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HomeMy WebLinkAboutNC0002305_Report_20201207' a i 66002 Windmill Way Wilmington, NC 28405 Client P • ; •t Sample1 1 1220-713 Isotope Dilution Method NCDEQ PFAS List Enthalpy Analytical, LLC — Ultratrace Lindsay Boone 0: (910) 212-5855 / F: 910-212-5866 Iboone(o)enthalpv.com / www.enthalpy.com 2714 Exchange Drive, Wilmington, NC 28405 Environmental Chemist, Inc., Wilmington, NC Lab #94 Sample Receipt Checklist 6602 Windmill Way Wilmington, NC 28405 910.392.0223 Client: G l.0 ( O-D F1l`S� Date: Z 2 20 Report Number. 20— Z(D { 3tn Receipt of sample: E HEM PickupA Client Delivery ❑ f UPS ❑ FedEx ❑ Other ❑ ❑ YES ❑ NO N/A re custody seals present on the cooler? ❑ YES ❑ NO N/A ]E2 ustody seals were present, were they intactJunbroken? Original temperature upon receipt kc °C Corrected temperature upon receipt °C How temperature taken: ❑ Temperature Blank Against Bottles IR Gun ID: Thomas Traceable 5/N 192511657 IR Gun Correction Factor °C: 0.0 YES ❑ NO 3. If temperature of cooler exceeded 6`C, was Project Mgr./QA notified? YES ❑ NO 4. Were proper custody procedures (relinquished/received) followed? NA YES ❑ NO 5. Were sample ID's listed on the COC? YES ❑ NO 6. Were samples ID's listed on sample containers? YES ❑ NO 7. Were collection date and time listed on the COC? YES ❑ NO 8. Were tests to be performed listed on the COC? YES ❑ NO 9. Did samples arrive in proper containers for each test? YES ❑ NO 10. Did samples arrive in good condition for each test? YES ❑ NO 11. Was adequate sample volume availableT YES ❑ NO 12. Were samples received within proper holding time for requested tests? YES 113 NO 113. Were acid preserved samples received at a pH of <2? YES I0 NO 114, Were cyanide samples received at a pH >12? YES ❑ NO 15. Were sulfide samples received at a pH >9? YES ❑ NO 116. Were NH3/TKN/Phenol received at a chlorine residual of <0.5 m/L? ** YES ❑ NO 117. Were Sulfide/Cyanide received at a chlorine residual of <0.5 m/L? ❑ YES ❑ NO 118. Were orthophosphate samples filtered in the field within 15 minutes? * TOC/Volatiles are pH checked at time of analysis and recorded on the benchsheet. ** Bacteria samples are checked for Chlorine at time of analysis and recorded on the benchsheet. Sample Preservation: (Must be completed for any sample(s) incorrectly preserved or with headspace) Sample(s) were received incorrectly preserved and were adjusted accordingly by adding (circle one): H2SO4 HNO3 HCI NaOH Time of preservation: If more than one preservative is needed, notate in comments below Note: Notify customerservice immediately for incorrectly preserved samples. Obtain a new sample or notify the state lab if directed to analyzed by the customer. Who was notified, date and time: Volatiles Sample(s) were received with headspace COMMENTS: DOC. QA.002 Rev 1 I certify that to the best of my knowledge all analytical data presented in this report: • Have been checked for completeness • Are accurate, error -free, and legible • Have been conducted in accordance with approved protocol, and that all deviations and analytical problems are summarized in the appropriate narrative(s) This analytical report was prepared in Portable Document Format (.PDF) and contains 18 pages. jo, Mik I j OA iew Performed by: Juanica L Thomas kN-iHALPY 12/23/2020 Report Issued Date: EU # 1220-713 2 of 18 ERi1'HALPY A .N A I% I f L A I EU # 1220-713 3 of 18 Enthalpy Analytical Job No.: 1220-713-1 PFAS by Isotope Dilution (non -potable water) Environmental Chemist Project No.: 2020-20436 Compound CAS 20-52023 ng/L PFBA; 375-22-4 <LOD (0.155) U PFPeA= 2706-90-3 489 PFHxA 307-24-4 172 PFHpA 375-85-9 123 PFOA 335-67-1 27.4 Acids PFNA 375-95-1 5.16 PFDA 335-76-2 5.99 PFUnDA 2058-94-8 1.10 PFDoDA 307-55-1 0.187 J PFTrDA 72629-94-8 <LOD (0.0732) U PFTeDA PFBS° 376-06-7 375-73-5 <LOD (0.0816) U <LOD (0.0816) U PFPeS 2706-91-4 <LOD (0,0973) U PFHxS 355-46-4 <LOD (0.0813) U Sulfonates PFHpS 375-92-8 <LOD (0.0766) U PFOS 1763-23-1 21.6 PFNS 68259-12-1 <LOD (0.0643) U PFDS PFOSA 335-77-3 754-91-6 <LOD (0.133) U 2.09 Other N-McFOSAA 2355-31-9 4.58 N-EtFOSAA 2991-50-6 0.198 J EU # 1220-713 4 of 18 III ' MilliA r: EU # 1220.713 5 of 18 Enthalpy Analytical Job No.: 1220-713.1 PFAS by Isotope Dilution (non -potable water) Environmental Chemist Project No.: 2020-20436 Enthalpy ID 1220-713-001-1 Sample Name 2052023 Matrix Aqueous Sampling Date 20201201 00:00 Prep Batch EU11351 Sample Vol (mL) 254.31 Prep Date 2020-12-09 16:31 Extract Vol (mL) 0.4 Analysis Date 2020-12-10 00:15 Dilution Factor 1 Extract Sample Formatted Compound CAS Concentration Concentration Result LOD L00 Recovery Recovery Flags ng/L nglL ng/L ng/L ng/L Limits PFBA 375-22-4 NO NO <LOD 0.155 0.299 U PFPeA 2706-90-3 310817.11 4B9 489 0.0883 0289 PFHxA 307.24.4 109283.40 172 172 0.155 0.289 PFHpA 375-859 78408.37 123 123 0.0683 0.289 PFOA 335-67-1 17412.14 27.4 27A 0.0781 0.289 Acids PFNA 375-95-1 3281.12 5.16 5.16 0.0500 0.2B9 PFDA 335-76-2 3807.15 5.99 5.99 0.123 0.289 PFUnDA 2058-94-8 700.41 1.10 1.10 0.0473 0.289 PFDoDA 307-55-1 119.15 0.187 0.187 0.0467 0.289 J PFTrDA 72629-94-8 NO NO <LOD 0.0732 0.289 U PFTeDA PFBS 376-06-7 375-73-5 NO ND NO ND < 01) <LOD 0.0816 0.0816 0.289 0.256 U U PFPeS 2706-91-4 NO NO <LOD 0.0973 0.272 U PFHxS 355-46-4 NO NO <LOD 0.0813 0.264 U Sulfonates PFHpS 375-92-8 NO NO <LOD 0.0766 0.275 U PFOS 1763-23.1 13740.74 21.6 21.6 0.0463 0.269 PFNS 68259-12-1 NO NO <LOO 0.0643 0.278 U PFOS PFOSA 335-77-3 754-91-6 NO 1326.38 NO 2.09 <LOD 2.09 0.133 0.359 0.280 0.360 U Other N-MCFOSAA 2355-31-9 2909.86 4.58 4.58 0.0535 0.289 N-EtFOSAA MPFBA 2991-50-6 125.82 3580.62 0.198 5.63 0.198 0.0640 0.289 20-150% 71.6% J MSPFPeA 4967.84 7.81 20-150% 99.4% M3PFBS 26344.86 41.4 41.4 20-150% 526.9%0 MSPFHxA 2814.18 4.43 20-150% 56.3% M4PFHpA 4577.30 720 20-150% 91.5% M3PFHxS 5337.17 8.39 8.39 20-150% 106.7% M8PFOA 4877.94 7.67 20-150% 97.6% M9PFNA 5931.87 9.33 9.33 20-150% 118.6% ES MBPFOS 4402.70 6.92 20-150% 88.1% M8FOSA-1 1423.57 224 20-150% 28.5% M6PFDA 4250.25 6.69 20-150% 85.0% d3-N-MaFOSAA 3135.42 4.93 20-150% 62.7-A d5-N-EtFOSAA 303226 4.77 20-150% 60.6% M7PFUdA 4064.88 6.39 20-150% 81.3% MPFDoA 2277-79 3.58 20-150% 45.6% M2PFTeDA 867.06 1.36 20-150% 17.3%0 EU # 1220-713 6 of 18 EU # 1220-713 7 of 18 Enthalpy Analytical Job No.: 1220-713-1 PFAS by Isotope Dilution (non -potable water) Environmental Chemist Project No.: 2020-20436 Enthalpy ID MB-11351-PFAS Sample Name MB-11351-PFAS Matrix Aqueous Sampling Date Prep Batch EU11351 Prep Date 2020A2-0916:31 Analysis Date 2020-12-09 23:29 Sample Vol (mL) 250 Extract Vol (mL) 0A Dilution Factor 1 Extract Sample Formatted Compound CAS Concentration Concentration Result LOD LOD LOO Recoveryng/L Recovery Flags ng/L ng/L ngIL ng/L Limits PFBA 375-224 NO NO <LOD 0.157 0.294 U PFPeA 2706-90-3 NO ND <LOD 0.0898 0.294 U PFHxA 307-244 34.136 0.0558 <LOD 0.158 0.294 U PFHpA 375-85-9 1.69 0.00271 <LOD 0.0695 0294 U PFOA 335-67-1 48.51 0.0776 <LOD 0.0795 0.294 U Acids PFNA 375-95-1 NO NO <LOD 0.0509 0.294 U PFDA 335-76-2 NO NO <LOD 0.125 0294 U PFUnDA 2058.94-8 NO NO <LOD 0.0481 0.294 U PFDODA 30755-1 NO ND <LOD 0.0475 0.294 U PFTrOA 72629-94-8 NO ND <LOD 0.0745 0.294 U PFTeDA PFBS 376-06-7 375-73.5 NO ND NO ND <LOD <LOD 0.0630 0.0830 0294 0.261 U U PFPeS 2706-914 NO NO <LOD 0.0990 0277 U PFHxS 355464 NO NO <1_00 0.0827 0.269 U Sulfonates PFHpS 375-92-8 NO NO <LOD 0.0779 0.280 U PFOS 1763-23-1 NO NO <LOD 0.0471 0.274 U PFNS 68259-12-1 NO NO <LOD 0.0654 0.283 U PFDS PFOSA 335-77-3 754-91-6 ND ND NO NO <LOD <LOD 0.135 0.365 0.285 0.366 U U Other N-MCFOSAA 235531-9 NO NO <LOD 0.0544 0.294 U N-EtFOSAA MPFBA 2991-50.6 NO 4674.14 NO 7.48 <LOD 0.0651 0.294 20450% 93.5% U MSPFPeA 5572.44 8.92 8.92 20-150% 111.4% M3PFBS 5624.38 9.00 9.00 20-150% 112.5% MSPFHxA 5065.84 8.11 8.11 20-150% 101.3% M4PFHpA 4749.33 7.60 20-150% 95.0% M3PFHxS 4637-02 7.42 20-150% 92.7% MBPFOA 5106.81 8.17 8.17 20-150% 102.1% M9PFNA 4930.27 7.89 20-150% 98.6% ES MBPFOS 4349.59 6.96 20-150% 87.0% M8FOSA-1 2923.90 4.68 20-150% 58S% M6PFDA 4286.09 6.8E 20-150% 65.7% d3-N-MCFOSAA 3435.93 5.50 20-150% 68.7% d5-N-EtFOSAA 3257.46 521 20-150% 65.1% WPFUdA 4016.99 6.43 20-150% 80.3% MPFDOA 3798.39 6.08 20-150% 76.0% M2PFreDA 2104-11 3.37 20-150% 42.1% EU#1220.713 8of 18 Enthalpy Analytical Jab No.: 1220-713-1 PFAS by Isotope Dilution (non -potable water) Environmental Chemist Project No.: 2020-20436 Enthalpy ID OPR-11351-PFAS Sample Name OPR-11351-PFAS Matrix Aqueous Sampling Date Prep Batch EU11351 Sample Vol (mL) 250 Prep Date 2020-12-09 16:31 Extract Vol (mL) 04 Analysis Date 2020-12-0923:52 Dilution Factor 1 Extract Sample Formatted LOD LOD Recovery Compound CAS Concentration Concentration Result ng/L ng/L Limits Recovery Flags ng/L ng/L n91L PFBA 375-22 4 11034.18 17.7 17.7 0.157 0.294 88.3% PFPeA 2706-90-3 11293.32 18.1 18.1 0.0898 0.294 90.3% PFHxA 307.244 11766.04 18.6 18.8 0.166 0.294 94.1% PFHpA 375-85-9 11232.29 18.0 16.0 0.0695 0.294 89.9% PFOA 335-67-1 10033.66 16.1 16.1 0.0795 0.294 80.3% Acids PFNA 375-95-1 11265.50 18.0 18.0 0.0509 0.294 90.1% PFOA 335-76-2 12944.11 20.7 20.7 0.125 0.294 103.6% PFUnDA 2058-94-8 12229,76 19.6 19.6 0.0481 0.294 97.8% PFDoDA 307.55-1 10181.31 16.3 16.3 0.0475 0.294 81.5% PFTrDA 72629-94-8 13664.06 21.9 21.9 0.0745 0.294 109.3% PFTeDA PFBS 376-06-7 375-73-5 10935.33 10281.40 17.5 16.5 17.5 16.5 0.0830 0.0830 0294 0.261 87.5% 02.7% PFPeS 2706-914 10330,68 16.5 16.5 0.0990 0.277 67.8% PFHxS 355464 10788.38 17.3 17.3 0.0827 0.269 94.4% Sulfonates PFHpS 375-92-8 10184.84 16.3 16.3 0.0779 0.280 85.5% PFOS 1763-23-1 9796.15 15.7 15.7 0.0471 0.274 84.49/6 PFNS 68259-12-1 9942-44 15.9 15.9 0.0654 0.283 82.7% PFDS PFOSA 335.77-3 754-91-6 11665.011 12177.51 18.7 19.5 18.7 19.5 OA35 0.365 0.285 0.366 96.7% 97.4% Other N-MCFOSAA 2355-31-9 11065.98 17.7 17.7 0.0544 0.294 88.5% N-EtFOSAA MPFBA 2991-50-6 10786.63 4750.35 17.3 7.60 17.3 0.0551 0.294 20-150% 86.3% 95.0% M5PFPeA 5261.33 8.42 8.42 20-150 % 105.2 % M3PFSS 4931.67 7.89 20-150% 96.6% M5PFHxA 4793.72 7.67 20-150% 95.9% M4PFHPA 4919.79 7.87 20-150% 98.4% M3PFHxS 4670.70 7A7 20-150% 93.4% M8PFOA 5013.76 8.02 8.02 20-150% 100.3% M9PFNA 4973.47 7.96 20.150% 99.5% ES MBPFOS 4736.32 7.58 20-150 % 94.7% MSFOSA-1 3625.58 5.80 20-150% 72.5% MBPFDA 4111.43 6.68 20-150% 82.2% d3-N-McFOSAA 3359.21 5.37 20-150% 67.2% d5-N-EIFOSAA 3414.77 5.46 20-150% 68.3% M7PFUeA 3997.99 6.40 20-150% 80.0% MPFDoA 4209.62 6.74 20-150% 84.2% M2PFTeDA 2471.18 3.95 1 20.150%1 49.4% EU # 1220-713 9 of 18 SEM=M111-11plim EU # 1220-713 10 of 18 Enthalpy Analytical Narrative Summary Company Environmental Chemist Job No. - 1220-713-1 PFAS by Isotope Dilution (non -potable water) Client ID. 2020-20436 1. Custody Ann Marie Baxter received the samples on December 07, 2020 at 6.8 °C after being relinquished by Environmental Chemist. The samples were received in good condition. Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, LLC Table 1 - Sample Inventory EU Lab Sample ID Client Sample ID Matrix 1220-713-001-1 20-52023 Aqueous 2. Methods and Analytes A list of analytes of interest and corresponding methods of analysis is shown in Table 3. Abbreviations are defined in the listed Appendices. Table 3 - Methods and Analytes EU Method Analytes Cleanup Method EU-047 NCDEQ - PFAS List ENVI-Garb 3. Analysis The samples were analyzed using Waters Acquity UPLC equipped with Xevo TQ MS (LC/MS/ MS "Kili"). For aqueous samples, the sample volume was measured gravimetrically by the laboratory, and spiked with Extraction Standard (ES). The sample was then mixed well and centrifuged, if needed. The samples were then extracted via SPE, and the extracts were cleaned up using ENVI-Garb. Each final sample extract was transferred to an autosampler vial, spiked with Injection Standard (IS), and brought to a final volume of 400NL prior to analysis. 4. Calibration In the initial calibration, the reported analytes exhibited RA2 of >_ 0.99. The reported analytes in the calibration standards, continuing calibration (concal) and Initial Calibration Verification (ICV) met the 30% accuracy criterion for native analytes. Pnnted 2020 12 15 Pale 1 of 2 EU N 1220-M 11 of 18 Enthalpy Analytical Narrative Summary Company Environmental Chemist Job No. 1220-713-1 PFAS by Isotope Dilution (non -potable water) Client ID. 2020-20436 5. QC Notes The QC sample analyses passed all method criteria. The samples were extracted within the 28-day from collection holding time and analyzed within the 28-day from extraction to analysis holding time required by the method. 6. Reporting Notes Some labeled standards in the samples fell outside the limits for ES recoveries, as notated by a Q qualifier. The target analytes are quantified based on their ratio to the labeled standards, therefore, undergo the same losses as the labeled standards. As a result, low or high recoveries do not cause any change to ratios or contribute any additional error in the measurement of the target analytes. Therefore, the data are considered acceptable. The results presented in this report are representative of the samples as provided to the laboratory. These analyses met the requirements of the TNI Standard. Any deviations from the requirements of the reference method or TNI Standard have been stated above. EnthalpyAnalytical, LLC in Wilmington NC is accredited by the Louisiana Department of Environmental Quality to the 2009 TNI Standard under certificate number 05075. Printed 2020-12-15 Page 2 of 2 EU # 1220-713 12 of 18 General Reporting Notes — Data Qualifiers ENTHALPY The following are general reporting notes that are applicable to all Enthalpy Analytical, LLC - Wilmington, NC data reports, unless specifically noted otherwise. General Data Qualifiers • B - The analyte was found in the method blank, at a concentration that was at least 10% of the concentration in the sample. • Cxx - Two or more congeners co -elute. In EDDs, C denotes the lowest IUPAC congener in a co - elution group and additional co-eluters for the group (`xx') are shown with the number of the lowest IUPAC co-eluter. • E - The reported concentration exceeds the calibration range (upper point of the calibration curve). For FIRMS data, this condition does not imply additional measurement uncertainty. For LC-MS/MS data, these values should be considered as having measurement uncertainty higher than values within the calibration range. • EDL - Estimated Detection Level. Specific to Dioxin/Furan tests and equivalent to MDL • EMPC -Estimated Maximum Possible Concentration Specific to Dioxin/Furan tests to indicate the signal/noise ratio wass not sufficient for peak identification (the determined ion -abundance ratio was outside the allowed theoretical range), or where there was a co -eluting interference. Indicates that a peak was identified but did not meet the method specified ion -abundance ratio. • IR - The ion ratio between the primary and secondary ions was observed to be outside the method criteria therefore the actual analyte concentration cannot be accurately determined as defined by DoD QSM Table B-15. • J - The analyte has a concentration below the minimum calibration level (LOQ value) but greater than the LOD. These values should be considered as having measurement uncertainty higher than values within the calibration range • L - Indicates that an analyte has a concentration below the Minimum Detection Limit (MDL). The reported concentration is not recommended for regulatory use as the analyte signal may have a signal-to-noise ratio less than the criteria deemed necessary to be considered a detected analyte. • LOD - Limit of Detection: For reports conforming to the DOD ELAP QSM, this is the QSM- defined LOD. For reports conforming to TNI requirements (but not DOD ELAP QSM requirements), this value is the minimum detection limit (MDL). The LOD is adjusted for sample weight or volume. • LOQ -Limit of Quantiation: For reports conforming to the DOD ELAP QSM, this is the QSM- defined LOQ. For reports conforming to TNI requirements (but not DOD ELAP QSM requirements), this value is the reporting limit (RL). The LOD is adjusted for sample weight or volume. • <LODQ - Analyte was not found at a concentration high enough to be reported as detected. It is reported as less than the LOD, and the LOD is given in the parentheses. EU116_v4 (General Reporting Notes -Data Qualifiers) Enthalpy Analytical, LLC - Wilmington, NC EU # 1220-713 13 of 18 �v General Reporting Notes — Data Qualifiers ENTHA PL Y • ND — Indicates a non -detect. • NR — Indicates a value that is not reportable due to issues observed in sample preparation or analysis. • PR — The associated congener(s) is(are) poorly resolved. • QI — Indicates the presence of a quantitative interference. • RL — Reporting Limit. Lowest reportable value. The level is higher than the MDL. • SI — Denotes "Single Ion Mode" and is utilized for PCBs where the secondary ion trace has a significantly elevated noise level due to background PFK. Responses for such peaks are calculated using an EMPC approach based solely on the primary ion area(s) and may be considered estimates. • U — The analyte was not detected. • V —The labeled standard recovery is not within method control limits. • X —Results from re-injection/repeat/second-column analysis. Lab Identifiers/ Data Attributes • AR — Indicates use of the archived portion of the sample extract. • CU —Indicates a sample that required additional clean-up prior to HRMS injection/processing. • D — Dilution Data. Result was obtained from the analysis of a dilution. The number that follows the "D" indicates the dilution factor. • DE — Indicates a dilution performed with the addition of ES (Extraction Standard) solution. • DUP — Designation for a duplicate sample. • MS — Designation for a matrix spike. • MSD — Designation for a matrix spike duplicate. • RJ — Indicates a reinjection of the sample extract. • S — Indicates a sample split. The number that follows the "S" indicates the split factor. • R — Indicates a re -extraction of the sample. EUI l6_v4 (General Reporting Notes -Data Qualifiers) Enthalpy Analytical, LLC — Wilmington, NC EJ # 1220-713 14 of 1a Attachment B Analyte Name Acronym Perfl4atetradecanoic acid PFTeA Perfluo' otridecanoic acid _ ' PFTriA Perfluor-ododecanolc acid PFDoA . Perfluoroundecanoic acid PFUnA Perfluorodecanoicacid - PFDA" Perfluo'Tononanoic acid - PFNA Perfluo�ooctanoic acid PFOA Ferfluoroheptanolc acid PFHQA -1 .. Perfluorohexanolc acid — PFHxA Perfluoiopentanoic acid PFPeA Perfluojobutanoic acid PFBA Per fluoiodecanesulfomc acid PFDS Perfluorononanesulfonic PFNS _acid Perfluorooctanesulfomcacid PFOS Perfluoroheptanesulfonic acid PFHpS Perfluorohexanesulfonic acid _ PFHxS _ acid_„ Perfluotopentanesulfonic acid .__ PFPeS _- Perfl_uorobutanesulfonic'acid PFBS Perfluofooctanesulfonamide PFOSA acetic Old 2-(N- ethylperfluorooctanesulfonamido) N-McFOSAA acetic acid Fluorinated Molecular r CAS Carbon Formula Number Chain Length ? G, CuF27C00H 376 06 7 t Cn C,2FnC00H 72629-94-8 C_,: C,,F COOH �C,oF2,COOH 307-55-1 _C„ 2O58-94-8 Go l CgFi9C00H 335-76-2 C E CBF17COOH 375 95-1 Ca C7F1sCOOH 335-67-1 C, C6F13C00H 375-$5-9 Co CSFIICOOH 307 24-4 C, C4FsC_0_0H 2706-90-3 C, C3F7COOH 375-22-4 C,o CioF21S03H 335 77-3 C r CsFigS03H 6825.... [ C. C8Fi7S03H 1763 23 1 C, _ - C7FISS03H ._-.- 375-92-8 Ca C6F13S03H 355-46-4 C, C5Fn503H 2706-914 C, MG C4F9S03H 375-73-5 _ -- - CB C8F17SO2NH2 754-91-6 Ca C8Fl7SO2N(C2H5) 2991-50-6 CH2COOH C. C8F17S02N(CH3) 2355-31-9 CHCOOH EU # 1220-713 15 of 18 YMail . E N THA LPY A xAI)IICd I. EU # 1220-713 16 of 18 f [ !I $ I § \ [