Loading...
HomeMy WebLinkAboutNC0002305_Report_2021041466002 Windmill Way Wilmington, NC 28405 Client Project # • Sample Received: 04/14/21 LNI HALPY Analytical Repo i • Enthalpy Analytical, L — ltratr ce Linsay Boone 0: (910) 212-5855 / F: 910-212-5866 Iboone(aenthalpv.com / www.enthalpy.com 2714 Exchange Drive, Wilmington, NC 28405 I certify that to the best of my knowledge all analytical data presented in this report: • Have been checked for completeness • Are accurate, error -free, and legible • Have been conducted in accordance with approved protocol, and that all deviations and analytical problems are summarized in the appropriate narrative(s) This analytical report was prepared in Portable Document Format (PDF) and contains 18 pages. Digitally signed by Bryan Vining DN: cn=Bryan Vining, o=Enthalpy Analytical Ultratrace, ou, email=bryan.vining@enth alpy.com, c=US Date: 2021.04.23 17:06:06 -04'00' 23MAR21 Report Issued Date: EU#0421-749 Page 2 of 18 .,: EN FHALPY EU#0421-749 Page 3 of 18 9 ' Enthalpy Analytical Job No.: 0421-749-1 PFAS by Isotope Dilution (non -potable water) Environmental Chemist Client No.: 2021-05591 21-13824 Compound CAS ng/L PFBA 375-22-4 50.1 PFPeA 2706-90-3 369 PFHxA 307-24-4 145 PFHpA 375-85-9 95.3 PFOA 335-67-1 10.2 Acids PFNA 375-95-1 1.58 PFDA 335-76-2 1.77 PFUnDA 2058-94-8 0.332 PFDoDA 307-55-1 <LOD (0.201) U PFTrDA 72629-94-8 <LOD (0.150) U PFTeDA PFBS 376-06-7 375-73-5 <LOD (0.217) U <LOD (0.354) U PFPeS 2706-91-4 <LOD (0.205) U PFHxS 355-46-4 1.24 Sulfonates PFHpS 375-92-8 <LOD (0.135) U PFOS 1763-23-1 8.10 PFNS 68259-12-1 <LOD (0.0861) U PFDS PFOSA 335-77-3 754-91-6 <LOD (0.191) U 1.76 Other N-McFOSAA 2355-31-9 2.44 N-EtFOSAA 2991-50-6 <LOD (0.109) U EU#0421-749 Page 4 of 18 EN I HALPY EU#0421-749 Page 5 of 18 Enthalpy Analytical Job No.: 0421-749-1 PFAS by Isotope Dilution (non -potable water) Environmental Chemist Client No.: 2021-05591 Enthalpy ID 0421-749-001-1 Prep Batch EU71717 Sample Vol (mL) 250.88 Sample Name 21-13824 Prep Date 2021-04-1515:30 Extract Vol (mL) 0A Matrix Aqueous Analysis Date 2021-0416 20:45 Dilution Factor 1 Sampling Data 2021040700:00 Analyst rappelle Method Code WM-026 Received Date 2021-04-1411:00 Instrument Fili Sample Type Sample Extract Sample Formatted LOD LOO Recovery Compound CAS Concentration Concentration Result Recovery Flags ng1L nglL ng/L nglL nglL Limits PFBA 375-224 31450.15 50.1 $0.1 0.152 0,293 PFPeA 2706-90-3 231687.12 369 369 0.169 0293 PFHxA 307-244 91030,41 145 145 0.192 0.293 PFHpA 375-85-9 59753.10 95.3 95.3 0.122 0.293 PFOA 335-67-1 6410.23 10.2 10.2 0.176 0.293 Acids PFNA 375-95-1 988.34 1.58 1.58 0.0758 0.293 PFDA 335-76-2 1110.07 1,77 1.77 0.0642 0293 PFUnDA 2068-94-8 208.40 0.332 0.332 0.184 0.293 PFDoDA 307-55-1 ND NO <LOD 0.201 0.293 U PFTrDA 72629-94-8 NO NO <LOD 0.150 0,293 U PFTaDA PFBS 376-06-7 375-73-5 NO NO NO NO <LOD <LOD 0.217 0.354 0.293 0.354 U U PFPeS 2706-914 NO NO <LOD 0.205 0,276 U PFHxS 355464 777,30 1.24 1.24 0.190 0,268 Suffocates PFHpS 375.92-8 NO NO <LOD 0.135 0.279 U PFOS 1763-23-1 5078.67 8.10 8.10 0.159 0,273 PFNS 68259-12-1 NO ND <LOD 0.0861 0.282 U PFDS PFOSA 335-77-3 764-91-6 NO 1105.28 NO 1.76 <LOD 1.76 0,191 0.130 0.284 0,365 U Other N-McFOSAA 2355-31-9 1531.96 2.44 2,44 0.143 0,293 N-EtFOSAA MPFBA 2991-506 59.77 3251.10 0,0953 5.18 <LOD 0.109 0.293 20-150% 65.0% U M5PFPeA 4239.11 6.76 20-150% 84.8% M3PFBS 13712.92 21.9 20-150% 274.3%0 M5PFHxA 3390.85 5.41 20-150% 67.8% M3HFPO-DA 3979,80 6.35 20-150% 79.6% M4PFHRA 4486,54 7.15 20-150% 89.7% M3PFHxS 3730.20 5.95 20-150% 74,6% M8PF0A 4681.04 7.46 20-150% 93.6% ES M9PFNA 5339.99 8.51 20-150% 106,8 % M8PFOS 4189.28 6.65 20-150 % 83.8 % MSFOSA-1 1875,43 2.99 20-150% 375% M6PFDA 4524.64 7.21 20-150% 90.5% d3-N-MCFOSAA 3737.09 5.96 20-150% 74.7% d5-N-EtFOSAA 3860.83 6.16 20-150% 77.2% M7PFUdA 3981.57 6.35 20-150% 79.6% MPFDOA 3265.23 5.21 20-150% 65.3% M2PFTaDA 1782A6 2.84 20-150% 35.6% EU#0421-749 Page 6 of 18 EU#0421-749 Page 7 of 18 Enthalpy Analytical Job No.: 0421-749-1 PFAS by Isotope Dilution (non -potable water) Environmental Chemist Client No.: 2021-05591 Enthalpy ID MB-11717-PFAS Prep Batch EU11717 Sample Vol (mL) 250 Sample Name MB-11717-PFAS Prep Date 2021-04-15 15:30 Extract Vol url 0.4 Matrix Aqueous Analysis Date 2021-04-16 18:03 Dilution Factor 1 Sampling Date Analyst rappelle Method Code WM-026 Received Date 2021-04A515o30 Instrument Fill Sample Type Blank Extract Sample Formatted LOD LOD Recovery Compound CAS Concentration Concentration Result nglL ng;L Limits Recovery Flags ng/L muL ng/L PFBA 375-224 ND NO <LOD 0.153 0.294 U PFPeA 2706-90-3 NO NO <LOD 0,170 0.294 U PFHxA 307-24-4 6,97 0.0112 <LOD 0.193 0.294 U PFHpA 375-85-9 33.25 0.0532 -LOD 0,122 0.294 U PFOA 335-67-1 NO ND <LOD 0.177 0.294 U Acids PFNA 375-95-1 NO NO <LOD 0.0761 0.294 U PFDA 335-76-2 ND ND -LOD 0,0845 0,294 U PFUnDA 2058-94-8 NO NO -LOD 0.185 0.294 U PFDoDA 307-55-1 NO NO <LOD 0202 0.294 U PFTrDA 72629-94-8 NO NO <LOD 0.151 0,294 U PFTeDA PFBS 376-06-7 375-73-5 NO ND NO NO -LOD <LOD 0,21E 0.355 0,294 U55 U U PFPeS 2706-914 NO NO <LOD 0.206 0.277 U PFHxS 35546.4 NO NO <LOD 0.191 0.269 U Sulronates PFHpS 375-92-8 NO NO <LOD 0.135 0.280 U PFOS 1763-23-1 ND ND <LOD 0-160 0.274 U PFNS 68259-12-1 ND NO -LOD 0,0864 0.283 U PFDS PFOSA 335-77-3 754-91-6 NO NO ND NO <LOD <LOD 0.192 0.130 0285 0.366 U U Other N-McFOSAA 2355-31-9 NO NO <OD 0.144 0294 U N-EtFOSAA MPFBA 2991-50-6 NO 4926,86 NO 7.88 <LOD 0A09 0,294 20-150% 98,5% U M5PFPeA 5285.55 8,46 20-150% 105.7% M3PFB5 5250,81 8.40 20-150% 105.0% M5PFHxA 4B25.62 7.72 20-160% 96.5% M3HFPO-DA 5121,95 8.20 20-150% 102.4% M4PFHpA 5077.04 8.12 20-150% 101.5% M3PFHxS 4956.12 7,93 20-150% 991% M8PFOA 4950.86 7.92 20-150% 99.0% ES M9PFNA 5857,30 9.37 20-150% 117.1% M8PFOS 4216.46 6,75 20-150% 84.3% M6FOSA-I 259648 4,15 20-150% 599% M6PFDA 4012,34 6.42 20-150% 80.2% 0-N-MeFOSAA 2519A6 4.03 20-150% 50.4% dB-N-EtFOSAA 2375.17 3.80 20-150% 47.5% M7PFUdA 2614.27 4.18 20-150% 52.3% MPFDOA 234438 3.75 20-150% 46.9% M2PFTeDA 1799.59 2.89 20-t 507 EU#0421-749 Page 8 of 18 Enthalpy Analytical Job No.: 0421-749-1 PFAS by Isotope Dilution (non -potable water) Environmental Chemist Client No,: 2021-05591 Enthalpy ID OPR-11717-PFAS Prep Batch EU11717 Sample Vol (mL) 250 Sample Name OPR-11717-PFAS Prep Date 2021-04-15 15:30 Extract Vol (ML) 0.4 Matrix Aqueous Analysis Date 2021-04-1618:26 Dilution Factor 1 Sampling Date Analyst rappelle Method Code WM-026 Received Date 2021-041515:30 Instrument Fill Sample Type Control Extract Sample Formatted Compound CAS Concentration Concenbation Result LOD LOQ Recovery ng/L ng/L ng;L ng/L ng/L Limits ery Flags PFBA 375-22-4 14093.86 22.6 22S 0,153 0.294 73-129%,8% PFPeA 2706-90-3 12720.04 20.4 20A 0.170 0294 72-129%.8% PFHxA 307-24-4 13350.74 21.4 21.4 0.193 0294 72-129%.8% PFHPA 375-65-9 12878.51 20.6 20.6 0.122 0.294 72-130%.0% PFOA 335-67-1 13988.59 22.4 22.4 0.177 0,294 71-133%% Acids PFNA 375-95-1 13398.67 21A 21.4 0.0761 0294 69-130%.2% T170.0%Q PFDA 335-76-2 16116.77 25.8 25.8 0.0845 0.294 71-129%9% PFUnDA 2058-94-8 10761.01 17.2 172 0.185 0.294 69-133%1% PFDoDA 30755-1 14056.61 22,5 22.5 0.202 0.294 72-134%5% PFTrDA 72629-94-8 21253.93 34.0 34.0 0.151 0.294 65-144%0%QPFTeDA 376-06-714937.73 375-73-5 11355.80 23.9 18.2 23.9 18.2 0.218 0.355 0294 0.355 71-132%5%PFBS 72-134%41PFPeS 2706-91 4 12509.73 20.0 20.0 0.206 0.277 71-127%4 % PFHxS 355464 11943,67 19.1 19.1 0.191 0.269 68-131 % 104.5% Sulfonates PFHPS 375-92-8 15943.30 25.5 25.5 0.135 0.280 69-134% 133.8% PFOS 1763.23-1 12628.84 202 20.2 0.160 0274 65-140% 108.9% PFNS 68259-12-1 12260.86 19.6 19.6 0.0864 0.283 69-127% 102.0% PFDS PFOSA 335-77-3 754-91-6 9772.93 14604.49 15.6 23.4 15.6 23.4 0,192 0."0 0.285 0.366 53-142% 67-137% 81.0% 116.8% Other N-McFOSAA 2355-31-9 14735-84 23.6 23.6 0.144 0294 65-136% 117.9% IMSPFHxA N-EtFOSAA MPFBA 2991-50.6 15297.43 4470.37 24.5 7.15 24.5 0.109 0.294 61-135% 20-150% 122.4% 89.4% MSPFPeA 4849.64 7.76 20-150% 97.0% M3PFBS 4861.90 7.78 20-150% 97.2% 4586.96 7.34 20-150% 91.7% M3HFPO-DA 5169.56 8.27 20-150 % 103.4 % M4PFHPA 4163-52 6.66 20-150% 83.3% M3PFHxS 4507.40 7.21 20-150% 90,1 % M8PFOA 3556.00 5.69 20-150% 71.1 % ES M9PFNA 3635.07 5.82 20-150% 72.7% MBPFOS 3194.05 5.11 20-150% 63.9% M8FOSA-I 2269.74 3.63 20.150% 45.4% M6PFDA 2596.06 4.15 20-150% 51.9% d3-N-MCFOSAA 2223.37 3S6 20-150% 44.5% d5-N-EtFOSAA 185220 2.96 20-150% 37.0% M7PFUdA 2496.31 3.99 20-150% 49.9% MPFDoA 1660.14 2,66 20-150 % 33.2 % M2PFTeDA 1127.10 1.80 20-150% 22.5% EU#0421-749 Page 9 of 18 M= EU#0421-749 Page 10 of 18 Enthalpy Analytical Narrative Summary Company Environmental Chemist i Job No. 0421-749-1 PFAS by Isotope Dilution (non -potable water) Client ID. 2021-05591 j 1. Custody —I i Anthony Stokes received the samples on April 14, 2021 at 4.6 °C after being relinquished by Environmental Chemist. The samples were received in good condition. Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, LLC Table 1 -Sample Inventory 2. Methods and Analytes A list of analytes of interest and corresponding methods of analysis is shown in Table 3, Abbreviations are defined in the listed Appendices. i j Table 3 - Methods and Analytes EU-047 3. Analysis The samples were analyzed using Waters Acquity UPLC equipped with Xevo TQ MS (LC/MS/ MS "Fill"). For aqueous samples, the sample volume was measured gravimetrically by the laboratory, and spiked with Extraction Standard (ES). The sample was then mixed well and centrifuged, if needed. The samples were then extracted via SPE, and the extracts were cleaned up using ENV[-Carb. iEach final sample extract was transferred to an autosampler vial, spiked with Injection Standard (IS), and brought to a final volume of 400pL prior to analysis. 4. Calibration In the initial calibration, the reported analytes exhibited R A 2 of >_ 0.99. The reported analytes in the calibration standards, continuing calibration (concal) and Initial Calibration Verification (ICV) met the 30% accuracy criterion for native analytes. EUl:0421-749 Page 11 of 18 - -- - - Enthalpy Analytical Narrative Summary 1y Environmental Chemist 0421-749-1 PFAS by Isotope Dilution (non -potable water) ). 2021-05591 5. QC Notes Except where noted below, the QC sample analyses passed all method criteria. QC samples that did not meet method acceptance criteria were: In the LCS sample, OPR-11717-PFAS, PFTrDA was recovered above the upper acceptance limit. However, this analyte was not detected in the sample, and, thus, the data were accepted. The samples were extracted within the 28-day from collection holding time and analyzed within the 28-day from extraction to analysis holding time required by the method. 6. Reporting Notes Some labeled standards in the samples fell outside the limits for ES recoveries, as noted by a Q qualifier. The target analytes are quantified based on their ratio to the labeled standards, therefore, undergo the same losses as the labeled standards. As a result, low or high recoveries do not cause any change to ratios or contribute any additional error in the measurement of the target analytes. Therefore, the data are considered acceptable. The results presented in this report are representative of the samples as provided to the laboratory. These analyses met the requirements of the TNI Standard. Any deviations from the requirements of the reference method or TNI Standard have been stated above. Enthalpy Analytical, LLC in Wilmington INC is accredited by the Louisiana Department of Environmental Quality to the 2009 TNI Standard under certificate number 05075. _ __. EU#0421-749 Page 12 of 18_.. _.. _... __. 4 General Reporting Notes — Data Qualifiers iN IHALPY The following are general reporting notes that are applicable to all Enthalpy Analytical, LLC - Wilmington, NC data reports, unless specifically noted otherwise. General Data Qualifiers ® B — The analyte was found in the method blank, at a concentration that was at least 10% of the concentration in the sample. ® Cxx — Two or more congeners co -elute. In EDDs, C denotes the lowest IUPAC congener in a co- clution group and additional co-cluters for the group (`xx') arc shown with the number of the lowest IUPAC co-eluter. a E — The reported concentration exceeds the calibration range (upper point of die calibration curve). For HRMS data, this condition does not imply additional measurement uncertainty. For LC-MS/MS data, these values should be considered as having measurement uncertainty higher than values within the calibration range. ® EDL — Estimated Detection Level. Specific to Dioxin/Furan tests and equivalent to MDL ® EMPC —Estimated Maximum Possible Concentration Specific to Dioxin'Furan tests to indicate the signal noise ratio Wass not sufficient for peak identification (the determined ion -abundance ratio was outside the allowed theoretical range), or where there was a co -eluting interference. Indicates that a peak was identified but did not meet the method specified ion -abundance ratio. ® IR — The ion ratio between the primary and secondary ions was observed to be outside the method criteria therefore the actual analyte concentration cannot be accurately detennined as defined by DoD QSM Table 13-15. ® J —The analyte has a concentration below the minimum calibration level (LOQ value) but greater than the LOD. These values should be considered as having measurement uncertainty higher than values within the calibration range ® L - Indicates that an analyte has a concentration below the Minimum Detection Limit (MDL). The reported concentration is not recommended for regulatory use as the analyte signal may have a signal-to-noise ratio less than the criteria deemed necessary to be considered a detected analyte. ® LOD — Limit of Detection: For reports conforming to the DOD ELAP QSM, this is the QSM- defined LOD. For reports conforming to TNI requirements (but not DOD ELAP QSM requirements), this value is the minimum detection limit (MDL). The LOD is adjusted for sample weight or volume. ® LOQ —Limit of Quantiation: For reports conforming to the DOD ELAP QSM, this is the QSM- defined LOQ. For reports conforming to TNI requirements (but not DOD FLAP QSM requirements), this value is the reporting limit (RL). The LOD is adjusted for sample weight or volume. ® <LODQ — Analyte was not found at a concentration high enough to be reported as detected. It is reported as less than the LOD, and the LOD is given in the parentheses. EUI 16_v4 (General Reporting Notes -Data Qualifiers) Enthalpy Analytical, LLC — Wilmington, NC EU#0421-749 Page 13 of 18 � � u _m General Reporting Notes —17ata Qualifiers • ND — Indicates a non -detect. • NR — Indicates a value that is not reportable due to issues observed in sample preparation or analysis. • PR —The associated congener(s) is(are) poorly resolved. • QI — indicates the presence of a quantitative interference. • RL — Reporting Limit. Lowest reportable value. The level is higher than the MDL. • SI — Denotes "Single Ion Mode" and is utilized for PCBs where the secondary ion trace has a significantly elevated noise level due to background PFK. Responses for such peaks are calculated using an EMPC approach based solely on the primary ion area(s) and may be considered estimates. • U —The analyte was not detected. V — The labeled standard recovery is not within method control limits. • X — Results from re-injection/repeat/second-column analysis. Lab Identifiers/ Data Attributes • AR — Indicates use of the archived portion of the sample extract. • CU — Indicates a sample that required additional clean-up prior to HRMS injection/processing. • D — Dilution Data. Result was obtained from the analysis of a dilution. The number that follows the "D" indicates the dilution factor. • DE — Indicates a dilution performed with the addition of ES (Extraction Standard) solution. • DUP —Designation for a duplicate sample. • MS — Designation for a matrix spike. • MSD — Designation for a matrix spike duplicate. • RJ — Indicates a reinjection of the sample extract. • S — Indicates a sample split. The number that follows the "S" indicates the split factor. • R — Indicates a re -extraction of the sample. EU t 16_v4 (General Reporting Notes -Data Qualifiers) Enthalpy Analytical, LLC Wilmington, NC EU#0421-749 Page 14 of 18 Attachment B Analyte Name Acronym Fluorinated Molecular CAS Carbon Formula Number Chain Length Perfluorotetradecanoic acid PFTeA CGI CaFz7COOH 376-06-7 Perfluorotridecanoic acid PFTriA C12 CeFssCOOH 72629-94-8 Perfluorododecanoic acid PFDoA C12 C„FnCOOH 307-55-1 Peifluoroundecanoic acid PFUnA C11 CmF2,000H 2O58-94-8 Pelfluorodecanoic acid PFDA C,o C9Fi9C0OH 335-76-2 Perfluorononanoic acid PFNA C, CsFi7COOH 375-95-1 Perfluorooctanoic acid PFOA C. C7Fi5COOH 335-67-1 Perfluoroheptanoic acid PFHpA C7 C6F13COOH 375-85-9 Perfluorohexanoic acid PFHxA C, CsFiiCOOH 307-24-4 Perfluoropentanoic acid PFPeA C, C41'9COOH 2706-90-3 Perfluorobutanoic acid PFBA C, C3F7000H 375-22-4 Perfluorodecanesulfonic acid PFDS Cu• CioF2iS031-1 335-77-3 Perfluorononanesuifonic acid PFNS C.7 CgFJ9S03H 68259-12-1 Perfluorcoetanesulfonic acid PFOS C„ C8Fi7SO3H 1763-23-1 Perfluoroheptanesulfonic acid PFHpS C7 C7FI5503H 375-92-8 Perfluorohexanesulfonic acid PFHxS C� C61`13SOM 35546-4 Perfluoropentanesulfonic acid PFPeS C, C;FIIS03H 2706-91-4 Perfluorobutanesulfonic acid PFBS Cnovc C4F9S03H 375-73-5 Perfluorooctanesuffonamide PFOSA C„ C8F17SO2NH2 754-91-6 2-(N-Ethylperfluorooctanesulfonamido) N-EtFOSAA C„ CsF»SO2N(C2Hs) 2991-50-6 acetic acid CH2COOH 2-(N-Methylperfluorooctanesulfonamido) N-McFOSAA Ck C8F17SO2N(CH3) 2355-31-9 acetic acid CHCOOH EU#0421-749 Page 15 of 18 {�� W t ^d H-i A L P EU#0421-749 Page 16 of 18 teport it 2021-05591 ft Date 21-13824 4/7/2021 Environmental Chemist 66002 Windmill Way, Wilmington, NC 2840$ ( �� Phone: 910-392-0223 Fax: 910-3924434 e_- info a environmentalchemists,com REQUEST FOR SUBCONTRACTED SERVICES Time Matrix Analysis Requested Preservation Comments 9:00 Water ,90B A) Coal, 4C b T L° / +. / C®!, /-<-�' Xe L r G/ 6 L / % (f--y�%l%(� CL7w'%Gr�v✓ /'✓41 Prepared by: Relinquished By: Received By; Wednesday, April 14, 2021 For Shipment By: f���(UI �t Date/Time: W Dale/Time: 7911y'/Z Ell#0421-749 Page 17 of 18 Page I or i This Is The Last Page EU#0421-749 Page 18 of 18 -"6Il1't�w�t Analytical B Consulting Chemists T: Guilford East °SS: 1754 NC Highway 903 sville, NC 28349 Sample Identification Date I Time 1, 2. Temperature Delivered By:, VI R N M IY AL CHEMISTS, I N C 26602 Windmill Way ENlmington, NC 8405 OFFICE: 910 392110223 FAX 910- NCDENR: DWO CERTIFICATION #94 NCDHHS: DLS CERTIFICATION #37729 392-4424 COLLECTION AND CHAIN OF CUSTODY PROJECT NAME: Weekly WW (Wednesday) REPORT NO: a I _ S9 1 CONTACT NAME: Marty Fritz PO NO: REPORT TO: PHONE/ PROJECT: Week E-MAIL: SAMPLE TYPE: I = Influent,.E = Effluent, W = Well, ST = Stream, SO = Soil, SL = on a OM° ° _ U z PRESERVATION Temp z Oo 0 s O s O z O [1, % G P X E G 7'e- 1 P tf moo. �or■�■■■�� )42 Other: ANALYSIS REQUESTED ], TSS' ], NH3 ` I7 ON d X Fecal 7Z X Sulfide TN. TP. 11-21