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Home My WebLink AboutWQ0021826_2023 Residual Annual Report_20240228 (2)Initial Review Reviewer nathaniel.thorn burg Is this submittal an application? (Excluding additional information.) * Yes No If not an application what is the submittal type?* Annual Report Residual Annual Report Additional Information Other Annual Report Year* 2023 Permit Number (IR) * WQ0021826 Applicant/Permittee City of Roxboro Email Notifications Does this need review by the hydrogeologist? * Yes No Regional Office Raleigh CO Reviewer Admin Reviewer Wanda Gerald Submittal Form Project Contact Information Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence. Name* Lysa Finnerty Email Address* Ifinnerty@SYNAGRO.com Project Information ......................... Application/Document Type* New (Fee Required) Modification - Major (Fee Required) Renewal with Major Modification (Fee Required) Annual Report Additional Information Other Phone Number* 4105376150 Modification - Minor Renewal GW-59, NDMR, NDMLR, NDAR-1, N DAR-2 Residual Annual Report Change of Ownership We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type:* Wastewater Irrigation High -Rate Infiltration Other Wastewater Reclaimed Water Closed -Loop Recycle Residuals Single -Family Residence Wastewater Other Irrigation Permit Number:* WQ0021826 Has Current Existing permit number Applicant/Permittee Address* 435 Williams Court, Ste 100, Baltimore, MD 21220 Facility Name* City of Roxboro Class B Residuals Program Please provide comments/notes on your current submittal below. Submission of the 2023 Annual Report for City of Roxboro, NC At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here. (Application Form, Engineering Plans, Specifications, Calculations, Etc.) Roxboro NC 2023 Annual Report FINAL.pdf 11.28MB Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger than upload limit. * By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Mail payment to: NCDEQ — Division of Water Resources Attn: Non -Discharge Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Signature Alva �Cit'wt%tl� Submission Date 2/28/2024 435 Williams Court, Suite 100 Baltimore, MD 21220 www.synagro.com FEBRUARY 28, 2024 NCDEQ Division of Water Resources Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: 2023 Annual Report for Permit No. WQ0021826 Dear NCDEQ: SYNAGRO Synagro is submitting one electronic copy of the above referenced report on behalf of the City of Roxboro, NC. If you have any questions or need additional information, please do not hesitate to contact Brooks Lockhart at (336) 599-3116 ext. 8 or Adam Brigman at (704) 650-4341. Sincerely, P '-MY-- Derrick Shivar Environmental Compliance Manager Enclosures cc: Brooks Lockhart, City of Roxboro YOUR PARTNER FORA CLEANER, GREENERWORLD CITY OF ROXBORO, NC RESIDUALS LAND APPLICATION PROGRAM Permit No. WQ0021826 2023 ANNUAL REPORT City of Roxboro, NC Residuals Land Application Program 2023 Annual Report TABLE OF CONTENTS 1. Certification Form and Annual Operations Summary 2. Annual Residual Sampling Summary Forms and Residuals Analyses 3. Annual Land Application Field Summary Forms 4. TCLP Analysis 5. Pathogen ReductionNector Attraction Reduction 6. Soil pH & Lime Application Records 7. Soil Analyses SECTION 1 ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit #: W00021826 County Person Year 2023 Facility Name (as shown on permit) City of Roxboro WWTP & WTP NPDES No. NCO021024 Land Application Operator Synag.ro Phone# (336) 998-7150 Land application of residuals as allowed by the above permit occurred during the past calendar year? X YES NO. if NO, skip PartA, and Part Band proceed to Part C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A — Residuals Application Summary: Total number of application fields in the permit: 13 Total number of fields utilized for land application during the year: 6 Total amount of dry tons applied during the year for all application sites: 215.06 Total number of acres utilized for land application during the year: 62.60 Part B — Annual Compliance Statement: Facility was compliant during calendar year 2023 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Quality X YES NO. If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T. I 105(a) or the Pollutant Loading Rates in 15A NCAC 02T .1 105(b) (Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All monitoring and reporting requirements in 15A NCAC 02T .1 1 I I were complied with (applicable to 40 CFR Part 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. l I . Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13, All buffer requirements as specified on the permit were maintained during each application of residuals. Part C — Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. 1 am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. Brooks Lockhart. Citv Manaeer Permittee Name and Title (type or print) Signature of Prepar * Date (if different from Permittee) Signature of Pernlittee Date 2/01 /2024 S of LaTVApplier Date (if different7rom Permittee and Preparer) *Preparer is defined in 40 CFR Part 503.9(r) and ISA NCAC 02T .1102 (26) DENR FORM ACF (12/2006) OPERATIONS SUMMARY - LAND APPLICATION - NORTH CAROLINA ALL COUNTIES - ALL SITES DATE RANGE: 1/1/2023 - 12/31/2023 ROXBORO,NC ROXBORO, NC WWTP AEROB. DIGESTED CAKE MONTH/YEAR September 2023 October 2023 November 2023 TOTAL Units Key: D - Dry Tons; G — Gallons; W — Wet Tons; Y — Cubic Yards Report Date: 2/9/2024 5:09:52 PM AMOUNT UNIT DRY TONS UNIT DRY METRIC TONS 459.00 Y 79.25 D 71.88 119.00 Y 17.14 D 15.54 824.00 Y 118.67 D 107.64 1,402.00 Y 215.06 D 195.06 SECTION 2 ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WO Permit Number- W000218M Laboratory: Facility Name: ROXBORO, NC Waypoint Analytical Virginia Inc Residual Source WO # or NPDES#: NCO021024 VWWTP Name: ROXBORO WWTP Residual Analysis Data Product Type Sample or Composite Date AEDCAK 01126/23 AEDCAK 10123/23 Parameter (mgfkg dry weight) Ceiling Conc. Limit Percent Solids (%) NA 20.50 17.10 Arsenic 75 4.22 5.91 Cadmium 85 1,14 1.9 Copper 4300 410 2500 Chromium NA 30.3 42 Lead 840 34.1 46.6 Mercury 57 0.785 0.06 Molybdenum 75 8.15 10.5 Nicl i 420 18 28.5 Selenium 1D0 4.46 6,2 Zinc 7500 863 1700 Total Phosphorus NA 16200 24300 TKN NA 52700 33700 Ammonia -Nitrogen NA 693 749 Nitrate and Nitrite NA 28.6 924 For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits. 'I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel property gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of tones and imprisonment for knowing violations," -��C gn. Signature of Preparer' 'Preparer is defrned in 40 CFR Part 503,9(r) and 15 A NCAC 2T.1102(26) Date DENR FORM RSSF (1212006) Printed, 2/8/2024 23530 PM For: 2102 01 ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed, tOiQ Permit Number: WQ0021826 Laboratory: Facility Name: ROXBORO, NC WaypointAnalytica! Virginia Inc. Residual Source NPDES ■ or WQ#: NCO021024 WWTPName: ROXBOROWWTP Residual Analysis Data Product Type AEDCAK AEDCAK Sample or Composite Date 01126123 10123/23 Parameters (mgfkg dry weight) Aluminium 16100 53300 Calcium 10700 10500 Magnesium 2620 2470 PH (s.u.l 7.70 5.60 Potassium 2800 1730 Sodium 576 696 PAN 15975 11181 SAR (Ratio) 0,5842 0.6546 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordiance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations' Y.- Signature of PreparerDate 'Pmparer is defined in 40 CFR Pan 503.9(r) and 15 A NCAC 2T.1102(26) Printed: 218/2024 2r35.09 PM For: 2102 01 DENR FORM RSSF-B (12t2006) Waypointo ANALYTICAL 2/8/2023 Synagro Central LLC/ Roxboro Mary Brewer 284 Boger Road Mocksville, NC, 27028 Ref: Analytical Testing Report Number: 23-027-0006 Project Description: Roxboro WW rP 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Dear Mary Brewer: Waypoint Analytical Virginia, Inc. received sample(s) on 1/27/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table if applicable. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information Sincerely, &;'-� AldA� Brandi Watson Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 8 • 7621 Whitepine Road, Richmond, VA 23237 Waypoint Main 804-743-9401 0 Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com Sample Summary Table Report Number: 23-027-0006 Client Project Description: Roxboro WWTP Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 60569 Storage Pad Solids 01/26/2023 12:55 01/27/2023 60569 Storage Pad Solids 01/26/2023 12:55 01/27/2023 60569 Storage Pad Solids 01/26/2023 12:55 01/27/2023 60569 Storage Pad Solids 01/26/2023 12:55 01/27/2023 60569 Storage Pad Solids 01/26/2023 12:55 01/27/2023 60569 Storage Pad Solids 01/26/2023 12:55 01/27/2023 60569 Storage Pad Solids 01/26/2023 12:55 01/27/2023 60569 Storage Pad Solids 01/26/2023 12:55 01/27/2023 SM-4500-NH3C WP MTN 9045D WP MTN 4500NO3F-2011 WP MTN 6010D WP MTN SW-7471B WP MTN SM-4500-NH3C-TKN WP MTN SM-2540G WP MTN WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN Page 2 of 8 WayPANALYTICAL 46487 Synagro Central LLC/ Roxboro Project Mary Brewer 284 Boger Road Information Mocksville , NC 27028 Report Number : 23-027-0006 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Roxboro WWTP REPORT OFANALYSIS Report Date : 02/08/2023 Received : 01/27/2023 Brandi Watson Lab No : 60569 Sample ID : Storage Pad Matrix: Solids Sampled: 1/26/2023 12:55 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Moisture 79.5 % 0.010 1 02/02/2317:14 CJD SM-2540G Potassium 2800 mg/Kg - dry 48.8 1 02/02/23 22:01 TJS 6010D Sulfur 7320 mg/Kg - dry 48.8 1 02/02/23 22:01 TJS 6010D Calcium 10700 mg/Kg - dry 244 1 02/02/23 22:01 TJS 6010D Magnesium 2620 mg/Kg - dry 24.4 1 02/02/23 22:01 TJS 6010D Sodium 576 mg/Kg - dry 122 1 02/02/23 22:01 TJS 6010D Iron 15700 mg/Kg - dry 48.8 1 02/02/23 22:01 TJS 6010D Aluminum 16100 mg/Kg - dry 24.4 1 02/02/23 22:01 TJS 6010D Manganese 634 mg/Kg - dry 2.44 1 02/02/23 22:01 TJS 6010D Copper 410 mg/Kg - dry 2.44 1 02/02/23 22:01 TJS 6010D Zinc 863 mg/Kg - dry 6.10 1 02/02/23 22:01 TJS 6010D Cadmium 1.14 mg/Kg - dry 0.488 1 02/02/23 22:01 TJS 6010D Chromium 30.3 mg/Kg - dry 1.22 1 02/02/23 22:01 TJS 6010D Nickel 18.0 mg/Kg - dry 1.22 1 02/02/23 22:01 TJS 6010D Lead 34.1 mg/Kg - dry 1.46 1 02/02/23 22:01 TJS 6010D Arsenic 4.22 mg/Kg - dry 2.44 1 02/03/23 16:55 TJS 6010D Mercury 0.785 mg/Kg - dry 0.771 1 02/02/23 15:23 JTR SW-7471B Selenium 4.46 mg/Kg - dry 2.44 1 02/02/23 22:01 TJS 6010D Molybdenum 8.15 mg/Kg - dry 1.22 1 02/02/23 22:01 TJS 6010D Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit Page 3 of 8 �' WayP 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com 46487 Synagro Central LLC/ Roxboro Project Roxboro WWTP Mary Brewer Report Date : 02/08/2023 284 Boger Road Information : Received : 01/27/2023 Mocksville , NC 27028 Brandi Watson Report Number : 23-027-0006 REPORT OFANALYSIS Lab No : 60569 Matrix: Solids Sample ID : Storage Pad Sampled: 1/26/2023 12:55 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Ammonia Nitrogen 693 mg/Kg - dry 488 1 02/07/23 13:00 CLP SM-4500-NH3C Nitrate+Nitrite-N 28.6 mg/Kg - dry 21.3 1 02/02/23 15:05 ZBD 4500NO3F-2011 Organic N 52000 mg/Kg - dry 1220 1 02/03/23 10:30 CALCULATION pH 7.7 S.U. 1 02/03/2315:43 SAR 9045D Total Solids 20.5 % 0.010 1 02/02/23 17:14 CJD SM-2540G Total Kjeldahl Nitrogen 52700 mg/Kg - dry 1220 1 02/03/23 10:30 JPJ ;M-4500-NH3C-TKI` Phosphorus 16200 mg/Kg - dry 24.4 1 02/02/23 22:01 TJS 6010D Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit Page 4 of 8 Waypointo ANALYTICAL Client: Synagro Central LLC/ Roxboro Project: Roxboro VWVfP Lab Report Number: 23-027-0006 Date: 2/7/2023 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com CASE NARRATIVE Metals Analysis Method 601 OD Sample 50060 (OIM-LOK 751) Analyte: Aluminum QC Batch No: 1-661849/1-661575 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 50060 (OIM-LOK 751) Analyte: Calcium QC Batch No: 1-661849/1-661575 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 50060 (OIM-LOK 751) Analyte: Iron QC Batch No: 1-661849/1-661575 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 50060 (OIM-LOK 751) Analyte: Potassium QC Batch No: 1-662058/1-661575 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 50060 (OIM-LOK 751) Analyte: Magnesium QC Batch No: 1-661849/1-661575 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 50060 (OIM-LOK 751) Analyte: Manganese QC Batch No: 1-661849/1-661575 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 50060 (OIM-LOK 751) Analyte: Phosphorus QC Batch No: 1-661849/1-661575 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 50060 (OIM-LOK 751) Analyte: Lead Page 5 of 8 Waypointo ANALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com QC Batch No: 1-661849/1-661575 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post digestion spike was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 50060 (OIM-LOK 751) Analyte: Sulfur QC Batch No: 1-661849/1-661575 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 50060 (OIM-LOK 751) Analyte: Zinc QC Batch No: 1-661849/1-661575 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Page 6 of 8 WayPAoInt.. NALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Shipment Receipt Form Customer Number: 46487 Customer Name: Synagro Central LLC/ Roxboro Report Number: 23-027-0006 Shipping Method 0 Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client 0 Courier 0 Other: Thermometer ID: Shipping container/cooler uncompromised? * Yes 0 No Number of coolers/boxes received Custody seals intact on shipping container/cooler? 0 Yes 0 No Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? # Yes 0 No COC agrees with sample label(s)? # Yes 0 No COC properly completed # Yes 0 No Samples in proper containers? # Yes 0 No Sample containers intact? # Yes 0 No Sufficient sample volume for indicated test(s)? # Yes 0 No All samples received within holding time? # Yes 0 No Cooler temperature in compliance? # Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. # Yes 0 No Water - Sample containers properly preserved Yes 0 No 0 N/A Water - VOA vials free of headspace 0 Yes 0 No N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A F_ High concentration container (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low concentration EnCore samplers (48 hr) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes * No Comments: Signature: IDavid Lennon Date & Time: 01/27/2023 12:33:55 Page 7 of 8 .� 91 m z wm � m 2 p m Z -u m >a 3� K r a m m .r m m LZ cc n = c M a t CD CL 0- m a Cr K cli �� r �r 3� ra m� vw m �m m o M� CD 0 m CD C] J. cr Page 8 of 8 OI j n v 4t mm im .-ST .V J� m mo g°; C; 3 my vv I b 2 m m Q m Waypointo ANALYTICAL 11 /8/2023 Synagro Central LLC/ Roxboro Mary Brewer 284 Boger Road Mocksville, NC, 27028 Ref: Analytical Testing Report Number: 23-297-0005 Project Description: Roxboro 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Dear Mary Brewer: Waypoint Analytical Virginia, Inc. received sample(s) on 10/24/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table if applicable. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information Sincerely, &;'-� AldA� Brandi Watson Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 7 • 7621 Whitepine Road, Richmond, VA 23237 Waypoint Main 804-743-9401 0 Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com Sample Summary Table Report Number: 23-297-0005 Client Project Description: Roxboro Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 63786 Roxboro Solids 10/23/2023 15:10 10/24/2023 63786 Roxboro Solids 10/23/2023 15:10 10/24/2023 63786 Roxboro Solids 10/23/2023 15:10 10/24/2023 63786 Roxboro Solids 10/23/2023 15:10 10/24/2023 63786 Roxboro Solids 10/23/2023 15:10 10/24/2023 63786 Roxboro Solids 10/23/2023 15:10 10/24/2023 63786 Roxboro Solids 10/23/2023 15:10 10/24/2023 63786 Roxboro Solids 10/23/2023 15:10 10/24/2023 SM-4500-NH3C WP MTN 9045D WP MTN 4500NO3F-2016 WP MTN 6010D WP MTN SW-7471B WP MTN SM-4500-NH3C-TKN WP MTN SM-2540G WP MTN WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN Page 2 of 7 WayPANALYTICAL 46487 Synagro Central LLC/ Roxboro Project Roxboro Mary Brewer 284 Boger Road Information Mocksville , NC 27028 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Report Number : 23-297-0005 REPORT OFANALYSIS Report Date : 11/08/2023 Received : 10/24/2023 Brandi Watson Lab No : 63786 Matrix: Solids Sample ID : Roxboro Sampled: 10/23/2023 15:10 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Moisture 82.9 % 0.010 1 10/26/2316:12 CAH SM-2540G Sulfur 11300 mg/Kg - dry 58.5 1 10/27/23 23:54 JTR 6010D Calcium 10500 mg/Kg - dry 292 1 10/27/23 23:54 JTR 6010D Aluminum 53300 mg/Kg - dry 29.2 1 10/27/23 23:54 JTR 6010D Manganese 994 mg/Kg - dry 2.92 1 10/27/23 23:54 JTR 6010D Organic N 32940 mg/Kg - dry 1462 1 11/07/23 07:09 CALCULATION Nickel 28.5 mg/Kg - dry 1.46 1 10/27/23 23:54 JTR 6010D Lead 46.6 mg/Kg - dry 1.75 1 10/27/23 23:54 JTR 6010D Arsenic 5.91 mg/Kg - dry 2.92 1 10/27/23 23:54 JTR 6010D Selenium 6.20 mg/Kg - dry 2.92 1 10/27/23 23:54 JTR 6010D Test Results Units MQL DF Date / Time By Analytical Analyzed Method Total Solids 17.1 % 0.010 1 10/26/23 16:12 CAH SM-2540G Phosphorus 24300 mg/Kg - dry 29.2 1 10/27/23 23:54 JTR 6010D Copper 2500 mg/Kg - dry 2.92 1 10/27/23 23:54 JTR 6010D Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit Page 3 of 7 WayPANALYTICAL 46487 Synagro Central LLC/ Roxboro Project Roxboro Mary Brewer 284 Boger Road Information Mocksville , NC 27028 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Report Number : 23-297-0005 REPORT OFANALYSIS Report Date : 11/08/2023 Received : 10/24/2023 Brandi Watson Lab No : 63786 Sample ID : Roxboro Matrix: Solids Sampled: 10/23/2023 15:10 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Total Kjeldahl Nitrogen 33700 mg/Kg - dry 1460 1 11/07/23 07:09 JPJ ;M-4500-NH3C-TKI` Potassium 1730 mg/Kg - dry 58.5 1 10/27/23 23:54 JTR 6010D Magnesium 2470 mg/Kg - dry 29.2 1 10/27/23 23:54 JTR 6010D Sodium 696 mg/Kg - dry 146 1 10/27/23 23:54 JTR 6010D Iron 30000 mg/Kg - dry 58.5 1 10/27/23 23:54 JTR 6010D Zinc 1700 mg/Kg - dry 7.31 1 10/27/23 23:54 JTR 6010D Ammonia Nitrogen 749 mg/Kg - dry 585 1 11/07/23 10:19 JPJ SM-4500-NH3C Nitrate+Nitrite-N 924 mg/Kg - dry 29.2 1 10/26/23 17:42 CLP 4500NO3F-2016 Cadmium 1.90 mg/Kg - dry 0.585 1 10/27/23 23:54 JTR 6010D Chromium 42.0 mg/Kg - dry 1.46 1 10/27/23 23:54 JTR 6010D Mercury <1.06 mg/Kg - dry 1.06 1 10/27/23 12:02 FDS SW-7471B pH 5.6 S.U. 1 10/26/2314:18 ANV 9045D Molybdenum 10.5 mg/Kg - dry 1.46 1 10/27/23 23:54 JTR 6010D Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit Page 4 of 7 Waypointo ANALYTICAL Client: Synagro Central LLC/ Roxboro Project: Roxboro Lab Report Number: 23-297-0005 Date: 11 /7/2023 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com CASE NARRATIVE Metals Analysis Method 601 OD Sample 63787 (Eden VWVTP) Analyte: Aluminum QC Batch No: 1-713991/1-713293 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Solids Total Mercury Analysis - CVAA Method 7471A Sample 63814 (23102407.01A) Analyte: Mercury QC Batch No: 1-713736/1-713529 The matrix spike, matrix spike duplicate and the post digestion spike were all outside of the quality control acceptance ranges. Matrix interference is suspected. Page 5 of 7 WayPAoInt.. NALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Shipment Receipt Form Customer Number: 46487 Customer Name: Synagro Central LLC/ Roxboro Report Number: 23-297-0005 Shipping Method 0 Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client 0 Courier 0 Other: Thermometer ID: Shipping container/cooler uncompromised? * Yes 0 No Number of coolers/boxes received Custody seals intact on shipping container/cooler? 0 Yes 0 No Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? # Yes 0 No COC agrees with sample label(s)? # Yes 0 No COC properly completed # Yes 0 No Samples in proper containers? # Yes 0 No Sample containers intact? # Yes 0 No Sufficient sample volume for indicated test(s)? # Yes 0 No All samples received within holding time? # Yes 0 No Cooler temperature in compliance? # Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. # Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No N/A Water - VOA vials free of headspace 0 Yes 0 No N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A F_ High concentration container (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low concentration EnCore samplers (48 hr) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes * No Comments: Signature: IDavid Lennon Date & Time: 10/24/2023 09:04:53 Page 6 of 7 1! � � m 3 � co �17 Z- r u z Y., 0 �r �n d� am rim r i T, a 9n R_ Mmz ago �D M� Page 7 of 7 SECTION 3 FACILITY NAME: ROXBORO, NC LAND OWNER: RONALD CARVER OPERATOR: RONALD CARVER CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: WQ0021826 FIELD#: NC-PS-00024-0-0001- ANNUAL DRY TONS APPLIED: 120.87 SITE #: NC PS 00024 PREDOMINANT SOIL SERIES: GEORGEVILLE CROP 1 MAX. PAN: 211 CROP 2 NAME: ACRES UTILIZED: 23.3 ACRES PERMITTED:23.3 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Page: 1 Gallons (Gj - Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (lbs/acre) Application Month Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 9/28/2023 187.00 (Y) 20,500 1.386 ROAEDC DRY 0-<1/2"" SUR 0.5 0.30 52,700.00 693.00 28.60 44.274 FSH 9/29/2023 272.00 (Y) 20.500 2.016 ROAEDC DRY 0-<1/2"" SUR 0.5 0.30 62,700.00 693.00 28.60 64.398 FSH Sep-23 459.00 (Y) 10/2/2023 119.00 (Y) 17.100 0.736 ROAEDC DRY 0-<1/2"" SUR 0.5 0.30 33,700,00 749.00 924.00 16.448 FSH Oct-23 119.00 (Y) 11/20/2023 170.00 (Y) 17.100 1.051 ROAEDC DRY 0-<1/2" SUR 0.5 0,30 33,700.00 749.00 924.00 23.497 FSH Nov-23 170.00 (Y) I I I I I I 1 1, 1 A Total 5.189 Total 148.617 0.000 AS CD CU CR PB HG MO NI SE ZN I P Lime Applied Annual Ibs/acre Applied 0.050 0.015 11.721 0.356 0.398 0.009 0.093 0.224 0.052 11.944 197.019 Dat� e F� Lbs/Ac Cumulative ibs/acre Applied 1.414 3 0.313 1 f I t .67 86.262 i 11.294 1 7.582 I 0.187 1.347 64 1.029 j 148.340 g Permit PAN Limit (Ibs/acre) 1st Crop! _ I L 211- Federal C.PLR. (Ibs/acre)**_ 36.6 34.8 1,339.0 267.9 15.0 �W375.0 ROAEDC = ROXBORO, NC WWTP AEROB. DIGESTED CAKE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for su mi g false information, including the possibility of fines and imprr nnt or L owing violations." NAT R F LA LIER DATE (7� NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 *** * See Site pH & Lime Application Records Section of Report Printed: 1/24/2024 DEN FORM FSF (12/2006) FACILITY NAME: ROXBORO, NC LANDOWNER: RONALD CARVER OPERATOR: RONALD CARVER CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMITM WQ0021826 FIELD#: NC-PS-00024-0-0002- ANNUAL DRY TONS APPLIED: 14.69 SITE #: NC PS 00024 PREDOMINANT SOIL SERIES: GEORGEVILLE CROP 1 MAX. PAN: 211 CROP 2 NAME: ACRES UTILIZED: 4.4 ACRES PERMITTED:4.4 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Page: 1 Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 11/21/2023 102.00 (Y) 17.100 3,339 ROAEDC DRY 0- 1/2"" SUR 0.5 0.30 33,7D0.00 749.00 924.00 74.656 FSH Nov-23 102.00 (Y) Annual Ibs/acre Applied Total 3.339 Total 74.656 0.000 0.966 f 0.208 8.082 I 5.730 I 0.133 1 1 I SE ZN P Lime Applied 900.041 11.352 162.260 Date Lbs/Ac Permit PAN Limit (Ibs/acre) 1st Cropl 211 Federal C.P.L_R. (Ibs/acre)****� 36.6 34.8 1,339.0 267.9 15.0 375.0 89.0 2,500.0�� -------------------- - ROAEDC = ROXBORO, NC WWTP AEROB. DIGESTED CAKE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for b itting false information, including the possibility of fines and imprisonrn nt for owing violations." 70' ICI ATUR O D APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, ]NJ - Injection, SURIN - Incorporation *** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 1/24/2024 DENR FORM FSF (12/2006) FACILITY NAME: ROXBORO, INC LAND OWNER: RONALD CARVER OPERATOR: RONALD CARVER CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT#: WQ0021826 FIELD#: NC-PS-00024-0-0003- ANNUAL DRY TONS APPLIED: 14.69 SITE #: NC PS 00024 PREDOMINANT SOIL SERIES: GEORGEVILLE CROP 1 MAX. PAN: 211 CROP 2 NAME: ACRES UTILIZED: 4.3 ACRES PERMITTED: 4.3 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Page: 1 Gallons (G) _ w Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 11/21/2023 Nov-23 102.00 102.00 (Y) (Y) _ 17.100 M3.416 ROAEDC DRY 0-<1/2"" SUR 0.5 0.30 33,700.00 749.00 924.00 76.392 FSH Total 3.416 Total 76.392 0.000 AS HG I SE Annual Ibs/acre Applied 0 040 0 0113� 17 082� 0.287� 0 3118 0 007 0072 O.N95 0 042 ZN 6 16 033 Lime Applied ppliedLbs/Ac An 11.61 Date Cumulative Ibs/acre Applied 1.018 f 0.207 ! 73.101 1 8.218 5.578 1 0.133 1 1.008 I 5.176� I 0.685 1 113.156 Permit PAN Limit (lbslacre) 1st Crop; 211 Federal C.P.L.R. (Ibs/acre)**** 36 6 34.8 1,339.0 267.9 1 15.0 375.0 89.0 2,500.0 ROAEDC = ROXBORO, NC W WTP AEROB. DIGESTED CAKE "1 certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." ,0f1nNAtVRt ONL&WEIAPPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, [NJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 1/24/2024 DENR FORM FSF (12/2006) FACILITY NAME: ROXBORO, NC LANDOWNER: PAUL BAILEY OPERATOR: PAUL BAILEY CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT#: WQ0021826 FIELD#: NC-PS-00025-0-0001-A ANNUAL DRY TONS APPLIED: 21.60 SITE #: NC PS 00025 PREDOMINANT SOIL SERIES: GEORGEVILLE CROP 1 MAX. PAN: 211 CROP 2 NAME: ACRES UTILIZED: 20.2 ACRES PERMITTED: 20.2 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Page: 1 Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 11/29/2023 150.00 (Y) 17.100 1.069 ROAEDC DRY 0-<1/2"" SUR 0.5 0.30 33,700.00 749.00 924.00 23.914 FSH Nov-23 150.00 (Y) Total 1.069 Total 23.914 0.000 AS CD CU CR PB HG MO NI SE ZN P Lime Applied FAnual Ibs/acre Applied 0.013 1 0.004 1v5.347-1 0.090 �1 0.100 1 0.002 1 0.022 - 0.061 0.013 3.636 1 51.976 �— Date F Lbs/Ac 1.684 1 0.324 { 1 84.534 i 12.341 I 8.287 j 0.181 1.484 1 8.026 1 0.937 1 144.090 st Crop' I Federal C.P.L.R. (Ibs/acre)"'" 36.6 B 34.8 1 1,339.0 I 4 267.9 1 15.0 375.0 I 89.0 2,500.0�� ROAEDC = ROXBORO, NC WWTP AEROB. DIGESTED CAKE l L 1 " I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties f, ,sub ' ing false information, including the possibility of fines and imprisonment for inowg violations." �. SIGNA RE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 1/24/2024 DENR FORM FSF (12/2006) FACILITY NAME: ROXBORO, NC LAND OWNER: PAUL BAILEY OPERATOR: PAUL BAILEY CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMITM WQ0021826 FIELDA NC-PS-00025-0-0001-B ANNUAL DRY TONS APPLIED: 10.80 SITE #: NC PS 00025 PREDOMINANT SOIL SERIES: GEORGEVILLE CROP 1 MAX. PAN: 211 CROP 2 NAME: ACRES UTILIZED: 3.1 ACRES PERMITTED: 3.1 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Page: 1 Gallons (G) w _ Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 11/29/2023 75.00 (Y) 17.100 3.484 ROAEDC DRY 0-<1/2" SUR 0.5 0.30 33,700.00 749.00 924.00 77.914 FSH Nov-23 75.00 (Y) Total 3.484 Total 77,914 0.000 -� AS CD CU CR PB HG MO NI SE ZN P Lime Applied Annual Ibs/acre Applied 0.041 0.013 17.422 0.293 0.325 0.007 0.073 0.199 0,043 11.847 169.341 Date Lbs/Ac Cumulative Ibs/acre Applied 1.054 1 1 0.227 1 74.445 8.464 1 5.706 0.144 1.011 5,215 I 0.739 115.585 Permit PAN Limit (Ibs/acre) 1st Crop J� 211 Federal C.P.L.R.(Ibs/acre)**** 36.6 34.8 1,339.0 267.9 15.0 375L 89.0 ROAEDC = ROXBORO, NC WWTP AEROB. DIGESTED CAKE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for ubmitting false information, including the possibility of fines and impnisompent,for.knowing violations." TL "SI N E OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 1/24/2024 DENR FORM FSF (12/2006) FACILITY NAME: ROXBORO, NC LAND OWNER: PAUL BAILEY OPERATOR: PAUL BAILEY CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT#: WQ0021826 FIELD#: NC-PS-00025-0-0002- ANNUAL DRY TONS APPLIED: 32.41 SITE #: NC PS 00025 PREDOMINANT SOIL SERIES: GEORGEVILLE CROP 1 MAX. PAN: 211 CROP 2 NAME: ACRES UTILIZED: 7.3 ACRES PERMITTED: 7.3 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Page: 1 - ~Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) w� % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 11/28/2023 200.00 (Y) 17.100 3.946 ROAEDC DRY 0-<1/2"" SUR 0.5 0.30 33,700.00 749.00 924.00 88.232 FSH 11/29/2023 25.00 (Y) 17.100 0.493 ROAEDC DRY 0-<1/2"" SUR 0.5 0.30 33,700.00 749.00 924.00 11.029 FSH Nov-23 225.00 (Y) Ibs/acre Applied Total 4.439 AS CD CU CR 0.052 0.017 22. 95 0 3T Total 99.261 0.000 3 HG MO NI 0 SE 055 ZN 1 P —r Lime Applied 14 0.009 0.093 0.253 15.093 215.736 P4- Date Cumulative Ibs/acre Applied 0.697 l 0.150 1 62.608 � 5,695 3.783 0.083 0.711 I 3.790 1 0.537 87.205 Permit PAN Limit (Ibs/acre) 1st Cropl I I�! 2111 Federal C.P.L.R. (Ibs/acre)**** 36.6 34.8 1,339.0 267.9 15.0 ._ 375.0 89.0 2,500.0N- ROAEDC = ROXBORO, NC WWTP AEROB. DIGESTED CAKE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for rowing violations." r / f 0 l� 0%NAT OF LAND APPLIER DA E NR = Not Reported or Not Required ** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, [NJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***"* See Site pH & Lime Application Records Section of Report Printed: 1/24/2024 DENR FORM FSF (12/2006) SECTION 4 SUMM111 ENVIRONMENTAL TECHN❑LOMZ3. INC ArrzrJy0ca1 Laboralorfas February 15, 2021 Alex Fox Synagro 284 Boger Rd. Mocksville, NC 27028 TEL: FAX: RE: Roxboro WWTP Dear Alex Fox: Summit Environmental Technologies, Inc. 3310 Win St. Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com Order No.: 21020351 Summit Environmental Technologies, Inc. received 1 sample(s) on 2/5/2021 for the analyses presented in the following report. There were no problems with the analytical events associated with this report unless noted in the Case Narrative. Quality control data is within laboratory defined or method specified acceptance limits except where noted. If you have any questions regarding these tests results, please feel free to call the laboratory. Sincerely, Jennifer Woolf Project Manager 3310 Win St. Cuyahoga Falls, Ohio 44223 Arkansas 88-0735, California 2943, Colorado, Connecticut PH-0108, Florida NELAC E87688, Idaho OH00923, Illinois 200061, Indiana C-OH-13, Kansas E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Maryland 339, Michigan 9988, Minnesota 1780279, Nevada OH009232020-1, New Hampshire 2996, New Jersey OH006, New York 11777, North Carolina 39705 and 631, North Dakota R-201, Ohio DW, Ohio VAP C1,0052, Oklahoma 2019-155, Oregon OH2O0001, Pennsylvania 011, Rhode Island LA000317, South Carolina 92016001, Texas T104704466-19-16, Utah OH009232020-12, Virginia VELAP 10381, West Virginia 9957C Page 1 of 36 summly Summit Environmental Technologies, Inc. Case Narrative 3310 Win St. ENVIRONMENTAL TEC„HQLOG4r;S,INC. Cuyahoga Falls, Ohio44223 WO#: 21020351 Arralyi9cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com Date: 2/15/2021 CLIENT: Synagro Project: Roxboro WWTP WorkOrder Narrative: 21020351: This report in its entirety consists of the following documents: Cover Letter, Case Narrative, Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody, Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit Environmental Technologies, Inc., Work Order Number assigned to this report. Summit Environmental Technologies, Inc., holds the accreditations/certifications listed at the bottom of the cover letter that may or may not pertain to this report. Please refer to the "Accreditation Program Analytes Report" for accredited analytes list. The information contained in this analytical report is the sole property of Summit Environmental Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results contained in this report are only representative of the samples received. Conditions can vary at different times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible for use or interpretation of the data included herein. All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as "dry weight" using the "-dry" designation on the reporting units. This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any comments or problems with the analytical events associated with this report are noted below. Analytical Sequence QC Notes: 40PPM SVOC-MSTR S(8270): CCV exhibited outlying recoveries for several analytes. Associated samples may be biased accordingly. 40PPM SVOC-MSTR S(8270): Surrogate outside recovery limits. Minimum method criterion of one surrogate within established recovery limits was met. LCS-47770 TCLP-SVOC-CPEST(8081B): Possible high bias for Heptachlor due to high recovery in CCV. Pest CCV 100ppb TCLP-SVOC-CPEST(8081B): CCV exhibits high recovery for Heptachlor. Associated samples are N.D. for this analyte. LCS-47770 TCLP-SVOC-CPEST(8081B): Possible high bias for Endrin and Methoxychlor due to high recoveries in CCV. Original Page 2 of 36 SUMMIY Summit Environmental Technologies, Inc. Case Narrative 3310 Win St. ENVIRONMENTAL TEC„HQLOG4r;S,INC. Cuyahoga Falls, Ohio44223 WO#: 21020351 Arralyi9cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com Date: 2/15/2021 CLIENT: Synagro Project: Roxboro WWTP Pest CCV 500ppb TCLP-SV0C-CPEST(8081B): CCV exhibits high recoveries for Endrin and Methoxychlor. Associated samples are N.D. for these analytes. Original Page 3 of 36 �� Summit Environmental Technologies, In Qualifiers and Acronyms SU3310 Win S Ekiwlt OMM@N-rALTECHN❑LOG{r,S,INC Cuyahoga Falls, Ohio442� WO#: 21020351 Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-446 Wehsite: httn:11www.settek.co Date: 2/15/2021 These commonly used Qualifiers and Acronyms may or may not be present in this report. Qualifiers U The compound was analyzed for but was not detected. J The reported value is greater than the Method Detection Limit but less than the Reporting Limit. H The hold time for sample preparation and/or analysis was exceeded. D The result is reported from a dilution. E The result exceeded the linear range of the calibration or is estimated due to interference. MC The result is below the Minimum Compound Limit. The result exceeds the Regulatory Limit or Maximum Contamination Limit. in Manual integration was used to determine the area response. d Manual integration in which peak was deleted N The result is presumptive based on a Mass Spectral library search assuming a 1:1 response. P The second column confirmation exceeded 25% difference. C The result has been confirmed by GC/MS. X The result was not confirmed when GC/MS Analysis was performed. B/MB+ The analyte was detected in the associated blank. G The ICB or CCB contained reportable amounts of analyte. QC-/+ The CCV recovery failed low () or high (+). R/QDR The RPD was outside of accepted recovery limits. QL-/+ The LCS or LCSD recovery failed low () or high (+). QLR The LCS/LCSD RPD was outside of accepted recovery limits. QM-/+ The MS or MSD recovery failed low () or high (+). QMR The MS/MSD RPD was outside of accepted recovery limits. QV-/+ The ICV recovery failed low () or high (+). S The spike result was outside of accepted recovery limits. Z Deviation; A deviation from the method was performed; Please refer to the Case Narrative for additional information Acronyms ND Not Detected RL Reporting Limit QC Quality Control MDL Method Detection Limit MB Method Blank LOD Level of Detection LCS Laboratory Control Sample LOQ Level of Quantitation LCSD Laboratory Control Sample Duplicate PQL Practical Quantitation Limit QCS Quality Control Sample CRQL Contract Required Quantitation Limit DUP Duplicate PL Permit Limit MS Matrix Spike RegLvl Regulatory Limit MSD Matrix Spike Duplicate MCL Maximum Contamination Limit RPD Relative Percent Different MinCL Minimum Compound Limit ICV Initial Calibration Verification RA Reanalysis ICB Initial Calibration Blank RE Reextraction CCV Continuing Calibration Verification TIC Tentatively Identified Compound CCB Continuing Calibration Blank RT Retention Time PLC Reporting Limit Check CF Calibration Factor DF Dilution Factor RF Response Factor This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting. Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this list or for additional information regarding the use of these Qualifiers on reported data. Original Page 4 of 36 �� 1 � Summit Environmental Technologies, Inc. SU3310 Win St. ENVIRCNMEWAL YECHHOLOGNUS, JNC, Cuyahoga Falls, Ohio 44223 Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com CLIENT: Synagro Project: Roxboro WWTP Lab SampleID Client Sample ID 21020351-001 Roxboro VAVTP Tag No Date Collected 2/4/2021 12:30:00 PM Workorder Sample Summary WO#: 21020351 15-Feb-21 Date Received Matrix 2/5/2021 12:25:00 PM Sludge Page 5 of 36 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. DATES REPORT ENVIRONMENTAL TECHN❑ L0G1E5, IrJG Cuyahoga Falls, Ohio 44223 WO#: 21020351 ArWyft cal taboralonas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 15-Feb-21 Client: Synagro Project: Roxboro WWTP Sample ID Client Sample ID Collection Date Matrix Test Name Leachate Date Prep Date Analysis Date 21020351-OOIA Roxboro WWTP 2/4/2021 12:30:00 PM Sludge Ignitability of Solids (SW-846: 1030) 2/10/2021 11:35:50 AM Paint Filter Free Liquids Test (SW-846 2/15/2021 1:35:00 PM pH (SW9045D) 2/12/2021 2:15:00 PM Reactive Cyanide (9014/7.3.32)-Solid 2/10/2021 2:23:00 PM Reactive Sulfide (9034)/7.3.42 2/10/2021 2:23:00 PM TCLP Herbicides by EPA 832113 2/7/2021 8:00:00 PM 2/9/2021 9:51:00 PM TCLP Mercury Analysis (SW1311/7472/7/2021 8:00:00 PM 2/12/2021 9:15:00 AM 2/12/2021 1:39:00 PM TCLP Metals Analysis (SW1311/6010:2/7/2021 8:00:00 PM 2/8/2021 1:50:00 PM 2/9/2021 2:03:38 PM TCLP Pesticides Analysis (SW1311/8(2/7/2021 8:00:00 PM 2/9/2021 2:00:00 PM 2/10/2021 11:30:00 PM TCLP Pesticides Analysis (SW1311/8(2/7/2021 8:00:00 PM 2/9/2021 2:00:00 PM 2/10/2021 11:30:00 PM TCLP Semi-Volatiles Analysis 2/7/2021 8:00:00 PM 2/8/2021 12:00:00 PM 2/9/2021 9:22:00 PM (SW1311/8270) TCLP Volatiles Analysis 2/9/2021 6:37:00 AM Original Page 6 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVITtONMENTALTECHNOLOGIE_3,IRC Cuyahoga Falls, Ohio44223 Arralyt9cal Laboralories TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://�i,-"-m,.settek.coin Analytical Report (base report) WO#: 21020351 Date Reported: 2/15/2021 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 2/4/2021 12:30:00 PM Lab ID: 21020351-OOIA Project: Roxboro WWTP Client Sample ID Roxboro WWTP Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP MERCURY ANALYSIS (SW1311/7470) TCLP Mercury ND 0.00200 mg/L SW7470A SW7470A Analyst: EAM 1 2/12/2021 1:39:00 PM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW6010D SW301OA Analyst: DNS TCLP METALS ANALYSIS (SW1311/6010) TCLP Arsenic(As) ND 0.500 mg/L 1 2/9/2021 2:03:38 PM TCLP Barium(Ba) ND 5.00 mg/L 1 2/9/2021 2:03:38 PM TCLP Cadmium(Cd) ND 0.100 mg/L 1 2/9/2021 2:03:38 PM TCLP Chromium(Cr) ND 0.200 mg/L 1 2/9/2021 2:03:38 PM TCLP Lead(Pb) ND 0.500 mg/L 1 2/9/2021 2:03:38 PM TCLP Selenium(Se) ND 0.0500 mg/L 1 2/9/2021 2:03:38 PM TCLP Silver(Ag) ND 0.500 mg/L 1 2/9/2021 2:03:38 PM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8270 SW351OC Analyst: RIS TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270) 1,4-Dichlorobenzene ND 0.200 mg/L 2 2/9/2021 9:22:00 PM 2,4,5-Trichlorophenol ND 0.500 mg/L 2 2/9/2021 9:22:00 PM 2,4,6-Trichlorophenol ND 0.500 mg/L 2 2/9/2021 9:22:00 PM 2,4-Dinitrotoluene ND 0.100 mg/L 2 2/9/2021 9:22:00 PM Cresols, Total ND 10.0 mg/L 2 2/9/2021 9:22:00 PM Hexachloro-1,3-butadiene ND 0.0400 mg/L 2 2/9/2021 9:22:00 PM Hexachlorobenzene ND 0.100 mg/L 2 2/9/2021 9:22:00 PM Hexachloroethane ND 0.200 mg/L 2 2/9/2021 9:22:00 PM Nitrobenzene ND 0.200 mg/L 2 2/9/2021 9:22:00 PM Pentachlorophenol ND 0.500 mg/L 2 2/9/2021 9:22:00 PM Pyridine ND 0.500 QC+ mg/L 2 2/9/2021 9:22:00 PM Surr: 2-Fluorophenol 92.6 10 - 157 %Rec 2 2/9/2021 9:22:00 PM Surr: Phenol-d6 93.4 10 - 169 %Rec 2 2/9/2021 9:22:00 PM Surr: Nitrobenzene-d5 86.1 32.1 - 130 %Rec 2 2/9/2021 9:22:00 PM Surr: 2,4,6-Tribromophenol 116 45.4 - 166 %Rec 2 2/9/2021 9:22:00 PM Surr: 2-Fluorobiphenyl 93.8 35.7 - 130 %Rec 2 2/9/2021 9:22:00 PM Surr: p-Terphenyl-d14 113 70 - 145 %Rec 2 2/9/2021 9:22:00 PM Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response MC Value is below Minimum Compound Limit. N Tentatively identified compounds ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original RL Reporting Detection Limit U Samples with CalcVal <MDL Page 7 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVITtONMENTALTECHNOLOGIE_3,IRC Cuyahoga Falls, Ohio44223 Arrafyt9caf Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://�i,-"-m,.settek.coin Analytical Report (base report) WO#: 21020351 Date Reported: 2/15/2021 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 2/4/2021 12:30:00 PM Lab ID: 21020351-OOIA Project: Roxboro WWTP Client Sample ID Roxboro WWTP Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP PESTICIDES ANALYSIS (SW1311/8081) Chlordane, total ND Toxaphene ND Endrin ND gamma-BHC ND Heptachlor ND Heptachlor epoxide ND Methoxychlor ND Surr: TCMX 72.0 Surr: DCB 77.3 TCLP HERBICIDES BY EPA 8321 B 2,4-D ND 2,4,5-TP ND Surr: 2,4-Dichlorophenylacetic aci 75.5 TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP VOLATILES ANALYSIS 1,1-Dichloroethene ND 1,2-Dichloroethane ND MEK ND Benzene ND Carbon tetrachloride ND Chlorobenzene ND Chloroform ND Tetrachloroethene ND Trichloroethene ND Vinyl chloride ND Surr: 4-Bromofluorobenzene 114 Surr: Di brom ofl uorom ethane 93.7 Surr: Toluene-d8 95.0 SW8081 SW351OC Analyst: CSS 0.0250 mg/L 1 2/10/2021 11:30:00 PM 0.0500 mg/L 1 2/10/2021 11:30:00 PM 0.00250 QC+ mg/L 1 2/10/2021 11:30:00 PM 0.00250 mg/L 1 2/10/2021 11:30:00 PM 0.00250 QC+ mg/L 1 2/10/2021 11:30:00 PM 0.00250 mg/L 1 2/10/2021 11:30:00 PM 0.00250 QC+ mg/L 1 2/10/2021 11:30:00 PM 10 - 119 %Rec 1 2/10/2021 11:30:00 PM 10 - 119 %Rec 1 2/10/2021 11:30:00 PM SW8321 SW1311 M Analyst: TM 0.500 mg/L 50 2/9/2021 9:51:00 PM 0.500 mg/L 50 2/9/2021 9:51:00 PM 70 - 130 %Rec 50 2/9/2021 9:51:00 PM SW8260 SW1311 M Analyst: SLV 0.250 mg/L 50 2/9/2021 6:37:00 AM 0.250 mg/L 50 2/9/2021 6:37:00 AM 5.00 mg/L 50 2/9/2021 6:37:00 AM 0.250 mg/L 50 2/9/2021 6:37:00 AM 0.250 mg/L 50 2/9/2021 6:37:00 AM 2.50 mg/L 50 2/9/2021 6:37:00 AM 0.250 mg/L 50 2/9/2021 6:37:00 AM 0.250 mg/L 50 2/9/2021 6:37:00 AM 0.250 mg/L 50 2/9/2021 6:37:00 AM 0.100 mg/L 50 2/9/2021 6:37:00 AM 70 - 130 %Rec 50 2/9/2021 6:37:00 AM 70 - 130 %Rec 50 2/9/2021 6:37:00 AM 70 - 130 %Rec 50 2/9/2021 6:37:00 AM Qualifiers: B Analyte detected in the associated Method Blank H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected PL Permit Limit RL Reporting Detection Limit E Value above quantitation range M Manual Integration used to determine area response N Tentatively identified compounds P Second column confirmation exceeds R RPD outside accepted recovery limits original U Samples with CalcVal <MDL Page 8 of 36 MMIT Summit Environmental Technologies, Inc. Analytical Report SU3310 Win St. ENVIRONMENTAL TECHNQLOGlr,$.IRC Cuyahoga Falls, Ohio44223 (base report) Arralyt9cal Laboralories TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 21020351 Website: http://www.settek.com Date Reported: 2/15/2021 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 2/4/2021 12:30:00 PM Lab ID: 21020351-OOIA Project: Roxboro WWTP Client Sample ID Roxboro WWTP Analyses Result RL Qual Units DF Date Analyzed RCI SW9014 Analyst: MS REACTIVE CYANIDE (9014/7.3.3.2)-SOLID Cyanide, Reactive ND 0.500 mg/Kg 1 2/10/2021 2:23:00 PM PAINT FILTER FREE LIQUIDS TEST (SW-846: 9095) SW9095 Analyst: DHC Free Liquid pass 1 2/15/2021 1:35:00 PM IGNITABILITY OF SOLIDS (SW-846: 1030) SW1030 Analyst: KMW Ignitability non flammable mm/sec 1 2/10/2021 11:35:50 AM RCI SW9045D Analyst: DHC PH (SW9045D) pH 6.7 s.u.@18.1C 1 2/12/2021 2:15:00 PM RCI SW9034 Analyst: MS REACTIVE SULFIDE (9034)/7.3.4.2 Sulfide, Reactive ND 25.0 mg/Kg 1 2/10/2021 2:23:00 PM Qualifiers: B Analyte detected in the associated Method Blank H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected PL Permit Limit RL Reporting Detection Limit E Value above quantitation range M Manual Integration used to determine area response N Tentatively identified compounds P Second column confirmation exceeds R RPD outside accepted recovery limits original U Samples with CalcVal <MDL Page 9 of 36 Summit Environmental Technologies, Inc. Accreditation Program MM'EF frSU3310 Win St. Anal tes Report Y ENOROMMEWAL IrECHNOL,t 01ES, INC Cuyahoga Falls, Ohio 44223 Y Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 21020351 Website: http://www.settek.com 15-Feb-21 Client: Synagro State: NW Project: Roxboro WWTP Program Name: NC—WW—SCM Sample ID Matrix Test Name Analyte Status 21020351-OOIA Sludge Ignitability of Solids (SW-846: 1030) Ignitability A Sludge Paint Filter Free Liquids Test (SW-846: 9095) Free Liquid A Sludge pH (SW9045D) Hydrogen Ion (pH) A Sludge Reactive Cyanide (9014/7.3.32)-Solid Cyanide, Reactive U Sludge Reactive Sulfide (9034)/7.3.42 Sulfide, Reactive U Sludge TCLP Herbicides by EPA 8321B 2,4,5-TP A Sludge TCLP Herbicides by EPA 8321B 2,4-D A Sludge TCLP Mercury Analysis (SW1311/7470) Mercury A Sludge TCLP Metals Analysis (SW1311/6010) Arsenic A Sludge TCLP Metals Analysis (SW1311/6010) Barium A Sludge TCLP Metals Analysis (SW1311/6010) Cadmium A Sludge TCLP Metals Analysis (SW1311/6010) Chromium A Sludge TCLP Metals Analysis (SW1311/6010) Lead A Sludge TCLP Metals Analysis (SW1311/6010) Selenium A Sludge TCLP Metals Analysis (SW1311/6010) Silver A Sludge TCLP Pesticides Analysis (SW1311/8081) Chlordane, total A Sludge TCLP Pesticides Analysis (SW1311/8081) Endrin A Sludge TCLP Pesticides Analysis (SW1311/8081) gamma-BHC A Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor A Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor epoxide A Sludge TCLP Pesticides Analysis (SW1311/8081) Methoxychlor A Sludge TCLP Pesticides Analysis (SW1311/8081) Toxaphene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 1,4-Dichlorobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,5-Trichlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,6-Trichlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4-Dinitrotoluene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Cresols, Total A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobutadiene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachloroethane A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Nitrobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pentachlorophenol A Key Key NC WW SCM A Accredited NC WW SCM U Unavailable Original # 1 Page 10 of 36 Summit Environmental Technologies, Inc. Accreditation Program MM'EF frSU3310 Win St. Anal tes Report Y ENVIROMMEWAL IrECHHOL,t 01ES, INC Cuyahoga Falls, Ohio 44223 Y Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 21020351 Website: http://www.settek.com 15-Feb-21 Client: Synagro State: NW Project: Roxboro WWTP Program Name: NC—WW—SCM Sample ID Matrix Test Name Analyte Status 21020351-OOIA Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pyridine A Sludge TCLP Volatiles Analysis 1,1-Dichloroethene A Sludge TCLP Volatiles Analysis 1,2-Dichloroethane A Sludge TCLP Volatiles Analysis 2-Butanone A Sludge TCLP Volatiles Analysis Benzene A Sludge TCLP Volatiles Analysis Carbon tetrachloride A Sludge TCLP Volatiles Analysis Chlorobenzene A Sludge TCLP Volatiles Analysis Chloroform A Sludge TCLP Volatiles Analysis Tetrachloroethene A Sludge TCLP Volatiles Analysis Trichloroethene A Sludge TCLP Volatiles Analysis Vinyl chloride A NC WW SCM A Accredited NC WW SCM U Unavailable Original # 1 Page 11 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com QC SUMMARY REPORT WO#: 21020351 15-Feb-21 Client: Synagro Project: Roxboro WWTP BatchID: 47725 Sample ID: MB-47725 SampType: MBLK TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 123570 Client ID: PBS Batch ID: 47725 TestNo: SW8260 SW1311M Analysis Date: 2/9/2021 SegNo: 3196874 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene ND 0.250 1,2-Dichloroethane ND 0.250 MEK ND 5.00 Benzene ND 0.250 Carbon tetrachloride ND 0.250 Chlorobenzene ND 2.50 Chloroform ND 0.250 Tetrachloroethene ND 0.250 Trichooroethene ND 0.250 Vinyl chloride ND 0.100 Surr: 4-Bromofluorobenzene 2750 Surr: Dibromofluoromethane 2250 Surr: Toluene-d8 2530 2500 110 70 130 2500 90.1 70 130 2500 101 70 130 Sample ID: LCS-47725 SampType: LCS TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 123570 Client ID: LCSS Batch ID: 47725 TestNo: SW8260 SW1311M Analysis Date: 2/9/2021 SegNo: 3196875 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 0.964 0.250 1.00 0 96.4 64.7 136 1,2-Dichloroethane 1.05 0.250 1.00 0 105 70 130 MEK 5.29 5.00 5.00 0 106 55.1 149 Benzene 1.07 0.250 1.00 0 107 70 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 12 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com QC SUMMARY REPORT WO#: 21020351 15-Feb-21 Client: Synagro Project: Roxboro WWTP BatchID: 47725 Sample ID: LCS-47725 SampType: LCS TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 123570 client ID: LCSS Batch ID: 47725 TestNo: SW8260 SW1311M Analysis Date: 2/9/2021 SegNo: 3196875 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Carbon tetrachloride 1.07 0.250 1.00 0 107 70 130 Chlorobenzene ND 2.50 1.00 0 99.4 70 130 Chloroform 0.972 0.250 1.00 0 97.2 70 130 Tetrachloroethene 1.12 0.250 1.00 0 112 70 134 Trichloroethene 0.943 0.250 1.00 0 94.3 62.8 160 Vinyl chloride 0.900 0.100 1.00 0 90.0 67.1 130 Surr:4-Bromofluorobenzene 2860 2500 114 70 130 Surr: Dibromofluoromethane 2260 2500 90.5 70 130 Surr: Toluene-d8 2510 2500 101 70 130 Sample ID: 21020425-001AMS SampType: MS TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 123570 client ID: BatchQC Batch ID: 47725 TestNo: SW8260 SW1311M Analysis Date: 2/9/2021 SegNo: 3196883 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 0.975 0.250 1.00 0 97.5 13.6 202 1,2-Dichloroethane 1.14 0.250 1.00 0 114 55.7 138 MEK 5.26 5.00 5.00 0 105 65.3 118 Benzene 1.11 0.250 1.00 0 ill 49.2 145 Carbon tetrachloride 1.13 0.250 1.00 0 113 26.7 156 Chlorobenzene ND 2.50 1.00 0 98.6 33.7 159 Chloroform 1.00 0.250 1.00 0 100 48.5 145 Tetrachloroethene 1.07 0.250 1.00 0 107 19.2 191 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 13 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com QC SUMMARY REPORT WO#: 21020351 15-Feb-21 Client: Synagro Project: Roxboro WWTP BatchID: 47725 Sample ID: 21020425-001AMS SampType: MS TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 123570 client ID: BatchQC Batch ID: 47725 TestNo: SW8260 SW1311M Analysis Date: 2/9/2021 SegNo: 3196883 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Trichloroethene 0.994 0.250 1.00 0 99.4 38.4 167 Vinyl chloride 0.790 0.100 1.00 0 79.0 27.3 161 Surr:4-Bromofluorobenzene 2840 2500 114 70 130 Surr: Dibromofluoromethane 2310 2500 92.3 70 130 Surr: Toluene-d8 2440 2500 97.5 70 130 Sample ID: 21020425-001AMSD SampType: MSD TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 123570 client ID: BatchQC Batch ID: 47725 TestNo: SW8260 SW1311M Analysis Date: 2/9/2021 SegNo: 3196884 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 0.958 0.250 1.00 0 95.8 13.6 202 0.975 1.81 25 1,2-Dichloroethane 1.13 0.250 1.00 0 113 55.7 138 1.14 1.10 25 MEK 5.21 5.00 5.00 0 104 65.3 130 5.26 0.983 25 Benzene 1.12 0.250 1.00 0 112 49.2 145 1.11 0.765 25 Carbon tetrachloride 1.09 0.250 1.00 0 109 26.7 156 1.13 3.02 25 Chlorobenzene ND 2.50 1.00 0 99.4 33.7 159 0 0 25 Chloroform 0.994 0.250 1.00 0 99.4 48.5 145 1.00 1.00 25 Tetrachloroethene 1.06 0.250 1.00 0 106 19.2 191 1.07 0.328 25 Trichloroethene 0.995 0.250 1.00 0 99.5 38.4 167 0.994 0.101 25 Vinyl chloride 0.885 0.100 1.00 0 88.4 27.3 161 0.790 11.2 25 Surr:4-Bromofluorobenzene 2840 2500 114 70 130 0 25 Surr: Dibromofluoromethane 2320 2500 92.9 70 130 0 25 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 14 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com QC SUMMARY REPORT WO#: 21020351 15-Feb-21 Client: Synagro Project: Roxboro WWTP BatchID: 47725 Sample ID: 21020425-001AMSD SampType: MSD TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 123570 Client ID: Batch= Batch ID: 47725 TestNo: SW8260 SW1311M Analysis Date: 2/9/2021 SegNo: 3196884 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Surr: Toluene-d8 2390 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits 2500 95.7 70 130 0 25 E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 15 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com QC SUMMARY REPORT WO#: 21020351 15-Feb-21 Client: Synagro Project: Roxboro WWTP BatchID: 47736 Sample ID: MB-47736 SampType: MBLK TestCode: SVOC-BNA_T Units: mg/L Prep Date: 2/8/2021 RunNo: 123599 client ID: PBS Batch ID: 47736 TestNo: SW8270 SW3510C Analysis Date: 2/9/2021 SegNo: 3197838 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene ND 0.100 2,4,5-Trichlorophenol ND 0.250 2,4,6-Trichlorophenol ND 0.250 2,4-Dinitrotoluene ND 0.0500 o-Cresol ND 0.250 Cresols, Total ND 5.00 Hexachloro-1,3-butadiene ND 0.0200 Hexachlorobenzene ND 0.0500 Hexachloroethane ND 0.100 Nitrobenzene ND 0.100 Pentachlorophenol ND 0.250 Pyridine ND 0.250 Surr: 2-Fluorophenol 0.910 Surr: Phenol-d6 0.846 Surr: Nitrobenzene-d5 0.800 Surr: 2,4,6-Tribromophenol 1.18 Surr: 2-Fluorobiphenyl 0.795 Surr: p-Terphenyl-d14 1.04 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits 1.000 91.0 10 130 1.000 84.6 10 130 1.000 80.0 19 130 1.000 118 10 130 1.000 79.5 22 130 1.000 104 34 130 E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco QC+ Original Page 16 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com QC SUMMARY REPORT WO#: 21020351 15-Feb-21 Client: Synagro Project: Roxboro WWTP BatchID: 47736 Sample ID: LCS-47736 SampType: LCS TestCode: SVOC-BNA_T Units: mg/L Prep Date: 2/8/2021 RunNo: 123599 client ID: LCSS Batch ID: 47736 TestNo: SW8270 SW3510C Analysis Date: 2/9/2021 SegNo: 3197839 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.589 0.100 0.8000 0 73.7 36.4 130 2,4,5-Trichlorophenol 0.940 0.250 0.8000 0 117 31.7 132 2,4,6-Trichlorophenol 0.927 0.250 0.8000 0 116 31.1 133 2,4-Dinitrotoluene 0.897 0.0500 0.8000 0 112 43.3 130 o-Cresol 0.762 0.250 0.8000 0 95.3 32.9 130 Cresols, Total ND 5.00 1.600 0 95.2 31.7 130 Hexachloro-1,3-butadiene 0.648 0.0200 0.8000 0 81.0 31.4 130 Hexachlorobenzene 0.790 0.0500 0.8000 0 98.8 43.1 130 Hexachloroethane 0.553 0.100 0.8000 0 69.2 36.5 130 Nitrobenzene 0.700 0.100 0.8000 0 87.5 39.5 130 Pentachlorophenol 0.826 0.250 0.8000 0 103 34 130 Pyridine 0.408 0.250 0.8000 0 51.0 10 130 Surr: 2-Fluorophenol 0.920 1.000 92.0 17.1 130 Surr: Phenol-d6 0.919 1.000 91.9 10 130 Surr: Nitrobenzene-d5 0.773 1.000 77.3 32.6 130 Surr:2,4,6-Tribromophenol 1.27 1.000 127 4.43 130 Surr:2-Fluorobiphenyl 0.806 1.000 80.6 41.8 130 Surr: p-Terphenyl-d14 1.17 1.000 117 36.4 130 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco QC+ Original Page 17 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com QC SUMMARY REPORT WO#: 21020351 15-Feb-21 Client: Synagro Project: Roxboro WWTP BatchID: 47736 Sample ID: 21020275-003AMS SampType: MS TestCode: SVOC-BNA_T Units: mg/L Prep Date: 2/8/2021 RunNo: 123599 client ID: BatchQC Batch ID: 47736 TestNo: SW8270 SW3510C Analysis Date: 2/9/2021 SegNo: 3197840 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.620 0.500 0.8000 0 77.5 33.8 126 2,4,5-Trichlorophenol ND 1.25 0.8000 0 115 28.7 144 QC+ 2,4,6-Trichlorophenol ND 1.25 0.8000 0 107 12.8 153 2,4-Dinitrotoluene 0.875 0.250 0.8000 0 109 20.4 155 o-Cresol ND 1.25 0.8000 0 91.8 10 148 Cresols, Total ND 25.0 1.600 0 95.1 10 148 Hexachloro-1,3-butadiene 0.674 0.100 0.8000 0 84.2 29 130 Hexachlorobenzene 0.826 0.250 0.8000 0 103 33.7 134 Hexachloroethane 0.577 0.500 0.8000 0 72.1 32.8 132 Nitrobenzene 0.703 0.500 0.8000 0 87.9 20 158 Pentachlorophenol ND 1.25 0.8000 0 113 10 176 Pyridine ND 1.25 0.8000 0 54.6 10 130 m Surr:2-Fluorophenol 0.887 1.000 88.7 3.39 130 Surr: Phenol-d6 0.914 1.000 91.4 5 130 Surr: Nitrobenzene-d5 0.831 1.000 83.1 14.5 154 Surr: 2,4,6-Tribromophenol 1.33 1.000 133 19.5 130 S Surr:2-Fluorobiphenyl 0.852 1.000 85.2 34.4 130 Surr: p-Terphenyl-d14 1.09 1.000 109 8.86 156 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 18 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com QC SUMMARY REPORT WO#: 21020351 15-Feb-21 Client: Synagro Project: Roxboro WWTP BatchID: 47736 Sample ID: 21020275-003AMSD SampType: MSD TestCode: SVOC-BNA_T Units: mg/L Prep Date: 2/8/2021 RunNo: 123599 client ID: BatchQC Batch ID: 47736 TestNo: SW8270 SW3510C Analysis Date: 2/9/2021 SegNo: 3197841 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.642 0.500 0.8000 0 80.2 33.8 126 0.6200 3.49 30 2,4,5-Trichlorophenol ND 1.25 0.8000 0 118 28.7 144 0 0 30 QC+ 2,4,6-Trichlorophenol ND 1.25 0.8000 0 114 12.8 153 0 0 30 2,4-Dinitrotoluene 0.993 0.250 0.8000 0 124 20.4 155 0.8750 12.6 30 o-Cresol ND 1.25 0.8000 0 93.9 10 148 0 0 30 Cresols, Total ND 25.0 1.600 0 94.6 10 148 0 0 30 Hexachloro-1,3-butadiene 0.736 0.100 0.8000 0 92.0 29 130 0.6740 8.79 30 Hexachlorobenzene 0.907 0.250 0.8000 0 113 33.7 134 0.8260 9.35 30 Hexachloroethane 0.554 0.500 0.8000 0 69.2 32.8 132 0.5770 4.07 30 Nitrobenzene 0.675 0.500 0.8000 0 84.4 20 158 0.7030 4.06 30 Pentachlorophenol ND 1.25 0.8000 0 127 10 176 0 0 30 Pyridine ND 1.25 0.8000 0 51.8 10 130 0 0 30 m Surr:2-Fluorophenol 0.917 1.000 91.7 3.39 130 0 Surr: Phenol-d6 0.915 1.000 91.5 10 130 0 Surr: Nitrobenzene-d5 0.892 1.000 89.2 14.5 154 0 Surr: 2,4,6-Tribromophenol 1.41 1.000 141 19.5 130 0 S Surr:2-Fluorobiphenyl 1.00 1.000 100 34.4 130 0 Surr: p-Terphenyl-d14 1.23 1.000 123 8.86 156 0 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 19 of 36 MM'T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 21020351 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com 15-Feb-21 Client: Synagro Project: Roxboro WWTP BatchID: 47739 Sample ID: LCS-47739 SampType: LCS TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 2/8/2021 RunNo: 123588 Client ID: LCSS Batch ID: 47739 TestNo: SW6010D SW3010A Analysis Date: 2/9/2021 SegNo: 3197527 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 1.97 0.500 2.000 0 98.5 80 120 TCLP Barium(Ba) ND 5.00 2.000 0 103 80 120 TCLP Cadmium(Cd) 1.99 0.100 2.000 0 99.4 80 120 TCLP Chromium(Cr) 2.12 0.200 2.000 0 106 80 120 TCLP Lead(Pb) 2.06 0.500 2.000 0 103 80 120 TCLP Selenium(Se) 2.10 0.0500 2.000 0 105 80 120 TCLP Silver(Ag) 2.09 0.500 2.000 0 104 80 120 Sample ID: 21020375-001AMS SampType: MS TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 2/8/2021 RunNo: 123588 Client ID: Batch= Batch ID: 47739 TestNo: SW6010D SW3010A Analysis Date: 2/9/2021 SegNo: 3197532 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 2.08 0.500 2.000 0.01527 103 70 130 TCLP Barium(Ba) ND 5.00 2.000 0.2650 94.1 70 130 TCLP Cadmium(Cd) 1.96 0.100 2.000 0.003513 97.6 70 130 TCLP Chromium(Cr) 3.22 0.200 2.000 1.234 99.2 70 130 TCLP Lead(Pb) 1.80 0.500 2.000 0 89.9 70 130 TCLP Selenium(Se) 2.40 0.0500 2.000 0.01924 119 70 130 TCLP Silver(Ag) 2.13 0.500 2.000 0 107 70 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 20 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com QC SUMMARY REPORT WO#: 21020351 15-Feb-21 Client: Synagro Project: Roxboro WWTP BatchID: 47739 Sample ID: 21020375-001AMSD SampType: MSD TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 2/8/2021 RunNo: 123588 Client ID: Batch= Batch ID: 47739 TestNo: SW6010D SW3010A Analysis Date: 2/9/2021 SegNo: 3197533 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 2.08 0.500 2.000 0.01527 103 70 130 2.076 0.00432 20 TCLP Barium(Ba) ND 5.00 2.000 0.2650 92.5 70 130 0 0 20 TCLP Cadmium(Cd) 1.92 0.100 2.000 0.003513 96.0 70 130 1.956 1.63 20 TCLP Chromium(Cr) 3.18 0.200 2.000 1.234 97.1 70 130 3.218 1.32 20 TCLP Lead(Pb) 1.78 0.500 2.000 0 89.0 70 130 1.798 0.967 20 TCLP Selenium(Se) 2.42 0.0500 2.000 0.01924 120 70 130 2.402 0.767 20 TCLP Silver(Ag) 2.06 0.500 2.000 0 103 70 130 2.132 3.56 20 Sample ID: MB-47739 SampType: MBLK TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 2/8/2021 RunNo: 123588 Client ID: PBS Batch ID: 47739 TestNo: SW6010D SW3010A Analysis Date: 2/9/2021 SegNo: 3197574 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) ND 0.500 TCLP Barium(Ba) ND 5.00 TCLP Cadmium(Cd) ND 0.100 TCLP Chromium(Cr) ND 0.200 TCLP Lead(Pb) ND 0.500 TCLP Selenium(Se) ND 0.0500 TCLP Silver(Ag) ND 0.500 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 21 of 36 MM'T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 21020351 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com 15-Feb-21 Client: Synagro Project: Roxboro WWTP BatchID: 47770 Sample ID: LCS-47770 SampType: LCS TestCode: TCLP-SVOC- Units: mg/L Prep Date: 2/9/2021 RunNo: 123720 Client ID: LCSS Batch ID: 47770 TestNo: SW8081 SW3510C Analysis Date: 2/10/2021 SegNo: 3203003 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Endrin 0.00976 0.000500 0.0100 0 97.6 10 130 mQC+ gamma-BHC 0.00957 0.000500 0.0100 0 95.7 10 130 Heptachlor epoxide 0.0101 0.000500 0.0100 0 101 10 130 Methoxychlor 0.0118 0.000500 0.0100 0 118 10 178 QC+ Surr: TCMX 15.6 20.00 78.2 10 130 Surr: DCB 19.8 20.00 99.0 10 130 Sample ID: MB-47770 SampType: MBLK TestCode: TCLP-SVOC- Units: mg/L Prep Date: 2/9/2021 RunNo: 123720 Client ID: PBS Batch ID: 47770 TestNo: SW8081 SW3510C Analysis Date: 2/10/2021 SegNo: 3203004 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Chlordane, total ND 0.00250 Toxaphene ND 0.00500 Endrin ND 0.000500 gamma-BHC ND 0.000500 Heptachlor epoxide ND 0.000500 Methoxychlor ND 0.000500 Surr: TCMX 15.2 20.00 76.1 10 119 Surr: DCB 18.6 20.00 92.8 10 119 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco QC+ QC+ Original Page 22 of 36 MM'T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMEWAL rECHN❑ Lggir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 21020351 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com 15-Feb-21 Client: Synagro Project: Roxboro WWTP BatchID: 47770 Sample ID: LCS-47770 SampType: LCS TestCode: TCLP-SVOC- Units: mg/L Prep Date: 2/9/2021 RunNo: 123719 Client ID: LCSS Batch ID: 47770 TestNo: SW8081 SW3510C Analysis Date: 2/10/2021 SegNo: 3202987 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Heptachlor 0.0103 0.000500 0.0100 0 103 10 130 QC+ Sample ID: MB-47770 SampType: MBLK TestCode: TCLP-SVOC- Units: mg/L Prep Date: 2/9/2021 RunNo: 123719 Client ID: PBS Batch ID: 47770 TestNo: SW8081 SW3510C Analysis Date: 2/10/2021 SegNo: 3202988 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Heptachlor ND 0.000500 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco QC - Original Page 23 of 36 SUMM'T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 21020351 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com 15-Feb-21 Client: Synagro Project: Roxboro WWTP BatchID: 47816 TCLP Mercury ND 0.00200 TCLP Mercury 0.00390 0.00200 0.00400 0 97.5 80 120 TCLP Mercury 0.00434 0.00200 0.00400 0 108 75 125 Sample ID: 21020428-002AMSD SampType: MSD TestCode: HG_TCLP(74 Units: PPM Prep Date: 2/12/2021 RunNo: 123777 Client ID: Batch= Batch ID: 47816 TestNo: SW7470A SW7470A Analysis Date: 2/12/2021 SegNo: 3204261 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual TCLP Mercury 0.00431 0.00200 0.00400 0 108 75 125 0.00434 0.694 20 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 24 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ Lggir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com QC SUMMARY REPORT WO#: 21020351 15-Feb-21 Client: Synagro Project: Roxboro WWTP BatchID: 47816 Sample ID: 21020428-002AMSD SampType: MSD TestCode: HG_TCLP(74 Units: PPM Prep Date: 2/12/2021 RunNo: 123777 client ID: BatchQC Batch ID: 47816 TestNo: SW7470A SW7470A Analysis Date: 2/12/2021 SegNo: 3204261 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sample ID: M1132-47816 SampType: MBLK TestCode: HG_TCLP(74 Units: PPM Prep Date: 2/12/2021 RunNo: 123777 client ID: PBS Batch ID: 47816 TestNo: SW7470A SW7470A Analysis Date: 2/12/2021 SegNo: 3204271 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Mercury ND 0.00200 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 25 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ Lggir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com QC SUMMARY REPORT WO#: 21020351 15-Feb-21 Client: Synagro Project: Roxboro WWTP BatchID: R123634 Sample ID: LCS-R123634 SampType: LCS TestCode: Ignitability_S Units: mm/sec Prep Date: RunNo: 123634 Client ID: LCSS Batch ID: R123634 TestNo: SW1030 Analysis Date: 2/10/2021 SegNo: 3199173 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Ignitability 7.46 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits 7.240 0 103 70 130 E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 26 of 36 SUMM'T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 21020351 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com 15-Feb-21 Client: Synagro Project: Roxboro WWTP BatchID: R123659 Sulfide, Reactive ND 25.0 Sulfide, Reactive 2330 25.0 2430 0 95.9 85 115 Sulfide, Reactive 2410 25.0 2430 0 99.2 80 120 Sample ID: 21020349-001AMSD SampType: MSD TestCode: Sulfide,React Units: mg/Kg Prep Date: RunNo: 123659 Client ID: Batch= Batch ID: R123659 TestNo: SW9034 Analysis Date: 2/10/2021 SegNo: 3200356 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive 2330 25.0 2430 0 95.9 80 120 2410 3.38 30 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 27 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ Lggir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com QC SUMMARY REPORT WO#: 21020351 15-Feb-21 Client: Synagro Project: Roxboro WWTP BatchID: R123659 Sample ID: 21020349-001AMSD SampType: MSD TestCode: Sulfide,React Units: mg/Kg Prep Date: RunNo: 123659 client ID: BatchQC Batch ID: R123659 TestNo: SW9034 Analysis Date: 2/10/2021 SegNo: 3200356 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 28 of 36 SUMM'T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 21020351 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com 15-Feb-21 Client: Synagro Project: Roxboro WWTP BatchID: R123682 Cyanide, Reactive ND 0.500 Cyanide, Reactive 9.55 0.495 10.00 0 95.5 85 115 Cyanide, Reactive 0.566 0.500 0.5000 0 113 65 135 Sample ID: 21020349-001AMS SampType: MS TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 123682 Client ID: Batch= Batch ID: R123682 TestNo: SW9014 Analysis Date: 2/10/2021 SegNo: 3201229 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 8.20 0.500 10.00 0 82.0 75 125 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 29 of 36 MM'T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 21020351 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com 15-Feb-21 Client: Synagro Project: Roxboro WWTP BatchID: R123682 Sample ID: 21020349-001AMS SampType: MS TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 123682 Client ID: Batch= Batch ID: R123682 TestNo: SW9014 Analysis Date: 2/10/2021 SegNo: 3201229 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sample ID: 21020349-001AMSD SampType: MSD TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 123682 Client ID: Batch= Batch ID: R123682 TestNo: SW9014 Analysis Date: 2/10/2021 SegNo: 3201230 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 8.28 0.500 10.00 0 82.8 75 125 8.197 0.968 10 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 30 of 36 MM'T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMEWAL rECHN❑ Lggir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 21020351 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com 15-Feb-21 Client: Synagro Project: Roxboro WWTP BatchID: R123768 Sample ID: 21020470-002ADUP SampType: DUP TestCode: pH_S(9045D) Units: s.u.@18.4C Prep Date: RunNo: 123768 Client ID: Batch= Batch ID: R123768 TestNo: SW9045D Analysis Date: 2/12/2021 SegNo: 3203974 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual pH 7.0 0 0 0 0 7.0 0.6 10 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 31 of 36 MM'T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 21020351 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com 15-Feb-21 Client: Synagro Project: Roxboro WWTP BatchID: R123768 Sample ID: PH 7 CHECK SampType: LCS TestCode: PH_0IL(9045 Units: s.u.@19.4C Prep Date: RunNo: 123768 Client ID: LCSW Batch ID: R123768 TestNo: SW9045D Analysis Date: 2/12/2021 SegNo: 3203969 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual pH 7.0 7.0 0 101 90 110 Sample ID: PH 7 CHACK SampType: LCS TestCode: PH_0IL(9045 Units: s.u.@19.00 Prep Date: RunNo: 123768 Client ID: LCSW Batch ID: R123768 TestNo: SW9045D Analysis Date: 2/12/2021 SegNo: 3204026 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual pH 7.0 7.0 0 101 90 110 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 32 of 36 MM'T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 21020351 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com 15-Feb-21 Client: Synagro Project: Roxboro WWTP BatchID: R123768 Sample ID: LCS-R123768 SampType: LCS TestCode: pH_NPW(450 Units: s.u.@18.1C Prep Date: RunNo: 123768 Client ID: LCSW Batch ID: R123768 TestNo: SW9045D Analysis Date: 2/12/2021 SegNo: 3203913 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual pH 7.0 7.0 0 101 98.6 101.4 Sample ID: 21020409-001ADUP SampType: DUP TestCode: pH_NPW(450 Units: s.u.@19.7C Prep Date: RunNo: 123768 Client ID: Batch= Batch ID: R123768 TestNo: SW9045D Analysis Date: 2/12/2021 SegNo: 3203915 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual pH 7.0 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits 7.0 0.4 5 H E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 33 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ Lggir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com QC SUMMARY REPORT WO#: 21020351 15-Feb-21 Client: Synagro Project: Roxboro WWTP BatchID: R123824 Sample ID: 21020350-001ADUP SampType: DUP TestCode: FreeLiquid_S Units: Prep Date: RunNo: 123824 client ID: BatchQC Batch ID: R123824 TestNo: SW9095 Analysis Date: 2/15/2021 SegNo: 3206305 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Free Liquid pass Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits 0 0 20 E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 34 of 36 tu { -A 0 L a is mmmsma ppaft =f ma ma �i ra W Y V is '•ammV'm6tr''DO RL •POSER S!!00* H (t m"w&w w � ' A"mftSEM-AM'.WPMM"8& N-AUQ :qv-v'4o-a'PPb I--1%Am"-, pm-Sug-rw s SON" a �+s as al L milk W 13 R i i • J 0 0) m a - Page 35 of 36 �� Summit Environmental Technologies, Inc. SU3310 Win St. ENVIRONMENTAL TECHNOLOQH�S.IfiC Cuyahoga Falls, Ohio44223 Sample Log -In Check List Arrafocaf Laboralorias TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,,",m,.settek.com Client Name: SYN-NC-27028 Work Order Number: 21020351 RcptNo: 1 Logged by: Jacqueline Rasile Completed By: Jacqueline Rasile Reviewed By: Jennifer Woolf 2/5/2021 12:25:00 PM 2/5/2021 1:28:53 PM 2/5/2021 3:44:03 PM Chain of Custody 1. Is Chain of Custody complete? Yes ❑ No ❑d Not Present ❑ 2. How was the sample delivered? UPS Lop In 3. Coolers are present? Yes ❑d No ❑ NA ❑ 4. Shipping container/cooler in good condition? Yes d❑ No ❑ Custody seals intact on shipping container/cooler? Yes ❑ No ❑ Not Present V No. Seal Date: Signed By: 5. Was an attempt made to cool the samples? Yes ❑d No ❑ NA ❑ 6. Were all samples received at a temperature of >0° C to 6.0°C Yes ❑d No ❑ NA ❑ 7. Sample(s) in proper container(s)? Yes ❑d No ❑ 8. Sufficient sample volume for indicated test(s)? Yes ❑d No ❑ g. Are samples (except VOA and ONG) properly preserved? Yes ❑d No ❑ 10. Was preservative added to bottles? Yes ❑ No ❑d NA ❑ 11. Is the headspace in the VOA vials less than 1/4 inch or 6 mm? Yes ❑ No ❑ No VOA Vials ❑� 12. Were any sample containers received broken? Yes ❑ No ❑d 13. Does paperwork match bottle labels? Yes No ❑ (Note discrepancies on chain of custody) 14. Are matrices correctly identified on Chain of Custody? Yes ❑d No ❑ 15. Is it clear what analyses were requested? Yes ❑d No ❑ 16. Were all holding times able to be met? Yes No ❑ (If no, notify customer for authorization.) Special Handling (if applicable) 17. Was client notified of all discrepancies with this order? Yes ❑d No ❑ NA ❑ Person Notified: IRvan Copeland Date: 1 2/5/2021 By Whom: JJennifer Woolf Via: 0 eMail ❑ Phone ❑ Fax ❑ In Person Regarding: state? Client Instructions: INC 18. Additional remarks: NC project address not included Cooler Information Cooler No Temp °C Condition I Seal Intact Seal No Seal Date Signed By 1 12.3 Goodl Not Present Page 36 of 36 SECTION 5 ANNUAL PATHOGEN AND VECTOR ATTRACTION ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City of Roxboro WWTP WQ Permit dumber: WQ 0021826 WWTP Name: Roxboro WWTP NPDES Number: NC 0021024 Monitoring Period: From 01/01/2023 To 12/31/2023 Pathogen Reduction (40 CFR 503.32115A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. i/A (time/temp) Alt. 2/B (Alk Treatment) Alt. 31C (Prior Testing) Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion If applicable to alternative performed ( Parameter I Allowable Level in Sludge Fecal 2x10 to the 61h CFU Coliform power per gram of total solids CFU 2x 10 to the 61h CFU power per gram of total solids I solids Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal lass A or Class B) complete the following monitorin i data: Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo, Mean Maximum Units dences Analysis 28037 34387 48077 CFU/g 0 4/yr Grab 9222D CFU/g CFU/g Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: Option/Alt. I (VS reduction) Option/Alt. 2 (40-day bench) Option/Alt. 3 (30-day bench) X Option/Alt. 4 (Spec. 02 uptake) Option/Alt. 5 (14-Day Aerobic) Option/Alt. 6 (Alk Stabilization) Option/Alt. 7 (Drying — Stable) Option/Alt. 8 (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (injection) (incorporation) No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) 9 certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02TA 106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met" "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1 107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attracion reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Derek Clayton, WWTP Superintendent Preparer Name and Title Land Applier Name and Title (if applicable) (type or print) 2= L3- 2 ti Signature of Preparer* 11 Date Signature of Land Applier (if applicable) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) Date Meritech, Inc. Environmental Laboratory Laboratory Certification No.16S i.k-- 0-17 Contact: Alex Fox Page 1Report Date: 1/17/2023 Client: Synagro 284 Boger Road Project: Roxboro Mocksville, NC 27028 Date Sample Rcvd: 1/10/2023 Meritech Work Order # 01102350 Sample: R 1 Grab 1/10/23 Parameters Results Analysis Date Reporting Limit Method % Total Solids 20.8 Ito 1/12/23 0-100 % SM 2540B Fecal Coliform (Sludge) 48,077 CFU/g dry wt 1/10/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 01102351 Sample: R 2 Grab 1/10/23 Parameters Results Analysis Date Reporting Limit Method % Total Solids 21.2 % 1/12/23 0-100 % SM 2540B Fecal Coliform (Sludge) 33,019 CFU/g dry wt 1/10/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 01102352 Sample: R 3 Grab 1/10/23 Parameters Results Analysis Date Reporting Limit Method % Total Solids 21.1 % 1/12/23 0-100 % SM 2540B Fecal Coliform (Sludge) 28,436 CFU/g dry wt 1/10/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 01102353 Sample: R 4 Grab 1/10/23 Parameters Results Analysis Date Reporting Limit Method % Total Solids 21.4 % 1/12/23 0-100 % SM 2540B Fecal Coliform. (Sludge) 42,056 CFU/g dry wt 1/10/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 01102354 Sample: R 5 Grab 1/10/23 Parameters Results Analysis Date Reporting Limit Method % Total Solids 21.0 % 1/12/23 0-100 % SM 2540B Fecal Coliform (Sludge) 38,095 CFU/g dry wt 1/10/23 130 CFU/g dry wt SM 9222D 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 Meritech, Inc. Environmental Laboratory Laboratory Certification No.165 Page 2 Contact: Alex Fox Report Date: 1/17/2023 Client: 5ynagro 284 Boger Road Project: Roxboro Mocksville, NC 27028 Date Sample Rcvd: 1/10/2023 Meritech Work Order # 01102355 Sample: R 6 Grab 1/10/23 Parameters Results Analysis Date Reporting_ Limit Method % Total Solids 21.4 % 1/12/23 0-100 % SM 2540B Fecal Coliform (Sludge) 28,037 CFU/g dry wt 1/10/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 01102356 Sample: R 7 Grab 1/10/23 Parameters Results Analysis Date Reporting Limit Method % Total Solids 21.4 % 1/12/23 0-100 % SM 2540E Fecal Coliform (Sludge) 28,037 CFU/g dry wt 1/10/23 130 CFU/g dry wt SM 9222D I hereby certify that I have reviewed and approve these data. Laboratory Representative 642 Tamco Road, Reidsville, North CaroIina 27320 tel.(336)342-4748 fax.(336)342-1522 ❑ ❑ ❑ t,, („ N MCD rn x rD Q r < rD ER 7 3 a Q 0- fD N v �' N CD O k i(D m rD 3 C Z p V' C) ;a 0 rt ro � 3 0 o m rD 0 a h i _ 4} -� m n Q q Q X O v'{ CO• n rl O ro fD c7 3 fu '* w w �, a (A Q n yj � 4�-- O Cn `4 ti4�n , vM 0- SD [d H fD 3 3 3 m N o a o I m rr > � ❑ ti h ro �O 3 z n o x f7 0 o fD r* N 0 ° m _ rD mro A Q m Q m rr _ w C ro rD -Q m 7 T L V -.�- — 3 �r rrt S fD � ^C � fD Ln 0 m r 7� 9 iD D Q r O r-r T M ro (D X e-F rD -v m m -0 Z O O W x p o `q m cn f� c/ J �' CL �^ a W w 0 � a TO w rD M N c o � CA = -'IM ❑ v n ° = S� �i v-i m rDG s y ' 1 m c �} - 3 3 ck p m O N c t" `� ��° o> s O o < 5 DIGESTER "COOLER" SLUDGE ROXBORO WWTP LAB % TOTAL RESIDUE and VOLATILE SOLIDS STANDARD METHODS 18TH ED. 2540B and 2540E Analyst: Nicki Dalton, Crystal Shotwell DATE / TIME OF TEST SAMPLE DATE DISH # VOL. ML INITIAL DISH WEIGHT (grams) WEIGHT DISH + WET SOLIDS (grams) WEIGHT WET SOLIDS (grams) (Total) Time In Oven (Total) Time Out Oven WEIGHT DISH + DRY SOLIDS (grams) WEIGHT DRY SOLIDS (grams) % TOTAL SOLIDS IGNITED WEIGHT (grams) WEIGHT VOLATILE SOLIDS (grams) % VOLATILE SOLIDS ANALYST INITIALS RPD's if Needed 1/4/23 1/3/2023 9 35 73.4460 107.8805 34.4345 7:41 AM 8:41 AM 73.6644 .2184 0.63 73.5213 .1431 66 ND 0% 444 AM 1/3/2023 8 35 77.9028 113.0816 35.1788 7:41 AM 8:41 AM 78.1246 .2218 0.63 77.9791 .1455 66 ND 1/10/23 1/10/2023 8 35 77.9015 111.9999 34.0984 7:35 AM 8:35 AM 78.0846 .1831 0.54 77.9622 .1224 67 ND 0% 444 AM 1/10/2023 9 35 73.4457 107.6452 34.1995 7:35 AM 8:35 AM 73.6291 .1834 0.54 73.5063 .1228 67 ND 1/17/23 1/17/2023 8 35 77.9028 111.6261 33.7233 7:19 AM 8:19 AM 78.0745 .1717 0.51 77.9598 .1147 67 ND 0% 458 AM 1/17/2023 9 35 73.4469 107.5864 34.1395 7:19 AM 8:19 AM 73.6197 .1728 0.51 73.5043 .1154 67 ND 1/24/23 1/24/2023 9 35 73.4472 108.2938 34.8466 7:05 AM 8:05 AM 73.6113 .1641 0.47 73.5004 .1109 68 ND 0% 455 AM 1/24/2023 8 35 77.9037 112.6608 34.7571 7:05 AM 8:05 AM 78.0666 .1629 0.47 77.9563 .1103 68 ND 1/31/23 1/31/2023 9 35 73.4484 107.6093 34.1609 7:15AM 8:15AM 73.6037 .1553 0.45 73.4991 .1046 67 ND 0% 448 AM 1/31/2023 8 35 77.9042 112.7576 34.8534 7:15 AM 8:15 AM 78.0614 .1572 0.45 77.956 .1054 67 ND 2/7123 2/7/2023 9 35 73.4492 107.2672 33.8180 6:59 AM 7:59 AM 73.5927 .1435 0.42 73.4957 .0970 68 ND 1% 443 AM 2/7/2023 8 35 77.9056 112.3569 34.4513 6:59 AM 7:59 AM 78.0522 .1466 0.43 77.9535 .0987 67 ND VSR 0 x - Blank 2023 ( Quarter) VECTOR ATTRACTION CALCULATIONS DIGESTER "COOLER" SLUDGE ROXBORO WWTP LAB % TOTAL RESIDUE and VOLATILE SOLIDS STANDARD METHODS 18TH ED. 2540B and 2540E Analyst: Nicki Dalton, Crystal Shotwell DATE / TIME OF TEST SAMPLE DATE DISH # VOL. ML INITIAL DISH WEIGHT (grams) WEIGHT DISH + WET SOLIDS (grams) WEIGHT WET SOLIDS (grams) (Total) Time In Oven (Total) Time Out Oven WEIGHT DISH + DRY SOLIDS (grams) WEIGHT DRY SOLIDS (grams) % TOTAL SOLIDS IGNITED WEIGHT (grams) WEIGHT VOLATILE SOLIDS (grams) % VOLATILE SOLIDS ANALYST INITIALS RPD's if Needed 4/5/23 4/4/2023 5 35 82.3927 116.0981 33.7054 7:36 AM 8:36 AM 82.7153 .3226 0.96 82.5027 .2126 66 ND 0% 441 AM 4/4/2023 6 35 76.3202 110.8845 34.5643 7:36 AM 8:36 AM 76.6501 .3299 0.95 76.4327 .2174 66 ND 4/11/23 4/11/2023 6 35 76.3208 110.7807 34.4599 8:13 AM 9:13 AM 76.6286 .3078 0.89 76.4289 .1997 65 ND 0% 523 AM 4/11/2023 5 35 82.3931 117.0160 34.6229 8:13 AM 9:13 AM 82.7018 .3087 0.89 82.5019 .1999 65 ND 4/18/23 4/18/2023 6 35 76.3219 111.0216 34.6997 7:14 AM 8:14 AM 76.6119 .2900 0.84 76.4227 .1892 65 ND 0% 445 AM 4/18/2023 5 35 82.3944 116.8646 34.4702 7:14 AM 8:14 AM 82.6806 .2862 0.83 82.4935 .1871 65 ND 4/25/23 4/25/2023 5 35 82.3950 115.8800 33.4850 7:22 AM 822 AM 82.6418 .2468 0.74 82.4764 .1654 67 ND 0% 521 AM 4/25/2023 6 35 76.3226 110.4272 34.1046 7:22 AM 822 AM 76.5714 .2488 0.73 76.4045 .1669 67 ND 5/2/23 5/2/2023 6 35 76.3243 110.7616 34.4373 7:17 AM 8:17 AM 76.5888 .2645 0.77 76.4182 .1706 64 CLS 0% 4:52 AM 5/2/2023 5 35 82.3965 116.8659 34.4694 7:17 AM 8:17 AM 82.6620 .2655 0.77 82.4908 .1712 64 CLS 5/9/23 5/9/2023 5 35 82.3970 116.2637 33.8667 7:18 AM 8:18 AM 82.6216 .2246 0.66 82.4729 .1487 66 ND 0% 445 AM 5/9/2023 6 35 76.3247 110.9520 34.6273 7:18 AM 8:18 AM 76.5516 .2269 0.66 76.4019 .1497 66 ND VSR 0 x - Blank 2023 ( Quarter) VECTOR ATTRACTION CALCULATIONS DIGESTER "COOLER" SLUDGE ROXBORO WWTP LAB % TOTAL RESIDUE and VOLATILE SOLIDS STANDARD METHODS 18TH ED. 2540B and 2540E Analyst: Nicki Dalton, Crystal Shotwell DATE / TIME OF TEST SAMPLE DATE DISH # VOL. ML INITIAL DISH WEIGHT (grams) WEIGHT DISH + WET SOLIDS (grams) WEIGHT WET SOLIDS (grams) (Total) Time In Oven (Total) Time Out Oven WEIGHT DISH + DRY SOLIDS (grams) WEIGHT DRY SOLIDS (grams) % TOTAL SOLIDS IGNITED WEIGHT (grams) WEIGHT VOLATILE SOLIDS (grams) % VOLATILE SOLIDS ANALYST INITIALS RPD's if Needed 7/11/23 7/10/2023 5 35 82.3979 117.5176 35.1197 7:56 AM 8:56 AM 82.6307 .2328 0.66 82.4853 .1454 62 ND 2% 445 AM 7/10/2023 6 35 76.3258 110.5668 34.2410 7:56 AM 8:56 AM 76.5531 .2273 0.66 76.4141 .1390 61 ND 7/18/23 7/17/2023 5 35 82.3992 117.3725 34.9733 7:02 AM 8:02 AM 82.6244 .2252 0.64 82.4873 .1371 61 ND 0% 438 AM 7/17/2023 6 35 76.3263 110.6192 34.2929 7:02 AM 8:02 AM 76.5459 .2196 0.64 76.4124 .1335 61 ND 7/25/23 7/24/2023 6 35 76.3268 110.5080 34.1812 7:01 AM 8:01 AM 76.5239 .1971 0.58 76.402 .1219 62 ND 2% 433 AM 7/24/2023 5 35 82.3992 116.8764 34.4772 7:01 AM 8:01 AM 82.5920 .1928 0.56 82.4704 .1216 63 ND 8/1/23 7/31/2023 6 35 76.3277 110.3257 33.9980 6:52AM 7:52AM 76.5075 .1798 0.53 76.3945 .1130 63 ND 0% 435 AM 7/31/2023 5 35 82.3999 116.9838 34.5839 6:52 AM 7:52 AM 82.5802 .1803 0.52 82.4664 .1138 63 ND 8/8/23 8/7/2023 6 35 76.3287 110.9598 34.6311 7:02 AM 8:02 AM 76.5075 .1788 0.52 76.3932 .1143 64 ND 0% 4:32 AM 8/7/2023 5 35 82.4011 117.6101 35.2090 7:02 AM 8:02 AM 82.5817 .1806 0.51 82.4664 .1153 64 ND 8/14/23 8/14/2023 6 35 76.3292 110.3636 34.0344 6:54 AM 7:54 AM 76.4977 .1685 0.50 76.3908 .1069 63 ND 0% 445 AM 8/14/2023 5 35 82.4014 116.5815 34.1801 6:54 AM 7:54 AM 82.5707 .1693 0.50 82.4635 .1072 63 ND VSR 0 x - Blank 2023 ( Quarter) VECTOR ATTRACTION CALCULATIONS DIGESTER "COOLER" SLUDGE ROXBORO WWTP LAB % TOTAL RESIDUE and VOLATILE SOLIDS STANDARD METHODS 18TH ED. 2540B and 2540E Analyst: Nicki Dalton, Crystal Shotwell DATE / TIME OF TEST SAMPLE DATE DISH # VOL. ML INITIAL DISH WEIGHT (grams) WEIGHT DISH + WET SOLIDS (grams) WEIGHT WET SOLIDS (grams) (Total) Time In Oven (Total) Time Out Oven WEIGHT DISH + DRY SOLIDS (grams) WEIGHT DRY SOLIDS (grams) % TOTAL SOLIDS IGNITED WEIGHT (grams) WEIGHT VOLATILE SOLIDS (grams) % VOLATILE SOLIDS ANALYST INITIALS RPD's if Needed 10/5/23 10/4/2023 5 35 82.4015 117.3877 34.9862 7:17 AM 8:17 AM 82.6502 .2487 0.71 82.4948 .1554 62 ND 0% 433 AM 10/4/2023 6 35 76.3293 110.7354 34.4061 7:17 AM 8:17 AM 76.5723 .2430 0.71 76.4214 .1509 62 ND 10/11/23 10/11/2023 5 35 82.4010 116.9475 34.5465 7:03AM 8:03AM 82.6061 .2051 0.59 82.4733 .1328 65 ND 0% 4:37 AM 10/11/2023 6 35 76.3287 111.7918 35.4631 7:03 AM 8:03 AM 76.5347 .2060 0.58 76.4 .1347 65 ND 10/18/23 10/18/2023 5 35 82.4010 115.8218 33.4208 7:14 AM 8:14 AM 82.5903 .1893 0.57 82.4684 .1219 64 ND 0% 434 AM 10/18/2023 6 35 76.3288 110.5054 34.1766 7:14 AM 8:14 AM 76.5251 .1963 0.57 76.3987 .1264 64 ND 10/25/23 10/25/2023 5 35 82.4013 116.7124 34.3111 7:27 AM 827 AM 82.5880 .1867 0.54 82.4683 .1197 64 ND 2% 434 AM 10/25/2023 6 35 76.3290 110.7429 34.4139 7:27 AM 827 AM 76.5123 .1833 0.53 76.3935 .1188 65 ND 11/1/23 11/1/2023 6 35 76.3293 110.1837 33.8544 6:48AM 7:48AM 76.5151 .1858 0.55 76.3972 .1179 63 ND 0% 4:37 AM 11/1/2023 5 35 82.4016 117.2930 34.8914 6:48 AM 7:48 AM 82.5917 .1901 0.54 82.4715 .1202 63 ND 11/8/23 11/8/2023 6 35 76.3299 111.6640 35.3341 6:50 AM 7:50 AM 76.4969 .1670 0.47 76.3886 .1083 65 ND 0% 429 AM 11/8/2023 5 35 82.4026 116.6055 34.2029 6:50 AM 7:50 AM 82.5682 .1656 0.48 82.4612 .1070 65 ND VSR 0 x - Blank 2023 ( Quarter) VECTOR ATTRACTION CALCULATIONS 2023 503 VECTOR ATTRACTION This is our worksheet showing that in using the 503.33(b)(option3) that we are within the vector attraction reduction limit of 15% Reduction Formula In - Out .66 - .675 -.015 -0.015 In - (In x Out) .66- (.66 x .675) .66 - .446 In - Out .66-.66 .00 In - (In x Out) .66- (.66 x .66) .66 - .436 In - Out .615 - .63 -.015 In - (In x Out) .615- (. 615 x .63) .615 - .387 In - Out .62 - .65 -.030 In - (In x Out) .62- (.62 x .65) .62 - .403 Reduction .214 -.070 x 100 -7.00 First Quarter .000 .224 .000 x 100 0.00 Second Quarter -0.015 .228 -0.066 x 100 -6.58 Third Quarter -.030 .217 -0.138 x 100 -13.82 Fourth Quarter 2023 2023 2023 2023 SECTION 6 Agricultural Lime Application Log Year: 2023 Project: Roxboro Field (state -county -site -field) Soil pH Lime Requirement (from soil analysis)II Tons/Acre L Applied Date Applied NC-PS-24-1 5.8 0.0 tons/ac. 0.0 NC-PS-24-2 5.7 0.0 tons/ac. 0.0 NC-PS-24-3 5.9 0.0 tons/ac. 0.0 NC-PS-25-1A 5.7 0.0tons/ac. 0.0 NC-PS-25-1 B 6.0 0.0 tons/ac. 0.0 NC-PS-25-02 6.2 0.0 tons/ac. 0.0 SECTION 7 FY24-SL018908 NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/Divisions/Agronomic-Services Report No. k5i I"14'4+;4 Client: Ronald Carver Advisor: Ryan Copeland Predictive 105 Carver Farm Rd SYNAGRO °± f' Roxboro, NC 27573 284 Boger Road �- Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Sampled County : Person _ Soil Testing Section Sampled: Received: 11/22/2023 Completed: 01/24/2024 Farm: PS-24 Client ID: 545159 Advisor ID: 499503 Sample ID: PS241 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.4 120-200 0 110 0 0 0 0 0 0 Note: 12 2- Fescue/OGrass/Tim, M 0.0 120-200 0 110 0 0 0 0 0 0 Note: 12 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.27 1.00 9.4 83 1.6 5.8 154 16 66 16 59 591 372 372 460 460 522 0.1 1 Sample ID: PS242 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.5 120-200 0 0 0 0 0 0 0 0 Note: 12 2- Fescue/OGrass/Tim, M 0.0 120-200 0 0 0 0 0 0 0 0 Note: 12 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.41 0.93 8.8 84 1.4 5.7 66 106 58 19 71 718 448 448 228 228 241 0.0 North Carolina Tai wLm Truk f and Ctwinlsskm Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/Divisions/Agronomic-Services Report No. FY24-SL018908 Ronald Carver Page 2 of 3 Sample ID: PS243 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 60 0 0 0 0 0 0 0 Note: 12 2- Fescue/OGrass/Tim, M 0.0 120-200 60 0 0 0 0 0 0 0 Note: 12 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.46 0.99 8.0 83 1.4 5.9 34 90 57 20 57 744 463 463 157 157 173 0.1 1 NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/Divisions/Agronomic-Services Report No. FY24-SL018908 Ronald Carver Page 3 of 3 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Ac exchangeable acidity Lime B boron If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either BS% % CEC occupied by basic ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 to 75 Ib/1000 sq ft) Ca% % CEC occupied by calcium at one time, even if the report recommends more. You can apply the rest in similar increments every six months until the CEC cation exchange capacity full rate is applied. If Mg is recommended and lime is needed, use dolomitic lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Each nutrient recommendation for field crops or other large areas are listed separately in units of lb/acre unless K-1 potassium index otherwise specified. Recommendations for N (and sometimes for B) are based on research/field studies for the crop K20 potash being grown, not on soil test results. Recommendations for K and P will depend on K-1 and P-1 soil test results and the Mg% % CEC occupied by magnesium crop to be grown. Generally, at K-1 and P-1 values > 50, recommendations will be minimal. If Mg is needed and no lime is MIN mineral soil class recommended, 0-0-22 (11.5% Mg) is an excellent source; 175 to 250 lb/acre alone or in a fertilizer blend will usually Mn manganese satisfy crop needs. Soluble salt levels (SS-1) appear only on reports for diagnostic/problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn-I manganese index notations appear on the soil report in the recommendation section, refer to NCDA&CS M-0 mineral -organic soil class $Note: Secondary Nutrients and Micronutrients. Various NCDA&CS crop notes also address lime and fertilizer needs. N nitrogen Na sodium Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft. If you cannot find NO3-N nitrate nitrogen the exact fertilizer grade recommended on the report, visit NCDA&CS Fertilizer Substitutions to find information that may ORG pH pH organic soil class current soil pH help you choose a comparable alternate. For more information, read NCSU publication, phosphorus index A Homeowner's Guide to Fertilizer. In general, homeowners do not need to be concerned about micronutrients. P-1 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven parameters [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. Zn-AI zinc availability index The remaining 16 parameters [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-AI2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinely available)] indicate levels of plant nutrients or other fertility measurement. Visit NCDA&CS Understand Your Report for more information. Page 1 of 1 Report No: 24-044-1522 Account No: 46622 Advisor: Synagro Central LLC/ Technical Mary Brewer 284 Boger Road Mocksville NC 27028 (D waypolnt.m ANALYTICAL Client: Paul Bailey 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Farm: NC-PS-25 Date Received: 02/13/2024 Date of Report: 02/15/2024 Lab No Field ID Sample ID Soil Class HM% W/V pH Ac P-1 K-1 S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I CEC BS % Ca % Mg % ESP Na 21466 25-1A MIN 1.8 5.7 1.3 41 27 48 463 0 0 123 123 75 6.1 78 52 23 1.0 0.1 21467 25-1 B MIN 1.7 6.0 0.8 42 20 52 469 0 0 113 113 70 5.2 85 57 25 1.2 0.1 21468 25-2 MIN 2.0 6.2 1.0 17 28 83 244 0 0 95 95 100 8.0 87 67 18 0.7 0.1 Comment: Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3 North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc.