NC0022217_Historical_2012

_
j 'o"� - I
M OT I VA
ENTERPRISES LLC
ffo
CERTIFIED MAIL 70113500 0002 9771 1888
RETURNED RECEIPT REQUESTED
October 16, 2012
Ms. Dina Sprinkle
NCDENR, Division of Water Quality
Point Source Branch
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
Subject:
NPDES Permit Renewal Application for the Motiva Raleigh
NPDES Permit No. NCO022217
Dear Ms. Sprinkle:
Motiva Enterprises LLC (Motiva) owns and operates the Raleigh Terminal. This facility is covered
under NPDES Permit No. NCO022217 which will expire on April 30, 2013. A permit renewal
package is due to the Division of Water Quality within 180 days prior to permit expiration.
Please find attached an original and two copies of the NPDES permit application, including the
Application Form — Short Form C, a summary table of effluent data since August 2009, a map of the
facility and surrounding area, and a diagram of the wastewater system. Please note the following:
The terminal is able now to store ethanol or gasoline/ethanol blend (denatured ethanol) in
addition to the gasoline and distillate currently indicated in the NPDES permit. Currently
only one tank stores ethanol on site (Tank 30724). However, Tanks 30722, 30723, 30726,
31532, and 31533 have the capability to store these four products. The facility notified Mr.
Bob Guerra, NC DWQ, of this change in an email from Ms. Brittany Robinson, IJRS, on
June 19, 2012. A copy of that email is included as Attachment V.
The terminal requests the removal of the permit condition to analyze and report all
parameters under Test Methods 624 and 625 (PCS Codes 76028 and 76029) It is noted that
several specific parameters would remain in the permit and tested by these methods;
however, the only parameters reported would be those specifically identified in the permit. It
is noted that the remaining parameters analyzed by these methods are not expected to be
present in the outfall and are not detected (See Attachment II).
The "NPDES Permitting Requirements for Petroleum Bulk -Storage Surface Storage Greater
than One Million Gallons 2005 — Permitting Strategy" posted on the NC DNER websitet
and included as Attachment VI, provides guidance for including Methods 624 and 625 in
NPDES permits. Specifically, if no parameters are detected other than BTEX, screening for
1 hnp://portal.ncdner.org/c/document_tibrary/get_file?uuid=503ecO2f-ef6c-4f81-8669-e885dc8fa9aa&groupid=38364
410 Ton Spar Rwd. CMbBa, NC 28214 Ph (704) 3993301 Fez (7N) 3948988

�71-7-7777
4t 1 774
I
,All
Wj tlili, t1l I f 49 fill/l.t! I J;j
r
I r-OWA
J(! —ft (,I
rij-,jIl! !)(171 O':f.-JICI
!r;i-fiq to iv v- I; 'at -1V71" 4,rfim-w Al
.,I[ at it lltiLln,
..ir', 'j. A Mt �10 4.
"I --rP e, jo), loil J;rlffl. (%I tillif ;f,:j -,fl: .1 1, ::%r f,
'i- 41 1A 41-j4o, &4
jt F, C't jfjblj,ff)a Jiffl-lq 'frivil urjiflfl., J1
.at i;
-1It.
" 7' !
_.Te 'L'epdj Sel 11 r.J ifrr T
fl
01 hrimd 'imt, !Y'<', .4 :)''is 1;)!, J.1, OT
qcv b-.am4 ',Uillk�Vf Ai

Ms. Dina Sprinkle
NC DWQ
October 16, 2012
Page 2
all 624/625 parameters can be deleted from the permit. Based on this guidance, the facility
requests that reporting for all 624/625 parameters be deleted from the permit.
The facility does not generate sludge and therefore not required to submit sludge
management plan.
If you have any questions upon receipt of this package, please contact me at [phone] or Mr.
Marco Zarate, Environmental Support Person for the terminal at [phone].
Sincerely,
/ P&v WXLS
Ken Watson
Complex Manager
cc: Motiva Terminal Superintendent
Raleigh Terminal Files
Marco Zarate, Terminal Environmental Support - URS Corporation
Attachment I — Application Form — Short Form C
Attachment H — Effluent Data Summary
Attachment III — Map of Facility and Surrounding Area
Attachment W — Diagram of the Wastewater Treatment System
Attachment V — Ethanol Storage Email Notification
Attachment VI - NPDES Permitting Requirements for Petroleum Bulk -Storage Surface Storage
Greater than One Million Gallons2005 — Permitting Strategy
410 Tan Saar ROK ChWWft. NC 28214 Ph": (/04) 399-1904 Fey (M) 384-GM

Attachment I
Application Form — Short Form C

NPDES PERNUT APPLICATION — SHORT FORM C — Minor Industrial
Minor industrial, manufacturing and commercial facilities.
Mail the complete application to:]
N. C. Department of Environment and Natural Resources
Division of Water Quality / NPDES Unit
1617 Mail Service Center, Raleigh, NC 27699-1617
NPDES Permit Number I NCO022217
Please print or type.
1. Contact Information:
Owner Name
Motiva Enterprises LLC
Facility Name
Motiva Enterprises LLC — Raleigh Terminal
Mailing Address
2232 Ten Ten Road
City
Apex
State / Zip Code
NC 27539-8115
Telephone Number
[phone]
Fax Number
[phone]
e-mail Address
[e-mail]
2. Location of facility producing discharge:
Check here if same as above ❑r
Street Address or State Road
City
State / Zip Code
County
3. Operator Information:
Name of the firm, consultant or other entity that operates the facility. (Note that this is not referring to the
Operator in Responsible Charge or ORC)
Name Motiva Enterprises LLC
Mailing Address 2232 Ten Ten Road
State / Zip Code NC 27539-8115
Telephone Number [phone]
Fax Number [phone]
4. Ownership Status:
Federal ❑ State 11 Private 0 Public
Page 1 of 5 C-MI 10/08

NPDES PERMIT APPLICATION — SHORT FORM C — Minor Industrial
Minor industrial, manufacturing and commercial facilities.
5. Standard Industrial Classification (SIC) code(s): 5171
6. Number of Employees:
Describe the treatment system List all installed waste treatment components with capacities, describe the
processes that generate wastewaters. If the space provided is not sufficient attach a separate sheet of
paper with the system description.
There are no wastewater treatment components for this facility. Only retention pond prior to discharge.
S. Is facility covered under federal effluent limitation guidelines?
If yes, specify the category?
No Q Yes
9. Principal product(s) produced: No products are produced — the facility is a terminal
that stores gasoline, petroleum distillates, and
ethanol
Principal raw material(s) consumed: Not Applicable (the values below are based on
throughput of the storage facility)
Briefly describe the manufacturing process(es):
The facility is a distribution terminal for gasoline and petroleum distillates. It does not produce,
manufacture, or consume products or raw materials. Gasoline and distillates are received via pipeline,
which are then stores in above ground storage tanks. Ethanol is received via tanker truck. All products are
loaded out via tanker truck through the terminal's loading rack.
Page 2 of 5 C•MI 10/08

NPDES PERMIT APPLICATION — SHORT FORM C — Minor Industrial
Minor industrial, manufacturing and commercial facilities.
10. Amount of principal product or raw material consumed
List specific amounts consumed and/or units ofproduct over the last three ears
Product or Raw Material
Consumed
(AVERAGE)
Product or Raw Material
Consumed
(PEAK)
per Day
536,000 gallons product distributed
607,500 gallons product distributed
per Month
16,100,000 gallons product distributed
18,220,000 gallon product distributed
per Year
192,500,000 gallons product distributed
194,200,000 gallons product distributed
11. Frequency of discharge: Continuous Intermittent
If intermittent:
Days per week discharge occurs: 7• Duration:
' Discharge is intermittent and is determined by local rainfall amounts
12. Type of wastewater discharged to surface waters only
24 Hours
Discharge
Flow
GALLONS PER DAY
Sanitary — monthly average
N/A
Utility water, etc. — monthly average
N/A
Process water — monthly average
N/A
Stormwater — monthly average
260.000 (amount dependent on rainfall
Other — monthly average
Explain:
N/A
Monthly Average
total discharge (all )
260,000 (amount dependent on rainfall
13. Number of separate discharge points: 1 Outfall Identification number(s) 001
14. Name of receiving stream(s) (Provide a map showing the exact location of each outjal/, including latitude and
longitude):
Unnamed tributary to Middle Creek within the Neuse River Basin. Latitude — 35' 42' 57'N, Longitude — 78' 48'
56"W (Refer to Attachment III).
Page 3 of 5 C•MI 10108

NPDES PERMIT APPLICATION - SHORT FORM C - Minor Industrial
Minor industrial, manufacturing and commercial facilities.
15. EBluent Data
Provide data for the parameters listed. Temperature and pH shall be grab samples. for all other parameters 24-hour composite
sampling shall be used. if more than one analysis is reported, report daily maximum and monthly average. If only one analysis is
reported. report as daily maximum.
Parameter Daily Monthly Units of
Maximum Average Measurement
* Biochemical Oxygen Demand (BOD5)
* Chemical Oxygen Demand (COD)
* Total Organic Carbon
Total Suspended Solids
* Ammonia as N
* Temperature (Summer) See Attachement 11.
* Temperature (Winter)
* pH
* Fecal Coliform (If sanitary waste is
resent)
* Total Residual Chlorine (if chlorine is
used)
* Not required to be monitored under current permit.
16. List all permits, construction approvals and/or applications (check all that apply and provide permit numbers or
check none if not applicable):
Type Permit Number Type Permit Number
Hazardous Waste (RCRA)
None
UIC (SDWA) WI0500057
NPDES NCO022217
PSD (CAA) None
Non -attainment program (CAA) None
NESHAPS (CAA) None
Ocean Dumping (MPRSA) None
Dredge or Fill (Section 404 or CWA) None
Other — Synthetic Minor Air Permit 0451OR13
17. List any chemicals that maybe discharged (Please list and explain source and potential source amounts.)
None in addition to compounds being analyzed.
Page 4 of 5 C-MI 10/08

NPDES PERMIT APPLICATION - SHORT FORM C - Minor Indtistrial
Minor industrial, manufacturing and commercial facilities.
18. Is this facility located on Indian country? (Check one)
Yes ❑ No O
19. Applicant Certification
I certify that I am familiar with the information contained in the application and that to the best of my knowledge and
belief such information is true, complete, and accurate.
Ken Watson Complex Manager
Printed Name of Person Signing Title
Signature of Applicant Date
North Carolina General Statute 143-215.6 (b) (2) provides that; Any person who knowingly makes any false statement representation,
or certification in any application, record, report, plan, or other document files or required to be maintained under Article 21 or
regulations of the Environmental Management Commission implementing the Article, or who falsifies, tampers with, or knowingly
renders inaccurate any recording or monitoring device or method required to be operated or maintained under Article 21 or regulations
of the Environmental Management Commission implementing that Article, shall be guilty of a misdemeanor punishable by a fine not
to exceed $25,000, or by imprisonment not to exceed six months, or by both. (18 U.S.C. Section 1001 provides a punishment by a
fine not more than $25,000 or imprisonment not more than 5 years, or both, for a similar offense.)
Page 5 of 5 C-MI 10/08

Attachment II
Effluent Data Summary

Table No. 1: Outlall 001 OMR Summery M1Sm Aug 2009 to Aug 2012
III EnImI LLC -Apu (IIGYMO Twlna
OutM MI
enruYM
ONb
Femil LImR
Flow
Y00
Teal
MmNIG
Flax
MO
Lb^Mv6
R
Few Me Lead
low wN IWyev
Mmtra Mawr•
RI Report
TU
wall
40
TeW
FlwyMme
all"
TeYI
Z..
nryL
TOIMF
M
M
oe0
nyt
N.0
TOW
.. ,
Iota.myL
NIMY
qu.
M.
YTp/
eel,
Mwn
III
To-
uyL
Varl Mnmr.
ayL
2
urL
4r NwNM.•
AMOI � QSI
Oap I T.
Peae.Jba
IMM �ap
Au.
T..fty
LCxSO%
VpNW
0.d]
122
<0.%
<B.ta
Ua
•50
O.+e
018
20I
n0
<t0
a -.nee
mJla
sr ee.m.a
rewrN
tO1R0W
0.128
03I3
Sale
-N.M
Zit
O12s
DAM
OSM
410.,1
OSe
HI.
150
am
101
QO10
<la
o100
VlF
NO ROW
FOR THIS
MOMIM
4 Dcv
0126
135
.05
720
200
.SO
I
021
1.0.Ia
<IO
<IO
41V30W
0.11
03
119
YtIMd
HO FLDW
OR IHISM
M1
0.
p250
I p
55
<0.%
p.5e
15 S
111.
0.%
O.V
Q 0.1
a
.+0
<t0
tlt](1W]
01%
0106
210
119
<005
261
B6
60
250
Ou
20<IO
.+0
<10
Sne a.,
rt.W
Sea mbwt
nw8.
alaa
MI
NOFLOWF 1 M
O taB 1 B.
6o
<OOS
ITo
as
4W
6M
751
<50<5O
.5.
.5.
Tw_,tt
L IS MONTH
t Vt6
1
0210
66
-<O:%
Ib
N
<50
1E0
O.II
QO<IO
<10
.10
1
02w
.11
lag
IM
lu
. o
Ise
01.
Qo<+0
.la
.10
lrznrzmo
o2+a
1rzs'Am
o25i
oae2
uv
120
-ON
]1.
N.
15.0
3A
..
120
<1.0
IT
110
See
rn.Wf
Bw.pndvE
rmlta
Ltd
IlOol
NO GLOW
FOR THIS
MCN]X
2l&XXO
OZ52
18
<OM
].0
as
15.0
3.60
0
<20<10
.10
<10
3 10
Oda OSID +a-
41(Ata
NO FLOW GOR TXIS MQV+N
Nt Q(HO
NO FLOW FOR THIS MOMH
b2l01a
Me
oTb
]]5
ba
.0d
a95
13
.50
1.19
ON
< 0
.10
.10
.10
1/132p1a
O.Id
T.O
.ap
1.9
04
.,a
.+a
.10
.10
See Me:IN
reulln
Sen.Orlis]
rneulY
lrzerz0lo
O.+BBe
a.]05
Sae
5'ts^A10
02a+
a0MN1D
o.2M
0515
]M
]s
<005
o3e
an
au
0.
0].
<30
<I1
nn
<la
vIFA10
NO FLOW
FOR TH19
10 V1010
01xi
IM V10+o
0na O35 a.n
125
<am
I.a
9s
.sa
I F
<00s
.1a
<la
<10
00
110
1111=10
Xa now FOR TMS MONTH
12=1010
NO FLOW FOR THIS MONTH
O08
'HMMI
NOR -OW FORTHIS
2QIf101a
Old 010 1D
a.
205
as,
32
.50
0%
0d
<20
<ta
q0
.1.
1,S
See alle[I'eC
rFetle
See eaCpE
mulls
Iiaa
WIMII
NO FLOW FOR TXIS LCNIX
MN "
0262 0152o O
.IO
ION
.O.IM
52
40
03e
0.1
1'.
<Oe
0 0
ID
qo
IltJ1I
O
XO FLOW P IHt4 MONa
VI Mll
NO FLOW FOR THIS M
]NVN+1
az+o
o]ip
iM
Iu
IT
4.20Ila
1 5menp+f
0
0n
Qo
<I,
See Y1c I1M
rtfJl.
See mwllo]
rnWY
me
ad
14
TOO
.sa
2"
ou
20
"a
a
.1.
1,L
5<JM10+f
ode
OJ
WIM11
L
I$
N IH
1W 14m1
NOFLDW FOR M15 MONTH
11I 11
I1.iM OIM
<50
<0%
S4
U
<50
6.TO
0%
120
.+0
410
1,
.10
V/IFMII
NO FLOW GOR
1AN2012
"TO
<S0
1005
112
25
1$0
1211
0115
120
110
<10
.10
IT
See ellclml
r®Ib
See SKI
reylln
.100
1p1FM4
0]M
0a50
5Td
3 wow
a+ID
60
.OM
<0.4
1LII
.6.D
<OM
Ob
QO
<10
aTo
.IO
.10
.&I
0-'
aIM
<0M]
YIFM+2
- Ne
1 0
.pw
m.1e
tSo
.50
.0.
ozo
120
<10
.10
n0
.la
0 U
OTM
VY 12
OTM
YVM12
0. M
YYNI
0
]s0T0
Q.1
VIM12
FLGN
fOP THIS
MpITXHEM
YI/Ml
NO LOH FOR INIS MCII M

TaBla No. I Ou0a11001 DMR Summary Rom Aug 1000 to Aug M10
MI EnaTnaes LLC �APee BW VON) T*minaI
Cajoall MI
PmmIW
I.MIn
Flan
MOO
Tall
Monthly
Flow
M0
.'.a
TWIN nLead
MlmnnlN o".
uwIa 6 MonIlma
T99
moL
ToYI
Phoephoru
M9
"La
pIMMI
mplL
TUNleuy
Nill
060
m,L
Y.0
Tnnl
NlLZI,
n, l
In.
plug
Nlbed
My
MTBE
ugL
Bxulm
YBIL
Toluww
u9IL
ENyl Bann.
UA
%pnn
noR
"a"NIulnle(
apd Im.d tlQ91
Y9M1
.1.11 T.
PugNpW
M.. WI
u91L
My4
Totl[I1y
'I
11
WIMI
NOFLOWFMTHII
]II Ia
O. MB'1
1
o.al
. o
mm
a o
>_a
use
aaa
o
< o
<1.0
<Lo
a.
ao
$ee otls!pE
eaWip
$ea e1W,
�wNs
1
A
:oa -:.
m1
ssl
.�;tl�
aN
t.e
.BT
o9
o-0
Mnknum
a.lom
aaPM
p.l
e.00
<.m
<aa
a
.1
<v
Nw
at.00
V.
<O.a
atap
,too
Imum a. soo
nsmg
aspau
o.
n.op
<o.es
uo
aBm
laeo
tm
42110.21
q.0
1 <a.
<s.o
1a01,mp
ry,luow celb Inalun a type on W oMfl. TNe coenct value wu enYM Inb NII WN w IMw Nuu MII na mtich Nuupml...., AMR.
ee mM In aelw In. dat.lon Ilmll In eru.. as d.lrz tM JeM1alun IWK le U. when -.,In, rl uoe.

Microbac Laboratories, Inc.
Page I of ✓en 2MP
FAYETTEVILLE DIVISION
2592 HOPE MILLS ROAD
STATE CERT ID.
FAYETTEVILLE,NC 28306
NC#II
[phone] FAX [phone]
NC 037714
R. W. SANDERS, VICE PRESIDENT
USDA #3787
http://w .n3icmbac.com E-Mail: mmdcn a( nicmba .com
WATER - AIR WASTES - FOOD
- PHARMACEUTICALS
NUTRACEUTICALS
CERTIFICATE OF ANALYSIS
Motiva Enterprise
Date Reported:
V31/2009
Mr. Scott Dilling
Date Received:
0/2009
2232 Tcn-Tcn Road
Order. Nwnbcr.
0901-00275
Apex, NC 27502
Imroice Na :
63006
Customer#.
S003
Sample Date:
in2009
Permit No. NC0022217
Sample Time:
9:00
Sampler: Scott
Subject Outfall sample - Monthly/Yrly
SMP Test
Method
Rn tt
Date
Time
Teeb
GALLONS DISotARGED
147"
I/7/2m9
9.00
LLT
LIBRARY SEARCH-625
EPA 623
SEE COMMENTS
1/31/2009
17:DO
011
METHYL-T-BUTYL ErHER
EPA 624
<0.DDW pp.
1/16/2009
12:01
011
NITROGEN, NITRATE
SM 4500 NW E
0.16 m /L
I/7/2009
9:00
ENC
NITROGEN, NITRITE
SM 45DO NO2 8
0.02 mg/L
11712009
15:00
ENC
NITROGEN, TOTAL K)EIDAML
SM 45M N (M) C
10.14 mg/L
1/16/1009
8:30
KAK
OIL 8 GREASE (HEM)
EPA 1664 A
<5.DO mgA
1/0/1D09
10:30
RAS
PHOSPHORUS, TOTAL
SM 4500 P E
<0.05 mg/L
1/8/2Dp9
9:30
OCR
SEMI YOtATILES
EPA 625
1/15/2009
17:28
CHI
1,2,4TRICE ORO�E
EPA 625
<0.0 mg/L
I115/2009
1728
CHI
1,2-0ICHLOROSENZENE
EPA 625
<0.0094 mg
2/15/2t109
17:28
CHI
1,2-DIPHENYLHYDRVINE
EPA 625
<0.0094 VA
2/15/2009
I7:28
01I
1,3-DICHLOROBENZENE
EPA 625
<O. 0 ag/L
1/15/2009
17:28
CHI
1,4DIQLLOR08ENZENE
EPA 625
<O.D094m A
1/15/2009
17:28
CHI
2,4-DINLTROTOLUENE
EPA 625
<0.009/ng/L
1/15/2009
17:28
CHI
ZE DINITROTOLUENE
EPA 625
<0.0094 mg/L
1/15/2009
17:28
CHI
2-CHLORONAPHTHAIENE
EPA 625
<O.D094 rtg/L
1/I5/2009
17:28
Oil
3,3-DICHLOROBE14ZIDINE
EPA 625
<0 W0 ,/L
I/IS/1009
1728
CHI
4-BROMOPHef(l PIFNYI ETHER
EPA 625
<0.OD94 mg/L
1/15/2(309
17:28
CNI
4CHLOROPHENYL PHENYL ETHER
EPA 625
-0.0094 mg)L
IAS/2009
1728
CHI
ACEIAPTTHENE
EPA 625
<0.0094 mg)L
1/15/2009
17:29
CHI
ACENAPHTMENE
EPA 625
<0.0094 myL
1/15/2OD9
17:28
CHI
ANTHRACENE
EPA 625
<0.0094 m9/1.
1/15/2009
17:28
CH[
BENZIDBNE
EPA 625
<O.D47 m9/1.
1/15/2009
17:28
CHI
BEN70(aydfTHIACENE
EPA 625
<O.DD94 mg/L
1/1512009
17:28
ONI
8ENZO(a)PYREI4E
EPA 625
<D.0094 rn9/L
1/15/2009
17:28
Ott
LAB CODES. N.O-N. Detnied lY-None F.w <- Ln.-Lbm >^Orwmr d. Eer- Enimgnl
n.. a.u..a m.. tir...w. m.a..m tee., ..e ..®^Y^I^9ew.<,s.�Q,. u,Y e.e..rnKq •.�F�•.+a �.s,�,rti
roleea
m.tro�uvea.nme.��-�Ms�e.nro..mv�ti.n Qaue wm>s.esw<.nm,mw.a lnm e. sm.m�r.
umA4na3Ro5«imq ro.d s,�emn m..,,e,N c �v:.�+r.cctrmed a�..be .•e icm.,C

F 9 W° R y d
4 'Qn m zQ�
9 SRo �ii8.�
8 N }( O N
� 6 8
H
z�d+�
0
a
i

N icrobac Laboratories, Inc. Page 3 of
FAYETIEVILLE DIVISION
STATE.CERT ID.
2592 HOPE MILLS ROAD
FAYETTEVILLE,NC 28306
NC#11
[phone] FAX [phone]
NC #37714
R. W. SANDERS, VICE PRESIDENT .
USDA #3787
http://w micmbac.com UM&A nmden@mi=bac.com
WATER • AIR • WASTES - FOOD • PHARMACEUTICALS • NUTRACEUTICALS
CERTIFICATE OF ANALYSIS
Motiva Enrerlaix
Date Reported:
1/31/2009
Mc ScottDilling
Date Received:
1/7/2009
2232 Te Ten Road
Older Number.
0901-00275
Apex, NC 27502
InvoiceNo.:
63006
'
Customer#:
S003
Sample Date:
1///2009
Permit No. NC0022217
Sample Time:
9:00
Sampler. Scott
Subject Outfall sample - Monthly/Ydy
Ship
Ted
Method
Raul/
Date
Time
Tech
YCDE
EOlueetr firab
:-
....:60nOn110d'n .. ,✓1
_ _#si
-
TAIRM
N-Nr1AOSODI-N4ROVM1A14[NE
EPA 625
<O.OD94 m0/L
illw2 09
1726
CHI
N-NnROSODIR811RINWE
EPA 625
<0.0094 np,11.
I/15/2009
17:20
all
PHENANTHRENE
EPA 625
<0.009/ap/L
1/15/2009
17:28
Oil
PYRENE
EPA 62S
<0809/ng/L
I/1wnw
1720
Oil
2,3,4,6-TETRACHLOROPHENOL
E➢A625
-0.0094 ng/L
1/15/2009
17A0
CHI
2,4,5-iNIORDROPHENOL
EPA 625
<0.0094 Ra1/L
1/15/2009
17:28
CHI
2,4,6-TRIOROROPHEROL
EPA 625
<om%Rg/L
1/15j2009
17:28
CHI
2,4-DIOitOROPHENOL
EPA 625
<0.1094 RKA
1/15/2009
17:20
CHI
2,4-DIHEnmP1610L
EPA 625
<0.0094 mg/L
IIIV2009
17:20
all
2,4-DINnR0HffN0L
ETA 625
<0.047 oVA
1/15nm
17:28
OH
2,6DKHLOROPHENOL
EPA 625
<0.0094 ny/l
i/IWOD9
17:28
OO
2-CHLOROPMENOL
ETA 625
<0.0094 RVA
1/15am
17:28
CHI
241EIHYIRB/OL
EPA 625
<0.0094 Ry/L
1/15/N109
17:28
CHI
3/4METHYLPHENOL
EPA 625
<0.0094 Rg/L
1/IS/2009
17:28
CHI
2-NNROPHENN.
ETA 625
<0.0094 nqA
1/15/2009
17.28
Oil
4,6DINITRO-2-ME HnPHEN0L
EPA 625
<0.047 maX
1/15/2009
17:20
Obi
4-CHLORO-3-PETTIYIPHENOL
EPA 62S
<0.019 mg/L
1/I5/2009
17:28
Oil
4-NrTROPHENOL
EPA as
<0.047 nl%&
I/IS/2009
1720
Oil
DINOSES
EPA 625
<O.0094 mg/L
1115/20M
17:28
oil
oCKESOL
ETA62S
<OOM mg/L
1/35/2009
17:28
Oil
p,mCRESOL
EPA625
<O.0094 Rg/L
1/15/20W
1728
Oil
PENTACHLOROPHENOL
EPA 625
<0.047 ffVA
I/IwM
1728
Oil
PHENOL
EPA 625
<0.0094 Rg1L
1/15/2009
17:20
CHI
SOLIDS, TOTAL SUSPENDED
SM 2540 D
12.2 m9/L
Irr2009
13:15
HAR
TURBmrrY
SH 21" 8
24.8 Rm
1/7/2009
12:55
HAE
LAB CODESNA) -None Da od N/F-None Found <-r tbm >-Omemaue Ex -Pe -d d
Tr anw+be6.ewaawd.ea as w,e��ne�ng mnw.rwsnW n...rti•)o.�i.�d��rw.�x.
roam
n,ae. ew e � isrr Tr..+r.►.tiaRad,.�uuo..pe ev^.u.r..rm.ep..a6.�er arRroR.
1®.e4PA1aaSNTI�q FedriAFnraeuW9 Cbrttletl MbeM1%kYdr+Me wY MasN

Q
�
a
a�
w
0 tCo 4 N P W
t�!
reo z�5
E
a v1
'gg�
.W.1�J OW
W
W
B
<
oa
a
}
��� � Fh asasasssssssssassasasssas ;
t Ill,d
8
i�caH
.y 8 o U toS B $ N N J e .. a e e N= C- a .. a e e e ---
� B
Oa� °rn ti > � >
Jn P � o 0 0 o v r 9v v v o N
q v v v v v v v v v v v v v ✓✓kk]] a E
U z
O �g
Q
e
e
8 LL' �rs �sBBa
~ a $.@
4
a a a a a a a a a c<
B B B B fi B B B 6
IR
�F"
� NFL
.. o o a g e
m d 0 0 SS y e s W 5 s a A
8

g o e g e p o o e o o'R e e a e p g eo e
,fY
yy V I C
do °U - > > - = > > > > ? : .. > ; > > °Y
EF�g
�K., oo�oo 000e _voo
�e
16 p a p
ii '�'j�Y I � V � � ryPry ryP ry< ry? P !P`� N N N n ryPry ry �PV ryP N � pG E d
F B B B B 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 aBq v a
r �
HT11'
w
S
i
SF b s P
y b b c E x x x
ti � px 7p $J o
VJ H U S N

N icrobac Laboratories, Inc.
Page bof6 -/W,7 zO c
FAYETTEVILLE DIVISION
2592 HOPE MILLS ROAD
STATE CERT m.
FAYETTEVILLE, NC 28306
NC Nll
[phone] FAX [phone]
NC #37714
R. W. SANDERS, VICE PRESIDENT,
USDA #3787
http://www.tnicrobaccom F-MaiLnmdcm@,niicmbac.com
WATER • AIR WASTES - FOOD • PHARMACEUTICALS - NUTRACEUTICALS
CERTIFICATE OF ANALYSIS
Modva Enterprise
Date Repotted:
1/31/2009
Mr. Scott Dining
Date Received:
1/7/2009
2232 TerrTen Road
Order Number:
0901-00275
Apex, NC 27502
Iwoice No.:
63006
Customer 9:
S003
Sample Date:
1/7/2009
Permit No. NCO022217
Sample Time:
9100
Sampler Scott
Subject Outfall sample - Monthly/Yrly
SNIP Test Method Reaalt Dete Time Tech
RESPECTFULLY SUBMITTED
MICROBAC LABORATORIES, INC.
ThmkYwjorYcrr bu.rouss. We urvire�owjeedba.* on our Irnl.f v,ver ro you. Pleaw mnrmr Vs Labarvtwy Dvenar, Am Swden at 91P864-19IO, RoMx Margw,
COO,mmargary7amrrabac.rom a T.eor Boyn, CEO. a rtboyce®mrnodac.c wgharycmmmworsuggeeaan
LAB CODES. NA) - Norm Da.at d N/F - None Fo.md <- Ia d , > - O.mm dim Ec - L.timmN
MEMBER
e.duo. mrt t�mMm ee rtwm,m woa>mwnro.a..mro>oe,s a.vm.wu.�ue.wA.n nom u.�m.mn.
tom. a.�rd+ro rood s.�:nmoco�.oao, cs.,aiw noouo�oct�i uwhe.,d a<d�

N icrobac Laboratories, Inc.
Pop I ors
JV� Ze y
FAYETTEVILLE DIVISION
S�
2592 HOPE MH.1S ROAD
STATE CERT ID.
'r FAYETTEVIIIZ NC 28306
NC NII
[phone] FAX [phone]
NC N37714
R. W. SANDERS, VICE PRESIDENT .
USDA k3787
http://wwwxaicrobu eom F Mml [e-mail]
WATER - AIR- WASTES • FOOD • PHARMACEUTICALS • NUMACEITRCALS
CERTIFICATE OF ANALYSIS
Motiva Enterprise
Date Repotted:
8H17aOD9
Mr. Scott Dilling
Date Received:
7/22/2009
2232 Tcn-Ten Road
Order Number.
0907-00365
Apex, NC 27502
Invoice No.:
67345
Customer ll:
S003
Sample Date:
7/22/2009
Permit No. NCO022217
Sample Time:
8:15
Sampler: Scott
Subject Outfall- Mtwscmi-Year/Ydy
SNIP Test
Method
Result
pate
Time
Tech
-
� aNaa t�8s
T
GALLONS DISCHARGED
105000
722/2OD9
8:15
CT
LIBRARY SEARCH -625
EPA 625
Seem
7/30/2009
22:35
CHI
METHYL T-BUM ETHER
EPA 624
<0.0020 m9/L
7/30/2009
22:35
CHI
NpROGEN, NITRATE
SM 4500 NO3 E
0.14 uVA
7/2.3/2009
8:30
ARS
NITROGEN, NITRITE
SM 4500 NO2 B
<0.02 u %A
7/242a09
8:30
AAS
NITROGEN, TOTAL KMDAHHL
SM 45W N (org) C
2.5 OgA.
7/272t109
8:50
TUA
OIL 6 GREASE (HEM)
EPA 1664 A
<5.Do m9A
8/42009
9:20
DU
PHOSPHDRUS, TOTAL
SM 450D P E
<0315 mg/L
7/302009
12:21
RAS
SEER VOLATRS
EPA 625
7/302009
2D:12
CHI
1,2,4TRICLMOBFA2ENE
EPA 625
<0D10 mg/L
720/2009
20:12
CHI
1,2-DICHLOROSENZENE
EPA 625
<0,040 mg/L
720/M
20:12
CHI
1,3-MCHLOROBENZENE
EPA 625
<0.010 mg/L
7/3O/2M9
20:12
CHI
1,4-DICHLOROBMZE NE
EPA625
<ODIO ag/L
7/30/ZW9
20:12
CHI
2,+DINMkOTOLUENE
EPA 625
<0.010 agA
720/2009
20:12
CHI
2,6-DINDROTOLUENE
EPA 625
0.010 ag/L
7/302OD9
20:12
CHI
2QLLORONAROIWENE
EPA625
<0.010 mg/L
7201M
20:12
CHI
3,3-DICLOROBENMINE
EPA 625
0.051 mgA
713WMN
20:12
CHI
4BROMOPHENYL PHENYL ETHER
EPA 625
<0.010 mg/L
7/30/2009
20;12
CHI
+CH1OROPH9YI PHENYL ETHER
EPA 625
<0.020 ng/L
7/30/2009
20:12
CHI
ACTNAMUHENE
EPA 625
<0.010 u.%/L
7/30/2009
20:12
CHI
ACU MiTHYLENE
EPA 625
<0.010 agA
7M2D09
20:12
CHI
ANTHRACE NE
EPA 625
<0.010 nwA
7/3012M
20:12
CHI
BENZO(a)WTHRACENE
EPA 625
<0.010 mg/L
7/302OD9
20:12
CHI
BENZO(a)PYRENE
EPA 625
<0A10 Rg/L
7/30/20D9
Mu
CHI
BE3NZO(b)RUORAMTHBIE
EPA 625
<O.OtOmg/L
7/302009
20:U2
CI
BENZO(gh)PERYIEIif
EPA 625
0.01D ma/L
7/302009
20:12
CHI
LAB CODES: NA)-N. Dadd NIF - Nape Fowl Ex-Fit®etcl
T„dm wk aawr iXu,�bn mnnnee u,ua.wwrmrv^1^emo,��n.romea adr tlm rnsbG).�.k>m.M.iatled 4�ae MEMBER
mdMn a.a�Ymtm 6e�md,md.bA um pRtrd,eaMooe�v wPe wNoi[wrYGn we.a.�M1em N.�m,.m,..
ussNacx®..mq woe s.:�.m�ca.w,a a°�i.e.mmm�n Mgew�,a

Microbac Laboratories, Inc.
Pap;z
'
FAYETTEVILLE DIVISION
2592 HOPE MILLS ROAD
STATE CERT m.
FAYETTEVILLE, NC 28306
NC #I1
[phone] FAX [phone]
NC 167714
R- W. SANDERS, VICE PRESIDENT
USDA 03787
htV://a .micmbac.com E-Mazl [e-mail]
CHEMISTRY - MICROBIOLOGY • FOOD SAFETY - CONSUMER PRODUCTS
WATER - AIR - WASTES•FOOD• PHARMACEUTICALS- NUTRACEUTICALS
CERTIFICATE OF ANALYSIS
Motiva Enterprise
Date Reported:
W17/2009
Mr. Scott Di fling
Date Received:
7/22/2009
2232 Ten-Tcu Road
Order. Nlmbcr.
0907-00365
Apex, NC 27502
Invoice No.:
67345
Customer#:
S003
Sample Date:
7/22/2009
Permit No. NCO022217
Sample Time:
8:15
Sampler. Scott
Subject Outfall- Mtl✓Semi-Year/Yrty
SMP Tat Method Revell Ate Time Te<h
BENZD(AuORANiNENE
EPA 625
<0.010 ng/L
7/30/2009
20:12
CHI
015(2-0RDROETHOXY)MEMANE
EPA 625
<0A10 mq/L
7/30/2009
20: 12
CHI
BL5(20ROR0E7NYLX7HM
EPA 625
<0.010 w-2A
7Mj2009
20. 12
QII
BLS(2UROROSOMOPYLIEMER
EPA 625
<0A10 mq/L
7/30/2009
20: 12
oil
05(2-ETI'fW0 YL),i1411ATE
EPA 625
<O.OIO m0/L
7/30/2 i
20:12
CMI
BUTYL BENZYL PKrHALATE
EPA 625
<0.010 a*&
7/N12009
20:12
DU
CHRYSENE
EPA 625
<0A10 mR/L
7TA12009
20: 12
CHI
DIBENZ(a,h)tNIHKACEIE
EPA 625
<0.010 mq/L
7/30/2DO9
20:12
CNI
DIETHYL RifIILLATE
EPA 625
<0.010 nVA
7/30/2p9
20:12
oil
DIMETHIL P/HHAlATE
EPA 625
<OA10 nVIL
7/3020D9
20: 12
CHI
DI-N-BUIYLPHTHNCl
EPA 625
<OAIO nVA
7/3W2009
20:12
On
DI-N-OCIYLMiHALATE
EPA 625
40.010 mq/L
7/3012009
20:12
Oil
FLUORARTHENE
EPA 625
<0.010 mq/L
7/30/2009
20:12
Q0
FLUOME
EPA 625
<0.010 mq/1.
7/30/2009
20:12
CHI
HEXAMOROBEENZBIE
EPA 625
<0.010 nq/L
7/30/2OD9
20AZ
CHI
HE04MROBUTADIB/E
EPA 625
<0.010 mq/L
7%30INN
20:12
CHI
MEXAOILDROETIWIE
EPA 625
<0.010 nVA
7/3012M
20A2
CHI
INOENO(L2,3c01'"lENE
EPA625
<0A10 ng/L
7/302009
20:12
M
ISOPHORONE
EPA 625
<0.010 MOA
7/30/2009
29:12
CHI
NAPIIINALENE
EPA 625
<0.010 nVA
7/302009
20:I2
CHI
NITROBENZENE
EPA 625
<0.010 mq/L
7/30/2009
20:12
all
N-NITROSODI--MPYU0101E
EPA 625
<0.010 m9A
7/30/2009
20:12
CHI
PHENARTIIRETIE
EPA 625
<0A10 ff*A
7/30/20°9
20:12
CHI
PYRENE
EPA 625
<0.010 mR/L
7/30/2009
20:12
CHI
2A9 TRIQ1LOROPH040L
EPA 625
<0.010 "A
7/30/2009
20: 12
CHI
2,4-DI00DRORff1401.
EPA 625
<0.010 np/L
7/302009
20:12
CHI
LAB CODES N/D-N. DNaled N/F=N.F.W
<-La.thm >=Ormtad.m
F -P .wd
rexam
mtlYn ae[ [ Y M b le,gM1Jml A1. Y N PR bYMilYiq a My purss.iM[ w@n q e.MM1em Ne YIMtN
15L9Ml�aTebp faW S.NuunlvsYr9 <.mYaI.N IYae6mpYy NW/vWRartA

a
y a 9
yI v
£ g42
s s a. §� a s���
e
eeeeeee sseve $
[333 8 e
0505� \ LL W •�r�l u �E
W W
ry ry ryry v� �!j ry pqo ep� ry eeVV ry IV N ry ��yy ryry 1V �
(••' `% ri b V V O � � V a V ^ ^ V �O V b N V b J b V �O C �p V V � 6
x
g• p�
0
0 $
• ��� 6 d �tE 3 X 0 8 � b S b b b b b o S` O 3 i
o gy
rr

a
U U E Q
y zz:�
O
G
moaz�5
Q
z
Q
u
66
u
$ ; k H L
ar B
� s"".a. "a.s��sa�s�ss8ss".s��sassa rtg
x ;seese�e�eeeseeseeseeIIv Iv
F�F
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0�
5 23 5

B
Microbac Laboratories, Inc.
Page 5of5
'
FAYETTEVILLE DIVISION
2592 HOPE MILLS ROAD
STATE CERT ID.
FAYETTEVILLE, NC 28306
NC#11
[phone] FAX [phone]
NC #37714
R. W. SANDERS, VICE PRESIDENT,
USDA #3787
http://ww Mkrobac.com E-Mal7: nmden@mic bac.com
CHEMISTRY • MICROBIOLOGY • FOOD SAFETY - CONSUMER PRODUCTS
WATER • AIR • WAKES • FOOD - PHARMACEUTICALS - NUTRACEUTTCALS
CERTIFICATE OF ANALYSIS
Motive Enterprise
Date Reported:
8/17/2009
Mr. Scort Dil6og
Date Received:
7/22/2009
2232 Tea -Ten Road
Order Number:
0907-00365
Apex, NC 27502
Invoice No.:
67345
Customer #:
S003
Permit No. NCO022217
Semple Date:
7/22/2009
Sample Time:
8:15
Sampler. Scott
Subject Outfall - Mth/Semi-Year/Ytiy
SNIP Teel a(Uiad Rewlt Irate Time Tab
TRiCHLOROMIENE
EPA 624
<0.0010 ppm
7/30/2009
22:35
Oil
TRIQaDRDRUORONETKANE
EPA 624
<0.0010 ppm
7/30/2009
22:3S
CHI
VUM. ACETATE
EPA 624
<0.0010 ppm
7/30/2009
223S
CHI
VINYL ORORIDE
EPA 624
<a0020 ppm
7/30/2009
22:35
QII
BIOASSAY, ACUFE, rATHD, lC50
>100 %
7/23r2M
11:00
ETS
C.OMMEPM
VOA LAMY did not dete ed a parana m qna flan 50 n 11-
SVOA tlb ty did oat detected a" pararne m 9t r than SO "/L
RESPECTFULLY SUBMITTED: �IJCe� We &"FI6
MICROBAC LABORATORIES, INC.
77u,.t/aajor,ow dumm R'e urvi4loriaed6ad on ovr4xf gYsmae m)'ou PfsatecWaY fh lado^'�')Dosetw,Ron,SmNerrm9!?abY-1920, Roden Mogan,
COO, 7Yawr ft.. CPO, m fdo3<a�.. •vh arry emvnsw mwggernTe
LA MDES-. NiD-Nom Detected N,F-Noce Fo,md <-I< ,h. Onaterthnn Fit -&=wed
Mb,aW°ner Yif°im,m�mNMmeR,M Wv�anP^I�'�Vhar�.4,,R ns,t IN uiTal�)MYjW W�.m1eM,W tle alplala
mWWe tlettYre[b!e'4m�d+M1„4 uMMbMaN^J votiv NWantleie..tan�opwdfmm a„Yb,wn.
IHA9AlOVaIITMq iqy Sriptiu, Cdvutlrq (lprbl pi 1p�°IILgYy M,lta 14�rtA

® Microbac Laboratories, Inc.
Page l of �/spe Z,Ir
FAYETTEVUJ,E DMSION
2592 HOPE MILLS ROAD
STATE CERT m.
FAYETTEVILLE, NC 28306
NC#II
[phone] FAX (910) 8%8774
NC #37714
R. W. SANDERS, VICE PRESIDENT.
USDA #3797
http://a xaicrobac.com E-Mail: ms [e-mail]
miembac.com
W � S • W SWBS F OODY PHARMACE 1�TICALS • MfIRACEUTICALS
I
CERTIFICATE OF ANALYSIS
Motiva Enterprise
Date Reported:
2/10/2010
Mr. Scott Dilfiog
Date Received:
V25/2010
2232 Ten -Ten Road
Order. Number.
1DOI-00742
Apm NC 27502
Invoice No.:
71297
Customer#:
S003
Sample Date:
1/25/2010
Permit No. NCO022217
Sample Time:
9:15
Sampler. Scott
Subject Outfall- Momhiy/Semi/Yearly
SMP Tat
Method
Reap
Hate
Time
Tech
�fGrad
T ,� ..
BIOASSAY, ACUTE, MM Uf50
>100 %
I/26/2010
0:00
ETS
GALLONS DISORARGED
241,5DO
1/25/2mO
0:15
RDM
LIBRARY SEARCH - 625
EPA 625
See Ca/maat
2/3/2010
0:00
CHI
METHYL-T-BUTYL ETHER
EPA 624
<0.0020 MIA
2/3fMIO
IS:39
CM
NITROGEN, NITRATE
EPA 300.0
0.50 nex
1/2W2010
9:18
DCR
NITROGEN, NITRAE
EPA 3WO
<0.15 ng1L
V2WMIO
91.18
DCR
NITROGEN, TOTAL KJELDA HL
SM 4500 N (am) C
3.1 flax
2/8/MIO
a.-V
TDA
OIL 6 GREASE (IBA)
EPA 1664 A
<5.00 ng/L
2/2/2010
9:45
DCR
MDSPHORUS, TOTAL
SM 45M P F
<O.05 m8/L
1/29/2010
15:10
TDA
SEMI VOLATILE
EPA625
2/!/1010
11:07
CHI
1,2,7_TRICNLOROBM"E
EPA 625
<0.010 me/L
2/2/ID10
11:07
QN
1,2-0101LOROBEIC"E
®A 625
<0.010 "A
2WWIO
11.07
CHI
1,2-0IMHENTHIDRAZBHE ,
EPA 625
<0.010 *a
zalm10
11:07
CHI
1,3-0I0NLOROBEIMM
EPA 625
<0.010 U10A
2/7/2010
I1:07
CHI
1,4-0ICHLOROBBLENE
EPA 625
<0.010 mg/L
2/2/NI0
I1:07
CHI
2,4-0INrTROTOLUH/E
EPA 625
<0A10 not
212MIO
11:07
CHI
Z6-DINrTROIDLUENE
EPA 625
<0.010 m8/L
2///2010
11:07
CHI
2-CHLORONAPHTRUM
EPA 625
<0.010 ng/L
2/2/2010
11:07
CHI
3,3-DICHLOROBENMV(E
EPA625
<0.051 ng/L
2/2/2010
11:07
CHI
48ROMOPHeM PfE//1'L ETHER
EPA 625
<0.010 m9/L
2RMIO
11:07
CHI
+CHLOROPHENT PHEWYL ETHER
EPA 625
<0.010 mg/L
ZW"t0
11:07
CHI
ACENARHDIENE
EPA 625
<0.010 m9/L
2/1/2010
11:07
CHI
ACENAPMTHYLHHE
BA 625
<0.010 m9/L
7/ MIO
11.07
CHI
ANIHRACENE
EPA625
<0.010 ng/L
2R1010
11.07
oil
BENZIDBIE
EPA 625
<0A51 ng/L
2/2MIO
11:07
CHI
BMzO(ayxrHRA 111E
EPA 625
<O.Olo ng/L
2/2/2010
11:07
CHI
LAB CODES: NO-Nwe D.L.W N/F-None Fwed <-Lee O® >-Gnewd.. FaL=Fx®eled
llwm Nalr lJs„MbemYYeem atrm.,®,e.ew,o eovnee4 �ee4 tlemipl,(Q enly.eeY mdsel�m,tle ���
mar,oeee,sre.,v.so,e.e.►��.a.eHr.a,w:s..e,. wr�..uwe.,s,.00-..+u..e. ee.,.r..
1�8141®i11Ra0 fmIL.WWnrMueA CTnbINeeWbbpblMtllm ae Atr,f

F
�
Q�� �
�
a``sss'ss'sS'ss's'ssss's'sss"Ss'aS's"s
°.Q U
L z
5 a
C°
rT
rT
rl r3
rT
rT
rZ
rT
N
Ed U
a p� z 5
�i
�y
a
o
q
e
w 9
e
d
2
e
d
e e
e q
o
o
e
o
0
a
o
N
q
3
e
e
o
o
0
e
o
0
3
e
0
o
0
E$
2
o
0
a
E
q
8
o 2
o 0
8
a
a
n
JS
W W
pp9 p 1 F
ITI
rn

® Microbac Laboratories, Inc.
Page of
FAYETTEVILLE DIVISION
2592 HOPE MILLS ROAD
STATE CERT ID.
FAYETTEVILLE, NC 28306
NC#11
[phone] FAX [phone]
NC 037714
R_ W. SANDERS, VICE PRESIDENT
USDA #3787
http://w .micmbac.com E-Mail: [e-mail]
WA7'ERS�AIYR WIACSRTES�OFLOOD PHARMACEUTITICAALLSN�R PRODUCTS
CERTIFICATE OF ANALYSIS
Motiva Enterprise
Dam Reported:
2/10/2010
Mr. Scott Dilling
Dam Received:
1/25/2010
2232 Ten -Ten Road
Ordcr. Number.
1001-00742
Apex, NC 27502
Invoice No.:
71297
Customer#:
S003
Permit No. NC0022217
Sample Dam:
1/2512010
Sampler: Scott
Sample Time:
8:15
Subject Outfall- Monthly/Semi/Yearly
SNIP Tat Method Result Date Time Tech
N-NtrROSODIMETH1IM101E
EPA 625
<0.010 ng/L
W2.12010
11:07
CHI
N-NrtRO5O0I N-PROPYIAMME
EPA 625
<0.010 mg/L
2/ZQ010
11:07
CHI
N-NFROSODIPMENri INE
EPA 625
<0.010 ng/L
2/212010
11:07
Q l
PNENANTHRENE
EPA 625
<0.010 mg/L
2MMI0
11:07
CH1
MEW
EPA625
<0.0I0 mg/L
2/2/2010
11:07
CHI
2,3,4,E-7ETRACHLOROPHENOL
EPA 625
<0.010 mg/L
2/2/2010
I1:07
CHI
2,4,5-TRICLLLOROPHENOL
EPA 625
<0.010 mgA
2/2/2010
11:07
M
2,4,64MCKGROPHENOL
EPA 625
<0.010 ngA
2j4?010
11:07
CHI
2,4DICHLOROFT"OL
EPA 625
<0,010 ngA
2(2/2010
I1:07
CHI
2,4DIMETHYLPHENOL
EPA 625
<0.010 mg/L
212JAI0
I1:07
CHI
2,4DLNITROMIENOL
EPA 625
<0.051 ng/I-
212/2010
11:07
C41
2,FDI0HLOROMIENOL
EPA 625
<0.010 VIL
2(2(2010
11:07
CHI
2-MOROPHENOL
EPA 625
<O.010 r,qA
21212010
11:07
CHI
2-MEMYLPHMOL
EPA 625
<0.010 ng/L
2/2/20t0
11:07
CHI
3/4MEMYLPMENOL
EPA 625
<0.0I0 nWL
2/2(2010
11:07
CHI
2-NI1FROPMENOL
EPA 625
<0.010 rna
2/42010
11:07
CHI
4,6bOINNRO-2-MEnolPHENOL
EPA 625
<0.051 rtg/l-
21WO10
11:07
all
4CHLORO 3-METHYLM¢NOL
EPA 625
<0.020 ngA
2/2(2010
11:07
CHI
4NITROM ENOL
EPA 625
<0.051 mg/L
2/2/2010
11:07
CHI
DMOSEB
EPA 625
<0.010 ng/L
2/2j2010
11:07
CHI
o-CRE50L
EPA 625
<0.010 ngA
2/212010
11:07
CHI
P,M-CRESOL
EPA 625
<0,010 ng/L
2(2(2010
11:07
oil
PENTACHLOROPHENOL
EPA 625
<a051 n,,A
2/2/2010
11:07
CHI
PHENOL
EPA 625
<0.010 mg/L
2(2/2010
11:07
CHI
SOLIDS, WEAL SUSPEND®
SM 2540 D
L2 ngA
1/27/2010
8:30
TDA
LAB CODES: NM-N. Daen.d N/F - None Fowd <=Lem U. I CG.erO Ft,=E,tin
mdtin tMa�Mbli nyM�avi.feh vinM bMe6N vdfuWLm .11u�<nr\an N9aJ M1am Ae Y'a-.sr,.
�.s�aauon rmy rme siarm ra.vmia cb+viue aeoao6ga a.wt�.m a-a.Fn

® Microbac Laboratories, Inc. Page of
FAYEITEVILLE DIVISION
2592 HOPE MILLS ROAD
STATE CERT ID.
FAYETTEVILLE, NC 28306
NC#11
[phone] FAX [phone]
NC #37714
R. W. SANDERS, VICE PRESIDENT.
USDA 43787
http://w .n2icrubac.com E-Nail: owders@mia bac.com
CHEMISTRY • MICROBIOLOGY, FOOD SAFM • CONSUMER PRODUCTS
WATER - AIR WASTES - FOOD - PHARMACEUTICALS - NUTRACEUTICALS
CERTIFICATE OF ANALYSIS
Motiva Enterprise Date Reported: 2/10/2010
Mr. ScottDilling Date Received: 1/23/2010
2232 Ten -Ten Road Order Number: 1001-00742
Apes, NC 27502 Invoice No.: 71297
Customer #: S003
Sample Date: 1/25/2010
Permit No. NCOM217 Sample Time: 8:15
Sampler: Scott
Subject Outfall - Monthly/Semi/Yearly
SMP Test Mehod Result late Time Tech
.. ,. ..... ':..z`Ei L.. <..rt_". �,T .-'- - ='� • vdsf.1��:�`-v"�" _ :_� v.y�z..�w°..^:.:. Y i.:1ru-t�+Ki
TURBIDITY
SM 2130 B
29.4 rb
11252010
15:10
TDA
VOUTRES
EPA 624
2/320IO
15:39
CNI
1,1,1-TRI040ROETHANE
EPA 624
<0.0010 mg/L
2/3/2010
1539
(HI
43,2.2-TRKMOROETHNIE
EPA 624
<0.0010 mg/L
2132010
15:39
01l
1,1,2-71I010ROETHANE
EPA 624
<O.D010 og
2132010
15:39
01I
1,1-01041.0R0ETHANE
EPA 624
<0.0010 mg/L
2/3/2010
15:39
Oil
IJ-DI0ILOROETHENE
EPA 624
10.D010 mill
2j32010
15:39
Oil
1,2-DICHLOROBEN2ENE
EPA 624
<0.0020 NIL
2/31201D
15:39
Oil
1,2-0ICHLORt7t1HANE
EPA 624
<0.0010 rng/L
2DI2010
15:39
Oil
1,2 DI0ILOROPROPANE
EPA 624
<0.0010 mill
2132DIO
15:39
CHI
1,3-DIOII-MBENZENE
EPA 624
<0.0020 mgA
2/3/2010
15:39
CHI
1,4DI(HLOROBENZENE
EPA 624
<0.0020 MPA
2/3/2010
15:39
CHI
2LHLOROETHYL VOM ETHER
EPA 624
<0.0020 mg/L
202010
15:39
0U
2-0 LOROTOLUENE
EPA 624
<0.0010 mg/L
2/32010
15:39
CHI
2 HDMON£
EPA 624
<0.0050 mg/L
2132010
15:39
CHI
ArADLEIN
EPA 624
<0.010 mg/L
2/32010
15:39
CHI
ACETONE
EPA 624
0.026 mg/L
2/32010
15:39
011
ACRYLONITRILE
EPA 624
0.010 milt
2/32010
15:39
Oil
BENZENE
LPA 624
<0.0010 ,It
213MID
15:39
CHI
BROMODICHLOROMETHANE
EPA 624
<O.DOlo mill
2132010
15:39
CHI
BROMOM"
EPA 624
<0.0010 m9/L
2/3/2010
15:39
Clll
BROMOMETHME
EPA 624
<0.0020 mg/L
2/32010
15:39
nil
CARBON DISULFIDE
EPA 624
<0.0020 mg/t
2/3/2010
15:39
CHI
CARBON TETRACHLORIDE
EPA 629
<0.0010 mVL
Z/3/2010
15:39
CHI
01LOROBENZENE
EPA 624
<0.0010 mg/L
2132010
15_39
CHI
LAB CODES'. NO -Nora Detected N/F - Novo Found <- L®.0� > - G[aler stun E.e = E.timeted
mtllallv..im.mb Reba-MrluNYrtfa`heMn9 mee�P^im ntiv..ARn .VPerY lmm ee Yb,.m.1.
1®�{P.JaLYilI TeLq Fwi 5u8.Wr,Co.utl,9 CM,.vlod lltoAWvl.4uMe+vtlR�a

e
F r
o U r �
r
a
Q zz�
H
y� µ2
cc X o 4
O [9� oppp
0
u
e
e�vq�z�5
a�d�dwoa
co5W5�Q
Oy x
h'7ti'i
J
m
M-
a
-
-
i
UU
O
ax
`-p, ={�aa'• � o � �
$
F,
��Rr�M �,°
o0
CCU
LCc�
C��+J
0
CC�++
CC�n+
n�"
[�c+'
oaeo0
CCU
oCr�
CQI�
CC+
eQl�
0oao0000
CCU
(C+
Cg+
LC�
CCU
tPlc+'
cC�
CCU
n,U
�x
U5
a
9
2
B
e
IL
8
L
Cr7QQ
�
jvF° v F �
5
7
t
p@ @g9
a
w
Ci
a
U
E
4'ac. °�
T
�
v
u:
&
o z
V
o
b
b
2-3
F
b
o
g
b
z
a�
o
o
s
w
w
ri
m
e
5
4 N
�y
n
ryO<

® Microbac Laboratories, Inc. Page 6 of 6 ✓an 2 Q/G
FAYETTEVILLE DMSION
2592 HOPE MILLS ROAD
STATE CERT ID.
FAYETTEVILLE,NC 28306
NC 0"
[phone] FAX [phone]
NC d37714
R. W. SANDERS, VICE PRESIDENT.
USDA #3787
htip://w xaicmbac.com E-Mail: [e-mail]
CERTIFICATE OFANALYSIS
Motiva Enterprise
Date Reported:
2/10/2010
Mr. Scott Dilling
Date Received:
1/25/2010
2232 Tern -Ten Road
Order Number:
1001-00742
Apex, NC 27502
Invoice No.:
71297
Customer M:
S003
Sample Date:
1/25/2010
PermitNo. NCO022217
Sample Time:
8:15
Sampler Scott
Subject Outfali- Monthly/Semi/Yearly
SHIP Tot Method Roult Date Time Tab
TSS QC recoverywas rlb%, dad b v ild batqunl8led. Turblday retntive perrnrrtdeviatlon was
greater than 5%. AN drbidby QC passed.
COMMENTS:
VOA library did not ded�bd any Paranabtn greater than 50 rry/L
SVOA library did net detected an, paralmten greater than 50 mp/L
RESPECTFULLY SUBMITTED: 12_ ►l miLax
MICROBAC LABORATORIES, INC.
1'hadywforywrbwinsu Ws imve yowfrrdback on wrfswl llJsrvicemyw. Pi�aa swmcrrh l.abaremryDvecmr, Ran Smdenm9t0.d61-f930, Ruben Morgan,
COO. ar mrorgor{dynrcrobu.mn mTrswreayr., CEO, arrboyes(drninvbac.mn wiUany namrnb orxgvaom.
LABCODESN/D-Nw Der<eted N/F-Nooe Fmnd <-La. Nao >-Qrweerthan Ex-Fitvneted
m.am..nun.nN,�.r..m�n.�an...neme.ennwmM mo.Tv.�Kah u....sM(q.�bme.�e . �.e..e wm u. reran
mmvilMeemlbh� {,Awrr a•NM4NSNN volt r.�Voe.nwe.rrb�WM^�tl M1we Y.YbnCII
1®.6Ml.BEN TewO rml5vbtlbn fvrinl9 CImIM n' Yi9bIMW/vWnrad�

Ju/y ZO/O
Fayetteville Division
2592 Rope Mills Rd
8-B Wendy Court
F9ycnevrTle,NC28306
'Greembw% NC 27409
910.964.1920 Phone
33&956.9710 Phone
9109649774 Faz
336.9569711 Fats
Certificate of Analysis
Motive Enterprise
Mr. Scat Dilling P CO= GatGB sample-Mthly/Semt-Amend Dat<Rcpated AuguA 12, 2010
2232 Ten -Ten Road Date Received: Jdy n 2010
Apex NC, 27502 Sampled By. Soon Dining Date Sampled: Jdy l2, 2010
Outfall001, EtlIneot
1007301-01
' Analyze Result Unit Analysis Date rime Analyst Method Qualifi¢
1,1,1-Trichlomethane
<0.0010
mg/L
7/16110 22:26
JLN
EPA 624
1, 42,2-Teuachlorodhane
<0.0010
MA
7/1&10 22:26
JLN
EPA 624
1,1,2-Trichloroethana
<0.0010
mg/L
7/16110 22:26
J1.N
EPA 624
I,1-Dichloroadme
<0.0010
MA
7/16/10 2226
JLN
EPA 624
1,1-Dichloroethete
<0.0010
W.
7/16110 22:26
JLN
EPA 624
1,2-Dichlorobeoume
<0.0020
mg/L
7/16110 2226
JLN
EPA 624
1,2-Dichloroeth,
<0.0010
UWE
7/16/10 2226
JLN
EPA 624
1,2-Dichloropmpane
<0.0010
mg/L
7/16/10 22:26
JLN
EPA 624
1,3-Dichlorobemzeae
<0.0020
mg/L
7/16/10 22:26
JLN
EPA 624
1,4-Duhlorobeozene
<0.0020
mg/L
7/16/10 2226
JLN
EPA 624
2-Chloroethyl Vinyl Ether
<0.0020
mg/L
71161102226
JLN
EPA 624
2-Heznnone
<0.0050
mg/L
7116110 2226
JLN
EPA 624
Acetone
<0.0050
mg/L
7/16/10 2226
JLN
EPA 624
Benzene
<0.0010
MA
7/16/10 2226
JLN
EPA 624
Bromor ichlommedu me
<0.0010
mg/L
7116110 22:26
JLN
EPA 624
Bromoform
<0.0010
mg/L
7/16/10 2226
JLN
EPA 624
Bromomethane
<0.0020
111A
7/16/10 22:26
JLN
EPA 624
Carbon disulfide
<0.0020
mg/L
7116/10 22:26
JLN
EPA 624
Carbon Tetrachloride
<0.0010
mg/L
7/16✓10 2226
JLN
EPA 624
Chloroberzene
<0.0010
mg/L
7116110 22:26
JLN
EPA 624
Chloroethana
<0.0020
mg/L
7/16/10 2226
JLN
EPA 624
Chloroform
<0.0010
mg/L
7/16/10 22:26
JLN
EPA 624
Chloromethane
<0.0020
Ing/L
7/16/10 22:26
JLN
EPA 624
cis-1,2-Dichlometheae
<0.0010
mg/L
7/16110 2226
JLN
EPA 624
Dibromochlorometheue
<0.0010
mg/L
7/16/10 2226
JLN
EPA 624
State cerukaboraK Respmffi ly Submitted
NCDNR a11. e889
NCDOH 037714, a37796 �. a00h6
USDA #3787 LW.SwkmVP44mwgmgDuector
Tve You for Yew h kman. Wep.e./wr7a�dwmY,NdmMweR A®mamWYP/Ywgi¢A1�b,Lwlvtma/aa64HA.fsvabae.AdaeZr
pWe�vlevaz.nw b aasa!Rr. C2'm, u dwv,�Lpno6.cas Mn i,,r�ba�naiLL P sc 1 of 6

910.864.8774 Fax
336.856.9711 Fax
Certificate of Analysis
Motive Enterprise t
W. Scott Dilling Project: OaNah aampk-MtldJ/5em1-Aaaaai Date Repotled: Augmt 12, 2010
2232 Te Ten Road Date Rccc ved: h4y 12, 2010
Apex NC, 27502 Sampled By: Scon Dilling Date Samplcd July 12, 2010
Outfall 001, Effluent
1007301-01
Analyte
Rrn11t
Unit
Analysis Datelfime
Analyst
Method Qualifier
a++aM>m * IaooOec- O+ogotmd N>
Ethylbenzrne
<0.0010
mg/L.
7/16/10 22:26
JLN
EPA 624
Methylenc Chloride
<0.0020
mg/L
7/16/10 22:26
JLN
EPA 624
Methyl -ten -Butyl Ether
<0.0020
mg/L
7/16110 22:26
JLN
EPA 624
Tetrachloroethene
<0.0010
mg/L
7/16/10 22:26
JLN
EPA 624
Toluene
<0.0010
mg/L
7/16/10 22:26
JLN
EPA 624
tans-1,2-Dichlorocthme
<0.0010
mg/L
7/16/10 2226
JLN
EPA 624
trans-1,3-Dichloropropene
<0.0010
mg/L
7/16110 22:26
JLN
EPA 624
Tnchlormthene
<0.0010
mg/L
7/16110 22:26
JLN
EPA 624
Trichloro0uoromcthanc
<0.0010
mg/L
7/16/10 22:26
JLN
EPA 624
Vinyl acetate
<0.0010
mg/L
7/16/10 22:26
JLN
EPA 624
Vinyl chloride
<0.0020
mgl1.
7/16/10 22:26
JLN
EPA 624
1,2,4•Trichlombenzene
-:0.010
mg/L-
7/I6/10 22:47
CR
EPA 625
1,2-Dichlorobenune
<0.010
mg/L
7/16/10 22:47
CR
EPA 625
1,2-Dipbmylhydmdne
m.010
mg/L
7/16/10 22:47
CR
EPA 625
1,3-Dichlorobenzeoc
<0.010
mg/L
7/16110 22:47
CR
EPA 625
1,4-Dichlorobenzene
<0.010
mg/L
7/16/10 22:47
CR
EPA 625
2,2'cxybis(I-chloropmpane)
<0.010
mg/L.
7116/10 22:47
CR
EPA 625
2,4,5.Trichlorophenol
<0 010
mg/L
7/16/10 22:47
CR
EPA 625
2,4,6-Trichlorophenol
<0.010
mg/L
7/16110 22:47
CR
EPA 625
2,4-Dichlorophenol
<0.010
mg/L
7116/10 22:47
CR
EPA 625
2,4-Dimethylphmol
<0.010
mg/L.
7116/10 22:47
CR
EPA 625
2,4-Dinitrophenol
<0.052
mg/L
7/16/10 22:47
CR
EPA 625
2,4-Dinitrotoluene
<0.010
mg/L
7/16/10 22:47
CR
EPA 625
2,6-DicWorophenol
<0.010
mg/L.
7/16/10 22:47
CR
EPA 625
2,6-Dinitrotoluene
<0.010
mg/L
7/16110 22,47
CR
EPA 625
State Cenificabons:
Respectfully Submitted
NCDNR 911. 0693
.�a
w- AmmaNb
NCDOH MT714, #37795
LT.
USDA #3787
R W. S.&m VP/Memevy Di
T1uM tou lur tot>d6rt156. W. lr�Mn,wriadbr3 aw av fe el a�rarMpwa Plassr[a+wef tli M/La.agmB Db'v... Rw.Lmim a� 91686ti19r0..Ge.e, Nd �4.
Jm[v/�Dn�mdn�.rnm orTmw Bows CEO.
Ngc2 of6

Fayetteville Division
2592 Hope NUI.. Rd
S-B Wendy Corot
Fayetcevae, NC 29306
Cma..&., NC 27409
910.964.1920 Move
336.956.9710 Pbmc
910.964.9774 Fax
336.&569711 Fax
Certificate of Analysis
Motiva Fntaprm
Mr. Scott Dillmg Project Outtall mapte-M1hly/Semi-Annual Dade Rcponod: Aogaa 12,2010
2232 Te Ten Road Date Received: July 12, 2010
Apes NC, 27502 Sampled By Scup Dillmg Datc Sampled: Juty 12, 2010
Ootfall001. Effluent
1007301-01
Analyte Result Unit Analysis Datclrime Analyst Method Qualifia
2-ChlorooaphdWene
<0.010
mg/L
7/16110 22:47
CR
EPA 625
2-Chlomphmol
<0.010
1119/1-
7/16110 22:47
CR
EPA 625
2-Methyhlaphthalme
<0.010
mg/L
7/16110 22:47
CR
EPA 625
2-Methylphmol
m.010
mg/L
7/16/10 22:47
CR
EPA 625
2-Nitroenilme
<0.010
mg/L
7/16/10 22:47
CR
EPA 625
2-Nitrophenot
.0.010
mg/L
7/16/IO 22:47
CR
EPA 625
3,3'-lhchlombenzidine
<0.052
mg/1.
7/16/10 22:47
CR
EPA 625
3/4-Methylphmol
<0.010
mg/L
7/16/10 22:47
CR
EPA 625
3-Nitroaniline
<O.O10
mg/L
7116110 22:47
CR
EPA 625
4,6-1)initro-2-methylphenol
<0.026
mg/L
7/16/10 22:47
CR
EPA 625
4-Bromophmyl-phmylether
<0.010
mg/L
7/16/10 22:47
CR
EPA 625
4-Chlmo-3-methylphenol
<0.021
mg/L
7/16/10 22:47
CR
EPA 625
4-ChImomiline
<0.010
mg/L
7/16/10 22:47
CR
EPA 625
4-Chlorophmyl-phenyletha
m.010
mgl1.
7/16110 22:47
CR
EPA 625
4-Nitroanilme
<0.010
mg/L
7/16/10 22:47
CR
EPA 625
4-Nitrophenol
<0.052
mg/L
7116/10 22:47
CR
EPA 625
Acenaphthme
.00.010
1119/1.
7/16/10 22:47
CR
EPA 625
Accnaphthylene
<.010
mg/L
7/16/10 22.47
CR
EPA 625
Acetophenone
<0.010
mg/L
7/16110 22:47
CR
EPA 625
Aniline
<0.010
n4l
7/16/10 22:47
CR
EPA 625
Anthracene
-�I).010
mg/L
7/16/10 2247
CR
EPA 625
Benzidine
<0.052
m91L
7/16/10 22:47
CR
EPA 625
Beuzo (a) anthtacene
<0.010
roar
7116/10 22:47
CR
EPA 625
Benzo[alpyreue
<0.010
mg/L
7/16/10 22:47
CR
EPA 625
Benzo[b)fluoranthenc
<0.010
mg/L
7/16110 22:47
CR
EPA 625
state cerffeations Respectfully Submitted
NCONR #11, 0693
NCOOR 9K37714,#37796 W. w- ,tea
t DA a3797 R W. Smdas, VPN mm g INccta
Tlw�k you to )aeMssims W. hrrh�,nnJmdB�i mwrkW oJamM ro ,a Plm��mrefrti VPil/ gvq Dhaer,dm.Sawdmn9/ndM.1914-ra.v Note. /.eMaLm
fwdamrwmc a- n�, amK cro, er reo,.:@.nde.�..�.ru m,. ®e.o o.,.,aerroR
Page 3 of 6

FayetteviDe Division
2592 Hop. Nli is Rd
&B Wendy Court
Fayenenik, NC 28306
'Gtecashom, NC 27409
910.964.1920 Phone
336.856.9710 Phone
910.864.9774 Fax
336.956.9711 Fax
Certificate of Analysis
Motiva Entaptise
Mr. Scou Dillml; Project Oatfan"Osple-M"ISeml-Animal hart Repmtcd. Augmt12,2010
2232 Ten -Ten Road Date Rec hed: July 12, 2010
Apex NC, 27502 Sampled By: Scott Dilling Date Sampled July 12, 2010
Oatfatl 001, Effluent
1007301-01
tAnalyse Result Unit Analysis Date rune Analyst Method Qualifier
Benzo[g,h,i]perylme
<0.010
mg/L
7/16/10 22:47
CR
EPA 625
Benzo[k]Buotanthene
<0.010
mg/L
7/16110 22:47
CR
EPA 625
Bcnzoic Add
<0.010
mg/L-
7/16/10 22:47
CR
EPA 625
Bcnzyl alcohol
m.020
mg/L
7/16110 22:47
CR
EPA 625
beta-Chloronaphtbalene
<0.010
mg/L.
7/16/10 22:47
CR
EPA 625
bis(2-Chloroethoxy)mcthane
<0.010
mg/L
7/16110 22:47
CR
EPA 625
Bis(2-Chlomctbyl)ether
<0.010
mg/L
7/16110 22:47
CR
EPA 625
Bis(2-Ethylhexyl)phthaiatc
<0.010
mg/L
7116110 22:47
CR
EPA 625
Butylbenzylphihalate
<0.010
mg/L
7/16/10 22:47
CR
EPA 625
Carbazole
�4).OLO
mg/L
7/16/10 22:47
CR
EPA 625
Chrysene
<0010
mg/L
7/16/10 22:47
CR
EPA 625
Dibenz[a,h]anthracene
<0.010
mg/L
7/16/10 22:47
CR
EPA 625
Dibecaofit an
<0.010
mg/L-
7/16/10 22:47
CR
EPA 625
Diethylphthalate
<0.010
mg/L
7/16/10 22:47
CR
EPA 625
Dimethylphthalate
<0.010
mg/L
7/16/10 22:47
CR
EPA 625
Di-n-butylphthalate
<0.010
mg/L
7/16/10 22:47
CR
EPA 625
Di-n-octylphthalate
<0.010
mg/L.
7/16/10 22:47
CR
EPA 625
Fluoranthene
<0.010
tng/L
7/16/10 22:47
CR
EPA 625
Flucrene
<0.010
mg/L
7/16/10 22:47
CR
EPA 625
Hexachlotobenzene
<0.010
rng/L
7/16/10 22:47
CR
EPA 625
Hexachlorobumdiene
-CO.010
mg/L
7/16/10 22:47
CR
EPA 625
Hexachlorocyclopentadene
<0.010
mg/L-
7/16110 22:47
CR
EPA 625
Hexachloroethane
<0.010
mg/L
7/16/10 22:47
CR
EPA 625
ludeno[l,2,3-cd]pyrenc
<0.010
mg/L
7/16110 22:47
CR
EPA 625
Isophorone
<D.010
mg/L
7/I6/10 22:47
CR
EPA 625
State Certi6caoons: Respectfully Submitted
NCDNR
NCDOH #37714, 437795 AnAbQMb
USDA 93787 A W. Sanders, VP/Maoagmg Du
Thark YoubprGrser� Wr bMrawr/A/bortmur4wl a/ae.rr�royaa Plwev roman Ts VPiymyb,x [bay,xw.6,daa ae 91aa6r-I➢X1.Jao No6v. Fru6fmau
J^^k+ nnovWc.mn T. ae,.z UO, .
Poge 4 at 6

Fayetteville Division
2592 Hope Mills Rd
8-B Wendy Court
FayeOrnlle, NC 28306
'Cneenaborn, NC 27409
910.964.1920 Phone
336.856.9710 Phone
910.964.8774 Fax
336.856.9711 Fax
Certificate of Analysis
Motiva Eaterpriae
Mr. Scott Dillmg pmjtct: OaHausample-Mthly/SemtAwueal Dd1e RV-1ted, August 12,2010
2232 Te Ten Road Date Received: July 12, 2010
Apex NC, 27502 Sampled By: Scott Dilling Date Samplad: JWy 12, 2010
OutfeH 001, Effluent
1007301-01
Acolyte
Result
Unit
AOalysis Datell'ime
Analyst
Method Qualifies
kaNantW yRrmaz- nNt9on
m-Dichlombenzene
<0.010
mg/L
7/16/10 22:47
CR
EPA 625
Naphtbalme,
m.010
mg/L
7/16/10 22:47
CR
EPA 625
Nitrobenzene
<0.0I0
mg/L
7/16/10 22:47
CR
EPA 625
N-Nitrosod®ethylamine
m.010
mg/L
7/16110 22:47
CR
EPA 625
N-Nitmso-di-n-pmpylamme
<0.010
mg/L
7/16110 2247
CR
EPA 625
N-Nitmsodiphenylamine
m.010
mg/L
7/16110 22:47
CR
EPA 625
Prntachlotophenol
<0.052
mg/L
7/16110 22:47
CR
EPA 625
Phenanthrene
m.010
mg/L
7/I6110 22:47
CR
EPA 625
Phenol
m.010
mg/L
7/16110 22:47
CR
EPA 625
Pyreue
<0.010
mg/L
7/16/10 22:47
CR
EPA 625
Pyridine
<0.010
1118/1.
7/16/10 22:47
CR
EPA 625
k W,ed W Mbabs[ - FaRne&e gNrim
Flow Reading
105000
gaUday
7/12/10 13:15
RDM
Field
Total Kjeldahl Nitrogen
3.31
-a
7/15/10 13:30
AJF
SM 20th, 450ONC
Nitrate as N
0.180
mg/L
7/14/10 10:20
ENC
EPA 300.0
Nitrite as N
<0.0300
_ 1ng/L
7/14/10 10:20
ENC
EPA 300.0
Total Nitrogen
3.49
mg/L
7/15/10 13:30
AJF
Calculation
Oil & Grease (HEM)
<5.00
mg/L
7/19110 8:00
RAS
EPA 1664
Phosphorus, Total
<0.050
mg/L
727/10 14:56
ARS
SM 20th Ed. 4500 P F
Total Suspended Solids
22.0
mg/L
7119/10 15:10
AMM
SM 20th Ed, 2540 D H
Turbidity
21
NTU
7/12/10 16:00
TDA
SM 20th Ed. 2130 B
COMMEtaS:
VOA Ubary did not detected any parameters greater than SO mg/L
SVGA Library Sid not detected any parameters greater than 50 mg/L
Sate Cedi6raeons: Respectfully Submitted
NCONR #11. #693 NCDOH #37714,#37795 a ■
USDA #3767 R. W. Sender- W Managing Du
Tlurk Jeayw Wa.a Mb1,wNiiud♦•YZmar.P.coma. the YPilrmeaba Dh,rrer, RanSmdoa ae➢IOd61-I➢�4! Notq Av4Vmt a1
/"a��i4mvsoba¢.. a Tm Ames CEO ai H,h e,—e,ar�d—
Ps#c 5 of6

Zo/O
Fayetteville Division
2592 Rope Mills Rd
8-a Wendy Court
F.ycftcw l NC 29306
`Greensboro, NC 27409
910.964.1920 Phone
336.856.9710 Phone
910.864,8774 Fax
336.856.9711 Fax
Certificate of Analysis
Mod" FAterprise
Mr. Soon DiLLin Project: Out&H sampk - MtWr%emi-Amml Date Reported: Auguri 12, 2010
2232 ien-Tcn Road Datc Received: Juty 12, 2010
Apex NC, 27502 Sampled By Scon DWmg Date Sampled: July 12, 2010
Notes and Dvruddons
Anatyte was prepared and/or analyrnd outside of the analytical method holding time
SNte CeMf=bore: Respectfully Submitted
NCONR $11, 1M �p
NCDOH 837714, a37795 W . W . 80abdSv
USDA 93787 R- W. S.. m, VPM.Sui Duee
Thw*Y br tov Naha We aMv�feel6trt m o.r 1. ef,. .ropy Ptw mran rae WA qag �m lm rndea w gj"a /9)4 �N aPr.edae ur
pe[a�er4reacnmerS Bmv.CEO
Page 6 of6

F6 ao�i
Fayetteville Division
2592 Hope Mills Rd
Fayetteville, NC 28306
910.864,1920 Phone
910.864.8774 Fax
Certificate of Analysis
Motive Enterprise - Apex
Mr. Scott Dilling project: Outfall sample- Mt61y/SemiYr/Yrly Date Reported: March 21, 2011
2232 Ten -Ten Road Date Received: February 21, 2011
Apex NC, 27502 Sampled By: Scott Dilling Date Sampled: February 21, 2011
Outfall 001, Effluent
1102401-01
Analyte Result Unit Analysis Date/Time Analyst Method Qualifier
Bioassay - Acute
>100
%
2122/11
0:00
is
EPA-821-R-02-012
k*WW In: MIvaEM - rnicagalaM DMsan
I, 1, 1-Trichloroethane
<0.0010
mg/L
2124/11
18:11
BR
EPA 624
1, 1,2,2-Tetrachloroedwe
<0.0010
mg/L
2/24/11
18:11
BR
EPA 624
1, 1,2-Trichloroethane
<0.0010
mg/L
2/24/11
18:11
BR
EPA 624
l,l-Dichloroedwe
<0.0010
mg/L
2/24/11
18:11
BR
EPA 624
l,l-Dichloroethene
<0.0010
mg/L
224/I1
18:11
BR
EPA 624
1,2-Dichlorobenzene
<0.0020
mg/L
2/24/11
18:11
BR
EPA 624
1,2-Dichloroethane
<0.0010
mg/L
224/11
18:11
BR
EPA 624
1,2-Dichlompropane
<0.0010
mg/L
224/11
18:11
BR
EPA 624
1,3-Dichlorobenzene
<0.0020
mg/L
224/11
18:11
BR
EPA 624
1,4-Dichlombenzerte
<0.0020
mg/L
2/24/11
18:11
BR
EPA 624
2-Chloroethyl Vinyl Ether
<0.0020
mg/L
2/24/11
18:11
BR
EPA 624
2-Hexanone
<0.0050
mg/L
2/24/11
18:11
BR
EPA 624
Acetone
0.024
mg/L
2/24/11
18:11
BR
EPA 624
Benzene
<0.0010
mg/L
2/24/11
18:11
BR
EPA 624
Bromodichloromethane
<0.0010
mg/L
2/24111
18:11
BR
EPA 624
Bromoform
<0.0010
mg/L
2/24/I1
18:11
BR
EPA 624
Bromomethane
<0.0020
mg/L
2/24/11
18:11
BR
EPA 624
Carbon disulfide
<0.0020
mg/L
2/24/11
18:11
BR
EPA 624
Carbon Tetrachloride
<0.0010
mg/L
224/11
18:11
BR
EPA 624
Chlorobenzene
<0.0010
mg/L.
2/24/11
18:11
BR
EPA 624
Chlomethane
<0.0020
mg/L
2/24/11
18:11
BR
EPA 624
Chloroform
0.0038
mg/L
2/24/11
18:11
BR
EPA 624
Chloromethane
<0.0020
mg/L
2/24/11
18:11
BR
EPA 624
cis-1,2-Dichloroethene
<0.0010
mg/L
2/24/11
18:11
BR
EPA 624
State Cerfifiw8ons:
Respectfully Submitted
NCDNR #II
NCDOH #37714
USDA a3787
R. W. sanders, VP/Managing Director
Tha6ky fmycortwsinesa. M4 firNa voxr/eedaneYmorrr/ewf oJnrvre to con. Pleew mrnaa the VP Mvraairra Diwcrur, Non Fmlenarfl/aaG/-/fl10,./arnn Nohe; IM.rirknl.m
jrwkuu�.r:rmhaeuver ur Twrwtlorv, <'ED, ar Iboyxlv,nhrobx.awr
r.irh any wanmrevrmggrnionr.
Page I of6

Fayetteville Division
2592 Hope Mills Rd
Fayetteville, NC 28306
910.864.1920 Phone
910.864.8774 Fez
Certificate of Analysis
Motiva Enterprise - Apex
Mr. Scott Dilling Project: Outfall sample - Mthly/SemiYr/Yrly Date Reported: March 21, 2011
2232 Ten -Ten Road Date Received: February 21, 2011
Apex NC, 27502 Sampled By: Scott Dilling Date Sampled: February 21, 2011
Outfall 001, Effluent
1102401-01
L Analyte
Result
Unit
Analysis Date/Time
Analyst
Method Qualifier
awyml by: Mlva6ar- Ql agoam DF+Won
Dibromochloromethane
<0.0010
mg/L
2124/11
18:11
BR
EPA 624
Ethylbenzene
<0.0010
mg/L
2124/11
18:11
BR
EPA 624
Methylene Chloride
0.0025
mg/L
2/24/11
18:11
BR
EPA 624
Methyl-tert-Butyl Ether
<0.0020
mg/L
2/24111
18:11
BR
EPA 624
Tetrachloroethene
<0.0010
mg/L
2/24/11
18:11
BR
EPA 624
Toluene
<0.0010
mg/L
2/24/11
18:11
BR
EPA 624
Total Xylene
<0.0010
mg/L
2/24/11
18:11
BR
EPA 624
toms-1,2-Dichloroethene
<0.0010
mg/L
2/24/11
18:11
BR
EPA 624
trans-1,3-Dichloropmpene
<0.0010
mg/L
2/24/11
18:11
BR
EPA 624
Trlchlomethene
<0.0010
mg/L
2124/I1
18:11
BR
EPA 624
Trichlomfiuoromethane
<0.0010
mg/L
2/24/11
18:11
BR
EPA 624
Vinyl acetate
<0.0010
mg/L
2/24/11
18:11
BR
EPA 624
Vinyl chloride
<0.0020
mgjL
2/24/11
I8:11
BR
EPA 624
1,2,4-Trichlorobemmne
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
1,2-Dichlorobenzene
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
1,2-Diphenylhydrazine
<0.010
mg/L
225/11
14:31
CR
EPA 625
1,3-Dichlorobenzene
<0.010
mg/L
2125/11
14:31
CR
EPA 625
1,4-Dichlorobenzene
<0.010
mg/L
2/25111
14:31
CR
EPA 625
2,2'oxybis(1-chloropropane)
<0.010
mg/L
2125/11
I4:31
CR
EPA 625
2,4,5-Trichlomphenol
<0.010
mg/L
2125/11
14:31
CR
EPA 625
2,4,6-Trichlomphenol
<0.010
mg/L
2125111
14:31
CR
EPA 625
2,4-Dichlorophenol
<0.010
mg/L
2/25111
14:31
CR
EPA 625
2,4-Dimethylphenol
<0.010
mg/L
225/11
14:31
CR
EPA 625
2,4-Dinitrophenol
<0.052
mg/L
2125111
14:31
CR
EPA 625
2,4-Dinitrotoluene
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
State Certifications: Respectfully Submitted
NCDNR #11
NCOOH #37714 112. W- .8sWaef.Nab
USDA #3787 R W. Sanders, VP/Managing Director
Think you la your Wsirreea. l44 prWw wrrfirdhxkun onr legal oJrrr�n ro wn. Pleau simmer rhr MAfirvging Dire.ror, Ran Snmlrrs ar Yla-abr-Iv?O,.Imnva Nakey PrviJenr, ar
Jnaaesnp,icroMa.avm u. Tmw Ro,�ee. CEO, er rsvyeerLfrirmbrc....rhh mry emmnvnu u-rnRgrrrione. Page 2 of 6

Fayetteville Division
2592 Hope Mills Rd
Fayetteville, NC 28306
910.864.1920 Phone
910.864,8774 Fax
Certificate of Analysis
Motiva Enterprise - Apex
Mr. Scott Dill ing Project: Outfall sample - Mthly/SemiYr/Yrly Date Reported: March 21, 2011
2232 Ten -Ten Road Date Received: February 21, 2011
Apex NC, 27502 Sampled By Scott Dilling Date Sampled: February 21, 2011
Outfall 001, Effluent
1102401-01
Analyte Result Unit Analysis Date/Time Analyst Method Qualifier
2,6-Dichlorophenol
<0.010
mg/L
2/25/I1
14:31
CR
EPA 625
2,6-Dinitrotoluene
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
2-Chlomnaphthalene
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
2-Chlorophenol
<0.010
mg/L
2/25/I1
14:31
CR
EPA 625
2-Methylnaphthalene
<0.010
mg/L
2125/11
14:31
CR
EPA 625
2-Methylphenol
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
2-Nitroaniline
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
2-Nitrophenol
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
3,3'-Dichlorobenzidine
<0.052
mg/L
2/25/11
14:31
CR
EPA 625
3/4-Methylphenol
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
3-Nitroaniline
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
4,6-Dinitro-2-methylpherwl
<0.026
mg/L
2/25/11
14:31
CR
EPA 625
4-Bromophenyl-phenylether
<0.010
mg/L
2125/11
14:31
CR
EPA 625
4-Chloro-3-methylphenol
<0.021
mg/L
2/25/11
14:31
CR
EPA 625
4-Chloroaniline
<0.010
mg/L
2/25/I1
14:31
CR
EPA 625
4-Chlomphenyl-phenylether
<0.010
mgtL
2/25/I1
14:31
CR
EPA 625
4-Nitroaniline
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
4-Nitrophenol
<0.052
mg/L
2/25/11
14:31
CR
EPA 625
Acenaphthene
<0.010
mg/L
225/11
14:31
CR
EPA 625
Acenaphthylene
<0.010
mg/L
2/25/I1
14:31
CR
EPA 625
Acetophenone
<0.010
mg/L
225/11
14:31
CR
EPA 625
Aniline
<0.010
mg/L
225/11
14:3I
CR
EPA 625
Anthracene
<0.010
mg/L
2/25/I1
14:31
CR
EPA 625
Be tzidine
<0.052
mg/L
2/25/I1
14:31
CR
EPA 625
Benno (a) anthracene
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
State Certifications: Respectfully Submitted
NCDNR #11
NCDOH #37714
USDA #3787 R W. sanders, YP/Mmaging Dirtctor
Thank you for your Eutlnesa. sK invlx wnrkr✓aw:ew+our lvxl ofxrMur ro w,. Plmx camnu the VP Mamgmg Dlxwr,Ran.Fn✓rnw V/0A64IV1a, Jnmri Nohvr, Pxri✓ew, at
;vMen �icmboc.mm wTnrwBoxv.CEU, ar rdawndjrirrohvurvn wid wyruxxmnorruggvrtio,v.
Page 3 of

Fayetteville Division
2592 Hope Mills Rd
Fayetteville, NC 28306
910.864.1920 Phone
910.864.8774 Fax
Certificate of Analysis
Motiva Enterprise - Apex
Mr. Scoa Dilling Project: Oulfall sample- Mthly/SemiYr/Yrly Date Reported. March21,2011
2232 Ten -Ten Road Date Received: February 21, 2011
Apex NC, 27502 Sampled By: Scott Dilling Date Sampled: February 21, 2011
Outfall 001, Effluent
1102401-01
Analyte
Result
Unit
Analysis Date/Time
Analyst
Method Qualifier
MalyaM by: Mkrobac -gbgW pu"alon
Benzo[a]pyrene
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
Benzo[b]0uoranthene
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
Benzo[g,h,i]perylene
<0.010
mg(L
2/25/1 l
14:31
CR
EPA 625
Benzo[k1 luorenthene
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
Benzoic Acid
<0.010
mg/L
225/11
14:31
CR
EPA 625
Benzyl alcohol
<0.010
mg/L
2/25/I1
14:31
CR
EPA 625
beta-Chloronaphthalene
<0.010
mg/L
2/25/I1
14:31
CR
EPA 625
bis(2-Chloroethoxy)methane
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
Bis(2-Chloroethyl)ether
<0.010
mg(L
2/25/11
14:31
CR
EPA 625
Bis(2-Ethylhexyl)phthalate
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
Butylbenzylphthalate
<0.010
mg(L
2/25/11
14:31
CR
EPA 625
Carbazole
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
Chrysene
<0.010
mg/L
2125111
14:31
CR
EPA 625
Dibenz[a,h]anthracene
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
Dibenzofaran
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
Diethylphthalate
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
Dimethylphthalate
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
Di-n-butylphthalme
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
Di-n-octylphthalate
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
Fluoranthene
<0.010
mg/L
2/25111
14:31
CR
EPA 625
Fluorene
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
Hexachlorobenzene
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
Hexachlorobutadiene
<0.010
mg/L
2/25/I1
14:31
CR
EPA 625
Hexachlorocyclopentadiene
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
Hexachloroethane
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
State Certifications: Respectfully Submitted
NCDNR #11 � l
NCDOH #37714 �. �. aCauaaPad
USDA #3787 R. W. Sanders, VP/Managing Director
Thankyoufuyourbuainass. WinNrs wsrfeeJAaak on our/minJ.rr,ixro w,. Nlmrr,p,nn rAe YP Mnmgrn80irteror Ron sanrkrs rtr9/MN-lY�a. Jaues NWrs. Prnre4n(a
h�o4.rdpi.roAw.,vm arT wrao/oe,('EO,arbvar�icroMa an �rrM oqv ro.,aenb wiu8xanmr.
Page 4 of 6

Fayetteville Division
2592 Hope Mills Rd
Fayetteville, NC 28306
910.864.1920 Phone
910.864.8774 Fax
Certificate of Analysis
Motive Enterprise - Apex
Mr. Scott Dilling Project. Outfall sample - Mthly/SemiYr/Yrly Date Reported: March 21, 2011
2232 Ten -Ten Road Date Received: February 21, 2011
Apex NC, 27502 Sampled By: Scott Diliing Date Sampled: February 21, 2011
Outfall001, Effluent
1102401.01
Analyse Result Unit Analysis Datelfime Analyst Method Qualifier
Indeno[1,2,3-cd]pyrene
Isophorone
m-Dichlorobenzene
Naphthalene
Nitrobenzene
N-Nitrosodimethy lamine
N-Nitroso-di-n-psopylam ine
N-Nitrosodiphenylarnme
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
Pyridine
Analyzed by: Hlvobac-Fa19teNee mvskn
Flow Reading
Nitrate as N
Nitrite as N
Total Nitrogen
Oil & Grease (HEM)
Phosphorus, Total
Total Suspended Solids
Total Kjeldahl Nitrogen
Turbidity
<0.010
mg/l,
2/25111
14:31
CR
EPA 625
<0.010
mg/L
2/25/I1
14:31
CR
EPA 625
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
<0.010
mg/L
2/25111
14:31
CR
EPA 625
<0.010
mg/L
2/25111
14:31
CR
EPA 625
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
<0.010
mg/L
2/25/11
14:3I
CR
EPA 625
<0.010
mg/L
225111
14:31
CR
EPA 625
<0.050
mg/L
2/25/11
14:31
CR
EPA 625
<0.010
mg/L
225/11
1431
CR
EPA 625
<0.010
mg/L
2125/11
14:31
CR
EPA 625
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
<0.010
mg/L
2/25/11
14:31
CR
EPA 625
168000
gal/day
2/21/11
10:00
RDM
Field
0.0800
mg/L
222/11
8:16
TDA
EPA 300.0
<0.0300
mg/L
2/22/I1
8:16
TDA
EPA 300.0
0.950
mg/L
228111
10:00
TDA
Calculation
<5.00
mg/L
3/8/11
9:00
RAS
EPA 1664
<0.050
mg/L
2/23/11
15:48
ARS
SM 20th Ed. 4500 P F
6.00
mg/L
2/23/11
13:45
AMM
SM 20th Ed. 2540 D
0.870
mg/L
2/28/11
10:00
TDA
SM 20th, 45GONC
5.2
NTU
2/27/11
14:45
TDA
SM 20th Ed. 2130 B
LIBRARY SEARCH: VOA Library did not detected any parameters greater than 50 mg/L.
SVGA Ubary did not defected any parameters greater than 50 mg/L.
State Certi8ca8ons: Respectfully Submitted
NCDNR #11
NCDCH #37714 Aa.rrar wl &
USDA #3787 R. W. Senders, VP/Maaaging Director
Al2
Thank yorz for yourbuainee6. YlF hntlkwrnJeedMGrm orn lr,W/fscm mvoa.P/iase cnmacr the PPhIM00Wa Dincw Ron Snnden at YledaJ-MY Jm None, Pm i&,c. ar
y,6herWjn,cmhnc.wn ur "frtwr tlorr. ('f.0, nr rhourt f,icra6ac.ram n4rh miymsrarnrz or nrpRextiomr. Page 5 of 6

Fayetteville Division
2592 Hope Mills Rd
Fayetteville, NC 28306
910.864.1920 Phone
910.864.8774 Fax
Certificate of Analysis
Motiva Enterprise - Apex
Mr. Scott Dilling Project Outfall sample - Mthlyl&miYr/Yrly Date Reported. March 21, 2011
2232 Ten -Ten Road Date Received: February 21, 2011
Apex NC, 27502 Sampled By: Scott Dilling Date Sampled. February 21, 2011
Qualifier Definitions
A 12 MS/MSD fail recovery, but the LCS passes criteria.
State Certifications: Respectfully Submitted
NCDNR #11
NCDNN 037714 ire w- ,rbcswisc ae,
USDA 03787 R. W. Sanders, VP/Managing Director
Thnnkyoutoryourbuskreu. LYe ionic wxr/rrd6ndmon/e.rl lrrr.+ie ro lmrv.P/mre mnmcr rhr YP Mormgr�Di�ecwr, Ron SmMrra or LledbJ-/Yle,Jmro Noka, PrcXdrnr, ar
j,mkex�rrcroMc.wn or Tmw Boyx. (TO, ar rho-rcwrh�nmrtrMcam oidr Page 6 of 6

Fayerteville Division
2592 Hope MBle Rd
FayeOevillq NC 29306
910.861.I920 Phone
910.864.8774 Fair
Certificate of Analysis
Motive Eotalm e-Apcx
Mc Scott Dining Proja OuthB sample - Mddy/Senel-Aaaad Dale Reported: August 24, 2011
2232 Te Ten Road Date Received: 1* 18, 2011
Apex NC, 27502 Sampled By: Brows Date Sampled Ady 18, 2011
Oottall 001, Effluent
1107322-01
IAnalyte
Result
Unit
Analysis Dete/I-mm
Analyst
Method Qaeli -
M•bma br PeoaWc - FayelMae Dm*n
Flow Reding
210000
gal/day
7/19/11
9:00
RDM
Field
Nitrate as N
0.264
mg/L
7119111
13:12
AMM
EPA 300.0
Nitrite as N
0.0624
mg/L
7/19/I1
13:12
AMM
EPA 300.0
Total Nitrogen
4.53
ma
7/21/I1
16:09
AMM
Calculation
Oil k Grease (ITEM)
<5.00
mg/L
7/22/1 l
8:30
DSK
EPA 1664
Phosphonts, Total
<0.050
mg.&
7/22/I 113:14
ARS
SM 20th Ed 4500 P F
Total Smpeaded Solids
14.4
MOIL
7/20/11
9:30
DSK
SM 20th Ed 2540 D
Total KjeldaM Nitrogen
4.20
mg/L
7/21111
16:09
AMM
SM 20th, 450ONC
Turbidity
3.9
NfU
7/19/11
14:20
ARS
SM 20th Ed 2130 B
kmtr abr:M=toctabeabigbr-auosdam
1,1,1-Trichloroethane
<0.0010
mO/L
7/30111
4:17
mil
EPA 624 Rev 7/95
U
1.1,2,2-Tetrachloroethane
<0.0010
mg/L
7/30111
4:17
mil
EPA 624 Rev 7/95
U
1, 1,2-Trichloroethane
<0.0010
mg/L
7/30/11
4:17
mil
EPA 624 Rev, 7/95
U
I,1-Dichloruethane
<0.0010
mg/L
7/30111
4:17
mil
EPA 624 Rev 7/95
U
1,1-Dichloroetheee
<0.0010
mg/L
7/30/11
4:17
mil
EPA 624 Rev 7/95
U
1,2-Dichlorobenzeoe
<0.0020
mg/L
7/30/11
4:17
mil
EPA 624 Rev 7/95
U
1,2-Dichlomctl me
<0.0010
mg/L
7/30111
4:17
mil
EPA 624 Rev 7/95
U
1,2-Dichloropmpme
<O.D010
mg/L
7/30/11
4:17
mil
EPA 624 Rev 7/95
U
1,3-Dichlorobenzeae
<0.0020
mg/L
7/30/11
4:17
mil
EPA 624 Rev 7/95
U
1,4-Dichbmbenrene
<0.0020
mg/L
7130/11
4:17
mil
EPA 624 Rev 7/95
U
2-Cliloroethyl vinyl ether
<0.0020
mg/L
7/30/I1
4:17
mfl
EPA 624 Rev 7/95
U
2-Hexanone
<0.0050
mg/L
7/30/11
4:17
mil
EPA 624 Rev, 7195
U
Acetone
0.0076
MB/L
7130/11
4:17
mil
EPA 624 Rev 7/95
Benzene •
<0.0010
mg/L
7/30/11
4:17
mil
EPA 624 Rev 7/95
U
Bromodichlorome0mne
<0.0010
mg/L
7130/11
4:17
mil
EPA624 Rev 7/95
U
Bromoform
<0.0010
tng/L
7130/11
4:17
mil
EPA 624 Rev 7/95
U
StmeNCD R IBratlarre:
NCDNR aft
�Su 'ttb� ed
NCDOH 037714
ijlr_YR—W__Y
USDA 03707
Ruben Dome, M i i® Manager
iMayav Byer biahaa. W. atnryau.k.Aeed wraobrvdd+ewmropa
Naae.veeorrerot.ats Ee.eae•, aWnllseroal0•dN-19M 1m,e NWat RWbq ar
Jnalu�arbeear.aw wTrawrdwe. CEO, or Ao @wreober
Age1
46

0
Fayetteville Division
2592 Hope Mills Rd
Fayettevi8q NC 29306
910.864.1920 Phone
910.864.8774 Fax
Certificate of Analysis
Mmiva Fatecpme-Apex
Mr. Seen Dilling Project OMM S—Ple- Mthly/SemFAmeal Date Rcpuemd: August 24, 2011
2232 Teo -Ten Road Date Received: July 18, 2011
Apex NC, 27502 Sampled By: Brown Dam Sampled: July 1$, 2011
Outfall001, Effluent
1107322-01
I Anslytc Result Unit Analysis Datdlimc Analyst Method Qualifier
Bromomethane
<0.0020
mg/L
7/30/I1
4:17
mil
EPA 624 Rev 7195
U
Carbon Disulfide
<0.0020
mg/L
7/30/11
4:17
mil
EPA 624 Rev 7/95
U
Carbon tetrachloride
<0.0010
mg/L
7130/11
4:17
mil
EPA 624 Rev 7195
U
Chlorobenzme
<0.0010
mg/L
7/30/11
4:17
mil
EPA 624 Rev 7/95
U
Chloroetharm •
<0.0020
mg/L
7/30/11
4:17
mil
EPA 624 Rev 7/95
U
Chloroform
<0.0010
M91L
7/30/11
4:17
mil
EPA 624 Rev 7/95
U
Chloromethane
<0.0020
Newt
7/30/11
4:17
mil
EPA 624 Rev 7/95
Ua
cis-1,3-Dichloropropme
<0.0010
MOIL
7/30/11
4:17
mil
EPA 624 Rev 7/95
U
Dtbromochloromethane
<0.0010
mg/L
7/30/11
4:17
mil
EPA 624 Rev 7/95
U
Etbylbenzcne a
<0.0010
mg/L
7/30111
4:17
mil
EPA 624 Rev 7/95
U
Methylene chloride
<0.0020
mg/L
7/30/11
4:17
mil
EPA 624 Rev 7/95
U
Methyl-t-Butyl Elba
<0.0020
mg/L
7/30/11
4:17
mil
EPA 624 Rev 7/95
U
Twuhloroethene
<0.0010
MOIL
7130/11
4:17
mil
EPA 624 Rev 7/95
Us
Toluene
<0.0010
mg/L
7130111
4:17
mil
EPA 624 Rev 7/95
U
Total 1,2-Dichloroethene
<0.0010
mg/L
7/30111
4:17
mil
EPA 624 Rev 7/95
U
Total Xylenes
<0.0010 -
Mg/L
7130/11
4:17
mil
EPA 624 Rev 7N5
U
ten-1.2-Dichbmethme
<0.0010
mg/L
7/30/11
4:17
mil
EPA 624 Rev 7/95
U
tram-1,3-Dichlompropene
<0.0010
MO&
7/30111
4:17
mil
EPA 624 Rev 7/95
U
Trichloroedrene
<0.0010
MOIL
7130/I1
4:17
mil
EPA 624 Rev 7/95
Ua
TmIdorofhwmmethane .
<0.0010
m8/L
7/30/11
4:17
mil
EPA 624 Rev 7/95
U
Ymyl Acetate
<0.0010
MS/L
7/30/11
4:17
mil
EPA 624 Rev 7N5
U
Vinyl chloride
<0.0020
mg/L
7/30/11
4:17
mil
EPA 624 Rev 7N5
U
Surrogate: 1,1-Diehloroelhm,o-D4112 % 88.2-132
7130111
437
m1l
EPA 624 Rev 7195
Srn gale: 4-BromoJharoba¢en6922 % 80.120
7130111
4:17
mil
EPA 624 Rev 7195
Srm7qllate.DI&magf7naromethanelJ2% 80-120
7130111
4:17
mil
EPA 624 Rev 7/95
Surrogate: Toluene-D8
JOJ % 80-120
713WIl
4:17
mil
EPA 624 Rev 7W
StateNCD R #It Ban:
NCONR anr[=7iV`Y17WIe
�ia oh,,,,
NCDOH 837714
USDA 03787
Itabrn Dams, IAvism Maaagc
Thank utwycu Noima. Wa,.arwwlwdaadw
mh,NNaw,luwroa lfm.ewmad.AWM,Irw,es. x•anlbwrwelOJear➢1al
n•tee, AvWat.a
rkrWw.m,rw r•nwlyae, C2'a, wrEewe�,agoaw.ew
aaa ayesarramaapmeaa
Page
2 of6

0
Fayetteville Division
2592 Hope Mina Rd
Fayetteville, NC 28306
910.864.1920'Phme
910.964.8774 Fat
Certificate of Analysis
Motive Enterprise -Apex
Mc Scott Dillin8 Project: Outtan temple - MMY/Sem4Annual Dam Reported: August 24, 2011
2232 Tea -Teo Road Dam Received: July 18, 2011
Apex NC, 27502 Sampled By: Bro Date Sampled:.luly 19, 2011
Outfafl 001, Effluent
1107322-01
I Amlyte Result Unit Analysis Date/rote Analyst Method Qualifier
1,2,4-Trichlombenune
<10
pg/L
7126/11 16:31
BR
EPA 625 Rev 7/95
1,2-Dichlorobenzcne
<10
pg/L
7/2N11 16:31
BR
EPA 625 Rev 7/95
1,2-Diphmylhydrazine
<I0
µSIL
7/26111 16:31
BR
EPA 625 Rev 7/95
1,3-Dichlorobeuane
<10
µS/L
7/26/11 16:31
BR
EPA 625 Rev 7/95
l,4-Dichlorobmzcne
<10
pg/L
7/26/11 16:31
BR
EPA 625 Rev 7/95
2,2'-oxybis(1-chlocopropsne)
<10
µOIL
7/26/11 16:31
BR
EPA 625 Rev 7/95
2,4,5-Trichlorophenol
<10
µOIL.
7/26/11 16:31
BR
EPA 625 Rev 7/95
2,4,6-Trichlorophenol
<10
µOIL
7/26111 16:31
BR
EPA 625 Rev 7N5
2,4-Dichlorophenol
<10
p9/L
7/26111 16:31
BR
EPA 625 Rev 7/95
2,4-L)®ethylphmol
<10
µg/L
7/26/11 16:31
BR
EPA 625 Rev 7195
2,4-D ni ropheool
<52
pg/L
7/26/11 16:31
BR
EPA 625 Rev 7195
2,44Dinitrotoluene
<10
ps/L
7/26/I1 16:31
BR
EPA 625 Rev 7/95
2,6-Dichlorophenol
<10
pg/L
7/26/11 16:31
BR
EPA 625 Rev 7/95
2,6-Dmitrotolucae
<10
pg/L
7/26/11 16:31
BR
EPA 625 Rev 7/95
2-Chloranaphthalene
<10
ps/L
7/26/11 16:31
BR
EPA 625 Rev 7/95
2-Chl=phenol
<10
ps/L
7/26/11 16:31
BR
EPA 625 Rev 7/95
2-Methyhtephthakm
<10
µg/L
7/2N11 16:31
BR
EPA 625 Rev 7/95
2-Methylphenol
<10
µg/L
7/26/11 16:31
BR
EPA 625 Rev 7N5
2-Nibuaniline
<10
µg/L
7/26/11 16:31
BR
EPA 625 Rev 7/95
2-Nitrophenol
<10
µg/L
7/26/11 16:31
BR
EPA 625 Rev 7/95
3,3'-Dichlorobmzidine
<52
pg/L
7/26/11 16:31
BR
EPA 625 Rev 7/95
3/4-Methylphenol
<10
µg/L
7/26111 16:31
BR
EPA 625 Rev 795
3-Nitroaniline
<10
µg/L
7/26/11 16:31
BR
EPA 625 Rev 7/95
4,6•Dmitro-2-atethylphenol
<26
µg/L,
7/26/II 16:31
BR
EPA 625 Rev 7/95
4-Brontophenyl phenyl ether
<10
pg/L
7/26111 16:31
BR
EPA 625 Rev 7195
StateCertifiratlofK: NCD �qu •nlnm,
NCDNR #11
NCDOH 937714
USDA X3787 Rabmi Deans, Di w biwagc
11uWc you b your a,Niea. 14'r Mp wcyad6,Jwm. L,daJv,su aye viaa.a„mara.DMtle.11arrs..xeEur Avwsa910dN-191Q JamNahq AaWex. m
JwoaeEDvkmbcnm w llaor#yca. C£O, m reo,.ce@vxvexma MNmpmvrw wiagavv,fam.
Pogo 3 of 6

Fayetteville Division
2592 Hope Mill, Rd
Faymevilk, NC 29306
910.864.1920 Phone
910.864.8774 Fax
Certificate of Analysis
Motiva Exa%mnse -Apes
Mr. Sean Dilling
Date Rrymted: August 24, 2011
Project Ontm atople-Mtw/semFAmml
2232 Teo -Ten Road
Date Received: July 18, 2011
Apex NC, 27502
Sampled Br.. Brown Date Sampled: July 19, 2011
OuttaB 001, Effluent
1107322-01
IAtalyte
Result
Unit
Analysis Datc(rtme
Analyst
Method Qualifier
NWymO br HtooWc labmtw Inc-04.9�
4Chloro-3-methylphenol
<21
µs/L
7/26/11 16:31
BR
EPA 625 Rev 7/95
4-Chlamanilim
<10
pg/L
7/26111 16:31
BR
EPA 625 Rev 7/95
4-Cblmophmyl phenyl ether
<10
pg/L
7/26111 16:31
BR
EPA 625 Rev 7/95
4-Nitromiline
<10
pg/L
7/26/11 16:31
BR
EPA 625 Rev 7/95
4-Nitrophmol
<52
µg/L
726111 16:31
BR
EPA 625 Rev 7/95
Acemphthme
<10
pg/L
7/26111 16:31
BR
EPA 625 Rev 7/95
Aceoaphthylcne
<10
µs/L
7/26111 16:31
BR
EPA 625 Rev 7/95
Acetophmme
<10
µg/L
7/2N11 16:31
BR
EPA 625 Rev 7/95
Aniline
<10
pg/L
7/26111 16:31
BR
EPA 625 Rev 7N5
Amhracene
<10
µg/L
7/26t11 16:31
BR
EPA 625 Rev 7/95
Benzidine
<52
µg/L
7/2611I 16:31
BR
EPA 625 Rev 7N5
Benzo[a]anthacene
<10
pg/L
7/26(11 16:31
BR
EPA 625 Rev 7N5
Benzo[a]pyreoe
<10
µg/L
7/26/1I 16:31
BR
EPA 625 Rev 7/95
Banzo[b]fluoraotbmc
<10
µ81L
7/26111 16:31
BR
EPA 625 Rev 7N5
Benzo[ghjkmylcne
<10
µg/L
72N11 16:31
BR
EPA 625 Rev 7/95
Bem[klfluoranthene
<10
pg/L
726/11 16:31
BR
EPA 625 Rev 7/95
Benzoic acid
< 0
pg/L
72NI1 16:31
BR
EPA 625 Rev 7/95
Benzyl alcohol
<10
µg/L
726111 16:31
BR
EPA 625 Rev 7N5
Bis(2-chloroethoxy)med me
<10
pg/L
7/26/]1 16:31
BR
EPA 625 Rev 7/95
Bis(2-chlormthyl)ether
<10
pg/L
7/26/11 16:31
BR
EPA 625 Rev 7/95
Bis(2-ethylhcxyl)phthalate
<10
pg/L
726r11 16:31
BR
EPA 625 Rev 7/95
Butyl benzyl phthalate
<10
µg/L
726t11 16:31
BR
EPA 625 Rev 7/95
Catbaznle
<10
pg/L
726111 16:31
BR
EPA 625 Rev 7N5
Chrysmc
<10
µg/L
726/11 16:31
BR
EPA 625 Rev 7/95
Dibenz[a,h]mthmcme
<10
µg/L
726111 16:31
BR
EPA 625 Rev 7/95
Sure Ceta1w8one:
Hcorat #n
DOH 37714 USltalwtDtana; Drvtaoa t4mtla
USDA a3787
7baac you bryao btubnaa Wi hrvM�ax(m@od onaar MleJavq,aNpa PlamanwranrYna4awlraaIIe. xodalnanxsmaladel-I/]e,Jme Mda PrvtivK ar
pot�@�a,ae.�.a,ar w r�.w.aa,e. eeo. aroetaKa.naeacc.ca..an aar�a,aarmambu.
Page {af6

Fayetteville Division
2592 Hop. Mille Rd
Fayene il1e, NC 28306
910.864.1920 Phoa<
910.864.8774 Fax
Certificate of Analysis
Motiva Fntaprise - Apex
Mr. Scon Ming Project OaW ample-MWy/SemI-Annual Date Reponed: Aug•.t 24, 2011
2232 Tea-Tm Rued Date Received: July 18, 2011
Apex NC, 27502 Sampled By. Brown Date Sampled: JWy 18, 2011
Outfall 001, Effluent
110732MI
I Analyte Result Unit Analysis Date Time Am lyst Method Qualifies
Dibcnzofurnn
<10
pg/L
7/26/11 16:31
BR
EPA 625 Rev 7/95
Diethyl phthalate
<10
µg/L
7126/11 16:31
BR
EPA 625 Rev 7/95
Dimethyl phthalate
<10
pg/L
7/26/11 16:31
BR
EPA 625 Rev 7/95
Di-n-butyl phthalate
<10
µg/L
7/26/11 16:31
BR
EPA 625 Rev 7/95
Di-n-octyl phthalate
<10
µg/L
7/26/11 16:31
BR
EPA 625 Rev 7/95
Fluoranthme
<10
pg/L
7/26/11 16:31
BR
EPA 625 Rev 7/95
Fluorene
<10
pg/L
7/26/11 16:31
BR
EPA 625 Rev 7/95
Hexachlorobenzene
<10
pg/L
7/2NI1 16:31
BR
EPA 625 Rev 7/95
Hexachlorobutadiene
<10
µg/L
7/26/11 16:31
BR
EPA 625 Rev 7/95
Hmchlotocyclopentadime
<10
pg/L
7/26/11 16:31
BR
EPA 625 Rev 7/95
Hexachlomethane
<10
pg/L
7/26/11 16:31
BR
EPA 625 Rev 7/95
lndmo[ 1.2,3cd]pymc
<10
µg/L
7126/11 16:31
BR
EPA 625 Rev 7/95
lsophmonc
<10
pg/L
7/26/11 16:31
BR
EPA 625 Rev 7/95
Naphthalene
<10
µg/L
7/26/I1 16:31
BR
EPA 625 Rev 7/95
Nitrobenzene
<10
µg/L
7/26/11 16:31
BR
EPA 625 Rev 7/95
N-Ninosodimethylamine
<10
µ81L
7/26/11 16:31
BR
EPA 625 Rev 7/95
N-Nimsodi-n-propylanune
<10
µgfL
7/26/11 16:31
BR
EPA 625 Rev 7/95
N-Ninvsodiphenylamine
<10
pg/L
7/26/11 16:31
BR
EPA 625 Rev 7/95
P=wchImaphenol
<52
pg/L
7/2NI1 16:31
BR
EPA 625 Rev 7/95
Phenanthme
<10
µg/L
7/26111 16:31
BR
EPA 625 Rev 7/95
Phenol
<10
AWL
7/26/11 16:31
BR
EPA 625 Rev 7/95
Pyrene
<10
µg/L
7/26/11 16:31
BR
EPA 625 Rev 7/95
Pyridine
<10
µg/L
7/2&11 16:31
BR
EPA 625 Rev 7/95
Svr gate: 1,4,6-Tribromophenol 124 Y. 15.2-143
7126111 16.31
BR
EPA 625 Rev 7195
SumRute:2-Fluombiphemyl
88.9%17.3-110
7126111 16:31
BR
£PA 625 Rev 7N5
Sta-rogote: 2-Fluorophenol
73.7 % 10-67.1
7126111 16:31
BR
EPA 625 Rev 7195
Slate
pe [fulFy Su tied
R 011a8ore:
NCUNR
#3
USDA 3787
USDA p3787
Rabat Dvma, D"'°'® Mamger
liunkyw kryw dubreis. W�invree
�omfeedearkw av Mel oJaerNu re�w Plewe rarron rlwpivbiar llawgv, xuden Qvnwm➢l0.eel-19: a, lmne,Ydm, Pmldmr, ar
jnoto�2•,Krvdn�rom or Tw Bowe.CEO,
Peer5a(6

Fayetteville Division
2592 Hope Nils Rd
FaydWalle, NC 28306
910.864.1920Thone
910.864.9774 Fax
Certificate of Analysis
Motiva Enterprise -Apm
Mt Smn Dining Projmt: Outfmn sample - MtW/Semi-Annual Date Repwtcd: Augmt 24, 2011
2232 Tea-Tm Road Date Received: July 18, 2011
Apex NC, 27502 Sampled By: Brown Date Sampkd July 18, 2011
Oatiall 001, Effluent
1107322-01
Analyte
Result Unit
Analysis Datelr=
Analyst
Method
k.Vnd W � taboret K ac
- 0*.W and
St gate: NltmberrrenedJ
92.3 % 10-115
7126111 16:31
BR
EPA 625 Rev 7195
Su gale: Phmol-d5
43.5 % 10-50.9
7126111 16:31
BR
EPA 625 Rev 7195
Sr gale: Tembenv d14
128 % 10.1-131
7126111 16:31
BR
EPA 62J Rev 7195
Quallfier Dermitions
Ua Undetected
U Analyte included in the analysis, but not detected
Qualifier
Stag ons:
'tt
NCDNR # 11
�Su
DOH 037714
USDA 03767
US
Aabett Demo, Divitiw Manager
Think ya fa ymx davr_s. W b.uirc w.riradAr�onm/eW of.,mfc�ra� ➢lemmnm lerHY4M Lmiaav, Robvrnvmem➢IOdbF/9}4
J®v Natq RvHmr, or
T., m ,.Ceo. or rea,�Aroee.�.r>.r.ua ery.e,o,ww e.�are,r.
Page 6 of 6

Jan -�b i ;t-
Fayetteville Division
2392 Hope M M Rd
Fayenevi0e6NC 2R306
910.964.1926 Phone
910.864.8774 Fu
Certificate of Analysis
Motive Enterprise -Ape:
Mc Scott Dilliug 14oject: OatfiH sampk- - MthbSem[Yr/Yrly Date Reported: lom my 31, 2012
2232 Tm-Ten Road Date Rxeived: January 09, 2012
Apex NC, 27502 Sampled By. Scott Dilling Date Sampled: Jaoaary 09, 2012
Outfall 001, Effluent
1201121-01
Anslyte
Result
Unit
Analysis Daw ime
Analyst
Method Qualifier
wWan ar. tits
Bioassay -Acute
>I00
%
1/10/12 0:00
ETS
EPA-821-R-02-012
bu/.ad 6r tatebs- r vWrAe Db
Nitrate asN
0.0745
mg/L
1/10/12 20:41
JAW
EPA300.0 B
Nitrite asN
0.0703
mg/L
1/10/12 20:41
JAW
EPA300.0
Total Nitrogen
126
mg/L
1/11/12 7:06
AMM
Calculation
Oil & Grease (HEM)
<5.00
mg/L
1/19/12 15:00
JAW
EPA 1664
Phosphorus, Total
<0.050
mg/L
1/12112 1330
AMM
SM 20th Ed- 4500 P F
Total Suspended Solids
<5.00
mg/L
1/10112 19:18
JAW
SM 20th Ed. 2540 D
Total Kjeldahl Nitrogen
1.12
mg/L
1/11/12 7:06
AMM
SM 20th, 450ONC
babae by: 1aaa6ec taboraaalq ar. - Daogo`d
1,1,1-Tnchlorcethane
<0.0010
mg/L
1/18/12 15:08
iln
EPA 624 Rev 7/95
U
1,1,2,2-Tetrachlorcethane
<0.0010
mg/L
1/19112 15:08
iln
EPA 624 Rev 7/95
U
1,1,2-Trichloroethane
<0.0010
mg/L
1118/12 1508
iln
EPA 624 Rev 7/95
U
1,1-Dichloroethane
<0.0010
mg/L
1/18/12 15:08
,iln
EPA 624 Rev 7/95
U
1,1-Dichloroethene
<0.0010
mg/L
1/18/12 15:08
jin
EPA 624 Rev 7/95
U
1,2-Dichlorobenzene
<0.0020
mg/L
1/18/12 15,08
iln
EPA 624 Rev 7/95
U
1,2-Dichloroethane
<0.0010
mg/L
1/18/12 15:08
iln
EPA 624 Rev 7/95
U
1,2-Dichloropropane
<0.0010
mg/L
1/18/12 15:09
iln
EPA 624 Rev 7/95
U
1,3-Dichlorobenzene
<0.0020
mg/L
1/19/12 15:08
iln
EPA 624 Rev 7/95
U
1,4-Dichlombenzene
<0.0020
mg/L
1/18/12 15:08
iln
EPA 624 Rev 7/95
U
2-C6loroethyl vinyl ether
<0.0020
mg/L
I/19/12 15:08
7o
EPA 624 Rev 7/95
U
2-Hexanone
<0.0050
mg/L
1/19/12 1508
ilu
EPA 624 Rev7195
U
Acetone
<0.0050
mg/L
1/18/12 15:08
iln
EPA 624 Rev 7/95
Us
Benzene
<0.0010
mg/L
1/19/12 15:08
iln
EPA 624 Rev 7/95
U
Bromodichloromethane
<0.0010
mg/L
1119/12 1508
On
EPA 624 Rev 7/95
U
Bromoform
<0.0010
mg/L
1/18112 15:08
7n
EPA 624 Rev 7/95
U
Staa CertlFra6ona:
Respectfully Submitted
NCDNR all
NCDNN $37714
Robert Dormer
USDA 03787
Ratio D. Dmtian W.S.
1hnYla forlwrfaedroea Wab,ialparlfµNaodanae*!,wltJ,e,i�b)a<P/actcwaL
lAeOW6faLasav, RabrLbnrmDl0.adFlVM.! vNa6a N�dev.m
Jada.da(aaibolereae ar rTarawv. CEO, neas.deyn�.lsa7mares�.eba
Pw1 of 6

Fayetteville Division
2592 Hope Mdb Rd
Fgyettev0le, NC 29306
910.864.1926 Phoue
910.864.8774 Fn
Certificate of Analysis
Motive Enterprise - Apex
Mr. Scott DiIiing Date R
2232 Ten -Tea Road �0afls�Pk-Mt6�l9emfYr/Yr1y � J/nuI'31.2012
Due Received: Jemury 09, 2012
Apex NC, 27502 S"Vied By. Scott Dilling Date Sampled: January 09 2012
Outfan 001. E8laent
1201121-01
I Analyse Result Unit Analysis Date/rime Analyst Method Qualifier
Bromomethane
<0.0020
mg/L
1/19/12 15:08
jln
EPA 624 Rev 7/95
U
Carbon Disulfide
<0.0020
mg/L
1/18/12 15A8
iln
EPA 624 Rev 7/95
U
Carbon tetrachloride
<0.0010
mg/L
I/18/12 15:08
jln
EPA 624 Rev 7/95
U
Chlorobenzene
<0.0010
mg/L
1/18/12 I5:08
An
EPA 624 Rev 7/95
U
Chtomethane
<0.0020
mg/L
1/I8/12 15:08
gn
EPA 624 Rev 7/95
U
Chloroform
<0.0010
mg/L
I/18/12 15:08
jln
EPA 624 Rev 7/95
U
Chloromethane
<0.0020
mg/L
1/18/12 15:08
On
EPA 624 Rev 7/95
U
cis-1,3-Dichloropropene
<0.0010
mg/L
1/18/12 15.08
jln
EPA 624 Rev 7/95
U
Dibromochloromethane
<0.0010
mg/L.
I/IS/12 15.08
An
EPA 624 Rev 7195
U
Ethylbenzene
<0.0010
mg/L
1/18/12 15A8
jln
EPA 624 Rev 7/95
U
Methylene chloride
<0.0020
mg/L
1/18/12 15.08
An
EPA 624 Rev 7/95
U
Methyl-t-Butyl Ether
<0.0020
mg/L
1/18/12 15:08
jln
EPA 624 Rev 7/95
U
Tetrachloroethene
<0.0010
mg/L
1/19/12 15:08
An
EPA 624 Rev 7/95
U
Toluene
<0.0010
mg/L
1118/12 15:08
An
EPA 624 Rev 7/95
U
Tota11,2-Djchloroethene
<0.0010
mg/L
1/18/12 15:08
jln
EPA 624 Rev 7/95
U
Total Xylenes
<0.0010
mg/L
1/I8/12 15:08
An
EPA 624 Rev 7/95
U
trans-1,2-Dichlomethene
<0.0010
mg/L
1/18/12 I5:09
An
EPA 624 Rev 7/95
U
trans-1,3-Dichloropropene
<0.0010
mg/L
I/19/12 15:08
jln
EPA 624 Rev 7195
U
Trichloroethene
<0.0010
mg/L
1/18/12 15,08
iln
EPA 624 Rev 7/95
U
Trichlorofluoromethane
<0.0010
mg/L
1/18/12 I5:08
An
EPA 624 Rev 7195
U
Vinyl Acetate
<0.0010
mg/L
1/I8/12 15:08
iin
EPA 624 Rev 7/95
U
Vinyl chloride
<0.0020
mg/L
1/18/12 I5:08
jln
EPA 624 Rev 7/95
U
Surro¢ate: 1.1-Dichloroethane>W% 80-132
1118112 15:08
jln
EPA 624 Rev 7195
Sumeate: 4-Nmmotluombenz8hd % 80-120
1118112 15:08
jln
EPA 624 Rev 7195
Swrogrite: Dibitimo /uOlOmed/lj)i1[t°% 80.120
1118112 15:08
jln
EPA 624 Rev 719S
Surmvate: Toluene-D8
100 % 80410
1118112 15:08
On
EPA 624 Rev 7195
Slate Cermm itiona:
Rcspectfilly Submitted
NCONR all
NCDON 037714
Robert Dernter
USDA 03787
Rabat D®er, Tltvidm Mwgc
71WIIk Fa N yarbueYm n4 b.bepsledmceenmkwlaJ.et.lopi PMmaraxaaal.gwm.Jl.lym, Re6mrDamsm 9ledrFl➢Ia, lm,m Mato. AvldmG m
/wnwfm�dniaabcros ort Dy.v,[EO.meew.agar�usepeam.Mapm.waa
aa�maa
Pge2 of6

Fayetteville Division
2592 Hope Mills Rd
Fayetteville, NC 29306
910.864.192U Pbwe
910.864.rm Fax
Certificate of Analysis
Motive Enterprise -Apex
Mr. Scott Dilliog Ject: Oat4B ample - Date Reported: Jatmmy 31, 2012
2232 Tea -Ten Roed �O P Mth�/Semll r/Yriy Date Received:
Jam ary 09, 2012
Apex NC, 27502
Sailed By. Scott INIIing Date Sampled: Jantnry 09, 2012
Oatfall 001, Effluent
1201121-01
' Analyte Result Unit Analysis Date/rime Analyst Method Qualifier
1,2,4-Trichlorobenzene
<10
AWL
1/13/12 1821
CLR
EPA 625 Rev 7/95
1,2-Dicblorobenzene
QO
µg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
1,2-Dipheaylhydraz;ne
<10
µg/L.
1113/12 1921
CLR
EPA 625 Rev 7/95
1,3-Dichlombenzene
<10
µg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
1,4-Dichlorobeozene
<10
µg/L
1113/12 1821
CLR
EPA 625 Rev 7/95
2,2'oxybis(1-chlompropane)
<10
µg/L
1/13112 18:21
CLR
EPA 625 Rev 7/95
2,4,5-Trichlorophenol
QO
µg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
2,4,6-Trichlorophenol
<10
µg/L
1/13/12 1821
CLR
EPA 625 Rev 7195
2,4-Dichlorophenol
<10
µg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
2,4-Dimethylphenol
<10
µg/L
1/13/12 18:21
CLR
EPA 625 Rev 7/95
2,4-Dimtrophenol
<52
µg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
2,4-Dinitrotoluene
<10
µg/L
1/13/12 18:21
CLR
EPA 625 Rev 7/95
2,6•Dicblorophenol
<10
µg/L
1/13112 1821
CLR
EPA 625 Rev 7/95
2,6-Dinitrotoluene
<10
µg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
2-Chlommphthalene
<10
µg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
2-Chlorophenol
<10
µg/L
1/13/12 18:21
CLR
EPA 625 Rev 7/95
2-MethylnaphdWene
<10
µg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
2-Methylpbenol
<10
µg/L
1/13/12 18:21
CLR
EPA 625 Rev 7/95
2-Nitroaniline
<10
µg/L
1113/12 1821
CLR
EPA 625 Rev 7/95
2-Nitrophenol
<10
µg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
3,3'-Dichlorobenzidine
<52
µg/L
1/13/12 18:21
CLR
EPA 625 Rev 7/95
3/4-Methylphenol
<10
µg/L.
1/13/12 1821
CLR
EPA 625 Rev 7/95
3-Nitroaailine
<10
µg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
4,6-Dinitm-2-methylphcnol
Q6
µg/L
1113/12 1921
CLR
EPA 625 Rev 7/95
4-Bromophenyl phenyl ether
<I0
µg/L,
1/13/12 1821
CLR
EPA 625 Rev 7/95
State Cern6cabons
NCONR att RespectJ011y Submitted
NCOON 037714 Robert Denner
USDA *3787 Rabin D® Div M.W
Thw*you%xyardmLeec. Wi irweJm/m�6mlmo Me'N+mb mrva lMmemrav NallhcbrYmgv, le6mllvmm9r0.ae4/910.J leafm. MmMmLm
/me.roL�xrbvlar.mrm Ties Dam. CEO. a,a�vm.dgs�eknlm,m..M m�aamaeormnmem[
Pye 3 of6

Fayetteville Division
2592 Hope Mild Rd
FgcOevM%NC 2a306
910.964.1920 Phone
910.g6crm Fax
Certificate of Analysis
Motiva Eatetprise - Apex
Mr. Scott Dining Project: Outran sample - MtWjSendYr/Yrly Date Reported: Jammy 31, 2012
2232 Teo -Ten Road Date Received: January 09, 2012
Apex NC, 27502 Sampled By. Scott Dilling Date Sampled: Jmuary09, 2012
Outran 001, Effluent
1201121-01
' Analyse Result Unit Analysis Date/l'ime Analyst Method Qualifier
4-Chlom-3-methylphenol
QI
µg/L
I/13/12 1821
CLR
EPA 625 Rev 7195
4-Chloroaniline
<10
1191L
1/13/12 1821
CLR
EPA 625 Rev 7/95
4-Chlomphenyl phenyl ether
<10
µg/L
I/13/12 18:21
CLR
EPA 625 Rev 7/95
4-Nitroaniline
<10
µg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
4-Nitropbenol
<52
pg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
Acenaphthene
<10
pg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
Acenaphthylene
<10
pg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
Acetophenone
<10
pg/L
1/13112 1921
CLR
EPA 625 Rev 7/95
Aniline
QO
pg/L
1/13/12 18:21
CLR
EPA 625 Rev 7/95
Anthracene
<10
pg/L
1113/12 18:21
CLR
EPA 625 Rev 7/95
Benzidine
<52
pg/L
I/13/12 1821
CLR
EPA 625 Rev 7/95
Benzo[alaothracene
<10
µ91L
1/13/12 1821
CLR
EPA 625 Rev 7/95
Benzo[a]pyrene
<10
µg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
Benzo[b]fluotanthene
<10
pg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
Benzo[g,b,ilperylene
<10
µg/L
1/13/12 1821
CLR
EPA 625 Rev 7195
Benzo[k]fluoranthene
<10
µg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
Benzoic acid
<10
µg/L
1/13/12 1921
CLR
EPA 625 Rev 7/95
Benzy] alcohol
<10
pg/L
1/13/12 18:21
CLR
EPA 625 Rev 7/95
Bis(2chloroethoxy)methane
<10
µg/L
1/13/12 1911
CLR
EPA 625 Rev 7/95
Bis(2chloroethyl)ether
<10
µg/L
1/13/12 18:21
CLR
EPA 625 Rev 7/95
Bis(2-ethylhexyl)phthalate
<10
µg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
Butyl benzyl phthalate
<10
µg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
Carbazole
<10
µg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
Chrysene
<10
pg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
Dbenz[a,h]anduacene
<10
pg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
Soros CerVicaboos:
Resp=dWly Submitted
NCDNR all
NCDOH a37714
Robert Demmer
USDA a3787
RAW D® , Di y M"w
7a Y.fty. E,vhm lWY.iwrovidAml owevr lna'a/aaMnrolaa lYnr,rwmrMlMMtlal/ ^dc•lalw LasmDlaJN-79Ja Jm.e Xaln J .Wm m
Awc.nole(dmbdw.<mrw n..Qaew.. QO. mnmbyr�b.Meo• utlagoavwnv wwpaebv.
PDae1o76

Fayetteville Division
2592 Hope Mills Rd
FryoOeville, NC 29306
9I0.W.1920Phone
910.W.8774 Fax
Certificate of Analysis
Motiva Enterprise -Apex
Mr. Scott Dilling Project: OuW sample - MthlyMadYr/Yrty Date Reported: laouary31, 2012
2232 Ten -Ten Road Date Received: lamny 09, 2012
Apex NC, 27502 Sampled By. Scott Dilling Date Sampled: January 09, 2012
OatfaB 001, Effluent
1201121-01
I Analyte Result unit Analysis Date/rime Analyst Method Qualifier
Dibenzofutm
<10
µg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
Diethyl phthalate
<10
µg/L
I/13112 1921
CLR
EPA 625 Rev 7/95
Dimethyl phthalate
<10
µg/L
1/13112 1821
CLR.
EPA 625 Rev 7/95
Di-n-butyl phthalate
<10
µg/L
1/13/12 18:21
CLR
EPA 625 Rev 7/95
Di-n-octyl phthalate
<10
pg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
Fluormthene
<10
µg/L
I/13/12 18:21
CLR
EPA 625 Rev 7/95
Fluorene
<10
µg/L
1/13/12 1821
CLR.
EPA 625 Rev 7195
Hexachlorobenzene
<10
µg/L
1/13/12 1821
CLR.
EPA 625 Rev 7/95
Hexachlorobutadiene
<10,
µg/L
1/13/12 18:21
CLR.
EPA 625 Rev 7/95
Hexachlorocyclopentadiene
<10
µg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
Hexachloroethane
<10
µg/L
1/13/12 18:21
CLR
EPA 625 Rev 7195
Indeno[lA3cd]pyrene
<10
µg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
Isophorooe
<10
µg/L
1/13/12 18:21
CLR
EPA 625 Rev 7/95
Naphthalene
<10
µg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
Nitrobenzene
<10
µg/L
1/13/12 18:21
CLR.
EPA 625 Rev 7/95
N-Nitrosodimethylamine
<10
µg/L
1/13/12 18:21
CLR
EPA 625 Rev 7/95
N-Nitrosodi-n-propylamine
<10
µg/L
1/I3/12 18:21
CLR
EPA 625 Rev 7/95
N-Nitrosodiphenylamiae
<10
µg/L
I/13/12 18:21
CLR
EPA 625 Rev 7195
Pentachloropbenol
<52
µg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
Phenmthrene
<10
µg/L
1/13/12 1821
CLR
EPA 625 Rev 7/95
Phenol
<10
µg/L
1/13/12 18:21
CLR
EPA 625 Rev 7/95
Pyrene
<10
µg/I.
1/13/12 1821
CLR.
EPA 625 Rev 7/95
Pyridine
<10
µg/L
1/13/12 1821
CLR
EPA 625 Rev 7195
Surrogate: 2.4.6-TrihromoohenW %
47.&138
1113112 18:21
CLR
EPA 625 Rev 7195
Surroaare: 2-Fluorobiahenvl 673 %
14110
1113112 18:11
CLR
EPA 625 Rev 7195
Surroaare: 1-Fhroroohenol 48.2 %
10-110
1113112 18:21
CLR
EPA 625 Rev 7195
State Cer6lcaGans Respectfully Submitted
NCDNR N11
NCDOH 03r714 Robert Dermer
USDA 93787 RobcdDe IXy
7RN Wabrpu� Pfft KW
b�"^�a@.krda.cvwrinwam.c CEO.
Pye 5 or6

H
Fayetteville Division
2592 Hope Mills Rd
Faycntville, NC 28306
910.864.1926 Phone
910.864.8774 Fax
Certificate of Analysis
Motive Entetprise -Apex
Mc Scott Dilling P110jut OeHall s Date Reported: January 31, 2012
ample - MthlySetdYr/Yrly
2232 Trn-Tea Roed Date Received: Jenuery 09, 2012
Apex NC, 27502 Setapleday: ScM Dillies Date Semplcd: January09, 2012
On" 001. Beat
1201121-01
' Analyte Result Unit Amlysis DaIdnine Analyst Method Qualifier
Surrogare: Nilrvbenzene-d5
67.0% 10-110
111311218:21
CLR
EPA 625 Rev 7195
Surrogate: Phenol45
36.9% 10-60.8
J113112 18.21
CLR
EPA 625Rev 7N5
.Sumeate'%rvhenvl-d14
594%16.8410
111311218:21
CLR
EPA 625 Rev 7/95
Turbidity
2.5 NTU
1/16/12 7S9
SA
EPA 100.1 H
LIBRARY SEAR~_ .
"lam with did not dfRteed arty perameiers greater flue 5a Rg/L
SVGA Ube search did not detected arty parameters gna than 50 M911-
Qualifier Dermitions
Ua Undetected
U Aoalyte inchdcd in the analysis, but not detected
H Analyze was prgwcd and/or analyzed outside of the analytical method bolding time
B Detected on the associated Method Blank
State Cert6catians:
Respectfully Submitted
NCONR all
NCDDM e37714
Robert Dermer
USDA 03787
Robot Deme, Division Manage
It�R�Ya+br Ynatarsi�nsa. N4 avi vov/mJMct vn and IMrv.;r. ra>mr Plw.conrarriM M.i.6m Yo�uger, RnlorLome m➢10.d6l-lent JamR Nab. AvNnr. er
pee..ote(dminrrAx.m a ]1.vBm.e. Cro. m newr.Eal.4dmkn6rcm.iib inn rm.ama a,yryoixrz
page 6 of 6

tVS aw ZL
Fayetteville Division
2592 Hope Mills Rd
Fayetteville, NC 28306
910.864.1920 Phone
910.864.8774 Fax
Certificate of Analysis
Motiva Enterprise -Apex
Mr. Scott Dilling Project: Outfall sample - Mthly/Semi-Annual
2232 Ten -Ten Road
Apex NC, 27502
Outfall 001, Effluent
1207447-01
Date Reported: August 06, 2012
Date Received: July 18, 2012
Date Sampled: July 18, 2012
Sampled By: Brown
Analyte Result Units Analyzed Analyzed By Method Qualifier
Analyzed by: Mivobw - Fayetteville Mvision
Flow Reading
210000
gal/day
7/18/12 9:00
DSD
Field
Nitrate as N
0.195
mg/L
7119/12 1:28
JAW
EPA 300.0
Nitrite asN
0.0641
mg/L
7/19/12 1:28
JAW
EPA300.0
Total Nitrogen
4.46
mg/L
8/I/12 16:30
JAG
Calculation
Oil & Grease (HEM)
13.8
mg/L
7/26/12 16:42
1R
EPA 1664
Phosphorus, Total
<0.050
mg/L
7/24/12 12:16
JAO
SM 20th Ed. 4500 P F
Total Suspended Solids
<5.00
mg/L
7/20/12 11:10
JR
SM 20th Ed. 2540 D
Total Kjeldahl Nitrogen
4.20
mg/L
8/1/12 16:30
JAO
SM 20th, 4500NC
B
Turbidity
3.3
NTU
7/18/12 16:50
DSK
SM 20th Ed. 2130 B
Aru*md by: Microbac Laboratories, Inc. - Chiragorand
l,l,l-Trichloroethane
<0.0010
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
1,1,2,2-Tetrachloroethane
<0.0010
mg/L
7129112 23:50
iln
EPA 624 Rev 7/95
U
1,1,2-Trichloroethane
<0.0010
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
],I-Dichloroethane
<O.0010
mg/L
7129/12 23:50
iln
EPA 624 Rev 7/95
U
l,l-Dichloroethene
<0.0010
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
1,2-Dichlorobenzene
<0.0020
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
1,2-Dichloroethane
<0.0010
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
1,2-Dichloropropane
<0.0010
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
1,3-Dichlorobenzene
<0.0020
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
1,4-Dichlorobenzene
<0.0020
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
2-Chloroethyl vinyl ether
<0.0020
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
2-Hexanone
<0.0050
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
Acetone
<0.0050
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
Ua
Benzene
<0.0010
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
Bromodichloromethane
<0.0010
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
Bromoform
<0.0010
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
Bromomethane
<0.0020
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7195
U
Carbon Disulfide
<0.0020
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
State Certifications;
Respectfully Submitted
NCDNR #II
NCDO14 N37714
USDA #3787
t-axiC,4_�
Bonnie K. Sanders, Administrative Assistant
Page 1 of 6

Microbac I
Motiva Enterprise - Apex
Mr. Scott Dilling
2232 Ten -Ten Road
Apex NC, 27502
Fayetteville Division
2592 Hope Mills Rd
Fayetteville, NC 28306
910,864.1920 Phone
910.864.8774 Fax
Certificate of Analysis
Project: Outfall sample - Mthly/Semi-Annual
Outfall 001, Effluent
1207447.01
Date Reported: August 06, 2012
Date Received: July 18, 2012
Date Sampled: July 18, 2012
Sampled By: Brown
Analyald by: Micron[ laboamries, Im. - CTImgola d
Carbon tetrachloride
<0.0010
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
Chlorobenzene
<0.0010
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
Chloroethane
<0.0020
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
Chloroform
<0.0010
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
Chloromethane
<0.0020
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
cis-1,3-Dichloropropene
<0.0010
mg/L
7/29112 23:50
iln
EPA 624 Rev 7/95
U
Dibromochloromethane
<0.0010
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
Ethylbenzene
<0.0010
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
Methylene chloride
<0.0020
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
Methyl-t-Butyl Ether
<0.0020
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
Tetrachloroethene
<0.0010
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
Ua
Toluene
<0.0010
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
Total 1,2-Dichloroethene
<0.0010
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
Total Xylenes
<0.0010
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
trans-1,2-Dichloroethene
<0.0010
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
trans-1,3-Dichloropropene
<0.0010
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
Trichloroethene
<0.0010
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
Trichlorofluoromethane
<0.0010
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
Vinyl Acetate
<0.0010
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
Vinyl chloride
<0.0020
mg/L
7/29/12 23:50
iln
EPA 624 Rev 7/95
U
Surrogate. 1,1-Dichlowethone-D4
110 %
80%- l32%
712912012 23:50
jln
EPA 624 Rev 7195
Swrogate: 4-8romoJluorobenzene
84.5 %
80'0 - 120%
712912012 23:50
jln
EPA 624 Rev 7195
Surrogate: Dibromopuoromethane
110 %
80% -110'0
712912012 23:50
iln
EPA 624 Rev 7195
Surrogate: Toluene-D8
92.8 %
80'f o - 110%
712912012 23:50
jln
EPA 624 Rev 7195
1,2,4-Trichlorobenzene
<0.01 I
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
1,2-Dichlorobenzene
<0.01I
mg/L
7125/1222:17
CR
EPA 625 Rev 7195
1,2-Diphenylhydrazine
<0.011
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
1,3-Dichlorobenzene
<0.011
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
State Certifications'.
NCDNR #II
NCDOH #37714
USDA #3787
Respectfully Submitted
Bonnie K. Sanders, Administrative Assistant
Page 2 of 6

Fayetteville Division
2592 Hope Mills Rd
Fayetteville, NC 28306
910.864.1920 Phone
910.864.8774 Fax
Certificate of Analysis
Motiva Enterprise -Apex Date Reported: August 06, 2012
Mr. Scott Dilling Project: OuHall sample - Mthly/Semi-Annual Date Received: July 18, 2012
2232 Ten -Ten Road Date Sampled: July 18, 2012
Apex NC, 27502 Sampled By: Brown
Outfall 001, Effluent
1207447-01
Analyte Result Units Analyzed Analyzed By Method Qualifier
Analyzed by: Microbac Laboratories, Inc. - Giex3oland
1,4-Dichlorobenzene
<0.011
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
2,2'-oxybis(1-chloropropane)
<0.011
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
2,4,5-Trichlorophenol
<0.01I
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
2,4,6-Tichlorophenol
<0.01I
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
2,4-Dichlorophenol
<0.011
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
2,4-Dimethylphenol
<0.011
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
2,4-Dinitrophenol
<0.053
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
2,4-Dinitrotoluene
<0.0I1
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
2,6-Dichlorophenol
<0.011
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
2,6-Dinitrotoluene
<0.01I
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
2-Chloronaphthalene
<0.011
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
2-Chlorophenol
<0.0I I
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
2-Methylnaphthalene
<0.0I I
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
2-Methylphenol
<0.011
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
2-Nitroaniline
<0.011
mg/L
7/25112 22:17
CR
EPA 625 Rev 7/95
2-Nitrophenol
<0.011
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
3,3'-Dichlorobenzidine
<0.053
mg/L
7/25/12 22:I7
CR
EPA 625 Rev 7/95
3/4-Methylphenol
<0.01I
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
3-Nitroaniline
<0.011
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
4,6-Dinitro-2-methylphenol
<0.026
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
4-Bromophenyl phenyl ether
<0.011
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
4-Chloro-3-methylphenol
<0.021
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
4-Chloroaniline
<0.0I I
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
4-Chlorophenyl phenyl ether
<0.0I1
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
4-Nitroaniline
<0.01 I
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
4-Nitrophenol
<0.053
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
Acenaphthene
<0.0I I
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7195
Acenaphthylene
<0.011
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
State Certifications: Respectfully Submitted
NCDNR #I1
NCDOH #37714
USDA #3787
Bonnie K. Sanders, Administrative Assistant
Page 3 of 6

Fayetteville Division
2592 Hope Mills Rd
Fayetteville, NC 28306
910.864.1920 Phone
910.864.8774 Fax
Certificate of Analysis
Motiva Enterprise - Apex
Mr. Scott Dilling Project: Outfall sample - Mthly/Semi-Annual
2232 Ten -Ten Road
Apex NC, 27502
Outfall 001, Effluent
1207447-01
Date Reported: August 06, 2012
Date Received: July 18, 2012
Date Sampled: July 18, 2012
Sampled By: Brown
Analyzed by: Mkrobw labDr rles, Inc. - (Tlogoland
Acetophenone
<0.011
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
Aniline
<0.01I
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
Anthracene
<0.0I I
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
Benzidine
<0.053
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
Benzo[a]anthracene
<0.011
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7195
Benzo[a]pyrene
<0.0I I
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
Benzo[b]fluoranthene
<0.0I I
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
Benzo[g,h,i]perylene
<0.0I I
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
Benzo[k]fluoranthene
<0.0I1
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
Benzoic acid
<0.011
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
Benzyl alcohol
<0.0I1
mg/L
7125/12 22:17
CR
EPA 625 Rev 7/95
Bis(2-chloroethoxy)methane
<0.0II
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7195
Bis(2-chloroethyl)ether
<0.0I I
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
Bis(2-ethylhexyl)phthalate
<0.011
mg/L
7125/12 22:17
CR
EPA 625 Rev 7/95
Butyl benzyl phthalate
<0.011
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
Carbazole
<0.0I I
mg/L
7/25112 22:17
CR
EPA 625 Rev 7/95
Chrysene
<0.0I I
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
Dibenz[a,h]anthracene
<0.011
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
Dibenzol'uran
<0.0I I
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
Diethyl phthalate
<0.0II
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
Dimethyl phthalate
<0.0I1
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7195
Di-n-butyl phthalate
<0.0I I
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
Di-n-octyi phthalate
<0.0I I
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
Fluoranthene
<0.011
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
Fluorene
<0.0I I
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
Hexachlorobenzene
<0.0II
mg/L
7/25/12 22:I7
CR
EPA 625 Rev 7/95
Hexachlorobutadiene
<0.011
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
Hexachlorocyclopentadiene
<0.0II
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
State Certifications: Respectfully Submitted
NCDNR #II n
NCDOH #37714 s,,`/p,
USDA #3787 td,Q/l.a_�
Bonnie K. Sanders, Administrative Assistant
Page 4 of 6

Fayetteville Division
2592 Hope Mills Rd
Fayetteville, NC 28306
910.864.1920 Phone
910.864.8774 Fax
Certificate of Analysis
Motive Enterprise - Apex
Mr. Soott Dilling Project: Outfall sample - Mthly/Semi-Annual
2232 Ten -Ten Road
Apex NC, 27502
01001, Effluent
1207447-01
Date Reported: August 06, 2012
Date Received: July 18, 2012
Date Sampled: July 18, 2012
Sampled By: Brown
Analyte Result Units Analyzed Analyzed By Method Qualifier
Analyzed by: Mlcmbac leborabwlM Inc. - Ctamgoland
Hexachloroethane
<0.011
Indeno[l,2,3cd]pyrene
<0.011
Isophorone
<0.0I I
Naphthalene
<0.0II
Nitrobenzene
<0.0II
N-Nitrosodimethylamine
<0.011
N-Nitrosodi-n-propylamine
<0.011
N-Nitrosodiphenylamine
<0.0II
Pentachlorophenol
<0.053
Phenanthrene
<0.011
Phenol
<0.011
Pyrene
<0.011
Pyridine
<0.011
Surrogate: 2,4,6-7ilbromophenol
104 %
Surrogate: 2-Fluorobipherryl
52.5 %
Surrogate: 2-Fluorophenol
46.7 %
Surrogate: Nifrobenzene-d5
54.5 %
S�gate: Phenol-d5
41.4 %
Sw gare: Terphenyl-d14
64.1 %
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
ri
7/25/12 22:17
CR
EPA 625 Rev 7/95
mg/L
7/25112 22:17
CR
EPA 625 Rev 7/95
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
ri
7/25/12 22:17
CR
EPA 625 Rev 7/95
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7195
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
mg/L
7/25/12 22:17
CR
EPA 625 Rev 7/95
47.8%-138%
712512012 12:17
CR
EPA 625 Rev 7195
10•00 -11000A
712512012 2237
CR
EPA 625 Rev 7195
10% - 110a0
712512012 22:17
CR
EPA 625 Rev 7195
1000 - 110%
712512012 22.17
CR
EPA 625 Rev 7195
10% - 60.8%
7125M2 22:17
CR
EPA 625 Rev 7195
16 8% -110a/
712512012 22:17
CR
EPA 625 Rev 7195
LIBRARY SEARCH:
VOA Library search did not detected any parameters greater than 50 mg/L
SVGA Library snatch dM not detected any parameters greater roan 50 mg/L
State Certifications:
NCDNR K11
NCDOH #37714
USDA 43787
Respectfully Submitted
Bonnie K. Sanders, Administrative Assistant
Page 5 of 6

Motiva Enterprise -Apex
Mr. Scott Dilling
2232 Ten -Ten Road
Apex NC, 27502
Notes and Definitions
Us Undetected
Fayetteville Division
2592 Hope Mills Rd
Fayetteville, NC 28306
910.864.1920 Phone
910.864.8774 Fax
Certificate of Analysis
Project: Outfall sample - Mthly/Semi-Annual
Analyte included in the analysis, but not detected
Detected in the associated Method Blank
State Certifications.
NCDNR #11
NCDOH #37714
USDA #3787
Date Reported August 06, 2012
Date Received: July 18, 2012
Date Sampled: July 18, 2012
Sampled By: Brown
Respectfully Submitted
Bonnie K. Sanders, Administrative Assistant
Page 6 of 6

Attachment III
Map of Facility and Surrounding Area

Vvi
Mill
'•r-
'I
i
XWE
t
s '
9
I
Ili
f��
R
fr it
1
1 0.3 1. I•
1 0.2 1 O�6 1:
WLFL-TV (Raleigh), USGS Apex (NC) Quadrangle 'I
Projection is UTM Zone 17 NAD83 Datum r
M=-6.715
G=1.276
Motiva Enterprises Raleigh Terminal Outfall 001

Attachment IV
Diagram of the Wastewater Treatment System

Loading Rack
Stormwater
Attachment II
Motiva Enterprises LLC
Raleigh Terminal
Recovered
Product Sent Offsite
SPCC Tank
Containment
Pond
Outfall 001
Unnamed Tributary to Middle Creek
Tank Farm
Stormwater
(Diked Area)

Attachment V
Ethanol Storage Email Notification

Robinson, Brittany
From:
Guerra, Bob <[e-mail]>
Sent:
Tuesday, June 19, 2012 2:12 PM
To:
Robinson, Brittany
Cc
Zarate, Marco
Subject:
RE: Motiva Raleigh Terminal NPDES Permit NC0022217
Thank you the notification. I will print this email and place it in the files
From: Robinson, Brittany rmailto:brittanv.robinson(Clurs.com1
Sent: Tuesday, June 19, 2012 1:49 PM
To: Guerra, Bob
Cc: Zarate, Marco
Subject: Motiva Raleigh Terminal NPDES Permit NC0022217
Dear Mr. Guerra,
As we previously discussed, the Motiva Raleigh terminal (NPDES Permit NC0022217) stores ethanol on site, in addition
of petroleum hydrocarbon fuels. The facility applied for and obtained approval from the Division of Air Quality for this
change; however, the site failed to notify the Division of Water Quality. you noted that since this did not affect the
discharge permit of the facility and rather the description of materials stored in the Supplemental Information Page of
the permit, the facility should wait and address as part of the NPDES Permit Renewal due in November 2012. The
purpose of this email is to notify your office of this change and that Motiva will address in its next NPDES permit renewal
due October 30, 2012. If you have any questions, please contact Mr. Marco Zarate, Environmental Support Person for
the site, at 919-461-1342.
Brittany Robinson, PE
URS Corporation
1600 Perimeter Park Drive
Suite 400
Morrisville, NC 27560
Work: 919.461.1455
Cell: 919.888.6453
Fax: [phone]
Email: Brittanv.Robinson(@urs.com
Note My Email Address has changed
This e-mail and any attachments contain URS Corporation confidential information that may be proprietary or privileged. If you
receive this message in error or are not the intended recipient, you should not retain, distribute, disclose or use any of this
information and you should destroy the e-mail and any attachments or copies.

Attachment VI
NPDES Permitting Requirements for
Petroleum Bulk -Storage Surface Storage Greater
than One Million Gallons 2005 — Permitting Strategy

NPDES Permitting Requirements for
Petroleum Bulk -Storage
Surface Storage Greater than One Million Gallons
2005 — Permitting Strategy
Introduction / Background
North Carolina's Division of Water Quality issues individual, point -source NPDES permits for
stormwater to all vehicle -fuel and petroleum terminals with above ground storage capacities exceeding
one million gallons. Storages exceeding this volume are specifically excluded from Stormwater
General Permit NCG080000, and therefore require a point -source discharge permit.
This document is intended to update the 2001 strategy for up -coming permit cycles. (For a history of
this permitting strategy, see the Division's 2001 Permitting Strategy: Permit Requirements for
Discharges from Oil and Petroleum Storage Facilities, version. 30A12001.)
Bulk -storage facilities typically retain and manage stormwater behind secondary -containment dikes.
Diked areas are designed with sufficient volume to confine product in the event of a tank failure.
Stormwater, often comprising several storm events, is held behind these dikes in proximity to the
tanks and appurtenant piping. The permittee typically holds this stormwater for controlled release.
Permitting Requirements
1. Flow — Discharge Rate and Duration
Instructions to Permit Writer: Establish average and maximum flows for the previous cycle for the
purpose of calculating limits for various parameters of concern. These should be noted in the Fact
Sheet.
Stormwater flow in bulk -storage permits is not limited. Flow measurements are required, however, and
methods shall reflect a typical controlled release discharge event. Flow shall be monitored, reported,
and recorded using one of four approved methods. The following instructions shall appear as a
footnote in permit section A. (L) Effluent Limits and Monitoring Conditions:
"Flow shall be monitored with each discharge event — During periods of no
flow, the Permittee shall submit a signed, monthly Discharge Monitoring Report
(DMR) indicating "No discharge." Flow may be monitored using any one of
four methods:
a) measure flow continuously;
b) calculate flow (see Rational Equation below) based on total rainfall per
unit area draining to the outfall; exclude built -upon areas (best method
for facilities with large runoff -collection ponds);
c) estimate flow at 20-minute intervals during the entire discharge event; or
d) report flow based on discharge pump logs."
Page 1 of 6
Version 09Sep 2005

NPDES Permitting Requirements for
Petroleum Bulk -Storage
Surface Storage Greater than One Million Gallons
2005 — Permitting Strategy
The Rational Equation: Q=KuCIA, where:
Q = flow (peak flow rate (cfs or m''/sec)
Ku = units conversation factor = 1.008 for U.S. standard units (usually ignored because it
is so close to 1), or 0.278 for SI units
C = dimensionless runoff coefficient for the watershed, loosely defined as the ratio of
runoff to rainfall
I = intensity of rainfall taken from the intensity -duration -frequency curves for the
specified design return period at the time ojconcentration, tc (in/h or mm/h). tc =
time of concentration (time after the beginning of rainfall excess when all portions of
the drainage basin are contributing simultaneously to flow at the outlet).
A = area of tributary watershed (acres or km2)
The rational equation is used to calculate the runoff from a region, given:
• the runoff coefficient which accounts for infiltration and other potential losses in the
region,
• the rainfall intensity to the region,
• the time it takes for runoff to travel from the region's upper reaches to its outlet, and
• the region's drainage area.
2. Acute Toxicity.
Instructions to Permit Writer: Evaluate toxicity compliance. Replace toxicity test method if different
from: Fathead Minnow (Pimephales promelas), 24-hr definitive, LC-50> 100% (TAE6C). Concerning
monitoring frequency:
If any annual WET test demonstrates toxicity [failure for pass/fail or LC-50
reported less than 100 %], then increase WET testing to quarterly.
If Permittee tests annually with no demonstration of toxicity, continue
annual monitoring.
If Permittee tests quarterly with no demonstration of toxicity (i.e., the last 5
consecutive tests have "passed" or demonstrate LC-50 > 100%), then reduce
monitoring to annually.
Rationale: Acute toxicity testing (as opposed to chronic testing) is deemed appropriate to evaluate the
end -of -pipe immediate impact of short-term, episodic discharges. All Permit Effluent Limitations and
Monitoring Conditions shall include the following Wet Testing footnote:
"The Permittee shall collect Acute Toxicity samples concurrently with BTEX sampling."
[Reference item 4. below]:
Page 2 of 6
Version 09Sep 2005

NPDES Permitting Requirements for
Petroleum Bulk -Storage
Surface Storage Greater than One Million Gallons
2005 — Permitting Strategy
3. Total Suspended Solids (TSS) / Oil and Grease
Instructions to Permit Writer: Oil and Grease - Monitor monthly - No Limit
Instructions to Permit Writer: TSS - Monitor monthly; Daily Maximum Limit, 45.0 mgR.
Monitoring Footnote: "Where possible, the grab sample for Oil and
Grease should be skimmed from the water surface of a quiescent (calm
water) zone."
Rationale: A daily maximum TSS limit of 45 mg/L is recommended as a minimum stormwater
management practice. Although historically, TSS and Oil and Grease have not been significant
problems in oil -terminal stormwater discharges. TSS and Oil and Grease are deemed good general
indicators of effluent stormwater quality for these facilities.
4. BTEX
Instructions to Permit Writer: Monitor monthly. If data indicate RP, add limit and monitor monthly.
Rationale: Benzene, toluene, ethylbenzene and xylene (BTEX) are common toxicants found in fuel
petroleum. Previous scans for volatile and semi -volatile compounds included BTEX (methods EPA
624/625). A review of these scans revealed BTEX frequently in stormwater, while other 624/625
parameters were uncommon or never detected. Therefore, future permits shall require BTEX
monitoring for lighter fuels and naphthalene for diesel fuel (see 6.).
5. Naphthalene (for Diesel)
Instructions to Permit Writer: Monitor monthly — No limit
Rationale: Naphthalene is commonly found in heavier fuels, such as fuel oil or diesel. Most bulk -
terminals store heavier fuels. (NOTE: If the permittee can demonstrate to the Division that its facility
does not now, nor has ever, stored diesel fuel or other heavy fuels, it may petition to remove this
requirement from the permit.) The Division recommends no permit limit because EPA has established
no criteria for naphthalene.
Page 3 of 6
Version 09Sep 2005

NPDES Permitting Requirements for
Petroleum Bulk -Storage
Surface Storage Greater than One Million Gallons
2005 — Permitting Strategy
6. EPA Methods 624/625 (as applicable)
Instructions to Permit Writer: Conduct RPA on parameter "hits," but only those with NC stream
standards and /or federal criteria*.
• if RP, monitor monthly and add permit limit.
• if detected (but no RP), Monitor semi-annually.
• if no parameters detected other than BTEX, delete 624/625 from permit.
Rationale: This strategy serves to resolve previous investigations into the need to conduct EPA
screening by test Methods 624/625. For Permittees assigned to conduct volatile and semi -volatile
scans who did not comply with the permit, assessment will be considered. RPA will be restricted to
parameters of concern (POC) with North Carolina State water quality standards and federal criteria.
'NOTE: the Permit Writer shall use aquatic life or Human Health standards as appropriate.
7. Tank Solids, Tank Bottom Water, and Rag Layer
Instructions to Permit Writer: Keep the footnote:
"Direct discharge of tank solids, tank bottom water, or the rag layer is not
permitted."
Rationale: Tank -bottom sediments accumulate over 4-5 years (typically %- to 1-inch thick) and
invasive rainwater (1-6 inches thick) regularly settles to the bottom of any bulk -storage container.
These layers typically mix at the interface with overlying fuel to form a %-inch-thick foamy waste
called a "rag layer." Because of the relatively high levels of hydrocarbon compounds contained in
these three wastes layers, their untreated discharge is not permitted.
8. Hydrostatic Tank Testing
Instructions to Permit Writer: Keep the footnote:
The permittee shall not discharge tank solids, tank bottom water, or the
tank rag layer. The permittee shall not discharge tank (or pipe) contents
following hydrostatic testing unless benzene concentration is less than
1.19 µg/L and toluene concentration is less than 11 µg/L.
Rationale: As routine container maintenance, bulk -storage Permittees typically conduct hydrostatic
tank testing every five to six years. Prior to testing, the Permittee empties the tank of product, and
properly disposes of tank -bottom wastes (see 7. above). Tanks are cleaned, coated, and welded (as
Page 4 of 6
Version 09Sep 2005

NPDES Permitting Requirements for
Petroleum Bulk -Storage
Surface Storage Greater than One Million Gallons
2005 — Permitting Strategy
necessary), then refilled with water for hydrostatic pressure testing. Some facilities use stream or lake
water, while others use potable city water. Testing water is then drained from the tank.
Because this test -water may contain hydrocarbons or other toxicants, the Permittee shall sample and
analyze this waste prior to direct discharge. Should benzene, toluene, and/or other parameter levels
exceed their respective water quality standard, direct discharge of this waste is not permitted.
Permitting Special Considerations
9. Methyl Tertiary Butyl Ether (MTBE) in Water Supply (WS) Waters
Instructions to Permit Writer: Evaluate compliance and document analyte database in Fact Sheet.
• If not detected, lower monitoring frequency to quarterly.
• If detected, continue monthly monitoring and require Permittee to
submit an Action Plan within 12 months of the permit effective date.
Rationale: In 2001, the EPA tagged MTBE as a potential human carcinogen. North Carolina
responded to EPA's ongoing evaluations of this "anti -knock" additive by implementing efforts to limit
MTBE in discharges to water supply (WS) waters. Although North Carolina has not yet adopted a
water quality standard for MTBE, monitoring of this potential human health risk will continue in order
to provide data for future evaluation.
10. Benzene in Water Supply (WS) Waters
Instructions to Permit Writer: Evaluate RP using Human Health Standard (L 19 µg/L).
If RP, keep/add permit limit: Daily Max = 1.19 µg/L (allow dilution
using "annual average" flow).
If no RP, delete limit; continue monitoring monthly — all permits.
Rationale: Benzene is identified as a human carcinogen and therefore poses potential health risk to
drinking water. Therefore, a limit of 1.19 µg/L (Water Quality Standard) shall apply to all WS-
classified waters. The Division shall consider dilution (i.e., multiply the standard x dilution under
"average annual flow" conditions to calculate the permit limit). If the permittee discharges under
"zero -flow" conditions, the standard shall become the permit limit.
Page 5 of 6
Version 09Sep 2005

NPDES Permitting Requirements for
Petroleum Bulk -Storage
Surface Storage Greater than One Million Gallons
2005 — Permitting Strategy
11. Phenol in Water Supply (WS) Waters
Instructions to Permit Writer: Monitor: monthly. Evaluate "drainage -specific" RP. [See attached
Memorandum from Joe Corporon, September 08, 2005, for revised guidance calculations for the Paw
Creek area (total: 8 dischargers).]
• If RP, add limit: Daily Maximum distributed equally among all outfalls.
• If no RP, delete limit; continue monitoring monthly.
The Division shall determine permit limits based on a NC State standard for chlorinated phenolic
compounds of 1 µg/L. The Division shall evaluate each permittee's limit using drainage -specific
calculations for allowable phenol loading. This strategy dates from the 1980s [see Division memos for
Guilford County (1983); updated calculations governing dischargers to the Catawba River Basin
(2001) and Cape Fear River Basin (2003)].
Rationale: Discharges from fuel hydrocarbon bulk -storage facilities have a potential to contain
phenol, based on previous data statewide. Phenol, when combined with chlorine, forms chlorinated
phenolic compounds with potential to taint fish tissue and drinking water, thus degrading taste and
odor (organoleptic concerns).
12. Turbidity Monitoring
Instructions to Permit Writer:
• if detected, Monitor Quarterly
• if not detected, delete from permit.
• If RP exists (based on 50 NTU) - add limit and monitor Monthly.
Rationale: EPA questioned the potential of these facilities to violate stream standards because little
data were available. Sufficient data now exist to evaluate "reasonable potential" for a facility to exceed
50 NTU. The Permit writer shall use the entire permit cycle database (for those monitoring quarterly),
and the most recent two years of data (for those monitoring monthly). For all facilities, the following
shall appear on the Effluent Limitations and Monitoring page as a footnote:
"Turbidity — Effluent shall not cause receiving stream turbidity to exceed 50
NTU. If receiving stream background turbidity exceeds 50 NTU, effluent shall
not cause this background value to increase."
Page 6 of 6
Version 09Sep 2005