NC0090212_Application Attachment_20230712

AALBEMARLE 0
Albemarle Corporation
4250 Congress Street, Suite 900 Telephone: [phone]
Charlotte, North Carolina 28209 www.albemarle.com
July 12, 2023
NCDEQ/ DWR
NPDES Industrial Permitting Unit
Attn: Douglas Dowden
1617 Mail Service Center
Raleigh, NC 27699-1617
Subject: Permit Application
Additional Information Request
NCO090212 — Albemarle / Kings Mountain
348 Holiday Inn Drive, Kings Mountain
Cleveland County / MRO
Dear Sir:
In response to the April 27, 2023 NC DEQ Division of Water Quality Permitting's Industrial Permitting
Unit Additional Information Request (ADI), Albemarle submits herein all information requested.
ADDITIONAL INFORMATION REQUESTED
Delegation of Authorityfor Reports to be Filed: Based upon the information supplied it does not
appear that Albemarle has delegated state application(s) authority to Mr. Fisher. A solution would
be to add to the existing list in the letter accompanying the PA a line item for the "State of North
Carolina. "
Albemarle Response: Delegation of authority will be Jose Fernando Rodriguez, Mine Site
Director/GM. Attachment 1 includes the delegation of authority for the State of North Carolina, as
well as the Form 1 and Form 2E signatory pages.
2. PFAS Questionnaire: Please complete the PEAS questionnaire as Attachment I herein and
submit with the additional information. This request is based upon information supplied to date,
specifically related to chlorinated organics.
Albemarle Response: A completed PFAS Questionnaire has been included with this response to
comments in Attachment 2.
3. Form 2D Data Required: Information (e.g. studies) and data provided to date regarding
characteristics of the discharge is not sufficient enough to enable Division to determine limits and
monitoring frequency for an NPDES permit. To address this please provide one-time sampling
results for all missing pollutants in EPA's Form 2D, tables B, C and D from submitted
application. Analysis for compounds in table E is necessary to determine if such contaminants
might be present. Sampling from various elevations of Pit Lake due to its depth is essential to
provide representative samples of possible pollutants in the proposed discharge during the
anticipated project duration. Please closely adhere to instructions contained in EPA's form 2D for

AALBEMARLE 0
Albemarle Corporation
4250 Congress Street, Suite 900 Telephone: [phone]
Charlotte, North Carolina 28209 www.albemarle.com
presentation of results. Sampling shall be conducted according to sufficiently sensitive test
procedures (i.e., methods) approved under 40 CFR 136 for the analysis of pollutants or pollutant
parameters.
Albemarle Response:
The accumulation of storm water in Pit Lake did not occur "during manufacturing or processing" and
no processes or operations have been conducted in Pit Lake in 40 years. All dewatering activities will
occur prior to processes and operations re -starting on -site. However, as requested by NCDEQ, even
though Form 2D addresses discharges of process water while the Pit Lake contains nonprocess water,
Form 2D has been included with this response to comments in Attachment 3.
A one-time sampling event for all missing pollutants in EPA's Form 2D, tables B, C and D has been
included as an attachment to Form 2D. Samples were collected at various depths in the Pit Lake to
provide a complete profile of the water column. On Form 2D, samples from a depth of 150ft were
also included. These results do not take into account any mixing or dilution that would occur during
withdrawal and is representative of only a small section of the total volume. The remainder and
majority of the discharge will have lesser values as you can see in the attachment to Form 2D.
During this one-time sampling event, water quality data was collected from depths of 10, 50, 100, and
150 feet to provide a profile of the water quality throughout the Pit Lake. Table 1 shows the
percentage of Pit Lake Volume that each of the depths represent.
Table 1.
PL-Deep-10
PL-Deep-50
PL-Deep-100
PL-Deep-150
(0-1Oft depth)
(11-50ft depth)
(51-100ft depth)
(101-150ft depth)
Percentage of Pit
10.8%
36.9%
30.0%
16.8%
Lake Volume
4. SIC/NAISC Codes and Pre Mining Dewatering Activities: SIC /NAISC codes provided in
EPA's form I section 3 must be reflective of the characteristics of the discharge. Based upon the
information and data provided the discharge resultingfrom dewatering of Pit Lake is anticipated
to occur prior to Lithium mining activity. Please revise the SIC /NAISC codes accordingly.
Albemarle Response: Because the proposed temporary discharge is a dewatering event prior to
starting lithium mining activities, the SIC and NAICS codes that best reflect dewatering activities are
SIC Code 1799 — dewatering contractors and NAICS Code 238910 — dewatering contractors. The
forms have been updated to reflect this.
5. Dewatering Time Period Clarification: Please provide clarification as to why the EAA report
provided reflects dewatering is anticipated to occur for eight (8) months and yet the cost analysis
provided reflects a two (2) year period. If this apparent discrepancy is an error, please correct
and resubmit the corrected information.

AALBEMARLE 0
Albemarle Corporation
4250 Congress Street, Suite 900 Telephone: [phone]
Charlotte, North Carolina 28209 www.albemarle.com
Albemarle Response: The 8-month timeline is based on a continuous discharge at the maximum
discharge rate of 3500 gpm and was provided as the best -case and most -efficient timeline scenario
The two (2) year time frame was based on an average discharge rate of 2000-2500 gpm to account for
rain events and to accommodate maintenance activities. The expected length of time to dewater the
Pit Lake is 2 years.
6. Dewatering of Pit Lake and Groundwater: Since many of the elevations of Pit Lake are lower
than the existing groundwater table it is safe to assume that groundwater will flow into the lake
area during dewatering. Has this additional water source been factored into the anticipated time
period of eight (8) months or two (2) years for dewatering? If not how much more time will be
required to completely dewater Pit Lake? In addition, if more time is required to dewater Pit Lake
how will this affect the existing time schedule for recommencement of Mine's operation and
requirements of the related discharge permit (e.g., NPDES permit)? Please provide a plan for
such transition.
Albemarle Response: Based on Albemarle's extensive groundwater monitoring, Pit Lake monitoring,
and modeling, groundwater flow into the Pit Lake is minimal, compared to the approximate one
billion gallons of water in the Pit Lake and the stormwater inflow. This additional water source was
factored into the anticipated timeline for dewatering. Ongoing groundwater studies indicated that
groundwater inflow to the pit would increase as the hydraulic gradient towards the dewatered
pit increases. At the end of the dewatering process, it is projected that the maximum
groundwater inflow into the pit will reach approximately 150 gpm. This amount, with an
additional 20% contingency, has been incorporated into the lake dewatering timeline
estimate.
Albemarle will timely apply for the applicable permits for mine operation discharges to facilitate a
seamless transition between this temporary discharge and the future operational discharges. The
temporary discharge permit is only for the dewatering of the pit, prior to operational activities. Once
operation commences, the temporary discharge permit will be terminated, and the in place future
operational discharge permit will become active.
7. Dewatering of Pit Lake and Water Quality Standards: What measures (e.g. specific treatment
alternatives, such as pH control and aeration) will be employed to ensure that discharge of Pit
Lake will not cause: (1) Water quality standards violations related to pH, DO; (2) and / or
negatively impact (e.g. compromise) aquatic life do to identified parameters; such as, ammonia,
dissolved lithium?
Albemarle Response: Albemarle has conducted extensive sampling of the water in the Pit Lake and
determined that the pit water meets North Carolina Class C Standards without treatment. These
sample results were provided to NCDEQ with Albemarle's application. (December 13, 2022)
In an effort to provide reasonable assurance that protection of the environment and in response to
potential community concerns, Albemarle determined that treatment may be desirable at various
times during the dewatering process for hydrogen sulfide and ammonia. Notably, neither of these

AALBEMARLE 0
Albemarle Corporation
4250 Congress Street, Suite 900 Telephone: [phone]
Charlotte, North Carolina 28209 www.albemarle.com
constituents have NCDEQ Class C standards, but treatment for hydrogen sulfide will mitigate
potential odor concerns, and treatment for ammonia will mitigate potential aquatic life impacts.
Based on prior sampling, pH is not expected to create a water quality concern during dewatering and
the treatment for hydrogen sulfide and ammonia is expected to buffer the pH within NCDEQ Class C
standards (i.e., between 6 and 9).
Low dissolved oxygen (DO) occurs at certain depths of the pit; however, we expect DO will increase
at lower levels as the pit surface is drawn down. Water from the pit will enter South Creek reservoir
prior to being discharged to Kings Creek, which will provide further mixing and oxygenation to
improve water quality. Lastly, the chemical oxidation treatment for hydrogen sulfide and ammonia
will also increase oxygen in the discharged water.
Samples of the Pit Lake will be taken throughout the dewatering process to determine if additional
treatment may be required for constituents of concern. Real-time and grab samples will be collected
and analyzed prior to discharge, and Albemarle will comply with any sampling requirements and
effluent limits included in the final permit. If discharge monitoring indicates elevated parameters that
could affect water quality in Kings Creek, the water will be returned to the Pit Lake and the treatment
plant will be inspected and modified as necessary to ensure discharges meet water quality standards.
Additional information about the treatment system is provided in response to number 8., below.
8. Potential Downstream Impacts do to Dewatering: Based upon information provided to date, the
projected flow regime (e.g. volume and duration) will likely negatively impact creek stability and
water quality. Thus, please provide details on proposed treatment alternative(s) evaluation
demonstrating the facility will be capable of meeting water quality standards or limits at all times
accounting for potential variables that may exist during dewatering?
Albemarle Response: All water will meet discharge requirements at all ranges of flow and
duration. As stated in response to Question 7, Albemarle will treat water during dewatering. The
water treatment system will have process controls to adjust to changing water quality and flowrates
while maintaining compliance with the discharge permit.
Albemarle evaluated several alternatives to effectively treat the Pit Lake water, the final selected
alternative utilizes two stages of chemical oxidation, media filtration, followed by membrane
filtration. The water treatment system will be conservatively designed to treat maximum
concentrations of analytes identified in the Pit Lake.
In addition, the flow rate of the discharge will average 2,000-2,500 gallons per minute to maintain
Kings Creek channel integrity. Pit dewatering flow rates will be monitored in real time to ensure safe
operation and to maintain a flow rate that is suitable to the capacity of Kings Creek, particularly
during rain events.
9. Dewatering and "Minor Increase' : Please explain how proposed dewatering is a "minor
increases inflow due to the mine pit dewatering" and how this "is not expected to adversely
impact the banks of Kings Creek"? Based upon information provided to date the anticipated flow

AALBEMARLE 0
Albemarle Corporation
4250 Congress Street, Suite 900 Telephone: [phone]
Charlotte, North Carolina 28209 www.albemarle.com
regime (e.g. volume and duration) is far above the critical flow of the stream (e.g. 7Q10), thus the
potential exist for significant ecological impacts to downstream waterbodies. Lastly, has
Albemarle /Kings Mountain conducted a bioassay of the creek; if so please provide that
information? Please note that responses provided may necessitate ADI request(s).
Albemarle Response: A request was submitted on June 1, 2023 to USGS for the determination
of the Annual 7Q 10 streamflow for the onsite portion of Kings Creek. A response was
received on June 14 from USGS that the Annual 7Q 10 streamflow for Kings Creek as it
leaves Albemarle's property is approximately 0.39 cfs. SWCA opinion is that this Annual
7Q 10 estimate is not representative of current baseflow conditions for Kings Creek within
the vicinity of the proposed discharge location. The USGS also reported that the Average
Annual Discharge for this portion of Kings Creek is approximately 2.7 cfs. In May of 2022,
Albemarle installed a stream gage at a v-notch weir in Kings Creek as part of the original
mining operations at the Site. Using this observed data, the average daily streamflow flowing
over the v-notch weir was calculated to be 2.59 cfs.
These higher baseflow observations are likely a result of a permitted discharge from the
aggregate mining operation owned and operated by Martin Marietta, which is located just
upstream of the Site. As mentioned in Section 2.2.1 of the Kings Creek Stability and Water
Quality Assessment (Report) submitted with the permit application ( December 13, 2022),
Martin Marietta is permitted to discharge 2,250 gpm (5.01 cfs) into Kings Creek according to
their active mining permit (23-02).
Because of the corroboration with the reported Average Annual Discharge with the measured
baseflow observations, the HEC-RAS model was updated using the baseflow assumption of
2.59 cfs. The velocity and depth results of the analysis are as follows:
Existing Velocity
(fps)
Proposed Velocity
(fps)
Existing Water
Depth (ft)
Proposed
Water Depth
ft
Min
0.08
0.28
0.16
0.30
Max
2.58
3.84
2.54
2.74
Average
1.46
2.09
0.64
0.95
Although this increase in velocity and depth during baseflow conditions is significant, ranging from
8% to 250%, it can be safely assumed that the Kings Creek channel will remain stable throughout the
dewatering process. Figure 8-3 of the NRCS Stream Restoration Design National Engineering
Handbook indicates that Kings Creek, which was classified as a medium gravel stream with a D50 of
15 mm (see Section 2.3 of the Report), would remain stable for flows of 5 fps at a depth of 5 ft. The
maximum baseflow depth and velocity expected during the maximum dewatering flow rate of 3500
gpm is 3.84 fps at a depth of 2.54 ft, well below the critical threshold for a stream of this nature.

S\ALBEMARLE'
Albemarle Corporation
4250 Congress Street, Suite 900 Telephone: [phone]
Charlotte, North Carolina 28209 www.albemarle.com
Furthermore, as mentioned in Section 2.4 of the Report, attached to the permit application as Form 2E
Section 7.1 Attachment 1, the BEHI & NBS analysis that was conducted to determine the stream
bank erosion potential for Kings Creek determined that the stream banks within the vicinity of the
Site have "very low" to "low" erosion potential, largely due to the existing stream bank
characteristics such as vegetation, root depth & density, bank angle, and bank height ratio. This bank
erosion assessment further confirms the assumption that Kings Creek will be stable throughout the
duration of Albemarle's dewatering operations.
10. Data Submittal Concern: For this submittal and any future submittals be cognizant of the fact that
using a scroll bar for additional text information in any given text entry box may get lost for
review purposes, if the reviewer is reading a printed and/or scanned in version of the document. In
addition, scanned in documents of any nature for public access loose scroll bar functionality and
thus may not meet public accessibility requirements. Specifically for the application submitted in
EPA's form 2E section 7, to view the entirety of the text entered the viewer must be on a computer
viewing an original version of the application to use the scroll bar to view all entered text. Please
revise the attachment to eliminate the use of scroll bars.
Albemarle Response: Text contained within EPA's form 2E section 7 is included in this response as
Attachment 4.
IL Key Contacts) for Communications: To ensure continuity Division requests that Albemarle /
Kings Mountain designate a key contact with one backup for all communications. With that said
Derek Denard at: derek. denard(a�ncdenrgoy is the primary contact for NCDEQ with Doug
Dowden at: dou .dowdenfa?ncdenr. ov serving as the backup. All primary communications should
include these contacts.
Albemarle Response: John Kuhn (John.Kuhn(a'talbemarle.com) is the primary contact for Albemarle
and Morgan Warren at (morLan.warren±i�albemarle.com) is the backup contact.
Thank you in advance for your office's diligence on the matter. If you have any questions about
the NPDES permit application or this response to the additional information request, please contact me at
the following e-mail address: John.Kuhn@.albemarle.com or telephone number: 704-734-2708
r
n Kuhn
Mine Environmental Permitting Lead
Albemarle Lithium

Additional Information Request
Attachment 1
Delegation of Authority

LIMITED POWER OF ATTORNEY
FOR KINGS MOUNTAIN
I, Eric W. Norris, President, of Albemarle U.S., Inc., located at 4250 Congress Street, Suite 900,
Charlotte, North Carolina, 28209 (the "Company'), on behalf of the Company hereby appoint
Jose Fernando Rodriguez
as authorized representative of the Company (" Agent') for the purposes described herein.
The Agent shall have full power and authority to act on behalf of the Company with regard to
any and all reports and/or documents which are required to be or may be filed on behalf of the
Company's lithium mine and concentrator plant project located in Kings Mountain, North
Carolina. This power and authority shall include, but not be limited to, permits or licenses
issued by the:
1. North Carolina Department of Environmental Quality and other state agencies
2. Cleveland County, North Carolina
3. U.S. Department of Homeland Security
4. U.S. Department of Transportation
5. North Carolina Department of Transportation
6. U.S. Environmental Protection Agency
7. U.S. Fish and Wildlife Service
8. US Army Corps of Engineers
9. Mine Safety and Health Administration (MSHA)
10. Bureau of Alcohol, Tobacco, Firearms and Explosives (ATF)
This Limited Power of Attorney is effective as of the date signed below, and will continue until
December 31, 2025, and may be revoked at any time by providing written notice to the Agent.
o 4,
Dated this b day of June, 2023 at Charlotte, North Carolina.
Eric W. Norris
President, Energy Storage

State of North Carolina
County of Mecklenburg
a Notary Public for Mecklenburg County, North Carolina, do hereby
certify that i5riC• W . N QYYiS personally appeared before me this day and acknowledged
the due execution of the foregoing instrument.
k
Witness my hand and official seal, this the Day of June, 2023.
(Official Seal)
Notary Public
CARLESEE. �UNKER
NOTARY PUBLIC
Mecklenburg Courq
North Carolina

Additional Information Request
Attachment 2
PFAS Questionnaire

PFAS Questionnaire
1. Do you use any material or products (directly or indirectly) in your operations that contain
fluorinated chemicals? If so, please identify what materials or products contain fluorinated
chemicals.
Albemarle Response: No, the dewatering of the Pit Lake will not use material or products that contain
fluorinated chemicals.
• Please also address if you have any historical conditions and/or information for past
practices at the site related to fluorinated chemicals?
Albemarle Response: There is no historic conditions or information for past practices at the site
related to fluorinated chemicals.
2. Will your facility formulate or create products (directly or indirectly) which contain
fluorinated chemicals? If so, please identify the specific fluorinated chemicals that may be
formulated or created.
Albemarle Response: No, the facility will not formulate or create products which contain fluorinated
chemicals.
3. Will your facility produce solid waste, liquid waste, wastewater effluent, or other waste
containing fluorinated chemicals? Please be as specific as possible to describe what
fluorinated chemicals may result in the facility's wastewater, solid waste, or sludge.
Albemarle Response: No, the facility will not produce solid waste, liquid waste, wastewater effluent,
or other waste containing fluorinated chemicals.
4. Are there processes or operations that use equipment, material, or components that contain
PFAS chemicals (e.g., surface coating, clean room applications, solvents, lubricants, fittings,
tubing, processing tools, packaging, facility infrastructure)? Could these activities result in
fluorinated chemicals being discharged as products, or by-products (i.e., through leaching,
chemical process, heat treatment, pressurization, etc.)?
Albemarle Response: No, the process of dewatering will not include the use of equipment, material,
or components that contain PFAS chemicals
S. List CAS numbers of all known or believed present fluorinated compounds from the questions
above. Please provide descriptions, quantities, and whether there are any unknowns related to
the above questions.
Albemarle Response: There are no known or believed present fluorinated compounds at the site.

6. Are there other facilities or operations in the U.S. or internationally that are identical to or
may use processes similar to the facility in North Carolina? If so, please provide facility
identification information and wastewater characterization including all PFAS compounds?
Albemarle Response: While dewatering mine pits is common practice in the U.S. and internationally,
the Albemarle Kings Mountain temporary pit lake dewatering activities is unique because of the lack
of process water. No process or operations have been conducted in the Pit Lake in 40 years, and the
proposed dewatering will occur prior to operations commencing again.
7. Additionally, have any PFAS analytical results been collected with any analytical test method
similar to the following EPA Test Methods. Are any of the fluorinated compounds listed in one
of the following methods and can you provide us with data resulting from these test methods?
■ Methods 533 & 537.1 (drinking water)
■ SW-846: Method 8327 (water)
■ Draft Method 1633 (water, solids, tissue)
Albemarle Response: PFAS sampling of the Pit Lake was conducted on March 21, 2023 at three
locations. The sample depth at all three locations was 1 Oft below the water surface. Analytical results
as well as a map of monitoring locations have been included with this questionnaire.

ALBEMARLE KINGS MOUNTAIN
MINE
Pit Lake PFAS
Sampling
Aerial Imagery
Map
O Pit Lake Monitoring Location
Q Project Area
Cleveland County, NC
USGS 7.5' Quadrangle:
Kings Mountain, NC, 35081-B3
NAD 1983 StatePlane North
Carolina FIPS 3200 Feet
35.2155°N 81.3548°W
Base Map: Esri ArcGIS Online,
accessed June 2023
Updated: 6I2612023
Project No. 70316
Layout: Piti-ake_WAS _Sampling
Aprx: 70316_SoilSample_Report
0 700 1,400
Feet
3 Meters
0 175 350
,BAN\\
/ V )
1:17,000
SWCA
ENVIRONMENTAL CONSULTANTS

PFAS Pit Lake Sample Results
Analyte
Units
PL-2-10 (10 ft depth)
PL-5-10 (10 ft depth)
PL-8-10 (10 ft depth)
Result
Qualifier
Result
Qualifier
Result
Qualifier
11-Chloroeicosafluoro-3-oxaundecane-1-sulfonic acid (11-CI-PF3OUdS) ng/L <0.39 <0.39 <0.39
1 H, 1 H, 2H, 2H-Perfluorodecanesulfonic acid (8:2 FTS) ng/L <0.86 <0.86 <0.86
1 H, 1 H, 2H, 2H-Perfluorohexanesulfonic acid (4:2 FTS) ng/L <0.42 <0.42 <0.42
1 H, 1 H, 2H, 2H-Perfluorooctanesulfonic acid (6:2 FTS) ng/L <1.3 <1.3 <1.3
2H,2H,3H,3H-Perfluorodecanoic acid (7:3 FTCA) ng/L <6 <6 <6
2H,2H,3H,3H-Perfluorooctanoic acid (5:3 FTCA)
ng/L
<4.2
<4.2
<4.2
4,4,5,5,6,6,6-Heptafluorohexanoic acid (3:3 FTCA)
ng/L
<6.8
<6.8
<6.8
4,8-Dioxa-3H-perfluorononanoic acid (DONA)
ng/L
<0.36
<0.36
<0.36
9-Chlorohexadecafluoro-3-oxanonane-1-sulfonic acid (9-CI-PF3ONS)
ng/L
<0.45
<0.45
<0.45
Hexafluoropropyleneoxide dimer acid (HFPO-DA) (GenX)
ng/L
<0.41
<0.41
0.42
J
N-Ethylperfluorooctane sulfonamide (EtFOSAnn)
ng/L
<0.85
<0.85
<0.85
N-Ethylperfluorooctane sulfonamido acetic acid (NEtFOSAA)
ng/L
<0.95
<0.95
<0.95
N-Ethylperfluorooctane sulfonamido ethanol (EtFOSE)
ng/L
<0.92
<0.92
<0.92
N-Methylperfluorooctane sulfonamide (MeFOSA)
ng/L
<1.2
<1.2
<1.2
N-Methylperfluorooctane sulfonamido acetic acid (NMeFOSAA)
ng/L
<0.91
<0.91
<0.91
N-Methylperfluorooctane sulfonamido ethanol (MeFOSE)
ng/L
<0.82
<0.82
<0.82
Nonafluoro-3,6-dioxaheptanoic acid (NFDHA)
ng/L
<0.58
<0.58
<0.58
Perfluoro(2-ethoxyethane) sulfonic acid (PFEESA)
ng/L
<0.43
<0.43
<0.43
Perfluoro-3-methoxypropanoic acid (PFMPA)
ng/L
<0.41
<0.41
<0.41
Perfluoro-4-methoxybutanoic acid (PFMBA)
ng/L
<0.54
<0.54
<0.54
Perfluorobutanesulfonic Acid
ng/L
2.5
J
2.6
J
2.8
J
Perfluorobutanoic Acid
ng/L
6.7
6.8
7.3
Perfluorodecane Sulfonate
ng/L
<0.67
<0.67
<0.67
Perfluorodecanoic Acid
ng/L
0.64
J
0.99
I,J
0.84
J
Perfluorododecane sulfonic acid (PFDoS)
ng/L
<0.56
<0.56
<0.56
Perfluorododecanoic acid (PFDOA)
ng/L
<0.61
<0.61
<0.61
Perfluoroheptane sulfonate
ng/L
<0.69
<0.69
<0.69
Perfluoroheptanoic Acid
ng/L
3.6
J
3.7
J
4.2
J
Perfluorohexanesulfonic Acid
ng/L
3.9
J
3.6
J
3.7
J
Perfluorohexanoic Acid
ng/L
4.6
J
4.7
5
Perfluorononane sulfonic acid (PFNS)
ng/L
<0.33
<0.33
<0.33
Perfluorononanoic Acid
ng/L
1.7
J
1.6
J
2.1
J
Perfluoro-n-tridecanoic acid
ng/L
0.59
J
0.66
J
0.77
J
Perfluorooctane sulfonamide (PFOSAm)
ng/L
<0.72
<0.72
<0.72
Perfluorooctanesulfonic Acid
ng/L
4.7
J
5
5.2
Perfluorooctanoic Acid
ng/L
8.2
8.1
8.1
Perfluoropentane sulfonic acid (PFPeS)
ng/L
1.1
J
1
J
1.1
J
Perfluoropentanoic Acid
ng/L
5.2
5.4
5.9
Perfluorotetradecanoic acid (PFTDA)
ng/L
<1.3
<1.3
1.3
I,J
Perfluoroundecanoic Acid
ng/L
<0.82
<0.82
<0.82
< represents an analyte not detected, value provided is the Method Detection Limit (MDL)
Qualifiers: J- Denotes a concentration greater than the MDL and less than the reporting limit (RL), I - The MRL/MDL is elevated due to a matrix interference.

Additional Information Request
Attachment 3
EPA Form 2 D

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
NCO090212 Albemarle King's Mountain Mine OMB No. 2040-0004
U.S. Environmental Protection Agency
Form Application for NPDES Permit to Discharge Wastewater
21)
NPDES \"IGC P NEW MANUFACTURING, COMMERCIAL, MINING, AND SILVICULTURAL OPERATIONS
THAT HAVE NOT YET COMMENCED DISCHARGE OF PROCESS WASTEWATER
SECTION1 OUTFALL LOCATION
1.1 Provide information on each of the facilit 's outfalls in the table below.
a Outfall Receiving Water Latitude Longitude
— Number Name
U
0 01 Kings Creek 35' 12' 42.70" N 81° 21' 19.05" W
CE o o
S
O
o
SECTION1 DISCHARGE 1 I
i, 2.1 Month Day Year
� � d
d Ca
X v"i 09 01 2023
w p
SECTION• 1 I
3.1 For each outfall identified under Item 1.1, provide average flow and treatment information. Add additional sheets as
necessary.
**Outfall Number** 01
Operations
Operation Average Flow
Discharge from Pit Lake 2500 mgd
mgd
mgd
mgd
mgd
0 Treatment Units
Description Code from Final Disposal of Solid or Liquid
(include size, flow rate through each treatment unit, Exhibit 2D-1 Wastes Other Than by Discharge
> retention time, etc.)
Multimedia filtration, 2148gpm 1-Q 0.6lbs/minute Solid Waste
Ultra Filtration, 2105gpm No Code on 2D-1
EPA Form 3510-2D (Revised 3-19) Page 1

EPA Identification Number
NPDES Permit Number
Facility Name
Form Approved 03/05/19
NCO090212
Albemarle King's Mountain Mine
OMB No. 2040-0004
3.1
**Outfall Number** N/A
Cont.
Operations
Operation
Average Flow
N/A
mgd
mgd
mgd
mgd
mgd
Treatment
Description
(include size, flow rate through each treatment unit,
Units
Code from
Final Disposal of Solid or Liquid
retention time, etc.)
Exhibit 2D-1
Wastes Other Than by Discharge
N/A
a�
c
0
U
c
a�
E
iv
a�
L
N
**Outfall Number** N/A
o
Operations Contributing to Flow
Operation Average Flow
N/A
mgd
Q
mgd
mgd
mgd
mgd
Treatment
Description
(include size, flow rate through each treatment unit,
Units
Code from
Final Disposal of Solid or Liquid
retention time, etc.)
Exhibit 2D-1
Wastes Other Than by Discharge
N/A
EPA Form 3510-21D (Revised 3-19) Page 2

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
NCO090212 Albemarle King's Mountain Mine OMB No. 2040-0004
SECTION1' 1
4.1 Have you attached a line drawing to this application that shows the water flow through your facility with a water
3 balance? (See instructions for drawing requirements. See Exhibit 2D-2 at end of instructions for example.)
J i
o ✓❑ Yes ❑ No
SECTIONOR
SEASONAL FLOWSi
5.1
Except for stormwater runoff, leaks, or spills, are any expected discharges described in Sections 1 and 3 intermittent
or seasonal?
❑ Yes ❑✓ No 4 SKIP to Section 6.
5.2
Provide information on intermittent or seasonal flows for each applicable outfall. Attach additional pages, if
necessary.
Outfall
Operations
Frequency
Rate and Volume
Average
Average
Maximum Daily
Maximum Total
Number
(list)
Duration
Da sMeek
MonthsNear
Discharge
Volume
days/week
months/year
mgd
gallons
days
odays/week
months/year
mgd
gallons
days
LL
days/week
months/year
mgd
gallons
days
c
0
Outfall
Operations
Frequency
Rate and Volume
Average
Average
Maximum Daily
Maximum Total
o
Number
(list)
Duration
—
Da s[Week
MonthsNear
Discharge
Volume
days/week
months/year
mgd
gallons
days
E
days/week
months/year
mgd
gallons
days
a`
days/week
months/year
mgd
gallons
days
Outfall
Operations
Frequency
Rate and Volume
Average
Average
Maximum Daily
Maximum Total
Number
(list)
Duration
Da sMeek
MonthsNear
Discharge
Volume
days/week
months/year
mgd
gallons
days
days/week
months/year
mgd
gallons
days
days/week months/year mgd gallons days
SECTION•••
•
6.1
Do any effluent limitation guidelines (ELGs) promulgated by EPA under CWA Section 304 apply to your facility?
❑ Yes ❑� No 4 SKIP to Section 7.
6.2
Provide the following information on applicable El -Gs.
ELG Category
ELG Subcategory
Regulatory Citation
0 0
N/A
L
a
EPA Form 3510-21D (Revised 3-19) Page 3

EPA Identification Number
NPDES Permit Number
Facility Name
Form Approved 03/05/19
NCO090212
Albemarle King's Mountain Mine
OMB No.2040-0004
6.3
Are the limitations in the applicable ELGs expressed in terms of production (or other measure of operation)?
❑ Yes ❑� No 4 SKIP to Section 7.
6.4
Provide an expected measure of average daily production expressed in terms and units of applicable ELGs.
Expected Actual Average Daily Production for First Three Years
Outfall
Number
Year
Operation, Product, or Material
Quantity per Day
(note basis if applicable)
Unit of Measure
N/A
Year 1
Year 2
d
c
c
0
Year 3
U
c
0
N/A
Year 1
0
a
Year 2
Year 3
N/A
Year 1
Year 2
Year 3
SECTIONi
See the instructions to determine the parameters and pollutants you are required to monitor and, in turn, the tables you must
complete. Note that not all applicants need to complete each table.
Table A. Conventional and Non -Conventional Parameters
7.1
Are you requesting a waiver from your NPDES permitting authority for one or more of the Table A parameters for any
of your outfalls?
❑ Yes ❑✓ No + SKIP to Item 7.3.
7.2
If yes, indicate the applicable outfalls below. Attach waiver request and other required information to the application.
Outfall number N/A Outfall number N/A Outfall number N/A
7.3
Have you have provided estimates or actual data for all Table A parameters for each of your outfalls for which a
waiver has not been requested and attached the results to this application package?
No; a waiver has been requested from my
❑✓ Yes ❑ NPDES permitting authority for all parameters at
all outfalls.
Table B. Certain Conventional and Non -Conventional Pollutants
w
7.4
Have you checked "Believed Present" for all pollutants listed in Table B that are limited directly or indirectly by an
applicable ELG?
❑✓ Yes ❑ No
7.5
Have you checked "Believed Present" or "Believed Absent" for all remaining pollutants listed in Table B?
❑✓ Yes ❑ No
7.6
Have you provided estimated data for those Table B pollutants for which you have indicated are "Believed Present"
in your discharge?
❑✓ Yes ❑ No
EPA Form 3510-21D (Revised 3-19) Page 4

EPA Identification Number
NPDES Permit Number
Facility Name
Form Approved 03/05/19
NCO090212
Albemarle King's Mountain Mine
OMB No. 2040-0004
Table C. Toxic Metals, Total Cyanide, and Total Phenols
7.7
Have you indicated whether pollutants are "Believed Present" or "Believed Absent" for all pollutants listed on Table C
for all outfalls?
❑✓ Yes ❑ No
7.8
Have you completed Table C by providing estimated data for pollutants you indicated are "Believed Present,"
including the source of the information, for each applicable outfall?
❑✓ Yes ❑ No
Table D. Organic Toxic Pollutants GCIMS Fractions
7.9
Do you qualify for a small business exemption under the criteria specified in the Instructions?
❑ Yes 4 Note that you qualify at the top of 0 No
Table D, then SKIP to Item 7.12.
7.10
Have you indicated whether pollutants are "Believed Present" or "Believed Absent" for all pollutants listed on Table D
for all outfalls?
c
0
❑✓ Yes ❑ No
7.11
Have you completed Table D by providing estimated data for pollutants you indicated are "Believed Present,"
including the source of the information, for each applicable outfall?
Y
❑� Yes ❑ No
2,3,7,8-Tetrachlorodibenzo- -Dioxin TCDD
7.12
Does the facility use or manufacture one or more of the 2,3,7,8-TCDD congeners listed in the Instructions, or do you
know or have reason to believe that TCDD is or may be present in effluent from any of your outfalls?
d
'
E_
❑ Yes ✓❑ No
w
Table E. Certain Hazardous Substances and Asbestos
7.13
Have you indicated whether pollutants are "Believed Present" or "Believed Absent" for all pollutants listed in Table E
for all outfalls?
❑✓ Yes ❑ No
7.14
Have you completed Table E by reporting the reason the pollutants are expected to be present and available
quantitative data for pollutants you indicated are "Believed Present" for each applicable outfall?
❑✓ Yes ❑ No
Intake Credits, Tables A through E
7.15 Are you applying for net credits for the presence of any of the pollutants on Tables A through E for any of your
outfalls?
❑ Yes 4 Consult with your NPDES permitting 0 No
authority.
SECTION•••
i
8.1 Do you have any technical evaluations of your wastewater treatment, including engineering reports or pilot plant
studies?
C
0
a
❑✓ Yes ❑ No 4 SKIP to Item 8.3.
a�
a,
8 22
Have you provided the technical evaluation and all related documents to this application package?
✓❑ Yes ❑ No
a)
t8.3
Are you aware of any existing plant(s) that resemble production processes, wastewater constituents, or wastewater
w
treatment at your facility?
❑ Yes ❑✓ No 4 SKIP to Section 9.
EPA Form 3510-21D (Revised 3-19) Page 5

EPA Identification Number
NPDES Permit Number
Facility Name
Form Approved 03/05/19
NCO090212
Albemarle King's Mountain Mine
OMB No. 2040-0004
8.4
Provide the name and location of the similar plants.
Name of Similar Plants
Location of Similar Plants
N/A
� c
c U
c
W
SECTION'
OTHER
INFORMATION1
9.1
Have you attached any optional information that you would like considered as part of the application review process
(i.e.,
material beyond that which you have already noted in the application as being attached)?
❑✓
Yes
❑ No 4 SKIP to Section 10.
c
9.2
List the additional items and briefly note why you have included them.
E1.
A
profile of the Pit Lake water quality sampling results at various depths to suffice Tables A, B, C, and D.
L
_0
5
L
2.
d
3.
O
4.
5.
SECTIONi
CHECKLIST
AND CERTIFICATIONi
10.1
In Column 1 below, mark the sections of Form 2D that you have completed and are submitting with your application.
For each section, specify in Column 2 any attachments that you are enclosing to alert the permitting authority. Note
that not all applicants are required to com lete all
sections or tables, or provide attachments.
Column 1
Column 2
J❑
Section 1: Expected Outfall
❑
w/ attachments (e.g., responses for additional outfalls)
Location
❑J
Section 2: Expected
El
w/ attachments
Discharge Date
Section 3: Average Flows
❑
w/ attachments
_El
CD
and Treatment
❑✓
Section 4: Line Drawing
❑✓
w/ line drawing ❑ w/ additional attachments
R
`o
❑J
Section 5: Intermittent or
❑
wl attachments
Seasonal Flows
15
❑✓
Section 6: Production
❑
w/ attachments
c�
w/ Table A waiver
❑
request or ❑✓ Table A
H
approval
J
❑
Section 7: Effluent
❑J
Table B ❑J Table C
Characteristics
U
❑✓
Table D ✓❑ Table E
❑J
w/ other
attachments
J❑
Section 8: Engineering
0Report
wl technical evaluations and related attachments
✓❑
Section 9: Other Information
w/ optional information
❑
Section 10: Checklist and
❑
w/ attachments
Certification Statement
EPA Form 3510-21D (Revised 3-19) Page 6

EPA Identification Number f NPDES Permit Number Facility Name Form Approved 03/05/19
NC0090212 Albemarle King's Mountain Mine
OMB No. 2040-0004
10.2 Certification Statement
c
d
E I certify under penalty of law that this document and all attachments were prepared under my direction or supervision
2 in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
r_ information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
° directly responsible for gathering the information, the information submitted is, to the best of my knowledge and
0 = belief, true, accurate, and complete. l am aware that there are significant penalties for submitting false information,
including the possibility of fine and imprisonment for knowing violations.
or -
Name (print or type first and last name) Official title
c
a Jose Fernando Rodri Mine Site Director/GM
32
a _
d
Signature ' Date signed
r7l ►�I�3
EPA Form 3510-21) (Revised 3-19) Page 7

This page intentionally left blank.

EPA Identification Number Facility Name
Outfall Number
Form Approved 03/05/19
Albemarle King's Mountain Mine
01
OMB No. 2040-0004
CONVENTIONAL AND
NON•
•
1
Effluent Data
Intake Water
Maximum Daily
Average Daily
Source of Information
Believed Present?
Pollutant
Waiver
Requested
Units
(if applicable)
Discharge
Discharge
(use codes in instructions)
(check only one response per
(required)
(if available)
parameter)
❑
Check here if you have applied to your NPDES authority for a waiver for all of the pollutants listed on this table for the noted outfall.
1'
Biochemical oxygen
❑
Concentration
Previously Reported
❑Yes
❑
Mass
Previously Reported
demand (BOD5)
No
2
Chemical oxygen demand
❑
Concentration
Previously Reported
❑
❑
(COD)
Yes
No
Mass
Previously Reported
3
Total organic carbon
❑
Concentration
Previously Reported
❑
❑
(TOC)
Yes
No
Mass
Previously Reported
4
Total suspended solids
❑
Concentration
Previously Reported
❑
❑
(TSS)
Yes
No
Mass
Previously Reported
Concentration
Previously Reported
5.
Ammonia (as N)
❑
❑ Yes
❑ No
Mass
Previously Reported
6.
Flow
❑
Rate
Previously Reported
❑ Yes
❑ No
Temperature (winter)
❑
°C
°C
Previously Reported
7.
❑ Yes
❑ No
Temperature (summer)
❑
°C
°C
Previously Reported
pH (minimum)
❑
Standard units
S.U.
Previously Reported
$•
❑Yes
❑ No
pH (maximum)
❑
Standard units
S.U.
Previously Reported
Samplina shall be conducted accordina to sufficiently sensitive test procedures (i.e.. methods) approved under 40 CFR 136
for the analysis of pollutants or pollutant
parameters or
required under 40 CFR chapter I, subchapter N or 0. See instructions and 40 CFR 122.21(e)(3).
EPA Form 3510-2D (Revised 3-19) Page 1

This page intentionally left blank.

EPA Identification Number
Facility Name
Albemarle King's Mountain Mine
Outfall Number
01
Form Approved 03/05/19
OMB No. 2040-0004
TABLE B. CERTAIN CONVENTIONAL
AND NON CONVENTIONAL
POLLUTANTS (40 CFR 122.21(k)(5)(ii))'
Estimated Data for Pollutants Expected to be Present or Limited by an ELG
Provide both concentration and mass estimates for eachpollutant.)
Presence or Absence
check one
Pollutant
Believed
Present
Believed
Absent
Effluent
Intake Water
Units
Maximum Daily
Discharge
(required)
Average Daily
Discharge
if available
Source Information
(use codeess in instructions)
Believed Present?
(check only one
response per item)
❑
Check (✓) here if you believe all pollutants listed to be absent from the discharge. You need not complete Table B for the noted outfall unless you have quantitative data available.
1
Bromide
(24959-67-9)
❑
�
Concentration
Code 5 -Actual Water Quality
Data
❑ Yes ❑ No
Mass
2
Chlorine, total
residual
❑
❑
Concentration
Previously Reported
❑ Yes ❑ No
Mass
3.
Color
❑
❑
Concentration
Previously Reported
❑Yes ❑ No
Mass
4.
Fecal coliform
❑
❑✓
Concentration
Code 5 - Actual Water Quality
Data
❑ Yes ❑ No
Mass
5.
Fluoride
(16984-48-8)
❑
❑
Concentration
Previously Reported
❑Yes El No
Mass
6.
Nitrate -nitrite
❑
❑
Concentration
Previously Reported
❑Yes ❑ No
Mass
7.
Nitrogen, total
organic (as N)
❑
❑
Concentration
Previously Reported
❑Yes El No
Mass
8.
Oil and grease
❑
❑
Concentration
Previously Reported
El Yes ❑ No
Mass
9
Phosphorus (as P),
total (7723-14-0)
❑
❑
Concentration
Previously Reported
❑ Yes ❑ No
Mass
10.
Sulfate (as SO4)
(14808-79-8)
❑
❑
Concentration
Previously Reported
❑ Yes ❑ No
Mass
11.
Sulfide (as S)
❑
❑
Concentration
Previously Reported
El Yes ❑ No
Mass
EPA Form 3510-2D (Revised 3-19) Page 3

EPA Identification Number
Facility Name
Albemarle King's Mountain Mine
Outfall Number
01
Form Approved 03/05/19
OMB No. 2040-0004
TABLE B. CERTAIN CONVENTIONAL
AND NON CONVENTIONAL
POLLUTANTS (40 CFR 122.21(k)(5)(ii))'
Estimated Data for Pollutants Expected to be Present or Limited by an ELG
Provide both concentration and mass estimates for eachpollutant.)
Presence or Absence
check one
Pollutant
Believed
Present
Believed
Absent
Effluent
Intake Water
Units
Maximum Daily
Discharge
re wired
Average Daily
Discharge
if available
Source Information
(use codeess in instructions)
Believed Present?
(check only one
response per item)
12.
Sulfite (as S03)
(14265-45-3)
❑
Concentration
mg/L
2.0
Code 5 - Actual Water Quality
Data
❑� Yes ❑ No
Mass
Ibs
60,086,912
13.
Surfactants
❑
El❑Yes
Concentration
Previously Reported
❑ No
Mass
14.
Aluminum, total
(7429-90-5)
❑
❑
Concentration
Previously Reported
El Yes El No
Mass
15.
Barium, total
(7440-39-3)
❑
❑
Concentration
Previously Reported
❑ Yes ❑ No
Mass
16.
Boron, total
(7440-42-8)
❑
❑
Concentration
Previously Reported
❑ Yes ❑ No
Mass
17.
Cobalt, total
(7440-48-4)
❑
❑
Concentration
Previously Reported
El Yes ❑ No
Mass
18
Iron total
(7439-89-6)
❑
❑
Concentration
Previously Reported
❑ Yes ❑ No
Mass
19'
Magnesium, total
(7439-95-4)
❑
❑
Concentration
Previously Reported
El Yes ❑ No
Mass
20
Molybdenum, total
(7439-98-7)
❑
❑
Concentration
Previously Reported
❑ Yes ❑ No
Mass
21
Manganese, total
(7439-96-5)
❑
❑
Concentration
Previously Reported
❑ Yes ❑ No
Mass
22.
Tin total
(7440-31-5)
❑
❑
Concentration
Previously Reported
El Yes El No
Mass
EPA Form 3510-2D (Revised 3-19) Page 4

EPA Identification Number
Facility Name
Albemarle King's Mountain Mine
Outfall Number
01
Form Approved 03/05/19
OMB No. 2040-0004
TABLE B. CERTAIN CONVENTIONAL
AND NON CONVENTIONAL POLLUTANTS (40 CFR 122.21(k)(5)(ii))'
Presence or Absence
Estimated Data for Pollutants Expected to be Present or Limited by an ELG
check one
Provide both concentration and mass estimates for eachpollutant.)
Pollutant
Effluent
Intake Water
Maximum Daily
Average Daily
Source Information
Believed Present?
Believed
Believed
Present
Absent
Units
Discharge
Discharge
(use codeess in instructions)
(check only one
re uired
if available
response per item)
23.
Titanium, total
El
❑
Concentration
Previously Reported
El Yes ❑
Mass
(7440-32-6)
No
24.
Radioactivity
24.1
Alpha, total
❑
❑
Concentration
Previously Reported
❑Yes ❑ No
Mass
24.2
Beta, total
❑
❑
Concentration
Previously Reported
❑ Yes ❑ No
Mass
24.3.
Radium, total
❑
❑
Concentration
Previously Reported
❑ Yes ❑ No
Mass
24.4
Radium 226, total
❑
❑
Concentration
Previously Reported
❑ Yes ❑ No
Mass
1 Sampling shall be conducted according to sufficiently sensitive test procedures (i.e., methods) approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or
required under 40 CFR chapter I, subchapter N or 0. See instructions and 40 CFR 122.21(e)(3).
EPA Form 3510-2D (Revised 3-19) Page 5

This page intentionally left blank.

EPA Identification Number Facility Name Outfall Number Form Approved 03/05/19
Albemarle King's Mountain Mine 01 OMB No.2040-0004
TOXIC•TAL CYANIDE, AND TOTAL PHENOLS1
Presence or Absence Estimated Data for Pollutants Expected to be Present in Discharge
check one Provide both concentration and mass estimates for each pollutant.
Pollutant
(CAS Number, if available)
Believed
Present
Believed
Absent
Effluent
Intake Water
Units
Maximum
Daily
Discharge
(required)
Average
Daily
Discharge
if available
Source of Information
(Use codes in Instructions.)
Believed Present.
(Check only one
response per pollutant.)
❑
Check (✓) here if you believe all pollutants listed to be absent from the discharge. You need not complete Table C for the noted outfall unless you have quantitative data
available.
1.
Antimony, Total
(7440-36-0)
❑
❑
Concentration
Previously Reported
❑ Yes
❑ No
Mass
2.
Arsenic, Total
(7440-38-2)
❑
❑
Concentration
Previously Reported
❑ Yes
❑ No
Mass
3.
Beryllium, Total
(7440-41-7)
Concentration
Previously Reported
ElYes
❑ No
Mass
4.
Cadmium, Total
(7440-43-9)
❑
❑
Concentration
Previously Reported p
ElYes
ElNo
Mass
5.
Chromium, Total
(7440-47-3)
❑
❑
Concentration
Previously Reported
❑ Yes
❑ No
Mass
6.
Copper, Total
(7440-50-8)
❑
❑
Concentration
Previously Reported
❑ Yes
❑ No
Mass
7.
Lead, Total
(7439-92-1)
❑
❑
Concentration
Previously Reported
❑ Yes
❑ No
Mass
8.
Mercury, Total
(7439-97-6)
Concentration
Previously Reported
ElYes
ElNo
Mass
9.
Nickel, Total
(7440-02-0)
❑
❑
Concentration
Previously Reported p
ElYes
ElNo
Mass
10.
Selenium, Total
(7782-49-2)
❑
❑
Concentration
Previously Reported
❑ Yes
❑ No
Mass
11.
Silver, Total
(7440-22-4)
❑
❑
Concentration
Previously Reported
❑ Yes
❑ No
Mass
12.
Thallium, Total
(7440-28-0)
❑
❑
Concentration
Previously Reported p
ElYes
❑ No
Mass
13.
Zinc, Total
(7440-66-6)
Concentration
Previously Reported
ElYes
ElNo
Mass
14.
Cyanide, Total
(57-12-5)
Concentration
Previously Reported
ElYes
❑ No
Mass
15.
Phenols, Total
❑
Concentration
Code 5 - Actual Water
❑ Yes
0 No
Mass
1 Sampling shall be conducted according to sufficiently sensitive test procedures (i.e., methods) approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or
required under 40 CFR chapter I, subchapter N or 0. See Instructions and 40 CFR 122.21(e)(3).
EPA Form 3510-2D (Revised 3-19) Page 7

This page intentionally left blank.

EPA Identification Number
Facility Name Outfall Number
Albemarle King's Mountain Mine 01
Form Approved 03/05/19
OMB No.2040-0004
TABLE D. ORGANIC TOXIC'•LLUTANTS
Pollutant
(CAS Number, if available)
(Gas Chromatography/Mass
Presence or Absence
(check one)
S• • or • 1
Estimated Data for Pollutants Expected to Be Present in Discharge
(provide both concentration and mass estimates for each pollutant)
Believed
Present
Believed
Absent
Units
Effluent
Intake Water
Maximum
Daily
Discharge
Average
Daily
Discharge
Source of
Information
(use codes in instructions)
Believed Present?
(check only one response per
pollutant)
❑✓
Check here if all pollutants listed in Table D are expected to be absent from your facility's discharge.
❑
Check here if the facility believes it is exempt from Table D reporting requirements because it is a qualified small business. See the instructions for exemption criteria and for a list
of materials you must attach to the application.
Note: If you check either of the above boxes, you do not need to complete Table D for the noted outfall unless you have quantitative data available.
1.Organic Toxic Pollutants (GC/MS Fraction —Volatile Compounds)
1.1
Acrolein
(107-02-8)
❑
✓❑
Concentration
Code 5 Actual Water
Quality Data
El Yes ❑� No
Mass
1.2
Acrylonitrile
(107-13-1)
❑❑
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes ❑� No
Mass
1.3
Benzene
(71-43-2)
❑
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes ❑✓ No
Mass
1.4
Bromoform
(75-25-2)
❑
0Code
Concentration
5 Actual Water
Quality Data
❑ Yes 0 No
Mass
1.5
Carbon tetrachloride
(56-23-5)
❑
❑✓
Concentration
Code 5 -Actual Water
Quality Data
El Yes ❑� No
Mass
1.6
Chlorobenzene
(108-90-7)
❑
0Code
Concentration
5 Actual Water
Quality Data
El Yes ❑✓ No
Mass
1.7
Chlorodibromomethane
(124-48-1)
❑
❑✓
Concentration
Codes - Actual Water
Quality Data
El Yes ❑� NO
Mass
1.8
Chloroethane
(75-00-3)
❑
0
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes ❑� No
Mass
1.9
2-chloroethylvinyl ether
(110-75-8)
❑
❑✓
Concentration
Code 5 -Actual Water
Quality Data
❑Yes 0 No
Mass
1.10
Chloroform (67-66-3)
❑
❑
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes❑ No
Mass
1.11
Dichlorobromomethane
(75-27-4)
❑
❑�
Concentration
Code 5 -Actual Water
Quality Data
❑Yes ❑' NO
Mass
EPA Form 3510-21D (Revised 3-19) Page 9

EPA Identification Number
Facility Name Outfall Number
Albemarle King's Mountain Mine 01
Form Approved 03/05/19
OMB No.2040-0004
TABLE D. ORGANIC TOXIC'•LLUTANTS
Pollutant
(CAS Number, if available)
(Gas Chromatography/Mass
Presence or Absence
(check one)
S• • or • 1
Estimated Data for Pollutants Expected to Be Present in Discharge
(provide both concentration and mass estimates for each pollutant)
Believed
Present
Believed
Absent
Units
Effluent
Intake Water
Maximum
Daily
Discharge
Average
Daily
DISChar a
Source of
Information
(use codes in instructions)
Believed Present?
(check only one response per
pollutant)
1.12
1,1-dichloroethane
(75-34-3)
❑
❑s
Concentration
Code 5 -Actual Water
Quality Data
❑ Yes E No
Mass
1.13
1,2-dichloroethane
(107-06-2)
Concentration
Code 5 - Actual Water
Quality Data
ElYes IDNo
Mass
1.14
1,1-dichloroethylene
(75-35-4)
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes El No
Mass
1.15
1,2-dichloropropane
(78 87 5)
❑
❑✓
Concentration
Code 5 -Actual Water
Quality Data
❑Yes ❑� NO
Mass
1.16
1,3-dichloropropylene
(542-75-6)
❑
❑�
Concentration
Code 5 -Actual Water
Quality Data
❑Yes El No
Mass
1.17
Ethylbenzene
(100-41-4)
❑
❑✓
Concentration
Code 5 -Actual water
Quality Data
❑ Yes El No
Mass
1.18
Methyl bromide
(74-83-9)
❑
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes ❑� No
Mass
1.19
Methyl chloride
(74-87-3)
❑
Concentration
Code 5 - Actual Water
Quality Data
El Yes ❑� No
Mass
1.20
Methylene chloride
(75-09-2)
❑
❑✓
Concentration
Code 5 -Actual Water
Quality Data
❑Yes ❑� NO
Mass
1.21
1,1,2,2-tetrachloroethane
(79-34-5)
❑
❑✓
Concentration
Code 5 -Actual Water
Quality Data
❑Yes Z NO
Mass
1.22
Tetrachloroethylene
(127-18-4)
❑
❑�
Concentration
Code 5 -Actual Water
Quality Data
❑Yes '❑ NO
Mass
1.23
Toluene
(108-88-3)
❑
Concentration
Code 5 - Actual Water
Quality Data
El Yes ElNo
Mass
1.24
1,2-trans-dichloroethylene
(156-60-5)
❑
Concentration
Code 5 - Actual Water
Quality Data
El Yes ❑� No
Mass
EPA Form 3510-2D (Revised 3-19) Page 10

EPA Identification Number
Facility Name
Albemarle King's Mountain Mine
Outfall Number
01
Form Approved 03/05/19
OMB No.2040-0004
-TABLE D. ORGANIC TOXIC••LLUTANTS
Pollutant
(CAS Number, if available)
(Gas Chromatography/Mass
Presence or Absence
(check one)
S• • or • 1
Estimated Data for Pollutants Expected to Be Present in Discharge
(provide both concentration and mass estimates for each pollutant)
Believed
Present
Believed
Absent
Units
Effluent
Intake Water
Maximum
Daily
Discharge
Average
Daily
DISChar a
Source of
Information
(use codes in instructions)
Believed Present?
(check only one response per
pollutant)
1.25
1,1,1-trichloroethane
(71-55-6)
❑
❑✓
Concentration
Code 5 -Actual Water
Quality Data
❑Yes ❑� No
Mass
1.26
1,1,2-trichloroethane
(79-00-5)
❑
Concentration
Code 5 -Actual Water
Quality Data
❑ Yes ❑J No
Mass
1.27
Trichloroethylene
(79-01-6)
❑
Concentration
Code 5 - Actual Water
Quality Data
El Yes 0No
Mass
1.28
Vinyl chloride
(75-01-4)
El
❑�
Concentration
Code 5 Actual Water
Quality Data
❑ Yes ❑J No
Mass
2.Organic Toxic Pollutants (GC/MS Fraction —Acid Compounds)
2.1
2-chlorophenol
(95-57-8)
❑
0
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes ❑J No
Mass
2.2
2,4-dichlorophenol
(120-83-2)
❑
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes 0 No
Mass
2.3
2,4-dimethyl phenol
(105-67-9)
❑
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes ❑./ No
Mass
2.4
4,6-dinitro-o-cresol
(534-52-1)
❑
❑✓
Concentration
Code 5 -Actual Water
Quality Data
❑Yes ❑' No
Mass
2.5
2,4-dinitrophenol
(51-28-5)
❑
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes ❑J No
Mass
2.6
2-nitrophenol
(88-75-5)
❑
❑
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes No
Mass
2.7
4-nitrophenol
(100-02-7)
❑
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes ❑' No
Mass
2.8
p-chloro-m-cresol
(59-50-7)
❑
✓❑
Concentration
Code 5 -Actual Water
Quality Data
El Yes ID NO
Mass
2.9
Pentachlorophenol
(87-86-5)
❑
❑✓
Concentration
Code 5 -Actual Water
Quality Data
❑Yes ❑� No
Mass
EPA Form 3510-2D (Revised 3-19) Page 11

EPA Identification Number
Facility Name Outfall Number
Albemarle King's Mountain Mine 01
Form Approved 03/05/19
OMB No.2040-0004
TABLE D. ORGANIC TOXIC'•LLUTANTS
Pollutant
(CAS Number, if available)
(Gas Chromatography/Mass
Presence or Absence
(check one)
S• • or • 1
Estimated Data for Pollutants Expected to Be Present in Discharge
(provide both concentration and mass estimates for each pollutant)
Believed
Present
Believed
Absent
Units
Effluent
Intake Water
Maximum
Daily
Discharge
Average
Daily
DISChar a
Source of
Information
(use codes in instructions)
Believed Present?
(check only one response per
pollutant)
2.10
Phenol
(108-95-2)
❑
❑✓
Concentration
Code 5 Actual Water
Quality Data
❑ Yes ❑s No
Mass
2.11
2,4,6-trichlorophenol
(88-05-2)
❑
❑
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes ❑ No
Mass
3.Organic Toxic Pollutants (GC/MS Fraction —Base /Neutral Compounds)
3.1
Acenaphthene
(83-32-9)
❑❑
Concentration
Code 5 -Actual Water
Quality Data
Yes ❑� No
Mass
3.2
Acenaphthylene
(208-96-8)
❑
✓❑
Concentration
Code 5 Actual Water
Quality Data
El Yes ❑� No
Mass
3.3
Anthracene
(120-12-7)
❑
✓❑
Concentration
Code 5 -Actual Water
Quality Data
El Yes ❑' No
Mass
3.4
Benzidine
(92 87 5)
❑
❑�
Concentration
Code 5 -Actual Water
Quality Data
El Yes ❑' NO
Mass
3.5
Benzo (a) anthracene
(56-55-3)
❑
❑�
Concentration
Code 5 -Actual Water
Quality Data
❑Yes ❑' No
Mass
3.6
Benzo (a) pyrene
(50-32-8)
❑
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes ❑J No
Mass
3.7
3,4-benzofluoranthene
(205-99-2)
❑
❑
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes ❑ No
Mass
3.8
Benzo (ghi) perylene
(191-24-2)
❑
❑�
Concentration
Code 5 -Actual Water
Quality Data
El Yes 0 NO
Mass
3.9
Benzo (k) fluoranthene
(207-08-9)
❑
❑�
Concentration
Code 5 Actual Water
Quality Data
El Yes 0 No
M2SS
3.10
Bis (2-chloroethoxy) methane
(111-91-1)
❑
❑�
Concentration
Codes - Actual Water
Quality Data
El Yes 0 NO
Mass
3.11
Bis (2-chloroethyl) ether
(111-44-4)
❑
❑�
Concentration
Code 5 -Actual Water
Quality Data
❑Yes ❑' No
Mass
EPA Form 3510-2D (Revised 3-19) Page 12

EPA Identification Number
Facility Name Outfall Number
Albemarle King's Mountain Mine 01
Form Approved 03/05/19
OMB No.2040-0004
TABLE D. ORGANIC TOXIC'•LLUTANTS
Pollutant
(CAS Number, if available)
(Gas Chromatography/Mass
Presence or Absence
(check one)
S• • or • 1
Estimated Data for Pollutants Expected to Be Present in Discharge
(provide both concentration and mass estimates for each pollutant)
Believed
Present
Believed
Absent
Units
Effluent
Intake Water
Maximum
Daily
Discharge
Average
Daily
DISChar a
Source of
Information
(use codes in instructions)
Believed Present?
(check only one response per
pollutant)
3.12
Bis (2-chloroisopropyl) ether
(102-80-1)
❑
❑✓
Concentration
Code 5 -Actual Water
Quality Data
❑ Yes ❑� No
Mass
3.13
Bis (2-ethylhexyl) phthalate
(117-81-7)
❑
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes 0No
Mass
3.14
4-bromophenyl phenyl ether
(101-55-3)
❑
✓❑
Concentration
Code 5 -Actual Water
Quality Data
❑Yes 0 No
Mass
3.15
Butyl benzyl phthalate
(85-68-7)
❑
❑
Concentration
Code 5 - Actual Water
Quality Data
El Yes ❑ No
Mass
3.16
2-chloronaphthalene
(91-58-7)
❑❑
Concentration
Code 5 Actual Water
Quality Data
El Yes 0 No
M2SS
3.17
4-chlorophenyl phenyl ether
(7005-72-3)
❑
❑✓
Concentration
Code 5 Actual Water
Quality Data
El Yes ❑� No
Mass
3.18
Chrysene
(218-01-9)
❑
❑✓
Concentration
Code 5 -Actual Water
Quality Data
❑ Yes ❑� No
Mass
3.19
Dibenzo (a,h) anthracene
(53-70-3)
❑
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes ❑� No
Mass
3.20
1,2-dichlorobenzene
(95-50-1)
❑
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes ❑' No
Mass
3.21
1,3-dichlorobenzene
(541-73-1)
❑
❑
Concentration
Code 5 - Actual Water
Quality Data
El Yes ElNo
Mass
3.22
1,4-dichlorobenzene
(106-46-7)
❑
LI
Concentration
Code 5 Actual Water
Quality Data
El Yes 0 No
M2SS
3.23
3,3-dichlorobenzidine
(91-94-1)
❑
�
Concentration
CodeS- Actual Water
Quality Data
El Yes ❑� NO
Mass
3.24
Diethyl phthalate
(84-66-2)
❑
❑�
Concentration
Code 5 -Actual Water
Quality Data
❑Yes ❑� No
Mass
3.25
Dimethyl phthalate
(131-11-3)
❑
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes 0No
Mass
EPA Form 3510-2D (Revised 3-19) Page 13

EPA Identification Number
Facility Name Outfall Number
Albemarle King's Mountain Mine 01
Form Approved 03/05/19
OMB No.2040-0004
TABLE D. ORGANIC TOXIC'•LLUTANTS
Pollutant
(CAS Number, if available)
(Gas Chromatography/Mass
Presence or Absence
(check one)
S• • or • 1
Estimated Data for Pollutants Expected to Be Present in Discharge
(provide both concentration and mass estimates for each pollutant)
Believed
Present
Believed
Absent
Units
Effluent
Intake Water
Maximum
Daily
Discharge
Average
Daily
DISChar a
Source of
Information
(use codes in instructions)
Believed Present?
(check only one response per
pollutant)
3.26
Di-n-butyl phthalate
(84-74-2)
❑
❑�
Concentration
Code 5 -Actual Water
Quality Data
❑Yes 0 No
Mass
3.27
2,4-dinitrotoluene
(121-14-2)
❑
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes 0No
Mass
3.28
2,6-dinitrotoluene
(606-20-2)
❑
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes 0No
Mass
3.29
Di-n-octyl phthalate
(117-84-0)
❑
Concentration
Code 5 - Actual Water
Quality Data
El Yes ❑� No
Mass
3.30
1,2-diphenylhydrazine
(as azobenzene) (122-66 7)
❑
❑'
Concentration
Code 5 Actual Water
Quality Data
El Yes ❑' No
Mass
3.31
Fluoranthene
(206-44-0)
❑
❑�
Concentration
Code 5 Actual Water
Quality Data
El Yes ❑� No
Mass
3.32
Fluorene
(86-73-7)
❑❑
Concentration
Code 5 -Actual Water
Quality Data
El Yes 0 No
Mass
3.33
Hexachlorobenzene
(118-74-1)
❑
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes 0No
Mass
3.34
Hexachlorobutadiene
(87-68-3)
❑
❑
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes ❑ No
Mass
3.35
Hexachlorocyclopentadiene
(77-47-4)
❑
❑
Concentration
Code 5 - Actual Water
Quality Data
El Yes ❑ No
Mass
3.36
Hexachloroethane
(67-72-1)
❑❑
Concentration
Code 5 -Actual Water
Quality Data
El Yes ❑� NO
Mass
3.37.
Indeno (1,2,3-cd) pyrene
(193-39-5)
❑
�
Concentration
Code 5 -Actual Water
Quality Data
El Yes ❑� NO
Mass
3.38
Isophorone
(78-59-1)
❑❑
Concentration
Code 5 -Actual Water
Quality Data
❑Yes 0 No
Mass
3.39
Naphthalene
(91-20-3)
❑
❑�
Concentration
Code 5 -Actual Water
Quality Data
❑ Yes ❑� No
Mass
EPA Form 3510-2D (Revised 3-19) Page 14

EPA Identification Number
Facility Name Outfall Number
Albemarle King's Mountain Mine 01
Form Approved 03/05/19
OMB No.2040-0004
TABLE D. ORGANIC TOXIC'•LLUTANTS
Pollutant
(CAS Number, if available)
(Gas Chromatography/Mass
Presence or Absence
(check one)
S• • or • 1
Estimated Data for Pollutants Expected to Be Present in Discharge
(provide both concentration and mass estimates for each pollutant)
Believed
Present
Believed
Absent
Units
Effluent
Intake Water
Maximum
Daily
Discharge
Average
Daily
DISChar a
Source of
Information
(use codes in instructions)
Believed Present?
(check only one response per
pollutant)
3.40
Nitrobenzene
(98-95-3)
❑
❑�
Concentration
Code 5 -Actual Water
Quality Data
❑Yes 0 No
Mass
3.41
N-nitrosodimethylamine
(62-75-9)
❑
Concentration
Code 5 - Actual Water
Quality Data
El Yes ID No
Mass
3.42
N-nitrosodi-n-propylamine
(621-64-7)
❑
Concentration
Code 5 - Actual Water
Quality Data
El Yes ❑� No
Mass
3.43
N-nitrosodiphenylamine
(86-30-6)
❑
Concentration
Code 5 - Actual Water
Quality Data
El Yes ID No
Mass
3.44
Phenanthrene
(85-01-8)
❑
❑�
Concentration
Code 5 -Actual Water
Quality Data
El Yes ID NO
Mass
3.45
Pyrene
(129-00-0)
❑
❑�
Concentration
Code 5 Actual Water
Quality Data
El Yes ID No
Mass
3.46
1,2,4-trichlorobenzene
(120-82-1)
❑
✓❑
Concentration
Code 5 -Actual Water
Quality Data
❑ Yes ❑� No
Mass
4.Organic Toxic Pollutants (GC/MS Fraction —Pesticides)
4.1.
Aldrin
(309-00-2)
❑
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes ❑� No
Mass
4.2
a-BHC
(319-84-6)
❑❑
Concentration
Code 5 -Actual Water
Quality Data
Yes ❑� No
Mass
4.3
R-BHC
(319-85-7)
❑
❑
Concentration
Code 5 - Actual Water
Quality Data
El Yes � No
Mass
4.4
y-BHC
(58 89 9)
❑
❑
Concentration
Code 5 -Actual Water
Quality Data
El Yes 0 NO
Mass
4.5
b-BHC
(319-86-8)
❑
❑✓
Concentration
Code 5 Actual Water
Quality Data
El Yes 0 No
M2SS
4.6
Chlordane
(57-74-9)
❑
❑�
Concentration
Code 5 -Actual Water
Quality Data
❑Yes ❑� No
Mass
EPA Form 3510-2D (Revised 3-19) Page 15

EPA Identification Number
Facility Name Outfall Number
Albemarle King's Mountain Mine 01
Form Approved 03/05/19
OMB No.2040-0004
TABLE D. ORGANIC TOXIC'•LLUTANTS
Pollutant
(CAS Number, if available)
(Gas Chromatography/Mass
Presence or Absence
(check one)
S• • or • 1
Estimated Data for Pollutants Expected to Be Present in Discharge
(provide both concentration and mass estimates for each pollutant)
Believed
Present
Believed
Absent
Units
Effluent
Intake Water
Maximum
Daily
Discharge
Average
Daily
DISChar a
Source of
Information
(use codes in instructions)
Believed Present?
(check only one response per
pollutant)
4.7
4,4'-DDT
(50-29-3)
❑
❑�
Concentration
Code 5 Actual Water
Quality Data
❑ Yes ❑J No
Mass
4.8
4,4'-DDE
(72-55-9)
❑
Concentration
Code 5 - Actual Water
Quality Data
Yes ❑� No
Mass
4.9
4,4'-DDD
(72-54-8)
❑
❑
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes ❑ No
Mass
4.10
Dieldrin
(60-57-1)
❑
❑
Concentration
Code 5 - Actual Water
Quality Data
El ❑ No
Mass
4.11
a-endosulfan
(115-29-7)
❑
❑✓
Concentration
Code 5 -Actual Water
Quality Data
Yes ❑� No
Mass
4.12
R-endosulfan
(115-29-7)
❑
❑✓
Concentration
Code 5 -Actual Water
Quality Data
Yes ❑' NO
Mass
4.13
Endosulfan sulfate
(1031-07-8)
Concentration
Code 5 -Actual Water
Quality Data
ElYes ❑s No
Mass
4.14
Endrin
(72-20-8)
❑
❑✓
Concentration
Code 5 -Actual Water
Quality Data
El Yes 0 No
Mass
4.15
Endrin aldehyde
(7421-93-4)
❑
❑✓
Concentration
Code 5 - Actual Water
Quality Data
El Yes ❑s No
Mass
EPA Form 3510-2D (Revised 3-19) Page 16

EPA Identification Number
Facility Name Outfall Number
Albemarle King's Mountain Mine 01
Form Approved 03/05/19
OMB No.2040-0004
TABLE D. ORGANIC TOXIC'•LLUTANTS
Pollutant
(CAS Number, if available)
(Gas Chromatography/Mass
Presence or Absence
(check one)
S• • or • 1
Estimated Data for Pollutants Expected to Be Present in Discharge
(provide both concentration and mass estimates for each pollutant)
Believed
Present
Believed
Absent
Units
Effluent
Intake Water
Maximum
Daily
Discharge
Average
Daily
DISChar a
Source of
Information
(use codes in instructions)
Believed Present?
(check only one response per
pollutant)
4.16
Heptachlor
(76-44-8)
❑
❑�
Concentration
Code 5 Actual Water
Quality Data
❑ Yes ❑� No
Mass
4.17
Heptachlor epoxide
(1024-57-3)
❑
0
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes ❑� No
Mass
4.18
PCB-1242
(53469-21-9)
❑
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes ❑� No
Mass
4.19
PCB-1254
(11097-69-1)
❑
❑✓
Concentration
Code 5 Actual water
Quality Data
El Yes 2 No
Mass
4.20
PCB-1221
(11104-28-2)
❑
❑✓
Concentration
Code 5 Actual water
Quality Data
El Yes 0 No
Mass
4.21
PCB-1232
(11141-16-5)
❑
❑✓
Concentration
Code 5 Actual water
Quality Data
El Yes ❑/ No
Mass
4.22
PCB-1248
(12672-29-6)
❑
❑�
Concentration
Code 5 Actual Water
Quality Data
❑ Yes ❑� No
Mass
4.23
PCB-1260
(11096-82-5)
❑
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes ❑' No
Mass
4.24
PCB-1016
(12674-11-2)
❑
Concentration
Code 5 - Actual Water
Quality Data
❑ Yes ❑' No
Mass
4.25
Toxaphene
(8001-35-2)
❑
❑✓
Concentration
Code 5 Actual water
Quality Data
❑ Yes 0 No
Mass
1 Sampling shall be conducted according to sufficiently sensitive test procedures (i.e., methods) approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or
required under 40 CFR chapter I, subchapter N or 0. See instructions and 40 CFR 122.21(e)(3).
EPA Form 3510-2D (Revised 3-19) Page 17

This page intentionally left blank.

EPA Identification Number
Facility Name
Albemarle King's Mountain Mine
Outfall Number
01
Form Approved 03/05/19
OMB No. 2040-0004
FTABLE E. CERTAIN 'D•
Pollutant
• 1
Presence or Absence
(check one)
Reason Pollutant Believed Present in Discharge Available Quantitative Data
(specify units)
Believed
Present
Believed
Absent
❑✓
Check (✓) here if you believe all pollutants listed to be absent from the discharge. You need not complete Table E for the noted outfall unless you have quantitative data available.
1.
Asbestos
❑
❑
2.
Acetaldehyde
❑
❑
3.
Allyl alcohol
❑
❑
4.
Allyl chloride
❑
❑
5.
Amyl acetate
❑
❑
6.
Aniline
❑
❑
7.
Benzonitrile
❑
❑
8.
Benzyl chloride
❑
❑
9.
Butyl acetate
❑
❑
10.
Butylamine
❑
❑
11.
Captan
❑
❑
12.
Carbaryl
❑
❑
13.
Carbofuran
❑
❑
14.
Carbon disulfide
❑
❑
15.
Chlorpyrifos
❑
❑
16.
Coumaphos
❑
❑
17.
Cresol
❑
❑
18.
Crotonaldehyde
❑
❑
EPA Form 3510-2D (Revised 3-19) Page 19

EPA Identification Number
Facility Name
Albemarle King's Mountain Mine
Outfall Number
01
Form Approved 03/05/19
OMB No. 2040-0004
FTABLE E. CERTAIN 'D•
Pollutant
• 1
Presence or Absence
check one)
Reason Pollutant Believed Present in Discharge
Available Quantitative Data
(specify units)
Believed
Present
Believed
Absent
19.
Cyclohexane
❑
❑
20.
2,4-D (2,4-dichlorophenoxyacetic acid)
❑
❑
21.
Diazinon
❑
❑
22.
Dicamba
❑
❑
23.
Dichlobenil
❑
❑
24.
Dichlone
❑
❑
25.
2,2-dichloropropionic acid
❑
❑
26.
Dichlorvos
❑
❑
27.
Diethyl amine
❑
❑
28.
Dimethyl amine
❑
❑
29.
Dintrobenzene
❑
❑
30.
Diquat
❑
❑
31.
Disulfoton
❑
❑
32.
Diuron
❑
❑
33.
Epichlorohydrin
❑
❑
34.
Ethion
❑
❑
35.
Ethylene diamine
❑
❑
36.
Ethylene dibromide
❑
❑
37.
Formaldehyde
❑
❑
EPA Form 3510-2D (Revised 3-19) Page 20

EPA Identification Number
Facility Name
Albemarle King's Mountain Mine
Outfall Number
01
Form Approved 03/05/19
OMB No. 2040-0004
FTABLE E. CERTAIN 'D•
Pollutant
• 1
Presence or Absence
(check one)
Reason Pollutant Believed Present in Discharge
Available Quantitative Data
(specify units)
Believed
Present
Believed
Absent
38.
Furfural
❑
❑
39.
Guthion
❑
❑
40.
Isoprene
❑
❑
41.
Isopropanolamine
❑
❑
42.
Kelthane
❑
❑
43.
Kepone
❑
❑
44.
Malathion
❑
❑
45.
Mercaptodimethur
❑
❑
46.
Methoxychlor
❑
❑
47.
Methyl mercaptan
❑
❑
48.
Methyl methacrylate
❑
❑
49.
Methyl parathion
❑
❑
50.
Mevinphos
❑
❑
51.
Mexacarbate
❑
❑
52.
Monoethyl amine
❑
❑
53.
Monomethyl amine
❑
❑
54.
Naled
❑
❑
55.
Naphthenic acid
❑
❑
56.
Nitrotoluene
❑
❑
EPA Form 3510-2D (Revised 3-19) Page 21

EPA Identification Number
Facility Name
Albemarle King's Mountain Mine
Outfall Number
01
Form Approved 03/05/19
OMB No. 2040-0004
FTABLE E. CERTAIN 'D•
Pollutant
• 1
Presence or Absence
check one)
Reason Pollutant Believed Present in Discharge
Available Quantitative Data
(specify units)
Believed
Present
Believed
Absent
57.
Parathion
❑
❑
58.
Phenolsulfonate
❑
❑
59.
Phosgene
❑
❑
60.
Propargite
❑
❑
61.
Propylene oxide
❑
❑
62.
Pyrethrins
❑
❑
63.
Quinoline
❑
❑
64.
Resorcinol
❑
❑
65.
Strontium
❑
❑
66.
Strychnine
❑
❑
67.
Styrene
❑
❑
68
2,4 5-T (2,4,5-trichlorophenoxyacetic
acid
❑
❑
69.
TDE (tetrachlorodiphenyl ethane)
❑
❑
70
2,4,5-TP [2-(2,4,5-trichlorophenoxy)
propanoic acid]
❑
❑
71.
Trichlorofon
❑
❑
72.
Triethanolamine
❑
❑
73.
Triethylamine
❑
❑
74.
Trimethylamine
❑
❑
75.
Uranium
❑
❑
EPA Form 3510-2D (Revised 3-19) Page 22

EPA Identification Number
Facility Name
Albemarle King's Mountain Mine
Outfall Number
01
Form Approved 03/05/19
OMB No. 2040-0004
FTABLE E. CERTAIN 'D•
Pollutant
• 1
Presence or Absence
check one)
Reason Pollutant Believed Present in Discharge
Available Quantitative Data
(specify units)
Believed
Present
Believed
Absent
76.
Vanadium
❑
❑
77.
Vinyl acetate
❑
❑
78.
Xylene
❑
❑
79.
Xylenol
❑
❑
80.
Zirconium
❑
❑
1 Sampling shall be conducted according to sufficiently sensitive test procedures (i.e., methods) approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or
required under 40 CFR chapter I, subchapter N or 0. See instructions and 40 CFR 122.21(e)(3).
Click to go back to the beginning of Form
EPA Form 3510-2D (Revised 3-19) Page 23

Application Form 2D
Section 4 Attachment
Line Drawing

EA I
PIPE FITTINGS
{{�
EXPANSION JOINT
i-
FLANGE SET
r\ �
FLEXIBLE HOSE
-�
HOSE CONNECTION
ORIFICE FLANGES w/ PLATE
{o-
QUICK DISCONNECT
{
REDUCER, CONC.
{
REDUCER,ECC
RUPTURE DISK
THREADED CAP
I-
VICTAULIC COUPLING
WELDED CAP
AIR GAP
BLANK
SPACER
SPEC BLIND (CLOSED)
•
SPEC BLIND (OPEN)
INSTRUMENTATION SYMBOLS
BASKET STRAINER
Y-STRAINER
INLINE MIXER
MAGNETIC METER
PROPELLER METER
-1' lj ULTRASONIC METER
ROTOMETER
ROTOMETER
✓ �_% W/ INTEGRAL VALVE
VENTURI
DIAPHRAGM ISOLATOR
CALIBRATION COLUMN
PRESSURE ELEMENT
RADAR LEVEL ELEMENT
VALVE SYMBOLS
BACKFLOW PREVENTION VALVE
BALL VALVE
BALL FLOAT VALVE
• BUTTERFLY VALVE
�1 CHECK BALL VALVE
CORP STOP
CHECK VALVE
DIAPHRAGM VALVE
DIVERTER VALVE
GATE VALVE
Cam" I GLOBE VALVE
KNIFE VALVE
C� NEEDLE VALVE
Gj PINCH VALVE
[:3'� J PLUG VALVE
ROTARY VALVE
Al PRESSURE RELIEF VALVE
PRESSURE AND VACUUM RELIEF VALVE
PIPE LINE IDENTIFICATION
PIPE NUMBER LEGEND
LINE SERVICE SPECIFICATION
LINE NUMBER
SIZE INSULATION
IF REQUIRED
4"-100-WA-CSA1-HETi
OFF PAGE CONNECTOR
SERVICE
;> DRAWING NO
ORIGIN OR DESTINATION
OFF PAGE CONNECTOR (OFF -SCOPE PIPING)
SERVICE
ACTUATOR TYPES
BACK PRESSURE REGULATOR
FLOW
CYLINDRICAL ACTUATOR
DIAPHRAGM ACTUATOR
ELECTRIC ACTUATOR
FLOAT ACTUATOR
PISTON ACTUATOR
DIAPHRAGM ACTUATOR
� PRESSURE REDUCING REGULATOR
Pop- FLOW
iMj)
MOTOR ACTUATOR
SOLENOID ACTUATOR
LINE TYPES
PRIMARY PROCESS
PRIMARY PROCESS (EXISTING/FUTURE)
SECONDARY PROCESS
SECONDARY PROCESS (EXISTING/FUTURE)
TERTIARY PROCESS
TERTIARY PROCESS (EXISTING/FUTURE)
ELECTRICAL LEAD
PNEUMATIC SIGNAL
-0-0-0-0-0-0-0-0- DIGITAL SIGNAL
CAPILLARY TUBING
HYDRAULIC SIGNAL
ELECTROMAGNETIC SIGNAL
MECHANICAL LINK
C- C COPPER ETHERNET
F-F-F-F-F-F FIBER
M-M-M-M-M-M MODBUS
P-P-P-P-P-P PROFIBUS
INSULATION AND HEAT TRACING
SYMBOLS
INSULATED
INSULATED & TRACED
ABBREVIATIONS
ABBRV DESCRIPTION
IH INSULATION, HEAT RETENTION
HET INSULATION, ELECTRIC TRACING
PIPING SERVICES
ABBRV
DESCRIPTION
BA
BLOWER AIR
BR
BRINE
BW
BACKWASH
CH
CHEMICAL ADDITION
DW
POTABLE WATER
FW
FIRE WATER
GC
GLYCOL
IA
INSTRUMENT AIR
MW
MAKEDOWN WATER
N G
NATURAL GAS
PA
PLANT AIR
PW
PROCESS WATER
RW
RAW WATER
SC
SCUM
SW
SOFTENED WATER
TW
TREATED WATER
WA
FRESH/WELL WATER
WW
WASTE WATER
XR
EXCESS RECIRCULATION
TUBING SPECIFICATIONS
ABBRV DESCRIPTION
HDPE HIGH DENSITY POLYETHYLENE TUBING
LDPE LOW DENSITY POLYETHYLENE TUBING
PTFE PTFE (TEFLON) TUBING
PVDF POLYVINYLIDENE DIFLUORIDE (VITON) TUBING
PP POLYPROPYLENE TUBING
PU POLYURETHANE TUBING
TU TUBING (NON-SPECIFIC)
PIPE SPECIFICATIONS
ABBRV DESCRIPTION
ABS ACRYLONITRILE BUTADIENE STYRENE PIPE
PE11 HIGH DENSITY POLYETHYLENE - DR 11
PE17 HIGH DENSITY POLYETHYLENE - DR 17
PP1 POLYPROPYLENE PIPE
CPVC CHLORINATED POLYVINYL CHLORIDE
PVC POLYVINYL CHLORIDE
CSA1 CARBON STEEL PRESSURE CLASS 150 PSI
CSA2 CSA1 - EPDXY COATED
CSB1 CARBON STEEL PRESSURE CLASS 300 PSI
CSB2 CSB2 - EPDXY COATED
SA1 STAINLESS STEEL PRESSURE CLASS 150 PSI
SB1 STAINLESS STEEL PRESSURE CLASS 300 PSI
FUSED CONN.
THREADED CONN.
SOCKETWELD CONN.
SLOPE
RISE/RUN
PIPE SLOPE
� FLOW ARROW
CENTRIFUGAL PUMP
INSTRUMENT SYMBOLS
HMI/SCADA POINT
1 - INSTRUMENT TAG
2 - LOOP
{�{
3
3 -FUNCTION
� 7
4
4 - DESCRIPTION
2
6
5 - POINT NUMBER
6 - LOCATION
PLC 1/0 POINT
1 - INSTRUMENT TAG
2 - LOOP
4
3 - 1/0 TYPE
{
5
4-ADDRESS
6
5 - DESCRIPTION
6 - DESCRIPTION
PRIMARY POWER DEVICE
1 - INSTRUMENT TAG
3
2-LOOP
4
3-TYPE
2
5
4 - DESCRIPTION
6
5 - VOLTAGE
6 - LOCATION
INSTRUMENT/CONTROL
ELEMENT
PRIMARY OPERATED
1 - INSTRUMENT TAG
2-LOOP
4
3 - FUNCTION
2
5
4 - DESCRIPTION
---
6
5 - DESCRIPTION
6 - LOCATION
FIELD INSTRUMENT
PRIMARY ELEMENT
1 - INSTRUMENT TAG
2-LOOP
n
4
3 - FUNCTION
2
5
4 - DESCRIPTION
6
5 - DESCRIPTION
6 - LOCATION
PRIMARY FIELD EQUIPMENT POWERED
1 - INSTRUMENT TAG
2-LOOP
�4
3
3 - FUNCTION
5
4 - DESCRIPTION
6
5 - FURNISHED BY
6 - LOCATION
LINE SYMBOLS
EE:---:DC
DIAPHRAGM PUMP
CSA1
GEAR PUMP
CSB1
BATTERY
LIMIT
SUMP PUMP
TIE POINT SYMBOL
TO DRAIN SYSTEM
SPEC BREAK
BATTERY LIMIT
PUMP SYMBOLS
�nl
POSITIVE
DISPLACEMENT
PUMP
COMMON ABBREVIATIONS
ANALYSIS TEMPERATURE
AE ANALYSIS ELEMENT TE TEMPERATURE ELEMENT
AIT ANALYSIS INDICATING TRANSMITTER TT TEMPERATURE TRANSMITTER
ACV
FE
FT
FIT
FI
FS
FSL
FSH
FAL
FAH
FCV
TIT TEMPERATURE INDICATING TRANSMITTER
TI TEMPERATURE INDICATOR
STATIC MIXER TC TEMPERATURE CONTROLLER
ACTUATED CONTROL VALVE (OPEN CLOSE) TS TEMPERATURE SWITCH
FLOW ELEMENT TSL TEMPERATURE SWITCH LOW
FLOW TRANSMITTER TSH TEMPERATURE SWITCH HIGH
FLOW INDICATING TRANSMITTER TAL TEMPERATURE ALARM LOW
FLOW INDICATOR TAH TEMPERATURE ALARM HIGH
FLOW SWITCH TCV TEMPERATURE CONTROL VALVE
FLOW SWITCH LOW
FLOW SWITCH HIGH
FLOW ALARM LOW
FLOW ALARM HIGH
FLOW CONTROL VALVE (POSITIONING)
CURRENT
IT CURRENT TRANSMITTER
IIT CURRENT INDICATING TRANSMITTER
IY CURRENT TRANSDUCER
II CURRENT INDICATOR
IS CURRENT SWITCH
ISL CURRENT SWITCH LOW
ISH CURRENT SWITCH HIGH
IPY CURRENT TO PRESSURE TRANSDUCER
LEVEL
LE
LEVEL ELEMENT
LT
LEVEL TRANSMITTER
LIT
LEVEL INDICATING TRANSMITTER
LI
LEVEL INDICATOR
LS
LEVEL SWITCH
LSL
LEVEL SWITCH LOW
LSH
LEVEL SWITCH HIGH
LAL
LEVEL ALARM LOW
LAH
LEVEL ALARM HIGH
LCV
LEVEL CONTROL VALVE
PRESSURE
PE PRESSURE ELEMENT
PT PRESSURE TRANSMITTER
PIT PRESSURE INDICATING TRANSMITTER
PI PRESSURE INDICATOR
PS PRESSURE SWITCH
PSL PRESSURE SWITCH LOW
PSH PRESSURE SWITCH HIGH
PAL PRESSURE ALARM LOW
PAH PRESSURE ALARM HIGH
PCV PRESSURE CONTROL VALVE
PRV PRESSURE REDUCING VALVE
DIFFERENTIAL PRESSURE
PDT
DIFF
PRESSURE TRANSMITTER
PDIT
DIFF
PRESSURE INDICATING TRANSMITTER
PDI
DIFF
PRESSURE INDICATOR
PDS
DIFF
PRESSURE SWITCH
PDSL
DIFF
PRESSURE SWITCH LOW
PDSH
DIFF
PRESSURE SWITCH HIGH
PDAL
DIFF
PRESSURE ALARM LOW
PDAH
DIFF
PRESSURE ALARM HIGH
PDCV
DIFF
PRESSURE CONTROL VALVE
ZJ^lJ^lJ^lJ^lJ^
PROGRESSIVE CAVITY PUMP
DIFFERENTIAL TEMPERATURE
TDT DIFF TEMPERATURE TRANSMITTER
TDIT DIFF TEMPERATURE INDICATING TRANSMITTER
TDI DIFF TEMPERATURE INDICATOR
TDS DIFF TEMPERATURE SWITCH
TDSL DIFF TEMPERATURE SWITCH LOW
TDSH DIFF TEMPERATURE SWITCH HIGH
TDAL DIFF TEMPERATURE ALARM LOW
TDAH DIFF TEMPERATURE ALARM HIGH
TDCV DIFF TEMPERATURE CONTROL VALVE
POSITION
ZIT POSITION INDICATING TRANSMITTER
ZIC POSITION INDICATOR CLOSED
ZC POSITION CONTROLLER SWITCH CLOSED
ZO POSITION SWITCH OPEN
ZIO POSITION INDICATOR OPEN
P&ID PILOT DEVICE
HSA
HAND -OFF -AUTO SWITCH
HSLR
LOCAL -OFF -REMOTE SWITCH
HSS
START -STOP SWITCH
PBST
START PUSH BUTTON
PBSP
STOP PUSH BUTTON
PBOP
OPEN PUSH BUTTON
PBCL
CLOSE PUSH BUTTON
PBON
ON PUSH BUTTON
PBOF
OFF PUSH BUTTON
PBES
EMERGENCY STOP PUSH BUTTON
PBR
RESET PUSH BUTTON
PBUP
PUSH BUTTON UP
PBDN
PUSH BUTTON DN
PBRT
PUSH BUTTON RIGHT
PBLF
PUSH BUTTON LEFT
MISCELLANEOUS
EPS ELECTRIC TO PNEUMATIC SWITCH
MS MOTOR STARTER
HT MOISTURE/HUMIDITY TRANSMITTER
HV HAND VALVE
SP STATIC PRESSURE
QT QUANTITY TRANSMITTER
QP PRESSURE SETPOINT
SI SPEED INDICATION
ST SPEED TRANSMITTER
UY MULTI -VARIABLE CONVERTER
XV SOLENOID VALVE
YA STATUS ALARM
YR STATUS RUNNING
DEEP WELL PUMP SUBMERSIBLE PUMP
A ISSUED FOR REVIEW
REV # DESCRIPTION
--- --- --- KINGS MOUNTAIN
--- /A�T�RF /A�RT�F
ALL L M 11 V LETM
.. U�C 0 R P 0 R A T 1 0 N 348 HOLIDAY INN DRIVE
KINGS MOUNTAIN, NC 28286
This drawing is the confidential property of Albemarle Corporation and is issued with the express understanding and agreement that it
is not to be copied or reproduced, or used in any way detrimental to the interest of Albemarle Corporation and is to be returned on request.
--- --- --- --- KM 60 - MINE
--- --- --- --- PIT D E WATE R I N G
--- --- --- --- PIPING & INSTRUMENTATION DIAGRAM
--- --- --- --- RAW WATER FEED
JOB NO. DRAFTER: DRAWING NO. SHT. NO. REVISION
--- --- --- ---
125.01 JLB
JLB MWU HIM 05/17/2023 SCALE: DATE KM60-PR-PI-00201 1 A
CADD CHK'D APPR'D DATE AS NOTED 05/17/2023
F
E
791
r�
In
FAIMill

Application Form 2D
Section 8 Attachment
Engineering Report

Linkan
E N G I N E E R I N G
MEMORANDUM
DATE: March 14, 2023
TO: Morgan Warren
FROM: Sam Billin, P.E.
SUBJECT: Water Treatment Design Basis Memorandum
REFERENCE NO.: Albemarle Pit Dewatering Analysis, 125.01 137 Revl
OBJECTIVE
The purpose of this memorandum is to define the Basis of Design for a pit dewatering water
treatment system to be located at Albemarle's Kings Mountain mine.
The purpose of treatment is to lower the concentration of ammonia and sulfide species and other
constituents of concern (COCs) in the dewatering flows and enable discharge of treated effluent
to South Creek Reservoir. South Creek Reservoir discharges into Kings Creek. Kings Creek forms
part of the Broad River watershed deemed by the NC DEQ as Class C per ERM's report. Kings
Mountain (KM) pit water exceeds NC DEQ Class C reference values for various constituents.
DESIGN BASIS
Discharge Flow Rate
The requested discharge effluent flow rate to South Creek Reservoir is 2,000 gpm. Linkan will
perform a series of desktop models to predict flows based on achievable recovery. The objective
of the project is to treat roughly 1,300,000,000 gallons of retained pit water so as to facilitate mine
development. This effort is estimated to take between 15 and 16 months at the designated flowrate.
Location
Albemarle has recommended that the WTP be placed on the east side of the pit at the bottom of
the existing ramp or adjacent to the pavilion. Consideration of placing the WTP higher on the
bench southwest of the pit was abandoned after consideration of the blasting requirements to lay
in a pipeline line to the barge pumps.
Discharge Water Quality Standards
A permit application to discharge has been filed in November 2022. A permit has not been issued.
For this design basis memorandum, Linkan Engineering will use the NC DEQ Class C reference
values to assess treatment options. The NC DEQ Class C and In -Stream Target values are indicated
in Table 1 and are compared to the water quality results from the KM pit.
Linkan Engineering
2720 Ruby Vista Drive, Suite 101, Elko, Nevada 89801
Office: 775.777.8003

Feed Water Quality
The pit water will provide influent to the treatment system. Work has been conducted by SRK and
Linkan to sample and determine the current water quality from the pit. It was identified that at a
depth of 130-140 ft, water conditions vary from higher elevations. The focus of the design basis is
treatability at these depths. It is anticipated that upper elevations of water contain fewer
contaminants and that the full treatment may not be required on the entire water column.
We also anticipate that the lower reaches of the pit (150-165 feet) will be a difficult mix of settled
solids, sludge, organic matter, and other deposits. We anticipate that additional efforts and/or
changes to the treatment system may be required as we reach the end of the project and need to
modify to accommodate this last volume of water. Based on the supplied Stage/Storage curve, this
last 15 feet of water (150-165 feet) represents about 17 million gallons or 1.3% of the total project
volume, based on reported pit elevation of 816.55 ft as of February 6th, 2023. Accordingly, the
basis of design will focus on the 0-150 feet of depth at this time.
Table 1: Pit Water Analytical
PL-
PL-
PL-
DEEP-
DEEP-
PL-
PL-
NC DEQ
E Q
DEEP-80
DEEP-
DEEP-
130
130
DEEP-
DEEP -
Parameter
100
120
140
160
Class C
09/22/22
09/22/22
09/22/22
12/15/22
12/22/22
09/22/22
09/22/22
Stream
As
Treated
Received
Aluminum,
mg/L
<0.005
0.0076
<0.005
0.0593
0.0514
<0.005
0.0105
dissolved
Aluminum,
mg/L
0.106
<0.005
<0.005
0.0588
0.0542
0.0051
0.0077
total
Antimony,
mg/L
<0.0004
<0.0004
<0.0004
<0.0004
<0.0004
dissolved
Antimony,
mg/L
0.64
<0.0004
<0.0004
<0.0004
<0.0004
<0.0004
total
Acute:
Arsenic,
mg/L
0.340
0.00389
0.0032
0.00274
0.00278
0.00533
dissolved
Chronic:
0.150
Arsenic, total
mg/L
0.01
0.00541
0.00506
0.00504
0.00503
0.0065
Barium,
mg/L
<0.009
<0.009
<0.009
<0.009
0.0372
dissolved
Barium, total
mg/L
200
0.0139
0.0135
0.0134
0.0131
0.0426
Acute:
Beryllium,
mg/L
0.065
<0.00008
<0.00008
<0.00008
<0.00008
<0.0000
dissolved
Chronic:
8
0.0065
Beryllium,
mg/L
<0.00008
<0.00008
<0.00008
<0.00008
<0.0000
total
8
Boron,
mg/L
<0.03
<0.03
<0.03
<0.03
0.036
dissolved
Acute:
Boron, total
mg/L
34
<0.03
<0.03
<0.03
<0.03
0.043
Chronic:
7.3
Acute:
Cadmium,
mg/L
0.040
<0.00005
<0.00005
<0.00005
<0.00005
<0.0000
dissolved
Chronic
5
0.036
Cadmium, m,
mg/L
<0.00005
<0.00005
<0.00005
<0.00005
<0.0000
total
2

PL-
PL-
PL-
DEEP-
DEEP-
PL-
PL-
NC DEQ
DE Q
DEEP-80
DEEP-
DEEP-
130
130
DEEP-
DEEP -
Parameter
100
120
140
160
Class C
09/22/22
09/22/22
09/22/22
12/15/22
12/22/22
09/22/22
09/22/22
Stream
Calcium,
mg/L
58.8
60.8
60.8
62.3
61.7
65.9
dissolved
Calcium, total
mg/L
64.3
65.7
64.9
64.5
69.7
Chromiu
in III
Acute:
0.79417
Chronic:
Chromium,
mg/L
0.10331
<0.0005
<0.0005
<0.0005
<0.0005
<0.0005
dissolved
Chromiu
in IV
Acute:
0.016
Chronic:
0.011
Chromium,
mg/L
<0.0005
<0.0005
<0.0005
<0.0005
<0.0005
total
Cobalt,
mg/L
<0.02
<0.02
<0.02
<0.02
<0.02
dissolved
Acute:
Cobalt, total
mg/L
<0.02
<0.02
<0.02
<0.02
<0.02
Ch on.
1.6
Acute:
Copper,
mg/L
0.01969
<0.0008
<0.0008
<0.0008
0.00151
0.0012
<0.0008
0.00103
dissolved
Chronic:.
01266
Copper, total
mg/L
<0.0008
0.00152
0.00221
0.00101
0.00388
Iron, dissolved
mg/L
0.0269
0.021
0.0201
0.0276
0.0613
Iron, total
mg/L
1
0.0801
0.0359
0.0358
0.0391
0.067
Acute:
Lead,
0.10013
dissolved
mg/L
Chronic:
<0.0001
<0.0001
<0.0001
<0.0001
<0.0001
.0039
Lead, total
mg/L
<0.0001
<0.0001
<0.0001
<0.0001
<0.0001
Magnesium,
mg/L
14.5
14.9
14.9
15.2
15.2
15.4
dissolved
Magnesium,
mg/L
15.7
16.1
15.9
15.9
16.3
total
Manganese,
mg/L
3.33
3.15
3.15
3.2
4.07
dissolved
Manganese,
mg/L
0.1
3.58
3.37
3.33
3.29
4.22
total
Mercury,
ng/L
dissolved
Mercury, total
ng/L
0.012
Molybdenum,
mg/L
2
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
dissolved
Molybdenum,
mg/L
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
total
Acute:
Nickel,
0.65984
dissolved
mg/L
Chronic:
0.00085
0.00106
0.00097
0.00092
0.00217
0.07329
Nickel, total
mg/L
0.00086
0.0008
0.0008
0.00087
0.00222
Selenium,
mg/L
0.107
0.0937
0.0961
0.153
0.138
dissolved

PL-
PL-
PL-
DEEP-
DEEP-
PL-
PL-
NC DEQ
DE Q
DEEP-80
DEEP-
DEEP-
130
130
DEEP-
DEEP -
Parameter
100
120
140
160
Class C
09/22/22
09/22/22
09/22/22
12/15/22
12/22/22
09/22/22
09/22/22
Stream
Selenium,
mg/L
0.005
<0.0002
<0.0002
<0.0002
<0.0001
0.00019
<0.0002
<0.0002
Total
Acute:
Silver,
mg/L
0.0019
<0.001
<0.001
<0.001
<0.001
<0.001
dissolved
Chronic:
0.00006
Silver, total
mg/L
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
Sulfur,
mg/L
115
152
142
142
457
dissolved
Sulfur, total
mg/L
1
32.4
31.1
30.7
32.2
2.33
Thallium,
mg/L
<0.0001
<0.0001
<0.0001
<0.0001
<0.0001
dissolved
Thallium, total
mg/L
<0.0001
<0.0001
<0.0001
<0.00O1
<0.0001
Uranium,
mg/L
0.0005
0.00047
0.00044
0.00042
0.00027
dissolved
Uranium, total
mg/L
0.00043
0.0004
0.0004
0.00042
0.00042
Vanadium,
mg/L
<0.01
<0.01
<0.01
<0.01
<0.01
dissolved
Vanadium,
mg/L
<0.01
<0.01
<0.01
<0.01
<0.01
total
Acute:
Zinc,
mg/L
0.16522
0.0113
0.0108
0.0115
<0.006
0.0124
dissolved
Chronic:
0.16657
Zinc, total
mg/L
<0.006
<0.006
0.0629
<0.006
<0.006
Alkalinity as
CaCO3
Total
mg/L
20
127
139
129
118
127
509
Alkalinity
BOD5
mg/L
17
19
18
18
58.8
Carbon, total
mg/L
29.5
28.6
32.1
33.8
101
inorganic
Carbon, total
organic TOC
2.9
2.9
3
3.2
10.2
COD
mg/1
37
42
41
17
42
112
Chloride
mg/L
230
13.3
13.6
14.3
12.6
48.6
Color
Co/pt
20
1 20
10
20
20
Cyanide, Free
mg/L
0.4
<0.015
<0.015
<0.015
<0.015
<0.06
Cyanide, total
mg/L
0.005
<0.003
<0.003
<0.003
<0.003
<0.006
Fluoride
mg/L
1.8
0.34
0.35
0.35
0.36
0.33
Nitrogen,
mg/L
3.69
4.21
4.21
4.38
<0.05
4.22
36.9
ammonia
Residue,
Filterable
mg/L
326
342
342
338
496
TDS 180C
Residue, Non -
Filtrable (TSS)
mg/L
<10
<5
<10
51
<10
<10
105C
Sulfate
mg/L
1 129
118
121
152
180
116
6.2
Sulfide as S
mg/L
0.002
22.1
25.1
21.5
2.59
<0.02
22.7
72.2
pH
u/s
6.0-9.0

PL-
PL-
PL-
DEEP-
DEEP-
PL-
PL-
NC DEQ
DEQ
Q
DEEP-80
DEEP-
DEEP-
130
130
DEEP-
DEEP -
Parameter
100
120
140
160
Class C
09/22/22
09/22/22
09/22/22
12/15/22
12/22/22
09/22/22
09/22/22
Stream
Turbidity
NTU
<25
Nitrate
mg/1
<0.09
9.7
Nitrite
mg/1
0.1
<0.03
Nitrate +
mg/l
0.1
9.7
Nitrite
Note: DEEP-130 sample from Linkan as received. Values in bold RED exceed the NC DEQ values.
CONTAMINANTS OF CONCERN
Based on the bench work of the 130 ft sample and the on -going 140 ft sample test, COCs have
been identified as sulfide, ammonia and manganese. While ammonia is not listed in the NC DEQ
limits, it is anticipated that the final discharge permit will employ a discharge standard based on
EPA's freshwater quality criteria to protect aquatic organisms. Table 2 identifies the likely
constituents requiring treatment.
Table 2: Profile I Contaminants of Concern and Target Concentrations
Contaminant
Target Maximum
Treatment Level
Depth
80 ft
100 ft
120 ft
130 ft
140 ft
160 ft
Sulfide
mg/1 as S
0.002
22.1
25.1
21.5
2.59
22.7
72.2
Ammonia'
mg/1 as N
1.9
3.69
4.21
4.21
4.38
4.22
36.9
Manganese -Total
mg/1 as Mn
0.1
3.58
3.37
3.38
3.29
4.22
1 - From EPA's Aquatic Life Ambient Water Quality Criteria for Ammonia - Freshwater
In Situ Sampling
Additional pit water characterization was conducted by Linkan in situ during the week of March 6,
2023. The resulting data confirmed presence of contaminants of concern. Data collected is
summarized in Table 3.
Table 3: In -Situ Pit Characterization Data - March 6, 2023
Depth
Range
Sulfide Ammonia
m /L (m /L as N
pH ( s.u.
( ORP mV
Conductivity
(US/cm)NTU
Turbidity
(ft)
Ex ected Range
0-50
0.0 - 10.6
0.0 - 2.1
7.22 - 7.54
-225 - -209
425 -437
1.1 - 3.4
50-100
15.4 - 24.5
4.2 - 5.2
7.14 - 7.26
-282 - -269
531 - 245
1.4 - 3.4
100-150
16.6 - 22.6
3.1 -5.7
7.15 - 7.33
-279 - -255
538 - 556
2.1 - 3.3
>150
43.1 - 80.8
10.1 - 33.0
6.70 - 7.40
-281 - -269
576 - 750
5 - Opaque
Based on the in -situ sampling, the basis of design shall be 24.5 mg/L sulfide for all waters ranging
from 0 to 150 feet. The process shall be designed to allow bypass around any single treatment
process step in the event that step is not needed for water from that specific elevation.
5

Additional Testing
A sample of 140 ft pit water is currently being evaluated as per the treatment process described
herein at Linkan's Elko facility. All these works are in support of this design basis. Analytical
results will be presented when available.
MANAGEMENT OF TREATMENT WASTES
All liquid waste generated by the treatment system is anticipated to be pumped or gravity drained
back to the dewatering pit furthest away from the floating pump station. This liquid waste can be
comprised of periodic discharges of suspended solids and cleaning wastes from the water treatment
equipment.
Unit processes waste characterization are qualitatively described below:
• Media filter backwash waste is anticipated to be a combination of suspended particulate
from pit water larger than 20 µm in size and elemental sulfur from the oxidation of
hydrogen sulfide. Solids in the backwash will undergo additional filteration through
geobags. Filtrate from the geobags will be returned to the pit. The geobags will be
managed by Albemarle.
• Hollow fiber (HF) filtration backwash waste is anticipated to be suspended particles from
pit water larger than 0.01 µm in size and metal oxides from oxidation process. When
required, cleaning solutions consisting of high pH (sodium hydroxide and sodium
hypochlorite) and low pH (Citric acid) will be used to recover HF performance.
Linkan has not characterized the existing suspended solids in the water or the settled solids on the
pit floor. We understand these to be predominantly organics because of the pit flooding natural
vegetation. Note that all solids will be returned to the pit and settled. Management of the floor
slimes is not yet developed and beyond the scope of this design basis.
Metal hydroxides captured by the ultrafiltration will be comingled with the organic solids from
the pit floor. These solids should be subjected to RCRA hazard evaluation when they can be
secured. However, we do not anticipate that any individual metals concentration will exceed the
applicable RCRA standard for the 8 priority metals required for land application at a Class C
landfill.
All ammonia will be converted to gaseous nitrogen via Breakpoint Chlorination. Nitrogen gas will
be released from the top of the oxidation tank to the atmosphere.
PRELIMINARY ASSESSMENT
A preliminary Process Flow Diagram is attached that details the anticipated water treatment
process. Based upon the aforementioned bench testing and additional work, the pit water will
undergo physical chemical process. Pit water will be treated with a contingent coagulant (Ferric
Chloride or Aluminum Sulfate) to aid in the filtration process and oxidized with an estimated 215
mg/l of Sodium permanganate (-1220 gallons of 40% sodium permanganate per day to discharge
2,000 gpm) to convert hydrogen sulfide to elemental sulfur for removal in the media filters. The
filtrate of the media filters will be oxidized with an estimated 42 mg/l of Sodium Hypochlorite
(-910 gallons of 12.5% of sodium hypochlorite per day to discharge 2000 gpm) to remove
ammonia and oxidize fugitive manganese in the resulting water. The final step of treatment is
2

hollow fiber (HF) membrane to ensure particulate solids are removed from discharged water
including oxidized manganese.
The discharge criteria limit the allowable chloride in the effluent to 230 mg/L (NC DEQ). Based
on the existing chloride in the raw water, the process has been developed as a two -stage oxidant
to limit the addition of disassociated chloride from the chemical reagents used for treatment.
Finished water pH is estimated to be similar to the reported feed water pH. No pH conditioning
of the finished water is expected. However, if during the course of pilot testing results are contrary
to this preliminary assessment a pH dosing system will be included.
The unit processes will undergo periodic backwash and regeneration. The waste from these
processes is expected to be returned to the pit.
ONGOING WORK
The Design Basis Memorandum provides the framework for detailed design and Issued for
Construction Documents.
END
7

Application Form 2D
Section 9 Attachment
Pit Lake Profile Sampling Results

With the December 13, 2022 permit application, Albemarle included analytical data from water
quality sampling of the Pit Lake. As per NCDEQ's April 27, 2023 ADI letter, a one-time
sampling event for the pollutants not previously sampled on EPA's Form 2D tables A, B, C and
D has been included as this attachment to Form 2D. Samples were collected at various depths in
the Pit Lake to provide a complete profile of the water column.
On Form 2D, analytical results from samples taken at a depth of 150ft were entered into tables
A, B, C, and D. These results do not take into account any mixing or dilution that would occur
during withdrawal and are representative of only a small section of the total volume. Table 1
shows the percentage of Pit Lake Volume that each of the depths represent. The remainder and
majority of the discharge will have lesser values as you can see the following data summary
tables.
Table 1.
PL-Deep-10
PL-Deep-50
PL-Deep-100
PL-Deep-150
(I Oft depth)
(50ft depth)
(100ft depth)
(150ft depth)
Percentage of
10.8%
36.9%
30.0%
16.8%
Pit Lake
Volume

Analytical Results for the Pit Lake at a depth of 10 feet
Presence or
Estimated Data for Pollutants Expected to Be Present in Discharge
Absence
Effluent
Intake Water
Pollutant
(CAS Number, if available)
Believed
Believed
Present
Absent
Units
Maximum Daily
Average Daily
Source of
Discharge
Discharge
Information
Believed Present?
TABLE A. CONVENTIONAL AND NON CONVENTIONAL PARAMETER ESTIMATES
40 CFR 122.21(k)(5)(i))
Biochemical oxygen
Concentration
Results Previously
1.
Reported
demand (BOD5)
Mass
Chemical oxygen demand
Concentration
Results Previously
Reported
2.
(COD)
Mass
Concentration
Results Previously
3.
Total organic carbon (TOC)
Reported
Mass
Total suspended solids
Concentration
Results Previously
Reported
4.
(TSS)
Mass
Concentration
Results Previously
5.
Ammonia (as N)
Reported
Mass
Concentration
Results Previously
6.
Flow
Reported
Mass
Concentration
Results Previously
Temperature (winter)
Reported
7.
Mass
Concentration
Results Previously
Temperature (summer)
Reported
Mass
Concentration
Results Previously
pH (minimum)
Reported
8.
Mass
Concentration
Results Previously
pH (maximum)
Reported
Mass

Analytical Results forth e Pit Lake at a depth of 10 feet
Presence
or Absence
Estimated Data for Pollutants Expected to Be Present in Discharge
Pollutant
Believed
Believed
Effluent
Intake Water
(CAS Number, if available)
Present
Absent
Units
Believed
Maximum Daily Average Daily
Source of Information
Dischar e Discharge
presents
TABLE B. CERTAIN CONVENTIONAL AND NON CONVENTIONAL POLLUTANTS JL
40 CFR 122.21(kl(5)(ii)
1.
Bromide (24959-67-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2.
Chlorine, total residual
Concentration
Results Previously Reported
Mass
3.
Color
Concentration
Results Previously Reported
Mass
4.
Fecal coliform
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass
5.
Fluoride (16984-08-8)
Concentration
Results Previously Reported
Mass
6.
Nitrate -nitrite
Concentration
Results Previously Reported
Mass
7.
Nitrogen, total organic (as N)
Concentration
Results Previously Reported
Mass
8.
Oil and grease
Concentration
Results Previously Reported
Mass
9
Phosphorus (as P), total
(7723-14-0)
Concentration
Results Previously Reported
Mass
10.
Sulfate (as SO4) (14808-79-6
Concentration
Results Previously Reported
Mass
11.
Sulfide (as S)
Concentration
Results Previously Reported
Mass
12.
Sulfite (as SO3) (14265-45-3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
13.
Surfactants
Concentration
Results Previously Reported
Mass
14.
Aluminum, total (7429-90-5)
Concentration
Results Previously Reported
Mass
15.
Barium, total (7440-39-3)
Concentration
Results Previously Reported
Mass
16.
Boron, total (7440-42-8)
Concentration
Results Previously Reported
Mass
17.
Cobalt, total (7440-48-4)
Concentration
Results Previously Reported
Mass
18.
Iron, total (7439-89-6)
Concentration
Results Previously Reported
Mass
19.
Magnesium, total (7439-95-4)
Concentration
Results Previously Reported
Mass
20.
Molybdenum, total (7439-98-7
Concentration
Results Previously Reported
Mass
21.
Manganese, total (7439-96-5)
Concentration
Results Previously Reported
Mass
22.
Tin, total (7440-31-5)
Concentration
Results Previously Reported
Mass
23.
Titanium, total (7440-32-6)
Concentration
Results Previously Reported
Mass
Radioactivity
24.1
Alpha, total
Concentration
Results Previously Reported
Mass
24.2
Bela, total
Concentration
Results Previously Reported
Mass
24.3
Radium, total
Concentration
Results Previously Reported
Mass
24.4
Radium 226, total
Concentration
Results Previously Reported
Mass

Analytical Results forth e Pit Lake at a depth of 10 feet
Presence
or Absence
Estimated Data for Pollutants Expected to Be Present in Discharge
Pollutant
Believed
Believed
Effluent
Intake Water
(CAS Number, if available)
Present
Absent
Units
Believed
Maximum Daily Average Daily
Source of Information
Dischar e Discharge
present
TABLE C. TOXIC METALS, TOTAL CYANIDE, AND TOTAL PHENOLS
40 CFR 122.21(kH51(iii)(A)
1.
Antimony, Total (7440-36-0)
Concentration
Results Previously Reported
Mass
2.
Arsenic, Total (7440-38-2)
Concentration
Results Previously Reported
Mass
3.
Beryllium, Total (7440-41-7)
Concentration
Results Previously Reported
Mass
4.
Cadmium, Total (7440-43-9)
Concentration
Results Previously Reported
Mass
5.
Chromium, Total (7440-47-3)
Concentration
Results Previously Reported
Mass
6.
Copper, Total (7440-50-8)
Concentration
Results Previously Reported
Mass
7.
Lead, Total (7439-92-1)
Concentration
Results Previously Reported
Mass
8.
Mercury, Total (7439-97-6)
Concentration
Results Previously Reported
Mass
9.
Nickel, Total (7440-02-0)
Concentration
Results Previously Reported
Mass
10.
Selenium, Total (7782-49-2)
Concentration
Results Previously Reported
Mass
11.
Silver, Total (7440-22-0)
Concentration
Results Previously Reported
Mass
12.
Thallium, Total (7440-28-0)
Concentration
Results Previously Reported
Mass
13.
Zinc, Total (7440-66-6)
Concentration
Results Previously Reported
Mass
14.
Cyanide, Total (57-12-5)
Concentration
Results Previously Reported
Mass
15.
Phenols, Total
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass

Analytical Results for the Pit lake at a depth of 10 feet
Presence
or Absence
Estimated Data for Pollutants Expected to Be Present in Discharge
Pollutant
Believed
BelievedPresent
Effluent
Intake Water
(CAS Number, if available)
Absent
Units
Believed
Present's
Maximum Daily Average Daily
Dischar e Discharge Source of Information
TABLE D. ORGANIC TOXIC POLLUTANTS
1. Organic Toxic Pollutants
(GC/MS Fraction -Volatile
1.1
Acrolein (107-02-8)
X
Concentration
ICode 5 - Actual Water Quality Data
No
Mass
1.3
Benzene (71-43-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.4
Bromoform (75-25-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.5
Carbon tetrachloride (56-23-5)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.6
Chlorobenzene (108-90-7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.7
Chlorodibromomethane (124-
48-1)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.8
Chloroethane (75-00-3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.10
Chloroform (67-66-3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.11
Dichlorobromomethane (75-
27-4)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.12
1,1-dichloroethane (75-34-3)
X
Concentration
Code 5-Actual Water Quality Data
No
Mass
1.13
1,2-dichloroethane (107-06-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.15
1,2-dichloropropane (78-87-5)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.17
Ethylbenzene (100-01-4)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.18
Methyl bromide (74-83-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.19
Methyl chloride (74-87-3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.20
Methylene chloride (75-09-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.21
1,1,2,2-tet.chloroethane (79-
34-5)
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass
1.22
Tetrachloroethylene (127-18-
4)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.23
Toluene (108-88-3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
124
1,2-trans-dichloroethylene
(156-60-5)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
125
1,1,1-trichlomethane(71-55-
6)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
1 26
1,1,2-trichloroethane (79-00-
5)
X
Concentration
Code 5-Actual Water Quality Data
No
Mass
1.27
Tdchlomethylene (79-01-6)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1 28
Vinyl chloride (75-01-4)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2. Organic Toxic Pollutants
(GC/MS FractionAcid
2.1
2-chlorophenol (95-57-8)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2.2
2,4-dichlorophenol (120-83-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2.3
2,4-dimethylphenol (tO5E7-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2.4
4,6-dinitro-o-cresol (534-52-i)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2.5
2,4-dinitrophenol (51-28-5)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2.6
2-nitrophenol (88-75-5)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2.7
4-nitrophenol (100-02-7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2.8
p-chloro-m-cresol (59-50-7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2.9
Pentachlorophenol (87-86-5)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2.10
Phenol (108-95-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2.11
2,4,6-trichlo.phenol (88-05-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass

Results for the Pit Lake at a death of 10 feet
3. Organic Toxic Pollutants
(GC/MS Fraction -Base
3.1
Acenaphthene (83-32-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.2
Acenaphthylene (208-96-8)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.3
Anthmcene (120-12-7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.5
Benzo (a) anthracene (56-55-
3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.6
Benzo (a) pyrene (50-32-8)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.7
3,4-benzofluoranthene (205-
99 2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.8
Benzo (ghi) perylene (191-24-
2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3 9
Benzo (k) fluoranthene (207-
08-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.10
Bis (2-chloroethoxy) methane
(111-91-1)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.11
Bis (2-chloroethyl) ether (111-
44-4)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.13
Bis (2-ethylhezyl) phthalate
(117 81 7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.14
4-bromophenyl phenyl ether
(101-55-3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.15
Butyl benzyl phthalate (85-68-
7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.16
2-chloronaphthalene (91-58-7
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.18
Chrysene (218-01-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3 19
Dibenzo (a,h) anthracene (53-
70-3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.20
1,2-dichlorobenzene (95-50-i)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.21
1,3-dichlorobenzene (541-73-
1)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.22
1,4-dichlorobenzene (106-46-
7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.23
3,3-dichlorobenzidine (91-94-
1)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.24
Diethyl phthalate (84-66-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.25
Dimethyl phthalate (131-11-3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.26
Di-n-butyl phthalate (84-74-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.27
2,4-dinitrotoluene (121-14-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.28
2,6-dinitrotoluene (606-20-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.29
Di-noctyl phthalate (117-84-0)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.31
Fluoranthene (206-44-0)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.32
Fluorene (86-73-7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.33
Hexachlorobenzene (118-74-
1)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3 34
Hexachlorobutadiene (87-68-
3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.35
Hexachlorocyclopentadiene
(77474)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.36
Hexachloroethane (67-72-1)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.37
Indeno (1,2,3-cd) pyrene
(193-39-5)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.38
Isophorone (78-59-1)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.39
Naphthalene (91-20-3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.40
Nitrobenzene (98-95-3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.41
N-nitrosodimethylamine (62-
75-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.42
N-nitrosodi-n-propylamine
(621-64-7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.43
N-nitrosodiphenylamine (86-
30-6)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.44
Phenanthrene (85-01-8)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.45
Pyrene (129-00-0)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.46
1,2,4-tichlorobenzene (120-
82-1)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass

Analytical Results for the Pit Lake at a depth of 10 feet
4. Organic Toxic Pollutants
(GC/MS Fraction —Pesticides) AS
4.1
Aldrin (309-00-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.2
a-BHC (319-84-6)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.3
ji-BHC (319-85-7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.4
y-BHC (58-89-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.5
6-BHC (319-86-8)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.6
Chlordane (57-74-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.7
4,4'-DDT (50-29-3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.8
4,4'-DDE (72-55-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.9
4,4'-DDD (72-54-8)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.10
Dieldrin (60-57-1)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.11
a-endosulfan (115-29-7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.12
3-endosulfan (115-29-7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.13
Endosulfan sulfate (1031-07-
8)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.14
Endrin (72-20-8)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.15
Endrin aldehyde (7421-934)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.16
Heptachlor (76-44-8)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
417
Heptachlor epoxide(1024-57-
3)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
4.18
PCB-1242 (53469-21-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.19
PCB-1254 (11097-69-1)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.20
PCB-1221 (11104-28-2)
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass
4.21
PCB-1232 (11141-16-5)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.22
PCB-1248 (12672-29-6)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.23
PCB-1260 (11096-82-5)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.24
PCB-1016 (12674-11-2)
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass
4.25
Toxaphene (8001-35-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass

Analytical Results forth e Pit Lake at a depth of 50 feet
Presence
or Absence
Estimated Data for Pollutants Expected to Be Present in Discharge
Pollutant
Believed
Believed
Effluent
Intake Water
(CAS Number, if available)
Present
Absent
Units
Believed
Maximum Daily Average Daily
Source of Information
Dischar a Discharge
Present?
TABLE A. CONVENTIONAL AND NON CONVENTIONAL PARAMETER ESTIMATES
40 CFR 122.21(k)(510))
1
Biochemical oxygen demand
(BODS)
Concentration
Results Previously Reported
Mass
2
Chemical oxygen demand
(COD)
Concentration
Results Previously Reported
Mass
3.
Total organic carbon (TOC)
Concentration
Results Previously Reported
Mass
4.
Total suspended solids (TSS)
Concentration
Results Previously Reported
Mass
5.
Ammonia (as N)
Concentration
Results Previously Reported
Mass
6.
Flow
Concentration
Results Previously Reported
Mass
Temperature (winter)
Concentration
Results Previously Reported
Mass
7.
Temperature (summer)
Concentration
Results Previously Reported
Mass
Pp.H:(.minimum)Mass
Concentration
Results Previously Reported
6.
(aximum)
Concentration
Results Previously Reported
Mass

Analytical Results forth a Pit Lake at a depth of 50 feet
Presence
or Absence
Estimated Data for Pollutants Expected to Be Present in Discharge
Pollutant
Believed
Believed
Effluent
Intake Water
(CAS Number, if available)
Present
Absent
Units
Believed
Maximum Daily I Average Daily
Source of Information
Discharge Discharge
Present
TABLE B. CERTAIN CONVENTIONAL AND NON CONVENTIONAL POLLUTANTS
40 CFR 122.21(kV5)(ii)
1.
Bromide (24959-67-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2.
Chlorine, total residual
Concentration
Results Previously Reported
Mass
3.
Color
Concentration
Results Previously Reported
Mass
4.
Fecal coliform
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
5.
Fluoride (16984-48-8)
Concentration
Results Previously Reported
Mass
6.
Nitrate -nitrite
Concentration
Results Previously Reported
Mass
7.
Nitrogen, total organic (as N)
Concentration
Results Previously Reported
Mass
8.
Oil and grease
Concentration
Results Previously Reported
Mass
9
Phosphorus (as P), total
(7723-14-0)
Concentration
Results Previously Reported
Mass
10.
Sulfate (as SO4) (14808-79-8
Concentration
Results Previously Reported
Mass
11.
Sulfide (as S)
Concentration
Results Previously Reported
Mass
12.
Sulfite (as SO3) (14265-45-3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
13.
Surfactants
Concentration
Results Previously Reported
Mass
14.
Aluminum, total (7429-90-5)
Concentration
Results Previously Reported
Mass
15.
Barium, total (7440-39-3)
Concentration
Results Previously Reported
Mass
16.
Boron, total (7440-42-8)
Concentration
lResults Previously Reported
Mass
17.
Cobalt, total (7440-48-4)
Concentration
Results Previously Reported
Mass
18.
Iron, total (7439-89-6)
Concentration
Results Previously Reported
Mass
19.
Magnesium, total (7439-95-4)
Concentration
Results Previously Reported
Mass
20.
Molybdenum, total (7439-98-7
Concentration
Results Previously Reported
Mass
21.
Manganese, total (7439-96-5)
Concentration
Results Previously Reported
Mass
22.
Tin, total (7440-31-5)
Concentration
Results Previously Reported
Mass
23.
Titanium, total (7440-32-6)
Concentration
Results Previously Reported
Mass
Radioactivity
24.1
Alpha, total
Concentration
Results Previously Reported
Mass
24.2
Beta, total
Concentration
Results Previously Reported
Mass
24.3
Radium, total
Concentration
Results Previously Reported
Mass
24.4
Radium 226, total
Concentration
Results Previously Reported
Mass

Analytical Results for the Pit take at a depth of 50 feet
Presence or Absence
Estimated Data for Pollutants Expected to Be Present in Discharge
Pollutant
Effluent
Intake Water
(CAS Number, if available)
Believed Present
Believed Absent
Units
r 4'—mum Daily I Average Daily Source of Information
Dischar c Dischar e
eelleved Present
TABLE C. TOXIC METALS. TOTAL CYANIDE, AND TOTAL PHENOLS
1
40 CFR
Antimony, Total
(7440-36-0)
Results Previously Reported
Concentration
Mass
2
Arsenic, Total
(7440-38-2)
Concentration
Results Previously Reported
Mass
3
Beryllium, Total
(7440-41-7)
Concentration
Results Previously Reported
Mass
4
Cadmium, Total
(7440-43-9)
Concentration
Results Previously Reported
Mass
5
Chromium, Total
(7440-47-3)
Concentration
Results Previously Reported
Mass
5
Copper, Total
(7440-50-8)
Concentration
Results Previously Reported
Mass
7.
Lead, Total (7439-
92-1)
Concentration
Results Previously Reported
Mass
8
Mercury, Total
(7439-97-6)
Concentration
Results Previously Reported
Mass
9
Nickel, Total
(7440-02-0)
Concentration
Results Previously Reported
Mass
10
Selenium, Total
(7782-49-2)
Concentration
Results Previously Reported
Mass
11
Silver, Total (7440-
22-4)
Concentration
Results Previously Reported
Mass
12
Thallium, Total
(7440-28-0)
Concentration
Results Previously Reported
Mass
13
Zinc, Total (7440-
66-6)
Concentration
Results Previously Reported
Mass
14
Cyanide, Total (57-
12-5)
Concentration
Results Previously Reported
Mass
15.
Phenols, Total
x
Concentration
Code 5 - Actual Water Quality Data
No
Mass

Analytical Results forth a Pit Lake at a depth of 50 feet
Presence
or Absence
Estimated Data for Pollutants Expected to Be Present in Discharge
Pollutant
Believed
Believed
Effluent
Intake Water
(CAS Number, if available)
Present
Absent
Units
Believed
Maximum Daily Average Daily
Source of Information
Discharge Discharge
Present?
-ABLE D. ORGANIC TOXIC POLLUTANTS
1. Organic Toxic Pollutants
(GC/MS Fraction -Volatile
1.1
Acrolein (107-02-8)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.3
Benzene (71-43-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.4
Bromoform (75-25-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.5
Carbon tetrachloride (56-23-5
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.6
Chlorobenzene (108-90-7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.7
Chlorodibromomethane (124-
48-1)
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass
1.8
Chloroethane (75-00-3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.10
Chloroform (67-66-3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.11
Dichlorobromomethane (75-
27-4)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.12
1,1-dichloroethane (75-34-3)
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass
1.13
1,2-dichloroethane (107-06-2)
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass
1.15
1,2-dichloropropane (76-87-5)
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass
1.17
Ethylbenzene (100-41-4)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.18
Methyl bromide (74-83-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.19
Methyl chloride (74-87-3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.20
Methylene chloride (75-09-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.21
1,1,2,2-tetrachloroethane (79-
34-5)
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass
1.22
Tetrachloroethylene (127-18-
4)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.23
Toluene (108-88-3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.24
1,2-trans-dichloroethylene
(156-60-5)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.25
1,1,1-trichloroethane (71-55-6
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass
1.26
1,1,2-trichloroethane (79-00-5
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.27
Trichloroethylene (79-01-6)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.28
Vinyl chloride (75-01-4)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
111111111 2. Organic Toxic Pollutants
(GC/MS Fraction -Acid
Compounds) MAIL
2.1
2-chlorophenol (95-57-8)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2.2
2,4-dichlorophenol (120-83-2)
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass
2.3
2,4-dimethylphenol (105-67-9
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass
2.4
4,6-dinitro-o-cresol (534-52-1)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2.5
2,4-dinitrophenol (51-28-5)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2.6
2-nitrophenol (88-75-5)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2.7
4-nitrophenol (100-02-7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2.8
p-chloro-m-cresol (59-50-7)
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass

Analytical Results forth e Pit Lake at a depth of 50 feet
2.9
Pentachlorophenol (87-86-5)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2.10
Phenol (108-95-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2.11
2,4,6-trichlorophenol (88-05-2
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass
3. Organic Toxic Pollutants 7
(GC/MS Fraction -Base
3.1
Acenaphthene (83-32-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.2
Acenaphthylene (208-96-8)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.3
Anthracene (120-12-7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.5
Benzo (a) anlhracene (56-55-
3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.6
Benzo (a) pyrene (50-32-8)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.7
3,4-benzofluoranthene (205-
99-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.8
Benzo (ghi) perylene (191-24
2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.9
Benzo (k) fluoranthene (207-
08-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.10
Bis (2-chloroethoxy) methane
(111-91-1)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.11
Bis (2-chloroethyl) ether (111-
44-4)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.13
Bis (2-ethylhexyl) phthalate
(117-81-7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.14
4-bromophenyl phenyl ether
(101-55-3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.15
Butyl benzyl phthalate (85-68
7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.16
2-chloronaphthalene (91-58-7
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.18
Chrysene (218-01-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.19
Dibenzo (a,h) anthracene (53
70-3)
X
Concentration
IGode 5 - Actual Water Quality Data
No
Mass
3.20
1,2-dichlorobenzene (95-50-1
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.21
1,3-dichlorobenzene (541-73-
1)
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass
3.22
1,4-dichlorobenzene (106-46-
7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.23
3,3-dichlorobenzidine (91-94-
1)
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass
3.24
Diethyl phthalate (84-66-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.25
Dimethyl phthalate (131-11-3)
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass
3.26
Di-n-butyl phthalate (84-74-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.27
2,4-dinitrotoluene (121-14-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.28
2,6-dinitrotoluene (606-20-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.29
Di-n-octyl phthalate (117-84-0
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.31
Fluoranthene (206-44-0)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.32
Fluorene (86-73-7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.33
Hexachlorobenzene (118-74-
1)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.34
Hexachlorobutadiene (87-68-
3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.35
Hexachlorocyclopentadiene
(77-47-4)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.36
Hexachloroethane (67-72-1)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.37
Indeno (1,2,3-cd) pyrene (193
39-5)
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass
3.38
Isophorone (78-59-1)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.39
Naphthalene (91-20-3)
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass

Analytical Recults fnr the Pit I ake at a depth of SO feat
3.40
Nitrobenzene (98-95-3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.41
N-nitrosodimethylamine (62-
75-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.42
N-nitrosodi-n-propylamine
(621-64-7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.43
N-nitrosodiphenylamine (86-
30-6)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.44
Phenanthrene (85-01-8)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.45
Pyrene (129-00-0)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.46
1,2,4-trichlorobenzene (120-
82-1)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4. Organic Toxic Pollutants
(GC/MS Fraction -Pesticides)
4.1
Aldrin (309-00-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.2
a-BHC (319-84-6)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.3
(i-BHC (319-85-7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.4
y-BHC (58-89-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.5
S-BHC (319-86-8)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.6
Chlordane (57-74-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.7
4,4'-DDT (50-29-3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.8
4,4'-DDE (72-55-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.9
4,4'-DDD (72-54-8)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.10
Dieldrin(60-57-1)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.11
a-endosulfan (115-29-7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.12
(3-endosulfan (115-29-7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.13
Endosulfan sulfate (1031-07-8
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.14
Endrin (72-20-8)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.15
Endrin aldehyde (7421-93-0)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.16
Heptachlor (76-44-8)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.17
Heptachlor epoxide (1024-57-
3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.18
PCB-1242 (53469-21-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.19
PCB-1254 (11097-69-1)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.20
PCB-1221 (11104-28-2)
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass
4.21
PCB-1232 (11141-16-5)
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass
4.22
PCB-1248 (12672-29-6)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.23
PCB-1260 (11096-82-5)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.24
PCB-1016 (12674-11-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.25
Toxaphene (8001-35-2)
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass

Analytical Results forth e Pit Lake at a depth of 100 feet
Presence
or Absence
Estimated Data for Pollutants Expected to Be Present in Discharge
Pollutant
Believed
Believed
Effluent
Intake Water
(CAS Number, if available)
Present
Absent
Units
Maximum Daily Average Daily
Source of Information
Believed
Dischar q a Dischar a
Present%
TABLE A. CONVENTIONAL AND NON CONVENTIONAL PARAMETER ESTIMATES
40 CFR 122.21(k)(5)(i))
1
Biochemical oxygen demand
(BODS)
Concentration
Results Previously Reported
Mass
2
Chemical oxygen demand
(COD)
Concentration
Results Previously Reported
Mass
3.
Total organic carbon (TOC)
Concentration
Results Previously Reported
Mass
4.
Total suspended solids (TSS)
Concentration
Results Previously Reported
Mass
5.
Ammonia (as N)
Concentration
Results Previously Reported
Mass
6.
Flow
Concentration
Results Previously Reported
Mass
7
Temperature (winter)
Concentration
Results Previously Reported
Mass
Temperature (summer)
Concentration
Results Previously Reported
Mass
R
pH (minimum)
Concentration
Results Previously Reported
Mass
pH (maximum)
Concentration
IResults Previously Reported
Mass

Analytical Results forth e Pit Lake at a depth of 100 feet
Presence
or Absence
Estimated Data for Pollutants Expected to Be Present in Discharge
Pollutant
Believed
Believed
Effluent
Intake Water
(CAS Number, if available)
Present
Absent
Units
Maximum Daily Average Daily
Source of Information
Believed
Discharge Discharge
present
TABLE B. CERTAIN CONVENTIONAL AND NON CONVENTIONAL POLLUTANTS
H11141aarrA ARST6YTMI
1.
Bromide (24959-67-9)
X
Results Previously Reported
No
2.
Chlorine, total residual
Results Previously Reported
3.
Color
Results Previously Reported
4.
Fecal coliform
X
Results Previously Reported
N1,,
5.
Fluoride (16984-08-8)
Results Previously Reported
6.
Nitrate -nitrite
Results Previously Reported
7.
Nitrogen, total organic (as N)
Results Previously Reported
8.
Oil and grease
Results Previously Reported
9
Phosphorus (as P), total (7723
14-0)
Results Previously Reported
10.
Sulfate (as SO4) (14808-79-8)
Results Previously Reported
11.
Sulfide (as S)
Results Previously Reported
12.
Sulfite (as SO3) (14265-45-3)
X
Concentration
mgiL
4.0
Code 5 -Actual Water Quality Data
Yes
Mass
Ibs
120,173,824
13.
Surfactants
Results Previously Reported
14.
Aluminum, total (7429-90-5)
Results Previously Reported
15.
Barium, total (7440-39-3)
Results Previously Reported
16.
Boron, total (7440-42-8)
Results Previously Reported
17.
Cobalt, total (7440-48-4)
Results Previously Reported
18.
Iron, total (7439-89-6)
Results Previously Reported
19.
Magnesium, total (7439-95-4)
Results Previously Reported
20.
Molybdenum, total (7439-98-7
Results Previously Reported
21.
Manganese, total (7439-96-5)
Results Previously Reported
22.
Tin, total (7440-31-5)
Results Previously Reported
23.
Titanium, total (7440-32-6)
Results Previously Reported
Radioactivity
24.1
Alpha, total
Results Previously Reported
24.2
Beta, total
Results Previously Reported
24.3
Radium, total
Results Previously Reported
24.4
Radium 226, total
Results Previously Reported

Analytical Results forth e Pit Lake at a depth of 100 feet
Presence
or Absence
Estimated Data for Pollutants Expected to Be Present in Discharge
Pollutant
Believed
Believed
Effluent
Intake Water
(CAS Number, if available)
Present
Absent
Units
Maximum Daily Average Daily
Source of Information
Believed
Dischar a Discharge
present
TABLE C. TOXIC METALS, TOTAL CYANIDE, AND TOTAL PHENOLS
40 CFR 122.21(k)(5)(iii)(A)
1.
Antimony, Total (7440-36-0)
Results Previously Reported
2.
Arsenic, Total (7440-38-2)
Results Previously Reported
3.
Beryllium, Total (7440-41-7)
Results Previously Reported
4.
Cadmium, Total (7440-43-9)
Results Previously Reported
5.
Chromium, Total (7440-47-3)
Results Previously Reported
6.
Copper, Total (7440-50-8)
Results Previously Reported
7.
Lead, Total (7439-92-1)
Results Previously Reported
8.
Mercury, Total (7439-97-6)
Results Previously Reported
9.
Nickel, Total (7440-02-0)
Results Previously Reported
10.
Selenium, Total (7782-49-2)
Results Previously Reported
11.
Silver, Total (7440-22-4)
Results Previously Reported
12.
Thallium, Total (7440-28-0)
Results Previously Reported
13.
Zinc, Total (7440-66-6)
Results Previously Reported
14.
Cyanide, Total (57-12-5)
Results Previously Reported
15.
Phenols, Total
X
Code 5 - Actual Water Quality Data
No

Analytical Results forth e Pit Lake at a depth of 100 feet
Presence
or Absence
Estimated Data for Pollutants Expected to Be Present in Discharge
Pollutant
Believed
Believed
Effluent
Intake Water
(CAS Number, if available)
Present
Absent
Units
Maximum Daily Average Daily
Source of Information
Believed
Discharge Discharge
present-,
TABLE D. ORGANIC TOXIC POLLUTANTS
1. Organic Toxic Pollutants
(GC/MS Fraction -Volatile
1.1
Acrolein (107-02-8)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.3
Benzene (71-43-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.4
Bromoform (75-25-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.5
Carbon tetrachloride (56-23-5
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.6
Chlorobenzene (108-90-7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.7
Chlorodibromomethane (124-
48-1)
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass
1.8
Chloroethane (75-00-3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.10
Chloroform (67-66-3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.11
Dichlorobromomethane (75-27
4)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.12
1,1-dichloroethane (75-34-3)
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass
1.13
1,2-dichloroethane (107-06-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.15
1,2-dichloropropane (78-87-5)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.17
Ethylbenzene (100-41-4)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.18
Methyl bromide (74-83-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.19
Methyl chloride (74-87-3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.20
Methylene chloride (75-09-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.21
1,1,2,2-telrachloroethane (79-
34-5)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.22
Tetrachloroethylene (127-18-
4)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.23
Toluene (106-88-3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.24
1,2-trans-dichloroethylene
(156-60-5)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.25
1,1,1-tichloroethane (71-55-6
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1.26
1,1,2-tdchloroethane (79-00-5
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass
1.27
Trichloroethylene (79-01-6)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
1 28
Vinyl chloride (75-01-4)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2. Organic Toxic Pollutants
(GC/MS Fraction -Acid
2.1
2-chlorophenol (95-57-8)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2.2
2,4-dichlorophenol (120-83-2)
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass
2.3
2,4-dimethylphenol (105-67-9
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2.4
4,6-dinitro-o-cresol (534-52-1)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2.5
2,4-dinitrophenol (51-26-5)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2.6
2-nitrophenol (88-75-5)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2.7
4-nitrophenol (100-02-7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2.8
p-chloro-m-cresol(59-50-7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass

Analytical Results forth e Pit Lake at a depth of 100 feet
2.9
Pentachlorophenol (87-86-5)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2.10
Phenol (108-95-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
2.11
2,4,6-trichlorophenol (88-05-2
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass
3. Organic Toxic Pollutants
(GC/MS Fraction -Base
3.1
Acenaphthene (83-32-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.2
Acenaphthylene (208-96-8)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.3
Anthracene (120-12-7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.5
Benzo (a) anlhracene (56-55-
3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.6
Benzo (a) pyrene (50-32-8)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.7
3,4-benzofluomnthene (205-9
2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.8
Benzo (ghi) perylene (191-24
2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.9
Benzo (k) fluoranthene (207-
08-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.10
Bis (2-chloroethoxy) methane
(111-91-1)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.11
Bis (2-chloroethyl) ether (111-
44-4)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.13
Bis (2-ethylhexyl) phthalate
(117-81-7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.14
4-bromophenyl phenyl ether
(101-55-3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.15
Butyl benzyl phthalate (85-68
7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.16
2-chloronaphthalene (91-58-7
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.18
Chrysene (218-01-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.19
Dibenzo (a,h) anthracene (53
70-3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.20
1,2-dichlorobenzene (95-50-1
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.21
1,3-dichlorobenzene (541-73-
1)
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass
3.22
1,4-dichlorobenzene (106-46-
7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.23
3,3-dichlorobenzidine (91-94-
1)
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass
3.24
Diethyl phthalate (84-66-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.25
Dimethyl phthalate (131-11-3
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.26
Di-n-butyl phthalate (84-74-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.27
2,4-dinitrotoluene (121-14-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.28
2,6-dinitrotoluene (606-20-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.29
Di-n-octyl phthalate (117-84-0
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.31
Fluoranthene (206-44-0)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.32
Fluorene (86-73-7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.33
Hexachlorobenzene (118-74-
1)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.34
Hexachlorobutadiene (87-68-
3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.35
Hexachlorocyclopentadiene
(77-47-4)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.36
Hexachloroethane (67-72-1)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.37
Indeno (1,2,3-cd) pyrene (193
39-5)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.38
Isophorone (78-59-1)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.39
Naphthalene (91-20-3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass

Analytical Results forth e Pit Lake at a depth of 100 feet
3.40
Nitrobenzene (98-95-3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.41
N-nitrosodimethylamine (62-7
9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.42
N-nitrosodi-n-propylamine
(621-64-7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.43
N-nitrosodiphenylamine (86-3(
6)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.44
Phenanthrene (85-01-8)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.45
Pyrene (129-00-0)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
3.46
1,2,4-trichlorobenzene (120-8
1)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4. Organic Toxic Pollutants
(GC/MS Fraction -Pesticides)
4.1
Aldrin (309-00-2)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
4.2
a-BHC (319-84-6)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.3
(i-BHC (319-85-7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.4
y-BHC (58-89-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.5
S-BHC (319-86-8)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.6
Chlordane (57-74-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.7
4,4'-DDT (50-29-3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.8
4,4'-DDE (72-55-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.9
4,4'-DDD (72-54-8)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.10
Dieldrin(60-57-1)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.11
a-endosulfan (115-29-7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.12
(3-endosulfan (115-29-7)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.13
Endosulfan sulfate (1031-07-8
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.14
Endrin (72-20-8)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.15
Endrin aldehyde (7421-93�)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.16
Heptachlor (76-44-8)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.17
Heptachlor epoxide (1024-57-
3)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.18
PCB-1242 (53469-21-9)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.19
PCB-1254 (11097-69-1)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.20
PCB-1221 (11104-28-2)
X
Concentration
Code 5 -Actual Water Quality Data
No
Mass
4.21
PCB-1232 (11141-16-5)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.22
PCB-1246 (12672-29-6)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.23
PCB-1260 (11096-62-5)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.24
PCB-1016 (12674-11-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass
4.25
Toxaphene(8001-35-2)
X
Concentration
Code 5 - Actual Water Quality Data
No
Mass

Analytical ReauIt, for the Pit lake at a depth of 150 feet
Presence
or Absence
Estimated Data for Pollutants Ex ected to Be Present in Discharg(
Pollutant
Believed
Believed
Effluent
Intake Water
(CAS Number, if available)
Unite
Present
Absent
Believed Present?
Maximum Daily I Average Daily Source of Information
Discharge DISChaf E
TABLE A. CONVENTIONAL AND NON CONVENTIONAL PARAMETER ESTIMATES

Analytical Results for the Pit Lake at a depth of 150 feet
Pollutant
IcAs Number, if available)
Presence
or Absence
Estimated Data for Pollutants Expected to Be Present in Discharg(
Intake Water
Believed Present?
Believed
present
Believed
Absent
Units
Effluent
Maximum Daily
Dischar a
Average Daily Source of Information
Dischar e
TABLE B. CERTAIN CONVENTIONAL
AND NON CONVENTIONAL
POLLUTANTS
—
_
1.
40 CFR 122.21(k)(5)(II)
Bromide(24959-67-9)
X
Concentration
Code 5- Actual Water Quality Dala
No
Mas
2.
Chlorine, total residual
Concentration
Results Previously Reported
Mass
3.
Color
Concentration
Results Previously Reported
Mass
4.
Fecal colHonn
x
Concentration
Code S- Actual Water Quality Data
No
Mass
5.
Fluoride (1698448-8)
Concentration
Results Previously Reported
Mass
6.
Nitrate -nitrite
Concentration
Results Previously Reported
Mass
7.
Nitrogen, total organic (as N)
Concentration
Results Previously Reported
Mass
8.
Oil and grease
Concentration
Results Previously Reported
Mass
9.
Phosphorus (as P), total (7723-14-0)
Concentration
Results Previously Reported
Mass
10.
Sulfate (as SO4) (14808-79-8)
Concentration
Results Previously Reported
Mass
11.
Sulfide (as S)
Concentration
Results Previously Reported
Mass
12.
Sulfite (as S03)(14265-45-3)
X
Concentration
mg/L
2.0
Code S- Actual Water Quality Data
yes
Mass
[be
60,086.912
13.
Surfactants
Concentration
Results Previously Reported
Mass
14.
Aluminum, total (7429-90-5)
Concentration
Results Previously Reported
Mass
15.
Barium, total (7440-39-3)
Concentration
Results Previously Reported
Mass
16.
Boron, total (744042-8)
Concentration
Results Previously Reported
Mass
17.
Cobalt, total (744048-4)
Concentration
Results Previously Reported
Mass
18.
Iron, total (7439-896)
Concentration
Results Previously Reported
Mass
19.
Magnesium, total (7439-954)
Concentration
Results Previously Reported
Mass
20.
Molybdenum, total (7439-98-7)
Concentration
Results Previously Reported
Mass
21.
Manganese, total(7439-96-5)
Concentration
Results Previously Reported
Mass
22.
Tin, total(7440-31-5)
Concentration
Results Previously Reported
Mass
23.
Titanium, total (7440-326)
Concentration
Results Previously Reported
Mass
24.1
Alpha, total
Concentration
Results Previously Reported
Mas
24.2
Beta, total
Concentationsa
Results Previously Reported
Me
24.3
Radium, total
Concentration
Results Previously Reported
Mass
24.4
Radium 226, total
Concentration
Results Previously Reported
Mass

Analytical Results for the Pit Lake at a depth of 150 feet
Presence
or Absence
Estimated Data for Pollutants Ex ected to Be Present in Discharg(
Pollutant
Believed
Believed
Effluent
Intake Water
(CA5 Number, if available)
Present
Absent
Units
Believed Present?
Maximum Daily I Average Daily I Source of Information
Discharge Discharge
40 CFR 12221 fklf5lflliVAl in
Arsenic, Total (7440-38-2)
Beryllium, Total (744041-7)
Cadmium, Total (744043-9)
Chromium, Total (744047-3)
Mercury, Total (7439-97-6)
Nickel, Total (7440-02-0)
Selenium, Total (778249-2)
Silver, Total (7440-22-4)
Thallium, Total (7440-28-0)
Zinc Total 17440-66-6)
Cyanide, Total (57-12-5)

Analytical Results for the Pit Lake at a depth of 150 feet
Presence
or Absence
I
Estimated Data for Pollutants Ex ected to Be Present in Discharge
Pollutant
Believed
Believed
Effluent
Intake Water
(CAS Number, if available)
Present
Absent
Units
Believed Present?
Maximum Daily Average Daily Source of Information
Discharge Dischar e
1. kToxic Pollutards(GGMsn� am
1A
Acrolein (107-02-8)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
1.3
Benzene(71-43-2)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
1.4
Bromofo-(75-25-2)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
1.5
Carbon tetrachloride (56-23-5)
X
Concentration
Code 5-Actual Water Quality Data
No
Mass
1.6
Chlorobenzene(108-90-7)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
1.7
Chlorodibromomethane(124-48-1)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
1.8
Chloroethane(75-00-3)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
1.10
Chlorofoon(67-66-3)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
1.11
Dichlorobromomethane(75-27-4)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
1.12
1,1dichloroethane(75-34-3)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
1.13
1,2dichloroethane(107-06-2)
X
Concentratlon
Code 5- Actual Water Quality Data
No
Mass
1.15
1,2dlchloropropane(78-87-5)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
1.17
Ethylbenzene(100-41-0)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
1.18
Methyl bromide(74-83-9)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
1.19
Methyl chloride (74-87-3)
X
Concentration
Code 5-Actual Water Quality Data
No
Mass
1.20
Methylene chlodde(75-09-2)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
1.21
1,1,2,2-tetmehloroethane(79-34-5)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
1.22
Tetrachloroethylene(127-18-4)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
1.23
Toluene 1108-88-3)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
1.24
1,2-trans-dlchloroethylene(156-60-5)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
1.25
1,1,1-bioNoroeMane(71-558)
X
Concentration
Code 5-Actual Water Quality Data
No
Mass
1.26
1,1,2-hichloroeMane(79-00-5)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
1.27
Tdchloroethylene(79-01-6)
X
Concentration
Code 5-Actual Water Quality Data
No
Mass
1.28
Vinyl chloride (75-011)
X
Concentration
Code 5- Actual Water Quality Dale
No
Mass
; ...tits (GC/MS Fraction -Act
K=I
2.1
2chlorophenoI(95-57-8)
X
Concentration
Code 5- Actual Water Quality Dala
No
Mass
2.2
2,4dlahlorophenol(12083-2)
X
Concentratlon
Code 5- Actual Water Quality Data
No
Masa
2.3
2,4-0Imethylphenol(105-67-9)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
2.4
4,6-0inft-o-cresol(534-52-1)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
2.5
2,4dlnRrophenol(51-28-5)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
2.6
2-nitrophenol(88-75-5)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
2.7
4-nitrophenol(100-02-7)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
2.8
p-c1hloro-m-cresol(59,50-7)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
2.9
Pentachlorophenol(87-865)
X
Concentratlon
Code 5- Actual Water Quality Data
No
Mass
2.10
Phenol(108-95-2)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
2.11
2A6-lflchlorophenol(88-05-2)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass

Analytical Results for the Pit Lake at a depth of 150 feet
3. Organic Toxic Pollutants(QCIMS Fraction -Base
3A
Acenaphthene(83-32-9)
X
Concentration
Code 5- Actual Water Quality Data
No
mass
3.2
Acenaphthylene (208-96-8)
X
Concept ation
Code 5-Actual Water Quality Data
No
Mass
3.3
Anthacene(120-12-7)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.5
Benzo(a) anihracene(56-55-3)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.6
Ban. (a) pyrene(50-32-8)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.7
3,4-benzofluoanthene(205-99-2)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.8
Benzo(ghi) perylene(191-24-2)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.9
Benzo(k) fluoranlhene(207-08-9)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.10
Bis(2-chloroethoxy) methane(111-91-1)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.11
BIs(2-chloroethyl) ether(11144-4)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.13
Bis(2-ethylhexyl) phthalate(117-81-7)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.14
4-bromophenyl phenyl ether(10155-3)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.15
Butyl benzyl phthalate(85-68-7)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.16
2-chloronaphMalene(91-5&7)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.18
Chrysene(218-01-9)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.19
Dlbenzo(a,h) anthracene(53-70-3)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.20
1,2-0Ichlorobenzene(95-50-1)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.21
1,3dlchlorobenzene(541-73-1)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.22
1,4dlchlorobenzene(106-46-7)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.23
3,3dlchlorobenzidlne(91-94-1)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.24
Diethyl phthalate(84-66-2)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.25
Dlmethyl phthalate (131-11-3)
x
Concentration
Code 5-Actual Water Quality Data
No
Mass
3.26
Di-n-butyl phihalale(84-74-2)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.27
2,4dinitrotoluene(121-14-2)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.28
2,6dlnitrotoluene(606-20-2)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.29
DI-n-outyl phMalale(117-84-0)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.31
Fluoranthene(20644-0)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.32
Fluorene(86-73-7)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.33
Hexachlorobenzene(118-74-1)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.34
Hexachlorobutadlene(87-68-3)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.35
Hexachlorocyclopentadlene(7747-4)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.36
H-lifloroethane(67-72-1)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.37
Indeno(1,2,3-cd)pyrene(193-39-5)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.38
Isophorone(78-59-1)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.39
Naphthalene(91-20-3)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.40
Nitrobenzene(98-95-3)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.41
N-nitrosodimethylamine(62-75-9)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.42
N-n9rosodl-n-propylamine(621-64-7)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.43
N-nitrisodlphenylamine(86-30-6)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.44
Phenanthrene(85-01-8)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.45
Pyrene(129-00-0)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
3.46
12,4-trlchlorobenzene(120-82-1)
x
Concentration
Code 5-Actual Water Quality Data
No
Mass

Analytical Results for the Pit Lake at a depth of 150 feet
4. Organic Toxic Pollutants (GC/MS
4.1
Aldhn(309-00-2)
x
Concentration
Code 5- Actual Water Quality Data
No
Mas
4.2
a-BHC (319-84-6)
X
Concentration
Code 5-Actual Water Quality Data
No
Mass
4.3
fi-BHC(319-85-7)
x
Concentration
Code S- Actual Water Quality Data
No
Mass
4.4
y-BHC(58-89-9)
x
Concentration
Code S- Actual Water Quality Data
No
Mass
4.5
&BHC(319-86-8)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
4.6
Chlordane(57-74-9)
X
Concentration
Code S- Actual Water Quality Data
No
Mass
4.7
4,4'-DDT(50-29-3)
x
Concentration
Code S- Actual Water Quality Data
No
Mass
4.8
4,4'-DDE(72-55-9)
x
Concentration
Code S- Actual Water Quality Data
No
Mass
4.9
4,4'-DDD(72-54-8)
X
Concentration
Code S- Actual Water Quality Data
No
Mass
4.10
Dieldrin(60-57-1)
X
Concentration
Code S- Actual Water Quality Data
No
Mass
4.11
a-endosulfan(115-29-7)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
4.12
@endosulfan(115-29-7)
x
Concentration
Code S- Actual Water Quality Deus
No
Mass
4.13
Endosulfan sulfate(1031-07-8)
X
Concentration
Code S- Actual Water Quality Data
No
Mass
4.14
Endrin(72-20-8)
X
Concentration
Code S- Actual Water Quality Data
No
Mass
4.15
Endrin aldehyde (7421-93-4)
X
Concentration
Code 5-Actual Water Quality Data
No
Mass
4.16
Heptachlor(76-4-8)
x
Concentration
Code S- Actual Water Quality Data
No
Mass
4.17
Heptachlor epoxlde(1024-57-3)
X
Concentration
Code S- Actual Water Quality Data
No
Mass
4.18
PCB-1242(53469-21-9)
X
Concentration
Code S- Actual Water Quality Data
No
Mass
4.19
PCB-1254(11097-69-1)
X
Concentration
Code S- Actual Water Quality Data
No
Mass
4.20
PCB-1221(11104-28-2)
x
Concentration
Code S- Actual Water Quality Data
No
Mass
4.21
PCB-1232(11141-16-5)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass
4.22
PCB-1248(12672-296)
X
Concentration
Code S- Actual Water Quality Data
No
Mass
4.23
PCB-1260(11096-825)
X
Concentration
Code S- Actual Water Quality Data
No
Mass
4.24
PCB-1016(12674-14-2)
x
Concentration
Code 5- Actual Water Quality Data
No
Mass
4.25
Toxaphene(8001-35-2)
X
Concentration
Code 5- Actual Water Quality Data
No
Mass

Additional Information Request
Attachment 4
EPA Form 2E Section 7

SECTION 7. OTHER INFORMATION (40 CFR 122.21(h)(7))
Samples in Section 4 reflect expected discharge quality; the samples were taken from the Pit Lake, not
the outfall point.
Water quality of the discharge water contained within Pit Lake does not exceed Class C aquatic water
standards (See Engineering Alternative Analysis Attachment). The attached Kings Creek Stability and
Water Quality Assessment demonstrates that minor increases in flow due to the mine pit dewatering is
not expected to adversely impact the banks of Kings Creek and is not expected increase flood or
adversely affect elevations beyond the subject property lines. Based on the attached Engineering
Alternatives Analysis, direct discharge to Kings Creek is deemed the most environmentally sound
alternative of the economically viable alternatives for dewatering Pit Lake.
The dewatering configuration under consideration is conveyance of pit water to the South Creek
Reservoir prior to discharging to Kings Creek. The attached Plan Sets show the facility and proposed
aboveground pipeline will run from the pit to South Reservoir along existing roads with no additional
ground disturbance.