WQ0003504_2023 Residual Annual Report_20240229 (2)

Initial Review
Reviewer
nathaniel.thorn burg
Is this submittal an application? (Excluding additional information.) *
Yes No
If not an application what is the submittal type?* Annual Report
Residual Annual Report
Additional Information
Other
Annual Report Year* 2023
Permit Number (IR) * WQ0003504
Applicant/Permittee City of Durham
Email Notifications
Does this need review by the hydrogeologist? * Yes No
Regional Office Raleigh
CO Reviewer
Admin Reviewer Wanda Gerald

Submittal Form
Project Contact Information
Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence.
Name* Brent Collins
Email Address*
[e-mail]
Project Information
.........................
Application/Document Type*
New (Fee Required)
Modification - Major (Fee Required)
Renewal with Major Modification (Fee
Required)
Annual Report
Additional Information
Other
Phone Number*
3363993646
Modification - Minor
Renewal
GW-59, NDMR, NDMLR, NDAR-1,
N DAR-2
Residual Annual Report
Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:*
Wastewater Irrigation
High -Rate Infiltration
Other Wastewater
Reclaimed Water
Closed -Loop Recycle
Residuals
Single -Family Residence Wastewater
Other
Irrigation
Permit Number:*
WQ0003504
Has Current Existing permit number
Applicant/Permittee Address*
101 City Hall Plaza, Durham, NC 27701
Facility Name*
City of Durham Class B Residuals Program
Please provide comments/notes on your current submittal below.
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.
(Application Form, Engineering Plans, Specifications, Calculations, Etc.)
2023 Durham Annual Report - WQ0003504.pdf 10.15MB
Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger
than upload limit.
* By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has
been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the
North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts
of the application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
Signature
Submission Date 2/29/2024

M
i— Resources, Inc.
City of Durham
2023 Annual Report
Residuals Land Application
Permit No. WQ0003504
Prepared By:
EMA Resources, Inc.
Phone 336*751.1441 — Fax 336*751.1442
755 Yadkinville Rd — Mocksville, NC 27028

February 27, 2024
DENR/Water Quality Section
Non -Discharge Compliance Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Re: 2023 Annual Report — City of Durham
Treatment and Land Application of Residuals
Permit No. WQ0003504
Dear Sir or Madam:
Enclosed is the 2023 Annual Report for the above referenced land application permit.
During 2023 EMA Resources, Inc. land applied 2339.05 dry tons of wastewater residuals
to 599.2 acres of private farmland. Residuals from the Brown WTP were land applied
under EMA Resources Inc.'s Class A land application permit (WQ0041666). There was
no land application from the North Durham WRF. 353 dry tons of residuals from the
North Durham WRF were taken to the Sampson County Landfill. 54 dry tons of residuals
from the South Durham WRF were also taken to the Sampson County Landfill. Please
contact Brent Collins - Director of Technical Services if you have any further questions
regarding this report.
Sincerely,
z � e 4 /; I /1�1_
Brent Collins
Director of Technical Services
Brent. collins(&,,emaresourcesinc. com
Phone 336*751.1441 — Fax 336*751.1442
755 Yadkinville Rd — Mocksville, NC 27028

ANNUAL LAND APPLICATION CERTIFICATION FORNI
WQ Permit#: WQ0003504 County:
Facility Name (as shown on permit):
Land Application Operator:
hurham
Year: 2023
Citv of Durham
EMA Resources Inc. Phone: [phone]
Land application of residuals as allowed by the permit occurred during the past calendar year?
❑✓ Yes ❑ No - if No, skip Part A, and Part B and proceed to Part C. Also, If residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A - Residuals Application Summarv:
Total number of application fields in the pennit:1
139
Total number of fields utilized for land application during the year:
18
Total amotrnt of dry tons applied during the year for all application sites:
2339.05
Total number of acres utilizes for land application during the year:
599.2
Part B - Annual Compiance Statement:
Facility was compliant during calendar year 2023 with all conditions of the land application permit
(including but not limited to items 1-13 below) issued by the Division of Water Quality. 0 Yes ❑ No
If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action
taken.
1) Only residuals approved for this permit were applied to the permitted sites.
2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or
the limit specified in the permit.
3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies
of laboratory results are attached.
41 Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached.
5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3)
copies of certified laboratory results are attached.
6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T. I 105(a) or the Pollutant
Loading Rates in 15A NCAC 02T .1 105(b) (applicable to 40 CFR Part 503 regulated facilities).
7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part
503 regulated facilities).
K) All monitoring and reporting requirements in 15A NCAC 02T. I I I I were complied with (applicable to 40 CFR Part
503 regulated facilities).
9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior
authorization was received from the Division of Water Quality.
10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations.
11) Vegetative cover was maintained and proper crop management was performed on each site recein, residuals, as
specified in the permit.
12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
1 1) All buffer requirements as specified on the pennit were maintained during each application of residuals.
Part C - Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate,
and complete. 1 am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations." /
Don Greeley - Water Management Director
Pennittee Name and Title (type or print) Signature of PcrmJttetDate
acaw-C.a,. 02/06/24 tt e
2!3!2024
Signature of Preparer* Date Signature of Land Applier Date
(ifdifferent li-om Permittee) (if different fi-onn Permitice and Preparer)
* Preparer is defined in 40 CFR ['art 503.9 (r) and I5A NCAC 02T .1102 (26) DENR FORM ACF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number:
Facility Name:
Residual Source WQ # or
NPDES #:
WWTP Name:
Residual Analvsis Data
WQ0003504
City of Durham
NCO047597
South Durham WRF
Laboratory:
1)
2)
3)
4)
5)
Waypoint Analytical
Parameter
(mg/kg)
Conc.
Limit
m /k )a
(mg/kg) a
Sample or Composite Date
1/5/23
3/27/23
6/l/23
7/18/23
9/14/23
12/14/23
Percent Solids (%)
NA
16.1
15.9
16.1
16.1
16.7
18.1
Arsenic
75
3.8
3.17
4.66
3.68
4.95
2.9
Cadmium
85
0.988
0.811
0.677
0.981
1.23
1.1
Copper
4,300
430
407
376
404
425
424
Chromium
NA
19.9
18.6
18.8
19.1
19.9
18.2
Lead
840
13.5
14.3
14.3
15.7
17.4
14.4
Mercury
57
0.764
1.36
1.22
0.87
0.511
0.663
Molybdenum
75
24.6
21.8
25.7
36.7
34
21.7
Nickel
420
17.7
18.2
18.1
20.5
20.1
19.7
Selenium
100
4.05
4.63
6.27
5.64
4.61
4.35
Zinc
7,500
2800
2740
2650
2790
2690
2500
Total Phosphorus
NA
36800
34300
33300
35800
34600
37300
TKN
NA
50600
64200
57400
57600
54000
62400
Ammonia -Nitrogen
NA
6890
6920
7890
11800
7130
735
Nitrate and Nitrite
NA
28.6
27.9
69.6
9.25
1690
75.7
a For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
C11-
Signature of Preparer *
02/06/24
Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number:
WQ0003504
Facility Name: City of Durham
Residual Source
NPDES # or WQ#:
WWTP Name:
Residual Analvsis Data
NCO047597
South Durham WRF
Laboratory: 1) Waypoint Analytical
2)
3)
4)
5)
Parameter
(mg/kg)
Sample or Composite Date
1/5/23
3/27/23
6/l/23
7/18/23
9/14/23
12/14/23
Aluminum
27500
22300
24200
23700
27200
28600
Calcium
19100
20100
17600
19600
20400
18800
Magnesium
6000
6480
5470
6170
5900
6020
pH
7
7.6
7.8
8.2
5.8
8.4
Potassium
2880
3200
3420
3350
2950
3170
Sodium
839
830
801
845
1 958
1020
PAN
12216
14944
13917
15069
14629
12776
SAR
0.54
0.52
0.54
0.54
0.62
0.7
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Signature of Preparer *
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
02/06/24
Date
DENR FORM RSSF - B (12/2006)

1 /5/2023
mg/kg mg/L Equiv Weight Milli Equiv
Sodium 839 135.079 23 5.873
Calcium 19100 3075.1 20 153.755
Magnesium 6000 966 12 80.5
Percent Solids 16.1
SAR 0.54
SAR =
Na+
z (Ci a2+ + Mg2+ )
5.87300
0.5( 153.76 2 + 80.50000 2 )

3/27/2023
mg/kg
mg/L
Equiv Weight Milli Equiv
Sodium
830
131.97
23 5.737826
Calcium
20100
3195.9
20 159.795
Magnesium
6480
1030.32
12 85.86
Percent Solids
15.9
SAR
0.52
SAR =
Na+
z (Ci a2+ + Mg2+ )
5.73783
0.5( 159.8 2 + 85.86000 2 )

6/1 /2023
mg/kg
mg/L
Equiv Weight Milli Equiv
Sodium
801
128.961
23 5.607
Calcium
17600
2833.6
20 141.68
Magnesium
5470
880.67
12 73.38917
Percent Solids
16.1
SAR
0.54
SAR =
Na+
z (Ci a2+ + Mg2+ )
5.60700
0.5( 141.68 2 + 73.38917 2 )

7/18/2023
mg/kg
mg/L
Equiv Weight Milli Equiv
Sodium
845
136.045
23 5.915
Calcium
19600
3155.6
20 157.78
Magnesium
6170
993.37
12 82.78083
Percent Solids
16.1
SAR
0.54
SAR =
Na+
z (Ci a2+ + Mg2+ )
5.91500
0.5( 157.78 2 + 82.78083 2 )

9/14/2023
mg/kg
mg/L Equiv Weight Milli Equiv
Sodium
958
159.986 23 6.955913
Calcium
20400
3406.8 20 170.34
Magnesium
5900
985.3 12 82.10833
Percent Solids
16.7
SAR
0.62
SAR =
Na+
z (Ci a2+ + Mg2+ )
6.95591
0.5( 170.34 2 + 82.10833 2 )

12/14/2023
mg/kg
mg/L
Equiv Weight Milli Equiv
Sodium
1020
184.62
23 8.026957
Calcium
18800
3402.8
20 170.14
Magnesium
6020
1089.62
12 90.80167
Percent Solids
18.1
SAR
0.70
SAR =
Na+
z (Ci a2+ + Mg2+ )
8.02696
0.5( 170.14 2 + 90.80167 2 )

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Henry Thorpe Jr. Owner: Henry Thorpe Jr. Predominant Soil Series:
Acres Used: 46.1 Acres Permitted: 46.1 Site #: GRO1 Field #:
212.89
GeB
1
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
kVWPT_"1
Com-
posite
Date
©
©
m
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
TotalMED
••Event
1 1 �
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
1 11
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11•
�®
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 •
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 •
1�
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1
1 11:
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11:
�
�
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 •
�
1:
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 :•
OEM
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
®
:
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
•:
Total
' •
1 •� •
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 •�'
•
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/3/2024
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Durham WQ Permit #: WQ0003504 Field #: 1 Acres Utilized: 46.1
Land Owner: Henry Thorpe Jr. Annual Dry Tons Applied: 212.89 Site #: GRO1 Acres Permitted: 46.1
Operator: Henry Thorpe Jr. Predominant Soil Series: GeB Cation Exchange Capacity (non 503): 0
Crop 1 Name: Fescue -Pasture Crop 1 Max. PAN: 158.25 Crop 2 Name: Crop 2 Max. PAN:
o
o
Volume applied
(enter one) Solids/
Liquid
Cu. Yds Gallons
%
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
Wet
Moist)
Precip.
Past 24
Hrs.
inches
a
a
o
� --
*
°�
4.
w -
co
* N
TKN
mg/kg
Z a
.; El
o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
7/12
234
16.1
0.688
South Durham
D
<.5"
S
0.5
0.2
57600
11800
9.25
20.743
NA
Fescue
7/13
273
16.1
0.803
South Durham
D
<.5"
S
0.5
0.2
57600
11800
9.25
24.200
NA
Fescue
7/17
640
16.1
1.882
South Durham
D
<.5"
S
0.5
0.2
57600
11800
9.25
56.732
NA
Fescue
7/18
423
16.1
1.244
South Durham
D
<.5"
S
0.5
0.2
57600
11800
9.25
37.496
NA
Fescue
0.000
1
1
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
15701
o
As
Cd
Cu
Cr
Pb
Hg
Mo
N1
Se
Zn
P
139.1711
0.000
Lime Applied
Annuallbs/acre
0.034
0.009
3.731
0.176
0.145
0.008
0.339
0.189
0.052
25.768
330.649
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.226
0.089
19.203
2.814
1.629
0.032
0.548
0.904
0.677
110.105
Current Cumulative lbs/ac
0.260
1 0.098
22.934
2.990
1.774
0.040
0.887
1.093
0.729
135.873
Permitted C. P. L. R.****
36
34
1 133
1
267
1 15
374
1 89
2498
Permit PAN Limit 1 st/2nd Crop
158.25
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/3/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Henry Thorpe Jr. Owner: Henry Thorpe Jr. Predominant Soil Series:
Acres Used: 44.3 Acres Permitted: 44.3 Site #: GR05 Field #:
192.39
VaB
1
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
kVWPT_"1
Com-
posite
Date
©
©
m
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
TotalMED
••Event
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
1 11
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11•
1•
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1'
1 ••
1 111
1 111
1111
1 111
1111
1 111
1111
1 111
1 111
1111
1 111
1 ••
1 •
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 •
1 11:
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11:
�
�
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 •
�
1 :
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 :
1 1�•
1 111
1 111
1111
1 111
1111
1 111
1111
1 111
1 111
1111
1 111
1 1�•
®
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
Total
' •
1 • •
1 111
1 111
1111
1 111
1111
1 111
1111
1 111
1 111
1111
1 111
1' '
•
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/3/2024
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Durham WQ Permit #: WQ0003504 Field #: 1 Acres Utilized: 44.3
Land Owner: Henry Thorpe Jr. Annual Dry Tons Applied: 192.39 Site #: GR05 Acres Permitted: 44.3
Operator: Henry Thorpe Jr. Predominant Soil Series: VaB Cation Exchange Capacity (non 503): 0
Crop 1 Name: Fescue -Pasture Crop I Max. PAN: 146 Crop 2 Name: Crop 2 Max. PAN:
o
o
Volume applied
(enter one) Solids/
Liquid
Cu. Yds Gallons
%
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
Wet
Moist)
Precip.
Past 24
Hrs.
inches
a
a
o
� --
*
°�
4.
w -
co
* N
TKN
mg/kg
Z a
.; El
o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
7/19
167
16.1
0.511
South Durham
D
<.5"
S
0.5
0.2
57600
11800
9.25
15.405
NA
Fescue
7/20
590
16.1
1.806
South Durham
D
<.5"
S
0.5
0.2
57600
11800
9.25
54.425
NA
Fescue
7/21
217
16.1
0.664
South Durham
D
<.5"
S
0.5
0.2
57600
11800
9.25
20.017
NA
Fescue
7/26
395
16.1
1.209
South Durham
D
<.5"
S
0.5
0.2
57600
11800
9.25
36.437
NA
Fescue
7/27
1 50
16.1
0.153
South Durham
D
<.5"
S
0.5
1 0.2
57600
1 11800
9.25
1 4.612
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
14191
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
130.896
0.000
Lime Applied
Annuallbs/acre
0.032
0.009
3.509
0.166
0.136
0.008
0.319
0.178
0.049
24.234
310.9591
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.26
0.114
21.449
2.183
1.81
0.036
0.772
1.289
0.46
120.293
Current Cumulative lbs/ac
0.292
1 0.123
24.958
2.349
1.946
0.044
1.091
1.467
0.509
144.527
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
89
2498
Permit PAN Limit 1 st/2nd Crop
F 146
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/3/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Henry Thorpe Jr. Owner: Henry Thorpe Jr. Predominant Soil Series:
Acres Used: 40 Acres Permitted: 40 Site #: GR05 Field #:
169.76
VaB
2
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
kVWPT_"1
Com-
posite
Date
©
©
m
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
TotalME
D
-
••
Event
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
1 11:
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11:
' '
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
•
1•
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1•
��
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11
�
�
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
�
1 �
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1
1 1� :
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1�
®
:
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
•:
Total
'•
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
•
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/3/2024
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Durham WQ Permit #: WQ0003504 Field #: 2 Acres Utilized: 40
Land Owner: Henry Thorpe Jr. Annual Dry Tons Applied: 169.76 Site #: GR05 Acres Permitted: 40
Operator: Henry Thorpe Jr. Predominant Soil Series: VaB Cation Exchange Capacity (non 503): 0
Crop 1 Name: Fescue -Pasture Crop I Max. PAN: 146 Crop 2 Name: Crop 2 Max. PAN:
o
o
Volume applied
(enter one) Solids/
Liquid
Cu. Yds Gallons
%
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
Wet
Moist)
Precip.
Past 24
Hrs.
inches
a
a
o
� --
*
°�
4.
w -
co
* N
TKN
mg/kg
Z a
.; El
o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
7/21
245
16.1
0.830
South Durham
D
<.5"
S
0.5
0.2
57600
11800
9.25
25.030
NA
Fescue
7/24
434
16.1
1.471
South Durham
D
<.5"
S
0.5
0.2
57600
11800
9.25
44.338
NA
Fescue
7/25
473
16.1
1.603
South Durham
D
<.5"
S
0.5
0.2
57600
11800
9.25
48.323
NA
Fescue
7/26
50
16.1
0.169
South Durham
D
<.5"
S
0.5
0.2
57600
11800
9.25
5.108
NA
Fescue
7/31
1 50
16.1
0.169
South Durham
D
<.5"
S
0.5
0.2
1 57600
11800
1 9.25
5.108
NA
I Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
12521
01
As
Cd
Cu
Cr
Pb
Hg
Mo
N1
Se
Zn
P
127.9071
0.000
Lime Applied
Annuallbs/acre
0.031
0.008
3.429
0.162
0.133
0.007
0.312
0.174
0.048
23.682
303.870
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.252
0.116
20.394
2.902
2.039
0.037
0.784
1.579
0.499
123.24
Current Cumulative lbs/ac
0.283
1 0.124
1 23.823
3.064
2.172
0.044
1.096
1.753
0.547
146.922
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit 1 st/2nd Crop
F 146
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/3/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Henry Thorpe Jr. Owner: Henry Thorpe Jr. Predominant Soil Series:
Acres Used: 96.9 Acres Permitted: 96.9 Site #: GR05 Field #:
420.26
VaB
3
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
kVWPT_"1
Com-
posite
Date
©
m
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
D
App.
ME
Event
1
1 1 �
1 1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
1 11
1 11
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11•
.:
1 :..
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
��
IZfii'ii}iiiiii'�
1 1�
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1.
1 1�
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1� 1
1 11.
1 11
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11
1 ��
1 1 •
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
•�
1 •
1 1�
1 111
1111
1 111
1111
1 111
1111
1 111
1 111
1111
1 111
1 1
1 11`
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1�
®
:
.:
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
••
Total
'
••
1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111M
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/3/2024
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
Operator:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
Henry Thorpe Jr.
Henry Thorpe Jr.
Crop 1 Name:
Fescue -Pasture
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 420.26 Site #:
Predominant Soil Series: VaB
Crop 1 Max. PAN:
146
Crop 2 Name:
Acres Utilized:
GR05 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
96.9
96.9
0
p
0
M
Volume applied
(enter one) Solids/
Liquid
Cu. Yds Gallons
"
�"
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
e '
Moist)
Precip.
Past 24
Hrs.
inches
y
co
•*
a m
c
7y
?:
*
o'
* N•
TKN
mg/kg
Z
1
o
aq o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
lbs/acre
( )
Name of Crop Type
Receiving Residual
g
Application
Crop 1
Crop 2
Crop 1
Crop 2
7/18
284
16.1
0.397
South Durham
D
<.5"
S
0.5
0.2
57600
11800
9.25
11.977
NA
Fescue
7/19
423
16.1
0.592
South Durham
D
<.5"
S
0.5
0.2
57600
11800
9.25
17.839
NA
Fescue
7/28
256
16.1
0.358
South Durham
D
<.5"
S
0.5
0.2
57600
11800
9.25
10.796
NA
Fescue
8/1
590
16.1
0.826
South Durham
D
<.5"
S
0.5
0.2
57600
11800
9.25
24.882
NA
Fescue
8/2
590
16.1
0.826
South Durham
D
<.5"
S
0.5
0.2
57600
11800
9.25
24.882
NA
Fescue
8/3
228
16.1
0.319
South Durham
D
<.5"
S
0.5
0.2
57600
11800
9.25
9.615
NA
Fescue
10/12
468
16.7
0.679
South Durham
D
<.5"
S
0.5
0.2
54000
7130
1690
19.874
NA
Fescue
10/13
234
16.7
0.340
South Durham
D
<.5"
S
0.5
0.2
54000
7130
1690
9.937
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
3073
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn P
129.801
r 0.000
Lime Applied
Annuallbs/acre
0.035
0.009
3.547
0.167
0.140
0.007
0.313
0.177
0.047
23.997 308.084
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.417
0.101
20.841
1.786
1.282
0.032
0.519
1.467
0.417
111.729
Current Cumulative lbs/ac
0.452
0.110
24.388
1.953
1.422
0.039
0.832
1.644
0.464
135.726
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit 1 st/2nd Crop
I
F 146
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/3/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Henry Thorpe Jr. Owner: Henry Thorpe Jr. Predominant Soil Series:
Acres Used: 48.5 Acres Permitted: 48.5 Site #: GR05 Field #:
190.07
EnB
4
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
kVWPT_"1
Com-
posite
Date
©
m
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
TotalNEB
D
App.
Event
..
1 1
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
1 11
1 11
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11•
��®
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
1 1••
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1
1 1�
1 1:
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11
1 11
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11
1 1
1 •
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1
•�
1 1
1 11
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 •
1 1 •
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1'
®
:
:
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
Total
'o
m
1
1111
1111
1111
1111
1111
1111
1111
1111
1111
1111M
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/3/2024
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Durham WQ Permit #: WQ0003504 Field #: 4 Acres Utilized: 48.5
Land Owner: Henry Thorpe Jr. Annual Dry Tons Applied: 190.07 Site #: GR05 Acres Permitted: 48.5
Operator: Henry Thorpe Jr. Predominant Soil Series: EnB Cation Exchange Capacity (non 503): 0
Crop 1 Name: Fescue -Pasture Crop I Max. PAN: 146 Crop 2 Name: Crop 2 Max. PAN:
o
o
Volume applied
(enter one) Solids/
Liquid
Cu. Yds Gallons
%
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
Wet
Moist)
Precip.
Past 24
Hrs.
inches
a
a
o
� --
*
°�
4.
w -
co
* N
TKN
mg/kg
Z a
.; El
o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
7/27
423
16.1
1.183
South Durham
D
<.5"
S
0.5
0.2
57600
11800
9.25
35.641
NA
Fescue
7/28
89
16.1
0.249
South Durham
D
<.5"
S
0.5
0.2
57600
11800
9.25
7.499
NA
Fescue
10/16
390
16.7
1.131
South Durham
D
<.5"
S
0.5
0.2
54000
7130
1690
33.089
NA
Fescue
10/17
468
16.7
1.357
South Durham
D
<.5"
S
0.5
0.2
54000
7130
1690
39.707
NA
Fescue
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.100
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
1370
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
115 9361
o.000
Lime Applied
Annuallbs/acre
0.035
0.009
3.271
0.154
0.132
0.005
0.274
0.159
0.039
21.370
274.6291
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.234
0.085
17.175
1.607
1.06
0.031
0.539
1.119
0.264
125.348
Current Cumulative lbs/ac
0.269
0.094
20.446
1.761
1.192
0.036
0.813
1.278
0.303
146.718
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
89
1 2498
Permit PAN Limit 1 st/2nd Crop
1 146
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/3/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Henry Thorpe Jr. Owner: Henry Thorpe Jr. Predominant Soil Series:
Acres Used: 17.5 Acres Permitted: 17.5 Site #: GR05 Field #:
93.24
CeB2
7
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
.-•
Com-
posite
Date
,
©
©
m
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
D
-
••
Event
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
' '
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
� •
��
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1
1 11
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11
�
1 •
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 •
�
1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1
1 1�•
1 111
1 111
1111
1 111
1111
1 111
1111
1 111
1 111
1111
1 111
1 1�•
®
:
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
: • •
Total
' •
•: ••:
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
•: •':
•
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/3/2024
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Durham WQ Permit #: WQ0003504 Field #: 7 Acres Utilized: 17.5
Land Owner: Henry Thorpe Jr. Annual Dry Tons Applied: 93.24 Site #: GR05 Acres Permitted: 17.5
Operator: Henry Thorpe Jr. Predominant Soil Series: CeB2 Cation Exchange Capacity (non 503): 0
Crop 1 Name: Fescue -Hay Crop 1 Max. PAN: 216 Crop 2 Name: Crop 2 Max. PAN:
o
o
Volume applied
(enter one) Solids/
Liquid
Cu. Yds G8110nS
%
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
Wet
Moist)
Precip.
Past 24
Hrs.
inches
a
a
o
� --
*
4.
w -
co
* N
TKN
mg/kg
Z a
.; El
o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
10/18
429
16.7
3.448
South Durham
D
<.5"
S
0.5
0.2
54000
7130
1690
100.875
NA
Fescue
10/19
234
16.7
1.881
South Durham
D
<.5"
S
0.5
0.2
54000
7130
1690
55.023
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
663
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
155,8971
0.000
Lime Applied
Annuallbs/acre
0.053
0.013
4.529
0.212
0.185
0.005
0.362
0.214
0.049
28.665
368.698
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.128
0.044
12.325
0.657
0.532
0.015
0.414
0.574
0.158
79.72
Current Cumulative lbs/ac
0.181
0.057
16.854
0.869
0.717
0.020
0.776
0.788
0.207
108.385
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit 1 st/2nd Crop
1 216
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/3/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: David Walker Owner: David Walker Predominant Soil Series:
Acres Used: 4.4 Acres Permitted: 4.4 Site #: OR05 Field #:
16.46
GeB
7
Residual Analysis Data (Heavy Metals and Total Phosphorus use mj!/kj!, % Solids use Raw Percent #):
kVWPT_"1
Com-
posite
Date
©
©
m
Total
Phos-
phorus
Annual Heavy Metal Field Loadinjjs (Calculated in lbs/acre):
Total
D
ME
Event
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
1 11
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11•
��
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1�
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1.•
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
1 11�
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11�
1 �
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1
��
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
1 1 �
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
®�
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
Total
'
::1:
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
::1:
"1 certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/3/2024
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Durham WQ Permit #: WQ0003504 Field #: 7 Acres Utilized: 4.4
Land Owner: David Walker Annual Dry Tons Applied: 16.46 Site #: OR05 Acres Permitted: 4.4
Operator: David Walker Predominant Soil Series: GeB Cation Exchange Capacity (non 503): 0
Crop 1 Name: Fescue -Pasture Crop 1 Max. PAN: 158.25 Crop 2 Name: Crop 2 Max. PAN:
o
o
Volume applied
(enter one) Solids/
Liquid
Cu. Yds G8110nS
%
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
Wet
Moist)
Precip.
Past 24
Hrs.
inches
a
a
o
� --
*
°�
4.
w -
co
* N
TKN
mg/kg
Z a
.; El
o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
10/11
117
16.7
3.740
South Durham
D
<.5"
S
0.5
0.2
54000
7130
1690
109.420
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
117
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
109.420
0.000
Lime Applied
Annuallbs/acre
0.037
0.009
3.179
0.149
0.130
0.004
0.254
0.150
0.034
20.121
258.808
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.037
0.009
3.179
0.149
0.130
0.004
0.254
0.150
0.034
20.121
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit 1 st/2nd Crop
158.25
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/3/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
City of Durham Total Dry Tons Applied (Annual):
WQ0003504 Cation Exchange Capacity (non 503 only):
David Walker Owner: Don Walker Predominant Soil Series:
57.6 Acres Permitted: 57.6 Site #: OR06 Field #:
197.45
HrB
1
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
kVWPT_"1
Com-
posite
Date
,
©
©
m
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
TotalMEB
D
-
••
Event
1 1 �
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
1 11:
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11:
'
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
� .
1 •
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 •
1 •
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 '
1 11�
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11�
�
�
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
�
1 :
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 :
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
®
:..
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
:..
Total
' •
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
•
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/3/2024
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Durham WQ Permit #: WQ0003504 Field #: 1 Acres Utilized: 57.6
Land Owner: Don Walker Annual Dry Tons Applied: 197.45 Site #: OR06 Acres Permitted: 57.6
Operator: David Walker Predominant Soil Series: HrB Cation Exchange Capacity (non 503): 0
Crop 1 Name: Fescue -Pasture Crop I Max. PAN: 158 Crop 2 Name: Crop 2 Max. PAN:
o
o
Volume applied
(enter one) Solids/
Liquid
Cu. Yds Gallons
%
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
Wet
Moist)
Precip.
Past 24
Hrs.
inches
a
a
o
� --
*
°�
4.
w -
co
* N
TKN
mg/kg
Z a
.; El
o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
1015
585
16.7
1.428
South Durham
D
<.5"
S
0.5
0.2
54000
7130
1690
41.792
NA
Fescue
10/6
156
16.7
0.381
South Durham
D
<.5"
S
0.5
0.2
54000
7130
1690
11.145
NA
Fescue
10/10
624
16.7
1.524
South Durham
D
<.5"
S
0.5
0.2
54000
7130
1690
44.578
NA
Fescue
10/11
39
16.7
0.095
South Durham
D
<.5"
S
0.5
0.2
54000
7130
1690
2.786
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
4-0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
1404
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
100.301
0.000
Lime Applied
Annuallbs/acre
0.034
0.008
2.914
0.136
0.119
0.004
0.233
0.138
0.032
18.443
237.2181
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.421
0.183
29.791
2.381
1.58
0.047
0.781
1.636
0.48
155.108
Current Cumulative lbs/ac
0.455
0.191
32.705
2.517
1.699
0.051
1.014
1.774
0.512
173.551
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
89
1 2498
Permit PAN Limit 1 st/2nd Crop
1 158
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/3/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: David Walker Owner: Don Walker Predominant Soil Series:
Acres Used: 8.9 Acres Permitted: 8.9 Site #: OR06 Field #:
60.33
GeB
2
Residual Analysis Data (Heavy Metals and Total Phosphorus use mj!/kj!, % Solids use Raw Percent #):
kVWPT_"1
Com-
posite
Date
,
©
©
m
Total
Phos-
phorus
Annual Heavy Metal Field Loadinjjs (Calculated in lbs/acre):
TotalMED
••Event
1 1•
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1•
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
��
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
1 •
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 •
1 11
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11
�
1 �•
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 �•
�
��
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1•
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1•
®
• �
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
•
Total
' •
�•` 1
1 111
1 111
1111
1 111
1111
1 111
1111
1 111
1 111
1111
1 111
�•` 1
•
"1 certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/3/2024
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Durham WQ Permit #: WQ0003504 Field #: 2 Acres Utilized: 8.9
Land Owner: Don Walker Annual Dry Tons Applied: 60.33 Site #: OR06 Acres Permitted: 8.9
Operator: David Walker Predominant Soil Series: GeB Cation Exchange Capacity (non 503): 0
Crop 1 Name: Fescue -Hay Crop 1 Max. PAN: 211 Crop 2 Name: Crop 2 Max. PAN:
o
o
Volume applied
(enter one) Solids/
Liquid
Cu. Yds G8110nS
%
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
Wet
Moist)
Precip.
Past 24
Hrs.
inches
a
a
o
� --
*
°�
4.
w -
co
* N
TKN
mg/kg
Z a
.; El
o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
10/6
195
16.7
3.082
South Durham
D
<.5"
S
0.5
0.2
54000
7130
1690
90.159
NA
Fescue
10/9
234
16.7
3.698
South Durham
D
<.5"
S
0.5
0.2
54000
7130
1690
108.190
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
4291
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
198,3491
0.000
Lime Applied
Annuallbs/acre
0.067
0.017
5.762
0.270
0.236
0.007
0.461
0.273
0.063
36.471
469.107
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.621
0.173
44.298
3.053
2.22
0.072
0.902
2.509
0.615
184.996
Current Cumulative lbs/ac
0.688
0.190
50.060
3.323
2.456
0.079
1.363
2.782
0.678
221.467
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit I st/2nd Crop
1 211
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/3/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
City of Durham Total Dry Tons Applied (Annual):
WQ0003504 Cation Exchange Capacity (non 503 only):
Richard Vanhook Owner: Charlie Florence Predominant Soil Series:
41.3 Acres Permitted: 41.3 Site #: OR15 Field #:
202.49
GeB
1
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
kVWPT_"1
•
.•
Date
o
©
o
o
m
m
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
TotalMEBD
••Event
1
1 1 �
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1 •
1 11•
1 11
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
' 1
��®
IZfii'ii}iiiiii'�
1�
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1:
1 1:•
1 1�
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
1 11
1 11
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11:
�
1 1 •
1 111
1111
1 111
1111
1 111
1111
1 111
1 111
1111
1 111
1 •
�'
�1, M�
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1
1 1 •
1 1��
1 111
1111
1 111
1111
1 111
1111
1 111
1 111
1111
1 111
1 1 1
®��
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
: :
Total
' •m
:11
1111
1111
1111
1111
1111
1111
1111
1111
1111
1111
�1 '
•
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/3/2024
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Durham WQ Permit #: WQ0003504 Field #: 1 Acres Utilized: 41.3
Land Owner: Charlie Florence Annual Dry Tons Applied: 202.49 Site #: OR15 Acres Permitted: 41.3
Operator: Richard Vanhook Predominant Soil Series: GeB Cation Exchange Capacity (non 503): 0
Crop 1 Name: Fescue -Hay Crop 1 Max. PAN: 211 Crop 2 Name: Crop 2 Max. PAN:
o
o
Volume applied
(enter one) Solids/
Liquid
Cu. Yds G8110nS
%
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
Wet
Moist)
Precip.
Past 24
Hrs.
inches
a
a
o
� --
*
°�
4.
w -
co
* N
TKN
mg/kg
Z a
.; El
o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
3/24
468
16.1
1.536
South Durham
D
<.5"
S
0.5
0.2
50600
6890
28.6
37.538
NA
Fescue
3/28
507
16.1
1.665
South Durham
D
<.5"
S
0.5
0.2
50600
6890
28.6
40.666
NA
Fescue
8/31
149500
2.73
0.412
Hillsborough
D
<.5"
S
0.5
0.4
5590
3300
64.8
2.168
NA
Fescue
9/1
162500
2.73
0.448
Hillsborough
D
<.5"
S
0.5
0.4
5590
3300
64.8
2.357
NA
Fescue
9/5
1
201500
2.73
0.555
Hillsborough
D
<.5"
S
0.5
1 0.4
5590
3300
1 64.8
2.922
1 NA
Fescue
9/6
104000
2.73
0.287
Hillsborough
D
<.5"
S
0.5
0.4
5590
3300
64.8
1.508
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
975
617500
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
87.159
0.000
Lime Applied
Annuallbs/acre
0.056
0.013
2.910
0.584
0.130
0.008
0.176
0.145
0.070
18.283
240.3931
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.296
0.091
21.31
1.631
1.24
0.026
0.657
1.27
0.328
127.306
Current Cumulative lbs/ac
1 0.352
1 0.104
24.220
2.215
1.370
0.034
0.833
1.415
0.398
145.589
Permitted C. P. L. R.****
1 36
34
1 1338
1
1 267
1 15
1
1 374
89
2498
Permit PAN Limit 1 st/2nd Crop
I F 211
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/3/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Richard Vanhook Owner: Willie Vanhook Predominant Soil Series:
Acres Used: 8.5 Acres Permitted: 8.5 Site #: OR15 Field #:
103.91
GeB
3
Residual Analysis Data (Heavy Metals and Total Phosphorus use mj!/kj!, % Solids use Raw Percent #):
Sample or
1 1
2
3
41
1 51
6
L7 1
81
L 9
-1ol
Li 11
12
Com-
SD
Hillsb
rown
WTP
posite
1/5/23
8/3/23
10/5/23
Date
% Solids
16.1
2.73
19.7
Arsenic
3.8
9.26
14.5
Cadmium
0.988
1.85
1.36
Copper
430
46.3
80.2
Chromium
19.9
134
39.9
Lead
13.5
12.7
97
Mercury
0.764
0.774
0.102
Molyb-
24.6
5.56
1.8
denum
Nickel
17.7
9.3
1 35
Selenium
4.05
13
2.54
Zinc
2800
105
234
Total
Phos-
36800
1410
3620
horus
Annual Heavy Metal Field Loadinjjs (Calculated in lbs/acre):
Total
1 1 1
2
3 1
41
L5161
L7181
1_91
lol
ill 1
12
DT/Ac./
0
App .
14
Event
3.11
2.26
6.85
Arsenic
0.024
1 0.042
0.199
1 0.000
0.000
0.000
1 0.000
0.000
0.000
1 0.000
0.000
0.000
1 0.264
Cadmium
0.006
0.008
0.019
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.033
Copper
2.675
0.210
1.099
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.984
Chromium
0.124
0.606
0.547
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.277
Lead
0.084
0.057
1.329
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.471
Mercury
0.005
0.004
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.010
Molyb-
0.153
0.025
0.025
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.203
denum
Nickel
0.110
0.042
0.480
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.632
Selenium
1 0.025
0.059
0.035
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.119
Zinc
17.422
0.475
3.206
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
21.103
Total
Phos-
228.970
6.382
49.601
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
284.953
horus
"1 certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/3/2024
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Durham WQ Permit #: WQ0003504 Field #: 3 Acres Utilized: 8.5
Land Owner: Willie Vanhook Annual Dry Tons Applied: 103.91 Site #: OR15 Acres Permitted: 8.5
Operator: Richard Vanhook Predominant Soil Series: GeB Cation Exchange Capacity (non 503): 0
Crop 1 Name: Fescue -Pasture Crop 1 Max. PAN: 158 Crop 2 Name: Crop 2 Max. PAN:
o
o
Volume applied
(enter one) Solids/
Liquid
Cu. Yds G8110nS
%
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
Wet
Moist)
Precip.
Past 24
Hrs.
inches
a
a
o
� --
*
°�
4.
w -
co
* N
TKN
mg/kg
Z a
.; El
o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
3/29
195
16.1
3.111
South Durham
D
<.5"
S
0.5
0.2
50600
6890
28.6
75.995
NA
Fescue
9/6
110500
2.73
1.480
Hillsborough
D
<.5"
S
0.5
0.4
5590
3300
64.8
7.787
NA
Fescue
9/7
58500
2.73
0.783
Hillsborough
D
<.5"
S
0.5
0.4
5590
3300
64.8
4.122
NA
Fescue
10/2
351
19.7
6.851
Brown WTP
D
<.5"
S
0.5
0.4
10500
226
5.08
57.928
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
546
169000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
145 8331
o.000
Lime Applied
Annuallbs/acre
0.264
0.033
3.984
1.277
1.471
0.010
0.203
0.632
0.119
21.103
284.9531
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.224
0.08
17.831
1.516
0.971
0.021
0.539
1.088
0.256
106.672
Current Cumulative lbs/ac
0.488
0.113
21.815
2.793
2.442
0.031
0.742
1.720
0.375
127.775
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
89
1 2498
Permit PAN Limit 1 st/2nd Crop
1 158
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/3/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
City of Durham Total Dry Tons Applied (Annual):
WQ0003504 Cation Exchange Capacity (non 503 only):
Martin Carreow Owner: Wolfgang Lotz Predominant Soil Series:
26.9
Acres Permitted: 26.9 Site #: OR70 Field #:
122.66
HeB
2
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
kVWPT_"1
Com-
posite
Date
©
©
m
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
D
ME
Event
1 1 •
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1'
1 11
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11
�®
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
�
�
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 • •
�
1 ••
1 111
1 111
1111
1 111
1111
1 111
1111
1 111
1 111
1111
1 111
1 ••
1 1�
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1�
®
�:•
1 111
1 111
1111
1 111
1111
1 111
1111
1 111
1 111
1111
1 111
•�•
Total
'
•
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
•
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/3/2024
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Durham WQ Permit #: WQ0003504 Field #: 2 Acres Utilized: 26.9
Land Owner: Wolfgang Lotz Annual Dry Tons Applied: 122.66 Site #: OR70 Acres Permitted: 26.9
Operator: Martin Carreow Predominant Soil Series: HeB Cation Exchange Capacity (non 503): 0
Crop 1 Name: Soybeans Crop 1 Max. PAN: 147 Crop 2 Name: Crop 2 Max. PAN:
O =
o
Volume applied
(enter one) Solids/
Liquid
Cu. Yds Gallons
%
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
Wet
Moist)
Precip.
Past 24
Hrs.
inches
a
4 '�
'a
a
o
� --
*
°�
4.
w -
co
* N
TKN
mg/kg
Z a
.; El
o El
0
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
4/4
710
15.9
3.534
South Durham
D
<.5"
S
0.5
0.2
64200
6920
27.9
105.633
NA
Beans
4/5
206
15.9
1.025
South Durham
D
<.5"
S
0.5
0.2
64200
6920
27.9
30.648
NA
Beans
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
916
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
136.2811
0.000
Lime Applied
Annuallbs/acre
0.029
0.007
3.712
0.170
0.130
0.012
0.199
0.166
0.042
24.989
312.816
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.224
0.08
17.831
1.516
0.971
0.021
0.539
1.088
0.256
106.672
Current Cumulative lbs/ac
0.253
0.087
1 21.543
1.686
1.101
0.033
0.738
1 1.254
0.2a9d
Permitted C. P. L. R.****
36
34
1338
267
15
374
8
Permit PAN Limit 1 st/2nd Crop
F 147
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/3/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
City of Durham Total Dry Tons Applied (Annual):
WQ0003504 Cation Exchange Capacity (non 503 only):
Martin Carreow Owner: Wolfgang Lotz Predominant Soil Series:
30.7
Acres Permitted: 30.7 Site #: OR70 Field #:
143.55
ApB
3
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
kVWPT_"1
Com-
posite
Date
©
©
m
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
NED
Event
1 1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1 1
1 11:
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11:
:1.
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
:1•
1 �
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1
1 �
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
�
1 1�
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1�
�
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
1 1�
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1�
®�
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
Total
'
1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/3/2024
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

Facility Name:
Land Owner:
Operator:
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
City of Durham
Wolfgang Lotz
Martin Carreow
Crop 1 Name: Soybeans
WQ Permit #: WQ0003504 Field #:
Annual Dry Tons Applied: 143.55 Site #:
Predominant Soil Series: ApB
Crop 1 Max. PAN: 210 Crop 2 Name:
Acres Utilized:
OR70 Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
30.7
30.7
0
O =
o
Volume applied
(enter one) Solids/
Liquid
Cu. Yds G8110nS
%
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
Wet
Moist)
Precip.
Past 24
Hrs.
inches
a
4 '�
'a
a
o
� --
*
°�
4.
w -
co
* N
TKN
mg/kg
Z a
.; El
o El
0
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
4/5
426
15.9
1.858
South Durham
D
<.5"
S
0.5
0.2
64200
6920
27.9
55.535
NA
Beans
4/6
646
15.9
2.818
South Durham
D
<.5"
S
0.5
0.2
64200
6920
27.9
84.214
NA
Beans
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
1072
o
As
Cd
Cu
Cr
Pb
Hg
Mo
N1
Se
Zn
P
139.7491
0.000
Lime Applied
Annuallbs/acre
0.030
0.008
3.806
0.174
0.134
0.013
0.204
0.170
0.043
25.624
320.774
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.224
0.08
17.831
1.516
0.971
0.021
0.539
1.088
0.256
106.672
Current Cumulative lbs/ac
0.254
0.088
1 21.637
1.690
1.105
0.034
0.743
1.258
0.299
132.296
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
89
2498
Permit PAN Limit 1 st/2nd Crop
F 210
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/3/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
City of Durham Total Dry Tons Applied (Annual):
WQ0003504 Cation Exchange Capacity (non 503 only):
Martin Carreow Owner: Wolfgang Lotz Predominant Soil Series:
33.1
Acres Permitted: 33.1 Site #: OR70 Field #:
157.75
HeB
4
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
kVWPT_"1
Com-
posite
Date
©
©
m
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
TotalMEB
D
-
••
Event
1 1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1 1
1 11:
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11:
::1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
::1
��
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 •
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 •
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
�
1 1:
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1:
�
��
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1� �
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1••
®
• :
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
• :
Total
' •
• •�:
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
•'�:
•
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/3/2024
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Durham WQ Permit #: WQ0003504 Field #: 4 Acres Utilized: 33.1
Land Owner: Wolfgang Lotz Annual Dry Tons Applied: 157.75 Site #: OR70 Acres Permitted: 33.1
Operator: Martin Carreow Predominant Soil Series: HeB Cation Exchange Capacity (non 503): 0
Crop 1 Name: Soybeans Crop 1 Max. PAN: 147 Crop 2 Name: Crop 2 Max. PAN:
O =
o
Volume applied
(enter one) Solids/
Liquid
Cu. Yds Gallons
%
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
Wet
Moist)
Precip.
Past 24
Hrs.
inches
a
4 '�
'a
a
o
� --
*
°�
4.
w -
co
* N
TKN
mg/kg
Z a
.; El
o El
0
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
3/30
390
15.9
1.578
South Durham
D
<.5"
S
0.5
0.2
64200
6920
27.9
47.155
NA
Beans
3/31
195
15.9
0.789
South Durham
D
<.5"
S
0.5
0.2
64200
6920
27.9
23.578
NA
Beans
4/3
593
15.9
2.399
South Durham
D
<.5"
S
0.5
0.2
64200
6920
27.9
71.700
NA
Beans
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
1178
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
142.4331
0.000
Lime Applied
Annuallbs/acre
0.030
0.008
3.880
0.177
0.136
0.013
0.208
0.173
0.044
26.118
326.948
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.224
0.08
17.831
1.516
0.971
0.021
0.539
1.088
0.256
106.672
Current Cumulative lbs/ac
0.254
0.088
21.711
1.693
1.107
0.034
0.747
1.261
0.300
132.790
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit 1 st/2nd Crop
F 147
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/3/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: William Rogers Owner: Linwood Rogers Predominant Soil Series:
Acres Used: 4 Acres Permitted: 4 Site #: OR93 Field #:
15.67
HeB
7
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
kVWPT_"1
Com-
posite
Date
©
©
m
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
TotalME
D
-
••
Event
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
1 11•
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11•
::
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
::
1 �•
1 111
1 111
1111
1 111
1111
1 111
1111
1 111
1 111
1111
1 111
1 �•
��
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
�
�
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
�
1�
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1
1 1 •
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1 •
®�
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
� •
Total
' •
•: 1•
1 111
1 111
1111
1 111
1111
1 111
1111
1 111
1 111
1111
1 111
•: 1•
•
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/3/2024
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Durham WQ Permit #: WQ0003504 Field #: 7 Acres Utilized: 4
Land Owner: Linwood Rogers Annual Dry Tons Applied: 15.67 Site #: OR93 Acres Permitted: 4
Operator: William Rogers Predominant Soil Series: HeB Cation Exchange Capacity (non 503): 0
Crop 1 Name: Soybeans Crop I Max. PAN: 147 Crop 2 Name: Crop 2 Max. PAN:
O =
o
Volume applied
(enter one) Solids/
Liquid
Cu. Yds G8110nS
%
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
Wet
Moist)
Precip.
Past 24
Hrs.
inches
a
4 '�
'a
a
o
� --
*
°�
4.
w -
co :L
* N
TKN
mg/kg
Z a
.; El
o El
a� o0
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
3/31
117
15.9
3.917
South Durham
D
<.5"
S
0.5
0.2
64200
6920
27.9
117.06
NA
Beans
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
117
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
117,063T
0.000
Lime Applied
Annuallbs/acre
0.025
0.006
3.188
0.146
0.112
0.011
0.171
0.143
0.036
21.465
268.706
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.519
0.329
35.767
10.246
3.882
0.224
1.341
4.897
0.493
282.422
Current Cumulative lbs/ac
0.544
1 0.335
38.955
10.392
3.994
0.235
1.512
5.040
0.529
303.887
Permitted C. P. L. R.****
1 36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit 1 st/2nd Crop
1 1 147
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/3/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Roy Carver Owner: Roy Carver Predominant Soil Series:
Acres Used: 36.6 Acres Permitted: 36.6 Site #: PS07 Field #:
80.01
OrB
1
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
kVWPT_"1
Com-
posite
Date
©
©
m
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
D
MEB
Event
1 1 •
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1 •
1 11�
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11�
..
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
..
1 1:�
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1:�
1 1••
1 111
1 111
1111
1 111
1111
1 111
1111
1 111
1 111
1111
1 111
1 1•'
1 11�
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11�
�
1 •1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 •1
�
1 1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1.1
OEM
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
®
•:
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
•:
Total
'
•
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/3/2024
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Durham WQ Permit #: WQ0003504 Field #: 1 Acres Utilized: 36.6
Land Owner: Roy Carver Annual Dry Tons Applied: 80.01 Site #: PS07 Acres Permitted: 36.6
Operator: Roy Carver Predominant Soil Series: OrB Cation Exchange Capacity (non 503): 0
Crop 1 Name: Fescue -Pasture Crop 1 Max. PAN: 72.75 Crop 2 Name: Crop 2 Max. PAN:
o
o
Volume applied
(enter one) Solids/
Liquid
Cu. Yds G8110nS
%
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
Wet
Moist)
Precip.
Past 24
Hrs.
inches
a
a
o
� --
*
°�
4.
w -
co
* N
TKN
mg/kg
Z a
.; El
o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
8/9
551
16.1
2.041
South Durham
D
<.5"
S
0.5
0.2
57600
11800
9.25
61.520
NA
Fescue
8/10
39
16.1
0.144
South Durham
D
<.5"
S
0.5
0.2
57600
11800
9.25
4.354
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
5901
01
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
65.875
omo
Lime Applied
Annuallbs/acre
0.016
0.004
1.766
0.084
0.069
0.004
0.160
0.090
0.025
12.198
156.5181
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.152
0.03
17.691
0.54
0.328
0.007
0.182
0.461
0.338
31.501
Current Cumulative lbs/ac
0.168
1 0.034
19.457
0.624
0.397
0.011
0.342
0.551
0.363
43.699
Permitted C. P. L. R.****
36
34
1338
267
15
374
89
2498
Permit PAN Limit 1 st/2nd Crop
1 72.75
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/3/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Roy Carver Owner: Roy Carver Predominant Soil Series:
Acres Used: 24.4 Acres Permitted: 24.4 Site #: PS07 Field #:
57.36
OnA
2
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
kVWPT_"1
Com-
posite
Date
©
©
m
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
TotalMEB
D
-
••
Event
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
1 11
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11
• 11
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
' l l
1 1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1.1
1 1 �
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
1 11�
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11�
�
�
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
�
1 1 •
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1••
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
®�
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
Total
' •
•:
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
•:
•
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/3/2024
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Durham WQ Permit #: WQ0003504 Field #: 2 Acres Utilized: 24.4
Land Owner: Roy Carver Annual Dry Tons Applied: 57.36 Site #: PS07 Acres Permitted: 24.4
Operator: Roy Carver Predominant Soil Series: OnA Cation Exchange Capacity (non 503): 0
Crop 1 Name: Fescue -Pasture Crop I Max. PAN: 77.25 Crop 2 Name: Crop 2 Max. PAN:
o
o
Volume applied
(enter one) Solids/
Liquid
Cu. Yds Gallons
%
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
Wet
Moist)
Precip.
Past 24
Hrs.
inches
a
a
o
� --
*
°�
4.
w -
co
* N
TKN
mg/kg
Z a
.; El
o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
8/10
295
16.1
1.639
South Durham
D
<.5"
S
0.5
0.2
57600
11800
9.25
49.406
NA
Fescue
8/11
128
16.1
0.711
South Durham
D
<.5"
S
0.5
0.2
57600
11800
9.25
21.437
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
4231
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
70.843
0.000
Lime Applied
Annuallbs/acre
0.017
0.005
1.900
0.090
0.074
0.004
0.173
0.096
0.027
13.119
168.332
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.065
0.017
5.351
0.279
0.239
0.006
0.269
0.254
0.082
38.577
Current Cumulative lbs/ac
0.082
0.022
7.251
0.369
0.313
0.010
0.442
0.350
0.109
51.696
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit 1 st/2nd Crop
1 77.25
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/3/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Durham Total Dry Tons Applied (Annual):
Permit #: WQ0003504 Cation Exchange Capacity (non 503 only):
Operator: Roy Carver Owner: Roy Carver Predominant Soil Series:
Acres Used: 29.5 Acres Permitted: 29.5 Site #: PS07 Field #:
50.56
OnA
3
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
kVWPT_"1
Com-
posite
Date
©
©
m
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
TotalBOB
D
-
••
Event
1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
1 11
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1•
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1•
1 1 �
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1
1 11
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 11
�
1 •
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 •
�
1 1 1
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1 1
1 1 •
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 1'
®
� •�
1 111
1 111
1111
1 111
1111
1 111
1111
1 111
1 111
1111
1 111
• •�
Total
' •
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
1 111
•
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/3/2024
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Durham WQ Permit #: WQ0003504 Field #: 3 Acres Utilized: 29.5
Land Owner: Roy Carver Annual Dry Tons Applied: 50.56 Site #: PS07 Acres Permitted: 29.5
Operator: Roy Carver Predominant Soil Series: OnA Cation Exchange Capacity (non 503): 0
Crop 1 Name: Fescue -Pasture Crop I Max. PAN: 77 Crop 2 Name: Crop 2 Max. PAN:
o
o
Volume applied
(enter one) Solids/
Liquid
Cu. Yds Gallons
%
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
Wet
Moist)
Precip.
Past 24
Hrs.
inches
a
a
o
� --
*
°�
4.
w -
co
* N
TKN
mg/kg
Z a
.; El
o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
8/11
373
16.1
1.714
South Durham
D
<.5"
S
0.5
0.2
57600
11800
9.25
51.670
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp
to this form):
0.000
0.000
TOTALS:
3731
o
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
51.670
0.000
Lime Applied
Annuallbs/acre
0.013
0.003
1.385
0.065
0.054
0.003
0.126
0.070
0.019
9.564
122.722
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.067
0.018
4.95
0.256
0.223
0.007
0.238
0.232
0.067
30.621
Current Cumulative lbs/ac
0.080
0.021
6.335
0.321
0.277
0.010
0.364
0.302
0.086
40.185
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
1 374
1 89
1 2498
Permit PAN Limit 1 st/2nd Crop
1 77
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/3/2024 **Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

Waypointo
ANALYTICAL
1 /17/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Road
Mocksville, NC, 27028
Ref: Analytical Testing
Revised Lab Report Number: 22-004-0034
Client Project Description: Durham, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 1 Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 1/4/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a'—' symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.corn
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2022
Arkansas
State Program
88-0650
02/07/2022
California
State Program
2904
06/30/2022
Florida
State Program
- NELAP
E871157
06/30/2022
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2022
Illinois
State Program
- NELAP
200078
10/10/2022
Kentucky
State Program
80215
06/30/2022
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2022
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2022
South Carolina
State Program
84002
06/30/2022
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2022
Virginia
State Program
- NELAP
460181
09/14/2022
Page 1 of 1 00001/22-004-0034
Page 2 of 9

waypoint 2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
ANALYTICAL www.waypointanalytical.com
Sample Summary Table
Report Number: 22-004-0034
Client Project Description: Durham, NC
Lab No Client Sample ID Matrix Date Collected Date Received
97042 South Durham Solids 01/03/2022 12:05 01/04/2022
Page 3 of 9

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Durham, NC
Lab Report Number: 22-004-0034
Date: 1 /11 /2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 1 Fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
This report is being revised in order to add CCE to the project sample.
Metals Analysis Method 6010D
Sample 97328
Analyte: Aluminum
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Analyte: Arsenic
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Analyte: Calcium
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Analyte: Chromium
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Analyte: Iron
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Analyte: Potassium
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Analyte: Manganese
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Analyte: Lead
QC Batch No: 1-593850/1-593519
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Page 4 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Solids Total Mercury Analysis - CVAA Method 7471A
Sample 97329
Analyte: Mercury
QC Batch No: 1-593529/1-593334
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Page 5 of 9

Waypointo
ANALYTICAL
46245
EMA Resources Inc Project Durham, NC
Mr. Brent Collins
755 Yadkinville Road Information
Mocksville , NC 27028
Report Number : 22-004-0034
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Original Report Date : 01/11/2022
Revised Report Date: 01/17/2022
Received : 01/04/2022
REPORT OF ANAL YSIS
Lab No : 97042
Matrix: Solids
Sample ID : South Durham
Sampled:
1/3/2022 12:05
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Neutralizing Value (%CCE)
19.9
%
0.1
1
01/17/22 11:26
DXT
AOAC 955.01
Moisture
84.4
%
0.010
1
01/04/22 16:05
FMM
SW-DRYWT
Ammonia Nitrogen
8650
mg/Kg - dry
103
641
1
01/11/22 13:30
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
55.1
mg/Kg - dry
30.6
30.6
1
01/10/22 15:19
ZBD
4500NO3F-2011
Organic N
53590
mg/Kg - dry
10900
1
01/11/22 13:30
CALCULATION
pH
8.3
S.U.
1
01/06/2215:16
DRS
9045D
Total Solids
15.6
%
0.010
0.010
1
01/04/22 16:05
FMM
2540G-2011
Total Volatile Solids
68.1
%
0.010
0.010
1
01/04/22 16:05
FMM
2540G-2011
Total Kjeldahl Nitrogen
62200
mg/Kg - dry
10900
10
01/11/22 14:59
CLP 4500NORGD-2011
Phosphorus
41900
mg/Kg - dry
17.7
32.1
1
01/11/22 01:23
EAL
6010D
Aluminum
33500
mg/Kg - dry
29.6
32.1
1
01/11/22 01:23
EAL
6010D
Arsenic
3.21
mg/Kg - dry
1.54
3.21
1
01/11/22 01:23
EAL
6010D
Cadmium
1.04
mg/Kg - dry
0.128
0.641
1
01/11/22 01:23
EAL
6010D
Calcium
20400
mg/Kg - dry
248
321
1
01/11/22 01:23
EAL
6010D
Chromium
19.8
mg/Kg - dry
1.51
1.60
1
01/11/22 01:23
EAL
6010D
Copper
429
mg/Kg - dry
1.99
3.21
1
01/11/22 01:23
EAL
6010D
Iron
16900
mg/Kg - dry
54.6
64.1
1
01/11/22 01:23
EAL
6010D
Lead
32.3
mg/Kg - dry
1.15
1.92
1
01/11/22 01:23
EAL
6010D
Magnesium
6040
mg/Kg - dry
16.5
32.1
1
01/11/22 01:23
EAL
6010D
Manganese
533
mg/Kg - dry
2.08
3.21
1
01/11/22 01:23
EAL
6010D
Mercury
0.301
mg/Kg - dry
0.0442
0.101
1
01/07/22 12:50
JW2
7471A
Molybdenum
32.1
mg/Kg - dry
0.865
1.60
1
01/11/22 01:23
EAL
6010D
Nickel
19.5
mg/Kg - dry
0.769
1.60
1
01/11/22 01:23
EAL
6010D
Qualifiers/ DF
Dilution Factor
L
Limit Exceeded
Definitions MQL
Method Quantitation Limit
Page 6 of 9

Waypointo
ANALYTICAL
46245
EMA Resources Inc Project Durham, NC
Mr. Brent Collins
755 Yadkinville Road Information
Mocksville , NC 27028
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Original Report Date : 01/11/2022
Revised Report Date: 01/17/2022
Received : 01/04/2022
Report Number : 22-004-0034 REPOR T OF A NA L YSIS
Lab No : 97042
Sample ID : South Durham
Matrix: Solids
Sampled: 1/3/2022 12:05
Test
Results
Units
MDL
MQL
DF
Date / Time By
Analytical
Analyzed
Method
Potassium
3230
mg/Kg - dry
39.6
64.1
1
01/11/22 01:23 EAL
6010D
Selenium
6.22
mg/Kg - dry
2.05
3.21
1
01/11/22 01:23 EAL
6010D
Sodium
897
mg/Kg - dry
83.3
160
1
01/11/22 01:23 EAL
6010D
Zinc
2900
mg/Kg - dry
5.19
8.01
1
01/11/22 01:23 EAL
6010D
Sulfur
15600
mg/Kg - dry
33.2
64.1
1
01/11/22 01:23 EAL
6010D
Sodium Absorption Ratio
0.55
Ratio
0.01
0.01
1
01/11/22 01:23
CALCULATION
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
L Limit Exceeded
Page 7 of 9

(2)
WayPAoint..
NALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-004-0034
Shipping Method
Fed Ex 0 US Postal 0 Lab 0 Other:
0 UPS 0 Client 0 Courier Thermometer ID: T135
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
F
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
Yes
0 No
COC agrees with sample label(s)?
U Yes
0 No
COC properly completed
U Yes
0 No
Samples in proper containers?
U Yes
0 No
Sample containers intact?
Yes
0 No
Sufficient sample volume for indicated test(s)?
Yes
0 No
All samples received within holding time?
Yes
0 No
Cooler temperature in compliance?
Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
0 N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr) F Low concentration EnCore samplers (48 hr)
F_ High concentration pre -weighed (methanol -14 d) Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included?
0 Yes
0 No
Comments:
Signature: Emily M. Peterson Date & Time: 01/04/2022 10:25:43
Page 8 of 9

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Page 9 of 9

Waypointo
ANALYTICAL
3/9/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-061-0009
Client Project Description: Durham, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 1 Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 3/2/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a'—' symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 8

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.corn
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2022
Florida
State Program
- NELAP
E871157
06/30/2022
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2022
Illinois
State Program
- NELAP
200078
10/10/2022
Kentucky
State Program
80215
06/30/2022
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2022
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2022
South Carolina
State Program
84002
06/30/2022
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2022
Virginia
State Program
- NELAP
460181
09/14/2022
Page 1 of 1 00001 /22-061-0009
Page 2 of 8

waypoint 2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
ANALYTICAL www.waypointanalytical.com
Sample Summary Table
Report Number: 22-061-0009
Client Project Description: Durham, NC
Lab No Client Sample ID Matrix Date Collected Date Received
99705 South Durham Solids 03/01/2022 09:30 03/02/2022
Page 3 of 8

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Durham, NC
Lab Report Number: 22-061-0009
Date: 3/9/2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 1 Fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 6010D
Sample 85689 (WRC-Eco Gro (March))
Analyte: Aluminum
QC Batch No: 1-603764/1-603023
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 85689 (WRC-Eco Gro (March))
Analyte: Iron
QC Batch No: 1-603764/1-603023
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 85689 (WRC-Eco Gro (March))
Analyte: Phosphorus
QC Batch No: 1-603764/1-603023
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Page 4 of 8

0
Waypoint, 2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
ANALYTICAL www.waypointanalytical.com
46245
EMA Resources Inc Project Durham, NC
Mr. Brent Collins Report Date : 03/09/2022
755 Yadkinville Rd Information : Received : 03/02/2022
Mocksville , NC 27028 n �
Connie Cook
Report Number : 22-061-0009
REPOR T OF A NA L YSIS
Project
Manager
Lab No : 99705
Matrix:
Solids
Sample ID : South Durham
Sampled:
3/1/2022 9:30
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Neutralizing Value (%CCE)
7.2
%
0.1
1
03/07/22 09:15
DXT
AOAC 955.01
Moisture
87.2
%
1
03/07/22 16:11
FMM
SW-DRYWT
Ammonia Nitrogen
9840
mg/Kg - dry
125
781
1
03/09/22 14:00
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
<39.0
mg/Kg - dry
39.0
39.0
1
03/08/22 14:36
ZBD
4500NO3F-2011
Organic N
43910
mg/Kg - dry
1750
1
03/09/22 14:00
CALCULATION
pH
8.2
S.U.
1
03/09/2215:36
DRS
9045D
Total Solids
12.8
%
0.010
0.010
1
03/07/22 16:11
FMM
254OG-2011
Total Volatile Solids
66.8
%
0.010
0.010
1
03/07/22 16:11
FMM
254OG-2011
Total Kjeldahl Nitrogen
53800
mg/Kg - dry
1750
1
03/09/22 15:54
CLP 4500NORGD-2011
Phosphorus
36400
mg/Kg - dry
21.6
39.1
1
03/09/22 04:57
TJS
6010D
Aluminum
25400
mg/Kg - dry
36.1
39.1
1
03/09/22 04:57
TJS
6010D
Arsenic
3.56 J
mg/Kg - dry
1.88
3.91
1
03/09/22 04:57
TJS
6010D
Cadmium
0.691 J
mg/Kg - dry
0.156
0.781
1
03/09/22 04:57
TJS
6010D
Calcium
17800
mg/Kg - dry
302
391
1
03/09/22 04:57
TJS
6010D
Chromium
17.1
mg/Kg - dry
1.84
1.95
1
03/09/22 04:57
TJS
6010D
Copper
361
mg/Kg - dry
2.42
3.91
1
03/09/22 04:57
TJS
6010D
Iron
16800
mg/Kg - dry
66.6
78.1
1
03/09/22 04:57
TJS
6010D
Lead
17.9
mg/Kg - dry
1.41
2.34
1
03/09/22 04:57
TJS
6010D
Magnesium
5340
mg/Kg - dry
20.2
39.1
1
03/09/22 04:57
TJS
6010D
Manganese
524
mg/Kg - dry
2.54
3.91
1
03/09/22 04:57
TJS
6010D
Mercury
0.472
mg/Kg - dry
0.0517
0.119
1
03/03/22 12:12
JW2
7471A
Molybdenum
15.5
mg/Kg - dry
1.05
1.95
1
03/09/22 04:57
TJS
6010D
Nickel
16.4
mg/Kg - dry
0.937
1.95
1
03/09/22 04:57
TJS
6010D
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 5 of 8

0
Waypoint,
2790 Whitten
Road, Memphis, TN 38133
Main 901.213.2400 0
Fax [phone]
ANALYTICAL
www.waypointanalytical.com
46245
EMA Resources Inc
Project
Durham, NC
Mr. Brent Collins
Report Date : 03/09/2022
755 Yadkinville Rd
Information :
Received : 03/02/2022
Mocksville , NC 27028
Connie Cook
Report Number : 22-061-0009
REPOR T OF A NA L YSIS
Project Manager
Lab No : 99705
Matrix: Solids
Sample ID : South Durham
Sampled: 3/1/2022 9:30
Test
Results
Units
MDL
MQL DF
Date / Time By Analytical
Analyzed Method
Potassium
2960
mg/Kg - dry
48.3
78.1 1
03/09/22 04:57 TJS 6010D
Selenium
2.913
mg/Kg - dry
2.50
3.91 1
03/09/22 04:57 TJS 6010D
Sodium
672
mg/Kg - dry
102
195 1
03/09/22 04:57 TJS 6010D
Zinc
2590
mg/Kg - dry
6.33
9.77 1
03/09/22 04:57 TJS 6010D
Sulfur
12700
mg/Kg - dry
40.5
78.1 1
03/09/22 04:57 TJS 6010D
Sodium Absorption Ratio
0.40
Ratio
0.01
0.01 1
03/09/22 04:57 CALCULATION
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
J Estimated value
Page 6 of 8

(2)
WayPAoint..
NALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-061-0009
Shipping Method
Fed Ex 0 US Postal 0 Lab 0 Other:
0 UPS 0 Client 0 Courier Thermometer ID: T102
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
F
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
Yes
0 No
COC agrees with sample label(s)?
U Yes
0 No
COC properly completed
U Yes
0 No
Samples in proper containers?
U Yes
0 No
Sample containers intact?
Yes
0 No
Sufficient sample volume for indicated test(s)?
Yes
0 No
All samples received within holding time?
Yes
0 No
Cooler temperature in compliance?
Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
0 N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr) F Low concentration EnCore samplers (48 hr)
F_ High concentration pre -weighed (methanol -14 d) Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included?
0 Yes
0 No
Comments:
Signature: Makayla Weaver Date & Time: 03/02/2022 09:28:39
Page 7 of 8

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Page 8 of 8

Waypointo
ANALYTICAL
5/20/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-132-0037
Client Project Description: Durham, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 1 Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 5/12/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a'—' symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.corn
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2022
Florida
State Program
- NELAP
E871157
06/30/2022
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2022
Illinois
State Program
- NELAP
200078
10/10/2022
Kentucky
State Program
80215
06/30/2022
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2022
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2022
South Carolina
State Program
84002
06/30/2022
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2022
Virginia
State Program
- NELAP
460181
09/14/2022
Page 1 of 1 00001/22-132-0037
Page 2 of 9

waypoint 2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
ANALYTICAL www.waypointanalytical.com
Sample Summary Table
Report Number: 22-132-0037
Client Project Description: Durham, NC
Lab No Client Sample ID Matrix Date Collected Date Received
90568 South Durham Solids 05/11/2022 10:00 05/12/2022
Page 3 of 9

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Durham, NC
Lab Report Number: 22-132-0037
Date: 5/19/2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 1 Fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 6010D
Sample 90600 (TB-11-3)
Analyte: Aluminum
QC Batch No: 1-617172/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90600 (TB-11-3)
Analyte: Arsenic
QC Batch No: 1-616955/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Sample 90600 (TB-11-3)
Analyte: Calcium
QC Batch No: 1-616955/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90600 (TB-11-3)
Analyte: Chromium
QC Batch No: 1-616955/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90600 (TB-11-3)
Analyte: Iron
QC Batch No: 1-617172/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90600 (TB-11-3)
Analyte: Potassium
QC Batch No: 1-616955/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90600 (TB-11-3)
Analyte: Manganese
QC Batch No: 1-617172/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Page 4 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Sample 90600 (TB-11-3)
Analyte: Phosphorus
QC Batch No: 1-616955/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90600 (TB-11-3)
Analyte: Selenium
QC Batch No: 1-617172/1-616254
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Solids Total Mercury Analysis - CVAA Method 7471A
Sample 90592 (TB-7-3)
Analyte: Mercury
QC Batch No: 1-616692/1-615833
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Page 5 of 9

0
Waypoint, 2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
ANALYTICAL www.waypointanalytical.com
46245
EMA Resources Inc Project Durham, NC
Mr. Brent Collins Report Date : 05/20/2022
755 Yadkinville Rd Information : Received : 05/12/2022
Mocksville , NC 27028 n �
Connie Cook
Report Number : 22-132-0037
REPOR T OF A NA L YSIS
Project
Manager
Lab No : 90568
Matrix:
Solids
Sample ID : South Durham
Sampled:
5/11/2022
10:00
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Neutralizing Value (%CCE)
10.5
%
0.1
1
05/19/22 14:16
DXT
AOAC 955.01
Moisture
82.0
%
1
05/18/22 16:00
FMM
SW-DRYWT
Ammonia Nitrogen
10600
mg/Kg - dry
88.9
556
1
05/19/22 14:30
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
78.9
mg/Kg - dry
25.3
25.3
1
05/17/22 14:38
ZBD
4500NO3F-2016
Organic N
48890
mg/Kg - dry
5156
10390
1
05/17/22 17:12
CALCULATION
pH
7.5
S.U.
1
05/19/2215:08
DRS
9045D
Total Solids
18.0
%
0.010
0.010
1
05/18/22 16:00
FMM
2540G-2011
Total Volatile Solids
63.7
%
0.010
0.010
1
05/18/22 16:00
FMM
2540G-2011
Total Kjeldahl Nitrogen
59400
mg/Kg - dry
10400
10
05/17/22 17:12
CLP 4500NORGD-2011
Phosphorus
34300
mg/Kg - dry
15.3
27.8
1
05/18/22 18:15
TJS
6010D
Aluminum
26100
mg/Kg - dry
25.7
27.8
1
05/18/22 18:15
TJS
6010D
Arsenic
3.74
mg/Kg - dry
1.33
2.78
1
05/18/22 18:15
TJS
6010D
Cadmium
0.683
mg/Kg - dry
0.111
0.556
1
05/18/22 18:15
TJS
6010D
Calcium
19000
mg/Kg - dry
215
278
1
05/18/22 18:15
TJS
6010D
Chromium
19.3
mg/Kg - dry
1.31
1.39
1
05/18/22 18:15
TJS
6010D
Copper
366
mg/Kg - dry
1.72
2.78
1
05/18/22 18:15
TJS
6010D
Iron
17600
mg/Kg - dry
47.3
55.6
1
05/18/22 18:15
TJS
6010D
Lead
15.7
mg/Kg - dry
1.00
1.67
1
05/18/22 18:15
TJS
6010D
Magnesium
5070
mg/Kg - dry
14.3
27.8
1
05/18/22 18:15
TJS
6010D
Manganese
583
mg/Kg - dry
1.81
2.78
1
05/18/22 18:15
TJS
6010D
Mercury
0.2573
mg/Kg - dry
0.0339
0.778
1
05/17/22 12:21
JTR
7471A
Molybdenum
15.1
mg/Kg - dry
0.750
1.39
1
05/18/22 18:15
TJS
6010D
Nickel
15.9
mg/Kg - dry
0.666
1.39
1
05/18/22 18:15
TJS
6010D
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 6 of 9

0
Waypoint,
2790 Whitten
Road, Memphis, TN 38133
Main 901.213.2400 0
Fax [phone]
ANALYTICAL
www.waypointanalytical.com
46245
EMA Resources Inc
Project
Durham, NC
Mr. Brent Collins
Report Date : 05/20/2022
755 Yadkinville Rd
Information :
Received : 05/12/2022
Mocksville , NC 27028
Connie Cook
Report Number : 22-132-0037
REPOR T OF A NA L YSIS
Project Manager
Lab No : 90568
Matrix: Solids
Sample ID : South Durham
Sampled: 5/11/2022 10:00
Test
Results
Units
MDL
MQL DF
Date / Time By Analytical
Analyzed Method
Potassium
3260
mg/Kg - dry
34.3
55.6 1
05/18/22 18:15 TJS 6010D
Selenium
4.07
mg/Kg - dry
1.78
2.78 1
05/18/22 18:15 TJS 6010D
Sodium
817
mg/Kg - dry
72.2
139 1
05/18/22 18:15 TJS 6010D
Zinc
2520
mg/Kg - dry
4.50
6.94 1
05/18/22 18:15 TJS 6010D
Sulfur
12400
mg/Kg - dry
28.8
55.6 1
05/18/22 18:15 TJS 6010D
Sodium Absorption Ratio
0.57
Ratio
0.01
0.01 1
05/18/22 18:15 CALCULATION
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
J Estimated value
Page 7 of 9

(2)
WayPAoint..
NALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-132-0037
Shipping Method
Fed Ex 0 US Postal 0 Lab 0 Other:
0 UPS 0 Client 0 Courier Thermometer ID: T102
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
F
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
Yes
0 No
COC agrees with sample label(s)?
U Yes
0 No
COC properly completed
U Yes
0 No
Samples in proper containers?
U Yes
0 No
Sample containers intact?
Yes
0 No
Sufficient sample volume for indicated test(s)?
Yes
0 No
All samples received within holding time?
Yes
0 No
Cooler temperature in compliance?
Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
0 N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr) F Low concentration EnCore samplers (48 hr)
F_ High concentration pre -weighed (methanol -14 d) Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included?
0 Yes
0 No
Comments:
Signature: Emily M. Peterson Date & Time: 05/12/2022 09:51:50
Page 8 of 9

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Page 9 of 9

Waypointo
ANALYTICAL
7/25/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-193-0012
Client Project Description: Durham, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 1 Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 7/12/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a'—' symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 8

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.corn
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2023
Florida
State Program
- NELAP
E871157
06/30/2023
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2023
Illinois
State Program
- NELAP
200078
10/10/2022
Kentucky
State Program
80215
06/30/2022
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2023
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2023
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2023
Virginia
State Program
- NELAP
460181
09/14/2022
Page 1 of 1 00001/22-193-0012
Page 2 of 8

waypoint 2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
ANALYTICAL www.waypointanalytical.com
Sample Summary Table
Report Number: 22-193-0012
Client Project Description: Durham, NC
Lab No Client Sample ID Matrix Date Collected Date Received
97765 South Durham Solids 07/08/2022 08:00 07/12/2022
Page 3 of 8

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Durham, NC
Lab Report Number: 22-193-0012
Date: 7/25/2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 1 Fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 6010D
Sample 97768 (Brown WTP)
Analyte: Iron
QC Batch No: 1-627558/1-626741
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 97768 (Brown WTP)
Analyte: Manganese
QC Batch No: 1-627558/1-626741
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 97768 (Brown WTP)
Analyte: Selenium
QC Batch No: 1-627558/1-626741
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Solids Total Mercury Analysis - CVAA Method 7471A
Sample 97765 (South Durham)
Analyte: Mercury
QC Batch No: 1-627730/1-627536
Target analyte(s) was identified in the method blank associated with this project, below the Method Quantitation
Limit. Per laboratory protocol any associated affected sample result is flagged "B" to indicate that it was detected
in the method blank.
Sample 97766 (Shelby WTP)
Analyte: Mercury
QC Batch No: 1-627730/1-627536
Target analyte(s) was identified in the method blank associated with this project, below the Method Quantitation
Limit. Per laboratory protocol any associated affected sample result is flagged "B" to indicate that it was detected
in the method blank.
Page 4 of 8

0
Waypoint, 2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
ANALYTICAL www.waypointanalytical.com
46245
EMA Resources Inc Project Durham, NC
Mr. Brent Collins Report Date : 07/25/2022
755 Yadkinville Rd Information : Received : 07/12/2022
Mocksville , NC 27028 n �
Connie Cook
Report Number : 22-193-0012
REPOR T OF A NA L YSIS
Project
Manager
Lab No : 97765
Matrix:
Solids
Sample ID : South Durham
Sampled:
7/8/2022 8:00
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Moisture
87.0
%
1
07/12/22 15:45
FMM
SW-DRYWT
Ammonia Nitrogen
12500
mg/Kg - dry
123
769
1
07/25/22 07:37
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
41.0
mg/Kg - dry
32.3
32.3
1
07/19/22 14:57
ZBD
4500NO3F-2016
Organic N
38620
mg/Kg - dry
1300
2623
1
07/18/22 14:04
CALCULATION
pH
8.0
S.U.
1
07/18/2215:04
DRS
9045D
Total Solids
13.0
%
0.010
0.010
1
07/12/22 15:45
FMM
2540G-2011
Total Volatile Solids
66.5
%
0.010
0.010
1
07/12/22 15:45
FMM
2540G-2011
Total Kjeldahl Nitrogen
51200
mg/Kg - dry
2620
1
07/18/22 14:04
CLP 4500NORGD-2011
Phosphorus
39900
mg/Kg - dry
21.2
38.5
1
07/18/22 20:21
EAL
6010D
Aluminum
33200
mg/Kg - dry
35.5
38.5
1
07/18/22 20:21
EAL
6010D
Arsenic
6.96
mg/Kg - dry
1.85
3.85
1
07/18/22 20:21
EAL
6010D
Cadmium
0.969
mg/Kg - dry
0.154
0.769
1
07/18/22 20:21
EAL
6010D
Calcium
20500
mg/Kg - dry
298
385
1
07/18/22 20:21
EAL
6010D
Chromium
20.1
mg/Kg - dry
1.82
1.92
1
07/18/22 20:21
EAL
6010D
Copper
441
mg/Kg - dry
2.38
3.85
1
07/18/22 20:21
EAL
6010D
Iron
18700
mg/Kg - dry
65.5
76.9
1
07/18/22 20:21
EAL
6010D
Lead
17.9
mg/Kg - dry
1.38
2.31
1
07/18/22 20:21
EAL
6010D
Magnesium
5790
mg/Kg - dry
19.8
38.5
1
07/18/22 20:21
EAL
6010D
Manganese
668
mg/Kg - dry
2.50
3.85
1
07/18/22 20:21
EAL
6010D
Mercury
0.628 )B
mg/Kg - dry
0.0479
1.10
1
07/20/22 11:12
JTR
7471A
Molybdenum
23.7
mg/Kg - dry
1.04
1.92
1
07/18/22 20:21
EAL
6010D
Nickel
16.5
mg/Kg - dry
0.923
1.92
1
07/18/22 20:21
EAL
6010D
Potassium
3310
mg/Kg - dry
47.5
76.9
1
07/20/22 18:15
TJS
6010D
Qualifiers/ B
Analyte detected in blank
DF
Dilution Factor
Definitions J
Estimated value
MQL
Method Quantitation
Limit
Page 5 of 8

0
Waypoint,
2790 Whitten
Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
ANALYTICAL
www.waypointanalytical.com
46245
EMA Resources Inc
Project
Durham, NC
Mr. Brent Collins
Report Date : 07/25/2022
755 Yadkinville Rd
Information :
Received : 07/12/2022
Mocksville , NC 27028
Connie Cook
Report Number : 22-193-0012
REPOR T OF A NA L YSIS
Project Manager
Lab No : 97765
Matrix: Solids
Sample ID : South Durham
Sampled: 7/8/2022 8:00
Test
Results
Units
MDL
MQL DF Date / Time By Analytical
Analyzed Method
Selenium
5.76
mg/Kg - dry
2.46
3.85 1 07/18/22 20:21 EAL 6010D
Sodium
954
mg/Kg - dry
100
192 1 07/18/22 20:21 EAL 6010D
Zinc
2820
mg/Kg - dry
6.23
9.62 1 07/18/22 20:21 EAL 6010D
Sulfur
13400
mg/Kg - dry
39.8
76.9 1 07/18/22 20:21 EAL 6010D
Sodium Absorption Ratio
0.54
Ratio
0.01
0.01 1 07/18/22 20:21 CALCULATION
Qualifiers/ B Analyte detected in blank
Definitions
DF Dilution Factor
Page 6 of 8

(2)
WayPAoint..
NALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-193-0012
Shipping Method
Fed Ex 0 US Postal 0 Lab 0 Other:
0 UPS 0 Client 0 Courier Thermometer ID: T102
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
F
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
Yes
0 No
COC agrees with sample label(s)?
U Yes
0 No
COC properly completed
U Yes
0 No
Samples in proper containers?
U Yes
0 No
Sample containers intact?
Yes
0 No
Sufficient sample volume for indicated test(s)?
Yes
0 No
All samples received within holding time?
Yes
0 No
Cooler temperature in compliance?
Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
0 N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr) F Low concentration EnCore samplers (48 hr)
F_ High concentration pre -weighed (methanol -14 d) Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included?
0 Yes
0 No
Comments:
Signature: Emily M. Peterson Date & Time: 07/12/2022 09:36:17
Page 7 of 8

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Page 8 of 8

Waypointo
ANALYTICAL
10/13/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-277-0023
Client Project Description: Durham, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 1 Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 10/4/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a'—' symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 8

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.corn
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2023
Florida
State Program
- NELAP
E871157
06/30/2023
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2023
Illinois
State Program
- NELAP
200078
10/10/2023
Kentucky
State Program
80215
06/30/2023
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2023
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2023
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2023
Virginia
State Program
- NELAP
460181
09/14/2023
Page 1 of 1 00001/22-277-0023
Page 2 of 8

waypoint 2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
ANALYTICAL www.waypointanalytical.com
Sample Summary Table
Report Number: 22-277-0023
Client Project Description: Durham, NC
Lab No Client Sample ID Matrix Date Collected Date Received
92506 South Durham Solids 10/03/2022 11:45 10/04/2022
Page 3 of 8

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Durham, NC
Lab Report Number: 22-277-0023
Date: 10/12/2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 1 Fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 6010D
Sample 97015 (Bolster)
Analyte: Potassium
QC Batch No: L641846/L641319
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 97015 (Bolster)
Analyte: Magnesium
QC Batch No: 1-642077/1-641319
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 97015 (Bolster)
Analyte: Manganese
QC Batch No: L641846/L641319
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 97015 (Bolster)
Analyte: Sodium
QC Batch No: 1-641846/1-641319
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 97015 (Bolster)
Analyte: Sulfur
QC Batch No: 1-642077/1-641319
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 97015 (Bolster)
Analyte: Zinc
QC Batch No: 1-642350/1-641319
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Solids Total Mercury Analysis - CVAA Method 7471A
Sample 89992 (September Monthly Comp)
Analyte: Mercury
QC Batch No: 1-641708/1-641289
The matrix spike, matrix spike duplicate and the post digestion spike were all outside of the quality control
acceptance ranges. Matrix interference is suspected
Page 4 of 8

0
Waypoint, 2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
ANALYTICAL www.waypointanalytical.com
46245
EMA Resources Inc Project Durham, NC
Mr. Brent Collins Report Date : 10/13/2022
755 Yadkinville Rd Information : Received : 10/04/2022
Mocksville , NC 27028 n �
Connie Cook
Report Number : 22-277-0023
REPOR T OF A NA L YSIS
Project
Manager
Lab No : 92506
Matrix:
Solids
Sample ID : South Durham
Sampled:
10/3/2022
11:45
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Moisture
84.2
%
1
10/07/22 15:44
FMM
SW-DRYWT
Ammonia Nitrogen
9810
mg/Kg - dry
101
633
1
10/12/22 15:20
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
1690
mg/Kg - dry
31.5
31.5
1
10/08/22 11:28
ZBD
4500NO3F-2016
Organic N
41080
mg/Kg - dry
1329
2677
1
10/06/22 14:58
CALCULATION
pH
7.7
S.U.
1
10/11/2216:00
SAR
9045D
Total Solids
15.8
%
0.010
0.010
1
10/07/22 15:44
FMM
2540G-2011
Total Volatile Solids
63.3
%
0.010
0.010
1
10/07/22 15:44
FMM
2540G-2011
Total Kjeldahl Nitrogen
50900
mg/Kg - dry
2680
1
10/06/22 14:58
ANH 4500NORGD-2011
Phosphorus
40800
mg/Kg - dry
17.5
31.6
1
10/07/22 00:20
JTR
6010D
Aluminum
34400
mg/Kg - dry
29.2
31.6
1
10/07/22 00:20
JTR
6010D
Arsenic
4.92
mg/Kg - dry
1.52
3.16
1
10/07/22 00:20
JTR
6010D
Cadmium
0.848
mg/Kg - dry
0.127
0.633
1
10/07/22 00:20
JTR
6010D
Calcium
20400
mg/Kg - dry
245
316
1
10/07/22 00:20
JTR
6010D
Chromium
21.8
mg/Kg - dry
1.49
1.58
1
10/07/22 00:20
JTR
6010D
Copper
465
mg/Kg - dry
1.96
3.16
1
10/07/22 00:20
JTR
6010D
Iron
18400
mg/Kg - dry
53.9
63.3
1
10/07/22 00:20
JTR
6010D
Lead
18.3
mg/Kg - dry
1.14
1.90
1
10/07/22 00:20
JTR
6010D
Magnesium
6030
mg/Kg - dry
16.3
31.6
1
10/07/22 00:20
EAL
6010D
Manganese
603
mg/Kg - dry
2.06
3.16
1
10/07/22 00:20
JTR
6010D
Mercury
0.3803
mg/Kg - dry
0.0408
0.937
1
10/06/22 13:21
TJS
7471A
Molybdenum
21.8
mg/Kg - dry
0.854
1.58
1
10/07/22 00:20
JTR
6010D
Nickel
18.4
mg/Kg - dry
0.759
1.58
1
10/07/22 00:20
JTR
6010D
Potassium
3170
mg/Kg - dry
39.1
63.3
1
10/07/22 00:20
JTR
6010D
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 5 of 8

0
Waypoint,
2790 Whitten
Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
ANALYTICAL
www.waypointanalytical.com
46245
EMA Resources Inc
Project
Durham, NC
Mr. Brent Collins
Report Date : 10/13/2022
755 Yadkinville Rd
Information :
Received : 10/04/2022
Mocksville , NC 27028
Connie Cook
Report Number : 22-277-0023
REPOR T OF A NA L YSIS
Project Manager
Lab No : 92506
Matrix: Solids
Sample ID : South Durham
Sampled: 10/3/2022 11:45
Test
Results
Units
MDL
MQL DF Date / Time By Analytical
Analyzed Method
Selenium
6.65
mg/Kg - dry
2.03
3.16 1 10/07/22 00:20 JTR 6010D
Sodium
968
mg/Kg - dry
82.3
158 1 10/07/22 00:20 JTR 6010D
Zinc
3050
mg/Kg - dry
5.13
7.91 1 10/07/22 00:20 JTR 6010D
Sulfur
14600
mg/Kg - dry
32.8
63.3 1 10/07/22 23:37 TJS 6010D
Sodium Absorption Ratio
0.60
Ratio
0.01
0.01 1 10/07/22 00:20 CALCULATION
Qualifiers/ DF Dilution Factor
Definitions
J Estimated value
Page 6 of 8

(2)
WayPAoint..
NALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-277-0023
Shipping Method
Fed Ex 0 US Postal 0 Lab 0 Other:
0 UPS 0 Client 0 Courier Thermometer ID: T102
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
F
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
Yes
0 No
COC agrees with sample label(s)?
U Yes
0 No
COC properly completed
U Yes
0 No
Samples in proper containers?
U Yes
0 No
Sample containers intact?
Yes
0 No
Sufficient sample volume for indicated test(s)?
Yes
0 No
All samples received within holding time?
Yes
0 No
Cooler temperature in compliance?
Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
0 N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr) F Low concentration EnCore samplers (48 hr)
F_ High concentration pre -weighed (methanol -14 d) Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included?
0 Yes
0 No
Comments:
Signature: Makayla Weaver Date & Time: 10/04/2022 09:26:32
Page 7 of 8

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Page 8 of 8

Waypointo
ANALYTICAL
11 /16/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-313-0012
Client Project Description: Durham, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 1 Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 11/9/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a'—' symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 8

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.corn
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2023
Florida
State Program
- NELAP
E871157
06/30/2023
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2023
Illinois
State Program
- NELAP
200078
10/10/2023
Kentucky
State Program
80215
06/30/2023
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2023
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
47701
07/31/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2023
South Carolina
State Program
84002
06/30/2023
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2023
Virginia
State Program
- NELAP
460181
09/14/2023
Page 1 of 1 00001/22-313-0012
Page 2 of 8

waypoint 2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
ANALYTICAL www.waypointanalytical.com
Sample Summary Table
Report Number: 22-313-0012
Client Project Description: Durham, NC
Lab No Client Sample ID Matrix Date Collected Date Received
88406 South Durham Solids 11/08/2022 08:45 11/09/2022
Page 3 of 8

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Durham, NC
Lab Report Number: 22-313-0012
Date: 11 /16/2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 1 Fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 6010D
Sample 88406 (South Durham)
Analyte: Calcium
QC Batch No: L648346/L647961
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88406 (South Durham)
Analyte: Iron
QC Batch No: L648346/L647961
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88406 (South Durham)
Analyte: Phosphorus
QC Batch No: L648346/L647961
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88406 (South Durham)
Analyte: Sulfur
QC Batch No: L648346/L647961
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88406 (South Durham)
Analyte: Zinc
QC Batch No: L648346/L647961
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Page 4 of 8

0
Waypoint, 2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
ANALYTICAL www.waypointanalytical.com
46245
EMA Resources Inc Project Durham, NC
Mr. Brent Collins Report Date : 11/16/2022
755 Yadkinville Rd Information : Received : 11/09/2022
Mocksville , NC 27028 n �
Connie Cook
Report Number : 22-313-0012
REPOR T OF A NA L YSIS
Project
Manager
Lab No : 88406
Matrix:
Solids
Sample ID : South Durham
Sampled:
11/8/2022
8:45
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Moisture
83.7
%
1
11/10/22 16:03
FMM
SW-DRYWT
Ammonia Nitrogen
6500
mg/Kg - dry
98.2
613
1
11/15/22 13:30
CLP
4500NH3C-2011
Nitrate+Nitrite-N
150
mg/Kg - dry
30.4
30.4
1
11/11/22 10:39
ZBD
4500NO3F-2016
Organic N
47180
mg/Kg - dry
779.1
1571
1
11/15/22 09:09
DH
CALCULATION
pH
6.7
S.U.
1
11/16/2216:36
DRS
9045D
Total Solids
16.3
%
0.010
0.010
1
11/10/22 16:03
FMM
2540G-2011
Total Volatile Solids
68.0
%
0.010
0.010
1
11/10/22 16:03
FMM
2540G-2011
Total Kjeldahl Nitrogen
53700
mg/Kg - dry
1570
1
11/15/22 09:09
ANH 4500NORGD-2011
Phosphorus
39500
mg/Kg - dry
16.9
30.7
1
11/10/22 21:39
JTR
6010D
Aluminum
31300
mg/Kg - dry
28.3
30.7
1
11/10/22 21:39
JTR
6010D
Arsenic
4.29
mg/Kg - dry
1.47
3.07
1
11/11/22 13:33
TJS
6010D
Cadmium
0.816
mg/Kg - dry
0.123
0.613
1
11/10/22 21:39
JTR
6010D
Calcium
22300
mg/Kg - dry
237
307
1
11/10/22 21:39
JTR
6010D
Chromium
19.9
mg/Kg - dry
1.45
1.53
1
11/10/22 21:39
JTR
6010D
Copper
484
mg/Kg - dry
1.90
3.07
1
11/10/22 21:39
JTR
6010D
Iron
15300
mg/Kg - dry
52.3
61.3
1
11/10/22 21:39
JTR
6010D
Lead
15.5
mg/Kg - dry
1.10
1.84
1
11/10/22 21:39
JTR
6010D
Magnesium
6260
mg/Kg - dry
15.8
30.7
1
11/10/22 21:39
JTR
6010D
Manganese
530
mg/Kg - dry
1.99
3.07
1
11/10/22 21:39
JTR
6010D
Mercury
0.7123
mg/Kg - dry
0.0366
0.840
1
11/11/22 12:03
JTR
7471A
Molybdenum
23.9
mg/Kg - dry
0.828
1.53
1
11/10/22 21:39
JTR
6010D
Nickel
19.2
mg/Kg - dry
0.736
1.53
1
11/10/22 21:39
JTR
6010D
Potassium
3100
mg/Kg - dry
37.9
61.3
1
11/10/22 21:39
JTR
6010D
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 5 of 8

0
Waypoint,
2790 Whitten
Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
ANALYTICAL
www.waypointanalytical.com
46245
EMA Resources Inc
Project
Durham, NC
Mr. Brent Collins
Report Date : 11/16/2022
755 Yadkinville Rd
Information :
Received : 11/09/2022
Mocksville , NC 27028
Connie Cook
Report Number : 22-313-0012
REPOR T OF A NA L YSIS
Project Manager
Lab No : 88406
Matrix: Solids
Sample ID : South Durham
Sampled: 11/8/2022 8:45
Test
Results
Units
MDL
MQL DF Date / Time By Analytical
Analyzed Method
Selenium
6.20
mg/Kg - dry
1.96
3.07 1 11/10/22 21:39 JTR 6010D
Sodium
926
mg/Kg - dry
79.8
153 1 11/10/22 21:39 JTR 6010D
Zinc
3090
mg/Kg - dry
4.97
7.67 1 11/10/22 21:39 JTR 6010D
Sulfur
15200
mg/Kg - dry
31.8
61.3 1 11/10/22 21:39 JTR 6010D
Sodium Absorption Ratio
0.56
Ratio
0.01
0.01 1 11/10/22 21:39 CALCULATION
Qualifiers/ DF Dilution Factor
Definitions
J Estimated value
Page 6 of 8

(2)
WayPAoint..
NALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-313-0012
Shipping Method
Fed Ex 0 US Postal 0 Lab 0 Other:
0 UPS 0 Client 0 Courier Thermometer ID: T135
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
F
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
Yes
0 No
COC agrees with sample label(s)?
U Yes
0 No
COC properly completed
U Yes
0 No
Samples in proper containers?
U Yes
0 No
Sample containers intact?
Yes
0 No
Sufficient sample volume for indicated test(s)?
Yes
0 No
All samples received within holding time?
Yes
0 No
Cooler temperature in compliance?
Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
0 N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr) F Low concentration EnCore samplers (48 hr)
F_ High concentration pre -weighed (methanol -14 d) Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included?
0 Yes
0 No
Comments:
Signature: Emily M. Peterson Date & Time: 11/09/2022 09:33:58
Page 7 of 8

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Page 8 of 8

PaceAnalytical
ANALYTICAL REPORT
March 12. 2022
EMA Resources
Sample Delivery Group
Samples Received:
Project Number:
Description:
Report To:
L1462850
02/17/2022
Sludge
Mr. Brent Collins
755 Yadkinville Road
Mocksville, NC 27028
Entire Report Reviewed By
ziQ4ZQia i Cwl,Gt
Cassandra Foster
Project Manager
Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be
reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace
Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and ,
ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided,
and as the samples are received.
I
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1462850 03/12/22 11:41 1 of 34

TABLE OF CONTENTS
Cp: Cover Page
1
FP1
Tc: Table of Contents
2
Ss: Sample Summary
3
Cn: Case Narrative
4
Sr: Sample Results
5
FSS
SOUTH DURHAM L1462850-01
5
rqn
Qc: Quality Control Summary
7
Wet Chemistry by Method 9012 B
7
Fr]
Wet Chemistry by Method 9045D
8
Wet Chemistry by Method D93/1010A
9
FQ Cl
Mercury by Method 7470A
10
q
Metals (ICP) by Method 6010D
11
Volatile Organic Compounds (GC/MS) by Method 8260D
12
rAl
Chlorinated Acid Herbicides (GC) by Method 8151A
14
Pesticides (GC) by Method 8081B
15
FSC
Semi Volatile Organic Compounds (GC/MS) by Method 8270E
16
GI: Glossary of Terms
18
Al: Accreditations & Locations
19
Sc: Sample Chain of Custody
20
ACCOUNT: PROJECT: SDG:
DATE/TIME:
PAGE:
EMA Resources L1462850
03/12/22 11:41
2 of 34

SAMPLE SUMMARY
SOUTH DURHAM L1462850-01 Waste
Collected by
Brent Collins
Collected date/time
02/16/2209:30
Received date/time
02/17/2209:30
Method
Batch
Dilution Preparation
Analysis
Analyst
Location
date/time
date/time
Preparation by Method 1311
WG1821607
1 02/22/2211:34
02/22/2211:34
JWS
Mt. Juliet, TN
Preparation by Method 1311
WG1822926
1 02/24/2210:16
02/24/2210:16
JWS
Mt. Juliet, TN
Wet Chemistry by Method 9012 B
WG1821197
1 02/21/22 21:38
02/22/2213:30
LDT
Mt. Juliet, TN
Wet Chemistry by Method 9045D
WG1819608
1 02/19/22 09:00
02/19/2213:00
GI
Mt. Juliet, TN
Wet Chemistry by Method D93/1010A
WG1822168
1 02/23/22 01:00
02/23/22 01:00
WOS
Mt. Juliet, TN
Mercury by Method 7470A
WG1823213
1 02/24/2212:32
02/25/2212:41
ABL
Mt. Juliet, TN
Metals (ICP) by Method 6010D
WG1823233
1 02/24/2213:28
02/24/22 21:22
CCE
Mt. Juliet, TN
Volatile Organic Compounds (GC/MS) by Method 8260D
WG1824477
1 02/27/2217:21
02/27/2217:21
BMB
Mt. Juliet, TN
Chlorinated Acid Herbicides (GC) by Method 8151A
WG1825661
1 03/02/22 08:02
03/02/2218:27
CCW
Mt. Juliet, TN
Pesticides (GC) by Method 8081B
WG1821893
1 02/25/22 06:54
02/27/22 03:18
AMM
Mt. Juliet, TN
Semi Volatile Organic Compounds (GC/MS) by Method 8270E
WG1828339
1 03/09/22 23:30
03/10/2218:40
JNJ
Mt. Juliet, TN
Semi Volatile Organic Compounds (GC/MS) by Method 8270E
WG1828339
1 03/09/22 23:30
03/11/2213:23
LEA
Mt. Juliet, TN
Subcontracted Analyses
WG1822578
1 02/25/22 00:00
02/25/22 00:00
ANF
Subcontract
FP1
FTC
M
rqn
Fr]
PC]
I q,
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1462850 03/12/22 11:41 3 of 34

CASE NARRATIVE
All sample aliquots were received at the correct temperature, in the proper containers, with the FP1
appropriate preservatives, and within method specified holding times, unless qualified or notated within
the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples FTChave been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative, a non-conformance form
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my FSS
knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory, and no information or data have been
knowingly withheld that would affect the quality of the data.
Fr]
FQc
• GI
Cassandra Foster rAl
Project Manager
LE
Project Narrative
All Reactive Cyanide results reported in the attached report were determined as totals using method 9012 B.
L1462850 -01 contains subout data that is included after the chain of custody.
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1462850 03/12/22 11:41 4 of 34

■
SAMPLE RESULTS - 01
L1462850
SOUTH DURHAM
Collected date/time: 02/16/22 09:30
Preparation by Method 1311
Result Qualifier
Prep
Batch
Analyte
date / time
TCLP Extraction
2/22/202211:34:34 AM
WG1821607
TCLP ZHE Extraction -
2/24/202210:16:52 AM
WG1822926
Fluid 1
2/22/202211:34:34 AM
WG1821607
Initial pH 8.27
2/22/2022 11:34:34 AM
WG1821607
Final pH 5.28
2/22/202211:34:34 AM
WG1821607
Wet Chemistry by Method 9012 B
Result Qualifier RDL Dilution Analysis
Analyte mg/kg mg/kg date / time
Reactive Cyanide 0.424 J3 J6 0.250 1 02/22/202213:30
Wet Chemistry by Method 9045D
Result Qualifier Dilution Analysis
Analyte su date / time
Corrosivity by pH 7.97 T8 1 02/19/202213:00 WG1819608
Sample Narrative:
L1462850-01 WG1819608:7.97 at19.4C
Wet Chemistry by Method D93/1010A
Batch
Batch
WG1821197
FP1
FTC]
FS-S
rqn
FC]
I ql
rAl
FSC
Result
Qualifier
Dilution
Analysis
Batch
Analyte Deg. F
date / time
Ignitability DNI at 170
1
02/23/2022 01:00
WG1822168
Mercury by Method 7470A
Result
Qualifier
RDL
Limit
Dilution Analysis
Batch
Analyte mg/I
mg/I
mg/I
date/time
Mercury ND
0.0100
0.20
1 02/25/202212:41
WG1823213
Metals (ICP) by Method 6010D
Result
Qualifier
RDL
Limit
Dilution Analysis
Batch
Analyte mg/I
mg/I
mg/I
date/time
Arsenic ND
0.100
5
1 02/24/2022 21:22
WG1823233
Barium ND
0.100
100
1 02/24/2022 21:22
WG1823233
Cadmium ND
0.100
1
1 02/24/2022 21:22
WG1823233
Chromium ND
0.100
5
1 02/24/2022 21:22
WG1823233
Lead ND
0.100
5
1 02/24/2022 21:22
WG1823233
Selenium ND
0.100
1
1 02/24/2022 21:22
WG1823233
Silver ND
0.100
5
1 02/24/2022 21:22
WG1823233
Volatile Organic Compounds (GC/MS) by Method
8260D
Result
Qualifier
RDL
Limit
Dilution Analysis
Batch
Analyte mg/I
mg/I
mg/I
date/time
Benzene ND
0.0500
0.50
1 02/27/202217:21
WG1824477
Carbon tetrachloride ND
0.0500
0.50
1 02/27/202217:21
WG1824477
Chlorobenzene ND
0.0500
100
1 02/27/202217:21
WG1824477
Chloroform ND
0.250
6
1 02/27/202217:21
WG1824477
1,2-Dichloroethane ND
0.0500
0.50
1 02/27/202217:21
WG1824477
1,1-Dichloroethene ND
0.0500
0.70
1 02/27/202217:21
WG1824477
2-Butanone (MEK) ND
0.500
200
1 02/27/202217:21
WG1824477
Tetrachloroethene ND
0.0500
0.70
1 02/27/202217:21
WG1824477
Trichloroethene ND
0.0500
0.50
1 02/27/202217:21
WG1824477
Vinyl chloride ND
0.0500
0.20
1 02/27/202217:21
WG1824477
ACCOUNT:
PROJECT:
SDG:
DATE/TIME: PAGE:
EMA Resources
L1462850
03/12/22 11:41 5 of 34

SOUTH DURHAM
SAMPLE RESULTS
- 01
Collected date/time: 02/16/22 09:30
L1462850
Volatile Organic Compounds (GC/MS) by Method 8260D
Result
Qualifier RDL
Limit
Dilution
Analysis
Batch
FP1
Analyte
mg/I
mg/I
mg/I
date/time
(S)Toluene-d8
112
80.0-120
021271202217.21
WG1824477
FTc
(S) 4-Bromof/uorobenzene
88.9
77.0-126
021271202217.21
WG1824477
(S)1,2-Dich/oroethane-d4
92.3
70.0-130
021271202217.21
WG1824477
FSS
Chlorinated Acid Herbicides (GC) by
Method 8151A
4
Result
Qualifier RDL
Limit
Dilution
Analysis
Batch
Cn
Analyte
mg/I
mg/I
mg/I
date/time
2,4,5-TP (Silvex)
ND
0.00200
1
1
03/02/202218:27
WG1825661
2,4-D
ND
0.00200
10
1
03/02/202218:27
WG1825661
(S)2,4-Dichloropheny/Acetic Acid
74.6
14.0-158
031021202218:27
WG1825661
FC]
Pesticides (GC) by Method 8081B
Result
Qualifier RDL
Limit
Dilution
Analysis
Batch
q
Analyte
mg/I
mg/I
mg/I
date / time
Chlordane
ND
0.00500
0.03
1
02/27/2022 03:18
WG1821893
FAI
Endrin
ND
0.00500
0.02
1
02/27/2022 03:18
WG1821893
Heptachlor
ND
0.00500
0.0080
1
02/27/2022 03:18
WG1821893
Heptachlor epoxide
ND
0.00500
0.0080
1
02/27/2022 03:18
WG1821893
[Sc
Lindane
ND
0.00500
0.40
1
02/27/2022 03:18
WG1821893
Methoxychlor
ND
0.00500
10
1
02/27/2022 03:18
WG1821893
Toxaphene
ND
0.0100
0.50
1
02/27/2022 03:18
WG1821893
(S) Decachlorobipheny/
31.9
10.0-128
0212712022 03:18
WG1821893
(S) Tetrach/oro-m-xylene
42.3
10.0-127
0212712022 0318
WG1821893
Semi Volatile Organic Compounds
(GC/MS) by Method 8270E
Result
Qualifier RDL
Limit
Dilution
Analysis
Batch
Analyte
mg/I
mg/I
mg/I
date/time
1,4-Dichlorobenzene
ND
0.100
7.50
1
03/10/202218:40
WG1828339
2,4-Dinitrotoluene
ND
0.100
0.13
1
03/10/202218:40
WG1828339
Hexachlorobenzene
ND
0.100
0.13
1
03/10/202218:40
WG1828339
Hexachloro-1,3-butadiene
ND
0.100
0.50
1
03/10/202218:40
WG1828339
Hexachloroethane
ND
0.100
3
1
03/10/202218:40
WG1828339
Nitrobenzene
ND
0.100
2
1
03/10/202218:40
WG1828339
Pyridine
ND
0.100
5
1
03/11/202213:23
WG1828339
3&4-Methyl Phenol
ND
0.100
400
1
03/10/202218:40
WG1828339
2-Methylphenol
ND
0.100
200
1
03/10/202218:40
WG1828339
Pentachlorophenol
ND
0.100
100
1
03/10/202218:40
WG1828339
2,4,5-Trichlorophenol
ND
0.100
400
1
03/10/202218:40
WG1828339
2,4,6-Trichlorophenol
ND
0.100
2
1
03/10/202218:40
WG1828339
(S) 2-Fluorophenol
39.1
10.0-120
03110120221840
WG1828339
(S) 2-F/uorophenol
37.7
10.0-120
031111202213:23
WG1828339
(S) Phenol-d5
25.1
10.0-120
031101202218:40
WG1828339
(S) Phenol-d5
22.6
10.0-120
031111202213:23
WG1828339
(S) Nitrobenzene-d5
64.6
10.0-127
03/11/202213:23
WG1828339
(S) Nitrobenzene-d5
67.5
10.0-127
03/10/202218.40
WG1828339
(S) 2-Fluorobiphenyl
59.3
10.0-130
031101202218:40
WG1828339
(S) 2-Fluorobiphenyl
59.6
10.0-130
031111202213:23
WG1828339
(S)2,4,6-Tribromopheno/
82.0
10.0-155
03/11/202213:23
WG1828339
(S)2,4,6-Tribromopheno/
78.5
10.0-155
03/10/202218.40
WG1828339
(S) p-Terphenyl-d14
78.1
10.0-128
03/11/202213:23
WG1828339
(S) p-Terphenyl-d14
80.2
10.0-128
03/10/202218.40
WG1828339
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
PAGE:
EMA Resources
L1462850
03/12/22 11:41
6 of 34

WG1821197
Wet Chemistry by Method 9012 B
Method Blank (MB)
(MB) R3762532-1 02/22/22 13:22
MB Result
Analyte mg/kg
Reactive Cyanide U
MB Qualifier MB MDL MB RDL
mg/kg mg/kg
0.0390 0.250
L1462850-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1462850-01 02/22/22 13:30 • (DUP) R3762532-3 02/22/22 13:31
Original Result DUP Result Dilution DUP RPD
Analyte mg/kg mg/kg %
Reactive Cyanide 0.424 0.437 1 3.02
L1462872-01 Original Sample (OS) • Duplicate (DUP)
QUALITY CONTROL SUMMARY
L1462850-01
DUP Qualifier DUP RPD
Limits
20
(OS) L1462872-01 02/22/22 13:36 • (DUP) R3762532-6 02/22/22 13:37
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte mg/kg mg/kg % %
Reactive Cyanide 0.638 0.583 1 8.98 20
Laboratory Control Sample (LCS)
(LCS) R3762532-2 02/22/22 13:23
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte mg/kg mg/kg % %
Reactive Cyanide 2.50 2.52 101 85.0-115
L1462850-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1462850-01 02/22/22 13:30 • (MS) R3762532-4 02/22/22 13:34 • (MSD) R3762532-5 02/22/22 13:35
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD
Analyte mg/kg mg/kg mg/kg mg/kg % % % %
Reactive Cyanide 1.67 0.424 0.595 0.438 10.2 0.855 1 75.0-125 J3 J6 30.3
L1462970-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1462970-01 02/22/22 13:38 • (MS) R3762532-7 02/22/22 13:39 • (MSD) R3762532-8 02/22/22 13:40
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec.
Analyte mg/kg mg/kg mg/kg mg/kg % %
Reactive Cyanide 1.67 ND 1.00 1.11 60.0 66.8
ACCOUNT: PROJECT:
EMA Resources
RPD Limits
20
Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
1 75.0-125 J6 J6 10.7 20
SDG: DATE/TIME: PAGE:
L1462850 03/12/22 11:41 7 of 34
— I
Cp
FTc
FSS
rqn
FSr
_ �GI
FAI
FSC

WG1819608 QUALITY CONTROL SUMMARY
Wet Chemistry by Method 9045D L1462850-01
L1462467-02 Original Sample (OS) • Duplicate (DUP)
(OS) L1462467-02 02/19/22 13:00 • (DUP) R3761702-2 02/19/22 13:00
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte su su % %
Corrosivity by pH 7.63 7.63 1 0.000 1
Sample Narrative:
OS: 7.63 at 19C
DUP: 7.63 at 19C
Laboratory Control Sample (LCS)
(LCS) R3761702-1 02/19/22 13:00
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte su su % %
Corrosivity by pH 10.0 9.95 99.5 99.0-101
Sample Narrative:
LCS: 9.95 at 18.6C
FP1
FTc
FSS
LEI
FSr
�GI
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1462850 03/12/22 11:41 8 of 34

WG1822168 QUALITY CONTROL SUMMARY
Wet Chemistry by Method D93/1010A L1462850-01
L146355O-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1463550-01 02/23/22 01:00 • (DUP) R3763170-3 02/23/22 01:00
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte Deg. F Deg. F % %
Ignitability 155 160 1 3.18 10
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3763170-1 02/23/22 01:00 • (LCSD) R3763170-2 02/23/22 01:00
Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte Deg. F Deg. F Deg. F % % % % %
Ignitability 126 122 126 96.6 99.7 95.6-104 3.23 10
— I
Cp
FTc
FSS
rqn
FSr
�GI
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1462850 03/12/22 11:41 9 of 34

WG1823213
Mercury by Method 7470A
Method Blank (MB)
(MB) R3763883-1 02/25/22 12:26
MB Result
Analyte mg/1
Mercury U
MB Qualifier MB MDL MB RDL
mg/I mg/1
0.00330 0.0100
Laboratory Control Sample (LCS)
(LCS) R3763883-2 02/25/22 12:27
Spike Amount LCS Result LCS Rec.
Analyte mg/1 mg/1 %
Mercury 0.0300 0.0330 110
QUALITY CONTROL SUMMARY
L1462850-01
Rec. Limits LCS Qualifier
80.0-120
L1462462-06 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1462462-06 02/25/22 12:29 • (MS) R3763883-3 02/25/22 12:35 • (MSD) R3763883-4 02/25/22 12:37
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD
Analyte mg/1 mg/1 mg/I mg/1 % % % %
Mercury 0.0300 ND 0.0328 0.0322 109 107 1 75.0-125 1.82
RPD Limits
20
— I
Cp
FTc
FSS
rqn
FSr
�GI
_ $AI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1462850 03/12/22 11:41 10 of 34

WG1823233
Metals (ICP) by Method 6010D
Method Blank (MB)
(MB) R3763667-1 02/24/22 20:59
MB Result
MB Qualifier MB MDL
Analyte mg/I
mg/I
Arsenic U
0.0333
Barium U
0.0333
Cadmium U
0.0333
Chromium U
0.0333
Lead U
0.0333
Selenium U
0.0333
Silver U
0.0333
Laboratory Control Sample (LCS)
(LCS) R3763667-2 02/24/22 21:02
Spike Amount
LCS Result
LCS Rec.
Analyte mg/I
mg/I
%
Arsenic 10.0
9.70
97.0
Barium 10.0
9.90
99.0
Cadmium 10.0
9.81
98.1
Chromium 10.0
9.57
95.7
Lead 10.0
9.75
97.5
Selenium 10.0
10.2
102
Silver 2.00
1.76
88.2
QUALITY CONTROL SUMMARY
L1462850-01
MB RDL
mg/I
0.100
0.100
0.100
0.100
0.100
0.100
0.100
Rec. Limits LCS Qualifier
°/
80.0-120
80.0-120
80.0-120
80.0-120
80.0-120
80.0-120
L1462431-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1462431-01 02/24/22 21:05 • (MS) R3763667-4 02/24/22 21:10 • (MSD) R3763667-5 02/24/22 21:13
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
mg/I
mg/I
mg/I
mg/I
%
%
Arsenic
10.0
ND
9.65
9.74
96.5
97.4
Barium
10.0
0.210
10.1
10.1
98.6
99.0
Cadmium
10.0
ND
9.77
9.82
97.7
98.2
Chromium
10.0
ND
9.58
9.57
95.8
95.7
Lead
10.0
ND
9.82
9.78
98.2
97.8
Selenium
10.0
ND
10.1
10.1
101
101
Silver
2.00
ND
1.76
1.78
87.8
88.8
Dilution Rec. Limits
1 75.0-125
1 75.0-125
1 75.0-125
1 75.0-125
1 75.0-125
1 75.0-125
1 75.0-125
MS Qualifier MSD Qualifier RPD RPD Limits
0.908 20
0.399 20
0.458 20
0.155 20
0.341 20
0.503 20
1.16 20
FP1
FTc
FSS
rqn
FSr
�GI
FAI
FSC
ACCOUNT: PROJECT: SDG:
EMA Resources L1462850
DATE/TIME:
03/12/22 11:41
PAGE:
11 of 34

WG1824477 QUALITY CONTROL SUMMARY
Volatile Organic Compounds (GC/MS) by Method 8260D L1462850-01
Method Blank (MB)
(MB) R3764355-3 02/27/22 13:43
MB Result
MB Qualifier
MB MDL
MB RDL
Analyte
mg/I
mg/I
mg/I
Benzene
U
0.0167
0.0500
Carbon tetrachloride
U
0.0167
0.0500
Chlorobenzene
U
0.0167
0.0500
Chloroform
U
0.0833
0.250
1,2-Dichloroethane
U
0.0167
0.0500
1,1-Dichloroethene
U
0.0167
0.0500
2-Butanone (MEK)
U
0.167
0.500
Tetrachloroethene
U
0.0167
0.0500
Trichloroethene
U
0.0167
0.0500
Vinyl chloride
U
0.0167
0.0500
(S) Toluene-d8
115
80.0-120
(S) 4-Bromof/uorobenzene
91.4
77.0-126
(S)1,2-Dichloroethane-d4
90.5
70.0-130
Laboratory Control
Sample (LCS) • Laboratory
Control Sample
Duplicate (LCSD)
(LCS) R3764355-1 02/27/22 10:38 • (LCSD) R3764355-2 02/27/22 12:39
Spike Amount
LCS Result
LCSD Result
LCS Rec.
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier RPD
RPD Limits
Analyte
mg/I
mg/I
mg/I
%
%
%
%
%
Benzene
0.250
0.251
0.275
100
110
70.0-123
9.13
20
Carbon tetrachloride
0.250
0.229
0.222
91.6
88.8
68.0-126
3.10
20
Chlorobenzene
0.250
0.260
0.294
104
118
80.0-121
12.3
20
Chloroform
0.250
0.253
0.274
101
110
73.0-120
7.97
20
1,2-Dichloroethane
0.250
0.248
0.274
99.2
110
70.0-128
9.96
20
1,1-Dichloroethene
0.250
0.249
0.258
99.6
103
71.0-124
3.55
20
2-Butanone (MEK)
1.25
1.09
1.21
87.2
96.8
44.0-160
10.4
20
Tetrachloroethene
0.250
0.265
0.266
106
106
72.0-132
0.377
20
Trichloroethene
0.250
0.245
0.261
98.0
104
78.0-124
6.32
20
Vinyl chloride
0.250
0.289
0.291
116
116
67.0-131
0.690
20
(S) Toluene-d8
112
113
80.0-120
(S) 4-Bromofluorobenzene
91.1
90.5
77.0-126
(S) 1,2-Dichloroethane-d4
94.0
94.0
70.0-130
FP1
FTc
FSS
rqn
FSr
�GI
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1462850 03/12/22 11:41 12 of 34

WG1824477 QUALITY CONTROL SUMMARY
Volatile Organic Compounds (GC/MS) by Method 8260D L1462850-01
L1464040-04 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1464040-04 02/27/22 20:50 • (MS) R3764355-4 02/27/22 21:11 • (MSD) R3764355-5 02/27/22 21:32
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
mg/I
mg/I
mg/I
mg/I
%
%
Benzene
0.250
ND
0.166
0.168
66.4
67.2
Carbon tetrachloride
0.250
ND
0.160
0.168
64.0
67.2
Chlorobenzene
0.250
ND
0.219
0.219
87.6
87.6
Chloroform
0.250
ND
ND
ND
83.6
84.4
1,2-Dichloroethane
0.250
ND
0.201
0.196
80.4
78.4
1,1-Dichloroethene
0.250
ND
0.119
0.118
47.6
47.2
2-Butanone (MEK)
1.25
ND
1.05
1.12
84.0
89.6
Tetrachloroethene
0.250
3.96
3.77
3.56
0.000
0.000
Trichloroethene
0.250
ND
0.170
0.173
68.0
69.2
Vinyl chloride
0.250
ND
0.130
0.126
52.0
50.4
(S Toluene-d8
110
110
(S) 4-Bromof/uorobenzene
97.6
95.1
(S 1,2-Dichloroethane-d4
94.6
94.0
L1462927-03 Original Sample (OS) • Matrix Spike (MS)
(OS) L1462927-03 02/27/22 18:45 • (MS) R3764355-6 02/27/22 21:52
Spike Amount
Original Result
MS Result
MS Rec.
Analyte
mg/I
mg/I
mg/I
%
Benzene
0.250
ND
0.169
67.6
Carbon tetrachloride
0.250
ND
0.165
66.0
Chlorobenzene
0.250
ND
0.218
87.2
Chloroform
0.250
ND
ND
84.0
1,2-Dichloroethane
0.250
ND
0.199
79.6
1,1-Dichloroethene
0.250
ND
0.119
47.6
2-Butanone (MEK)
1.25
ND
1.05
84.0
Tetrachloroethene
0.250
ND
0.202
80.8
Trichloroethene
0.250
ND
0.184
73.6
Vinyl chloride
0.250
ND
0.131
52.4
(S) Toluene-d8
119
(S) 4-Bromofluorobenzene
97.6
(S)1,2-Dichloroethane-d4
93.9
Dilution Rec. Limits MS Qualifier MSD Qualifier
q
1 17.0-158
1 23.0-159
1 33.0-152
1 29.0-154
1 29.0-151
1 11.0-160
1 10.0-160
1 10.0-160
1 10.0-160
1 10.0-160
80.0-120
77.0-126
70.0-130
Dilution Rec. Limits MS Qualifier
1 17.0-158
1 23.0-159
1 33.0-152
1 29.0-154
1 29.0-151
1 11.0-160
1 10.0-160
1 10.0-160
1 10.0-160
1 10.0-160
80.0-120
77.0-126
70.0-130
RPD
RPD Limits
1.20
27
4.88
28
0.000
27
0.952
28
2.52
27
0.844
29
6.45
32
5.73
27
1.75
25
3.12
27
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EMA Resources L1462850 03/12/22 11:41 13 of 34

WG1825661
Chlorinated Acid Herbicides (GC) by Method 8151A
Method Blank (MB)
(MB) R3765874-1 03/02/22 16:58
MB Result
Analyte mg/I
2,4,5-TP (Silvex) U
2,4-D U
(S)2,4-Dichloropheny/Acetic 70.0
Acid
MB Qualifier MB MDL
mg/I
0.000667
0.000667
Laboratory Control Sample (LCS)
QUALITY CONTROL SUMMARY
L1462850-01
MB RDL
Mg/1
0.00200
0.00200
14.0-158
(LCS) R3765874-2 03/02/22 17:13
Spike Amount
LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
Analyte mg/1
mg/1
%
%
2,4,5-TP (Silvex) 0.0500
0.0417
83.4
50.0-125
2,4-D 0.0500
0.0451
90.2
50.0-120
(S) 2,4-Dich/oropheny/Acetic
74.0
14.0-158
Acid
L1463588-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1463588-01 03/02/22 20:24 • (MS) R3765874-3 03/02/22 20:38 • (MSD) R3765874-4 03/02/22 20:53
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
mg/I
mg/1
mg/I
mg/I
%
%
2,4,5-TP (Silvex)
0.0500
ND
0.0416
0.0359
83.2
71.8
2,4-D
0.0500
ND
0.0401
0.0407
80.2
81.4
(S)2,4-Dichloropheny/Acetic
74.4
74.2
Acid
Dilution Rec. Limits MS Qualifier MSD Qualifier RPD
1 50.0-125 14.7
1 50.0-120 1.49
14.0-158
RPD Limits
o�
20
20
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EMA Resources L1462850 03/12/22 11:41 14 of 34

WG1821893 QUALITY CONTROL SUMMARY
Pesticides (GC) by Method 8081B L1462850-01
Method Blank (MB)
(MB) R3764484-1 02/27/22 00:26
MB Result
MB Qualifier
MB MDL
MB RDL
Analyte mg/1
mg/I
mg/1
Chlordane U
0.00167
0.00500
Endrin U
0.00167
0.00500
Heptachlor U
0.00167
0.00500
Heptachlor epoxide U
0.00167
0.00500
Gamma BHC U
0.00167
0.00500
Methoxychlor U
0.00167
0.00500
Toxaphene U
0.00333
0.0100
(S) Decachlorobipheny/ 69.9
10.0-128
(S) Tetrach/oro-m-xylene 84.7
10.0-127
Laboratory Control Sample (LCS)
(LCS) R3764484-2 02/27/22 00:36
Spike Amount
LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
Analyte mg/1
mg/1
%
%
Endrin 0.0100
0.00897
89.7
57.0-134
Heptachlor 0.0100
0.00973
97.3
27.0-132
Heptachlor epoxide 0.0100
0.00875
87.5
57.0-130
Gamma BHC 0.0100
0.00928
92.8
55.0-129
Methoxychlor 0.0100
0.00852
85.2
54.0-155
(S) Decachlorobipheny/
58.7
10.0-128
(S) Tetrach/oro-m-xylene
78.5
10.0-127
L1460315-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1460315-01 02/27/22 00:45 • (MS) R3764484-3 02/27/22 00:55 • (MSD) R3764484-4 02/27/22 01:04
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
mg/1
mg/1
mg/I
mg/1
%
%
Endrin
0.0100
ND
0.00811
0.00829
81.1
82.9
Heptachlor
0.0100
ND
0.00842
0.00834
84.2
83.4
Heptachlor epoxide
0.0100
ND
0.00769
0.00724
76.9
72.4
Gamma BHC
0.0100
ND
0.00902
0.00838
90.2
83.8
Methoxychlor
0.0100
ND
0.00839
0.00752
83.9
75.2
(S) Decachlorobipheny/
52.0
48.5
(S) Tetrach/oro-m-xylene
66.6
68.2
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
1 10.0-160
2.20
1 16.0-136
0.955
1 10.0-160
6.03
1 14.0-141
7.36
1 10.0-160
P 10.9
10.0-128
10.0-127
RPD Limits
39
40
36
40
34
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EMA Resources L1462850 03/12/22 11:41 15 of 34

WG1828339
QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds
(GC/MS) by
Method 8270E
L1462850-01
Method Blank (MB)
(MB) R3768508-2 03/10/22 13:37
MB Result
MB Qualifier
MB MDL
MB RDL
Analyte mg/I
mg/I
mg/I
1,4-Dichlorobenzene U
0.0333
0.100
2,4-Dinitrotoluene U
0.0333
0.100
Hexachlorobenzene U
0.0333
0.100
Hexachloro-1,3-butadiene U
0.0333
0.100
Hexachloroethane U
0.0333
0.100
Nitrobenzene U
0.0333
0.100
Pyridine U
0.0333
0.100
3&4-Methyl Phenol U
0.0333
0.100
2-Methylphenol U
0.0333
0.100
Pentachlorophenol U
0.0333
0.100
2,4,5-Trichlorophenol U
0.0333
0.100
2,4,6-Trichlorophenol U
0.0333
0.100
(S) 2-Fluorophenol 41.4
10.0-120
(S) Phenol-d5 25.6
10.0-120
(S) Nitrobenzene-d5 68.7
10.0-127
(S) 2-F/uorobipheny/ 70.6
10.0-130
(S) 2,4,6-Tribromophenol 870
10.0-155
(S) p-Terphenyl-d14 94.3
10.0-128
Laboratory Control Sample (LCS)
(LCS) R3768508-1 03/10/22 13:16
Spike Amount
LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
Analyte mg/I
mg/I
%
%
1,4-Dichlorobenzene 0.500
0.357
71.4
18.0-120
2,4-Dinitrotoluene 0.500
0.513
103
49.0-124
Hexachlorobenzene 0.500
0.436
87.2
44.0-120
Hexachloro-1,3-butadiene 0.500
0.375
75.0
19.0-120
Hexachloroethane 0.500
0.365
73.0
15.0-120
Nitrobenzene 0.500
0.349
69.8
27.0-120
Pyridine 0.500
0.136
27.2
10.0-120
3&4-Methyl Phenol 0.500
0.333
66.6
31.0-120
2-Methylphenol 0.500
0.336
67.2
28.0-120
Pentachlorophenol 0.500
0.408
81.6
23.0-120
2,4,5-Trichlorophenol 0.500
0.438
87.6
44.0-120
2,4,6-Trichlorophenol 0.500
0.415
83.0
42.0-120
(S) 2-F/uorophenol
47.2
10.0-120
(S) Phenol-d5
29.7
10.0-120
(S) Nitrobenzene-d5
69.2
10.0-127
ACCOUNT:
PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources
L1462850 03/12/22 11:41 16 of 34
FP1
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WG1828339 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 8270E L1462850-01
Laboratory Control Sample (LCS)
(LCS) R3768508-1 03/10/22 13:16
Spike Amount LCS Result
Analyte mg/I mg/I
(S) 2-F/uorobiphenyl
(S) 2,4,6-Tribromophenol
(S) p-Terphenyl-d14
LCS Rec.
75.6
91.5
91.4
Rec. Limits LCS Qualifier
10.0-130
10.0-155
10.0-128
L1462850-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1462850-01 03/10/22 18:40 • (MS) R3768508-3 03/10/22 19:02 • (MSD) R3768508-4 03/10/22 19:23
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
mg/I
mg/I
mg/I
mg/I
%
%
1,4-Dichlorobenzene
0.500
ND
0.352
0.380
70.4
76.0
2,4-Dinitrotoluene
0.500
ND
0.500
0.528
100
106
Hexachlorobenzene
0.500
ND
0.415
0.445
83.0
89.0
Hexachloro-1,3-butadiene
0.500
ND
0.374
0.403
74.8
80.6
Hexachloroethane
0.500
ND
0.356
0.381
71.2
76.2
Nitrobenzene
0.500
ND
0.332
0.356
66.4
71.2
Pyridine
0.500
ND
ND
ND
7.36
16.1
3&4-Methyl Phenol
0.500
ND
0.291
0.331
58.2
66.2
2-Methylphenol
0.500
ND
0.284
0.320
56.8
64.0
Pentachlorophenol
0.500
ND
0.291
0.338
58.2
67.6
2,4,5-Trichlorophenol
0.500
ND
0.409
0.441
81.8
88.2
2,4,6-Trichlorophenol
0.500
ND
0.399
0.427
79.8
85.4
(S) 2-F/uorophenol
40.1
43.6
(S) Phenol-d5
26.1
28.5
(S) Nitrobenzene-d5
66.7
69.0
(S) 2-F/uorobipheny/
70.0
70.9
(S)2,4,6-Tribromophenol
84.5
9t0
(S) p-Terphenyl-d14
92.8
94.3
Dilution Rec. Limits
17.0-120
39.0-125
35.0-122
12.0-120
10.0-120
12.0-120
10.0-120
10.0-120
10.0-120
10.0-128
33.0-120
26.0-120
10.0-120
10.0-120
10.0-127
10.0-130
10.0-155
10.0-128
MS Qualifier MSD Qualifier RPD
7.65
5.45
6.98
7.46
6.78
6.98
J6 J3 74.3
12.9
11.9
14.9
7.53
6.78
RPD Limits
40
25
24
34
40
30
37
36
30
37
31
31
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EMA Resources
SDG:
L1462850
DATE/TIME:
03/12/22 11:41
PAGE:
17 of 34

GLOSSARY OF TERMS
Guide to Reading and Understanding Your Laboratory Report
The information below is
designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not
u
intended as a comprehensive explanation, and if you have additional questions please contact your project representative.
Results Disclaimer - Information
that may be provided by the customer, and contained within this report, include Permit Limits, Project Name,
FTC
Sample ID, Sample Matrix,
Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On -Site Data, Sampling Collection Dates/Times, and
Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received.
Abbreviations and Definitions
FSS
MDL
Method Detection Limit.
ND
Not detected at the Reporting Limit (or MDL where applicable).
rqn
RDL
Reported Detection Limit.
Rec.
Recovery.
Fr]
RPD
Relative Percent Difference.
SDG
Sample Delivery Group.
Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and
e
QC
(S)
Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be
detected in all environmental media.
U
Not detected at the Reporting Limit (or MDL where applicable).
Analyte
The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes
reported.
If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the
a
Dilution
standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the
laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the
result reported has already been corrected for this factor.
FSC
These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal
Limits
for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or
duplicated within these ranges.
Original Sample
The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control
sample. The Original Sample may not be included within the reported SDG.
This column provides a letter and/or number designation that corresponds to additional information concerning the result
Qualifier
reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and
potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable.
The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was
no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL"
Result
(Below Detectable Levels). The information in the results column should always be accompanied by either an MDL
(Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect
or report for this analyte.
Uncertainty
(Radiochemistry)
Confidence level of 2 sigma.
A brief discussion about the included sample results, including a discussion of any non -conformances to protocol
Case Narrative (Cn)
observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.
Quality Control
This section of the report includes the results of the laboratory quality control analyses required by procedure or
Summary (Qc)
analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not
being performed on your samples typically, but on laboratory generated material.
This is the document created in the field when your samples were initially collected. This is used to verify the time and
Sample Chain of
date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This
Custody (Sc)
chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the
samples from the time of collection until delivery to the laboratory for analysis.
This section of your report will provide the results of all testing performed on your samples. These results are provided
Sample Results (Sr)
by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for
each sample will provide the name and method number for the analysis reported.
Sample Summary (Ss)
This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and
times of preparation and/or analysis.
Qualifier
Description
J3
The associated batch QC was outside the established quality control range for precision.
J6
The sample matrix interfered with the ability to make any accurate determination; spike value is low.
P
RPD between the primary and confirmatory analysis exceeded 40%.
T8
Sample(s) received past/too close to holding time expiration.
v
The sample concentration is too high to evaluate accurate spike recoveries.
ACCOUNT:
PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources
L1462850 03/12/22 11:41 18 of 34

ACCREDITATIONS & LOCATIONS
Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122
Alabama
40660
Nebraska
NE-OS-15-05
Alaska
17-026
Nevada
TN000032021-1
Arizona
AZ0612
New Hampshire
2975
Arkansas
88-0469
New Jersey—NELAP
TN002
California
2932
New Mexico
TN00003
Colorado
TN00003
New York
11742
Connecticut
PH-0197
North Carolina
Env375
Florida
E87487
North Carolina'
DW21704
Georgia
NELAP
North Carolinas
41
Georgia'
923
North Dakota
R-140
Idaho
TN00003
Ohio—VAP
CL0069
Illinois
200008
Oklahoma
9915
Indiana
C-TN-01
Oregon
TN200002
Iowa
364
Pennsylvania
68-02979
Kansas
E-10277
Rhodelsland
LA000356
Kentucky16
KY90010
South Carolina
84004002
Kentucky 2
16
South Dakota
n/a
Louisiana
A130792
Tennessee' °
2006
Louisiana
LA018
Texas
T104704245-20-18
Maine
TN00003
Texas'
LAB0152
Maryland
324
Utah
TN000032021-11
Massachusetts
M-TN003
Vermont
VT2006
Michigan
9958
Virginia
110033
Minnesota
047-999-395
Washington
C847
Mississippi
TN00003
West Virginia
233
Missouri
340
Wisconsin
998093910
Montana
CERT0086
Wyoming
A21-A
A21-A — ISO 17025
1461.01
AIHA-LAP,LLC EMLAP
100789
A21-A — ISO 17025 s
1461.02
DOD
1461.01
Canada
1461.01
USDA
P330-15-00234
EPA—Crypto
TN00003
Drinking Water 2 Underground Storage Tanks 'Aquatic Toxicity ° Chemical/Microbiological 'Mold 6 Wastewater n/a Accreditation not applicable
Not all certifications held by the laboratory are applicable to the results reported in the attached report.
Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical.
FP1
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ACCOUNT: PROJECT: SDG: DATE/TIME:
EMA Resources L1462850 03/12/22 11:41
PAGE:
19 of 34

urofins
Environment Testing
America
ANALYTICAL REPORT
Eurofins Chicago
2417 Bond Street
University Park, IL 60484
Tel: [phone]
Laboratory Job ID: 500-212791-1
Client Project/Site: WG1822578
Pace Analytical National
12065 Lebanon Rd
Mt Juliet, Tennessee 37122
Attn: Jimmy Huckaba
Authorized for release by.
212512022 2:45:32 PM
Jim Knapp, Project Manager II
[phone]
[e-mail]
Designee for
Sandie Fredrick, Project Manager II
[phone]
[e-mail]
The test results in this report meet all 2003 NELAC, 2009 TNI, and 2016 TNI requirements for
accredited parameters, exceptions are noted in this report. This report may not be reproduced
except in full, and with written approval from the laboratory. For questions please contact the
Project Manager at the e-mail address or telephone number listed on this page.
This report has been electronically signed and authorized by the signatory. Electronic signature is
intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.

Client: Pace Analytical National
Project/Site: WG1822578
Table of Contents
Laboratory Job ID: 500-212791-1
CoverPage ..............................................
1
Table of Contents .........................................
2
Case Narrative ...........................................
3
Detection Summary ........................................
4
Method Summary .........................................
5
Sample Summary .........................................
6
Client Sample Results ......................................
7
Definitions ...............................................
8
QC Association ...........................................
9
QC Sample Results ........................................
10
Chronicle................................................
11
Certification Summary ......................................
12
Chain of Custody ..........................................
13
Receipt Checklists .........................................
14
Eurofins Chicago
Page 2 of 14 2/25/2022

Case Narrative
Client: Pace Analytical National
Project/Site: WG1822578
Job ID: 500-212791-1
Laboratory: Eurofins Chicago
Narrative
Job Narrative
500-212791-1
Comments
No additional comments.
Job ID: 500-212791-1
Receipt
The sample was received on 2/24/2022 10:00 AM. Unless otherwise noted below, the sample arrived in good condition, and where
required, properly preserved and on ice. The temperature of the cooler at receipt was 1.20 C.
General Chemistry
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
Eurofins Chicago
Page 3 of 14 2/25/2022

Detection Summary
Client: Pace Analytical National Job ID: 500-212791-1
Project/Site: WG1822578
Client Sample ID: SOUTH DURHAM Lab Sample ID: 500-212791-1
ENo Detections.
This Detection Summary does not include radiochemical test results.
0
Eurofins Chicago
Page 4 of 14 2/25/2022

Method Summary
Client: Pace Analytical National
Project/Site: WG1822578
Job ID: 500-212791-1
Method Method Description Protocol Laboratory
9034 Sulfide, Reactive SW846 TAL CHI
7.3.4 Sulfide, Reactive SW846 TAL CHI
Protocol References:
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
TAL CHI = Eurofins Chicago, 2417 Bond Street, University Park, IL 60484, TEL [phone]
Eurofins Chicago
Page 5 of 14 2/25/2022

Sample Summary
Client: Pace Analytical National Job ID: 500-212791-1
Project/Site: WG1822578
Lab Sample ID Client Sample ID Matrix Collected Received
500-212791-1 SOUTH DURHAM Solid 02/16/22 09:30 02/24/22 10:00
C
0
Page 6 of 14 EurofinsMV2022

Client Sample Results
Client: Pace Analytical National Job ID: 500-212791-1
Project/Site: WG1822578
Client Sample ID: SOUTH DURHAM Lab Sample ID: 500-212791-1
Date Collected: 02/16/22 09:30 Matrix: Solid
Date Received: 02/24/22 10:00
General Chemistry —
Analyte Result Qualifier LOQ LOD Unit D Prepared Analyzed Dil Fac
Sulfide, Reactive <3.9 49.5 3.9 mg/Kg 02/24/22 19:03 02/25/22 11:00 1
Eurofins Chicago
Page 7 of 14 2/25/2022

Definitions/Glossary
Client: Pace Analytical National
Project/Site: WG1822578
Glossary
Abbreviation These commonly used abbreviations may or may not be present in this report.
tt Listed under the "D" column to designate that the result is reported on a dry weight basis
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re -analysis, Re -extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level'
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRIES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
Job ID: 500-212791-1
0
Eurofins Chicago
Page 8 of 14 2/25/2022

QC Association Summary
Client: Pace Analytical National
Project/Site: WG1822578
General Chemistry
Prep Batch: 644394
Lab Sample ID
Client Sample ID
500-212791-1
SOUTH DURHAM
MB 500-644394/1-A
Method Blank
LCS 500-644394/2-A
Lab Control Sample
Analysis Batch: 644530
Lab Sample ID
Client Sample ID
500-212791-1
SOUTH DURHAM
MB 500-644394/1-A
Method Blank
LCS 500-644394/2-A
Lab Control Sample
F
Job ID: 500-212791-1
Prep Type
Matrix
Method
Prep Batch
Total/NA
Solid
7.3.4
Total/NA
Solid
7.3.4
Total/NA
Solid
7.3.4
Prep Type
Matrix
Method
Prep Batch
Total/NA
Solid
9034
644394
Total/NA
Solid
9034
644394
Total/NA
Solid
9034
644394
Eurofins Chicago
Page 9 of 14 2/25/2022

QC Sample Results
Client: Pace Analytical National
Project/Site: WG1822578
Method: 9034 - Sulfide, Reactive
Lab Sample ID: MB 500-644394/1-A
Matrix: Solid
Analysis Batch: 644530
MB MB
Analyte Result Qualifier
Sulfide, Reactive <3.9
Lab Sample ID: LCS 500-644394/2-A
Matrix: Solid
Analysis Batch: 644530
Analyte
Sulfide, Reactive
F
Job ID: 500-212791-1
Client Sample ID: Method Blank
Prep Type: Total/NA
Prep Batch: 644394 L
LOQ LOD Unit D Prepared Analyzed Dil Fac
50.0 3.9 mg/Kg 02/24/2218:46 02/25/2210:49 1
Client Sample ID: Lab Control Sample
Prep Type: Total/NA
Prep Batch: 644394
Spike LCS LCS %Rec.
Added Result Qualifier Unit D %Rec Limits F7
198 162.9 mg/Kg 82 80 -120
Is
Page 10 of 14
Eurofins Chicago
2/25/2022

Lab Chronicle
Client: Pace Analytical National
Project/Site: WG1822578
F
Job ID: 500-212791-1
Client Sample ID: SOUTH DURHAM Lab Sample ID: 500-212791-1
Date Collected: 02/16/22 09:30 Matrix: Solid
Date Received: 02/24/22 10:00
Batch
Batch
Dilution Batch
Prepared
Prep Type
Type
Method
Run Factor Number
or Analyzed Analyst Lab
Total/NA
Prep
7.3.4
644394
02/24/22 19:03 TMS TAL CHI
Total/NA
Analysis
9034
1 644530
02/25/22 11:00 TMS TAL CHI
Laboratory References:
TAL CHI =
Eurofins Chicago, 2417
Bond Street, University
Park, IL 60484, TEL [phone]
Page 11 of 14
Eurofins Chicago
2/25/2022

Accreditation/Certification Summary
Client: Pace Analytical National
Project/Site: WG1822578
Laboratory: Eurofins Chicago
All accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report.
Authority
Program
California
State
Georgia
State
Georgia (DW)
State
Hawaii
State
Illinois
NELAP
Indiana
State
Iowa
State
Kansas
NELAP
Kentucky (UST)
State
Kentucky (WW)
State
Louisiana
NELAP
Mississippi
State
North Carolina (WW/SW)
State
North Dakota
State
Oklahoma
State
South Carolina
State
USDA
US Federal Programs
Wisconsin
State
Wyoming
State
Identification Number
2903
N/A
939
Job ID: 500-212791-1
Expiration Date
04-29-22
04-29-22
04-30-21
NA
04-29-22
IL00035
04-29-22
C-I L-02
04-29-22
082
05-01-22
E-10161
10-31-22
AI#108083
04-29-22
KY90023
12-31-22
02046
06-30-22
NA
04-30-22
291
12-31-22
R-194
04-29-22
8908
08-31-22
77001003 04-29-22
P330-18-00018 02-11-24
999580010 08-31-22
8TMS-Q 04-30-22
* Accreditation/Certification renewal pending - accreditation/certification considered valid.
Page 12 of 14
Eurofins Chicago
2/25/2022

Sub -Contract Chain of Custody
Batch Date/Time: 02/23/22 13 44
2""'eAnalytical
Sub -Contract I. ab- IAUPII.
11
Address: 2417 Bond Street
/
City/State: University Park, it
60484
12065 Lebanon Rd
Contact.
500-212791 COC
Mt Juliet, TN 37122
Sandra.Fredrtckd�EurolinSet oom
Phone [phone]
Owner Lab: PACEMTJL
WO. WG1822578
Fax [phone]
Address: 12065 Lebanon Rd
Email: Midi Suboutl earn d.pacelabs com
City/State: Mt Juliet, FN 37122
Results Due Date: 03/09/22
Phone: [phone]
ESC Purchase Order #: 1 I462850
Fax: [phone]
Send Reports to: James C Huckaba
Sample ID
Container ID
Matrix State Collect Date Description
p
SOUTH DURHAM
SS NC 02/16/2. 2 09 30 Miscellaneous Analysis
p�fd 3�a 9paJ���
Relinquished by:A
Recieved by:-
4Date
Date
Relinquished by:
Date
Recieved by:
Date
Sample Number Sample Comments
Lab Use Only Lab Use Only
2 L1462950-01 Reactive Sulfide
Page 13 of 14 2/25/2022

Client: Pace Analytical National
Login Number: 212791
List Number: 1
Creator: Scott, Sherri L
Question
Login Sample Receipt Checklist
Answer Comment
Radioactivity wasn't checked or is </= background as measured by a survey
True
meter.
The cooler's custody seal, if present, is intact.
True
Sample custody seals, if present, are intact.
True
The cooler or samples do not appear to have been compromised or
True
tampered with.
Samples were received on ice.
True
Cooler Temperature is acceptable.
True
Cooler Temperature is recorded.
True
COC is present.
True
COC is filled out in ink and legible.
True
COC is filled out with all pertinent information.
True
Is the Field Sampler's name present on COC?
True
There are no discrepancies between the containers received and the COC.
True
Samples are received within Holding Time (excluding tests with immediate
True
HTs)
Sample containers have legible labels.
True
Containers are not broken or leaking.
True
Sample collection date/times are provided.
True
Appropriate sample containers are used.
True
Sample bottles are completely filled.
True
Sample Preservation Verified.
True
There is sufficient vol. for all requested analyses, incl. any requested
True
MS/MSDs
Containers requiring zero headspace have no headspace or bubble is
N/A
<6mm (1/4").
Multiphasic samples are not present.
True
Samples do not require splitting or compositing.
True
Residual Chlorine Checked.
N/A
1.2
Job Number: 500-212791-1
List Source: Eurofins Chicago
7
M
Eurofins Chicago
Page 14 of 14 2/25/2022

Company Name/Address: Billing information: dr ', i, C n;airer'PrPSP'vat've Chain of Custody Page _of_
EMA Resources Mr. Brent Collins Pres
7SS Yadkinville Road Chk aceAnalytical
755 Yadkinville Road Mocksville, NC 27028
Mocksville, NC 27028
12065 Lebanon Rd Mount lubet, TN 37122
Report to: Email To
5ubmrttny a sample na this chain of tuttody
Mr. Brent Collins [e-mail];roy.whitak constnvros.6—ledif—t and x ptanae of the
Pace Terms and Coodd,ons found at
Project Description City/State \�\\ L��a_ Please Circle htepauMro.wceab�pmih�bl5ipa„taneare
`./ • \ V- _- roans pM
Sludge Collected: �� � PT MT CT ET
Client Project # Lab Project # I SDG #
Phone: [phone]
� 1053
Collected by (print): Site/Facility ID # P.O. # a
rfn L n�/' Acctnum: EMARES
('� T v z Template:T11413
Collected b signature): Rush? (Lab MUST Be Notified) Quote # a
° u Prelogin: P895426
_ Same Day _ Five Day 1 z J
_ Next Day — 5 Day (Rad Only) Date Results Needed a- f PM: 807 - Justin Carr
Immediately _ Two Day _ 10 Day (Rad Only) No. U -
PB
✓ 1-4.
Packed on Ice N _ Y Three Day of -4_
ntrs > a snipped via: FedEX Ground
Sample10 Comp/Grab Matrix' Depth Date Time U Remarks Sample x(lab only)
- U f--
_._ SS 3' ��ol2Z- QaD 2 X X J
SDV� DJi ► 11,
' Matrix:Remarks: SampleReceirt e- t
SS Soil AIR - Air F- Filter pH Temp CDC Seal Present/Intact: P _Y _N
]CDC Signed/Accurate: L4 _N
GW- Groundwater B- Bioassay Bottles arrive intact: _/g N
WW - Waste Water ow Other
Correct bottles used: N
DW -Drinking Water Samples returned via: �j Z ^7 �� sufficient volume sent: 1l _N
OT
OT -Other Tracking # 6 ( -L -J L/ I: Applicable
_ UPS _ FedEx Courier VGA Zero Headspace: _Y _N
Relinquished b : (Signature) Date: Time: Received by. (Signature) TripBlank Received: Yes Preservation Correct; Checked: _Y _N
? y g ) RAD Screen <0.5 mR/hr: � _N
HCL .?//4,/ZZ 3a�o TBR/MeoH
Relinquished by : (Signature) Date: Time: Received by: (Signature) Tempe °C BotYes Received: If preservation required by Login: Cate/Time
4ID"=G1
Relinquished by : (Signature) Date: Time. Received for lab by: ig ure) &ate: Time: (� 2 Hold: Cond
kz�> !- '?- L— 6 J� NCF

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Durham WQ Permit Number: WQ0003504
NPDES Number: NCO047597
Monitoring Period: From l/l/2023 To 2/2/2023
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
1 Alt B (Alk Treatment) ❑
1 Alt. C (Prior Testing) ❑
A1t.D (No Prior Test) ❑
1 Process to Further Reduce Pathogengs ❑
If applicable to alternative
performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
He Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
Alt. (1) Fecal Density 21
Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative
performed (Class
B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
1 Air Drying ❑
Composting ❑
jAerobic Digestion ❑
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g �
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
Analytical
Tech -pique
Minimuni
Geo. Mean
Maximurr
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
2419
5073
7692
MPN/g
0
60 Days
G
CFu
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform
3 MPN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt.l (VS reduction) ©
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
1 Alt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed 011
CERTIFICATION STATEMENT (please check the appropriate statement)
© "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if
you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Charles Cocker - Superintendent - South
Durham WRF
Preparer Name and Title (type or print)
C C11,116.
WWTP Name:
South Durham WRF
Brent Collins; Director of Technical Services
Land Applier Name and Title (if applicable)(type or print)
02/06/2z ;!�Ie
2/3/2024
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Durham WQ Permit Number: WQ0003504
NPDES Number: NCO047597
Monitoring Period: From 3/l/2023 To 4/30/2023
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
1 Alt B (Alk Treatment) ❑
1 Alt. C (Prior Testing) ❑
A1t.D (No Prior Test) ❑
1 Process to Further Reduce Pathogengs ❑
If applicable to alternative
performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
He Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
Alt. (1) Fecal Density 21
Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative
performed (Class
B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
1 Air Drying ❑
Composting ❑
jAerobic Digestion ❑
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g �
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
Analytical
Tech -pique
Minimum
Geo. Mean
Maximurr
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
192
789
4828
MPN/g
0
60 Days
G
CFU
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform
3 MPN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt.l (VS reduction) ©
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
1 Alt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed 011
CERTIFICATION STATEMENT (please check the appropriate statement)
© "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if
you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Charles Cocker - Superintendent - South
Durham WRF
Preparer Name and Title (type or print)
C C11,116.
WWTP Name:
South Durham WRF
Brent Collins; Director of Technical Services
Land Applier Name and Title (if applicable)(type or print)
02/06/2z ;!�Ie
2/3/2024
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Durham WQ Permit Number: WQ0003504
NPDES Number: NCO047597
Monitoring Period: From 5/l/2023 To 6/30/2023
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
1 Alt B (Alk Treatment) ❑
1 Alt. C (Prior Testing) ❑
A1t.D (No Prior Test) ❑
1 Process to Further Reduce Pathogengs ❑
If applicable to alternative
performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
He Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
Alt. (1) Fecal Density 21
Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative
performed (Class
B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
1 Air Drying ❑
Composting ❑
jAerobic Digestion ❑
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g �
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
Analytical
Tech -pique
Minimum
Geo. Mean
Maximum
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
309
2325
47059
MPN/g
0
60 Days
G
CFU
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform
3 MPN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt.l (VS reduction) ©
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
1 Alt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed 011
CERTIFICATION STATEMENT (please check the appropriate statement)
© "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if
you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Charles Cocker - Superintendent - South
Durham WRF
Preparer Name and Title (type or print)
C C11,116.
WWTP Name:
South Durham WRF
Brent Collins; Director of Technical Services
Land Applier Name and Title (if applicable)(type or print)
02/06/2z ;!�Ie
2/3/2024
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Durham WQ Permit Number: WQ0003504
NPDES Number: NCO047597
Monitoring Period: From 7/l/2023 To 8/31/2023
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
1 Alt B (Alk Treatment) ❑
1 Alt. C (Prior Testing) ❑
A1t.D (No Prior Test) ❑
1 Process to Further Reduce Pathogengs ❑
If applicable to alternative
performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
He Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
Alt. (1) Fecal Density 21
Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative
performed (Class
B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
1 Air Drying ❑
Composting ❑
jAerobic Digestion ❑
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g �
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
Analytical
Tech -pique
Minimum
Geo. Mean
Maximurr
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
2512
4078
6250
MPN/g
0
60 Days
G
CFu
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform
3 MPN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt.l (VS reduction) ©
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
1 Alt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed 011
CERTIFICATION STATEMENT (please check the appropriate statement)
© "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if
you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Charles Cocker - Superintendent - South
Durham WRF
Preparer Name and Title (type or print)
C C11,116.
WWTP Name:
South Durham WRF
Brent Collins; Director of Technical Services
Land Applier Name and Title (if applicable)(type or print)
02/06/2z ;!�Ie
2/3/2024
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Durham WQ Permit Number: WQ0003504
NPDES Number: NCO047597
Monitoring Period: From 9/l/2023 To 10/31/2023
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
1 Alt B (Alk Treatment) ❑
1 Alt. C (Prior Testing) ❑
A1t.D (No Prior Test) ❑
1 Process to Further Reduce Pathogengs ❑
If applicable to alternative
performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
He Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
Alt. (1) Fecal Density 21
Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative
performed (Class
B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
1 Air Drying ❑
Composting ❑
jAerobic Digestion ❑
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g �
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
Analytical
Tech -pique
Minimuni
Geo. Mean
Maximurr
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
1571
4031
10059
MPN/g
0
60 Days
G
CFu
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform
3 MPN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt.l (VS reduction) ©
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
1 Alt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed 011
CERTIFICATION STATEMENT (please check the appropriate statement)
© "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if
you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Charles Cocker - Superintendent - South
Durham WRF
Preparer Name and Title (type or print)
C C11,116.
WWTP Name:
South Durham WRF
Brent Collins; Director of Technical Services
Land Applier Name and Title (if applicable)(type or print)
02/06/2z ;!�Ie
2/3/2024
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Durham WQ Permit Number: WQ0003504
NPDES Number: NCO047597
Monitoring Period: From l l/l/2023 To 12/31/2023
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
1 Alt B (Alk Treatment) ❑
1 Alt. C (Prior Testing) ❑
A1t.D (No Prior Test) ❑
1 Process to Further Reduce Pathogengs ❑
If applicable to alternative
performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
He Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
Alt. (1) Fecal Density 21
Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative
performed (Class
B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
1 Air Drying ❑
Composting ❑
jAerobic Digestion ❑
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g �
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
Analytical
Tech -pique
Minimuni
Geo. Mean
Maximurr.
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
1163
3822
8790
MPN/g
0
60 Days
G
CFu
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform
3 MPN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt.l (VS reduction) ©
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
1 Alt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed 011
CERTIFICATION STATEMENT (please check the appropriate statement)
© "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if
you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Charles Cocker - Superintendent - South
Durham WRF
Preparer Name and Title (type or print)
C C11,116.
WWTP Name:
South Durham WRF
Brent Collins; Director of Technical Services
Land Applier Name and Title (if applicable)(type or print)
02/06/2z ;!�Ie
2/3/2024
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

North & South Durham Sludge Fecal Coliform Analysis
2023 Summary
North Durham WRF
Sample
Date
Sample Set #1
MPN
f. coliform/g total solids
Sample Set #2
MPN
f. coliform/g total solids
Sample Set #3
MPN
f. coliform/g total solids
Sample Set #4
MPN
f. coliform/g total solids
Sample Set #5
MPN
f. coldorm/g total solids
Sample Set #6
MPN
f. coliform/g total solids
Sample Set #7
MPN
f. coliform/g total solids
Geometric Mean
f. col. / g. is
..r
No sampling - Composting
#NUMI
#NUM!
#NUM!
#NUM!
#NUM!
#NUM!
South Durham WRF
Sample
Date
Sample Set #1
MPN
f. coliform/g total solids
Sample Set #2
MPN
f. coliform/g total solids
Sample Set #3
MPN
f. coliform/g total solids
Sample Set #4
MPN
f. coliform/g total solids
Sample Set #5
MPN
f coliform/g total solids
Sample Set #6
MPN
f. coliform/g total solids
Sample Set #7
MPN
f. coliform/g total solids
Geometric Mean
f.Col. / g. is
2/16/2023
4,167
6,566
3,086
7,692
7,237
2,419
7,609
5,073
4/13/2023
660
373
4,828
1,508
500
192
1,104
789
6/5/2023
8,125
47,059
2,857
647
309
420
4,000
2,325
8/29/2023
2,512
3,825
5,028
4,102
6,250
4,848
3,125
4,078
10/24/2023
2,660
7,831
2,538
1,571
10,059
6,878
3,012
4,031
12/11 /2023
1,163
3,196
8,790,
1,625
5,895
8,414
4,522
3,822

South Durham Water Reclamation Facility
Sludge Report
January '2023
SD PRIMARY SLUDGE TO DIGESTER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
294,590
3.9
95,818
86.1
2
331,800
3.6
99,620
83.2
3
313,990
3.4
89,035
89.3
4
537,600
3.5
156,925
84.5
TOTAL
1,477,980
3.6
441,398
85.8
WASTING TO GRAVITY THICKENER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
924,000
0.95
73,550
79.0
2
884,000
0.94
68,986
77.8
3
784,000
0.96
63,032
78.0
4
1,304,000
1.02
110,950
77.8
TOTAL
3,896,000
0.97
316,518
78.2
SD ANAEROBIC SLUDGE TO PRESS
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
440,167
2.1
77,091
68.0
2
481,871
2.2
88,414
68.7
3
474,865
2.1
83,168
69.2
4
694,094
2.2
127,352
67.8
TOTAL
2,090,997
2.2
376,025
68.4
ANAEROBIC SLUDGE TO BEDS
WEEK
1
2
3
4
TOTAL
Gallons % Solids Lbs Dry % Vol
60,000
60,000
Summary
3.5 17,514 84.5
3.5 17,514 84.5
Total Gallons to Anaerobic Dig.
Total Pounds of Dry Solids to Anaerobic Dig
Total Pounds of Vol. Solids to Anaerobic Dig.
Total Gallons from Anaerobic Dig.
Total Ibs. of Dry Solids from Anaerobic Dig.
Total Ibs. of Vol. Solids from Anaerobic Dig.
Detention Time - Days
Gas Production Ft3
Ft3 of Gas Produced/lb of VM added
% Reduction
Pounds of Polymer Used - GBT
Pounds of Polymer Used - BFP
GRAVITY THICKENER TO ANAEROBIC DIGESTE
Ibs VM
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
82,500
82,884
79,508
132,602
377,493
TWAS GBT TO ANAEROBIC DIGESTE
Ibs VM
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
58,115
124,320
6.2
64,283
78.8
50,655
53,688
115,280
6.2
59,609
77.9
46,435
49,161
104,405
6.5
56,598
77.9
44,090
86,340
187,068
6.4
99,849
77.8
77,683
247,304
531,073
6.3
280,340
78.1
218,863
SD SOLIDS OFF PRESS
GRAVITY THICKENER TO GBT
Ibs VM
Yds
% Solids
% Vol
Gallons
% Solids Lbs Dry
% Vol
Ibs VM
52,422
414
16.4
70.9
191,266
5.5
87,734
77.8
68,257
60,740
472
15.7
72.1
177,357
5.5
81,354
77.3
62,886
57,552
430
15.7
72.0
160,623
4.8
64,301
76.4
49,126
86,345
690
15.7
71.8
287,797
3.6
86,408
75.5
65,238
257,059
2,006
15.9
71.7
817,043
4.9
319,796
76.8
245,507
SOLIDS OFF DRYING BEDS
Beds Yards
Ibs VM Cleaned % Solids Removed
i
i
14,799
14,799
% solids and % Vol on the 'SD Primary Sludge to Digester' are last years results.
The Lab ran the incorrect solids test. Values are deemed to be reasonable
2,009,053 based on historical results.
721,738
196,357 Weeks 1-4 of 'Gallons TWAS GBT to Anaerobic Digester is 65%
2,150,997 the 'Gravity Thickener to GBT' flow. Bad flow meter.
393,539
271,858
39
57 % (VK) 54 % (LBS)
Ibs Polymer $/Ib Poly Cost
889
$1.75 1,556
1,958
$1.75 3,427
$/DT
18.22

South Durham Water Reclamation Facility
Sludge Report
February '2023
SD PRIMARY SLUDGE TO DIGESTER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
325,080
3.7
100,313
88.3
2
351,960
3.2
93,931
89.4
3
353,640
4.0
117,974
82.7
4
414,960
3.6
124,588
88.1
TOTAL
1,445,640
3.6
436,806
87.1
WASTING TO GRAVITY THICKENER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
1,050,000
0.98
86,219
77.0
2
1,120,000
0.93
86,576
77.2
3
1,165,000
0.98
95,676
76.6
4
1,190,000
0.97
95,957
76.9
TOTAL
4,525,000
0.97
364,427
76.9
SD ANAEROBIC SLUDGE TO PRESS
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
486,050
2.2
89,180
69.4
2
511,394
2.2
93,831
69.7
3
526,317
2.1
92,179
69.6
4
453,454
2.5
94,545
63.0
TOTAL
1,977,215
2.3
369,735
67.9
ANAEROBIC SLUDGE TO BEDS
WEEK
1
2
3
4
TOTAL
GRAVITY THICKENER TO ANAEROBIC DIGESTE
Ibs VM Gallons % Solids Lbs Dry % Vol Ibs VM
88,577
83,974
97,565
109,762
379,877
'TWAS GBT TO ANAEROBIC DIGESTE
Ibs VM
i Gallons
% Solids
Lbs Dry
% Vol
66,351
137,650
6.9
79,212
77.5
66,797
136,960
7.0
79,957
77.4
73,263
150,930
4.0
50,350
75.6
73,791
140,690
6.8
79,788
77.5
280,203
566,230
6.2
289,308
77.0
SD SOLIDS OFF PRESS
Ibs VM
i
Yds
% Solids
% Vol
61,891
452
15.5
72.9
65,400
490
15.1
72.8
64,157
494
15.0
72.5
59,563
425
15.3
73.3
251,011
1,861
15.2
72.9
Gallons % Solids Lbs Dry % Vol Ibs VM
80,000
80,000
Summary
2.5
16,680
63.0
i
10,508
2.5
16,680
63.0
10,508
Total Gallons to Anaerobic Dig.
Total Pounds of Dry Solids to Anaerobic Dig
Total Pounds of Vol. Solids to Anaerobic Dig.
Total Gallons from Anaerobic Dig.
Total ibs. of Dry Solids from Anaerobic Dig.
Total Ibs. of Vol. Solids from Anaerobic Dig.
Detention Time - Days
Gas Production Ft3
Ft3 of Gas Produced/lb of VM added
% Reduction
Pounds of Polymer Used - GBT
Pounds of Polymer Used - BFP
2,011,870
726,114
603,054
2,057,215
386,415
261,520
35
SOLIDS OFF DRYING BEDS
Beds Yards
Cleaned % Solids Removed
Ibs VM
61,389
61,887
38,065
61,836
223,177
GRAVITY THICKENER TO GBT
Gallons
% Solids Lbs Dry
% Vol
Ibs VM
211,769
2.6
45,920
73.5
33,751
210,707
3.7
65,020
74.5
48,440
232,200
6.2
120,066
77.1
92,571
216,444
3.9
70,401
75.2
52,941
871,120
4.1
301,407
75.1
227,703
solids and % Vol on the 'SD Primary Sludge to Digester' are last years results.
The Lab ran the incorrect solids test. Values are deemed to be reasonable
based on historical results.
Weeks 1-4 of'Gallons TWAS GBT to Anaerobic Digester is 65%
the 'Gravity Thickener to GBT' flow. Bad flow meter.
61 % (VK) 57 % (LBS)
Ibs Polymer $/lb Poly Cost $/DT
1,057
$3.75 3,964
1,906 $3.75 7,148 38.66

South Durham Water Reclamation Facility
Sludge Report
March '2023
SD PRIMARY SLUDGE TO DIGESTER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
438,210
3.3
120,604
85.2
2
357,840
3.8
113,407
79.1
3
280,476
3.3
77,193
85.9
4
269,010
3.3
74,037
82.4
TOTAL
1,345,536
3.4
385,240
83.2
WASTING TO GRAVITY THICKENER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
1,190,000
0.94
93,334
76.1
2
1,195,000
0.91
90,238
75.9
3
1,260,000
1.01
105,805
75.8
4
1,884,000
0.91
142,450
76.4
TOTAL
5,529,000
0.94
431,826
76.1
SD ANAEROBIC SLUDGE TO PRESS
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
546,332
2.2
100,241
70.2
2
602,545
2.2
110,555
69.8
3
273,211
2.2
50,129
70.7
4
414,755
2.2
74,370
69.8
TOTAL
1,836,843
2.2 .
335,294
70.1
ANAEROBIC SLUDGE TO BEDS
WEEK
1
2
3
4
TOTAL
Gallons % Solids Lbs Dry % Vol
163,885 2.2
270,000 2.2
433,885 2.2
Summary
GRAVITY THICKENER TO ANAEROBIC DIGESTE
Ibs VM Gallons % Solids Lbs Dry % Vol
102,755
89,705
66,308
61,006
319,774
ITWAS GBT TO ANAEROBIC DIGESTE
Ibs VM
Gallons
% Solids
Lbs Dry
% Vol
71,019 -
130,956
5.7
62,254
77.2
68,478
210,390
6.6
115,807
76.5
80,240
186,608
5.3
82,484
76.2
108,810
310,034
6.3
161,605
76.0
328,547
837,988
6.0
422,151
76.5
SD SOLIDS OFF PRESS
Ibs VM
Yds
% Solids
% Vol
70,369
436
14.9
72.7
77,167
530
15.0
72.5
35,441
274
15.4
72.5
51,873
416
15.4
72.7
234,850
, 1,655
15.2
72.6
SOLIDS OFF DRYING BEDS
Beds Yards
Ibs VM Cleaned % Solids Removed
30,070 69.8 20,989
49,540 70.1 34,727
79,609 70.0 55,716
Total Gallons to Anaerobic Dig.
Total Pounds of Dry Solids to Anaerobic Dig
Total Pounds of Vol. Solids to Anaerobic Dig
Total Gallons from Anaerobic Dig.
Total Ibs. of Dry Solids from Anaerobic Dig.
Total Ibs. of Vol. Solids from Anaerobic Dig,
Detention Time - Days
Gas Production Ft3
Ft3 of Gas Produced/lb of VM added
% Reduction
Pounds of Polymer Used - GBT
Pounds of Polymer Used - BFP
Ibs VM
Ibs VM
48,060
88,592
62,853
122,739
322.245
GRAVITY THICKENER TO GBT
Gallons
% Solids Lbs Dry
% Vol
201,471
3.5
58,809
74.6
323,675
4.4
118,776
74.9
287,089
4.0
95,773
73.8
476,976
3.9
153,152
75.1
1,289,211
4.0
426,510
74.6
Ibs VM
43,872
88,963
70,680
115,017
318,533
% solids and % Vol on the 'SD Primary Sludge to Digester' are last years results.
The Lab ran the incorrect solids test. Values are deemed to be reasonable
2,183,524 based on historical results.
807,391
642,019 Weeks 1-4 of'Gallons TWAS GBT to Anaerobic Digester' is 65%
2,270,728 the 'Gravity Thickener to GBT' flow. Bad flow meter.
414,904
290,566
36
44 % (VK) 55 % (LBS)
Ibs Polymer $/lb Poly Cost
1,171 $3.75 4,391
1,805
$3.75 6,769
$/DT
40.37

South Durham Water Reclamation Facility
Sludge Report
April '2023
SD PRIMARY SLUDGE TO DIGESTER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
375,732
3.3
103,409
83.7
2
358,092
3.5
104,527
88.0
3
381,906
3.5
111,478
87.2
4
458,640
3.6
137,702
86.4
TOTAL
1,574,370
3.5
457,116
86.3
WASTING TO GRAVITY THICKENER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
1,330,000
0.87
96,185
76.9
2
1,330,000
1.07
119,099
74.6
3
1,330,000
0.93
102,682
73.7
4
1,710,000
0.88
125,881
73.6
TOTAL
5,700,000
0.94
443,846
74.7
SD ANAEROBIC SLUDGE TO PRESS
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
383,100
2.1
67,096
69.6
2
573,342
2.2
105,197
68.4
3
548,502
2.2
100,639
68.5
4
556,152
2.2
102,043
68.7
TOTAL
2,061,096
2.2
374,975
68.8
ANAEROBIC SLUDGE TO BEDS
GRAVITY THICKENER TO ANAEROBIC DIGESTE
Ibs VM Gallons % Solids Lbs Dry % Vol Ibs VM
86,553
91,984
97,209
118,975
I
394,721
TWAS GBT TO ANAEROBIC DIGESTE
Ibs VM
Gallons
% Solids
Lbs Dry
% Vol
74,007
165,486
6.5
89,710
77.1
88,851
192,977
6.6
106,222
74.7
75,666
175,324
5.8
84,808
75.0
92,634
185,095
4.9
75,641
74.7
331,159
718,882
6.0
356.381
75.4
Ibs VM
46,699
71,955
68,938
70,103
257,695
WEEK
Gallons % Solids
Lbs Dry
% Vol
Ibs VM
1
100,000 2A
17,514
69.6
12,190
2
3
4
67,165 2.2
12,323
68.7
8,466
TOTAL
167,165 2.2
29,837
69.2
20,656
Summary
Total Gallons to Anaerobic Dig.
Total Pounds of Dry Solids to Anaerobic Dig
Total Pounds of Vol. Solids to Anaerobic Dig.
Total Gallons from Anaerobic Dig.
Total Ibs. of Dry Solids from Anaerobic Dig.
Total lbs. of Vol. Solids from Anaerobic Dig.
Detention Time - Days
Gas Production Ft3
Ft3 of Gas Produced/lb of VM added
% Reduction
Pounds of Polymer Used - GBT
Pounds of Polymer Used - BFP
2,293,252
813,497
663,345
2,228,261
404,812
278,351
33
SD SOLIDS OFF PRESS
Yds
% Solids
% Vol
368
14.9
72.5
434
13.3
63.1
478
15.4
71.2
457
15.4
71.0
1,737
14.8
69.5
SOLIDS OFF DRYING BEDS
Beds Yards
Cleaned % Solids Removed
Ibs VM
69,166
79,348
63,606
56,504
268,624
GRAVITY THICKENER TO GBT
Gallons
% Solids Lbs Dry
% Vol
Ibs VM
254,594
3.9
82,809
75.7
62,687
296,888
3.7
91,614
74.8
68,527
269,729
4.5
101,229
73.5
74,404
284,762
3.9
92,622
73.9
68,447
1,105,973
4.0
368,274
74.5
274,065
% solids and % Vol on the 'SD Primary Sludge to Digester' are last years results.
The Lab ran the incorrect solids test. Values are deemed to be reasonable
based on historical results.
Weeks 1-4 of'Gallons TWAS GBT to Anaerobic Digester' is 65%
the'Gravity Thickener to GBT' flow. Bad flow meter.
54 % (VK) 58 % (LBS)
Ibs Polymer $/lb Poly Cost $/DT
1,084
$3.75 4,065
1,905 $3.75 7,144 38.10

South Durham Water Reclamation Facility
Sludge Report
May '2023
SD PRIMARY SLUDGE TO DIGESTER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
395,136
3.4
112,045
87.5
2
328,986
3.4
93,287
87.9
3
373,086
3.2
99,569
85.5
4
528,318
3.4
149,810
87.2
TOTAL
1,625,526
3.4
454,711
87.0
WASTING TO GRAVITY THICKENER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
1,330,000
0.92
101,525
73.0
2
1,330,000
0.90
100,258
72.6
3
1,330,000
0.91
101,288
72.9
4
1,908,000
0.86
136,277
73.6
TOTAL
5,898,000
0.90
439,347
73.0
SD ANAEROBIC SLUDGE TO PRESS
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
512,838
2.2
94,096
68.1
2
593,730
2.2
108,938
67.7
3
617,892
2.2
113,371
68.1
4
926,311
2.3
177,685
68.2
TOTAL
2,650,771
2.2
494,089
68.0
ANAEROBIC SLUDGE TO BEDS
WEEK
Gallons
% Solids
Lbs Dry
% Vol
1
2
3
4
TOTAL
85,000
85,000
;GRAVITY THICKENER TO ANAEROBIC DIGESTE
lbs VM Gallons % Solids Lbs Dry % Vol
98,039
82,000
85,132
130,634
395,805
ITWAS GBT TO ANAEROBIC DIGESTE
lbs
VM
� Gallons
%Solids
Lbs Dry
%Vol
74,147
�165,205
5.2
71,646
74.0
72,764
191,133
4.9
78,108
73.7
73,820
� 208,543
5.1
88,702
74.5
100,323
� 319,280
5.8
154,442
74.9
321,054
� 884,161
5.3
392,898
74.3
� SD SOLIDS OFF PRESS
lbs VM
Yds
%Solids
%Vol
64,079
447
15.4
70.8
73,751
486
15.5
73.4
77,206
434
15.9
70.3
121,181
786
15.5
70.7
336,216
2,153
15.6
71.3
SOLIDS OFF DRYING BEDS
Beds
Yards
lbs VM
Cleaned
%Solids
Removed
2.2 15,596 68.1 10,621
I
2.2 15,596 68.1 10,621 1
lbs
VM
lbs
VM
53,018
57,566
66,083
115,677
292,344
GRAVITY THICKENER TO GBT
Gallons lbs
%Solids Lbs Dry
%Vol
254,161
3.1
65,711
70.8
294,051
3.2
78,476
72.7
320,836
4.5
120,410
71.0
491,198
3.5
143,381
66.8
1,360,246
3.6
407,978
70.3
VM
46,523
57,052
85,491
95,778
284,845
Summary
%solids and %Vol on the'SD Primary Sludge to Digester' are last years results.
The Lab ran the incorrect solids test. Values are deemed to be reasonable
Total Gallons to Anaerobic Dig.
2,509,687
based on historical results.
Total Pounds of Dry Solids to Anaerobic Dig.
847,609
Total Pounds of Vol. Solids to Anaerobic Dig.
688,148
Weeks 1-4 of 'Gallons TWAS GBT to Anaerobic Digester' is 65%
Total Gallons from Anaerobic Dig.
2,735,771
the 'Gravity Thickener to GBT' flow. Bad flow meter.
Total lbs. of Dry Solids from Anaerobic Dig.
509,685
Total lbs. of Vol. Solids from Anaerobic Dig.
346,837
Detention Time -Days
31
Gas Production Ft3
Ft3 of Gas Produced/lb of VM added
Reduction
55
% (VK)
50 % (LBS)
lbs Polymer
$llb
Poly Cost $IDT
Pounds of Polymer Used -GBT
1,171
$3.75
4,391
Pounds of Polymer Used - BFP
2,837
$3.75
10,639 43.06

South Durham Water Reclamation Facility
Sludge Report
June '2023
SD PRIMARY SLUDGE TO DIGESTER
GRAVITY THICKENER TO ANAEROBIC DIGESTE
WEEK Gallons % Solids Lbs Dry
% Vol
lbs VM
Gallons
% Solids Lbs Dry % Vol
lbs VM
1 324,576 4.3 116,399
87.0
101,268
2 331,632 4.6 127,227
86.6
110,179
3 315,756 4.8 126,403
86.0
108,707
4 374,850 3.9 121,924
82.3
100,343
TOTAL 1,346,814 4.4 491,954
85.5
420,497 ;
WASTING TO GRAVITY THICKENER
TWAS GBT TO ANAEROBIC DIGESTE
WEEK Gallons % Solids Lbs Dry
% Vol
lbs VM
Gallons
% Solids Lbs Dry % Vol
lbs VM
1 1,465,000 0.79 96,087
74.2
71,314
118,984
5.0 49,616 74.9
37,163
2 1,508,045 0.71 89,513
74.2
66,459
171,878
5.3 75,974 74.9
56,904
3 877,897 0.54 39,286
74.1
29,103
88,140
4.7 34,549 75.0
25,912
4 1,268,700 0.69 73,138
72.9
53,341
146,513
5.4 65,373 74.3
48,539
TOTAL 5,119,642 0.68 298,023
73.9
220,217
525,515
5.1 225,512 74.8
168,518
SD ANAEROBIC SLUDGE TO PRESS
SD SOLIDS OFF PRESS
GRAVITY THICKENER TO GBT
WEEK Gallons % Solids Lbs Dry
% Vol
lbs VM
Yds
% Solids % Vol
Gallons % Solids Lbs Dry % Vol
lbs VM
1 614,657 2.0 102,525
68.3
70,024
.479
15.1 71.3
183,053 3.3 50,380 73.3
36,928
2 504,240 2.2 92,518
67.8
62,727
425
15.9 71.2
264,428 3.1 68,365 72.1
49,291
3 471,839 2.2 86,573
68.0
58,870
399
15.4 71.5
135,599 3.4 38,450 73.3
28,184
4 572,731 2.1 97,920
67.6
66,194
543
15.4 70.6
225,405 3.2 60,156 73.0
43,914
TOTAL 2,163,467 2.1 379,536
67.9
257,815
1,845
15.5 71.2
808,485 3.3 217,352 72.9
158,318
ANAEROBIC SLUDGE TO BEDS
SOLIDS OFF DRYING BEDS
Beds
Yards
WEEK Gallons % Solids Lbs Dry
% Vol
lbs VM
Cleaned
% Solids Removed
1
2
3
4
TOTAL
Summary
Weeks 1-3 of %Solids and %Vol for the 'SD Primary Sludge to Digester' are last.
years results. The Lab ran the incorrect solids test. Values are deemed to be
Total Gallons to Anaerobic Dig.
1,872,329
reasonable based on historical
results.
Total Pounds of Dry Solids to Anaerobic Dig.
717,465
Total Pounds of Vol. Solids to Anaerobic Dig.
589,014
Weeks 1-4 of 'Gallons TWAS GBT
to Anaerobic Digester' is 65%
Total Gallons from Anaerobic Dig.
2,163,467
the'Gravity Thickener to GBT' flow. Bad flow meter.
Total lbs. of Dry Solids from Anaerobic Dig.
379,536
Total lbs. of Vol. Solids from Anaerobic Dig.
257,815
Detention Time - Days
40
Gas Production Ft3
Ft3 of Gas Produced/lb of VM added
% Reduction
55
% (VK)
56 % (LBS)
lbs Polymer
$/Ib
Poly Cost
$/DT
Pounds of Polymer Used - GBT
887
$3.75
3,326
Pounds of Polymer Used - BFP
2,400
$3.75
9,000
47.43

South Durham Water Reclamation Facility
Sludge Report
July '2023
SD PRIMARY SLUDGE TO DIGESTER
GRAVITY THICKENER TO ANAEROBIC DIGESTE
WEEK Gallons % Solids Lbs Dry
% Vol
lbs VM
Gallons
% Solids
Lbs Dry
% Vol
lbs VM
1 250,488 6.2 129,522
83.7
108,410
2 350,172 6.7 195,669
81.4
159,275
3 285,420 6.7 159,487
81.7
130,301
4 455,820 6.4 243,298
87.9
213,859
TOTAL 1,341,900 6.5 727,977
83.7
611,845
WASTING TO GRAVITY THICKENER
TWAS GBT TO ANAEROBIC DIGESTE
WEEK Gallons % Solids Lbs Dry
% Vol
lbs VM
Gallons
% Solids
Lbs Dry
% Vol
lbs VM
1 986,446 0.66 54,462
70.4
38,319
142,688
5.5
65,451
72.5
47,452
2 1,031,293 0.56 48,534
72.3
35,096
155,696
5.9
76,612
71.7
54,931
3 939,789 0.55 43,444
71.6
31,121
125,478
5.3
55,464
71.4
39,601
4 1,544,633 0.58 74,936
69.2
51,823
185,973
5.3
82,204
71.5
58,776
TOTAL 4,502,161 0.59 221,377
70.9
156,357
609,835
5.5
279,730
71.8
200,759
SD ANAEROBIC SLUDGE TO PRESS
SD SOLIDS OFF PRESS
GRAVITY THICKENER TO GBT
WEEK Gallons % Solids Lbs Dry
% Vol
lbs VM
Yds
% Solids
% Vol
Gallons
% Solids Lbs Dry % Vol lbs VM
1 437,595 2.0 72,991
64.8
47,298
356
15.9
67.9
133,417
3.1 34,494 70.5 24,318
2 481,100 2.1 84,260
64.4
54,263
400
16.3
67.2
154,395
3.2 41,205 70.6 29,091
3 444,826 2.1 77,907
64.2
50,016
392
16.4
66.2
179,888
3.1 46,508 69.1 32,137
4 568,479 2.1 99,563
64.0
63,721
507
16.6
62.3
210,836
3.4 59,785 70.1 41,909
TOTAL 1,932,000 2.1 334,721
64.4
215,298
1,655
16.3
65.9
678,536
3.2 181,991 70.1 127,455
ANAEROBIC SLUDGE TO BEDS
SOLIDS OFF DRYING BEDS
Beds
Yards
WEEK Gallons % Solids Lbs Dry
% Vol
lbs VM
Cleaned
% Solids
Removed
1
2
3
4
TOTAL
Summary
Total Gallons to Anaerobic Dig.
1,951,735
Total Pounds of Dry Solids to Anaerobic Dig.
1,007,707
Total Pounds of Vol. Solids to Anaerobic Dig.
812,605
Total Gallons from Anaerobic Dig.
1,932,000
Total lbs. of Dry Solids from Anaerobic Dig.
334,721
Total lbs. of Vol. Solids from Anaerobic Dig.
215,298
Detention Time - Days
40
Gas Production Ft3
Ft3 of Gas Produced/lb of VM added
% Reduction
55
% (VK)
74
% (LBS)
lbs Polymer
$/Ib
Poly Cost
$/DT
Pounds of Polymer Used - GBT
774
$1.75
1,355
Pounds of Polymer Used - BFP
2,180
$1.75
3,815
22.80

South Durham Water Reclamation Facility
Sludge Report
August '2023
SD PRIMARY SLUDGE TO DIGESTER
GRAVITY THICKENER TO ANAEROBIC DIGESTE
WEEK Gallons % Solids Lbs Dry
% Vol
lbs VM
Gallons
% Solids
Lbs Dry
% Vol
lbs VM
1 279,456 5.4 125,856
84.2
105,971
2 310,980 5.7 147,834
85.3
126,102
3 253,893 6.9 146,105
87.7
128,134
4 439,632 4.7 170,494
79.6
135,713
TOTAL 1,283,961 5.7 590,288
84.2
495,920
WASTING TO GRAVITY THICKENER
TWAS GBT TO ANAEROBIC DIGESTE
WEEK Gallons % Solids Lbs Dry
% Vol
lbs VM
Gallons
% Solids
Lbs Dry
% Vol
lbs VM
1 1,052,522 0.69 60,393
70.4
42,514
170,976
5.4
77,001
72.0
55,441
2 1,388,472 0.57 66,055
70.1
46,281
190,531
5.0
79,451
71.6
56,887
3 831,113 0.53 36,816
72.2
26,580
152,528
4.8
61,060
72.4
44,207
4 1,898,369 0.87 137,631
72.5
99,767
406,303
5.0
167,734
72.7
121,859
TOTAL 5,170,475 0.67 300,895
71.3
215,142
920,338
5.1
385,246
72.2
278,394
SD ANAEROBIC SLUDGE TO PRESS
SD SOLIDS OFF PRESS
GRAVITY THICKENER TO GBT
WEEK Gallons % Solids Lbs Dry
% Vol
lbs VM
Yds
% Solids
% Vol
Gallons
% Solids Lbs Dry % Vol lbs VM
1 542,000 2.1 94,926
63.8
60,563
450
16.5
66.2
258,000
2.5 53,793 68.9 37,063
2 537,000 2.1 94,050
64.6
60,756
433
16.3
67.9
223,000
2.9 53,935 68.1 36,730
3 333,292 2.1 58,373
65.3
38,117
383
16.3
68.0
166,590
3.2 44,460 72.9 32,411
4 912,173 2.2 167,366
66.4
111,131
775
16.1
68.7
389,120
3.1 98,980 71.0 70,276
TOTAL 2,324,465 2.1 414,714
65.0
270,567
2,041
16.3
67.7
1,036,710
2.9 251,168 70.2 176,480
ANAEROBIC SLUDGE TO BEDS
SOLIDS OFF DRYING BEDS
Beds
Yards
WEEK Gallons % Solids Lbs Dry
% Vol
lbs VM
Cleaned
% Solids
Removed
1
2
3 50,000 2.1 8,757
66.4
5,815
4
TOTAL 50,000 2.1 8,757
66.4
5,815
Summary
Total Gallons to Anaerobic Dig.
2,204,299
Total Pounds of Dry Solids to Anaerobic Dig.
975,535
Total Pounds of Vol. Solids to Anaerobic Dig.
774,314
Total Gallons from Anaerobic Dig.
2,374,465
Total lbs. of Dry Solids from Anaerobic Dig.
423,471
Total lbs. of Vol. Solids from Anaerobic Dig.
276,382
Detention Time - Days
35
Gas Production Ft3
1,849,125
Ft3 of Gas Produced/lb of VM added
2.4
% Reduction
51
% (VK)
64
% (LBS)
lbs Polymer
$/Ib
Poly Cost
$/DT
Pounds of Polymer Used - GBT
1,142
$1.75
1,999
Pounds of Polymer Used - BFP
2,783
$1.75
4,870
23.49

South Durham Water Reclamation Facility
Sludge Report
September '2023
SD PRIMARY SLUDGE TO DIGESTER
GRAVITY THICKENER TO ANAEROBIC DIGESTE
WEEK Gallons % Solids Lbs Dry
% Vol
lbs VM
Gallons
% Solids
Lbs Dry
% Vol lbs VM
1 305,016 6.4 162,805
70.5
114,778 '
2 306,720 4.7 120,228
86.0
103,396
3 388,512 7.2 233,294
79.6
185,702
4 321,204 6.1 163,409
84.2
137,591
TOTAL 1,321,452 6.1 679,736
80.1
541,466
WASTING TO GRAVITY THICKENER
TWAS GBT TO ANAEROBIC DIGESTE
WEEK Gallons % Solids Lbs Dry
% Vol
lbs VM
Gallons
% Solids
Lbs Dry
% Vol lbs VM
1 1,402,297 0.89 103,569
70.0
72,529
233,239
5.4
105,042
72.4 76,050
2 1,387,741 0.77 89,498
71.4
63,910
220,948
5.5
101,349
72.6 73,579
3 1,356,071 0.75 85,081
73.1
62,170
233,964
4.6
89,758
72.1 64,715
4 1,653,659 0.85 117,044
73.0
85,427
273,537
4.8
108,362
72.9 78,941
TOTAL 5,799,768 0.82 395,192
71.9
284,036
961,688
5.1
404,510
72.5 293,286
SD ANAEROBIC SLUDGE TO PRESS
SD SOLIDS OFF PRESS
GRAVITY THICKENER TO GBT
WEEK Gallons % Solids Lbs Dry
% Vol
lbs VM
Yds
% Solids
% Vol
Gallons
% Solids Lbs Dry % Vol lbs VM
1 557,351 2.2 102,263
66.2
67,698
490
15.9
68.8
231,375
3.2 61,749 70.7 43,657
2 546,770 2.3 104,881
66.4
69,641
483
16.0
68.6
171,817
3.2 45,855 71.0 32,557
3 556,142 2.3 106,679
65.8
70,195
481
17.2
67.7
299,792
3.3 82,509 70.4 58,086
4 674,332 2.2 123,726
64.1
79,309
608
16.1
68.7
319,466
3.3 86,591 70.0 60,571
TOTAL 2,334,595 2.3 437,550
65.6
286,843
2,062
16.3
68.5
1,022,450
3.3 276,704 70.5 194,870
ANAEROBIC SLUDGE TO BEDS
SOLIDS OFF DRYING BEDS
Beds
Yards
WEEK Gallons % Solids Lbs Dry
% Vol
lbs VM
Cleaned
% Solids
Removed
1
2
3
4
TOTAL
Summary
Total Gallons to Anaerobic Dig.
2,283,140
Total Pounds of Dry Solids to Anaerobic Dig.
1,084,246
Total Pounds of Vol. Solids to Anaerobic Dig.
834,753
Total Gallons from Anaerobic Dig.
2,334,595
Total lbs. of Dry Solids from Anaerobic Dig.
437,550
Total lbs. of Vol. Solids from Anaerobic Dig.
286,843
Detention Time - Days
33
Gas Production Ft3
4,402,404
Ft3 of Gas Produced/lb of VM added
5.3
% Reduction
43
% (VK)
66
% (LBS)
lbs Polymer
$/lb
Poly Cost
$/DT
Pounds of Polymer Used - GBT
1,169
$1.75
2,046
Pounds of Polymer Used - BFP
2,784
$1.75
4,872
22.27

South Durham Water Reclamation Facility
Sludge Report
October '2023
SD PRIMARY SLUDGE TO DIGESTER
GRAVITY THICKENER TO ANAEROBIC DIGESTE
WEEK Gallons % Solids Lbs Dry
% Vol
Ibs VM
Gallons
% Solids
Lbs Dry
% Vol Ibs VM
1 314,390 6.1 159,943
87.2
139,470
2 295,644 3.8 93,695
88.7
83,108
3 341,652 4.0 113,975
85.1
96,993
4 443,892 5.5 203,613
85.4
173,886
TOTAL 1,395,578 4.9 571,227
86.6
493,457
WASTING TO GRAVITY THICKENER
TWAS GBT TO ANAEROBIC DIGESTE
WEEK Gallons % Solids Lbs Dry
% Vol
Ibs VM
Gallons
% Solids
Lbs Dry
% Vol Ibs VM
1 1,263,225 0.89 93,283
74.2
69,213
234,218
4.1
80,089
73.4 58,785
2 1,263,297 0.97 101,852
73.9
75,271
236,440
5.3
104,511
74.3 77,652
3 1,262,801 0.72 75,814
73.7
55,846
207,995
5.4
93,673
74.7 69,973
4 1,803,790 0.78 116,889
74.6
87,142
345,315
5.3
152,636
75.0 114,477
TOTAL 5,593,114 0.84 387,837
74.1
287,472
1,023,968
5.0
430,908
74.4 320,887
SD ANAEROBIC SLUDGE TO PRESS
SD SOLIDS OFF PRESS
GRAVITY THICKENER TO GBT
WEEK Gallons % Solids Lbs Dry
% Vol
Ibs VM
Yds
% Solids
% Vol
Gallons
% Solids Lbs Dry % Vol Ibs VM
1 524,719 2.4 105,028
66.9
70,264
472
16.3
69.4
260,542
3.8 82,571 70.4 58,130
2 571,436 2.3 109,613
66.8
73,221
476
16.3
69.3
263,285
3.9 85,636 72.1 61,744
3 487,800 2.3 93,570
67.1
62,785
392
16.3
69.5
227,219
3.4 64,430 70.7 45,552
4 780,353 2.2 143,179
67.5
96,646
686
15.9
70.3
357,316
1.4 41,720 26.3 10,972
TOTAL 2,364,308 2.3 451,390
67.1
302,916
2,026
16.2
69.6
1,108,362
3.1 274,357 59.9 176,398
ANAEROBIC SLUDGE TO BEDS
SOLIDS OFF DRYING BEDS
Beds
Yards
WEEK Gallons % Solids Lbs Dry
% Vol
Ibs VM
Cleaned
% Solids
Removed
1
2
3
4
TOTAL
Summary
Total Gallons to Anaerobic Dig.
2,419,546
Total Pounds of Dry Solids to Anaerobic Dig.
1,002,135
Total Pounds of Vol. Solids to Anaerobic Dig.
814,344
Total Gallons from Anaerobic Dig.
2,364,308
Total Ibs. of Dry Solids from Anaerobic Dig.
451,390
Total lbs. of Vol. Solids from Anaerobic Dig.
302,916
Detention Time - Days
32
Gas Production Ft3
4,697,128
Ft3 of Gas Produced/lb of VM added
5.8
% Reduction
53
% (VK)
63
% (LBS)
Ibs Polymer
$/Ib
Poly Cost
$/DT
Pounds of Polymer Used - GBT
1,141
$1.75
1,997
2,619
Pounds of Polymer Used - BFP
$1.75
4,583
20.31

South Durham Water Reclamation Facility
Sludge Report
November '2023
SD PRIMARY SLUDGE TO DIGESTER
GRAVITY THICKENER TO ANAEROBIC DIGESTE
WEEK Gallons % Solids Lbs Dry
% Vol
Ibs VM
Gallons
% Solids
Lbs Dry
% Vol Ibs VM
1 319,500 5.8 154,549
88.5
136,775
2 364,980 4.6 140,021
90.0
126,019
3 225,806 6.8 128,059
87.6
112,180
4 401,942 4.5 150,849
87.7
132,294
TOTAL 1,312,227 5.4 573,477
88.5
507,268 ..
WASTING TO GRAVITY THICKENER
TWAS GBT TO ANAEROBIC DIGESTE
WEEK Gallons % Solids Lbs Dry
% Vol
Ibs VM
Gallons
% Solids
Lbs Dry
% Vol Ibs VM
1 1,262,096 0.78 82,403
75.2
61,980
246,265
5.2
106,800
75.4 80,527
2 1,327,876 0.76 83,834
76.2
63,846
209,111
5.5
95,919
75.5 72,419
3 1,368,235 0.76 86,382
77.0
66,554
220,251
5.2
95,518
75.4 72,021
4 1,692,541 0.77 109,193
75.5
82,495
227,089
5.0
94,696
75.4 71,401
TOTAL 5,650,748 0.77 361,812
76.0
274,876
902,716
5.2
392,934
75.4 296,368
SD ANAEROBIC SLUDGE TO PRESS
SD SOLIDS OFF PRESS
GRAVITY THICKENER TO GBT
WEEK Gallons % Solids Lbs Dry
% Vol
Ibs VM
Yds
% Solids
% Vol
Gallons
% Solids Lbs Dry % Vol Ibs VM
1 554,538 2.2 101,747
67.3
68,475
461
15.3
70.2
279,129
4.4 102,429 74.1 75,900
2 488,720 2.1 85,594
67.5
57,776
450
14.9
70.6
233,390
4.2 81,752 73.4 60,006
3 130,489 2.1 22,854
67.4
15,403
178
14.2
71.0
244,491
4.0 81,562 73.1 59,622
4 554,232 1.9 87,824
67.3
59,105
550
14.5
71.5
259,407
3.5 75,721 71.8 54,368
TOTAL 1,727,979 2.1 298,018
67.4
200,760
1,639
14.7
70.8
1,016,417
4.0 341,464 73.1 249,895
ANAEROBIC SLUDGE TO BEDS
SOLIDS OFF DRYING BEDS
Beds
Yards
WEEK Gallons % Solids Lbs Dry
% Vol
Ibs VM
Cleaned
% Solids
Removed
1
2
3 90,000 2.1 15,763
67.4
10,624
4
TOTAL 90,000 2.1 15,763
67.4
10,624
Summary
Total Gallons to Anaerobic Dig.
2,214,943
Total Pounds of Dry Solids to Anaerobic Dig.
966,411
Total Pounds of Vol. Solids to Anaerobic Dig.
803,636
Total Gallons from Anaerobic Dig.
1,817,979
Total Ibs. of Dry Solids from Anaerobic Dig.
313,781
Total lbs. of Vol. Solids from Anaerobic Dig.
211,384
Detention Time - Days
36
Gas Production Ft3
2,575,497
Ft3 of Gas Produced/lb of VM added
3.2
% Reduction
58
% (VK)
74
% (LBS)
Ibs Polymer
$/Ib
Poly Cost
$/DT
Pounds of Polymer Used - GBT
973
$1.75
1,703
Pounds of Polymer Used - BFP
1,962
$1.75
3,434
23.04

South Durham Water Reclamation Facilitv
Sludge Report
December '2023
SD PRIMARY SLUDGE TO DIGESTER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
1
291,649
4.0
97,294
85.9
83,576
2
283,042
4.0
94,423
89.5
84,508
3
287,963
7.6
182,522
80.8
147,478
4
412,829
3.6
123,948
89.1
110,437
TOTAL
1,275,482
4.8
498,187
86.3
425,999
WASTING TO GRAVITY THICKENER
WEEK
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
1
1,261,981
0.70
73,344
76.8
56,321
2
1,222,258
0.68
69,812
76.2
53,194
3
1,171,376
0.85
82,843
75.8
62,799
4
1,603,813
0.75
100,399
75.9
76,168
TOTAL
5,259,428
0.75
326,398
76.2
248,483
SD ANAEROBIC SLUDGE TO PRESS
WEEK
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
1
478,304
1.7
67,814
67.8
45,978
2
478,496
1.9
75,822
68.8
52,166
3
473,898
1.9
75,094
68.7
51,589
4
545,258
2.0
88,675
68.6
60,787
TOTAL
1,975,956
1.9
307,406
68.5
210,520
WEEK
1
2
3
4
TOTAL
GRAVITY THICKENER TO ANAEROBIC DIGESTE
Gallons % Solids Lbs Dry % Vol Ibs VM
TWAS GBT TO ANAEROBIC DIGESTE
Gallons
% Solids
Lbs Dry
% Vol
Ibs VM
229,885
6.0
115,034
76.4
87,886
217,700
5.1
92,597
76.3
70,651
221,722
5.5
101,704
76.4
77,702
205,777
5.4
91,816
75.9
69,642
875,084
5.5
401,150
76.3
305,881
SD SOLIDS OFF PRESS
GRAVITY THICKENER TO GBT
Yds
% Solids
% Vol
Gallons
% Solids Lbs Dry
% Vol
Ibs VM
423
14.3
71.5
266,492
3.8
84,457
75.1
63,427
420
14.3
71.8
243,387
3.9
79,164
75.2
59,531
431
14.9
72.0
241,033
3.9
78,398
75.4
59,112
452
15.0
71.4
217,911
4.4
79,056
75.4
59,569
1,726
14.6
71.7
968,823
4.0
321,075
75.3
241,639
ANAEROBIC SLUDGE TO BEDS SOLIDS OFF DRYING BEDS
Beds Yards
Gallons % Solids Lbs Dry % Vol Ibs VM Cleaned % Solids Removed
Summary
Total Gallons to Anaerobic Dig.
Total Pounds of Dry Solids to Anaerobic Dig.
Total Pounds of Vol. Solids to Anaerobic Dig.
Total Gallons from Anaerobic Dig.
Total Ibs. of Dry Solids from Anaerobic Dig.
Total Ibs. of Vol. Solids from Anaerobic Dig.
Detention Time - Days
Gas Production Ft3
Ft3 of Gas Produced/lb of VM added
2,150,566
899,337
731,881
1.975.956
307,406
210,520
40
2,111,808
2.9
% Reduction
53 % (VK) 71 % (LBS)
Ibs Polymer $/Ib Poly Cost $/DT

NCDA&CS Agronomic Division Phone: [phone]
Website: www.ncagr.gov/agronomi/
Report No. FY24-SL002394
Client: Henry Thorpe
Advisor: Brent Collins
Predictive
5676 Old Roxboro Rd.
EMA Resources Inc
£
Oxford, NC 27565
755 Yadkinville Rd
x "
Soil Report Mehlich-3 Extraction
Mocksville, NC 27028
Sampled County: Granville
Links to Helpful Information
Client ID: 279166
Advisor ID: 405413
Sampled:
Received: 08/21/2023 Completed: 08/31/2023
Farm: GR01
Sample ID: 00001
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre)
N P2O5
K2O Mg S Mn Zn
Cu B
Information
Lime History:
1 - Fescue/OGrass/Tim, M 0.0
120-200 80
120 0 20 0 0
0 0
Note: 12
2 - 0.0
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V
CEC BS% Ac pH P-1 K-1
Ca% Mg%
S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI
Cu-I Na ESP SS-1 NO3-N
0.09 1.10
7.2 89 0.8 6.3 25 12
52 37
18 36 34 63 63
43 0.1 1
North Carolina
lobitty lru%t FuivJ Ctwnauukm
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler, Commissioner of Agriculture

NCDA&CS Agronomic Division Phone: [phone]
Website: www.ncagr.gov/agronomi/
Report No. FY24-SL002396
Predictive
Client:
Henry Thorpe
5676 Old Roxboro Rd.
Advisor: Brent Collins
EMA Resources Inc
£
x Soil Report Mehlich-3 Extraction
Oxford, NC 27565
755 Yadkinville Rd
Mocksville, NC 27028
Sampled County: Granville
„r
Links to Helpful Information
Client ID: 279166
Advisor ID: 405413
Sampled: Received: 08/21/2023 Completed: 08/31/2023
Farm: GR05
Sample ID: 00001
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre)
N P2O5
K2O
Mg S
Mn
Zn
Cu B
Information
Lime History:
1- Fescue/OGrass/Tim, M 1.3
120-200 0
80
0 0
0
0
0 0
Note: 12
2 - 0.0
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class:
Mineral
HM% W/V CEC BS% Ac pH P-1 K-1
Ca% Mg%
S-1
Mn-I
Mn-All Mn-Al2
Zn-I
Zn-AI
Cu-I Na ESP SS-1 NO3-N
0.32 1.13 5.5 63 2.0 4.9 149 27
40 20
53
169
118
619
619
195 0.1 2
Sample ID: 00002
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre)
N P2O5
K2O
Mg S
Mn
Zn
Cu B
Information
Lime History:
1 - Fescue/OGrass/Tim, M 0.9
120-200 10
90
0 0
0
0
0 0
Note: 12
2 - 0.0
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class:
Mineral
HM% W/V CEC BS% Ac pH P-1 K-1
Ca% Mg%
S-1
Mn-I
Mn-All Mn-AI2
Zn-I
Zn-AI
Cu-I Na ESP SS-1 NO3-N
0.32 0.98 6.8 76 1.6 5.3 59 23
50 24
83
964
595
455
455
196 0.1 1
North Carolina
f. 1 ' >
IOdvuO iiu%t lLaW Ctwnawukm
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler, Commissioner of Agriculture

NCDA&CS Agronomic Division Phone: [phone]
Website: www.ncagr.gov/agronomi/
Report No.
FY24-SL002396
Henry Thorpe
Page 2 of 3
Sample ID: 00003
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre)
N P2O5
K2O
Mg
S
Mn
Zn
Cu B
Information
Lime History:
1- Fescue/OGrass/Tim, M 0.3
120-200 0
80
0
0
0
0
0 0
Note: 12
2 - 0.0
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class:
Mineral
HM% W/V CEC BS% Ac pH P-1 K-1
Ca% Mg%
S-1
Mn-I
Mn-All
Mn-Al2
Zn-I
Zn-AI
Cu-I Na ESP
SS-1 NO3-N
0.27 1.08 7.3
83 1.2 5.8 311 27
55 26
38
223
151
1257
1257
298 0.1
1
Sample ID: 00004
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre)
N P2O5
K2O
Mg
S
Mn
Zn
Cu B
Information
Lime History:
1- Fescue/OGrass/Tim, M 1.0
120-200 0
50
0
0
0
0
0 0
Note: 12
2 - 0.0
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class:
Mineral
HM% W/V CEC BS% Ac pH P-1 K-1
Ca% Mg%
S-1
Mn-I
Mn-All
Mn-AI2
Zn-I
Zn-AI
Cu-I Na ESP
SS-1 NO3-N
0.36 1.14 4.6
63 1.7 5.1 134 44
37 22
29
296
195
449
449
156 0.0

NCDA&CS Agronomic Division Phone: [phone]
Website: www.ncagr.gov/agronomi/
Report No. FY24-SL010386
Client: Henry Thorpe
Advisor: Brent Collins
Predictive
5676 Old Roxboro Rd.
EMA Resources Inc
£
Oxford, NC 27565
755 Yadkinville Rd
x "
Soil Report Mehlich-3 Extraction
Mocksville, NC 27028
Sampled County: Granville
Links to Helpful Information
Client ID: 279166
Advisor ID: 405413
Sampled:
Received: 10/26/2023 Completed: 11/08/2023
Farm: GR05
Sample ID: 00007
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre)
N P2O5
K2O Mg S Mn Zn
Cu B
Information
Lime History:
1- Fescue/OGrass/Tim, M 0.0
120-200 0
100 0 0 0 0
0 0
Note: 12
2 - 0.0
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V
CEC BS% Ac pH P-1 K-1
Ca% Mg%
S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI
Cu-I Na ESP SS-1 NO3-N
0.76 1.08
10.0 84 1.6 6.0 143 20
63 20
34 243 163 745 745
271 0.0
North Carolina
lobitty lru%t FuivJ Ctwnauukm
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler, Commissioner of Agriculture

NCDA&CS Agronomic Division Phone: [phone]
Website: www.ncagr.gov/agronomi/
Report No. FY24-SL010354
Client: David Walker
Advisor: Brent Collins
Predictive
2909 Walker Road
EMA Resources Inc
£
Hillsborough, NC 27278
755 Yadkinville Rd
x "
Soil Report Mehlich-3 Extraction
Mocksville, NC 27028
Sampled County: Orange
Links to Helpful Information
Client ID: 526908
Advisor ID: 405413
Sampled:
Received: 10/25/2023 Completed: 11/08/2023
Farm: OR05
Sample ID: 00007
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre)
N P2O5
K2O Mg S Mn
Zn
Cu B
Information
Lime History:
1 - Fescue/OGrass/Tim, M 0.0
120-200 0
50 0 0 pH$
0
0 0
Note: 12 Note:
2- Fescue/OGrass/Tim, M 0.0
120-200 0
50 0 0 pH$
0
0 0
Note: 12 Note:
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V
CEC BS% Ac pH P-1 K-1
Ca% Mg%
S-1 Mn-I Mn-All Mn-Al2 Zn-I
Zn-AI
Cu-I Na ESP SS-1 NO3-N
0.41 1.05
13.9 95 0.6 7.1 91 44
80 14
30 1095 657 657 249
249
268 0.1 1
North Carolina
lobitty lru%t FuivJ Ctwnauukm
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler. Commissioner of Agriculture

NCDA&CS Agronomic Division Phone: [phone]
Website: www.ncagr.gov/agronomi/
Report No. FY24-SL010385
Predictive
Client:
Ronald Walker
3626 NC 57 N
Advisor: Brent Collins
EMA Resources Inc
£
x Soil Report Mehlich-3 Extraction
Hillsborough, NC 27278
755 Yadkinville Rd
Mocksville, NC 27028
Sampled County: Orange
„r
Links to Helpful Information
Client ID: 69935
Advisor ID: 405413
Sampled: Received: 10/26/2023 Completed: 11/08/2023
Farm: OR06
Sample ID: 00001
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre)
N P2O5
K2O
Mg S Mn
Zn
Cu B
Information
Lime History:
1- Fescue/OGrass/Tim, M 0.0
120-200 0
80
0 0 0
0
0 0
Note: 12
2 - 0.0
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-1
Ca% Mg%
S-1
Mn-I
Mn-All Mn-Al2 Zn-I
Zn-AI
Cu-I Na ESP SS-1 NO3-N
0.51 1.07 11.8 85 1.7 6.0 340 31
72 13
44
846
525 970
970
431 0.0
Sample ID: 00002
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre)
N P2O5
K2O
Mg S Mn
Zn
Cu B
Information
Lime History:
1- Fescue/OGrass/Tim, M 1.0
120-200 0
110
0 0 0
0
0 0
Note: 12
2 - 0.0
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-1
Ca% Mg%
S-1
Mn-I
Mn-All Mn-AI2 Zn-I
Zn-AI
Cu-I Na ESP SS-1 NO3-N
0.41 1.04 8.0 77 1.9 5.3 143 15
58 17
47
832
516 931
931
237 0.0
North Carolina
A� `� J
lotwcuo iru%( FtavJ Umnauukm
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler. Commissioner of Agriculture

NCDA&CS Agronomic Division Phone: [phone]
Website: www.ncagr.gov/agronomi/
Report No. FY23-SL029061
Client:
Richard Vanhook
Advisor:
Brent Collins
Predictive
9202 Walnut Grove Ch Rd
EMA Resources Inc
£
Hurdle Mills, NC 27541
755 Yadkinville Rd
x Soil Report Mehlich-3 Extraction
Mocksville, NC 27028
Sampled County: Orange
„r
Links to Helpful Information
Client ID: 356326
Advisor
ID: 405413
Sampled: Received: 04/05/2023 Completed: 04/14/2023
Farm: OR15
Sample ID: 00001
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre)
N P2O5
K2O
Mg S Mn
Zn
Cu
B
Information
Lime History:
1 - Fescue/OGrass/Tim, M 0.0
120-200 30
70
0 0 pH$
0
0
0
Note: 12 Note:
2 - Fescue/OGrass/Tim, M 0.0
120-200 30
70
0 0 pH$
0
0
0
Note: 12 Note:
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-1
Ca% Mg%
S-1
Mn-I
Mn-All Mn-Al2 Zn-I
Zn-AI
Cu-I
Na ESP SS-1 NO3-N
0.18 1.06 5.8 94 0.3 6.8 45 34
65 27
32
306
188 188 98
98
54
0.1 2
Sample ID: 00003
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre)
N P2O5
K2O
Mg S Mn
Zn
Cu
B
Information
Lime History:
1 - Fescue/OGrass/Tim, M 0.0
120-200 50
40
0 0 0
0
0
0
Note: 12
2- Fescue/OGrass/Tim, M 0.0
120-200 50
40
0 0 0
0
0
0
Note: 12
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-1
Ca% Mg%
S-1
Mn-I
Mn-All Mn-AI2 Zn-I
Zn-AI
Cu-I
Na ESP SS-1 NO3-N
0.51 1.03 6.6 85 1.0 6.2 38 52
54 28
52
1459 889 889 198
198
163
0.1 2
North Carolina
A� `� J
lotwcuo iru%( FtavJ Umnauukm
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler. Commissioner of Agriculture

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/ Report No. FY23-SL029059
Client: Wolfgang Lotz Advisor: Brent Collins
Predictive 8601 NC Hwy 49 EMA Resources Inc
Cedar Grove, NC 27231 755 Yadkinville Rd
x �
x
Soil Report Mehlich-3 Extraction Mocksville, NC 27028
S�, Sampled County: Orange
-
F" """'�•
Links to Helpful Information
Client ID: 464608 Advisor ID: 405413
Sampled: Received: 04/05/2023 Completed: 04/14/2023 Farm: OR70
Agronomist's Comments:
ATTENTION: This report was flagged with a "C" and/or "Z" to alert you that copper and/or zinc have accumulated in the soil and are approaching a level that could be
detrimental to crop production. The C and Z symbols are printed on your report for soil test Zn and Cu index levels of 2000 or more for agronomic crops; for peanuts with
zinc, the level is 250. This note is designed to be a "trigger" that allows enough time to either reduce the rate of application or find another field for application of biosolids
and/or waste water. The CTL (critical toxic level) for Cu and Zn is set at a 3000 index; for peanuts with zinc, the level is 500. Maintaining a pH of 6.0 or higher may reduce
potential for toxicity, especially for Zn. These levels are used by DENR as a benchmark to determine when application of waste products should be stopped. The CTL for
copper and zinc was set to prevent levels from accumulating to the point where they become toxic to crops grown on a field.
Sample ID: 00002
Recommendations: Lime Nutrients (lb/acre)
More
Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B
Information
Lime History:
1- Fescue/OGrass/Tim, M 0.5 120-200 0 50 0 0 0 Z 0 0
Note: 12 Note:
2- Fescue/OGrass/Tim, M 0.0 120-200 0 50 0 0 0 Z 0 0
Note: 12 Note:
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-1 Mn-All Mn-Al2 Zn-1 Zn-AI Cu-1 Na ESP SS-1 NO3-N
0.60 1.09 8.7 81 1.6 5.7 775 44 61 18 47 597 375 375 2974 2974 511 0.1 1
Sample ID: 00004
Recommendations: Lime Nutrients (lb/acre)
More
Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B
Information
Lime History:
1- Fescue/OGrass/Tim, M 0.5 120-200 0 60 0 0 0 Z 0 0
Note: 12 Note:
2- Fescue/OGrass/Tim, M 0.0 120-200 0 60 0 0 0 Z 0 0
Note: 12 Note:
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-1 Mn-All Mn-AI2 Zn-1 Zn-AI Cu-1 Na ESP SS-1 NO3-N
0.46 1.02 11.8 82 2.1 5.8 1005 39 60 20 41 297 195 195 4828 4828 855 0.1 1
North Carolina
k�h.iu,� ini�r 1 ur�t lu rna,��i.�n
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler. Commissioner of Agriculture

NCDA&CS Agronomic Division Phone: [phone]
Website: www.ncagr.gov/agronomi/
Report No. FY23-SL031775
Client: Wolfgang Lotz
Advisor: Brent Collins
Predictive
8601 NC Hwy 49
EMA Resources Inc
£
Cedar Grove, NC 27231
755 Yadkinville Rd
x "
Soil Report Mehlich-3 Extraction
Mocksville, NC 27028
Sampled County: Orange
Links to Helpful Information
Client ID: 464608
Advisor ID: 405413
Sampled:
Received: 05/04/2023 Completed: 05/15/2023
Farm: OR70
Sample ID: 00003
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre)
N P2O5
K2O Mg S Mn Zn
Cu B
Information
Lime History:
1-Soybean 0.0
0 70
40 0 0 0 0
0 0
Note: 3
2 - 0.0
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V
CEC BS% Ac pH P-1 K-1
Ca% Mg%
S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI
Cu-I Na ESP SS -I NO3-N
0.36 1.02
7.9 84 1.2 6.0 28 48
56 25
28 146 98 215 215
159 0.0
North Carolina
lobitty lru%t FuivJ Ctwnauukm
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler. Commissioner of Agriculture

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/ Report No. FY23-SL031778
Client: LJ Rogers Advisor: Brent Collins
Predictive 7912 NC Hwy 49 EMA Resources Inc
£ Mebane, NC 27302 755 Yadkinville Rd
x Soil Report Mehlich-3 Extraction Mocksville, NC 27028
Sampled County: Orange
„r
Links to Helpful Information
Client ID: 532835 Advisor ID: 405413
Sampled: Received: 05/04/2023 Completed: 05/15/2023 Farm: OR93
Agronomist's Comments:
ATTENTION: This report was flagged with a "C" and/or "Z" to alert you that copper and/or zinc have accumulated in the soil and are approaching a level that could be
detrimental to crop production. The C and Z symbols are printed on your report for soil test Zn and Cu index levels of 2000 or more for agronomic crops; for peanuts with
zinc, the level is 250. This note is designed to be a "trigger" that allows enough time to either reduce the rate of application or find another field for application of biosolids
and/or waste water. The CTL (critical toxic level) for Cu and Zn is set at a 3000 index; for peanuts with zinc, the level is 500. Maintaining a pH of 6.0 or higher may reduce
potential for toxicity, especially for Zn. These levels are used by DENR as a benchmark to determine when application of waste products should be stopped. The CTL for
copper and zinc was set to prevent levels from accumulating to the point where they become toxic to crops grown on a field.
Sample ID: 00007
Recommendations: Lime Nutrients (lb/acre)
More
Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B
Information
Lime History:
1- Fescue/OGrass/Tim, M 0.5 120-200 0 10 0 0 0 Z 0 0
Note: 12 Note:
2- Fescue/OGrass/Tim, M 0.0 120-200 0 10 0 0 0 Z 0 0
Note: 12 Note:
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-1 Mn-All Mn-Al2 Zn-1 Zn-AI Cu-1 Na ESP SS-1 NO3-N
0.27 1.18 10.7 82 2.0 5.8 926 74 61 18 41 197 135 135 3890 3890 570 0.1 1
North Carolina
IOdvuO iiu%t lLaW Ciannuukm
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler. Commissioner of Agriculture

NCDA&CS Agronomic Division Phone: [phone]
Website: www.ncagr.gov/agronomi/
Report No. FY24-SL002395
Predictive
Client:
Roy Carver
1220 Morton Pulliam Rd
Advisor: Brent Collins
EMA Resources Inc
£
x Soil Report Mehlich-3 Extraction
Roxboro, NC 27574
755 Yadkinville Rd
Mocksville, NC 27028
Sampled County: Person
„r
Links to Helpful Information
Client ID: 509635
Advisor ID: 405413
Sampled: Received: 08/21/2023 Completed: 08/31/2023
Farm: PS07
Sample ID: 00001
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre)
N P2O5
K2O
Mg S
Mn
Zn
Cu B
Information
Lime History:
1 - Fescue/OGrass/Tim, M 0.5
120-200 10
110
0 0
0
0
0 0
Note: 12
2 - 0.0
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class:
Mineral
HM% W/V CEC BS% Ac pH P-1 K-1
Ca% Mg%
S-1
Mn-I
Mn-All Mn-Al2
Zn-I
Zn-AI
Cu-I Na ESP SS-1 NO3-N
0.18 1.08 6.4 80 1.2 5.5 58 17
49 30
30
344
223
202
202
86 0.1 2
Sample ID: 00002
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre)
N P2O5
K2O
Mg S
Mn
Zn
Cu B
Information
Lime History:
1- Fescue/OGrass/Tim, M 1.1
120-200 0
70
0 0
0
0
0 0
Note: 12
2 - 0.0
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class:
Mineral
HM% W/V CEC BS% Ac pH P-1 K-1
Ca% Mg%
S-1
Mn-I
Mn-All Mn-AI2
Zn-I
Zn-AI
Cu-I Na ESP SS-1 NO3-N
0.27 1.08 11.6 82 2.1 5.4 62 35
49 32
56
114
85
279
279
126 0.1 1
North Carolina
f. 1 ' >
I0WOOLO iiu%t lLaW Ctwnawukm
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler, Commissioner of Agriculture

NCDA&CS Agronomic Division Phone: [phone]
Website: www.ncagr.gov/agronomi/
Report No.
FY24-SL002395
Roy Carver
Page 2 of 3
Sample ID: 00003
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre)
N P2O5
K2O
Mg
S
Mn
Zn
Cu B
Information
Lime History:
1 - Fescue/OGrass/Tim, M 0.0
120-200 80
0
0
20
pH$
0
0 0
Note: 12 Note:
2 - 0.0
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class:
Mineral
HM% W/V CEC BS% Ac pH P-1 K-1
Ca% Mg%
S-1
Mn-I
Mn-All
Mn-Al2
Zn-I
Zn-AI
Cu-I Na ESP
SS-1 NO3-N
0.09 1.16 11.2
98 0.2 7.2 26 85
57 37
22
203
121
74
74
117 0.1
1
Sample ID: 00005
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre)
N P2O5
K2O
Mg
S
Mn
Zn
Cu B
Information
Lime History:
1 - Fescue/OGrass/Tim, M 0.0
120-200 60
80
0
0
0
0
0 0
Note: 12
2 - 0.0
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class:
Mineral
HM% W/V CEC BS% Ac pH P-1 K-1
Ca% Mg%
S-1
Mn-I
Mn-All
Mn-AI2
Zn-I
Zn-AI
Cu-I Na ESP
SS-1 NO3-N
0.18 1.14 11.1
89 1.2 6.0 32 29
56 31
39
333
217
147
147
139 0.1
1

Signature Pages
Final Audit Report
Created: 2024-02-06
By: Brent Collins([e-mail])
Status: Signed
Transaction ID: CBJCHBCAABAAFgEVs8uzo5SKFWOWzGHLQrRlg8mwnZLM
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