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HomeMy WebLinkAboutWQ0002712_2023 Residual Annual Report_20240229 (2)Initial Review Reviewer nathaniel.thorn burg Is this submittal an application? (Excluding additional information.) * Yes No If not an application what is the submittal type?* Annual Report Residual Annual Report Additional Information Other Annual Report Year* 2023 Permit Number (IR) * WQ0002712 Applicant/Permittee City of Lincolnton Email Notifications Does this need review by the hydrogeologist? * Yes No Regional Office Mooresville CO Reviewer Admin Reviewer Wanda Gerald Submittal Form Project Contact Information Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence. Name* Lysa Finnerty Email Address* Ifinnerty@SYNAGRO.com Project Information ......................... Application/Document Type* New (Fee Required) Modification - Major (Fee Required) Renewal with Major Modification (Fee Required) Annual Report Additional Information Other Phone Number* 4105376150 Modification - Minor Renewal GW-59, NDMR, NDMLR, NDAR-1, N DAR-2 Residual Annual Report Change of Ownership We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type:* Wastewater Irrigation High -Rate Infiltration Other Wastewater Reclaimed Water Closed -Loop Recycle Residuals Single -Family Residence Wastewater Other Irrigation Permit Number:* WQ0002712 Has Current Existing permit number Applicant/Permittee Address* 435 Williams Court, Ste 100, Baltimore, MD 21220 Facility Name* City of Lincolnton Class B Residuals Program Please provide comments/notes on your current submittal below. Submission of the 2023 Annual Report for City of Lincolnton, NC At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here. (Application Form, Engineering Plans, Specifications, Calculations, Etc.) Lincolnton NC 2023 Annual Report FINAL.pdf 31.88MB Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger than upload limit. * By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Mail payment to: NCDEQ — Division of Water Resources Attn: Non -Discharge Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Signature Alva �Cit'wt%tt, Submission Date 2/29/2024 435 Williams Court, Suite 100 Baltimore, MD 21220 www.synagro.com FEBRUARY 29, 2024 NCDEQ Division of Water Resources Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: 2023 Annual Report for Permit No. WQ0002712 Dear NCDEQ: SYNAGRO Synagro is submitting an electronic copy of the above referenced report on behalf of the City of Lincolnton, NC. If you have any questions or need additional information, please do not hesitate to contact Richey Haynes at (704) 736-8980 or Alex Fox at (704) 881-3429. Sincerely, Derrick Shivar Environmental Compliance Manager Enclosures cc: Richey Haynes, City of Lincolnton Alex Fox, Synagro YOUR PARTNER FORA CLEANER, GREENERWORLD CITY OF LINCOLNTON, NC RESIDUALS LAND APPLICATION PROGRAM Permit No. WQ0002712 2023 ANNUAL REPORT City of Lincolnton, NC Residuals Land Application Program 2023 Annual Report TABLE OF CONTENTS 1. Certification Form and Annual Operations Summary 2. Annual Residual Sampling Summary Forms and Residuals Analyses 3. Annual Land Application Field Summary Forms 4. TCLP Analysis 5. Pathogen ReductionNector Attraction Reduction 6. Soil pH & Lime Application Records 7. Soil Analyses SECTION 1 ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Perniit #: WQ0002712 County Lincoln Year 2023 Facility Name (as shown on permit) City of Lincolnion WWTP and WTP NPDES No. NC0025496 & 0085588 Land Application Operator Svnaaro Phone# (336) 998-7150 Land application of residuals as allowed by the above permit occurred during the past calendar year? X YES NO. If NO, skip Part A, and Part B and proceed to Part C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A — Residuals Application Summary; Total number of application fields in the permit: 33 Total number of Gelds utilized for land application during the year: 8 Total amount of dry tons applied during the year for all application sites: 222.93 Total number of acres utilized for land application during the year: 197.95 Part B — Annual Compliance Statement: Facility was compliant during calendar year 2023 with all conditions of the land application pennit (including but not limited to items 1-13 below) issued by the Division of Water Quality X YES NO. If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the pennit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3 ) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in I SA NCAC 02T .I 105(a) or the Pollutant Loading Rates in 15A NCAC 02T .l 105(b) (Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All monitoring and reporting requirements in 15A NCAC 02T . I 1 1 I were complied with (applicable to 40 CFR Part 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. I I . Vegetative cover was maintained and proper crop management was perforated on each site receiving residuals, as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C —Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete, am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Ritchie Haynes, City Manager Pennittec Name and Title (type or print) � assay Signature of Preparer* Date (if different from Pennittee) Signature of P rttee Date 004�� 1131 /2024 SignatjeWaKd ArVer Date (if different from ernittee and Preparer) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T .l 102 (26) DENR FORK[ ACF (12/2006) OPERATIONS SUMMARY - LAND APPLICATION - NORTH CAROLINA ALL COUNTIES - ALL SITES PERMIT # WQ0002712 DATE RANGE: 1/1/2023 - 12/31/2023 LINCOLNTON, NC LINCOLNTON, NC WWTP ANAEROB. DIGESTED LIQUID MONTH/YEAR AMOUNT UNIT DRY TONS UNIT DRY METRIC TONS February 2023 279,000.00 G 40.37 D 36.62 April 2023 365,800.00 G 28.37 D 25.73 May 2023 533,200.00 G 41.36 D 37.51 July 2023 235,600.00 G 45.68 D 41.44 October 2023 161,200.00 G 11.49 D 10.43 November 2023 502,200.00 G 35.81 D 32.48 TOTAL LINCOLNTON, NC WATER PLANT LIQUID MONTH/YEAR October 2023 IEel f1I Units Key: D - Dry Tons; G — Gallons; W — Wet Tons; Y — Cubic Yards Report Date: 2/6/2024 10:32:46 PM 2,077,000.00 G 203.09 D 184.20 AMOUNT UNIT DRY TONS UNIT DRY METRIC TONS 173,600.00 G 19.84 D 17.99 173,600.00 G 19.84 D 17.99 SECTION 2 ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: W00002712 Facility Name: LINCOLNTON, NC Residual Source WQ # or NPDES#: NCO025496 WWTP Name: LINCOLNTON WWTP Residual Analysis Data Laboratory: PACE ANALYTICAL; Waypoint Analytical Virginia Inc. Product Type Sample or Composite Date LIQ 01/11/23 LIQ 04/04/23 LIQ 07/05/23 LIQ 09/27/23 Parameter (mglkg dry weight) Ceiling Conc, Limit Percent Solids (%) NA 3.47 1.86 4.65 1.71 Arsenic 75 5 6.8 <8.9 <29.4 Cadmium 85 0.65 <1.1 <2.2 <5.88 Copper 4300 280 320 150 580 Chromium NA 130 160 82 51.6 Lead 840 9.6 14 11 <17.6 Mercury 57 <0.52 <1 <0.42 <10.1 Molybdenum 75 7.7 8.8 <18 <14.7 Nickel 420 15 19 <19 <14.7 Selenium 100 6 <6.9 14 <29.4 Zinc 7500 310 430 160 <73.5 Total Phosphorus NA 47000 34000 15000 1940 TKN NA 71000 140000 81000 27500 Ammonia -Nitrogen NA 28000 42000 22000 <5880 Nitrate and Nitrite NA 241 260 136.8 <294 For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits, "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Preparer' Date •Preparer is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2T.1102(26) DENR FORM RSSF (1212006) Printed: 2/712024 6:22:01 PM For: 2161 01 ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WO permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ Permit Number: Facility Name: Residual Source NPDES # or WQ#: WWTP Name: WQ0002712 LINCOLNTON, NC NC0025496 LINCOLNTON WWTP Residual Analysis Data Laboratory: PACE ANALYTICAL; Waypoint Analytical Virginia Inc. Product Type LIQ LIQ LIQ LIQ Sample or Composite Date 01/11/23 04/04/23 07105/23 09/27/23 Parameters (n icg dry weight) Aluminium 8700 11000 5000 52900 Calcium 11000 14000 6200 <2940 Magnesium 5500 6200 3600 594 i (s.u.) 7.70 7.10 7.00 6.00 Potassium 6500 14000 5300 <588 Sodium 1800 3800 1200 <1470 PAN 22841 40860 22937 <8728 SAR (Ratio) 0.6493 0.9136 0.6442 0.8432 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordiance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Preparer' 'Preparer is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2T.1102(26) -7 Date Printed: 2312024 6:23:02 PM For : 2161 01 DENR FORM RSSF-B (12/2006) 0p 0 PaceAnalyfical Report of Analysis Synagro 12701 Lancaster Hwy Pineville, NC 28134 Attention: Alex Fox Project Name: Lincolnton Lot Number:YA12097 Date Completed:01/30/2023 NIM�� Mr� 01/30/2023 3:07 PM Approved and released by: Project Manager II: Lucas Odom Q PCCRBp�� AAW 'ye I ANSI NdmlAccre00- Board eORft Al A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 7 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Synagro Lot Number: YA12097 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Where sampling is conducted by the client, results relate to the accuracy of the information provided, and as the samples are received. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or discussed below. Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2- dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal Coliform Colilert-18. Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight unless flagged with a "W" qualifier. If you have any questions regarding this report, please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Inorganic Metals Sample -001 has been analyzed using approximately three grams of sample due to the low percent solid level. The LOQs have been adjusted accordingly. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 7 Client:Synagro Laboratory ID:YA12097-001 Description: LINCOLNTON Matrix: Solid Date Sampled:01/11/2023 0900 % Solids: 3.47 01/16/2023 1842 Date Received:01/12/2023 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Solids) SM 2540G 1 01/16/2023 1842 TAD 65010 1 350.1 (Ammonia - N ) 350.1 50 01/25/2023 1241 DMA 65582 1 (Nitrate - N ) 353.2 1 01/26/2023 1133 CMM 66119 1 (Nitrite - N ) 353.2 1 01/26/2023 1133 CMM 66116 1 (Phosphorus) 365.1 50 01/16/2023 1805 DMA 01/16/2023 0859 64846 1 (Soil pH meas) 9045D 1 01/13/2023 1441 BMG2 64417 1 351.4 (TKN) 351.2 5 01/18/2023 1813 DMA 01/17/2023 1258 64991 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 254OG 3.47 % 1 Ammonia - N (gas diffusion) 350.1 28000 1400 750 mg/kg 1 Nitrate - N (soluble) 353.2 230 5.8 0.77 mg/kg 1 Nitrite - N (soluble) 353.2 11 5.8 0.76 mg/kg 1 Phosphorus 7723-14-0 365.1 47000 7200 1400 mg/kg 1 Soil pH measured in water @ 20.5 ° C 9045D 7.7 su 1 TKN 351.2 71000 7200 3600 mg/kg 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 01/14/2023 1409 MRW2 01/14/2023 1025 64810 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 2.2 0.52 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601OD 1 01/18/2023 0018 JMH 01/17/2023 0843 64804 2 3050B 601OD 1 01/19/2023 0113 JMH 01/17/2023 0843 64804 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 8700 190 69 mg/kg 1 Arsenic 7440-38-2 6010D 5.0 J 6.9 2.3 mg/kg 1 Cadmium 7440-43-9 6010D 0.65 J 2.3 0.58 mg/kg 1 Calcium 7440-70-2 6010D 11000 2300 290 mg/kg 1 Chromium 7440-47-3 6010D 130 4.6 1.2 mg/kg 1 Copper 7440-50-8 6010D 280 4.6 2.1 mg/kg 1 Iron 7439-89-6 6010D 12000 46 21 mg/kg 1 Lead 7439-92-1 6010D 9.6 4.6 2.1 mg/kg 1 Magnesium 7439-95-4 6010D 5500 2300 290 mg/kg 1 Manganese 7439-96-5 6010D 200 6.9 2.7 mg/kg 1 Molybdenum 7439-98-7 6010D 7.7 J 19 4.6 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 7 Client:Synagro Laboratory ID:YA12097-001 Description: LINCOLNTON Matrix: Solid Date Sampled:01/11/2023 0900 % Solids: 3.47 01/16/2023 1842 Date Received:01/12/2023 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 01/18/2023 0018 JMH 01/17/2023 0843 64804 2 3050B 6010D 1 01/19/2023 0113 JMH 01/17/2023 0843 64804 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Nickel 7440-02-0 6010D 15 J 19 4.9 mg/kg 2 Potassium 7440-09-7 6010D 6500 2300 290 mg/kg 1 Selenium 7782-49-2 6010D 6.0 J 9.3 3.8 mg/kg 1 Sodium 7440-23-5 6010D 1800 J 2300 290 mg/kg 1 Zinc 7440-66-6 6010D 310 23 5.8 mg/kg 2 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 7 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 7 PACE ANALYTICAL SERVICES. LLC rl t'. ILIV C 1� I v z 1� r I ? rty 0 3 d 0 41 L F FFM- m uT1 L {% S h v m o .. � u a; 4D a v S m ,gam [53 C C � — 4o- SlErAl3uv 4N�. �} Wl i C. duol Ilewns <17 S f 7' w ! ' x al!3atlwu�0 j ta" � 4' I _ c e D A , d EO a� d�ani CL _ uI� o 1 a a EL ~ t E C 8 1 TL yy 6 E a i v' f 3 F`L H H EE s. F � a � c � u dF LLI r� •T G� W v a m yam} � 7 C ~ 3 Iq x +1F e L.I$ o � C CJE 4g m � a a h > > 3 z C C C F = C CK a Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 7 PACE ANALYTICAL SERVICES, LLC III Tilde= EN' f-FRfbi-VVCOL-0286vO2—';arrlples Receipt Checklist [SRC} Effective bate, Ri2pC177 Sample Receipt Checklist (SRC:) licxlt: cv Rf Go l ]ll;llcit d by:+date ts2,ik 1f12?3 Lrlt #: VA I?n4r 1�1CaF1S Ul']'tiCCI�?t: .�% i 3C: ClieAt. �_�'� lc'dE,7C Yes LN., 'so1. wac cwtudy 5C815 present nn t11e Laulcr? Yes I I j No . NA 2.1f cwsto, ;mils %mc resent, were AICY intact Mid Unbro ticn'r I I I ; 5fr;p M: "A � _ Ciilur�jr, Strip 1T]_ N A Test€d liy �� OF1'9keJ temperatuve upmi LcLcipt Derived (CruTmttd) tffapeiatiuc upon rlec6pt oSolid S1ial C yx 7'}i : 22—xo2? i.5 ++1.5 aC NA INN oC NA /NA oC NA INA, aC lwollod: Areailperatnm 131auk❑AZMLSt B-O ties IR Gun M: _ IR -Gan cloacction Factor Mctlwd of cool it- +f Wet k E1 T-cc Yac€€s ix 1� Ier me ZYes ❑Nu ❑NA 3. V4Fere wll conle�_4 rec�ivrd at or below 6,0'C? it na xa P1'D�eCt Mf�lnagcr noticed? PM wL-t5 N otified ll�v: phone J ollaiL faeo-tjj--fac>;. (circle our)_ 3Fe Afu 1,prINA 4- 1s dic connncrcial coilrier°s packing sEp attaellad is t us f717n? ,/ Yes No 5. WC[c proper €1Wocty C�1�c,; (relialr pr .5wL1lr€ceivc€f} followed? Y:s NO 6. wMC 5wilple II]s lit on the Coc aild all sample coutainers? Z Yes No 7, Was collection date &. iim h5t-ei ca thr COS' and all sample cunta hers'? — ,I sr S. Did all coIztabar hbd mfoniiatia.n [iD- date time) age: widi.thc C.QC" Yes 'do,19- ►h'crc testa to Lc pa-fonimd listccl ooa tw COC1 Q[ Yc.';l ❑Nol I1U. Did ali samples Haivr. in Lhc pi -apes oonraitcrs foT cacl, test �ljltyve i.ra good colic wCM +{Ilnbtnfn;x0, lids Gn, em.)'1 11. Was adequate saiilple volwne, availebiv 12, Weie all SWrglfeg rsw-d ed'Whin 46 [be hol[i ig tilde or 48 Ltoin- whxctiever tomes Z 'csl NO 13, WCM;111 s11DjAe5 LOW.-Lillcrs accoEwted_61.7 Nomissinvexce;s) Y �vsj. ❑I 1;Ia ❑d NA 14 - Wets VOA, 9015C and R RK-175 ;siluples E-c of bubl+lj >'�,ca-sire" { "aa Gvtui in dinmelef) in any of tIv. VOA vials? ' '�s NO ? A 13, Were 811 DROhndafs.'zmliietit seta kcs NMil'Cd at a pi I of < 2? 'es v NA 16-'Wciz all C do sainpla, receiv,-A a[ a pI1 > 12 and sul€]de m [cs rived at a PH? 9_> ❑ 'as ❑Yo L7-NA 17. -WIlv,! all awlscable FH�r-;c}�iYi4irlpllcyi l ?S.Ir -3 <1D.53i& ) sanrplestiee of I� r� iesidtud d3orhie? ONO ❑NA U�, Wals tit€ galj a 111i4zf listed cm dic coivaii 1abcP if yes_ iote # Sample > iv%ex-6-atEox ROusl Toe :oiuplettd fo7 my saiulple(s) nLrQ9eclfyprescinredor with tte.ldslmce.} 4Pi i 'IA weltr r€rcivcd incoa,=tly pres€n'cd aad we= a(4wted accQrdingly 51 lmyiple rteiviulg wide i' ' 1nL of circle ow: H2SO4, HNOS- W1..I, waoH t>sira- SR 1y NA 0 rune apreservatirni NA� - Unlut Chao one ppoiervaiiiT is nmderL please Bole in ;Jxe CQilithCrrrz lielaw- NA wrrc Tcceived will] 1XIMlc.S >6 nnn iii dia,netru. Snnlplea(s) t+ %tlr rrcci fed w1b TRC � 0.5 MPjr L. (if 1€19 i5 no) and wee djustpd acfUi'Lbjgly in sample rrceiving with mdiuoi tbiosulti6c A29r03) with thiique ID: NA Cmanxnts: Quill#rax ID! ssafi0 Pace* Analytical Sorvfcas, LLC Page I of 1 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 7 Sodium Absorption Ratio Calculation (SAR) Product Code Product Name 2161-01-LIQ-NC LINCOLNTON, NC WWTP ANAEROB. DIGESTED LIQUID Na mg/I = (Na mg/kg x % Solids) = 100 = (1800 x 3.4700) = 100 = 62.46 Ca mg/I = (Ca mg/kg x % Solids) = 100 = (11000 x 3.4700) = 100 = 381.7 Mg mg/I = (mg mg/kg x % Solids) = 100 = (5500 x 3.4700) = 100 = 190.85 Na meq = Na mg/I = Molec.Wgt.Na = 62.46 = 23 = 2.71565 Ca meq = Ca mg/I = Molec.Wgt.Ca = 381.7 = 20 = 19.085 Mg meq = Mg mg/I = Molec.Wgt.Mg = 190.85 = 12 = 15.9042 Sample Date Report Range Ratio 1 /11 /2023 1 /1 /2023 - 3/31 /2023 0.6493 SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] = 2.71565 = SgrRoot[0.5(19.085+15.9042)] = 0.649266 0p 0 PaceAnalyfical Report of Analysis Synagro 12701 Lancaster Hwy Pineville, NC 28134 Attention: Alex Fox Project Name: Lincolnton Lot Number:YD05127 Date Completed:04/26/2023 Project Manager:Lucas Odom 04/26/2023 4:11 PM Approved and released by: Project Coordinator 1: Jenna S. Holliday Q PCCRBp�� AAW 'ye I ANSI NdmlAccre00- Board eORft Al A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 7 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Synagro Lot Number: YD05127 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Where sampling is conducted by the client, results relate to the accuracy of the information provided, and as the samples are received. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or discussed below. Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2- dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal Coliform Colilert-18. Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight unless flagged with a "W" qualifier. If you have any questions regarding this report, please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Nitrate Analysis The matrix spike/matrix spike duplicate (MS/MSD) for batch 73337 recovered outside of the acceptance limits. The associated laboratory control sample (LCS) passed acceptance criteria. Therefore, the data has been reported. Nitrite Analysis The matrix spike/matrix spike duplicate (MS/MSD) for batch 73569 recovered outside of the acceptance limits. The associated laboratory control sample (LCS) passed acceptance criteria. Therefore, the data has been reported. Metals Analysis Sample YD05127-001 was classified as biosolids therefore in order to ensure proper digestion, the samples were weighed out around 3.00-3.50 grams. The LOQ has been adjusted accordingly. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvww.pacelabs.com Page 2 of 7 Client:Synagro Laboratory ID:YD05127-001 Description: Lincolnton Matrix: Solid Date Sampled: 04/04/2023 1130 % Solids: 1.86 04/10/2023 1756 Date Received:04/05/2023 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Solids) SM 2540G 1 04/10/2023 1756 TAD 72264 1 350.1 (Ammonia - N ) 350.1 25 04/14/2023 1618 CMM 72694 1 (Nitrate - N ) 353.2 1 04/19/2023 1506 CLL2 73337 1 (Nitrite - N ) 353.2 1 04/19/2023 1506 CLL2 73569 1 (Phosphorus) 365.1 25 04/11/2023 1739 DMA 04/07/2023 1132 71968 2 (Soil pH meas) 9045D 1 04/10/2023 1528 BMG2 72224 1 351.4 (TKN) 351.2 5 04/10/2023 1307 BMG2 04/07/2023 1040 71967 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 2540G 1.86 % 1 Ammonia - N (gas diffusion) 350.1 42000 1300 700 mg/kg 1 Nitrate - N (soluble) 353.2 230 S 11 1.4 mg/kg 1 Nitrite - N (soluble) 353.2 30 S 11 1.4 mg/kg 1 Phosphorus 7723-14-0 365.1 34000 6700 1300 mg/kg 1 Soil pH measured in water C) 15.2 ° C 9045D 7.1 su 2 TKN 351.2 140000 13000 6700 mg/kg 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 04/18/2023 1812 KAJ 04/13/2023 1410 72168 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 4.3 1.0 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 04/13/2023 1102 JMH 04/08/2023 1347 71943 2 3050B 6010D 1 04/20/2023 0754 JMH 04/08/2023 1347 71943 3 3050B 6010D 1 04/24/2023 2114 JMH 04/08/2023 1347 71943 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 11000 340 130 mg/kg 1 Arsenic 7440-38-2 6010D 6.8 J 13 4.2 mg/kg 1 Cadmium 7440-43-9 6010D ND 4.2 1.1 mg/kg 1 Calcium 7440-70-2 6010D 14000 4200 530 mg/kg 1 Chromium 7440-47-3 6010D 160 8.5 2.1 mg/kg 1 Copper 7440-50-8 6010D 320 8.5 3.8 mg/kg 1 Iron 7439-89-6 601OD 18000 85 38 mg/kg 3 Lead 7439-92-1 601OD 14 8.5 3.8 mg/kg 1 Magnesium 7439-95-4 601OD 6200 4200 530 mg/kg 2 Manganese 7439-96-5 6010D 510 13 5.0 mg/kg 1 LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range DL - Detection Limit Q - Surrogate failure ND - Not detected at or above the DL N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40% J - Estimated result < LOQ and > DL L - LCS/LCSD failure H - Out of holding time W - Reported on wet weight basis S - MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 7 Client:Synagro Laboratory ID:YD05127-001 Description: Lincolnton Matrix: Solid Date Sampled: 04/04/2023 1130 % Solids: 1.86 04/10/2023 1756 Date Received:04/05/2023 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 04/13/2023 1102 JMH 04/08/2023 1347 71943 2 3050B 6010D 1 04/20/2023 0754 JMH 04/08/2023 1347 71943 3 3050B 6010D 1 04/24/2023 2114 JMH 04/08/2023 1347 71943 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Molybdenum 7439-98-7 Nickel 7440-02-0 Potassium 7440-09-7 Selenium 7782-49-2 Sodium 7440-23-5 Zinc 7440-66-6 601OD 8.8 J 34 8.5 mg/kg 1 601OD 19 J 34 8.9 mg/kg 1 601OD 14000 4200 530 mg/kg 3 601OD ND 17 6.9 mg/kg 1 601OD 3800 J 4200 530 mg/kg 2 601OD 430 42 11 mg/kg 1 LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range DL - Detection Limit Q - Surrogate failure ND - Not detected at or above the DL N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40% J - Estimated result < LOQ and > DL L - LCS/LCSD failure H - Out of holding time W - Reported on wet weight basis S - MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 7 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 7 PACE ANALYTICAL SERVICES, LLC O A I ill a e m �a 0 6- � C 'Lt: - m MEMO. MANr LLI r [} 1. o R rr 7%6 [� � d 0 ;1 z X r LU 7 r. � r� I } ,Lr° f= E M _ ' L cam ii s co 20 .a n o ; C3 ql -173 I V� o m E 14 � z C r 0 G 5 01 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 7 k C I R I { J r Rs C7 � 2S r E � � m J C Z F d Ly ,a & r;FF � u L Y � 8 ti Z a PACE ANALYTICAL SERVICES, LLC PC# Tltla: EtJ'J-FNM--VCOL-02a&v02_SamplasReceipt ChaddistISKI fffcctivc Oats: SJ212022 Sample Receipt Checklist (SRC:} I Client: SYNACYRO C0010 Tlis Card edatc; RJR ,?dd04+3i LOI!-.: 1T}05127 MJF-L reeI'il,r; ,j J�ACe { kal UPS I I PAEx UtlLcr, 'la's +/ NO I . Fes. C[LS Lod y sea Is Vitgellt Du the coalea? ; Yes lWat V ETA 12. If custody scats were piesfal. were i1my iuta.=r and unbrolann? PTT Strip ID: NA_-- Cllurin: Ship IB_ xA Testcd by:*� Ona,iL,;IE taemperatmeUP041recriptr DrAvrd (l:tutetnl) tm p❑ rarc ifouiuetipl 'ya?dij �I��1�€ np FD: nC NA +r NA oC NA + NA nC NA 1?tiA . Tule.lLswd: WIxe wim-a'aA2 51mik. [�APinsr Bo ales 1R Gun ID; � IR Gim CoFrec'i Rwior: o eC Tulet wd of cvolarlt` 71 Wei ice Ell= PAS El Div, kc Moore QYes ❑m Uol IWere all coolem J;eceived al orbelow 5.0°C7 Yf ro. ft3ject CAI linker nCtii;Rr ?' }tiasNo itieclLy pholle.1 ellx,i.li lace -to -face (circle ca,z)_ Ycs 1+Tn , ETA 4_ N the comniereFal c-..lLders r Odr-L xq at,'; ;1 ed to dds form? ,I Ycr, Nn 5_ LTe pmpu- clusio# procL.,,Awm (relulquiqj-ed-rereived) fbllou'ed? - ycs 14) o 6_ Wmc. -mipic "- iiis�ed on the COC caul all snutple conrainis4 Ycs 7. W,-i s collection distr & tra,r Irsrcr on the CDC and all s�iujple cau4jftie[S? YesENo es S. Did all container Ialel --nfo a iou (M, date, mole) Wee ,%idi -1 'OTC'? Y9Weiv tcsu to be perf,aln,ed lisred on the COC? i ©Yes [-]NO 1U_ Did all ,�,Mflples wive in diepmpef coldaium fur MCI] tL` I FI,Ir1',3j ill prid coliMinit (I.ulbrakm lads on, erc,)P ,% 'fifes No 11, -Was 2jiguate saagk volme i dailable Yes Na 12_ -Were all Simi leg reMiv1 d wia uL `2 th-- halchg Euw or 48 hom.jwtucilmr col uu ttrsr? Qy cs ❑ a 13.1T uc: all samples CMII a mere aecotlnted for? -'wo nrissirp`rxc rss) ] s ❑ Tn ❑, , 14.WcleVC} 8015C2uidR K-i75s.-mi;lesfreeofbut�b6&e `},cu rce k'.'"cv61Iwnul 6unctu) iia My r)E& VOA viaLs? 'cs -FT�Tu _J)dNA 1 _ etr all DI{C1'i neEa lSJlll, lrirul sau Jcs rccca €i ar a i}>h1 o� = 2? ='e s �To [NA received At a pH > 9'. Yes F]ldo �V:]NA � �. ��'crcall a�;p ca LeId+�i�1�Vle�xtl[icle cuolf62�.t1(i[M�.3 (�.r,_Sp,�glf.j sair,plcs fic� of [-]Yts © ma F-INA 18- Was 12C qWe auniUer 1isTcd an the contaule label? It'Yes, Qrwtel,y ample)Presrnutlan (i4�a, 1 bccwull�lctedtrx au, satrple;s) inch[iectiyprase edor�vitttihea�s}+ace_) S3LIplt(s) u& wcrr nmivcd ineon-ccily pzcrecnrc;? and Zvcre ac�ustcd accordukp }y irL sau:plr rcccik Pn with nA mL of (Jule unc: H2SO4- HNYO3, MCI. NaOM ,zi ng Sk # KA Time of }uusrrva 1irk,l ' � 1f inoN tlLm me preservative is nted'd, plc-m ll-m in the 0 ,ui' 115 b�loty, Ssullple(s}a were ueeeisrwd 'Nid1 lntb es >6 nun in diameter. saagles;sj MA war; s civcd with TRC > 0.5 wa(L- (( `#19 is 110 aadwcN adjinsTed accordil,gly in sainplc Tcrxi i g,?} ('i1 sc d kim tluoulfia°e (Na25203) with Unique ID: 'a Comrneuis: U-' btlsbu Anslykical Serwirss, LLC Pege 1 of 1 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 7 Sodium Absorption Ratio Calculation (SAR) Product Code Product Name 2161-01-LIQ-NC LINCOLNTON, NC WWTP ANAEROB. DIGESTED LIQUID Na mg/I = (Na mg/kg x % Solids) = 100 = (3800 x 1.8600) = 100 = 70.68 Ca mg/I = (Ca mg/kg x % Solids) = 100 = (14000 x 1.8600) = 100 = 260.4 Mg mg/I = (mg mg/kg x % Solids) = 100 = (6200 x 1.8600) = 100 = 115.32 Na meq = Na mg/I = Molec.Wgt.Na = 70.68 = 23 = 3.07304 Ca meq = Ca mg/I = Molec.Wgt.Ca = 260.4 = 20 = 13.02 Mg meq = Mg mg/I = Molec.Wgt.Mg = 115.32 = 12 = 9.61 Sample Date Report Range Ratio 4/4/2023 4/1 /2023 - 6/30/2023 0.9136 SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] = 3.07304 = SgrRoot[0.5(13.02+9.61)] = 0.913569 0p 0 PaceAnalyfical Report of Analysis Synagro 12701 Lancaster Hwy Pineville, NC 28134 Attention: Alex Fox Project Name: Lincolnton Lot Number:YG07059 Date Completed:07/25/2023 NIM�� Mr� 07/25/2023 7:09 PM Approved and released by: Project Manager II: Lucas Odom Q PCCRBp�� AAW 'ye I ANSI NdmlAccre00- Board eORft Al A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 7 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Synagro Lot Number: YG07059 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Where sampling is conducted by the client, results relate to the accuracy of the information provided, and as the samples are received. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or discussed below. Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2- dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal Coliform Colilert-18, PFAS by Isotope Dilution SOP. Pace is a DoD/DoE and TNI accredited laboratory; however, Pace is not accredited for PFAS Direct Aqueous Injection or Method D8421. Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight unless flagged with a "W" qualifier. If you have any questions regarding this report, please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Inorganic Metals Sample -001 was classified as biosolids therefore in order to ensure proper digestion, the sample was weighed out to between 3.0 - 3.5 grams. The LOQ has been adjusted accordingly. The method blank for analytical batch 80621 contained Copper greater than the acceptance criteria. The associated samples contained detections for this analyte at concentrations greater than 1 OX the value found in the method blank; therefore sample results are not impacted. The data has been reported. Inorganic Non -Metals The method blank for prep batch 79588 contained total phosphate greater than the method acceptance criteria. The associated samples contained detections for this analyte at concentrations greater than 1 OX the value found in the method blank; therefore sample results are not impacted. The data has been reported. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 2 of 7 Client: Synagro Laboratory ID: YG07059-001 Description: Lincolnton Matrix: Solid Date Sampled: 07/05/2023 1030 % Solids: 4.65 07/11/2023 1543 Date Received:07/07/2023 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Solids) SM 2540G 1 07/11/2023 1543 CVR 79671 1 350.1 (Ammonia - N ) 350.1 25 07/10/2023 1213 CMM 79501 2 (Nitrate - N ) 353.2 1 07/22/2023 1356 CLL2 80779 2 (Nitrite - N ) 353.2 1 07/22/2023 1356 CLL2 80778 1 (Phosphorus) 365.1 20 07/14/2023 1531 DMA 07/10/2023 2319 79588 1 (Soil pH meas) 9045D 1 07/11/2023 1302 LMM2 79636 1 351.4 (TKN) 351.2 5 07/10/2023 1454 BMG2 07/09/2023 1855 79567 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 2540G 4.65 % 1 Ammonia - N (gas diffusion) 350.1 22000 540 280 mg/kg 1 Nitrate - N (soluble) 353.2 130 4.3 0.58 mg/kg 2 Nitrite - N (soluble) 353.2 6.8 4.3 0.57 mg/kg 2 Phosphorus 7723-14-0 365.1 15000 2200 430 mg/kg 1 Soil pH measured in water @ 9.7 ° C 9045D 7.0 su 1 TKN 351.2 81000 5400 2700 mg/kg 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 07/14/2023 0311 KJEW 07/13/2023 2210 79760 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 1.8 0.42 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601OD 5 07/19/2023 1815 LAB 07/12/2023 1123 79687 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 601OD 5000 710 270 mg/kg 1 Arsenic 7440-38-2 601OD ND 27 8.9 mg/kg 1 Cadmium 7440-43-9 601OD ND 8.9 2.2 mg/kg 1 Calcium 7440-70-2 601OD 6200 J 8900 1100 mg/kg 1 Chromium 7440-47-3 601OD 82 18 4.4 mg/kg 1 Copper 7440-50-8 601OD 150 18 8.0 mg/kg 1 Iron 7439-89-6 601OD 7600 180 81 mg/kg 1 Lead 7439-92-1 601OD 11 J 18 8.0 mg/kg 1 Magnesium 7439-95-4 601OD 3600 J 8900 1100 mg/kg 1 Manganese 7439-96-5 6010D 280 27 11 mg/kg 1 Molybdenum 7439-98-7 6010D ND 71 18 mg/kg 1 Nickel 7440-02-0 6010D ND 71 19 mg/kg 1 LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range DL - Detection Limit Q - Surrogate failure ND - Not detected at or above the DL N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40% J - Estimated result < LOQ and > DL L - LCS/LCSD failure H - Out of holding time W - Reported on wet weight basis S - MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 7 Client: Synagro Laboratory ID: YG07059-001 Description: Lincolnton Matrix: Solid Date Sampled: 07/05/2023 1030 % Solids: 4.65 07/11/2023 1543 Date Received:07/07/2023 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 5 07/19/2023 1815 LAB 07/12/2023 1123 79687 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Potassium 7440-09-7 Selenium 7782-49-2 Sodium 7440-23-5 Zinc 7440-66-6 601OD 5300 J 8900 1100 mg/kg 1 601OD 14 J 36 14 mg/kg 1 601OD 1200 J 8900 1100 mg/kg 1 601OD 160 89 22 mg/kg 1 LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range DL - Detection Limit Q - Surrogate failure ND - Not detected at or above the DL N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40% J - Estimated result < LOQ and > DL L - LCS/LCSD failure H - Out of holding time W - Reported on wet weight basis S - MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 7 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 7 PACE ANALYTICAL SERVICES, LLC 13o iu E E I. 41) cL - 3 T 113 Z t e dE LJLJ L3 C•& 42 6 PS M 36 O Tu ol Ln aw C.3 G[SAJ E LJV Ld N F E: C7 rL Z A fn 0a dilual. aldilus!3 w 5! C, Z 2 LD P3 -Cf L5 X Z El 8 iD '8 r3 n? -a =1 Z 7 at tn cl� IC E Q3 65 Ic 5 VP 13 4L E P, L L F- =d. =!D 8 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 7 PACE ANALYTICAL SERVICES, LLC RF,# Title' ENV-FRM4VCD.-028i5 vO2-5amp1es ReceipL Cheddist (SRC Gf a iv-2 date; 8/2{2022 Sample Receipt CbecUist (SR ) LjiCIlt= SYNA RO OIcrhswcrci bvld w-- f3R53 J 07+07%- 3 LaL, YGV059 lS offe€ aii�[ Pac;. (Akin 1-P l"�IIa Other; �'�S ,/ N0 1 'SV. is Cll�tacly s,��ls -art o.� .]>te tolola•7 x NQ ,7 1.,,— , -N Z. AA CILSEWI'w �i.11{ -mere 7 esenfi %Ycm dmy intad mid unbrolcrr? H Suip ID: OA ChLofuve Scrip M: xe Tc%trl by: NA Original t.-Irpetl3trlre upon recoij t/ l�CLlVtxl (CU11VU11:) tCLyLrIXULLUDe UP011 IOECipL VaSolid SnapZtl I[}' 3-1315 7 i 1.3 c NA } NA OC NA I NA DC XA 0 L A ipC Method: Zt1c Ipefafurc Bl ik❑A 1115C Bottles IR Chit M $ M Gim Cwectiala Factor:0 UU ik+ictltod Of to0h 11= [7-1 e'er 1Ce I C e Pac1-S © I)ry ice H0L1C oy-e ❑ No 7]NA 3_ "c11v all a001cas accept d M or a Lew 6.U", if no, was Proj(50 M3aaMnotfiied'? PM was Notificd by- ph., or entflll 1 t; Lee-Lo-&te (circle ow). y-es IxlO Y 1*lti 4_ h tllc mninlir6al CAI w!er%jmckiDg sll aleche6 io 41 5 fmn? ,/ Yts MNo 5. Wcl-c pTQper cusLndy JAMCC OM (Lx:liuquishe.(VreuNed) fo[bvcd" Yes NO 6_ %Verse wimple 4�5 j1strd ou l l{ cod' and 81l i]4llac:1:41r11xLI1 rR`� �f c5 NO 7. 'Was collection Mate & ti m listcd ex d1c COU and ;T snrWle containcls? y-es No & Rail cowaipm 1ab0 info.-aw too (W. dKe' Iii=) aacc with 11Lr C'OM AY -Ls; No P. Wert ttsts to Le pfftblwed llstai 413 tke Cou" Yes ❑ Na L0. Did all saunpies arrive in the profiler corttaiarn fur each test : LId'or its Brood cautdiLi❑rl (unbrokii, liras cni, crc.)7 d 'c. Na 11. was (egt1arLe salraple VwLlj L; avalxbls:'? N , 12, W"efe all saulples tweived virthin 1_ the holding oleic or 4& FLoM, wlr;cbever cotrL1-5 =].riff:' I�]Y-cs [:]Na I3. wkre all Sawples Cardaiucrb 7aLv okJoILN1 for^ (No InissfnzfoxCcss) ❑Y'cs ❑ hlo ❑hlr 14. Were VOA. 9015C deal RSK-17a salrgAes fmo of bubble >"PCR-3 ' (W'dr611101 il) ;n aiLy of VOA vials'? IS. Waft all DROhwalsr'iu7n�eut samples received at a pH of-- ?? 'es No , NA _ es N, t/ A 16a_ �� ert all Cy&lLde sks received at .9 pil > 12, and pilfide 4a11 }lass ValdVed at a PI l > 9? ❑{ ❑ll� oA 17. Weiv all applfeable 1+IIIj fI +Uc �alr4c lyilcnCU52 _1�G{18.3 1<'0.5w@@Q same e.s tee o rc.�siLLlal clLl[rril]c"� ❑ c] ©Nnl ❑NA 19. Wns file c uoTc rwabcr G-,trd fsn r11c cot LLaiuc-ir 1xhel? 1f yts, QLwLe r SHr1ll k Prv51e.UVH 1iULL (M UNI bV L:O1r P1r1cx1 flit- airy SaL1giWs) incorrectly pft56rwd of -Ki C; hcadspace.) S31Wle(S) 'N' were rc-ceivcd ioromcctlypnnscivcd wad were ad_[o'ed aceordi15gly in 58Lrlple folei%,jag with NA LILL uftijLLjt; one; MS04, HNO3. HC4 Z+aOI n uJilp, SR H WA Velar of flies :rvalioll NA i�'iLtaTr rkLmL c,rrc I n csq vHiiac ;s IlE#�I�Yl phase Lao L- in the connveem Mow y eecived wiTh tnibbles >6 umn 1R diRmircr_ SaIlLples(s) `� %vefe received with TRC > fl.511i 4, Of TTI9 is no ) atlll kvtk le adi 115; 0d;1ccorC il*y ill -5a€rrplc rud%riag t-vld1 50diwil Lhx+sa1511: (Nans�oj)'Alai TJlkkie ID-1 CaLlhlleaits: Qwltrax 1D. 563[30 pae'a $ .aria iytl cal Services, LLC Rage 1 of 1 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 7 Sodium Absorption Ratio Calculation (SAR) Product Code Product Name 2161-01-LIQ-NC LINCOLNTON, NC WWTP ANAEROB. DIGESTED LIQUID Na mg/I = (Na mg/kg x % Solids) = 100 = (1200 x 4.6500) = 100 = 55.8 Ca mg/I = (Ca mg/kg x % Solids) = 100 = (6200 x 4.6500) = 100 = 288.3 Mg mg/I = (mg mg/kg x % Solids) = 100 = (3600 x 4.6500) = 100 = 167.4 Na meq = Na mg/I = Molec.Wgt.Na = 55.8 = 23 = 2.42609 Ca meq = Ca mg/I = Molec.Wgt.Ca = 288.3 = 20 = 14.415 Mg meq = Mg mg/I = Molec.Wgt.Mg = 167.4 = 12 = 13.95 Sample Date Report Range Ratio 7/5/2023 7/1 /2023 - 9/30/2023 0.6442 SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] = 2.42609 = SgrRoot[0.5(14.415+13.95)] = 0.644214 Waypointo ANALYTICAL 10/9/2023 Synagro Central LLC/ Technical Mary Brewer 284 Boger Road Mocksville, NC, 27028 Ref: Analytical Testing Report Number: 23-271-0007 Project Description: Linconiton 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Dear Mary Brewer: Waypoint Analytical Virginia, Inc. received sample(s) on 9/28/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table if applicable. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information Sincerely, &;'-� ­AldA� Brandi Watson Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 8 • 7621 Whitepine Road, Richmond, VA 23237 Waypoint Main 804-743-9401 0 Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com Sample Summary Table Report Number: 23-271-0007 Client Project Description: Linconiton Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 63545 Linconiton WWTP Solids 09/27/2023 10:00 09/28/2023 63545 Linconiton WWTP Solids 09/27/2023 10:00 09/28/2023 63545 Linconiton WWTP Solids 09/27/2023 10:00 09/28/2023 63545 Linconiton WWTP Solids 09/27/2023 10:00 09/28/2023 63545 Linconiton WWTP Solids 09/27/2023 10:00 09/28/2023 63545 Linconiton WWTP Solids 09/27/2023 10:00 09/28/2023 63545 Linconiton WWTP Solids 09/27/2023 10:00 09/28/2023 63545 Linconiton WWTP Solids 09/27/2023 10:00 09/28/2023 SM-4500-NH3C WP MTN 9045D WP MTN 4500NO3F-2016 WP MTN 6010D WP MTN SW-7471B WP MTN SM-4500-NH3C-TKN WP MTN SM-2540G WP MTN WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN Page 2 of 8 Waypointo ANALYTICAL 46622 Synagro Central LLC/ Technical Project Linconiton Mary Brewer 284 Boger Road Information Mocksville , NC 27028 Report Number : 23-271-0007 REPORT OFA Lab No : 63545 Sample ID : Linconiton WWTP 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Report Date : 10/09/2023 Received : 09/28/2023 Brandi Watson VALYSIS Matrix: Solids Sampled: 9 / 27/ 2023 10:00 Test Results Units MQL DF Date / Time Analyzed By Analytical Method Moisture 98.3 % 0.010 1 10/02/2316:04 CAH SM-2540G Sulfur 1340 mg/Kg - dry 588 1 10/03/23 22:04 BKN 6010D Calcium <2940 mg/Kg - dry 2940 1 10/03/23 22:04 BKN 6010D Aluminum 52900 mg/Kg - dry 294 1 10/03/23 22:04 BKN 6010D Manganese 676 mg/Kg - dry 29.4 1 10/03/23 22:04 BKN 6010D Organic N 27470 mg/Kg - dry 14710 1 10/05/23 07:05 CALCULATION Nickel <14.7 mg/Kg - dry 14.7 1 10/03/23 22:04 BKN 6010D Lead <17.6 mg/Kg - dry 17.6 1 10/03/23 22:04 BKN 6010D Arsenic <29.4 mg/Kg - dry 29.4 1 10/03/23 22:04 BKN 6010D Selenium <29.4 mg/Kg - dry 29.4 1 10/03/23 22:04 BKN 6010D Test Results Units MQL DF Date / Time By Analytical Analyzed Method Total Solids 1.71 % 0.010 1 10/02/23 16:04 CAH SM-2540G Phosphorus 1940 mg/Kg - dry 294 1 10/03/23 22:04 BKN 6010D Copper 580 mg/Kg - dry 29.4 1 10/03/23 22:04 BKN 6010D Total Kjeldahl Nitrogen 27500 mg/Kg - dry 14700 1 10/05/23 07:05 JPJ ;M-4500-NH3C-TKI` Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit Page 3 of 8 Waypointo ANALYTICAL 46622 Synagro Central LLC/ Technical Project Linconiton Mary Brewer 284 Boger Road Information Mocksville , NC 27028 Report Number : 23-271-0007 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com REPORT OFANALYSIS Report Date : 10/09/2023 Received : 09/28/2023 Brandi Watson Lab No : 63545 Sample ID : Linconiton WWTP Matrix: Solids Sampled: 9/27/2023 10:00 Potassium <588 mg/Kg - dry 588 1 10/03/23 22:04 BKN 6010D Magnesium 594 mg/Kg - dry 294 1 10/03/23 22:04 BKN 6010D Sodium <1470 mg/Kg - dry 1470 1 10/03/23 22:04 BKN 6010D Iron 20400 mg/Kg - dry 588 1 10/03/23 22:04 BKN 6010D Zinc <73.5 mg/Kg - dry 73.5 1 10/03/23 22:04 BKN 6010D Ammonia Nitrogen <5880 mg/Kg - dry 5880 1 10/05/23 12:04 JPJ SM-4500-NH3C Nitrate+Nitrite-N <294 mg/Kg - dry 294 1 10/05/23 11:36 CLP 4500NO3F-2016 Cadmium <5.88 mg/Kg - dry 5.88 1 10/03/23 22:04 BKN 6010D Chromium 51.6 mg/Kg - dry 14.7 1 10/03/23 22:04 BKN 6010D Mercury <10.1 mg/Kg - dry 10.1 1 10/03/23 12:05 MRE SW-7471B pH 6.0 S.U. 1 10/02/2316:45 CNB 9045D Molybdenum <14.7 mg/Kg - dry 14.7 1 10/03/23 22:04 BKN 6010D Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit Page 4 of 8 Waypointo ANALYTICAL Client: Synagro Central LLC/ Technical Project: Linconiton Lab Report Number: 23-271-0007 Date: 10/9/2023 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com CASE NARRATIVE Metals Analysis Method 601 OD Sample 84290 Analyte: Aluminum QC Batch No: 1-708719/1-707887 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 84290 Analyte: Arsenic QC Batch No: L708544/L707887 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post digestion spike was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 84290 Analyte: Iron QC Batch No: L708544/L707887 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 84290 Analyte: Potassium QC Batch No: 1-709158/1-707887 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post digestion spike was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 84290 Analyte: Magnesium QC Batch No: L708544/L707887 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 84290 Analyte: Molybdenum QC Batch No: L708544/L707887 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post digestion spike was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 84290 Analyte: Lead QC Batch No: L708544/L707887 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Page 5 of 8 Waypointo ANALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Sample 84290 Analyte: Selenium QC Batch No: 1-708544/1-707887 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post digestion spike was performed and passed quality control acceptance ranges. No matrix interference is suspected. Page 6 of 8 WayPAoInt.. NALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Shipment Receipt Form Customer Number: 46622 Customer Name: Synagro Central LLC/ Technical Report Number: 23-271-0007 Shipping Method 0 Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client 0 Courier 0 Other: Thermometer ID: Shipping container/cooler uncompromised? * Yes 0 No Number of coolers/boxes received Custody seals intact on shipping container/cooler? 0 Yes 0 No Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? # Yes 0 No COC agrees with sample label(s)? # Yes 0 No COC properly completed # Yes 0 No Samples in proper containers? # Yes 0 No Sample containers intact? # Yes 0 No Sufficient sample volume for indicated test(s)? # Yes 0 No All samples received within holding time? # Yes 0 No Cooler temperature in compliance? # Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. # Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No N/A Water - VOA vials free of headspace 0 Yes 0 No N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A F_ High concentration container (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low concentration EnCore samplers (48 hr) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes * No Comments: Signature: IDavid Lennon Date & Time: 09/28/2023 09:58:23 Page 7 of 8 NOTES NZ (nm V) n w c n rr CD z o@ m m 4�00m Cr — ��n�`�� cu a � ' 0ro coC N a C R,7 y 0 CD' u om n p n w 0 .t _ a 0 N ❑- 3 cn La v m n W ❑ 3 w w CON {gyp C =� E z [A l! 0 C C9 y C7 0 O' d 7 Z C A� H A CL -0 w Z y t a 2 7 � � - N L•r v a C m 0 cl) a C c w n�i n i n M a n Cl) z N -Col C �. fD C ~ ❑ W CD D = N t L Z ❑ C CL CD N m Ln ' 6] C c CL o a n e Q Y v m L/ t c 0 ,+ IN to p + m m CD p 0 ca CD N w D7 o rho c k � Q 3 Q C 0. ❑ 6 3 0 � m G? ❑ CD m Q n Page 8 of 8 Sodium Absorption Ratio Calculation (SAR) Product Code Product Name 2161-01-LIQ-NC LINCOLNTON, NC WWTP ANAEROB. DIGESTED LIQUID Na mg/I = (Na mg/kg x % Solids) = 100 = (1470 x 1.7100) = 100 = 25.137 Ca mg/I = (Ca mg/kg x % Solids) = 100 = (2940 x 1.7100) = 100 = 50.274 Mg mg/I = (mg mg/kg x % Solids) = 100 = (594 x 1.7100) = 100 = 10.1574 Na meq = Na mg/I = Molec.Wgt.Na = 25.137 = 23 = 1.09291 Ca meq = Ca mg/I = Molec.Wgt.Ca = 50.274 = 20 = 2.5137 Mg meq = Mg mg/I = Molec.Wgt.Mg = 10.1574 = 12 = 0.84645 Sample Date Report Range Ratio 9/27/2023 10/1 /2023 - 0.8432 12/31 /2023 SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] = 1.09291 = SgrRoot[0.5(2.5137+0.84645)] = 0.843182 ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: W00002712 Laboratory: Facility Name: LINCOLNTON, NC Waypoint Analytical Virginia Inc. Residual Source WQ # or N PDES#: 01-55-010 WWTP Name: LINCOLNTON WTP Residual Analysis Data Product Type Sample or Composite Date WPL 10/03/23 Parameter (m91kg dry weight) Ceiling Conc. Limit Percent Solids {%) NA 2.74 Arsenic 75 <18.5 Cadmium 85 <3.7 Copper 4300 277 Chromium NA 163 Lead 840 11.1 Mercury 57 <6.56 Molybdenum 75 <9.26 Nickel 420 19.9 Selenium 100 <18.5 Zinc 7500 385 Total Phosphorus NA 31100 TKN NA 97000 Ammonia -Nitrogen NA 42600 Nitrate and Nitrite NA <185 For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Preparer* Date 'Preparer is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2T.1102(26) OENR FORM RSSF (1212006) Printed: 112712024 6:03:44 PM For: 2161 02 ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ Permit Number: WQ0002712 Facility Name: LINCOLNTON, NC Residual Source NPDES # or 1NQ#: 01-55-010 WWTP Name: LINCOLNTON WTP Residual Analysis Data Product Type WPi_ Sample or Composite Date 10/03/23 Parameters (mg/kg dry weight) Aluminium 9300 Calcium 12900 Magnesium 5480 PH (s.u.) 7.60 Potassium 9000 Sodium 2110 PAN 43261 SAR (Ratio) 0.6470 Laboratory: Waypoint Analytical Virginia Inc. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordiance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Preparer " "Preparer is defined in 40 CFR Part 503.9(r) and 15 A NCAC 27.1102(26) Date Printed' 112712024 6:05:01 PM For: 2161 02 DENR FORM FZSSF-B (12/2006) Waypointo ANALYTICAL 10/18/2023 Synagro Central LLC/ Technical Mary Brewer 284 Boger Road Mocksville, NC, 27028 Ref: Analytical Testing Report Number: 23-277-0006 Project Description: Linednton 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Dear Mary Brewer: Waypoint Analytical Virginia, Inc. received sample(s) on 10/4/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table if applicable. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information Sincerely, &;'-� ­AldA� Brandi Watson Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 10 • 7621 Whitepine Road, Richmond, VA 23237 Waypoint Main 804-743-9401 0 Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com Sample Summary Table Report Number: 23-277-0006 Client Project Description: Linednton Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 63608 Linednton Solids 10/03/202310:00 10/04/2023 63608 Linednton Solids 10/03/202310:00 10/04/2023 63608 Linednton Solids 10/03/202310:00 10/04/2023 63608 Linednton Solids 10/03/202310:00 10/04/2023 63608 Linednton Solids 10/03/202310:00 10/04/2023 63608 Linednton Solids 10/03/202310:00 10/04/2023 63608 Linednton Solids 10/03/202310:00 10/04/2023 63608 Linednton Solids 10/03/202310:00 10/04/2023 SM-4500-NH3C WP MTN 9045D WP MTN 4500NO3F-2016 WP MTN 6010D WP MTN SW-7471B WP MTN SM-4500-NH3C-TKN WP MTN SM-2540G WP MTN WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN Page 2 of 10 Waypointo ANALYTICAL 46622 Synagro Central LLC/ Technical Project Linednton Mary Brewer 284 Boger Road Information Mocksville , NC 27028 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Report Number : 23-277-0006 REPORT OFANALYSIS Report Date : 10/18/2023 Received : 10/04/2023 Brandi Watson Lab No : 63608 Sample ID : Linednton Matrix: Solids Sampled: 10/3/2023 10:00 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Moisture 97.3 % 0.010 1 10/05/2316:10 CAH SM-2540G Phosphorus 31100 mg/Kg - dry 185 1 10/07/23 02:07 BKN 6010D Sulfur 12100 mg/Kg - dry 370 1 10/07/23 02:07 BKN 6010D Calcium 12900 mg/Kg - dry 1850 1 10/07/23 02:07 BKN 6010D Aluminum 9300 mg/Kg - dry 185 1 10/07/23 02:07 TJS 6010D Manganese 530 mg/Kg - dry 18.5 1 10/07/23 02:07 BKN 6010D Copper 277 mg/Kg - dry 18.5 1 10/07/23 02:07 BKN 6010D Zinc 385 mg/Kg - dry 46.3 1 10/07/23 02:07 BKN 6010D Organic N 54440 mg/Kg - dry 9259 1 10/16/23 14:30 CALCULATION Nickel 19.9 mg/Kg - dry 9.26 1 10/11/23 13:52 6010D Lead 11.1 mg/Kg - dry 11.1 1 10/07/23 02:07 BKN 6010D Arsenic <18.5 mg/Kg - dry 18.5 1 10/07/23 02:07 BKN 6010D Selenium <18.5 mg/Kg - dry 18.5 1 10/07/23 02:07 BKN 6010D Test Results Units MQL DF Date / Time By Analytical Analyzed Method Total Solids 2.74 % 0.010 1 10/05/23 16:10 CAH SM-2540G Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit Page 3 of 10 Waypointo ANALYTICAL 46622 Synagro Central LLC/ Technical Project Linednton Mary Brewer 284 Boger Road Information Mocksville , NC 27028 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Report Number : 23-277-0006 REPORT OFANALYSIS Report Date : 10/18/2023 Received : 10/04/2023 Brandi Watson Lab No : 63608 Sample ID : Linednton Matrix: Solids Sampled: 10/3/2023 10:00 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Total Kjeldahl Nitrogen 97000 mg/Kg - dry 9260 1 10/18/23 10:30 JPJ ;M-4500-NH3C-TKI` Potassium 9000 mg/Kg - dry 370 1 10/07/23 02:07 BKN 6010D Magnesium 5480 mg/Kg - dry 185 1 10/07/23 02:07 BKN 6010D Sodium 2110 mg/Kg - dry 926 1 10/07/23 02:07 BKN 6010D Iron 16900 mg/Kg - dry 370 1 10/07/23 02:07 BKN 6010D Ammonia Nitrogen 42600 mg/Kg - dry 3700 1 10/16/23 14:30 JPJ SM-4500-NH3C Nitrate+Nitrite-N <185 mg/Kg - dry 185 1 10/11/23 15:36 CLP 4500NO3F-2016 Cadmium <3.70 mg/Kg - dry 3.70 1 10/07/23 02:07 BKN 6010D Chromium 163 mg/Kg - dry 9.26 1 10/07/23 02:07 BKN 6010D Mercury <6.56 mg/Kg - dry 6.56 1 10/09/23 11:27 MRE SW-7471B pH 7.6 S.U. 1 10/06/2316:07 CNB 9045D Total Volatile Solids 76.3 % 0.010 1 10/05/23 16:10 CAH SM-2540G Molybdenum <9.26 mg/Kg - dry 9.26 1 10/07/23 02:07 BKN 6010D Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit Page 4 of 10 Waypointo ANALYTICAL Client: Synagro Central LLC/ Technical Project: Linednton Lab Report Number: 23-277-0006 Date: 10/18/2023 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com CASE NARRATIVE Metals Analysis Method 601 OD Sample 63602 (61A-0146-Syncon-Replace Cooling Tower) Analyte: Aluminum QC Batch No: 1-709731/1-709057 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 63602 (61A-0146-Syncon-Replace Cooling Tower) Analyte: Calcium QC Batch No: 1-709473/1-709057 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 63602 (61A-0146-Syncon-Replace Cooling Tower) Analyte: Cadmium QC Batch No: 1-709473/1-709057 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post digestion spike was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 63602 (61A-0146-Syncon-Replace Cooling Tower) Analyte: Copper QC Batch No: 1-709473/1-709057 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 63602 (61A-0146-Syncon-Replace Cooling Tower) Analyte: Iron QC Batch No: 1-709473/1-709057 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 63602 (61A-0146-Syncon-Replace Cooling Tower) Analyte: Potassium QC Batch No: 1-709473/1-709057 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 63602 (61A-0146-Syncon-Replace Cooling Tower) Analyte: Magnesium QC Batch No: 1-709473/1-709057 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 63602 (61A-0146-Syncon-Replace Cooling Tower) Page 5 of 10 Waypointo ANALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Analyte: Manganese QC Batch No: 1-709473/1-709057 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 63602 (61A-0146-Syncon-Replace Cooling Tower) Analyte: Phosphorus QC Batch No: 1-709473/1-709057 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 63602 (61A-0146-Syncon-Replace Cooling Tower) Analyte: Lead QC Batch No: 1-709473/1-709057 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 63602 (61A-0146-Syncon-Replace Cooling Tower) Analyte: Zinc QC Batch No: 1-709473/1-709057 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 81582 (WRC Topsoil (Oct)) Analyte: Arsenic QC Batch No: 1-710201/1-709902 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post digestion spike was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 81582 (WRC Topsoil (Oct)) Analyte: Calcium QC Batch No: 1-710659/1-709902 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 81582 (WRC Topsoil (Oct)) Analyte: Cadmium QC Batch No: 1-710201/1-709902 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post digestion spike was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 81582 (WRC Topsoil (Oct)) Analyte: Iron QC Batch No: 1-710659/1-709902 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 81582 (WRC Topsoil (Oct)) Analyte: Potassium QC Batch No: 1-710659/1-709902 Page 6 of 10 Waypoint".0 - ANALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 81582 (WRC Topsoil (Oct)) Analyte: Magnesium QC Batch No: 1-710201/1-709902 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 81582 (WRC Topsoil (Oct)) Analyte: Manganese QC Batch No: 1-710659/1-709902 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 81582 (WRC Topsoil (Oct)) Analyte: Nickel QC Batch No: 1-710201/1-709902 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 81582 (WRC Topsoil (Oct)) Analyte: Lead QC Batch No: 1-710201/1-709902 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 81582 (WRC Topsoil (Oct)) Analyte: Sulfur QC Batch No: 1-710201/1-709902 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 81582 (WRC Topsoil (Oct)) Analyte: Selenium QC Batch No: 1-710201/1-709902 This analyte was analyzed at a dilution due to IEC interference/matrix interference. Sample 81582 (WRC Topsoil (Oct)) Analyte: Selenium QC Batch No: 1-710659/1-709902 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post digestion spike was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 81582 (WRC Topsoil (Oct)) Analyte: Zinc QC Batch No: 1-710201/1-709902 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Solids Total Mercury Analysis - CVAA Method 7471A Sample 97716 (Annual Sludge) Page 7 of 10 Waypoint".0 ANALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Analyte: Mercury QC Batch No: 1-709569/1-709290 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post digestion spike was performed and passed quality control acceptance ranges. No matrix interference is suspected. Page 8 of 10 WayPAoInt.. NALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Shipment Receipt Form Customer Number: 46622 Customer Name: Synagro Central LLC/ Technical Report Number: 23-277-0006 Shipping Method 0 Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client 0 Courier 0 Other: Thermometer ID: Shipping container/cooler uncompromised? * Yes 0 No Number of coolers/boxes received Custody seals intact on shipping container/cooler? 0 Yes 0 No Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? # Yes 0 No COC agrees with sample label(s)? # Yes 0 No COC properly completed # Yes 0 No Samples in proper containers? # Yes 0 No Sample containers intact? # Yes 0 No Sufficient sample volume for indicated test(s)? # Yes 0 No All samples received within holding time? # Yes 0 No Cooler temperature in compliance? # Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. # Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No N/A Water - VOA vials free of headspace 0 Yes 0 No N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A F_ High concentration container (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low concentration EnCore samplers (48 hr) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes * No Comments: Signature: IDavid Lennon Date & Time: 10/04/2023 10:05:26 Page 9 of 10 I 3 v c 0 CO mm. �. a�� c c 3 3 � o c m d N cr 3_ 64 V n 250 m n N %33 3z We -+ x m❑�N= m f,* m n c m �L7 vc7 m 3 m 3 3 Q a 3 a $ '�" w N N m y m w �. O r LA O �o �❑n�ti 4: CIP mood= � _ 3 � � rt1 n 4 a C a. J � � ti S m n w � � � o m 3 w kA r } 1n c � A n� 'L r � `C 7 0 E. W— Page 10 of 10 Sodium Absorption Ratio Calculation (SAR) Product Code Product Name 2161-02-WPL-NC LINCOLNTON, NC WATER PLANT LIQUID Na mg/I = (Na mg/kg x % Solids) = 100 = (2110 x 2.7400) = 100 = 57.814 Ca mg/I = (Ca mg/kg x % Solids) = 100 = (12900 x 2.7400) = 100 = 353.46 Mg mg/I = (mg mg/kg x % Solids) = 100 = (5480 x 2.7400) = 100 = 150.152 Na meq = Na mg/I = Molec.Wgt.Na = 57.814 = 23 = 2.51365 Ca meq = Ca mg/I = Molec.Wgt.Ca = 353.46 = 20 = 17.673 Mg meq = Mg mg/I = Molec.Wgt.Mg = 150.152 = 12 = 12.5127 Sample Date Report Range Ratio 10/3/2023 1 /1 /2023 - 12/31 /2023 0.6470 SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] = 2.51365 = SgrRoot[0.5(17.673+12.5127)] = 0.647023 SECTION 3 FACILITY NAME: LINCOLNTON, NC LAND OWNER: RANDY LEATHERMAN OPERATOR: RANDY LEATHERMAN CROP 1 NAME: CORN SILAGE (CSI) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: W00002712 FIELD#: NC-CA-00048-0-0010- ANNUAL DRY TONS APPLIED: 23.56 SITE #: NC CA 00048 PREDOMINANT SOIL SERIES: CECIL CROP 1 MAX. PAN: 238 CROP 2 NAME: ACRES UTILIZED: 22.2 ACRES PERMITTED: 22.2 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Page: 1 Gallons (G) Site I _ Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 5/2/2023 86,800.00 (G) 1.860 0.303 LIL DRY 0-<1/2"" SUR 0.5 0.20 140,000.00 42,000.00 260.00 24.782 CSI 5/3/2023 173,600.00 (G) 1.860 0.607 LIL DRY 0-<1/2"" SUR 0.5 0.20 140,000.00 42,000.00 260.00 49.565 CSI 5/4/2023 43,400.00 (G) 1.860 0.152 LIL DRY 0-<1/2"" SUR 0.5 0.20 140,000.00 42,000.00 260.00 12.391 CSI May-23 303,800.00 (G) Total 1.062 Total 86.738 0.000 AS CD CU CR PB HG MO NI SE ZN P Lime Applied Annual Ibs/acre Applied 0.014 0.002 0.679 0.340 0.030 0.002 0.019 0.040 0.015 0.913 72.176 Date Lbs/Ac Cumulative Ibs/acre Applied 0.100 0.017 2.491 0.675 0.108 0.006 0.067 0.112 0.092 2.259 Permit PAN Limit (Ibs/acre) 1st Crop 238 Federal C.P.L.R. (Ibs/acre)**** 36.6 1 34.8 1 1,339.0 267.9 1 15.0 375.0 1 89.0 1 2,500.0 LIL = LINCOLNTON, NC WWTPANAEROB. DIGESTED LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalti f submittin se information, including the possibility of fines and imprisonment for knowing violations." "SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *"" Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 2/7/2024 DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM` Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Total Dry Tons Applied (Annual): Facility Name: LINCOLNTON, NC Permit #: W00002712 Cation Exchange Capacity (non 503 only): 23.56 Operator: RANDY LEATHERMAN RANDY LEATHERMAN Predominant Soil Series! CECIL Owner: Acres Used: 22.20 Acres Permitted: 22.20 Site #: Field #: NC CA 00048 0010 NC CA 00048 Residual Analysis Data (Heavy Metals and Total Phosphorus use mglkg, % Solids use Raw Percent #): Source LIL Sample or Composite Date 1 4/04/23 2 3 4 5 6 7 8 9 10 11 12 Solids 1.86 Arsenic 6.800 Cadmium 1.100 Copper 320 Chromium 160.00 Lead 14.00 Mercury 1.000 Molybdenum 8.80 Nickel 19.00 Selenium 6.90 Zinc 430 Total Phosphorus 34000 Annual Heavy Metal Field Loadings (Calculated In Ibs/acre): Source LIL Total DT/Ac. / App. Event 1 1.06 2 3 4 5 6 7 8 9 10 11 12 Totals Arsenic 0.014 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.014 Cadmium 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Copper 0.679 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.679 Chromium 0.340 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.340 Lead 0.030 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.030 Mercury 0.002 0.000 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molybdenum 0.019 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.019 Nickel 0.040 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.040 Selenium 0.015 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.015 Zinc 0.913 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.913 Total Phosphorus 72.176 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 72.176 "l certify, and r penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are si i t penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". f77m,- 24-.2zl- Signature of Land Applier Date DENR FORM MFLSF (12/2006) FACILITY NAME: LINCOLNTON, NC LANDOWNER: ANGELA LINGERFELT OPERATOR: ANGELA LINGERFELT CROP 1 NAME: SMALL GRAIN (SM) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WO PERMIT #: W00002712 FIELD#: NC-LT-00036-0-0003- ANNUAL DRY TONS APPLIED: 16.15 SITE #: INC LT 00036 PREDOMINANT SOIL SERIES: CECIL CROP 1 MAX. PAN: 116 CROP 2 NAME: ACRES UTILIZED: 8.6 ACRES PERMITTED: 8.6 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Page: 1 Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 2/23/2023 31,000.00 (G) 3.470 0.522 LIL DRY 0-<1/2"" SUR 0.5 0.20 71,000.00 28,000.00 241.00 23.827 SM 2/24/2023 55,800.00 (G) 3.470 0.939 LIL DRY 0-<1/2"" SUR 0.5 0.20 71,000.00 28,000.00 241.00 42.889 SM 2/27/2023 24,800.00 (G) 3.470 0.417 LIL DRY 0-<1/2" SUR 0.5 0.20 71,000.00 28,000.00 241.00 19.062 SM Feb-23 1 111,600.00 (G) Total 1.878 Total 85.778 0.000 AS CD CU CR PB HG MO NI SE ZN P Lime Applied Annual Ibs/acre Applied 0.019 0.002 1.052 0.488 0.036 0.002 0.029 0.056 0.023 1.164 176.506 Date Lbs/Ac Cumulative Ibs/acre Applied 0.219 0.047 9.481 4.197 0.431 0.017 0.309 0.656 0.185 11.301 Permit PAN Limit jibs/acre) 1st Crop 116 P-i-I r` P I R llhe/onrnl**** 4r. r. I '2d R I 1 440 n I 7r.7 0 F n 179 n R0 n 1 Gnn n LIL = LINCOLNTON, INC WWTP ANAEROB. DIGESTED LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant pe 1 s for submi ing false information, including the possibility of fines and imprisonment for knowing violations." -2-0- & SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate *' Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 1/24/2024 DENR FORM FSF (12/2006) Facility Name: Permit #: Operator: Acres Used: 8.60 ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Total Dry Tons Applied (Annual): LINCOLNTON, NC WO0002712 Cation Exchange Capacity (non 503 only): ANGELA LINGERFELT ANGELA LINGERFELT Predominant Soil Series: Owner: Acres Permitted: 8.60 Site #: Field #: NC LT 00036 Rn�i.l��al A..-ie n- 1Hn - -.1. - T-1 .--- */ Cn ;- . n Dom- Dn.-- e\. 16.15 CECIL NC LT 00036 0003 Source LIL Sample or Composite Date 1 1/11123 2 3 4 5 6 7 8 9 10 11 12 Solids 3.47 Arsenic 5.000 Cadmium 0.650 Copper 280 Chromium 130,00 Lead 9.60 Mercury 0,520 Molybdenum 7.70 Nickel 15.00 Selenium 6.00 Zinc 310 Total Phosphorus 47000 Annual Heavv Metal Field Loadimis (Calculated in Ibs/acrel: Source LIL Total DT/Ac. / App.Event 1 1.88 2 3 4 5 6 7 8 9 10 11 12 Totals Arsenic 0.019 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.019 Cadmium 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Copper 1.052 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.052 Chromium 0.488 0.000 0.000 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.488 Lead 0.036 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.036 Mercury 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molybdenum 0.029 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.029 Nickel 0.056 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.056 Selenium 0.023 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0.023 Zinc 1.164 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.164 Total Phosphorus 176.506 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 176.506 " 1 certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are sig I t penalties for submitting false information, including the possibility ones and imprisonment for knowing violations". _r� Z �- Signature of Land Appher Date I DENR FORM MFLSF (12/2006) FACILITY NAME: LINCOLNTON, NC LANDOWNER: ANGELA LEATHERMAN OPERATOR: ANGELA LINGERFELT CROP 1 NAME: SMALL GRAIN ISM) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: W00002712 FIELD#: NC-LT-00036-0-0005- ANNUAL DRY TONS APPLIED: 24.22 SITE #: NC LT 00036 PREDOMINANT SOIL SERIES: CECIL CROP 1 MAX. PAN: 116 CROP 2 NAME: ACRES UTILIZED: 13.5 ACRES PERMITTED: 13.5 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX, PAN: Page: 1 Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- 1 Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 2/23/2023 55,800.00 (G) 3.470 0.598 LIL DRY 0-<1/2"" SUR 0.5 0.20 71,000.00 28,000.00 241.00 27.322 SM 2/24/2023 99,200.00 (G) 3.470 1.063 LIL DRY 0-<1/2"" SUR 0.5 0.20 71,000.00 28,000.00 241.00 48.572 SM 2/27/2023 12,400.00 (G) 3.470 0.133 LIL DRY 0-<1/2" SUR 0.5 0.20 71,000.00 28,000.00 241.00 6.072 SM Feb -23 167,400.00 (G) Total 1.794 Total 81.966 0.000 AS CD CU CR PB HG MO NI SE ZN P Lime Applied Annual Ibs/acre Applied 0.018 0.002 1.005 0.467 0.034 0.002 0.028 0.054 0.022 1.112 168.661 Date Lbs/Ac Cumulative Ibs/acre Applied 0.221 0.047 9.073 3.492 0.418 0.016 0.291 0.583 0.182 11.190 Permit HAN Limit (Ibs/acre) 1st Grop 116 Federal C.P.L.R. (Ibs/acre)**** 36.6 1 34.8 1 1,339.0 267.9 1 15.0 375.0 89.0 2,500.0 LIL = LINCOLNTON, NC WWTP ANAEROB. DIGESTED LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are signi penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 1/24/2024 DENR FORM FSF (12/2006) Facility Name: Permit #: Operator: Acres Used: 13.50 ANNUAL METALS FIELD LOADING SUMMARY FORM' Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Total Dry Tons Applied (Annual): LINCOLNTON, NC W00002712 Cation Exchange Capacity (non 503 only): ANGELA LINGERFELT ANGELA LEATHERMAN Predominant Soil Series: Owner: Acres Permitted: 13.50 Site #: Field #: NC LT 00036 Recidnal Gnalvciw nat. rHeaw Mctalc and Tntal Phncnh- neo mn14n ^/ Cnlide .- P.. P>r.nnf 91- 24.22 CECIL NC LT 00036 0005 Source LIL Sample or Composite Date 1 1/11/23 2 3 4 5 6 7 8 9 10 11 12 Solids 3.47 Arsenic 5.000 Cadmium 0.650 Copper 280 Chromium 130.00 Lead 9.60 Mercury 0.520 Molybdenum 7.70 Nickel 15.00 Selenium 6.00 Zinc 310 Total Phosphorus 47000 Annual Heavv Metal Field Loadinas (Calculated in Ibs/acrel: Source LIL Total DT/Ac. I App. Event 1 1.79 2 3 4 5 6 7 8 9 10 11 12 Totals Arsenic 0.018 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.018 Cadmium 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Copper 1.005 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.005 Chromium 0.467 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.467 Lead 0.034 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.034 Mercury 0.002 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molybdenum 0.028 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.028 Nickel 0.054 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.054 Selenium 0.022 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.022 Zinc 1,112 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.112 Total Phosphorus 168.661 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 168.661 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are signifi t enalties for sub 'ling false information, including the possibility of fines and imprti/s✓�onmen�t for knowing violations". �` [ cam` . Signature of Land Applier Date DENR FORM MFLSF (12/2006) FACILITY NAME: UNCOLNTON, NC LAND OWNER: RANDY LEATHERMAN OPERATOR: RANDY LEATHERMAN CROP 1 NAME: CORN SILAGE (CSI) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: W00002712 FIELD#: NC-LT-00047-0-0002- ANNUAL DRY TONS APPLIED: 56.74 SITE #: NC LT 00047 PREDOMINANT SOIL SERIES: CECIL CROP 1 MAX. PAN: 238 CROP 2 NAME: ACRES UTILIZED: 45.9 ACRES PERMITTED: 45.9 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Page: 1 Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Amount UOM Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Crop 1 Crop 2 Crop 1 Crop 2 5/4/2023 142,600.00 (G) 1.860 0.241 LIL DRY 0-<1/2"" SUR 0.5 0.20 140,000.00 42,000.00 260.00 19.692 CSI May-23 142,600.00 (G) 7/12/2023 204,600.00 (G) 4.650 0.864 LIL DRY 0-<1/2"" SUR 0.5 0.20 81,000.00 22,000.00 136.80 39.650 CSI 7/13/2023 31,000.00 (G) 4.650 0.131 LIL DRY 0-<1/2"" SUR 0.5 0.20 81,000.00 22,000.00 136.80 6.008 CSI Jul-23 235,600.00 (G) Total 1.236 Total 65.350 0.000 AS CD CU CR PB HG MO NI SE ZN P Lime Appl%Lb../.A:c:� Annual Ibs/acre Applied 0.021 0.005 0.453 0.240 0.029 0.001 0.040 0.047 0.031 0.526 46.245 Date Cumulative Ibs/acre Applied 0.077 1 0.012 f 2.649 I 0.758 # 0.121 0.005 I 0.083 I 0.135 I 0.086 1 2.338 1 I Permit PAN Limit (Ibs/acre) 1st Crop. E E 1 1 I I 238 Federal C.P.L.R. (Ibs/acre)**** 36.6 34.8 1,339.0 267.9 15.0 375.0 89.0 2,500.0 LIL = LINCOLNTON, NC WWTP ANAEROB. DIGESTED LIQUID "I certify, under penalty of law, that tPis document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant pen 'e or sub alse information, including the possibility of fines and imprisonment for knowing violations." 2- SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 2/7/2024 DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Total Dry Tons Applied (Annual): Facility Name: LINCOLNTON, NC 56.74 Permit M W00002712 Cation Exchange Capacity (non 503 only): Operator: RANDY LEATHERMAN RANDY LEATHERMAN Predominant Soil Series: CECIL Owner: Acres Used: 45.90 Acres Permitted: 45.90 Site #: Field #: NC LT 00047 0002 NC LT 00047 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Source LIL LIL Sample or Composite Date 1 4/04/23 2 7/05123 3 4 5 6 7 8 9 10 11 12 Solids 1.86 4.65 Arsenic 6.800 8.900 Cadmium 1.100 2.200 Copper 320 150 Chromium 160.00 82.00 Lead 14.00 11.00 Mercury 1.000 0.420 Molybdenum 8.80 18.00 Nickel 19.00 19.00 Selenium 6.90 14.00 Zinc 430 160 Total Phosphorus 34000 15000 Annual Heavy Metal Field Loadings (Calculated in Ibs/acre): Source LIL LIL Total DT/Ac. /APp.Event 1 0.24 2 1.00 3 4 5 6 7 8 9 10 11 12 Totals Arsenic 0.003 0.018 0.000 0.000 0.000 0,000 0.000 0.000 0,000 0.000 0.000 0.000 0.021 Cadmium 0.001 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 Copper 0.154 0.299 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.453 Chromium 0.077 0.163 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.240 Lead 0.007 0.022 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.029 Mercury 0.000 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 Molybdenum 0.004 0.036 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.040 Nickel 0.009 0.038 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.047 Selenium 0.003 0.028 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.031 Zinc 0.207 0.319 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.526 Total Phosphorus 16.386 29.859 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 46.245 1 certify, under enaIty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant n ies for submitti false information, including the possibility of fines and impr'iissoonnment for knowing violations". �s�y Signature o Land pplier Date DENR FORM MFLSF (12/2006) FACILITY NAME: LINCOLNTON, NC LAND OWNER: FLORENCE CRIMAN OPERATOR: RANDY LEATHERMAN CROP 1 NAME: RYE (RY) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WO PERMIT #: W00002712 FIELD#: NC-LT-00047-0-0004- ANNUAL DRY TONS APPLIED: 29.28 SITE #: NC LT 00047 PREDOMINANT SOIL SERIES: CECIL CROP 1 MAX. PAN: 115 CROP 2 NAME: ACRES UTILIZED: 31.2 ACRES PERMITTED: 31.2 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Page: 1 Gallons (G) Site _ Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) [[[ Application Month Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Crop 1 Crop 2 Crop 1 Crop 2 Amount UOM 10/26/2023 161,200.00 (G) 1.710 0.368 LIL DRY 0-<1/2"" SUR 0.5 0.20 27,500.00 5,880.00 294.00 6.425 RY Oct-23 161,200.00 (G) 10/25/2023 43,400.00 (G) 2.740 0.159 LIWPL DRY 0-<1/2"" SUR 0.5 0.40 97,000.00 42,600.00 185.00 13.738 RY Oct-23 43,400.00 (G) 11/28/2023 167,400.00 (G) 1.710 0.382 LIL DRY 0-<1/2"" SUR 0.5 0.20 27,500.00 5,880.00 294.00 6.672 RY 11/29/2023 12,400.00 (G) 1.710 0.028 LIL DRY 0-<1/2"" SUR 0.5 0.20 27,500.00 5,880.00 294.00 0.494 RY Nov-23 179,800.00 (G) Total 0.937 Total 27.329 0.000 AS CD I CU I CR I PB I HG MO NI SE I ZN I P Lime Applied Annual tbs/acre Applied 0.052 0.010 1 0.991 1 0.132 J 0.031 1 0.018 1 0.026 1 0.029 J 0.052 1 0.237 1 12.897 Date Lbs/Ac 1 3.151 Cumulative Ibs/acre Applied 0.140 0.018 1 3.896 1 0.844 1 0.172 1 0.024 1 0.116 1 0.189 1 0.116 Permit PAN Limit (Ibs/acre) 1st Crop 115 Federal C.P.L.R. (Ibs/acre)"" _ 36.6 1 34.8 1 1,339.0 267.9 1 15.0 375.0 1 89.0 2,500.0 LIL = LINCOLNTON, NC WWTP ANAEROB. DIGESTED LIQUID LIWPL = LINCOLNTON, NC WATER PLANT LIQUID "I certify, under penalty of law, tha this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant pe t s for submitti falsc information, including the possibility of fines and imprisonment for knowing violations." SIGNATURE OF LAND APPLIER ' ATE I NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation ***' C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 '**'* See Site pH & Lime Application Records Section of Report Printed: 1/24/2024 DENR FORM FSF (12/2006) Facility Name: Permit #: Operator: Acres Used: 31.23 ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Total Dry Tons Applied (Annual): LINCOLNTON, INC W00002712 Cation Exchange Capacity (non 503 only): RANDY LEATHERMAN FLORENCE CRIMAN Predominant Soil Series: Owner: Acres Permitted: 31.23 Site #: Field #: NC LT 00047 Rnairinal Analv�i� nor* I-- Mnin is - T-. --1- e/ C „ee -, 29.27 CECIL NC LT 00047 0004 Source LIL LIWPL Sample or Composite Date 1 9/27/23 2 10/03/23 3 4 5 6 7 8 9 10 11 12 % Solids 1.71 2.74 Arsenic 29.400 18.500 Cadmium 5.880 3.700 Copper 580 277 Chromium 51.60 163.00 Lead 17.60 11.10 Mercury 10,100 6.560 Molybdenum 14.70 9.26 Nickel 14.70 19.90 Selenium 29.40 18.50 Zinc 74 385 Total Phosphorus 1940 31100 Annual Heavv Metal Field Loadings (Calculated in Ibs/acre): Source LIL LIWPL Total DT/Ac. I App. Event 1 0.78 2 0.16 3 4 5 6 7 8 9 10 11 12 Totals Arsenic 0.046 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.052 Cadmium 0.009 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.010 Copper 0.903 0.088 0.000 0.000 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.991 Chromium 0.080 0.052 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.132 Lead 0.027 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.031 Mercury 0,016 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.018 Molybdenum 0.023 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.026 Nickel 0.023 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.029 Selenium 0.046 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.052 Zinc 0.114 0.122 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.237 Total Phosphorus 3.021 9.876 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 12.897 1 certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. 1 am aware that there are significant pKx- for submitting alse information, including the possibility offines and imprisonment for knowing violations". v -z- q--2 r Signature of Land Applier Date DENR FORM MFLSF (12/2006) FACILITY NAME: LINCOLNTON, NC LANDOWNER: SUE GILBERT OPERATOR: RANDY LEATHERMAN CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: W00002712 FIELD#: NC-LT-00047-0-0005- ANNUAL DRY TONS APPLIED: 22.99 SITE #: NC LT 00047 PREDOMINANT SOIL SERIES: CECIL CROP 1 MAX. PAN: 209 CROP 2 NAME: ACRES UTILIZED: 27.6 ACRES PERMITTED: 27.6 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Page: 1 Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Amount UOM Crop 1 1 Crop 2 Crop 1 Crop 2 11/29/2023 136,400.00 (G) 1.710 0.353 LIL DRY 0-<1/2"" SUR 0.5 0.20 27,500.00 5,880.00 294.00 6.154 FSH 11/30/2023 186,000.00 (G) 1.710 0.481 LIL DRY 0-<1/2"" SUR 0.5 0.20 27,500.00 5,880.00 294.00 8.391 FSH Nov-23 322,400.00 (G) I Total 0.834 Total 14.545 0.000 AS CD CU CR PB HG MO NI SE ZN P Lime Applied Annual Ibs/acre Applied 0.049 0.010 0.967 0.086 0.029 0.017 0.024 0.024 0.049 0.122 3.233 Date Lbs/Ac Cumulative Ibs/acre Applied 0.101 0.016 3.720 0.867 0.163 0.021 0.078 0.147 0.107 2.684 Permit PAN Limit (Ibs/acre) 1st Crop 209 Federal C.P.L.R. (Ibs/acre)**** — 36.6 34.8 T1,339.0 267.9 1 15.0 375.0 89.0 1 2,500.0 LIL = LINCOLNTON, NC WWTP ANAEROB. DIGESTED LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant pensubmittin false information, including the possibility of fines and imprisonment for knowing violations." a a for SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 **** See Site pH & Lime Application Records Section of Report Printed: 1/24/2024 DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Total Dry Tons Applied (Annual): Facility Name: LINCOLNTON, NC Permit #: WQ0002712 Cation Exchange Capacity (non 503 only): 22.99 Operator: RANDY LEATHERMAN SUE GILBERT Predominant Soil Series: CECIL Owner: Acres Used: 27.59 Acres Permitted: 27.59 Site #: Field #: NC LT 00047 0005 NC LT 00047 Residual Analysis Data (Heavy Metals and Total Phosphorus use mglkq. % Solids use Raw Percent #1: Source LIL Sample or Composite Date 1 9/27/23 2 3 4 5 6 7 8 9 10 11 12 Solids 1.71 Arsenic 29.400 Cadmium 5.880 Copper 580 Chromium 51.60 Lead 17.60 Mercury 10.100 Molybdenum 14.70 Nickel 14.70 Selenium 29.40 Zinc 74 Total Phosphorus 1940 Annual Heavy Metal Field Loadings (Calculated in Ibs/acre): Source LIL Total DT/Ac. / App. Event 1 0.83 2 3 4 5 6 7 8 9 10 11 12 Totals Arsenic 0.049 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.049 Cadmium 0.010 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.010 Copper 0.967 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.967 Chromium 0.086 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.086 Lead 0.029 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.029 Mercury 0.017 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.017 Molybdenum 0.024 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,024 Nickel 0.024 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.024 Selenium 0.049 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0.000 0.049 Zinc 0.122 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.122 Total Phosphorus 3.233 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 3.233 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are sight n penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of L nd Applier Date DENR FORM MFLSF (12/2006) FACILITY NAME: LINCOLNTON, NC LAND OWNER: MICHAEL N TERESA WESSON OPERATOR: MICHAEL N TERESA WESSON CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: W00002712 FIELD#: NC-LT-00049-0-0001- ANNUAL DRY TONS APPLIED: 35.07 SITE #: INC LT 00049 PREDOMINANT SOIL SERIES: CECIL CROP 1 MAX. PAN: 209 CROP 2 NAME: ACRES UTILIZED: 14.7 ACRES PERMITTED: 14.7 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Page: 1 Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Amount i UOM Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Crop 17 Crop 2 Crop 1 Crop 2 4/25/2023 179,800.00 (G) 1.860 0.947 LIL DRY 0-<1/2"" SUR 0.5 0.20 140,000.00 42,000.00 260.00 77.368 FSH 4/26/2023 80,600.00 (G) 1.860 0.424 LIL DRY 0-<1/2"" SUR 0.5 0.20 140,000.00 42,000.00 260.00 34.682 FSH Apr-23 260,400.00 (G) 10/25/2023 130,200.00 (G) 2.740 1.010 LIWPL DRY]0-<1/2"" SUR 0.5 0.40 97,000.00 42,600.00 185.06 87.382 FSH Oct-23 130,200.00 (G) I 1 1 1 Total 2.381 Total 199.432 0.000 AS CD CU CR PB J HG MO NI SE ZN P Lime Applied Annual Ibs/acre Applied 0.056 0.010 1.437 0.768 0.061 0.016 0.043 0.092 0.056 1.957 156.057 Date Lbs/Ac Cumulative Ibs/acre ADDlied 0.166 0.020 6.055 1.948 0.254 0.024 0.142 0.294 0.140 5.937 Permit PAN Limit (Ibs/acre) 1st Crop 209 Federal C.P.L.R. (Ibs/acre)**** 36.6 1 34.8 1 1,339.0 267.9 1 15.0 375.0 1 89.0 1 2,500.0 LIL = LINCOLNTON, NC WWTP ANAEROB. DIGESTED LIQUID LIWPL = LINCOLNTON, NC WATER PLANT LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are signifi enalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 77 - SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 2/7/2024 DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM" Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Total Dry Tons Applied (Annual): Facility Name: LINCOLNTON, NC Permit #: W00002712 Cation Exchange Capacity (non 503 only): Operator: MICHAEL N TERESA W ESSON MICHAEL N TERESA W ESSON Predominant Soil Series: Owner: Acres Used: 14.73 Acres Permitted: 14.73 Site #: Field #: NC LT 00049 no��d�i e��i..��� n�•� rues.,., nne•��� �..w ,•..•�i or...�..r.....�. ,.. � �e �.., e.,-e.. 35.07 CECIL NC LT 00049 0001 Source LIL LIWPL Sample or Composite Date 1 4104/23 2 10/03/23 3 4 5 6 7 8 9 10 11 12 Solids 1.86 2.74 Arsenic 6.800 18.500 Cadmium 1.100 3.700 Copper 320 277 Chromium 160.00 163.00 Lead 14.00 11.10 Mercury 1.000 6.560 Molybdenum 8.80 9.26 Nickel 19.00 19.90 Selenium 6.90 18.50 Zinc 430 385 Total Phosphorus 34000 31100 Annual Heavv Metal Field Loadinas (Calculated in Ibs/acrel: Source LIL LIWPL Total DT/Ac. / App.Event 1 1.37 2 1.01 3 4 5 6 7 8 9 10 11 12 Totals Arsenic 0.019 0.037 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.056 Cadmium 0.003 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.010 Copper 0.878 0.560 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.437 Chromium 0.439 0.329 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.768 Lead 0.038 0.022 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.061 Mercury 0.003 0.013 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.016 Molybdenum 0.024 0.019 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.043 Nickel 0.052 0.040 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.092 Selenium 0.019 0.037 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.056 Zinc 1.179 0.778 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.957 Total Phosphorus 93.239 62.818 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 156.057 " I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significa t p naI ies for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier Date DENR FORM MFLSF (12/2006) FACILITY NAME: LINCOLNTON, NC LAND OWNER: MICHAEL N TERESA WESSON OPERATOR: MICHAEL N TERESA WESSON CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WO PERMIT #: WQ0002712 FIELD#: NC-LT-00049-0-0002- ANNUAL DRY TONS APPLIED: 14.91 SITE #: NC LT 00049 PREDOMINANT SOIL SERIES: CECIL CROP 1 MAX. PAN: 209 CROP 2 NAME: ACRES UTILIZED: 34.2 ACRES PERMITTED: 34.2 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Page: 1 Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Solids Dry Tons/Ac Source Moist Inches Method' Rate** Rate*** mg/kg mg/kg mg/kg Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 4/26/2023 105,400.00 (G) 1.860 0.239 LIL DRY 0-<1/2"" SUR 0.5 0.20 140,000.00 42,000.00 260.00 19.534 FSH Al 105,400.00 (G) 5/2/2023 86,800.00 (G) 1.860 0.197 LIL DRY 0-<1/2"" SUR 0.5 0.20 140,000.00 42,000.00 260.00 16.087 FSH May-23 86,800.00 (G) 1 Total 0.436 Total 35.621 0.000 AS CD CL CR PB HG MO NI SE ZN P Lime Applied Annual Ibs/acre Applied 0.006 1 <0.001 0279 1 0.139 0.012 <0.001 0.008 0.017 0.006 0.375 29.640 Date Lbs/Ac Cumulative Ibs/acre Applied 0.045 F 0.005 2.030 1 0.532 0.080 0.004 0.040 0.088 0.034 1.640 Permit PAN Limit (Ibs/acre) 1st Crop 209 Federal C.P.L.R. (lbs/acre)**" 36.6 34.8 1 1,339.0 267.9 1 15.0 375.0 1 89.0 1 2,500.0 LIL = LINCOLNTON, NC WWTP ANAEROB. DIGESTED LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penal r submitting false information, including the possibility of fines and imprisonment for knowing violations." �2A �� — � 4-1 I SI NATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH R Lime Application Records Section of Report Printed: 2/7/2024 DENR FORM FSF (12/2006) Facility Name: Permit #: Operator: Acres Used: ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Total Dry Tons Applied (Annual): LINCOLNTON, NC WQ0002712 Cation Exchange Capacity (non 503 only): MICHAEL N TERESA WESSON MICHAEL N TERESA WESSON Predominant Soil Series: Owner: 34.20 Acres Permitted: 34.20 Site #: Field #: NC LT 00049 Rneirli�al Analveie nafa /Huaw Mnfal� anA Tnfal Pl.n�nr.nn�� r� mn/Ln a/_ Cnlirle �� n Raw Dnrrnr.f a\• 14.91 CECIL NC LT 00049 0002 Source LIL Sample or Composite Dale 1 4/04/23 2 3 4 5 6 7 8 9 10 11 12 %Solids 1.86 Arsenic 6.800 Cadmium 1.100 Copper 320 Chromium 160.00 Lead 14.00 Mercury 1.000 Molybdenum 8.80 Nickel 19.00 Selenium 6.90 Zinc 430 Total Phosphorus 34000 Annual Heavv Metal Field Loadings (Calculated in Ibs/acre): Source LIL Total DT/Ac. I App. Event 1 0.44 2 3 4 5 6 7 8 9 10 11 12 Totals Arsenic 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.006 Cadmium 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 Copper 0.279 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.279 Chromium 0.139 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.139 Lead 0.012 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0.012 Mercury 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,001 Molybdenum 0.008 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.008 Nickel 0.017 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.017 Selenium 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0.006 Zinc 0.375 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.375 Total Phosphorus 29.640 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 29.640 "7 certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are signifies e Ides for subm tti false information, including the possibility of fines and impriisjsoynmenntt for knowing violations". Signature of Land Applier Date DENR FORM MFLSF (12/2006) SECTION 4 SUMM111 ENVIRONMENTAL TECHN❑LOMZ3. INC Arraly0ca1 Laboralorfas January 24, 2023 Alex Fox Synagro 284 Boger Rd. Mocksville, NC 27028 TEL: FAX: RE: Lincolnton Dear Alex Fox: Summit Environmental Technologies, Inc. 3310 Win St. Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com Order No.: 23010835 Summit Environmental Technologies, Inc. received 1 sample(s) on 1/13/2023 for the analyses presented in the following report. There were no problems with the analytical events associated with this report unless noted in the Case Narrative. Quality control data is within laboratory defined or method specified acceptance limits except where noted. If you have any questions regarding these tests results, please feel free to call the laboratory. Sincerely, Jennifer Woolf Project Manager 3310 Win St. Cuyahoga Falls, Ohio 44223 Arkansas 88-0735, California 2943, Colorado, Connecticut PH-0108, Florida NELAC E87688, Idaho OH00923, Illinois 200061, Indiana C-OH-13, ISO/IEC 17025:2017 119125 L22-544, Kansas E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Maryland 339, Michigan 9988, Minnesota 1780279, Nevada 011009232020-1, New Hampshire 2996, New Jersey OH006, New York 11777, North Carolina 39705 and 631, North Dakota R-201, Ohio DW, Ohio VAP CL0052, Oklahoma 2019-155, Oregon OH2O0001, Pennsylvania 68-01335, Rhode Island LA000317, South Carolina 92016001, Texas T104704466-19-16, Utah 011009232020-12, Virginia VELAP 10381, West Virginia 9957C Page 1 of 39 MM' Y Summit Environmental Technologies, Inc. Case Narrative SU3310 Win St. ENVIRONMENTAL TEC„HQLOG4r;S,INC. Cuyahoga Falls, Ohio44223 wo#: 23010835 Arralyi9cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com Date: 1/24/2023 CLIENT: Synagro Project: Lincolnton WorkOrder Narrative: 23010835: This report in its entirety consists of the following documents: Cover Letter, Case Narrative, Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody, Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit Environmental Technologies, Inc., Work Order Number assigned to this report. Summit Environmental Technologies, Inc., holds the accreditations/certifications listed at the bottom of the cover letter that may or may not pertain to this report. Please refer to the "Accreditation Program Analytes Report" for accredited analytes list. The information contained in this analytical report is the sole property of Summit Environmental Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results contained in this report are only representative of the samples received. Conditions can vary at different times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible for use or interpretation of the data included herein. All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as "dry weight" using the "-dry" designation on the reporting units. This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any comments or problems with the analytical events associated with this report are noted below. Analytical Sequence Sample Notes: 23010835-OOIA TCLP-VOC-MSTR 8260D: CCV ane LCS-R156775 exhibited high recoveries for Vinyl chloride, Carbon tetrachloride, and Trichloroethene. Sample is ND for these analytes. Possible low bias for 1, 1 -Dichloroethene due to low recovery in CCV. Compound demostrates adequate instrument sensitivity in RLC. Sample is ND for I, I -Dichloroethene. Analytical Sequence QC Notes: MBLK VOC-MSTR_NPW(8260): Possible low bias for 1,1-Dichloroethene due to low recovery in CCV. Compound demostrates adequate instrument sensitivity in RLC. LCS VOC-MSTR_NPW(8260): LCS-R156775 exhibited high recoveries for for Vinyl chloride, Carbon tetrachloride, and Trichloroethene. Associated samples are ND for these analytes. Possible high bias Original Page 2 of 39 SUMMIY Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TEC„HQLOG4r;S,INC. Cuyahoga Falls, Ohio44223 Arralyi9cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com CLIENT: Synagro Project: Lincolnton Case Narrative wo#: 23010835 Date: 1/24/2023 for Vinyl chloride due to high recovery in CCV. Possible low bias for 1, 1 -Dichloroethene due to low recovery in CCV. Compound demostrates adequate instrument sensitivity in RLC. Original Page 3 of 39 MM' Summit Environmental Technologies, In Qualifiers and Acronyms SU3310 Win S EkiwllOMM@NTALTECHN❑LOG{r,23.INC Cuyahoga Falls, Ohio442� WO#: 23010835 Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-44E Wehsite: httn:11www.settek.co Date: 1/24/2023 These commonly used Qualifiers and Acronyms may or may not be present in this report. Qualifiers U The compound was analyzed for but was not detected. J The reported value is greater than the Method Detection Limit but less than the Reporting Limit. H The hold time for sample preparation and/or analysis was exceeded. D The result is reported from a dilution. E The result exceeded the linear range of the calibration or is estimated due to interference. MC The result is below the Minimum Compound Limit. The result exceeds the Regulatory Limit or Maximum Contamination Limit. in Manual integration was used to determine the area response. d Manual integration in which peak was deleted N The result is presumptive based on a Mass Spectral library search assuming a 1:1 response. P The second column confirmation exceeded 25% difference. C The result has been confirmed by GC/MS. X The result was not confirmed when GUMS Analysis was performed. B/MB+ The analyte was detected in the associated blank. G The ICB or CCB contained reportable amounts of analyte. QC-/+ The CCV recovery failed low (-) or high (+). R/QDR The RPD was outside of accepted recovery limits. QL-/+ The LCS or LCSD recovery failed low (-) or high (+). QLR The LCS/LCSD RPD was outside of accepted recovery limits. QM-/+ The MS or MSD recovery failed low (-) or high (+). QMR The MS/MSD RPD was outside of accepted recovery limits. QV-/+ The ICV recovery failed low (-) or high (+). S The spike result was outside of accepted recovery limits. Z Deviation; A deviation from the method was performed; Please refer to the Case Narrative for additional information Acronyms ND Not Detected RL Reporting Limit QC Quality Control MDL Method Detection Limit MB Method Blank LOD Level of Detection LCS Laboratory Control Sample LOQ Level of Quantitation LCSD Laboratory Control Sample Duplicate PQL Practical Quantitation Limit QCS Quality Control Sample CRQL Contract Required Quantitation Limit DUP Duplicate PL Permit Limit MS Matrix Spike RegLvl Regulatory Limit MSD Matrix Spike Duplicate MCL Maximum Contamination Limit RPD Relative Percent Different MinCL Minimum Compound Limit ICV Initial Calibration Verification RA Reanalysis ICB Initial Calibration Blank RE Reextraction CCV Continuing Calibration Verification TIC Tentatively Identified Compound CCB Continuing Calibration Blank RT Retention Time PLC Reporting Limit Check CF Calibration Factor DF Dilution Factor RF Response Factor This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting. Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this list or for additional information regarding the use of these Qualifiers on reported data. Original Page 4 of 39 �� 1 � Summit Environmental Technologies, Inc. SU3310 Win St. ENVIROMMEWAL YECHNO ijULES. JNG, Cuyahoga Falls, Ohio 44223 Analytical Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com CLIENT: Synagro Project: Lincolnton Lab SamplelD Client Sample ID 23010835-001 Lincolnton Tag No Date Collected 1/11/2023 10:00:00 AM Workorder Sample Summary WO#: 23010835 24 Jan-23 Date Received Matrix 1/13/2023 10:20:00 AM Solid Page 5 of 39 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. DATES "PORT ENVIRONMENTALTECHN❑L0G1ES,11+1C Cuyahoga Falls, Ohio44223 WO#: 23010835 ArWyft cal Laboraloriag TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com 24-Jan-23 Client: Synagro Project: Lincolnton Sample ID Client Sample ID Collection Date Matrix Test Name Leachate Date Prep Date Analysis Date 23010835-OOIA Lincolnton 1/11/2023 10:00:00 AM Solid Ignitability of Solids (SW-846: 1030) 1/18/2023 7:17:11 PM pH (SW9045D) 1/20/2023 4:11:32 PM Reactive Cyanide (9014/7.3.3.2)-Solid 1/23/2023 1:45:00 PM Reactive Sulfide (9034)/7.3.4.2 1/23/2023 1:45:00 PM TCLP Herbicides by EPA 8321B 1/17/2023 4:35:00 PM TCLP Mercury Analysis (SW1311/7471/16/2023 2:00:00 PM 1/17/2023 1:30:00 PM 1/18/2023 1:06:00 PM TCLP Metals Analysis (SW1311/6010:1/16/2023 2:00:00 PM 1/17/2023 1:00:00 PM 1/18/2023 1:22:00 PM TCLP Pesticides Analysis (SW1311/8(1/16/2023 2:00:00 PM 1/18/2023 10:31:44 AM 1/19/2023 12:46:00 AM TCLP Pesticides Analysis (SW1311/8(1/16/2023 2:00:00 PM 1/18/2023 10:31:44 AM 1/19/2023 12:46:00 AM TCLP Semi-Volatiles Analysis 1/16/2023 2:00:00 PM 1/17/2023 11:20:00 AM 1/18/2023 3:48:00 AM (SW1311/8270) TCLP Volatiles Analysis 1/19/2023 4:50:00 PM Original Page 6 of 39 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNQLOGIE$,IRC Cuyahoga Falls, Ohio44223 Arralyt9cal Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://�i,-"-m,.settek.coin Analytical Report (base report) WO#: 23010835 Date Reported: 1/24/2023 CLIENT: Synagro Tag Number: Matrix: SOLID Collection Date: 1/11/2023 10:00:00 AM Lab ID: 23010835-OOIA Project: Lincolnton Client Sample ID Lincolnton Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP MERCURY ANALYSIS (SW1311/7470) TCLP Mercury ND 0.00200 mg/L SW7470A SW7470A Analyst: JJF 1 1/18/2023 1:06:00 PM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW6010 SW301OA Analyst: RJE TCLP METALS ANALYSIS (SW1311/6010) TCLP Arsenic(As) ND 0.500 mg/L 1 1/18/2023 1:22:00 PM TCLP Barium(Ba) ND 5.00 mg/L 1 1/18/2023 1:22:00 PM TCLP Cadmium(Cd) ND 0.100 mg/L 1 1/18/2023 1:22:00 PM TCLP Chromium(Cr) ND 0.200 mg/L 1 1/18/2023 1:22:00 PM TCLP Lead(Pb) ND 0.500 mg/L 1 1/18/2023 1:22:00 PM TCLP Selenium(Se) ND 0.0500 mg/L 1 1/18/2023 1:22:00 PM TCLP Silver(Ag) ND 0.500 mg/L 1 1/18/2023 1:22:00 PM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8270 SW351OC Analyst: JAP TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270) 1,4-Dichlorobenzene ND 0.100 mg/L 1 1/18/2023 3:48:00 AM 2,4,5-Trichlorophenol ND 0.250 mg/L 1 1/18/2023 3:48:00 AM 2,4,6-Trichlorophenol ND 0.250 mg/L 1 1/18/2023 3:48:00 AM 2,4-Dinitrotoluene ND 0.0500 mg/L 1 1/18/2023 3:48:00 AM Cresols, Total ND 5.00 mg/L 1 1/18/2023 3:48:00 AM Hexachloro-1,3-butadiene ND 0.0200 mg/L 1 1/18/2023 3:48:00 AM Hexachlorobenzene ND 0.0500 mg/L 1 1/18/2023 3:48:00 AM Hexachloroethane ND 0.100 mg/L 1 1/18/2023 3:48:00 AM Nitrobenzene ND 0.100 mg/L 1 1/18/2023 3:48:00 AM Pentachlorophenol ND 0.250 mg/L 1 1/18/2023 3:48:00 AM Pyridine ND 0.250 mg/L 1 1/18/2023 3:48:00 AM Surr: 2-Fluorophenol 52.4 10 - 157 %Rec 1 1/18/2023 3:48:00 AM Surr: Phenol-d6 54.1 10 - 169 %Rec 1 1/18/2023 3:48:00 AM Surr: Nitrobenzene-d5 51.8 32.1 - 130 %Rec 1 1/18/2023 3:48:00 AM Surr: 2,4,6-Tribromophenol 64.7 45.4 - 166 %Rec 1 1/18/2023 3:48:00 AM Surr: 2-Fluorobiphenyl 56.2 35.7 - 130 %Rec 1 1/18/2023 3:48:00 AM Surr: p-Terphenyl-d14 77.7 70 - 145 %Rec 1 1/18/2023 3:48:00 AM Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response MC Value is below Minimum Compound Limit. N Tentatively identified compounds ND Not Detected OG1 P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit Page 7 of 39 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNQLOGIE$,IRC Cuyahoga Falls, Ohio44223 Arrafyt9caf Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://�i,-"-m,.settek.coin Analytical Report (base report) WO#: 23010835 Date Reported: 1/24/2023 CLIENT: Synagro Tag Number: Matrix: SOLID Collection Date: 1/11/2023 10:00:00 AM Lab ID: 23010835-OOIA Project: Lincolnton Client Sample ID Lincolnton Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8081 SW351OC Analyst: PGP TCLP PESTICIDES ANALYSIS (SW1311/8081) Chlordane, total ND 0.00250 mg/L 1 1/19/2023 12:46:00 AM Toxaphene ND 0.00500 mg/L 1 1/19/2023 12:46:00 AM Endrin ND 0.000500 mg/L 1 1/19/2023 12:46:00 AM gamma-BHC ND 0.000500 mg/L 1 1/19/2023 12:46:00 AM Heptachlor ND 0.000500 mg/L 1 1/19/2023 12:46:00 AM Heptachlor epoxide ND 0.000500 mg/L 1 1/19/2023 12:46:00 AM Methoxychlor ND 0.000500 mg/L 1 1/19/2023 12:46:00 AM Surr: TCMX 55.6 10 - 119 %Rec 1 1/19/2023 12:46:00 AM Surr: DCB 52.7 10 - 119 %Rec 1 1/19/2023 12:46:00 AM TCLP HERBICIDES BY EPA 8321B SW8321 Analyst: SRA 2,4-D ND 0.500 mg/L 50 1/17/20234:35:00 PM 2,4,5-TP ND 0.500 mg/L 50 1/17/20234:35:00 PM Surr: 2,4-Dichlorophenylacetic aci 96.2 70 - 130 %Rec 50 1/17/2023 4:35:00 PM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8260 Analyst: EMB TCLP VOLATILES ANALYSIS 1,1-Dichloroethene ND 0.100 QC- mg/L 20 1/19/2023 4:50:00 PM 1,2-Dichloroethane ND 0.100 mg/L 20 1/19/2023 4:50:00 PM MEK ND 2.00 mg/L 20 1/19/2023 4:50:00 PM Benzene ND 0.100 mg/L 20 1/19/2023 4:50:00 PM Carbon tetrachloride ND 0.100 QL+ mg/L 20 1/19/2023 4:50:00 PM Chlorobenzene ND 1.00 mg/L 20 1/19/2023 4:50:00 PM Chloroform ND 0.100 mg/L 20 1/19/2023 4:50:00 PM Tetrachloroethene ND 0.100 mg/L 20 1/19/2023 4:50:00 PM Trichloroethene ND 0.100 QL+ mg/L 20 1/19/2023 4:50:00 PM Vinyl chloride ND 0.0400QC+QL+mg/L 20 1/19/2023 4:50:00 PM Surr: 4-Bromofluorobenzene 96.0 70 - 130 %Rec 20 1/19/2023 4:50:00 PM Surr: Di brom ofl uorom ethane 97.9 70 - 130 %Rec 20 1/19/2023 4:50:00 PM Surr: Toluene-d8 104 70 - 130 %Rec 20 1/19/2023 4:50:00 PM Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response MC Value is below Minimum Compound Limit. N Tentatively identified compounds ND Not Detected OG1 P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit Page 8 of 39 MMIT Summit Environmental Technologies, Inc. Analytical Report SU3310 Win St. ENVIRONMENTAL TECHNOLOGIE_3, IRC Cuyahoga Falls, Ohio 44223 (base report) Arrafyt9caf Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 WO#: 23010835 Website: http://www.settek.com Date Reported: 1/24/2023 CLIENT: Synagro Tag Number: Matrix: SOLID Collection Date: 1/11/2023 10:00:00 AM Lab ID: 23010835-OOIA Project: Lincolnton Client Sample ID Lincolnton Analyses Result RL Qual Units DF Date Analyzed RCI SW9014 Analyst: MS REACTIVE CYANIDE (9014/7.3.3.2)-SOLID Cyanide, Reactive ND 0.485 mg/Kg 1 1/23/2023 1:45:00 PM IGNITABILITY OF SOLIDS (SW-846: 1030) SW1030 Analyst: SMZ Ignitability Non-flammable mm/sec 1 1/18/2023 7:17:11 PM RCI SW9045D Analyst: SMZ PH (SW9045D) pH 7.2 s.u.@20.6C 1 1/20/20234:11:32 PM RCI SW9034 Analyst: MS REACTIVE SULFIDE (9034)/7.3.4.2 Sulfide, Reactive 30.0 25.0 mg/Kg 1 1/23/2023 1:45:00 PM Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response MC Value is below Minimum Compound Limit. N Tentatively identified compounds ND Not Detected OG1 P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit Page 9 of 39 Summit Environmental Technologies, Inc. Accreditation Program SUMMIEF fr3310 Win St. Analv n tes Report ENwIROMMEWALYECHNOL.OG{r,S,INC Cuyahoga Falls, Ohio44223 J Y Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 23010835 Wehsite: http://www.settek.com 24 Jan-23 Client: Synagro State: NW Project: Lincolnton Program Name: NC_WW_SCM Sample ID Matrix Test Name Analyte Status 23010835-OOIA Solid Ignitability of Solids (SW-846: 1030) Ignitability A Solid pH (SW9045D) Hydrogen Ion (pH) A Solid Reactive Cyanide (9014/7.3.3.2)-Solid Cyanide, Reactive U Solid Reactive Sulfide (9034)/7.3.4.2 Sulfide, Reactive U Solid TCLP Herbicides by EPA 8321B 2,4,5-TP A Solid TCLP Herbicides by EPA 8321B 2,4-D A Solid TCLP Mercury Analysis (SW1311/7470) Mercury A Solid TCLP Metals Analysis (SW1311/6010) Arsenic A Solid TCLP Metals Analysis (SW1311/6010) Barium A Solid TCLP Metals Analysis (SW1311/6010) Cadmium A Solid TCLP Metals Analysis (SW1311/6010) Chromium A Solid TCLP Metals Analysis (SW1311/6010) Lead A Solid TCLP Metals Analysis (SW1311/6010) Selenium A Solid TCLP Metals Analysis (SW1311/6010) Silver A Solid TCLP Pesticides Analysis (SW1311/8081) Chlordane, total A Solid TCLP Pesticides Analysis (SW1311/8081) Endrin A Solid TCLP Pesticides Analysis (SW1311/8081) gamma-BHC A Solid TCLP Pesticides Analysis (SW1311/8081) Heptachlor A Solid TCLP Pesticides Analysis (SW1311/8081) Heptachlor epoxide A Solid TCLP Pesticides Analysis (SW1311/8081) Methoxychlor A Solid TCLP Pesticides Analysis (SW1311/8081) Toxaphene A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) 1,4-Dichlorobenzene A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,5-Trichlorophenol A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,6-Trichlorophenol A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4-Dinitrotoluene A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) Cresols, Total A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobenzene A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobutadiene A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachloroethane A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) Nitrobenzene A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) Pentachlorophenol A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) Pyridine A Original #1 Page 10 of 39 Summit Environmental Technologies, Inc. Accreditation Program SUMMIEF fr3310 Win St. Analv n tes Report ENVIROMMEWAL YECHHOL.OG{r,S, INC Cuyahoga Falls, Ohio 44223 J Y Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 23010835 Wehsite: http://www.settek.com 24 Jan-23 Client: Synagro State: NW Project: Lincolnton Program Name: NC_WW_SCM Sample ID Matrix Test Name Analyte Status 23010835-OOIA Solid TCLP Volatiles Analysis 1,1-Dichloroethene A Solid TCLP Volatiles Analysis 1,2-Dichloroethane A Solid TCLP Volatiles Analysis 2-Butanone A Solid TCLP Volatiles Analysis Benzene A Solid TCLP Volatiles Analysis Carbon tetrachloride A Solid TCLP Volatiles Analysis Chlorobenzene A Solid TCLP Volatiles Analysis Chloroform A Solid TCLP Volatiles Analysis Tetrachloroethene A Solid TCLP Volatiles Analysis Trichloroethene A Solid TCLP Volatiles Analysis Vinyl chloride A Original #1 Page 11 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT Client: Synagro Project: Lincolnton BatchID: 62252 WO#: 23010835 24-Jan-23 Sample ID: MB-62252 SampType: MBLK TestCode: SVOC-BNA_T Units: mg/L Prep Date: 1/17/2023 RunNo: 156649 client ID: PBS Batch ID: 62252 TestNo: SW8270 SW3510C Analysis Date: 1/17/2023 SegNo: 4170702 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene ND 0.0250 2,4,5-Trichlorophenol ND 0.0250 2,4,6-Trichlorophenol ND 0.0250 2,4-Dinitrotoluene ND 0.0250 o-Cresol ND 0.250 Cresols, Total ND 0.0500 Hexachloro-1,3-butadiene ND 0.0250 Hexachlorobenzene ND 0.0250 Hexachloroethane ND 0.0250 Nitrobenzene ND 0.0250 Pentachlorophenol ND 0.0250 Pyridine ND 0.0250 Surr: 2-Fluorophenol 0.426 Surr: Phenol-d6 0.526 Surr: Nitrobenzene-d5 0.431 Surr: 2,4,6-Tribromophenol 0.818 Surr: 2-Fluorobiphenyl 0.481 Surr: p-Terphenyl-d14 0.805 1.000 42.6 10 135 1.000 52.6 10 161 1.000 43.1 16.8 150 1.000 81.8 32.5 179 1.000 48.1 34 133 1.000 80.5 60.8 163 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 12 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT Client: Synagro Project: Lincolnton BatchID: 62252 WO#: 23010835 24-Jan-23 Sample ID: LCS-62252 SampType: LCS TestCode: SVOC-BNA_T Units: mg/L Prep Date: 1/17/2023 RunNo: 156649 Dient ID: LCSS Batch ID: 62252 TestNo: SW8270 SW3510C Analysis Date: 1/17/2023 SegNo: 4170703 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.297 0.0250 0.8000 0 37.1 35 130 2,4,5-Trichlorophenol 0.660 0.0250 0.8000 0 82.6 44 144 2,4,6-Trichlorophenol 0.671 0.0250 0.8000 0 83.9 45 141 2,4-Dinitrotoluene 0.679 0.0250 0.8000 0 84.9 56 136 o-Cresol 0.494 0.250 0.8000 0 61.7 36 134 Cresols, Total 1.03 0.0500 1.600 0 64.3 36 135 Hexachloro-1,3-butadiene 0.341 0.0250 0.8000 0 42.6 30 130 Hexachlorobenzene 0.620 0.0250 0.8000 0 77.5 58 130 Hexachloroethane 0.290 0.0250 0.8000 0 36.3 28 130 Nitrobenzene 0.432 0.0250 0.8000 0 54.0 39 133 Pentachlorophenol 0.606 0.0250 0.8000 0 75.8 33 151 Pyridine 0.265 0.0250 0.8000 0 33.1 10 130 Surr: 2-Fluorophenol 0.477 1.000 47.7 10 135 Surr: Phenol-d6 0.565 1.000 56.5 10 161 Surr: Nitrobenzene-d5 0.430 1.000 43.0 16.8 150 Surr:2,4,6-Tribromophenol 0.926 1.000 92.6 32.5 179 Surr:2-Fluorobiphenyl 0.532 1.000 53.2 34 133 Surr: p-Terphenyl-d14 0.756 1.000 75.6 60.8 163 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 13 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT Client: Synagro Project: Lincolnton BatchID: 62252 WO#: 23010835 24-Jan-23 Sample ID: 23010716-008AMS SampType: MS TestCode: SVOC-BNA_T Units: mg/L Prep Date: 1/17/2023 RunNo: 156649 Dient ID: Batch= Batch ID: 62252 TestNo: SW8270 SW3510C Analysis Date: 1/17/2023 SegNo: 4170705 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.358 0.0250 0.8000 0 44.8 38.3 130 2,4,5-Trichlorophenol 0.638 0.0250 0.8000 0 79.8 43.9 157 2,4,6-Trichlorophenol 0.649 0.0250 0.8000 0 81.1 37.5 159 2,4-Dinitrotoluene 0.619 0.0250 0.8000 0 77.4 52.1 151 o-Cresol 0.531 0.250 0.8000 0 66.4 25.1 143 Cresols, Total 1.08 0.0500 1.600 0 67.8 10 184 Hexachloro-1,3-butadiene 0.407 0.0250 0.8000 0 50.8 36.2 130 Hexachlorobenzene 0.597 0.0250 0.8000 0 74.6 57.1 139 Hexachloroethane 0.350 0.0250 0.8000 0 43.8 30.4 130 Nitrobenzene 0.501 0.0250 0.8000 0 62.7 34 140 Pentachlorophenol 0.582 0.0250 0.8000 0 72.7 24.1 171 Pyridine 0.327 0.0250 0.8000 0 40.8 10 130 Surr: 2-Fluorophenol 0.531 1.000 53.1 10 135 Surr: Phenol-d6 0.598 1.000 59.8 10 161 Surr: Nitrobenzene-d5 0.470 1.000 47.0 16.8 150 Surr:2,4,6-Tribromophenol 0.805 1.000 80.5 32.5 179 Surr:2-Fluorobiphenyl 0.537 1.000 53.7 34 133 Surr: p-Terphenyl-d14 0.711 1.000 71.1 60.8 163 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 14 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT Client: Synagro Project: Lincolnton BatchID: 62252 WO#: 23010835 24-Jan-23 Sample ID: 23010716-008AMSD SampType: MSD TestCode: SVOC-BNA_T Units: mg/L Prep Date: 1/17/2023 RunNo: 156649 Dient ID: Batch= Batch ID: 62252 TestNo: SW8270 SW3510C Analysis Date: 1/17/2023 SegNo: 4170706 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.419 0.0250 0.8000 0 52.4 38.3 130 0.3580 15.7 30 2,4,5-Trichlorophenol 0.729 0.0250 0.8000 0 91.2 43.9 157 0.6382 13.3 30 2,4,6-Trichlorophenol 0.741 0.0250 0.8000 0 92.6 37.5 159 0.6486 13.3 30 2,4-Dinitrotoluene 0.756 0.0250 0.8000 0 94.5 52.1 151 0.6194 19.9 30 o-Cresol 0.592 0.250 0.8000 0 74.1 25.1 143 0.5312 10.9 30 Cresols, Total 1.22 0.0500 1.600 0 76.2 10 184 1.085 11.7 30 Hexachloro-1,3-butadiene 0.448 0.0250 0.8000 0 56.0 36.2 130 0.4066 9.60 30 Hexachlorobenzene 0.732 0.0250 0.8000 0 91.6 57.1 139 0.5968 20.4 30 Hexachloroethane 0.400 0.0250 0.8000 0 50.0 30.4 130 0.3504 13.3 30 Nitrobenzene 0.547 0.0250 0.8000 0 68.4 34 140 0.5012 8.74 30 Pentachlorophenol 0.756 0.0250 0.8000 0 94.5 24.1 171 0.5818 26.0 30 Pyridine 0.309 0.0250 0.8000 0 38.6 10 130 0.3266 5.60 30 Surr: 2-Fluorophenol 0.601 1.000 60.1 10 135 0 Surr: Phenol-d6 0.686 1.000 68.6 10 161 0 Surr: Nitrobenzene-d5 0.535 1.000 53.5 16.8 150 0 Surr:2,4,6-Tribromophenol 0.988 1.000 98.8 32.5 179 0 Surr:2-Fluorobiphenyl 0.615 1.000 61.5 34 133 0 Surr: p-Terphenyl-d14 0.834 1.000 83.4 60.8 163 0 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 15 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT WO#: 23010835 24-Jan-23 Client: Synagro Project: Lincolnton BatchID: 62265 Sample ID: MB-62265 SampType: MBLK TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 1/17/2023 RunNo: 156653 Client ID: PBS Batch ID: 62265 TestNo: SW6010 SW3010A Analysis Date: 1/18/2023 SegNo: 4170960 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) ND 0.100 TCLP Barium(Ba) ND 5.00 TCLP Cadmium(Cd) ND 0.100 TCLP Chromium(Cr) ND 0.200 TCLP Lead(Pb) ND 0.100 TCLP Selenium(Se) ND 0.100 TCLP Silver(Ag) ND 0.100 Sample ID: LCS-62265 SampType: LCS TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 1/17/2023 RunNo: 156653 Client ID: LCSS Batch ID: 62265 TestNo: SW6010 SW3010A Analysis Date: 1/18/2023 SegNo: 4170964 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 2.12 0.100 2.000 0 106 80 120 TCLP Barium(Ba) ND 5.00 2.000 0 102 80 120 TCLP Cadmium(Cd) 2.03 0.100 2.000 0 101 80 120 TCLP Chromium(Cr) 2.10 0.200 2.000 0 105 80 120 TCLP Lead(Pb) 2.10 0.100 2.000 0 105 80 120 TCLP Selenium(Se) 1.92 0.100 2.000 0 96.2 80 120 TCLP Silver(Ag) 2.11 0.100 2.000 0 105 80 120 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 16 of 39 MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 23010835 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 24-Jan-23 Client: Synagro Project: Lincolnton BatchID: 62265 Sample ID: 23010805-001AMS SampType: MS TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 1/17/2023 RunNo: 156653 Client ID: Batch= Batch ID: 62265 TestNo: SW6010 SW3010A Analysis Date: 1/18/2023 SegNo: 4170970 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 2.00 0.100 2.000 0 99.9 70 130 TCLP Barium(Ba) ND 5.00 2.000 0.5863 76.0 70 130 TCLP Cadmium(Cd) 1.78 0.100 2.000 0 89.0 70 130 TCLP Chromium(Cr) 1.84 0.200 2.000 0 92.0 70 130 TCLP Lead(Pb) 1.81 0.100 2.000 0 90.7 70 130 TCLP Selenium(Se) 1.90 0.100 2.000 0 94.9 70 130 TCLP Silver(Ag) 1.99 0.100 2.000 0 99.4 70 130 Sample ID: 23010805-001AMSD SampType: MSD TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 1/17/2023 RunNo: 156653 Client ID: Batch= Batch ID: 62265 TestNo: SW6010 SW3010A Analysis Date: 1/18/2023 SegNo: 4170971 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 1.99 0.100 2.000 0 99.7 70 130 1.997 0.150 20 TCLP Barium(Ba) ND 5.00 2.000 0.5863 76.8 70 130 0 0 20 TCLP Cadmium(Cd) 1.76 0.100 2.000 0 88.1 70 130 1.780 1.04 20 TCLP Chromium(Cr) 1.82 0.200 2.000 0 91.1 70 130 1.841 1.05 20 TCLP Lead(Pb) 1.80 0.100 2.000 0 89.8 70 130 1.814 1.01 20 TCLP Selenium(Se) 1.89 0.100 2.000 0 94.4 70 130 1.899 0.523 20 TCLP Silver(Ag) 1.97 0.100 2.000 0 98.4 70 130 1.987 0.929 20 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 17 of 39 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 23010835 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 24-Jan-23 Client: Synagro Project: Lincolnton BatchID: 62271 TCLP Mercury ND 0.00200 TCLP Mercury 0.00403 0.00200 0.00400 0 101 80 120 TCLP Mercury 0.00444 0.00200 0.00400 0.0000260 110 75 125 Sample ID: 23010805-001AMSD SampType: MSD TestCode: HG_TCLP(74 Units: PPM Prep Date: 1/17/2023 RunNo: 156669 Client ID: Batch= Batch ID: 62271 TestNo: SW7470A SW7470A Analysis Date: 1/18/2023 SegNo: 4171496 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual TCLP Mercury 0.00405 0.00200 0.00400 0.0000260 101 75 125 0.00444 9.19 20 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected OG1 P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 18 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT Client: Synagro Project: Lincolnton BatchID: 62271 WO#: 23010835 24-Jan-23 Sample ID: 23010805-001AMSD SampType: MSD TestCode: HG_TCLP(74 Units: PPM Prep Date: 1/17/2023 RunNo: 156669 Dient ID: Batch= Batch ID: 62271 TestNo: SW7470A SW7470A Analysis Date: 1/18/2023 SegNo: 4171496 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 19 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 23010835 24-Jan-23 Client: Synagro Project: Lincolnton BatchID: 62279 Sample ID: MB-62279 SampType: MBLK TestCode: TCLP-SVOC- Units: mg/L Prep Date: 1/18/2023 RunNo: 156731 Client ID: PBS Batch ID: 62279 TestNo: SW8081 SW3510C Analysis Date: 1/18/2023 SegNo: 4172749 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Chlordane, total ND 0.00250 Toxaphene ND 0.00500 Endrin ND 0.000500 gamma-BHC ND 0.000500 Heptachlor ND 0.000500 Heptachlor epoxide ND 0.000500 Methoxychlor ND 0.000500 Surr: TCMX 11.7 Surr: DCB 11.6 20.00 58.4 10 119 20.00 57.8 10 119 Sample ID: LCS-62279 SampType: LCS TestCode: TCLP-SVOC- Units: mg/L Prep Date: 1/18/2023 RunNo: 156731 Client ID: LCSS Batch ID: 62279 TestNo: SW8081 SW3510C Analysis Date: 1/18/2023 SegNo: 4172750 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Chlordane, tot Toxaphene Endrin gamma-BHC Heptachlor Heptachlor epo Methoxychlor Surr: TCMX Qualifiers: al 0.0183 0.0 ND 0.0 0.0108 0.00 0.00848 0.00 0.0103 0.00 xide 0.00917 0.00 0.0114 0.00 12.0 B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit 0250 0 0 70 0500 0 0 70 0500 0.0100 0 108 10 0500 0.0100 0 84.8 10 0500 0.0100 0 103 10 0500 0.0100 0 91.7 10 0500 0.0100 0 114 10 20.00 60.1 10 E Value above quantitation range M Manual Integration used to determine area response OG 1 R RPD outside accepted recovery limits 130 130 130 130 130 130 178 130 H Holding times for preparation or anal MC Value is below Minimum Compound P Second column confirmation exceeds RL Reporting Detection Limit Original Page 20 of 39 B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit 0250 0 0 70 0500 0 0 70 0500 0.0100 0 108 10 0500 0.0100 0 84.8 10 0500 0.0100 0 103 10 0500 0.0100 0 91.7 10 0500 0.0100 0 114 10 20.00 60.1 10 E Value above quantitation range M Manual Integration used to determine area response OG 1 R RPD outside accepted recovery limits 130 130 130 130 130 130 178 130 H Holding times for preparation or anal MC Value is below Minimum Compound P Second column confirmation exceeds RL Reporting Detection Limit Original Page 20 of 39 130 130 130 130 130 130 178 130 H Holding times for preparation or anal MC Value is below Minimum Compound P Second column confirmation exceeds RL Reporting Detection Limit Original Page 20 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT WO#: 23010835 24-Jan-23 Client: Synagro Project: Lincolnton BatchID: 62279 Sample ID: LCS-62279 SampType: LCS TestCode: TCLP-SVOC- Units: mg/L Prep Date: 1/18/2023 RunNo: 156731 Client ID: LCSS Batch ID: 62279 TestNo: SW8081 SW3510C Analysis Date: 1/18/2023 SegNo: 4172750 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Surr: DCB 8.64 20.00 43.2 10 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 21 of 39 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 23010835 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 24-Jan-23 Client: Synagro Project: Lincolnton BatchID: R156631 2,4-D ND 0.0100 2,4,5-TP ND 0.0100 Surr: 2,4-Dichlorophenylacetic acid 0.945 1.000 94.5 70 130 2,4-D 0.0195 0.0100 0.01000 0 195 50 150 S 2,4,5-TP ND 0.0100 0.01000 0 83.0 50 150 Surr: 2,4-Dichlorophenylacetic acid 0.00850 0.01000 85.0 70 130 Sample ID: LCS TCLP 0.3 ppm SampType: LCS TestCode: TCLP-SVOC- Units: mg/L Prep Date: RunNo: 156631 Client ID: LCSS Batch ID: R156631 TestNo: SW8321 Analysis Date: 1/17/2023 SegNo: 4170273 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 2,4-D 0.302 0.0100 0.3000 0 101 60.5 141 2,4,5-TP 0.287 0.0100 0.3000 0 95.7 68.3 144 Surr: 2,4-Dichlorophenylacetic acid 0.287 0.3000 95.5 70 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected OG1 P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 22 of 39 MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 23010835 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 24-Jan-23 Client: Synagro Project: Lincolnton BatchID: R156631 Sample ID: LCSD TCLP 0.3 ppm SampType: LCSD TestCode: TCLP-SVOC- Units: mg/L Prep Date: RunNo: 156631 Client ID: LCSS02 Batch ID: R156631 TestNo: SW8321 Analysis Date: 1/17/2023 SegNo: 4170274 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 2,4-D 0.296 0.0100 0.3000 0 98.8 60.5 141 0.3023 2.00 30 2,4,5-TP 0.278 0.0100 0.3000 0 92.8 68.3 144 0.2872 3.08 30 Surr: 2,4-Dichlorophenylacetic acid 0.279 0.3000 93.1 70 130 0 0 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range M Manual Integration used to determine area response OG 1 R RPD outside accepted recovery limits Page 23 of 39 H Holding times for preparation or anal MC Value is below Minimum Compound P Second column confirmation exceeds RL Reporting Detection Limit Original Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT WO#: 23010835 24-Jan-23 Client: Synagro Project: Lincolnton BatchID: R156695 Sample ID: LCS-R156695 SampType: LCS TestCode: Ignitability_S Units: mm/sec Prep Date: RunNo: 156695 Client ID: LCSS Batch ID: R156695 TestNo: SW1030 Analysis Date: 1/18/2023 SegNo: 4171894 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Ignitability 7.69 7.240 0 106 70 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 24 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT WO#: 23010835 24-Jan-23 Client: Synagro Project: Lincolnton BatchID: R156775 Sample ID: MBLK SampType: MBLK TestCode: VOC-MSTR_ Units: mg/L Prep Date: RunNo: 156775 Client ID: PBW Batch ID: R156775 TestNo: SW8260 Analysis Date: 1/19/2023 SegNo: 4173516 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1, 1 -Dichloroethene ND 0.00500 QC- 1,2-Dichloroethane ND 0.00500 MEK ND 0.0250 Benzene ND 0.00500 Carbon tetrachloride ND 0.00500 Chlorobenzene ND 0.00500 Chloroform ND 0.00500 Tetrachloroethene ND 0.00500 Trichloroethene ND 0.00500 Vinyl chloride ND 0.00200 QC+ Surr:4-Bromofluorobenzene 49.6 50.00 99.3 70 130 Surr: Dibromofluoromethane 49.6 50.00 99.2 70 130 Surr: Toluene-d8 50.2 50.00 100 70 130 Sample ID: LCS SampType: LCS TestCode: VOC-MSTR_ Units: mg/L Prep Date: RunNo: 156775 Client ID: LCSW Batch ID: R156775 TestNo: SW8260 Analysis Date: 1/19/2023 SegNo: 4174204 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 0.0286 0.00500 0.0200 0 143 49 161 QC- 1,2-Dichloroethane 0.0271 0.00500 0.0200 0 135 48 151 MEK 0.0970 0.0250 0.100 0 97.0 10 190 Benzene 0.0275 0.00500 0.0200 0 138 34 169 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected OG1 P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 25 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT WO#: 23010835 24-Jan-23 Client: Synagro Project: Lincolnton BatchID: R156775 Sample ID: LCS SampType: LCS TestCode: VOC-MSTR_ Units: mg/L Prep Date: RunNo: 156775 Client ID: LCSW Batch ID: R156775 TestNo: SW8260 Analysis Date: 1/19/2023 SegNo: 4174204 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Carbon tetrachloride 0.0290 0.00500 0.0200 0 145 76 134 S Chlorobenzene 0.0264 0.00500 0.0200 0 132 54 144 Chloroform 0.0258 0.00500 0.0200 0 129 70 130 Tetrachloroethene 0.0259 0.00500 0.0200 0 130 66 134 Trichloroethene 0.0285 0.00500 0.0200 0 142 70 136 S Vinyl chloride 0.0339 0.00200 0.0200 0 170 49 136 SQC+ Surr:4-Bromofluorobenzene 49.7 50.00 99.4 70 130 Surr: Dibromofluoromethane 51.0 50.00 102 70 130 Surr: Toluene-d8 48.2 50.00 96.5 70 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 26 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT WO#: 23010835 24-Jan-23 Client: Synagro Project: Lincolnton BatchID: R156775 Sample ID: MBLK SampType: MBLK TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 156775 Client ID: PBS Batch ID: R156775 TestNo: SW8260 Analysis Date: 1/19/2023 SegNo: 4173517 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1, 1 -Dichloroethene ND 0.100 QC- 1,2-Dichloroethane ND 0.100 MEK ND 2.00 Benzene ND 0.100 Carbon tetrachloride ND 0.100 Chlorobenzene ND 1.00 Chloroform ND 0.100 Tetrachloroethene ND 0.100 Trichloroethene ND 0.100 Vinyl chloride ND 0.0400 QC+ Surr:4-Bromofluorobenzene 1000 1000 100 70 130 Surr: Dibromofluoromethane 980 1000 98.0 70 130 Surr: Toluene-d8 1020 1000 102 70 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 27 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT WO#: 23010835 24-Jan-23 Client: Synagro Project: Lincolnton BatchID: R156775 Sample ID: 23010834-001AMS SampType: MS TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 156775 Client ID: Batch= Batch ID: R156775 TestNo: SW8260 Analysis Date: 1/19/2023 SegNo: 4173523 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1, 1 -Dichloroethene 0.599 0.100 0.400 0 150 13.6 202 1,2-Dichloroethane 0.495 0.100 0.400 0 124 55.7 138 MEK 2.08 2.00 2.00 0 104 65.3 118 Benzene 0.559 0.100 0.400 0 140 49.2 145 Carbon tetrachloride 0.486 0.100 0.400 0 121 26.7 156 Chlorobenzene ND 1.00 0.400 0 126 33.7 159 Chloroform 0.499 0.100 0.400 0 125 48.5 145 Tetrachloroethene 0.469 0.100 0.400 0 117 19.2 191 Trichloroethene 0.471 0.100 0.400 0 118 38.4 167 Vinyl chloride 0.620 0.0400 0.400 0 155 27.3 161 Surr:4-Bromofluorobenzene 986 1000 98.6 91.7 109 Surr: Dibromofluoromethane 957 1000 95.7 75.5 118 Surr: Toluene-d8 1050 1000 105 94.1 105 QC- Q L+ Q L+ QL+QC+ S Sample ID: 23010834-001AMSD SampType: MSD TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 156775 Client ID: Batch= Batch ID: R156775 TestNo: SW8260 Analysis Date: 1/19/2023 SegNo: 4173524 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 0.537 0.100 0.400 0 134 13.6 202 0.599 10.9 25 QC- 1,2-Dichloroethane 0.469 0.100 0.400 0 117 55.7 138 0.495 5.48 25 MEK 2.21 2.00 2.00 0 110 65.3 118 2.08 5.84 25 Benzene 0.499 0.100 0.400 0 125 49.2 145 0.559 11.4 25 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected OG1 P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 28 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT WO#: 23010835 24-Jan-23 Client: Synagro Project: Lincolnton BatchID: R156775 Sample ID: 23010834-001AMSD SampType: MSD TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 156775 Client ID: Batch= Batch ID: R156775 TestNo: SW8260 Analysis Date: 1/19/2023 SegNo: 4173524 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Carbon tetrachloride 0.434 0.100 0.400 0 109 26.7 156 0.486 11.2 25 QL+ Chlorobenzene ND 1.00 0.400 0 109 33.7 159 0 0 25 Chloroform 0.454 0.100 0.400 0 114 48.5 145 0.499 9.36 25 Tetrachloroethene 0.405 0.100 0.400 0 101 19.2 191 0.469 14.7 25 Trichloroethene 0.423 0.100 0.400 0 106 38.4 167 0.471 10.6 25 QL+ Vinyl chloride 0.583 0.0400 0.400 0 146 27.3 161 0.620 6.28 25 QL+QC+ Surr:4-Bromofluorobenzene 981 1000 98.1 91.7 109 0 25 Surr: Dibromofluoromethane 990 1000 99.0 75.5 118 0 25 Surr: Toluene-d8 1030 1000 103 94.1 105 0 25 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 29 of 39 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 23010835 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 24-Jan-23 Client: Synagro Project: Lincolnton BatchID: R156838 pH 7.0 7.0 0 100 90 110 pH 12.5 0 0 0 0 12.5 0.2 10 pH 7.0 7.0 0 100 90 110 Sample ID: 23011173-001ADUP SampType: DUP TestCode: pH_S(9045D) Units: s.u.@20.5C Prep Date: RunNo: 156838 Client ID: Batch= Batch ID: R156838 TestNo: SW9045D Analysis Date: 1/20/2023 SegNo: 4175312 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual pH 6.5 0 0 0 0 6.4 0.6 10 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 30 of 39 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 23010835 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 24-Jan-23 Client: Synagro Project: Lincolnton BatchID: R156838 pH 7.0 7.0 0 100 90 110 pH 7.6 0 0 0 0 7.6 0 10 Sample ID: LCS-R156838 SampType: LCS TestCode: pH_S(9045D) Units: s.u.@20.5C Prep Date: RunNo: 156838 Client ID: LCSS Batch ID: R156838 TestNo: SW9045D Analysis Date: 1/20/2023 SegNo: 4175326 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual pH 7.0 7.0 0 101 90 110 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected OG1 P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 31 of 39 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 23010835 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 24-Jan-23 Client: Synagro Project: Lincolnton BatchID: R156838 pH 7.0 7.0 0 100 98.6 101.4 pH 6.9 6.9 0.4 5 H pH 7.0 7.0 0 100 98.6 101.4 Sample ID: 23010912-001ADUP SampType: DUP TestCode: pH_NPW(450 Units: s.u.@19.7C Prep Date: RunNo: 156838 Client ID: Batch= Batch ID: R156838 TestNo: SW9045D Analysis Date: 1/20/2023 SegNo: 4175285 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual pH 6.3 6.3 0.5 5 H Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 32 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT WO#: 23010835 24-Jan-23 Client: Synagro Project: Lincolnton BatchID: R156838 Sample ID: 23010912-001ADUP SampType: DUP TestCode: pH_NPW(450 Units: s.u.@19.7C Prep Date: RunNo: 156838 Dient ID: Batch= Batch ID: R156838 TestNo: SW9045D Analysis Date: 1/20/2023 SegNo: 4175285 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 33 of 39 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 23010835 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 24-Jan-23 Client: Synagro Project: Lincolnton BatchID: R156913 Cyanide, Reactive ND 0.495 Cyanide, Reactive 9.17 0.500 10.00 0 91.7 85 115 Cyanide, Reactive ND 0.481 0.5000 0 62.0 50 150 Sample ID: 23010840-001AMS SampType: MS TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 156913 Client ID: Batch= Batch ID: R156913 TestNo: SW9014 Analysis Date: 1/23/2023 SegNo: 4176952 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 7.77 0.495 10.00 0 77.7 75 125 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected OG1 P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 34 of 39 MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 23010835 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 24-Jan-23 Client: Synagro Project: Lincolnton BatchID: R156913 Sample ID: 23010840-001AMS SampType: MS TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 156913 Client ID: Batch= Batch ID: R156913 TestNo: SW9014 Analysis Date: 1/23/2023 SegNo: 4176952 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sample ID: 23010840-001AMSD SampType: MSD TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 156913 Client ID: Batch= Batch ID: R156913 TestNo: SW9014 Analysis Date: 1/23/2023 SegNo: 4176953 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 8.43 0.495 10.00 0 84.3 75 125 7.772 8.19 10 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range H Holding times for preparation or anal M Manual Integration used to determine area response MC Value is below Minimum Compound OG1 P Second column confirmation exceeds R RPD outside accepted recovery limits RL Reporting Detection Limit Original Page 35 of 39 MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 23010835 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 24-Jan-23 Client: Synagro Project: Lincolnton BatchID: R156917 Sample ID: 23010840-001AMS SampType: MS TestCode: Sulfide,React Units: mg/Kg Prep Date: RunNo: 156917 Client ID: Batch= Batch ID: R156917 TestNo: SW9034 Analysis Date: 1/23/2023 SegNo: 4177055 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive 1590 25.0 1710 0 93.0 80 120 Sample ID: 23010840-001AMSD SampType: MSD TestCode: Sulfide,React Units: mg/Kg Prep Date: RunNo: 156917 Client ID: Batch= Batch ID: R156917 TestNo: SW9034 Analysis Date: 1/23/2023 SegNo: 4177056 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive 1660 25.0 1710 0 97.1 80 120 1590 4.31 30 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range H Holding times for preparation or anal M Manual Integration used to determine area response MC Value is below Minimum Compound OG1 P Second column confirmation exceeds R RPD outside accepted recovery limits RL Reporting Detection Limit Original Page 36 of 39 MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 23010835 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 24-Jan-23 Client: Synagro Project: Lincolnton BatchID: R156917 Sample ID: MB-R156917 SampType: MBLK TestCode: Sulfide,React Units: mg/L Prep Date: RunNo: 156917 Client ID: PBW Batch ID: R156917 TestNo: SW9034 Analysis Date: 1/23/2023 SegNo: 4177039 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive ND 25.0 Sample ID: LCS-R156917 SampType: LCS TestCode: Sulfide,React Units: mg/L Prep Date: RunNo: 156917 Client ID: LCSW Batch ID: R156917 TestNo: SW9034 Analysis Date: 1/23/2023 SegNo: 4177040 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive 1670 25.0 1710 0 97.7 85 115 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range H Holding times for preparation or anal M Manual Integration used to determine area response MC Value is below Minimum Compound OG1 P Second column confirmation exceeds R RPD outside accepted recovery limits RL Reporting Detection Limit Original Page 37 of 39 .a 9 iiV ixrs3 � a��jno3C so oaus�]dwo, li�ao dg _�I�vp MQ Jul ❑ a N o g LA'4 N L z z Li R e l+ Oi 9 d 6 ' Q c qjaq4sad 6 y k ald mug jad umclope, Jo Aogmnu E r 5 � a p (sgwwwno tq Qj"dr).M41%(0 L,Ceu IL •Y01 (9 `•HO-N j iS :s�claaY my [� �L]R i£ �r4SxR IL �fOi�kl [i :uuU¢ussud (] a '40M SUNUP((= A%d'"INM sige2aa —N =nAdu 'yip Y,I!O -0 d `p!"b'l �1 aR(S �1 Q�i°8 �,uC :ifl16 pp L 7idm ES MISO(TwOj *�d ueuS 4-!) a C � LL 4 E 6 �u p w n 9 N � ■�� tt' } 9 '0 9 i m (C c� N o ry 8 c c or w a � + L � - K a h@ P T +❑� 0�UN Ga 1¢�"'NAma.a A Page 38 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMENTAL TECHN❑L4Ga1�S.IfiC Cuyahoga Falls, Ohio44223 Sample Log -In Check List Arrafocaf Laboralorias TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,,",m,.settek.coin Client Name: SYN-NC-27028 Work Order Number: 23010835 RcptNo: 1 Logged by: Anthony W. Britton 1/13/2023 10:20:00 AM' Completed By: Anthony W. Britton 1/13/2023 5:38:47 PM Reviewed By: Jennifer Woolf 1/16/2023 3:55:46 PM Chain of Custody 1. Is Chain of Custody complete? Yes ❑d No ❑ Not Present ❑ 2. How was the sample delivered? UPS Lop In 3. Coolers are present? Yes ❑d No ❑ NA ❑ 4. Shipping container/cooler in good condition? Yes d❑ No ❑ Custody seals intact on shipping container/cooler? Yes ❑ No ❑ Not Present V No. Seal Date: Signed By: 5. Was an attempt made to cool the samples? Yes ❑d No ❑ NA ❑ 6. Were all samples received at a temperature of >0° C to 6.0°C Yes ❑d No ❑ NA ❑ 7. Sample(s) in proper container(s)? Yes ❑d No ❑ 8. Sufficient sample volume for indicated test(s)? Yes ❑d No ❑ 9. Are samples (except VOA and ONG) properly preserved? Yes ❑d No ❑ 10. Was preservative added to bottles? Yes ❑ No ❑d NA ❑ 11. Is the headspace in the VOA vials less than 1/4 inch or 6 mm? Yes ❑ No ❑ No VOA Vials ❑� 12. Were any sample containers received broken? Yes ❑ No ❑d 13. Does paperwork match bottle labels? Yes No ❑ (Note discrepancies on chain of custody) 14. Are matrices correctly identified on Chain of Custody? Yes ❑ No ❑d 15. Is it clear what analyses were requested? Yes ❑d No ❑ 16. Were all holding times able to be met? Yes No ❑ (If no, notify customer for authorization.) Special Handling (if applicable) 17. Was client notified of all discrepancies with this order? Yes ❑ No ❑ NA V Person Notified: Date: By Whom: Via: ❑ eMail ❑ Phone ❑ Fax ❑ In Person Regarding: Client Instructions: 18. Additional remarks: Cooler Information Cooler No Temp °C Condition I Seal Intact Seal No Seal Date Signed By 1 15.0 Goodl Not Present Page 39 of 39 SECTION 5 ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City of Lincolnton WWTP WQ Permit Number: WQ 0002712 WWTP Name: Lincolnton WWTP NPDES Number: NC 0025496 Monitoring Period: From 01/01/2023 — To 03131/2023 Pathogen Reduction (40 CFR 503.32115A NCAC 02T.1106) - Please indicate level achieved and alternative perforated: Class A: Ah. 1 /A (timeltemp) Alt. 21B (Alk Treatment) All. 3!C (Prior Testing) Alt. 4/D (No Prior Test) All. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class R: Alt. (1) Fecal Density X All. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class R only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion If .....,H—hi. *.. nll..r.... t:.rn —fn --] t('laec A — !'loec R1 nnm alma tha f.11---—it—inn data. Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Gen. Mean Maximum Units dences Analysis Fecal 2x10to the 611 MPN MPN/g Coliform power per gram of total solids 2290 2955 3899 CFU/g 0 Quarterly Grab 9222D CFU SM 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grants total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503.33115A NCAC 02TA 107) - Please indicate optionlalternative performed- Option/Alt, 1 Option/Alt. 2 Option/Alt. 3 Option/Alt. 4 (VS reduction) X (40-day bench) (30-day bench) (Spec. 02 uptake) Option/Alt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate stateincnt) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1 107 have been met." "I certify, tinder penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement In 40 CFR 503.33/15A NCAC 02T.1 107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. 1 am aware that there are significant penalties for false certification including fine and imprisonment." Todd Elmore Water Resources Director Preparer Name anq Title ( type or print) Signature of Preparer* Date Land Applier Name and Title (if applicable) (type or print) Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1 102 (26) Meritech, Inc. Environmental Laboratory Laboratory Certification No. 165 Contact: Alex Fox Client: Synagro 284 B R d Page 1 Report Date: 1/17/2023 oger oa Project: Lincolnton Mocksville, NC 27028 Date Sample Rcvd: 1/11/2023 Meritech Work Order # 01112356 Parameters Sample: L 1 Grab Results Analysis Date 1/11/23 Reporting Limit Method % Total Solids 3.90 % 1/12/23 0-100 % SM 2540B Fecal Coliform (Sludge) 2,564 CFU/g dry wt 1/11/23 130 CFU/g drywt SM 9222D Meritech Work Order # 01112357 Sample: L 2 Grab 1/11/23 Parameters Results Analysis Date, Reporting Limit Method % Total Solids 3.74 % 1/12/23 0-100 % SM 2540E Fecal Coliform (Sludge) 3,889 CFU/g dry wt 1/11/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 01112358 Sample: L 3 Grab 1/11/23 Parameters Results Analysis Date Reporting Limit Method % Total Solids 3.60 % 1/12/23 0-100 % SM 2540B Fecal Coliform (Sludge) 3,030 CFU/g drywt 1/11/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 01112359 Parameters Sample: L 4 Grab Results Analysis Date 1/11/23 Reporting Limit Method % Total Solids 3.89 % 1/12/23 0-100 % SM 2540B Fecal Coliform (Sludge) 2,337 CFU/g drywt 1/11/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 01112360 Sample: L 5 Grab 1/11/23 Parameters Results Analysis Date Reporting Limit Method % Total Solids 3.97 % 1/12/23 0-100 % SM 2540B Fecal Coliform (Sludge) 2,290 CFU/g dry wt 1/11/23 130 CFU/g dry wt SM 9222D 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 F� Contact: Alex Fox Client: Synagro 284 Boger Road Mocksville, NC 27028 Meritech, Inc. Environmental Laboratory Laboratory Certification No.165 Page 2 Report Date: 1/17/2023 Project: Lincolnton Date Sample Rcvd: 1/11/2023 Meritech Work Order # 01112361 Sample: L 6 1/11/23 Parameters Results Analysis Date Reporting Limit Method % Total Solids 3.86 % 1/12/23 0-100 % SM 2540E Fecal Coliform (Sludge) 3,062 CFU/g dry wt 1/11/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 01112362 Sample: L 7 1/11/23 Parameters Results Analysis Date Reporting Limit Method % TotaI Solids 2.91 % 1/12/23 0-100 % SM 2540B Fecal Coliform (Sludge) 3,124 CFU/g dry wt 1/11/23 130 CFU/g dry wt SM 9222D I hereby certify that I have reviewed and approve these data. Laboratory Representative 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 ❑ ❑ ❑ ❑ Ln fn rD�' o -TI3 Q o rD r + O fi n _ r, O p - > c > a c = - N 7 3 s r m a a r -+ j �i -- O r� A f11 1 —J r j1 Q n C d Z —h 4 (D m ro ^p (D m n Z V' ! O } r-fi °' N Q O O_ c r Q Qj i v 2 o �} rD � � O O fTi fp o o yr (A 3 m 9] � ? a C � �. rD x '9 � Q h o a � 3 dG f S m o rD r W 1 'S O o n � W W O b 3 0 0 b I O 3 O O fn N O a N O rD fr4 Ln j 1 L� rn nNJa � j 0.CD • z ElCL ro m m rD _ rD CL rD tF 1 n d_ O "" n Q y Vi VY o O 7 G tCL o r a fZ rn C 0 ro < c = rDrD= O w f ° rl F o V� Ln Q m 1 CY m fa rt `b E � -u U� O C` :tt r _ Z T P n "` ro N :It CL C p m rD D v rD p r w rr°n D p 4 3 �' �' c *t p o 3 a) c a o O C f 0 fIf ° 3 I echnician \ quarter i Year SM 2540 a-2011, 2540 D-2011 NC0025496 All weighings are done in grams Time Collected % / 5 L� /—5-- / v 00 Date Collected a -zQ- Z-3 Date / Time In . D , Z 3 Ile (� Date / Time Out Total Wet Wgt D 5 , a OJ 0 r% �/1 l/ 0J� l �✓ (i Dish Wet Sludge Wgt (103-10 °C) Dried Wgt Dist, Dry Solids Wgt J Lf �, % Solids j t� AVG % Solids c Time In/Out V(�� � , v �) (103-1060{) Dried y! O, 3 t�O l� 6, W g D �3 ,y?, del) � 13 �y• . 550°C Wt !� y, 0 7 Z y, 6a 7 ? m Z i L5r 'Zb Volatile Solids Wgt r / h/ � , 2 / � 2 — n % Volatile Solids � V j AVG V %, Volatile Solids n E° TS DAF TS Slud e Dry Solids Wgt X 100 Total Solids_ Wet Solids Wgt % Volatile Solids = (Volatile Solids Wgt) x 100 Dried Solids Wgt 6 DAF - VS Sludge) x 100 l V % Reduction = (VS VS DAF - (VS DAF)(VS Sludge) ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City of Lincolnton WWTP WQ Permit Number: WWTP Name: Lincolnton WWTP NPDES Number: Monitoring Period: From 04/01/2023 To 06/30/2023 WQ 00t6247 NC 0025496 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. I/A (timeltemp) All. 2B (Alk Treatment) Alt. 3/C (Prior Testing) All. 41D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophitic Beta Ray Gamma Ray Pasteurization Class B: All. (1) Fecal Density _X Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion If — 1—hln to aItnrnnti— narr—pril trance A nr Claec R1 rmmntptn tha fnllnivino mnnifnrinv dntnr Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units dences Analysis Fecal 2x l0 to the 6`1i MPN MI'Mg Coliforin power per gram of total solids 8,485 11,173 14,778 CFU/g 0 Quarterly Grab 9222D CFU SM t000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503.33115A NCAC 02TA 107) - Please indicate option/alternative performed: Option/Alt, 1 Option/Alt. 2 Option/Alt. 3 Option/Alt. 4 (VS reduction) X (40-day bench) (30-day bench) (Spec. 02 uptake) Option/Alt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) (Drying — Stable) (Drying — Unstable) Option/Alt, 9 Option/Alt. 10 (injection) (Incorporation) No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) "9 certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32115A NCAC 02T.1 106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1 107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement to 40 CFR 503.33/15A NCAC 02T.1 107 have not been met." (Please note if you check this statement attach art explanation why you have not met one or both of the requirements.) "This detennination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the infornlation used to detennine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Todd Elmore Water Resources Director Preparer Name and Title ( type or print) Land Applier Name and Title (if applicable) (type or print) Signature of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) Meritech, Inc. Environmental Laboratory Laboratory Certification No. 165 Contact: Ryan Copeland Client: Synagro 284 Boger Road Mocksville NC 27028 Meritech Work Order # 040423212 Sample: L 1 Grab Parameters Results Analysis Date Page 1 Report Date: 4/13/2023 Date Sample Rcvd: 4/4/2023 4/4/23 Reporting Limit Method % Total Solids 2.44 % 4/6/23 0-100 % SM 2540E Fecal Coliform (Class B Sludge) 10,656 CFU/g dry wt 4/4/23 216 CFU/g dry wt SM 9222D Meritech Work Order # 040423213 Sample: L 2 Grab 4/4/23 Parameters Results Analysis Date Reporting Limit Method Total Solids 2.06 % 4/6/23 0-100 % SM 2540B Fecal Coliform (CIass B Sludge) 12,621 CFU/g dry wt 4/4/23 221 CFU/g dry wt SM 9222D Meritech Work Order # 040423214 Sample: L 3 Grab 4/4/23 Parameters Results Analysis Date Reporting Limit Method Total Solids 2.02 % 4/6/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) 10,396 CFU/g dry wt 4/4/23 215 CFU/g dry wt SM 9222D Meritech Work Order # 040423215 Sample: L 4 Grab 4/4/23 Parameters Results Analysis Date Reporting Limit Method % Total Solids 2.25 % 4/6/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) 8,485 CFU/g dry wt 4/4/23 222 CFU/g dry wt SM 9222D Meritech Work Order # 040423216 Sample: L 5 Grab 4/4/23 Parameters Results Analysis Date Reporting Limit Method Total Solids 2.20 % 4/6/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) 11,364 CFU/g dry wt 4/4/23 225 CFU/g dry wt SM 9222D 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 Meritech, Inc. Environmental Laboratory Laboratory Certification No. 165 Contact: Ryan Copeland CIient: Synagro 284 Boger Road MocksviIle, NC 27028 Page 2 Report Date: 4/13/2023 Date Sample Rcvd: 4/4/2023 Meritech Work Order # 040423217 Sample: L 6 Grab 4/4/23 Parameters Results Analysis Date Reporting Limit Method % Total Solids 2.20 % 4/5/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) 10,909 CFU/g dry wt 4/4/23 214 CFU/g dry wt SM 9222D Meritech Work Order # 040423218 Sample: L 7 Grab 4/4/23 Parameters Results Analysis Date Reporting Limit Method Vo Total Solids 2.03 % 4/5/23 0-100 % SM 2540E Fecal Coliform (Class B Sludge) 14,778 CFU/g dry wt 4/4/23 198 CFU/g dry wt SM 9222D I hereby certify that I have reviewed and approve these data. Laboratory Representative 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 ❑ ❑ ❑ ❑ up p a rD C '� [a Ln ` rD rD r CD Q r - ro n o c � a v rD 7 �-� S S � R C') 4 m C C.1 Q U N K ZF ` O 7J Q 01 N `.. 1 * •:J r J r `a < w ? ° r (D m = C n 2 C C) n 3 z 0 F rn rD C � t�-1' 4 � � •• N v a C)O z A o ° fv rD 0 o m 3 0 rD M a + S rt G �' LA * T cu x •9 o lu -1 rD au n r nm f o rD = '0 r'+ W rD O 0 (A 0 N 0 W ltiY Ln m m N 4�- w LA l l ^ CL D =I fD � � 3 ❑ rD 3 r� - o g G) o m D > n "J "Q rD m. .O-r fD rr Ln z rD o m rD m m n — <' 6 <' c' 3 v CL h CL a 0 M rD v — s r. M in m �1 O �8 n a p G rD c f' r y i7 I �i -r -u O Z rr 4 / Al �• y X CL O ^1ID cm rt rL iA bq n O ^ 3 w z D r ux Q c D ElO r N `� p 4 7 n S O O � -1 •o 1F �J JV O w < d n uuarter / Year 2 technician liv <�-- SM 2540 B-2011, 2640 D -2011 NCO025496 All weighings are done in grams . �-Ixlry �,-- Time Collected Date Collected Z--3 Z Date i Time In ,E2 2-3 ej /-5 Date I Time Out Z:, T Y j Total Wet Wgt , -) A r�Dish -2 Ll -t Wet Sludge Wgt 1 Z3 '51 (1 03-1050C) Dried L13-, .3 340 li -7, 3 Wgte Dish L/- Ll - 2j& 4-1 �-f I �r Dry Solids Wgt �,2 Z- YS, % Solids L AVG % Solids Time In/Out (103-1 o50C) Dried w9t 550')C Wt 2— :L4- Volatile Solids Wgt C % Volatile Solids AVG °!° Volatile Solids % TS DAF % TS Sludge % Total Solids = Dry Solids Wgt Wet solids Wgt x 100 % Volatile Solids = (Volatile Solids W90 Dried Solids Wgt -X '100 % Reduction (VS DAF - VS sludge)_ x 100 VS DAF - (VS DAF)(VS Sludge) ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City of Lincolnton WWTP WQ Permit Number: WQ 0016247 WWTP Name: Lincolnton WWTP NPDES Number: NC 0025496 Monitoring Period: From 07/01/2023 To 09/30/2023 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1 /A (time/temp) Alt. 21B (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/D (No Prior Test) Alt. S/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Litre Stabilization Air Drying _ Composting Aerobic Digestion Anaerobic Digestion IC ., 1;.... h1.. M ..U—.n !— ., rf..r. —1 lr — A nr Ch.. Rl Art1ilIM. tha f.11-1nn mnniMrino data• Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units dences Analysis Fecal 2x10 to the 61h MPN MPN/g Coliform power per gram of total solids 208 581 1,210 CFU/g 0 Quarterly Grab 9222DSM CFU 1000 MPN per gram of MPNIg total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) llCU of fecal coliform) Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate optionlalternative performed: Option/Alt. 1 Option/Alt. 2 Option/Alt. 3 Option/Alt. 4 (VS reduction) X (40-day bench) (30-day bench) (Spec. 02 uptake) Option/Alt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (injection) (Incorporation) No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32115A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/l5A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Todd Elmore Water Resources Director Preparer Name and Title ( type or print) Signature or Preparer* Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) Land Applier Name and Title (if applicable) (type or print) Signature of Land Applier (if applicable) Date Meritech, Inc. Environmental Laboratory Laboratory Certification No. 165 r Page 1 Contact: Alex Fox Report Date: 7/12/2 023 Client: Synagro 284 Boger Road Project, Lincolnton Mocksville, NC 27028 Date Sample Rcvd; 7/5/2023 Meritech Work Order # 07052341 Sample; L 1 Gram 7/5/23 Parameters Results Analysis Dat Reporting Li—mi Mk.th2d % Total Solids 3.67 % 7/6/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) 991 CFU/g dry wt 7/5/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 07052342 Sample: L 2 Grab 7/5/23 Parameters Results AnalySis Date Reporting Limit shod % Total Solids 4.37 % 7/6/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) 208 CFU/g dry wt 7/6/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 07052343 Sample: L 3 Grab 7/5/23 f arameters Results Analysis Date Reporting Limit Method Total Solids 4.32 % 7/6/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) 631 CFU/g dry wt 7/5/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 07052344 Sample: L 4 Grab 7/5/23 Parameters Results Analy5is Date Reporting Limit Method % Total Solids 4.51 % 7/6/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) 1,210 CFU/g drywt 7/5/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 07052345 Sample. L 5 Grab 7/5/23 Paramete $its Analysis Date Reporting Limit Metbod % Total Solids 4.17 % 7/6/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) 436 CFU/g dry wt 7/5/23 130 CFU/g dry wt SM 9222D 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 Meritech, Inc. Environmental Laboratory " Laboratory Certification No. 165 r Page 2 Contact: Alex Fox Report Date: 7/12/2023 Client: Synagro 284 Boger Road Project: Lincointon Mocksville, NC 27028 Date Sample Rcvd: 7/5/23 Meritech Work Order # 07052346 Sample: L 6 Grab 7/5/23 Parameters Results Analysis Date Reporting Limit Method % Total Solids 4.44 % 7/6/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) 409 CFU/g dry wt 7/5/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 07052347 Sample: L 7 Grab 7/5/23 R=rting Limit Method % Total Solids 4.56 % 7/6/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) 797 CFU/g dry wt 7/5/23 130 CFU/g dry wt SM 9222D l hereby certify that I have reviewed and approve these data. stA� Vb-nc -y Laboratory Representative 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 ❑ ❑❑❑ Ln U O Z) 0. T( � � rr+ S 3 rD Q m cn 0 rD x O Or ri' h o G' u Q S s m S rD O x M 0) A N Q N m Q fD m ro n C c m ° rf m " O a e }K o 0 CA m S o o m (q a w � m 0 � C.j m f") � t'a G fu W w 0)n w O a 3 ° �+ p 'n a o N O m ti y' rD L A i V c m � nNi � Smn n a Q 3 , 3 3 � ❑ � � N m a rP y ` o ° d c� r m n D n El PC y rr z o0 n �' r. = �, 3 v MQA % m _< m ro 72 S n+ o r o a a '° m ,T M f� n 6 Q C p t c rD -a ro ° 19� fD S nC rD in Q 'a %-.--� 9 rD C N M. r g o T Ln G ° r m f+ Oho rD d -- °' -0 p -0 m 3 m z y rD r f"h LL a !� io Uq C y S 128 ❑i c G oa c Q 3 m rya �, ro O a :3- ma ' 0 _ L CL ° " 0 ° 3 �.. to Eltl�j 2 O a -0 0 00 0 iewnician •' ! Sill 2W 8-201.1, 2540 ❑ -2011 Quareer 1 Year I = ci Z� Z NCO025496 All weighings are done in grams Time Collected ly 3 Date Collected Date / Time In Date / Time Out 9- 3 Total Wet Wgt Dish 1� Wet Sludge Wgt (103-105°C) Dried Wgt Dish Dry Solids W9t % Solids AVG % Solids Time InlOut Dd PC" 3 �Ivk /e'C/,-s ea L/`t z3S3 Z, Y3,q /Z)r 6�° /!(9 YS / / yT/ r a--3C3 (t03-105 550°C Wt Volatile Solids Wgt �1 r J 3 3 2 % Volatile Solids AVG d % Volatile Solids f °lo TS DAF = Gt % VS DAFi, E/1 TS Sludge =` % VS Sl1tCi E % Total Solids = Dry Solids Wgt Wet Solids Wqt % Volatile Solids = (Voiatiie Solids WO X 100 Dried Solids W9t % Reduction = (VS DAF - VS Sludge) YC 100 VS DAF - (VS DAF)(VS sludge) ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City of Lincolnton WWTP WWTP Name: Lincolnton WWTP WQ Permit Number: WQ 0016247 NPDES Number: NC 0025496 Monitoring Period: From 10101/2023 To 12/31/2023 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Ali. i/A (time/temp) Alt. 2B (Alk Treatment) All. 3/C (Prior Testing) Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion If annlirahle to alternative nerfnrmed (Class A nr Class Rl cmmnletp the fnllnwina mnnitnrinu data: Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units dences Analysis Fecal 2x10 to the 611' MPN MPN/g Coliform power per gram of total solids 287 398 616 CFU/g 0 Quarterly Grab 92221) CFU SM 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal colifomr) Vector Attraction Reduction (40 CFR 503.33115A NCAC 02T.1107) - Please indicate optiontalternative performed: Option/Alt. 1 Option/Alt. 2 Option/Alt. 3 Option/Alt. 4 (VS redaction) X (40-day bench) (30-day bench) (Spec. 02 uptake) Option/Alt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Aik Stabilization) (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement to 40 CFR 503.33/15A NCAC 02T.1 107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This detenninatioa has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including tine and imprisonment." Todd Elmore Water Resources Director Preparer Name and Title ( type or print) Signature of Preparer* Date Land Applier Name and Title (if applicable) (type or print) Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1 102 (26) Meritech, Inc. Environmental Laboratory Laboratory Certification No.165 Contact. Alex Fox Client: Synagro 284 Boger Road Mocksville, NC 27028 Report Date: Project: Date Sample Rcvd: Page 1 10/10/2023 Lincolnton 10/3/2023 Meritech Work Order # 100323158 Sample: L 1 Grab 10/3/23 Parameters Results Analysis Date Reporting Limit Method % Total Solids 2.33 % 10/5/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) <390 CFU/g dry wt 10/3/23 390 CFU/g dry wt SM 9222D Meritech Work Order # 100323159 Sample: L 2 Grab 10/3/23 Parameter Results Analysis Date Reporting Limit Metho a/a Total Solids 2.28 % 10/5/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) <399 CFU/g dry wt 10/3/23 399 CFU/g dry wt SM 9222D Meritech Work Order # 100323160 Sample: L 3 Grab 10/3/23 Parameters Results Analysis Date Reporting Limit Method % Total Solids 3.17 % 10/5/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) <287 CFU/g dry wt 10/3/23 287 CFU/g dry wt SM 9222D Meritech Work Order # 100323161 Sample: L 4 Grab 10/3/23 paramgt Results Analysis Date Reporting Limit Method % Total Solids 2.42 % 10/5/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) <376 CFU/g dry wt 10/3/23 376 CFU/g dry wt SM 9222D Meritech Work Order # 100323162 Sample: L 5 Grab 10/3/23 Parameters Results Analysis Date Reporting Limit Method % Total Solids 2.38 % 10/5/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) <382 CFU/g dry wt 10/3/23 382 CFU/g dry wt SM 9222D 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1S22 Meritech, Inc. Environmental Laboratory Laboratory Certification No. 165 Contact: Alex Fox Client: Synagro 284 Boger Road Mocksville, NC 27028 Meritech Work Order # 100323163 Sample: L 6 Grab Parameters Results Analysis Date % Total Solids 2.29 % 10/5/23 Fecal Coliform (Class B Sludge) <397 CFU/g dry wt 10/3/23 Meritech Work Order # 100323164 Sample: L 7 Grab Page 2 Report Date: 10/10/2023 Project: Lincolnton Date Sample Rcvd: 10/3/23 10/3/23 Reporting Limi Method 0-100 % SM 2540B 397 CFU/g dry wt SM 9222D Parameters Results Analysis Date Reporting Limit 10/3/23 Meth % Total Solids 2.95 % 10/5/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) 616 CFU/g dry wt 10/3/23 130 CFU/g dry wt SM 9222D I hereby certify that I have reviewed and approve these data. ,Laboratory Representative 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 7 a ) o , Fr , 7 /rD ` } 2 g Y \ § ] ( 2 \ / ! } � 2 \LA & 0 ° ] { & `# : � \ o 0 \ k 2 \ ` ( - 3 ° @ g , m ( ; } 2 2 .�} _ ■ z - I _ L LD } ` ƒ \ \ j}CL a > r_ § / e { - - - } 3 2 kIlk \ � - & ) } \ Ln & rt Lic = p - Pr _ a - @ & { \ ) � 0 2 " CL , F% Ll Z— y ; \§ & E 2) t }| �! ~ c R3 \ E ! �c E\ ; o _ G \§f\ƒ� Quarter i Year 41 fti i echnician ,/4� SM 2540 a-2011, 2540 0-2011 NCO025496 All weighings are done in grams Time Collected I Aq r/ Date Collected p�1b_ f � Date [Time In // Z3 Date 13ime Out Total Wet Wgt �1 v[J Z Z Dish 3 01 Wet Sludge Wgt l ! (103-105°C) Dried S 8 �� ` 7 � qg(7 �— Wgt�rp�t? Dish Dry Solids Wgt - (�� �, L t r✓ b 1 % Solids AVG % Solids r� / Time In1Out n c� Ilo / ��(103-105°C) Dried Wgt li'71 5�� 1rZ7 '� t Y LA" 561I 3 +acoo L{�.110�� 550°C Wt S b 0? L& ? t 2< 0 C w 2 1 P, -3 Volatile Solids Wgt %, Volatile Solids u ' f q � k— "" V 00 � . s1 1 AyG l 19 Volatile Solids E/.E AiE a , VS DAFSludge �i '- % VS Siud % Total Solids = Dry Solids Wgt x 100 Wet Solids Wgt % Volatile Solids (Volatile Solids Uilgt) X 100 Dried Solids Wgt % Reduction (VS DAF - VS Sludge) x 100 EE:: % VS DAF - (VS DAF)(VS Sludge) SECTION 6 Agricultural Lime Application Log Year: 2023 Project: Lincolnton Field (state -county -site -field) Soil pH Lime Requirement (from soil analysis) Tons/Acre Applied(CCE Eq.) Date Applied CA-48-10 LT-36-3 5.3 1.1 T/Ac 1 T/Ac 11 /13/23 LT-36-5 5.1 1.3T/Ac 1 T/Ac 11 /13/23 LT-47-2 6.1 O.OT/Ac O.OT/Ac LT-47-4 6.4 O.OT/Ac O.OT/Ac LT-47-5 6.0 O.OT/Ac O.OT/Ac LT-49-1 6.3 O.OT/Ac O.OT/Ac LT-49-2 5.7 .5T/Ac .5T/Ac * Lime is ordered waiting for Vendor to spread it SECTION 7 Page 1 of 1 Report Number: 24-017-0640 Account Number: 07778 Send To: Synagro/Alex Fox Alex Fox 284 Boger Rd Mocksville NC 27028 Waypoi nt(D - ANALYTICAL Farm: CA-48 "Every acre... Every year. "rM SOIL ANALYSIS REPORT Date Received: 01/17/2024 Date Of Analysis: 01/18/2024 Date Of Report: 01/18/2024 2850 Daisy Lane, Wilson, NC 27896 Main 252-206-1721 ° Fax 252-206-9973 www.waypointanalytical.com Grower: LINCOLNTON Analytical Method(s): Mehlich 3 Lime Index Humic Matter Loss On Ignition Water pH OM W/V ENR Phosphorus Potassium Magnesium Calcium Sodium pH Acidity C.E.0 Sample ID Lab Field ID Number % Soil Ibs/A M3 K Mg Ca Na Soil Buffer H Class ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate pH Index meq/100g meq/100g CA-48-10 13554 0.3 40 141 VH 161 H 97 L 1978 VH 13 VL 7.2 0.0 11.2 NC=117 NC=82 Percent Base Saturation Nitrate Sulfur Zinc Manganese Iron Copper Boron Soluble Salts Sample ID Field ID K Mg Ca Na H NO3 N S Zn Mn Fe Cu B SS % % % % % ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ms/cm Rate CA-48-10 3.7 7.2 88.3 0.5 0.0 11 L 15.3 VH 35 H 3.9 VH 0.5 L NC=23 NC=382.5 NC=219 NC=195.0 Values on this report represent the plant available nutrients in the soil. Rating after each value: VL (Very Low), L (Low), M (Medium) H (High), VH (Very High). ENR - Estimated Nitrogen Release. C.E.C. - Cation Exchange Capacity. Date Received: 01/17/2024 Date Of Report: 01 /18/2024 Explanation of symbols: % (percent), ppm (parts per million), Ibs/A This report applies to sample(s) tested. Samples are retained a (pounds per acre), ms/cm (milli -mhos per centimeter), meq/100g maximum of thirty days after testing. (milli -equivalent per 100 grams). Conversions: ppm x 2 = Ibs/A, Soluble by: Salts ms/cm x 640 = ppm. Analysis prepared by: Waypoint Analytical Carolina, Inc. SOIL FERTILITY RECOMMENDATIONS Nitrogen Phosphate Potash Magnesium Sulfur Zinc Manganese Iron Copper Boron Sample ID Intended Crop Yield Goal Lime N P20s K20 Mg S Zn Mn Fe Cu B Field ID bu Tons/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A CA-48-10 Corn 200 0.0 244 30 79 0 22 0 2 0 1.0 Comments: "The recommendations are based on research data and experience, but NO GUARANTEE or WARRANTY expressed or implied, concerning crop performance is made." Our reports and letters are for the exclusive and confidential use of our clients„ and may not be reproduced in whole or part, nor may any reference be made to the work,the results, or the company in any advertising, news release, or other public anouncements without obtaining our prior written authorization. Copy right 1977. NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/agronomi/ Report No. FY23-SL033723 k5i I"14'4+;4, Client: Alex Fox Advisor: Predictive Synagro 284 Boger Rd �- Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Links to Helpful Information Sampled: Received: 06/05/2023 Completed: 06/15/2023 Farm: Lt-36 Client ID: Sampled County : Lincoln 501947 Advisor ID: Sample ID: 3 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 1.1 120-200 0 0 0 0 0 0 0 0 Note: 12 2- Fescue/OGrass/Tim, M 0.0 120-200 0 0 0 0 0 0 0 0 Note: 12 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.51 1.01 7.9 75 2.0 5.3 271 94 54 15 64 187 129 129 404 404 351 0.2 3 Sample ID: 5 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 1.3 120-200 0 0 0 0 0 0 0 0 Note: 12 2- Fescue/OGrass/Tim, M 0.0 120-200 0 0 0 0 0 0 0 0 Note: 12 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.46 1.03 6.8 68 2.2 5.1 215 99 43 17 50 169 118 118 245 245 249 0.1 1 North Carolina Tai wLm Truk f and Ctwinlsskm Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/agronomi/ Report No. FY23-SLO33723 Alex Fox Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NOs-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft. If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.pov/apronomi/obpart4.htrntfsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-AI2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit www.ncagr.pov/agronomi/uyrst.htm NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/agronomi/ Report No. FY24-SL003602 k5i I"14'4+;4, Client: Alex Fox Advisor: Predictive Synagro 284 Boger Rd �- Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Links to Helpful Information Sampled: Received: 09/08/2023 Completed: 09/18/2023 Farm: Lt-47 Sampled County : Lincoln Client ID: 501947 Advisor ID: Sample ID: 2A Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 0 0 0 0 0 0 0 0 Note: 12 2- Fescue/OGrass/Tim, M 0.0 120-200 0 0 0 0 0 0 0 0 Note: 12 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.36 1.04 8.7 83 1.4 6.1 250 119 53 23 48 138 98 98 301 301 479 0.3 3 North Carolina Tai wLm Truk f and Ctwinlsskm Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/agronomi/ Report No. FY24-SL003602 Alex Fox Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NOs-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft. If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.pov/apronomi/obpart4.htrntfsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-AI2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit www.ncagr.pov/agronomi/uyrst.htm Page 1 of 2 Report Number: 24-002-0535 Account Number: 07778 Send To: Synagro/Alex Fox Alex Fox 284 Boger Rd Mocksville NC 27028 • Waypoint ANALYTICAL "Every acre... Every year. "rM 2850 Daisy Lane, Wilson, NC 27896 Main 252-206-1721 ° Fax 252-206-9973 www.waypointanalytical.com Grower: LINCOLNTON Farm: LT-47 SOIL ANALYSIS REPORT Analytical Method(s): Mehlich 3 Lime Index Humic Matter Loss On Ignition Water pH Date Received: 01/02/2024 Date Of Analysis: 01/03/2024 Date Of Report: 01/03/2024 OM W/V ENR Phosphorus Potassium Magnesium Calcium Sodium pH Acidity C.E.0 Sample ID Lab Field ID Number % Soil Ibs/A M3 K Mg Ca Na Soil Buffer H Class ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate pH Index meq/100g meq/100g 4 24257 0.6 52 146 VH 36 VL 221 VH 868 M 17 VL 6.4 0.9 7.3 NC=122 NC=18 5 24258 1.1 61 153 VH 83 L 174 H 939 M 27 VL 6.0 6.26 1.3 7.9 NC=127 NC=42 Percent Base Saturation Nitrate Sulfur Zinc Manganese Iron Copper Boron Soluble Salts Sample ID Field ID K Mg Ca Na H NO3 N S Zn Mn Fe Cu B SS % % % % % ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ms/cm Rate 4 1.3 25.2 59.5 1.0 13.7 11 L 13.9 VH 14 M 4.2 VH 0.6 M NC=23 NC=347.5 NC=88 NC=210.0 5 2.7 18.4 59.4 1.5 17.7 18 M 11.8 VH 7 L 2.4 H 0.6 M NC=37 NC=295.0 NC=44 NC=120.0 Values on this report represent the plant available nutrients in the Explanation of symbols: % (percent), ppm (parts per million), Ibs/A This report applies to sample(s) tested. Samples are retained a soil. Rating after each value: VL (Very Low), L (Low), M (Medium), (pounds per acre), ms/cm (milli -mhos per centimeter), meq/100g maximum of thirty days after testing. H (High), VH (Very High). ENR - Estimated Nitrogen Release. (milli -equivalent per 100 grams). Conversions: ppm x 2 = Ibs/A, Soluble by. C.E.C. - Cation Exchange Capacity. Salts ms/cm x 640 = ppm. Analysis prepared by: waypoint Analytical Carolina, Inc. Page 2 of 2 Report Number: 24-002-0535 Account Number: 07778 Send To: Synagro/Alex Fox Alex Fox 284 Boger Rd Mocksville NC 27028 Date Received: 01/02/2024 Date Of Report: 01 /03/2024 Waypoi nt(D - ANALYTICAL "Every acre... Every year. "rM Farm: LT-47 SOIL FERTILITY RECOMMENDATIONS 2850 Daisy Lane, Wilson, NC 27896 Main 252-206-1721 ° Fax 252-206-9973 www.waypointanalytical.com Grower: LINCOLNTON Nitrogen Phosphate Potash Magnesium Sulfur Zinc Manganese Iron Copper Boron Sample ID Intended Crop Yield Goal Lime N P205 K20 Mg S Zn Mn Fe Cu B Field ID Tons Tons/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A 4 Fescue Hay 4 0.0 200 0 250 0 10 0 4 0 0 5 Fescue Hay 4 0.8 200 0 250 0 9 0 4 0 0 Comments: "The recommendations are based on research data and experience, but NO GUARANTEE or WARRANTY expressed or implied, concerning crop performance is made." Our reports and letters are for the exclusive and confidential use of our clients„ and may not be reproduced in whole or part, nor may any reference be made to the work,the results, or the company in any advertising, news release, or other public anouncements without obtaining our prior written authorization. Copy right 1977. NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/agronomi/ Report No. FY23-SL033720 k5i I"14'4+;4, Client: Alex Fox Advisor: Predictive Synagro 284 Boger Rd �- Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Links to Helpful Information Sampled: Received: 06/05/2023 Completed: 06/15/2023 Farm: Lt-49+ Client ID: Sampled County : Lincoln 501947 Advisor ID: Sample ID: 1 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 50 80 0 0 0 0 0 0 Note: 12 2- Fescue/OGrass/Tim, M 0.0 120-200 50 80 0 0 0 0 0 0 Note: 12 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.36 1.08 9.2 90 0.9 6.3 37 31 63 25 26 84 63 63 68 68 87 0.1 1 Sample ID: 2 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.5 120-200 0 0 0 0 0 0 0 0 Note: 12 2- Fescue/OGrass/Tim, M 0.0 120-200 0 0 0 0 0 0 0 0 Note: 12 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.22 1.05 7.8 81 1.5 5.7 134 79 56 20 35 95 74 74 236 236 277 0.0 North Carolina Tai wLm Truk f and Ctwinlsskm Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/agronomi/ Report No. FY23-SLO33720 Alex Fox Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NOs-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft. If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.pov/apronomi/obpart4.htrntfsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-AI2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit www.ncagr.pov/agronomi/uyrst.htm