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Home My WebLink AboutWQ0014868_2023 Residual Annual Report_20240229 (2)Initial Review Reviewer nathaniel.thorn burg Is this submittal an application? (Excluding additional information.) * Yes No If not an application what is the submittal type?* Annual Report Residual Annual Report Additional Information Other Annual Report Year* 2023 Permit Number (IR) * W00014868 Applicant/Permittee Smithfield Fresh Meats Corp. Email Notifications Does this need review by the hydrogeologist? * Yes U No Regional Office Fayetteville CO Reviewer Admin Reviewer Wanda Gerald Submittal Form Project Contact Information Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence. Name* Brent Collins Email Address* brent.collins@emaresourcesinc.com Project Information ......................... Application/Document Type* New (Fee Required) Modification - Major (Fee Required) Renewal with Major Modification (Fee Required) Annual Report Additional Information Other Phone Number* 3363993646 Modification - Minor Renewal GW-59, NDMR, NDMLR, NDAR-1, N DAR-2 Residual Annual Report Change of Ownership We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type:* Wastewater Irrigation High -Rate Infiltration Other Wastewater Reclaimed Water Closed -Loop Recycle Residuals Single -Family Residence Wastewater Other Irrigation Permit Number:* WQ0014868 Has Current Existing permit number Applicant/Permittee Address* PO Box 99, Tarheel, NC 28392 Facility Name* Smithfield Fresh Meats Corp. Class B Residuals Program Please provide comments/notes on your current submittal below. At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here. (Application Form, Engineering Plans, Specifications, Calculations, Etc.) 2023 Smithfield Fresh Meats Annual Report - 8.18MB WQ0014868.pdf Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger than upload limit. * By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Mail payment to: NCDEQ — Division of Water Resources Attn: Non -Discharge Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Signature �r�rrt�ot�ly r Submission Date 2/29/2024 --Resources, Inc. Smithfield Fresh Meats Tar Heel Facility 2023 Annual Report Residuals Land Application Permit No. WQ0014868 Prepared By: EMA Resources, Inc. Phone 336975191441 — Fax 336975191442 755 Yadkinville Rd — Mocksville, NC 27028 February 27, 2024 DENR/Water Quality Section Non -Discharge Compliance Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: 2023 Annual Report — Smithfield Fresh Meats Corp. Treatment and Land Application of Residuals Permit No. WQ0014868 Dear Sir or Madam: Enclosed is the 2023 Annual Report for the above referenced land application permit. During 2023 EMA Resources, Inc. land applied 911.84 dry tons of wastewater residuals to 292.2 acres of private farmland. Please contact Brent Collins - Director of Technical Services if you have any further questions regarding this report. Sincerely, Z.-e4:241- Brent Collins Director of Technical Services brent.collins&emaresourcesinc.com Phone 336975191441 — Fax 336975191442 755 Yadkinville Rd — Mocksville, NC 27028 ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit#: WQ0014868 County: Bladen Year: 2023 Facility Name (as shown on permit): Land Application Operator: Smithfield Fresh Meats Corp. EMA Resources Inc. Phone: 336-751-1441 Land application of residuals as allowed by the permit occurred during the past calendar year? ® Yes ❑ No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A - Residuals Application Summary: Total number of application fields in thepermit: 37 Total number of fields utilized for land application during the year: 14 Total amount of dry tons applied during the year for all application sites: 911.84 Total number of acres utilizes for land application during the year: 292.2 Part B - Annual Compiance Statement: Facility was compliant during calendar year 2023 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Quality. ❑r Yes ❑ No If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1) Only residuals approved for this permit were applied to the permitted sites. 2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading Rates in 15A NCAC 02T .1105(b) (applicable to 40 CFR Part 503 regulated facilities). 7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8) All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as specified in the permit. 12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13) All buffer requirements as specified on the permit were maintained during each application of residuals. Part C - Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Andrea Tucker - Complex Plant Manager Permittee Name and Title (type or print) 02/21 /24 Dwayne (Feb 21, 202401:40 EST) Mina T ckei- 02/27/24 Andrea Tucker (Feb 27, 202410:34 EST) Signature of Permittee Z�fz Date 2/ 1 /2024 Signature of Preparer* Date Signature of Land Applier Date (if different from Permittee) (if different from Permittee and Preparer) * Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006) ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: Facility Name: Residual Source WQ # or NPDES #: WQ0014868 Laboratory: Smithfield Fresh Meats Corp. NCO078344 WWTP Name: Tarheel Plant WWTP Residual Analysis Data 1) 2) 3) 4) 5) Waypoint Analytical Parameter (mg/kg) Conc. Limit (mg/kg a Sample or Composite Date North 1/25/23 South 1/25/23 North 3/16/23 South 10/17/23 Additional Sample Percent Solids (%) NA 3.55 2.36 3.95 3.15 4.74 Arsenic 75 6.86 10 6.15 8.06 Cadmium 85 0.826 0.833 0.621 1.61 Copper 4,300 1530 463 1480 1310 Chromium NA 79.4 14.7 67.4 1 8.06 Lead 840 14.7 7.5 11.50 6.45 Mercury 57 0.191 0.27 0.554 0.694 Molybdenum 75 16.7 5.63 14.7 4.84 Nickel 420 68.9 22.2 61.8 6.26 Selenium 100 9.14 13.3 8.2 11.3 Zinc 7,500 3460 954 3380 137 Total Phosphorus NA 27500 6460 21500 2050 TKN NA 68900 129000 66200 66100 Ammonia -Nitrogen NA 18500 26700 9820 22100 Nitrate and Nitrite NA 140 200 25.6 89.7 a For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." ywa �cr,r 6evaynE Russ eb 1l, z:a4 ail ai EST] Signature of Preparer 02/21 /24 Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM RSSF (12/2006) ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ Permit Number: Facility Name: Smithfield Fresh Meats Corp. Residual Source NPDES # or WQ#: WWTP Name: Residual Analysis Data NCO078344 Tarheel Plant WWTP Laboratory: 1) Waypoint Analytical 2) 3) 4) 5) Parameter (mg/kg) Sample or Composite Date North 1/25/23 South 1/25/23 North 3/16/23 South 10/17/23 Additional Sample Aluminum 14100 2000 11300 233 Calcium 32000 5670 22600 1250 116000 Magnesium 2550 1580 2430 471 2410 pH 7.2 7.4 7.1 7.6 6.7 Potassium 5060 7670 4970 5260 Sodium 13500 19500 10100 12900 9810 PAN 19470 34010 16212 19940 SAR 3.67 9.04 3.38 13.96 1.70 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." �w� r�rr ovmvne auss Febn,z:R�ol:4u esrl Signature of Preparer *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) 02/21 /24 Date DENR FORM RSSF - B (12/2006) North 1 /25/23 mg/kg mg/L Equiv Weight Milli Equiv Sodium 13500 479.25 23 20.83696 Calcium 32000 1136 20 56.8 Magnesium 2550 90.525 12 7.54375 Percent Solids 3.55 SAR 3.67 SAR Na+ a (Ca2+ + M92+) 20.83696 0.5( 56.8 2 + 7.54375 2 ) North 3/16/23 mg/kg mg/L Equiv Weight Milli Equiv Sodium 10100 398.95 23 17.34565 Calcium 22600 892.7 20 44.635 Magnesium 2430 95.985 12 7.99875 Percent Solids 3.95 SAR 3.38 SAR Na+ a (Ca2+ + M92+) 17.34565 0.5( 44.635 2 + 7.99875 2 ) South 1 /25/23 mg/kg mg/L Equiv Weight Milli Equiv Sodium 19500 460.2 23 20.0087 Calcium 5670 133.812 20 6.6906 Magnesium 1580 37.288 12 3.107333 Percent Solids 2.36 SAR • 1. SAR Na+ a (Ca2+ + M92+) 20.00870 0.5( 6.6906 2 + 3.10733 2 ) South 10/17/23 mg/kg mg/L Equiv Weight Milli Equiv Sodium 12900 406.35 23 17.66739 Calcium 1250 39.375 20 1.96875 Magnesium 471 14.8365 12 1.236375 Percent Solids 3.15 SAR 13.96 SAR Na+ a (Ca2+ + M92+) 17.66739 0.5( 1.9688 2 + 1.23638 2 ) Additional Sample mg/kg mg/L Equiv Weight Milli Equiv Sodium 9810 464.994 23 20.21713 Calcium 116000 5498.4 20 274.92 Magnesium 2410 114.234 12 9.5195 Percent Solids 4.74 SAR 1.70 SAR Na+ a (Ca2+ + M92+) 20.21713 0.5( 274.92 2 + 9.51950 2 ) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Smithfield Farmland Corp. Total Dry Tons Applied (Annual): WQ0014868 Cation Exchange Capacity (non 503 only): Steve Dunham Owner: Steve Dunham Predominant Soil Series: 21.6 Acres Permitted: 21.6 Site #: SF03 Field # 42.68 LaB 1 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date Total Phos- phorus Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 11 21 3 4 5j 6j 7j 81 9 10 ill 12 DT/Ac./ App. .fir Event 1.98 Arsenic 0.026 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.026 Cadmium 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Copper 5.948 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 5.948 Chromium 0.290 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.290 Lead 0.052 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.052 Mercury 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 Molyb- 0.062 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.062 denum Nickel 0.258 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.258 Selenium 0.034 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.034 Zinc 13.516 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 13.516 Total Phos- 96.824 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 96.824 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4;�r- 2/l/2024 Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Smithfield Farmland Corp Land Owner: Steve Dunham Operator: Steve Dunham Crop 1 Name: Bermuda -Pasture WQ Permit #: WQ0014868 Field #: Annual Dry Tons Applied: 42.68 Site #: Predominant Soil Series: LaB Crop 1 Max. PAN: 110.25 Crop 2 Name: Acres Utilized: SF03 Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 21.6 21.6 0 o � N Q Volume applied enter one Solids/ ) Liquid Cu. Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a �a F w *o• o ,•d �, # w •, * N *� TKN mg/kg Z ; o M o mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 2/7 104000 3.75 0.753 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 26.865 NA Bermuda 2/8 169000 3.75 1.223 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 43.656 NA Bermuda 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 273000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 70.521 o.000 Lime Applied Annuallbs/acre 0.026 0.003 5.948 0.290 0.052 0.001 0.062 0.258 0.034 13.516 96.824 Date lbs/ac Prior Years Cumulative lbs/ac 0.316 0.099 46.756 2.64 0.703 0.023 1.312 3.891 0.422 182.213 Current Cumulative lbs/ac 0.342 0.102 52.704 2.930 0.755 0.024 1.374 4.149 0.456 195.729 Permitted C. P. L. R.**** 9 250 1 1000 1 250 500 Permit PAN Limit lst/2nd Crop i F 110.25 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 2/l/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Smithfield Fresh Meats Total Dry Tons Applied (Annual): 90.01 Permit #: WQ0014868 Cation Exchange Capacity (non 503 only): 8.3 Operator: Steve Dunham Owner: Steve Dunham Predominant Soil Series: Cc Acres Used: 13.3 Acres Permitted: 13.3 Site #: SF03 Field #: 2 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Sample or Com- posite Date 1 LCF 3/16/23 2 Spring Avg 3 10/17/23 4 5 6 7 8 9 10 11 12 % Solids 4.8 3.75 3.15 Arsenic 5.25 6.51 8.06 Cadmium 0.417 0.72 1.61 Copper 32.7 1505 1310 Chromium 22.1 73.4 8.06 Lead 14.7 13.1 6.45 Mercury 0.479 0.37 0.694 Molyb- denum 4.96 15.7 4.84 Nickel 11.7 65.35 6.26 Selenium 6.67 8.68 11.3 Zinc 111 3420 137 Total Phos- horus 1760 24500 2050 Annual Heavv Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 5j 6j 7j 81 9 10 11 1 12 DT/Ac./ App. .fir Event 2.64 2.52 1.61 Arsenic 1 0.028 0.033 0.026 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.086 Cadmium 0.002 0.004 0.005 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.011 Copper 0.173 7.591 4.205 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 11.969 Chromium 0.117 0.370 0.026 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.513 Lead 0.078 0.066 0.021 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.164 Mercury 0.003 0.002 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.007 Molyb- 0.026 0.079 0.016 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.121 denum Nickel 0.062 0.330 0.020 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.412 Selenium 0.035 0.044 0.036 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.115 Zinc 0.586 17.250 0.440 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 18.277 Total Phos- 9.296 123.578 6.581 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 139.455 horus "I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4; 2/l/2024 Signature of Land Applier Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Smithfield Fresh Meats Steve Dunham Operator: Steve Dunham Crop 1 Name: Rye Grass - Pasture WQ Permit #: WQ0014868 Field #: Annual Dry Tons Applied: 90.01 Site #: Predominant Soil Series: Ce Crop 1 Max. PAN: 168.75 Crop 2 Name: 2 SF03 Acres Utilized: Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 13.3 13.3 N Q Volume applied enter one Solids/ ( ) Liquid Cu. Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a F ,'tea c� w *o• o ,•d �, # 4 w •, * N *� TKN mg/kg Z o 8 M o mg/kg Nitrate and Nitrite mg/kg PAN Applied (lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 3/1 175500 4.8 2.641 Lower Cape Fear Dry <.5" S 0.5 0.4 1 2230 1390 20.8 5.556 NA Rye 3/7 84500 3.75 0.994 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 35.450 NA Rye 3/8 130000 3.75 1.528 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 54.539 NA Rye 11/2 104000 3.15 1.027 Tarheel WWTP Dry <.5" S 0.5 0.2 66100 22100 89.7 40.962 NA Rye 11/3 1 58500 3.15 0.578 Tarheel WWTP Dry <.5" S 0.5 0.2 66100 22100 1 89.7 23.041 NA Rye 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 552500 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 159,547F 0.000 Lime Applied Annuallbs/acre 0.086 0.011 11.969 0.513 0.164 0.007 0.121 0.412 0.115 18.277 139.455 Date lbs/ac Prior Years Cumulative lbs/ac 0.551 0.122 55.002 2.679 0.976 0.03 1.351 4.604 0.657 194.745 Current Cumulative lbs/ac 0.637 1 0.133 66.971 3.192 1.140 0.037 1.472 5.016 0.772 213.022 Permitted C. P. L. R.****1 9 1 250 1000 250 500 Permit PAN Limit lst/2nd Crop 1 1 168.75 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 2/1/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Smithfield Farmland Corp. Total Dry Tons Applied (Annual): WQ0014868 Cation Exchange Capacity (non 503 only): Steve Dunham Owner: Steve Dunham Predominant Soil Series: 21.3 Acres Permitted: 21.3 Site #: SF03 Field # 93.85 Cc 3 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date •. Total Phos- phor -us Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 11 2 1 3 4 5j 6j 7j 81 9 10 11 1 12 DT/Ac./ App. .fir Event 2.69 1.72 Arsenic 0.028 0.022 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.051 Cadmium 0.002 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 Copper 0.176 5.171 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 5.347 Chromium 0.119 0.252 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.371 Lead 0.079 0.045 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.124 Mercury 0.003 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Molyb- 0.027 0.054 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.081 denum Nickel 0.063 0.225 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.287 Selenium 0.036 0.030 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.066 Zinc 0.597 11.751 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 12.348 Total Phos- 9.462 84.182 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 93.644 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4;�r- 2/l/2024 Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Smithfield Farmland Corp Land Owner: Steve Dunham Operator: Steve Dunham Crop 1 Name: Rye Grass -Pasture WQ Permit #: WQ0014868 Field #: Annual Dry Tons Applied: 93.85 Site #: Predominant Soil Series: Ce Crop 1 Max. PAN: 168.75 Crop 2 Name: Acres Utilized: SF03 Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 21.3 21.3 0 o � N Q Volume applied enter one Solids/ ( ) Liquid Cu. Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a �a F w *o• o ,•d �, # w •, * N *� TKN mg/kg Z ; o M o mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 2/27 123500 4.8 1.161 Lower Cape Fear Dry <.5" S 0.5 0.4 2230 1390 1 20.8 2.441 NA Rye 2/28 117000 4.8 1.099 Lower Cape Fear Dry <.5" S 0.5 0.4 2230 1390 20.8 2.313 NA Rye 3/1 45500 4.8 0.428 Lower Cape Fear Dry <.5" S 0.5 0.4 2230 1390 20.8 0.899 NA Rye 3/8 78000 3.75 0.573 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 20.433 NA Rye 3/9 156000 3.75 1.145 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 40.865 NA Rye 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 0 520000 As Cd Cu Cr Pb H Mo Ni Se Zn P 66.952 0.00o Lime A lied Annuallbs/acre 0.051 0.005 5.347 0.371 0.124 0.004 0.081 0.287 0.066 12.348 93.644 Date lbs/ac Prior Years Cumulative lbs/ac 0.516 0.122 48.643 2.267 0.817 0.022 1.127 3.772 0.618 168.409 Current Cumulative lbs/ac 0.567 0.127 53.990 2.638 0.941 0.026 1.208 4.059 0.684 180.757 Permitted C. P. L. R.**** 1 9 1 250 1 1 1000 1 1 1 250 1 1 500 Permit PAN Limit lst/2nd Crop 168.75 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 2/1/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Smithfield Farmland Corp. Total Dry Tons Applied (Annual): 23.58 Permit #: WQ0014868 Cation Exchange Capacity (non 503 only): 7.8 Operator: Steve Dunham Owner: Steve Dunham Predominant Soil Series: LaB Acres Used: 8 Acres Permitted: 8 Site #: SF03 Field #: 5 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Sample or Com- posite Date 1 LCF 3/16/23 2 Spring Avg 3 10/17/23 4 5 6 7 8 9 10 11 12 % Solids 4.8 3.75 3.15 Arsenic 5.25 6.51 8.06 Cadmium 0.417 0.72 1.61 Copper 32.7 1505 1310 Chromium 22.1 73.4 8.06 Lead 14.7 13.1 6.45 Mercury 0.479 0.37 0.694 Molyb- denum 4.96 15.7 4.84 Nickel 11.7 65.35 6.26 Selenium 6.67 8.68 11.3 Zinc 111 3420 137 Total Phos- horus 1760 24500 2050 Annual Heavv Metal Field Loadings (Calculated in lbs/acre): Total 1J 2 1 3 4 5j 6j 7 8 9 10 11 12 DT/Ac./ App. .fir Event 0.49 2.03 0.43 Arsenic 0.005 0.026 0.007 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.038 Cadmium 0.000 0.003 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 Copper 0.032 6.119 1.119 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 7.270 Chromium 0.022 0.298 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.327 Lead 0.014 0.053 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.073 Mercury 0.000 0.002 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Molyb- 0.005 0.064 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.073 denum Nickel 0.011 0.266 0.005 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.282 Selenium 0.007 0.035 0.010 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.051 Zinc 0.108 13.906 0.117 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 14.131 Total Phos- 1.718 99.617 1.751 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 103.085 horus "I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4; 2/l/2024 Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Smithfield Farmland Corp Land Owner: Steve Dunham Operator: Steve Dunham Crop 1 Name: Rye Grass -Hay WQ Permit #: WQ0014868 Field #: Annual Dry Tons Applied: 23.58 Site #: Predominant Soil Series: LaB Crop 1 Max. PAN: 196 Crop 2 Name: Acres Utilized: SF03 Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: Q Volume applied enter one Solids/ ( ) Liquid Cu. Yds Gallons o /o Solids Volume A hed er pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. Wet, Wet, Moist) Precip. Past 24 Ms. inches a 4 � F w o ,•d # 4 w , * N TKN mg/kg Z ; o M o 5• mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 3/1 1 19500 1 4.8 0.488 Lower Cape Fear Dry <.5" S 0.5 1 0.4 2230 1390 1 20.8 1.026 NA Rye 3/7 104000 3.75 2.033 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 72.536 NA Rye 11/3 26000 3.15 0.427 Tarheel WWTP Dry <.5" S 0.5 0.2 66100 22100 89.7 17.025 NA Rye 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 149500 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 90.587 0.000 Lime Applied Annuallbs/acre 0.038 0.005 7.270 0.327 0.073 0.003 0.073 0.282 0.051 14.131 103.085 Date lbs/ac Prior Years Cumulative lbs/ac 0.396 0.095 36.765 1.94 0.555 0.017 0.856 2.762 0.482 128.525 Current Cumulative lbs/ac 0.434 0.100 44.035 2.267 0.628 0.020 0.929 3.044 0.533 142.656 Permitted C. P. L. R. * * * * 9 1 250 1 1 1000 1 1 1 250 1 1 500 Permit PAN Limit lst/2nd Crop I 196 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 2/1/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Smithfield Farmland Corp. Total Dry Tons Applied (Annual): 75.95 Permit #: WQ0014868 Cation Exchange Capacity (non 503 only): 4.9 Operator: Steve Dunham Owner: Steve & John Dunham Predominant Soil Series: LaB Acres Used: 16.5 Acres Permitted: 16.5 Site #: SF03 Field #: 6 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date •. Total Phos- phorus Annual Heavv Metal Field Loadings (Calculated in lbs/acre): Total 11 2 1 3 4 5j 6j 7j 81 9 10 11 1 12 DT/Ac./ App. .fir Event 2.90 1.71 Arsenic 0.038 0.028 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.065 Cadmium 0.004 0.005 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.010 Copper 8.714 4.475 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 13.189 Chromium 0.425 0.028 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.453 Lead 0.076 0.022 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.098 Mercury 0.002 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 Molyb- 0.091 0.017 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.107 denum Nickel 0.378 0.021 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 1 0.400 Selenium 0.050 0.039 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.089 Zinc 19.802 0.468 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 20.270 Total Phos- 141.855 7.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 horus L48.8581 "I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4; 2/l/2024 Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Smithfield Farmland Corp Land Owner: Steve & John Dunham Operator: Steve Dunham Crop 1 Name: Bermuda -Hay WQ Permit #: WQ0014868 Field #: Annual Dry Tons Applied: 75.95 Site #: Predominant Soil Series: LaB Crop 1 Max. PAN: 196 Crop 2 Name: 6 SF03 Acres Utilized: Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 16.5 16.5 o � N Q Volume applied enter one Solids/ ( ) Liquid Cu. Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a �a F w *o• o ,•d �, # - w •, * N *� TKN mg/kg Z ; o M o mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 2/8 52000 3.75 0.493 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 17.585 NA Bermuda 2/9 175500 3.75 1.663 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 59.348 NA Bermuda 2/14 78000 3.75 0.739 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 26.377 NA Bermuda 10/30 52000 3.15 0.414 Tarheel WWTP Dry <.5" S 0.5 0.2 66100 22100 89.7 16.509 NA Bermuda 10/31 1 130000 3.15 1.035 Tarheel WWTP Dry <.5" S 0.5 0.2 66100 22100 89.7 41.272 NA Bermuda 11/1 32500 3.15 0.259 Tarheel WWTP Dry <.5" S 0.5 0.2 66100 22100 89.7 10.318 NA Bermuda 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 520000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 1n.4oS o.000 Lime Applied Annuallbs/acre 0.065 0.010 13.189 0.453 0.098 0.005 0.107 0.400 0.089 20.270 148.858 Date lbs/ac Prior Years Cumulative lbs/ac 0.308 0.085 35.623 1.929 0.599 0.019 1.065 3.23 0.396 147.36 Current Cumulative lbs/ac 0.373 1 0.095 48.812 2.382 0.697 0.024 1.172 3.630 0.485 167.630 Permitted C. P. L. R.**** 1 9 1 250 1 1 1000 1 1 1 250 1 1 500 Permit PAN Limit lst/2nd Crop I I 196 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 2/1/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Smithfield Farmland Corp. Total Dry Tons Applied (Annual): WQ0014868 Cation Exchange Capacity (non 503 only): Steve Dunham Owner: Steve Dunham Predominant Soil Series: 37.2 Acres Permitted: 37.2 Site #: SF03 Field # 155.83 WmB 7 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date •. Total Phos- phorus Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 11 2 1 3 4 5j 6j 7j 81 9 10 11 1 12 DT/Ac./ App. .fir Event 2.08 2.11 Arsenic 0.027 0.034 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.061 Cadmium 0.003 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.010 Copper 6.252 5.533 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 11.785 Chromium 0.305 0.034 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.339 Lead 0.054 0.027 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.082 Mercury 0.002 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Molyb- 0.065 0.020 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.086 denum Nickel 0.271 0.026 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.298 Selenium 0.036 0.048 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.084 Zinc 14.207 0.579 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 14.785 Total Phos- 101.773 8.659 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 110.432 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4;�r- 2/l/2024 Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Smithfield Farmland Corp Land Owner: Steve Dunham Operator: Steve Dunham Crop 1 Name: Rye Grass - Hay WQ Permit #: WQ0014868 Field #: Annual Dry Tons Applied: 155.83 Site #: Predominant Soil Series: WmB Crop 1 Max. PAN: 210 Crop 2 Name: Acres Utilized: SF03 Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 37.2 37.2 Q Volume applied enter one Solids/ ( ) Liquid Cu. Yds Gallons o /o Solids Volume A hed er pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a 4 � F w *o• o ,•d 2 # 4 w , * N *� TKN mg/kg Z ; o oa o �• mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 2/20 136500 3.75 0.574 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 1 82.8 20.474 NA Rye 2/21 156000 3.75 0.656 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 23.399 NA Rye 2/22 136500 3.75 0.574 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 20.474 NA Rye 2/23 65000 3.75 0.273 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 9.749 NA Rye 10/19 110500 3.15 0.390 Tarheel WWTP Dry <.5" S 0.5 0.2 66100 22100 89.7 15.560 NA Rye 10/20 58500 3.15 0.207 Tarheel WWTP Dry <.5" S 0.5 0.2 66100 22100 1 89.7 8.238 NA Rye 10/23 143000 3.15 0.505 Tarheel WWTP Dry <.5" S 0.5 0.2 66100 22100 89.7 20.137 NA Rye 10/24 201500 3.15 0.712 Tarheel WWTP Dry <.5" S 0.5 0.2 66100 22100 89.7 28.374 NA Rye 10/25 84500 3.15 1 0.298 Tarheel WWTP Dry <.5" S 0.5 0.2 1 66100 22100 89.7 11.899 NA Rye 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 0 1092000 As Cd Cu Cr Pb H Mo Ni Se Zn P 158,304 0.00o Lime A lied Annuallbs/acre 0.061 0.010 11.785 0.339 0.082 0.004 0.086 0.298 0.084 14.785 110.432 Date lbs/ac Prior Years Cumulative lbs/ac 0.156 0.062 34.531 4.057 0.747 0.014 0.811 3.001 0.217 131.294 Current Cumulative lbs/ac 0.217 1 0.072 46.316 4.396 0.829 0.018 0.897 3.299 0.301 146.079 Permitted C. P. L. R.**** 1 9 1 250 1 1 1000 1 1 1 250 1 1 500 Permit PAN Limit lst/2nd Crop 210 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 2/1/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Smithfield Farmland Corp. Total Dry Tons Applied (Annual): Permit #: WQ0014868 Cation Exchange Capacity (non 503 only): Operator: Vance Tyson Owner: Vance Tyson Predominant Soil Series: Acres Used: 77 Acres Permitted: 77 Site #: SF06 Field #: 180.95 5.3 De 7 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date Total Phos- phorus Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 11 2 1 3 4 5j 6j 7j 81 9 10 11 1 12 DT/Ac./ App. .fir Event 2.35 Arsenic 0.031 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.031 Cadmium 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Copper 7.074 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 7.074 Chromium 0.345 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.345 Lead 0.062 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.062 Mercury 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molyb- 0.074 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.074 denum Nickel 0.307 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.307 Selenium 0.041 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.041 Zinc 16.074 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 16.074 Total Phos- 115.150 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 115.150 horus 1 1 1 1 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4;�r- 2/l/2024 Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Smithfield Farmland Corp Land Owner: Vance Tyson Operator: Vance Tyson Crop 1 Name: Soybeans WQ Permit #: WQ0014868 Field #: Annual Dry Tons Applied: 180.95 Site #: Predominant Soil Series: De Crop 1 Max. PAN: 156 Crop 2 Name: Acres Utilized: SF06 Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 77 77 N Q Volume applied enter one Solids/ ( ) Liquid Cu_ Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a F ,'tea c� w *o• o ,•d �, # 4 w •, * N *� TKN mg/kg Z 8 o oa o �• mg/kg Nitrate and Nitrite mg/kg PAN Applied (lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 3/20 182000 3.75 0.370 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 1 82.8 13.188 NA Beans 3/21 182000 3.75 0.370 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 13.188 NA Beans 3/22 143000 3.75 0.290 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 10.362 NA Beans 3/23 175500 3.75 0.356 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 12.717 NA Beans 3/24 169000 3.75 0.343 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 12.246 NA Beans 3/25 52000 3.75 0.106 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 1 82.8 3.768 NA Beans 3/31 169000 3.75 0.343 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 12.246 1 NA Beans 4/1 84500 3.75 0.172 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 6.123 NA Beans 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 1157000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 87841 0.000 Lime Applied Annuallbs/acre 0.031 0.003 7.074 0.345 0.062 0.002 0.074 0.307 0.041 16.074 115.150 Date lbs/ac Prior Years Cumulative lbs/ac 0.071 0.017 8.897 0.743 0.131 0.003 0.198 0.677 0.096 29.67 Current Cumulative lbs/ac 0.102 1 0.020 15.971 1.088 0.193 0.005 0.272 0.984 0.137 45.744 Permitted C. P. L. R.**** 9 1 250 1 1 1000 1 1 1 250 1 1 500 Permit PAN Limit lst/2nd Crop 1 156 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 2/1/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Smithfield Farmland Corp. Total Dry Tons Applied (Annual): WQ0014868 Cation Exchange Capacity (non 503 only): Steve Dunham Owner: JW Burney Predominant Soil Series: 21.8 Acres Permitted: 21.8 Site #: SF07 Field #: 85.83 Aa 1 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Sample or Com- posite Date 1 Spring Avg 2 10/17/23 3 4 5 6 7 j 8 9 j 10 J 11 12 % Solids 3.75 3.15 Arsenic 6.51 8.06 Cadmium 0.72 1.61 Copper 1505 1310 Chromium 73.4 8.06 Lead 13.1 6.45 Mercury 0.37 0.694 Molyb- denum 15.7 4.84 Nickel 65.35 6.26 Selenium 8.68 11.3 Zinc 3420 137 Total Phos- horus 24500 2050 Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 5j 6j 7 8 9 10 11 12 DT/Ac./ App. .fir Event 2.33 1.61 Arsenic 0.030 0.026 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 1 0.000 0.000 0.000 0.056 Cadmium 0.003 0.005 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.009 Copper 7.016 4.208 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 11.224 Chromium 0.342 0.026 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.368 Lead 0.061 0.021 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.082 Mercury 0.002 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Molyb- 0.073 0.016 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.089 denum Nickel 0.305 0.020 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.325 Selenium 0.040 0.036 0.000 1 0.000 0.000 0.000 1 0.000 0.000 0.000 1 0.000 0.000 0.000 0.077 Zinc 15.944 0.440 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 16.384 Total Phos- 114.219 6.585 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 120.804 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4;�r- 2/l/2024 Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Smithfield Farmland Corp Land Owner: JW Burney Operator: Steve Dunham Crop 1 Name: Rye Grass - Hay WQ Permit #: WQ0014868 Field #: Annual Dry Tons Applied: 85.83 Site #: Predominant Soil Series: Aa Crop 1 Max. PAN: 207 Crop 2 Name: Acres Utilized: SF07 Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 21.8 21.8 0 Q Volume applied enter one Solids/ ( ) Liquid Cu. Yds Gallons o /o Solids Volume A hed er pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a 4 � F w *o• o ,•d 2 # 4 w , * N *� TKN mg/kg Z ; o oa o �• mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 3/2 97500 3.75 0.699 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 1 82.8 24.955 NA Rye 3/3 130000 3.75 0.933 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 33.274 NA Rye 3/4 71500 3.75 0.513 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 18.300 NA Rye 3/6 26000 3.75 0.187 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 6.655 NA Rye 10/16 71500 3.15 0.431 Tarheel WWTP Dry <.5" S 0.5 0.2 66100 22100 89.7 17.181 NA Rye 10/17 162500 3.15 0.979 Tarheel WWTP Dry <.5" S 0.5 0.2 66100 1 22100 89.7 39.047 NA Rye 10/19 32500 3.15 0.196 Tarheel WWTP Dry <.5" S 0.5 0.2 66100 22100 89.7 7.809 NA Rye 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 591500 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 147,2211 0.000 Lime Applied Annuallbs/acre 0.056 0.009 11.224 0.368 0.082 0.004 0.089 0.325 0.077 16.384 120.804 Date lbs/ac Prior Years Cumulative lbs/ac 0.314 0.248 108.309 1.793 1.42 0.023 1.244 2.954 0.455 318.5 Current Cumulative lbs/ac 0.370 1 0.257 119.533 2.161 1.502 0.027 1.333 3.279 0.532 334.884 Permitted C. P. L. R.**** 1 9 1 250 1 1 1000 1 1 1 250 1 1 500 Permit PAN Limit lst/2nd Crop 207 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 2/1/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Smithfield Farmland Corp. Total Dry Tons Applied (Annual): WQ0014868 Cation Exchange Capacity (non 503 only): Steve Dunham Owner: JW Burney Predominant Soil Series: 12.3 Acres Permitted: 12.3 Site #: SF07 Field #: 45.90 Aa 3 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date •. Total Phos- phorus Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 11 2 1 3 4 5j 6j 7j 81 9 10 11 1 12 DT/Ac./ App. .fir Event 2.07 1.67 Arsenic 0.027 0.027 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.054 Cadmium 0.003 0.005 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.008 Copper 6.219 4.365 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 10.584 Chromium 0.303 0.027 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.330 Lead 0.054 0.021 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.076 Mercury 0.002 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Molyb- 0.065 0.016 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.081 denum Nickel 0.270 0.021 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.291 Selenium 0.036 0.038 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.074 Zinc 14.131 0.456 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 14.588 Total Phos- 101.234 6.831 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 108.065 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4;�r- 2/l/2024 Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Smithfield Farmland Corp Land Owner: JW Burney Operator: Steve Dunham Crop 1 Name: Rye Grass - Pasture WQ Permit #: WQ0014868 Field #: Annual Dry Tons Applied: 45.90 Site #: Predominant Soil Series: Aa Crop 1 Max. PAN: 155.25 Crop 2 Name: Acres Utilized: SF07 Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 12.3 12.3 Q Volume applied enter one Solids/ ( ) Liquid Cu. Yds Gallons o /o Solids Volume A hed er pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a 4 � F w *o• o ,•d 2 # 4 w , * N *� TKN mg/kg Z ; o oa o �• mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 3/4 45500 3.75 0.578 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 1 82.8 20.640 NA Rye 3/6 117000 3.75 1.487 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 53.075 NA Rye 10/18 143000 3.15 1.527 Tarheel WWTP Dry <.5" S 0.5 0.2 66100 22100 89.7 60.901 NA Rye 10/19 13000 3.15 0.139 Tarheel WWTP Dry <.5" S 0.5 0.2 66100 22100 89.7 5.536 NA Rye 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 318500 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 140-153T 0.000 Lime Applied Annuallbs/acre 0.054 0.008 10.584 0.330 0.076 0.004 0.081 0.291 0.074 14.588 108.065 Date lbs/ac Prior Years Cumulative lbs/ac 0.1 0.037 18.898 2.71 0.565 0.01 0.587 1.988 0.16 93.884 Current Cumulative lbs/ac 0.154 1 0.045 29.482 3.040 0.641 0.014 0.668 2.279 0.234 108.472 Permitted C. P. L. R. * * * * 9 1 250 1 1 1000 1 1 1 250 1 1 500 Permit PAN Limit lst/2nd Crop 155.25 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 2/1/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Smithfield Farmland Corp. Total Dry Tons Applied (Annual): WQ0014868 Cation Exchange Capacity (non 503 only): Steve Dunham Owner: JW Burney Predominant Soil Series: 19.3 Acres Permitted: 19.3 Site #: SF07 Field #: 77.01 WmB 6 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date •. Total Phos- phorus Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 11 2 1 3 4 5j 6j 7j 81 9 10 11 1 12 DT/Ac./ App. .fir Event 2.27 1.73 Arsenic 0.029 0.028 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.057 Cadmium 0.003 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.009 Copper 6.818 4.520 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 11.337 Chromium 0.333 0.028 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.360 Lead 0.059 0.022 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.082 Mercury 0.002 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Molyb- 0.071 0.017 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.088 denum Nickel 0.296 0.022 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.318 Selenium 0.039 0.039 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.078 Zinc 15.493 0.473 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 15.965 Total Phos- 110.985 7.073 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 118.058 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4;�r- 2/l/2024 Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Smithfield Farmland Corp Land Owner: JW Burney Operator: Steve Dunham Crop 1 Name: Rye Grass - Hay WQ Permit #: WQ0014868 Field #: Annual Dry Tons Applied: 77.01 Site #: Predominant Soil Series: WmB Crop 1 Max. PAN: 220 Crop 2 Name: 6 SF07 Acres Utilized: Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 19.3 19.3 0 N Q Volume applied enter one Solids/ ( ) Liquid Cu. Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) precip. Past 24 Ms. inches a F ,'tea c� w *o• o ,•d �, # w •, * N *� TKN mg/kg Z 8 o M o mg/kg Nitrate and Nitrite mg/kg PAN Applied (lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 2/18 45500 3.75 0.369 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 13.154 NA Bermuda 2/19 110500 3.75 0.895 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 31.946 NA Bermuda 2/23 97500 3.75 0.790 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 28.188 NA Bermuda 2/24 26000 3.75 0.211 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 7.517 NA Bermuda 10/25 1 117000 3.15 0.796 Tarheel WWTP Dry <.5" S 0.5 0.2 66100 22100 89.7 31.756 NA Bermuda 10/26 136500 3.15 0.929 Tarheel WWTP Dry <.5" S 0.5 1 0.2 66100 22100 89.7 37.048 NA Bermuda 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 533000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 149,60 00.000 Lime Applied Annuallbs/acre 0.057 0.009 11.337 0.360 0.082 0.004 0.088 0.318 0.078 15.965 118.058 Date lbs/ac Prior Years Cumulative lbs/ac 0.413 0.267 119.476 6.947 1.981 0.032 1.826 15.486 0.549 399.536 Current Cumulative lbs/ac 0.470 0.276 130.813 7.307 2.063 0.036 1.914 15.804 0.627 415.501 Permitted C. P. L. R.****1 9 1 250 1 1 1000 1 1 1 250 1 1 500 Permit PAN Limit lst/2nd Crop 220 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 2/1/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Smithfield Farmland Corp. Total Dry Tons Applied (Annual): WQ0014868 Cation Exchange Capacity (non 503 only): Steve Dunham Owner: JW Burney Predominant Soil Series: 12.1 Acres Permitted: 12.1 Site #: SF07 Field #: 46.43 Aa 8 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date •. Total Phos- phorus Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 11 21 3 4 5j 6j 7j 81 9 10 ill 12 DT/Ac./ App. .fir Event 1.93 1.91 Arsenic 0.025 0.031 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.056 Cadmium 0.003 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.009 Copper 5.815 4.991 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 10.806 Chromium 0.284 0.031 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.314 Lead 0.051 0.025 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.075 Mercury 0.001 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Molyb- 0.061 0.018 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.079 denum Nickel 0.253 0.024 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.276 Selenium 0.034 0.043 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.077 Zinc 13.215 0.522 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 13.737 Total Phos- 94.668 7.811 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 102.479 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4;�r- 2/l/2024 Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Smithfield Farmland Corp Land Owner: JW Burney Operator: Steve Dunham Crop 1 Name: Bermuda -Pasture WQ Permit #: WQ0014868 Field #: Annual Dry Tons Applied: 46.43 Site #: Predominant Soil Series: Aa Crop 1 Max. PAN: 155 Crop 2 Name: Acres Utilized: SF07 Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 12.1 12.1 o � N Q Volume applied enter one Solids/ ( ) Liquid Cu. Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a �a F w *o• o ,•d �, # - w •, * N *� TKN mg/kg Z ; o M o mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 2/17 65000 3.75 0.840 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 29.974 NA Bermuda 2/18 84500 3.75 1.092 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 38.966 NA Bermuda 10/26 91000 3.15 0.988 Tarheel WWTP Dry <.5" S 0.5 0.2 66100 22100 89.7 39.396 NA Bermuda 10/27 84500 3.15 0.917 Tarheel WWTP Dry <.5" S 0.5 0.2 66100 22100 89.7 36.582 NA Bermuda 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 325000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 144.917 o.000 Lime Applied Annuallbs/acre 0.056 0.009 10.806 0.314 0.075 0.004 0.079 0.276 0.077 13.737 102.479 Date lbs/ac Prior Years Cumulative lbs/ac 0.301 0.084 40.579 4.857 0.83 0.021 1.135 3.296 0.415 151.222 Current Cumulative lbs/ac 0.357 0.093 51.385 5.171 0.905 0.025 1.214 3.572 0.492 164.959 Permitted C. P. L. R.**** 9 250 1 1000 1 250 500 Permit PAN Limit lst/2nd Crop i Fl-55 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 2/1/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Smithfield Farmland Corp. Total Dry Tons Applied (Annual): 60.62 Permit #: WQ0014868 Cation Exchange Capacity (non 503 only): Operator: Richard Dunham Owner: Bonnie Meeker Predominant Soil Series: WmB Acres Used: 21.3 Acres Permitted: 21.3 Site #: SF07 Field #: 9 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date •. Total Phos- phorus Annual Heavv Metal Field Loadings (Calculated in lbs/acre): Total 11 2 1 3 4 5j 6j 7j 81 9 10 11 1 12 DT/Ac./ App. .fir Event 2.00 0.84 Arsenic 0.026 0.014 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.040 Cadmium 0.003 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.006 Copper 6.032 2.206 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 8.238 Chromium 0.294 0.014 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.308 Lead 0.053 0.011 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.063 Mercury 0.001 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Molyb- 0.063 0.008 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.071 denum Nickel 0.262 0.011 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 1 0.272 Selenium 0.035 0.019 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.054 Zinc 13.707 0.231 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 13.938 Total Phos- 98.196 3.452 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 horus L01.6481 "I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4; 2/l/2024 Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Smithfield Farmland Corp Land Owner: Bonnie Meeker Operator: Richard Dunham Crop 1 Name: Bermuda -Hay WQ Permit #: WQ0014868 Field #: Annual Dry Tons Applied: 60.62 Site #: Predominant Soil Series: WmB Crop 1 Max. PAN: 220 Crop 2 Name: 9 SF07 Acres Utilized: Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 21.3 21.3 0 o � N Q Volume applied enter one Solids/ ( ) Liquid Cu. Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a �a F w *o• o ,•d �, # - w •, * N *� TKN mg/kg Z ; o M o mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 2/15 110500 3.75 0.811 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 28.946 NA Bermuda 2/16 91000 3.75 0.668 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 23.838 NA Bermuda 2/24 71500 3.75 0.525 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 18.730 NA Bermuda 11/1 97500 3.15 0.601 Tarheel WWTP Dry <.5" S 0.5 0.2 66100 22100 89.7 23.978 NA Bermuda 11/2 1 39000 3.15 0.241 Tarheel WWTP Dry <.5" S 0.5 0.2 66100 22100 89.7 9.591 NA Bermuda 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 409500 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 105,0841 0.000 Lime Applied Annuallbs/acre 0.040 0.006 8.238 0.308 0.063 0.003 0.071 0.272 0.054 13.938 101.648 Date lbs/ac Prior Years Cumulative lbs/ac 0.369 0.122 41.547 4.466 0.914 0.021 1.187 3.712 0.456 170.774 Current Cumulative lbs/ac 0.409 0.128 49.785 4.774 0.977 0.024 1.258 3.984 0.510 184.712 Permitted C. P. L. R. * * * * 1 9 1 250 1 1 1000 1 1 1 250 1 1 500 Permit PAN Limit lst/2nd Crop 1 220 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 2/1/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Smithfield Farmland Corp. Total Dry Tons Applied (Annual): 21.35 Permit #: WQ0014868 Cation Exchange Capacity (non 503 only): Operator: Richard Dunham Owner: Bonnie Meeker Predominant Soil Series: LaB Acres Used: 7.5 Acres Permitted: 7.5 Site #: SF07 Field #: 14 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): ... 010711RENWINEME Com- posite Date OEM MEMEEM MEMO Total Phos- phorus Annual Heavv Metal Field Loadings (Calculated in lbs/acre): Total 11 2 1 3 4 5j 6j 7 8 9 10 11 12 DT/Ac./ App. .fir Event 2.85 Arsenic 0.037 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.037 Cadmium 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Copper 8.566 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 8.566 Chromium 0.418 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.418 Lead 0.075 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.075 Mercury 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molyb- 0.089 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.089 denum Nickel 0.372 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.372 Selenium 0.049 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.049 Zinc 19.467 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 19.467 Total Phos- 139.454 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 139.454 horus "I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4; 2/l/2024 Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Smithfield Farmland Corp Land Owner: Bonnie Meeker Operator: Richard Dunham Crop 1 Name: Bermuda -Hay WQ Permit #: WQ0014868 Field #: Annual Dry Tons Applied: 2135 Site #: Predominant Soil Series: LaB Crop 1 Max. PAN: 147 Crop 2 Name: 14 Acres Utilized: SF07 Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 7.5 7.5 o � N Q Volume applied enter one Solids/ ) Liquid Cu. Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a �a F w *o• o ,•d �, # w •, * N *� TKN mg/kg Z ; o M o mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 2/10 117000 3.75 2.439 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 87.043 NA Bermuda 2/14 19500 3.75 0.407 Tarheel WWTP Dry <.5" S 0.5 0.2 67550 14160 82.8 14.507 NA Bermuda 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 136500 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 101.551 o.000 Lime Applied Annuallbs/acre 0.037 0.004 8.566 0.418 0.075 0.002 0.089 0.372 0.049 19.467 139.454 Date lbs/ac Prior Years Cumulative lbs/ac 0.329 0.091 43.555 2.867 0.846 0.024 1.143 3.433 0.449 154.784 Current Cumulative lbs/ac 0.366 0.095 52.121 3.285 0.921 0.026 1.232 3.805 0.498 174.251 Permitted C. P. L. R.**** 9 250 1 1000 1 250 500 Permit PAN Limit lst/2nd Crop i Fl-47 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 2/1/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Smithfield Farmland Corp. Total Dry Tons Applied (Annual): 8.13 Permit #: WQ0014868 Cation Exchange Capacity (non 503 only): Operator: Richard Dunham Owner: Bonnie Meeker Predominant Soil Series: At Acres Used: 3 Acres Permitted: 3 Site #: SF07 Field #: 15 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): ... 010711RENWINEME Com- posite Date OEM MEMEEM MEMO Total Phos- phorus Annual Heavv Metal Field Loadings (Calculated in lbs/acre): Total 11 2 1 3 4 5j 6j 7 8 9 10 11 12 DT/Ac./ App. .fir Event 2.71 Arsenic 0.035 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.035 Cadmium 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Copper 8.160 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 8.160 Chromium 0.398 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.398 Lead 0.071 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.071 Mercury 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molyb- 0.085 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.085 denum Nickel 0.354 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.354 Selenium 0.047 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.047 Zinc 18.543 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 18.543 Total Phos- 132.839 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 132.839 horus 1 1 1 1 "I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4; 2/l/2024 Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Smithfield Farmland Corp Land Owner: Bonnie Meeker Operator: Richard Dunham Crop 1 Name: Bermuda -Hay WQ Permit #: WQ0014868 Field #: Annual Dry Tons Applied: 8.13 Site #: Predominant Soil Series: At Crop 1 Max. PAN: 237 Crop 2 Name: 15 Acres Utilized: SF07 Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: Q Volume applied enter one Solids/ Liquid Cu_ Yds Gallons o /o Solids Volume A hed er pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a 4 � F w *o• o ,•d 2 # 4 w , * N *� TKN mg/kg Z ; o oa o �• mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 2/9 52000 3.75 2.711 Tarheel WWTP Dry <.5" S 0.5 0.2 1 67550 14160 82.8 96.715 NA Bermuda 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 52000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 96.715 0.000 Lime Applied Annuallbs/acre 0.035 0.004 8.160 0.398 0.071 0.002 0.085 0.354 0.047 18.543 132.839 Date lbs/ac Prior Years Cumulative lbs/ac 0.034 0.004 7.274 0.389 0.064 0.001 0.093 0.346 0.046 16.882 Current Cumulative lbs/ac 0.069 0.008 15.434 0.787 0.135 0.003 0.178 0.700 0.093 35.425 Permitted C. P. L. R.**** 1 9 1 250 1 1 1000 1 250 500 Permit PAN Limit lst/2nd Crop 1 237 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 2/1/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) Waypointo ANALYTICAL 2/15/2023 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Rd Mocksville, NC, 27028 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Ref: Analytical Testing Revised Lab Report Number: 23-026-9016 (Original Report 23-026-0016) Client Project Description: Smithfield, ND Dear Mr. Brent Collins: Waypoint Analytical, LLC. received sample(s) on 1/26/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling stage (refer to the chain of custody) results apply to the sample as received. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in the scope because NELAP accreditation is either not available or has not been applied for. Additional certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable. A full list of certifications is available upon request. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Connie Cook Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 8 Waypointo ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 0 Fax 901.213.2440 www.waypointanalytical.com Certification Summary Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN State Program Lab ID Expiration Date Alabama State Program 40750 02/28/2023 Arkansas State Program 88-0650 02/07/2023 California State Program 2904 06/30/2023 Florida State Program - NELAP E871157 06/30/2023 Georgia State Program C044 02/18/2023 Georgia State Program 04015 06/30/2023 Illinois State Program - NELAP 200078 10/10/2023 Kentucky State Program 80215 06/30/2023 Kentucky State Program KY90047 12/31/2023 Louisiana State Program - NELAP LA037 12/31/2023 Louisiana State Program - NELAP 04015 06/30/2023 Mississippi State Program MS 02/11/2023 North Carolina State Program 47701 07/31/2023 North Carolina State Program 415 12/31/2023 Pennsylvania State Program - NELAP 68-03195 05/31/2023 South Carolina State Program 84002 06/30/2023 Tennessee State Program 02027 11/14/2025 Texas State Program - NELAP T104704180 09/30/2023 Virginia State Program 00106 06/30/2023 Virginia State Program - NELAP 460181 09/14/2023 Page 1 of 1 00001/23-026-9016 Page 2 of 8 Waypoint ANALYTICAL Report Number: 23-026-9016 Client Project Description: Smithfield, ND Lab No Client Sample ID 97603 North Digester 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Sample Summary Table Matrix Date Collected Date Received Solids 01/25/2023 08:05 01/26/2023 Page 3 of 8 Waypointo ANALYTICAL Client: EMA Resources Inc Project: Smithfield, ND Lab Report Number: 23-026-9016 Date: 2/15/2023 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 0 fax 901.213.2440 www.waypointanalytical.com CASE NARRATIVE This report is being revised to enter correct percent moisture results. Correct results have now been entered. Metals Analysis Method 601 OD Sample 60540 Analyte: Aluminum QC Batch No: 1-661330/1-660893 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 60540 Analyte: Iron QC Batch No: 1-661330/1-660893 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 60540 Analyte: Sulfur QC Batch No: 1-661330/1-660893 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Page 4 of 8 Waypointo ANALYTICAL 46245 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Rd Mocksville , NC 27028 Report Number : 23-026-9016 Project Information 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Smithfield, ND Original Report Date : 02/06/2023 Revised Report Date: 02/15/2023 Received : 01/26/2023 REPORT OFANALYSIS Lab No : 97603 Matrix: Solids Sample ID : North Digester Sampled: 1/25/2023 8:05 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Moisture 96.5 % 1 02/02/2316:40 JJJ SW-DRYWT Ammonia Nitrogen 18500 mg/Kg - dry 457 2860 1 02/03/23 13:30 CLP 4500NH3C-2011 Nitrate+Nitrite-N <140 mg/Kg - dry 140 140 1 01/30/23 14:33 ZBD 4500NO3F-2016 Organic N 50310 mg/Kg - dry 708.6 1429 1 02/02/23 14:51 DH CALCULATION pH 7.2 S.U. 1 02/03/2315:43 SAR 9045D Total Solids 3.55 % 0.010 0.010 1 01/30/23 17:10 CJR 2540G-2011 Total Volatile Solids 75.1 % 0.010 0.010 1 01/30/23 17:10 CJR 2540G-2011 Total Kjeldahl Nitrogen 68900 mg/Kg - dry 1430 1 02/02/23 14:51 ANH 4500NORGD-2011 Phosphorus 27500 mg/Kg - dry 78.9 143 1 01/31/23 01:21 JTR 6010D Aluminum 14100 mg/Kg - dry 132 143 1 01/31/23 01:21 JTR 6010D Arsenic <6.86 mg/Kg - dry 6.86 14.3 1 01/31/23 01:21 JTR 6010D Cadmium 0.8263 mg/Kg - dry 0.571 2.86 1 01/31/23 01:21 JTR 6010D Calcium 32000 mg/Kg - dry 1110 1430 1 01/31/23 01:21 JTR 6010D Chromium 79.4 mg/Kg - dry 6.74 7.14 1 01/31/23 01:21 JTR 6010D Copper 1530 mg/Kg - dry 8.86 14.3 1 01/31/23 01:21 JTR 6010D Iron 16000 mg/Kg - dry 243 286 1 01/31/23 01:21 JTR 6010D Lead 14.7 mg/Kg - dry 5.14 8.57 1 01/31/23 01:21 JTR 6010D Magnesium 2550 mg/Kg - dry 73.7 143 1 01/31/23 01:21 JTR 6010D Manganese 657 mg/Kg - dry 9.29 14.3 1 01/31/23 01:21 JTR 6010D Mercury <0.191 mg/Kg - dry 0.191 4.37 1 01/30/23 16:07 JTR 7471A Molybdenum 16.7 mg/Kg - dry 3.86 7.14 1 01/31/23 01:21 JTR 6010D Nickel 68.9 mg/Kg - dry 3.43 7.14 1 01/31/23 01:21 JTR 6010D Potassium 5060 mg/Kg - dry 177 286 1 01/31/23 15:58 JTR 6010D Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 5 of 8 • 27090 Whitten Road, Memphis, TN 38133 Waypoint Main 901.213.2400 ° Fax 901.213.2440 ANALYTICAL www.waypointanalyiical.com 46245 EMA Resources Inc Project Smithfield, ND Original Report Date : 02/06/2023 Mr. Brent Collins Revised Report Date: 02/15/2023 755 Yadkinville Rd Information : Received : 01/26/2023 Mocksville , NC 27028 Report Number : 23-026-9016 REPORT OFANALYSIS Lab No : 97603 Sample ID : North Digester Matrix: Solids Sampled: 1/25/2023 8:05 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Selenium <9.14 mg/Kg - dry 9.14 14.3 1 01/31/23 01:21 JTR 6010D Sodium 13500 mg/Kg - dry 371 714 1 01/31/23 01:21 JTR 6010D Zinc 3460 mg/Kg - dry 23.1 35.7 1 01/31/23 01:21 JTR 6010D Sulfur 23000 mg/Kg - dry 148 286 1 01/31/23 01:21 JTR 6010D Sodium Absorption Ratio 3.63 Ratio 0.01 0.01 1 01/31/23 01:21 CALCULATION Qualifiers/ DF Dilution Factor Definitions J Estimated value Page 6 of 8 s WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133 21.2440 Main 901.213.240fl °Fax 901.213.2440 N A LYT I C A L www.waypointanalytical.com Shipment Receipt Form Customer Number: 46245 Customer Name: EMA Resources Inc Report Number: 23-026-0016 Shipping Method 0 Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client 0 Courier 0 Other: Thermometer ID: IT135 Shipping container/cooler uncompromised? * Yes 0 No Number of coolers/boxes received Custody seals intact on shipping container/cooler? 0 Yes 0 No Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? # Yes 0 No COC agrees with sample label(s)? # Yes 0 No COC properly completed # Yes 0 No Samples in proper containers? # Yes 0 No Sample containers intact? # Yes 0 No Sufficient sample volume for indicated test(s)? # Yes 0 No All samples received within holding time? # Yes 0 No Cooler temperature in compliance? # Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. # Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No N/A Water - VOA vials free of headspace 0 Yes 0 No N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A F_ High concentration container (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low concentration EnCore samplers (48 hr) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes * No Comments: Signature: lEmily M. Peterson Date & Time: 01/26/2023 10:50:25 Page 7 of 8 Cl. N o LL E F E p E' F 6 c u V o� — U m m N a m U Z q ru O ou a m nax w E N 3 3 v Q Q v V ¢ — 4J y ao� = ❑ o o o 6N omz� g L N �r T = V V 2 2 2 I 2= V ¢ Q o o CL K[ LL iv Q a 2 C iQ q VI Q m V 4 w 4 w=_ W W 5 Y Cc a 2 ¢ 2 VJ ❑ 0 a w _ d G - Q w a w a 4 O n m' 3 0 0 m E a 7 u £ - Ir 2 E CO E x ? N 0 S■►i � oI °' Q y E � E £ E t � U ❑ L �• C � � � m F tl Hd r- �� a � �/) 5P!IOS JBIO T a U a m �Q N N DiuefiJO/aIeJkiN a , � Lnco m eiuOWWV/N>il CN �� ro ' m IIJ 4! w W w C ❑ — (amog) 51e3aW a 7 a 7 a C N a Q q = fl a N a d ,gyp C7 C7 to m Q a afisodwo(�] �o geij9] `] ro a L n w n v {AaN 43 as;ali} xrj;elN a cr cr slaws;ua:) }a jagwnN c E C a C oar 9 s c 4 �- o L.j c r� LT,l V ^' O •a U c a a(Y') s m y F t y E o A- C � nl a E Y W � m o a t ° az� ¢ Z a �a �Q E Q v m O.S , Q N v E W g oLu P _ m Fm Page 8 of 8 Waypointo ANALYTICAL 2/15/2023 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Rd Mocksville, NC, 27028 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Ref: Analytical Testing Revised Lab Report Number: 23-026-9017 (Original Report 23-026-0017) Client Project Description: Smithfield, SD Dear Mr. Brent Collins: Waypoint Analytical, LLC. received sample(s) on 1/26/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling stage (refer to the chain of custody) results apply to the sample as received. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in the scope because NELAP accreditation is either not available or has not been applied for. Additional certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable. A full list of certifications is available upon request. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Connie Cook Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 8 Waypointo ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 0 Fax 901.213.2440 www.waypointanalytical.com Certification Summary Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN State Program Lab ID Expiration Date Alabama State Program 40750 02/28/2023 Arkansas State Program 88-0650 02/07/2023 California State Program 2904 06/30/2023 Florida State Program - NELAP E871157 06/30/2023 Georgia State Program C044 02/18/2023 Georgia State Program 04015 06/30/2023 Illinois State Program - NELAP 200078 10/10/2023 Kentucky State Program 80215 06/30/2023 Kentucky State Program KY90047 12/31/2023 Louisiana State Program - NELAP LA037 12/31/2023 Louisiana State Program - NELAP 04015 06/30/2023 Mississippi State Program MS 02/11/2023 North Carolina State Program 47701 07/31/2023 North Carolina State Program 415 12/31/2023 Pennsylvania State Program - NELAP 68-03195 05/31/2023 South Carolina State Program 84002 06/30/2023 Tennessee State Program 02027 11/14/2025 Texas State Program - NELAP T104704180 09/30/2023 Virginia State Program 00106 06/30/2023 Virginia State Program - NELAP 460181 09/14/2023 Page 1 of 1 00001/23-026-9017 Page 2 of 8 Waypoint ANALYTICAL Report Number: 23-026-9017 Client Project Description: Smithfield, SD Lab No Client Sample ID 97608 South Digester 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Sample Summary Table Matrix Date Collected Date Received Solids 01/25/2023 08:40 01/26/2023 Page 3 of 8 Waypointo ANALYTICAL Client: EMA Resources Inc Project: Smithfield, SD Lab Report Number: 23-026-9017 Date: 2/15/2023 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 0 fax 901.213.2440 www.waypointanalytical.com CASE NARRATIVE This report is being revised to enter corrected percent moisture results. Correct results have now been entered. Metals Analysis Method 6010D Sample 60540 Analyte: Aluminum QC Batch No: 1-661330/1-660893 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 60540 Analyte: Iron QC Batch No: 1-661330/1-660893 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 60540 Analyte: Sulfur QC Batch No: 1-661330/1-660893 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Page 4 of 8 Waypointo ANALYTICAL 46245 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Rd Mocksville , NC 27028 Report Number : 23-026-9017 Project Information 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Smithfield, SD Original Report Date : 02/06/2023 Revised Report Date: 02/15/2023 Received : 01/26/2023 REPORT OFANALYSIS Lab No : 97608 Matrix: Solids Sample ID : South Digester Sampled: 1/25/2023 8:40 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Moisture 97.6 % 1 02/02/2316:40 JJJ SW-DRYWT Ammonia Nitrogen 26700 mg/Kg - dry 667 4170 1 02/03/23 13:30 CLP 4500NH3C-2011 Nitrate+Nitrite-N <200 mg/Kg - dry 200 200 1 01/30/23 14:35 ZBD 4500NO3F-2016 Organic N 102100 mg/Kg - dry 10330 20830 1 02/02/23 15:09 DH CALCULATION pH 7.4 S.U. 1 02/03/2315:43 SAR 9045D Total Solids 2.36 % 0.010 0.010 1 01/30/23 17:10 CJR 2540G-2011 Total Volatile Solids 79.1 % 0.010 0.010 1 01/30/23 17:10 CJR 2540G-2011 Total Kjeldahl Nitrogen 129000 mg/Kg - dry 20800 10 02/02/23 15:09 ANH 4500NORGD-2011 Phosphorus 6460 mg/Kg - dry 115 208 1 01/31/23 01:26 JTR 6010D Aluminum 2000 mg/Kg - dry 193 208 1 01/31/23 01:26 JTR 6010D Arsenic <10.0 mg/Kg - dry 10.0 20.8 1 01/31/23 01:26 JTR 6010D Cadmium <0.833 mg/Kg - dry 0.833 4.17 1 01/31/23 01:26 JTR 6010D Calcium 5670 mg/Kg - dry 1610 2080 1 01/31/23 01:26 JTR 6010D Chromium 14.7 mg/Kg - dry 9.83 10.4 1 01/31/23 01:26 JTR 6010D Copper 463 mg/Kg - dry 12.9 20.8 1 01/31/23 01:26 JTR 6010D Iron 4250 mg/Kg - dry 355 417 1 01/31/23 01:26 JTR 6010D Lead <7.50 mg/Kg - dry 7.50 12.5 1 01/31/23 01:26 JTR 6010D Magnesium 1580 mg/Kg - dry 108 208 1 01/31/23 01:26 JTR 6010D Manganese 104 mg/Kg - dry 13.5 20.8 1 01/31/23 01:26 JTR 6010D Mercury <0.270 mg/Kg - dry 0.270 6.21 1 01/30/23 16:02 JTR 7471A Molybdenum <5.63 mg/Kg - dry 5.63 10.4 1 01/31/23 01:26 JTR 6010D Nickel 22.2 mg/Kg - dry 5.00 10.4 1 01/31/23 01:26 JTR 6010D Potassium 7670 mg/Kg - dry 258 417 1 01/31/23 16:03 JTR 6010D Qualifiers/ DF Dilution Factor MQL Method Quantitation Limit Definitions Page 5 of 8 Waypointo ANALYTICAL 46245 EMA Resources Inc Project Smithfield, SD Mr. Brent Collins 755 Yadkinville Rd Information Mocksville , NC 27028 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Original Report Date : 02/06/2023 Revised Report Date: 02/15/2023 Received : 01/26/2023 Report Number : 23-026-9017 REPORT OFANALYSIS Lab No : 97608 Sample ID : South Digester Matrix: Solids Sampled: 1/25/2023 8:40 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Selenium <13.3 mg/Kg - dry 13.3 20.8 1 01/31/23 01:26 JTR 6010D Sodium 19500 mg/Kg - dry 542 1040 1 01/31/23 01:26 JTR 6010D Zinc 954 mg/Kg - dry 33.8 52.1 1 01/31/23 01:26 JTR 6010D Sulfur 6830 mg/Kg - dry 216 417 1 01/31/23 01:26 JTR 6010D Sodium Absorption Ratio 9.15 Ratio 0.01 0.01 1 01/31/23 01:26 CALCULATION Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit Page 6 of 8 s WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133 21.2440 Main 901.213.240fl °Fax 901.213.2440 N A LYT I C A L www.waypointanalytical.com Shipment Receipt Form Customer Number: 46245 Customer Name: EMA Resources Inc Report Number: 23-026-0017 Shipping Method 0 Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client 0 Courier 0 Other: Thermometer ID: IT135 Shipping container/cooler uncompromised? * Yes 0 No Number of coolers/boxes received Custody seals intact on shipping container/cooler? 0 Yes 0 No Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? # Yes 0 No COC agrees with sample label(s)? # Yes 0 No COC properly completed # Yes 0 No Samples in proper containers? # Yes 0 No Sample containers intact? # Yes 0 No Sufficient sample volume for indicated test(s)? # Yes 0 No All samples received within holding time? # Yes 0 No Cooler temperature in compliance? # Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. # Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No N/A Water - VOA vials free of headspace 0 Yes 0 No N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A F_ High concentration container (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low concentration EnCore samplers (48 hr) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes * No Comments: Signature: lEmily M. Peterson Date & Time: 01/26/2023 10:51:41 Page 7 of 8 � c d N o _ L # ° o U a C3] E E E a � �o o (3) o U Z d d z a ❑ ❑ N b G 0 N a O! U O 0 y =' nCA 'T x= c E C7 d] 4� n ❑ o a !i ¢ = n= v v v g caa�a p � N Q 2 �iO� 97 iA y cod C G g o�n c m ❑ � � Y C T T V V S z z x T u v a m N �7 CL 4 W W 0 am I 7 F 7 ra a a a L 4��:. n' LY ZA- FA Y G LL a Q Q a a ❑O ❑ c y E -o 7 a 7 v 7 = N 0! N /� E a- di N _ em u E �c z _� p� rti^Li E cn oe a a LL ' 0 LM snl � = Lu � 4 � w Q) n w E E +vy E E H �� ° m " � a a 2L'I❑ a �x\ T �,R m SPHOS Ielal N V �,% J CI 1 ❑ ❑ U CL a U N O'ue6JOJa;eJl!N a6i m y Ln g EIUOWWV/NN-L z w o � _0 W - a ¢ w ui ,u (co 09) S�elaW E r.. "0rod a ❑ � m c g o a z z z c U s,na d= W< i3p5odwo(Z)� io qel{g) r, V E_ ? V a a N a a N a n N (AaH o1 la;aaJ xuleyy y L 7 7 3 � m Q e a c .@ c r V Y Q sjauie;uo:);o jagwnk VI a LC d' a d' T a� d m u T xe QD m rn ih C O m J = a 0 V a 0 ! • ..+ � ro is a i 6 a m V d o ate+ c .L-✓�� m N F�r E c N a \� G O o R C ^� T o V V l 0. /y`'� G L-! CL a K m � a 4 0 j R co J LL a � n 13) U p •.rr � � ,,, 04, 2 ;6 m 7 in r E F a O F- �; a d ❑ dJ V ... F c a: N � LO z I,- Page 8 of 8 Waypointo ANALYTICAL 4/5/2023 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Rd Mocksville, NC, 27028 Ref: Analytical Testing Lab Report Number: 23-076-0022 Client Project Description: Smithfield 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Dear Mr. Brent Collins: Waypoint Analytical, LLC. received sample(s) on 3/17/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling stage (refer to the chain of custody) results apply to the sample as received. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in the scope because NELAP accreditation is either not available or has not been applied for. Additional certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable. A full list of certifications is available upon request. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Connie Cook Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 9 Waypointo ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 0 Fax 901.213.2440 www.waypointanalytical.com Certification Summary Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN State Program Lab ID Expiration Date Alabama State Program 40750 02/29/2024 Arkansas State Program 88-0650 02/07/2024 California State Program 2904 06/30/2023 Florida State Program - NELAP E871157 06/30/2023 Georgia State Program C044 11/14/2025 Georgia State Program 04015 06/30/2023 Illinois State Program - NELAP 200078 10/10/2023 Kentucky State Program 80215 06/30/2023 Kentucky State Program KY90047 12/31/2023 Louisiana State Program - NELAP LA037 12/31/2023 Louisiana State Program - NELAP 04015 06/30/2023 Mississippi State Program MS 02/11/2023 North Carolina State Program 47701 07/31/2023 North Carolina State Program 415 12/31/2023 Pennsylvania State Program - NELAP 68-03195 05/31/2023 South Carolina State Program 84002 06/30/2023 Tennessee State Program 02027 11/14/2025 Texas State Program - NELAP T104704180 09/30/2023 Virginia State Program 00106 06/30/2023 Virginia State Program - NELAP 460181 09/14/2023 Page 1 of 1 00001/23-076-0022 Page 2 of 9 Waypoint ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Sample Summary Table Report Number: 23-076-0022 Client Project Description: Smithfield Lab No Client Sample ID Matrix Date Collected Date Received 81757 Smithfield North Solids 03/16/2023 06:00 03/17/2023 Page 3 of 9 Waypointo ANALYTICAL Client: EMA Resources Inc Project: Smithfield Lab Report Number: 23-076-0022 Date: 4/4/2023 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 0 fax 901.213.2440 www.waypointanalytical.com CASE NARRATIVE Block Digestion and FIA Method 4500NORGD-2011 Analyte: Total Kjeldahl Nitrogen QC Batch No: L671670/L671640 Matrix spike recovery outside of control limits. Acceptable LCS recovery indicates the system was in control, but the reported result could be affected by matrix interference or non -homogeneous sample. Metals Analysis Method 601 OD Sample 81389 Analyte: Calcium QC Batch No: L671288/L670600 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 81389 Analyte: Chromium QC Batch No: L671288/L670600 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 81389 Analyte: Copper QC Batch No: L671288/L670600 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 81389 Analyte: Iron QC Batch No: L671288/L670600 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 81389 Analyte: Potassium QC Batch No: L671288/L670600 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 81389 Analyte: Manganese QC Batch No: L671288/L670600 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 81389 Analyte: Phosphorus Page 4 of 9 Waypoint".0 - ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 0 fax 901.213.2440 www.waypointanalytical.com QC Batch No: 1-671288/1-670600 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 81389 Analyte: Lead QC Batch No: 1-671288/1-670600 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 81389 Analyte: Sulfur QC Batch No: 1-671288/1-670600 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 81389 Analyte: Zinc QC Batch No: 1-671288/1-670600 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Solids Total Mercury Analysis - CVAA Method 7471A Sample 90250 Analyte: Mercury QC Batch No: 1-671176/1-670913 The matrix spike, matrix spike duplicate and the post digestion spike were all outside of the quality control acceptance ranges. Matrix interference is suspected Page 5 of 9 Waypointo ANALYTICAL 46245 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Rd Mocksville , NC 27028 Project Smithfield Information : 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Report Date : 04/05/2023 nReceived : 03/17/2023 C-�*�-� = Connie Cook Report Number : 23-076-0022 REPORT OFANALYSIS Project Manager Lab No : 81757 Matrix: Solids Sample ID : Smithfield North Sampled: 3/16/2023 6:00 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Moisture 96.1 % 1 03/23/23 15:29 CJD SW-DRYWT Ammonia Nitrogen 9820 mg/Kg - dry 410 2560 1 03/28/23 10:30 JPJ 4500NH3C-2011 Nitrate+Nitrite-N <25.6 mg/Kg - dry 25.6 128 1 03/21/23 15:08 ZBD 4500NO3F-2016 Organic N 56330 mg/Kg - dry 635.9 1282 1 03/24/23 13:29 CALCULATION pH 7.1 S.U. 1 03/24/2316:00 CNB 9045D Total Solids 3.95 % 0.010 0.010 1 03/23/23 15:29 CJD 2540G-2011 Total Volatile Solids 78.5 % 0.010 0.010 1 03/23/23 15:29 CJD 2540G-2011 Total Kjeldahl Nitrogen 66200 mg/Kg - dry 1280 1 03/24/23 13:29 ANH 4500NORGD-2011 Phosphorus 21500 mg/Kg - dry 70.8 128 1 03/21/23 20:06 BKN 6010D Aluminum 11300 mg/Kg - dry 118 128 1 03/21/23 20:06 BKN 6010D Arsenic <6.15 mg/Kg - dry 6.15 12.8 1 03/21/23 20:06 BKN 6010D Cadmium 0.6213 mg/Kg - dry 0.513 2.56 1 03/21/23 20:06 BKN 6010D Calcium 22600 mg/Kg - dry 992 1280 1 03/21/23 20:06 BKN 6010D Chromium 67.4 mg/Kg - dry 6.05 6.41 1 03/21/23 20:06 BKN 6010D Copper 1480 mg/Kg - dry 7.95 12.8 1 03/21/23 20:06 BKN 6010D Iron 16500 mg/Kg - dry 218 256 1 03/21/23 20:06 BKN 6010D Lead 11.5 mg/Kg - dry 4.62 7.69 1 03/21/23 20:06 BKN 6010D Magnesium 2430 mg/Kg - dry 66.2 128 1 03/21/23 20:06 BKN 6010D Manganese 626 mg/Kg - dry 8.33 12.8 1 03/21/23 20:06 BKN 6010D Mercury <0.554 mg/Kg - dry 0.554 4.59 1 03/21/23 13:38 FDS 7471A Molybdenum 14.7 mg/Kg - dry 3.46 6.41 1 03/21/23 20:06 BKN 6010D Nickel 61.8 mg/Kg - dry 3.08 6.41 1 03/21/23 20:06 BKN 6010D Potassium 4970 mg/Kg - dry 158 256 1 03/21/23 20:06 BKN 6010D Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 6 of 9 • Waypoint 27090 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 ANALYTICAL www.waypointanalyiical.com 46245 EMA Resources Inc Project Smithfield Mr. Brent Collins Report Date : 04/05/2023 755 Yadkinville Rd Information : Received : 03/17/2023 Mocksville , NC 27028 Connie Cook Report Number : 23-076-0022 REPORT OFANALYSIS Project Manager Lab No : 81757 Matrix: Solids Sample ID : Smithfield North Sampled: 3/16/2023 6:00 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Selenium <8.21 mg/Kg - dry 8.21 12.8 1 03/21/23 20:06 BKN 6010D Sodium 10100 mg/Kg - dry 333 641 1 03/21/23 20:06 BKN 6010D Zinc 3380 mg/Kg - dry 20.8 32.1 1 03/21/23 20:06 BKN 6010D Sulfur 23400 mg/Kg - dry 133 256 1 03/21/23 20:06 BKN 6010D Sodium Absorption Ratio 3.34 Ratio 0.01 0.01 1 03/21/23 20:06 CALCULATION Qualifiers/ DF Dilution Factor Definitions J Estimated value Page 7 of 9 s WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133 21.2440 Main 901.213.240fl °Fax 901.213.2440 N A LYT I C A L www.waypointanalytical.com Shipment Receipt Form Customer Number: 46245 Customer Name: EMA Resources Inc Report Number: 23-076-0022 Shipping Method 0 Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client 0 Courier 0 Other: Thermometer ID: IT136 Shipping container/cooler uncompromised? * Yes 0 No Number of coolers/boxes received Custody seals intact on shipping container/cooler? 0 Yes 0 No Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? # Yes 0 No COC agrees with sample label(s)? # Yes 0 No COC properly completed # Yes 0 No Samples in proper containers? # Yes 0 No Sample containers intact? # Yes 0 No Sufficient sample volume for indicated test(s)? # Yes 0 No All samples received within holding time? # Yes 0 No Cooler temperature in compliance? # Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. # Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No N/A Water - VOA vials free of headspace 0 Yes 0 No N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A F_ High concentration container (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low concentration EnCore samplers (48 hr) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes * No Comments: Signature: IMallory Earle Date & Time: 03/17/2023 09:36:50 Page 8 of 9 a N +r .o 3 p s D CL CD • _ r E F E a� �,,; CIS q o a W d d d 'ti p = 9 y r) �i66 m Iv N N m N Z y N g H� a ZX asa ax E L) �y ❑ m� w n y o V N ¢ 2 �I # A a a� o❑ zun L VI �d' C m _T V ��+ 2 0 2 Z I I S Q CCQ C ❑ E 3 '^ UI Q1 2 Q � � Zi ❑ 0. vV Q m u ❑ ..+ 4 L7 S _ � � � � � � � .0 M 1 N a r a z a x ®u L / 0. Q) V Y LL _w ❑ ❑ `C U Q b 5. H 7 w 7 Q 7 C in W q Y OdC C E E Y w N Lu o SA� a 4 = Q, a s of 0 a A g E �J Hu . d u O LL t a cc a I2 Vol 01 ''nn m ❑ m ❑ ro ❑ li splos poi V L.7 _T a y � N oiue6apfa;ea;iN a v m o d E E e#u0LUWV/Wi o � �1 # v y 3 as En a m! ee Q _ o (CIO109) slel a Q a v t7 x 0 to c U u� ❑ y C d 1 Q m Q a az�sodwvt7l �a qek;�} z A m ro a .0 m a (RaN o; 1apN) xuyevy r N Q C tr G E - 5jauieluo,3 }o iagwnN c '^ c u tt a ro m p m a� m a S �' w o o a o o cr) L y ;_ T c� u ❑7 a a` M a n 0 q a m 4 � S o rt d �o 0o N N C N V •�� w V, H V CAPN co�U C o G � am 7� r r � a a — z a y v v d O c ai N YNt E 2 Q' Co 7 i m C {{7� C ¢LO LL Page 9 of 9 Waypointo ANALYTICAL 11 /7/2023 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Rd Mocksville, NC, 27028 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Ref: Analytical Testing Revised Lab Report Number: 23-291-9074 (Original Report 23-291-0074) Client Project Description: Smithfield Dear Mr. Brent Collins: Waypoint Analytical, LLC. received sample(s) on 10/18/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling stage (refer to the chain of custody) results apply to the sample as received. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in the scope because NELAP accreditation is either not available or has not been applied for. Additional certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable. A full list of certifications is available upon request. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Connie Cook Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 7 Waypointo ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 0 Fax 901.213.2440 www.waypointanalytical.com Certification Summary Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN State Program Lab ID Expiration Date Alabama State Program 40750 02/29/2024 Arkansas State Program 88-0650 02/07/2024 California State Program 2904 06/30/2024 Florida State Program - NELAP E871157 06/30/2024 Georgia State Program C044 11/14/2025 Georgia State Program 04015 06/30/2024 Illinois State Program - NELAP 200078 10/31/2024 Kentucky State Program 80215 06/30/2024 Kentucky State Program KY90047 12/31/2023 Louisiana State Program - NELAP LA037 12/31/2023 Louisiana State Program - NELAP 04015 06/30/2024 Mississippi State Program MS 11/14/2025 North Carolina State Program 47701 07/31/2024 North Carolina State Program 415 12/31/2023 Pennsylvania State Program - NELAP 68-03195 05/31/2024 South Carolina State Program 84002 06/30/2024 Tennessee State Program 02027 11/14/2025 Texas State Program - NELAP T104704180 09/30/2024 Virginia State Program 00106 06/30/2024 Virginia State Program - NELAP 460181 09/14/2024 Page 1 of 1 00001/23-291-9074 Page 2 of 7 Waypoint ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Sample Summary Table Report Number: 23-291-9074 Client Project Description: Smithfield Lab No Client Sample ID Matrix Date Collected Date Received 89582 South Smithfield Solids 10/17/2023 08:45 10/18/2023 Page 3 of 7 Waypointo ANALYTICAL 46245 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Rd Mocksville , NC 27028 Report Number : 23-291-9074 Project Smithfield Information : 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Original Report Date : 11/01/2023 Revised Report Date : 11/07/2023 Received : 10/18/2023 REPORT OFANALYSIS Lab No : 89582 Matrix: Solids Sample ID : South Smithfield Sampled: 10/17/2023 8:45 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Moisture 96.9 % 1 11/02/23 17:28 CJR SW-DRYWT Ammonia Nitrogen 22100 mg/Kg - dry 516 3230 1 10/25/23 09:08 JPJ 4500NH3C-2011 Nitrate+Nitrite-N 89.73 mg/Kg - dry 32.3 161 1 10/19/23 12:10 CLP 4500NO3F-2016 Organic N 44060 mg/Kg - dry 9161 1 10/25/23 09:08 DH CALCULATION pH 7.6 S.U. 1 10/20/2316:00 CNB 9045D Total Solids 3.15 % 0.010 0.010 1 11/02/23 17:28 CJR 2540G-2011 Total Volatile Solids 80.2 % 0.010 0.010 1 11/02/23 17:28 CJR 2540G-2011 Total Kjeldahl Nitrogen 66100 mg/Kg - dry 9160 1 11/01/23 09:13 ANH 4500NORGD-2011 Phosphorus 2050 mg/Kg - dry 90.3 161 1 10/19/23 20:51 TJS 6010D Aluminum 233 mg/Kg - dry 150 161 1 10/19/23 20:51 BKN 6010D Arsenic <8.06 mg/Kg - dry 8.06 16.1 1 10/19/23 20:51 TJS 6010D Cadmium <1.61 mg/Kg - dry 1.61 3.23 1 10/19/23 20:51 TJS 6010D Calcium <1250 mg/Kg - dry 1250 1610 1 10/19/23 20:51 TJS 6010D Chromium <8.06 mg/Kg - dry 8.06 8.06 1 10/19/23 20:51 TJS 6010D Copper 1310 mg/Kg - dry 9.68 16.1 1 10/23/23 18:37 BKN 6010D Iron 584 mg/Kg - dry 276 323 1 10/19/23 20:51 BKN 6010D Lead <6.45 mg/Kg - dry 6.45 9.68 1 10/19/23 20:51 TJS 6010D Magnesium 471 mg/Kg - dry 83.9 161 1 10/19/23 20:51 TJS 6010D Manganese 16.13 mg/Kg - dry 11.3 16.1 1 10/19/23 20:51 BKN 6010D Mercury <0.694 mg/Kg - dry 0.694 5.74 1 10/23/23 13:38 FDS 7471A Molybdenum <4.84 mg/Kg - dry 4.84 8.06 1 10/19/23 20:51 TJS 6010D Nickel 6.263 mg/Kg - dry 4.84 8.06 1 10/19/23 20:51 TJS 6010D Potassium 5260 mg/Kg - dry 200 323 1 10/19/23 20:51 BKN 6010D Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 4 of 7 Waypointo ANALYTICAL 46245 EMA Resources Inc Project Smithfield Mr. Brent Collins 755 Yadkinville Rd Information Mocksville , NC 27028 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Original Report Date : 11/01/2023 Revised Report Date : 11/07/2023 Received : 10/18/2023 Report Number : 23-291-9074 REPORT OFANALYSIS Lab No : 89582 Sample ID : South Smithfield Matrix: Solids Sampled: 10/17/2023 8:45 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Selenium <11.3 mg/Kg - dry 11.3 16.1 1 10/19/23 20:51 TJS 6010D Sodium 12900 mg/Kg - dry 419 806 1 10/19/23 20:51 TJS 6010D Zinc 137 mg/Kg - dry 27.4 40.3 1 10/19/23 20:51 TJS 6010D Sulfur 1580 mg/Kg - dry 168 323 1 10/19/23 20:51 TJS 6010D Sodium Absorption Ratio 22.5 Ratio 0.01 0.01 1 10/19/23 20:51 CALCULATION Qualifiers/ DF Dilution Factor Definitions J Estimated value Page 5 of 7 s WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133 21.2440 Main 901.213.240fl °Fax 901.213.2440 N A LYT I C A L www.waypointanalytical.com Shipment Receipt Form Customer Number: 46245 Customer Name: EMA Resources Inc Report Number: 23-291-0074 Shipping Method 0 Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client 0 Courier 0 Other: Thermometer ID: IT99 Shipping container/cooler uncompromised? * Yes 0 No Number of coolers/boxes received Custody seals intact on shipping container/cooler? 0 Yes 0 No Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? # Yes 0 No COC agrees with sample label(s)? # Yes 0 No COC properly completed # Yes 0 No Samples in proper containers? # Yes 0 No Sample containers intact? # Yes 0 No Sufficient sample volume for indicated test(s)? # Yes 0 No All samples received within holding time? # Yes 0 No Cooler temperature in compliance? # Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. # Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No N/A Water - VOA vials free of headspace 0 Yes 0 No N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A F_ High concentration container (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low concentration EnCore samplers (48 hr) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes * No Comments: Signature: ICarleen Qualls Date & Time: 10/18/2023 11:35:32 Page 6 of 7 � N ai Y LL {l7 E E E J 10 O a r 0 U � F F 0 o U N L QJ W M1� O o U G7 3 � ry v j d ry v s Qz=Nxa� c, E U Z ❑ O a m v 2 Q v ❑ rQ1 2 6J m y oa g 7t O V p m o fl o f a s c jT c-ti u u s a z s x x u Q 0 yV ]C 7 0-0 ❑ a u LL [II QL 0 x Q} a.+ R 33a w [4 5❑¢ in ¢ m V❑ u u l7 z w w cc u Q N r z z G a r LL. N ❑ M a a a Q N a a ❑ m w m 3 O V i £E n 1 2 V 7 N R i aw°J n S snl v _0 Em E v � — �I --I L ° D r a i� ❑ a i a m V c m Q ❑ m ❑ m a m J 0 Sp!lOs Ielol C N 3v CL N N 'J'ue6ap/aeJI!N ¢o m o L[7 Y 2 -E -r- of ai - c0 o w E E ?iuvwwy1N311 ❑ u ? d � C x u t�0�09i slE'}ajN z z z y v a 2p C) a` C7 l7 L7 Q o Cl y a v a [AaN of as}aV] xu;eVy y v� v l � n 1 �d Q . IS ^y �h wauip;uo3;o-jagtunN N C 10 V—_— L- V N a m o s to c a I c o !� m ¢ o t rp C w Cam. E d L d ❑ 11 w� d a V m 0. V a �] ❑ a y o a 7t a d ° co J S `a cr m a ?{) = ❑ J M 3 Vn 7 V N �n �'j a �q vZc E , \- o m01 m 7_ r a a Y m v ary c w LO d iO C ❑ Q LJn� ¢` Page 7 of 7 Waypointo ANALYTICAL 11 /17/2023 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Rd Mocksville, NC, 27028 Ref: Analytical Testing Lab Report Number: 23-313-0137 Client Project Description: Smithfeild 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Dear Mr. Brent Collins: Waypoint Analytical, LLC. received sample(s) on 11/9/2023 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling stage (refer to the chain of custody) results apply to the sample as received. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in the scope because NELAP accreditation is either not available or has not been applied for. Additional certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable. A full list of certifications is available upon request. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Connie Cook Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 6 Waypointo ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 0 Fax 901.213.2440 www.waypointanalytical.com Certification Summary Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN State Program Lab ID Expiration Date Alabama State Program 40750 02/29/2024 Arkansas State Program 88-0650 02/07/2024 California State Program 2904 06/30/2024 Florida State Program - NELAP E871157 06/30/2024 Georgia State Program C044 11/14/2025 Georgia State Program 04015 06/30/2024 Illinois State Program - NELAP 200078 10/31/2024 Kentucky State Program 80215 06/30/2024 Kentucky State Program KY90047 12/31/2023 Louisiana State Program - NELAP LA037 12/31/2023 Louisiana State Program - NELAP 04015 06/30/2024 Mississippi State Program MS 11/14/2025 North Carolina State Program 47701 07/31/2024 North Carolina State Program 415 12/31/2023 Pennsylvania State Program - NELAP 68-03195 05/31/2024 South Carolina State Program 84002 06/30/2024 Tennessee State Program 02027 11/14/2025 Texas State Program - NELAP T104704180 09/30/2024 Virginia State Program 00106 06/30/2024 Virginia State Program - NELAP 460181 09/14/2024 Page 1 of 1 00001/23-313-0137 Page 2 of 6 Waypoint ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Sample Summary Table Report Number: 23-313-0137 Client Project Description: Smithfeild Lab No Client Sample ID Matrix Date Collected Date Received 89355 Smithfield Solids 11/08/202310:00 11/09/2023 Page 3 of 6 • Waypoint 27090 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 ANALYTICAL www.waypointanalyiical.com 46245 EMA Resources Inc Project Smithfeild Mr. Brent Collins Report Date : 11/17/2023 755 Yadkinville Rd Information : Received : 11/09/2023 Mocksville , NC 27028 Connie Cook Report Number : 23-313-0137 REPORT OFANALYSIS Project Manager Lab No : 89355 Matrix: Solids Sample ID : Smithfield Sampled: 11/8/2023 10:00 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Moisture 95.26 % 0.010 0.010 1 11/10/2316:14 CAH SW-DRYWT pH 6.7 S.U. 1 11/14/2317:00 CNB 9045D Total Solids 4.74 % 0.010 0.010 1 11/10/23 16:14 CAH 2540G-2011 Calcium 116000 mg/Kg - dry 816 1050 1 11/14/23 19:07 BKN 6010D Magnesium 2410 mg/Kg - dry 54.9 105 1 11/14/23 19:07 BKN 6010D Sodium 9810 mg/Kg - dry 274 527 1 11/14/23 19:07 BKN 6010D Sulfur 14900 mg/Kg - dry 110 211 1 11/14/23 19:07 BKN 6010D Sodium Absorption Ratio 1.69 Ratio 0.01 0.01 1 11/14/23 19:07 CALCULATION Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit Page 4 of 6 s WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133 21.2440 Main 901.213.240fl °Fax 901.213.2440 N A LYT I C A L www.waypointanalytical.com Shipment Receipt Form Customer Number: 46245 Customer Name: EMA Resources Inc Report Number: 23-313-0137 Shipping Method 0 Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client 0 Courier 0 Other: Thermometer ID: 1036 Shipping container/cooler uncompromised? * Yes 0 No Number of coolers/boxes received Custody seals intact on shipping container/cooler? 0 Yes 0 No Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? # Yes 0 No COC agrees with sample label(s)? # Yes 0 No COC properly completed # Yes 0 No Samples in proper containers? # Yes 0 No Sample containers intact? # Yes 0 No Sufficient sample volume for indicated test(s)? # Yes 0 No All samples received within holding time? # Yes 0 No Cooler temperature in compliance? # Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. # Yes 0 No Water - Sample containers properly preserved Yes 0 No 0 N/A Water - VOA vials free of headspace 0 Yes 0 No N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A F_ High concentration container (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low concentration EnCore samplers (48 hr) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes * No Comments: Signature: tuber Smith Date & Time: 11/09/2023 16:31:50 Page 5 of 6 ❑ -C m m a T L E E _ C N N Sc O W ❑ ❑ ❑ i 1 N Q 0 z I c� v N h N a y u�x a=^ xr� n� a o v c _ 0 io 3 y r d 2 m o p vi G7 v opt O o oN c 00 um o ` T u u x x i x x x (] Y ❑ u 0 O a � u A7 ❑ d LA Q m C D n wLC n a ¢it J z z z L u a� v N V N LL �q rt T El° d w C y N u u e E --a £Oj snlw N ,6a ��F NEI d� H a v� °1 E3 ro• a a sp+io5 Ielol r a N N a'ue6JO/@Ie4!N a a m � a w 0 Ln [D ❑ _ v H a W N 1r111�\l y V W W W E a ai N ¢❑ ao N ra s a a 11 (Go wq) slelan a z z o a c U m a ina C m `q cn cn n m Q a s a;isodw❑{�] �o ge�(gj E _+ i► J� r (Aah 03 JaOld) X!Jlew v N r C L_ C_ suauie;uo:) jo -jagwnN � A R �❑ M1 m N m CC a+ 9C a GL V T a O o rJ La N CO lO rJ ❑ a r1 N 1 a m l/ ,�1 ❑ t1 V r2 "' a T m 0') ui o C) N -r o d o -roT a E d d O �f•1 n O y dC � T ❑ V ML u W b - J a� ` 7 a O N m ✓1 V ti � Ln Q pN� LL ��ti •�� 7;�� m dj ( E o Qa M� — E s;LA ¢ z a a �Q F,z �wcn iv E ❑ ❑ h n a a ry ° ❑ c Q} V .Qp LO cQ [1j r- m a` t+ w a * �/ 5 E 2 m Rio Page 6 of 6 13 ace Analytical ' ANALYTICAL REPORT February 07, 2023 EMA Resources Sample Delivery Group:-1579735 Samples Received: 01/26/2023 Project Number: Description: Sludge Report To: Mr. Brent Collins 755 Yadkinville Road Mocksville, NC 27028 Entire Report Reviewed By: z � �� Cassandra Foster Project Manager Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067and ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy ofthe information provided, and as the samples are received. ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1579735 02/07/23 13:01 1 of 22 TABLE OF CONTENTS Cp: Cover Page Tc: Table of Contents Ss: Sample Summary Cn: Case Narrative Sr: Sample Results NORTH DIGESTER L1579735-01 Qc: Quality Control Summary Wet Chemistry by Method 9012 B Wet Chemistry by Method 9034-9030B Wet Chemistry by Method 9045D Wet Chemistry by Method D93/1010A Mercury by Method 7470A Metals (ICP) by Method 6010D Volatile Organic Compounds (GC/MS) by Method 8260D Semi -Volatile Organic Compounds (LCMS) by Method SW-846 8321 Pesticides (GC) by Method 8081B Semi Volatile Organic Compounds (GC/MS) by Method 8270E GI: Glossary of Terms al: Accreditations & Locations Sc: Sample Chain of Custody 2 3 4 5 5 7 7 8 9 10 11 12 14 16 17 18 20 21 22 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1579735 02/07/23 13:01 2 of 22 SAMPLE SUMMARY Collected by NORTH DIGESTER L1579735-01 Waste Brent Collins Collected date/time Received date/time 01/25/23 08:05 01/26/23 09:00 C P Method Batch Dilution Preparation Analysis Analyst date/time date/time Preparation by Method 1311 WG1996662 1 01/31/23 09:19 01/31/23 09:19 JWS Preparation by Method 1311 WG1996665 1 01/30/2312:43 01/30/2312:43 _TM Wet Chemistry by Method 9012 B WG1997323 1 01/31/23 08:27 01/31/2316:52 LDT Wet Chemistry by Method 9034-9030B WG1995314 1 01/31/23 08:16 01/31/2317:39 RLS Wet Chemistry by Method 9045D WG1995819 1 01/27/2314:00 01/27/2315:52 KAD Wet Chemistry by Method D93/1010A WG1997129 1 01/31/23 0146 01/31/23 0146 CRB Mercury by Method 7470A WG1997957 1 02/01/23 09:35 02/01/2314:30 SRT Metals (ICP) by Method 6010D WG1998017 1 02/01/2313:12 02/01/2318:39 ZSA Volatile Organic Compounds (GC/MS) by Method 8260D WG1997560 1 02/01/23 0123 02/01/23 0123 DWR Semi -Volatile Organic Compounds (LCMS) by Method SW-846 8321 WG1998509 1 02/03/23 08:59 02/06/2314:41 AMG Pesticides (GC) by Method 8081B WG1998181 1 02/02/23 08:38 02/03/2314:45 RDH Semi Volatile Organic Compounds (GC/MS) by Method 8270E WG1998182 1 02/01/23 22:28 02/02/2312:59 CCW Location FC Mt. Juliet, TN Mt. Juliet, TN Mt. Juliet, TN Mt. Juliet, TN Mt. Juliet, TN Fn Mt. Juliet, TN Mt. Juliet, TN Mt. Juliet, TN Fr Mt. Juliet, TN Mt. Juliet, TN Rc Mt. Juliet, TN Mt. Juliet, TN GI SAI RC ACCOUNT: PROJECT: SDG: DATE/TIME: EMA Resources L1579735 02/07/23 13:01 PAGE: 3 of 22 CASE NARRATIVE All sample aliquots were received at the correct temperature, in the proper containers, with the FP appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples FC have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my FS knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. 0 Fr FQ-cl GI Cassandra Foster Project Manager RC Project Narrative All Reactive Cyanide results reported in the attached report were determined as totals using method 9012 B. All Reactive Sulfide results reported in the attached report were determined as totals using method 9034-903013. ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1579735 02/07/23 13:01 4 of 22 SAMPLE RESULTS - 01 L1579735 NORTH DIGESTER Collected date/time: 01/25/23 08:05 Preparation by Method 1311 Result Qualifier Prep Batch Analyte date / time TCLP Extraction 1/31/2023 9:19:10 AM WG1996662 TCLP ZHE Extraction - 1/30/202312:43:39 PM WG1996665 Fluid 1 1/31/2023 9:19:10 AM WG1996662 Initial pH 7.54 1/31/2023 9:19:10 AM WG1996662 Final pH 4.65 1/31/2023 9:19:10 AM WG1996662 Wet Chemistry by Method 9012 B Result Qualifier RDL Analyte mg/kg mg/kg Reactive Cyanide ND 0.250 Wet Chemistry by Method 9034-9030B Result Qualifier RDL Analyte mg/kg mg/kg Reactive Sulfide ND 75.0 Wet Chemistry by Method 9045D Dilution Analysis Batch date / time 1 01/31/202316:52 WG1997323 Dilution Analysis Batch date / time 1 01/31/202317:39 WG1995314 Result Qualifier Dilution Analysis Batch Analyte su date / time Corrosivity by pH 7.53 T8 1 01/27/202315:52 WG1995819 Sample Narrative: L1579735-01 WG1995819:7.53 at19.4C Wet Chemistry by Method D93/1010A Result Analyte Deg. F Ignitability DNI at170 Mercury by Method 7470A Qualifier Dilution Analysis Batch date / time 1 01/31/2023 0146 WG1997129 Result Qualifier RDL Limit Analyte mg/I mg/I mg/I Mercury ND 0.0100 0.20 Metals (ICP) by Method 6010D Result Qualifier RDL Limit Analyte mg/I mg/I mg/I Arsenic ND 0.100 5 Barium ND 0.100 100 Cadmium ND 0.100 1 Chromium ND 0.100 5 Lead ND 0.100 5 Selenium ND 0.100 1 Silver ND 0.100 5 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier RDL Limit Analyte mg/I mg/I mg/I Benzene ND 0.0500 0.50 Carbon tetrachloride ND 0.0500 0.50 Chlorobenzene ND 0.0500 100 Chloroform ND 0.250 6 ACCOUNT: PROJECT: EMA Resources Dilution Analysis Batch date / time 1 02/01/202314:30 WG1997957 Dilution Analysis Batch date / time 1 02/01/202318:39 WG1998017 1 02/01/202318:39 WG1998017 1 02/01/202318:39 WG1998017 1 02/01/202318:39 WG1998017 1 02/01/202318:39 WG1998017 1 02/01/202318:39 WG1998017 1 02/01/202318:39 WG1998017 Dilution Analysis Batch date / time 1 02/01/2023 0123 WG1997560 1 02/01/2023 0123 WG1997560 1 02/01/2023 0123 WG1997560 1 02/01/2023 0123 WG1997560 SDG: DATE/TIME: PAGE: L1579735 02/07/23 13:01 5 of 22 NORTH DIGESTER SAMPLE RESULTS Collected date/time: 01/25/23 08:05 L1579735 Volatile Organic Compounds (GC/MS) by Method 8260D - 01 Result Qualifier RDL Limit Dilution Analysis Batch Analyte mg/I mg/I mg/I date/time 1,2-Dichloroethane ND 0.0500 0.50 1 02/01/2023 0123 WG1997560 1,1-Dichloroethene ND 0.0500 0.70 1 02/01/2023 0123 WG1997560 2-Butanone (MEK) ND 0.500 200 1 02/01/2023 0123 WG1997560 Tetrachloroethene ND 0.0500 0.70 1 02/01/2023 0123 WG1997560 Trichloroethene ND 0.0500 0.50 1 02/01/2023 0123 WG1997560 Vinyl chloride ND 0.0500 0.20 1 02/01/2023 0123 WG1997560 (S) Toluene-dH 107 80.0-120 0210112023 01.23 WG1997560 (S) 4-Bromofluorobenzene 89.6 77.0-126 0210112023 01.23 WG1997560 (S) 1,2-Dichloroethane-d4 94.6 70.0-130 021011202301.23 WG1997560 Semi -Volatile Organic Compounds (LCMS) by Method SW-846 8321 Result Analyte mg/I 2,4-D ND 2,4,5-TP (Silvex) ND (S) Z4-DB-D3 101 Pesticides (GC) by Method 8081B Qualifier RDL Limit Dilution Analysis Batch mg/I mg/I date / time 0.0200 10 1 02/06/202314:41 WG1998509 0.0200 1 1 02/06/202314:41 WG1998509 70.0-130 021061202314.41 WG1998509 Result Qualifier RDL Limit Analyte mg/I mg/I mg/I Chlordane ND 0.00500 0.03 Endrin ND 0.00500 0.02 Heptachlor ND 0.00500 0.0080 Heptachlor epoxide ND 0.00500 0.0080 Lindane ND 0.00500 0.40 Methoxychlor ND 0.00500 10 Toxaphene ND 0.0100 0.50 (S) Decochlorobiphenyl 50.8 10.0-128 (S) Tetrochloro-m-xylene 64.6 10.0-127 Semi Volatile Organic Compounds (GC/MS) by Method 8270E Analyte 1,4-Dichlorobenzene 2,4-Dinitrotoluene Hexachlorobenzene Hexachloro-1,3-butadiene Hexachloroethane Nitrobenzene Pyridine 3&4-Methyl Phenol 2-Methylphenol Pentachlorophenol 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol (S) 2-Fluorophenol (S) Phenol-d5 (S) Nitrobenzene-d5 (S) 2-Fluorobiphenyl (S) Z4, 6-Tribromophenol (S) p-Terphenyl-d14 ACCOUNT: EMA Resources Dilution Analysis date / time 1 02/03/202314:45 1 02/03/202314:45 1 02/03/202314:45 1 02/03/202314:45 1 02/03/202314:45 1 02/03/202314:45 1 02/03/202314:45 0210312023 14.45 0210312023 14.45 Batch WG1998181 WG1998181 WG1998181 WG1998181 WG1998181 WG1998181 WG1998181 WG1998181 WG1998181 Result Qualifier RDL Limit Dilution Analysis Batch mg/I mg/I mg/I date/time ND 0.100 7.50 1 02/02/202312:59 WG1998182 ND 0.100 0.13 1 02/02/202312:59 WG1998182 ND 0.100 0.13 1 02/02/202312:59 WG1998182 ND 0.100 0.50 1 02/02/202312:59 WG1998182 ND 0.100 3 1 02/02/202312:59 WG1998182 ND 0.100 2 1 02/02/202312:59 WG1998182 ND 0.100 5 1 02/02/202312:59 WG1998182 ND 0.100 400 1 02/02/202312:59 WG1998182 ND 0.100 200 1 02/02/202312:59 WG1998182 ND 0.100 100 1 02/02/202312:59 WG1998182 ND 0.100 400 1 02/02/202312:59 WG1998182 ND 0.100 2 1 02/02/202312:59 WG1998182 35.1 10.0-120 021021202312.59 WG1998182 25.7 10.0-120 021021202312.59 WG1998182 60.6 10.0-127 021021202312.59 WG1998182 58.4 10.0-130 021021202312.59 WG1998182 67.0 10.0-155 021021202312.59 WG1998182 67.2 10.0-128 021021202312.59 WG1998182 PROJECT: SDG: DATE/TIME: PAGE: L1579735 02/07/23 13:01 6 of 22 WG1997323 QUALITY CONTROL SUMMARY Wet Chemistry by Method 9012 B L1579735-01 Method Blank (MB) C p (MB) R3336214-1 01/31/2316:43 MB Result MB Qualifier MB MDL MB RDL Analyte mg/kg mg/kg mg/kg TC I Reactive Cyanide U 0.0390 0.250 FS L1579757-05 Original Sample (OS) • Duplicate (DUP) [�n] (OS) L1579757-05 01/31/2316:56 • (DUP) R3336214-3 01/31/2316:57 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits F Analyte mg/kg mg/kg Reactive Cyanide ND ND 1 12.0 20 L1579757-08 Original Sample (OS) • Duplicate (DUP) GI (OS) L1579757-08 01/31/2317:02 • (DUP) R3336214-4 01/31/2317:03 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits FAI Analyte mg/kg mg/kg Reactive Cyanide 0.282 ND 1 16.6 20 FSc Laboratory Control Sample (LCS) (LCS) R3886214-2 01/31/23 16:49 Spike Amount LCS Result LCS Rec. Analyte mg/kg mg/kg Reactive Cyanide 2.50 2.38 95.3 Rec. Limits LCS Qualifier 85.0-115 L1579757-13 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1579757-13 01/31/2317:03 • (MS) R3336214-5 01/31/2317:09 • (MSD) R3336214-6 01/31/2317:10 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/kg mg/kg mg/kg mg/kg Reactive Cyanide 1.66 ND 1.10 1.09 56.1 55.7 1 75.0-125 J6 J6 0.638 20 Sample Narrative: MS: Matrix spike failure due to matrix. MSD: Matrix spike failure due to matrix. ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1579735 02/07/23 13:01 7 of 22 WG1995314 Wet Chemistry by Method 9034-9030B Method Blank (MB) (MB) R3886483-1 01/31/231739 MB Result MB Qualifier MB MDL Analyte mg/kg mg/kg Reactive Sulfide U 30.0 Laboratory Control Sample (LCS) (LCS) R3886483-2 01/31/23 1739 Spike Amount LCS Result LCS Rec. Analyte mg/kg mg/kg Reactive Sulfide 100 95.3 95.3 QUALITY CONTROL SUMMARY L1579735-01 MB RDL mg/kg 75.0 Rec. Limits LCS Qualifier 53.8-124 L1580173-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1530173-03 01/31/2317:39 • (MS) R3336483-3 01/31/2317:39 • (MSD) R3336483-4 01/31/2317:39 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/kg mg/kg mg/kg mg/kg Reactive Sulfide 100 ND ND ND 36.3 51.2 1 10.0-136 0.000 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1579735 02/07/23 13:01 3 of 22 WG1995819 QUALITY CONTROL SUMMARY Wet Chemistry by Method 9045D L1579735-01 Laboratory Control Sample (LCS) C (LCS) R3335230-1 01/27/231552 p Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier ITC] Analyte su su % % Corrosivity by pH 10.0 9.90 99.0 99.0-101 F Sample Narrative: SS LCS: 9.9 at18C [Cn] 5 Sr �GI FAI FSC1 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1579735 02/07/23 13:01 9 of 22 WG1997129 QUALITY CONTROL SUMMARY Wet Chemistry by Method D93/1010A L1579735-01 L1579735-01 Original Sample (OS) • Duplicate (DUP) (OS) L1579735-01 01/31/23 0146 • (DUP) R3335376-3 01/31/23 0146 Original Result DUP Result Dilution DUP RPD Analyte Deg. F Deg. F Ignitability DNI at170 DNI at170 1 0.000 L1580173-04 Original Sample (OS) • Duplicate (DUP) DUP Qualifier DUP RPD Limits i 10 (OS) L1530173-04 01/31/23 01:46 • (DUP) R3335376-4 01/31/23 0146 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte Deg. F Deg. F Ignitability DNI at170 DNI at170 1 0.000 10 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3335376-1 01/31/23 01:46 • (LCSD) R3335376-2 01/31/23 0146 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte Deg. F Deg. F Deg. F Ignitability 126 128 128 102 102 95.6-104 0.000 10 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1579735 02/07/23 13:01 10 of 22 WG1997957 QUALITY CONTROL SUMMARY Mercury by Method 7470A L1579735-01 Method Blank (MB) (MB) R3886455-1 02/01/231337 MB Result MB Qualifier MB MDL MB RDL Analyte mg/I mg/I mg/I Mercury U 0.00330 0.0100 Laboratory Control Sample (LCS) (LCS) R3886455-2 02/01/23 13:39 Spike Amount LCS Result LCS Rec. Analyte mg/I mg/I Mercury 0.0300 0.0281 93.7 Rec. Limits LCS Qualifier 80.0-120 L1579559-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1579559-01 02/01/23 13:42 • (MS) R3336455-3 02/01/23 13:44 • (MSD) R3336455-4 02/01/23 13:46 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/I mg/I mg/I mg/I Mercury 0.0300 ND 0.0301 0.0299 100 99.7 1 75.0-125 0.667 20 L1579721-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1579721-02 02/01/2313:43 • (MS) R3336455-5 02/01/2313:50 • (MSD) R3336455-6 02/01/2313:53 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/I mg/I mg/I mg/I Mercury 0.0300 ND 0.0307 0.0312 102 104 1 75.0-125 1.62 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1579735 02/07/23 13:01 11 of 22 WG1998017 Metals (ICP) by Method 6010D Method Blank (MB) (MB) R3886553-1 02/01/231723 MB Result MB Qualifier MB MDL MB RDL Analyte mg/I mg/I mg/I Arsenic U 0.0333 0.100 Barium U 0.0333 0.100 Cadmium U 0.0333 0.100 Chromium U 0.0333 0.100 Lead U 0.0333 0.100 Selenium U 0.0333 0.100 Silver U 0.0333 0.100 Laboratory Control Sample (LCS) (LCS) R3886553-2 02/01/23 1730 QUALITY CONTROL SUMMARY L1579735-01 Spike Amount LCS Result LCS Rec. Rec. Limits Analyte mg/I mg/I Arsenic 10.0 9.61 96.1 80.0-120 Barium 10.0 9.95 99.5 80.0-120 Cadmium 10.0 9.78 97.8 80.0-120 Chromium 10.0 9.51 95.1 80.0-120 Lead 10.0 9.57 95.7 80.0-120 Selenium 10.0 9.99 99.9 80.0-120 Silver 2.00 1.93 96.3 80.0-120 LCS Qualifier L1579694-06 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1579694-06 02/01/23 17:34 • (MS) R3336553-4 02/01/23 17:39 • (MSD) R3336553-5 02/01/23 17:42 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Analyte mg/I mg/I mg/I mg/I Arsenic 10.0 ND 10.5 10.5 105 104 Barium 10.0 0.750 10.6 10.5 98.0 97.6 Cadmium 10.0 0.560 11.3 11.2 107 106 Chromium 10.0 ND 9.40 9.31 94.0 93.1 Lead 10.0 ND 10.1 9.99 100 99.3 Selenium 10.0 0.226 10.9 11.0 107 107 Silver 2.00 ND 2.19 2.17 110 109 Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits 1 75.0-125 0.548 20 1 75.0-125 0.371 20 1 75.0-125 0.647 20 1 75.0-125 0.997 20 1 75.0-125 1.17 20 1 75.0-125 0.524 20 1 75.0-125 0.870 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1579735 02/07/23 13:01 12 of 22 WG1998017 QUALITY CONTROL SUMMARY Metals (ICP) by Method 6010D L1579735-01 L1579718-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1579713-02 02/01/23 17:45 • (MS) R3336553-6 02/01/23 17:43 • (MSD) R3336553-7 02/01/2317:50 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Analyte mg/I mg/I mg/I mg/I Arsenic 10.0 ND 9.86 9.83 98.6 98.3 Barium 10.0 ND 10.1 10.1 100 101 Cadmium 10.0 ND 9.89 9.93 98.9 99.3 Chromium 10.0 ND 9.58 9.58 95.8 95.8 Lead 10.0 ND 9.71 9.79 97.1 97.9 Selenium 10.0 ND 10.0 10.0 99.5 99.4 Silver 2.00 ND 1.95 1.96 97.4 98.0 ACCOUNT: EMA Resources PROJECT: Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits 1 75.0-125 0.260 20 1 75.0-125 0.395 20 1 75.0-125 0.446 20 1 75.0-125 0.0516 20 1 75.0-125 0.873 20 1 75.0-125 0.162 20 1 75.0-125 0.591 20 SDG: DATE/TIME: PAGE: L1579735 02/07/23 13:01 13 of 22 WG1997560 QUALITY CONTROL SUMMARY Volatile Organic Compounds (GC/MS) by Method 8260D L1579735-01 Method Blank (MB) (MB) R3336511-3 01/31/23 22:26 MB Result MB Qualifier MB MDL MB RDL Analyte mg/I mg/I mg/I Benzene U 0.0167 0.0500 Carbon tetrachloride U 0.0167 0.0500 Chlorobenzene U 0.0167 0.0500 Chloroform U 0.0833 0.250 1,2-Dichloroethane U 0.0167 0.0500 1,1-Dichloroethene U 0.0167 0.0500 2-Butanone (MEK) U 0.167 0.500 Tetrachloroethene U 0.0167 0.0500 Trichloroethene U 0.0167 0.0500 Vinyl chloride U 0.0167 0.0500 (S) Toluene-dH 112 80.0-120 (S) 4-Bromofluorobenzene 84.4 77.0-126 (S) 1,2-Dichloroethane-d4 97.1 70.0-130 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3336511-1 01/31/23 20:13 • (LCSD) R3336511-2 01/31/23 2142 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte mg/I mg/I mg/I Benzene 0.250 0.230 0.250 92.0 100 70.0-123 8.33 20 Carbon tetrachloride 0.250 0.223 0.261 89.2 104 68.0-126 15.7 20 Chlorobenzene 0.250 0.266 0.280 106 112 80.0-121 5.13 20 Chloroform 0.250 0.217 0.243 86.8 97.2 73.0-120 11.3 20 1,2-Dichloroethane 0.250 0.212 0.233 84.8 93.2 70.0-128 9.44 20 1,1-Dichloroethene 0.250 0.201 0.232 80.4 92.8 71.0-124 14.3 20 2-Butanone (MEK) 1.25 1.00 1.12 80.0 89.6 44.0-160 11.3 20 Tetrachloroethene 0.250 0.277 0.309 ill 124 72.0-132 10.9 20 Trichloroethene 0.250 0.264 0.309 106 124 78.0-124 15.7 20 Vinyl chloride 0.250 0.233 0.284 93.2 114 67.0-131 19.7 20 (S) Toluene-dH ill ill 80.0-120 (S) 4-Bromofluorobenzene 89.6 90.6 77.0-126 (S) 1,2-Dichloroethane-d4 94.8 92.0 70.0-130 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1579735 02/07/23 13:01 14 of 22 WG1997560 QUALITY CONTROL SUMMARY Volatile Organic Compounds (GC/MS) by Method 8260D L1579735-01 L1579950-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1579950-01 02/01/23 02:51 • (MS) R3336511-4 02/01/23 06:09 • (MSD) R3336511-5 02/01/23 06:31 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Analyte mg/I mg/I mg/I mg/I Benzene 0.250 ND 0.140 0.195 56.0 78.0 Carbon tetrachloride 0.250 ND 0.0991 0.192 39.6 76.8 Chlorobenzene 0.250 ND 0.188 0.250 75.2 100 Chloroform 0.250 ND ND ND 58.8 76.0 1,2-Dichloroethane 0.250 ND 0.178 0.193 71.2 77.2 1,1-Dichloroethene 0.250 ND 0.0827 0.145 33.1 58.0 2-Butanone (MEK) 1.25 ND 1.22 1.14 97.6 91.2 Tetrachloroethene 0.250 ND 0.127 0.236 50.8 94.4 Trichloroethene 0.250 ND 0.149 0.227 59.6 90.8 Vinyl chloride 0.250 ND 0.109 0.198 43.6 79.2 (S) Toluene-dH 106 109 (S) 4-Bromofluorobenzene 90.8 91.6 (S) 1,2-Dichloroethane-d4 91.8 89.4 ACCOUNT: EMA Resources PROJECT: Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits 1 17.0-158 J3 32.8 27 1 23.0-159 J3 63.8 28 1 33.0-152 J3 28.3 27 1 29.0-154 25.5 28 1 29.0-151 8.09 27 1 11.0-160 J3 54.7 29 1 10.0-160 6.78 32 1 10.0-160 J3 60.1 27 1 10.0-160 J3 41.5 25 1 10.0-160 J3 58.0 27 80.0-120 77.0-126 70.0-130 SDG: DATE/TIME: PAGE: L1579735 02/07/23 13:01 15 of 22 WG1998509 QUALITY CONTROL SUMMARY Semi -Volatile Organic Compounds (LCMS) by Method SW-846 8321 L1579735-01 Method Blank (MB) (MB) R3887909-2 02/06/231210 MB Result Analyte mg/I 2,4-D U 2,4,5-TP (Silvex) U (S) Z4-DB-D3 93.5 MB Qualifier MB MDL MB RDL mg/I mg/I 0.00667 0.0200 0.00667 0.0200 70.0-130 Laboratory Control Sample (LCS) (LCS) R3887909-1 02/06/23 1148 Spike Amount LCS Result Analyte mg/I mg/I 2,4-D 0.200 0.202 2,4,5-TP (Silvex) 0.200 0.207 (S) Z4-DB-D3 LCS Rec. Rec. Limits LCS Qualifier 101 70.0-130 104 70.0-130 103 70.0-130 L1579501-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1579501-01 02/06/2312:53 • (MS) R3337909-3 02/06/2313:15 • (MSD) R3337909-4 02/06/2313:37 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/I mg/I mg/I mg/I 2,4-D 0.200 ND 0.215 0.203 108 102 1 70.0-130 5.74 30 2,4,5-TP (Silvex) 0.200 ND 0.199 0.203 99.5 102 1 70.0-130 1.99 30 (S) Z4-DB-D3 89.5 88.0 70.0-130 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1579735 02/07/23 13:01 16 of 22 WG1998181 Pesticides (GC) by Method 8081B Method Blank (MB) (MB) R3887533-1 02/03/231317 MB Result MB Qualifier Analyte mg/I Chlordane U Endrin U Heptachlor U Heptachlor epoxide U Gamma BHC U Methoxychlor U Toxaphene U (S) Decachlorobiphenyl 76.9 (S) Tetrochloro-m-xylene 68.5 Laboratory Control Sample (LCS) (LCS) R3887533-2 02/03/23 13:25 Spike Amount LCS Result Analyte mg/I mg/I Endrin 0.0100 0.0104 Heptachlor 0.0100 0.0112 Heptachlor epoxide 0.0100 0.00995 Gamma BHC 0.0100 0.00983 Methoxychlor 0.0100 0.0122 (S) Decachlorobiphenyl (S) Tetrochloro-m-xylene QUALITY CONTROL SUMMARY L1579735-01 MBMDL mg/I MBRDL mg/I 0.00167 0.00500 0.00167 0.00500 0.00167 0.00500 0.00167 0.00500 0.00167 0.00500 0.00167 0.00500 0.00333 0.0100 LCS Rec. 104 112 99.5 98.3 122 80.3 70.7 10.0-128 10.0-127 Rec. Limits LCS Qualifier 57.0-134 27.0-132 57.0-130 55.0-129 54.0-155 10.0-128 10.0-127 L1579735-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1579735-01 02/03/23 14:45 • (MS) R3337533-3 02/03/23 14:54 • (MSD) R3337533-4 02/03/23 15:03 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/I mg/I mg/I mg/I Endrin 0.0100 ND 0.00842 0.00976 84.2 97.6 1 10.0-160 14.7 39 Heptachlor 0.0100 ND 0.00915 0.0107 91.5 107 1 16.0-136 15.6 40 Heptachlor epoxide 0.0100 ND 0.00811 0.00942 81.1 94.2 1 10.0-160 14.9 36 Gamma BHC 0.0100 ND 0.00857 0.00981 85.7 98.1 1 14.0-141 13.5 40 Methoxychlor 0.0100 ND 0.00961 0.0114 96.1 114 1 10.0-160 17.0 34 (S) Decachlorobiphenyl 46.8 61.7 10.0-128 (S) Tetrochloro-m-xylene 64.1 71.9 10.0-127 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1579735 02/07/23 13:01 17 of 22 WG1998182 QUALITY CONTROL SUMMARY Semi Volatile Organic Compounds (GC/MS) by Method 8270E L1579735-01 Method Blank (MB) (MB) R3886726-2 02/02/231009 MB Result MB Qualifier MB MDL MB RDL Analyte mg/I mg/I mg/I 1,4-Dichlorobenzene U 0.0333 0.100 2,4-Dinitrotoluene U 0.0333 0.100 Hexachlorobenzene U 0.0333 0.100 Hexachloro-1,3-butadiene U 0.0333 0.100 Hexachloroethane U 0.0333 0.100 Nitrobenzene U 0.0333 0.100 Pyridine U 0.0333 0.100 3&4-Methyl Phenol U 0.0333 0.100 2-Methylphenol U 0.0333 0.100 Pentachlorophenol U 0.0333 0.100 2,4,5-Trichlorophenol U 0.0333 0.100 2,4,6-Trichlorophenol U 0.0333 0.100 (S) 2-Fluorophenol 38.6 10.0-120 (S) Phenol-d5 25.1 10.0-120 (S) Nitrobenzene-d5 66.4 10.0-127 (S) 2-Fluorobiphenyl 66.8 10.0-130 (S) 2,4, 6-Tribromophenol 74.5 10. 0-155 (S) p-Terphenyl-d14 75.8 10.0-128 Laboratory Control Sample (LCS) (LCS) R3886726-1 02/02/23 09:47 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte mg/I mg/I 1,4-Dichlorobenzene 0.500 0.322 64.4 18.0-120 2,4-Dinitrotoluene 0.500 0.435 87.0 49.0-124 Hexachlorobenzene 0.500 0.371 74.2 44.0-120 Hexachloro-1,3-butadiene 0.500 0.335 67.0 19.0-120 Hexachloroethane 0.500 0.339 67.8 15.0-120 Nitrobenzene 0.500 0.364 72.8 27.0-120 Pyridine 0.500 0.113 22.6 10.0-120 3&4-Methyl Phenol 0.500 0.259 51.8 31.0-120 2-Methylphenol 0.500 0.268 53.6 28.0-120 Pentachlorophenol 0.500 0.397 79.4 23.0-120 2,4,5-Trichlorophenol 0.500 0.399 79.8 44.0-120 2,4,6-Trichlorophenol 0.500 0.388 77.6 42.0-120 (S) 2-Fluorophenol 42.4 10.0-120 (S) Phenol-d5 29.2 10.0-120 (S) Nitrobenzene-d5 65.1 10.0-127 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1579735 02/07/23 13:01 18 of 22 WG1998182 QUALITY CONTROL SUMMARY Semi Volatile Organic Compounds (GC/MS) by Method 8270E L1579735-01 Laboratory Control Sample (LCS) (LCS) R3886726-1 02/02/23 09:47 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte mg/I mg/I (S) 2-Fluorobiphenyl 73.7 10.0-130 (S) 2,4, 6-Tribromophenol 83.0 10. 0-155 (S) p-Terphenyl-d14 77.0 10.0-128 L1579559-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1579559-01 02/02/2311:55 • (MS) R3336726-3 02/02/2312:16 • (MSD) R3336726-4 02/02/2312:37 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits Analyte mg/I mg/I mg/I mg/I 1,4-Dichlorobenzene 0.500 ND 0.294 0.283 58.8 56.6 1 17.0-120 2,4-Dinitrotoluene 0.500 ND 0.399 0.351 79.8 70.2 1 39.0-125 Hexachlorobenzene 0.500 ND 0.346 0.305 69.2 61.0 1 35.0-122 HexachIaro-1,3-butadiene 0.500 ND 0.306 0.292 61.2 58.4 1 12.0-120 Hexachloroethane 0.500 ND 0.308 0.296 61.6 59.2 1 10.0-120 Nitrobenzene 0.500 ND 0.335 0.310 67.0 62.0 1 12.0-120 Pyridine 0.500 ND 0.202 0.175 40.4 35.0 1 10.0-120 3&4-Methyl Phenol 0.500 ND 0.263 0.244 52.6 48.8 1 10.0-120 2-Methylphenol 0.500 ND 0.274 0.248 54.8 49.6 1 10.0-120 Pentachlorophenol 0.500 ND 0.355 0.327 71.0 65.4 1 10.0-128 2,4,5-Trichlorophenol 0.500 ND 0.382 0.340 76.4 68.0 1 33.0-120 2,4,6-Trichlorophenol 0.500 ND 0.375 0.327 75.0 65.4 1 26.0-120 (S) 2-Fluorophenol 42.4 38.4 10.0-120 (S) Phenol-d5 27.0 25.4 10.0-120 (S) Nitrobenzene-d5 57.8 56.4 10.0-127 (S) 2-Fluorobiphenyl 68.9 60.0 10.0-130 (S)2,4,6-Tribromophenol 76.5 64.0 10.0-155 (S) p-Terphenyl-d14 69.5 60.0 10.0-128 MS Qualifier MSD Qualifier RPD RPD Limits 3.81 40 12.8 25 12.6 24 4.68 34 3.97 40 7.75 30 14.3 37 7.50 36 9.96 30 8.21 37 11.6 31 13.7 31 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1579735 02/07/23 13:01 19 of 22 GLOSSARY OF TERMS Guide to Reading and Understanding Your Laboratory Report The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and ifyou have additional questions please contactyour project representative. Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name, Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On -Site Data, Sampling Collection Dates/Times, and Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received. Abbreviations and Definitions u Fc Fss] MDL Method Detection Limit. ND Not detected at the Reporting Limit (or MDL where applicable). Fn RDL Reported Detection Limit. Rec. Recovery. Fr RPD Relative Percent Difference. SDG Sample Delivery Group. Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and F (S) Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be detected in all environmental media. U Not detected at the Reporting Limit (or MDL where applicable). Analyte The name ofthe particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported. Ifthe sample matrix contains an interfering material, the sample preparation volume or weight values differ from the F Dilution standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor. Rc These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal Limits for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or duplicated within these ranges. Original Sample The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control sample. The Original Sample may not be included within the reported SDG. This column provides a letter and/or number designation that corresponds to additional information concerning the result Qualifier reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications ofthe Qualifier in the Case Narrative if applicable. The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. Ifthere was no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL" Result (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte. Uncertainty (Radiochemistry) Confidence level of 2 sigma. A brief discussion about the included sample results, including a discussion of any non -conformances to protocol Case Narrative (Cn) observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report. Quality Control This section ofthe report includes the results ofthe laboratory quality control analyses required by procedure or Summary (Qc) analytical methods to assist in evaluating the validity ofthe results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material. This is the document created in the field when your samples were initially collected. This is used to verify the time and Sample Chain of date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This Custody (Sc) chain of custody also documents all persons (excluding commercial shippers) that have had control or possession ofthe samples from the time of collection until delivery to the laboratory for analysis. This section ofyour report will provide the results of all testing performed on your samples. These results are provided Sample Results (Sr) by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for each sample will provide the name and method number for the analysis reported. Sample Summary (Ss) This section ofthe Analytical Report defines the specific analyses performed for each sample ID, including the dates and times of preparation and/or analysis. Qualifier Description J3 The associated batch QC was outside the established quality control range for precision. J6 The sample matrix interfered with the ability to make any accurate determination, spike value is low. T8 Sample(s) received past/too close to holding time expiration. ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1579735 02/07/23 13:01 20 of 22 ACCREDITATIONS & LOCATIONS Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122 Alabama 40660 Nebraska N E-OS-15-05 Alaska 17-026 Nevada TN000032021-1 Arizona AZ0612 New Hampshire 2975 Arkansas 88-0469 New Jersey—NELAP TNO02 California 2932 New Mexico TN00003 Colorado TN00003 New York 11742 Connecticut PH-0197 North Carolina Env375 Florida E87487 North Carolina' DW21704 _ Georgia NELAP North Carolina 3 41 Georgia' 923 North Dakota R-140 Idaho TN00003 Ohio—VAP CL0069 Illinois 200008 Oklahoma 9915 Indiana C-TN-01 Oregon TN200002 Iowa 364 Pennsylvania 68-02979 Kansas E-10277 Rhode Island LA000356 Kentucky' 6 KY90010 South Carolina 84004002 Kentucky 2 16 South Dakota n/a Louisiana A130792 Tennessee'" 2006 Louisiana LA018 Texas T104704245-20-18 Maine TN00003 Texas5 LABO152 Maryland 324 Utah TN000032021-11 Massachusetts M-TNO03 Vermont VT2006 Michigan 9958 Virginia 110033 Minnesota 047-999-395 Washington C847 Mississippi TN00003 West Virginia 233 Missouri 340 Wisconsin 998093910 Montana CERT0086 Wyoming A2 LA A2LA— ISO 17025 1461.01 AIHA-LAP,LLC EMLAP 100789 A2 LA — ISO 17025 5 1461.02 DOD 1461.01 Canada 1461.01 USDA P330-15-00234 EPA—Crypto TN00003 Drinking Water 2 Underground Storage Tanks 3 Aquatic Toxicity "Chemical/Microbiological 5 Mold 6 Wastewater n/a Accreditation not applicable Not all certifications held by the laboratory are applicable to the results reported in the attached report. Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical. Rc ACCOUNT: PROJECT: SDG: DATE/TIME: EMA Resources L1579735 02/07/23 13:01 PAGE: 21 of 22 Company Name/Address: EMA Resources 755 Yadkinville Road Mocksville, NC 27028 Report to: Mr. Brent Collins Project Description: Sludge Phone: 336-751-1441 Collected by (print): CFg"'1 LsatI s Collected by (signature): /0� Immediately Packed on Ice N Y ✓ Sample ID No��r"' P:SCs�r ' Matrix: 5S - Soil AIR - Air F - Filter GW- Groundwater B- Bioassay WW - wastewater DW -Thinking Water OT - Other Relinquished by : (Signaturel Relinquished by: (Signature) Relinquished by : (Signature) Billing Information Mr. Brent Collins LC'hCk' 7S5 Yadkinville Road Mocksville, NC 27028 Small To brent.collin s@e maresou rcesi nc. tom; roy.whita k City/State aG/. Please Circle: ' Collected: / rlli•1«�� PT MT CT C Project # ILab Project # v Site/Facaity ID # P.O. # z ai Q L R ? (Lab MUST Be Notified) Quote # Same Day Five Day z V J Next Day 5 Day Iliad Only) Date Results Needed ri _ _ Two Day _ 10 Day (Rad Only) No. V _ —Three Day of r�-t � U Camp/Grab Matrix' Depth Date Time ntrs u r— r ss 3` ►12SIZ3 9;aS z X X Samples returned via: —UPS _ FedEx _Courier bate: 1/yslz 3 Date: Date: Tracking r �� Time: Received by (Signature) UUU 3= 3 0 Time: Received by: (Signature) Time, Received for lab by: (Signature) i Chain of Custody "age— of _ aceAnaWical >e 120651ebanon 0.d Mount 1.1w. TN SIL22 5�1,mittmga ample via this chain of custody —titutes acknaWledgment and acceptance Of the Pace Terms and COndkik— found -0 Mtpe:/Anfu.wtel,bs comlAuVs19.-s4andard- tarm.Pdr SDG # ! 5 / Cl I/'� L D165 Acctnum: EMARES Template:T11413 Prelogin: P895389 PM: 807-Justin r II `,} � PB: l sV4, snipped vlac Fed X Ground Remarks Sample 0 (lab only) 4 Sample ReceILL Checklist CGC Seal Present/Intact: CGC Signed/Accurate: rNP _y _N —N pH Temp Flow Other — —" Bottles arrive intact: Correct betties used: Sufficient volume sent: cable �r _N c/4/ N i11 N r y 9 Lf p f J ace VOA Zero Headapace: _Y N _N Preservation Correct/Checked: RP.D Screen <0.5 mR/hr: Y f Y _N Trip Blank Received: Yes / HCL/ MecH TRR Temp: I/ °C Bottles Received: If preservation required by Login: Date/Time 0,1 ate: 1./ Tme: Hold: Conditio J_I - / n OO NCF / OK ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Smithfield Fresh Meats Corp. WQ Permit Number: WQ0014868 WWTP Name: Tarheel WWTP NPDES Number: NCO078344 Monitoring Period: From l/l/2023 To 12/31/2023 Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) ❑ Alt B (Alk Treatment) &-, I Alt. C (Prior Testing) ❑ Alt.D (No Prior Test) ❑ 1 Process to Further Reduce Pathogengs ❑ If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost ❑ Heat Drying ❑ Heat Treatment ❑ Thermophilic ❑ Beta Ray ❑ Gamma Ray ❑ Pasteurization ❑ Class B: Alt. (1) Fecal Density 0 Alt. (2) Process to Significantly Reduce Pathogens ❑ If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization ❑ Air Drying ❑ Composting ❑ Aerobic Digestion ❑ Anaerobic Digestion ❑ If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density g � Number o 1;xcee- ences Frequency of Analysis Sample Type Analytical Tech -pique Minimum Geo. Mean Maximum Units Fecal Coliform 2 x 10 to the 6th power per gram of total solids MPN CFU 301508 404427 464986 CFU/ g 0 l Quarterly G SM9222D 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed: Alt. I (VS reduction) L Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) ❑ Alt. 4 (Spec. Oz uptake) ❑ Alt. 5 (14-Day Aerobic) ❑ Alt. 6 (Alk. Stabilization ❑ Alt 7 (Drying - Stable) jAlt. 8 (Drying - Unstable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) ❑ No vector attraction reduction alternatives were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) ❑`' "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." ❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Dwayne Russ - ORC Brent Collins; Director of Technical Services Preparer Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print) Dwa�n kgrlf 02i2 1 i2Z Dwayne Russ (Feb 21, 202401:40 EST) 2/l/2024 Signature of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM PVRF 02T (12/2006) Meritech, Inc. Environmental Laboratory Laboratory Certification No.165 r Contact: Brent Collins Client: EMA Resources, Inc 755 Yadkinville Road Page 1 Report Date: 2/8/2023 Mocksville, NC 27028 Date Sample Rcvd: 1/30/2023 Meritech Work Order # 01302303 Sample: North Digester 1 Grab 1/30/23 Parameters Result Analysis Date Reporting Limit Method % Total Solids 3.81 % 2/2/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) 383,202 CFU/g dry wt 1/30/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 01302304 Sample: North Digester 2 Grab 1/30/23 Parameters Result Analysis Date Reporting Limit Method % Total Solids 3.84 % 2/2/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) 416,667 CFU/g dry wt 1/30/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 0130230S Sample: North Digester 3 Grab 1/30/23 Parameters Result Analysis Date Reportinng Limit Method % Total Solids 3.98 % 2/2/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) 301,508 CFU/g dry wt 1/30/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 01302306 Sample: North Digester 4 Grab 1/30/23 Parameters Result Analysis Date Reporting Limit Method % Total Solids 3.46 % 2/2/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) 426,428 CFU/g dry wt 1/30/23 130 CFU/g dry wt SM 9222D 642 Tamco Road, Reidsville, North Carolina 27320 tel,(336)342-4748 fax.(336)342-1522 Meritech, Inc. Environmental Laboratory Laboratory Certification No.165 } �. Contact: Brent Collins Client: EMA Resources, Inc 755 Yadkinville Road Mocksville, NC 27028 Page 2 Report Date: 2/8/2023 Date Sample Rcvd: 1/30/2023 Meritech Work Order # 01302307 Sample: North Digester 5 Grab 1/30/23 Parameters Result Analysis Date Reporting Limit Method % Total Solids 3.13 % 2/2/23 0-100 % SM 2S40B Fecal Coliform (Class B Sludge) 431,310 CFU/g dry wt 1/30/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 01302308 Sample: North Digester 6 Grab 1/30/23 Parameters Result Analysis Date Reporting Limit Method % Total Solids 3.42 % 2/2/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) 429,825 CFU/g dry wt 1/30/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 01302309 Sample: North Digester 7 Grab 1/30/23 Parameters Result Analysis Date Reporting Limit Method % Total Solids 3.57 % 2/2/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) 464,986 CFU/g dry wt 1/30/23 130 CFU/g dry wt SM 9222D I hereby certify that I have reviewed and approve these data. AmafAa,±�c-(m� — Laboratory Representative 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 £ax.(336)342-1522 ❑ ❑ ❑ CD O -n rD rD m m fD r X m O o -- m z m a ro n O q O 3 '' ' 3 _ S. _ S. �. Z n as rD ¢ n p � m m c a C 0 N ci z a tA rD ro s z o m 0 C 7 V 0 3 rD b O rn NLn3 orpo Cr M sn � rD r a fli QrQ n n � W w 0 A uj W y v + 3 N N nm r�nA A � CL rV W rD CD ro r ro � O o > n ❑ Q d N rr Q �. N 7 n rt rt 3 ° �o m m L b = n !D n M. N 3 m _ CC C 07 CD b V m � n c" n C' c N �_ v m Q O rt Id1 D o a � b 5 a rD row Q o' p = rp b (D N �3�! v Z C_ n Q ( W V) F �' N v rp rD rr ro rf O N EL rD _- ru �� ^ ° W V) Q L D Q y o. O D (Ty n CD Q l L/ d (D x 2 w m O a X O �• — n v f m O m �— Qu+ a rD w w rn rn VOCL rn 0 3 ro 3 I.- F� F-- A Q rb D 00 N O r rD rD CL c N E., ^ 0 c ZrD n 6\� ❑ •1A� C Ln N O A a rD ® r O = o •tit .ti] ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Smithfield Fresh Meats Corp. WQ Permit Number: WQ0014868 WWTP Name: Tarheel WWTP NPDES Number: NCO078344 Monitoring Period: From l/l/2023 To 12/31/2023 Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) ❑ Alt B (Alk Treatment) &-, I Alt. C (Prior Testing) ❑ Alt.D (No Prior Test) ❑ 1 Process to Further Reduce Pathogengs ❑ If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost ❑ Heat Drying ❑ Heat Treatment ❑ Thermophilic ❑ Beta Ray ❑ Gamma Ray ❑ Pasteurization ❑ Class B: Alt. (1) Fecal Density 0 Alt. (2) Process to Significantly Reduce Pathogens ❑ If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization ❑ Air Drying ❑ Composting ❑ Aerobic Digestion ❑ Anaerobic Digestion ❑ If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density g � Number o 1;xcee- ences Frequency of Analysis Sample Type Analytical Tech -pique Minimum Geo. Mean Maximum Units Fecal Coliform 2 x 10 to the 6th power per gram of total solids MPN CFU 338824 486532 634146 CFU/ g 0 l Quarterly G SM9222D 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed: Alt. I (VS reduction) L Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) ❑ Alt. 4 (Spec. Oz uptake) ❑ Alt. 5 (14-Day Aerobic) ❑ Alt. 6 (Alk. Stabilization ❑ Alt 7 (Drying - Stable) jAlt. 8 (Drying - Unstable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) ❑ No vector attraction reduction alternatives were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) ❑`' "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." ❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Dwayne Russ - ORC Brent Collins; Director of Technical Services Preparer Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print) Dwa�n kgrlf 02i2 1 i2Z Dwayne Russ (Feb 21, 202401:40 EST) 2/l/2024 Signature of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM PVRF 02T (12/2006) Meritech, Inc. Environmental Laboratory Laboratory Certification No.165 Page 1 Contact: Brent Collins Report Date: 2/8/2023 Client: EMA Resources, Inc 755 Yadkinville Road Mocksville, NC 27028 Date Sample Rcvd: 1/30/2023 Meritech Work Order# 01302310 Sample: South Digester 1 Grab 1/30/23 Parameters Re u t Analysis Date Reporting Limit Method % Total Solids 2,77 % 2/2/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) 483,755 CFU/g dry wt 1/30/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 01302311 Sample: South Digester 2 Grab 1/30/23 Parameters Result Analysis Date Reporting Limit Method % Total Solids 2.33 % 2/2/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) 600,858 CFU/g drywt 1/30/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 01302312 Sample: South Digester 3 Grab 1/30/23 Parameters Result Analysis Date Reparting Limit Method % Total Solids 4.25 % 2/2/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) 338,824 CFU/g dry wt 1/30/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 01302313 Sample: South Digester 4 Grab 1/30/23 )Parameters Result Analysis Date Reporting Limit Method % Total Solids 2.05 % 2/2/23 0-100 % SM 2540E Fecal Coliform (Cass B Sludge) 634,146 CFU/g dry wt 1/30/23 130 CFU/g dry wt SM 9222D 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 Meritech, Inc. Environmental Laboratory Laboratory Certification No.165 lei - Page 2 Contact: Brent Collins Report Date: 2/8/2023 Client: EMA Resources, Inc 755 Yadkinville Road Mocksvdle, NC 27028 Date Sample Rcvd: 1/30/2023 Meritech Work Order # 01302314 Sample: South Digester 5 Grab 1/30/23 Parameters Result Analysis Date Reporting Limit Method % Total Solids 2.89 % 2/2/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) 467,128 CFU/g dry wt 1/30/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 0130231S Sample: South Digester 6 Grab 1/30/23 Parameters R. esult Analysis Date Reporting Limit Method % Total Solids 3.10 % 2/2/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) 451,613 CFU/g dry wt 1/30/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 01302316 Sample: South Digester 7 Grab 1/30/23 Parameters Result Analysis Date Reporting Limit Method % Total Solids 2.94 % 2/2/23 0-100 % SM 2540E Fecal Coliform. (Class B SIudge) 489,796 CFU/g drywt 1/30/23 130 CFU/g dry wt SM 9222D I hereby certify that I have reviewed and approve these data. Har)o Laboratory Representative 642 Tarnco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 ❑❑❑❑Ln 2 S C� O Ti CL c -0 3 r�D rD m f rVk� < rr g n O 3 �- S Q m S n rDw CL O rD A �. r r-r * � O c Z O ro o (Jt -r W N *# �p m ro 3 C � s 3 O .� T CL z o a o o m o w w m rD o m � Gf �• m x o r n rD W f7 y aj o ' w w n 3 rA un w m f� b ON O en� 0 N N m ip v m �• ID 7H6 3 N In d O CL NDO f m m r.3o Z M n D DrD C� O y r-r• 0- Q a o rb �• rL d z Z n x rr � p LA rn F-+ � O 3 � O I� I.. 11 ^ ID ro rD v — W V m Ln m rD O Ln D m � a O �_ Q O C o- rD a o O rD O c .T! rfi 0 rD 3 — Z n — n iS O (fi X- ro cn CL r+ O V 0 CL n iD �• � Q Lnn p 0 S O !R T •r3 re 1 r ti 6J � � 11 VV x �D D h 3 y 47— f _v m - - Z i' del n rp N � , � • • � G1 * ]..L cb to � �r w W w W m 3 � s C31 LJl m _� m Lh an S v UVi (n F� ti n 00 0 ^ 3 '�, rre O M O rorr rc .,y cn :3y, a �A, r C) N CLM W Xfi r o n p a n a - a O O ; v -y ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Smithfield Fresh Meats Corp. WQ Permit Number: WQ0014868 WWTP Name: Tarheel WWTP NPDES Number: NCO078344 Monitoring Period: From l/l/2023 To 12/31/2023 Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) ❑ Alt B (Alk Treatment) &-, I Alt. C (Prior Testing) ❑ Alt.D (No Prior Test) ❑ 1 Process to Further Reduce Pathogengs ❑ If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost ❑ Heat Drying ❑ Heat Treatment ❑ Thermophilic ❑ Beta Ray ❑ Gamma Ray ❑ Pasteurization ❑ Class B: Alt. (1) Fecal Density 0 Alt. (2) Process to Significantly Reduce Pathogens ❑ If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization ❑ Air Drying ❑ Composting ❑ Aerobic Digestion ❑ Anaerobic Digestion ❑ If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density g � Number o 1;xcee- ences Frequency of Analysis Sample Type Analytical Tech -pique Minimum Geo. Mean Maximum Units Fecal Coliform 2 x 10 to the 6th power per gram of total solids MPN CFU 93366 99962 104478 CFU/ g 0 l Quarterly G SM9222D 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed: Alt. I (VS reduction) L Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) ❑ Alt. 4 (Spec. Oz uptake) ❑ Alt. 5 (14-Day Aerobic) ❑ Alt. 6 (Alk. Stabilization ❑ Alt 7 (Drying - Stable) jAlt. 8 (Drying - Unstable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) ❑ No vector attraction reduction alternatives were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) ❑`' "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." ❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Dwayne Russ - ORC Brent Collins; Director of Technical Services Preparer Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print) Dwa�n kgrlf 02i2 1 i2Z Dwayne Russ (Feb 21, 202401:40 EST) 2/l/2024 Signature of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM PVRF 02T (12/2006) Meritech, Inc. Environmental Laboratory Laboratory Certification No.165 Contact: Brent Collins Client: EMA Resources, Inc 755 Yadkinville Road M k 11 NC 2 Page 1 Report Date: 3/29/2023 oc svi e, 7028 Date Sample Rcvd: 3/16/2023 Meritech Work Order # 03162313 Sample: Smithfield North 1 Grab 3/16/23 Parameters Result Analysis Date Reporting Limit Method % Total Solids 4.07 % 3/17/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) 93,366 CFU/g dry wt 3/16/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 03162314 Sample: Smithfield North 2 Grab 3/16/23 Parameters Result Analysis Date Reporting Limit Method % Total Solids 4.02 % 3/17/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) 104,478 CFU/g dry wt 3/16/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 03162315 Sample: Smithfield North 3 Grab 3/16/23 Parameters % Total Solids Fecal Coliform (Class B Sludge) Result Analysis Date Reporting limit Method 3.95 % 3/17/23 0-100 % SM 2540B 101,266 CFU/g dry wt 3/16/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 03162316 Sample: Smithfield North 4 Grab 3/16/23 Parameters Result % TotaI Solids 3.99 % Fecal Coliform (Class B Sludge) 102,757 CFU/g dry wt Analysis Date Reporting Limit Method 3/17/23 0-100 % SM 2540B 3/16/23 130 CFU/g dry wt SM 9222D 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)3424748 fax.(336)342-1522 Meritech, Inc. Environmental Laboratory Laboratory Certification No. 165 Contact: Brent Collins CIient: EMA Resources, Inc 755 Yadkinville Road Mocksville, NC 27028 Page 2 Report Date: 3/29/2023 Date Sample Rcvd: 3/16/2023 Meritech Work Order # 03162317 Sample: Smithfield North 5 Grab 3/16/23 Parameters Result Analysis Date Re orting Limit Method % Total Solids 4.05 % 3/17/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) 103,704 CFU/g dry wt 3/16/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 03162318 Sample: Smithfield North 6 Grab 3/16/23 Parameters Result Analysis Date Reporting Limit Method % Total Solids 3.93 % 3/17/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) 99,237 CFU/g dry wt 3/16/23 130 CFU/g dry wt SM 9222D Meritech Work Order # 03162319 Sample: Smithfield North 7 Grab 3/16/23 Parameters Result Analysis Date Reporting Limit Method % Total Solids 3.98 % 3/17/23 0-100 % SM 2540B Fecal Coliform (Class B Sludge) 95,477 CFU/g dry wt 3/16/23 130 CFU/g dry wt SM 9222D I hereby certify that have reviewed and approve these data. 4rna nr� Nanc.oeb Laboratory Representative 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 El El 11 3 c, O 7 �+ C _� r* - 3 a rD 3 O m EA 0 CL m rb.P m ` C p � c c c 1 ry m a ra o- ro a- D rD 3 31 \ TJ QI v .CC .[ N 0 e rD NJ�. 4 o 3 � d �{ '� N (® m ra C c rD 3 z m m o rir N a ® U) d 0 _ ` Vz o 0 S rD o o m m v, r Q o d Qn x o CR. ['} n m n O CD _ c n w w -3 r4 `� N O1 � rn � Q O C70 O w 0 w N D io ti m fD IGY 3 N m^ ro m PO A \Ln N ry 0� C/T � a CL � ID 3 (D 3 3 3 ra ro m ro � 0 'Q z d D > ri CL ❑ CL rD. Z � _ h cn O � 7C n d Ln V F-` ] D I R :0 N w — CD rn n m n N W w m V m Ln ° l n a CL R eD Q CD o 0 p D [D a O N 3 C � z C ('Dn n rD ra C r.+ - d O n -•r rD ..,, rD �� ( C N 00 rL O ry 0 ro _ `��]i M x � J ' O'k J ✓ i '`� -o -0 m — v Z n� 01 - O O Iu x p Q r a • M , I �_ I M W w o o 3 ro W W m u io o= r, C V1 a = Ln uVi p o A 4�. cm 3 3 2. rD v o rD # lu b° R y v' m O C N S Q v C r .-+ p i3 -�• N O N ❑ O m C ® (D a � n n D O O J iC = ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Smithfield Fresh Meats Corp. WQ Permit Number: WQ0014868 WWTP Name: Tarheel WWTP NPDES Number: NCO078344 Monitoring Period: From l/l/2023 To 12/31/2023 Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) ❑ Alt B (Alk Treatment) &-, I Alt. C (Prior Testing) ❑ Alt.D (No Prior Test) ❑ 1 Process to Further Reduce Pathogengs ❑ If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost ❑ Heat Drying ❑ Heat Treatment ❑ Thermophilic ❑ Beta Ray ❑ Gamma Ray ❑ Pasteurization ❑ Class B: Alt. (1) Fecal Density 0 Alt. (2) Process to Significantly Reduce Pathogens ❑ If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization ❑ Air Drying ❑ Composting ❑ Aerobic Digestion ❑ Anaerobic Digestion ❑ If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density g � Number o 1;xcee- ences Frequency of Analysis Sample Type Analytical Tech -pique Minimum Geo. Mean Maximum Units Fecal Coliform 2 x 10 to the 6th power per gram of total solids MPN CFU 198113 261876 630915 CFU/ g 0 l Quarterly G SM9222D 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed: Alt. I (VS reduction) L Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) ❑ Alt. 4 (Spec. Oz uptake) ❑ Alt. 5 (14-Day Aerobic) ❑ Alt. 6 (Alk. Stabilization ❑ Alt 7 (Drying - Stable) jAlt. 8 (Drying - Unstable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) ❑ No vector attraction reduction alternatives were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) ❑`' "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." ❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Dwayne Russ - ORC Brent Collins; Director of Technical Services Preparer Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print) Dwa�n kgrlf 02i2 1 i2Z Dwayne Russ (Feb 21, 202401:40 EST) 2/l/2024 Signature of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM PVRF 02T (12/2006) Meritech, Inc. Environmental Laboratory Laboratory Certification No. 165 0 Contact: Brent Collins Client: EMA Resources, Inc 755 Yadkinville Road Mocksville, NC 27028 Page 1 Report Date: 11/1/2023 Date Sample Rcvd: 10/25/2023 Meritech Work Order # 10252312 Sample: Smithfield South 1 Grab 10/25/23 Parameters Result Analysis Date Reporting Limit Method %Total Solids 3.15 % 10/26/23 0-100 % SM 2540E Fecal Coliform (Sludge) 219,048 col/g dry wt 10/25/23 130 col/g dry wt SM 9222D Meritech Work Order # 10252313 Sample: Smithfield South 2 Grab 10/25/23 Parameters Result Analysis Date Reporting Limit Method %Total Solids 3.18 % 10/26/23 0-100 % SM 2540B Fecal Coliform (Sludge) 198,113 col/g dry wt 10/25/23 130 col/g dry wt SM 9222D Meritech Work Order # 10252314 Sample: Smithfield South 3 Grab 10/25/23 Parameters Result Analysis Date Reporting Limit Method %Total Solids 3.05 % 10/26/23 0-100 % SM 2540E Fecal Coliform (Sludge) 252,459 col/g dry wt 10/25/23 130 col/g dry wt SM 9222D Meritech Work Order # 10252315 Sample: Smithfield South 4 Grab 10/25/23 Parameters Result Analysis Date Reporting Limit Method %Total Solids 3.26 % 10/26/23 0-100 % SM 2540B Fecal Coliform (Sludge) 226,994 col/g dry wt 10/25/23 130 col/g dry wt SM 9222D 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 Meritech, Inc. Environmental Laboratory Laboratory Certification No. 165 r Contact: Brent Collins Client: EMA Resources, Inc 755 Yadkinville Road Mocksviile, NC 27028 Page 2 Report Date: 11/1/2023 Date Sample Rcvd: 10/25/23 Meritech Work Order # 10252316 Sample: Smithfield South 5 Grab Parameters Result Analysis Date Reporting Limit % Total Solids 3.29 % 10/26/23 0-100 % Fecal Coliform (Sludge) 246,201 col/g dry wt 10/25/23 130 col/g dry wt Meritech Work Order # 10252317 Parameters Sample: Smithfield South 6 Grab 10/25/23 Method SM 2540B SM 9222D 10/25/23 Result Analysis Date Reporting Limit Method % Total Solids 3.11 % 10/26/23 0-100 % SM 2540B Fecal Coliform (Sludge) 218,650 col/g dry wt 10/25/23 130 col/g dry wt SM 9222D Meritech Work Order # 10252318 Sample: Smithfield South 7 Grab 10/25/23 Parameters Result Analysis Date Reporting Limit Method % Total Solids 3.17 % 10/26/23 0-100 % SM 2540B Fecal Coliform (Sludge) 630,915 col/g dry wt 10/25/23 130 col/g dry wt SM 9222D I hereby certify that I have reviewed and approve these data. Laboratory Representative 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)3424748fax.(336)342-1522 ❑ ❑ ❑ ❑ S _� 0 fD 0 m a X T3 rrD-r -v 9 o VI(D Q C 4' N Or fD r'F 0• 3 O :} o. C m m ro s a ^ 0- s Q s CL rp O m N cu j• Cl Q N Q Q ro a J i1y� -t tea lv .. fD m rD C c LA rD 0 Ln ` rD o ; F• m, nn X O Z O _ f7 n N o o rn n a - cn h 3 Z rn "I v o � ana rr o n f 1 o o = o ni w w O 3 f� {A �"' w > p N !' v o o a Qp 3 m p n Ln v rn rN.o w pop (D m --I -a rD 3 3 3 rD ro ro Z MO 2. ry n 9 > fl DCL y. 1 o a ro 7 C:L rD N ❑ r_* rah f I O O N ro 3 r9 W V m m ro m rr'n r"o lb `[' - n -a m` O D r:3r O Lri 7r D n a w 4t ao_ S..y C 0] ro o_ - F c p O w X- LA ro o o 3 n rD m @ CD O rDCL c p v n J C'CL p to Q Uq 0 o (D ro X -o -0 m -n ro Z ti a aqq m °' p a. X o ❑ C * \ c w w m o w o m S L,ray. a :0 w w d1 Ql n m a`a Z ° Ui In fl O n 3 r{p O w a r0 3 N m Ln Q 6 m= N a cu of ❑ o �Jo �^ In N o 3 rD 01 T ? * a r O v 3 tiWe— NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY23-SL029058 Client: Steve Durham Advisor: Brent Collins Predictive 2467 Burney Rd. EMA Resources Inc White Oak, NC 28399 755 Yadkinville Rd # ' Soil Report-3 Extraction Mocksville, NC 27028 _ Sampled County : Bladen Links to Helpful Information Client ID: 520266 Advisor ID: 405413 Sampled: Received: 04/05/2023 Completed: 04/14/2023 Farm: SF03 Agronomist's Comments: ATTENTION: This report was flagged with a "C" and/or "Z" to alert you that copper and/or zinc have accumulated in the soil and are approaching a level that could be detrimental to crop production. The C and Z symbols are printed on your report for soil test Zn and Cu index levels of 2000 or more for agronomic crops; for peanuts with zinc, the level is 250. This note is designed to be a "trigger" that allows enough time to either reduce the rate of application or find another field for application of biosolids and/or waste water. The CTL (critical toxic level) for Cu and Zn is set at a 3000 index; for peanuts with zinc, the level is 500. Maintaining a pH of 6.0 or higher may reduce potential for toxicity, especially for Zn. These levels are used by DENR as a benchmark to determine when application of waste products should be stopped. The CTL for copper and zinc was set to revent levels from accumulating to the point where they become toxic to crops grown on a field. Sample ID: 00001 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Bermuda hay/past., M 0.0 180-220 0 70 0 0 pH$ Z 0 0 Note: 12 Note: 2 -Bermuda hay/past., M 0.0 180-220 0 70 0 0 pH$ Z 0 0 Note: 12 Note: Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.92 1.13 15.1 95 0.8 6.7 586 69 80 13 99 155 100 100 2820 2820 580 0.3 2 Sample ID: 00004 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Bermuda hay/past., M 0.0 180-220 0 120 0 0 pH$ 0 0 0 Note: 12 Note: 2 -Bermuda hay/past., M 0.0 180-220 0 120 0 0 pH$ 0 0 0 Note: 12 Note: Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Organic HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 5.53 1.04 18.2 94 1.1 6.7 170 45 66 27 47 104 68 68 1108 1839 180 0.3 2 North Carolina Tcbatcu (rusk f umi Cixnmisskm Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY23-SL029058 Steve Durham Page 2 of 3 Sample ID: 00006 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Bermuda hay/past., M 0.0 180-220 0 190 0 0 pH$ 0 0 0 Note: 12 Note: $ 2 -Bermuda hay/past., M 0.0 180-220 0 190 0 0 pH$ 0 0 0 Note: 12 Note: $ Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.46 1.34 14.5 100 0.0 7.5 409 19 95 4 54 94 51 51 1621 1621 922 0.1 1 Sample ID: 00007 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Bermuda hay/past., M 0.0 180-220 0 150 0 0 pH$ 0 0 0 Note: 12 Note: $ 2 -Bermuda hay/past., M 0.0 180-220 0 150 0 0 pH$ 0 0 0 Note: 12 Note: $ Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.46 0.97 12.0 95 0.6 6.7 240 34 68 26 47 284 177 177 1477 1477 979 0.2 2 NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/agronomi/ Report No. FY24-SL010465 kSi l"14'4+;4, Client: Steve Dunham Advisor: Brent Collins Predictive 2467 Burney Rd. EMA Resources Inc °± f' White Oak, NC 28399 755 Yadkinville Rd �- Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Sampled County : Bladen _1 Links to Helpful Information Sampled: Received: 10/26/2023 Completed: 11/09/2023 Farm: SF03 Client ID: 169244 Advisor ID: 405413 Sample ID: 00002 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 0 70 0 0 0 0 0 0 Note: 12 2- Fescue/OGrass/Tim, M 0.0 120-200 0 70 0 0 0 0 0 0 Note: 12 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.36 1.45 3.0 72 0.8 5.8 246 36 55 11 28 52 48 48 702 702 326 0.1 3 Sample ID: 00003 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 0 90 0 0 0 0 0 0 Note: 12 2- Fescue/OGrass/Tim, M 0.0 120-200 0 90 0 0 0 0 0 0 Note: 12 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral -Organic HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 4.81 1.19 12.3 82 2.2 5.9 379 24 66 15 35 30 37 37 831 1039 836 0.1 1 North Carolina Tai wLm Truk f and Ctwinlsskm Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/agronomi/ Report No. FY24-SL010465 Steve Dunham Page 2 of 3 Sample ID: 00005 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Fescue/OGrass/Tim, M 0.0 120-200 0 110 0 0 pH$ 0 0 0 Note: 12 Note: $ 2 - Fescue/OGrass/Tim, M 0.0 120-200 0 110 0 0 pH$ 0 0 0 Note: 12 Note: $ Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral -Organic HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 4.95 1.10 16.1 93 1.2 6.6 233 15 72 20 99 58 43 43 1255 1569 581 0.2 1 NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY23-SL029192 k5i I"14'4+;4 Client: Vance Tyson Advisor: Brent Collins Predictive 4925 NC Hwy 87 S EMA Resources Inc °± f' Fayetteville, NC 28306 755 Yadkinville Rd �- Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Sampled County : Cumberland _1 Links to Helpful Information Sampled: Received: 04/05/2023 Completed: 04/14/2023 Farm: SF06 Client ID: 508814 Advisor ID: 405413 Sample ID: 00007 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Soybean 0.5 0 0 0 0 0 0 0 0 0 Note: 3 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 2.22 1.23 8.9 77 2.0 5.8 563 110 56 15 86 284 180 1104 1104 559 0.2 2 North Carolina Tcbwiv Truk f and Ct wmisskm Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY23-SL029063 Client: William / JW Burney Advisor: Brent Collins Predictive 7379 Hwy 53 W EMA Resources Inc White Oak, NC 28399 755 Yadkinville Rd # ' Soil Report-3 Extraction _ Mocksville, NC 27028 Sampled County : Bladen Links to Helpful Information Client ID: 178596 Advisor ID: 405413 Sampled: Received: 04/05/2023 Completed: 04/14/2023 Farm: SF07 Agronomist's Comments: ATTENTION: This report was flagged with a "C" and/or "Z" to alert you that copper and/or zinc have accumulated in the soil and are approaching a level that could be detrimental to crop production. The C and Z symbols are printed on your report for soil test Zn and Cu index levels of 2000 or more for agronomic crops; for peanuts with zinc, the level is 250. This note is designed to be a "trigger" that allows enough time to either reduce the rate of application or find another field for application of biosolids and/or waste water. The CTL (critical toxic level) for Cu and Zn is set at a 3000 index; for peanuts with zinc, the level is 500. Maintaining a pH of 6.0 or higher may reduce potential for toxicity, especially for Zn. These levels are used by DENR as a benchmark to determine when application of waste products should be stopped. The CTL for copper and zinc was set to revent levels from accumulating to the point where they become toxic to crops grown on a field. Sample ID: 00001 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Bermuda hay/past., M 0.0 180-220 0 160 0 0 pH$ 0 0 0 Note: 12 Note: 2 -Bermuda hay/past., M 0.0 180-220 0 160 0 0 pH$ 0 0 0 Note: 12 Note: Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.32 0.98 11.3 91 1.0 6.6 223 30 64 26 42 287 180 180 1429 1429 1006 0.2 2 Sample ID: 00003 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Bermuda hay/past., M 0.0 180-220 0 160 0 0 pH$ 0 0 0 Note: 12 Note: 2 -Bermuda hay/past., M 0.0 180-220 0 160 0 0 pH$ 0 0 0 Note: 12 Note: Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.32 0.97 11.6 91 1.0 6.5 230 32 63 27 42 275 174 174 1456 1456 1001 0.2 2 North Carolina Tcbatcu (rusk f umi Cixnmisskm Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY23-SL029063 William / JW Burney Page 2 of 3 Sample ID: 00006 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Bermuda hay/past., M 0.0 180-220 0 140 0 0 0 Z 0 0 Note: 12 Note: $ 2- Bermuda hay/past., M 0.0 180-220 0 140 0 0 0 Z 0 0 Note: 12 Note: $ Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.41 1.00 12.4 86 1.8 6.0 982 39 68 16 50 154 109 109 5358 5358 1470 0.2 2 Sample ID: 00008 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Bermuda hay/past., M 0.0 180-220 0 90 0 0 pH$ 0 0 0 Note: 12 Note: $ 2 -Bermuda hay/past., M 0.0 180-220 0 90 0 0 pH$ 0 0 0 Note: 12 Note: $ Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.36 1.10 9.9 95 0.5 7.0 213 60 82 11 49 238 144 144 1028 1028 444 0.1 1 NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY23-SL029064 kSi l"14'4+;4, Client: Bonnie Meeker Advisor: Brent Collins Predictive 19850 Hwy 87 W EMA Resources Inc °± f' Tar Heel, NC 28392 755 Yadkinville Rd �- Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Sampled County : Bladen _1 Links to Helpful Information Sampled: Received: 04/05/2023 Completed: 04/14/2023 Farm: SF07 Client ID: 440578 Advisor ID: 405413 Sample ID: 00009 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Bermuda hay/past., M 0.0 180-220 0 160 25 0 0 0 0 0 Note: 12 2 -Bermuda hay/past., M 0.0 180-220 0 160 $ 0 0 0 0 0 Note: 12 Note: $ Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.27 1.35 5.6 78 1.2 5.9 628 29 70 5 30 363 235 235 1589 1589 951 0.1 2 Sample ID: 00014 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Bermuda hay/past., M 1.6 180-220 0 180 25 0 0 0 0 0 Note: 12 2 -Bermuda hay/past., M 0.0 180-220 0 180 $ 0 0 0 0 0 Note: 12 Note: $ Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.51 1.31 3.6 36 2.3 4.7 244 22 27 5 47 59 52 52 416 416 353 0.1 3 North Carolina Tai wLv Truk f and Ct wmisskm Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY23-SL029064 Bonnie Meeker Page 2 of 3 Sample ID: 00015 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1- Bermuda hay/past., M 1.1 180-220 0 160 0 0 0 0 0 0 Note: 12 2- Bermuda hay/past., M 0.0 180-220 0 160 0 0 0 0 0 0 Note: 12 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.92 1.23 5.6 63 2.1 5.3 281 29 46 14 47 150 107 107 557 557 108 0.1 2 Pages from 2023 Smithfield Fresh Meats Annual Report - WQ0014868 Final Audit Report 2024-02-21 Created: 2024-02-19 By: Brent Collins (brent.collins@emaresourcesinc.com) Status: Signed Transaction ID: CBJCHBCAABAAck344W7QFLMH6pKMT1 EfnVRdOel8UMjJ "Pages from 2023 Smithfield Fresh Meats Annual Report - WQO 014868" History Document created by Brent Collins (brent.collins@emaresourcesinc.com) 2024-02-19 - 7:25:42 PM GMT- IP address: 206.85.202.26 Document emailed to Dwayne Russ (druss@smithfield.com) for signature 2024-02-19 - 7:25:46 PM GMT Email viewed by Dwayne Russ (druss@smithfield.com) 2024-02-19 - 7:26:05 PM GMT- IP address: 172.172.8.186 Document e-signed by Dwayne Russ (druss@smithfield.com) Signature Date: 2024-02-21 - 6:40:12 AM GMT - Time Source: server- IP address: 50.225.252.4 Agreement completed. 2024-02-21 - 6:40:12 AM GMT a Adobe Acrobat Sign Pages from 2023 Smithfield Fresh Meats Annual Report - WQ0014868 Final Audit Report 2024-02-27 Created: 2024-02-22 By: Brent Collins (brent.collins@emaresourcesinc.com) Status: Signed Transaction ID: CBJCHBCAABAA04k8jMEKW53W4NTnhFzLhjRuggYaWy79 "Pages from 2023 Smithfield Fresh Meats Annual Report - WQO 014868" History Document created by Brent Collins (brent.collins@emaresourcesinc.com) 2024-02-22 - 5:23:09 PM GMT- IP address: 206.85.202.26 P-► Document emailed to Andrea Tucker (atucker@smithfield.com) for signature 2024-02-22 - 5:23:13 PM GMT Email viewed by Andrea Tucker (atucker@smithfield.com) 2024-02-27 - 3:33:55 PM GMT- IP address: 104.47.51.126 C-�q, Document e-signed by Andrea Tucker (atucker@smithfield.com) Signature Date: 2024-02-27 - 3:34:09 PM GMT - Time Source: server- IP address: 50.225.252.6 % Agreement completed. 2024-02-27 - 3:34:09 PM GMT 0 Adobe Acrobat Sign