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Home My WebLink AboutWQ0012404_Annual Report_20240228Initial Review Reviewer nathaniel.thorn burg Is this submittal an application? (Excluding additional information.) * Yes No If not an application what is the submittal type?* Annual Report Residual Annual Report Additional Information Other Annual Report Year* 2023 Permit Number (IR) * WQ0012404 Applicant/Permittee CF Nitrogen, Inc. Email Notifications Does this need review by the hydrogeologist? * Yes No Regional Office CO Reviewer Admin Reviewer Submittal Form Project Contact Information Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence. Name* Amy Brooks Email Address* Amy. Brooks@geosyntec.com Project Information ......................... Application/Document Type* New (Fee Required) Modification - Major (Fee Required) Renewal with Major Modification (Fee Required) Annual Report Additional Information Other Phone Number* 704-227-0843 Modification - Minor Renewal GW-59, NDMR, NDMLR, NDAR-1, N DAR-2 Residual Annual Report Change of Ownership We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type:* Wastewater Irrigation High -Rate Infiltration Other Wastewater Reclaimed Water Closed -Loop Recycle Residuals Single -Family Residence Wastewater Other Irrigation Groundwater Remediation Permit Number:* WO0012404 Has Current Existing permit number Applicant/Permittee Address* 2375 Waterview Drive, Northbrook, IL 60062 Facility Name* CF Nitrogen Site Please provide comments/notes on your current submittal below. 2023 Annual Report for Non -Discharge Injection Permit for land application of nitrogen -enriched groundwater. Report includes annual groundwater monitoring data. At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here. (Application Form, Engineering Plans, Specifications, Calculations, Etc.) CAR230002 2023 Annual Report.pdf 7.6MB Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger than upload limit. * By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Mail payment to: NCDEQ — Division of Water Resources Attn: Non -Discharge Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Signature 6;0 yaO Submission Date 2/28/2024 Prepared for: CF Industries, Inc. 2375 Waterview Drive Northbrook, IL 60062 2023 LAND APPLICATION PROGRAM ANNUAL REPORT NON -DISCHARGE INJECTION PERMIT WQ0012404 CF NITROGEN SITE HERTFORD COUNTY, NORTH CAROLINA Prepared by: GeosyntecO' consultants Geosyntec Consultants of NC, P.C. Geosyntec Consultants of NC, P.C. 1300 S Mint Street, Suite 300 Charlotte, North Carolina 28203 Project Number: GN7566 February 2024 2023 Annual Report —Permit No. WQ0012404 CF Nitrogen Site Land Application Program TABLE OF CONTENTS 1.0 INTRODUCTION................................................................................................... I 2.0 LAND APPLICATION SUMMARY.................................................................... 2 3.0 ANNUAL GROUNDWATER MONITORING ................................................... 4 4.0 REFERENCES........................................................................................................5 List of Figures Figure 1 Site Location Map Figure 2 Site Layout Figure 3A Potentiometric Surface Map (18 January 2023) Figure 313 Potentiometric Surface Map (27 April 2023) Figure 3C Potentiometric Surface Map (26 July 2023) Figure 3D Potentiometric Surface Map (26 October 2023) Figure 4A Elevation Cross Sections (January 2023) Figure 413 Elevation Cross Sections (April 2023) Figure 4C Elevation Cross Sections (July 2023) Figure 4D Elevation Cross Sections (October 2023) Figure 5 Monthly Rainfall It cf nr Tnhlac Table 1 Groundwater Elevation Data Table 2 Monthly Rainfall 2023 Table 3 Annual Residuals Sampling Summary Form List of Appendices Appendix A Annual Land Application Certification Form Appendix B 2023 Application Summary and Field Loading Rate Reports Appendix C Field Application Summaries Appendix D Approved Land Application Sites Appendix E Residuals Sampling Analytical Reports CAR24002 i February 2023 2023 Annual Report —Permit No. WQ0012404 CF Nitrogen Site Land Application Program 1.0 INTRODUCTION This 2023 Land Application Program Annual Report has been prepared by Geosyntec Consultants of NC, P.C. (Geosyntec) on behalf of CF Industries (CFI) for the Former CF Nitrogen Ahoskie Site (Site) located at 100 Farmers Chemical Road, Hertford County, North Carolina. The Site includes 157 acres of a 1,105-acre property and is located along the south bank of the Chowan River, as shown in Figure 1. The Site operated as a fertilizer manufacturing plant from 1969 through 1982 and groundwater impacts in the form of nitrogen compounds have been documented. In 1976, a slurry wall was constructed along the perimeter of the Site facility as shown on Figure 2. In 1998, CFI began a program of groundwater extraction into a holding lagoon followed by trucking of extracted water to area farms for land application in accordance with Non - Discharge Injection Permit (Permit No. WQ0012404) from the North Carolina Department of Environmental Quality (NCDEQ), Division of Water Resources (DWR). This report has been prepared to document land application activities conducted in Hertford and Northampton counties during the 2023 compliance year under the Non -Discharge Injection Permit. The Annual Land Application Certification Form is included in Appendix A. As specified in Attachment A of Permit No. WQ0012404, analyses to demonstrate that residuals are non -hazardous are only required once per permit cycle and pathogen and vector monitoring is not applicable. Therefore, Toxicity Characteristic Leaching Procedure (TCLP), pathogen and vector monitoring, and soil analysis are not addressed in this annual report. CAR240002 1 February 2024 2023 Annual Report —Permit No. WQ0012404 CF Nitrogen Site Land Application Program 2.0 LAND APPLICATION SUMMARY This section summarizes land application activities of recovered nitrogen -enriched groundwater. Quarterly flow during 2023 was calculated based on Transfer Pump Station 91 flow meter readings. The extraction system recovered approximately 9,935,800 gallons of groundwater into the holding lagoon during calendar year 2023, as summarized in the table below: 1st Quarter (January — March 2023) 1,927,800 gallons 2nd Quarter (April — June 2023) 2,149,800 gallons 3rd Quarter (July — September 2023) 2,807,500 gallons 4th Quarter (October — December 2023) 3,050,700 gallons Total Groundwater Recovery for 2023 9,935,800 gallons A second flow meter in Transfer Pump Station #2 recorded that approximately 9,409,000 gallons of extracted groundwater were pumped from the holding lagoon into trucks for land application. Nitrogen -enriched groundwater was applied to 17 soybean, wheat, and corn planted fields at 4 sites, as summarized in Appendix B which includes an overall land application summary and field loading rate reports. Land application of nitrogen -enriched groundwater occurred on 168 days in 2023. Daily application summaries are provided in Appendix C. The quarterly land application volumes are summarized in the table below: 1st Quarter (January —March 2022) 1,971,000 gallons 2nd Quarter (April — June 2022) 1,966,000 gallons 3rd Quarter (July — September 2022) 2,689,000 gallons 4th Quarter (October — December 2022) 2,783,000 gallons Total Groundwater Recovery for 2022 9,409,000 gallons Maximum agronomic rates were calculated based on analytical data from the holding lagoon, field crop type, and field soil series. As shown in the field loading rate reports in Appendix B, these maximum agronomic rates were not exceeded during application of the nitrogen - enriched groundwater in 2023. The list of land application sites approved under this permit is included in Appendix D. No new sites were added to the list in 2023. Contact information for WQ0012404 permit holder (CFI) and the Operator in Responsible Charge (Granville Farms) is included below: CAR240002 2 February 2024 2023 Annual Report —Permit No. WQ0012404 CF Nitrogen Site Land Application Program CF Nitrogen, Inc. Mr. Kelvin Roth 2375 Waterview Drive Northbrook, IL 60062 847-405-2738 Granville Farms, Inc. Mr. Jay Bryant 8229 Highway 96 North/P.O. Box 1396 Oxford, North Carolina 27565 252-358-2129 (direct) 919-690-8000 (office) CAR240002 3 February 2024 2023 Annual Report —Permit No. WQ0012404 CF Nitrogen Site Land Application Program 3.0 ANNUAL GROUNDWATER MONITORING Depth to groundwater is measured quarterly in 44 wells and piezometers across the Site. Groundwater elevations from these quarterly monitoring events are summarized in Table 1 and potentiometric maps of interpreted groundwater elevation contours inside and outside of the slurry wall are included as Figures 3A, 313, 3C, and 3D for January, April, July, and October 2023, respectively. Cross -sectional depictions of quarterly groundwater elevations are shown across two transects of the Site in Figures 4A, 413, 4C, and 4D. Historical water level trends dating back to the onset of groundwater recovery in 1998 are included in prior annual reports (S&ME, 2022). The cross -sections depict current groundwater elevation conditions in comparison to the slurry wall and show that groundwater elevations within the wall remain below the slurry wall with the exception of some internal pockets, demonstrating that the slurry wall and extraction program are effectively containing the nitrogen -enriched groundwater. A rainfall gauge is located at the Site and checked on a weekly basis. The total annual recorded rainfall at the Site in 2023 was 50.86 inches, compared with the annual average of 46 inches for the area. Monthly recorded precipitation totals are compared to average rainfall totals for the area (from www.usa.com as reported by S&ME [S&ME, 2022]) and presented in Table 2 and the past four years of Site data are shown in Figure 5. In 2023, monthly precipitation was varied, with above average precipitation in June, July, August, and December and below average precipitation in February, March, September, and October. Groundwater pumping for land application efforts for 2023, on average, maintained the groundwater elevation within the slurry wall below 30 feet above mean sea level (ft-amsl). There were transitory exceptions early in the year followed by improved groundwater elevations. Samples of the nitrogen -enriched groundwater were collected in January, April, July, and October 2023. Samples were analyzed for nitrogen as ammonia, nitrate and nitrite, and total Kjeldahl nitrogen (TKN), aluminum, calcium, phosphorus, magnesium, potassium, sodium and pH. A summary of laboratory results is provided in Table 3. The analytical laboratory data reports are provided in Appendix E. CAR240002 4 February 2024 2023 Annual Report —Permit No. WQ0012404 CF Nitrogen Site Land Application Program 4.0 REFERENCES S&ME. 2022. 2021 Annual Report Land Application Program, CF Nitrogen, Inc., Permit No. WQ0012404. CAR240002 5 February 2024 TABLES Table 1 Groundwater Elevations CF Nitrogen - Ahoskie Facility Hertford County, North Carolina Well ID Top of Casing Elevation (ft MSL) 1/18/2023 Depth to Groundwater Water Elevation ft BTOC ft MSL 4/27/2023 Depth to Groundwater Water Elevation ft BTOC ft MSL 7/26/2023 Depth to Groundwater Water Elevation ft BTOC ft MSL 10/26/2023 Depth to Groundwater Water Elevation ft BTOC ft MSL C-22 39.65 25.08 14.57 25.42 14.23 25.58 14.07 25.62 14.03 C-23* 41.08 10.90 30.18 11.48 29.60 11.98 29.10 13.30 27.78 C-28* 39.01 29.68 9.33 29.32 9.69 29.90 9.11 30.70 8.31 C-29 43.14 15.90 27.24 10.98 32.16 16.78 26.36 18.10 25.04 C-32 36.85 26.54 10.31 26.38 10.47 27.08 9.77 27.30 9.55 C-33 39.40 11.92 27.48 11.54 27.86 12.80 26.60 13.54 25.86 C-4 42.88 13.40 29.48 13.46 29.42 14.02 28.86 15.28 27.60 MWI-1 45.09 14.80 30.29 14.80 30.29 15.54 29.55 16.36 28.73 MWI-2 1 44.64 14.88 29.76 14.48 30.16 15.30 29.34 16.18 28.46 MWI-3 44.93 15.36 29.57 14.98 29.95 15.58 29.35 16.52 28.41 MWI-4 42.03 10.98 31.05 15.18 26.85 11.70 30.33 12.82 29.21 MWO-5 41.32 17.52 23.80 17.60 23.72 18.28 23.04 18.38 22.94 MWI-6* 46.31 16.66 29.65 16.30 30.01 17.12 29.19 17.80 28.51 MWI-7 44.24 18.00 26.24 15.80 28.44 16.98 27.26 17.72 26.52 MWO-8 42.93 17.42 25.51 16.92 26.01 17.88 25.05 18.28 24.65 PI-1 42.41 12.68 29.73 12.82 29.59 13.52 28.89 15.02 27.39 PI-2 42.60 13.02 29.58 13.12 29.48 14.28 28.32 15.18 27.42 PO-3 42.05 23.64 18.41 23.90 18.15 23.80 18.25 23.80 18.25 PI-4 42.43 12.84 29.59 12.48 29.95 13.30 29.13 14.40 28.03 PI-5 43.05 13.58 29.47 13.36 29.69 14.50 28.55 15.52 27.53 PO-6 43.38 20.92 22.46 13.64 29.74 20.70 22.68 21.58 21.80 PI-7 43.60 13.68 29.92 22.40 21.20 14.42 29.18 15.08 28.52 PI-8 43.16 15.20 27.96 17.92 25.24 16.02 27.14 17.00 26.16 PI-9 43.19 13.98 29.21 12.98 30.21 13.80 29.39 14.52 28.67 PI-10 44.52 14.38 30.14 14.22 30.30 15.18 29.34 15.84 28.68 PI-11 42.57 14.48 28.09 14.10 28.47 15.50 27.07 16.40 26.17 PO-12 39.20 22.90 16.30 22.12 17.08 22.58 16.62 23.22 15.98 PI-13R* 43.25 13.92 29.33 13.00 30.25 14.12 29.13 14.90 28.35 PI-14 43.86 14.70 29.16 14.80 29.06 16.22 27.64 16.90 26.96 PO-15 42.28 19.04 23.24 18.90 23.38 18.90 23.38 19.42 22.86 PO-16 42.41 16.50 25.91 15.30 27.11 16.58 25.83 17.10 25.31 PI-17 42.90 12.78 30.12 13.30 29.60 14.88 28.02 15.50 27.40 PI-18 42.57 13.14 29.43 13.12 29.45 13.90 28.67 14.98 27.59 PI-19 41.31 12.66 28.65 12.92 28.39 13.50 27.81 14.78 26.53 PI-20 42.48 12.88 29.60 12.98 29.50 13.74 28.74 14.90 27.58 PI-21 42.33 12.68 29.65 12.88 29.45 13.50 28.83 14.92 27.41 PI-22 43.13 12.88 30.25 12.78 30.35 13.56 29.57 14.42 28.71 PI-23 42.96 12.58 30.38 12.46 30.50 13.60 29.36 14.80 28.16 PI-24 43.97 14.60 29.37 14.08 29.89 15.36 28.61 16.04 27.93 PO-25 38.85 15.12 23.73 14.72 24.13 15.30 23.55 15.60 23.25 PO-26 42.31 16.68 25.63 15.52 26.79 16.50 25.81 16.98 25.33 PO-235 44.35 29.30 15.05 29.48 14.87 29.88 14.47 29.80 14.55 PO-236 43.62 29.82 13.80 29.78 13.84 30.50 13.12 31.04 12.58 PO-237 44.63 18.30 26.33 17.62 27.01 18.42 26.21 19.12 25.51 Notes: * indicates well has been replaced or repaired ft MSL - feet mean sea level ft BTOC - feet below top of casing CAR240002 Page 1 of 1 February 2024 Table 2 Monthly Rainfall 2023 CF Nitrogen - Ahoskie Facility Hertford County, North Carolina Month 2023 Site Recorded Rainfall (inches) Average Rainfall for Cofield (inches) January 3.82 3.6 February 2.12 3.1 March 1.92 4.1 April 2.74 3.5 May 4.00 3.8 June 7.10 4.1 July 8.81 4.8 August 7.24 4.8 September 3.10 4.6 October 1.10 3.2 November 2.48 3.1 December 6.43 3.3 Annual Total 50.86 46.0 Monthly Average 4.24 3.83 Notes: Site rainfall from on -Site rain gauge Average rainfall for Cofield, NC from www.usa.com as reported by S&ME CAR240002 Page 1 of 1 February 2024 ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ Permit Number: WQ0012404 Laboratory: 1) Facility Name: CF Nitrogen, Inc. 2) Residual Source NSA 3) NPDES # or WQ#: 4) WWTP Name: Nitrogen -Enriched Groundwater Recovery Systerr 5) Residual Analysis Data Waypoint Analytical Parameter (mg/kg) Sam le or Com osite Date 1/11/23 4/12/23 7/28/23 10/25/23 TKN 194 215 215 225 Ammonia -Nitrogen 1.68 160 28.8 140 Nitrate -Nitrite 186 223 173 85.8 Calcium 50.8 60.1 59.9 64.9 Sodium 26.7 31.5 30.6 29.9 Aluminum 0.522 0.742 0.894 0.667 Total Phosphorus 2.64 2.18 2.13 2.35 Potassium 31.8 28.8 28.2 31.2 Magnesium 14.1 17.8 16.4 16.2 pH 6.4 5.7 7.1 6.5 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Preparer * 2/27/24 Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM RSSF - B (12/2006) FIGURES E E E � I n 4 •� 4 f _ Jet \ 4 YO R/Ile • -� -- •- - -- - - l` 'Tunis .r" � �� - - ^- y �4 4 _� � � �- - .►- \ G,g� -- -- jJtne! Waste— /� • - T 4 401 Tunis •f8C0 l__- y ?,'ir Pam/ P I - - 5ubsta 5 ti rI ` -- 403' as _ SEABOARD � p Legend Property Boundary Approximate Site Boundary Notes: 1. Property Boundary obtained from Hertford County GIS Department. 2. Site boundary locations are approximate and were obtained from figures prepared by SWE in April 1996 and in August 2011. 3. Basemap obtained from: Copyright:© 2013 National Geographic Society, i-cubed %._z" 17una 0 1,000 2,000 4,000 Feet Site Location Map FormerCF Industries Ahoskie Site 100 Farmers Chemical Road Hertford County, North Carolina " Geosynte& Figure y , eonsuitants ,� Raleigh, North Carolina March 2023 \\charlotte-01\data\GIS\Projects\C\CF Industries\MXDs\CAR240003 - 2023 Annual Report\2023_ Contour _Maps\2023_Contour _Maps.aprx\Q1 2/23/2024 4:06 PM (EHoward) \\charlotte-01\data\GIS\Projects\C\CF Industries\MXDs\CAR240003 - 2023 Annual Report\2023_ Contour _Maps\2023_Contour _Maps.aprx\Q2 2/23/2024 4:06 PM (EHoward) \\charlotte-01\data\GIS\Projects\C\CF Industries\MXDs\CAR240003 - 2023 Annual Report\2023_ Contour _Maps\2023_Contour _Maps.aprx\Q3 2/23/2024 4:06 PM (EHoward) \\charlotte-01\data\GIS\Projects\C\CF Industries\MXDs\CAR240003 - 2023 Annual Report\2023_ Contour _Maps\2023_Contour _Maps.aprx\Q4 2/23/2024 4:06 PM (EHoward) Elevation Cross Section A - A' 50 45 40 35 v 30 v 25 0 v 20 MWI-9 MWI-7 w 15 �Pl-131R 10 MW O-8 C-33 s C-32 0 0 400 800 1,200 1,600 2,000 2,400 2,800 Distance (Feet) 50 45 40 35 N v 30 v 25 0 20 v w 15 10 5 0 0 Legend Land Surface Elevation Groundwater Elevation Slurry Wall I Monitoring Well 400 800 1,200 Elevation Cross Section B-B' 1,600 Distance (Feet) 2,000 2,400 2,800 '0-236 3,200 Notes: Elevation Cross Sections 1. Land Surface Elevation from NCOneMap 20 foot resolution Light Detection and January 2023 Ranging (LiDAR) digital elevation model. Former CF Industries Ahoskie Site 100 Farmers Chemical Road 2. Groundwater Elevations from January 2023 monitoring well measurement event. Hertford County, North Carolina 3 Well, piezometer, and slurry wall boundary locations and elevations are approximate and were obtained from reports prepared by S&ME in April 1996 and in ❑ FigUre August 2011. Geosyntec :L'U,yuurt.ursWLa;1;,�J � 11... _ 4. Vertical exaggeration approximately 10x. �etlyt{It..;lets MClinnscNu: G-3500an1C-:�`: 4a Raleigh, NC February 2024 \\charlotte-01\data\GIS\Projects\C\CF Industries\MXDs\CAR240003 - 2023 Annual Report\Figure 4a - Q1 Cross Sections.mxd 2/27/2024 2:02:24 PM EHoward Elevation Cross Section A - A' 50 45 40 35 v 30 v 25 0 v 20 MWI-9 MWI-7 w 15 �Pl-131R 10 MWO-8 C-33 s C-32 0 0 400 800 1,200 1,600 2,000 2,400 2,800 Distance (Feet) 50 45 40 35 N v 30 v 25 0 20 v w 15 10 5 0 0 Legend Land Surface Elevation Groundwater Elevation Slurry Wall I Monitoring Well 400 800 1,200 Elevation Cross Section B-B' 1,600 Distance (Feet) 2,000 2,400 2,800 '0-236 3,200 Notes: Elevation Cross Sections 1. Land Surface Elevation from NCOneMap 20 foot resolution Light Detection and April 2023 Ranging (LiDAR) digital elevation model. Former CF Industries Ahoskie Site 100 Farmers Chemical Road 2. Groundwater Elevations from April 2023 monitoring well measurement event. Hertford County, North Carolina 3 Well, piezometer, and slurry wall boundary locations and elevations are approximate and were obtained from reports prepared by S&ME in April 1996 and in ❑ FigUre August 2011. Geosyntec :L'U,yuurt.ursWLa;1;,�J � 11... _ 4. Vertical exaggeration approximately 10x. �etlyt{It..;lets MClinnscNu: G-3500an1C-:�`: 4b Raleigh, NC February 2024 \\charlotte-01\data\GIS\Projects\C\CF Industries\MXDs\CAR240003 - 2023 Annual Report\Figure 4b - Q2 Cross Sections.mxd 2/27/2024 2:03:28 PM EHoward 50 45 40 35 v 30 v 25 0 20 v w 15 PI-13R 10 MWO-f 5 0 0 50 45 40 35 N v 30 v 25 0 20 v w 15 10 5 0 0 Legend Land Surface Elevation Groundwater Elevation Slurry Wall I Monitoring Well Elevation Cross Section A - A' MWI-9 400 800 1,200 1,600 Distance (Feet) 400 800 1,200 Elevation Cross Section B-B' 1,600 Distance (Feet) 4WI-7 2,000 2,000 C-33 2,400 2,400 C-32 2,800 2,800 '0-236 3,200 Notes: Elevation Cross Sections 1. Land Surface Elevation from NCOneMap 20 foot resolution Light Detection and July 2023 Ranging (LiDAR) digital elevation model. Former CF Industries Ahoskie Site 100 Farmers Chemical Road 2. Groundwater Elevations from July 2023 monitoring well measurement event. Hertford County, North Carolina 3 Well, piezometer, and slurry wall boundary locations and elevations are approximate and were obtained from reports prepared by S&ME in April 1996 and in ❑ FigUre August 2011. Geosyntec :L'U,yuurt.ursWLa;1;,�J � 11... _ 4. Vertical exaggeration approximately 10x. �etlyt{It..;lets MClinnscNu: G-3500an1C-:�`: 4c Raleigh, NC February 2024 \\charlotte-01\data\GIS\Projects\C\CF Industries\MXDs\CAR240003 - 2023 Annual Report\Figure 4c - Q3 Cross Sections.mxd 2/27/2024 2:03:56 PM EHoward 50 45 40 35 v 30 LL 25 20 w 15 PI-13R 10 5 MWO-E 0 0 50 45 40 00,0 35 N v 30 v 25 0 zo PI-11 v w 15 10 s APO-12 0 0 Legend Land Surface Elevation Groundwater Elevation Slurry Wall I Monitoring Well Elevation Cross Section A - A' MWI-9 MWI-7 C-33 C-32 400 800 1,200 1,600 2,000 2,400 2,800 Distance (Feet) 400 800 MWI-4 1,200 Elevation Cross Section B-B' 1,600 Distance (Feet) PI-5 I PI-8 2,000 2,400 2,800 PI-2 PO-236 3,200 Notes: Elevation Cross Sections 1. Land Surface Elevation from NCOneMap 20 foot resolution Light Detection and October 2023 Ranging (LiDAR) digital elevation model. Former CF Industries Ahoskie Site 100 Farmers Chemical Road 2. Groundwater Elevations from October 2023 monitoring well measurement event. Hertford County, North Carolina 3 Well, piezometer, and slurry wall boundary locations and elevations are approximate and were obtained from reports prepared by S&ME in April 1996 and in 17 (y August 2011. Geosyn.tec VQS;'I k1k 1.i)l:Sl I Figure Ifll.�1» 11.. .(_ g N C LLvj se Nu: G-3500 a nd C ,�r_ 4. Vertical exaggeration approximately 10x. its 4d Raleigh, NC February 2024 \\charlotte-01\data\GIS\Projects\C\CF Industries\MXDs\CAR240003 - 2023 Annual Report\Figure 4d - Q4 Cross Sections.mxd 2/27/2024 2:04:08 PM EHoward 10 9 7 N 6 V C_ r6 C M cc 4 3 2 D Jan Feb Mar Apr May lun Jul Aug Sep Oct Nov Dec ■ 2020 Rainfall a 2021 Rainfall ■ 2022 Rainfall ■ 2023 Rainfall Average Monthly Rain for Cofield, NC P Notes: Monthly Rainfall 1. 2020, 2021, 2022, and 2023 rainfall from Site gauge. Former CF Industries site 2. Average monthly rainfall from usa.com for Cofield, NC as reported by S&ME. 10o Farmers chemical cal Road d Hertford County, North Carolina aGeosyntec° _ e�.�r.....r�,..r_ :.l..� —. xeo�nr. ae Figure ❑un ulnn[s 5 Raleigh, NC February 2024 APPENDICES APPENDIX A Annual Land Application Certification Form DocuSign Envelope ID: 11 AC1 B94-C666-4646-95D6-8EEBE379CFB5 _ ✓ATION CERTIFICATION FORM WQ Permit#: WQ0012404 County: Facility Name (as shown on permit): Land Application Operator: Hertford Granville Farms; Inc. Year: 2023 CF Nitrogen, Inc. Phone: 919-690-8000 Land application of residuals as allowed by the permit occurred during the past calendar year? 0 Yes ❑ No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A - Residuals Application Summary: Total number of application fields in the IL rmit: 402 Total number of fields utilized for land application during the year: 17 Total amount of dry tons applied during the year for all application sites: N/A Groundwater Recovery System Total number of acres utilizes for land application during the year: 356.2 Part B - Annual Compiance Statement: Facility was compliant during calendar year 2023 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Resources. r❑ Yes ❑ No If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1) Only residuals approved for this permit were applied to the permitted sites. 2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached_ 6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading Rates in 15A NCAC 02T .1105(b) (applicable to 40 CFR Part 503 regulated facilities). 7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8) All monitoring and reporting requirements in 15A NCAC 02T . I I I 1 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Resources. 10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as specified in the permit. 12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13) All buffer requirements as specified on the permit were maintained during each application of residuals. Part C - Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." DocuSigned by: Kelvin E Roth VP, EHSQ Az--�C- �-q 2/28/2024 RA o�� f3f3RQ.�.y. Pennittee Name and Title (type or print) Signature of Permittee Date 2/27/24 MEN 21z?p -( Signature of Pr arer* Date Eric Howard, Geosyntec Consultants of NC, P.C. of Land Applier Jay Bryant, Granville Farms, Inc. Date APPENDIX B 2023 Application Summary and Field Loading Rate Reports CF Nitrogen, Inc. - Cofield, North Carolina Field Loading Rate Report - Nitrogen Enriches! Groundwater Pennit # WQUO12404 OWNER: Stephen Burgess OPERATOR: RESIDUAL SOURCE: Permitted Acre s:93.5 Nitrogen Enriched Groundwater Croln Wheat Predominwit Soil: Bonneau - BoB FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PERACRE Acty iulac Nulrien(% (11r,41c) PAN P K 42 Q1-23 93 5 617.000 6.599 0.24 14.40 0 15 1 78 Site No 27 Q4-23 935 561.000 6.000 0.22 9.08 0 12 1.56 Annual Totals 1.179.000 12,i19 041, 13,17 027 .3 34 102 RYELimit (ll}s.lacm/ year) 7/Z (Sjgn. , of Land :lppher) I3aic "I certlfv. under penally of late: that this doeumenI nRs prepared un dur my direct inn or mperviston lit accordance voIIt a systam desi�ixied to assure that qualified personnel properly gathered and evaluated the information sulmitted. I am a�,%are tlial there arc sign&aall I pan altle_c for submitting false information, including the possibility of fines and imprisonment for knoningviolaltons CF Nitrogen, Inc. - CorieId, North Carolina Field Loading Rate Report - Nitrogen Enriched Groundwater Permit # WQ0012404 OWNER: Stephen Burgess OPERATOR: RESTD UAL SOURCE: Permitted Acres:17.7 Nitrogen Enriched Groundwater Croy Wheat Predominant Soil: Norfolk - NoB FIELD DATE ACRES L} UZED TOTAL GALLONS GALLONS PER ACRE Acre Woe Nutrients (lbs1ac) PAN P K 43 Q1-23 17.7 593,000 33.503 I.23 68.36 0.74 8.89 Site No 27 Q4-23 177 406.t 0 22.938 084 3.1.71 045 5.97 Annual Totals 999.000 56,441 2,08 103 Oti 1.19 14.86 123 RYE Limit ( bs.lacrelvcar) r �] Z Z 7'2 (Sign of Land Appherj Date "I certifj,. under penalty of law, that this doctnnent was prepared under my direction Of supervissan In aeeordance with a system d;stgned to assure that qualiticd personnel properly gatlteredand evaluated the information submitted. I am aware that there are simiI ficanI penalties for st6mittntg False information, including the passibility of fines and imprisonment for knowingviolation s" CF Nitrogen, Inc. - Cofield, North Carolina Field Loading Rate Report - Nitrogen Enriched Groundwater Permit # WQ00 [ 2404 OWNER: Stephen Burgess OPERATOR: RESIDUAL SOURCE: Permitted Acres.29.2 Nitrogen Enriched Groundwater Croix Wheat Predominant Soil: Bon neau - Bo FIELD DATE ACRES UFI11ZM TOTAL GALLONS GALLONS PERACRE Acre inlac Nutrients Ubslac) PAN P K 44 Q1-23 292 431MO 14.760 054 30.12 0.33 392 Site No 27 Q4-2 3 292 676.000 23 J51 0.85 45.55 0.42 5.52 Annual `Totals L107MO 37.911 1.40 1 75.66 1 0.74 L 9A4 102 RYE• U nit {lbs.lacrelyear} Z Ai Z`� {4go`a of Land Applier] Date "I eertiN. under Pen a]ty of inn: that this docianont nns prepared on der my direction or supervision in accordance nrth a system desigr:ed to assure tliat gnelified personna] properly gatherod and evaluated She information sulxnitted. I am avvara that there are significant penalties for submitting false information. including the possibility of fines and imprisonment for kno"ing violations." CF Nitrogen. Inc. - Cofield, North Carolina Field Loading Rate Report - Nitrogen Enriched Groundwater Permit M WQ0012404 OWNER: Stephen Burgess OPERATOR: RESIDUAL SOURCE: Permitted Acres: 17.5 Nitrogen Enriched Groundwater Crop: Wheat Predomin;unt Sail: Norfolk - NoB FIELD DATE ACRES U1'111 TOTAL GALLONS GALLONS PER ACRE Acre infac Nutrients (1hdu) PAN P K 15 Q1-23 17.3 3X000 18.857 069 38.48 0.42 300 5itc Na. 27 Q4-23 I7.5 415M0 23.714 087 35M 0_47 6.17 Annual rotalS 745-000 157 7416 088 11 18 123 RYE Limit (lhs.lacrcl► car) T—N�s kz�� z jzy [SSgiature of Land Appl[erl Date "1 ccrtifv. under pen at(v or la%v, that this docLim enI -,,kas prepared under my direction or supervision in ascendance wtli a system designed I assure that qualified personnel properly gat hared and eva]uated the in form atinn submitted. I am av�mre that Ihere are siegiidicant penalties ror submittizig false infonnatian, inclWin gthe possibility of fines and imprisonment for knoufngviolations." CF Nitrogen, Inc. - Cofeld, North Carolina Field Loading Rate Report - Nitrogen Enriched Groundwater Permit # WQ0012404 OWNER: Stephen Burgess OPERATOR: RESIDUAL SOURCE: Permitted Acres: 13.9 Nitrogen Enriched Groundwater Crop Wheat Predominant Sail: Bonneau - BoB FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre inluc Nutrients (Ihstac) PAN P K 46 Q2-23 13.9 178.000 12.806 0.47 34.14 0.23 308 Sits No. Q4-23 13.9 280.000 20.144 074 30.49 0.40 5.24 27 Annual Totals 458-000 32.95n 1.21 6462 0.63 832 102 RYEUrnit (1Us.lacrelycat) 2 Z- 7 ,' c, :-4 m-&t-urt2bf Land Applicr) Date "I certiN- under penalty of law that this document nas prepared under my direction or supervision in accordance wth a system designed to assure that gtwlificd personncl properly gathered and evaluated the information submitted. 1 am aware that there are significant penalties for submitting false information. including ilia possibility of fines and imprisonment for knowng violations." CF Nitrogen, Inc. - CoCeld, North Carolina Field Loading Rate Report - Nitrogen Enriched Groundwater Permit # WQ00I2404 OWNER: Stephen But-gess OPERATOR.: RESIDUAL SOURCE: Pe rmitted Acres: 20.8 Nitrogen Enriched GroundMuter Croix Whcat Predominant Soil: Bonneau - BoB FULD DATE ACRES UrILi.ZED TOTAL GALLONS GALLONS PER ACRE Acre inlac Nutrients (ibslnc) PAN P K 47 Q2-23 20.8 433.000 20,817 077 50.96 0.41 5.19 Site No 27 Q4-23 20.8 445,000 21.394 0.79 32.37 0.42 5.57 Annual Totals 879 000 42.212 1.55 83.33 0.83 10.76 102 RYE HMit (lbs.lacrely ear) e of Land Appher] Date "I certify. under penalty of lan: that this document .%us prepared under my direction or supervision in accordance nilh a system desigted to assure. that qua IiLcd personnel pro parly gathered andevatusted the information subrnitted, i am snare that there are signs icant penalties for submitting ralw information, including the possibility of fines and imprisonment for knovuneviolation S." CF Nitrogen, Inc. - Cofteld, North Carolina Field Loading Date Report - Nitrogen Enriched Groundwater Permit # WQ0012404 OWNER: Judith, Allison, and Walter Perry OPERATOR: RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 17.6 Crnlr. Corn Predominant Soil: Norfolk - NoA FTEID DATE ACRES UTILIZED TOTAL, GALLONS GALLANS PER ACRE Acre in/ac Nutrients (16slac) PAN F P K 1 Q3-23 176 292,000 1b.591 061 33.68 029 3.90 Site No 28 Anntt.tl Totals 292_000 16591 061 33 68 0.29 390 131 RYE [unit (lbs ./acre/y car) e? y (41 e of Land Applier) NTe "I certify. tntd:r penally of law, that this document nns prepared under my direction or siipervisIon in accordance vith a system dasiped to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information. includingthe possibility of fincsand imprisonment for knowng►+iolations." CF Nitrogen, Inc. - Colield, North Carolina Field Loading Rate Report - Nitrogen Enriched Groundwater Pe emit # WQOOI 2404 OWNER: Judith, Allison, and Walter Perry OPERATOR: RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 25.1 Crow- Snvheanc Predominant Sail: Norfolk - NnA FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acne inlac Nutrients {Ihslac) PAN P K 3 Q3-23 25 1 739.000 29.442 1.08 59.77 052 6.93 Site No 28 Annual Totals 739.000 29.442 1.09 59.77 0.52 6.93 200 RYE Limit Ohs .ache/' ear) -?z2 q of Land Applierl baT, " i ccrts&, under penalty of tan: that this docranent .%Rs prepared under my direction or supervision in accordance nstlu a svOen) dessgned to assure thal qualified personnel properly gathered and evalualed the information submitted. f am amm 11iat tharc are significant penalties for submitting false information. inclnulingthe possibilily of fines and imprisonment far knowngviolations-" CF Nitrogen, Inc, - Cofield, North Carolina Field Loading Rate Report - Nitrogen Enriched Groundwater Permit # WQOO12404 OWNER: Judith, Allison, and Walter Perry OPERATOR: RESIDUAL SOURCE: Nitrogen Enrched Groundwater Permitted Acres: AG Croce Corn Predominant Sail: Norfolk - NoA FIELD DATE ACRES Ur4LIZED TOTAL GALLONS GALLONS PERACRE Acre inlac Nutrients Ohs,/ac) PAN P K 7 Q3-23 16 350.000 21.87:5 081 5833 0.40 526 Site No 28 Annual Totals 350.000 21,975 0.81 58.33 0.40 5.26 131 RYELimit (Ibs herely car) CK, -�&- Z ,7 ,f--f 45igrf + of Land ApplicrI LX,.v "1 certify, under penalty of law; that this document ►►as prepared under my direction or supervision to accordance ►►ittl a system d signed to assure that qualified personnel properly gathered and avaluated lice in format ion submitted. l am aware that there are significant penalties for submitting false information. including the possibility of fines and imprisonment for kno►►tngviolations." CF Nitrogen, Inc. - Colield, North Carolina Field Loading Rage Report - Nitrogen Enriched Groundwater Permit # WQ0012404 OWNER: Judith. Allison, and Walter Perry OPERATOR: RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres:9.2 CroFr Corn PrecbmirimtSoil: Goldsboro - GoA FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PER ACRE Acre i nlac Nutrients Ihhhtt PAN P K 8 2-23 9.2 405.000 441022 1.62 117.38 0.80 1058 Sitc No 28 Anneud Totals 405.000 44,022 1 62 117381 0.80 1058 158 RYE Emit albs /acrcl� car) L 7 Z el (Sig i of Land Appher) beta "[ car IiA% eind:r penalty of law: that this do cum ant was prepared under my direction or supervision in accordance with a systcm dosegnad I assure that qualified pzrsonncl properly gathered and evaItin t A the in formation subinitled. I am "are that there are sign licanT pcnaiIics fors hmitIing false: in form atton, rucIuding She possibility of fin es and iinprisonmenI Ibr knwain gviol aIions." CF Nitrogen, Inc. - Cofield, North Carolina Field Loading Rate Report - Nitrogen Enriched Gronndwater Pennit # WQOO12404 OWNER: Judith, Allison, and Walter Perri OPERATOR: RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Aches: 9.9 CroiK Corn Predourinant Soil: Goldsboro - GoA FIELD DATE ACRES Ui'IUT.ED TOTAL GALLONS GALLONS PERACRE Acre in/sc Nutrients Lignite) PAN P K 9 Q3-23 9.9 237,0(t) 23.939 0.88 63 83 044 7 77 Site No 28 Annual Totals 237.000 23.939 0.88 63,83 ❑ 44 5.75 tag RVE Limit obs.lacre/year} C�� -S-A-- 'Z z V-1 Y tat_ rc of Lana AppHer i tr:: "1 certif,!. under penally of law: that this docuntent was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and avaluated the information submitted. I am aware that there are sivlifieant pen allies for submitting false inforntxtion. including the possibility of fines and imprisonment For l.nowingvtotal ion s." CF Nitrogen, Inc. - Cofield, North Carolina Field Loading Rate Report - Nitrogen Enriched Groundwater Permit # WQ0012404 OWNER: .John Loch Mitchell OPERATOR: Walter Perry RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 8.7 Crop_ Sovbeans Pretleminant Soil. Bonneau - EoB FIELD DATE ACRES UTIIiZED TOTAL GALLONS GAUA)N5 PER ACRE Acre inlac Nutrients (IF>.slac) PAN P 1K 13 Q3-23 8.7 356.000 40.920 1.51 83.07 073 9.63 Sitc No. 28 Annual Totais 356-000 40.920 1 L51 83.07 0.73 9.63 200 RYElimit (lbs.lacrelyear) zIz �IzY c.. Lan u:eppnera vaic "I certify, under penail% of law that this document vss prepared wider my direction or supervision in accordance with a system destened to assure that qualified personnel properly gathered and evaluated tlra information submitted. I am aware thal there are significant penalties for submitting false information, including the possibility of fsltes and imprisonment for knouingviolations." CF Nitrogen, Inc. - Cofield, North Carolina Field Loading Rate Report - Nitrogen Enriched Groundwater Pennit # WQ0012404 OWNER: John Lock Mitchell OPERATOR: Walter Perry_ RESID UAL SOURCE: Pernritted Acres: 7 Nitrogen Enriched Groundwater Croy Soybeans PredominwitSoil - Bonneau -BOB FIELD DATE ACRES UTILIZED TOTAL GALLONS GALLONS PERACRE Acre inlac Nutrients (IW- ac) PAIN P K 14 Q3-23 7 150.000 21.429 0.79 43 50 0.38 5.04 Site No 28 Annual Totals 150M0 21729 039 43.50 0-39 5.04 200 RYE Limit (lbs.lacrely ear) & a of Land Applied Hate "i certif'v. under penalty of law. that this do rum anI was preparedunder my direction or supervision in accordance with a system desimied to assure that qua[ iiied personnel propefly gathered and evaluated the information submitted. I am aware that there are sign if7canI penalties for subniittrng false information. including the possibility of fines and imprisonment for knowing violations." CF Nitrogen, Inc. - Cofield, North Carolina Field Loading Rate Report - Nitrogen Enriched Groundwater Permit # WQatll2404 OWNER: William W. and Nellie Ward OPERATOR: William Ward RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: I5.1 C'rnn: Snrfisranc Preilr minant SnU7 Norfolk - NnR FIELD I DATE ACRES UTILUMD TOTAL GALLONS GALLONS PER ACRE Acre irtlac N tHents lx0ae PAN P K 2-23 151 381_000 25.232 093 67.28 0.46 6.06 Silc No 33 Annual Totals 38 L000 25.232 0.93 67.28 0.46 6.06 161 RYE H ni t pbs.rncuchvcar) �-� -ZY6-- -�- /2 �/? , ( (S49Tta a of Land AppIier) Da:: "I scrt1fv. wider pan aIty a£law, that this dociunonI nas prepared tinder n:y direction nr super visin n in accordance .Ni tIt a systcm desimiad to assure that qualified person»el properly gathered and evaluated ilta to formation suhin it zed, l am aware that there are significant penallics for sultmitttng False information, including the possibility o£tines and imprisonment for knowng violal tons " CF Nitrogen, Inc. - Co4ield, North Carolina Field Loading Rate Report - Nitrogen Enriched Groundwater Permit # WQ0012404 OWNER: William W, and Nellie Ward OPERATOR: William Ward RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 13.6 C'rnrt Rn hpnnC PrPsinminant Cnil• Vnerallr - ➢VnR FIELD DATE ACRES UI'lL7ZFD TOTAL GALLONS GALLONS PERACRE Acre inlac Nutrients (1bs/ac) PAN P K 4 Q3-23 13.6 49.000 3,603 0 l 3 9.61 007 0.87 Site No. 33 Annual Totals 49.000 1.603 0.13 9.61 0.07 0.87 161 RYE Gaut Qbs.lttctelyear) zZz?/Z `I turc of Land Applier) Bait "I certify. under pena[ty of law tliat this doeoment vms prepared under my direction or supervision in aceprdanee with a system deli Paled to assure Ilia( qualified personnel properly gathered and evaluated the infornation submitted. i am av}arc that there are significant penalties for submitting false information, including the possibility of fines and im prisonment for knowng violations." CF Nitrogen, Inc. _ Cofield, North Carolin,-r Field Loading Rate Report - Nitrogen Enriched Groundwater Permit # WQOO12404 OWNER: William W. and Nellie Ward OPERATOR: William Ward RESIDUAL SOURCE: Nitrogen Enriched Groundwater Permitted Acres: 14.2 CroF Soybeans Predominant Soil: Tarboro - TaB FIELD DATE ACRES []'I U ZED TOTAL GALLONS GALLONS PER ACRE Acre inlac Nun•iends lixslac PAN P K 7 2-23 14.2 569.000 40.070 1,48 106.84 0.73 9.63 Site No. 33 Annual Totals 569.000 40,070 1.49 106.84 0.73 9 63 200 RYE Limit 1'sJac i& car) z-7/Z tr r ftie of Land Applier] Date "I certifv. und:r penalty of law, that thisdoctunent %ins preparedunder my direction or supervision in accordance pith a system designed -to assure that qualified personnel properly gathered and evaluatedthe information submitled. I am a►%ure that thereare significant penalties for submitting false information, inchiAngthe possibility of finds and imprisonment for knowing violations." CF Nitrogen, Inc. - Cofield, North Carolina Field Loading Rate Report _ Nitrogen Enriched Groundwater Permit # WQ0012404 OWNER: Christie Cobb OPERATOR: Lee Britt RESIDUAL SOURCE: Permitted Acres: 27.2 Nitrogen Enriched Groundwater Crop: Soybeans PredaWnantSoil: Norfolk -NoA n u D HATE ACRES UTMIZED TOTAL GALLONS GALLONS PER ACRE Arrr ittlac Nun ienm Ihclac PAN P K 5 3-23 27-2 516.000 18.971 070 40.57 0.34 4,48 Site No. 35 Annual Totals 1 516-000 18.971 MO 10.57 034 4.48 200 RYE Limit ( bs hcrely ear) o�i'dLan`d'Apptier) Date "I certify- under penalty of lay+: that this document Has prcparod nndcr my direction or supervision in accordance vwh a system dcsipmed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information_ including the possibility of Ones and imprisonment for knowing violations." 2023 Nitrogen Enriched Groundwater Summary CF Nitrogen - Ahoskie Facility Hertford County, North Carolina Permit #WQ0012404 Permitted Site Field Number Application Quarter Acres Utilized Total Gallons Galons per Acre Inches per Arce PAN Obs/ac) 42 Q1 93.5 617,000 6,599 0.24 14.40 Q4 561,000 6,000 0.22 9.08 Site 27 43 Q1 17.7 593,000 33,503 1.23 68.36 Q4 406,000 22,938 0.84 34.71 44 Q1 29.2 431,000 14,760 0.54 30.12 Q4 676,000 23,151 0.85 45.55 Steven Burgess 45 Q1 17.5 330,000 18,857 0.69 38.48 Q4 415,000 23,714 0.87 35.88 46 Q2 13.9 178,000 12,806 0.47 34.14 Q4 280,000 20,144 0.74 30.48 47 Q2 20.8 433,000 20,817 0.77 50.96 Q4 445,000 21,394 0.79 32.37 Site 28 Walter Perry 1 Q3 17.6 292,000 16,591 0.61 33.68 3 Q3 25.1 739,000 29,442 1.08 1 59.77 7 Q3 16 350,000 21,875 0.81 58.33 8 Q2 9.2 414,000 45,000 1.66 119.98 9 Q3 9.9 237,000 23,939 0.88 63.83 13 Q3 8.7 356,000 40,920 1.51 83.07 14 Q3 7.0 150,000 1 21,429 0.79 43.50 Site 33 William Ward Jr. 3 Q2 15.1 372,000 24,636 0.91 65.69 4 Q3 13.6 49,000 3,603 0.13 9.61 5 Q2 14.2 569,000 40,070 1.48 106.84 Site 35 Lee Britt 5 Q3 27.2 516,000 18,971 0.70 40.57 Acronyms: PAN - Plant Available Nitrogen lbs/ac - pounds per acre 2023 Land Application Total Quarter 1 1,971,000 Quarter 2 1,966,000 Quarter 3 2,689,000 Quarter 4 2,783,000 Annual 9,409,000 2023 Groundwater Recovered to Holding Lagoon Quarter 1 1,927,800 Quarter 2 2,149,800 Quarter 3 2,807,500 Quarter 4 3,050,700 Annual 9,935,800 APPENDIX C Field Application Summaries 2023 Field Application Summary CF Nitrogen, Inc. Permit #WQ0012404 Site ID: 27 Application Method: Surface Site Name: Steven Burgess Total Application: 5,365,000 Site Acres: 192.6 Field 42 43 44 45 46 47 Acres 93.5 17.7 29.2 17.5 13.9 20.8 Crop Wheat Wheat Wheat Wheat Wheat Wheat 1/4/2023 62,000 1/6/2023 67,000 1/10/2023 68,000 1/11/2023 49,000 1/12/2023 69,000 1/16/2023 66,000 1/17/2023 42,000 1/19/2023 67,000 1/20/2023 69,000 1/21/2023 32,000 1/25/2023 26,000 2/6/2023 - 29,000 2/7/2023 67,000 2/8/2023 59,000 2/9/2023 65,000 2/10/2023 45,000 2/11/2023 32,000 2/15/2023 33,000 2/16/2023 32,000 - 2/17/2023 13,000 2/20/2023 64,000 2/21/2023 64,000 2/22/2023 63,000 2/23/2023 53,000 2/24/2023 13,000 2/27/2023 65,000 2/28/2023 - 64,000 3/1/2023 65,000 - 3/6/2023 65,000 3/7/2023 32,000 3/8/2023 33,000 3/9/2023 34,000 3/10/2023 32,000 3/16/2023 32,000 3/17/2023 19,000 3/20/2023 26,000 3/21/2023 58,000 3/22/2023 50,000 3/24/2023 58,000 3/30/2023 57,000 3/31/2023 32 000 4/3/2023 32,000 4/4/2023 33,000 4/5/2023 25,000 4/6/2023 31,000 4/11/2023 30,000 4/12/2023 31,000 4/13/2023 30,000 4/14/2023 19,000 4/17/2023 33,000 4/18/2023 32,000 4/19/2023 31,000 4/20/2023 7,000 4/21/2023 11,000 4/24/2023 88,000 4/25/2023 89,000 - 4/26/2023 1 89,0001 - 2023 Field Application Summary CF Nitrogen, Inc. Permit #WQ0012404 Site ID: 27 (continued) Application Method: Surface Site Name: Walter Perry Total Application: 5,365,000 Site Acres: 192.6 Field 42 43 44 45 46 47 Acres 93.5 17.7 29.2 17.5 13.9 20.8 Crop Wheat Wheat Wheat Wheat Wheat Wheat 10/11/2023 46,000 10/12/2023 76,000 10/13/2023 37,000 10/16/2023 100,000 10/17/2023 54,000 10/18/2023 49,000 10/19/2023 49,000 10/20/2023 44,000 10/23/2023 57,000 10/24/2023 82,000 10/25/2023 - 82,000 10/26/2023 64,000 - 10/27/2023 53,000 10/30/2023 60,000 10/31/2023 57,000 11/1/2023 70,000 11/2/2023 50,000 11/3/2023 52,000 11/6/2023 - 64,000 11/7/2023 82,000 11/8/2023 54,000 11/9/2023 57,000 11/10/2023 39,000 11/13/2023 66,000 11/14/2023 53,000 11/15/2023 - 59,000 11/16/2023 55,000 11/17/2023 54,000 11/20/2023 54,000 11/21/2023 33,000 11/28/2023 65,000 11/29/2023 61,000 11/30/2023 64,000 12/1/2023 38,000 - 12/4/2023 85,000 12/5/2023 77,000 12/6/2023 19,000 12/7/2023 61,000 12/8/2023 52,000 - 12/12/2023 91,000 12/13/2023 64,000 12/14/2023 55,000 12/15/2023 78,000 12/20/2023 98,000 12/21/2023 80,000 12/22/2023 43,000 - - Quarter 1 617,000 593,000 431,000 330,000 - - arter 2 - - - - 178,000 433,000 Quarter 3 - - - - - - Quart 4 561,000 406,000 676,000 415,000 280,000 445,000 Field Totals 1,178,000 999,000 1 1,107,0001 745,000 1 458,000 1 878,000 2023 Field Application Summary CF Nitrogen, Inc. Permit #WQ0012404 Site ID: 28 Site Name: Walter Perry Site Acres: 93.5 Application Method: Surface Total Application: 2,529,000 Field 1 3 7 8 9 13 14 Acres 17.6 25.1 16.0 9.2 9.9 8.7 7.0 Crop Corn Soybeans Corn Corn Corn Soybeans Soybeans 6/20/2023 - - - 57,000 - - - 6/26/2023 - - - 94,000 - - - 6/27/2023 - - - 86,000 - - - 6/28/2023 - - - 57 000 - - - 6/29/2023 - - - 55,000 - - - 6/30/2023 - - - 56,000 - - - 7/6/2023 - - - - 62,000 - - 7/7/2023 - - - - 36,000 - - 7/10/2023 - - - - 139,000 - - 7/11/2023 - - 101,000 - - - - 7/12/2023 - - 52,000 - - - - 7/13/2023 - - 41,000 - - - - 7/14/2023 - - 12,000 - - - - 7/24/2023 - - 64,000 - - - - 7/26/2023 - - 80,000 - - - - 8/9/2023 58,000 - - - - - - 8/10/2023 59,000 - - - - - - 8/11/2023 59,000 - - - - - - 8/14/2023 57,000 - - - - - - 8/15/2023 59,000 - - - - - - 8/17/2023 - - - - - 71,000 - 8/18/2023 - - - - - 49,000 - 8/21/2023 - - - - - 81,000 - 8/22/2023 - - - - - 93,000 - 8/28/2023 - - - - - 62,000 - 8/30/2023 - - - - - - 75,000 9/5/2023 - - - - - - 75,000 9/15/2023 - 58,000 - - - - - 9/16/2023 - 60,000 - - - - - 9/18/2023 - 57,000 - - - - - 9/19/2023 - 59,000 - - - - - 9/20/2023 - 58,000 - - - - - 9/21/2023 - 89,000 - - - - - 9/22/2023 - 66,000 - - - - - 9/25/2023 - 56,000 - - - - - 9/26/2023 - 57,000 - - - - - 9/27/2023 - 29,000 - - - - - 9/28/2023 - 69,000 - - - - - 9/29/2023 - 81,000 - - - - - Quarter 1 - - - - - - - Quarter 2 - - - 405,000 - - - Quarter 3 292,000 739,000 350,000 - 237,000 356,000 150,000 Quarter 4 - - - -I - - - Field Totals 292,000 739,000 350,0001 405,0001 237,000 356,000 150,000 2023 Field Application Summary CF Nitrogen, Inc. Permit #WQ0012404 Site ID: 33 Application Method: Surface Site Name: William Ward Jr. Total Application: 999,000 Site Acres: 42.9 Field 3 4 5 Acres 15.1 13.6 14.2 Crop Soybeans Soybeans Soybeans 5/3/2023 - - 63,000 5/4/2023 - - 62,000 5/5/2023 - - 50,000 5/8/2023 - - 57,000 5/9/2023 - - 69,000 5/10/2023 - - 26,000 5/11/2023 - - 30,000 5/12/2023 - - 50,000 5/15/2023 - - 45,000 5/16/2023 - - 39,000 5/17/2023 - - 39,000 5/18/2023 - - 39,000 5/23/2022 31,000 - - 5/24/2022 30,000 - - 5/25/2022 31,000 - - 5/26/2022 37,000 - - 5/30/2023 39,000 - - 5/31/2023 40,000 - - 6/l/2023 37,000 - - 6/2/2023 40,000 - - 6/20/2023 40,000 - - 6/27/2023 56,000 - - 7/6/2023 - 49,000 - uarter 1 - - - uarter 2 381,000 - 569,000 Quarter 3 - 49,000 - uarter 4 - - - Field Totals 381,000 49,000 569,000 2023 Field Application Summary CF Nitrogen, Inc. Permit #WQ0012404 Site ID: 35 Application Method: Surface Site Name: Lee Britt Total Application: 516,000 Site Acres: 27.2 Field 5 Acres 27.2 Crop Soybeans 7/27/2023 88,000 7/28/2023 63,000 7/31/2023 118,000 8/3/2023 64,000 8/4/2023 20,000 8/7/2023 63,000 8/8/2023 100,000 Quarter 1 - uarter 2 - uarter 3 516,000 Quarter 4 - Field Totals 516,0001 APPENDIX D Approved Land Application Sites 2023 Approved Land Application Sites CF Nitrogen, Inc. Permit #W Q0012404 Site Field Site Name Owner County Net Acres Dominant Soil Series Latitude Longitude 11 1 C.F. NITROGEN CF Nitrogen, Inc. HERTFORD 42.1 Craven - CrA 36° 22' 18.607" N 76° 52' 6.611" W 11 2 C.F. NITROGEN CF Nitrogen, Inc. HERTFORD 77 Craven -CrA 36° 22' 15.533" N 76° 51' 47.081" W 11 3 C.F. NITROGEN CF Nitrogen, Inc. HERTFORD 46.9 Craven - CrA 36° 22' 4.598" N 76° 51' S4.527" W 19 10W C.C. WOODARD C.C. Woodard NORTHAMPTON 3.8 Bonneau - BoB 36° 31' 26.426" N 77° 20' S4.784" W 19 11W C.C. WOODARD C.C. Woodard NORTHAMPTON 29.5 Bonneau - BoB 36° 31' 26.519" N 77° 20' 44.315" W 19 12W C.C. WOODARD C.C. Woodard NORTHAMPTON 4.6 Bonneau - BoB 36° 31' 44.580" N 77° 20' 26.546" W 19 13W C.C. WOODARD C.C. Woodard NORTHAMPTON 7.9 Norfolk- NoB 36° 31' 12.981" N 77° 20' 10.349" W 19 14W C.C. WOODARD C.C. Woodard NORTHAMPTON 9.3 Norfolk- NoB 36° 31' 18.958" N 77° 20' 11.351" W 19 15W C.C. WOODARD C.C. Woodard NORTHAMPTON 11.2 Norfolk- NoB 36° 31' 26.516" N 77° 20' 11.092" W 19 1G C.C. WOODARD C.C. Woodard NORTHAMPTON 58.6 Altavista - AtA 36° 32' 9.400" N 77° 21' S.050" W 19 1W C.C. WOODARD C.C. Woodard NORTHAMPTON 31.7 Norfolk- NoB 36° 30' 45.799" N 77° 20' 27.020" W 19 2G C.C. WOODARD C.C. Woodard NORTHAMPTON 13.6 Tarboro -TaB 36° 32' 17.834" N 77° 21' 22.344" W 19 2W C.C. WOODARD C.C. Woodard NORTHAMPTON 23 Norfolk - NoB 36° 30' 47.856" N 77° 20' 48.971" W 19 3G C.C. WOODARD C.C. Woodard NORTHAMPTON 36.3 Altavista -AtA 36° 32' 27.269" N 77° 21' 3.689" W 19 3W C.C. WOODARD C.C. Woodard NORTHAMPTON 74.1 Norfolk- NoB 36° 30' 39.932" N 77° 21' 1.368" W 19 4G C.C. WOODARD C.C. Woodard NORTHAMPTON 42.5 Roanoke - Ro 36° 32' 42.629" N 77° 20' S8.170" W 19 4W C.C. WOODARD C.C. Woodard NORTHAMPTON 77.2 Norfolk- NoB 36° 30' 25.249" N 77° 20' S6.297" W 19 5G C.C. WOODARD C.C. Woodard NORTHAMPTON 25.7 Wickham - WkA 36° 32' 35.655" N 77° 21' 4.581" W 19 5W C.C. WOODARD Cecil Whitehead NORTHAMPTON 14.3 Norfolk- NoB 36° 30' 20.037" N 77° 20' 47.758" W 19 6W C.C. WOODARD Amanda Cooke, et al NORTHAMPTON 23.5 Norfolk - NoB 36° 30' 33.904" N 77° 20' 34.762" W 19 7W C.C. WOODARD C.C. Woodard NORTHAMPTON 103.3 Norfolk - NoA 36° 30' 15.429" N 77° 20' 19.892" W 19 8W C.C. WOODARD C.C. Woodard NORTHAMPTON 11.1 36° 30' 15.313" N 77° 20' 28.934" W 19 9W C.C. WOODARD C.C. Woodard NORTHAMPTON 15.8 Norfolk- NoB 36° 30' 30.281" N 77° 20' 26.692" W 22 1 CHARLES J. STEPHENSON Charles J. Stephenson NORTHAMPTON 24.9 Goldsboro - GoA 36° 27' 23.181" N 77° 24' S5.340" W 22 2 CHARLES J. STEPHENSON Charles J. Stephenson NORTHAMPTON 24.3 Goldsboro - GoA 36' 27' 18.332" N 77° 24' 41.482" W 22 3 CHARLES J. STEPHENSON Charles J. Stephenson NORTHAMPTON 11.7 Goldsboro - GoA 36° 27' 15.457" N 77° 24' 29.028" W 22 4 CHARLES J. STEPHENSON Charles J. Stephenson NORTHAMPTON 11.9 Goldsboro - GoA 36° 26' S7.471" N 77° 24' 29.804" W 22 5 CHARLES J. STEPHENSON Charles J. Stephenson NORTHAMPTON 7.3 Goldsboro - GoA 36° 25' 43.788" N 77° 23' S8.836" W 22 6 CHARLES J. STEPHENSON NORTHAMPTON 4.4 36° 27' S8.073" N 77° 23' 42.905" W 22 7 CHARLES J. STEPHENSON NORTHAMPTON 11.2 36° 27' 49.003" N 77° 23' 39.383" W 22 8 CHARLES J. STEPHENSON NORTHAMPTON 8.2 36° 27' 49.615" N 77° 23' 43.995" W 22 9 CHARLES J. STEPHENSON NORTHAMPTON 32.6 36° 27' 39.612" N 77° 23' 39.037" W 23 1 JOHNNY POWELL Johnny Powell HERTFORD 26.4 Norfolk - NoA 36° 17' 0.084" N 76° 44' 1.992" W 23 10 JOHNNY POWELL Johnny Powell HERTFORD 17.3 Craven - CrA 36° 20' 26.781" N 76° 49' 43.836" W 23 12 JOHNNY POWELL Johnny Powell HERTFORD 27.5 Craven - CrA 36° 22' 28.205" N 76° 54' 9.079" W 23 13 JOHNNY POWELL Johnny Powell HERTFORD 20.5 Craven - CrA 36° 21' 37.114" N 76° 54' 0.366" W 23 14 JOHNNY POWELL Johnny Powell HERTFORD 18.9 Craven - CrA 36° 21' 42.487" N 76° 54' 24.524" W 23 15 JOHNNY POWELL Johnny Powell HERTFORD 19 Norfolk - NoA 36° 22' 35.738" N 76° 55' S8.204" W 23 16 JOHNNY POWELL Johnny Powell HERTFORD 45 Craven - CrB 36° 18' 34.219" N 76° 55' 44.240" W 23 2 JOHNNY POWELL Johnny Powell HERTFORD 14 Norfolk - NoA 36° 16' 41.190" N 76° 45' 11.647" W 23 3 JOHNNY POWELL Thaddeus F. Scott HERTFORD 39.2 Norfolk- NoA 36° 17' 45.949" N 76° 45' 45.877" W 2023 Approved Land Application Sites CIF Nitrogen, Inc. Permit #W Q0012404 Site Field Site Name Owner County Net Acres Dominant Soil Series Latitude Longitude 23 4 JOHNNY POWELL Thaddeus F. Scott HERTFORD 22.1 Norfolk - NoA 36' 17' S4.764" N 76° 45' 43.836" W 23 5 JOHNNY POWELL Johnny Powell HERTFORD 27.7 Norfolk - NoB 36° 18' 20.250" N 76° 47' 16.085" W 23 8 JOHNNY POWELL Johnny Powell HERTFORD 32.4 Caroline - CaA 36° 17' 12.543" N 76° 52' S9.292" W 23 9 JOHNNY POWELL Johnny Powell HERTFORD 23.1 Craven - CrA 36° 20' 6.312" N 76° 51' 25.022" W 24 10 CH ESTER POWELL Shirley Deramus HERTFORD 6.1 Bonneau - BoB 36° 17' S1.176" N 76° 43' 19.503" W 24 11 CHESTER POWELL Shirley Deramus HERTFORD 12.6 Goldsboro - GoA 36° 18' 3.574" N 76° 43' 19.621" W 24 13 CH ESTER POWELL Chester Powell HERTFORD 15.7 Craven - CrA 36° 15' 22.758" N 76° 49' 8.287" W 24 2 CH ESTER POWELL Chester Powell HERTFORD 14.6 Norfolk - NoA 36° 19' 14.614" N 76° 50' 39.422" W 24 3 CHESTER POWELL Chester Powell HERTFORD 11.7 Wickham - WkB 36° 19' 26.954" N 76° 50' 34.101" W 24 4 CHESTER POWELL Chester Powell HERTFORD 11 Goldsboro - GoA 36° 18' S5.824" N 76° 48' S1.794" W 24 5 CH ESTER POWELL Chester Powell HERTFORD 14 Bonneau - BoB 36° 18' 45.201" N 76° 48' 49.050" W 24 6 CH ESTER POWELL Chester Powell HERTFORD 13.5 Craven - CrA 36° 20' 26.047" N 76° 51' S1.935" W 24 7 CHESTER POWELL Chester Powell HERTFORD 3.6 Craven -CrA 36° 20' 17.029" N 76° 51' 45.243" W 24 8 CHESTER POWELL Chester Powell HERTFORD 6.3 Lenoir- Ln 36° 15' S0.055" N 76° 53' 31.858" W 24 9 CHESTER POWELL Chester Powell HERTFORD 13.1 Craven - CrA 36° 15' 49.899" N 76° 53' S3.653" W 27 1 STEVEN BURGESS Neil Burgess NORTHAMPTON 48 Norfolk - NoA 36° 26' 0.596" N 77° 12' S1.345" W 27 10 STEVEN BURGESS Stephen Burgess NORTHAMPTON 20.5 Craven -CrA 36° 23' S1.725" N 77° 13' S2.363" W 27 11 STEVEN BURGESS Stephen Burgess NORTHAMPTON 23.4 Craven -CrA 36° 23' 42.607" N 77° 13' S2.055" W 27 12 STEVEN BURGESS Stephen Burgess NORTHAMPTON 16.7 Craven -CrA 36° 23' 40.130" N 77° 13' 40.271" W 27 13 STEVEN BURGESS Stephen Burgess NORTHAMPTON 5.2 Craven -CrA 36° 23' 34.918" N 77° 13' 13.065" W 27 14 STEVEN BURGESS Lori. S. Burgess NORTHAMPTON 14.7 Goldsboro - GoA 36° 24' 34.717" N 77° 16' 4.531" W 27 15 STEVEN BURGESS Stephen Burgess NORTHAMPTON 6.5 Norfolk- NoB 36° 26' 30.751" N 77° 17' 10.347" W 27 16 STEVEN BURGESS Stephen Burgess NORTHAMPTON 5.6 Norfolk- NoB 36° 26' 28.081" N 77° 17' 2.505" W 27 17 STEVEN BURGESS Stephen Burgess NORTHAMPTON 23.5 Norfolk- NoB 36° 26' 32.804" N 77° 16' S2.897" W 27 18 STEVEN BURGESS Lori. S. Burgess NORTHAMPTON 11.1 Goldsboro - GoA 36° 26' 11.199" N 77° 14' 39.355" W 27 19 STEVEN BURGESS Lori. S. Burgess NORTHAMPTON 19.1 Goldsboro - GoA 36° 26' 18.996" N 77° 14' 25.209" W 27 2 STEVEN BURGESS Neil Burgess NORTHAMPTON 57.1 Norfolk- NoA 36° 26' 0.324" N 77° 12' 36.361" W 27 20 STEVEN BURGESS Eloise T. Ward NORTHAMPTON 13.8 Goldsboro - GoA 36° 26' 20.229" N 77° 14' 18.066" W 27 21 STEVEN BURGESS Eloise T. Ward NORTHAMPTON 3.8 Goldsboro - GoA 36° 26' 19.405" N 77° 14' 13.675" W 27 22 STEVEN BURGESS Eloise T. Ward NORTHAMPTON 6.7 Goldsboro - GoA 36° 26' 34.683" N 77° 14' 15.462" W 27 23 STEVEN BURGESS Eloise T. Ward NORTHAMPTON 32.9 Bonneau - BoB 36° 27' S0.240" N 77° 15' 27.375" W 27 24 STEVEN BURGESS Eloise T. Ward NORTHAMPTON 21.5 Bonneau - BoB 36° 28' 6.790" N 77° 15' 16.893" W 27 25 STEVEN BURGESS Eloise T. Ward NORTHAMPTON 37.3 Bonneau - BoB 36° 28' 4.380" N 77° 14' 45.308" W 27 26 STEVEN BURGESS Eloise T. Ward NORTHAMPTON 11.8 Norfolk - NoB 36° 27' S3.529" N 77° 14' 41.940" W 27 27 STEVEN BURGESS Eloise T. Ward NORTHAMPTON 14.4 Norfolk- NoB 36° 28' 2.984" N 77° 14' 34.720" W 27 28 STEVEN BURGESS Eloise T. Ward NORTHAMPTON 25.4 Norfolk- NoB 36° 27' S3.454" N 77° 14' 25.633" W 27 29 STEVEN BURGESS Eloise T. Ward NORTHAMPTON 60.7 Norfolk- NoB 36° 27' 47.991" N 77° 14' 16.603" W 27 3 STEVEN BURGESS Neil Burgess NORTHAMPTON 25.9 Rains - Ra 36° 25' 49.693" N 77° 12' 33.150" W 27 30 STEVEN BURGESS Eloise T. Ward NORTHAMPTON 6.1 Autryville -AuA 36° 28' 11.470" N 77° 14' S1.369" W 27 31 STEVEN BURGESS Eloise T. Ward NORTHAMPTON 10.3 Norfolk - NoA 36° 28' 16.011" N 77° 14' S3.227" W 27 32 STEVEN BURGESS Eloise T. Ward NORTHAMPTON 26 Bonneau - BoB 36° 28' 23.024" N 77° 14' 53.475" W 2023 Approved Land Application Sites CIF Nitrogen, Inc. Permit #W Q0012404 Site Field Site Name Owner County Net Acres Dominant Soil Series Latitude Longitude 27 33 STEVEN BURGESS Eloise T. Ward NORTHAMPTON 10.3 Norfolk - NoA 36° 28' 22.470" N 77° 14' 42.445" W 27 34 STEVEN BURGESS Eloise T. Ward NORTHAMPTON 18.4 Bonneau - BoB 36° 28' 27.102" N 77° 14' 29.696" W 27 35 STEVEN BURGESS Eloise T. Ward NORTHAMPTON 9.6 Goldsboro - GoA 36° 28' 30.481" N 77° 14' 18.185" W 27 36 STEVEN BURGESS Eloise T. Ward NORTHAMPTON 9.6 Autryville - AuA 36° 28' 24.849" N 77° 13' S6.619" W 27 37 STEVEN BURGESS Eloise T. Ward NORTHAMPTON 18.3 Autryville - AuA 36° 28' 23.084" N 77° 14' 12.159" W 27 38 STEVEN BURGESS Eloise T. Ward NORTHAMPTON 3 Norfolk - NoA 36° 28' 10.616" N 77° 14' 9.562" W 27 39 STEVEN BURGESS Kevin B. Burgess NORTHAMPTON 20.6 Norfolk- No 36° 26' 42.268" N 77° 12' 39.993" W 27 4 STEVEN BURGESS Neil Burgess NORTHAMPTON 27.6 Norfolk - NoA 36° 25' 36.985" N 77° 12' 39.874" W 27 40 STEVEN BURGESS Kevin B. Burgess NORTHAMPTON 21.8 Norfolk- No 36° 26' 34.398" N 77° 12' 35.105" W 27 41 STEVEN BURGESS Stephen Burgess NORTHAMPTON 9.8 Norfolk- NoB 36° 27' 33.424" N 77° 11' 46.100" W 27 42 STEVEN BURGESS Stephen Burgess NORTHAMPTON 93.7 Bonneau - BoB 36° 27' 42.736" N 77° 11' 32.583" W 27 43 STEVEN BURGESS Stephen Burgess NORTHAMPTON 17.9 Norfolk- No 36° 27' 35.242" N 77° 11' 20.962" W 27 44 STEVEN BURGESS Stephen Burgess NORTHAMPTON 29.2 Bonneau - BoB 36° 27' 43.357" N 77° 11' 11.919" W 27 45 STEVEN BURGESS Stephen Burgess NORTHAMPTON 17.5 Norfolk- No 36° 27' S0.235" N 77° 11' 3.993" W 27 46 STEVEN BURGESS Stephen Burgess NORTHAMPTON 13.9 Bonneau - BoB 36° 27' 27.292" N 77° 11' 17.834" W 27 47 STEVEN BURGESS Stephen Burgess NORTHAMPTON 21.5 Bonneau - BoB 36° 27' 36.256" N 77° 11' 6.928" W 27 48 STEVEN BURGESS Kevin B. Burgess NORTHAMPTON 16.6 State - StA 36° 27' 31.987" N 77° 10' 14.778" W 27 49 STEVEN BURGESS Kevin B. Burgess NORTHAMPTON 6.8 Tarboro -TaB 36° 27' 27.185" N 77° 10' 6.934" W 27 5 STEVEN BURGESS Neil Burgess NORTHAMPTON 17.1 Norfolk- NoA 36° 25' 18.624" N 77° 12' 39.921" W 27 50 STEVEN BURGESS Kevin B. Burgess NORTHAMPTON 18.7 Altavista- Ata 36° 27' 37.362" N 77° 9' S9.447" W 27 51 STEVEN BURGESS Kevin B. Burgess NORTHAMPTON 55.6 Tarboro - TaB 36° 27' 39.146" N 77° 9' 39.095" W 27 52 STEVEN BURGESS Lori S. Burgess HERTFORD 45.8 Norfolk - NoA 36° 25' 2.247" N 77° 6' 1.211" W 27 53 STEVEN BURGESS Lori S. Burgess HERTFORD 11.1 Norfolk - NoA 36° 24' 42.337" N 77° 5' S5.609" W 27 54 STEVEN BURGESS Steven Burgess HERTFORD 46.1 Norfolk - NoA 36° 24' 35.852" N 77° 6' S.751" W 27 55 STEVEN BURGESS Steven Burgess HERTFORD 7.6 Craven - CrA 36° 21' 18.013" N 77° 7' 40.293" W 27 56 STEVEN BURGESS Steven Burgess HERTFORD 10.5 Craven - CrA 36° 21' 19.550" N 77° 7' 31.600" W 27 57 STEVEN BURGESS Steven Burgess HERTFORD 13.6 Craven - CrA 36° 21' 21.592" N 77° 7' 21.107" W 27 58 STEVEN BURGESS Steven Burgess HERTFORD 6.3 Lenoir- Ln 36° 21' 12.295" N 77° 7' 18.129" W 27 59 STEVEN BURGESS Steven Burgess HERTFORD 10.7 Lenoir - Ln 36° 21' 8.309" N 77° 7' 24.184" W 27 6 STEVEN BURGESS Stephen Burgess NORTHAMPTON 55 Bonneau - BoB 36° 26' 6.955" N 77° 11' 20.730" W 27 60 STEVEN BURGESS Steven Burgess HERTFORD 2.8 Lenoir - Ln 36° 21' 4.232" N 77° 7' 7.764" W 27 61 STEVEN BURGESS Steven Burgess HERTFORD 16.3 Craven - CrA 36° 21' 4.138" N 77° 6' S9.455" W 27 62 STEVEN BURGESS Steven Burgess HERTFORD 3.1 Craven -CrA 36° 20' S5.553" N 77° 7' 3.102" W 27 63 STEVEN BURGESS Adam and Wendy Burgess HERTFORD 14.7 Craven - CrA 36° 21' 14.487" N 77° 6' S6.533" W 27 64 STEVEN BURGESS Adam and Wendy Burgess HERTFORD 32.2 Craven - CrA 36° 21' 24.404" N 77° 6' S1.450" W 27 65 STEVEN BURGESS Bobby Bridges NORTHAMPTON 68.7 Bonneau - BoB 36° 25' 47.041" N 77° 15' 4.934" W 27 66 STEVEN BURGESS Neil and Donna Burgess NORTHAMPTON 18.4 Norfolk- No 36° 24' 4.351" N 77° 15' 9.677" W 27 67 STEVEN BURGESS Fannie Bryant NORTHAMPTON 33.7 Bonneau - BoB 36° 27' 45.548" N 77° 10' 46.927" W 27 68 STEVEN BURGESS Martha Pearlman NORTHAMPTON 58.4 Goldsboro - GoA 36° 30' 4.636" N 77° 11' 14.171" W 27 69 STEVEN BURGESS Ronald Woodard NORTHAMPTON 44.5 Gritney - GxB 36° 29' 55.530" N 77° 11' 18.333" W 27 7 STEVEN BURGESS Judi B. Burgess NORTHAMPTON 13.9 Craven- CrA 36° 24' 21.610" N 77° 13' 28.511" W 2023 Approved Land Application Sites CIF Nitrogen, Inc. Permit #W Q0012404 Site Field Site Name Owner County Net Acres Dominant Soil Series Latitude Longitude 27 70 STEVEN BURGESS Ronald Woodard NORTHAMPTON 87.6 Lynchburg - Ly 36° 28' S4.348" N 77° 12' 24.865" W 27 71 STEVEN BURGESS William E. Davis NORTHAMPTON 68.5 Bonneau - BoB 36° 27' 29.924" N 77° 15' 30.473" W 27 72 STEVEN BURGESS William E. Davis NORTHAMPTON 43.1 Bonneau - BoB 36° 27' 26.712" N 77° 15' 7.022" W 27 73 STEVEN BURGESS William E. Davis NORTHAMPTON 83.2 Norfolk - NoA 36° 27' 10.063" N 77° 15' 14.328" W 27 8 STEVEN BURGESS Judi B. Burgess NORTHAMPTON 18.4 Norfolk- No 36° 23' S9.938" N 77° 14' 11.276" W 27 9 STEVEN BURGESS Lori. S. Burgess NORTHAMPTON 19.9 Caroline - CaA 36° 23' S7.276" N 77° 13' S8.261" W 28 1 WALTER PERRY Judith, Allison, and Walter Perry HERTFORD 18.2 Norfolk - NoA 36° 19' 32.103" N 76° 50' 16.055" W 28 10 WALTER PERRY Judith, Allison, and Walter Perry HERTFORD 1.8 Goldsboro - GoA 36° 19' 44.664" N 76° 51' 18.343" W 28 11 WALTER PERRY Judith, Allison, and Walter Perry HERTFORD 3.8 Craven - CrB 36° 19' 49.086" N 76° 51' 15.511" W 28 12 WALTER PERRY Judith, Allison, and Walter Perry HERTFORD 3.8 Craven - CrB 36° 19' 46.823" N 76° 51' 11.795" W 28 13 WALTER PERRY John Lock Mitchell HERTFORD 9.6 Bonneau - BoB 36° 17' 43.342" N 76° 49' 37.641" W 28 14 WALTER PERRY John Lock Mitchell HERTFORD 7.2 Bonneau - BoB 36° 17' 36.085" N 76° 49' 45.448" W 28 15 WALTER PERRY Berry Perry, John Mitchell, Eleanor Lane, Penny Beasley, and Ken Mitchell HERTFORD 17.9 Craven - CrA 36° 17' 19.677" N 76° 50' 13.000" W 28 16 WALTER PERRY John Mitchell, Eleanor Lane, Penny Beasley, Ken Mitchell, and Wiccacon HERTFORD 19 Conetoe - CoB 36° 18' 3.420" N 76° 50' 23.119" W 28 17 WALTER PERRY Margaret Hall HERTFORD 17.9 Craven - CrA 36° 23' 0.077" N 76° 56' S2.624" W 28 18 WALTER PERRY Bettt Everette Perry HERTFORD 7.6 Craven - CrA 36° 17' 30.536" N 76° 49' S3.993" W 28 2 WALTER PERRY Judith, Allison, and Walter Perry HERTFORD 17.5 Norfolk- NoA 36° 19' 27.115" N 76° 50' S.237" W 28 3 WALTER PERRY Judith, Allison, and Walter Perry HERTFORD 25.4 Norfolk - NoA 36° 19' 48.791" N 76° 50' 9.866" W 28 4 WALTER PERRY Judith, Allison, and Walter Perry HERTFORD 11 Wickham - WkA 36° 19' 20.292" N 76° 49' S1.641" W 28 5 WALTER PERRY Judith, Allison, and Walter Perry HERTFORD 9.6 Conetoe - CoB 36° 19' 10.848" N 76° 49' 34.028" W 28 6 WALTER PERRY Judith, Allison, and Walter Perry HERTFORD 22.4 Norfolk - NoA 36° 19' 24.337" N 76° 50' 25.244" W 28 7 WALTER PERRY Judith, Allison, and Walter Perry HERTFORD 17.7 Norfolk - NoA 36° 19' S0.569" N 76° 51' 3.932" W 28 8 WALTER PERRY Judith, Allison, and Walter Perry HERTFORD 9.2 Goldsboro - GoA 36° 19' 42.110" N 76° 51' 7.129" W 28 9 WALTER PERRY Judith, Allison, and Walter Perry HERTFORD 10.2 Goldsboro - GoA 36° 19' 41.702" N 76° 51' 13.815" W 29 1 RONALD BYRD Ronald Byrd BERTIE 8.4 Leaf- Lf 36° 9' 30.915" N 76° 57' S5.069" W 29 10 RONALD BYRD Ronald Byrd BERTIE 4.7 Exum - ExB 36° 9' 24.304" N 76° 57' S5.737" W 29 2 RONALD BYRD Ronald Byrd BERTIE 2.5 Leaf - Lf 36° 9' 31.346" N 76° 58' 1.562" W 29 3 RONALD BYRD Ronald Byrd BERTIE 6.3 Exum - ExA 36° 9' 31.291" N 76° 58' 10.162" W 29 4 RONALD BYRD Ronald Byrd BERTIE 10.4 Exum - ExA 36° 9' 27.573" N 76° 58' 9.054" W 29 5 RONALD BYRD Ronald Byrd BERTIE 11.3 Exum - ExA 36° 9' 27.734" N 76° 58' 20.925" W 29 6 RONALD BYRD Ronald Byrd BERTIE 3.1 Leaf- Lf 36° 9' 25.020" N 76° 58' 34.804" W 29 7 RONALD BYRD Ronald Byrd BERTIE 5.4 Granthum - Gt 36° 9' 24.363" N 76° 58' 12.161" W 29 8 RONALD BYRD Ronald Byrd BERTIE 10.2 Granthum - Gt 36° 9' 21.566" N 76° 58' 7.179" W 29 9 RONALD BYRD Ronald Byrd BERTIE 0.6 Exum - ExA 36° 9' 24.036" N 76° 58' 0.440" W 30 1 KEN DRED C. WILLIAMS, JR. Kendred C. Williams, Jr. BERTIE 15.8 Exum - ExA 36° 8' 15.358" N 76° 57' 12.753" W 30 10 KEN DRED C. WILLIAMS, JR. Kendred C. Williams, Jr. BERTIE 5.1 Norfolk - NoA 36° 12' 45.459" N 76° 56' 46.979" W 30 11 KEN DRED C. WILLIAMS, JR. Kendred C. Williams, Jr. BERTIE 2.9 Norfolk - NoB 36° 12' 48.282" N 76° 56' 45.979" W 30 12 KEN DRED C. WILLIAMS, JR. Kendred C. Williams, Jr. BERTIE 1.8 Norfolk - NoA 36° 12' 48.587" N 76° 56' 39.709" W 30 13 KENDRED C. WILLIAMS, JR. Kendred C. Williams, Jr. BERTIE 6.7 Lenoir - Ln 36° 12' 52.102" N 76° 56' 41.556" W 2023 Approved Land Application Sites CF Nitrogen, Inc. Permit #W Q0012404 Site Field Site Name Owner County Net Acres Dominant Soil Series Latitude Longitude 30 14 KENDRED C. WILLIAMS, JR. Kendred C. Williams, Jr. BERTIE 1.2 Lenoir - Ln 36° 12' S7.059" N 76° 56' 38.576" W 30 15 KENDRED C. WILLIAMS, JR. Kendred C. Williams, Jr. BERTIE 14.8 Leaf - Lf 36° 13' 3.145" N 76° 56' 36.713" W 30 16 KENDRED C. WILLIAMS, JR. Kendred C. Williams, Jr. BERTIE 7 Craven -CrA 36° 13' 9.958" N 76° 56' 31.451" W 30 1 17 KENDRED C. WILLIAMS, JR. Kendred C. Williams, Jr. BERTIE 28.3 Craven -CrA 36° 13' 6.125" N 76° 57' 3.875" W 30 18 KENDRED C. WILLIAMS, JR. Kendred C. Williams, Jr. BERTIE 21.5 Craven -CrA 36° 12' S5.486" N 76° 57' 0.708" W 30 19 KENDRED C. WILLIAMS, JR. Kendred C. Williams, Jr. BERTIE 11.1 Goldsboro - GoA 36° 12' S4.983" N 76° 56' 47.763" W 30 2 KENDRED C. WILLIAMS, JR. Kendred C. Williams, Jr. BERTIE 6.2 Exum - ExA 36° 8' 22.279" N 76° 57' 12.860" W 30 20 KENDRED C. WILLIAMS, JR. Kendred C. Williams, Jr. BERTIE 11.3 Craven -CrA 36° 12' 13.245" N 76° 56' S0.566" W 30 21 KENDRED C. WILLIAMS, JR. C.S. Hollomon, Jr. BERTIE 7.8 Lenoir - Ln 36° 12' 23.858" N 76° 56' 49.065" W 30 22 KENDRED C. WILLIAMS, JR. C.S. Hollomon, Jr. BERTIE 8.5 Craven -CrA 36° 12' 16.399" N 76° 56' S4.681" W 30 23 KENDRED C. WILLIAMS, JR. C.S. Hollomon, Jr. BERTIE 10.5 Craven -CrA 36° 12' 15.822" N 76° 56' S9.570" W 30 24 KENDRED C. WILLIAMS, JR. C.S. Hollomon, Jr. BERTIE 4.4 Craven - CrA 36° 12' 18.403" N 76° 57' 2.636" W 30 25 KENDRED C. WILLIAMS, JR. C.S. Hollomon, Jr. BERTIE 1.7 Craven -CrA 36° 12' 19.761" N 76° 57' 6.055" W 30 26 KENDRED C. WILLIAMS, JR. C.S. Hollomon, Jr. BERTIE 4.3 Craven -CrA 36° 12' 25.354" N 76° 57' 12.666" W 30 27 KENDRED C. WILLIAMS, JR. C.S. Hollomon, Jr. BERTIE 4.6 Craven -CrA 36° 12' 16.578" N 76° 57' 7.822" W 30 28 KENDRED C. WILLIAMS, JR. C.S. Hollomon, Jr. BERTIE 5.7 Craven - CrA 36° 12' 13.411" N 76° 57' 9.197" W 30 29 KENDRED C. WILLIAMS, JR. C.S. Hollomon, Jr. BERTIE 13.5 Craven -CrA 36° 12' 8.095" N 76° 57' 8.021" W 30 3 KENDRED C. WILLIAMS, JR. Kendred C. Williams, Jr. BERTIE 1.3 Craven -CrA 36° 12' 47.867" N 76° 56' 34.765" W 30 30 KENDRED C. WILLIAMS, JR. Kendred C. Williams, Jr. BERTIE 5.3 Nahunta - Na 36° 10' 35.600" N 76° 57' 24.961" W 30 31 KENDRED C. WILLIAMS, JR. Kendred C. Williams, Jr. BERTIE 22.4 Exum - ExA 36° 10' 28.760" N 76° 57' 24.017" W 30 32 KENDRED C. WILLIAMS, JR. Kendred C. Williams, Jr. BERTIE 8.2 Goldsboro - GoA 36° 10' 24.620" N 76° 57' 15.099" W 30 33 KENDRED C. WILLIAMS, JR. Kendred C. Williams, Jr. BERTIE 19.7 Goldsboro - GoA 36° 10' 17.882" N 76° 57' 19.755" W 30 34 KENDRED C. WILLIAMS, JR. Kendred C. Williams, Jr. BERTIE 26.3 Goldsboro - GoA 36° 10' 18.000" N 76° 57' 29.177" W 30 35 KENDRED C. WILLIAMS, JR. Kendred C. Williams, Jr. BERTIE 1.1 Exum - ExA 36° 10' 21.152" N 76° 57' 37.204" W 30 36 KENDRED C. WILLIAMS, JR. David C. Powell BERTIE 20 Exum - ExA 36° 13' 13.964" N 76° 54' 33.645" W 30 37 KENDRED C. WILLIAMS, JR. E.M. Powell and Sons, Inc. BERTIE 21.4 Exum - ExA 36° 13' 6.455" N 76° 54' 25.570" W 30 38 KENDRED C. WILLIAMS, JR. E.M. Powell and Sons, Inc. BERTIE 23.9 Exum - ExA 36° 12' 49.149" N 76° 54' 30.213" W 30 39 KENDRED C. WILLIAMS, JR. E.M. Powell and Sons, Inc. BERTIE 27.3 Exum - ExA 36° 12' 41.927" N 76° 54' 25.912" W 30 4 KENDRED C. WILLIAMS, JR. Kendred C. Williams, Jr. BERTIE 26.9 Norfolk- No 36° 12' 44.615" N 76° 56' 22.379" W 30 40 KENDRED C. WILLIAMS, JR. T.E. Ruffin BERTIE 21.2 Exum - ExA 36° 9' 23.203" N 76° 57' 24.390" W 30 41 KENDRED C. WILLIAMS, JR. T.E. Ruffin BERTIE 8.5 Exum - ExA 36° 9' 24.246" N 76° 57' 37.675" W 30 42 KENDRED C. WILLIAMS, JR. T.E. Ruffin BERTIE 5.2 Exum - ExA 36° 9' 26.602" N 76° 57' 43.399" W 30 43 KENDRED C. WILLIAMS, JR. T.E. Ruffin BERTIE 7.9 Exum - ExA 36° 9' 23.065" N 76° 57' 46.249" W 30 44 KENDRED C. WILLIAMS, JR. James C. Askew BERTIE 3.7 Exum - ExB 36° 11' 19.068" N 76° 57' 21.141" W 30 45 KENDRED C. WILLIAMS, JR. James C. Askew BERTIE 7.3 Exum - ExB 36° 11' 17.474" N 76° 57' 17.646" W 30 46 KENDRED C. WILLIAMS, JR. James C. Askew BERTIE 12.6 Gritney - Gt 36° 11' 17.233" N 76° 57' 10.640" W 30 47 KENDRED C. WILLIAMS, JR. Oliver B. Balance BERTIE 12.9 Exum - ExA 36° 11' 12.236" N 76° 57' 9.772" W 30 5 KENDRED C. WILLIAMS, JR. Kendred C. Williams, Jr. BERTIE 34.6 Craven - CrB 36° 12' 43.537" N 76° 56' 7.064" W 30 6 KENDRED C. WILLIAMS, JR. Kendred C. Williams, Jr. BERTIE 9.4 Craven - CrB 36° 12' 31.532" N 76° 56' 10.265" W 30 7 KENDRED C. WILLIAMS, JR. Kendred C. Williams, Jr. BERTIE 13.1 Craven - CrB 36° 12' 38.174" N 76° 56' 25.938" W 30 8 KENDRED C. WILLIAMS, JR. Kendred C. Williams, Jr. BERTIE 8.8 Craven - CrB 36° 12' 40.617" N 1 76° 56' 34.833" W 2023 Approved Land Application Sites CIF Nitrogen, Inc. Permit #W Q0012404 Site Field Site Name Owner County Net Acres Dominant Soil Series Latitude Longitude 30 9 KEN DRIED C. WILLIAMS, JR. Kendred C. Williams, Jr. BERTIE 17.1 Norfolk - NoA 36° 12' 42.191" N 76° 56' 49.543" W 31 1 RAY CHAMBLEE Ray and Linda Chamblee HERTFORD 9.3 Craven -CrA 36° 20' 42.913" N 76° 55' 26.930" W 31 2 RAY CHAMBLEE Jackie Chamblee HERTFORD 10.2 Craven - CrB 36° 20' 41.081" N 76° 55' 20.161" W 31 3 RAY CHAMBLEE Jackie Chamblee HERTFORD 18.3 Craven - CrA 36° 20' 47.274" N 76° 55' 14.466" W 31 4 RAY CHAMBLEE Ray and Linda Chamblee HERTFORD 9.7 Craven -CrA 36° 20' 42.892" N 76° 55' 4.595" W 31 5 RAY CHAMBLEE Ray and Linda Chamblee HERTFORD 6.2 Goldsboro - GoA 36° 20' 31.662" N 76° 55' 16.269" W 32 1 WILLIAM SESSOMS Janic Simmons Sessoms HERTFORD 7.7 Wakulla - WaB 36° 17' S3.973" N 76° 48' S3.605" W 32 10 WILLIAM SESSOMS William H. and Delores Sessoms HERTFORD 10.2 Norfolk- No 36° 17' 41.372" N 76° 47' 33.482" W 32 11 WILLIAM SESSOMS Wiccacon Properties, LLC HERTFORD 4.7 Craven -CrA 36° 17' 47.455" N 76° 49' 32.354" W 32 12 WILLIAM SESSOMS Ernest Chamblee HERTFORD 14.8 Craven - CrA 36° 15' 22.866" N 76° 49' 8.532" W 32 2 WILLIAM SESSOMS William H. Sessoms HERTFORD 32.3 Lynchburg - Ly 36° 17' S0.761" N 76° 48' 41.904" W 32 3 WILLIAM SESSOMS William H. Sessoms HERTFORD 5.1 Craven - CrB 36° 17' 27.008" N 76° 48' 39.134" W 32 4 WILLIAM SESSOMS Joyce Ann Sessoms HERTFORD 11 Bonneau - BoB 36° 18' 7.370" N 76° 48' 45.362" W 32 5 WILLIAM SESSOMS Joyce Ann Sessoms HERTFORD 5.8 Lynchburg - Ly 36° 17' 43.244" N 76° 49' 16.391" W 32 6 WILLIAM SESSOMS William H. Sessoms HERTFORD 2.8 Lynchburg - Ly 36° 17' 42.601" N 76° 49' 27.496" W 32 7 WILLIAM SESSOMS William H. and Joyce Anne Sessoms HERTFORD 32.4 Goldsboro - GoA 36° 17' 24.243" N 76° 47' S8.143" W 32 8 WILLIAM SESSOMS William H. and Delores Sessoms HERTFORD 25.7 Norfolk- No 36° 17' 32.439" N 76° 47' 24.156" W 32 9 WILLIAM SESSOMS William H. and Delores Sessoms HERTFORD 13.9 Norfolk- No 36° 17' 36.529" N 76° 47' 36.460" W 33 1 WILLIAM WARD, JR. William W. and Nellie Ward HERTFORD 3.4 Caroline - CaB 36° 14' 36.477" N 76° 56' 23.588" W 33 10 WILLIAM WARD, JR. Michael A. and Deborah Spalding HERTFORD 8.4 Craven - CrB 36° 14' 28.840" N 76° 58' 26.683" W 33 11 WILLIAM WARD, JR. Michael A. and Deborah Spalding HERTFORD 3.9 Craven - CrB 36° 14' 25.529" N 76° 58' 16.858" W 33 12 WILLIAM WARD, JR. Michael A. and Deborah Spalding HERTFORD 2.5 Craven - CrA 36° 14' 20.819" N 76° 58' 17.798" W 33 13 WILLIAM WARD, JR. Rosa H. Sessoms HERTFORD 25.4 Craven -CrA 36° 15' 8.121" N 77° 0' 47.156" W 33 14 WILLIAM WARD, JR. Rosa H. Sessoms HERTFORD 6.5 Leaf- Lf 36° 15' 11.776" N 77° 0' 37.238" W 33 15 WILLIAM WARD, JR. Rosa H. Sessoms HERTFORD 4.3 Craven -CrA 36° 15' 14.675" N 77° 0' 30.413" W 33 16 WILLIAM WARD, JR. Rosa H. Sessoms HERTFORD 4.8 Craven -CrA 36° 15' 20.651" N 77° 0' 31.135" W 33 17 WILLIAM WARD, JR. Leonard L. Godwin BERTIE 11.4 Norfolk - NoA 36° 13' 37.929" N 77° 0' 4.532" W 33 18 WILLIAM WARD, JR. Leonard L. Godwin BERTIE 11.9 Goldsboro - GoA 36° 13' 30.514" N 76° 59' S4.192" W 33 19 WILLIAM WARD, JR. Ola Sanders BERTIE 17.2 Goldsboro - GoA 36° 12' 14.561" N 76° 56' 9.510" W 33 2 WILLIAM WARD, JR. William W. and Nellie Ward HERTFORD 11.9 Craven - CrC2 36° 14' 46.503" N 76° 56' 22.931" W 33 20 WILLIAM WARD, JR. Ruth H. Metcalf BERTIE 3.8 Exum - ExA 36° 14' 6.177" N 76° 54' 30.362" W 33 21 WILLIAM WARD, JR. Ruth H. Metcalf, et al BERTIE 13.5 Exum - ExA 36° 14' 2.098" N 76° 54' 24.049" W 33 22 WILLIAM WARD, JR. Mildred Harris BERTIE 17.8 Exum - ExA 36° 13' S3.392" N 76° 54' 11.451" W 33 23 WILLIAM WARD, JR. Agnes O. Moore, et al BERTIE 9.7 Goldsboro - GoA 36° 13' 42.509" N 76° 54' 8.902" W 33 3 WILLIAM WARD, JR. William W. and Nellie Ward HERTFORD 15.1 Norfolk- NoB 36° 14' 46.687" N 76° 56' 20.886" W 33 4 WILLIAM WARD, JR. William W. and Nellie Ward HERTFORD 13.6 Norfolk- No 36° 14' 48.047" N 76° 56' 11.534" W 33 5 WILLIAM WARD, JR. William W. and Nellie Ward HERTFORD 14.2 Tarboro -TaB 36° 15' 1.266" N 76° 56' 8.504" W 33 6 WILLIAM WARD, JR. William W. and Nellie Ward HERTFORD 14.7 Norfolk- No 36° 14' 42.574" N 76° 56' 9.010" W 33 7 WILLIAM WARD, JR. William W. and Nellie Ward HERTFORD 6.1 Craven- CrB 36° 14' 37.269" N 76° 56' 8.627" W 33 8 WILLIAM WARD, JR. William W. and Nellie Ward HERTFORD 3.2 Craven - CrB 36° 14' 35.114" N 76° 56' 14.184" W 33 9 WILLIAM WARD, JR. Michael A. and Deborah Spalding HERTFORD 14.5 Craven - CrA 36° 14' 23.149" N 76° 58' 28.335" W 2023 Approved Land Application Sites CIF Nitrogen, Inc. Permit #W Q0012404 Site Field Site Name Owner County Net Acres Dominant Soil Series Latitude Longitude 34 1 NELLIE BROWN Nellie B. Brown MARTIN 27.9 Goldsboro - GoA 35° 59' 36.824" N 77° 20' 9.198" W 34 2 NELLIE BROWN Nellie B. Brown MARTIN 20.1 Goldsboro - GoA 35° 59' 30.502" N 77° 20' 17.788" W 34 3 NELLIE BROWN Nellie B. Brown MARTIN 4.2 Lynchburg - Ly 35° 59' 26.056" N 77° 20' 24.440" W 34 4 NELLIE BROWN Nellie B. Brown MARTIN 28.8 Lynchburg- Ly 35° 59' 20.303" N 77° 20' 17.226" W 35 1 Lee Britt Hulda Tayloe BERTIE 4.9 Norfolk - NoB 36° 14' 04.471" N 76° 48' 13.455" W 35 2 Lee Britt Hulda Tayloe BERTIE 6.5 Goldsboro - GoA 36° 14' 03.732" N 76° 48' 16.368" W 35 3 Lee Britt Hulda Tayloe BERTIE 4.5 Goldsboro - GoA 36° 13' 53.829" N 76° 48' 14.551" W 35 4 Lee Britt Ken Evans BERTIE 17.6 Craven - CrA 36° 14' 56.825" N 76° 48' 04.082" W 35 5 Lee Britt Christie Cobb HERTFORD 27.2 Norfolk - NoA 36° 15' 19.874" N 76° 46' 56.222" W 35 6 Lee Britt Christie Cobb HERTFORD 18.4 Norfolk - NoB 36° 15' 23.330" N 76° 46' 57.737" W 35 7 Lee Britt Christie Cobb HERTFORD 19.3 Norfolk- NoB 36° 15' 19.273" N 76° 46' 52.156" W APPENDIX E Residuals Sampling Analytical Reports Waypointo ANALYTICAL 1 /25/2023 Soil Plus, LLC Joyce Barrett P.O. Box 1396 Oxford, NC, 27565 Ref: Analytical Testing Report Number: 23-012-0009 Project Description: CF Ind. 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Dear Joyce Barrett: Waypoint Analytical Virginia, Inc. received sample(s) on 1/12/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table if applicable. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information Sincerely, Brandi Watson Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 5 Waypoint - 7621 Whitepine Road, Richmond, WA 23237 Main 804-743-9401 ° Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com Sample Summary Table Report Number: 23-012-0009 Client Project Description: CF Ind. Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 60392 CF011123 Aqueous 01/11/2023 08:32 01/12/2023 SM-4500-NH3C-TKN WP MTN 60392 CF011123 Aqueous 01/11/2023 08:32 01/12/2023 4500NO3F-2011 WP MTN 60392 CF011123 Aqueous 01/11/2023 08:32 01/12/2023 6010D WP MTN 60392 CF011123 Aqueous 01/11/2023 08:32 01/12/2023 9045D WP MTN 60392 CF011123 Aqueous 01/11/2023 08:32 01/12/2023 SM-4500-NH3C WP MTN WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN Page 2 of 5 Waypointo ANALYTICAL 04596 Soil Plus, LLC Project CF Ind. Joyce Barrett P.O. Box 1396 Information Oxford , NC 27565 Report Number : 23-012-0009 REPORT 0 Lab No : 60392 Sample ID : CF011123 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Report Date : 01/25/2023 Received : 01/12/2023 Brandi Watson VALYSIS Matrix: Aqueous Sampled: 1/11/2023 8:32 Test Results Units MQL DF Date I Time By Analytical Analyzed Method Calcium 50.8 mg/L 0.500 1 01/23/23 21:17 JTR 6010D Sodium 26.7 mg/L 0.500 1 01/23/23 21:17 JTR 6010D Aluminum 0.522 mg/L 0.100 1 01/23/23 21:17 JTR 6010D Test Results Units MQL DF Date I Time By Analytical Analyzed Method Nitrate+Nitrite-N 186 mg/L 2.00 20 01/23/2315:43 ZBD 4500NO3F-2011 Phosphorus 2.64 mg/L 0.100 1 01/23/23 21:17 JTR 6010D Total Kjeldahl Nitrogen 194 mg/L 5.00 1 01/24/23 13:45 JPJ ;M-4500-NH3C-TKl` Potassium 31.8 mg/L 0.500 5 01/24/2313:56 TJS 6010D Magnesium 14.1 mg/L 0.100 1 01/23/23 21:17 JTR 6010D Ammonia Nitrogen 1.68 mg/L 1.00 1 01/23/23 13:00 ZBD SM-4500-NH3C pH 6.4 S.U. 1 01/23/2314:30 SAR 9045D Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit Page 3 of 5 WaypANALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalyfrical.com Shipment Receipt Form Customer Number: 04596 Customer Name: Soil Plus, LLC Report Number: 23-012-0009 Shipping Method 0 Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client 0 Courier 0 Other: Thermometer ID: Shipping container/cooler uncompromised? Yes 0 No Number of coolers/boxes received 1 Custody seals intact on shipping container/cooler? 0 Yes 0 No Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? # Yes 0 No COC agrees with sample Iabel(s)? # Yes 0 No COC properly completed # Yes 0 No Samples in proper containers? # Yes 0 No Sample containers intact? # Yes 0 No Sufficient sample volume for indicated test(s)? # Yes 0 No All samples received within holding time? # Yes 0 No Cooler temperature in compliance? # Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. # Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No N/A Water - VOA vials free of headspace 0 Yes 0 No N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No N/A F_ High concentration container (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low concentration EnCore samplers (48 hr) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes * No Comments: Signature: IDavid Lennon Date & Time: 01/12/2023 12:17:39 Page 4 of 5 r m z ` x rn � x U x c ¢ x 0 T U Q w x m a x 0 cn r a 9 0 V] ❑ = p) m CL x _z x 'a a Z Z n Ez x ^ LO LO UCD I— N C Iv N C �. fy G J ❑] N E . .-. o n .-. ❑i a . ❑ a a a a D J U LC] G C] r z y I A a Es, L m V w 1-9 —� .o 0. 2 rm o m- m o x 4- aD a- On- On- Da- '�o 0-) _° IU xl f Iy` I iI 0 r do E I Q7 u w O L] LL U) `o Q1 E A o W m r E U-) o 1% J 67 N OOO m �, J CO U N L] "a Po.' °o.' 0 o m E EEa E ❑ �7 L) C7 U Ou C7U to E j T �. U � n _ a �' V w x E m `o C �] E u � N LL LL n ar C3 ID n L Z m� 0 N v E v N U) a z Q J ip C M cv c ill C Q cu ro o a p m ❑ c `co E w E p ❑ E ° C En C iA .Q Q A MMU [�v ° Q7 E E m U E E ° �.. c ❑ Q u � [] t m w � O C7 is a. t� ❑ �i m .�'�� v7 ❑ m 2 6 c) �•�cn m°Emm�m �Q °a -= U ;E2t;- CL m Q Q C j N m0 Q in O CA Y o'C N m N_ 'C C [D v V V ❑ V° p z N N m a 7 > V ❑ ° V r C U Q) c � v .... M W L = z a 2 0 0 n Page 5 of 5 Waypointo ANALYTICAL 5/4/2023 Soil Plus, LLC Joyce Barrett P.O. Box 1396 Oxford, NC, 27565 Ref: Analytical Testing Report Number: 23-104-0012 Project Description: CF Ind. 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Dear Joyce Barrett: Waypoint Analytical Virginia, Inc. received sample(s) on 4/14/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table if applicable. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information Sincerely, Brandi Watson Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 6 Waypoint - 7621 Whitepine Road, Richmond, WA 23237 Main 804-743-9401 ° Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com Sample Summary Table Report Number: 23-104-0012 Client Project Description: CF Ind. Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 61777 CF041223 Aqueous 04/12/2023 14:10 04/14/2023 SM-4500-NH3C-TKN WP MTN 61777 CF041223 Aqueous 04/12/2023 14:10 04/14/2023 4500NO3F-2011 WP MTN 61777 CF041223 Aqueous 04/12/2023 14:10 04/14/2023 6010D WP MTN 61777 CF041223 Aqueous 04/12/2023 14:10 04/14/2023 9045D WP MTN 61777 CF041223 Aqueous 04/12/2023 14:10 04/14/2023 SM-4500-NH3C WP MTN WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN Page 2 of 6 Waypointo ANALYTICAL 04596 Soil Plus, LLC Project CF Ind. Joyce Barrett P.O. Box 1396 Information Oxford , NC 27565 Report Number : 23-104-0012 REPORT 0 Lab No : 61777 Sample ID : CF041223 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Report Date : 05/04/2023 Received : 04/14/2023 Brandi Watson VALYSIS Matrix: Aqueous Sampled: 4/ 12/ 2023 14:10 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Calcium 60.1 mg/L 0.500 1 04/20/23 22:48 TJS 6010D Sodium 31.5 mg/L 0.500 1 04/20/23 22:48 TJS 6010D Aluminum 0.742 mg/L 0.100 1 04/20/23 22:48 TJS 6010D Test Results Units MQL DF Date / Time By Analytical Analyzed Method Nitrate+Nitrite-N 223 mg/L 10.0 100 04/20/23 09:10 ZBD 4500NO3F-2011 Phosphorus 2.18 mg/L 0.100 1 04/20/23 22:48 TJS 6010D Total Kjeldahl Nitrogen 215 mg/L 5.00 1 05/02/23 15:50 JPJ ;M-4500-NH3C-TKI` Potassium 28,8 mg/L 0.500 5 04/21/23 20:40 TJS 6010D Magnesium 17.8 mg/L 0.100 1 04/20/23 22:48 TJS 6010D Ammonia Nitrogen 160 mg/L 1.00 1 04/19/23 09:30 ZBD SM-4500-NH3C pH 5.7 S.U. 1 05/03/2316:00 CNB 9045D Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit Page 3 of 6 Waypointo ANALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytica1.com Client: Soil Plus, LLC CASE NARRATIVE Project: CF Ind. Lab Report Number: 23-104-0012 Date: 5/4/2023 Metals Analysis Method 601 OD Sample 61777 (CF041223) Analyte: Potassium QC Batch No: L677786/L676939 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Page 4 of 6 Way Point. ANALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalyfrical.com Shipment Receipt Form Customer Number: 04596 Customer Name: Soil Plus, LLC Report Number: 23-104-0012 Shipping Method 0 Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client 0 Courier 0 Other: Thermometer ID: Shipping container/cooler uncompromised? Yes 0 No Number of coolers/boxes received Custody seals intact on shipping container/cooler? 0 Yes 0 No Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? # Yes 0 No COC agrees with sample label(s)? # Yes 0 No COC properly completed # Yes 0 No Samples in proper containers? # Yes 0 No Sample containers intact? # Yes 0 No Sufficient sample volume for indicated test(s)? # Yes 0 No All samples received within holding time? # Yes 0 No Cooler temperature in compliance? # Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. # Yes 0 No Water - Sample containers properly preserved Yes 0 No 0 N/A Water - VOA vials free of headspace 0 Yes 0 No N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 - compliance criteria met 0 Yes 0 No N/A F_ High concentration container (48 hr) F_ Low concentration EnCore samplers (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes * No Comments: Signature: Pavid Lennon Date & Time: 04/14/2023 09:56:54 Page 5 of 6 QD m LO Q w , Z I x ❑] x N e tTo •V U x m E 7+ a U7 m p 2 ❑ N m d x s c N U) ❑ @ (D _ n CL a) ❑ CL U U m Z [[3 a7 .m O x ? , cv a] E Z LLI 4, 0 ,n (0 Y x mom u) i� J p N W C C C i If c cm E r E i G m a m o E N� NN NNN � ono _ ❑ Q 0 y{ Q] G o a ' mm L7 a c6ca f7 a m� L7 a mro C7 a — U'�oc a� d 4 a y n7 C t] U 7 x r E Lv _ z c = F 0 j.. ••� U E U _ m r O ro p7 .� 0 f9 u.-: CL U a� co o r e'7 �' otl E o c o [D — @ �E _j F- co� {j o) N 00 a 3 �� m:� � ❑ CO -0 CV R 0 E � E 0 E m E 7 E � m o� a —n o ni 0 6 0 t� c) c� � = Q Q N o {!) p x I I Q `�U a7 d N❑ a- U � : m Y ❑ E N LL n J 0 H ~ tp FL y = U _ °0'_� V7 ❑ V� d o `o ❑ ❑ E c cu Q Page 6 of 6 Waypointo ANALYTICAL 8/28/2023 Soil Plus, LLC Joyce Barrett P.O. Box 1396 Oxford, NC, 27565 Ref: Analytical Testing Report Number: 23-213-0002 Project Description: CF Ind. 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Dear Joyce Barrett: Waypoint Analytical Virginia, Inc. received sample(s) on 8/1/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table if applicable. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information Sincerely, Brandi Watson Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 5 Waypoint - 7621 White pine Road, Richmond, WA 23237 Main 804-743-9401 ° Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com Sample Summary Table Report Number: 23-213-0002 Client Project Description: CF Ind. Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 62994 CF072823 Aqueous 07/28/2023 10:25 08/01/2023 SM-4500-NH3C WP MTN 62994 CF072823 Aqueous 07/28/2023 10:25 08/01/2023 SM-4500-NH3C-TKN WP MTN 62994 CF072823 Aqueous 07/28/2023 10:25 08/01/2023 4500NO3F-2016 WP MTN 62994 CF072823 Aqueous 07/28/2023 10:25 08/01/2023 6010D WP MTN 62994 CF072823 Aqueous 07/28/2023 10:25 08/01/2023 9045D WP MTN 62994 CF072823 Aqueous 07/28/2023 10:25 08/01/2023 SM-2540B WP MTN WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN Page 2 of 5 Waypointo ANALYTICAL 04596 Soil Plus, LLC Project CF Ind. Joyce Barrett P.O. Box 1396 Information Oxford , NC 27565 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Report Date : 08/28/2023 Received : 08/01/2023 Brandi Watson Report Number : 23-213-0002 REPORT OFANALYSIS Lab No : 62994 Matrix: Aqueous Sample ID : CF072823 Sampled: 7/28/2023 10:25 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Total Kjeldahl Nitrogen 215 mg/L 5.00 1 08/15/23 10:00 JPJ ;M-4500-NH3C-TKI` Phosphorus 2.13 mg/L 0.100 1 08/07/23 22:45 TJS 6010D Potassium 28.2 mg/L 0.500 5 08/09/23 01:09 TJS 6010D Calcium 59.9 mg/L 0.500 1 08/07/23 22:45 TJS 6010D Magnesium 16.4 mg/L 0.100 1 08/07/23 22:45 TJS 6010D Sodium 30.6 mg/L 0.500 1 08/07/23 22:45 TJS 6010D Nitrate+Nitrite-N 173 mg/L 2.00 20 08/03/2314:29 CLP 4500NO3F-2016 pH 7.1 S.U. 1 08/03/2315:25 CNB 9045D Test Results Units MQL DF Date / Time By Analytical Analyzed Method Ammonia Nitrogen 28.8 mg/L 1.00 1 08/14/23 10:00 CLP SM-4500-NH3C Aluminum 0.894 mg/L 0.100 1 08/07/23 22:45 TJS 6010D Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit H Beyond holding time Page 3 of 5 Way Point. ANALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalyfrical.com Shipment Receipt Form Customer Number: 04596 Customer Name: Soil Plus, LLC Report Number: 23-213-0002 Shipping Method 0 Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client 0 Courier 0 Other: Thermometer ID: Shipping container/cooler uncompromised? Yes 0 No Number of coolers/boxes received Custody seals intact on shipping container/cooler? 0 Yes 0 No Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? # Yes 0 No COC agrees with sample label(s)? # Yes 0 No COC properly completed # Yes 0 No Samples in proper containers? # Yes 0 No Sample containers intact? # Yes 0 No Sufficient sample volume for indicated test(s)? # Yes 0 No All samples received within holding time? # Yes 0 No Cooler temperature in compliance? # Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. # Yes 0 No Water - Sample containers properly preserved Yes 0 No 0 N/A Water - VOA vials free of headspace 0 Yes 0 No N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 - compliance criteria met 0 Yes 0 No N/A F_ High concentration container (48 hr) F_ Low concentration EnCore samplers (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes * No Comments: Signature: Pavid Lennon Date & Time: 08/01/2023 10:10:11 Page 4 of 5 !. � ° o m. IS m o 5 fT�v f0 n o U] v°i sNn rp w cJ �v -i Z 7 t•• �� T1 Q C� ❑ D pm SmZLC 0 7 Q? v Ni 3 ev N W ro Q O 7 I I co Q yam m 7y CI] p to a m c C} G7 C7 G3 0 C) C7 ) D O " ❑ N ` c N ❑ a ° ro a 0 @ 3fE C� V J C° m 3 CC0, yc c•� 5ro C) ul Z aa�� -_3 m ° p7 - mCO iA ul C� �C C 9' C] W O O CL _. (D „ o ° � F,- mm �y w r� 0 3 v m IOD ❑ ❑' ❑ ❑ CD M N N N N N N N N (A N N m co CD Q W `� [7 C7 p a a c c m rt 1 Z 7C In �Xlo b❑ a v a 3 N a x x :- �. Z 'l7 Cl] x Z CA ' a can CD ro ig m za a Z v u x M. m m C7 no zT ccn RL ❑ P UL 10 'n 1^ ❑ x (D ° Co x n x x z CD 4�L n cr o CO (m Li Page 5 of 5 Waypointo ANALYTICAL 11 /13/2023 Soil Plus, LLC Joyce Barrett P.O. Box 1396 Oxford, NC, 27565 Ref: Analytical Testing Report Number: 23-300-0002 Project Description: CF Ind. 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Dear Joyce Barrett: Waypoint Analytical Virginia, Inc. received sample(s) on 10/27/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table if applicable. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information Sincerely, Brandi Watson Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 6 Waypoint - 7621 White pine Road, Richmond, WA 23237 Main 804-743-9401 ° Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com Sample Summary Table Report Number: 23-300-0002 Client Project Description: CF Ind. Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 63821 CF Aqueous 63821 CF Aqueous 63821 CF Aqueous 63821 CF Aqueous 63821 CF Aqueous 10/25/2023 11:00 10/27/2023 10/25/2023 11:00 10/27/2023 10/25/2023 11:00 10/27/2023 10/25/2023 11:00 10/27/2023 10/25/2023 11:00 10/27/2023 SM-4500-NH3C-TKN WP MTN 4500NO3F-2016 WP MTN 6010D WP MTN 9045D WP MTN SM-4500-NH3C WP MTN WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN Page 2 of 6 Waypointo ANALYTICAL 04596 Soil Plus, LLC Project CF Ind. Joyce Barrett P.O. Box 1396 Information Oxford , NC 27565 Report Number : 23-300-0002 REPORT OFA Lab No : 63821 Sample ID : CF 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Report Date : 11/13/2023 Received : 10/27/2023 Brandi Watson VALYSIS Matrix: Aqueous Sampled: 10/ 25/ 2023 11:00 Test Results Units MQL DF Date / Time Analyzed By Analytical Method Calcium 64.9 mg/L 0.500 1 11/03/2316:14 BKN 6010D Sodium 29.9 mg/L 0.500 1 11/03/2316:14 BKN 6010D Aluminum 0.667 mg/L 0.100 1 11/03/2316:14 BKN 6010D Test Results Units MQL DF Date / Time By Analytical Analyzed Method Nitrate+Nitrite-N 85.8 mg/L 1.00 10 11/07/2314:29 CLP 4500NO3F-2016 Phosphorus 2.35 mg/L 0.100 1 11/03/23 16:14 BKN 6010D Test Results Units MQL DF Date / Time By Analytical Analyzed Method Total Kjeldahl Nitrogen 225 mg/L 5.00 1 11/13/23 06:45 JPJ ;M-4500-NH3C-TKI` Potassium 31.2 mg/L 1.00 10 11/06/2312:48 BKN 6010D Magnesium 16.2 mg/L 0.100 1 11/03/2316:14 BKN 6010D Ammonia Nitrogen 140 mg/L 1.00 1 11/07/23 13:00 CLP SM-4500-NH3C pH 6.5 S.U. 1 10/31/2316:00 CNB 9045D Qualifiers/ DF Dilution Factor MQL Method Quantitation Limit Definitions Page 3 of 6 Waypointo ANALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytica1.com Client: Soil Plus, LLC CASE NARRATIVE Project: CF Ind. Lab Report Number: 23-300-0002 Date: 11 /13/2023 Metals Analysis Method 601 OD Sample 63821 (CF) Analyte: Potassium QC Batch No: 1-715477/1-714824 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Page 4 of 6 Way Point. ANALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalyfrical.com Shipment Receipt Form Customer Number: 04596 Customer Name: Soil Plus, LLC Report Number: 23-300-0002 Shipping Method 0 Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client 0 Courier 0 Other: Thermometer ID: Shipping container/cooler uncompromised? Yes 0 No Number of coolers/boxes received Custody seals intact on shipping container/cooler? 0 Yes 0 No Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? # Yes 0 No COC agrees with sample label(s)? # Yes 0 No COC properly completed # Yes 0 No Samples in proper containers? # Yes 0 No Sample containers intact? # Yes 0 No Sufficient sample volume for indicated test(s)? # Yes 0 No All samples received within holding time? # Yes 0 No Cooler temperature in compliance? # Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. # Yes 0 No Water - Sample containers properly preserved Yes 0 No 0 N/A Water - VOA vials free of headspace 0 Yes 0 No N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 - compliance criteria met 0 Yes 0 No N/A F_ High concentration container (48 hr) F_ Low concentration EnCore samplers (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes * No Comments: Signature: Pavid Lennon Date & Time: 10/27/2023 10:27:50 Page 5 of 6 g 40 g O5Pd o LO � a r3� u m J z I x ro Q U a 'a N W Z LO Y Ln U co 1' v {6 J r U l� a 2 C, .o x T is a m o rn v D x to m o. L U] ❑ a — U N M N � N � x E V LL (A z a d E H g m o E CO � to F- N N 0 J o c Z Lo u CN _ EL co-2 n • � 2 m C �D a CL r � LL _• x x r-i PON CT O x� I ❑ O O fA [] N -U N V N 2 m m m m 2 0-52 a. C7 �I C7If 41 C7 CL Ix co xI �J m m a a n ou 0L) C7U m E m `o J C (P d cL cn V 0 U 'D 1f a E cNa r, cu Q7 Q. Z Q d LL! J m . m co @ SF c c -3 N C7 V) Q c 07 1 LO @_ C o E U 67 7 0] 5,• C N.ea0 N o��°y 6> @ [n -2 E�* z ? Cz •� -� L) 0 L) C m Q L? -E ro Z w 0 — m �¢ o c u] `m -U�c m E E m m n ¢ a o C ¢ N Cc @ «S 65 41 U Q c O E m � Y p o L z❑ c y N y @ C a LD 5, `o c m m map CO z a 2 0 u Q