethoxy)methane
ug/L
50
33.2
66
33-184
bis(2-Chloroethyl) ether
ug/L
50
35.7
71
12-158
bis(2-Ethylhexyl)phthalate
ug/L
50
45.1
90
B-158
Butylbenzylphthalate
ug/L
50
42.4
85
1-152
Chrysene
ug/L
50
37A
74
17-168
Di-n-butylphthalate
ug/L
50
42.3
85
1-120
Di-n-octylphthalate
ug/L
50
57.0
114
4-146
Dibenz(a,h)anthracene
ug/L
50
43.1
86
1-227
Diethylphthalate
ug/L
50
35.7
71
1-120
Dimethylphthalate
ug/L
50
34.3
69
1-120
Fluoranlhene
ug/L
50
38.3
77
26-137
Fluorene
ug/L
50
36.1
72
59-121
Hexachlorobenzene
ug/L
50
31.9
64
1-152
Hexachlorocyclopentadiene
ug/L
50
18.6
37
25-150
Hexachloroethane
ug/L
50
31.9
64
40-120
Indeno(1,2,3-cd)pyrene
ug/L
50
41.4
83
1-171
Isophorone
ug/L
50
36.1
72
21-196
N-Nitroso-di-n-propylamine
ug/L
50
37.0
74
1-230
N-Nitrosodimethylamine
ug/L
50
27.6
55
25-150
N-Nitrosodiphenylamine
ug/L
50
39.2
78
25-150
Naphthalene
ug/L
50
36.1
72
21-133
Nitrobenzene
ug/L
50
36.7
73
56
35-180
14-176
Pentachlorophenol
ug/L
100
55.9
79
54-120
Phenanthrene
ug/L
50
39.6
32
5-120
Phenol
ug/L
50
50
16.1
36.1
72
52-120
Pyrene
ug/L
71
10-137
2,4,6-Tribromophenol (S)
%
65
15-120
2-Fluorobiphenyl (S)
%
-49
10-120
2-Fluorophenol(S)
%
74
10-120
Nitrobenzene-d5(S)
%
32
10-120
Phenol-d6 (S)
%
67
11-131
Terphenyl-04 (S)
%
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2785925
2785926
Parameter
35524868001
Units Result
ug/L 0.86U
ug/L 0.88U
ug/L 0.79U
MS
Spike
Conc.
MSD
Spike MS
Cones Result
49 17.3
49 31.2
49 16.7
MSD MS
Result % Rec
13.5 35
23.6 63
13.2 34
MSD
% Rec
%Rec
Limits RPD Qual
32-129 25 J(M1)
25-150 28
1-172 23
28
48
27
49.5
49.5
49.5
1,2-Dichlorobenzene
1,2-Diphenylhydrazine
1,3-Dichlorobenzene
Results presented
on this page are in
the units indicated
by the
"units' column except where an alternate unit Is presented to the right of the result.
Date: 01/30/2020 04:23 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 17 of 31

aceAna1j4ica1
'
www.plcllabs.com
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Hunteraville, NC 28078
[phone]
Project: PPA 1/16
Pace Project No.: 92461128
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2785925
2785926
MS
MSD
35524868001
Spike
Spike
MS
MSD
MS
MSD
%Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
1,4-Dichlorobenzene
ug/L
0.93U
49.5
49
17.1
13.4
35
27
20-124
2,4,6-Trichlorophenol
ug/L
1.3U
49.5
49
16.1
12.3
33
25
37-144
2,4-Dichlorophenol
ug/L
1.7U
49.5
49
15.6
12.2
32
25
39-135
2,4-Dimethylphenol
ug/L
1.2U
49.5
49
18.0
13.8
36
28
32-120
2,4-Dinitrophenol
ug/L
8.81.1
248
245
107
82.3
43
34
1-191
2,4-Dinitrotoluene
ug/L
0.88U
49.5
49
28A
22.7
57
46
39-139
2,6-Dinitrotoluene
ug/L
0.96U
49.5
49
26.7
19.9
54
41
50-158
2-Chloronaphthalene
ug/L
0.96U
49.5
49
17.3
13.4
35
27
60-120
2-Chlorophenol
ug/L
1.31.)
49.5
49
16.4
12.7
33
26
2-Nitrophenol
ug/L
0.89U
49.5
49
17.3
13.5
35
28
3,3'-Dichlorobenzidine
ug/L
2.1U
99
98
53.0
43.6
54
44
4,6-Dinitro-2-methylphenol
ug/L
2.5U
99
98
51.9
42.4
52
43
4-Bromophenylphenyl ether
ug/L
0.80U
495
49
23.2
17.4
47
36
4-Chloro-3-methylphenol
ug/L
3.6U
99
98
38.8
28.4
39
29
4-Chlorophenylphenyl ether
ug/L
0.85U
49.5
49
22.5
15.4
45
31
4-Nitrophenol
ug/L
4.OU
248
245
50.7
3851
21
16
Acenaphthene
ug/L
025U
49.5
49
21.8
15.7
44
32
Acenaphthylene
ug/L
0.21U
49.5
49
23.5
17.2
47
35
Anthracene
ug/L
0.14U
49.5
49
30.4
25.3
61
52
Benzo(a)anthracene
ug/L
0.32U
49.5
49
28.4
245
57
50
Benzo(a)pyrene
ug/L
029U
495
49
29.4
24.9
59
51
Benzo(b)fluoranthene
ug/L
0.27U
49.5
49
27.0
230
55
47
Benzo(g,hJ)perylene
ug/L
0.37U
49.5
49
29.3
25.1
59
51
Benzo(k)fluoranthene
ug/L
0.42U
49.5
49
26.1
22.9
53
47
bis(2-Chloroethoxy)methane
ug/L
0.90U
49.5
49
17.4
13.3
35
27
bis(2-Chloroethyl) ether
ug/L
0.98U
49.5
49
19.7
15.2
40
31
bis(2-Ethylhexy0phthalate
ug/L
0.77U
49.5
49
33.9
29.6
69
60
Butylbenzylphthalate
ug/L
0.77U
49.5
49
33.5
29.3
68
60
Chrysene
ug/L
0.21U
49.5
49
27.1
23.8
55
49
Di-n-butylphthalate
ug/L
0.74U
49.5
49
31.1
26.6
63
54
Di-n-octylphthalate
ug/L
0.65U
49.5
49
39.4
33.9
80
69
Dibenz(a,h)anthracene
ug/L
0.54U
49.5
49
30.7
25.6
62
52
Diethylphthalate
ug/L
0.57U
49.5
49
27.4
22.2
55
45
Dimethylphthalate
ug/L
0.75U
49.5
49
25.3
19.6
51
40
Fluoranthene
ug/L
0.21U
49.5
49
28.4
23.5
57
48
Fluorene
ug/L
0.21U
49.5
49
25.7
18.8
52
38
Hexachlorobenzene
ug/L
0.71U
49.5
49
22.3
18.5
45
38
12
Hexachlorocyclopentadiene
ug/L
0.86U
49.5
49
81
5.81
16
Hexachloroethane
ug/L
1.1U
49.5
49
16.2
12.7
33
26
Indeno(1,2,3-cd)pyrene
ug/L
0.281U
49.5
49
30.0
25.7
61
52
31
Isophorone
ug/L
0.87U
49.5
49
19.8
15.0
40
41
32
N-Nitroso-di-n-propylamine
ug/L
0.97U
49.5
49
20.4
15.6
21
N-Nitrosodimethylamine
ug/L
0.89U
49.5
49
13.4
10.5
27
48
N-Nitrosodiphenylamine
ug/L
0.98U
49.5
49
28.6
23.3
58
38
30
Naphthalene
ug/L
0.33U
49.5
49
18.8
14.9
RPD Qual
25
27 J(M1)
25 J(M1)
27 J(M1)
26
22
29 J(M1)
26 J(M1),
J(R1)
23-134 25
29-182 24 J(M1)
1-262 20
1-181 20
53-127 29 J(M1)
22-147 31
25-158 37
1-132
47-145
33-145
27-133
33-143
17-163
24-159
1-219
11-162
33-184
12-158
8-158
1-152
17-168
1-120
4-146
1-227
1-120
1-120
26-137
59-121
1-152
25-150
40-120
1-171
21-196
1-230
25-150
25-150
21-133
Results presented on this page are In the units Indicated by the "Units" column except where an attentate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/30/2020 04:23 PM without the written consent of Pace Analytical Services, LLC.
32 J(M1)
31
18
15
17
16
15
13
26 J(M1)
25
14
13
13
16
15
18
21
25
19
31 J(M1)
19
J(M1)
24 J(M1)
16
28
27
25 J(M1)
20
23
Page 18 of 31

aceAnalXical a
www.pacolaba.com
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite too
Huntersvllle, NC 28078
(704 )87S 9092
Project: PPA 1/16
Pace Project No.: 92461128
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
2785925
2785926
MS
MSD
35524868001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Nitrobenzene
ug/L
1.1U
49.5
49
20.0
15.5
40
32
35-180
25 J(M1)
Pentachlorophenol
ug/L
4.5U
99
98
36.2
29.8
37
30
14-176
19
Phenanthrene
ug/L
0.22U
49.5
49
29.6
24.7
60
50
54-120
18 J(M1)
Phenol
ug/L
1.91.)
49.5
49
6.9
5.1
14
10
5-120
30
Pyrene
ug/L
0.19U
49.5
49
29.6
25.8
60
53
52-120
14
2,4,6-Tribrornophenol (S)
%
52
41
10-137
2-Fluorobiphenyl (S)
%
37
28
15-120
2-Fluorophenol (S)
%
23
17
10-120
Nitrobenzene-d5 (S)
%
43
33
10-120
Phenol-d6 (S)
%
15
11
10-120
Terphenyl-d14 (S)
%
54
49
11-131
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /30/2020 04:23 PM without the written consent of Pace Analytical Services, LLC_
Page 19 of 31

2aceAnalytical'
r' www.pacaiibr.rom
Project: PPA 1116
Pace Project No.: 92461128
QC Batch: 520339
QC Batch Method SM 254OC-2011
Associated Lab Samples: 92461128001
METHOD BLANK: 2784480
f Associated Lab Samples: 92461128001
I
Parameter Units
F
Total Dissolved Solids mg/L
i
{
i
i
LABORATORY CONTROL SAMPLE: 2784481
t
Parameter Units
Total Dissolved Solids mg/L
SAMPLE DUPLICATE: 2784482
Parameter
local Dissolved Solids
SAMPLE DUPLICATE: 2784483
Parameter
Total Dissolved Solids
Pace Analytical Services, LLC
9800 Kincey Ave Suite 100
Huntersville. NC 28078
[phone]
QUALITY CONTROL DATA
Analysis Method: SM 254OC-2011
Analysis Description: 2540C Total Dissolved Solids
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 25.0 01/21/20 00:30
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
250 268 107 90-110
92461139002 Dup
Units Result Result
mg/L 94.0 97.0
92461361001 Dup
Units Result Result
mg/L 65.0 66.0
RPD Qualifiers
3
RPD Qualifiers
2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/30/2020 04:23 PM without the written consent of Pare Analytical Services, LLC. Page 20 of 31

2aceAnalytical"
Pace Analytical Services, LLC
9800 Kincey Ave Sulte 100
Huntersvllle. NC 28078
www.pscoleb:.cam
[phone]
QUALITY CONTROL DATA
Project: PPA 1/16
Pace Project No.: 92461128
QC Batch: 521303
Analysis Method: EPA 350.1 Rev 2.01993
QC Batch Method: EPA 350.1 Rev 2.01993
Analysis Description: 350.1 Ammonia
Associated Lab Samples: 92461128001
METHOD BLANK: 2789012
Matrix: Water
Associated Lab Samples: 92461128001
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Nitrogen, Ammonia mg/L
ND 0.10 01/25/20 18:50
LABORATORY CONTROL SAMPLE: 2789013
Spike 1-CS LCS % Rec
Parameter Units
Cone. Result % Rec Limits
Qualifiers
Nitrogen, Ammonia mg/L
5 4.9 98 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2789014 2789015
MS MSD
92461042001
Spike Spike MS MSD MS
MSD
% Rec
Parameter Units Result
Cone. Cone. Result Result % Rec
% Rec
Limits RPD Qual
Nitrogen, Ammonia mg/L ND
5 5 6.3 6.3 124
124
90-110 0 J(M1)
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2789016 2789017
MS MSD
92461048001
Spike Spike MS MSD MS
MSD
% Rec
Parameter Units Result
Cone. Cone. Result Result % Rec
% Rec
Limits RPD Quai
Nitrogen, Ammonia mg/L 77.7
5 5 83.7 84.3 120
132
90-110 1 M6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 01/30/2020 04:23 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 31

aceAnaoica!x
www.pgcdabt.com
i +
Project: PPA 1116
Pace Project No.: 92461128
QC Batch. 521602
QC Batch Method: EPA 351.2 Rev 2.0 1993
Associated Lab Samples: 92461128001
METHOD BLANK: 2790441
Associated Lab Samples: 92461128001
Parameter Units
Nitrogen, Kjeldahl, Total mg/L
LABORATORY CONTROL SAMPLE: 2790442
Parameter Units
Nitrogen, Kjeldahl, Total mg/L
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersvi Ile, NC 28078
(704 )87 59092
QUALITY CONTROL DATA
Analysis Method: EPA 351.2 Rev 2.0 1993
Analysis Description: 351.2 TKN
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.50 01/29/20 07:33
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
10 9.4 94 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2790443 2790444
MS MSD
92461098001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Kjeldahl, Total mg/L 8.5 10 10 18.8 18.7 103 102 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2790445 2790446
MS MSD
92461105001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Kjeldahl, Total mg/L 1.1 10 10 10.4 10 5 93 94 90 110 1
Results presented on this page are In the units indicated by the "Units' column except where an artemate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 01/30/2020 04:23 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 31

1, ace Analytical
www.pacellbt.com
QUALITY CONTROL DATA
Project: PPA 1116
Pace Project No.: 92461128
QC Batch: 521420 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, preserved
Associated Lab Samples: 92461128001
METHOD BLANK: 2789585 Matrix: Water
Associated Lab Samples: 92461128001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, NO2 plus NO3 mg/L ND 0.040 01/26/20 18:32
Pace Analytical Services, LLC
9800 Kincey Ave Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 2789586
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, NO2 plus NO3 mg/L 2.5 2.4 96 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2789587 2789588
MS MSD
92461058003 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua)
Nitrogen, NO2 plus NO3 mg/L ND 2.5 2.5 2.0 2.0 so 78 90-110 2 J(M1)
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2789589 2789590
MS MSD
92461105001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, NO2 plus NO3 mg/L 2.4 2.5 2.5 4.5 4.5 66 84 90-110 1 J(M1)
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right or the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/30/2020 04:23 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 31

aceAnalytiical
/ www.pacdabs.com
Project: PPA 1/16
Pace Project No.: 92461128
QC Batch: 520152
QC Batch Method: EPA 365.1 Rev 2.0 1993
Associated Lab Samples: 92461128001
METHOD BLANK: 2783548
Associated Lab Samples: 92461128001
Parameter Units
Phosphorus mg/L
LABORATORY CONTROL SAMPLE: 2783549
Parameter Units
Phosphorus mg/L
Pace Analytical Services, LLC
9800 Kincey Ave, Suite 100
Huntersvi Ile, NC 28078
(704)8759092
QUALITY CONTROL DATA
Analysis Method: EPA 365.1 Rev 2.0 1993
Analysis Description: 365.1 Phosphorus, Total
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.050 01/20/2013:48
Spike LCS LCS % Rec
Cone. Result % Rec Limits Qualifiers
2.5 2.4 96 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2783550 2783551
MS MSD
92461056002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPO Qual
Phosphorus mg/L 0.071 2.5 2.5 2.4 2.5 92 96 90-110 3
i
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2783552 2783553
MS MSD
92461058003 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L 0.63 2.5 2.5 3.1 3 0 97 96 90-110 1
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /30/2020 04:23 PM without the written consent of Pace Analytical Services, LLC Page 24 of 31

aceAnalytical
www.pacelsbc.com
Project: PPA 1116
Pace Project No.: 92461128
QC Batch. 520201
QC Batch Method: EPA 420.4 Rev 1.0 1993
Associated Lab Samples: 92461128001
METHOD BLANK: 2783695
Associated Lab Samples: 92461128001
Parameter Units
Phenol mg/L
LABORATORY CONTROL SAMPLE: 2783696
Parameter Units
Phenol mg/L
Pace Analytical Services, LLC
9800 Klncey Ave. Suite 100
Huntersville. NC 28078
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA 420.4 Rev 1.0 1993
Analysis Description: 420.4 Phenolics
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.020 01/20/20 14 52
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
0.05 0.050 100 90-110
MATRIX SPIKE & MATRD( SPIKE DUPLICATE: 2783697 2783698
MS MSD
92460638001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phenol mg/L 0.026 0.05 0.05 0.066 0.063 81 74 90-110 5 J(M1)
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2783699 2783700
MS MSD
92460841001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phenol mg/L 0.042 0.05 0.05 0.089 0.087 94 90 90-110 2
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/30/2020 04:23 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 31

7ace Analytical
/ www.plcollbs.com
+i
t
QUALITY CONTROL DATA
Project: PPA 1/16
Pace Project No.: 92461128
QC Batch: 520165 Analysis Method: SM 4500-CN-E-2011
QC Balch Method: SM 4500-CN-E-2011 Analysis Description: 450OCNE Cyanide, Total
Associated Lab Samples: 92461128001
Pace Analytical Services, LLC
9800 Kincey Ave- Suite 100
Huntersville. NC 28078
[phone]
METHOD BLANK: 2783620
Matrix: Water
Associated Lab Samples: 92461128001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Cyanide
mg/1-
ND 0.0080
0120/20 00:38
LABORATORY CONTROL SAMPLE:
2783621
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Cyanide
mg/L
0.1
0.10
103 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2783622
2783623
MS
MSD
2627910002
Spike
Spike MS
MSD MS MSD % Rec
Parameter
Units Result
Conc.
Conc. Result
Result % Rec % Rec Limits RPD Qual
Cyanide
mg/L 0.023
0.1
0.1 0.099
0.10 76 78 80-120 2 J(M1)
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2783624 2783625
MS MSD
92461262002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Cyanide mg/L ND 0.1 0.1 0.094 0.097 90 92 80-120 2
Results presented an this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 01/30/2020 04:23 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 31

aceAnalyticaI
www.pacol4bt.com
QUALIFIERS
Project: PPA 1/16
Pace Project No.: 92461128
DEFINITIONS
Pace Analytical Services, LLC
9800 Kincey Ave Suite 100
Huntersvllle, NC 28078
(7-04)B75-9092
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited anatytes.
TNI - The NELAC Institute.
LABORATORIES
PAS I -A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services Charlotte
ANALYTE QUALIFIERS
I The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit.
J(M1) Estimated Value. Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LOS)
recovery.
J(P5) Estimated Value. The EPA or method required sample preservation degrades this compound, therefore acceptable
recoveries may not be achieved in sample matrix spikes.
J(RI) Estimated Value. RPD value was outside control limits.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
Date. 01/30/2020 04:23 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, '_LC
Page 27 of 31

i
aceAnalytical
wwrr.psale6c.cam
I
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
PPA 1/16
92461128
Lab ID
Sample ID
92461128001
TARBORO WWTP EFFLUENT
92461128001
TARBORO WWTP EFFLUENT
92461128001
TARBORO WWTP EFFLUENT
92461128002
TARBORO WWTP EFF LLHG
BLANK
92461128001
TARBORO WWTP EFFLUENT
92461128001
TARBORO WWTP EFFLUENT
92461128001
TARBORO WWTP EFFLUENT
92461128001
TARBORO WWTP EFFLUENT
92461128001
TARBORO WWTP EFFLUENT
92461128001
TARBORO WWTP EFFLUENT
92461128001
TARBORO WWTP EFFLUENT
92461128001
TARBORO WWTP EFFLUENT
92461128001
TARBORO WWTP EFFLUENT
92461128001
TARBORO WWTP EFFLUENT
Date: 01/30/2020 04:23 PM
Pace Analytical Services, LLC
9800 Kincey Ave Suite 100
Huntersvi Ile, NO 28078
[phone]
Analytical
QC Batch Method
QC Batch
Analytical Method
Batch
EPA 1664B
521729
EPA 200.7 Rev 4.4 1994
521153
EPA 200.7 Rev 4.4 1994
521 176
EPA 1631E
520497
EPA 1631E
520545
EPA 1631E
520497
EPA 1631E
520545
EPA 625.1
520690
EPA 625.1
521 044
EPA 624.1
520503
SM 254OC-2011
520339
TKN+NO3+NO2
522018
Calculation
EPA 350.1 Rev 2.0 1993
521303
EPA 351.2 Rev 2.0 1993
521602
EPA 351.2 Rev 2.0 1993
521 967
EPA 353.2 Rev 2.0 1993
521420
EPA 365.1 Rev 2.0 1993
520152
EPA 365.1 Rev 2.0 1993
520236
EPA 420.4 Rev 1.0 1993
520201
EPA 420.4 Rev 1.0 1993
520279
SM 4500-CN-E-2011
520165
SM 4500-CN-E-2011
520193
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services. LLC.
Page 28 of 31

-o
am
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0
0
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ID
CL
Cu
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i
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1
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ltcmtt
BP41.1-125 mL Plastic Unpreserved (N/A) (0-)
8P3tt-250 mL Plastc Unprwerved (N/A)
BP21Y500 mL Plastic Unpresenred (N/A)
BP11,11-111ter Plastic Unpreserved (N/A)
N
BP45-125 mL Plastc H2SO4 (pH < 2) (Cl-)
11-7
BP3N-250 mL plastic HNO3 (pH <2)
5P4Z-125 mL Plastic ZN Acetate & NPOH (>9)
BP4C-125 mL Plastic NaOH (pH > 12) (Cl-)
WGFU-WWe-mouthedGlassfar Unpreserved
�j
AGSU-111ter Amber Unpreserved 4N/A) (CI-)
AGIH-1 Ilte r Amber HO (pH < 2 )
AG3U-250 mLAmber Unpreserved (N/A) (CF)
AGIS-Utter Amber H25O4 (pH <2)
AG35-250 mL Amber HZSO4 (pH < 2)
AG3A(OG3A)-250 mL Amber NH40 (N/A)(CI-)
DG914-40 mL VOA HCl (N/A)
_
_ -
VG9T-40 mL VOA Na25203 (N/A)
W
VGW-40 mt. VOA Unp (N/A)
DG9P-40 mL VOA H3PO4 (N/A)
VOAK 16 v1.1. per kh)-5035 Mt (N/A)
V/GK (3 A.1% per kk)-V PH/G&; kit (N/A)
SPST-125 mL Storlie Piasuc (N/A -lab)
SPZT-250 ml Sterile Plastic (N/A- lab)
BP3A-250 mL PUMIC (NH2)25O4 (9.3-9.7)
A43OU-100 ml-Amber Unpreserved vials (N/A)
VSGU.20 mL Sdntlilatlon vials (N/A)
DO91J-40 mL Amber Unpreserved vials IN/A)
41k
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Page 31 of 31

2 C>2A
aceAnalytical
www.pacelabs.com
April 27, 2021
Mr. Mike Allen
Town of Tarboro
506 Dowd Street
PO Box 220
Tarboro, NC 27886
RE: Project: PPA 4/13
Pace Project No.: 92532949
Dear Mr. Allen:
Pace Analytical Services. LLC
'E001G— Axe Se,=,e -Gz
Hunter`vik_ NC 2K78
(704 )575-9092
Enclosed are the analytical results for sample(s) received by the laboratory on April 13, 2021. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network.
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me
Sincerely,
Chris Derouen
[e-mail]
[phone]
Project Manager
Enclosures
P
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced except in full
without the written consent of Pace Analytical Services, LLC.
Page 1 of 31

i /Jyrr�
i lace
Analyt.121
rrr-ix'erala-con
Project. PPA 4/13
Pace Project No.: 92532949
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville. NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive. Asheville, NC 28804
Flonda/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
VirginiaNELAP Certification #: 460221
North Carolina Wastewater Certification #. 40
South Carolina Certification #: 99030001
VrginiaNELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services. LLC
Pace Analytical Services, LLC
9800 KinceyAve Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 31

1��alceAnalytical
www.pacelabs.com
Project: PPA 4/13
Pace Project No.: 92532949
Lab ID Sample ID
92532949001 TARBORO WWTP EFFLUENT
92532949002 TARBORO WWTP LLHG BLANK
-A = Pace Analytical Services - Asheville
-C = Pace Analytical Services - Charlotte
SAMPLE ANALYTE COUNT
Method Analysts
EPA 1664E
CJM
EPA 200.7 Rev 4.4 1994
RDT
EPA 1631E
KRL
EPA 625.1
PKS
EPA 624.1
BSH
SM 254OC-2011
ZMC
TKN+NO3+NO2 Calculation
EWS
EPA 350.1 Rev 2.0 1993
NAL
EPA 351.2 Rev 2.0 1993
MFO
EPA 353.2 Rev 2.0 1993
NGP
EPA 365.1 Rev 2.0 1993
MDW
EPA 420.4 Rev 1.0 1993
KDF 1
SM 4500-CN-E-2011
CJL
EPA 1631 E
KRL
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced. except in full
without the written consent of Pace Analytical Services, LLC
Pace Analytical Services, LLC
96PJ Kmoey Ave Sure ':)c
Huntersville NC 26G76
(7 04)875-C-092
A natytes
Reported Laboratory
1
PASI-C
15
PASI-A
1
PASI-A
59
PASI-C
39
PASI-C
1
PASI-A
i
PAS I -A
1
PASI-A
1
PASI-A
1
PAS I -A
1
PASI-A
1
PASI-A
1
PASI-A
1
PASI-A
Page 3 of 31

laceA aVical
ww�r pxd�bsron
I
i
Project: PPA 41l 3
Pace Project No : 92532949
i Sample: TARBORO WWTP
C EFFLUENT
jParameters
HEM, oil and Grease
Oil and Grease
200.7 MET ICP
Antimony
Arsenic
Beryllium
Cadmium
Calcium
Chromium
Copper
Lead
Magnesium
Nickel
Selenium
Silver
Thallium
Hardness. Total(SM 23408)
Zinc
1631E Mercury,Low Level
Mercury
625 RVE
Acenaphthene
Acenaphthylene
Anthracene
Be nzo(a)a nth race ne
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
4-Bromophenylphenyl ether
Butytbenzylphthalate
4-Chloro-3-methylphe nol
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
2-Chloronaphthalene
2-Chlorophenol
4-Chlorophenylphenyl ether
Chrysene
Dibenz(a,h)anthracene
1.2-Dichlorobenzene
Pace Analytical Services', LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
ANALYTICAL RESULTS
Lab ID: 92532949001 Collected: 04/13/21 09:00 Received: 04/13/21 13:45 Matrix: Water
Results Units Report Limit OF Prepared Analyzed CAS No. Qual
Analytical Method: EPA 1664E
Pace Analytical Services - Charlotte
NO mg/L 5.0 1 04/23/2111:34
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services -Asheville
NO
ug/L
5.0
1
04/22/21 01:33
04/25/21 16:44
7440-36-0
NO
ug/L
10.0
1
04/22/21 01:33
04125/2116:44
7440-38-2
NO
ug1L
1.0
1
04/22/2101:33
04125/2116:44
7440-41-7
NO
ug/L
1.0
1
04122/2101:33
04/25/21 16:44
7440-43-9
7690
ug/L
100
1
04/22/21 01:33
04/25/21 16:44
7440-70-2
NO
ug/L
5.0
1
04/22/21 01:33
04/25/21 16:44
7440-47-3
10.5
ug/L
5.0
1
04/22/21 01:33
04/25/21 16:44
7440-50-8
NO
ug/L
5.0
1
04122/2101:33
04/25/21 16:44
7439-92-1
2250
ug/L
100
1
04/22/21 01:33
04125M 16:44
7439-95-4
NO
ug/L
5.0
1
04/22/21 01:33
04125/2116:44
7440-02-0
NO
ug/L
10.0
1
04/22/21 01:33
04/2512116:44
7782-49-2
NO
ug/L
5.0
1
04/22/21 01:33
04/25/21 16:44
7440-22-4
NO
ug/L
10.0
1
04/22/21 01:33
04/25/21 16:44
7440-28-0
28500
ug/L
662
1
04/22/21 01:33
04/25/21 16:44
14.2
ug/L
10.0
1
04/22/21 01:33
04/25/21 16:44
7440-66-6
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical Services - Asheville
4.08 ng/L 0.50 1 04/16/21 11:05 04/20/21 19:14 7439-97-6
Analytical Method: EPA625 1 Preparation Method: EPA625.1
Pace Analytical
Services - Charlotte
NO
ug/L
5.0
1
04/20/21 07:23
04/20/21 13:17
83-32-9
NO
ug/L
5.0
1
04/20/21 07:23
04/20/21 13:17
208-96-8
NO
ug/L
5.0
1
0412012107:23
04/20/21 13:17
120-12-7
NO
ug/L
5.0
1
04/20/21 07:23
04/20/21 13:17
56-55-3
NO
ug/L
5.0
1
04/20/21 07:23
04/20/21 13:17
50-32-8
ND
ug/L
5.0
1
04/20/21 07:23
04/20/21 13:17
205-99-2
ND
ug/L
5.0
1
04/20/21 07:23
04/20/21 13:17
191-24-2
ND
ug/L
5.0
1
04120/2107:23
04/20/21 13:17
207-08-9
NO
ug/L
5.0
1
04/20/21 07:23
04/20/21 13:17
101-55-3
ND
ug/L
5.0
1
04/20/21 07:23
04120/2113:17
85-68-7
NO
ug/L
5.0
1
04/20/21 07:23
04/20/21 13:17
59-50-7
NO
ug/L
10.0
1
04/20/2107:23
04/20/21 13:17
111-91-1
ND
ug/L
5.0
1
04120/2107:23
04/20/21 13:17
111-44-4
ND
ug/L
5.0
1
04/20/21 07:23
04/20/21 13:17
91-58-7
ND
ug/L
5.0
1
04/20/21 07:23
04/20/21 13:17
95-57-8
ND
ug/L
5.0
1
04/2012107:23
04/2012113:17
7005-72-3
ND
ug/L
5.0
1
04/20/21 07:23
04/20/21 13:17
218-01-9
ND
ug/L
5.0
1
04/20/21 07:23
04/20/21 13:17
53-70-3
NO
ug/L
5.0
1
04/20/21 07:23
04/20/21 13:17
95-50-1
REPORT OF LABORATORY ANALYSIS
This_ report shall not be reproduced, except in full,
Date: 04/272021 04 55 PM without the wntten consent of Pace Analytical Services. LLC Page 4 of 31

Pace Analytical Services, LLC
aceAnal ica! `&00 Kr�y Ave SL_ie , :,.
www.pacelahs.com
.Y Huntersville NC 28C76
(7O4)875-9092
ANALYTICAL RESULTS
Project: PPA 4/13
Pace Project No. 92532949
Sample: TARBORO WWTP Lab ID: 92532949001 Collected: 04/13/21 09,00 Received: 0411321 13:45 Matrix: Water
EFFLUENT
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
625 RVE
Analytical Method: EPA 625 1 Preparation Method: EPA 625.1
Pace Analytical
Services - Charlotte
1,3-Dichlorobenzene
ND
ug1L
5.0
1
0420/2107:23
04202113:17
541-73-1
1,4-Dichlorobenzene
NO
ug/L
5.0
1
04/202107:23
04202113:17
106-46-7
3,3'-Dichlorobenzidine
ND
ug/L
10.0
1
0420M 07 23
042021 13:17
91-94-1
2,4-Dichlorophenol
ND
ug/L
5.0
1
04/20/21 07:23
042021 13:17
120-83-2
Diethylphtha late
ND
ug/L
5.0
1
04202107:23
042021 13:17
84-66-2
2,4-Dimethylphenol
ND
ug/L
10.0
1
04/202107:23
042021 13:17
105-67-9
t Dimethylphtha late
NO
ug/L
5.0
1
D4202107:23
042021 13:17
131-11-3
Di-n-butylphthalate
NO
ug/L
5.0
1
W202107:23
04/2021 13:17
84-74-2
4,6-Dinitro-2-methylphenol
NO
ug/L
10.0
1
0412021 07:23
04/2021 13:17
534-52-1
2,4-Dinitrophenol
ND
ug/L
50.0
1
04/2021 07:23
04/2021 13:17
51-28-5
2,4-Dinitrotoluene
ND
ug/L
5.0
1
04/202107:23
04/202113:17
121-14-2
2,6-Dinitrotoluene
ND
ug/L
5.0
1
04202107:23
04202113:17
606-20-2
Di-n-octylphthalate
ND
ug/L
50
1
0412021 07:23
042021 13:17
117-84-0
1,2-Diphenylhydrazine
ND
ug/L
5,0
1
04/202107:23
042021 13:17
122.66-7
bis(2-Ethylhexyl)phthalate
ND
ug/L
5 0
1
0412021 07:23
042021 13:17
117-81-7
anthene
ND
ug/L
5 0
1
04/2021 07:23
042021 13:17
206- 4-0
ene
ND
ug/L
5.0
1
04202107:23
04202113:17
86-73-7
Hexachlorobenzene
ND
ug/L
5.0
1
04/202107:23
04/20/21 13:17
118-74-1
Hexachtorocyclopentadiene
ND
ug/L
10.0
1
04/2021 07:23
042021 13:17
77-47-4
I Hexachloroethane
ND
ug/L
5.0
1
04/202107:23
04202113:17
67-72-1
1ndeno(1,2,3-cd)pyrene
ND
ug/L
5.0
1
04202107:23
04/202113:17
193-39-5
Isophorone
ND
ug/L
10.0
1
04/20/21 07:23
0412021 13:17
78-59-1
Naphthalene
NO
ug/L
5.0
1
041202107:23
04/2012113:17
91-20-3
Nitrobenzene
ND
ug/L
5.0
1
04/20121 07:23
04/2021 13:17
98-95-3
2-Nitrophenol
ND
ug/L
5.0
1
041202107:23
041202113:17
88-75-5
4-Nitrophenol
ND
ug/L
10.0
1
04/20/21 07:23
04/20/21 13:17
100-02-7
N-Nitrosodimethylamine
NO
ug/L
5.0
1
04/202107:23
041202113:17
62-75-9
N-Nitroso-di-n-propylamine
ND
ug/L
5.0
1
04/20/21 07:23
04202113:17
621-64-7
N-Nitrosodiphenylamine
ND
ug/L
10.0
1
04/20/21 07:23
041202113:17
W30-6
Pentachlorophenol
ND
ug/L
10.0
1
04/20/21 07:23
04202113:17
87-W5
Phenanthrene
ND
ug/L
5.0
1
04202107:23
04202113:17
85-01-8
Phenol
ND
ug/L
5.0
1
04/2021 07:23
041202113:17
108-95-2
Pyrene
ND
ug/L
5.0
1
0412021 07:23
04202113:17
129-00-0
2,4,6-Trichlorophenol
ND
ug/L
10.0
1
04/2021 07:23
042021 13:17
88-W2
Surrogates
Nitrobenzene-d5 (S)
75
%
10-120
1
04/20/21 07:23
04/20/21 13:17
4165-60-0
2-Fluorobiphenyl (S)
63
%
15-120
1
04/2021 07:23
04/20/21 13:17
321-60-8
Terphenyl-d14 (S)
75
%
11-131
1
04/20/21 07.23
04/20/21 13:17
1718-51-0
Phenol-d6 (S)
46
%
10-120
1
04/20/21 07:23
04/20/21 13:17
13127-88-3
2-Fluorophenol (S)
63
%
10-120
1
04/20/21 07:23
04/20/21 13:17
367-12-4
2,4,6-Tribromophenol (S)
105
%
10-137
1
04/20/21 07:23
04/20/21 13:17
118-79-6
624 Volatile Organics
Analytical Method: EPA624.1
Pace Analytical
Services - Charlotte
- Mein
NO
ug/L
5.0
1
04/15/21 19:32
107-02-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced. except in tun
Date: 04/27/2021 04.55 PM without the written consent of Pace Ana"cal Services. LLC. Page 5 of 31

aceAnalyticals
vrr_pcNalstm
Project: PPA 4/13
Pace Project No.: 92532949
Sample: TARBORO WWTP
EFFLUENT
Parameters
624 Volatile Organics
Acrylonitrile
Benzene
B romod ich lorometh a n e
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethylvinyl ether
Chloroform
Chloromethane
Dibromochloromethane
1.2-Dichiorobenzene
1,3-Dichlorobenzene
1 4-Dichlorobenzene
1. 1 -Dichloroethane
1.2-Dichloroethane
1. 1 -Dichloroethene
trans-12-Dichloroethene
1.2-Dichloropropane
cis-1,3-Dichloropropene
trans-1.3-Oichloropropene
Ethylbenzene
Hexachloro-1,3-butadiene
Methylene Chloride
Naphthalene
1,1.2, 2-Tetrachloroethane
Tetrachloroethene
Toluene
1.2.4-Trichlorobe nze ne
1.1 1-Trichloroethane
1.1.2-Trichloroethane
Tnchloroethene
Tnch to rofluoro meths ne
Vinyl chloride
Surrogates
4-Bromofluorobenzene (S)
Toluene-d8 (S)
1.2-Dichloroethane-d4 (S)
2540C Total Dissolved Solids
Total Dissolved Solids
Date 04/27/2021 04:55 PM
Pace Analytical Services:LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Lab ID: 92532949001 Collected 04/13/21 09:00 Received: 04113/21 13:45 Matrix: Water
Results Units
Report Limit OF Prepared Analyzed CAS No. Qual
Analytical Method: EPA 624.1
Pace Analytical
Services - Charlotte
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
NO
ugtL
ND
ug/L
ND
ug/L
NO
ug/L
ND
ug/L
2.2
ug/L
ND
ug/L
ND
ug/L
NO
ug/L
ND
ug/L
NO
ug/L
NO
ug/L
NO
ug/L
NO
ug/L
ND
ug/L
ND
ug/L
NO
ug/L
NO
ug/L
NO
ug/L
NO
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
NO
ug/L
NO
ug/L
ND
ug/L
NO
ug/L
NO
ug/L
NO
ug/L
ND
ug/L
ND
ug/L
102 %
96 ova
93 %
Analytical Method: SM 254OC-2011
Pace Analytical Services -Asheville
210 mg/L
5.0
1
04/15/21 19:32
107-13-1
1.0
1
04/15/2119:32
71-43-2
2.0
1
04/15/21 19:32
75-27-4
2.0
1
04/15/21 19:32
75-25-2
2.0
1
04A 5/21 19:32
74-83-9
2.0
1
04/15/21 19:32
56-23-5
2.0
1
04/15/21 19:32
108-90-7
2.0
1
04/15/21 19:32
75-00-3
5.0
1
04/15M 19:32
110-75-8
2.0
1
04/15/21 19:32
67-66-3
2.0
1
04/15/21 19:32
74-87-3
2.0
1
04/15/21 19:32
124-48-1
2.0
1
04/15/21 19:32
95-50-1
2.0
1
04/15/21 19:32
541-73-1
2.0
1
04/15/21 19:32
106-46-7
2.0
1
04/15/21 19:32
75-34-3
2.0
1
04/15/21 19:32
107-06-2
2.0
1
04/15/21 19:32
75-35-4
2.0
1
04/15/21 19:32
156-60-5
2.0
1
04/15/21 19:32
78-87-5
2.0
1
04/15/21 19:32
10061-01-5
2.0
1
04/15/21 19:32
10061-02-6
1.0
1
04/15/21 19:32
100-41-4
5.0
1
04/15/21 19:32
87-68-3
2.0
1
04/15/21 19:32
75-09-2
5.0
1
04/15/21 19:32
91-20-3
2.0
1
04115M 19:32
79-34-5
2.0
1
04/15/21 19:32
127-18-4
1.0
1
04/15/21 19:32
108-85-3
2.0
1
04/15/21 19:32
120-82-1
2.0
1
04/15/21 19:32
71-55-6
2,0
1
04/15/21 19:32
79-00-5
2.0
1
04/15/21 19:32
79-01-6
2.0
1
04/15M 19:32
75-69-4
2.0
1
04/15/21 19:32
75-01-4
70-130
1
04/15/21 19:32
460-00-4
70-130
1
04/15/21 19:32
2037-26-5
70-130
1
04/15/21 19:32
17060-07-0
25.0
1
04/17/21 16:51
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analyucal Services, LLC
J(HS)
Page 6 of 31

Pace Analyticzl Services, LLC
aceAnalytical 98,X Kmcey Awe Sucze
Hurter,_oie NC 2E0 E
www.pacelabs.com
Lu)E i 5-8052
ANALYTICAL RESULTS
Project: PPA 4/13
Pace Project No.: 92532949
Sample: TARBORO WWTP
Lab ID: 92532949001 Collected: 04/13/21 09:00 Received 0411321 13:45 Matrix: Water
EFFLUENT
Parameters
Results Units Report Limit DF Prepared Analyzed CAS No Qua]
Total Nitrogen Calculation
Analytical Method. TKN+NO3+NO2 Calculation
Pace Analytical Services - Asheville
Total Nitrogen
9.5 mg/L 0 52 1 04/26/21 14:21
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L 0.10 1 04/2521 15:33 7664-41-7
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 3512 Rev 2 0 1993
Pace Analytical Services - Asheville
Nitrogen, Kjeldahl, Total
1.0 mg/L 0.50 1 04/2321 17A9 04/2421 04 49 7727-37 9
353.2 Nitrogen, NO2/NO3 pres.
Analytical Method: EPA 3532 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, NO2 plus NO3
8.5 mg/L 0.12 3 04,120121 13.48
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method EPA 365.1 Rev 2.0 1993
Pace Analytical Services - Asheville
rtivaphorus
0.40 mg/L 0.050 1 0412021 18:00 04/20/21 23 05 7723-14-0
420.4 Phenolics, Total
Analytical Method: EPA420.4 Rev 1.0 1993 Preparation Method: EPA420.4 Rev 1.0 1993
Pace Analytical Services - Asheville
Phenolics, Total Recoverable
ND mg/L 0.020 1 G4/26r21 08:55 042621 15:22 64743-03-9
450OCNE Cyanide, Total
Analytical Method: SM 4500-CN-E-2011 Preparation Method SM 4500-CN-E-2011
Pace Analytical Services Asheville
Cyanide
ND mg/L 00080 1 04/1921 23:20 042021 20:40 57-12-5
Sample: IAKt5UKU VVVV It' LLMU
BLANK
Parameters
1631E Mercury,Low Level
Mercury
Date: 04/27/2021 04:55 PM
Lab ID: 92532949002 Collected: 04/13/21 09:00 Received: 04/13/21 13:45 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Analytical Method: EPA 1631E Preparation Method: EPA 1631E
Pace Analytical Services - Asheville
ND ng/L 0.50 1 04/16/21 11:05 04/202117:11 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced except in tutl
without the written consent of Pace Anarca! Services, LLG
Page 7 of 31

1- aceAna&tical'
w"-pacdatrsrore
Project: PPA 4/13
Pace Project No.: 92532949
QC Batch: 615662
OC Batch Method. EPA 1664B
Associated Lab Samples: 92532949001
METHOD BLANK: 3239981
Associated Lab Samples: 92532949001
Parameter
Units
Oil and Grease
mg/L
LABORATORY CONTROL SAMPLE:
3239982
Parameter
Units
Oil and Grease
mg/L
MATRIX SPIKE SAMPLE.
3239983
Parameter
Units
Oil and Grease
mg/L
QUALITY CONTROL DATA
Analysis Method: EPA 1664B
Analysis Description: 1664 HEM, Oil and Grease
Laboratory: Pace Analytical Services - Charlotte
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 5.0 04/23/21 11:34
Spike LCS LCS
Conc. Result % Rec
40 33.8 84
35626481001 Spike MS
Result Conc. Result
1.61 4C 31.4
Pace Analytical Serviceq,'LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
% Rec
Limits Qualifiers
78-114
MS % Rec
Rec Limits Qualifiers
74 78-114 J(M1)
Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 0427/2021 04:55 PM without the written consent of Pace Analytical Services, LLC Page 8 of 31

�IaceAnai(Xical
Pace Anatytical Services, LLC
9500 KnceyAve Sutte
www.pacelabs.cam Huntersville NC 26 -+5
(704)875-8o82
QUALITY CONTROL DATA
Project: PPA4/13
Pace Project No.: 92532949
QC Batch: 614244 Analysis Method: EPA 1631 E
QC Batch Method: EPA 1631E Analysis Description: 1631E Mercury.Low Level
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92532949001, 92532949002
METHOD BLANK: 3232754 Matrix: Water
Associated Lab Samples: 92532949001. 92532949002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 04/20/2116:10
METHOD BLANK. 3232755 Matrix: Water
Associated Lab Samples: 92532949001, 92532949002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 041202117:34
"nc'rHOD BLANK: 3232756
ciated Lab Samples: 92532949001, 92532949002
Parameter Units
Mercury ng/L
LABORATORY CONTROL SAMPLE 3232757
Parameter Units
Mercury ng/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.50 04/2021 20:41
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
5 5.29 106 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3232758 3232759
MS MSD
92532836004 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Mercury ng/L 1.13 25 25 26 4 26.9 101 103 71-125 2
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3232760 3232761
MS MSD
92532949001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Mercury ng/L 4.08 25 25 32.5 32.8 114 115 71-125 1
Results presented on this page are In the units indicated by the "Units- column except where an attemate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced. except in full
Date: 04/27/2021 04:55 PM without the written consent of Pace Anatytical Services. LLC
Page 9 of 31

I� ,r
>GaceAnalytical
r+r+r �scM�as roc
Project: PPA4113
Pace Project No.: 92532949
QC Batch: 615369
QC Batch Method: EPA 200.7 Rev 4.4 1994
Associated Lab Samples: 92532949001
METHOD BLANK: 3238506
Associated Lab Samples: 92532949001
I Parameter
Units
Antimony
ug/L
Arsenic
ug/L
Beryllium
ug/L
Cadmium
ug/L
Calcium
ug/L
Chromium
ug/L
Copper
ug/L
Hardness, Total(SM 2340B)
ug/L
Lead
ug/L
Magnesium
ug/L
Nickel
ug/L
Selenium
ug/L
'>ilver
ug/L
thallium
ug/L
Zinc
ug/L
QUALITY CONTROL DATA
Analysis Method: EPA 200.7 Rev 4.4 1994
Analysis Description. 200.7 MET
LaboratoryPace Analytical Services -Asheville
Matrix: Water
Blank
Reporting
Result
Limit
Analyzed
ND
5.0
04/25/21 16:32
NO
10.0
04/25/21 16:32
NO
1.0
04/25/21 16:32
NO
1.0
04/25/21 16:32
ND
100
04/25/21 16:32
NO
5.0
04/25/21 16:32
NO
5.0
04/25/21 16:32
NO
662
04125/2116:32
NO
5.0
04/25/21 16:32
NO
100
04/25/21 16:32
NO
5.0
04/25/21 16:32
ND
10.0
04/25/21 16:32
NO
5.0
04/25/2116.32
ND
10.0
04/25/21 16:32
ND
10.0
04/25/21 16:32
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
3238507
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
500
522
104
85-115
Arsenic
ug/L
500
489
98
85-115
Beryllium
ug/L
500
527
105
85-115
Cadmium
ug/L
500
507
101
85-115
Calcium
ug/L
5000
5020
100
85-115
Chromium
ug/L
500
517
103
85-115
Copper
ug/L
500
549
110
85-115
Hardness. Total(SM 23408)
ug/L
33100
34000
103
85-115
Lead
ug/L
500
512
102
85-115
Magnesium
ug/L
5000
5210
104
85-115
Nickel
ug/L
500
498
100
85-115
Selenium
ug/L
500
525
105
85-115
Silver
ug/L
250
251
100
85-115
Thal! um
uo/L
500
495
99
85-115
Zinc
ug/L
500
505
101
85-115
Pace Analytical Services, LLC
9800 KinceyAve Suite too
Huntersville, NC 28078
[phone]
Qualifiers
Results presented on this page are in the units indcated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced. except in full,
Date 04/27/2021 04:55 PM without the written consent of Pace Analytical Services. LLC
Page 10 of 31

1'!�aceAnal ical r:
www.pacelabs.com
QUALITY CONTROL DATA
Project PPA 4113
Pace Project No-. 92532949
Pace Anatytic..al Se"ces. LLC
5800 K7>cef Ave & se " ti
Hurtersville NC 2K7E
(704)8759092
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3238508
3238509
MS
MSD
92532949001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc
Conc
Result
Result
% Rec
% Rec
Limits
RPD Qua[
Antimony
ug/L
NO
500
500
513
520
103
104
70-130
1
Arsenic
ug/L
NO
500
500
486
494
97
99
70-130
2
Beryllium
ug/L
ND
500
500
495
512
99
102
70-130
3
Cadmium
ug/L
ND
500
500
500
508
100
102
70-130
2
Calcium
ug/L
7690
5000
5000
12400
12800
93
103
70-130
4
Chromium
ug/L
NO
500
500
501
504
100
101
70-130
1
Copper
ug/L
10.5
500
500
547
544
107
107
70-130
1
Hardness, Total(SM 2340B)
ug/L
28500
33100
33100
61400
62900
99
104
70-130
3
Lead
ug/L
NO
500
500
488
493
97
98
70-130
1
Magnesium
ug/L
2250
5000
5000
7420
7500
103
105
70-130
1
Nickel
ug/L
NO
500
500
480
491
96
98
70-130
2
Selenium
ug/L
NO
500
500
539
541
108
108
70-130
0
Silver
ug/L
NO
250
250
248
254
99
101
70-130
2
Thallium
ug/L
NO
500
500
457
468
91
94
70-130
2
Zinc
ug/L
14.2
500
500
516
518
100
101
70-130
0
tIX SPIKE & MATRIX SPIKE DUPLICATE:
3238510
MS
92533677001
Spike
Parameter
Units
Result
Conc.
Antimony
ug/L
ND
500
Arsenic
ug/L
NO
500
Beryllium
ug/L
NO
500
Cadmium
ug/L
NO
500
Calcium
ug/L
23800
5000
Chromium
ug/L
ND
500
Copper
ug/L
ND
500
Hardness, Total(SM 2340B)
ug/L
74800
33100
Lead
ug/L
NO
500
Magnesium
ug/L
3710
5000
Nickel
ug/L
ND
500
Selenium
ug/L
ND
500
Silver
ug/L
NO
250
Thallium
ug/L
NO
500
Zinc
ug/L
128
500
3238511
MSD
Spike
MS
MSD
MS
MSD
% Rec
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
500
484
504
96
100
70-130
4
500
478
490
92
94
70-130
2
500
502
501
100
100
70-130
0
500
488
498
97
99
70-130
2
5000
28900
28600
101
95
70-130
1
500
484
484
97
97
70-130
0
500
516
514
99
99
70-130
0
33100
108000
107000
100
98
70-130
1
500
475
478
95
96
70-130
1
5000
8720
8700
100
100
70-130
0
500
481
487
95
96
70-130
1
500
514
505
102
100
70-130
2
250
200
204
80
82
70-130
2
500
405
442
81
88
70-130
9
500
606
596
95
94
70-130
2
Results presented on this page are in the units indicated by the "Units" column except where an attemate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced except n full
Date: 04/27/2021 04.55 PM without the written consent o1 Pace Ana4lical Services. LLC
Qual
Page 11 of 31

�IaceAnaVicaI
trtnr_pacNalsmm
QUALITY CONTROL DATA
Project: PPA 4113
Pace Project No.: 92532949
QC Batch: 613629
QC Batch Method: EPA 624.1
Associated Lab Samples: 92532949001
Analysis Method:
Analysis Description:
Laboratory:
EPA 624.1
624 MSV
Pace Analytical Services - Charlotte
METHOD BLANK: 3229486
Matrix. Water
Associated Lab Samples: 92532949001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
1,1,1-Trichloroethane
ug/L
ND
2.0
04/15/21 11:28
1.1,2,2-Tetrachloroethane
ug/L
ND
2.0
04/1512111:28
1.1.2-Trichloroethane
ug/L
NO
2.0
04/1512111:28
1. 1 -Dichloroethane
ug/L
ND
2.0
04/15/21 11:28
1-1-Dichloroethene
ug/L
NO
2.0
04/15/21 11:28
1.2.4-Trichlorobenzene
ug/L
NO
2.0
04/1512111:28
1.2-Dichlorobenzene
ug/L
ND
2.0
04/15/21 11:28
1.2-Dichloroethane
ug/L
NO
2.0
04/15/21 11:28
1.2-Dichloropropane
ug/L
NO
2.0
04/15/21 11:28
1.3-Dichlorobenzene
ug/L
ND
2.0
04/15/21 11:28
1,4-Dichlorobenzene
ug/L
ND
2.0
04/15/21 11:28
--Chloroethylvinyl ether
ug/L
ND
5.0
04/1521 11:28
,crolein
ug/L
ND
5.0
04/15/21 11:28
r,crylonitrile
ug/L
ND
5.0
04/15/21 11:28
Benzene
ug/L
ND
1.0
04/15/21 11:28
Bromodichloromethane
ug/L
ND
2.0
04/15/21 11:28
Bromoform
ug/L
ND
2.0
041152111:28
Bromomethane
ug/L
NO
2.0
041152111:28
Carbon tetrachloride
ug/L
ND
2.0
04/15/21 11:28
Chlorobenzene
ug/L
NO
2.0
04/15/21 11:28
Chloroethane
ug/L
NO
2.0
041152111:28
Chloroform
ug/L
NO
2.0
041152111:28
Chloromethane
ug/L
ND
2.0
04/15/21 11:28
cis- 1.3-Dich loropropene
ug/L
ND
2.0
041152111:28
Dibromochloromethane
ug/L
ND
2.0
04/15/21 11:28
Ethylbenzene
ug/L
NO
1.0
04/15/21 11:28
Hexachloro-1 ,3-butadiene
ug/L
ND
5.0
04/15/21 11:28
Methylene Chloride
ug/L
NO
2.0
04/1521 11:28
Naphthalene
ug/L
ND
5.0
04/152111:28
Tetrachloroethene
ug/L
ND
2.0
04/15/21 11:28
Toluene
ug/L
ND
1.0
04/15/21 11:28
trans-1,2-Dichloroethene
ug/L
ND
2.0
04/15/21 11:28
trans- 1,3-Dichloropropene
ug/L
ND
2.0
04/15/21 11:28
Trichloroethene
ug/L
NO
2.0
04/15/21 11:28
Trichlorofluoromethane
ug/L
NO
2.0
04/15/21 11:28
Vinyl chloride
ug/L
ND
2.0
04/15/21 11:28
1.2-Dichloroethane-d4 (S)
%
93
70-130
0411521 11:28
4-Bromofluorobenzene (S)
%
100
70-130
04/1521 11:28
Toluene-d8 (Si
%
93
70-130
04/1521 11:28
Pace Analytical Services., LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shalt not be reproduced, except in full,
Date 04Y772021 04.55 PM without the written consent of Pace Analytical Services. LLC
Page 12 of 31

/ acekal ical '
www.pacelabs.com
QUALITY CONTROL DATA
Project: PPA 4113
Pace Project No.: 92532949
Pace Analytical Services- LLC
6600Kirx:Ey Av,e Sure '
Hunlersville NC 26E 7 9
(/04)875-CC-02
LABORATORY CONTROL SAMPLE.
Parameter
3229487
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1. 1, 1-Trichloroethane
ug/L
20
20.4
102
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
20.1
100
70-130
1,1,2-Trichloroethane
ug/L
20
19.8
99
70-130
1,1-Dichloroethane
ug/L
20
16.6
83
70-130
1,1-Dichloroethene
ug/L
20
17.7
89
70-132
1,2,4-Trichlorobenzene
ug/L
20
21.5
107
70-130
1,2-Dichlorobenzene
ug/L
20
20.8
104
70-130
1,2-Dichloroethane
ug/L
20
17.7
88
70-130
1,2-Dichloropropane
ug/L
20
18.4
92
70-130
1,3-Dichlorobenzene
ug/L
20
20.8
104
70-130
1,4-Dichlorobenzene
ug/L
20
20.1
101
70-130
2-Chloroethylvinyl ether
ug/L
40
35.6
89
67-130
Acrolein
ug/L
100
84.7
85
60-140
Acrylonitrile
ug/L
100
72.5
73
70-130
Benzene
ug/L
20
20.2
101
70-130
Bromodichloromethane
ug/L
20
19.0
95
70-130
Bromoform
ug/L
20
21.1
106
70-130
Bromomethane
ug/L
20
19.6
98
30-177
)n tetrachloride
ug/L
20
20.8
104
70-130
obenzene
ug/L
20
22.7
113
70-130
Chloroethane
ug/L
20
203
101
46-131
Chloroform
ug/L
20
20.3
101
70-130
Chloromethane
ug/L
20
16.5
82
49-130
cis-1,3-Dichloropropene
ug/L
20
20.5
102
70-130
Dibromochloromethane
ug/L
20
206
103
70-130
Ethylbenzene
ug/L
20
19.9
100
70-130
Hexachloro-1,3-butadiene
ug/L
20
20A
102
70-131
Methylene Chloride
ug/L
20
14.5
72
68-130
Naphthalene
ug/L
20
20.8
104
70-133
Tetrachloroethene
ug/L
20
221
110
70-130
Toluene
ug/L
20
20.2
101
70-130
trans-1,2-Dichloroethene
ug/L
20
15.5
77
70-130
trans-1,3-Dichloropropene
ug/L
20
21.4
107
70-130
Trichloroethene
ug/L
20
20.5
103
70-130
Trichlorofluoromethane
ug/L
20
23.5
118
61-130
Vinyl chloride
ug/L
20
190
95
59-142
1 ,2-Dichloroethane-d4 (S)
%
92
70-130
4-Bromofluorobenzene (S)
%
97
70-130
Toluene-d8 (S)
%
100
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3229488
3229489
MS
MSD
92532888001 Spike
Spike
MS
MSD MS MSD % Rec
Parameter Units Result Conc.
Conc.
Result
Result % Rec % Rec Limits RPD Qual
1,1,1-Trichloroethane ug/L ND 20
20
20.6
20.5 103 103 70-148 0
Results presented on this page are in the units indicated by the
"Units" column except where
an altemate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced. except �n full
Date. 04/27/2021 04:55 PM without the written consent of Pace Analytical Services, LLC.
Page 13 of 31

Pace Analytical Services{ LLC
�/
/* v 9800 Kincey Ave Suite 100 -
aeeAnal4ica! Huntersville, NC 26078
trtrer.►acdalsrao [phone]
QUALITY CONTROL DATA
Project: PPA 4/13
Pace Project No. 92532949
MATRIX SPIKE & MATRIX SPIKE DUPLICATE.
3229488
3229489
MS
MSD
92532888001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc
Result
Result
% Rec
% Rec
Limits
RPD Qual
1 1.22-Tetrachloroethane
ug/L
NO
20
20
20.6
21.0
103
105
70-131
2
1 .1 2-Trichloroethane
ug/L
NO
20
20
18.8
8 9
94
95
70-136
0
1.1-Dichloroethane
ug/L
NO
20
20
19.6
19.7
98
99
71-143
0
1.1-Dichloroethene
ug/L
ND
20
20
19.7
19.8
98
99
70-158
1
1 2.4-Tnchlorobenzene
ug/L
ND
20
20
218
22.6
109
113
70-139
4
1 2-Dichlorobenzene
ug/L
NO
20
20
219
220
109
110
70-133
0
1.2-Dichloroethane
ug/L
NO
20
20
17.9
184
90
92
72-137
2
1.2-Dichloropropane
ug/L
NO
20
20
19.0
19.5
95
98
70-138
3
1,3-Dichlorobenzene
ug/L
NO
20
20
21.7
213
108
106
75-133
2
1 ,4-Dichlorobenzene
ug/L
NO
20
20
21.7
21.4
108
107
70-133
1
2-Chloroethylvinyl ether
ug/L
NO
40
40
NO
ND
0
0
10-200
J(P5)
Acrolein
ug/L
NO
100
100
82.6
84 6
83
85
50-150
2
Acrylonitrile
ug/L
NO
100
100
87.9
913
88
91
68-140
4
Benzene
ug/L
ND
20
20
19.7
196
99
98
75-125
1
Bromodichloromethane
ug/L
ND
20
20
18.9
19.8
94
99
70-138
5
Bromoform
ug/L
ND
20
20
19.7
20.4
99
102
57-138
3
Rromomethane
ug/L
NO
20
20
20.7
20.9
104
104
10-200
1
,arbon tetrachloride
ug/L
ND
20
20
21A
21.4
107
107
70-125
0
;hlorobenzene
ug/L
NO
20
20
20.6
206
103
103
82-137
0
Chloroethane
ug/L
NO
20
20
22.5
20.7
112
104
51-166
8
Chloroform
ug/L
NO
20
20
18.3
18.6
92
93
70-121
1
Chloromethane
ugiL
NO
20
20
17.5
17.6
87
88
24-161
1
cis-1 ,3-Dichloropropene
ug/L
NO
20
20
18.8
193
94
96
70-142
2
Dibromochloromethane
ug/L
NO
20
20
20.2
207
101
104
69-133
3
Ethylbenzene
ug/L
NO
20
20
20.8
21 1
104
105
75-134
2
Hexachloro-1,3-butadiene
ug/L
NO
20
20
21A
23.9
107
119
62-151
11
Methylene Chloride
ug/L
NO
20
20
17 1
17.2
85
86
64-148
1
Naphthalene
ug/L
ND
20
20
21.3
228
106
114
57-150
7
Tetrachloroethene
ug/L
NO
20
20
19.7
197
98
99
70-133
0
Toluene
ug/L
NO
20
20
19.0
18 9
95
94
75-134
1
trans-1,2-Dichloroethene
ug/L
ND
20
20
19.5
19.2
98
96
70-143
2
trans-1.3-Dichloropropene
ug/L
ND
20
20
18.5
18.7
92
94
70-138
1
Trtchloroethene
ug,rL
ND
20
20
18.0
17.8
90
89
75-138
1
Tnchlorofluoromethane
ug/L
ND
20
20
19.1
18.9
96
95
61-154
1
Vinyl chloride
ug/L
NO
20
20
19.7
19.5
98
98
55-172
1
1 2-Dichloroethane-d4 (S)
%
103
104
70-130
4-Bromofluoroberizene (S)
%
100
101
70-130
Toiuene-cl8 (S)
%
97
95
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
Th.s report shall not be reproduced, except n full.
Date 04/272021 04 55 PM witnout the wntten consent of Pace Analytical Services. LLC
Page 14 of 31

1'aceAnalXical'
www.pacelabs.com
QUALITY CONTROL DATA
Project: PPA 4/13
Pace Project No.: 92532949
QC Batch: 614807 Analysis Method EPA 625.1
QC Batch Method. EPA 625 1 Analysis Description: 625 MSS
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92532949001
METHOD BLANK. 3235405
Matrix:
Water
Associated Lab Samples: 92532949001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
1,2-Dichlorobenzene
ug/L
ND
5.0
04/202108:43
1,2-Diphenylhydrazine
ug/L
ND
5.0
04202108:43
1,3-Dichlorobenzene
ug/L
ND
5 0
042021 0843
1,4-Dichlorobenzene
ug/L
NO
5.0
04202108A3
2,4,6-Trichlorophenol
ug/L
NO
10.0
04/202108.43
2,4-Dichlorophenol
ug/L
NO
50
04/20/21 0843
2,4-Dimethylphenol
ug/L
NO
100
0412021 08:43
2,4-Dinitrophenol
ug/L
ND
50.0
04/2021 0843
2,4-Dinitrotoluene
ug/L
NO
5.0
041202108A3
2,6-Dinitrotoluene
ug/L
ND
5.0
042021 0843
2-Chloronaphthalene
ug/L
NO
5.0
04202108:43
nrophenol
ug/L
ND
5.0
04/20/21 08:43
ophenol
ug/L
ND
5.0
0412012108:43
,),a-uichlorobenzidine
ug/L
NO
10.0
04/20/21 08A3
4,6-Dinitro-2-methylphenol
ug/L
NO
10.0
04/202l08A3
4-Bromophenylphenyl ether
ug/L
ND
5.0
04/2021 08A3
4-Chloro-3-methylphenol
ug/L
ND
5.0
042021 0843
4-Chlorophenylphenyl ether
ug/L
NO
5.0
042021 08A3
4-Nitrophenol
ug/L
ND
10.0
042021 08A3
Acenaphthene
ug/L
NO
5.0
04/202108:43
Acenaphthylene
ug/L
ND
5.0
04202108A3
Anthracene
ug/L
ND
5.0
04/2021 08A3
Benzo(a)anthracene
ug/L
NO
50
04/2021 08A3
Benzo(a)pyrene
ug/L
ND
5.0
04/2021 MA3
Benzo(b)fluoranthene
ug/L
ND
5.0
04/202108:43
Benzo(g,h,i)perylene
ug/L
NO
5.0
04/20210843
Benzo(k)fluoranthene
ug/L
ND
5.0
04/20/21 08:43
bis(2-Chloroethoxy)methane
ug/L
NO
10.0
04/202108:43
bis(2-Chloroethyl) ether
ug/L
ND
5.0
04/20/21 08:43
bis(2-Ethylhexyl)phthalate
ug/L
ND
5.0
04/20/21 08:43
Butylbenzylphthalate
ug/L
ND
5.0
04/20/21 08:43
Chrysene
ug/L
ND
5.0
04/20/21 08:43
Di-n-butylphthalate
ug/L
ND
5.0
041202108:43
Di-n-octylphthalate
ug/L
NO
5.0
041202108A3
Dibenz(a,h)anthracene
ug/L
ND
5.0
04/202108:43
Diethylphthaiate
ug/L
NO
5.0
04/202108:43
Dime thylphthalate
ug/L
ND
5.0
04202108:43
Fluoranthene
ug/L
ND
5.0
04202108:43
Fluorene
ug/L
ND
5.0
04202108:43
Hexachlorobenzene
ug/L
ND
5.0
04202108:43
Pace Analytical Services. LLC
Kxrcey Ave Skr^ e - G-
Huntersviil,e NC 2807E
(7, Uy675---oc2
Results presented on this page are in the units indicated by the "Units' column except where an altemate unit is presented to the right of the result -
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full
Date: 04/27/2021 04:55 PM without the written consent of Pace Analytical Services. LLC
Page 15 of 31

FaceAnalytical s
nnr lacel�lsrors
Project: PPA 4113
Pace Project No. 92532949
QUALITY CONTROL DATA
METHOD BLANK: 3235405
Matrix:
Water
Associated Lab Samples: 92532949001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Hex achlorocyclopentadiene
ug/L
ND
10.0
04/20/21 08:43
Hexachloroethane
ug/L
ND
5.0
04/20/21 08:43
Indeno(1,2,3-cd)pyrene
ug/L
ND
5.0
04/20/21 08:43
Isophorone
ug/L
ND
10.0
04/20/21 08:43
N-Nitroso-di-n-propylamine
ug/L
ND
5.0
04/20/21 08:43
N-Nitrosodimethylamine
ug/L
ND
5.0
04/20/21 08:43
N-Nitrosodiphenylamine
ug/L
ND
10.0
04/20/21 08:43
Naphthalene
ug/L
ND
5.0
04/20/2108:43
Nitrobenzene
ug/L
ND
5.0
04120/2108:43
Pentachlorophenol
ug/L
ND
10.0
04120/2108:43
Phenanthrene
ug/L
ND
5.0
04/20/21 08:43
Pheno,
ug/L
ND
5.0
04/20/21 08:43
Pyrene
ug/L
ND
5.0
04/20/21 08:43
2.4 6-Tnbromophenol (S)
%
75
10-137
04/20/21 08:43
2-Fluorobiphenyl (S)
%
100
15-120
04/20/21 08:43
2-Fluorophenol (S)
%
44
10-120
04/20/21 08:43
Nitrobenzene-d5 (S)
%
109
10-120
04/20/21 08:43
3henol-d6 (S)
%
56
10-120
04/20/21 08:43
ferphenyl-d14 (S)
%
107
11-131
04/20/21 08:43
Pace Analytical Services, LLC
9800 Kincey Ave Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
Parameter
3235406
Units
Spike
Cone.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1.2-Dichlorobenzene
ug/L
50
34.5
69
32-129
1 2-Diphenylhydrazine
ug/L
50
42.4
85
25-150
1.3-D:chlorobenzene
ug/L
50
33.4
67
1-172
14-Dlchlorobenzene
ug/L
50
34.0
68
20-124
2 4.6-Trichlorophenol
ug/L
50
37.3
75
37-144
2.4-Dichlorophenol
ug/L
50
38.6
77
1-191
2,4-Dimethylphenol
ug/L
50
39.6
79
32-119
2,4-Dinitrophenol
ug/L
250
237
95
1-181
2A-Dinitrotoluene
ug/L
50
44.7
89
39-139
2,6-Dinitrotoluene
ug/L
50
42.8
86
50-158
2-Chloronaphthalene
ug/L
50
36.6
73
60-118
2-Chlorophenol
ug/L
50
36.1
72
23-134
2-Nitrophenol
ug/L
50
39.2
78
29-182
3,3'-Dichlorobenzidine
ug/L
100
95.1
95
1-262
4.6-Dinitro-2-methylphenol
ug/L
100
103
103
1-181
4-Bromophenylphenyl ether
ug/L
50
48.6
97
53-127
4-Ch)oro-3-methylphenol
ug/L
100
73.9
74
22-147
4-Chforophenylphenyl ether
ug/L
50
40.8
82
25-158
4-Nitrophenol
ug/L
250
125
50
1-132
Acenaphthene
ug/L
50
39.5
79
47-145
Aoenaphthyiene
ug/L
50
40.7
81
33-145
Results Presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not De reproduced, except in full,
Date. 04 c712021 04:55 PM without the written consent of Pace Analytical Services. LLC,
Page 16 of 31

f aceAnal ical
www.pacelabs.com
QUALITY CONTROL DATA
Project: PPA 4/13
Pace Project No.: 92532949
Pace Anatyt"I Services. LLC
96W Kr-y Ave. &qe - 00
Huntersville NC 28r,76
t r 041875-9C92
LABORATORY CONTROL SAMPLE:
3235406
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Anthracene
ug/L
50
47.2
94
1-166
Benzo(a)anthracene
ug/L
50
48.5
97
33-143
3 Benzo(a)pyrene
ug/L
50
50.5
101
17-163
Benzo(b)fluoranthene
ug/L
50
50.8
102
24-159
Benzo(g,h,i)perylene
ug/L
50
52.1
104
1-219
Benzo(k)fluoranthene
ug/L
50
47,8
96
11-162
bis(2-Chloroethoxy)methane
ug/L
50
38.4
77
33-184
bis(2-Chloroethyl) ether
ug/L
50
41.7
83
12-158
bis(2-Ethylhexyl)phthalate
ug/L
50
52.8
106
8-158
Butylbenzylphthalate
ug/L
50
51.2
102
1-152
Chrysene
ug/L
50
47.3
95
17-168
Di-n-butylphthalate
ug/L
50
50.1
100
1-118
D i-n-octylp htha late
ug/L
50
53.3
107
4-146
Dibenz(a,h)anthracene
ug/L
50
50.1
100
1-227
Diethylphthalate
ug/L
50
44.3
89
1-114
Dimethylphthalate
ug/L
50
41.0
82
1-112
i Fluoranthene
ug/L
50
48.9
98
26-137
Fl,,^•-ne
ug/L
50
42.1
84
59-121
1 :hlorobenzene
ug/L
50
43.8
88
1-152
I..,-ji-ilorocyclopentadiene
ug/L
50
33.5
67
25-150
Hexachloroethane
ug/L
50
33.4
67
40-113
1ndeno(1,2,3-cd)pyrene
ug/L
50
51.5
103
1-171
Isophorone
ug/L
50
38.5
77
21-196
N-Nitroso-di-n-propylamine
ug/L
50
39.9
80
1-230
N-Nitrosodimethylamine
ug/L
50
32.1
64
25-150
N-Nitrosodiphenylamine
ug/L
50
45.3
91
25-150
Naphthalene
ug/L
50
36.7
73
21-133
j Nitrobenzene
ug/L
50
37.5
75
35-180
j Pentachlorophenol
ug/L
100
92.9
93
14-176
Phenanthrene
ug/L
50
46.4
93
54-120
Phenol
ug/L
50
23.9
48
5-112
Pyrene
ug/L
50
48.5
97
52-115
2,4,6-Tribromophenol (S)
%
114
10-137
2-Fluorobiphenyl(S)
%
79
15-120
2-Fluorophenol(S)
%
56
10-120
Nitrobenzene-d5(S)
%
84
10-120
Phenol-d6 (S)
%
45
10-120
Terphenyl-d14 (S)
%
85
11-131
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3235407
3235408
MS
MSD
92531692003 Spike
Spike MS
MSD
MS MSD % Rec
Parameter
Units Result Conc,
Conc. Result
Result
% Rec % Rec Limits RPD Qual
1,2-Dichlorobenzene
ug/L
ND 50
50 28 7
25.6
57 51 32-129 12
1,2-Diphenylhydrazine
ug/L
ND 50
50 511
52.5
102 105 25-150 3
Results presented on this page are in the units indicated by the "Units"
column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall
not be reproduced except in full
Date: 04/27/2021 04:55 PM
without the written consent
of Pace Analytical Services, LLC,
Page 17 of 31

�aceAnaVical
i
- rn","cetabernrs
QUALITY CONTROL DATA
Project: PPA 4/13
Pace Project No.: 92532949
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3235407 3235408
Pace Analytical Services; LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
MS
MSD
92531692003
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc,
Result
Result
% Rec
% Rec
Limits RPD Qual
1.3-Dichlorobenzene
uo/L
NO
50
50
27.9
24.9
56
50
1-172
11
14-Dichlorobenzene
ug/L
NO
50
50
28.5
25.7
57
51
20-124
10
2 4.6-Trichlorophenoi
ugfL
ND
50
50
48.1
45.0
96
92
37-144
5
2.4-Dlchlorophenol
uo/L
NO
50
50
50.2
47.6
100
95
1-191
5
2.4-Dinethylphenol
ug/L
49.3
50
50
113
98.9
127
99
32-119
13 J(MI)
2.4-Diniirophenol
ug/L
NO
250
250
NO
30.61
6
12
1-181
2.4-Dinitrotoluene
ug/L
NO
50
50
51.4
53.8
103
108
39-139
4
2,6-Dinitrotoluene
ug/L
ND
50
50
51.3
52.4
103
105
50-158
2
2-Chloronaphthalene
ug/L
NO
50
50
36.0
36.0
72
72
60-118
0
2-Chlorophenol
ug/L
ND
50
50
43.9
44.7
88
89
23-134
2
2-Nitrophenol
ug/L
NO
50
50
53.0
50.5
106
101
29-182
5
3.3'-Dichlorobenzidine
ug/L
ND
100
100
112
109
112
109
1-262
2
4.6-Dinitro-2-methylphenol
ug/L
ND
100
100
79.4
63.7
79
64
1-181
22
4-Bromophenylphenyl ether
ug/L
NO
50
50
56.3
59.0
113
118
53-127
5
4-Chloro-3-methylphenol
ug/L
NO
100
100
95.4
95.8
95
96
22-147
0
4-Chlorophenylphenyl ether
ug/L
ND
50
50
43.5
46.5
87
93
25-158
7
4-Nitrophenol
ug/L
NO
250
250
85.1
71.1
34
28
1-132
18
�cenaphthene
ug/L
201
50
50
281
244
160
87
47-145
14 J(M1)
Icenaphthylene
ug/L
70.1
50
50
127
117
115
94
33-145
9
Anthracene
ugfL
11.7
50
50
68.1
66.2
113
109
1-166
3
Benzo(a)anthraoene
ug/L
ND
50
50
57.4
56.4
115
113
33-143
2
Benzo(a)pyrene
ug/L
ND
50
50
56.8
57.7
114
115
17-163
2
Benzo(b)fiuoranthene
ug/L
ND
50
50
57.6
56.8
115
114
24-159
1
Benzo(g,h,i)perylene
ug/L
ND
50
50
58.8
61.2
118
122
1-219
4
Benzo(k)fluoranthene
ug/L
NO
50
50
57.3
56.9
115
114
11-162
1
bis(2-Chloroethoxy)methane
ug/L
NO
50
50
51.5
49.2
100
96
33-184
5
bis(2-Chloroethyl) ether
ug/L
NO
50
50
50.8
50.8
102
102
12-158
0
bis(2-Ethylhexyi)phthalate
ug/L
NO
50
50
59.9
58.5
120
117
8-158
2
Butylbenzylphthalate
ug/L
ND
50
50
63.3
62.2
127
124
1-152
2
Chrysene
ug/L
ND
50
50
56.7
55.6
113
111
17-168
2
Di-n-butylphthalate
ug/L
ND
50
50
56.1
56.5
112
113
1-118
1
Di-n-octyiphtha late
ug/L
NO
50
50
61.3
62.0
123
124
4-146
1
Dibenz(a.h)anthracene
ugfL
ND
50
50
57.8
57.9
116
116
1-227
0
Dtethylphthatate
ugfL
ND
50
50
50.5
52.6
101
105
1-114
4
Dimethylphtha late
ug/L
ND
50
50
49.4
50.3
99
101
1-112
2
Fiuoranthene
ugfL
ND
50
50
59.6
58.5
112
110
26-137
2
Fluorene
ugfL
71.0
50
50
131
122
121
102
59-121
7
Hexachlorobenzene
ugfL
NO
50
50
49.7
51.1
99
102
1-152
3
Hexachlorocyciopentadiene
ug/L
ND
50
50
24.8
22.8
50
46
25-150
8
Hexachloroethane
ugfL
NO
50
50
28.9
24.7
58
49
40-113
16
Indeno(1.2.3-cd)pyrene
ug/L
NO
50
50
58.2
59.5
116
119
1-171
2
Isophorone
ugfL
NO
50
50
51.2
50.2
102
100
21-196
2
N-Ntroso-di-n-propylamine
ug/L
NO
50
50
47X
49.9
94
100
1-230
6
N-Nitrosodimethytamine
ugfL
ND
50
50
40.6
42.0
81
84
25-150
4
N-Ndrosodiphenylamine
ugfL
ND
50
50
56.2
57.2
112
114
25-150
2
Naphthalene
ug/L
1220
50
50
1380
1180
322
-72
21-133
15 J(M1)
Results Presented on this page are
in the units indicated by the
"Units" column except where
an alternate unit is presented to the right
of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date 04127t2021 04:55 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 31

�aceAalytical'
www,pacelabs.com
QUALITY CONTROL DATA
Project: PPA 4/13
Pace Project No.: 92532949
Pace Analytx al Secvbces. ULC
96W Kvxxy Ave Stn- cc
Huntersviile. NC 2€;78
(7104j67--9092
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3235407
3235408
MS
MSD
92531692003
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Nitrobenzene
ug/L
ND
50
50
47.1
454
94
91
35-180
4
Pentachlorophenol
ug/L
ND
100
100
915
75.3
92
75
14-176
19
Phenanthrene
ug/L
74.6
50
50
139
129
128
108
54-120
8 i(MI)
Phenol
ug/L
ND
50
50
34.4
36.3
62
66
5-112
6
Pyrene
ug/L
5.9
50
50
67.1
654
122
119
52-115
3 J(M1)
2,4,6-Tribromophenol (S)
%
124
121
10-137
2-Fluorobiphenyl(S)
%
86
81
15-120
2-Fluorophenol(S)
%
58
67
10-120
Nitrobenzene-d5(S)
%
105
97
10-120
Phenol-d6 (S)
%
54
57
10-120
Terphenyl-d14 (S)
%
99
97
11-131
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 04/27/2021 04:55 PM without the written consent of Pace Analytical Services, LLC.
Page 19 of 31

?aceAnalXical l
w w.Dacaii05ton
QUALITY CONTROL DATA
Pace Analytical Serviccs, LLC
9800 KinceyAve. 'Suite 100
Huntersville, NC 28078
[phone]
Project: PPA4/13
Pace Project No.: 92532949
QC Batch 614459
Analysis Method:
SM 2540C-2011
QC Batch Method: SM 254OC-2011
Analysis Description:
2540C Total Dissolved Solids
Laboratory:
Pace Analytical Services -Asheville
Associated Lab Samples: 92532949001
METHOD BLANK: 3233880
Matrix: Water
Associated Lab Samples: 92532949001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Total Dissolved Solids
mg/L
ND 25.0 04/17/21 16:48
LABORATORY CONTROL SAMPLE 3233881
Spike LCS
LCS % Rec
Parameter
Units
Cone. Result
% Rec Limits Qualifiers
Total Dissolved Solids
mg/L
249 250
100 90-110
SAMPLE DUPLICATE: 3233882
92533738001 Dup
Parameter
Units
Result Result
RPD Qualifiers
Total Dissolved Solids
mg/L
563 553
2
SAMPLE DUPLICATE: 3233883
92533102001 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 160 166 4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date 04272021 04,55 PM wdhout the written consent of Pace Analytical Services, LLC Page 20 of 31

laceAnalvtical'
.
www.pacelans.com
Project: PPA 4/13
Pace Project No.: 92532949
QC Batch: 616029
QC Batch Method: EPA 350.1 Rev 2.0 1993
Associated Lab Samples: 92532949001
METHOD BLANK: 3241901
Associated Lab Samples: 92532949001
i
i
Parameter Units
Nitrogen, Ammonia mg/L
LABORATORY CONTROL SAMPLE: 3241902
Parameter Units
Nitrogen, Ammonia mg/L
Pace Analytical Services, LLC
QSW K.—ceyAv*. Sure `G_
Huntersville NC 26075
(704)875-90G2
QUALITY CONTROL DATA
Analysis Method: EPA 350.1 Rev 2.0 1993
Analysis Description. 350.1 Ammonia
Laboratory: Pace Analytical Services - Asheville
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers_
ND 0.10 04/252115:09
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
5 5.0 99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3241903 3241904
MS MSD
92532798001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 10.7 5 5 15.6 15.7 100 100 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3241920 3241921
MS MSD
92533344004 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Quaff
Nitrogen, Ammonia mg/L 29.7 5 5 34 9 34 9 105 105 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an a@emate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced. except in full
Date: 04/27/2021 04:55 PM without the written consent of Pace Analytical Services, LLC.
Page 21 of 31

toaceAnaVical
trrv�aczra kssore
QUALITY CONTROL DATA
Project: PPA 4/13
Pace Project No.: 92532949
i
QC Batch: 615860 Analysis Method: EPA 351.2 Rev 2.0 1993
QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN
Laboratory' Pace Analytical Services -Asheville
Associated Lab Samples: 92532949001
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
METHOD BLANK: 3240907 Matrix: Water
Associated Lab Samples: 92532949001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Neldahl, Total mg/L ND 0.50 04/24/21 04:34
LABORATORY CONTROL SAMPLE: 3240908
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Nitrogen, Kjeldahl, Total mg/L 10 9.5 5 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3240909 3240910
MS MSD
92532938012 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen. Neldahl. Total mg/L 23.1 200 200 174 184 75 81 90-110 6 J(M1)
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3240911 3240912
MS MSD
92532938015 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Kjeldahl,Total mg/L 948 200 200 1190 1140 122 94 90-110 5 J(M1)
Results presented on this page are in the units indicated by tho "Units" column except where an ahemate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date 04l27l2021 04 55 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 31

�aceAnalyticaf
www.pacelabs.com
Project: PPA 4/13
Pace Project No.: 92532949
t
QC Batch: 614819
j QC Batch Method: EPA 353.2 Rev 2.0 1993
l
Associated Lab Samples. 92532949001
METHOD BLANK: 3235434
Associated Lab Samples: 92532949001
Parameter Units
Nitrogen, NO2 plus NO3 mg/L
LABORATORY CONTROL SAMPLE: 3235435
Parameter Units
Nitrogen, NO2 plus NO3 mg/L
Pace Analytical Services. LLC
95C0 K_-icey Ave Some - X
Huntersvitle NC 2807E
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA 353.2 Rev 2.0 1993
Analysis Description: 353.2 Nitrate + Nitrite. preserved
Laboratory: Pace Analytical Services -Asheville
Matrix: Water
Blank Reporting
Result Limit Anatyzed Qualifiers
ND 0.040 04/20/2113:02
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
2.5 26 106 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3235436 3235437
MS MSD
92532782001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen, NO2 plus NO3 mg/L 0.11 2.5 2.5 1.7 1.8 55 66 90-110 1 J(M1)
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3235438 3235439
MS MSD
92532823002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, NO2 plus NO3 mg/L 5A 2.5 2.5 7.9 7.9 102 101 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced. except in full.
Date: 04J27/2021 04:55 PM without the written consent of Pace Analytical Services, L.L.C.
Page 23 of 31

/16 laceAnal 1cal
nrr. Wei a hs.z0M
Project: PPA4/13
Pace Project No.: 92532949
QC Batch: 614975
QC Batch Method: EPA 365.1 Rev 2.0 1993
Associated Lab Samples: 92532949001
METHOD BLANK: 3236236
Associated Lab Samples. 92532949001
Parameter Units
Phosphorus mg/L
QUALITY CONTROL DATA
Analysis Method: EPA 365.1 Rev 2.0 1993
Analysis Description: 365.1 Phosphorus, Total
Laboratory: Pace Analytical Services -Asheville
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.050 04/20/2122:51
Pace Analytical Service&, LLC
9800 Kincey Ave Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 3236237
Spike LCS LCS % Rec
Parameter Units Conc Result % Rec Limits Qualifiers
Phosphorus mg/L 2.5 2 5 102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3236238 3236239
MS MSD
92532782001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L 1.4 2.5 2.5 4.2 4.1 114 106 90-110 5 J(MI)
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3236240 3236241
MS MSD
92532786003 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L 0.051 2.5 2 5 2.6 2.6 103 102 90-110 1
Results presented on this page are in the units indcated by the "Units" column except where air alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date 04/272021 04.55 PM withotrt the written consent of Pace Analytical Services. LLC
Page 24 of 31

��IaceAnaiytical
www.paceiabs.com
Project: PPA4/13
Pace Project No.: 92532949
QC Batch: 615854
j QC Batch Method: EPA 420.4 Rev 1.0 199-
E
Associated Lab Samples: 92532949001
METHOD BLANK: 3240876
Associated Lab Samples: 92532949001
i
E
¢ Parameter
if Phenolics, Total Recoverable
QUALITY CONTROL DATA
Analysis Method: EPA 420.4 Rev 1.0 1993
Analysis Description: 420.4 Phenolics
Laboratory: Pace Analytical Services - Asheville
Matrix. Water
Blank Reporting
Units Result Limit Analyzed Qualifiers
mg/L ND 0,020 0412612115:04
Pace Analytical services, PLC
9EC-3 K ncey Ave Su-.e 1 I-C
Huntersville NC 215 7e
(7041675-9062
LABORATORY CONTROL SAMPLE: 3240877
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Phenolics, Total Recoverable mg/L 0.05 0.048 96 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3240878
3240879
MS
MSD
92532305005 Spike
Spike
MS
MSD MS MSD % Rec
Parameter Units Result Conc,
Conc.
Result
Result % Rec % Rec Limits RPD Qua[
Phenolics, Total Recoverable mg/L 0,031 0.05
0.05
0.054
0.063 45 64 90-110 16 JI M1).
J(R1)
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3240880 3240881
MS MSD
35625413002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phenolics, Total Recoverable mg/L 0,0076 0.05 0.05 0.030 0.027 56 50 90-110 11 J(M1),
U J(R1)
Results presented an this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced. except in full
Date: 04/27/2021 04.55 PM without the written consent of Pace Analytical Services, LLC
Page 25 of 31

xA� aceAnaoical
wvw pacdabs-rm
Project: PPA 4113
Pace Project No.: 92532949
QC Batch: 614748
QC Batch Method: SM 4500-CN-E-2011
Associated Lab Samples: 92532949001
METHOD BLANK: 3235269
Associated Lab Samples: 92532949001
Parameter Units
Cyanide
mg/L
QUALITY CONTROL DATA
Analysis Method: SM 4500-CN-E-2011
Analysis Description: 450OCNE Cyanide, Total
Laboratory: Pace Analytical Services - Asheville
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0,0080 04/20/21 20 17
Pace Analytical Services, LLC
9800 Kincey Ave, Suite 1o0 "
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 3235270
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Cyanide mg/L 01 0.11 107 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3235289 3235290
MS MSD
92533227001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Cyanide mg/L 0.043 0.1 0.1 0,065 0.066 22 23 80-120 2 J(M1)
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3235291 3235292
MS MSD
92532836002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Cyanide mg/L ND 0.1 0.1 0.061 0.065 61 65 80-120 5 i(MI)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced. except in full.
Date. 04I272021 04:55 PM without the wTitten consent of Pace Analytical Services. LLC.
Page 26 of 31

lralceAnalyfical
www.pacelabs.com
QUALIFIERS
Project: PPA 4/13
Pace Protect No : 92532949
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
MDL -Adjusted Method Detection Limit.
Pace Analytical Services. LLC
seer K.ncey Ave S,17e - G-
Huntersville NC 2BC7e
ti Dale � �ses2
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
INC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acroiein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
ANALYTE QUALIFIERS
I The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit.
J(HS) Estimated Value. Results are from sample aliquot taken from VOA vial with headspace (air bubble greater than 6 mm
diameter).
J(M1) Estimated Value. Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS)
recovery.
J(P5) Estimated Value. The EPA or method required sample preservation degrades this compound, therefore acceptable
recoveries may not be achieved in sample matrix spikes.
J(RI) Estimated Value. RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced except in full.
Date: 04/27/2021 04:55 PM without the written consent of Pace Analytical Services LLC Page 27 of 31

/►� Pace Analytical Services, LLC
l� 9800 Kincey Ave Suite 100
f lacema'Vt,y f(a' A Huntersville, NC 28078
• er icllahtmo [phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
ProjectPPA4/13
Pace Project No.: 92532949
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Analytical
Batch
92532949001
TARBORO WWTP EFFLUENT
EPA 16648
615662
92532949001
TARBORO WWTP EFFLUENT
EPA 200.7 Rev 4.4 1994
615369
EPA200.7 Rev 4.4 1994
615400
92532949001
TARBORO WWTP EFFLUENT
EPA1631E
614244
EPA1631E
614566
92532949002
TARBORO WWTP LLHG BLANK
EPA1631E
614244
EPA1631E
614566
92532949001
TARBORO WWTP EFFLUENT
EPA625.1
614807
EPA625.1
614865
92532949001
TARBORO WWTP EFFLUENT
EPA624.1
613629
92532949001
TARBORO WWTP EFFLUENT
SM 2540C-2011
614459
92532949001
TARBORO WWTP EFFLUENT
TKN+NO3+NO2
616212
Calculation
92532949001
TARBORO WWTP EFFLUENT
EPA350 1 Rev 2.0 1993
616029
92532949001
TARBORO WWTP EFFLUENT
EPA 351.2 Rev 2.0 1993
615860
EPA 351.2 Rev 2.0 1993
615982
92532949001
TARBORO WWTP EFFLUENT
EPA 353.2 Rev 2.0 1993
614819
92532949001
TARBORO WWTP EFFLUENT
EPA 365.1 Rev 2.0 1993
614975
EPA 365.1 Rev 2 0 1993
615050
92532949001
TARBORO WWTP EFFLUENT
EPA420.4 Rev 1.0 1993
615854
EPA420.4 Rev 1.0 1993
616144
92532949001
TARBORO WWTP EFFLUENT
SM 4500-CN-E-2011
614748
SM 4500-CN-E-2011
614787
Date 04/2712021 04:55 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
wrihout the vmtten consent of Pace Analytical Services, LLC
Page 28 of 31

Document Name: Doament Revised: October 29, 2020
d,,���� S_ —pie Condition Upon Receipt(M It
Page 1 of 2
C6Af181ytICaf' Document No.: Issuing Authorty:
F-CAR-CS-033-Rea07 pace Carollnas QUAY Ofite _
Laboratory receiving samples:
Asheville ❑ Eden Greenwood(] Huntersville ❑ Raleigh® Mechanicsville[] Atlanta[:) Kernersville❑
,. Client Name: Pro]edfh WOE : 92532949
n Receipt 1-Dwn U:C %i>✓riotD !I' IIIII III IIII I III
Courier: ❑Fed Ex []UPS ❑USPS []Client
❑ Commercial Npace ❑Other. 92532949
Custody Seal Present? ❑Yes [ENo Seals Intact? []Yes �QNo
Date/Stdlab Person baminieg CorKeMc �11 c%'f? 2
Packing Material: ❑Bubble Wrap []Bubble Bags ONone ❑ Other Biological Tissue Frozen?
C]Yes ONO Mi N/A
Thermometer:
,, ]Wet ❑Blue ❑tone
❑ IR Gun ID: 4q 17005 Type of Ice:
Correction Factor:
Cooler Temp: —' Add/Subtract ('C) 0 . Q Temp should be above freezing to 6'C ❑Samiles oct of temp cntgrta. samples on Ice, coogns procez
CoalerTemp Corrected ('C): j, huteg�r.
USDA Regulated Soil (RN/A, water sample)
Did samples originate In a quarantine zone within the United States: CA, NY, or SC (check maps)? Did-amples WgiWe from; foreign source (intemationally,
>» r—lv., r-ler..
Yes No—
commecUs/Oisorepencr
Chain of Custody Present?
Yes
No
N/A
1.
Samples Arrlved within Hold Time?
Yes
No
WA
2-
Short Hold Time Analysts (<72 hr.)?
0yes
QNo
N/A
3.
Rush Turn Around Time Re uested7
nyeS
WNo
CJNJA
4-
Sufficient Volume?
Caye3
No
WA
5-
Correct Containers Used?
Eyes
❑No
❑N/A
6.
-Pace Containers Used?
CIN.
EINIA
Containers Intact?
M
MNa
N/A
7.
Dlssolved analysis: Samples Feld Filtered?
[]yes
No
KNIA
8-
Sample Labels Match COC?
MYes
[3No
❑N/A
9.
-includes Date/Time/ID/Analysis Matrix:
Headspace In VOA Vials (>5.6mm)?
Trip Blank Present?
Yes
❑Yes
No
[]No
WA
10.
Tri O nk Custody Seals Present?
Dyes
-
WA
field 0= WU1re°r Ures u110
COMMENTS/SAMPLE DISCREPANCY
Lot 10 of split containers:
CLIENT NOTIFICATIONf RFSOLU71ON
Person contacted:
Project Manager SCURF Review:
Project Manager SRF Review:
Date/Time:
Date:
Date:
Page 29 of 31

T
W
co
m
w
0
0
w
u
3
m
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rs
I
a
a
^
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ro
3
3
0
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o
Qo
a
O
�
c
a
th
tA
fD
3
tD
w
S
a 2
0
.o
fA
p
3
0
a �
n
n
tl
m
n
i
3
~
Kemq
BP4U-12S mL Plastic Unpreserved(N/A)(C6)
©P3U-250 mL Plastic Unpreserved (N/A)
BP21.1-500 mL Plastic Unpreserved (N/A)
BP1U-1 liter Plastic Unpreserved (N/A)
Zzz
BP45-22S mL PI —tic 112504 (pH < 2) (CI-)
BP3N-250 mL plastic HNO3 (pH < 2)
BP4Z-125 ml Plastic ZN Acetate & NoOFI (>9)
BP4C-125 mL Plastic NaOH (pH> 12) (Cl-)
WGFU-WIde-mouthed Glass Jar Unpreserved
(� \
)U
AG1U-1 lltur t—ber Unprc o—d (N/A) (CI-)
AG111-1 liter Amber HCJ (pH < 2)
3U-250 mL Amber Unpreserved (N/A) (CI-)
AG1S-1 liter Amber H2504 (pH < 2)
A(335-250 mL Amber IA2504 (pH < 2)
G3A(DG3A)-250 mL Amber NH4G (N/A)((1-)
DG91,11-40 mL VOA HCI (N/A)
VGST-40 mL VOA Na25203 (N/A)
VGBU-40 mL VOA Unp (N/A)
OGSP-40 mL VOA H31`04 (N/A)
VOAK (6 vlets per klt)-5035 kh (N/A)
V/GK (3 vials per kit)-VPH/Gas kit (N/A)
SP5T-125 mL Sterne Plastic (N/A - lab)
SP2T-250 mL Sterne Plastic (N/A- lab)
ZZ
LL �.
BP3A-250 mL Plastic (NH2)2504 (9.3-9.7)
AGOU-300 mL Amber Unprescrved vials {N/A)
VSGU-20 mL Sclntl(latlon vials (N/A)
�1
D69U-40 mL Amber Unpreserved vials (N/A)
O
m
2
n

.C+ CHAIN -OF -CUSTODY / Analytical Request Document

�II
. t Analytical
www.pacelebsrom
March 07, 2023
Kevin Peaden
Town of Tarboro
506 Dowd Street
PO Box 220
Tarboro, NC 27886
RE: Project: ANNUAL TEST OCTOBER
Pace Project No.: 92630982
2�ZZ_
Pace Analytical services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
Dear Kevin Peaden:
Enclosed are the analytical results for sample(s) received by the laboratory on October 13. 2022. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
OWL
Angela Baioni for
Terri Page
[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced• except in full,
without the written consent of Pace Analylicst Services, LLC.
Page 1 of 31

it Analytical
www.pacelabs.com
Project: ANNUAL TEST OCTOBER
Pace Project No.: 92630982
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87W
North Carolina Drinking Water Certification M 37712
North Carolina Wastewater Certification #: 40
CERTIFICATIONS
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Flodda/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water#: LA029
Virginia/VELAP Certification #: 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 10C
Huntersville, NC 28078
(704)8759092
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 31

/0",
Anal l
ytca
www.pacwabs.com
Project: ANNUAL TEST OCTOBER
Pace Project No.: 92630982
Lab ID Sample ID
92630982001 TOWN OF TARBORO EFFLUENT
92630982002 LLHG BLANK
J-A = Pace Analytical Services - Asheville
;I-C = Pace Analytical Services - Charlotte
Pace Analytical Services, LLC
9800 iGncey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Analytes
Method
Analysts
Reported
Laboratory
EPA 1664E
REL
1
PASI-C
EPA 200.7 Rev 4.4 1994
SBW
15
PASI-A
EPA 1631 E
RDT
1
PASI-A
EPA625.1
PKS
59
PASI-C
EPA624.1
SAS
39
PASI-C
SM 254OC-2015
CS1
1
PASI-A
TKN+NO3+NO2 Calculation
MDW
1
PASI-A
EPA 350.1 Rev 2.0 1993
ARJ
1
PASI-A
EPA 351.2 Rev 2.0 1993
MFO
1
PASI-A
EPA353.2 Rev 2.0 1993
KDF1
1
PASI-A
EPA365.1 Rev 2.0 1993
MDW
1
PASI-A
EPA 420.4 Rev 1.0 1993
KDF1
1
PASI-A
SM 4500-CN-E-2016
ANM
1
PASI-A
EPA 1631 E
RDT
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduoed, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 31

3
/��14ceAnalXical
www.pacelabs.com
Project: ANNUAL TEST OCTOBER
Pace Project No.: 92630982
Sample: TOWN OF TARBORO
EFFLUENT
Parameters
HEM, Oil and Grease
Oil and Grease
200.7 MET ICP
Antimony
Arsenic
Beryllium
Cadmium
Calcium
Chromium
Copper
Lead
Magnesium
Nickel
'enium
rer
,allium
Hardness, Tbtal(SM 2340B)
Zinc
1631E MercuMl-ow Level
Mercury
625 RVE
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h, i )perylerie
Benzo(k)fluoranthene
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-Chloro-3-methyl phenol
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
2-Chloronaphthalene
2-Chlorophenol
4-Chlorophenylphenyl ether
Chrysene
^ibenz(a, h)anthracene
2-Dichlorobenzene
Date: 03/07/2023 04:58 PM
Pace AnatOrat Services, LLC
9800 Kincey Ave Suite 100
Huntersviile, NC 28078
(704�875-9092
ANALYTICAL RESULTS
Lab ID: 92630982001 Collected: 1Oil 3/22 08:00 Received: 10/13/22 11:50 Matrix: Water
Results Units Report Limit OF Prepared Analyzed CAS No. Qual
Analytical Method: EPA 1664E
Pace Analytical Services - Charlotte
NO mg/L 4.9 1 10124/22 04:34
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
NO
ug/L
5.0
1
10/25/2211:20
10/28/2218:54 7440-36-0
ND
ug/L
10.0
1
10/25/2211:20
10128/2218:54 7440-38-2
NO
ug/L
1.0
1
10/25/2211:20
10/28/2218:54 7440-41-7
NO
ug/L
1.0
1
1012512211:20
1012812218:54 7440-43-9
11200
ug/L
100
1
10125/2211:20
1012812218:54 7440-70-2
NO
ug/L
5.0
1
10/25/2211:20
10/28/2218:54 7440-47-3
11.1
ug/L
5.0
1
10/25/2211:20
10128/2218:54 7440-50-8
NO
ug/L
5.0
1
10/25/2211:20
10/28/2218:54 7439-92-1
2750
ug/L
100
1
10/25/2211:20
10/2812218:54 7439-95-4
NO
ug/L
5.0
1
10/25/2211:20
10/28/2218:54 7440-02-0
NO
ug/L
10.0
1
10/25/2211:20
10/28/2218.54 T782-49-2
ND
ug/L
5.0
1
10/2512211:20
10/28/2218:54 7440-22A
ND
ug/L
10.0
1
10/25/2211:20
10/28/2218:54 7440-28-0
39300
ug/L
662
1
10/25M 11:20
10/28/22 18:54
23.4
ug1L
10.0
1
10/25/2211:20
10128/2218:54 7440-66-6
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Pace Analytical
Services - Asheville
1.13
ng/L
0.50
1
10127/2210:00
11/17/2215:01 7439-97-6
Analytical Method: EPA 625.1 Preparation Method: EPA
625.1
Pace Analytical
Services - Charlotte
NO
ug/L
5.0
1
10/20/2214:41
1012112214:52 83-32-9
ND
ug/L
5.0
1
10120/2214:41
10/21/2214:52 208-96-8
ND
ug/L
5.0
1
10/20/2214:41
10/2112214.52 120-12-7
ND
ug/L
5.0
1
10/20/2214:41
10/21/2214:52 56-55-3
N D
ug/L
5.0
1
10/20/22 14:41
10/21122 14:52 50-32-8
NO
ug/L
5.0
1
10/2012214:41
1012112214:52 205-99-2
ND
ug/L
5.0
1
10/20/2214:41
10121/2214:52 191-24-2
NO
ug/L
5.0
1
10/20/2214:41
10/2112214:52 207-08-9
ND
ug/L
5.0
1
10/2012214:41
10/21/2214:52 101-55-3
ND
ug/L
5.0
1
1012012214:41
10/21/2214:52 85-68-7
ND
ug/L
5.0
1
1012012214:41
1012112214:52 59-50-7
ND
ug/L
10.0
1
10/20/22 14:41
10/21 /22 14:52 111-91-1
ND
ug/L
5.0
1
10/20/22 14:41
1012112214:52 111- 4-4
NO
ug/L
5.0
1
10/20/22 14:41
10121 /22 14:52 91-58-7
ND
ug/L
5.0
1
10120/2214:41
10/21/2214:52 95-57-8
ND
ug/L
5.0
1
10120/2214:41
1012112214:52 7005-72-3
NO
ug/L
5.0
1
1012012214:41
10/2112214:52 21Ml-9
ND
ug/L
5.0
1
10120/2214:41
10/21/2214:52 53-70-3
ND
ug/L
5.0
1
10/20/2214:41
10121/2214:52 95-50-1
REPORT OF LABORATORY ANALYSIS
This report shall not tie reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 31

1)1d1cel,Analj6cal
www.pacelabs.com
ANALYTICAL RESULTS
Pace Ana"cal Services, LLC
9800 Kincey Ave Suite 100
Huntersville, NC 28078
[phone]
Project: ANNUAL TEST OCTOBER
Pace Project No.: 92630982
Sample: TOWN OF TARBORO Lab ID: 92630982001 Collected: 10/13/22 08:00 Received: 10/13/22 11:50 Matrix: Water
EFFLUENT
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
625 RVE
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical
Services - Charlotte
1,3-Dichlorobenzene
ND
ug/L
5.0
1
10120/2214:41
1012112214:52
541-73-1
1,4-Dichlorobenzene
N❑
ug/L
5.0
1
1012012214:41
10/21/2214:52
106-46-7
3,3'-Dichlorobenzidine
NO
ug/L
10.0
1
10/2012214.41
10/21/2214:52
91-94-1
2,4-Dichlorophenol
ND
ug/L
5.0
1
10/20/22 14:41
10/2112214:52
120-83-2
Diethylphthalate
NO
ug/L
5.0
1
10120/2214:41
10/21/2214:52
84-66-2
2,4-Dimethylphenol
NO
ug/L
10.0
1
1012012214:41
1012112214:52
105-67-9 J(1-1)
Dimethylphthalate
NO
ug/L
5.0
1
10(2012214A1
10/21/2214:52
131-11-3
Di-n-butylphthalate
ND
ug/L
5.0
1
10/20/2214:41
10/21/2214:52
84-74-2
4,6-Dinitro-2-methylphenol
ND
ug/L
10.0
1
10120/2214:41
10/21/2214:52
534-52-1
2,4-Dinitrophenol
NO
ug/L
50.0
1
10/20/22 14:41
10121/2214:52
51-28-5
2,4-Dinitrotoluene
NO
ug/L
5.0
1
10/2012214:41
10(21/2214:52
121-14-2
2,6-Dinitrotoluene
NO
ug/L
5.0
1
10120/2214:41
10/21/2214:52
606-20-2
Di-n-octylphthalate
NO
ug/L
5.0
1
10120/2214:41
10/21/2214:52
117-84-0
1,2-Diphenylhydrazine
ND
ug/L
5.0
1
10/20/2214:41
10/2112214:52
122-66-7
bis(2-Ethylhexyl)phthalate
ND
ug/L
5.0
1
10/2012214:41
10/21/2214:52
117-81-7
-anthene
NO
ug/L
5.0
1
10/20/22 14:41
10/2112214:52
206-44-0
'ene
ND
ug/L
5.0
1
10/20/22 14:41
1012112214:52
86-73-7
Hexachlorobenzene
ND
ug/L
5.0
1
10/20/2214:41
10/2112214:52
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
10.0
1
10/20/22 14:41
10/2112214:52
77-47-4
Hexachloroethane
ND
ug/L
5.0
1
10120/2214:41
10/2112214:52
67-72-1
Indeno(1,2,3-cd)pyrene
ND
ug/L
5.0
1
10/20/2214:41
10J21/2214:52
193-39-5
Isophorone
ND
ug/L
10.0
1
10/20/22 14:41
10/2l/2214:52
78-59-1
Naphthalene
ND
ug/L
5.0
1
10/20/22 14:41
10/21/2214:52
91-20-3
Nitrobenzene
ND
ug/L
5.0
1
10/20/22 14:41
10/2112214:52
W95-3
2-Nitrophenol
NO
ug/L
5.0
1
10120/2214:41
10/2112214:52
88-75-5
4-Nitrophenol
NO
ug/L
10.0
1
10/20/2214:41
10121/2214:52
100-02-7
N-Nitrosodimethylamine
ND
ug/L
5.0
1
10/2012214:41
10/21/2214:52
62-75-9
N-Nitroso-di-n-propylamine
ND
ug/L
5.0
1
10/2012214:41
10/21/2214:52
621-64-7
N-Nitrosodiphenylamine
NO
ug/L
10.0
1
10/2012214:41
10/21/2214:52
86-30-6
Pentachlorophenol
NO
ug/L
10.0
1
10/20/22 14:41
10/21/2214:52
87-86-5
Phenanthrene
NO
ug/L
5.0
1
10/20/22 14:41
10/21/2214:52
85-01-8
Phenol
NO
ug/L
5.0
1
10/20/22 14:41
10/21/2214:52
108-95-2
Pyrene
NO
ug/L
5.0
1
10/2012214:41
10/21/2214:52
129-00-0
2,4,6-Trichlorophenol
ND
ug/L
10.0
1
10/20/22 14:41
10/2112214:52
88-06-2
Surrogates
Nitrobenzene-d5 (S)
98
%
10-120
1
10/20/22 14:41
10/21/22 14:52
4165-60-0
2-Fluorobiphenyl (S)
71
%
15-120
1
10/20/22 14:41
10/21/22 14:52
321-6M
Terphenyl-d14 (S)
110
%
11-131
1
10/20/22 14:41
10/21/22 14:52
1718-51-0
Phenol-d6 (S)
42
%
10-120
1
10/20/22 14:41
10/21/22 14:52
13127-88-3
2-Fluorophenol (S)
55
%
10-120
1
10/20/22 14:41
10/21/22 14:52
367-12-4
2,4,6-Tribromophenol (S)
94
%
10-137
1
10/20/22 14:41
10/21122 14:52
118-79-6
624 Volatile Organics
Analytical Method: EPA 624.1
Pace Analytical Services - Charlotte
"---nlein
ND
ug/L
5.0
1
10/19/2217:35
107-02-8
REPORT OF LABORATORY ANALYSIS
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Date: C3/07/2023 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 31

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Project: ANNUAL TEST OCTOBER
Pace Project No.: 92630982
Sample: TOWN OF TARBORO
EFFLUENT
Parameters
624 Volatile Organics
Acrylonitrile
Benzene
Bro mod i ch I oro m ethan e
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethylvinyl ether
Chloroform
Chloromethane
Dibromochloromethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1 4-Dichlorobenzene
Dichloroethane
Dichloroethane
1,1-Dichloroethene
trans- 1, 2-Dichloroethene
1,2-Dichioropropane
cis- 1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachloro-1,3-butadiene
Methylene Chloride
Naphthalene
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichforofluoromethane
Vinyl chloride
Surrogates
4-Bromofluorobenzene (S)
Toluene-d8 (S)
1,2-Dichloroethane-04 (S)
2540C Total Dissolved Solids
Total Dissolved Solids
Date: 03/07/2023 04:58 PM
Pace Analytcal Services, LLC
9800 1<7incey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Lab ID: 92630982001 Collected: 10/13/22 08:00 Received: 10/13/22 11:50 Matrix: Water
Results Units Report Limit
Analytical Method: EPA 624.1
Pace Analytical
Services - Charlotte
NO
ug/L
5.0
NO
ug/L
1.0
ND
ug/L
2.0
NO
ug/L
2.0
ND
ug/L
2.0
ND
ug/L
2.0
ND
ug/L
2.0
NO
ug/L
2.0
ND
ug/L
5.0
3.4
ug/L
2.0
ND
ug/L
2.0
ND
ug/L
2.0
ND
ug/L
2.0
ND
ug/L
2.0
NO
ug/L
2.0
ND
ug/L
2.0
ND
ug/L
2.0
ND
ug/L
2.0
ND
ug/L
2.0
ND
ug/L
2.0
NO
ug/L
2.0
ND
ug/L
2.0
NO
ug/L
1.0
NO
ug/L
5.0
ND
ug/L
2.0
ND
ug/L
5.0
ND
ug/L
2.0
ND
ug/L
2.0
NO
ug/L
1.0
ND
ug/L
2-0
ND
ug/L
2.0
NO
ug/L
2.0
NO
ug/L
2.0
ND
ug/L
2.0
NO
ug/L
2.0
99 %
70-130
104 %
70-130
84 %
70-130
Analytical Method: SM 254OC-2015
Pace Analytical Services - Asheville
317 mg/L
DF Prepared
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
25.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, I.L.C.
Analyzed CAS No. Qual
10/19/22 17:35
107-13-1
10/19/22 17:35
71-43-2
10/1912217:35
75-27-4
10/19/22 17:35
75-25-2
10/19/22 17:35
74-83-9
1Oil 9/2217:35
56-23-5
10/19/22 17:35
108-90-7
10/19/22 17:35
75-00-3
10 / 19122 17:35
110-75-8
10/1912217:35
67-66-3
1011912217:35
74-87-3
10/19/22 17:35
124-48-1
10/19/22 17:35
95-50-1
1011912217:35
541-73-1
10/19/22 17:35
106-46-7
1011912217:35
75-34-3
10/19/22 17:35
107-06-2
1011912217:35
75-35-4
10/19/22 17:35
156-60-5
10/l9/2217:35
78-87-5
10/19/22 17:35
10061-01-5
10/19/22 17:35
10061-02-6
10/ 19122 17:35
100-41- 4
10/19/2217:35
87-68-3
10/1912217-35
75-09-2
10/1912217:35
91-20-3
10/19/2217:35
79-34-5
10/ 19122 17:35
127-184
10/19/22 1735
108-88-3
10/19/22 17:35
120-62-1
10/19/22 17:35
71-55-6
10/19/22 17:35
79-00-5
10/19/22 17:35
79-01-6
10/1912217:35
75-69-4
10119/2217:35
75-01-4
10119/2217:35 460-00-4
10/19/22 17:35 2037-26-5
10/19/22 17:35 17060-07-0
10/17/22 11:12
J(L1)
J(L1)
Page 6 of 31

aceAnalytical
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ANALYTICAL RESULTS
Project: ANNUAL TEST OCTOBER
Pace Project No.: 92630982
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: TOWN OF TARBORO Lab ID: 92630982001 Collected: 10/13/22 08:00 Received: 10/13/22 11:50 Matrix: Water
EFFLUENT
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Total Nitrogen Calculation
Analytical Method: TKN+NO3+NO2 Calculation
Pace Analytical Services - Asheville
Total Nitrogen
16.6 mg/L 0.040 1 10/21/22 21 A 5
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, Ammonia
0.13 mg/L 0.10 1 10/18/22 16:44 7664-41-7
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 3512 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, Kjeldahl, Total
1.5 mg/L 0.50 1 10/19/22 20:09 10/20/22 07:28 7727-37-9
353.2 Nitrogen, NO2/NC3 pros.
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, NO2 plus NO3
15.2 mg/L 0.24 6 10/21/22 14:14
aar 1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
1.9 mg/L 0.050 1 10/2512215:10 10/2512218:49 7723-14-0
420.4 Phenolics, Total
Analytical Method: EPA 420.4 Rev 1.0 1993 Preparation Method: EPA 420.4 Rev 1.0 1993
Pace Analytical Services - Asheville
Phenolics, Total Recoverable
ND mg/L 0.020 1 10/17/22 12:25 10/19/22 08:57 64743-03-9
450OCNE Cyanide, Total
Analytical Method: SM 4500-CN-E-2016 Preparation Method: SM 4500-CN-E-2016
Pace Analytical Services - Asheville
Cyanide
ND mg/L 0.0080 1 10/24/22 17:12 10/24/22 20:28 57-12-5
Sample: LLHG BLANK Lab ID: 92630982002 Collected: 10/13/22 08:00 Received: 10/13/22 11:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1631E Mercury,Low Level Analytical Method: EPA 1631E Preparation Method: EPA 1631 E
Pace Analytical Services - Asheville
Mercury ND ng/L 0.50 1 10/27/2210:00 11117/2213:47 7439-97-6
Date: 03/07/2023 04:58 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full:
without the written consent of Pace Analytical Services, LLC.
Page 7 of 31

aceAnalytical x
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QUALITY CONTROL DATA
Project: ANNUAL TEST OCTOBER
Pace Project No.: 92630982
QC Batch: 732231 Analysis Method: EPA 1664B
QC Batch Method: EPA 1664E Analysis Description: 1664 HEM, Oil and Grease
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92630982001
METHOD BLANK: 3811501
Associated Lab Samples: 92630982001
Parameter Units
Oil and Grease mg/L
LABORATORY CONTROL SAMPLE: 3811502
Parameter Units
Oil and Grease mg/L
Pace Analytical Services, LLC
9800 Kincey Ave, Suite 100
Hunterswlle, NC 28078
(704)8759092
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 5.0 10/24/22 04:34
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
40 35.0 88 78-114
MATRIX SPIKE SAMPLE:
Parameter
3811503
Units
92631594002
Result
Spike MS MS % Rec
Conc. Result % Rec Limits Qualifiers
and Grease
mg/L
ND
39.4 32.6 80 78-114
SAMPLE DUPLICATE: 3811504
92631560002
Dup
Parameter
Units
Result
Result RPD Qualifiers
Oil and Grease
mg/L
7.1
7.7 8
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 03/07/2023 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 31

�oeAnalytical'
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Project: ANNUAL TEST OCTOBER
Pace Project No.: 92630982
QC Batch: 737421
QC Batch Method: EPA 1631 E
Associated Lab Samples: 92630982001, 92630982002
METHOD BLANK: 3837648
Associated Lab Samples: 92630982001, 92630982002
Parameter Units
Mercury ng/L
METHOD BLANK: 3837649
Associated Lab Samples: 92630982001, 92630982002
Parameter Units
Mercury ng/L
QUALITY CONTROL DATA
Analysis Method: EPA 1631E
Analysis Description: 1631 E Mercury,Low Level
Laboratory: Pace Analytical Services - Asheville
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.50 11/1712213:08
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.50 11/17/2214:14
_THOD BLANK: 3837650 Matrix: Water
—sociated Lab Samples: 92630982001, 92630982002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 11/17/2216:18
Pace Analytical Services, LLC
9600 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 3837651
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury
ng/L 5 4.68 94 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3837652 3837653
MS MSD
36752362001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua[
Mercury ng/L 0.00062 25 25 18.6 20.3 72 79 71-125 9
2 ug/L
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3837654 MS MSD 3837655
92631292001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result % Rec %Rec Limits RPD Qual
23.0 23.7 82 85 71-125 3
Mercury ng/L 2.55 25 25
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/07/2023 04:58 PM without the written consent of Pace Analytical Services, LLC.
Page 9 of 31

/�I,aceAnalXical'
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QUALITY CONTROL DATA
Project: ANNUAL TEST OCTOBER
Pace Project No.: 92630982
QC Batch: 732522 Analysis Method: EPA 200.7 Rev 4.4 1994
QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92630982001
METHOD BLANK: 3812905
Associated Lab Samples: 92630982001
Parameter
Units
Matrix: Water
Blank Reporting
Result Limit
Analyzed
Antimony
ug/L
NO
5.0
1012812217:55
Arsenic
ug/L
ND
10.0
10/2812217:55
Beryllium
ug/L
NO
1.0
10/28/2217:55
Cadmium
ug/L
NO
1.0
10/28/2217:55
Calcium
ug/L
NO
100
10/2812217:55
Chromium
ug/L
ND
5.0
10/28/2217:55
Copper
ug/L
ND
5.0
10/2812217:55
Hardness, Total(SM 2340B)
ug/L
NO
662
10/28/22 17:55
Lead
ug/L
NO
5.0
10/2812217:55
Magnesium
ug1L
NO
100
1012812217:55
Nickel
ug/L
ND
5.0
10/28/2217:55
G-lenium
ug/L
NO
10.0
10128/2217.55
ver
ug/L
ND
5.0
10/28/221T55
ug/L
NO
10.0
10128/2217:55
...allium
Zinc
ug/L
NO
10.0
10/2812217:55
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
3812906
Units
Spike
Conc.
LCS
Result
LCS
% Rec
%Rec
Limits
Antimony
ug/L
500
497
99
85-115
Arsenic
ug/L
500
495
99
85-115
Beryllium
ug/L
500
504
101
85-115
Cadmium
ug/L
500
503
101
85-115
Calcium
ug/L
5000
5080
102
85-115
Chromium
ug/L
500
509
102
85-115
Copper
ug/L
500
508
102
85-115
Hardness, Total(SM 2340B)
ug/L
33100
33100
100
85-115
Lead
ug/L
500
509
102
85-115
Magnesium
ug/L
5000
4950
99
85-115
Nickel
ug/L
500
509
102
85-115
Selenium
ug/L
500
496
99
85-115
Silver
ug/L
250
240
96
85-115
ug/L
500
501
100
85-115
Thallium
ug/L
500
487
97
85-115
Zinc
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)87 -9092
Qualifiers
Results presented on this page are In the units Indlcated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/0712023 04:58 PM without the written consent of Pace Analytical Services, LLC.
Page 10 of 31

aceAnalytical
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Project: ANNUAL TEST OCTOBER
Pace Project No.: 92630982
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
Parameter
Antimony
Arsenic
Beryllium
Cadmium
Calcium
Chromium
Copper
Hardness, Total(SM 2340B)
Lead
Magnesium
Nickel
Selenium
Silver
Thallium
Zinc
QUALITY CONTROL DATA
3812907
MS
92630395001 Spike
Units Result Conc.
ug/L ND 500
ug/L ND 500
ug/L ND 500
ug/L ND 500
ug/L 5390 5000
ug/L ND 500
ug/L ND 500
ug/L 23700 33100
ug/L ND 500
ug/L 2490 5000
ug/L ND 500
ug/L ND 500
ug/L ND 250
ug/L ND 500
ug/L 0.020 500
mg/L
. „ATRIX SPIKE & MATRIX SPIKE DUPLICATE:
Parameter
Antimony
Arsenic
Beryllium
Cadmium
Calcium
Chromium
Copper
Hardness, Total(SM 234013)
Lead
Magnesium
Nickel
Selenium
Silver
Thallium
Zinc
3812909
MS
92630968003 Spike
Units Result Conc.
ug/L ND 500
ug/L ND 500
ug/L ND 500
ug/L ND 500
ug/L 7450 5000
ug/L 142 500
ug/L 38.9 500
ug/L 28100 33100
ug/L 24.7 500
ug/L 2310 5000
ug/L 318 500
ug/L ND 500
ug/L ND 250
ug(L ND 500
ug/L 223 500
MSD
Spike
Conc.
500
500
500
500
5000
500
500
33100
500
5000
500
500
250
500
500
3812908
MS
Result
506
494
521
515
10500
521
516
56800
512
7440
517
521
245
481
521
Pace Analytical Services, LLC
9800 Kncey Ave. Suite 100
Hunlersville, NC 28078
(704)8759092
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
506
101
101
70-130
0
497
99
99
70-130
1
523
104
105
70-130
0
517
103
103
70-130
0
10500
101
102
70-130
0
524
104
105
70-130
1
517
103
103
70-130
0
57000
100
101
70-130
1
515
102
103
70-130
1
7490
99
100
70-130
1
519
103
104
70-130
0
525
104
105
70-130
1
247
98
99
70-130
1
484
96
97
70-130
1
521
100
100
70-130
0
3812910
MSD
Spike
MS
MSD
MS
Conc.
Result
Result
% Rec
500
526
521
105
500
539
528
106
500
530
524
106
500
518
512
103
5000
12600
12700
104
500
666
664
105
500
583
579
109
33100
62200
61100
103
500
545
540
104
5000
7450
7170
103
500
839
842
104
500
545
538
108
250
249
245
100
500
388
382
78
500
729
721
101
MSD % Rec
% Rec Limits
104 70-130
104 70-130
105 70-130
102 70-130
104 70-130
104 70-130
108 70-130
100 70-130
103 70-130
97 70-130
105 70-130
106 70-130
98 70-130
76 70-130
100 70-130
Qual
RPD Qual
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 03/07/2023 04:58 PM without the written consent of Pace Analytical Services, LLC.
1
2
1
1
0
0
1
2
1
4
0
1
2
2
1
Page 11 of 31

I WkeAnalXical'
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Project: ANNUAL TEST OCTOBER
Pace Project No.: 92630982
QC Batch: 731364
QC Batch Method: EPA624.1
Associated Lab Samples: 92630982001
QUALITY CONTROL DATA
Analysis Method: EPA 624.1
Analysis Description: 624 MSV
Laboratory: Pace Analytical Services - Charlotte
METHOD BLANK: 3807482
Matrix: Water
Associated Lab Samples: 92630982001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
1,1,1-Trichloroethane
ug/L
ND
2.0
10/19/22 14:16
1,1,2,2-Tetrachloroethane
ug/L
ND
2.0
10119/2214:16
1,1,2-Trichloroethane
ug/L
ND
2.0
10/1912214:16
1,1-Dichloroethane
ug/L
ND
2.0
10119/2214:16
1,1-Dichloroethene
ug/L
ND
2.0
10/19/22 14:16
1,2,4-Trichlorobenzene
ug/L
ND
2.0
10/19/22 14:16
1,2-Dichlorobenzene
ug/L
ND
2.0
10/19/22 14:16
1,2-Dichloroethane
ug/L
ND
2.0
10/19/22 14:16
1,2-Dichloropropane
ug/L
ND
2.0
10/19/22 14:16
1,3-Dichlorobenzene
ug/L
ND
2.0
10/19/22 14:16
1,4-Dichlorobenzene
ug/L
ND
2.0
10/19/22 14:16
"-loroethylvinyl ether
ug/L
ND
5.0
10/19/22 14:16
lein
ug/L
ND
5.0
10119/2214:16
,,,onitrile
ug/L
ND
5.0
10/19/22 14:16
Benzene
ug/L
ND
1.0
10/19/22 14:16
Bromodichloromethane
ug/L
ND
2.0
10/19/22 14:16
Bromoform
ug/L
ND
2.0
10/19/22 14:16
Bromomethane
ug/L
ND
2.0
10119/2214:16
Carbon tetrachloride
ug/L
ND
2.0
10/19/22 14:16
Chlorobenzene
ug/L
ND
2.0
10/19/22 14:16
Chloroethane
ug/L
ND
2.0
10/1912214:16
Chloroform
ug/L
ND
2.0
10/19/22 14:16
Chloromethane
ug/L
ND
2.0
10/1 g122 14:16
cis-1,3-Dichloropropene
ug/L
ND
2.0
10/19/22 14:16
Dibromochloromethane
ug/L
ND
2.0
10/19/22 14:16
Ethylbenzene
ug/L
ND
1.0
10/19/22 14:16
Hexachloro-1,3-butadiene
ug/L
ND
5.0
10119/2214:16
Methylene Chloride
ug/L
ND
2.0
10/19/22 14:16
Naphthalene
ug/L
ND
5.0
10/19/22 14:16
Tetrachloroethene
ug/L
ND
2.0
10/19/22 14:16
Toluene
ug/L
ND
1.0
10/19/22 14:16
trans-1,2-Dichloroethene
ug/L
ND
2.0
10/19/22 14:16
trans-1,3-Dichloropropene
ug/L
ND
2.0
10/19/22 14:16
Trichloroethene
ug/L
ND
2.0
10/1912214:16
Trichlorofluoromethane
ug/L
ND
2.0
10/1912214:16
Vinyl chloride
ug/L
ND
2.0
10/19/22 14:16
1,2-Dichloroethane-d4 (S)
%
84
70-130
10/19/22 14:16
4-Bromofluorobenzene (S)
%
99
70-130
10/19/22 14:16
Toluene-d8 (S)
%
105
70-130
10/19/22 14:16
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/07/2023 04:58 PM without the written consent of Pace Analytical Services, LLC
Page 12 of 31

aceAnalXical
www.pacelabs.com
QUALITY CONTROL DATA
Project: ANNUAL TEST OCTOBER
Pace Project No.. 92630982
Pace Analytical Services, LLC
9800 Kinsey Ave. Suite 100
Huntersvgle, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
Parameter
3807483
Units
Spike
Conc.
LCS
Result
LCS
% Rec
%Rec
Limits Qualifiers
1,1,1-Trichloroethane
ug/L
20
16.8
84
92
70-130
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
18.4
93
70-130
1,1,2-Trichloroethane
ug/L
20
18.7
17.2
86
70-130
1,1-Dichloroethane
ug/L
20
20
17.0
85
70-130
1,1-Dichloroethene
ug/L
20
19.9
99
70-130
1,2,4-Trichlorobenzene
ug/L
20
19.9
99
70-130
1,2-Dichlorobenzene
ug/L
20
16.0
80
70-130
1,2-Dichloroethane
ug/L
ug/L
20
18.6
93
70-130
1,2-Dichloropropane
ug/L
20
19.5
97
70-130
1,3-Dichlorobenzene
20
19.2
96
70-130
1,4-Dichlorobenzene
ug/L
40
38.4
96
63-130
2-Chloroethylvinyl ether
ug/L
82.1
82
60-140
Acrolein
ug/L
ug/L
100
100
89.6
90
70-130
Acrylonitrile
ug/L
20
17.6
88
70-130
Benzene
ug/L
20
17.5
87
70-130
Bromodichloromethane
20
18.4
92
70-130
Bromoform
ug/L
ug/L
20
19.5
97
45-151
-nmomethane
ug/L
20
17.5
87
70-130
rbon tetrachloride
20
19.5
97
70-130
_ lorobenzene
ug/L
ug/L
20
25.0
25
1�
40-152
Chloroethane
ug/L
20
16.9
70-130
Chloroform
ug/L
20
27.2
184
58-130 J(L1)
Chioromethane
ug/L
20
17.1
86
70-130
cis- 1,3-Dichloropropene
20
18.1
90
70-130
Dibromochloromethane
ug/L
20
18.7
93
70-130
Ethylbenzene
ug/L
ug/L
20
21.7
1
-13
Hexachloro-1,3-butadiene
20
16.2
81
66-130
Methylene Chloride
ug/L
20
19.1
95
70-130
Naphthalene
ug/L
20
19.4
97
70-130
Tetrachloroethene
uglL
20
17.9
89
70-130
Toluene
ug/L
ug/L
20
17.5
88
70-130
trans-1,2-Dichloroethene
20
17.2
86
70-130
trans-1,3-Dichloropropene
ug/L
20
19.4
97
70-130
Trichloroethene
ug/L
ug/L
20
23.9
144
62-130
Trichlorofluoromethane
ZO
28.
1
62-130 J(L1)
Vinyl chloride
ug/L
85
70-130
1,2-Dichloroethane-d4 (S)
100
70-130
4-Bromofluorobenzene (S)
97
70-130
Toluene-d8 (S)
%
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3807484 MS MSD
92630207002 Spike Spike MS
Units Result Conc_ Conc. Result
ug/L ND 200 200 201
Parameter
1,1,1-Trichi oroethane
3807485
MSD MS MSD % Rec
Result % Rec % Rec Limits RPD Qual
203 101 102 70-150 1
Results presented on this page are in the units Indicated by the -Unhs" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shag not be reproduced. except in full,
Date: 03/07/2023 04:58 PM without the written consent of Pace Analytical Services, LLC.
Page 13 of 31

117WaceAnalyfical'
www.pacelabs.com
QUALITY CONTROL DATA
Project: ANNUAL TEST OCTOBER
Pace Project No.: 92630982
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3807484
MS
92630207002 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3807485
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD Qual
1,1,2,2-Tetrachloroethane
ug/L
ND
200
200
209
210
105
105
69-142
0
1,1,2-Trichloroethane
ug/L
NO
200
200
217
214
109
107
70-138
2
1,1-Dichloroethane
ug/L
NO
200
200
198
199
99
100
70-150
1
1,1-Dichloroethene
ug/L
NO
200
200
202
204
101
102
70-156
1
1,2,4-Trichlorobenzene
ug/L
NO
200
200
229
236
115
118
70-146
3
1,2-Dichlorobenzene
ug/L
ND
200
200
223
227
111
114
70-141
2
1,2-Dichloroethane
ug/L
ND
200
200
183
182
92
91
69-143
1
1,2-Dichloropropane
ug/L
NO
200
200
216
212
108
106
70-156
2
1,3-Dichlorobenzene
ug/L
ND
200
200
224
227
112
113
70-143
1
1,4-Dichlorobenzene
ug/L
ND
200
200
218
221
109
110
70-142
1
2-Chloroethylvinyl ether
ug/L
NO
400
400
ND
ND
0
0
10-200
J(P5)
Acrolein
ug/L
ND
1000
1000
987
993
99
99
40-160
1
Acrylonitrile
ug/L
ND
1000
1000
1050
1030
105
103
69-147
2
Benzene
ug/L
ND
200
200
203
202
102
101
70-142
1
Bromodichloromethane
ug/L
ND
200
200
202
199
101
100
70-139
1
Bromoform
ug/L
ND
200
200
198
197
99
99
64-140
0
Rromomethane
ug/L
ND
200
200
144
149
72
75
28-192
3
irbon tetrachloride
ug/L
NO
200
200
202
201
101
100
70-140
1
ilorobenzene
ug/L
ND
200
200
227
227
114
113
70-141
0
Chloroethane
ug/L
ND
200
200
185
187
92
93
58-191
1
Chloroform
ug/L
NO
200
200
204
202
99
98
70-138
1
Chloromethane
ug/L
ND
200
200
191
187
96
93
43-162
2
cis- 1,3-Dichloropropene
ug/L
ND
200
200
201
198
101
99
68-151
2
Dibromochloromethane
uglL
NO
200
200
199
200
100
100
70-144
0
Ethylbenzene
ug/L
ND
200
200
219
223
110
112
70-143
2
Hexachloro-1,3-butadiene
uglL
ND
200
200
280
290
140
145
64-163
4
Methylene Chloride
ug/L
ND
200
200
196
195
90
89
70-144
1
Naphthalene
ug/L
ND
200
200
220
224
110
112
62-149
2
Tetrachloroethene
ug/L
NO
200
200
226
226
113
113
70-143
0
Toluene
ug/L
NO
200
200
211
211
105
105
60-14-4
0
trans- 1,2-Dichloroethene
ug/L
ND
200
200
210
209
105
104
70-151
1
trans-1,3-Dichloropropene
ug/L
ND
200
200
190
196
95
98
70-139
3
Trichloroethene
ug/L
ND
200
200
227
225
114
113
70-142
1
Trichlorofluoromethane
ug/L
ND
200
200
164
166
82
83
62-146
1
Vinyl chloride
ug/L
ND
200
200
211
214
106
107
61-162
1
1,2-Dichloroethane-d4 (S)
%
88
84
70-130
4-Bromofluorobenzene (S)
%
100
100
70-130
Toluene-d8 (S)
%
98
97
70-130
Results presented on this page are In the units Indicated by the "Units' column except where an alternate unit Is presented to the right of the resutL
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/07/2023 04:58 PM without the written consent of Pace Analytical Services, LLC.
Page 14 of 31

1�;a'ceAnalyfical-
www.pactiabs.com
Project:
ANNUAL TEST OCTOBER
Pace Project No.:
92630982
QC Batch:
731589
QC Batch Method:
EPA 625.1
Associated Lab Samples: 92630982001
QUALITY CONTROL DATA
Analysis Method: EPA 625.1
Analysis Description: 625 MSS
Laboratory: Pace Analytical Services - Charlotte
METHOD BLANK: 3808536
Associated Lab Samples: 92630982001
Parameter
Units
Matrix: Water
Blank Reporting
Result Limit
Analyzed
1,2-Dichlorobenzene
ug/L
ND
5.0
10/20/2218:05
1,2-Diphenylhydrazine
ug/L
ND
5.0
10/20/2218:05
1,3-Dichlorobenzene
ug/L
ND
5.0
10/20/2218:05
1,4-Dichlorobenzene
ug/L
ND
5.0
10/20/2218:05
2,4,6-Trichiorophenol
ug/L
NO
10.0
10/20/2218:05
2,4-Dichlorophenol
ug/L
NO
5.0
10/2012218:05
2,4-Dimethylphenol
ug/L
ND
10.0
10/20/2218:05
2,4-Dinitrophenol
ug/L
NO
50.0
10/20/2218:05
2,4-Dinitrotoluene
ug/L
NO
5.0
10/20/2218:05
2,6-Dinitrotoluene
ug/L
NO
5.0
10/20/2218:05
2-Chloronaphthalene
ug/L
ND
5.0
10/20/2218:05
-hlorophenol
ug/L
NO
5.0
10/2012218:05
itrophenol
ug/L
NO
5.0
10/2012218:05
:3,:3,-Dichlorobenzidine
ug/L
ND
10.0
1012012218:05
4,6-Dinitro-2-methyl phenol
ug/L
NO
10.0
10/20/2218:05
4-Bromophenylphenyl ether
ug/L
NO
5.0
10/20/22 18:05
4-Chloro-3-methylphenol
ug/L
NO
5.0
10/2012218:05
4-Chlorophenylphenyl ether
ug/L
NO
5.0
10/20122 18:05
4-Nitrophenol
ug/L
NO
10.0
1012012218:05
Acenaphthene
ug/L
NO
5.0
10120/2218:05
Acenaphthylene
ug/L
NO
5.0
10120/2218:05
Anthracene
ug/L
NO
5.0
10/20/2218:05
Benzo(a)anthracene
ug/L
ND
5.0
10/20/2218:05
Benzo(a)pyrene
ug/L
NO
5.0
10/20/2218:05
Benzo(b)fluoranthene
ug/L
NO
5.0
10/20/2218:05
Benzo(g,h,i)perylene
ug/L
NO
5.0
10/20/2218:05
Senzo(k)fluoranthene
ug/L
ND
5.0
10120/2218:05
bis(2-Chloroethoxy)methane
ug/L
ND
10.0
10/2012218:05
bis(2-Chloroethyl) ether
ug/L
NO
5.0
10/20/22 18:05
bis(2-Ethylhexyl)phthalate
ug/L
ND
5.0
10/20t2218:05
Butylbenzylphthalate
ug/L
NO
5.0
10/20Y2218:05
Chrysene
ug/L
ND
5.0
10/2012218:05
Di-n-butylphthalate
ug/L
NO
5.0
10/20/2218:05
Di-n-octylphthalate
ug/L
NO
5.0
1012012218:05
Dibenz(a,h)anthracene
ug/L
ND
5.0
10120/2218:05
Diethylphthalate
ug/L
ND
5.0
10/2012218:05
Dimethylphthalate
ug/L
NO
5.0
10120/2218:05
Fluoranthene
ug/L
ND
5.0
10/20/2218:05
Fluorene
ug/L
NO
5.0
10/20/2218:05
Hexachlorobenzene
ug/L
NO
5.0
10/20/2218:05
Qualifiers
Pace Analytical Services, LLC
9800 Kncey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units indicated by the "Units' column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/07/2023 04:58 PM without the written consent of Pace Analytical Services, LLC.
Page 15 of 31

Pace Analytical Services, LLC
aceAnalytical �i 9800 Kinsey Ave. Suite100
Huntersviile, NC 28078078
www.pacolabs.ctall
p04t875-9092
QUALITY CONTROL DATA
Project: ANNUAL TEST OCTOBER
Pace Project No.: 92630982
METHOD BLANK: 3808536
Associated Lab Samples: 92630982001
Parameter
Units
Matrix: Water
Blank Reporting
Result Limit
Analyzed Qualifiers
Hexachlorocyclopentadiene
ug/L
ND
10.0
10/20/2218:05
Hexachloroethane
ug/L
ND
5.0
10/20/2218:05
Indeno(1,2,3-W)pyrene
ug/L
ND
5.0
10/20/2218:05
Isophorone
ug/L
ND
10.0
10/20/2218:05
N-Nitroso-di-n-propylamine
ug/L
ND
5.0
10/20/2218:05
N-Nitrosodimethylamine
ug/L
ND
5.0
10/2012218:05
N-Nitrosodiphenylamine
ug/L
ND
10.0
10/20/2218:05
Naphthalene
ug/L
ND
5.0
10/20/2218:05
Nitrobenzene
ug/L
ND
5.0
10/20/2218:05
Pentachlorophenol
ug/L
ND
10.0
10/20/2218:05
Phenanthrene
ug/L
ND
5.0
1012012218:05
Phenol
ug/L
ND
5.0
10/20/2218:05
Pyrene
ug/L
ND
5.0
10/20/2218:05
2,4,6-Tribromophenol (S)
%
107
10-137
10/20/22 18:05
2-Fluorobiphenyl (S)
%
73
15-120
10/20/22 18:05
2-Fluorophenol (S)
%
73
10-120
10/20/22 18:05
nlitrobenzene-d5 (S)
%
101
10-120
10/20/22 18:05
:not-d6 (S)
%
57
10-120
10/20/22 18:05
.-.ahenyl-dl4 (S)
%
116
11-131
10/20122 18:05
LABORATORY CONTROL SAMPLE:
Parameter
3808537
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,2-Dichlorobenzene
ug/L
50
38.0
76
32-129
1,2-Diphenylhydrazine
ug/L
50
49.5
99
25-150
1,3-Dichlorobenzene
ug/L
50
35.2
70
1-172
1,4-Dichlorobenzene
ug/L
50
35.9
72
20-124
2,4,6-Tdchlorophenol
ug/L
50
46.0
92
37-144
2,4-Dichlorophenol
ug/L
50
47.7
95
1-191
2,4-Dimethylphenol
ug/L
50
63.3
127
32-119 J(L1)
2,4-Dinitrophenol
ug/L
250
161
64
1-181
2,4-Dinitrotoluene
ug/L
50
61.2
122
39-139
2,6-Dinitrotoluene
ug/L
50
57.4
115
50-158
2-Chloronaphthalene
ug/L
50
47.8
96
60-118
2-Chlorophenol
ug/L
50
43.0
86
23-134
2-Nitrophenol
ug/L
50
51.7
103
29-182
3,3'-Dichlorobenzidine
ug/L
100
110
110
1-262
4,6-Dinitro-2-methylphenol
ug/L
100
93.2
93
1-181
4-Bromophenylphenyl ether
ug/L
50
46.3
93
53-127
4-Chloro-3-methylphenol
ug/L
100
99.9
100
22-147
4-Chlorophenylphenyl ether
ug/L
50
48.2
96
25-158
4-Nitrophenol
ug/L
250
128
51
1-132
Acenaphthene
ug/L
50
47.6
95
47-145
Acenaphthylene
ug/L
50
46.7
93
33-145
Results presented on this page are in the units Indicated by the -Unhs- column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/07/2023 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 31

�ca eAnal ical
www.pacelah.com
QUALITY CONTROL DATA
Project: ANNUAL TEST OCTOBER
Pace Project No.: 92630982
Pace Analytical Services, LLC
9800 IGncey Ave. Suite 100
HuntersviNe, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
Parameter
3808537
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Anthracene
ug/L
50
43.1
86
1-166
Benzo(a)anthracene
ug/L
50
48.2
96
33-143
Benzo(a)pyrene
ug/L
50
50.0
100
17-163
Benzo(b)fluoranthene
ug/L
50
50.7
101
24-159
Benzo(g,hJ)perylene
ug/L
50
54.0
108
1-219
Benzo(k)fluoranthene
ug/L
50
48.4
97
11-162
bis(2-Chloroethoxy)methane
ug/L
50
47.5
95
33-184
bis(2-Chloroethyl) ether
ug/L
50
44.8
90
12-158
bis(2-Ethylhexyl)phthalate
ug/L
50
56.5
113
8-158
Butylbenzylphthalate
ug/L
50
57.9
116
1-152
Chrysene
ug/L
50
47.7
95
17-168
Di-n-butylphthalate
ug/L
50
57.3
115
1-118
Di-n-octylphthalate
ug/L
50
64.9
130
4-146
Dibenz(a,h)anthrace ne
ug/L
50
52.8
106
1-227
Diethylphthalate
ug/L
50
54.3
109
1-114
Dimethylphthalate
ug/L
50
51.7
103
1-112
Fluoranthene
ug/L
50
54.3
109
26-137
Fluorene
ug/L
50
49.3
99
59-121
(achlorobenzene
ug/L
50
45.9
92
1-152
(achlorocyclopentadiene
ug/L
50
47.1
94
25-150
Hexachloroethane
ug/L
50
36.0
72
40-113
Indeno(1,2,3-cd)pyrene
ug/L
50
55.4
111
1-171
Isophorone
ug/L
50
49.6
99
21-196
N-Nitroso-di-n-propylamine
ug/L
50
49.4
99
1-230
N-Nitrosodimethylamine
ug/L
50
41.5
83
25-150
N-Nitrosodiphenylamine
ug/L
50
47.8
96
25-150
Naphthalene
ug/L
50
42.1
84
21-133
Nitrobenzene
ug/L
50
50.4
101
35-180
Pentachlorophenol
ug/L
100
66.4
66
14-176
Phenanthrene
ug/L
50
48.4
97
54-120
Phenol
ug/L
50
30.6
61
5-112
Pyrene
ug/L
50
44.1
88
52-115
2,4,6-Tribromophenol (S)
%
99
10-137
2-Fluorobiphenyl (S)
%
91
15-120
2-Fluorophenol(S)
%
69
10-120
Nitrobenzene-d5(S)
%
102
10-120
Phenol-d6 (S)
%
59
10-120
Terphenyl-d14 (S)
%
98
11-131
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3808538
3808539
MS
MSD
35753351001 Spike
Spike MS
MSD
MS MSD % Rec
Parameter
Units
Result Conc.
Conc. Result
Result
% Rec % Rec Limits RPD Qual
1,2-Dichlorobenzene
ug/L
1.8U 50
50 6.9
6.1
14 12 32-129 12 J(M1)
1,2-Diphenylhydrazine
ug/L
1.6U 50
50 41.3
44.8
83 90 25-150 8
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/07/2023 04:58 PM without the written consent of Pace Analytical Services, L.L.C.
Page 17 of 31

,11',;keAnal ical Y
www.pacoiab3.com
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)8759092
Project: ANNUAL TEST OCTOBER
Pace Project No.: 92630982
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3808538
3808539
MS
MSD
35753351001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits RPD Qual
1,3-Dichlorobenzene
ug/L
1.6U
50
50
5.4
4.91
11
10
1-172
1,4-Dichlorobenzene
ug/L
1.7U
50
50
6.0
5.6
12
11
20-124
7 J(M1)
2,4,6-Trichlorophenol
ug/L
1.6U
50
50
36.4
42.1
73
84
37-144
15
2,4-Dichlorophenol
ug/L
1AU
50
50
32.8
38.2
66
76
1-191
15
2,4-Dimethylphenol
ug/L
1.71-1
50
50
48.5
52.1
97
104
32-119
7
2,4-Dinitrophenol
ug/L
26.OU
250
250
112
226
45
90
1-181
68 J(R1)
2,4-Dinitrotoluene
ug/L
1.6U
50
50
51.6
56.4
103
113
39-139
9
2,6-Dinitrotoluene
ug/L
1.7U
50
50
46.7
53.5
93
107
50-158
14
2-Chloronaphthalene
ug/L
1.7U
50
50
29.2
33.9
58
68
60-118
15 J(M1)
2-Chlorophenol
ug/L
1.2U
50
50
27.9
30.8
56
62
23-134
10
2-Nitrophenol
ug/L
1.41-1
50
50
33.8
36.0
68
72
29-182
6
3,3'-Dichlorobenzidine
ug/L
8.1U
100
100
93.5
98.6
94
99
1-262
5
4,6-Dinitro-2-methylphenol
ug/L
7-8U
100
100
72.0
106
72
106
1-181
39 J(R1)
4-Bromophenylphenyl ether
ug/L
1.8U
50
50
37.0
41.5
74
83
53-127
11
4-Chloro-3-methylphenol
ug/L
3.3U
100
100
78.6
86.5
79
87
22-147
10
4-Chlorophenylphenyl ether
ug/L
2.OU
50
50
38.1
43.8
76
88
25-158
14
4-Nitrophenol
ug/L
6.6U
250
250
77.1
142
31
57
1-132
60 J(R1)
Acenaphthene
ug/L
2.OU
50
50
34.5
39.1
69
78
47-145
12
;naphthylene
ug/L
2.OU
50
50
34.2
38.4
68
77
33-145
12
hracene
ug/L
2.3U
50
50
35.7
39.9
71
80
1-166
11
Benzo(a)anthracene
ug/L
2.7U
50
50
42.1
45.3
84
91
33-143
7
Benzo(a)pyrene
ug/L
2.81J
50
50
41.7
43.4
83
87
17-163
4
Benzo(b)fluoranthene
ug/L
2.6U
50
50
41.5
43.9
83
88
24-159
6
Benzo(g,h,i)perylene
ug/L
2.8U
50
50
44.8
46.1
90
92
1-219
3
Benzo(k)fluoranthene
ug/L
2.71.1
50
50
41.7
42.7
83
85
11-162
2
bis(2-Chloroethoxy)methane
ug/L
1.8U
50
50
31.7
34.1
63
68
33-184
7
bis(2-Chloroethyl) ether
ug/L
1.9U
50
50
29.4
31.5
59
63
12-158
7
bis(2-Ethylhexyl)phthalate
ug/L
3.7U
50
50
50.8
54.7
102
109
8-158
7
Butylbenzylphthalate
ug/L
3.1U
50
50
49.6
56.3
99
113
1-152
13
Chrysene
ug/L
2.8U
50
50
41.6
45.6
83
91
17-168
9
Di-n-butylphthalate
ug/L
2.21-1
50
50
49.2
53.8
98
108
1-118
9
Di-n-octylphthalate
ug/L
3.9U
50
50
56.8
62.2
114
124
4-146
9
Dibenz(a,h)anthracene
ug/L
3.OU
50
50
43.1
45.3
86
91
1-227
5
Diethylphthalate
ug/L
2.OU
50
50
46.0
50.2
92
100
1-114
9
Dimethylphthalate
ug/L
2.1U
50
50
43.0
48.4
86
97
1-112
12
Fluoranthene
ug/L
2.2U
50
50
45.9
50.2
92
100
26-137
9
Fluorene
ug/L
2.1 U
50
50
38.9
44.7
78
89
59-121
14
Hexachlorobenzene
ug/L
2.2U
50
50
40.8
44.5
82
89
1-152
9
Hexachlorocyclopentadiene
ug/L
1.6U
50
50
11.4
15.0
23
30
25-150
28 J(M1)
Hexachloroethane
ug/L
1.4U
50
50
2.81
2.81
6
6
40-113
J(M1)
Indeno(1,2,3-cd)pyrene
ug/L
2.9U
50
50
46.3
47.6
93
95
1-171
3
Isophorone
ug/L
1.7U
50
50
35.8
39.3
72
79
21-196
9
N-Nitroso-di-n-propylamine
ug/L
1.3U
50
50
34.3
39.3
69
79
1-230
13
N-Nitrosodimethylamine
ug/L
1.9U
50
50
27.5
32.9
55
66
25-150
18
N-Nitrosodiphenylamine
ug/L
3.OU
50
50
39.7
43.7
79
87
25-150
10
Naphthalene
ug/L
2.11U
50
50
13.9
15.0
28
30
21-133
7
Results presented on this page are In the units Indicated by the "Units" column
except where an ottemate unit is presented to the right of the resuh_
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 03/07/2023 04:58 PM without the written consent of Pace Analytical Services, LLC- Page 18 of 31

lace A nalyfical
www.pacwabs.com
QUALITY CONTROL DATA
Project: ANNUAL TEST OCTOBER
Pace Project No.: 92630982
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3808538
MS
35753351001
Spike
Parameter
Units
Result
Conc.
Nitrobenzene
ug/L
1.9U
50
Pentachlorophenol
ug/L
3.61-11
100
Phenanthrene
ug/L
2.OU
50
Phenol
ug/L
1.41-1
50
Pyrene
ug/L
2.21.1
50
2,4,6-Tdbromophenol (S)
%
2-Fluorobiphenyl (S)
%
2-Fluorophenol(S)
%
Nitrobenzene-d5 (S)
%
Phenol-d6 (S)
%
Terphenyl-il4 (S)
%
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersvilie, NC 28078
[phone]
3808539
MSD
Spike
MS
MSD
MS
MSD
% Rec
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
50
31.0
32.0
62
64
35-180
3
100
63.2
87.6
63
88
14-176
32 J(R1)
50
41.7
44.3
83
89
54-120
6
50
20.5
26.0
41
52
5-112
24
50
37.2
41.5
74
83
52-115
11
84
97
10-137
50
47
15-120
42
50
10-120
65
63
10-120
38
48
10-120
83
91
11-131
Results presented on this page are In the units Indicated by the "units" column except where an altenune unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/07/2023 04:58 PM without the written consent of Pace Analytical Services, LLC.
Page 19 of 31

Pace Analytical Services, LLC
s
aceAnalytical
1 www.pecNabscola
9800 Kincey Ave. Suite 100
Huntersvilie, NC 28078
(704)8759092
QUALITY CONTROL DATA
Project: ANNUAL TEST OCTOBER
Pace Project No.: 92630982
QC Batch: 730596 Analysis Method: SM 254OC-2015
QC Batch Method: SM 254OC-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92630982001
METHOD BLANK: 3804003
Associated Lab Samples: 92630982001
Parameter Units
Total Dissolved Solids mg/L
LABORATORY CONTROL SAMPLE: 3804004
Parameter Units
Total Dissolved Solids mg/L
SAMPLE DUPLICATE: 3804005
Parameter Units
—tal Dissolved Solids mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 25.0 10/17/2211:11
Spike LCS
Conc. Result
251 256
92630978001 Dup
Result Result
318 320
SAMPLE DUPLICATE: 3804006
92631082003 Dup
Parameter Units Result Result
Total Dissolved Solids mg/L 160 165
LCS % Rec
% Rec Limits Qualifiers
102 90-110
RPD Qualifiers
1
RPD Qualifiers
3
Results presented on this page are In the units Indicated by the "Units' column except where an sltemate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not he reproduced, except in full,
Date: 03/07/2023 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 31

,11�aceAnal ical
www.pacelabs.com
Project: ANNUAL TEST OCTOBER
Pace Project No.: 92630982
QC Batch: 730880
QC Batch Method: EPA 350.1 Rev 2.0 1993
Associated Lab Samples: 92630982001
METHOD BLANK: 3805314
Associated Lab Samples: 92630982001
Parameter Units
Nitrogen, Ammonia mg/L
LABORATORY CONTROL SAMPLE: 3805315
Parameter Units
Nitrogen, Ammonia mg/L
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersv4e, NC 28078
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA 350.1 Rev 2.0 1993
Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services -Asheville
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.10 10/18/22 15:46
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
5 4.9 98 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3805316 3805317
MS MSD
92630802002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 8.3 5 5 13.3 13.6 100 107 90-110 3
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3805318 3805319
MS MSD
92630810001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 0.20 5 5 5.3 5.3 101 102 90-110 0
Results presented on this page are In the units indicated by the 'Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 03/07/2023 04:58 PM without the written consent of Pace Analytical Services, LLC.
Page 21 of 31

/'�alce Anal ical
11 www.pacelabs.com
QUALITY CONTROL DATA
Project: ANNUAL TEST OCTOBER
Pace Project No.: 92630982
QC Batch: 731527 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, preserved
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92630982001
METHOD BLANK: 3808313
Associated Lab Samples: 92630982001
Parameter Units
Nitrogen, NO2 plus NO3 mg/L
LABORATORY CONTROL SAMPLE: 3808314
Parameter Units
Nitrogen, NO2 plus NO3 mg/L
Pace Anatytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.040 10/21/2212:26
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
2.5 2.6 105 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3808315 3808316
MS MSD
92632052009 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, NO2 plus NO3 mg/L 0.25 2.5 2.5 2.7 2.7 97 97 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3808317 3808318
MS MSD
92632053001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, NO2 plus NO3 mg/L ND 2.5 2.5 2.2 2.2 86 87 90-110 1 J(M1)
Results presented on this page are in the units Indicated by me'Units' column except where an attemate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shaA not be reproduced, except in full,
Date: 03/07/2023 04:58 PM without the written consent or Pace Analytical Services, LLC.
Page 23 of 31

aceAnalytical y
wtriw.pacelabs.com
Project: ANNUAL TEST OCTOBER
Pace Project No.: 92630982
QC Batch: 732376
QC Batch Method: EPA 365.1 Rev 2.0 1993
Associated Lab Samples: 92630982001
METHOD BLANK: 3812289
Associated Lab Samples: 92630982001
Parameter Units
Phosphorus mg/L
QUALITY CONTROL DATA
Analysis Method: EPA 365.1 Rev 2.0 1993
Analysis Description: 365.1 Phosphorus, Total
Laboratory: Pace Analytical Services -Asheville
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.050 10/25/22 18:34
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Hunlersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 3812290
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Phosphorus mg/L 2.5 2.6 104 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3812291 3812292
MS MSD
92630971001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L 0.12 2.5 2.5 2.8 2.7 105 103 90-110 2
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3812293 3812294
MS MSD
92630971002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L ND 2.5 2.5 2.6 2.7 101 106 90-110 4
Results presented on this page an in the units indicated by the 'Units" column eccept where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 03/07/2023 04:58 PM without the written consent of Pace Analytical Services, LLC.
Page 24 of 31

Pace Analytical Services, LLC
/+ /� /+�
ace Analytical
9800 KGncey Ave. Suite 100
Huntersville, NC 28076
www.picitabs.com
[phone]
QUALITY CONTROL DATA
Project: ANNUAL TEST OCTOBER
Pace Project No.: 92630982
QC Batch: 730617
Analysis Method:
EPA420.4 Rev 1.0 1993
QC Batch Method: EPA 420.4 Rev 1.0 1993
Analysis Description:
420.4 Phenolics
Laboratory:
Pace Analytical Services - Asheville
Associated Lab Samples: 92630982001
METHOD BLANK: 3804045
Matrix: Water
Associated Lab Samples: 92630982001
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Phenolics, Total Recoverable mg/L
ND 0.020 10/19122 07:34
LABORATORY CONTROL SAMPLE: 3804046
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Phenolics, Total Recoverable mg/L
0.05 0.053
105 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3804047 3804W
MS MSD
92630567002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phenolics, Total Recoverable _ mg/L ND 0.05 0.05 0.061 0.055 112 99 90-110 11 J(M1),
J(R1)
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3804049 3B04050
MS MSD
92631014001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phenolics, Total Recoverable mg/L ND 0.05 0.05 0.046 0.044 91 88 90-110 4 J(M1)
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/07/2023 04:58 PM without the written consent of Pace Analytical Services, LLC.
Page 25 of 31

aceAnal ica1'
www.pacolabs.com
Project: ANNUAL TEST OCTOBER
Pace Project No.: 92630982
QC Batch: 732399
QC Batch Method: SM 4500-CN-E-2016
i
E
Associated Lab Samples: 92630982001
X
METHOD BLANK: 3812349
Associated Lab Samples: 92630982001
Parameter Units
Cyanide mg/L
LABORATORY CONTROL SAMPLE: 3812350
Parameter Units
Cyanide mg/L
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
QUALITY CONTROL DATA
Analysis Method: SM 4500-CN-E-2016
Analysis Description: 4500CNE Cyanide, Total
Laboratory: Pace Analytical Services - Asheville
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.0080 10/24/22 20:20
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
0.1 0.099 99 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3812351 3812352
MS MSD
92630787002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Cyanide mg/L 0.19 0.1 0.1 0.43 0.43 232 235 80-120 1 J(M1)
Results presented on this page are In the units Indleated by the "Units" column except where an attemate unit is presented to the right of the resutL
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/07/2023 04:58 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 31

7 eAnalXical
www.pacelabs.com
QUALIFIERS
Project: ANNUAL TEST OCTOBER
Pace Project No.: 92630982
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
MDL -Adjusted Method Detection Limit.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
I The reported value is between the laboratory method detection limit and the laboratory practical quanttation limit.
J(L1) Estimated Value. Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in
associated samples may be biased high.
J(M1) Estimated Value. Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS)
recovery.
J(P5) Estimated Value. The EPA or method required sample preservation degrades this compound, therefore acceptable
recoveries may not be achieved in sample matrix spikes.
J(R1) Estimated Value. RPD value was outside control limits.
Date: 03/07/2023 04:58 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 27 of 31

mil
WO# a 92f 30982
�C�Ce
P ei�
/
CHAIN -OF -CUSTODY / Analytical Request Docurne
The Chan-of-Cus�lody is a LEGAL DOCUMENT. All relevant fte�ds must be complell
II111 III III IIIIIII IIIt
n
i
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ts�D Le DCO 77de: ENV-FR"UN1-OM v0!_Tech Spec Sample Condition
Upon Recelpt
•4+or� t� 22
Laboratory recehrirt; samples:
Asheville ❑ Eden ❑ Greenwood ❑ Huntersviile ❑ RaleighVmacNnicsville❑ Atlanta[:] KernerrAlle❑
— -Client Name:
Ma,, 6 T,Rf ,Project 0:
Courier: _MF1,Pr, EJUPS CIUSPS[]client
❑ Commercial ace ❑Other:
Carrier Tracking Number, ,
Custody Seal Present? ❑Yes No Seals Intact? Des /o t
Date/Initlais Parson Examining Contents:
Psddng Material: ❑Bubble Wrap �bble Bags ❑None ❑ Other Biological Tissue F en?
❑Yes ❑No �/A
Thermometer: 2 ire Gun JD -a r�8 � ❑ None
f Type of lu: Wet ❑Blue
Cooler Temp (•C ): to `0 Cotrectlon Fac .- Add / Sutlaact ('C) _JCLO_ Temp should be above freezing to VC
❑Samples out of temp criteria. Samples on Ice, cooling process
corrected CootrrTmrp (•C ): hasbegun
USDA Regulated Sal! (❑ N/A, water sample)
Did samples oftrate In a quarantine tone within the United States: CA, NY, or SC (hec)c maps)? DU samples originate from a forelgn source (IntarDaifonally,
❑Yes -f 7o Indudkut Hawaii and Puerto Rico)? Des Ao
Comments/Oiscre
Chain of Custody Present? -
es[]No
N/A
I
Samples Arrived Within k1clThne7
E5,
ON.
N A
2.
Short NOW Time AnalvA kn hr.)?
a
No
N/A
3.
Rush Turn Mound T1m* ?
ONJA
4.
Suffk tent Volume?
nNo
N/A
5.
Correct Containers Used?
-Pace Containers Used?
Yes
[]No❑N/A
No
N/A
G.
Contakwz Intact?
26s
QN0
N/A
7.
Dissolved analysis: Samples Field Filtered?
es
ONo
J207A
8.
Sample Labels Match COV
-IndudesDatefrtme/ID/ Matrbr.
ZYes
❑No
QN/A
9.
Heacispace In VOA Vials 6mm ?
OY.
ZNo
N A
10.
Trip Blank Present?
Trip Blank Cusudy Seas Present?
❑Yes
n
❑No
ON.
A
IY A
11.
COMMENTS/SAMPLE DISCREPANCY RaidOsta a ulredT
e4 []Yes []No
Lot ID of splk containers:
Temp Loa: Tamp must be MakdAlned CUENT NOTIFICATION/RESOLUTION
at c4 C durfrsg login, record temp
every 20 minutes.
Time opened: Tgrip
Time: put in cooler
Time: Tempi
Person Contacted: Date/11me:
Project Manager SCURF Review: Date:
Project Manages AF RgVL
Qualtrax Document 1D- 70677 Page 1 of 2

zv 23
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-90
August 07, 2023
Kevin Peaden
Town of Tarboro
506 Dowd Street
PO Box 220
Tarboro, NC 27886
RE: Project: ANNUALTEST
Pace Project No.: 92676601
Dear Kevin Peaden:
Enclosed are the analytical results for sample(s) received by the laboratory on July 11, 2023. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Ormond Beach
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Terri Page
terri.page@pac,elabs.com
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 29

0
Project: ANNUALTEST
Pace Project No.: 92676601
Pace Analytical Services Ormond Beach
8 East Tower Circle, Ormond Beach, FL 32174
Alaska DEC- CS/UST/LUST
Alabama Certification #: 41320
Colorado Certification: FL NELAC Reciprocity
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
DoD-ANAB #:ADE-3199
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maine Certification #: FLO1264
Maryland Certification: 4346
Massachusetts Certification #: M-FL1264
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Pace Analytical Services Charlotte
South Carolina laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Feld Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification # E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification it: 40
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-90C-
CERTIFICATIONS
Missouri Certification #: 236
Montana Certification # Cert 0074
Nebraska Certification: NE-OS-28-14
New Hampshire Certification #: 2958
New Jersey Certification #: FL022
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Ohio DEP 87780
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification M 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 29

Pace Analytical Services, LLC
�Vace'
9800 KinceyAve. Suite 100
Huntersville, NC 28078
(704)875.909"
SAMPLE ANALYTE COUNT
Project: ANNUAL TEST
Pace Project No.: 92676601
Lab ID Sample ID Method
Analysts
Analyses
Reported
Laboratory
92676601001 TARBARO WWTP EFFLUENT EPA 1664E
REL
1
PASI-C
EPA 200.7
KC2
15
PASI-O
EPA 625.1
PKS
59
PASI-C
EPA 624.1
LMB
39
PASI-C
SM 254OC-2015
JMH1
1
PASI-A
TKN+NO3+NO2 Calculation
MDW
1
PASI-A
EPA 350.1 Rev 2.0 1993
ARJ
1
PASI-A
EPA 351.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 353.2 Rev 2.0 1993
EGC
1
PASI-A
EPA 365.1 Rev 2.0 1993
Zip
1
PASI-A
EPA 420.4 Rev 1.0 1993
ARJ
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Anatytical Services - Charlotte
PASI-O = Pace Analytical Services - Ormond Beach
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 29

Pace Analytical Services, LLC
9800 KinceyAve. Suite t00
/�%�p Huntersville, NC 28078
ace,
� J (704)875-909"
P
ANALYTICAL RESULTS
Project: ANNUAL TEST
Pace Project No.: 92676WI
Sample: TARBARO WWTP
tab ID: 92676601001 Collected:
07/11/23 09:45
Received: 07/11/23 13131 Matrix: Water
EFFLUENT
Parameters
Results
Units Report Limit
DF
Prepared
Analyzed
CAS No.
Qual
HEM, Oil and Grease
Analytical Method: EPA 1664B
Pace Analytical Services - Charlotte
Oil and Grease
ND
mg/L
4.9
1
07/17/23 07:37
200.7 MET ICP
Analytical Method:
EPA 200.7 Preparation Method: EPA 200.7
Pace Analytical Services - Ormond Beach
Antimony
ND
mg/L
0.015
1
07/14/23 05:01
07/17/23 20:54
7440-36-0
Arsenic
ND
mg/L
0.010
1
07/14/23 05:01
07/17/23 20:54
7440-38-2
Beryllium
ND
mg/L
0.0040
1
07/14/23 05:01
07/17/23 20:54
7440-41-7
Cadmium
ND
mg/L
0.0010
1
07/14/23 05:01
07/17/23 20:54
7440-43-9
Calcium
11.8
mg/L
0.50
1
07/14/23 05:01
07/17/23 20:54
7440-70-2
Chromium
ND
mg/L
0.0050
1
07/14/23 05:01
07/17/23 20:54
7440-47-3
Copper
0.0093
mg/L
0.0050
1
07/14/23 05:01
07/17/23 20:54
7440-50-8
Lead
ND
mg/L
0.010
1
07/14/23 05:01
07/17/23 20:54
7439-92-1
Magnesium
3.5
mg/L
0.50
1
07/14/23 05:01
07/17/23 20:54
7439-95-4
Nickel
ND
mg/L
0.0050
1
07/14/23 05:01
07/17/23 20:54
7440-02-0
Selenium
ND
mg/L
0.015
1
07/14/23 05:01
07/17/23 20:54
7782-49-2
Silver
ND
mg/L
0.0050
1
07/14/23 05:01
07/17/23 20:54
7440-22-4
Thallium
ND
mg/L
0.015
1
07/14/23 05:01
07/17/23 20:54
7440-28-0
Tot Hardness asCaCO3 (SM 2340B
43.8
mg/L
3.3
1
07/14/23 05:01
07/17/23 20:54
Zinc
0.025
mg/L
0.020
1
07/14/23 05:01
07/17/23 20:54
7440-66-6
625 RVE
Analytical Method:
EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
Acenaphthene
ND
ug/L
5.0
1
07/13/23 09:36
07/14/23 00:08
83-32-9
Acenaphthylene
ND
ug/L
5.0
1
07/13/23 09:36
07/14/23 00:08
208-96-8
Anthracene
ND
ug/L
5.0
1
07/13/23 09:36
07/14/23 00:08
120-12-7
Benzo(a)anthracene
ND
ug/L
5.0
1
07/13/23 09:36
07/14/23 00:08
56-55-3
Benzo(a)pyrene
ND
ug/L
5.0
1
07/13/23 09:36
07/14/23 00:08
50-32-8
Benzo(b)ffuoranthene
ND
ug/L
5.0
1
07/13/23 09:36
07/14/23 00:08
205-99.2
Benzo(g,h,i)perylene
ND
ug/L
5.0
1
07/13/23 09:36
07/14/23 00:08
191-24-2
Benzo(k)Fluoranthene
ND
ug/L
5.0
1
07/13/23 09:36
07/14/23 00:08
207-08-9
4-Bromophenylphenyl ether
ND
ug/L
5.0
1
07/13/23 09:36
07/14/23 00:08
101-55-3
Butylbenzylphthalate
ND
ug/L
5.0
1
07/13/23 09:36
07/14/23 00:08
85-68-7
4-Chloro-3-methylphenol
ND
ug/L
5.0
1
07/13/23 09:36
07/14/23 00:08
59-50-7
bis(2-Chloroethoxy)methane
ND
ug/L
10.0
1
07/13/23 09:36
07/14/23 00:08
111-91-1
bis(2-Chloroethyl)ether
ND
ug/L
5.0
1
07/13/23 09:36
07/14/23 00:08
111-44-4
2-Chloronaphthalene
ND
ug/L
5.0
1
07/13/23 09:36
07/14/23 00:08
91-58-7
2-Chlorophenol
ND
ug/L
5.0
1
07/13/23 09:36
07/14/23 00:08
95-57-8
4-Chlorophenylphenyl ether
ND
ug/L
5.0
1
07/13/23 09:36
07/14/23 00:08
7005-72-3
Chrysene
ND
ug/L
5.0
1
07/13/23 09:36
07/14/23 00:08
218-01.9
Dibenz(a,h)anthracene
ND
ug/L
5.0
1
07/13/23 09:36
07/14/23 00:08
53-70-3
1,2-Dichlorobenzene
ND
ug/L
5.0
1
07/13/23 09:36
07/14/23 00:08
95-50-1
1,3-Dichlorobenzene
ND
ug/L
5.0
1
07/13/23 09:36
07/1412300:08
541-73-1
J(R1)
1,4-Dichlorobenzene
ND
ug/L
5.0
1
07113/2309:36
07/14/23 00:08
106-46-7
J(R1)
3,3'-Dichlorobenzidine
ND
ug/L
10.0
1
07/13/23 09:36
07/14/23 00:08
91-94-1
IL
2,4-Dichlorophenol
ND
ug/L
5.0
1
07/13/23 09:36
07/14/23 00:08
120-83-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in
full,
Date: 08/07/2023 08:51 AM
without the written consent of Pace
Analytical
Services,
LLC.
Page 4 of 29

Pace Analytical Services, LLC
/� 9800 Kincey Ave. Suite 100
ace, Huntersville, NC 28078
(�( [phone]
ANALYTICAL RESULTS
Project: ANNUALTEST
Pace Project No.: 92676601
Sample: TARBARO WWTP
Lab IO: 92676601001 Collected:
07/11/23 09:45
Received: 07/11/23 13:31 Matrix:
Water
EFFLUENT
Parameters
Results
Units Report Limit
OF
Prepared Analyzed
CAS No.
Qual
625 RVE
Ana"cal Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical
Services - Charlotte
Diethylphthalate
ND
ug/L
5.0
1
07/13/23 09:36 07/14/23 00:08
84-66-2
J(1-1),
J(M0)
2,4-Dimethylphenol
ND
ug/L
10.0
1
07/13/23 09:36 07/14/23 00:08
105-67-9
J(M1)
D imethylphtha late
ND
ug/L
5.0
1
07/13/23 09:36 07/14/23 00:08
131-11-3
J(1-1),
J(M0)
Di-n-butylphthalate
ND
ug/L
5.0
1
07/13/23 09:36 07/14/23 00:08
84-74-2
J(M1)
4,6-Dinitro-2-methylphenol
ND
ug/L
10.0
1
07/13/23 09:36 07/14/23 00:08
534-52-1
2,4-Din&ophenol
ND
ug/L
50.0
1
07/13/23 09:36 07/14/23 00:08
51-28-5
J(RI)
2,4-Dinitrotoluene
ND
ug/L
5.0
1
07/13/23 09:36 07/14/23 00:08
121-14.2
2,6-Dinitrotoluene
ND
ug/L
5.0
1
07/13/23 09:36 07/14/23 00:08
606-20-2
Di-n-octylphthalate
ND
ug/L
5.0
1
07/13/23 09:36 07/14/23 00:08
117-84-0
1,2-Diphenylhydrazine
NO
ug/L
5.0
1
07/13/23 09:36 07/14/23 00:08
122-66-7
bis(2-Ethy1hexyl)pht1halate
ND
ug/L
5.0
1
07/13/23 09:36 07/14/23 00:08
117-81-7
Fluoranthene
ND
ug/L
5.0
1
07/13/23 09:36 07/14/23 00:08
206-44-0
Fluorene
ND
ug/L
5.0
1
07/13/2 3 09:36 07/14/23 00:08
86-73-7
J(M1)
Hexachlorobenzene
ND
ug/L
5.0
1
07/13/23 09:36 07/14/23 00:08
118-74-1
Hexachbrocyclopentadiene
NO
ug/L
10.0
1
07/13/23 09:36 07/14/23 00:08
77-47-4
Hexachloroethane
NO
ug/L
5.0
1
07/13/23 09:36 07/14/23 00:08
67-72-1
J(R1)
Indeno(1,2,3-cd)pyrene
NO
ug/L
5.0
1
07/13/23 09:36 07/14/23 00:08
193-39-5
Isophorone
ND
ug/L
10.0
1
07/13/23 09:36 07/14/23 00:08
78-59-1
Naphthalene
NO
ug/L
5.0
1
07/13/23 09:36 07/14/23 00:08
91-20-3
Nitrobenzene
ND
ug/L
5.0
1
07/13/23 09:36 07/14/23 00:08
98-95-3
2-NArophenol
ND
ug/L
5.0
1
07/13/23 09:36 07/14/23 00:08
88-75-5
4-Nitrophenol
NO
ug/L
10.0
1
07/13/23 09:36 07/14/23 00:08
100-02-7
N-Nitrosodimethylamine
NO
ug/L
5.0
1
07/13/23 09:36 07/14/23 00:08
62-75-9
N-Nhroso-di-n-propylamine
NO
ug/L
5.0
1
07/1312309:36 07/14/23 00:08
621-64-7
N-Nitrosodiphenylamine
NO
ug/L
10.0
1
07/13/23 09:36 07/14/23 00:08
86-30-6
Pentachlorophenol
ND
ug/L
10.0
1
07/13/23 09:36 07/14/23 00:08
87-86-5
Phenanthrene
ND
ug/L
5.0
1
07/13/23 09:36 07/14/23 00:08
85-01-8
J(M1)
Phenol
ND
ug/L
5.0
1
07/13/23 09:36 07/14/23 00:08
108-95-2
Pyrene
NO
ug/L
5.0
1
07/13/23 09:36 07/14/23 00:08
129-00-0
J(1-1),
J(M0)
2,4,6-Trichlorophenol
NO
ug/L
10.0
1
07/13/23 09:36 07/14/23 00:08
88-06-2
Surrogates
Nitrobenzene-d5 (S)
96
%
10-120
1
07/13/23 09:36 07/14/23 00:08
4165-60-0
2-Fluorobiphenyt (S)
83
%
15-120
1
07/13/23 09:36 07/14/23 00:08
321-60-8
Terphenyl-d14 (S)
118
%
11-131
1
07/13/23 09:36 07/14/23 00:08
1718-51-0
Phenol-d6 (S)
51
%
10-120
1
07/13/23 09:36 07/14/23 00:08
13127-88-3
2-Fluorophenol (S)
65
°%
10-120
1
07/13/23 09:36 07/14/23 00:08
367-12-4
2,4,6-Tribromophenol (S)
98
°%
10-137
1
07/13/23 09:36 07/14/23 00:08
118-79-6
624 Volatile Organics
Analytical Method: EPA 624.1
Pace Analytical
Services - Charlotte
Acrolein
ND
ug/L
5.0
1
07/12/2319:00
107-02-8
Acrylonitrile
ND
ug/L
5.0
1
07/12/2319-00
107-13-1
Benzene
NO
ug/L
1.0
1
0711212319:00
71-43-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2023 08:51 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 29

Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ANNUALTEST
Pace Project No.: 92676601
Sample: TARBARO WWTP
Lab ID: 92676601001 Collected:
07/11/23
09:45 Received:
07/11/23 13:31 Matrix: Water
EFFLUENT
Parameters
Results
Units Report Limit
DF Prepared
Analyzed CAS No. Qual
624 Volatile Organics
Analytical Method: EPA 624.1
Pace Analytical Services - Charlotte
Bromodichloromethane
ND
ug/L
2.0
1
07/12/23 19:00 75-27-4
Bromoform
ND
ug/L
2.0
1
07/12/23 19:00 75-25-2
Bromomethane
ND
ug/L
2-0
1
07/12/23 19:00 74-83-9
Carbon tetrachloride
ND
ug/L
2.0
1
07/12/23 19:00 56-23-5
Chlorobenzene
ND
ug/L
2.0
1
07112/2319:00 108-90-7
Chloroethane
ND
ug/L
2.0
1
07/12/23 19:00 75-00-3
2-Chloroethylvinyl ether
ND
ug/L
5.0
1
07/12/23 19:00 110-75-8
Chloroform
2.2
ug/L
2.0
1
07/12/23 19:00 67-66-3
Chloromethane
ND
ug/L
2.0
1
07/12/23 19:00 74-87-3
Dibromochloromethane
ND
ug/L
2.0
1
07/12/23 19:00 124-48-1
1,2-Dichlorobenzene
ND
ug/L
2.0
1
07/12/23 19:00 95-50-1
1,3-Dichlorobenzene
ND
ug/L
2.0
1
07/12/23 19:00 541-73-1
1,4-Dichlorobenzene
ND
ug/L
2.0
1
07/12/23 19:00 106-46-7
1, 1 -Dichloroethane
ND
ug/L
2.0
1
07/12/23 19:00 75-34-3
1,2-Dichloroethane
ND
ug/L
2.0
1
07/12/23 19:00 107-06-2
1,1-Dichloroethene
ND
ug/L
2.0
1
07/12/23 19:00 75-35-4
trans- 1,2-Dichloroethene
ND
ug/L
2.0
1
07/1212319:00 156-60-5
1,2-Dichioropropane
ND
ug/L
2.0
1
07/12/23 19:00 78-87-5
cis- 1, 3-Dichloropropene
ND
ug/L
2.0
1
07/12/23 19:00 10061-01-5
trans-1,3-Dichloropropene
ND
ug/L
2.0
1
07/12/23 19:00 10061-02-6
Ethylbenzene
ND
ug/L
1.0
1
07/12/23 19:00 100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
5.0
1
07/12/23 19:00 87-68-3
Methylene Chloride
ND
ug/L
2.0
1
07/12/23 19:00 75-09-2
Naphthalene
ND
ug/L
5.0
1
07/12/23 19:00 91-20-3
1,1,2,2-Tetrachloroethane
ND
ug/L
2.0
1
07/12/23 19:00 79-34-5
Tetrachloroethene
ND
ug/L
2.0
1
07/1212319.00 127-18.4
Toluene
ND
ug/L
1.0
1
07/12/23 19:00 108-88-3
1,2,4-Trichlorobenzene
ND
ug/L
2.0
1
07/12/23 19:00 120-82-1
1,1,1-Trichloroethane
ND
ug/L
2.0
1
07/12/23 19:00 71-55-6
1,1,2-Trichloroethane
ND
ug/L
2.0
1
07/12/23 19:00 79-00-5
Trichloroethene
ND
ug/L
2.0
1
07/12/23 19:00 79-01-6
Trichlorofluoromethane
ND
ug/L
2.0
1
07/12/23 19:00 75-69-4
Vinyl chloride
ND
ug/L
2.0
1
07/12/23 19:00 75-01-4
Surrogates
4-Bromofluorobenzene (S)
100
%
70-130
1
07/12/23 19:00 460-00-4
Toluene-d8 (S)
99
%
70-130
1
07/12/23 19:00 2037-26-5
1,2-Dichloroethane-d4 (S)
104
%
70-130
1
07/12/23 19:00 17060-07-0
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services - Asheville
Total Dissolved Solids
271
mg/L
25.0
1
07/13/23 17:04
Total Nitrogen Calculation
Analytical Method: TKN+NO3+NO2 Calculation
Pace Analytical Services - Asheville
Total Nitrogen
18.8
mg/L
0.040
1
07/22/23 12:04
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2023 08:51 AM
without the written consent of Pace Analytical Services, LLC.
Page 6 of 29

Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
bra:J
Huntersville, NC 28078
/
[phone]
ANALYTICAL RESULTS
Project: ANNUALTEST
Pace Project No.: 92676601
Sample: TARBARO WWTP
EFFLUENT
Parameters
Lab ID: 92676601001 Collected: 07/11/23 09:45 Received: 07/11/23 13:31 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, Ammonia
ND mg/L 0A0 1 07/22/23 12:23 7664-41-7
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, Kjeldahl, Total
2.1 mg/L 0.50 1 07/21 /23 12:28 07/22/23 04:35 7727-37-9
353-2 Nitrogen, NO2IN03 pres-
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, NO2 plus NO3
16.6 mg/L 0.24 6 07/20/23 13:33
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services - Asheville
Phosphorus
2.1 mg/L 0.050 1 07/19/2316:51 07/20/2312:41 7723-14-0
420.4 Phenolics, Total
Analytical Method: EPA 420.4 Rev 1.0 1993 Preparation Method: EPA 420.4 Rev 1.0 1993
Pace Analytical Services -Asheville
Phenolics, Total Recoverable
ND mg/L 0.020 1 07/20/23 14:45 07/20/23 17:09 64743-03-9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2023 08:51 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 29

!1-�Face
QUALITY CONTROL DATA
Project: ANNUALTEST
Pace Project No.: 92676601
QC Batch: 787139 Analysis Method: EPA 1664B
QC Batch Method: EPA 1664E Analysis Description: 1664 HEM, Oil and Grease
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92676601001
METHOD BLANK: 4080653 Matrix: Water
Associated Lab Samples: 92676601001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Oil and Grease mg/L ND 5.0 07/17/23 07:37
LABORATORY CONTROL SAMPLE: 4080654
Spike LCS
Parameter Units Conc. Result
Oil and Grease mg/L 40 35.4
MATRIX SPIKE SAMPLE: 4080655
35811935004 Spike
Parameter Units Result Conc.
Oil and Grease mg/L 7.9 39
SAMPLE DUPLICATE: 40B 656
92676601001 Dup
Parameter Units Result Result
Oil and Grease mg/L ND 1.51
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LCS % Rec
% Rec Limits Qualifiers
88 78-114
MS MS % Rec
Result % Rec Limits Qualifiers
42.8 89 78-114
RPD Qualifiers
Results presented on this page are in the units indicated by the 'Units' column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2023 08:51 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 29

QUALITY CONTROL DATA
Project: ANNUAL TEST
Pace Project No.: 92676601
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: 933483 Analysis Method: EPA 200.7
QC Batch Method: EPA 200.7 Analysis Description: 200.7 MET
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 92676601001
METHOD BLANK. 5130205
Associated Lab Samples: 92676601001
Parameter
Units
Matrix: Water
Blank Reporting
Result Limit
Analyzed Qualifiers
Antimony p�
mg/L
ND
0.015
07/17/2318:26
Arsenic
mg/L
ND
0.010
07/17/2318:26
Beryllium
mg/L
ND
0.0040
07/17/2318:26
Cadmium
mg/L
ND
0.0010
07117/2318:26
Calcium
mg/L
ND
0.50
07/17/2318:26
Chromium
mg/L
ND
0.0050
07/1712318:26
Copper
mg/L
ND
0.0050
07/17/2318:26
Lead
mg/L
ND
0.010
07117/2318:26
Magnesium
mg/L
ND
0.50
0711712318:26
Nickel
mg/L
ND
0.0050
07/17/2318:26
Selenium
mg/L
ND
0.015
07/17/2318:26
Silver
mg/1
ND
0.0050
07/17/2318:26
Thallium
mg/L
ND
0.015
07/17/2318:26
Tot Hardness asCaCO3 (SM 2340B
mg/L
ND
3.3
07/17/23 18:26
Zinc
mg/L
ND
0.020
07/17/2318:26
LABORATORY CONTROL SAMPLE:
5130206
Spike
1-CS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Antimony
mg/L
0.25
0,24
97
85-115
Arsenic
mg/L
025
0.23
90
85-115
Beryllium
mg/L
0.025
0.024
98
85-115
Cadmium
mg/L
0.025
0.024
95
85-115
Calcium
mg/L
12.5
12.1
97
85-115
Chromium
mg/L
0.25
0.24
98
85-115
Copper
mg/L
0.25
0.25
101
85-115
Lead
mg/L
0.25
0.25
100
85-115
Magnesium
mg/L
12.5
12.6
100
85-115
Nickel
mg/L
0.25
0.25
100
85-115
Selenium
mg/L
0.25
0.24
95
85-115
Silver
mg/L
0.025
0.023
94
85-115
Thallium
mg/L
0.25
0.23
92
85-115
Tot Hardness asCaCO3 (SM 2340B
mg/L
82.7
81.9
99
85-115
Zinc
mg/L
1.2
1.2
95
85-115
Results presented on this page are in the units indicated by the 'Units' column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08107/2023 08:51 AM without the written consent of Pace Analytical Services, LLC,
Page 9 of 29

QUALITY CONTROL DATA
Project: ANNUAL TEST
Pace Project No.: 92676601
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
5130207
5130208
MS
MSD
35812640001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Antimony
mg/L
0.0055
0.25
0.25
0.26
0.25
102
101
70-130
1
U
Arsenic
mg1L
0.0034
0.25
0.25
0.24
0.24,
97
96
70-130
1
U
Beryllium
mg/L
0.00017
0.025
0.025
0.026
0.025
103
102
70-130
1
U
Cadmium
mg/L
0.00033
0.025
0.025
0.025
0.025
101
100
70-130
1
U
Calcium
mg/L
50.1
12.5
12.5
63.3
62.5
105
99
70-130
1
Chromium
mg/L
0,0017
0.25
0.25
0.26
0.26
103
102
70-130
0
U
Copper
mg/L
0.D12
0.25
0.25
0.28
0.28
106
105
70-130
0
Lead
mg/L
0.0021
0,25
0.25
0.27
0.26
106
104
70-130
1
U
Magnesium
mg/L
1.1
12.5
12.5
14.4
14.3
106
106
70-130
1
Nickel
mg/L
0.00221
0.25
0.25
0.26
0.26
105
103
70-130
1
Selenium
mg/L
0.0039
0.25
0,25
0.25
0.25
101
100
70-130
1
U
Silver
mg/L
0.0010
0.025
0.025
0.025
0.024
100
98
70-130
3
U
Thallium
mg/L
0.0029
0.25
0.25
0.24
0.24
95
95
70-130
0
U
Tot Hardness asCaCO3 (SM
mg/L
130
82.7
82.7
217
215
106
103
70-130
1
2340E
Zinc
mg/L
0.0161
1.2
1.2
1.3
1.3
101
99
70-130
1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
5130209
5130210
MS
MSD
92676601001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qua[
Antimony
mg/L
ND
0.25
0.25
0.25
0.25
99
99
70-130
0
Arsenic
mg/L
ND
0.25
0.25
0.23
0.23
93
93
70.130
1
Beryllium
mg/L
ND
0.025
0.025
0.025
0.025
100
101
70-130
1
Cadmium
mg/L
ND
0.025
0.025
0.024
0.024
96
97
70-130
1
Calcium
mg/L
11.8
12.5
12.5
23.5
24.0
93
98
70-130
2
Chromium
mg/L
ND
0.25
0,25
0.25
0.25
98
99
70-130
1
Copper
mg/L
0.0093
0.25
0.25
0.26
0,26
101
101
70-130
0
Lead
mg/L
ND
0.25
0.25
0.25
0.25
101
102
70-130
1
Magnesium
mg/L
3.5
12.5
12.5
16.2
16.6
102
105
70-130
2
Nickel
mg/L
ND
0.25
0.25
0.25
0.25
100
101
70-130
1
Selenium
mg/L
ND
0.25
0.25
0.24
0.24
97
97
70-130
0
Silver
mg/L
ND
0.025
0.025
0.024
0.024
95
97
70-130
2
Thallium
mg/L
ND
0.25
0.25
0.23
0.23
93
93
70-130
1
Tot Hardness asCaCO3 (SM
mg/L
43.8
82.7
82.7
126
128
99
102
70-130
2
2340B
Zinc
mg/L
0.025
1.2
1.2
1.2
1.2
96
97
70-130
1
Results presented on this page are in the units indicated by the 'Units' column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2023 08:51 AM without the written consent of Pace Analytical Services, LLC.
Page 10 of 29

QUALITY CONTROL DATA
Project: ANNUAL TEST
Pace Project No.: 92676601
QC Batch: 786253 Analysis Method: EPA 624.1
QC Batch Method: EPA 624.1 Analysis Description: 624 MSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92676601001
METHOD BLANK: 4076466
Associated Lab Samples: 92676601001
Parameter
Units
Matrix: Water
Blank Reporting
Result Limit
Analyzed
1,1,1-Trchloroethane
ug/L
NO
2.0
07/12/23 16:18
1,1,22-Tetrachloroethane
ug/L
NO
2.0
07/12/23 16:18
1,1,246chloroethan e
ug/L
NO
2.0
07/12/23 16:18
1,1-Dichloroethane
ug/L
NO
2.0
07/12/23 16:18
1,1-Dichloroethene
ug/L
ND
2.0
07/1212316:18
1,2,4-Tdchlorobenzene
ug/L
ND
2.0
07/12/23 16:18
1,2-Dichlorobenzene
ug/L
ND
2.0
07/12/23 16:18
1,2-Dichloroethane
ug/L
ND
2.0
07/12/23 16:18
1,2-Dichloropropane
ug/L
ND
2.0
07/12/23 16:18
1,3-Dichlorobenzene
ug/L
NO
2.0
07/12/23 16:18
1,4-Dlchlorobenzene
ug/L
ND
2.0
07/12/23 16:18
2-Chloroethylvinyl ether
ug/L
NO
5.0
07/12/23 16:18
Acrolein
ug/L
ND
5.0
07/12/23 16:18
Acrylonithle
ug/L
NO
5.0
07/12/23 16:18
Benzene
ug/L
NO
1.0
07/12/23 16:18
Bromodichloromethane
ug/L
NO
2.0
07/1212316:18
Bromoform
ug/L
NO
2.0
07/12/23 16:18
Bromomethane
ug/L
ND
2.0
0711212316:18
Carbon tetrachloride
ug/L
NO
2.0
07/12/23 16:18
Chlorobenzene
ug/L
NO
2.0
07/12/23 16:18
Chloroethane
ug/L
NO
2.0
07/12/23 16:18
Chloroform
ug/L
NO
2.0
07/12/23 16:18
Chloromethane
ug/L
NO
2.0
07/12/23 16:18
cis-1,3-Dichloropropene
ug/L
ND
2.0
07/12/23 16:18
Dibromochloromethane
ug/L
NO
2.0
07/12/23 16:18
Ethylbenzene
ug/L
ND
1.0
07/12/23 16:18
Hexachloro-1,3-butadiene
ug/L
ND
5.0
07/12/23 16:18
Methylene Chloride
ug/L
ND
2.0
07/12/23 16:18
Naphthalene
ug/L
NO
5.0
07112/2316:18
Tetrachloroethene
ug/L
NO
2.0
07/12/23 16:18
Toluene
ug/L
NO
1.0
07/12/23 16:18
trans-1,2-Dichloroethene
ug/L
NO
2.0
07/12/23 16:18
trans-1,3-Dichloropropene
ug/L
NO
2.0
07/12/23 16:18
Trichloroethene
ug/L
NO
2.0
07/1212316:18
Trichlorofluoromethane
ug/L
ND
2.0
07/12/23 16:18
Vinyl chloride
ug/L
NO
2.0
07/12/23 16:18
1,2-Dichloroethane-d4 (S)
%
102
70-130
07/12/23 16:18
4-Bromofiuorobenzene (S)
%
100
70.130
07/12/23 16:18
Toluene-d8 (S)
%
100
70-130
07/12/23 16:18
Qualifiers
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Resuits presented on this page are in the units indicated by the 'Units' column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2023 08:51 AM without the written consent of Pace Analytical Services, LLC.
Page 11 of 29

ace
i
t
I
QUALITY CONTROL DATA
Project: ANNUALTEST
Pace Project No.: 92676601
LABORATORY CONTROL SAMPLE:
Parameter
4076467
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1,1-Trichloroethane
ug/L
20
19.6
98
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
18.5
92
70-130
1,12-Trichloroethane
ug/L
20
19.1
95
70-130
1, 1 -Dichloroethane
ug/L
20
19.4
97
70-130
1,1-Dichloroethene
ug/L
20
21.3
107
70-130
1,2,4-Tdchlorobenzene
ug/L
20
18.6
93
70-130
1,2-Dichlorobenzene
ug/L
20
18.5
93
70-130
1,2-Dichloroethane
ug/L
20
19.1
95
70-130
1,2-Dichloropropane
ug/L
20
19.1
95
70-130
1,3-Dichlorobenzene
ug/L
20
18.1
90
70-130
1,4-Dichlorobenzene
ug/L
20
18.3
91
70-130
2-Chloroethylvinyl ether
ug/L
40
36.6
92
63-130
Acrolein
ug/L
100
91.4
91
60-140
Acrylonitriie
ug/L
100
94.8
95
70-130
Benzene
ug/L
20
18.5
93
70-130
Bromodichloromethane
ug/L
20
18.1
91
70-130
Bromoforrn
ug/L
20
17.5
88
70-130
Bromomethane
ug/L
20
16.9
85
45-151
Carbon tetrachloride
ug/L
20
19.3
97
70-130
Chlorobenzene
ug/L
20
18.1
90
70-130
Chloroethane
ug/L
20
20.7
103
40-152
Chloroform
ug/L
20
19.3
96
70-130
Chloromethane
ug/L
20
19.9
99
58-130
cis-1,3-Dichloropropene
ug/L
20
18.6
93
70-130
Dibromochloromethane
ug/L
20
17.5
88
70-130
Ethylbenzene
ug/L
20
17.9
89
70-130
Hexachloro-1 ,3-butadiene
ug/L
20
17.7
89
70-135
Methylene Chloride
ug/L
20
19.1
96
66-130
Naphthalene
ug/L
20
18.1
91
70-130
Tetrachloroethene
ug/L
20
18.0
90
70-130
Toluene
ug/L
20
18.2
91
70-130
trans- 1, 2-Dichloroethene
ug/L
20
19.9
99
70-130
trans- 1, 3-Dichloropropene
ug/L
20
18.3
91
70-130
Tichloroethene
ug/L
20
18.9
95
70-130
Trichlorofluoromethane
ug/L
20
20.1
101
62-130
Vinyl chloride
ug/L
20
18.3
92
62-130
1,2-Dichloroethane-d4 (S)
%
106
70-130
4-Bromofluorobenzene (S)
%
101
70.130
Toluene-d8 (S)
%
100
70.130
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Results presented on this page are in the units indicated by the 'Units' column except where an alternate unit is presented to the right or the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in lull.
Date: 08/07/2023 08:51 AM without the written consent of Pace Analytical Services, LLC.
Page 12 of 29

QUALITY CONTROL DATA
Project: ANNUAL TEST
Pace Project No.: 92676601
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
4076468
MS
92676518001
Spike
Parameter
Units
Result
Conc.
1,1,1-Trichloroethane
ug/L
NO
20
1,1,2,2-Tetrachloroethane
ug/L
ND
20
1,1,2-Trichloroethane
ug/L
ND
20
1,1-Dichloroethane
ug/L
ND
20
1,1-Dichloroethene
ug/L
ND
20
1,2,4-Trichlorobenzene
ug/L
NO
20
1,2-Dichlorobenzene
ug/L
ND
20
1,2-Dichloroethane
ug/L
NO
20
1,2-Dichioropropane
ug/L
NO
20
1,3-Dichlorobenzene
ug/L
NO
20
1,4-Dichlorobenzene
ug/L
NO
20
2-Chloroethytvinyl ether
ug/L
NO
40
Acrolein
ug/L
ND
100
Acrylonitrile
ug/L
ND
100
Benzene
ug/L
NO
20
Bromodichioromethane
ug/L
NO
20
Bromoform
ug/L
NO
20
Bromomethane
ug/L
ND
20
Carbon tetrachloride
ug/L
ND
20
Chlorobenzene
ug/L
NO
20
Chloroethane
ug/L
ND
20
Chloroform
ug/L
NO
20
Chloromethane
ug/L
NO
20
cis-1,3-Dichloropropene
ug/L
ND
20
Dibromochloromethane
ug/L
ND
20
Ethylbenzene
ug/L
ND
20
Hexachloro-1.3-butadiene
ug/L
NO
20
Methylene Chloride
ug/L
NO
20
Naphthalene
ug/L
ND
20
Tetrachloroethene
ug/L
ND
20
Toluene
ug/L
NO
20
trans- 1,2-Dichloroethene
ug/L
NO
20
trans-1,3-Dichloropropene
ug/L
NO
20
Trichloroethene
ug/L
NO
20
Trichlorofluoromethane
ug/L
NO
20
Vinyl chloride
ug/L
NO
20
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
oho
Toluene-d8 (S)
MSD
Spike
Conc.
4076960
MS
Result
MSD
Result
20
31.0
24.0
20
27.1
20.5
20
28.0
21.4
20
31.5
24.0
20
34.1
27.0
20
25.1
19.3
20
26.1
20.6
20
28.9
22.1
20
29.2
22.3
20
25.7
20.0
20
25.7
20.0
40
NO
ND
100
131
101
100
147
113
20
29.6
22.7
20
29.0
21.8
20
27.0
20.2
20
30.4
24.0
20
29.5
23.3
20
26.7
21.3
20
33.6
27.2
20
30.3
23.4
20
33.4
26.3
20
28.0
21.3
20
27.2
20.2
20
26.2
21.1
20
25.3
19.7
20
30.4
23.2
20
25.1
19.7
20
25.4
19.9
20
28.2
22.2
20
31.4
24.2
20
27.6
20.9
20
29.2
22.8
20
31.5
25.3
20
31.1
24.6
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Hunlersville, NC 28078
[phone]
MS
MSD
% Rec
% Rec
% Rec
Limits
RPD Qual
155
120
70-150
25 J(M1),
J(R1)
135
103
69-142
28
140
107
70-138
27 J(MI)
157
120
70-150
27 J(M1),
J(R1)
170
135
70-156
23 J(M1)
125
96
70-146
26
131
103
70-141
24
145
110
69-143
27 J(M1)
146
112
70-156
27
128
100
70-143
25 J(RI)
128
100
70-142
25
0
0
10-200
J(M1)
131
101
40-160
26
147
113
69-147
26
148
114
70.142
26 J(MI)
145
109
70-139
28 J(MI)
135
101
64-140
29 J(R1)
152
120
28-192
24
147
116
70-140
23 J(M1)
134
106
70-141
23
168
136
58-191
21
149
114
70-138
26 J(MI)
167
131
43-162
24 J(M1)
140
106
68-151
27
136
101
70-144
29
131
106
70-143
21
127
98
64-163
25
152
116
70-144
27 J(MI)
126
99
62-149
24
127
100
70-143
24 J(R1)
141
111
69-144
24 J(R1)
157
121
70-151
26 J(M1)
138
104
70-139
28
146
114
70-142
25 J(M1)
157
126
62-146
22 J(M1)
155
123
61-162
23
100
107
70-130
102
103
70-130
101
100
70-130
Results presented on this page are in the unhs indicated by the 'Units' column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full Date: 08/07/2023 08:51 AM without the wntten consent of Pace Analytical Services, LLC.
Page 13 of 29

Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ANNUAL TEST
Pace Project No.: 92676601
QC Batch: 786462 Analysis Method: EPA 625.1
QC Batch Method: EPA 625.1 Analysis Description: 625 MSS
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92676601001
METHOD BLANK: 4077495 Matrix: Water
Associated Lab Samples: 92676601001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
1,2-Dichlorobenzene
ug/L
NO
5.0
07/13/23 19:27
1,2-Diphenylhydrazine
ug/L
NO
5.0
07/13/23 19:27
1,3-Dichlorobenzene
ug/L
NO
5.0
07/13/23 19:27
1,4-Dichlorobenzene
ug/L
NO
5.0
07/13/23 19:27
2,4,6-Trichlorophenol
ug/L
NO
10.0
07/13/23 19:27
2,4-Dichlorophenol
ug/L
ND
5.0
07/13/23 19:27
2,4-Dimethylphenol
ug/L
ND
10.0
07/13/23 19:27
2,4-Dinitrophenol
ug/L
ND
50.0
07/1312319:27
2,4-Dinitrotoluene
ug/L
NO
5.0
07/13/23 19:27
2,6-Dinitrotoluene
ug/L
NO
5.0
07/13/23 19:27
2-Chloronaphthalene
ug/L
NO
5.0
07/13/23 19:27
2-Chlorophenol
ug/L
NO
5.0
07/13/23 19:27
2-Nitrophenol
ug/L
NO
5.0
07/13/23 19:27
3,3'-Dichlorobenzidine
ug/L
NO
10.0
07/13/23 19:27 IL
4,6-Dinitro-2-methylphenol
ug/L
NO
10.0
07/13/23 19:27
4-Bromophenylphenyl ether
ug/L
ND
5.0
07/13/23 19:27
4-Chloro-3-methylphenol
ug/L
ND
5.0
07113/2319:27
4-Chlorophenylphenyl ether
ug/L
NO
5.0
07/13/23 19:27
4-Nitrophenol
ug/L
NO
10.0
07/1312319:27
Acenaphthene
ug/L
NO
5.0
07/13/2319:27
Acenaphthylene
ug/L
NO
5.0
07/13/23 19:27
Anthracene
ug/L
NO
5.0
07/13/23 19:27
Benzo(a)anthracene
ug/L
NO
5.0
07/13/23 19:27
Benzo(a)pyrene
ug/L
ND
5.0
07/13/23 19:27
Benzo(b)fluoranthene
ug/L
NO
5.0
07/13/23 19:27
Benzo(g,h,i)perylene
ug/L
ND
5.0
07/13/23 19:27
Benzo(k)fluoranthene
ug/L
NO
5.0
07/13/23 19:27
bis(2-Chloroethoxy)methane
ug/L
NO
10.0
07/13/23 19:27
bis(2-Chloroethyl) ether
ug/L
NO
5.0
07/13/23 19:27
bis(2-Ethylhexyl)phthalate
ug/L
NO
5.0
07/13/23 19:27
Butylbenzylphthalate
ug/L
NO
5.0
07/13/23 19:27
Chrysene
ug/L
NO
5.0
07/13/23 19:27
Di-n-burylphthalate
ug/L
NO
5.0
07/13/23 19:27
Di-n-octylphthalate
ug/L
NO
5.0
07/13/2319:27
Dibenz(a,h)anthracene
ug/L
NO
5.0
07/13/23 19:27
Diethylphthalate
ug/L
ND
5.0
07/13/23 19:27
Dimethylphthalate
ug/L
ND
5.0
07/13/23 19:27
Fluoranthene
ug/L
NO
5.0
07/13/23 19:27
Fluorene
ug/L
NO
5.0
07/13/23 19:27
Hexachlorobenzene
ug/L
ND
5.0
07/13/23 19:27
Results presented on this page are in the units indicated by the 'Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2023 08:51 AM without the written consent of Pace Analytical Services, LLC.
Page 14 of 29

� ace
Project: ANNUALTEST
Pace Project No.: 92676601
QUALITY CONTROL DATA
METHOD BLANK: 4077495
Matrix:
Water
Associated Lab Samples: 92676601001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Hexachlorocyclopentadiene
ug/L
ND
10.0
07/13/2319:27
Hexachloroethane
ug/L
ND
5.0
07/13/23 19:27
Indeno(1,2,3-cd)pyrene
ug/L
ND
5.0
07/13/23 19:27
Isophorone
ug/L
ND
10.0
07/13/23 19:27
N-Nitroso-di-n-propylamine
ug/L
ND
5.0
07/13/23 19:27
N-Nitrosodimethylamine
ug/L
ND
5.0
07/13/23 19:27
N-Nitrosodiphenylamine
ug/L
ND
10.0
07/1312319:27
Naphthalene
ug/L
ND
5.0
07/1312319:27
Nitrobenzene
Pentachlorophenol
ug/L
ND
5.0
07/13/23 19:27
Phenanthrene
ug/L
ug/L
ND
ND
10.0
07/13/23 19:27
Phenol
5.0
07113/2319:27
Pyrene
ug/L
ND
5.0
07/13/2319:27
2,4,6-Tdbromophenol (S)
ug/L
%
ND
5.0
07/13/23 19:27
2-Fluorobiphenyl (S)
%
75
10-137
07/13/23 19:27
2-Fluorophenol (S)
%
82
15-120
07/13/23 19:27
Nitrobenzene-d5 (S)
%
47
10-120
07/13/23 19:27
Phenol-d6 (S)
91
10-120
07/13/23 19:27
Terphenyl-d14 (S)
%
%
48
10-120
07/13/23 19:27
123
11-131
07/13/23 19:27
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE.
4077496
Parameter
-
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,2-Dichlorobenzene
ug/L
_
50
38.8
78
-
32-1
1,2-Diphenylhydrazine
u9�-
50
53.5
107
25-15050
1,3-Dichlorobenzene
ug/L
50
36.9
74
1,4-Dichlorobenzene
ug/L
50
37.0
1-172
2,4,6-Trichlorophenol
ug/L
50
74
20-124
2,4-Dichlorophenol
ug/L
50
26.4
53
37-144
2,4-Dimethylphenol
ug/L
50
33.0
66
1-191
2,4-Dinitrophenol
ug/L
250
58.5
117
32-119
2,4-Dinitrotoluene
ug/L
50
138
61.1
55
1-181
2,6-Dinitrotoluene
ug/L
50
122
39-1
2-Chloronaphthalene
ug/L
50
62.1
124
50-15858
2-Chlorophenol
ug/L
50
50.6
101
60-118
2-Nitrophenol
ug/L
50
32.7
65
23-134
3,3'-Dichlorobenzidine
ug/L
100
29.4
59
29-182
4,6-Dinitro-2-methylphenol
ug/L
100
108
108
1-262 IL
4-Bromophenylphenyl ether
ug/L
9/L
50
67.8
1-181
4-Chloro-3-methylphenol
ug/L
100
56.4
113
53-127
4-Chlorophenylphenyl ether
u9�-
50
95.5
95
22-1
4-Nitrophenol
ug/L
250
56.7
113
25-15858
Acenaphthene
ug/L
50
45.4
18
1-132
Acenaphthylene
ug/L
50
54.1
108
47-145
54.7
109
33-145
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2023 08:51 AM without the written consent of Pace Analytical Services, LLC.
Page 15 of 29

ace
QUALITY CONTROL DATA
Project: ANNUAL TEST
Pace Project No.: 92676601
LABORATORY CONTROL SAMPLE:
4077496
Spike
LCS LCS
Parameter
Units
Conc.
Result % Rec
Anthracene
ug/L
50
53.0
Benzo(a)anthracene
ug/L
50
57.5
Benzo(a)pyrene
ug/L
50
56.8
Benzo(b)fluoranthene
ug/L
50
57.3
Benzo(g,h,i)perylene
ug/L
50
55.5
Benzo(k)fluoranthene
ug/L
50
61.4
bis(2-Chloroethoxy)methane
ug/L
50
54.9
bis(2-Chloroethyl) ether
ug/L
50
67.3
bis(2-Ethylhexyl)phthalate
ug/L
50
57.1
Butylbenzylphthalate
ug/L
50
56.9
Chrysene
ug/L
50
59.1
Di-n-butylphthalate
ug/L
50
56.9
Di-n-octylphthalate
ug/L
50
58.2
Dibenz(a,h)anthracene
ug/L
50
56.8
Diethylphthalate
ug/L
50
58.2
Dimethylphthalate
ug/L
50
57.9
Fluoranthene
ug/L
50
59.4
Fluorene
ug/L
50
57.7
Hexachiorobenzene
ug/L
50
58.5
Hexachlorocyclopentadiene
ug/L
50
37.7
Hexachloroethane
ug/L
50
35.2
Indeno(1,2,3-cd)pyrene
ug/L
50
57.0
Isophorone
ug/L
50
57.3
N-Nitroso-di-n-propylamine
ug/L
50
58.6
N-Nitrosodimethylamine
ug/L
50
40.2
N-Nitrosodiphenylamine
ug/L
50
56.2
Naphthalene
ug/L
50
43.8
Nitrobenzene
ug/L
50
53.1
Pentachlorophenol
ug/L
100
49.5
Phenanthrene
ug/L
50
57.8
Phenol
ug/L
50
22.7
Pyrene
ug/L
50
60.4
2,4,6-Tribromophenol (S)
%
2-Fluorobiphenyl (S)
2-Fluorophenol (S)
%
Nitrobenzene-d5 (S)
%
Phenol-d6 (S)
%
Terphenyl-d14 (S)
%
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
% Rec
Limits Qualifiers
106
1-166
115
33-143
114
17-163
115
24-159
111
1-219
123
11-162
110
33-184
135
12-158
114
8-158
114
1-152
118
17-168
114
1-118
116
4-146
114
1-227
116
1-114 J(Ll)
116
1-112 J(L1)
119
26-137
115
59-121
117
1-152
75
25-150
70
40-113
114
1-171
115
21-196
117
1-230
80
25-150
112
25-150
88
21-133
106
35-180
49
14-176
116
54-120
45
5-112
121
52-115 J(L1)
55
10-137
101
15-120
34
10-120
103
10-120
44
10-120
117
11-131
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
4077499
40T7500
MS
MSD
92676601001 Spike
Spike MS
MSD MS
MSD % Rec
Parameter Units
Result Conc.
Conc. Result
Result % Rec
% Rec Limits RPD Qual
1,2 Dichlorobenzene ug/L
ND 50
50 26.6
35.1 53
70 32-129 28
1,2-Diphenylhydrazine ug/L
ND 50
50 57.7
55.9 115
112 25-150 3
Results Presented on this page are in the units Indicated by the 'Units' column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2023 08:51 AM without the written consent of Pace Analytical Services, LLC.
Page 16 of 29

Pace Analytical Services, LLC
ace 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)B75-9092
QUALITY CONTROL DATA
Project: ANNUAL TEST
Pace Project No.. 92676601
MATRIX SPIKE $ MATRIX SPIKE DUPLICATE:
4077499
40T7500
MS
MSD
92676601001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
1,3-Dichiorobenzene
ug/L
NO
50
50
23.2
33.9
46
68
1-172
37 J(R1)
1,4-Dichlorobenzene
ug/L
ND
50
50
25.1
34.4
50
69
20-124
32 J(R1)
2,4,6-Tdchlorophenol
ug/L
NO
50
50
66.4
62.3
133
125
37-144
6
2,4-Dichlorophenol
ug/L
ND
50
50
61.7
55.6
123
111
1-191
10
2,4-Dimethylphenol
ug/L
NO
50
50
70.5
62.9
141
126
32-119
11 J(M1)
2,4-Dinitrophenol
ug/L
NO
250
250
376
144
150
58
1-181
89 J(RI)
2,4-Dinitrotoluene
ug/L
ND
50
50
67.3
66.3
135
133
39-139
1
2,6-Dinitrotoluene
ug/L
ND
50
50
68.4
66.4
137
133
50-158
3
2-Chloronaphthalene
ug/L
ND
50
50
50.7
46.3
101
93
60-118
9
2-Chlorophenol
ug/L
NO
50
50
55.3
50.4
111
101
23-134
9
2-Nitrophenol
ug/L
ND
50
50
63.4
56.6
127
113
29-182
11
3,3'-Dichlorobenzidine
ug/L
ND
100
100
104
118
104
118
1-262
121L
4,6-Dinitro-2-methylphenol
ug/L
ND
100
100
152
135
152
135
1-181
11
4-Bromophenylphenyl ether
ug/L
NO
50
50
63.5
62.8
127
126
53-127
1
4-Chloro-3-methylphenol
ug/L
NO
100
100
124
111
124
111
22-147
11
4-Chlorophenylphenyl ether
ug/L
ND
50
50
60.3
57.6
121
115
25-158
5
4-Nitrophenol
ug/L
NO
250
250
162
134
65
54
1-132
18
Acenaphthene
ug/L
ND
50
50
55.6
52.4
111
105
47-145
6
Acenaphthylene
ug/L
NO
50
50
56.3
53.2
113
106
33-145
6
Anthracene
ug/L
ND
50
50
58.3
58.1
117
116
1-166
0
Benzo(a)anthracene
ug/L
NO
50
50
65.2
65.5
130
131
33-143
0
Benzo(a)pyrene
ug/L
NO
50
50
65.1
63.6
130
127
17-163
2
Benzo(b)fluoranthene
ug/L
ND
50
50
64.9
63.5
130
127
24-159
2
Benzo(g,h,i)perylene
ug/L
NO
50
50
73.2
74.6
146
149
1-219
2
Benzo(k)fluoranthene
ug/L
ND
50
50
67.5
65.2
135
130
11-162
4
bis(2-Chloroethoxy)methane
ug/L
ND
50
50
60.5
54.7
121
109
33-184
10
bis(2-Chloroethyl) ether
ug/L
ND
50
50
64.1
70.2
128
140
12-158
9
bis(2-Ethylhexyl)phthalate
ug/L
NO
50
50
68.5
66.3
137
133
8-158
3
Butylbenzylphthalate
ug/L
ND
50
50
69.1
68.9
138
138
1-152
0
Chrysene
ug/L
ND
50
50
66.7
67.6
133
135
17-168
1
Di-n-butylphthalate
ug/L
ND
50
50
65.6
64.3
131
129
1-118
2 J(M1)
Di-n-octylphthalate
ug/L
NO
50
50
70.4
71.2
141
142
4.146
1
Dibenz(a,h)anthracene
ug/L
ND
50
50
73.8
73.2
148
146
1-227
1
Diethylphthalate
ug/L
ND
50
50
63.3
62.8
127
126
1-114
1 J(M0)
Dimethylphthalate
ug/L
NO
50
50
62.5
62.4
125
125
1-112
0 J(MO)
Fluoranthene
ug/L
NO
50
50
66.9
68.0
134
136
26-137
2
Fluorene
ug/L
ND
50
50
63.0
59.9
126
120
59-121
5 J(M1)
Hexachlorobenzene
ug/L
NO
50
50
64.7
62.2
129
124
1-152
4
Hexachlorocyclopentadiene
ug/L
NO
50
50
28.9
29.9
58
60
25-150
3
Hexachloroethane
ug/L
NO
50
50
20.3
32.8
41
66
40-113
47 J(R1)
Indeno(1,2,3cd)pyrene
ug/L
ND
50
50
75.3
74.3
151
149
1-171
1
Isophorone
ug/L
ND
50
50
62.8
58.0
126
116
21-196
8
N-Nitroso-di-n-propylamine
ug/L
ND
50
50
65.3
58.1
131
116
1-230
12
N-Nitrosodimethylamine
ug/L
ND
50
50
44.1
40.5
88
81
25-150
9
N-Nitrosodiphenylamine
ug/L
NO
50
50
59.4
59.5
119
119
25-150
0
Naphthalene
ug/L
NO
50
50
36.1
38.0
72
76
21-133
5
Results presented on this page are in
the units indicated by the 'Units' column except where an alternate unit
is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This
report shall
not be reproduced, except in full,
Date: 08/07/2023 08:51 AM
without the written consent of Pace Analytical Services, LLC.
Page 17 of 29

Pace Analytical Services, LLG
!] �1 / 9800 Kincey Ave. Suite 100
ace G Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ANNUAL TEST
Pace Project No.: 92676601
MATRIX SPIKE 8 MATRIX SPIKE DUPLICATE:
4077499
4077500
MS
MSD
92676601001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Nitrobenzene
ug/L
NO
50
50
56.4
49.9
113
100
35-180
12
Pentachlorophenol
ug/L
ND
100
100
132
124
132
124
14-176
6
Phenanthrene
ug/L
ND
50
50
62.5
62.7
125
125
54-120
0 J(M1)
Phenol
ug/L
NO
50
50
35.1
32.2
70
64
5-112
8
Pyrene
ug/L
NO
50
50
69.2
68.5
138
137
52-115
1 J(M0)
2,4,6-Thbromophenol (S)
%
116
119
10-137
2-Fluorobiphenyl (S)
%
96
94
15-120
2-Fluorophenol (S)
%
69
66
10-120
Nitrobenzene-d5 (S)
%
106
97
10-120
Phenol-c16 (S)
%
63
60
10-120
Terphenyl-d14 (S)
%
120
124
11-131
Results presented on this page are In the units indicated by the `Units' column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 08/07/2023 08:51 AM without the written consent of Pace Analytical Services, LLC.
Page 18 of 29

Pace Analytical Services, LLC
ace,
/� 9800 Kincey Ave. Suite 100
aw / ' /�+ Huntersville, NC 28078
(J [phone]
QUALITY CONTROL DATA
Project: ANNUALTEST
Pace Project No.: 92676601
QC Batch: 786593 Analysis Method: SM 254OC-2015
QC Batch Method: SM 254OC-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92676601001
METHOD BLANK: 4078275
Associated Lab Samples: 92676601001
Parameter Units
Total Dissolved Solids mg1L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 25.0 07/13/2317:03
LABORATORY CONTROL SAMPLE & LCSD:
4078276
4079231
Spike LCS
LCSD
LCS LCSD
% Rec Max
Parameter
Units
Conc. Result
Result
% Rec % Rec
Limits RPD RPD Qualifiers
Total Dissolved Solids
mg/L
250 252 244
101 98
90-110 3 25
SAMPLE DUPLICATE: 4078775
92676120021
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Total Dissolved Solids
mg/L
266
278
4
Results presented on this page are in the units indicated by the 'Units' column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2023 08:51 AM without the written consent of Pace Analytical Services, LLC. Page 19 of 29

Pace Analytical Services, LLC
�'1 n 9800 Kincey Ave. Suite 100
f � G Huntersville, NC 28078
�+ [phone]
QUALITY CONTROL DATA
Project: ANNUALTEST
Pace Project No.: 92676601
QC Batch: 788579
Analysis Method: EPA
350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993
Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92676601001
METHOD BLANK: 4087710
Matrix: Water
Associated Lab Samples: 92676601001
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Nitrogen, Ammonia mg/L
ND 0.10
07/22/23 11:51
LABORATORY CONTROL SAMPLE: 4087711
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Nitrogen, Ammonia mg/L
I
5 5.0
100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4087712 4087713
MS MSD
92677613001
Spike Spike MS
MSD MS MSD
% Rec
1 Parameter Units Result
!I
Conc. Conc. Result
Result % Rec % Rec
Limits RPD Qual
Nitrogen, Ammonia mg/L ND
5 5 5.0
5.0 100 100
90-110 0
MATRIX SPIKE 8 MATRIX SPIKE DUPLICATE: 4087714 4087715
MS MSD
92677618001
Spike Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec
Limits RPD Qual
Nitrogen, Ammonia mg/L 11.4
5 5 16.3
16.3 98 98
90-110 0
Results presented on this page are in the units Indicated by the 'Units' column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in lull,
Date: 08/07/2023 08:51 AM without the wrinen consent of Pace Analytical Services, LLC Page 20 of 29

Project: ANNUALTEST
Pace Project No.: 92676601
QC Batch: 788085
QC Batch Method: EPA 351.2 Rev 2.0 1993
Associated Lab Samples: 92676601001
METHOD BLANK: 4085556
Associated Lab Samples: 92676601001
Parameter Units
Nitrogen, Kjeldahl, Total mg/L
LABORATORY CONTROL SAMPLE: 4085557
Parameter Units
Nitrogen, Kjeldahl, Total mg/L
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Hunlersville, NC 28078
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA 351.2 Rev 2.0 1993
Analysis Description: 351.2 TKN
Laboratory: Pace Analytical Services - Asheville
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.50 07/22/23 04:25
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
10 10.5 105 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4085558 4085559
MS MSD
92676650005 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Kjeldahl, Total mg/L 27.3 10 10 37.3 39.4 100 122 90-110 6 J(M1)
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4085560 4085561
MS MSD
92676650010 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Kjeldahl, Total mg/L 1.3 10 10 12.1 11.9 108 106 90-110 1
Results presented on this page are in the units indicated by the 'Units' column except where an alternate unit is presented to the right or the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2023 08:51 AM without the written consent of Pace Analytical Services, LLC. Page 21 of 29

Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ANNUALTEST
Pace Project No.: 92676601
QC Batch: 787765 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, preserved
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92676601001
METHOD BLANK: 4083746
Matrix: Water
Associated Lab Samples: 92676601001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Qualifiers
Nitrogen, NO2 plus NO3
mg/L
ND 0.040
07/20/23 12:49
LABORATORY CONTROL SAMPLE:
4083747
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Nitrogen, NO2 plus NO3
mg/L
2.5
2.5
99
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4083748
4083749
MS
MSD
92677531002
Spike
Spike MS
MSD
MS
MSD
% Rec
Parameter
Units Result
Conc.
Conc. Result
Result
% Rec
% Rec
Limits
RPD Qual
Nitrogen, NO2 plus NO3
mg/L 0.054
2.5
2.5 2.3
2.3
89
88
90-110
1 J(M1)
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4093750
4083751
MS
MSD
92677531003
Spike
Spike MS
MSD
MS
MSD
% Rec
Parameter
Units Result
Conc.
Conc. Result
Result
% Rec
% Rec
Limits
RPD Qual
Nitrogen. NO2 plus NO3
mgfL 0.056
2.5
2.5 2.3
2.3
89
88
90-110
1 J(M1)
Results presented on this page are in the units indicated by the 'Units' column except where an alternate unit is presented to the right or the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2023 08:51 AM without the wntten consent of Pace Analytical Services, LLC. Page 22 of 29

I�Face
QUALITY CONTROL DATA
Project: ANNUALTEST
Pace Project No.: 92676601
QC Batch: 787699 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92676601001
METHOD BLANK: 4083462 Matrix: Water
Associated Lab Samples: 92676601001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phosphorus mg/L ND 0.050 07/20/2312:33
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, INC 28078
[phone]
LABORATORY CONTROL SAMPLE:
4083463
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Phosphorus
mg/L
2.5
2.5
100
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4083464
4083465
MS
MSD
92677528002
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits RPD Qual
Phosphorus
mg/L ND
2.5
2.5
2.5
2.6
101
102
90-110 2
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4083466
4083467
MS
MSD
92677530003
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits RPD Qual
Phosphorus
mg/L 0.58
2.5
2.5
3.1
3.1
100
102
90-110 1
Results presented on this page are in the units Indicated by the 'Units' column except where an atternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2023 08:51 AM without the written consent of Pace Analytical Services, LLC. Page 23 of 29

Pace Analytical Services, LLC
ace
9800 Kincey Ave. Suite 100
/� / V Huntersville, NC 28078
(�( �J {,/ [phone]
QUALITY CONTROL DATA
Project: ANNUALTEST
Pace Project No.: 92676601
QC Batch: 787957
Analysis Method: EPA 420.4 Rev 1.0 1993
QC Batch Method: EPA 420.4 Rev 1.0 1993
Analysis Description: 420.4 Phenolics
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92676601001
METHOD BLANK: 4084907
Matrix: Water
Associated Lab Samples: 92676601001
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Phenolics, Total Recoverable mg/L
ND 0.020
07/20/23 16:57
LABORATORY CONTROL SAMPLE: 4084908
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Phenolics, Total Recoverable mg/L
0.05 0.055
109 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4084909 4084910
MS MSD
92676200002
Spike Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec
Limits RPD Qual
Phenolics, Total Recoverable mg/L ND
0.05 0.05 0.058
0.065 116 130
90-110 11 J(M1),
J(R1)
MATRIX SPIKE 8 MATRIX SPIKE DUPLICATE: 4084911 4084912
MS MSD
35811263001
Spike Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec
Limits RPD Qual
Phenolics, Total Recoverable mg/L 0.076U
0.05 0.05 .171
0.21 296 378
90-110 D3,J(M1)
Results presented on this page are in the units Indicated by the 'Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2023 08:51 AM without the written consent of Pace Analytical Services, LLC. Page 24 of 29

/ ace
QUALIFIERS
Project: ANNUALTEST
Pace Project No.: 92676601
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
MDL - Adjusted Method Detection Limit.
Pace Analytical Services, LLC
9800 Kincey Ave_ Suite 100
Huntersville, NC 28078
[phone]
PQL - Practical Quantitation Limit_
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total' may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
I The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit.
D3 Sample was diluted due to the presence of high levels of non -target analyzes or other matrix interference.
IL This analyte exceeded secondary source verification criteria low for the initial calibration. The reported results should be
considered an estimated value.
J(L1) Estimated Value. Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in
associated samples may be biased high.
J(MO) Estimated Value_ Matrix spike recovery was outside laboratory control limits.
J(M1) Estimated Value. Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS)
recovery,
J(R1) Estimated Value. RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/07/2023 08:51 AM without the written consent of Pace Analytical Services, LLC. Page 25 of 29

Toxicity Testing
Ceriodaphnia dubia
Pimephales Promelas

FACILITY NAME AND PERMIT NUMBER: I PERMIT ACTION REQUESTED: I RIVER BASIN:
Tarboro WWTP, NCO020605 Renewal I Tar -Pamlico
Part EA Toxicity Testing Data
Summary of Submitted Biomonitoring Test Information
Organism: Ceriodaphnia Dubia
Date
Pipe
Collection
Testing
Submitted
Number
Date
Date
Method
Summary
01/09/19
001
01/08/19
01/10/19
Chronic Pass/Fail
PASS
04/09/19
001
04/09/19
04/11/19
Chronic Pass/Fail
PASS
07/10/19
001
07/09/19
07/11/19
Chronic Pass/Fail
FAIL
08/14/19
001
08/13/19
08/15/19
Chronic Pass/Fail
PASS
09/11/19
001
09/10/19
09/12/19
Chronic Pass/Fail
PASS
10/22/19
001
10/08/19
10/10/19
Chronic Pass/Fail
PASS
01/15/20
001
01/14/20
01/16/20
Chronic Pass/Fail
PASS
04/20/20
001
04/20/20
04/22/20
Chronic Pass/Fail
PASS
07/14/20
001
07/13/20
07/15/20
Chronic Pass/Fail
PASS
10/07/20
001
10/06/20
10/08/20
Chronic Pass/Fail
PASS
01/12/21
001
01/11/21
01/13/21
Chronic Pass/Fail
PASS
07/14/21
001
07/13/21
07/15/21
Chronic Pass/Fail
PASS
10/06/21
001
10/05/21
10/07/21
Chronic Pass/Fail
PASS
02/01/22
001
01/11/22
01/13/22
Chronic Pass/Fail
PASS
04/06/22
001
04/05/22
04/07/22
Chronic Pass/Fail
PASS
07/13/22
001
07/12/22
07/14/22
Chronic Pass/Fail
PASS
10/05/22
001
10/04/22
10/06/22
Chronic Pass/Fail
PASS
01/11/23
001
01/10/23
01/12/23
Chronic Pass/Fail
PASS
04/05/23
001
04/04/23
04/06/23
Chronic Pass/Fail
PASS
07/19/23
001
07/18/23
07/20/23
Chronic Pass/Fail
PASS
10/11/23
001
10/10/23
10/12/23
Chronic Pass/Fail
PASS
Organism: Pimephales Promelas (Fathead Minnow Fish)
Date
Pipe
Collection
Testing
Submitted
Number
Date
Date
Method
Summary
07/14/20
001
07/13/20
07/15/20
Chronic Multi-Conc.
ChV > 32.00%
01/12/21
001
01/12/21
01/14/21
Chronic Multi-Conc.
ChV > 32.00%
10/05/22
001
10/04/22
10/06/22
Chronic Multi-Conc.
ChV > 32.00%
07/19/23
001
07/19/23
07/21/23
Chronic Multi-Conc.
ChV > 32.00%

EPA Form 2A
(inc. Parts A, B, C, D, E & F)