WQ0004095_2023 Residual Annual Report_20240228 (2)

Initial Review
Reviewer
nathaniel.thorn burg
Is this submittal an application? (Excluding additional information.) *
Yes No
If not an application what is the submittal type?* Annual Report
Residual Annual Report
Additional Information
Other
Annual Report Year* 2023
Permit Number (IR) * WQ0004095
Applicant/Permittee PCS Phosphate Company, Inc.
Email Notifications
Does this need review by the hydrogeologist? * Yes U No
Regional Office Washington
CO Reviewer
Admin Reviewer Wanda Gerald

Submittal Form
Project Contact Information
Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence.
Name* James Chandler Stroud
Email Address*
[e-mail]
Project Information
.........................
Application/Document Type*
New (Fee Required)
Modification - Major (Fee Required)
Renewal with Major Modification (Fee
Required)
Annual Report
Additional Information
Other
Phone Number*
12524026044
Modification - Minor
Renewal
GW-59, NDMR, NDMLR, NDAR-1,
N DAR-2
Residual Annual Report
Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:*
Wastewater Irrigation
High -Rate Infiltration
Other Wastewater
Reclaimed Water
Closed -Loop Recycle
Residuals
Single -Family Residence Wastewater
Other
Irrigation
Permit Number:*
WQ0004095
Has Current Existing permit number
Applicant/Permittee Address*
1530 NC Hwy 306 South Aurora, NC 27808
Facility Name*
PCS Phosphate Class B Residuals Program
Please provide comments/notes on your current submittal below.
Annual Residual Land Application Report - 2023
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.
(Application Form, Engineering Plans, Specifications, Calculations, Etc.)
2023 Annual Report_ Residuals Land Application
1.74MB
Program_WQ0004095 Final_Feb 2024.pdf
Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger
than upload limit.
* By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has
been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the
North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts
of the application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
Signature
�?,rnl C .filN.flrt' c S-rnrs
Submission Date 2/28/2024

Alutrien-
CERTIFIED MAIL
February 26, 2024
Division of Water Resources
Information Processing Unit/Non-Discharge Branch
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
Subject: Permit #WQ0004095
PCS Phosphate Company, Inc.1
Residual Land Application Program
2023 Annual Report
Dear Mr. Thornburg,
As required by Condition IV.8 - Monitoring and Reporting Requirements, of the above
reference permit, attached is the Annual Residual Land Application Report for the 2023 calendar
year.
Please do not hesitate to contact me at (252)-402-6044 if I can answer any questions or provide
any additional information.
Sincerely,
James Ch er Stroud
Supervisor, Environmental Affairs & Technical Services
Nutrien — Aurora
Attachments
PC: 12-04-01
ec: Lauren Raup-Plummer — DWR, NDB (w/attachments)
K.A. Alnandy (w/attachments)
B.S. Curtis (w/attachments)
L. D. Davis (w/attachments)
1530 NC Hwy 306 South, Aurora, NC USA 27806 nutrien.00m
1 Effective January 1, 2018, PCS Phosphate Company, Inc. is an indirect subsidiary of Nutrien Ltd. PCS Phosphate Company, Inc.
remains the legal operating entity and permittee.

Residual Land Application Program
PCS Phosphate Company, Inc.
Aurora, NC
Permit No. WQ0004095
2023 Annual Report

Table Of Contents
1. Annual Land Application Certification Form (ACF)
2. Annual Residual Sampling Summary Form (RSSF) — A &B
3. Annual Metals Field Loading Summary Form (MFLSF)
4. Annual Land Application Field Summary Form (FSF)
5. Annual Pathogen & Vector Attraction Reduction Form (PVRF)
6. PVRF Records — Sludge Stabilization Form
7. Residuals Analysis Report — Element One, Inc.
8. Soil Analysis Results — NCDA&CS
9. Realistic yield Expectations Summary - NCSU
10. Monitoring & Reporting Requirements (Annual)

ANNUAL LAND APPLICATION CERTIFICATION FORM
WQ Permit#: WQ0004095 County: Beaufort Year: 2023
Facility Name (as shown on permit):
PCS Phosphate Company, Inc.
Land Application Operator: PCS Phosphate Company, Inc. Phone:
Land application of residuals as allowed by the permit occurred during the past calendar year?
© Yes ❑ No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A - Residuals Application Summary:
252-322-8283
Total number of a lication fields in thepermit:
Two
Total number of fields utilized for land application during the year:
One
Total amount of dry tons applied during the year for all application sites:
6.58640241
Total number of acres utilizes for land application during the year:
4.4
Part B - Annual Compiance Statement:
Facility was compliant during calendar year 2023 with all conditions of the land application permit
(including but not limited to items 1-13 below) issued by the Division of Water Resources. 0 Yes ❑ No
If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action
taken.
1) Only residuals approved for this permit were applied to the permitted sites.
2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or
the limit specified in the permit.
3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies
of laboratory results are attached.
4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached.
5) All other monitoring was performed in accordance with the permit and reported during the year as required and three
(3) copies of certified laboratory results are attached.
6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant
Loading Rates in 15A NCAC 02T .1105(b) (applicable to 40 CFR Part 503 regulated facilities).
7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part
503 regulated facilities).
8) All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part
503 regulated facilities).
9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior
authorization was received from the Division of Water Resources.
10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations.
11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as
specified in the permit.
12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13) All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C - Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate,
and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations."
William M. Ponton
Permittee Name and Title (type or print)
Signature of Permittee Date
Signature of Preparer* Date Signature of Land Applier Date
(if different from Permittee) (if different from Permittee and Preparer)
* Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number:
WQ0004095
Facility Name: PCS Phosphate, Inc.
Residual Source WQ # or
NPDES #:
070111::'
WWTP Name: PCS Phosphate Company, Inc.
Residual Anal sis Data
Laboratory:
1)
2)
3)
4)
5)
Element One, Inc.
Parameter
(mg/kg)
Cone.
Limit
m a
Sample or Composite Date
03/16/23
Percent Solids (%)
NA
6.3
Arsenic
75
0.603
Cadmium
85
1.67
Copper
4,300
167
Chromium
NA
17.9
Lead
840
5.73
Mercury
57
1.25
Molybdenum
75
7.38
Nickel
420
12.6
Selenium
100
1.38
Zinc
7,500
1165
Total Phosphorus
NA
7556
TKN
NA
11159
Ammonia -Nitrogen
NA
617
Nitrate and Nitrite
NA
1495
For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penlayies for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Signature of Preparer *
Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number: WQ0004095
Facility Name: PCS Phosphate Company, Inc.
Residual Source
NPDES # or WQ#:
67011::'
WWTP Name: PCS Phosphate Company, Inc.
Residual Analysis Data
Laboratory:
1)
2)
3)
4)
5)
Element One, Inc.
Parameter
(mg/kg)
-
W
------
------------
----------
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
.- ,` , / �J
Signature of Preparer *
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
ztlz61 ZCe,2y
Date
DENR FORM RSSF - B (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: PCs Phosphate Company, Inc. Total Dry Tons Applied (Annual):
Permit #: WQ0004095 Cation Exchange Capacity (non 503 only):
Operator: CS Phosphate Company, In Owner: Reserveco, Inc. Predominant Soil Series:
Acres Used: 4.4 Acres Permitted: 9.9 Site #: PCs Field #:
6.59
PCs 02
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
DateLei
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
Ill
121131
1
L 5
161
7 1
8 1
9
101
111
12
DT/Ac./
y
o
App.m
y
Event
1.50
Arsenic
0.000
0.000
0.000
0.000
1 0.002
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
0.002
Cadmium
0.000
0.000
0.000
0.000
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
Copper
0.000
0.000
0.000
0.000
0.500
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.500
ChrorniLiiii
0.000
0.000
0.000
0.000
0.054
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.054
Lead
0.000
0.000
0.000
0.000
0.017
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.017
Mercury
0.000
0.000
0.000
0.000
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Molyb-
0.000
0.000
0.000
0.000
0.022
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.022
denum
Nickel
0.000
0.000
0.000
0.000
0.038
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.038
Selenium
0.000
0.000
0.000
0.000
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000 1
0.004
Zinc
0.000
0.000
0.000
0.000
3.488
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.488
Total
Phos-
0.000
0.000
0.000
0.000
22.621
0.000
0.000
0.000
0.000
0.000
0.000
0.000
22.621
phorus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: PCS Phosphate Company, Inc. WQ Permit #: WQ0004095 Field #: PCS 02
Land Owner: Reservco, Inc. Annual Dry Tons Applied: 6.5864 Site #: PCS
Acres Utilized: 4.4
Acres Permitted: 9.99
Operator: PCS Phosphate Company, Predominant Soil Series: BoB - Bonneau Cation Exchange Capacity (non 503):
Crop 1 Name:
Crop 1 Max. PAN:
Crop 2 Name:
Crop 2 Max. PAN:
o
N
Qom.,
Volume applied
PP
(enter one) Solids/
Liquid
9
Cu. Yds Gallons
%
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
Wet,
Moist)
Precip.
Past 24
Hrs.
inches)
Y
b
a 5
T o'
ory w
*
�'
''
* w
o,
7o E
K g
co �'
* N'
* Q'
TKN
mg/kg
a 9
o 5
ao C
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
pp
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
0.000
0.000
0.000
4/5/23
12809
6.3
0.765
PCS WWTP
Dry
0
S
0.5
0.3
7656
783
549
4.592
NA
Bermuda
0.000
R�lPCS
0.000
0.000
4/6/23
12,262
6.3
0.732
WWTP
Dry
0.32
S
0.5
0.3
7656
783
549
4.396
NA
Bermuda
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
11.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
TOTALS:
01
25071
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
8.989
0.1)00
Lime plied
Annuallbs/acre
0.002
0.005
0.500
0.054
0.017
0.004
0.022
0.038
0.004
3.488
22.621
.......
'
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.085
0.249
17.729
0.07
0.686
0.033
0.295
0.528
0.119
68.578
Current Cumulative lbs/ac
0.087
0.254
18.229
0.124
0.703
0.037
0.317
0.566
0.123
72.066
Permitted C. P. L. R.****
36
34
1,338
n/a
267
15
n/a
374
89
2,498
Permit PAN Limit 1st/2nd Crop
. . . . . . . . . . . . . . 226 50
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, i cluding the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0
*** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
Signature of Land Applier iule aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: PCS Phosphate Company, Inc.
WWTP Name: PCS Phosphate Company, Inc.
WQ Permit Number: WQ0004095
NPDES Number: Non Discharge
Monitoring Period: From l/1/2023 To 12/31/2023
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
Alt B (Alk Treatment) ❑
Alt. C (Prior Testing) ❑
A1t.D (No Prior Test) ❑
Process to Further Reduce Pathogengs ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost L31
Heat Drying ❑
Heat Treatment ❑
= Thermophilic ❑
Beta Ray L31
Gamma Ray❑
Pasteurization ❑
Class B:
Alt. (1) Fecal Density ❑ Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization El Air Drying ❑
1 Composting ❑ Aerobic Digestion ❑
e
Anaerobic Di stion [3.............................
..... .
If applicable to alternative performed (Class A or Class B) complete the following
monitoring
data:
Parameter
Allowable Level
in Sludge
g
Pathogen Density
Number °
Excee-
n . s
Frequency
of Analysis
Y
Sample
Type
' na ytica
Tech-
ni
inimu
Geo. Mean
aximu
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
CFU
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform) I
3 MPN per 4 grams
total solid (dry
wei,_ht)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt.1 (VS reduction) ❑Alt. 2 (40-day bench) ❑klt. 3 (30-day bench) ❑klt. 4 (Spec. 02 uptake) ❑
Alt. 5 (14-Day Aerobic) ®Alt. 6 (Alk. Stabilization ❑Ut 7 (Drying - Stable) ❑Alt. 8 (Drying - Unstable) ❑
Alt. 9 (Iniection) Df Alt. 10 (Incorporation) ❑Jo vector, attraction reduction alternatives were Derformed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
® "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
William M. Ponton, General ManagerZ=:::�-
Preparer Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print)
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

►Jutrien-
Waste Water Treatment Plant (WWTP)
Sludge Stabilization Form
ZD Z3
*pH Is read in SU. Instrument ID- Oakton 300 serial # 459794 (temp and pH combo meter)
PH Meter Cal.
Date/ Time
Starting pH
Buff pH
Meter
*pH in SU
4.0 = 4.0 ! 1 P Ptt Temp in °C
pH Meter Cal.
Date/ Time
After lime
Buff H
P
Meter
*pH in SU
4.0
PH Temp in °C
$3
�9.
7.0= ?•� Ig
a3�
7.0= 701
1$
10.00 = ra.a lit
12.45= IZA
IP �
7.0= '1'al i$'
7.0= 70
pn Acceptance i-ritena */-v.i su at c.) _`
Basin
Date
*pH in SU
Starting pH/
°C
Added pounds
of Lime
After Lime pH
(sludge)
°C
Time
Date
*pH in SU
i (24 HrpH)
Limed sludge pH/
Temp
Temp
Temp°C
1
i s
�.�s
J�
,3oa
)Z.Ia
17
►.too'
2
J00
(Z.lf
171
110�r
Y
1Z•lo
20
3
y- 3
(0141
IL
36J
)Za
11
1410
-
i' 2 • it
Zo
4
'L1'3
30a
1 Z: IV
17
11
12.76
J t
Waste
Basin
�,NN
ORC
Signature &
Date w
G r,ments:
_'!?9 201h

el,
Element One Inc.
6319-D Carolina Beach Rd.
Wilmington, NC 28412
Phone: [phone]
Fax: 910 792-W63
el lab dfv,,iel lab.com
FINAL REPORT OF ANALYSES
Element One, Inc. Project Number e40231
Nutrien March 30, 2023
1530 Hwy 306 South Client Project Name: Bio Solids
Aurora, NC 27806 Client PO Number. 2101194967
E1 Project Number e40231
Sample ID: Stabilized Bio Solids
Sample Matrix SS
Sample Type
Grab
Date Received 3/16/2023
Date Sampled 03/15/2023
Time Sampled
1000
Time Received 1000
Sampler
Delivered
by
FedEx
Received by LLB
Extraction Begun 03/20/23 1600 Extraction Ended
03/21/23 0830 E1 Sample # 40231
TCLP
Parameter
Result
Unit Cale. RL Dilution
DL Method
Date
Chromium, TCLP digested
< 0.05
mg/L 0.05
50
0.001 EPA 1311/6020B
03/22/23
Arsenic, TCLP digested
< 0.05
mg/L 0.05
50
0.001 EPA 131116020E
03/22/23
Selenium, TCLP digested
< 0.05
mg/L 0.05
50
0.001 EPA 1311/6020B
03/22/23
Silver, TCLP digested
< 0.05
mg/L 0.05
50
0.001 EPA 1311/6020B
03/22/23
Cadmium, TCLP digested
< 0.05
mg/L 0.05
50
0.001 EPA 1311/6020B
03/22/23
Barium, TCLP digested
0.180
mg/L 0.05
50
0.001 EPA 131116020B
03/22/23
Lead, TCLP digested
< 0.05
mg/L 0.05
50
0.001 EPA 1311/6020B
03/22/23
Mercury, TCLP digested < 0.0004
mg/L 0.0004
2
0.0002 EPA 131117470A
03/22/23
Solids
6.3
%
SM254OG
03/16/23
pH, Initial
12.56
SU
EPA 1311
03/20/23
Fluid Determination pH
11.90
SU
EPA 1311
03/20/23
TCLP pH, Final
12.60
SU
EPA 1311
03/21/23
pH, Extraction Fluid #2
2.88
SU
EPA 1311
03/20/23
Ken Smith, L boratory Director
40231 Nutrien Report Packet Compiled by
Certifications: NJ NELAP NCO09 and NC DWQ DENR 604
Page 1 of 3

el,
elementOne
Nutrien
1530 Hwy 306 South
Aurora, NC 27806
Sample Matrix SS
Date Sampled 03/15/2023
Sampler
Element One Inc.
6319-0 Carolina Beach Rd.
Wilmington, NC 28412
Phone: [phone]
Fax: 910 792-N53
[e-mail]
FINAL REPORT OF ANALYSES
Element One, Inc. Project Number e40231
Parameter
Result
As Received
Sodium, Total
91.0
Magnesium, Total
225
Aluminum, Total
77.6
Phosphorus, Total
476
Potassium, Total
80.1
Calcium, Total
20151
Chromium, Total
1.13
Nickel, Total
0.792
Copper, Total
10.5
Zinc, Total
73.4
Arsenic, Total
< 0.038
Selenium, Total
0.087
Molybdenum, Total
0.465
Cadmium, Total
0.105
Lead, Total
0.361
Mercury, Total
< 0.079
Solids
6.3
pH, as received
12.18
Ken Smith, Laboratory Director
March 30, 2023
Client Project Name: Bio Solids
Client PO Number: 2101194967
El Project Number e40231
Sample ID: Stabilized Bio Solids
Sample Type
Grab
Date Received 3/16/2023
Time Sampled 1000
Time Received 1000
Delivered by
FedEx
Received by LLB
E1
Sample # 40231
TOT
Result
Unit
Dilution
DL
Method
Date
Dry Basis
1444
mg/kg
50
0.2
EPA 301 OA16020B
03/21/23
3571
mg/kg
50
0.2
EPA 3010A/602013
03/21/23
1232
mg/kg
50
0.01
EPA 3010A/602013
03/21/23
7556
mg/kg
50
0.2
EPA 301 OA16020B
03/21/23
1271
mg/kg
5
0.2
EPA 3010A/602013
03/21/23
319857
mg/kg
2500
0.4
EPA 3010AM02013
03/21/23
17.9
mg/kg
5
0.01
EPA 3010A/602013
03/21/23
12.6
mg/kg
5
0.01
EPA 3010A/602013
03/21/23
167
mg/kg
50
0.01
EPA 3010A/602013
03/21/23
1165
mg/kg
50
0.01
EPA 3010A/6020B
03/21123
< 0.603
mg/kg
5
0.01
EPA 3010AI6020B
03/21/23
1.38
mg/kg
5
0.01
EPA 3010A/602013
03/21/23
7.38
mg/kg
5
0.01
EPA 3010A/602013
03/21/23
1.67
mg/kg
5
0.01
EPA 3010A/602013
03/21j'23
5.73
mg/kg
5
0.01
EPA 3010A/602013
03/21123
< 1.25
mg/kg
1
0.1
EPA 7471 B
03/30/23
%
SM254OG
03/16/23
SU
EPA 9045D
03/16/23
40231 Nutrien Report Packet Compiled byQ'\
Certifications: NJ NELAP NCO09 and NC DWQ DENR 604
Page 2 of 3

el,
elementOne
Nutrien
1530 Hwy 306 South
Aurora, NC 27806
Element One Inc.
6319-D Carolina Beach Rd.
Wilmington, NC 28412
Phone: [phone]
Fax: [phone]
[e-mail]
FINAL REPORT OF ANALYSES
Element One, Inc. Project Number e40231
March 30, 2023
Client Project Name: Bio Solids
Client PO Number: 2101194967
E1 Project Number e40231
Sample ID: Stabilized Bio Solids
Sample Matrix SS
Sample Type
Grab
Date Sampled 03/15/2023
Time Sampled
1000
Sampler
Delivered by
FedEx
Parameter
Result
Result Unit
Dilution DL
As Received
Dry Basis
Total Nitrogen-N
797
12651 mg/kg
Nitrate+Nitrite-N
94.2
1495 mg/kg
5 0.5
Kjeidahl Nitrogen, TKN*
703
11159 mg/kg
Ammonia as N`
38.9
617 mg/kg
Organic Nitrogen-N
664
10540 mg/kg
Solids
6.3
NHy�
�MR
{ 149S
Date Received
Time Received
Received by
E1 Sample #
Method
3/16/2023
1000
LLB
40231 TOT
Date
EPA 300.0+ SM 4500 Ng B 03/21/23
EPA 300.0
03/16/23
SM 4500 Nom B
03/20/23
SM 4500 NH3 C
03/21/23
calculation
03/21/23
SM2540G
03/16/23
[ 3,162.tiI { I1%b3•S
KN and NF13-N samples were subcontracted to Environmental Chemists, Inc. for analysis.
e nvJ.'r,3. t o 1 bs. tDiv, Taws q0(6 b' 1 x 6.0 0 -3. = n3
Ken Smith, Laboratory Director Page 3 of 3
40231 Nutrien Report Packet Compiled by
Certifications: NJ NELAP NCO09 and NC DWQ DENR 604

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ANALYnM & COHWLTM CHEW%'n
Environmental Chemists, Inc,
MM Windmill Way, % TmMSwn, NC 28403 + 910-VIOM Lab • 91MM.4424 Fax
710 Bowaeripwn Roan, Mw teo, NC 29954 + =V3MM Lab/Fax
255-A Vf*ni %ftn Highway, Jacksonville, NC 28540 • 910.347-%C Lab/Fax
info@environmentaebenimem
Element One Date of Report: Mar 30, 2023
6319-D Carolina Beach Road Customer PO d:
Wilmington NC 28412 Customer ID: 08100049
Attention: Reportlf: 2023.05466
PrajectID: 40231
Lab ID Sample ID: Collect Dateffime Matrix Sampled by
23-13640 Site: 40231 3/151=3 10:00 AM Solid/Sludge Dale Davis
Test Method Results Date Analyzed
Ammonia Nitrogen GM45WN13C-MI 38.9mgft 03212023
Total Kjeldahl Nitrogen (TKN) sMaW Nam a-WI1 703 mgikg 03/202023
Comment: Reported on an as revived basis.
Reviewed by:
FkCW*. 20234WS Page 1 B 1

Analytical & Consulting Chemists
CLIENT:_Element One, Inc._._,
ADDRESS:-6318-D Carolina Beach Rd.
Wiimingtan, NC 28412^_
Davis
Sample Identification
Date Time
i
40231 0311 rN23 1000
1.
ENVIRONMENTAL CHEMISTS, INC six Windmill Way Wilmington, NC 28409
NCDENR: DWQ CERTERICATION # 94 NCDHHS. OLS CERTIFICAMN 0 37729 OFFICE: 910-3924M FAX [phone]
COLLECTION AND CHAIN OF CUSTODY
PROJECT NAME: REPORT NO:
CONTACT NAME: —Paula Smith PO NO:
REPORT TO: Paula Smith PHONEWAX: 910-793-0i2e
COPYTO:— E-MAIL_Paula.Smith@el lab com
SAMPLE TYPE: I n Influent, E Effluent, W = well, ST = Strmn, SO a So(I, SL = Sludge, Other.
$ PRESERVATION
I I 11111
j ANALYSIS REQUESTED
o
4.8 1 SL I G I P I I le2r _(A4 X I I I I I I INH3, TKN
- DECHLORINATION: Samphla for Ammonia, TKN, Cyanide, Phenol and BacWe must be deeh1winated (0.2 ppmt or less) in the field at the time of e011 WNL See reverse for lnatruetious
Transfer _ _ Ralinnsdmkr4 nu. w_-_..._ _
Temperature when Received:_ Accepted:_
Delivered By:___ Received
Comments:

NCDA&CS Agronomic Division Phone: [phone]
Website: www.ncagr.gov/agronomi/
Report No.
FY23-SL026939
��45'�C{t1kR,4�
Client:
Dale / Larry Davis / Davis Jr.
Advisor:
Predictive
1530 NC Hwy 306 S
=ti
Aurora, NC 27806
= ` Soil Report Mehlich-3 Extraction
Sampled County: Beaufort
1pfui Information
Client ID: 446314
Advisor ID:
Sampled: 02/27/2023 Received: 03/03/2023 Completed: 03/14/2023
Pam,: Nutrien
Sample ID: 00001
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre)
N P2O5
K2O
Mg S
Mn
Zn
Cu B
Information
Lime History:
1 -Bermuda hay/past., E 0.0
60-80 0
100
0 0
pH$
0
0 0
Note: 12 Note:
0.20 tons/acre; 4/2022
2 -Fescue/OGrass/Tim, E 0.0
50-70 0
70
0 0
pH$
0
0 0
Note: 12 Note:
Test Results [units - WN in glcd; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class:
Mineral
HM% WN CEC BS% Ac PH P-1 K-1
Ca% Mg%
S4
Mn-I
Mn-All Mn-AI2
Zn-I
Zn-AI
Cu-I Na ESP SS-1 NO3-N
0.36 1.39 7.3 100 0.0 6.7 208 18
88 11
30
86
57 57
1209
1209
451 0.0
Sample ID: 00002
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre)
N P2O5
K2O
Mg S
Mn
Zn
Cu B
Information
Lime History:
1 -Bermuda hay/past., E 0.0
60-80 0
100
0 0
pH$
0
0 0
Note: 12 Note:
2- Fescue/OGrass/Tim, E 0.0
50-70 0
60
0 0
pH$
0
0 0
Note: 12 Note:
Test Results [units - WN in g1cm3; CEC and Na in meq/100 cm3; NO3-N In mg/dM3]:
Soil Class:
Mineral
HM% WN CEC BS% Ac pH P-1 K-1
Ca% Mg%
S-1
Mn-I
Mn-All Mn-Al2
Zn4
Zn AI
Cu4 Na ESP SS-1 NO3-N
0.46 1.37 7.1 100 0.0 7.0 235 22
88 10
52
93
58 58
755
755
271 0.0
North Carolina
4
Tciamo Trust hod Cmmissk*
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Trox/er, Commissioner of Agriculture

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomc Report No. FY23-SLO26939
Dale / Larry Davis / Davis Jr. Page 2 of 2
Understanding the Soil Report: explanation of measurements, abbreviations and units
Recommendations
Lime
If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either
ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting.
For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at
time, even if the report recommends more. You can apply the rest in similar increments every six months until the full i
is applied. If MG is recommended and lime is needed, use dolomitric lime.
Fertilizer
Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of
lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies
for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they
are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is
an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear
only on reports for greenhouse soil or problem samples.
Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z
notations appear on the soil report, refer to $Note: Secondary Nuth s and Micronutrients. In general, homeowners do not
need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit
ncagr.gov/agronomi/pubs.htm.
Recommendations for small areas, such as home lawns/gardens, are listed in units of lb/1000 sq ft . If you cannot find
the exact fertilizer grade recommended on the report, visit www.nca4r.gov/agronomi/obpart4.hnd information that
may help you choose a comparable alternate. For more information, read A Homeowners Guide to Fertilizer.
Test Results
Report Abbreviations
Ac
B
BS%
Ca%
CEC
Cu-I
ESP
HM%
K4
K2O
Mg%
MIN
Mn
Mn-All
Mn-AI2
Mn-I
M-0
N
Na
NO3-N
ORG
PH
P4
P2O5
S4
SS-1
WN
The first seven values [soil class, HM%, WN, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI
remaining 16 [P-I, K-1, Ca%, Mg%, Mn-I, Mn-All, Mn-AI2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS-1, NO3-N (not routinel Zn-1
available)] indicate levels of plant nutrients or other fertility measurement. Visit www•ncaar.aov/agronomi/uyrsthtm
exchangeable acidity
boron
% CEC occupied by basic cations
% CEC occupied by calcium
cation exchange capacity
copper index
exchangeable sodium percent
percent humic matter
potassium index
potash
% CEC occupied by magnesium
mineral soil class
manganese
Mn-availability index for crop 1
Mn-availability index for crop 2
manganese index
mineral -organic soil class
nitrogen
sodium
nitrate nitrogen
organic soil class
current soil pH
phosphorus index
phosphate
sulfur index
soluble salt index
weight per volume
zinc availability index
zinc index

Beaufort Courty, NC
w
Z SELECT YOUR SOIL
BoB. Bonneau loamy sand, 0 to 4 percent slopes
SLOPE
(0 Use Representative SlopeTypical of the Soil Map Unit
0 Use Illy Slope: —
REAMS71C ESTIVATEw3
ihEl_D WROGEN NITROGEN P REMOn►A� RS
P, FACTOR RATE MO
CFiQP I) RS;ACRE p-.pVoACRV
lr if
Sep ag-ass 'Hav' 3.9Tors 49 192 45
Barney :',Sr&ny Bushels
els 1.58 94 23
iuestern 4.4Tons 49 210 52
Common Bermudagrass (stay) 3.97ons 49 192 47
Corn (Crain)` 129 0.78 101 57
Bushels
Cara (Silage) OTons 11.8 0 0
vvtSorn S$6 pounds 0.11 75 14
DaE;. Sg-ass j:w,ay) 3.9 Tons 49 192 51
yes-Vje 'Ian' 1.5Tons 49 72 23