NC0020605_Historical_2009

LYN
NCDENR
North Carolina Department of Environment and Natural Resources
Pat McCrory
Governor
Attn: Gary D. Harton, P.E.
The Wooten Company
301 West 14' Street
Greenville, NC 27834
Dear Mr.Harton:
Division of Water Resources
Thomas A. Reeder
Director
March 10, 2014
John E. Skvada, III
Secretary
Subject: Receipt of permit renewal
Permit NCO020604
Edgecombe County
The NPDES Unit received your permit renewal application on March 10, 2014. A member of the
NPDES Unit will review your application. They will contact you if additional information is required to
complete your permit renewal. You should expect to receive a draft permit approximately 30-45 days
before your existing permit expires.
If you have any additional questions concerning renewal of the subject permit, please contact Joe
Corporon [phone].
Sincerely,
OR, 1 4 20"14
Wren Thedford
Wastewater Branch
cc: Central Files
Raleigh Regional Office
NPDES Unit
1617 Mail Service Center, Ralegh, North Carolina 27699-1617
Location: 512 N. Salisbury St Raleigh, North Carolina 27604
Phone: [phone] Fax: [phone]rCustomer Service:1-877-623-6748
Internet:: www.ncwater.oro
An Equal OppoMnittMfirmative Action Employer

Application for Renewal of
NPDES Permit No. NCO020605
Town of Tarboro, North Carolina
114
DL
Luau,
March 2014
Prepared by:
The Wooten Company
301 West 14th Street
Greenville, North Carolina 27834
[phone]

March 7, 2014
Mr. Joe Corporon
NCDENR, Division of Water Resources
THE Water Quality Permitting
Surface Water Protection Section-NPDES
WOOTEN
512 N. Salisbury Street
COMPANY 9`"Floor - Archdale Building
Raleigh, North Carolina 27604
ENGINEERING
Re: Request for NPDES Permit Renewal
PLANNING NPDES Permit No. NCO020605
ARCH ITECTU RE Town of Tarboro, North Carolina
Dear Mr. Corporon:
On behalf of the Town of Tarboro, enclosed please find one (1) original and two
(2) copies of an application package for the renewal of the above -referenced
NPDES Permit. Each application package contains the following items:
1. EPA Form 2A, including results from:
• Four (4) Priority Pollutant Analyses, dated April 26, 2010, January
19, 2011, June 6, 2012 and October 23, 2013.
• Results of Chronic Toxicity Testing
2. Written Documentation for Authorized Representative
3. Topographical Site Map
4. Process Flow Schematic
5. Sludge Management Plan
The Wooten Company is the Town of Tarboro's authorized representative in
preparing the NPDES permit renewal package. No major modifications have
occurred at the facility since issuance of the most recent permit. If you should
have any questions about the renewal applications, please contact our office at
[phone].
Best regards,
THE WOOTEN COMP NY
By:
301 West 14th Street William A. Larsen EI
Greenville NC 27834 Enclosures
cc: Alan Thornton, Town of Tarboro
252.757.1096
fax [phone]

Application for Renewal of
NPDES Permit No. NCO020605
Town of Tarboro, North Carolina
March 2014
MAR 1 0 2014
Prepared by:
The Wooten Company
301 West 14th Street
Greenville, North Carolina 27834
[phone]

�faT"N
Town of Tarboro
' 17160)
P.O. Box 220 — 500 Main Street
r4 c.aA
Tarboro, NC 27886-0220
Telephone [phone]
Fax [phone]
www.tarboro-ne.com
February 20, 2014
NC DENR
Division of Water Quality, NPDES Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Re: NPDES Permit Renewal Application
Permit No. NC0020605
Dear Application Reviewer:
The letter is to confirm that The Wooten Company is the Town of Tarboro's
Authorized Representative in preparing the NPDES Permit Renewal Application.
I certify under penalty of law that this document and all attachments were
prepared under my direction and supervision in accordance with a system designed to
assure that qualified personnel properly gather and evaluated the information submitted.
Based on my inquiry of the person or persons who manage the system or those persons
directly responsible for gathering the information, the information is, to the best and
belief, true, accurate, and complete. I am aware that there are significant penalties for
submitting false information, including the possibility of fine and imprisonment for
]mowing violations.
If you need additional information, please contact me at [phone].
Sincerely,
Alan Thomton
Town Manager

EPA Form 2A
(inc. Parts A, B, C, D, E & F)

FACILITY NAME AND PERMIT NUMBER:
Tarboro WWTP, NC00206
FORM
2A
NPDES
APPLICATION OVERVIEW
PERMIT ACTION REQUESTED:
Renewal
2A APPLICATION
RIVER BASIN:
Tar -Pamlico
Form 2A has been developed in a modular format and consists of a "Basic Application Information" packet
and a "Supplemental Application Information" packet. The Basic Application Information packet is divided
into two parts. All applicants must complete Parts A and C. Applicants with a design flow greater than or
equal to 0.1 mgd must also complete Part B. Some applicants must also complete the Supplemental
Application Information packet. The following items explain which parts of Form 2A you must complete.
BASIC APPLICATION INFORMATION:
A. Basic Application Information for all Applicants. All applicants must complete questions A.1 through A.B. A treatment works
that discharges effluent to surface waters of the United States must also answer questions A.9 through A.12.
B. Additional Application Information for Applicants with a Design Flow 2 0.1 mgd. All treatment works that have design flows
greater than or equal to 0.1 million gallons per day must complete questions BA through B.6.
C. Certification. All applicants must complete Part C (Certification)
SUPPLEMENTAL APPLICATION INFORMATION:
D. Expanded Effluent Testing Data. A treatment works that discharges effluent to surface waters of the United States and meets
one or more of the following criteria must complete Part D (Expanded Effluent Testing Data):
1. Has a design flow rate greater than or equal to tmgd.
2. Is required to have a pretreatment program (or has one in place), or
3. Is otherwise required by the permitting authority to provide the information.
E. Toxicity Testing Data. A treatment works that meets one or more of the following criteria must complete Part E (Toxicity Testing
Data):
1. Has a design flow rate greater than or equal to 1 mgd,
2. Is required to have a pretreatment program (or has one in place), or
3. Is otherwise required by the permitting authority to submit results of toxicity testing.
F. Industrial User Discharges and RCRAICERCLA Wastes. A treatment works that accepts process wastewater from any
significant industrial users (SIUs) or receives RCRA or CERCLA wastes must complete Part F (Industrial User Discharges
and RCRA/CERCLA Wastes). SIUs are defined as:
1. All industrial users subject to Categorical Pretreatment Standards under 40 Code of Federal Regulations (CFR) 403.6 and
40 CFR Chapter I, Subchapter N (see instructions); and
2. Any other industrial user that:
a. Discharges an average of 25,000 gallons per day or more of process wastewater to the treatment works (with certain
exclusions); or
b. Contributes a process wastestream that makes up 5 percent or more of the average dry weather hydraulic or organic
capacity of the treatment plant; or
c. Is designated as an SIU by the control authority.
G. Combined Sewer Systems. A treatment works that has a combined sewer system must complete Part G (Combined Sewer
Systems).
ALL APPLICANTS MUST COMPLETE PART C (CERTIFICATION)
EPA Fonn 3510-2A law. 1-99). Replaces EPA forms 7550.6 & 7550-22. Page 1 of 25

FACILITY NAME AND PERMIT NUMBER:
Tarboro WWTP. NCO020605
BASIC APPLICATION INFORMATION
PERMIT ACTION REQUESTED: RIVER BASIN:
Renewal I Tar -Pamlico
PART A. BASIC APPLICATION INFORMATION FOR ALL APPUCANTS:
All treatment works must complete questions A.1 through A8 of this Basic Application Information Packet.
AA. Facility Information.
Facility Name Town of Tarboro Wastewater Trea ni nl PlailL
Mailing Address Post Office Box 220
Contact Person
Title
Telephone Number
Facility Address Service Road off SR 2rB/HiQhwav 64 Junction
(not P.O. Box) Tarboro North Carolina 27666
A.2. Applicant Information. If the applicant is different from the above, provide the following:
Applicant Name
Mailing Address Post Office Box 220
Tarboro North Carolina 27686
Contact Person Alan Thornton
Title Town Manager
Telephone Number (2521641-4250
Is the applicant the owner or operator (or both) of the treatment works?
® owner ® operator
Indicate whether correspondence regarding this permit should be directed to the facility or the applicant.
❑ facility ® applicant
A.3. Existing Environmental Permits. Provide the peomd number of any existing environmental permits that have been issued to the treatment works
(include state -issued permits).
NPOES NC0020606 PSD N/A
UIC N,A Other W00003047
RCRA NIA Other NiA
A.4. Collection System Information. Provide information on municipalities and areas served by the facility. Provide the name and population of each
entity and, if known, provide information on the type of collection system (combined vs. separate) and its ownership (municipal, private, etc.)
Name Population Served Type of Collection System Ownership
Town of Tarboro 10,585 5eearate Sanitary Municipal
Town of Princeville 2,226 Separate Sanitary Municipal
Edgecombe Cc WSD No. 5 200 Separate Sanitary Municipal
Total population served 13,011
EPA Foon 3510.2A (Rev. 1-99). Replaces EPA forms 7550.6 & 7550-22. Page 2 of 25

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP. NCO020605 I Renewal Tar -Pamlico
A.S. Indian Country.
a. Is the treatment works located in Indian Country?
❑ Yes ® No
b. Does the treatment works discharge to a receiving water that is either in Indian Country or that is upstream from (and eventually flows
through)Indian Country?
❑ Yes ® No
A.B. Flow. Indicate the design flow rate of the treatment plant (i.e., the wastewater flow rate that the plant was bmfl to handle). Also provide the
average daily flow rate and maximum daily flaw rate for each of the last three years. Each years data must be based on a 12-month time period
with the 12" month of 'this year' occurnng no more than three months poor to this application submittal.
a. Design flow rate 5.0 mgd
Two Years Apo Last Year This Year
b. Annual average daily flow rate 1,920 1.822 1.838
c. Maximum daily flow rate 6,876 4.700 4.858
A.7. Collection System. Indicate the type(s) of collection system(s) used by the treatment plant. Check all that apply. Also estimate the percent
contribution (by miles) of each.
® Separate sanitary sewer 100 %
71 Cori storm and sandary sewer WA o
A.B. Discharges and Other Disposal Methods.
a. Does the treatment works discharge effluent to waters of the U.S.? ® Yes ❑ No
If yes, list how many of each of the following types of discharge points the treatment works uses:
I. Discharges of treated effluent
It. Discharges of untreated or partially treated effluent
Ill. Combined sewer overflow points
N. Constructed emergency overflows (prior to the headworks)
v. Other WA
b. Does the treatment works discharge effluent to basins, ponds, or other surface impoundments
that do not have outlets for discharge to waters of the U.S-? ❑ Yes
If yes, provide the following for each surface impoundment:
Location'
Annual average daily volume discharge to surface impoundmenf(s)
Is discharge ❑ continuous or ❑ intermittent?
C. Does me treatment works land -apply treated wastewater?
If yes, provide the following for each land application site:
Location:
Number of acres.
Annual average daily volume applied to site: NIA
Is land application ❑ continuous or ❑ intermittent?
d. Does the treatment works discharge or transport treated or untreated wastewater to another
treatment works?
0
® No
N A mgd
❑ Yes N No
mgd
❑ Yes N No
EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550.6 8 7550-22, Page 3 of 25

FACIUTY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
If yes, describe the mean(s) by which the wastewater from the treatment works is discharged or transported to the other treatment works
(a g., tank truck, pipe).
N/A
If transport is by a party other than the applicant, provide.
Transporter Name WA
Mailing Address WA
WA
Contact Person WA
Title WA
Telephone Number ( IN/A
For each treatment works that receives this discharge, provide the following:
Name NIA
Mailing Address WA
WA
Contact Person WA
Title WA
Telephone Number 1 IN/A
If known. provide the NPDES permit number of the treatment works that receives this discharge WA
Provide the average daily flow rate from the treatment works into the receiving facility. WA mgd
e. Does the treatment works discharge or dispose of its wastewater in a manner not included
in A.8. through A.8 d above (e.g., underground percolation, well injection): ❑ Yes ® No
If yes, provide the following for each disposal method:
Description of method (including location and size of site(s) if applicable)'.
WA
Annual daily volume disposed by this method: NIA
Is disposal through this method ❑ continuous or ❑ intermittent?
EPA Form 3510-2A (Rev. 1-99). Replaces EPA forma 755" B 7550-22. Page 4 of 25

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP, NCO020605 Renewal I Tar -Pamlico
WASTEWATER DISCHARGES:
If you answered "Yes" to question A.8.a, complete questions A.9 through A.12 once for each outfall (including bypass points) through
which effluent is discharged. Do not include information on combined sewer overflows In this section. If you answered "No" to guestlon
A-8.a, go to Part B. "Additional Application Information for Applicants with a Design Flow Greater than or Equal to 0.1 mgd."
A.9. Description of Outfall.
a. Outfall number
b. Location
(City or tam, if applicable)
(County)
(Labluds)
C. Distance from shore (if applicable)
d- Depth below surface (if applicable)
e. Average daily flow rate
f Does this oMall have either an intermittent or a periodic discharge
If yes, provide the following information.
Number of times per year discharge occurs'.
Avemge duration of each discharge.
Average flow per discharge.
Months in which discharge occurs:
g. Is oulfa8 equipped with a diffuser?
A.10. Description of Receiving Waters
(Zip Code)
(State)
(Lnrgitude)
NIA - cascade aeration into rnmr it
NIA It.
m9d
❑ Yes ® No (go to A.9.g.)
❑ yes ® No
mgd
a. Name of receiving water Tar River
b. Name of watershed (8 known) Lower Tar
United States Soil Conservation Service 14-digit watershed code (if known): 03020103010020
c. Name of State Management/River Basin if known): Tar -Pamlico
United States Geological Survey B<9gfl hydrologic cataloging unit code if known). 03020103
d. Critical low flow of receiving stream (if applicable)
acute WA its chronic WA crs
e. Total hardness of receiving stream at critical low flow (if applicable) r NIA mg/1 of CaCO�
EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 d 7550.22. Page 5 of 25

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
A.11. Description of Treatment
a. What level of treatment are provided? Check all that apply.
N Primary S Secondary
N Advanced ❑ Other. Describe. NIA
b. Indicate the following removal rates (as applicable):
Design BOD5 removal or Design CB005 removal 95 r
Design SS removal 85 %
Design P removal 80
Design N removal 75 %
Other N/A NIA %
C. What type of disinfection is used for the effluent from this outfall? If disinfection varies by season, please descnbe
chlorine Gas
If disinfection is by chlorination is dechlorination used for this ourfall? ® Yes ❑ No
Does the treatment plant have post aeration? ® Yes ❑ No
A.12. Effluent Testing Information. All Applicants that discharge to waters of the US must provide effluent testing data for the following
parameters. Provide the Indicated effluent testing required by the permitting authority for each ourfall through which effluent Is
discharged. Do not Include Information on combined sewer overflows in this section. All Information reported must be based on data
collected through analysis conducted using 40 CFR Part 136 methods. In addition, this data must comply with QA/QC requirements of
40 CFR Part 136 and other appropriate QA/QC requirements for standard methods for analytes not addressed by 40 CFR Part 136. At a
minimum, effluent testing data must be based on at least three samples and must be no more than four and one-half years apart.
Ouffall number: 001
MAXIMUM DAILY VALUE
AVERAGE DAILY VALUE
PARAMETER
Value
Units
Value
of Samples
pH (Minimum)
4.9
s.u.
pH (Maximum)
7.6
s.u.
365
Flow Rate
4.86
mgd
1.838
RUnitsNumber
Temperature(Winter)
24.0
C'
15.2
182
Temperature (Summer)
27.0
C'
22.7
183
' For pH Pleaserert a minimum
and a maximum daily value
MAXIMUM DAILY
AVERAGE DAILY DISCHARGE
POLLUTANT
DISCHARGE
ANALYTICAL
MLIMDL
Number of
METHOD
Cone.
Units
Cone.
Units
Samples
CONVENTIONAL AND NON
CONVENTIONAL
COMPOUNDS
BIOCHEMICAL OXYGEN
BODS
14.00
m /L
4.08
MCVL
365
30
DEMAND (Report one)
C8005
NIA
N/A
N/A
NIA
NIA
FECAL COLIFORM
>600
# I100 mL
11.55
1111100 mL
365
200
TOTAL SUSPENDED SOUDS(TSS)
41.00
m IL
6.41
m IL
365
30
- END OF PART A.
REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE
EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550.6 a 7550-22, Page 6 of 25

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
BASIC APPLICATION INFORMATION
PART B. ADDITIONAL APPLICATION INFORMATION FOR APPLICANTS WITH A DESIGN FLOW GREATER THAN OR
EQUAL TO 0.1 MGD (100,000 gallons per day).
All applicants with a design flow rate i 0.1 mgd must answer questions BA through B.6. All others go to Part C (Certification).
B.I. Inflow and Infiltration. Estimate the average number of gallons per day that flow into the treatment works from inflow and/or infiltration
135,000 gpd
Briefly explain any steps underway or planned to minimize inflow and infiltration
The Town budaets $100,000 annually for any sewer line and manhole rehabilitation and replacement.
B.2. Topographic Map. Attach to this application a topographic map of the area extending at least one mile beyond facility property boundaries. This
map most show the outline of the facility and the following information. (You may submit more than one map if one map does not show the entire
area.)
a. The area surrounding the treatment plant, including all unit processes.
b. The major pipes or other structures through which wastewater enters the treatment works and the pipes or other structures through which
treated wastewater is discharged from the treatment plant. Include ouffalls from bypass piping, if applicable.
c. Each well where wastewater from the treatment plant is injected underground.
d. Wells, springs, other surface water bodies, and drinking water wells that are. 1) within'G mile of the property boundaries of the treatment
works, and 2) listed in public record or otherwise known to the applicant.
e. Any areas where the sewage sludge produced by the treatment works is stored, treated, cr disposed
L If the treatment works receives waste that is classified as hazardous under the Resource Conservation and Recovery Act (RCRA) by truck, rail.
or special pipe, show on the map where the hazardous waste enters the treatment works and where it is treated, stored, and/or disposed.
B.3. Process Flow Diagram or Schematic. Provide a diagram showing the processes of the treatment plant, including all bypass piping and all
backup power sources or redundancy in the system. Also provide a water balance showing all treatment units. including disinfection (e.g.,
chlorination and dechlordation). The water balance must show daily average flow rates at influent and discharge points and approximate daily flow
rates between treatment units. Include a beef narrative description of the diagram.
BA. OperatioNMairfenance Performed by Centractor(s).
Are any operational or maintenance aspects (related to wastewater treatment and effluent quality) of the treatment works the responsibility of a
contractor? ❑ Yes ® No
If yes, list the name, address. telephone number, and status of each contractor and describe the contractors responsibilities (attach additional
pages if necessary).
Name N/A
Mailing Address. N/A
N/A
Telephone Number: f )N/A
Responsibilities of Contractor: N/A
B.S. Scheduled improvements and Schedules of Implementation. Provide information on any uncompleted implementation schedule or
uncompleted plans for improvements that will affect the wastewater treatment, effluent quality, or design capacity of the treatment works. If the
treatment works has several different implementation schedules or is planning several improvements, submit separate responses to queston B.5
for each. (If none. go to question B.6 )
a. List the oufall number (assigned in question A9) for each outtall that is covered by this implementation schedule.
N/A
b. Indicate whether the planned improvements or implementation schedule am required by local. State, or Federal agencies.
❑ Yes IR No
EPA Forth 3510.2A (Rev. 1-99). Replaces EPA forms 7550.6 & 7550-22. Page 7 of 25

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
C. If the answer to 13.5,b is "Yes," briefly describe, including new maximum daily inflow rate (if applicable).
N/A
it Provide dates imposed by any compliance schedule or any actual dates of completion for the implementation steps listed below, as
applicable. For improvements planned independently of local, State, or Federal agencies, indicate planned or actual completion dates, as
applicable. Indicate dates as accurately as possible.
Schedule Actual Completion
Implementation Stage MM/DD/YYYY MM/DD/YYYY
- Begin Construction N/A N/A
- End Construction N/A NIA
- Begin Discharge N/A NIA
-Attain Operational Level WA WA
e. Have appropriate permits/clearances concerning other Federal/State requirements been obtained? ❑ Yes ® No
Describe briefly. N/A
B.6. EFFLUENT TESTING DATA (GREATER THAN 0.1 MGD ONLY).
Applicants that discharge to waters of the US must provide effluent testing data for the following parameters. Provide the indicated
effluent testing required by the permitting authority for each outfall through which effluent is discharged. Do not include information
on combine sewer overflows in this section. All Information reported must be based on data collected through analysis conducted
using 40 CFR Part 136 methods. In addition, this data must comply with QAIOC requirements of 40 CFR Part 136 and other appropriate
OA/QC requirements for standard methods for analytes not addressed by 40 CFR Part 136. At a minimum effluent testing data must be
based on at least three pollutant scans and must be no more than four and one-half years old.
Outfall Number. 001
MAXIMUM DAILY
AVERAGE DAILY DISCHARGE
POLLUTANT
DISCHARGE
ANALYTICAL
MLIMDL
Numbe rof
METHOD
Cone.
UnitsConc.
Units
Samples
CONVENTIONAL AND NON CONVENTIONAL COMPOUNDS
AMMONIA (as N)
6.40
mglL
<5.00
mglL
228
EPA 353.2
9
CHLORINE (TOTAL
46.00
uglL
<25.00
U91L
144
RESIDUAL, TRC)
DISSOLVED OXYGEN
12.7
mg/L
9.79
mglL
365
5
TOTAL KJELDAHL
2.74
mg/L
1.70
mg/L
12
EPA 351.2
0.5
NITROGEN(TKN)
NITRATE PLUS NITRITE
13.10
mg/L
8.09
mg/L
12
EPA 353.2
0.1
NITROGEN
OIL and GREASE
N/A
WA
NIA
WA
WA
EPA 1664A
5
PHOSPHORUS (Total)
0.90
mg/L
0.27
mg(L
52
EPA 365.1
0.1
TOTAL DISSOLVED
N/A
N/A
NIA
N/A
N/A
SOLIDS (TDS)
OTHER. NITROGEN (Total)
14.26
mg/L
9.79
mg/L
12
END OF PART B.
REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE
EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 8 7550-22. ' :.1:- P oI L`

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro Will NCO020605
Renewal
Tar -Pamlico
BASIC APPLICATION INFORMATION
PART C. CERTIFICATION
All applicants must complete the Certification Section. Refer to instructions to determine who is an officer for the purposes of this
certification. All applicants must complete all applicable sections of Form 2A, as explained in the Application Overvlew. Indicate below which
parts of Form 2A you have completed and are submitting. By signing this certification statement, applicants confirm that they have reviewed
Form 2A and have completed all sections that apply to the facility for which this application is submitted.
Indicate which parts of Form 2A you have completed and are submitting:
® Basic Application Information packet Supplemental Application Information packet
® Part D (Expanded Effluent Testing Data)
® Part E (Toxicity Testing: Biomonitoring Data)
® Part F (Industrial User Discharges and RCRAICERCLA Wastes)
❑ Part G (Combined Sewer Systems)
ALL APPLICANTS MUST COMPLETE THE FOLLOWING CERTIFICATION.
I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel property gather and evaluate the information submitted. Based on my inquiry of the person or persons who
manage the system or those persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment
for knowing violations
Name and official title Gary D. Hart P. The ie
Signature
Telephone number 2 7 7-11 96
Date signed
Upon request of the permitting authority, you must submit any other information necessary to assure wastewater treatment practices at the treatment
works or identify appropriate permitting requirements.
SEND COMPLETED FORMS TO:
NCDENR/ DWQ
Attn: NPDES Unit
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 & 7550-22, Page 9 of 25

FACILITY NAME AND PERMIT NUMBER:
Tarboro WWTP, NCO0206C
PERMIT ACTION REQUESTED:
Renewal
RIVER BASIN:
Tar -Pamlico
SUPPLEMENTAL APPLICATION INFORMATION
PART D. EXPANDED EFFLUENT TESTING DATA
Refer to the directions on the cover page to determine whether this section applies to the treatment works.
Effluent Testing: 1.0 mgd and Pretreatment Works. If the treatment works has a design flow greater than or equal to 1.0 mgd or it has (or is required
to have) a pretreatment program, or is otherwise required by the permitting authority to provide the data, then provide effluent testing data for the following
pollutants. Provide the indicated effluent testing information and any other information required by the permitting authority for each outfall through which
effluent is discharged. Do not include information on combined sewer overflows in this section. All information reported must be based on data collected
through analyses conducted using 40 CFR Part 136 methods. In addition, these data must comply with QAIQC requirements of 40 CFR Part 136 and
other appropriate OA/OC requirements for standard methods for anaiytes not addressed by 40 CFR Part 136. Indicate in the blank rows provided below
any data you may have on pollutants not specifically listed in this form. At a minimum, effluent testing data must be based on at least three pollutant
scans and must be no more than four and one-half years old.
Ouffall number: 001 (Complete once for each cuffall discharging effluent to waters of the United States.)
POLLUTANT
MAXIMUM DAILY DISCHARGE
AVERAGE DAILY DISCHARGE
ANALYTICAL
METHOD
MLIMDL
Conic.
Units
Masrs
Units
Conic.
Units
Mass
Units
Number
Of
Samples
METALS (TOTAL RECOVERABLE), CYANIDE, PHENOLS, AND HARDNESS.
ANTIMONY
6.8
ug/L
3.58
ug/L
4
EPA 200.7
5
ARSENIC
45.0
ug/L
<5.0
ug/L
4
EPA 200.7
5
BERYLLIUM
0.0
ug/L
0.0
ug/L
4
EPA 200.7
1
CADMIUM
< 1.0
ug/L
< 1.0
ug/L
4
EPA 200.7
1
CHROMIUM
< 5.0
ug1L
< 5.0
ug/L
4
EPA 200.7
5
COPPER
35.0
ug/L
8.33
uglL
12
EPA 200.7
5
LEAD
<5.0
ug/L
<5.0
ug/L
4
EPA 200.7
5
MERCURY
2.3
nglL
1.36
ng/L
4
EPA 1631E
0.5
NICKEL
12.0
ug/L
10.7
ug/L
12
EPA 200.7
10
SELENIUM
<10.0
ug/L
410.0
ug/L
4
EPA 200.7
10
SILVER
< 5.0
ug1L
< 5.0
ug/L
4
EPA 200.7
5
THALLIUM
<10.0
ug/L
<10.0
uglL
4
EPA 200.7
10
ZINC
36.0
ug/L
25.42
uglL
12
EPA 200.7
10
CYANIDE
<0.005
mglL
<0.005
mg/L
4
SM 4500-CN-E
0.005
TOTAL PHENOLIC
COMPOUNDS
.035
mglL
.023
mg/L
4
EPA 420.4
0.01
HARDNESS (as CaCO3)
40.2
mg/L
36.55
mg/L
4
SM 23408
0.65
Use this space (or a separate sheer) to provide information on other metals requested by the permit writer
EPA Form 3510-2A (Rev, 1-99), Replaces EPA forms 1550.6 8 7550-22, Page 10 of 25

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
Ouffall number: 001 (Complete once for each outfall discharging effluent to waters of the United Stales.)
MAXIMUM DAILY DISCHARGE
AVERAGE DAILY DISCHARGE
POLLUTANT
ANALYTICAL
MLIMDL
Number
Cone.
Units
Mass
Units
Cone-
Units
Mass
Units
Of
METHOD
Samples
VOLATILE ORGANIC COMPOUNDS
ACROLEIN
<100
ug/L
<100
ug/L
4
EPA 624
100
ACRYLONITRILE
<100
ug/L
<100
ug/L
4
EPA 624
100
BENZENE
<5.0
ug/L
<5.0
uglL
4
EPA 624
5
BROMOFORM
<5.0
ug/L
<5.0
ug/L
4
EPA 624
5
CARBON
TETRACHLORIDE
<5.0
ug/L
<5.0
ug1L
4
EPA 624
5
CHLOROBENZENE
<5.0
ug1L
<5.0
ug/L
4
EPA 624
5
CHLORODISROMO.
<5.0
ug1L
<5.0
ug1L
4
EPA 624
5
METHANE
CHLOROETHANE
<10.0
ug/L
<10.0
ug/L
4
EPA 624
10
2-CHLOROETHYLVINYL
<10.0
uglL
<10.0
ug/L
4
EPA 624
10
ETHER
CHLOROFORM
45.0
ugfL
<5.0
ug/L
4
EPA 624
5
HLOROSROMO-
<5.0
ug/L
<5.0
uglL
4
EPA 624
5
METHANE
ME
1,1-DICHLOROETHANE
45.0
ug/L
<5.0
uglL
4
EPA 624
5
1,2-DICHLOROETHANE
<5.0
uglL
<5.0
ug/L
4
EPA 624
5
TRANS-I,2-01CHLORO-
<5.0
ug/L
<5.0
ug/L
4
EPA 624
5
ETHYLENE
HL ETHYLENEE
ETHYL
<5.0
ug/L
<5.0
ug/L
4
EPA 624
5
1,2-DICHLOROPROPANE
45.0
ug/L
<5.0
ug/L
4
EPA 624
5
1,3-DICHLORO-
<5.0
ug/L
<5.0
ug/L
4
EPA 624
5
PROPYLENE
ETHYLBENZENE
<5.0
ug/L
<5.0
ug1L
4
EPA 624
5
METHYL BROMIDE
<5.0
ug/L
45.0
ug/L
4
EPA 624
5
METHYL CHLORIDE
<5.0
ug/L
<5.0
ug/L
4
EPA 624
5
METHYLENE CHLORIDE
<5.0
ug/L
<5.0
ug/L
4
EPA 624
5
1, TETRA-
<5.0
ug/L
<5.0
ug/L
4
EPA 624
5
CHLORLOROETFIANE
TETRAC HLORO-
<5.0
ug/L
<5.0
ug/L
4
EPA 624
5
ETHYLE NE
ETHYLE
TOLUENE
<5.0
ug/L
<5.0
ug/L
4
EPA 826
5
EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 6 7550-22. Page 11 of 25

FACILITY NAME AND PERMIT NUMBER:
Tarboro WWTP, NCO020605
PERMIT ACTION REQUESTED:
Renewal
RIVER BASIN:
Tar -Pamlico
Outfall number. 001 (Complete once for each outfall discharging effluent to waters of the United States.)
POLLUTANT
MAXIMUM DAILY DISCHARGE
AVERAGE DAILY DISCHARGE
ANALYTICAL
METHOD
MLIMDL
Conic.
Units
Mass
Units
Cone.
Units
Mass
Units
Number
of
Samples
1,1,1
TRICHLOROETHANE
<5.0
ug/L
<5.0
ug/L
4
EPA 624
5
1,1,2
TRICHLOROETHANE
<5.0
ug/L
<5.0
ug/L
4
EPA 624
5
TRICHLOROETHYLENE
<5.0
ug/L
<5.0
ug/L
4
EPA 624
5
VINYL CHLORIDE
<5.0
ug/L
<5.0
ug/L
4
EPA 624
5
Use this space (or a separate sheet) to provide infomtation on other volatile organic ocmpounds requested by the permit writer
ACID -EXTRACTABLE COMPOUNDS
P-CHLORO-M-CRESOL
<10.0
ug/L
<10.0
ug/L
4
EPA624
10
2-CHLOROPHENOL
<10.0
ug/L
<10.0
ug/L
4
EPA 624
10
2bDICHLOROPHENOL
<10.0
uglL
<10.0
ug/L
4
EPA 624
10
2,4-DIMETHYLPHENOL
<10.0
ug/L
410.0
ug/L
4
EPA 624
10
4,6.DINITRO-0-CRESOL
<60.0
uglL
<50.0
uglL
4
EPA 624
50
2,4-DINITROPHENOL
<50.0
uglL
<50.0
ug/L
4
EPA 624
50
2-NITROPHENOL
<10.0
ug/L
<10.0
ug/L
4
EPA 624
10
4-NITROPHENOL
<50.0
ug/L
<50.0
ug/L
4
EPA 624
50
PENTACHLOROPHENOL
<60.0
ug/L
<50.0
uglL
4
EPA 624
50
PHENOL
<10.0
ug/L
<10.0
ug/L
4
EPA624
10
2.4,6
TRICHLOROPHENOL
<10.0
ug/L
<10.0
ug/L
4
EPA 624
10
Use this space (or a separate sheep to provide information on other acid-etractable compounds requested by the permit writer
BASE -NEUTRAL COMPOUNDS
ACENAPHTHENE
<6.4
uglL
<6.4
ug/L
4
EPA 625
6.4
ACENAPHTHYLENE
<6.4
uglL
<6.4
ug/L
4
EPA 625
6.4
ANTHRACENE
<6.4
uglL
<6.4
ug/L
4
EPA 625
6.4
BENZIDINE
<6.4
ug/L
<6.4
ug/L
4
EPA 625
6.4
BENZO(A)ANTHRACENE
<6.4
ug/L
<6.4
ug/L
4
EPA 625
6.4
8ENZ0(AIPYRENE
<6.4
uglL
<6.4
uglL
4
EPA 625
6.4
EPA Form 3510-2A (Rev. 1-99). Repiaces EPA f0m1s 7550E 6 7550-22. Page 12 of 25

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
Outfall number: 001 (Complete once for each outtall discharging effluent to waters of the United States.)
MAXIMUM DAILY DISCHARGE
AVERAGE DAILY DISCHARGE
POLLUTANT
ANALYTICAL
MLMIDL
Number
COn6
Units
Mass
UnRs
Conc.
Unks
Mass
Units
of
METHOD
Samples
3.4 BENZO-
FLUORANTHENE
ASA
uglL
46A
ug/L
4
EPA 625
6.4
BENZO(GHI)PERYLENE
<6A
ug/L
AGA
ug/L
4
EPA 625
6.4
SENZO(K)
FLUORANTHENE
<6A
ug/L
AGA
ug/L
4
EPA 625
6.4
BIS (2-CHLOROETHOXY)
<6.4
ug/L
AGA
uglL
4
EPA 625
12.8
METHANE
BIS (2-CHLOROETHYL)-
AGA
ug/L
AGA
ug/L
4
EPA 625
6.4
ETHER
BIS (2-CHLOROGO-
<6A
ug/L
AGA
uglL
4
EPA 625
6.4
PROPYL)ETHER
BIS (2-ETHYLHEXYL)
46.4
ug/L
AGA
ug/L
4
EPA 625
6.4
PHTHALATE
PHENYL ETHER
PHENYL ETHER
AGA
ug/L
AGA
uglL
4
FPA 625
6.4
BUTYL BENZYL
AGA
uglL
AGA
ug/L
4
EPA 625
6.4
PHTHALATE
CH NAPHTHALENE
N
AGA
ugfL
<6A
ug/L
4
EPA 625
6.4
4-CHLORPHENYL
AGA
uglL
AGA
ugfL
4
EPA 625
6.4
PHENYLETHER
CHRYSENE
AGA
ugfL
AGA
ugfL
4
EPA 625
6.4
DI-N-BUTYL PHTHALATE
AGA
ugfL
<6A
ug/L
4
EPA 625
6.4
DI-N-OCTYL PHTHALATE
AGA
uglL
AGA
uglL
4
EPA 625
6.4
DISENZO(A,H)
ANTHRACENE
ASA
U91L
AGA
ug/L
4
EPA 625
6.4
1,2-DICHLOROBENZENE
AGA
u91L
<6A
uglL
4
EPA 625
6.4
1,3-DICHLOROBENZENE
AGA
uglL
AGA
ug/L
4
EPA 625
6.4
1,4-DICHLOROBENZENE
AGA
ug/L
AGA
ug/L
4
EPA 625
6.4
3.3-DICHLORO-
46A
uglL
AGA
ug/L
4
EPA625
6.4
BENZIDINE
DIETHYL PHTHALATE
<8A
ug/L
<6A
ugfL
4
EPA 625
6.4
DIMETHYL PHTHALATE
46A
uglL
AGA
uglL
4
EPA 625
6.4
2,4-DINITROTOLUENE
AGA
ug/L
AGA
uglL
4
EPA 625
6.4
2.6-DINITROTOLUENE
AGA
ug/L
AGA
ug/L
4
EPA 625
6.4
1,2-DIPHENYL-
AGA
uglL
AGA
ug/L
4
EPA 625
6.4
HYDRAZINE
EPA Fwn 3510-ZA (Rev. 1-99). Replaces EPA tOMS 7550-6 & 7550-22. Page 13 of 25

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
Outfall number: 001 (Complete once for each outfall discharging effluent to waters of the United Stales.)
MAXIMUM DAILY DISCHARGE
AVERAGE DAILY DISCHARGE
POLLUTANT
ANALYTICAL
MLIMDL
Number
Conc.
Units
Mass
Units
Cone.
Units
Mass
Units
of
METHOD
Samples
FLUORANTHENE
46.4
ug/L
<6.4
ug/L
4
EPA 625
6.4
FLUORENE
46.4
ug/L
<6.4
ug/L
4
EPA 625
6.4
HEXACHLOROBENZENE
46.4
ug/L
<6.4
ug/L
4
EPA 625
6.4
HEXA-
46.4
ug/L
<6.4
ug/L
4
EPA 625
6.4
BUTADJENE
DIENE
HEROCVCLO-
<120
ug/L
412.8
uglL
4
EPA 625
12.8
PENTADIENE
NTADIE
HEXACHLOROETHANE
<6.4
ug/L
<6.4
ug/L
4
EPA 625
6.4
INDENO(1,213-CD)
<6.4
ug/L
<6.4
ug/L
4
EPA 625
6.4
PYRENE
ISOPHORONE
<12.8
ug/L
<12.8
ug/L
4
EPA 625
12.8
NAPHTHALENE
<6.4
ug/L
<6.4
ug/L
4
EPA 625
6.4
NITROBENZENE
<6.4
ug/L
<6.4
ug/L
4
EPA 625
6.4
N-NITROSOOI-N-
<6.4
ug/L
<6.4
ug/L
4
EPA 625
6.4
PROPYLAMINE
N-NITROSODI-
<6.4
ug/L
<6.4
ug/L
4
EPA 625
6A
METHYLAMINE
N-NITROSODI-
<12.8
ug/L
<12.8
ug/L
4
EPA 625
12.8
PHENYLAMINE
PHENANTHRENE
<6.4
ug/L
46.4
ug/L
4
EPA 625
6.4
PYRENE
<6.4
ug/L
<6.4
ug/L
4
EPA 625
6.4
1,2,4-
c6.4
ug/L
<6.4
ug/L
4
EPA 625
6.4
TRICHLOROBENZENE
Use this space (or a separate sheet) to provide information on other base -neutral compounds requested by the permit writer
Use this space (or a separate sheet) to provide information on other pollutants (e.g., pesticides) requested by the permit writer
- _.- -._- _ - i
END OF PART D.
REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE
EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550.6 8 7550-22,

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
SUPPLEMENTAL APPLICATION INFORMATION
PART E. TOXICITY TESTING DATA
POTWs meeting one a more of the following criteria must provide the results of whole effluent toxicity tests for acute or chronic toxicity for each of the
facility's discharge points1) POTWs with a design flaw rate greater than or equal to 1.0 mgd; 2) POTWs with a pretreatment program (or Nose that are
required to have one under 40 CFR Part 403); or 3) POTWs required by the permitting authority to submit data for these parameters.
• At a minimum, these results must include quarterly testing for a 12-month period within the past 1 year using multiple species (minimum of two
species), or the results from four tests performed at least annually in the four and one -had years prior to the application, provided the results
show no appreciable toxicay, and testing for acute metier chronic toxicity, depending on the range of receiving water dilution. Do net include
information on combined sewer overflows in this section. All information reported must be based on data collected through analysis conducted
using 40 CFR Part 136 methods. In addition, this data must comply with OAfOC requirements of 40 CFR Part 136 and other appropriate OA/OC
requirements for standard methods for analytes not addressed by 40 CFR Part 136.
• In adddim submit the results of any other whole effluent toxicity tests from the past four and one -had years If a whole effluent toxicity test
conducted during the past four and one -hag years revealed toxicity, provide any information on the cause of the toxicity or any results of a
toxicity reduction evaluation, if one was conducted.
• If you have already submitted any of the information requested in Part E, you need not submit it again. Rather, provide the information
requested in question E.4 for previously submitted information. If EPA methods were not used, report the reasons for using aftemate methods.
If test summaries are available that contain all of the information requested below, they may be submitted in place of Part E.
If no biomonttoring data is required, do not complete Part E. Refer to the Application Overview for directions on which other sections of the form to
can fete.
E.I. Required Tests.
Indicate the number of whale effluent toxicity tests conducted in the past four and one-half years.
® chronic ❑ acute
E.Y. Individual Test Data. Complete the following chart for each whole effluent toxicity lest conducted in the last four and one-half years. Allow one
column per test (where each species constitutes a lest). Copy this page if more than three tests are being reported.
Test number Test number: Test number.
a. Test information.
Test Species & test method number
Age at initiation of test
Oulfall number
Dates sample collected
Date test started
Duration
b. Give toxicity test methods followed.
Manual title
Edition number and year of publication
Page number(s)
c. Give the sample collection method(s) used. For multiple grab samples. indicate the number of grab samples used.
24-Hour composite
Grab
d. Indicate where the sample was taken in relation to disinfection. (Check all that apply for each.
Before disinfection
After disinfection
After dechlorination
EPA Form 3510-2A (Rev. 1-9e). Replaces EPA forms 7550-6 8 7550-22. Page 15 of 25

FACILITY NAME AND PERMIT NUMBER:
Tarboro WWTP, NCO020605
PERMR ACTION REQUESTED:
Renewal
RIVER BASIN:
Tar -Pamlico
Test number: Test number: Test number:
e. Describe the point in the trestmera process at which the sample was collected.
Sample was collected:
I. For each test, include whether the test was intended to assess chronic toxicity, acute toxicity, or both
Chronic toxicity
Acute toxicity
g. Provide the type of test performed.
Static
Static -renewal
Flow -through
h. Source of dilution water. If laboratory water, specify type; if receiving water, specify source.
Laboratory water
Receiving water
I. Type of dilution water. If salt water, specify 'natural" or type of artificial sea setts or brine used.
Fresh water
Salt water
j. Give the percentage effluent used for all concentrations In the test series.
k. Parameters measured during the test. (State whether parameter meets test method specifications)
PH
Salinity
Temperature
Ammonia
Dissolved oxygen
I. Test Results,
Acute:
Percent survival in 100%
effluent
%
%
%
LC60
95% C.I.
%
%
%
Control percent survival
%
%
%
Other (describe)
EPA Farm 3510-2A (Rev. 1-99). Replaces EPA forms 7550.6 & 7560-22. Page 16 of 25

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
Chronic
NOEC
%
%
%
ICzs
%
%
%
Control percent survival
%
%
%
Other (describe)
m. Quality Control/Quality Assurance.
Is reference toxicant data available?
Was reference toxicant test within
acceptable bounds?
What date was reference toxicant test
I I
I I
l I
run (MM/DDIYYYY)?
Other (describe)
E.3. Toxicity Reduction Evaluation. Is the treatment works involved in a Toxicity Reduction Evaluation?
❑ Yes ❑ No If yes, describe.
E.d. Summary of Submitted Blomoniloring Teat Information. If you have submitted biomomforing test information, or information regarding the
cause of toxicity, within the past four and one-haH years, provide the dates the information was submitted to the permitting authority and a summary
of the results.
Date submitted: / / (MM/DD/YYYY)
Summary of results: (see instructions)
Please see attached summary. --
END OF PART E.
REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE.
EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 & 7550-22. :" I ` r"

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
SUPPLEMENTAL APPLICATION INFORMATION
PART F.INDUSTRIAL USER DISCHARGES AND RCRAICERCLA WASTES
All treatment works receiving discharges from significant industrial users or which receive RCRA,CERCLA, or other remedial wastes must
complete part F.
GENERAL INFORMATION:
F.I. Pretreatment program. Does the treatment works have, or is subject to, an approved pretreatment program?
E Yes ❑ No
F.2. Number of Significant Industrial Users (SIUs) and Categorical Industrial Users (CIUs). Provide the number of each of the folbwing types of
Industrial users that discharge to the treatment works.
a. Number of non -categorical SIUs. 1
b. Number of ClUs. 3
SIGNIFICANT INDUSTRIAL USER INFORMATION:
Supply the following information for each SIU. If more than one SIU discharges to the treatment works, copy questions F.3 through F.8 and
provide the Information requested for each SIU.
F.3. Significant Industrial User Information. Provide the name and address of each SIU discharging to the treatment works. Submit additional pages
as necessary.
Name: Air System Components
Mailing Address: 3301 Main Street
Tarboro, North Carolina 27886
FA. Industrial Processes. Describe all the industrial processes that affect or contribute to the SIU's discharge.
Manufactur no of metal drills to( air cond bonino registers.
F.S. Principal Product(s) and Raw Material(s). Describe all of the principal processes and raw materials that affect or contribute to the SIU's
discharge.
Principal producl(s): Air Duct Registers
Raw material(s): Sheet Metal Pant
F.6. Flow Rate.
a. Process wastewater flow rate Indicate the average daily volume of process wastewater discharge into the collection system in gallons per
day (gpd) and whether the discharge is continuous or intermittent.
40,000 gpd (100% continuous or intermittent)
b. Non -process wastewater flow rate. Indicate the average daily volume of non -process wastewater flow discharged Into the collection system
in gallons per day (gpd) and whether the discharge is continuous or intermittent.
1.000 gpd (100% continuous or intermittent)
F.7. Pretreatment Standards. Indicate whether the SIU is subject to the following:
a. Local limits E Yes ❑ No
b. Categorical pretreatment standards E Yes ❑ No
If subject to categorical pretreatment standards. which category and subcategory?
40 CFR 4 A
EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550E 6 7550-22. Page 18 of 25

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
F.B. Problems at the Treatment Works Attributed to Waste Discharge by the SIU. Has the SIU caused or contributed to any problems (e.g.,
upsets, interference) at the treatment works in the Past three years?
❑ Yes ® No If yes, describe each episode.
N/A
RCRA HAZARDOUS WASTE RECEIVED BY TRUCK, RAIL, OR DEDICATED PIPELINE:
F.9. RCRA Waste. Does the treatment works receive or has it in the past three years received RCRA hazardous waste by truck, rail or dedicated pipe?
❑ Yes ® No (go to F 12)
F.10. Waste transport. Method by which RCRA waste is received (check all that apply):
❑ Truck ❑ Rail ❑ Dedicated Pipe
F.11. Waste Description. Give EPA hazardous waste number and amount (volume of mass, specify units).
EPA Hazardous Waste Number Amount Units
N/A WA N/A
WA NIA NIA
WA WA N/A
CERCLA (SUPERFUND) WASTEWATER, RCRA REMEDIATION/CORRECTIVE ACTION
WASTEWATER, AND OTHER REMEDIAL ACTIVITY WASTEWATER:
F.17. Remediation Waste. Does the treatment works currently (or has it been notified that it will) receive waste from remedial activities?
❑ Yes (complete F.13 through F.15.) N No
F.13. Waste Origin. Describe the site and type of facility at which the CERCLAIRCRAlor other remedial waste originates (or is excepted to ongmate in
the next five years).
NIA
F.14. Pollutants. List the hazardous constituents that are received (or are expected to be received). Include data on volume and concentration, if
known. (Attach additional sheets c necessary.)
N/A
. F.15. Waste Treatment
a. Is this waste treated (or will be treated) prior to entering the treatment works?
❑ Yes ❑ No
If yes, describe the treatment (provide information about the removal efficiency):
NIA
b. Is the discharge for will the discharge be) continuous or intermittent?
❑ Continuous ❑ Intermittent If intenniftent describe discharge schedule.
NIA
END OF PART F.
REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE
EPA Form 3510-2A (Rev. 1.99). Replaces EPA forms 7550-6 & 7550-22. Page 19 of 25

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
SUPPLEMENTAL APPLICATION INFORMATION
PART RINOUSTRIAL USER DISCHARGES AND RCRA/CERCLA WASTES
All treatment works receiving discharges from significant industrial users or which receive RCRA,CERCLA, or other remedial wastes must
complete part F.
GENERAL INFORMATION:
F.I. Pretreatment program. Does the treatment works have, or is subject to, an approved pretreatment program?
S Yes ❑ No
F.2. Number of Significant Industrial Users (SIUs) and Categorical Industrial Users (CIUs). Provide the number of each of the following types of
industrial users that discharge to the treatment works.
c. Number of non -categorical SIUs. 1
d. Number of ClUs. 3
SIGNIFICANT INDUSTRIAL USER INFORMATION:
Supply the following information for each SIU. N more than one SIU discharges to the treatment works, copy questions F.3 through Re and
provide the information requested for each SIU.
F.J. Significant Industrial User Information. Provide the name and address of each SIU discharging to the treatment works. Submit additional pages
as necessary.
Name: Glenoit Fabrics TT Coroorahon
Mailing Address: 3001 N Main Street
Tarboro. North Carolina 27886
FA. Industrial Processes. Describe all the industrial processes that affect or contribute to the SIU's discharge.
Raw Stock Dveino Fiber Preparaaon Silver Knitting Coating/Heat Setting Finishing and Inspection
F.5. Principal Product(s) and Raw Material(s). Describe all of the principal processes and raw materials that affect or contribute to the SIU's
discharge.
Principal pmr l(5) Silver Knitted Fabrics and Coated Base Rua Fabrics
Raw malerial(s): Polvo ophylene Acrylic, Modacrvl c Polyester Nylon Slaple Fibers, Polvp of hvlene & Polyester Yams Acrvkc & Rubber
Coat'ncis
F.6. Flow Rate.
a Process wastewater flow rate Indicate the average daily volume of process wastewater discharge into the collection system in gallons per
day (gpd) and whether the discharge is continuous or intermittent.
188,000 gpd ( continuousor 100% intermittent)
d. Non -process wastewater flow rate. Indicate the average daily volume of non -process wastewater flow discharged into the collection system
in gallons per day (gpd) and whether the discharge is continuous or intermittent.
47.000 gpd (100% continuous or intermittent)
F.7. Pretreatment Standards. Indicate whether the SIU is subject to the folowing:
a. Local limits ® Yes ❑ No
b. Categorical pretreatment standards ® Yes ❑ No
If subject to categorical pretreatment standards, which category and subcategory?
an CFR 410 subpart E
EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 & 7550-22. Page 20 of 25

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
F.B. Problems at the Treatment Works Attributed to Waste Discharge by the SIU. Has the SIU caused or contributed to any problems (e.g.,
upsets, interference) at the treatment works in the past three years?
❑ Yes ® No If yes, describe each episode.
N/A
RCRA HAZARDOUS WASTE RECEIVED BY TRUCK, RAIL, OR DEDICATED PIPELINE:
F.9. I Waste. Does the treatment works receive or has it In the past three years received RCRA hazardous waste by truck. rail or dedicated pipe?
❑ Yes ® No (go to F.12)
F.10. Waste transport Method by which RCRA waste is received (check all that apply).
❑ Truck ❑ Rail ❑ Dedicated Pipe
Rill. Waste Description. Give EPA hazardous waste number and amount (volume or mass, specify units).
EPA Hazardous Waste Number A ou Units
N/A N/A NIA
WA WA WA
N/A N/A WA
CERCLA (SUPERFUND) WASTEWATER, RCRA REMEDIATION/CORRECTIVE ACTION
WASTEWATER, AND OTHER REMEDIAL ACTIVITY WASTEWATER:
F.12. Remedlatlon Waste. Does the treatment works currently (or has it been notified that it will) receive waste from remedial activities?
❑ Yes (complete F.13 through F.15.) ® No
FAIL Waste Origin. Describe the site and type of facility at which the CERCLAIRCRA/or other remedial waste originates for is excepted to ongniate in
the next five years).
NIA
F.14. Pollutants. List the hazardous constituents that are received (or are expected to be received). Include data on volume and concentration, if
known. (Attach addttlonal sheets I necessary.)
N/A
F.15. Waste Treatment
c. Is this waste treated (or will be treated) prior to entering the treatment works?
❑ Yes ❑ No
If yes, describe the treatment (provide information about the removal efficiency):
NIA
d. Is the discharge (or will the discharge be) continuous or intermittent?
❑ Continuous ❑ Intermittent If Intermittent, describe discharge schedule.
NIA
END OF PART F.
N ICH OTHER PARTS
REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMI E WH
OF FORM 2A YOU MUST COMPLETE
EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 8 7560-22. AP

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
SUPPLEMENTAL APPLICATION INFORMATION
PART F.INDUSTRIAL USER DISCHARGES AND RCRA/CERCLA WASTES
All treatment works receiving discharges from significant Industrial users or which receive RCRA,CERCLA., or other remedial wastes must
complete part F.
GENERAL INFORMATION:
F.I. Pretreatment program. Does the treatment works have, or is subject to, an approved pretreatment program?
® Yes ❑ No
F.2. Number of Significant Industrial Users (SIUs) and Categorical Industrial Users (CIUs). Provide the number of each of the following types of
Industrial users that discharge to the treatment works
e. Number of non -categorical SIUs 1
f. Number of ClUs. 3
SIGNIFICANT INDUSTRIAL USER INFORMATION:
Supply the following information for each SIU. R more than one SIU discharges to the treatment works, copy questions F.3 through Re and
provide the information requested for each SIU.
F.3. Significant Industrial User Information. Provide the name and address of each SIU discharging to the treatment works, Submit additional pages
as necessary
Name. The Hillshina Brands Company
Mailing Address: 110 Sara Lee Road
Tarboro Norm Carolina 27886
F.l. Industrial Processes. Describe all the industrial processes that affect or contribute to the SIU's discharge.
Pmducfun of consumable basic food and dessed pastries
F.5. Principal Product(s) and Raw Materlal(s). Describe all of the principal processes and raw materials that affect or contribute to the SIU's
discharge.
Principal product(s): Pound Cake Muffins, s Danish. Laver Cakes
Raw matenal(s): nour. Eggs Milk Sonar, Spices Stabilizers, Colonnos. Flavorings
F.6. Flow Rate.
e. Process wastewater Row rate. Indicate the average daily volume of process wastewater discharge into the collection system in gallons per
day (gpd) and whether the discharge is continuous or intermittent.
300.000 gpd ( continuousor 100% intermittent)
f. Non -process wastewater flow rate. Indicate the average derly volume of non -process wastewater Row discharged into the collection system
in gallons per day (gpd) and whether the discharge is continuous or intermittent.
50,000 gpd (yi continuousor intermittent)
F.7. Pretreatment Standards. Indicate whether the SIU is subject to the following:
a. Local limits ® Yes ❑ No
b. Categorical pretreatment standards ❑ Yes ® No
If subject to categorical pretreatment standards, which category and subcategory?
N/A
EPA Form 3510.2A (Rev. 1-99). Replaces EPA forms 7550.6 6 7550.22. Page 22 of 25

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
F.8. Problems at the Treatment Works Attributed to Waste Discharge by the SIU. Has the SIU caused or contributed to any problems (e.g..
upsets, interference) at the treatment works in the past three years?
❑ Yes N No If yes, describe each episode.
WA
RCRA HAZARDOUS WASTE RECEIVED BY TRUCK, RAIL, OR DEDICATED PIPELINE:
F.9. RCRA Waste. Does the treatment works receive or has 8 in the past three years received RCRA hazardous waste by truck, rail or dedicated pipe?
❑ Yes ® No (go to F 12)
F.10. Waste transport. Method by which RCRA waste is received (check all that apply)
❑ Truck ❑ Rail ❑ Dedicated Pipe
F.11. Waste Description. Give EPA hazardous waste number and amount (volume or mass, specify units).
EPA Hazardous Waste Number Amount Units
WA N/A NIA
WA N/A WA
WA N/A WA
CERCLA (SUPERFUND) WASTEWATER, RCRA REMEDIATIONICORRECTIVE ACTION
WASTEWATER, AND OTHER REMEDIAL ACTIVITY WASTEWATER:
F.12. Remediation Waste. Does the treatment works currently (or has it been notified that It will) receive waste from remedial activities?
❑ Yes (complele F 13 through F.15.) N No
F.13. Waste Origin. Describe the site and type of facility at which the CERCLA/RCRA/or other remedial waste originates (or is excepted to orgniale in
the next five years).
NIA
F.14. Pollutants. List the hazardous constituents that are received (or are expected to be received) Include data on volume and cor centration. if
known. (Attach additional sheets if necessary.)
N/A
F.15. Waste Treatment
e Is this waste treated (or will be treated) prior to entering the treatment works?
❑ Yes ❑ No
If yes, describe the treatment (provide information about the removal efficiency):
N/A
f. Is the discharge (or will the discharge be) continuous or inlemtiltenO
❑ Continuous ❑ Intermittent If intermittent, describe discharge schedule
N/A
END OF PART F.
REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS
r1F FrTRM 9A Ynt I MI IRT rt CIMPI FTF
EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 8 7550-22.

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
SUPPLEMENTAL APPLICATION INFORMATION
PART F.INDUSTRIAL USER DISCHARGES AND RCRAICERCLA WASTES
All treatment works receiving discharges from significant Industrial users or which receive RCRA,CERCLA, or other remedial wastes must
complete part F.
GENERAL INFORMATION:
F.I. Pretreatment program. Does the Treatment works have, or is subject to, an approved pretreatment program?
N Yes ❑ No
F.2. Number of Significant Industrial Users (SIUs) and Categorical Industrial Users (CIUs). Provide the number of each of the following types of
industrial users foal discharge to the treatment works.
g. Number of non -categorical SIUs. 1
h. Number of CIUs. 3
SIGNIFICANT INDUSTRIAL USER INFORMATION:
Supply the following Information for each SIU. If more than one SIU discharges to the treatment works, copy questions F.3 through F.8 and
provide the information requested for each SIU.
F.3. Significant Industrial User Information. Provide the name and address of each SIU discharging to the treatment works. Submit additional pages
as necessary.
Name: Mayo Knitting Mill, Inc.
Mailing Address: P.O. Box 160
Tarboro, North Carolina 27886
FA. Industrial Processes. Describe all the industrial processes that affect a contribute to the SIU's discharge.
Kni",nQ, Dyeing Finishina. Packaging and Shlopino of Hosiery
F.5. Principal Product(s) and Raw Material(s). Describe all of the principal processes and raw materials that affect or contribute to the SIU's
discharge.
Principal product(s): Hos'ery
Raw material(s) : Yarns Dyes Chemicals
F.6. Flow Rate.
g. Process wastewater flow rate. Indicate the average daily volume of process wastewater discharge into the collection system in gallons per
day (gpd) and whether the discharge is continuous or intermittent
250.000 gpd ( conlinu cis or 100% intermittent)
h. Non -process wastewater flow rate. Indicate the average daily volume of non -process wastewater flow discharged into the collection system
in gallons per day (gpd) and whether the discharge is continuous or intermittent.
1.000 gpd (100% continuous or intermittent)
F.7. Pretreatment Standards. Indicate whether the SIU is subject to the following:
a. Local limits ® Yes ❑ No
b. Categorical pretreatment standards ® Yes ❑ No
If subject to categorical pretreatment standards, which category and subcategory?
40 CFR 410 suboad G
EPA Fom, 3510-2A (Rev. 1-99). Replaces EPA forms 7550-(8 7550-22. Page 24 of 25

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
F.B. Problems at the Treatment Works Attributed to Waste Discharge by the SIU. Has the SIU caused or contributed to any problems (e.g.,
upsets, interference) at the treatment works in the past three years?
❑ Yes E No If yes, describe each episode.
WA
RCRA HAZARDOUS WASTE RECEIVED BY TRUCK, RAIL, OR DEDICATED PIPELINE:
F.9. RCRA Waste. Does the treatment works receive or has h in the past three years received RCRA hazardous waste by truck, rail or dedicated pipe?
❑ Yes E No (go to F.12)
F.10. Waste transport. Method by which RCRA waste is received (check all that apply)
❑ Truck ❑ Rail ❑ Dedicated Pipe
F.11. Waste Description, Give EPA hazardous waste number and amount (volume or mass, specify units)
EPA Hazardous Waste Number Amount Units
NIA NIA N/A
WA WA WA
NIA WA NIA
CERCLA (SUPERFUND) WASTEWATER, RCRA REMEDIATION/CORRECTIVE ACTION
WASTEWATER, AND OTHER REMEDIAL ACTIVITY WASTEWATER:
F.12. Remediabon Waste. Does the treatment works currently (or has B been notified that it will) receive waste from remedial activities?
❑ Yes (complete F.13 through F.15.) E No
F.13. Waste Origin. Describe the site and type of facility, at which the CERCLA/RCRA/or other remedial waste originates (or is excepted to origniate in
the next five years).
WA
F.14. Pollutants. List the hazardous constituents that are received (or are expected to be received). Include data on volume and concentration, if
known (Attach additional sheets if necessary.)
N/A
F.15. Waste Treatment.
g. is this waste treated (or will be treated) prior to entering the treatment works?
❑ Yes ❑ No
If yes, describe the treatment (provide information about the removal efficiency):
NIA
h. Is the discharge (or will the discharge be) continuous or intermittent?
❑ Continuous ❑ Intermittent If intermittent, describe Discharge schedule.
N/A
END OF PART F.
REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE
EPA Form 3510.2A (Rev. 1-99). Replaces EPA forms 7550-6 A 7550-22. , �, ' ,Ii LS

Topographic Map &
Process Flow Diagram

C
..
• • S D'lf�!Tas _ � i
;±±ate Fflvy r: mil,
Aft.
a �
tt t
�• �r �1 �� \�� DISCHARGE
` OUTFALL 001
WWTP
Town of Tarboro WWTP
NPDES:NCO020605
Non -Discharge: WQ0002047
Permit Retiuvv: ,
December 2013
A
Feet
0 1,000 2,000
v
I i iL WOOTEN COMPANY

Sludge Management Plan

Sludge Management Plan
Town of Tarboro Wastewater Treatment Plant
NPDES Permit No. NC0020605
Non -Discharge Permit No. WQ0002047
The Town of Tarboro operates a 5.0 mgd modified biological nutrient removal (BNR) plant
which discharges its effluent into the Tar River in the Tar -Pamlico River Basin under NPDES
Permit No. NC0020605. Waste sludge from the primary clarifiers is discharged into two (2)
anaerobic digesters for sludge stabilization while waste activated sludge from the modified BNR
system is pumped to the aerobic sludge digester for stabilization. The anaerobically and
aerobically stabilized sludges are later pumped to the aerated sludge basin for further long term
stabilization and storage prior to disposal by land application. Periodically, supernatant from the
anaerobic digester, aerobic digester, and sludge stabilization/storage basin is withdrawn and
recycled back to the plant headworks for reprocessing. Sludge can also be dewatered using
sludge drying beds prior to disposal by land application.
The stabilized sludge that meets pollutant limits and Class B pathogen reduction and vector
attraction reduction requirements is disposed of in accordance with Non -Discharge Permit No.
WQ0002047. The Class B pathogen reduction requirement is met using Alternative 1 and the
vector attraction reduction requirement is met performing Option 9. Pathogen reduction is
verified through in-house monitoring of fecal coliform bacteria. Sludge is land applied on five
sites (37 fields) totaling 828 acres. The 200 acre Tarboro Farm site is owned by the Town while
the Bourne Farm and Taylor Farm sites are owned by private parties.

Anaerobic Digesters
Sludge Drying Beds
Aerobic Digesters
Town of Tarboro Wastewater Treatment Plant
Process Flow Diagram
Primary Clarifiers
Aerated Sludge Hoidini
Trklding Filters
Secondary Clarillers
\And
Dislnredlon
Cascade
Aeration
�nG><'i L 3grY1,
Sl��s�n

Priority Pollutant Analyses

11!BceAnalytical e
vww.pacebes com
i
April 26, 2010
Mr, Hubert Whitehead
Town of Tarboro
506 Dowd Street
PO Box 220
Tarboro, NC 27886
RE: Project: WASTEWATER EFF
Pace Project No.: 9267233
Dear Mr. Whitehead:
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28604
[phone]
Pace Analytical Services, Inc.
9800 Kinsey Ave. Suite 100
HuntersAile, NC 28076
Enclosed are the analytical results for sample(s) received by the laboratory on April 13, 2010. The
results relate only to the samples included in this report. Results reported herein conform to the
most current NELAC standards, where applicable, unless otherwise narrated in the body of the
report.
[phone]
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All
Microbiological analyses were performed at the laboratory where the samples were received.
If you have any questions concerning this report, please feel free to contact me.
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the w06en consent of Pace Analytical Services, Inc..
/feE
Page 1 of 25

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
• 2225 Riverside Dr. 9800 Kincey Ave. Suits 100
/ _ aceAnalXical Asheville, NC 28804 Huntersville, NC 28078
/ nn.pr-0WSWa
[phone] [phone]
Project: WASTEWATER EFF
Pace Project No.: 9267233
Charlotte Certification IDs
Connecticut Certification #: PH-0104
Florida/NELAP Certification #: E87627
9800 Kincey Ave. - Ste 100 Huntersville, NC 28078
West Virginia Certfiption #: 357
Virginia Certification M 00213
Tennessee Certification M 04010
South Carolina Drinking Water Cart. #: 990060003
South Carolina Certification #: 990060001
Asheville Certification IDs
Connecticut Certification* PH-0106
2225 Riverside Dr. Asheville, NC 28804
Virginia Certification #: 00072
Tennessee Certification #: 2980
South Carolina Certification #: 9DO30001
South Carolina Bioassay Certification #: 99030002
Pennsylvania Certification #: 68-03578
North Carolina Wastewater Certification It: 40
CERTIFICATIONS
Pennsylvania Certification #: 68-00784
North Carolina Wastewater Certification #: 12
North Carolina Field Services Certification #: 5342
North Carolina Drinking Water Certification M 37706
New Jersey Certification M NC012
Louisiana/LELAP Certification #: 04034
Kentucky UST Certification #: 84
North Carolina Drinking Water Certification #: 37712
North Carolina Bioassay Certification #: 9
New Jersey Certification #: NC011
Massachusetts Certification #: M-NC030
Louisiana/LELAP Certification M 03095
Florida/NELAP Certification M E87648
West Virginia Certification #: 356
REPORT OF LABORATORY ANALYSIS
This report shall not he reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
r
Page 2 of 25

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
G,e .1 ,.,./1 hI,,,,/° 2225 Riverside Dr. 98001Cincey Ave. Suite 100
/tl alyfi I Asheville, NC 28804 Huntersville, NC 28078
wwxasaYas.um
[phone] [phone]
ANALYTICAL RESULTS
PmjecL WASTEWATER EFF
Pace Project No.: 9267233
Sample: WASTEWATER EFF Lab ID: 9267233001 Collected: 04/13/10 08:00 Received: 04/13/10 14:45 Mabix Water
Parameters
Results Units
Report Limit
DF
Prepared Analyzed CAS No. Oual
HEM, Oil and Grease
Analytical Method: EPA 1664A
Oil and Grease
NO mg/L
5.0
1
0412611010:19
200.7 MET ICP
Analytical Method: EPA 200.7
Preparation McOwd: EPA 200.7
Antimony
NO ug/L
5.0
1
04/16/1012:35 04/19/1019:23 7440-36-0
Arsenic
NO ug/L
5.0
1
04/16/10 12:35 04/19/10 19:23 7440-38-2
Beryllium
NO ug/L
1.0
1
04/16/1012:35 04/19/1019:23 744D-41.7
Cadmium
NO ug/L
1.0
1
04116/1012:35 04/19/1019:23 744D-43-9
Calcium
10800 ug/L
100
1
D4116/1012:35 04/19/1019:23 7440-7D-2
Chromium
NO ug/L
5.0
1
"16/1012:35 04119/1019:23 7440.47-3
Copper
NO ug1L
5.0
1
04116/1012:35 04119/1019:23 7440-50-8
Lead
NO ug/L
5.0
1
04/16/10 12:35 04119/10 19:23 7439-92-1
Magnesium
2420 ug/L
1D0
1
04116/1012:35 04/1911019:23 7439-95-4
Nickel
NO ug/L
5.D
1
04/16/1012:35 04/1911019:23 7440-02-0
Selenium
NO ug1L
10.0
1
04/16/1012:35 04119/1019:23 7782-49-2
Silver
NO ug/L
5.0
1
04/16/10 12:35 04/19/10 19:23 7440-22-4
Thallium
NO ug/L
10.0
1
04116/1012:35 0411911019:23 7440-28-0
Zinc
NO ug/L
10.0
1
04/1611012:35 04/19/1019:23 7440-66-6
2340E Hardness, Total (Calc.)
Analytical Method: SM 2340B
Total Hardness
37.0 mii
0.65
1
04/19/10 19:23
245.1 Mercury
Analytical Method: EPA 245.1
Preparation Method: EPA 245.1
Mercury
NO ug/L
0.20
1
04/1611010:55 04116/1018:28 7439-97-6
625 MSSV
Analytical Method: EPA 625 Preparation Method: EPA 625
Acenaphthene
NO ug/L
5.1
1
04/20/10 11:30 04/24/10 07:58 83-32-9
Acenaphthylene
NO ug/L
5.1
1
04120/10 11:30 04/24/10 07:58 208-96-8
Anthracene
NO ug/L
5.1
1
04/20/10 11:30 04/24/10 07:58 120-12-7
Benzo(a)anthracene
NO ug/L
5.1
1
04/20/10 11:30 04/24/10 07:58 56-55-3
Benzo(a)pyrene
ND ug/L
5.1
1
04/20/10 11:30 04/24/10 07:58 50-32-8
Benzo(b)fluoranthene
ND ug/L
5.1
1
04120/10 11:30 0424110 07:58 205-99-2
Senzo(g,h,i)perylene
NO ug/L
5.1
1
04/20/10 11:30 04/2411007:58 191-24-2
Benzo(k)fluoranthene
NO uglL
5.1
1
0420/10 11:30 0424/10 07:58 207-08-9
4-Bromophenylphenyl ether
NO ug/L
5.1
1
04/20/10 11:30 0424110 07:58 101-55-3
Butylbenzylphthelate
ND ug/L
5.1
1
042011011:30 0424/1007:58 85-68-7
4-Chlom-3-methylphenol
ND ug/L
5.1
1
04120/10 11:30 04124/1007:58 59.50-7
bis(2-Chlomethoxy)methane
NO ug/L
10.2
1
0412011011:30 04/24/10 07:58 111-91-1
bis(2-Chlomethyl) ether
NO ug/L
5.1
1
04120/10 11:30 04/2411007:58 111-44-4
bls(2-CNomisopropyl) ether
NO ug/L
5.1
1
04/20110 11:30 0424110 07:58 108-60-1
2-Chioromphthalene
NO ug/L
5.1
1
04/20/10 11:30 0424110 07:58 91-58-7
2-Chlorophenol
NO ug/L
5.1
1
04/20/10 11:30 0424110 07:58 95-57-8
4-Ohlorophenylphenyl ether
NO ug/L
5.1
1
04/20/1011:30 0424110 07:58 7005-72-3
Chrysene
NO ug/L
5.1
1
04120/10 11:30 04/24/10 07:58 218-01-9
Dibenz(a,h)anthracene
NO ug/L
5.1
1
04120/10 11:30 0424110 07:58 53.7D-3
1,2-Dichlorobenzene
NO ug/L
5.1
1
04120/10 11:30 04/24/10 07:58 95-50-1
1,3-Dichlorobenzene
NO ug/L
5.1
1
04/20110 11:30 04/24/10 07:58 541-73-1
)ate: 04/26/2010 04:59 PM
REPORT OF LABORATORY
ANALYSIS Page 3 of 25
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without the wriaen consent of,Pace
Analytical Services, Inc
3/l.lOpR.i

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalytical a 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
/ Asheville, NC 28804 Huntersville, NC 28078
werpnN6s.com
(828R54-7176 [phone]
ANALYTICAL RESULTS
Project: WASTEWATER EFF
Pace Project No.: 9267233
Sample: WASTEWATER EFF Lab ID: 9267233001 Collected: 04/13/10 08:00 Received: 04/13/10 14:45 Matrix: Water
Parameters
Results Units
Report Limit
OF
Prepared Analyzed CAS No. Qua[
625 MSSV
Analytical Method: EPA 626 Preparation Method: EPA 625
1,4-Dich[orobenzene
NO uglL
5.1
1
04120/1011:30 04/24/1007:58 106-46-7
3,3'-Dich[orobenzidine
NO ug/L
5.1
1
0412011011:30 04/24/10 07:58 91-94-1
2,4-Dichiorophenol
NO ug/L
5.1
1
04/2011011:30 04/24/10 07:58 120-83-2
Diethylphthalate
NO ug(L
5.1
1
04/20/10 11:30 04/24/10 07:58 84-66-2
2,4-Dimethy[phenol
NO ug/L
10.2
1
04/20/10 11:30 04/24/10 07:58 105-67-9
Dimethylphthalate
NO uglL
5.1
1
04/20/10 11:30 04/24/10 07:58 131-11-3
Di-n-butylphthalate
NO uglL
5.1
1
04/20/10 11:30 04/24/10 07:58 84-74-2
4,6-Dinitro-2-methy[phenol
NO ug/L
2DA
1
04/20/1011:30 04/24/1007:68 534-52-1
2,4-Dinitrophenol
NO ug/L
51.0
1
04/20/10 11:30 04124/10 07:58 51-28-5
2,4-Dinitmtoluene
NO ug/L
5.1
1
04/20/10 11:30 04/24/10 07:58 121-14-2
2,6-Dinitroto[uene
NO ug/L
5.1
1
04/20/10 11:30 04124/10 07:58 606-20-2
DI-nocrylphthalate
NO uglL
5.1
1
04/20110 11:30 04124/10 07:58 11741"
1,2-Diphenylhydrazine
NO ug(L
5.1
1
04/20/1011:30 04/24/1007:58 122-66-7
bis(2-Ethy[hexyl)phtha[ate
NO ug/L
5.1
1
04/20/1011:30 042411007:58 117-81-7
Fluoranthene
NO ug/L
5.1
1
04/20/10 11:30 04/24/10 07:58 20644-0
Fluorene
NO ug/L
5.1
1
04/20/10 11:30 04/24/10 07:58 86-73-7
Hexachlorobenzene
NO ug/L
5.1
1
04/20110 11:30 04124/10 07:58 118-74-1
Hexachlorocyclopentadiene
NO ug/L
10.2
1
04/20/10 11:30 04/24/10 07:58 77-47-4
Hexachloroethane
NO ug/L
5.1
1
04/2D/10 11:30 D4/24/10 07:58 67-72-1
Indeno(1,2,3-cd)pyrene
NO ug/L
5.1
1
0*20/1011:30 04/24/1007:68 193-39-5
Isophorone
NO ug/L
10.2
1
04/20/10 11:30 04/24/10 07:58 78-59-1
Naphthalene
NO ug/L
5.1
1
04/20/10 11:30 04124/10 07:58 91-20-3
Nitrobenzene
NO ug/L
5.1
1
04/20/10 11:30 04/24/10 07:58 98-95-3
2-Nitrophenol
NO ug/L
5.1
1
04/2011011:30 D4/24/1007:58 88-75-5
4-Nitropherlol
NO ug/L
51.0
1
04120/1011:30 04124/10 07:58 100-02-7
N-Nitrasodimethylamine
NO uglL
5.1
1
04/20/1011:30 04/24/10 07:58 62-75-9
N-Nitrosodi-n-propylamine
NO ug/L
5.1
1
04/2011011:30 04124/10 07:58 621-64-7
N-Nitrosodiphenylamine
NO ug/L
10.2
1
04/20/1011:30 04/24/10 07:58 86-30.6
Pentachlorophenol
NO ug/L
25.5
1
0420/1011:3D 04/24/10 07:58 87-86-5
Phenanthrene
NO ug/L
5.1
1
0420/10 11:30 04/24/10 07:58 85-01-8
Phenol
NO ug/L
5.1
1
D4/20/10 11:30 04/24/10 07:58 108-95-2
Pyrene
NO ug/L
5.1
1
04120/1011:30 04/24/10 07:58 129-00-0
2,4,6-Trichlorophenol
NO ug/L
10.2
1
04120/1011:30 04/2411D 07:58 88-W2
Nitrobenzene-d5(S)
70 %
1D-120
1
042011011:30 0412411007:58 4165-60-0
2-Fluorobiphenyl(S)
63 %
15-120
1
04/20/10 11:30 04/24/10 07:58 321-60-8
Terphenyldl4 (S)
78 %
11-131
1
04/20/10 11:30 0424/10 07:58 1718-51-0
Phenold6 (S)
27 %
10-120
1
04120/1011:30 04/24110 07:58 13127-88-3
2-Fluoropherlol (S)
42 %
10-120
1
04/20/10 11:30 04/24/10 07:58 367-12-4
2,4,6-Tribromophemi (S)
74 %
10-137
1
04/20/10 11:30 04/24/10 07:58 118.79.6
624 Volatile Organics
Analytical Method: EPA 624
Acrolein
NO ug/L
100
1
04/1511014:56 107-02-8
Acrylonitrile
NO ug/L
100
1
04/1511014:56 107-13-1
Benzene
NO ug/L
5.0
1
04/15/10 14:56 71-43-2
Bromodichloromethane
NO ug/L
5.0
1
04/15/1014:56 75-27-4
Bromoform
NO ug/L
5.0
1
04/15/1014:56 75-25-2
Bromomethane
NO ug/L
10.0
1
04/15/1014:56 74-83-9
late: 04261201004:59PM
REPORT OF LABORATORY
ANALYSIS Page 4of25
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iAnalytical Services, Inc

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
e 2225 Riverside Dr. 98001Gncey Ave. Suite 100
ceAnalytical Asheville. NC 28804 Huntersville, NC 28078
[phone] [phone]
ANALYTICAL RESULTS
Project: WASTEWATER EFF
Pace Project No.: 9267233
Sample: WASTEWATER EFF Lab ID: 9267233001 Collected: 04/13/1008:00 Received: 0411311014:45 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
624 Volatile Organics Analytical Method: EPA 624
Carbon tetrachloride
ND ug/L
5.0
1
04115/10 14:56 56-23.5
Chlorobenzene
NO ug/L
5.0
1
04115/1014:56 108-90-7
Chloroethane
NO ug/L
10.0
1
04/15/1014:56 75-00-3
2-Chloroethylvinyl ether
NO ug/L
10.0
1
04/15/10 14:56 110-75-8
Chloroform
NO ug/L
5.0
1
04/15/1014:56 67-66-3
Chloromethane
NO ug/L
5.0
1
0411511014:56 74-87-3
Dibromochloromethane
NO ug/L
5.0
1
0411511014:56 124-48-1
1,2-DicNorobenzene
NO ug/L
5.0
1
04115/10 14:56 95-50-1
1,3-Dictgorobenzene
NO ug/L
5.0
1
04115/10 14:56 541-73-1
14-Dichlorobenzene
NO ug/L
5.0
1
04/1511014:56 106-46-7
1,1-Dichloroethane
NO ug/L
5.0
1
04/15/10 14:56 75-34-3
1,2-Dichloroethane
NO ug/L
5.0
1
04115/1014:56 107-06-2
1,1-Dichloroethene
ND ug/L
5.0
1
04/15/1014:56 75-35-4
trans-1,2-Dichlorcethene
NO ug/L
5.0
1
04/15/1014:56 156-60-5
1,2-Dichloropropane
NO ug/L
5.0
1
04/15/1014:56 78-87-5
cis-1.3-Dichloropropene
NO ug/L
5.0
1
04/15/1014:56 10061-01-5
trans-1,3-Dichloropropene
NO ug/L
5.0
1
04/15(10 14:56 10061-02-6
Ethylbenzene
NO ug/L
5.0
1
04/15/10 14:56 100.41.4
Hexachloro-1,3-butadiene
NO ug/L
5.0
1
D4115/1014:56 87-68-3
Methylene Chloride
NO ug/L
5.0
1
04/15110 14:56 75-09-2
Naphthalene
NO ug/L
5.0
1
04115/10 14:56 91-20-3
1,12,2-Tetrachlorcethane
NO ug/L
5.0
1
0411511014:56 79-34-5
Tetrachlorothene
NO ug/L
5.0
1
04/15110 14:56 127-184
Toluene
NO ug/L
5.0
1
0411511014:56 108-88-3
1,2,4-Trichlorobenzene
NO ug(L
5.0
1
04115/10 14:56 120-82-1
1,1,1-Trichloroethane
NO ug(L
5.0
1
04/15/1014:56 71-55-6
1, 1,2-Trichloroethane
ND ug/L
5.0
1
04/15/10 14:56 79-00-5
Trichloroethene
NO ug/L
6.0
1
0411511014:56 79-01-6
Trichlorofluoromethane
NO ug/L
10.0
1
0411511014:56 75-694
Vinyl chloride
ND ug/L
5.0
1
04115/10 14:56 75-01-4
Dibromofluoromethane (S)
105 %
88-113
1
0411511014:56 186853-7
4-Bromofluoroberizene (S)
97 %
86-111
1
04/15/10 14:56 460-004
Toluene-d8 (S)
99 %
92-105
1
04115/10 14:56 2037-26-5
1,2-Dichloroethaned4(S)
104 %
70-130
1
0411511014:56 17060-07-0
2540C Total Dissolved Solids
Analytical Method: SM 2540C
Total Dissolved Solids
358 mg/L
20.0
1
04/14110 19:34
351.2 Total Kjefdahl Nitrogen
Analytical Method: EPA 351.2
Nitrogen, Kjefdahl, Total
1.5 ng/L
0.50
1
04/23/10 11:49 7727.37-9
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
7.2 mg/L
0.10
1
04/13/1023:56
Nitrogen, Nitrite
NO mg/L
0.10
1
04113/10 23:56
Nitrogen, NO2 plus NO3
7.2 mg/L
0.10
1
04/13/10 23:56
late: 041261201004:59 PM REPORT OF LABORATORY ANALYSIS Page 5 of 25
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without the written consent of Pace Analytical Services, Inc..
i�iPi

ceArialyYcal
www Whaa.
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersvllle, NC 20078
[phone]
Project: WASTEWATER EFF
Pace Project No.: 9267233
Sample: WASTEWATER EFF Lab ID: 9267233001 Collected: 04/13/10 08:00 Received: 04/13/10 14:45 Matrix Water
Parameters Results Units Report Unlit OF Prepared Analyzed CAS No. Qual
365.1 Phosphorus, Total
Analytical Method: EPA 365.1
Phosphorus
0.10 mg[L 0.10 1 0412011012:01 7723-14-0
420.4 Phenolics, Total
Analytical Method: EPA 420.4
Phenol
NO ml 0,010 1 04/2011014:57 108-95-2
4500CNE Cyanide, Total
Analytical Method: SM 4500-CN-E
Cyanide
NO mg/L 0.0050 1 04/21/10 17:46 57-12-5
)ate: 04/26(2010 04:59 PM REPORT OF LABORATORY ANALYSIS Page 6 of 25
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oof—f.Pace
yAnalytical Services, Inc..
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Pace Analytical Services, Inc. Paw Arnlytical Services, Inc.
^,,,,/ ' • 22.25 Riverside Dr. 9800 Kinmy Ave. Suite 100
xrwp yfican Asheville, NC 28804 Huntersville, NC 28078
re [phone] [phone]
QUALITY CONTROL DATA
Project: WASTEWATER EFF
Pace Project No.: 9267233
QC Batch: GCSV/7530 Analysis Method: EPA 1664A
QC Batch Method: EPA 16W Analysis Description: 1664 HEM, Oil and Grease
Associated Lab Samples: 9267233001
METHOD BLANK: 433707
Associated Lab Samples: 9267233001
Parameter Units
Oil and Grease mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 5.0 04/2611010:18
LABORATORY CONTROL SAMPLE: 433708
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Oil and Grease mg/L 40 38.4 96 78-114
MATRIX SPIKE SAMPLE: 433709
9267233001 Spike MS MS %Rec
Parameter Units Result Conc. Result % Rec Limits Qualifiers
Oil and Grease mg/L ND 40 38.7 96 78-114
)ate: 04/26/2010 04:59 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
�I 1104�.ii
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Pace Analytical Services, Inc. Paco Analytical Services, Inc.
/� ,,,,/, �, • 2225 Riverside W. 9800 Kincey Ave. Suite 100
CCARBij cal Asheville, NC 28804 Hunlereville, NC 28078
..P�oNMe.mm
[phone] [phone]
QUALITY CONTROL DATA
Project: WASTEWATER EFF
Pace Project No.: 9267233
OC Batch: MPRP/6155
Analysis Method:
EPA 200.7
OC Batch Method: EPA 200.7
Analysis Description:
200.7 MET
Associated Lab Samples:
9267233001
METHOD BLANK: 429678
Matrix: Water
Associated Lab Samples:
9267233001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Qualifiers
Antimony
ug/L
ND
5.0
04/1911018:18
Arsenic
ug/L
NO
5.0
04/19/1018:18
Beryllium
uglL
NO
1.0
04119/1018:18
Cadmium
ug/L
NO
1.0
0411911018:18
Calcium
ug/L
NO
100
04119/1018:18
Chromium
ug/L
NO
5.0
04119/1018:18
Copper
ug/L
NO
5.0
04/19/10 18:18
Lead
ug/L
NO
5.0
04/19/10 18:18
Magnesium
ug/L
ND
100
04119/1018:18
Nickel
ug/L
ND
5.0
04/19/10 18:18
Selenium
ug/L
NO
10.0
04/1911018:18
Silver
ug/L
ND
5.0
04/19/1018:18
Thallium
ug/L
ND
10.0
04/1911018:18
Zinc
ug/L
ND
10.0
04/19/1018:18
LABORATORY CONTROL SAMPLE: 429679
Spike
LCS
LCS %Rec
Parameter
Units
Conc.
Result
%Rec Limits Qualifiers
Antimony
ug/L
500
512
102
85-115
Arsenic
ug/L
500
527
105
86-115
Beryllium
ug/L
500
558
112
85-115
Cadmium
ug/L
500
542
108
85-115
Calcium
ug/L
5000
5380
108
85-115
Chromium
ug/L
500
531
106
85-115
Copper
ug/L
Soo
496
99
85-115
Lead
ug/L
500
533
107
85-115
Magnesium
ug/L
5000
5050
101
85-115
Nickel
ug/L
500
524
105
85-115
Selenium
ug/L
500
525
105
85-115
Silver
ug/L
250
241
96
85-115
Thallium
ug/L
500
502
100
85-115
Zinc
ug/L
500
542
108
85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 429680
429681
MS
MSD
9267441001
Spike
Spike
MS
MSD MS
MSD
% Rec
Parameter
Units Result
Conc.
Conc.
Result
Result %Rec % Rec
Limits RPD Qual
Antimony
ug/L NO
500
500
577
568
115 113
70-130 2
Arsenic
ug/L 96.6
500
500
720
709
125 122
70-130 2
Beryllium
ug/L 4.9
500
500
524
512
104 101
70-130 2
Date: 04/26/2010 04:59 PM
REPORT OF LABORATORY ANALYSIS
Page 8 of 25
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without the written consent of Paco Analytical Services, Inc
V j,en ueyeV •i

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
lytica/ s 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
aceAna
w.�.e lyfi a Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone]
ANALYTICAL RESULTS
Project: , PPA 1/6111
Pace Project No.: 9285382
Sample: Wastewater Eff
Lab ID: 9285382001 Collected: 01/06/11 08:00 Received: 01/06/11 14:45 Matrix: Water
Parameters
Results Units
Report Limit
OF
Prepared Analyzed CAS No. Oual
1631E Mercury, Low Level
Analytical Method: EPA 1631E
Mercury
3.66 ng/L
0.50
1
01/10/11 09:45 01/12/11 12:54 7439-97-6 tg
HEM, Oil and Grease
Analytical Method: EPA 1664A
Oil and Grease
NO mg/L
5.0
1
01/13(11 10:21
200.7 MET ICP
Analytical Method: EPA 200.7 Preparation Method: EPA 200.7
Antimony
6.8 ug/L
5.0
1
01/14111 12:00 01/17/11 15:12 7440.36.0
Arsenic
NO ug/L
5.0
1
01/14/11 12:00 01/17/11 15:12 7440-38-2
Beryllium
NO ug/L
1.0
1
01/14/1112:00 01/17/11 15:12 7440-41-7
Cadmium
ND ug/1-
1.0
1
01114/1112:00 01/17/11 15:12 7440.43-9
Calcium
10400 ug/L
100
1
0111411112:00 01117/11 15:12 7440-7D-2
Chromium
NO ug/L
5.0
1
01/14/11 12:00 01/17111 15:12 7440.47-3
Copper
6.6 ug/L
5.0
1
01/14/11 12:00 01/17/11 15:12 7440-50-8
Lead
NO ug/L
5.0
1
01/14/11 12:00 01/17/11 15:12 7439-92-1
Magnesium
2630 ugli-
100
1
01/14/11 12:00 01/17/11 15:12 7439-95-4
Nickel
NO ug/L
5.0
1
01/14111 12:00 01/17/11 15:12 7440-02-0
Selenium
NO ug/L
10.0
1
01/1411112:00 01117/11 15:12 7782-49-2
Silver
NO ug/L
5.0
1
01/14/1112:00 01/17/11 15:12 7440-224
Thallium
NO ug/L
10.0
1
01/14/1112:00 01/18N111:11 7440-28-0
Zinc
39.2 ug/L
10.0
1
01/14/11 12:00 01117/1115:12 7440-66-6
2340E Hardness, Total (Cale.)
Analytical Method: SM 2340B
Total Hardness
36.8 mg/L
0,65
1
01/14/11 21:17
625 MSSV
Analytical Method: EPA 625 Preparation Method: EPA 625
Acenaphthene
NO ug1L
5.2
1
01/06/11 D9:30 01/10/11 16:02 83-32-9
Acenaphthylene
NO ug/L
5.2
1
01/06/11 09:30 01/10/1116:02 2D8-96-8
Anthracene
ND ug/L
5.2
1
01/06/11 09:30 01/10/11 16:02 120-12-7
Benzo(a)anthracene
ND ug/L
5.2
1
01/06111 09:30 01/10/11 16:02 56-55-3
Benzo(a)pyrene
NO ug/L
5.2
1
01/06/11 D9:30 01/10/11 16:02 5D-32-8
Benzo(b)fluoranthene
NO ug/L
5.2
1
0110&11 09:30 01/10/11 16:02 205-99-2
Benzo(g Xi)perylene
NO ug/L
52
1
01/06/11 09:30 01/10/11 16:02 191-24-2
Benzo(k)fluoranthene
NO ug/L
5.2
1
01/06111 D9:30 01/10/11 16:02 207-OB-9
4-Bromophenylphenyl ether
NO ug/L
52
1
01/06/11 09:30 01/10/11 16:02 101-55-3
Butylbenzylphthalate
NO ug/L
52
1
01/06/11 09:30 01/10/11 16:02 85-68-7
4-Chloro-3-methylphenol
NO ug/L
5.2
1
01/06/11 09:30 01/10/11 16:02 59-50-7
bis(2-Chloroethoxy)melhane
NO ug/L
10.4
1
01/06/11 09:30 01/10/11 16:02 111-91-1
bis(2-CNoroethyl) ether
NO ug/L
5.2
1
01/06111 09:30 01/10/11 16:02 111444
bis(2-Chlomisopropyl) ether
NO ug/L
5.2
1
01/06/11 09:30 01/10/11 16:02 108-60-1
2-Chloronaphthalene
NO ug/L
5.2
1
01/06/11 09:30 01/10111 16:02 91-58-7
2-Chlorophenol
NO ug/L
5.2
1
01/06/11 09:30 01/1D/1116:02 95-57-8
4-Chlorophenylphenyl ether
NO ug/L
5.2
1
01/06111 09:30 01/10/11 16:02 7005-72-3
Chrysene
NO ug/L
5.2
1
01/06/11 09:30 01M0/11 16:02 218-01-9
Dibenz(a,h)anthracene
NO uglL
52
1
01/06/11 09:30 01/10/11 16:02 53-70-3
1,2-Dichlorobenzene
NO ug/L
52
1
01/06/11 09:30 01/10/11 16:02 95-50-1
1,3-Dichlorobenzene
NO ug/L
5.2
1
01/06/11 D9:30 01/10/11 16:02 541-73.1
late: 01/19/2011 09:10AM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced. except in lull,
without the written consent of Pace Analytical Services, Inc..
r yci:
Page 4 of 28

Pace Analytical Sarvkes, Inc. Pace Analytical Services, Inc.
• 2225 Riverside Dr. 9800 Vincey Ave. Suite 100
-
c mlytical Asheville, NC 28804 Huntersville, NC 28078
1 wwwV�Mabs.am
(828)2547176 [phone]
ANALYTICAL RESULTS
Project: PPA 1/6111
Pace Project No.: 9285382
Sample: Wastewater EH Lab ID: 9285382001 Collected: 01/06/11 08:00 Received: 01/06/11 14:45 Matrix Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
1,4-Dichlorobenzene
NO ug/L
5.2
1
01/06/11 09:30 01/10/11 16:02
106-46-7
3,3'-Dichlorobenzidine
NO ug/L
26.0
1
01/W11 09:30 01/10/11 16:02
91-94-1
2,4Dichlorophenol
NO ug/L
5.2
1
01/06/11 09:30 01/10/11 16:02
120-83-2
Diethylphthalate
NO ug/L
5.2
1
01/06/11 09:30 01/10/11 16:02
84-66-2
2,4-Dimethylphenol
NO ug/L
10.4
1
01/06111 09:30 01/10/11 16:02
105.67-9
Dimethylphthalate
NO ug/L
5.2
1
01/06/11 09:30 01110/11 16:02
131-11-3
Di-n-butylphthalate
NO ug/L
5.2
1
01/06/11 09:30 01/10/11 16:02
84-74-2
4,6-Dinitro-2-methylphenol
NO ug/L
20.8
1
01/06/11 09:30 01110/11 16:02
534-52-1
2,4-Dinitrophenol
NO ug/L
52.1
1
01/06/11 09:30 01110/11 16:02
51-28-5
2,4-Dinitrbtoluene
NO uglL
5.2
1
01/06/11 09:30 01/10/11 16:02
121-14-2
2,6-Dinitrotoluene
NO ug/L
5.2
1
01/0&11 09:30 01/10/11 16:02
606-20-2
Di-n-oclylphthalate
NO ug/L
5.2
1
01/06/11 09:30 01/10/11 16:02
117-64-0
1,2-Diphenylhydrazine
NO ug/L
5.2
1
01/06/11 09:30 01/10/11 16:02
122-66-7
bis(2-Ethylhexyl)phtholate
NO ug/L
5.2
1
01/06/11 09:30 01/10/11 16:02
117-81-7
Fluoranthene
NO ug/L
5.2
1
01/06/11 09:30 01/10111 16:02
206-44-0
Fluorene
NO ug/L
5.2
1
01/06111 09:30 01/10/11 16:02
86-73-7
Hexachlorobenzene
NO ug/L
5.2
1
0110611109:30 01/10M116:02
118-74-1
Hexachlorocyclopentadiene
NO ug/L
10.4
1
01/06/11 D9:30 01/10/11 16:02
77-47-4
Hexachlorpethane
NO ug/L
5.2
1
01/06/11 09:30 01/10/1116:02
67-72-1
Inderto(1,'2,3-cd)pyrene
NO ug/L
5.2
1
01/06/11 09:30 01/10/11 16:02
193-39-5
Isophorone
NO ug/L
10.4
1
01/06111 09:30 01/10/11 16:02
78-59-1
Naphthalene
NO uglL
5.2
1
01/06M1 D9:30 01/10/11 16:02
91-20-3
Nitrobenzene
NO ug/L
5.2
1
01/06/11 09:30 01/10/11 16:02
98-95-3
2-Nitrophenol
NO ug/L
5.2
1
01/06/11 09:30 01110/11 16:02
88-75-5
4-Nitropherol
NO ug/L
52.1
1
01/06/11 09:30 01/10/11 16:02
100-02-7
N-Nitrosodimethylamine
NO uglL
5.2
1
01/06111 09:30 01/1011116:02
62-75-9
N-Nltroso-di-n-propylamine
NO ug(L
5.2
1
01/06/11 09:30 01/10/11 16:02
621-64-7
N-Nitrosodiphenylemine
NO ug/L
10.4
1
01/06/11 09:30 01/10/11 16:02
86-30-6
Pentachlorophenol
NO ug/L
26.0
1
01/06/11 09:30 01/10/11 16:02
87-86-5
Phenantlirene
NO ug/L
5.2
1
01/06/11 09:30 01/10/11 16:02
85-01-8
Phenol
NO uglL
5.2
1
01/06/11 09:30 01/10/11 16:02
108-95-2
Pyrene
NO ug/L
5.2
1
01/D6/11 09:30 01/10111 16:02
129-00-0
2,4,6-Tdchlorophenol
NO ug/L
10.4
1
01106/11 09:30 01/10/11 16:02
88-06.2
Nitrobenzerl(S)
57 %
10.120
1
01/O6/11 09:30 01/10/11 16:02
4165-60-0
2-Fluorobiphenyl (S)
71 %
15-120
1
01/D6111 09:30 01/10/11 16:02
321-60-8
Terphenyl-d14(S)
76 %
11-131
1
01/0611109:30 01A0/1116:02
1718-51-0
Phenol-06(S)
24 %
1D-120
1
01/0&1109:30 01/10/11 16:02
13127-88-3
2-Fluomphenol (S)
33 %
1D-120
1
01/0&11 09:30 01/10/11 16:02
367-12-4
2,4,6-Tdbromophenol(S)
97 %
10-137
1
01/06/11 09:30 01/10/11 16:02
118-79-6
624 Volatile Organics Analytical Method: EPA 624
Acrolein
NO uglL 100 1
01/11/11 13:32
107-02-8
Acrylonitrile
NO ug/L 100 1
01/11111 13:32
107-13-1
Benzene
NO ug/L 5.0 1
01/11/11 13:32
71-43-2
Bromodichloromethane
ND ug/L 5.0 1
01/11/11 13:32
75-27-4
Bromofonn
NO ug/L 5.0 1
01/11/11 13:32
75-25-2
Bromomethane
NO ug/L 10.0 1
01/11/11 13:32
74-83-9
)ate: 01/19/2011 09:10 AM
REPORT OF LABORATORY ANALYSIS
Page 5 of 28
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

/1,,,, ,,,,/ Pace Analytical Services, Inc. Pace Analytical Services, Inc.
cI Pi N /Ql�IA/ a 2225 le. NC de Dr. 9600 Kinsey Ave. Suite 078
Asheville. NC 28804 Huntersville, NC 26076
r wwwaaraYDr.orvn
[phone] [phone]
Project: PPA 1/6/11
Pace Project No.: 9285382
Sample: Wastewater Eff
! Parameters
ANALYTICAL RESULTS
Lab ID: 9295382001 Collected: 01/06/11 08:00 Received: 01/06tl l 14:45 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No. Qual
624 Volatile Organics Analytical Method: EPA 624
Carbon tetrachloride
NO uglL
5.0
1
01/11/11 13:32
56-23-5
Chlorobenzene
NO ug/L
5.0
1
01/11/11 13:32
108-90-7
Chloroethane
NO ug4-
10.0
1
01/11/11 13:32
75-M3
2-Chloroethylvinyl ether
NO ug/L
10.0
1
01/11/11 13:32
110-75-8
Chloroform
NO ug/L
5.0
1
01/11/11 13:32
67-66-3
Chloromelhane
NO ug/L
5.0
1
01/11/11 13:32
74-87-3
Dibromochloromethane
NO ugIL
5.0
1
01/11/11 13:32
12448-1
1,2-Dichlorobenzene
NO ug(L
5.0
1
01/11/11 13:32
95-50-1
1,3-Dichlorobenzene
NO ug/L
5.0
1
01/11/11 13:32
541-73-1
1,4-Dichlorobenzene
NO ug/L
5.0
1
01/11/11 13:32
106-46-7
1,1-Dichloroe0lane
NO ug/L
5.0
1
01/11/11 13:32
75-34-3
1,2-Dihloroethane
NO ug/L
5.0
1
01/11/11 13:32
1074)fr2
1,1-Dichloroethene
NO ug/L
5.0
1
01/11/11 13:32
75-35-4
trans-1,2-Dichloroethene
NO uglL
5.0
1
01/11/11 13:32
156-60-5
1,2-Dichloropropane
NO ug/L
5.0
1
01/11/11 13:32
78-87-5
cis-1,3-Dichloropropene
NO ug/L
5.0
1
01/11/11 13:32
10061-01-5
trans-1,3-Dlohloropropene
NO ug/L
5.0
1
01/11/11 13:32
10061-02-0
Ethylbenzene
NO ug/L
5.0
1
01/11/11 13:32
100-41A
Hexachloro-1,3-butadiene
NO uglL
5.0
1
01/11/11 13:32
87-68-3
Methylene Chloride
NO ug/L
5.0
1
01/11/11 13:32
75-09-2
Naphthalene
NO ug/L
5.0
1
01/11/11 13:32
91-2D-3
1,1,2,2-Tetmchloroethane
NO ug/L
5.0
1
01/11/11 13:32
79-34-5
Tetrachloroethene
NO ug/L
5.0
1
01/11/11 13:32
127-18-4
Toluene
NO ug/L
5.0
1
01/11/11 13:32
108-88-3
1,2,4-Trichlorobenzene
NO ug/L
5.0
1
01/11/11 13:32
120-82-1
1,1,1-Triddoroethane
NO ug/L
5.0
1
01/11111 13:32
71-55-6
1,1,2-TricNoroethene
NO ug1L
5.0
1
01/11/11 13:32
79-00-5
Trichloroethene
NO ug/L
5.0
1
01/11/11 13:32
79-01-6
Trichlorofluoromethane
NO ug/L
10.0
1
01/11/11 13:32
75-69-4
Vinyl chloride
NO ug/L
5.0
1
01/11/11 13:32
75-01A
Dibromolluoromethane (S)
103 %
70-130
1
01/11/11 13:32
1868-53-7
4-Bromofluorobenzene (S)
103 %
70-130
1
01/11/11 13:32
460-00-4
Toluened8 (S)
101 %
70-130
1
01/11/11 13:32
2037-265
1,24 ichloroethaned4 (S)
86 %
70-130
1
01/11/11 13:32
17060-07-0
2540C Total Dissolved Solids
Analytical Method: SM 2540C
Total Dissrolved Solids
338 mg1L
25.0
1
01/12/11 14:58
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2
Nitrogen, Kjeldahl, Total
3.0 mgll-
0.50
1
01/18111 12:19
7727-37-9
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
7.9 mg/L
0.10
1
01/07/11 10:55
Nitrogen, Nitrite
NO mg/L
0.10
1
01/07/11 10:55
Nitrogen, NO2 plus NO3
7.9 mg/L
0.10
1
01/07/11 10:55
Date: 01/19/201109:10 AM REPORT OF LABORATORY ANALYSIS Page 6of 28
This report shall not be reproduced, except in full.
without the written consent of PaceAnalyticalAnalytical Services, Inc..

Pace Analytical services, Inc. Pace Analytical Services, Inc.
2225 Riverside Dr. 9800 Kincey Ave. Suite 100
aceAwlytical Asheville. NC 28804 Huntersville, NC 28078
� eewaaceleas mm
[phone] [phone]
ANALYTICAL RESULTS
Project: PPA 1/6/11
Pace Project No.: 9285382
Sample: -Wastewater Eff
Lab ID: 9285382001 Collected:
01/06/11 08:00
Received: 01/1)6/11 14:45 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
365.1 Phosphorus, Total
Analytical Method: EPA 365.1
Phosphorus
0.64 mg/L
0.10
1
01118111 09:56
7723-14-0
420.4 Phenolics, Total
Analytical Method: EPA 420.4
Phenol
ND mg/L
0,010
1
01/09/11 17:46
108-95-2
4500CNE'Cyanide, Total
Analytical Method: SM 4500-CN-E
Cyanide
0.0067 mg/L
0.0050
1
01/16/11 12:16
57-12-5
ate: 01/19/2011 09:10 AM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
JLL�L.
Page 7 of 28

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
� /�/��r • 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
Ce' ""cal Ashevite, NC 28804 Huntersville, NC 28078
a++arP..W." e
[phone] [phone]
QUALITY CONTROL DATA
Project: PPA 1/6111
Pace Project No.: 9285382
QC Batch: CVFS/2334
Analysis Method: EPA 1631 E
QC Batch Method: EPA 1631E
Analysis Description: 1631E Mercury
Associated Lab Samples: 9285382001
METHOD BLANK: 404878
Matrix: Water
Associated Lab Samples: 9285382001
Blank Reporting
r Parameter Units
Result Limit
Analyzed
Qualifiers
Mercury ng/L
ND 0.50
01/1211111:17
METHOD BLANK: 404879
Matrix: Water
Associated Lab Samples: 9285382001
Blank Reporting
Parameter Units
Result Limit
Analyzed
Qualifiers
Mercury ng/L
ND 0.50
01/12/11 12:36
METHOD BLANK: 404880
Matrix: Water
Associated Lab Samples: 9285382001
Blank Reporting
Parameter Units
Result Limit
Analyzed
Qualifiers
Mercury ng/L
ND 0.50
01/12/11 13:53
LABORATORY CONTROL SAMPLE & LCSD: 404881
404882
Spike LCS LCSD
LCS LCSD
%Rec
Max
Parameter Units
Conc. Result Result
%,Rec %Rec
Limits RPD RPD Qualifiers
Mercury ng/L
5 5.26 4.39
105 88
79-121
18 24
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 404883
404884
MS MSD
9285364002
Spice Spike MS
MSD MS
MSD
% Rec
r Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec
Limits RPD Qual
Mercury ng[L 17.9
50 50 64.9
62.2
94 89
75-125 4
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 404885
404886
MS MSD
4041458001
Spike Spike MS
MSD MS
MSD
%Rec
Parameter Units Result
Conc. Conc. Result
Result %Rec %Rec
Limits RPD Qual
Mercury ng/L 47.7
200 200 220
239
86 96
75-125 8
)ate: 01/19/2011 09:10 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
f I IGidi:� c
Page 8 of 28

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
' 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
aceMalytical Asheville, NC 28804 Huntersville, NC 28078
. [phone] [phone]
QUALITY CONTROL DATA
Project PPA 1/6/11
Pace Project No.: 9285382
OC Batch: GCSV/9D47 Analysis Method: EPA 1664A
OC Batch Method: EPA 1664A Analysis Description: 1664 HEM, Oil and Grease
Associated Lab Samples: 9285382001
METHOD BLANK: 550882
Matrix:
Water
Associated Lab Samples: 9285382001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Oil and Grease
mg/L
ND
5.0
01/13111 10:16
LABORATORY CONTROL SAMPLE:
550883
Spike
LCS
1-CS %Rec
Parameter
Units
Conc.
Result
% Rao Limits Qualifiers
08 and Grease
mg/L
40
38.1
95 78-114
MATRIX SPIKE SAMPLE: 550884
9285382001 Spike MS MS % Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Oil and Grease rrg/L ND 40 39.2 97 78-114
)ate: 01/19/2011 09:10 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent
to�ofPace
irAnalytical Services. Inc..
Page 9 of 28

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
• 2225 Riverside Dr. 9800 Kinsey Ave. Suke 100
ace Analytical Asheville, NC 28804 Huntersville, NC 2807E
mvw.pecele0s.ccm
[phone] [phone]
QUALITY CONTROL DATA
Project: PPA 1/6111
Pace Project No.: 9285382
OC Batch: MPRP/7718
Analysis Method:
EPA 200.7
QC Batch Method: EPA 200.7
Analysis Description:
2001 MET
Associated Lab Samples: 9285382001
METHOD BLANK: 551445
Matrix: Water
Associated Lab Samples: 9285382001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Qualifiers
Antimony
ug/L
ND
5.0
0111711115:09
Arsenic
ug/L
ND
5.0
01/1711115:09
Beryllium
ug/L
ND
1.0
01/1711115:09
Cadmium
ug/L
NO
1.0
01/1711115:09
Calcium"
ug/L
NO
100
01/17/1115:09
Chromium
ug/L
NO
5.0
01117/1115:09
Copper
ug/L
NO
5.0
01/1711115:D9
Lead
ug/L
NO
5.0
01117/1115:D9
Magnesium
ug/L
NO
100
01117/1115:09
Nickel
ug/L
ND
5.0
01/17/1115:09
Selenium
ug/L
NO
10.0
01117/1115:09
Silver
ug/L
ND
5.0
01117/1115:09
Thallium
ug/L
ND
10.0
01/17/1115:09
Zinc
ug/L
NO
10.0
01/1711115:09
LABORATORY CONTROL SAMPLE:
551446
Spike
LCS
LCS %
Rec
Parameter
Units
Conc.
Result
%Rec Limits Qualifiers
Antimony
ug/L
500
488
98
85-115
Arsenic
ug/L
500
495
99
85-115
Beryllium
ug/L
500
603
101
85-115
Cadmium
ug/L
500
505
101
85-115
Calcium !
ug/L
5000
4950
99
85-115
Chromium
ug/L
500
499
100
85-115
Copper
ug/L
500
487
97
85.115
Lead
ug/L
500
507
101
85-115
Magnesium
ug/L
5000
4930
99
85.115
Nickel
ug/L
500
499
100
85-115
Selenium
ug/L
500
494
99
W115
Silver
ug/L
250
251
100
85-115
Thallium
ug/L
500
486
97
85-115
Zinc
ug/L
5D0
504
101
85-115
MATRIX SPIKE SAMPLE:
551447
9285373001
Spike
MS
MS
%Rec
Parameter
Units
Result
Conc.
Result
%Rec
Limits Qualifiers
Antimony
ug/L
ND
500
5D6
101
70-130
Arsenic
ug/L
NO
50D
525
105
70-130
Beryllium
ug/L
NO
5D0
518
104
70-130
Cadmium
ug/L
NO
500
508
102
70.130
)ate: 01/1'9/2011 09:10 AM REPORT OF LABORATORY ANALYSIS Page 10 of 28
This report shall not be reproduced, except in full
without the written conseof PPaam�\ Analytical Services. Inc
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Pace Analytical Services, Inc. Pace Analytical Services, Inc.
s 2225 Riverside Dr. 9800 Kircey Ave. Suite 100
aceAnalytical Asheville, NC 28804 Huntersville, NC 28078
w.,. .�
[phone] p04J875-9092
Project: PPA 1011
Pace Project No.: 9285382
1
SAMPLE DUPLICATE: 551448
Parameter Units
Zinc U91L
QUALITY CONTROL DATA
9285382001 Dup
Result Result RPD Qualifiers
39.2 38.5 2
SAMPLE DUPLICATE. 551450
Parameter
Units
9285406002
Result
Dup
Result RPD Qualifiers
Antimony
ug/L
ND
ND
Arsenic
ug/L
ND
ND
Beryllium
ug/L
ND
.381
Cadmium
ug/L
ND
ND
Calcium
ug/L
ND
46,91
Chromium
ug/L
ND
1.21
Copper
ug/L
11.1
12.0 8
Lead
ug/L
ND
ND
Magnesium
ug/L
ND
8.81
Nickel f
ug/L
ND
ND
Selenium
ug/L
ND
ND
Silver
ug/L
ND
.341
Thallium
ug/L
ND
ND
Zinc
ug/L
ND
1.51
ate: 01/19/2011 09:10 AM REPORT OF LABORATORY ANALYSIS
This report shall not 6e reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 12 of 28

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
PaceAnalytica/ a 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
Asheville, NO 28804 Huntersville, NO 28078
i www.pscNseemm
�I (828)2547176 [phone]
QUALITY CONTROL DATA
Project: r PPA 116/11
Pace Project No.: 9285382
QC Batch: OEXT/12335 Analysis Method: EPA 625
QC Batch Method: EPA 625 Analysis Descripflon: 625 MSS
Associated Lab Samples: 9285382001
METHOD BLANK: 549006
Associated Lab Samples:
" Parameter
9285382001
Matrix:
Blank
Units Result
Water
Reporting
Limit
Analyzed
1,2-Dichlorobenzene
ug/L
NO
5.0
01107/1116:21
1,2-Diphenylhydrazine
ug/L
NO
5.0
01/07/11 16:21
1,3-Dichlorobenzene
ug/L
NO
5.0
0110711116:21
1,4-Dichlorobenzene
u91L
NO
5.0
01/07/11 16:21
2,4,6-Trichlorophenol
ug/L
NO
10.0
01/07/11 16:21
2,4-DlcNorophenol
ug/L
NO
5.0
01/07/11 16:21
2,4-Dimethylphenol
ug/L
NO
10.0
01/07/11 16:21
2,4-Dinitrophenol
ug/L
NO
50.0
01/07/11 16:21
2,4-Dinitrotoluene
ug/L
NO
5.0
01107/111621
2,6-Dinitrotoluene
ug/L
NO
5.0
01/071111621
2-Chloronaphthalene
ug/L
NO
5.0
01/0711116:21
2-Chlorophenol
ug/L
NO
5.0
01/07/11 16:21
2-Nitrophenol
ug/L
NO
5.0
01/07/11 16:21
3,T-Dichlorobenzidine
ug/L
NO
25.0
01/07/11 16:21
4,6-Dinitro-2-methylphenol
ug/L
NO
20.0
01/0711116:21
4-Bromophenylphenyl ether
ug/L
NO
5.0
01/07/11 16:21
4-Chlwo3methylphenol
uglL
NO
5.0
01107/1116:21
4-Chlorophenylphenyl ether
uglL
NO
5.0
01/07/11 16:21
4-Nitrophenol
ug/L
NO
50.0
01107/1116:21
Acenaphthene
ug/L
NO
5.0
01/07/11 16:21
Acenaphthylene
ug/L
NO
5.0
01/07/11 16:21
Anthracena
ug/L
NO
5.0
01/07/11 16:21
Senzo(a)anthracene
ug/L
NO
5.0
01/07/11 16:21
Benzo(a)pyrene
ug/L
NO
5.0
01/07/11 16:21
Benzo(b)fluoranthene
ug/L
NO
5.0
01/07/11 16:21
Benzo(g,h,i)perylene
ug/L
NO
5.0
01107/1116:21
Benzo(k)fluoranthene
ug/L
NO
5.0
01/07/11 16:21
bis(2-Chloroethoxy)methane
ug/L
NO
10.0
01/07/11 16:21
bis(2-Chl6roethyl) ether
ug/L
NO
5.0
01/071`11 16:21
bis(2-Chloroisopropyl) ether
ug/L
NO
5.0
01/07/11 16:21
bis(2-Ethylhexyl)ph1halate
ug/L
NO
5.0
01/07/1116:21
Butylbenzylphthalate
ug/L
NO
5.0
01/07/11 16:21
Chrysene
ug/L
NO
5.0
01107/1116:21
Di-n-butylphthalate
ug/L
NO
5.0
01/07/11 16:21
Di-noctylphthalate
ug/L
NO
5.0
01/07/11 16:21
Dibenz(a,h)anthracene
ug/L
NO
5.0
01/07/11 16:21
Diethylphthalate
ug/L
NO
5.0
01107/1118:21
Dimethylphthalate
ug/L
NO
5.0
01107/1116:21
Fluoranttfene
ug/L
NO
5.0
0110711116:21
Fluorene
ug/L
NO
5.0
01107/1116:21
Hexachlorobenzene
ug/L
NO
5.0
01/0711116:21
Hexachlorocyclopentadiene
ug/L
NO
10.0
01/07/11 16:21
Hexachloroethene
ug/L
NO
5.0
01/07/11 16:21
)ate: 01/191201109:10AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical
Services, Inc..
Qualifiers
Page 13 of 28

Pace Analytical services, Inc. Pace Analytical Services, Inc.
1 ,► s 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
CeAwl `im, Asheville, NC 28804 Huntersville, NC 28078
www.wmleexavn
i (828)2547176 [phone]
QUALITY CONTROL DATA
Project: PPA 1161l1
Pace Project No.: 9285382
METHOD BLANK: 549D06 Matrix: Water
Associated Lab Samples: 9285382001
Parameter
Units
Blank
Result
Reporting
Limit
Analyzed Qualifiers
Indeno(1,2,3-cd)pyrene
ug/L
ND
5.0
01/07/11 16:21
Isophorone
ug/L
NO
10.0
01/07/1116:21
N-Nitrow-di-n-propylamine
ug/L
NO
5.0
01/07/1116:21
N-Nitrosodimethylamine
uglL
NO
5.0
01/07/11 16:21
N-Nitrosodiphenylamine
ug/L
ND
10.0
01/07/1116:21
Naphthalene
ug/L
ND
5.0
01107/1116:21
Nitrobenzene
u91L
NO
5.0
01/07/1116:21
Pentachlorophenol
ug/L
ND
25.0
01/07/1116:21
Phenanlhrene
ug/L
ND
5.0
01107/1118:21
Pherlol r
ug/L
ND
5.0
01/07/1116:21
Pyrene
ug/L
ND
5.0
01/07/1116:21
2,4,6-Tribromopherlol(S)
%
70
1D-137
01/07/11 16:21
2-Fluorobiphenyl (S)
%
55
15-120
01/07/11 16:21
2-Fluoropheriol(S)
%
27
10-120
DI/07/11 16:21
NitrobenzeneE5 (S)
%
44
10-120
01/07/11 16:21
Phenol-d6(S)
%
18
10-120
01/07/1116:21
Terphenyl-d14 (S)
%
74
11-131
01/07111 16:21
LABORATORY CONTROL SAMPLE: 549007
Spike
LIDS
LIDS
% Roe
Parameter
Units
Conc.
Result
%Rao
Limits Qualifiers
1,2-Dichlorobenzene
ug/L
50
27.3
55
32-129
1,2-Dipheny1hydrazine
ug/L
50
31.6
63
25-150
1,343iohlorobenzene
ug/L
50
25.4
51
1-172
1,4-Dichlorobenzene
ug/L
50
26.1
52
20-124
2,4,6-TricNorophenol
ug/L
50
41.5
93
37-144
2,4-Dichlorophenoi
ug/L
50
38.7
77
1-191
2,4-Dimepylphenol
ug/L
50
34.3
69
32-119
2,4-Dinitrophenol
ug/L
250
147
59
1-181
2,4-Dinitrotoluene
ug/L
50
44.0
88
39-139
2,640initrotoluene
ug/L
50
39.6
79
5D-158
2-Chloronaphthalene
ug/L
5D
38.6
77
60-118
2-Chlorophenol
ug/L
50
33.2
66
23-134
2-Nitrophenol
ug/L
50
35.4
71
29-182
3,3'-Dichlorobenzidine
ug/L
100
64.3
64
1-262
4,6-Dinitro-2-methylpherwl
ug/L
100
77.9
78
1-181
4-Bromophenylphenyl ether
ug/L
50
34.9
70
53-127
4-Chloro-3-methylpheral
ug/L
100
71.4
71
22-147
4-Chlorophenylphenyl ether
ug/L
50
36.7
73
25-158
4-Nitrophenol
ug/L
250
86.7
35
1-132
Aoenaphlhene
ug/L
50
39.0
78
47-145
Acenaphlhylene
ug/L
50
37.9
76
33-W
Anlhracene
ug/L
50
40.0
8o
1-166
Benzo(a)anthracene
ug/L
50
39.0
78
33-143
Benzo(a)pyrene
ug/L
50
35.6
71
17-163
)ate: 01/191201109:10AM REPORT OF LABORATORY ANALYSIS Pap 14of28
This report shall not t» reproduced, except in full,
without the written consent
of �Pace
Analytical Services, Inc..
vLl l Y�ll.^l.

aceAnalytical
wmv.yacelebs.cwm
.
Project: PPA 1/6/11
Pace Project No.: 9285382
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 29804
[phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 VOncey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
549007
Spike
LCS
LCS
% Roe
' Parameter
Units
Cone.
Result
%Rec
Limfis
Qualifiers
Benzo(b)fluoranthene
ug/L
50
37.0
74
24-159
Benzo(g,h,i)perylene
ug/L
50
40.3
81
1-219
Benzo(k)fluoranthene
ug/L
50
35.7
71
11-162
bis(2-Chioroethoxy)methane
ug/L
50
31.1
62
33-184
bis(2-Chloroethyl) ether
ug/L
50
31.0
62
12-158
bis(2-Chloroisopropyl) ether
ug/L
50
28.7
57
36-166
bis(2-Ethylhexyl)phthalate
ug/L
50
33.4
67
8-158
Butyibenzylphthalate
ug/L
50
33.3
67
1-152
Chrysene
ug/L
50
38.8
78
17-168
Di-n-butylphthalate
ug/L
50
36.2
72
1-118
Di-n-octylphthalate
ug/L
50
32.5
65
4-146
Dibenz(a,h)anthracene
ug/L
50
39.3
79
1-227
Diethylphthalate
ug/L
50
36.3
73
1-114
Dimethylphthalete
ug/L
50
34.6
69
1-112
Fluoranthene
ug/L
50
43.5
87
26-137
Fluorene
ug/L
50
40.1
80
59-121
Hexachlorobenzene
ug/L
50
39.7
79
1-152
Hexachlorocyclopentadiene
ug/L
50
23.9
48
25-150
Hexachloroethane
ug/L
50
21.2
42
40-113
Indeno(1,2,3-cd)pyrene
ug/L
50
39.7
79
1-171
Isophorone
ug/L
50
32.9
66
21-196
N-Nitros"i-n-propylamine
ug/L
50
31.7
63
1-230
N-Nitrosodimelhylamine
ug/L
50
21.6
43
25-150
N-Nitrosodiphenylamine
ug/L
50
35.3
71
25-150
Naphthalene
ug/L
50
33.6
67
21-133
Nitrobenzene
ug/L
50
31.6
63
35-180
Pentachlorophenol
ug/L
100
91.1
91
14-176
Phenanthrene
ug/L
50
39.2
78
54-120
Phenol !
ug/L
50
14.6
29
5-112
Pyrene
ug/L
50
37.9
76
52-115
2,4,6-Tribromophenol (S)
%
99
10-137
2-Fluorobiphenyl (S)
%
77
15-120
2-Fluorophenol(S)
%
40
10-120
Nitrobenzen"S (S)
%
65
10-12D
Phenol-d6 (S)
%
27
10-120
Terphenyl-d14(S)
%
76
11-131
MATRIX)SPIKE & MATRIX SPIKE DUPLICATE:
549008
549009
MS
MSD
9285174001
Spike
Spike
MS
MSD
MS
MSD
%Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result %Rae
%Rec
Limits
RPD Qual
1,2-Dichlorobenzene
ug/L
NO
100
100
57.7
58.3
58
58
32-129
1
1,2-Diphenythydrazine
ug/L
NO
100
100
71.2
74.2
71
74
25-150
4
1,3-Dichlorobenzene
ug/L
NO
100
100
54.4
55.6
54
56
1-172
2
1,4-Dichlombenzene
ug/L
NO
100
100
55.8
58.5
56
57
20-124
1
2,4,6-TncNorophenol
ug/L
NO
100
100
91.0
91.2
91
91
37-144
0
2,4-Dich19rophenol
ug/L
NO
100
100
75.1
81.4
75
81
1-191
8
Date: 01/19/2011 09:10 AM
REPORT OF
LABORATORY ANALYSIS
Page 15 o128
This report shall not be reproduced, except in full,
without the wriaen conse((nt�f.t �of PPPaar�ccee AnalyOcaI Services, Inc
:(LL�O6.15

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Pace Analytical Services, Inc. Paw Analytical Services, Inc.
Ce l /cal • 2225 Riverside Dr. 9800 Kinwy Ave. Suite 100
Asheville, NC 28804 Huntersvills, NC 28078
ewapowisim e
(828)2547176 [phone]
QUALITY CONTROL DATA
Project: PPA 1011
r
Pace Project No.: 9285382
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 549008
MS
9285174001 Spike
Parameter
Units Result Cone.
Pyrene
ug(L ND 100
2,4,8•Tribromophenol (S)
%
2-Fluorot9phenyl (S)
%
2-Fluorophenol (S)
%
Nitrobenzene-d5 (S)
%
Phenol-d8 (S)
%
Terphenyl-014 (S)
%
)ate: 01/19/2011 09:10 AM
MSD
Spike
MS
MSD MS
Conc.
Result
Result %Rec
100
77.9
T7.8 78
98
81
51
71
40
77
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced. except in full,
without the written conseof Pace Analytical Services, Inc..
MSD % Rec
%Rec Limits RPD
78 52-115 0
94 10-137
75 15-120
51 10-12D
89 10-120
39 10-120
75 11-131
Qual
Page 17 of 28

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
�/�/r� /�� a 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
Ce' mlji i`^"' Asheville. NC 28804 Huntersville. NC 28078
.w«pisabbi orn
(828)2547/76 [phone]
QUALITY CONTROL DATA
Project PPA 116/11
Pace Project No.: 9285382
QC Batch: MSW13700
Analysis Method: EPA 624
QC Batch Method: EPA 624
Analysis Description: 624 MSV
Associated Lab Samples: 9285382001
METHOD BLANK 550246
Matrix: Water
Associated Lab Samples: 9285382001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Quallfiers
1,11-Tdchloroethane
ug/L
ND
5.0
01/11/1110:48
1, 1,2,2-Tetrachloroethane
ug/L
ND
5.0
01/1111110:48
1,1,2-Tdchloroethane
ug/L
ND
5.0
01/11/1110:48
1,1-Dichloroethane
ug/L
ND
5.0
01/1111110:48
1,1-Dichloroethene
ug/L
NO
5.0
01/11/1110:48
1,24-TridNorobenzene
ug/L
ND
5.0
01/1111110:48
1,2-Dichlombenzene
ug/L
ND
5.0
0111111110:48
1,2-0khl6rcethane
ug/L
ND
5.0
0111111110:48
1,2-Dichloropropane
ug/L
NO
5.0
0 1 /11111 10:48
1,3-0bNoroberzene
ug/L
NO
5.0
01/1111110,48
1,4-Dichloroberzene
ug/L
NO
5.0
01/11/1110:48
2-Chloroethylvinyl ether
ug/L
NO
10.0
01/11/11 10:48
Acrolein
ug/L
ND
100
01111/1110:48
Acrylonhdle
ug/L
ND
100
01/11/11 10:48
Benzene
ug/L
NO
5.0
01/1111110:48
Bromodichloromethane
ug/L
NO
5.0
01/11/1110:48
Brontoform
ug/L
NO
5.0
01/11/1110:48
Bromom4thane
uglL
NO
10.0
01111/1110:48
Carbon tetrachloride
ug/L
NO
5.0
01/11/1110:48
Chlorobenzene
ug/L
NO
5.0
01/11111 10:48
Chloroethane
uglL
NO
10.0
0111111110:48
Chloroform
ug/L
ND
5.0
0111111110:48
Chloromethane
ug1L
ND
5.0
01/1111110:48
cis-1,3-Dichloropropene
ug/L
ND
5.0
01/11/1110:48
Dibromochloromethane
ug/L
ND
5.0
01/11/1110:48
Ethylbenzene
ug/L
NO
5.0
01111/1110:48
Hexachloro-1,3-butadiene
ug/L
ND
5.0
01/1111110:48
Methylene Chloride
ug/L
NO
5.0
01/11/11 10:48
Naphthalene
ug/L
NO
5.0
0111111110:48
Tetrachloroethene
ug/L
NO
5.0
0111111110:48
Toluene
ug/L
NO
5.0
01/11/1110:48
trans-1,2-Dichloroethene
ug/L
NO
5.0
01/11/1110:48
trans-1,3-Dichloropropene
ug/L
ND
5.0
01111/1110:48
Trichloroethene
ug/L
NO
5.0
01/11/11 10:48
Trichlorofluoromethane
ug/L
NO
10.0
01/11/1110:48
Vinyl chloride
ug/L
ND
5.0
01/11/11 10:48
1,2-Dichloroethane-d4 (S)
%
90
70-130
01/11/11 10:48
4-Bronaffuorobenzene(S)
'Y
111
70-130
01/11/1110:48
Dibromoflwrometharle (S)
%
106
70-130
01/11/11 10:48
Toluened8 (S)
%
97
70-130
01/11/11 10:48
)ate: 01/19/2011 09:10 AM REPORT OF LABORATORY ANALYSIS Page 18 of 28
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
�:

Pace Analytical Services, Inc. Pecs AnalyBical Services, Inc.
�
• 2225 Riverside tic. 9800IOrmy Ave. Sule 100
CeAwl 1 r`«I Asheville. NC 28804 Huntersville, NC 28078
vmm:pec,MWx.cvn
[phone] [phone]
QUALITY CONTROL DATA
Project: PPA 1/6111
Pace Project No.: 9285382
LABORATORY CONTROL SAMPLE: 550247
Spike
LCS
LCS
%Rec
Parameter
Units
Conc.
Result
%Rao
Limits Qualifiers
1, 1,1-Triohloroethane
ug/L
20
18.9
95
52-162
1, 12,2-Tetrachloroethane
ug/L
20
18.7
94
46-157
1, 1,2-Trichlorcethane
ug/L
20
24.3
121
52-150
11-Dichioroethane
ug/L
20
18.8
94
59-155
1,1-Dichloroethene
ug/L
20
18.2
91
1-234
1,2,4-Tdchlorobenzene
ug/L
20
22.3
111
70-130
1,2-Dichloroberizene
ug/L
20
21.1
105
18-190
1,2-Dichloroethane
ug/L
20
16.0
80
49-155
1,2-Dichbropropane
ug/L
20
20.9
104
1-210
1,3-Dichlgmbenzene
ug/L
20
21.2
106
59-156
1,4-Dichlorober¢eoe
ug/L
20
21.3
107
18-190
2-Chloroethylvinyl ether
ug/L
40
24.9
62
1-305
Acrolein
ug/L
100
95.21
95
15-152
Acrylonitrile
ug/L
100
89.21
89
75-132
Benzene
ug/L
20
21.5
108
37-151
Bromodicltloromethane
ug/L
20
19.9
99
35-155
Bromoform
ug/L
20
21.6
108
45-169
Bromomethane
ug/L
20
11.2
56
1-242
Carbon tetrachloride
ug/L
20
%9
99
70-140
Chlorobepzene
ug/L
20
22.0
110
37-160
Chloroethane
ug/L
20
16.8
84
14-230
Chloroform
ug/L
20
20.1
101
51-138
Chloromethane
ug/L
20
11.5
57
1-273
cis-1,3-Dichloropropene
ug/L
20
20.2
101
1-227
Dibromochloromethane
ug/L
20
18.2
91
53-149
Ethylbenzane
ug/L
20
20.5
102
37-162
Hexachloro-1,3-butadiene
ug/L
20
23.0
115
70-130
Methylene Chloride
ug/L
20
17.1
85
1-221
Naphthalene
ug/L
20
20.2
101
70-130
Tetrachloroethene
ug/L
20
22.5
113
64-148
Toluene
ug/L
20
22.7
114
47-150
trans-1,2-Dicldoroethene
ug/L
20
18.2
91
54-156
trans-1,3-Dichlompropene
ug/L
20
18.5
93
17-183
Trichloroethene
ug/L
20
24.1
121
71-157
Trichlorofluoromethane
ug/L
20
15.1
76
17-181
Vinyl chloride
ug/L
20
15.8
79
1-251
1,2-Dichloroethan"4(S)
%
67
70-130 J(SO)
4-Bromofluorobenzene (S)
%
105
70-130
Dibromofluoromethane (S)
%
88
70-130
Toluene-48 (S)
%
101
70-130
MATRIX SPIKE 8 MATRIX SPIKE DUPLICATE: 550248
550249
MS
MSD
9285382001
Spike
Spike MS
MSD
MS MSD
%Rec
Parameter
Units Result
Conic.
Conc. Result
Result % Roo % Rec
Limits RPD Qual
1, 1, 1-Trichloroethane
ug/L NO
20
20 20.4
21.0
102 105
46-171 3
1,12,2-Tetrachloroethane
ug/L NO
20
20 24.5
25.4
122 127
73-159 4
)ate: 011IQ12011 09:10 AM
REPORT OF LABORATORY ANALYSIS
Page 19 of 28
This report anal not be reproduced, except in full,
without the written conse({ntF�t of rPam Analytical Services, Inc
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Pace Analytical Services, Inc. Pace Analytical Services, Inc.
• 2225 Riverside Dr. 9800 Kincey Ave. Smte 100
ace Analytical Asheville, NC 28804 Hunters, le. NC 28078
' NeW°'0 care [phone] [phone]
Project: PPA 116/11
Pace Project No.: 9285382
QC Batch: WET/15027
QC BatcK Method: SM 2540C
Associated Lab Samples: 9285382001
METHOD BLANK: 550717
Associated Lab Samples: 9285382001
Parameter Units
Total Dissolved Solids mg/L
QUALITY CONTROL DATA
Analysis Method: SM 2540C
Analysis Description: 2540C Total Dissolved Solids
Matrix: Water
Blank Reporting
Result limit Analyzed Qualifiers
ND 25.0 01112/1114:57
LABORATORY CONTROL SAMPLE: 550718
Spike LCS LCS % Rec
Parameter Units Conc. Result %Rec Limits Qualifers
Total Dissolved Solids mg/L 250 238 95 80-120
SAMPLE DUPLICATE: 550719
Parameter
Total Dissolved Solids
Date: 01/19/2011 09:10 AM
9285382001 Dup
Units Result Result
mg/L 338 345
RPD Qualifiers
2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace
Analytical Services, Inc..
Page 21 of 28

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
• 2225 Riverside Dr. 9800 Klncey Ave. Suite 100
aceAnalj&cal Asheville, NC 28804 Huntersville. NC 28078
»wwpes+.
(e26)254-I176 (704)e75-9092
Project: PPA'1/6/11
Pace Project No,: 9285382
OC Batch: WETA/8960
CC Batch Method: EPA 351.2
Associated Lab Samples: 9285382001
METHOD BLANK: 552101
Associated Lab Samples: 9285382001
1. Parameter Units
Nitrogen, Kjeldahl, Total mg/L
QUALITY CONTROL DATA
Analysis Method: EPA 351.2
Analysis Description: 351.2 TKN
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
NO 0.50 01/18/11 12:03
LABORATORY CONTROL SAMPLE:
552102
Spike LCS
LCS
% Rao
Parameter
Units
Conc. Result
% Rec
Limits
Qualifiers
Nitrogen, Kjeldahl, Total
mg/L
10 10.1
101
9D-110
MATRIX SPIKE SAMPLE:
552103
9285262003 Spike
MS
MS
%Rae
Parameter
Units
Result Cone.
Result
%Rec
Limits Qualifiers
Nitrogen, Kjeldahl, Total
mg/1-
16.7 10
30.3
136
90-110 J(Mi)
MATRIX SPIKE SAMPLE: 552105
9285362003 Spike MS MS % Rec
r Parameter Units Result Conc. Result %Rac Limits Qualifiers
Nitrogen, Kjeldahl, Total mg/L 2.6 10 15.9 132 90-110 J(M1)
SAMPLE DUPLICATE: 552104
9285455001 Dup
Parameter Units Result Result RPD Qualifiers
Nitrogen, Kjeldahl, Total mg/L <0.50 ND
SAMPLE DUPLICATE: 552106
9285382001 Dup
Parameter Units Result Result RPD Qualifiers
Nitrogen, Kjeldahl, Total mg/L 3.0 3.1 1
late: 01/19/2011 09:10 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced. except in full,
without the written consent
of Pam Analytical Services, Inc..
�LLIGaOR.�i
Page 22 of 28

�eAnalj&al e
i
Pace Analytical Services, Inc. Pace Analytical services, Inc.
2225 Riverside Dr. 9800 Kincey Ave. Suite 100
Asheville, NC 28804 Hunlersv0le, NC 28078
[phone] [phone]
QUALITY CONTROL DATA
Project:
PPA 1/6/11
Pace Project No.:
9285382
QC Batch:
WETA/8910
Analysis Method: EPA 353.2
OC Batch Method:
EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 9285382001
METHOD BLANK:
549591
Matrix: Water
Associated Lab Samples: 9285382001
Parameter Units
Nitrogen, Nitrate mg/L
Nitrogen, Nitrite mg/L
Nitrogen, NO2 plus NO3 mg/L
LABORATORY CONTROL SAMPLE: 549592
Parameter Units
Nitrogen, Nitrate mg/L
Nitrogen, Nitrite mg/L
Nitrogen, NO2 plus NO3 mg/L
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.10 01/0711110:17
ND 0.10 01/07/1110:17
ND 0.10 01/0711110:17
Spike LCS LCS %Red
Conc. Result %Rec Limits Qualifiers
5 5.2 103 90-110
1 1.0 102 90-110
5 5.2 103 90-110
MATRIX SPIKE SAMPLE:
549593
9285302001 Spike MS
MS % Rec
Parameter
Units
Result Cone. Result
% Rec Limits Qualifiers
Nitrogen, Nitrate
mg/L
0.91 5 6.4
111 90-110 J(Ml)
Nitrogen, Nitrite
mg/L
ND 1 1.5
147 90-110 J(M1)
Nitrogen, NO2 plus NO3
mg/L
0.91 5 6A
111 90-11c J(M1)
MATRIX SPIKE SAMPLE:
549594
9285302002 Spike MS
MS % Rec
Parameter
Units
Result Conc. Result
%Rec Limits Qualifiers
Nitrogen, Nitrate
mg/L
0.84 5 6.1
106 90-110
Nitrogen,+Nitrte
mg/L
ND 1 1.5
144 90-110 J(M1)
Nitrogen, NO2 plus NO3
mg1L
0.84 5 6.1
106 90-110
SAMPLE DUPLICATE: 549595
9285302003 Dup
Parameter Units Result Result RPD Qualifiers
Nitrogen, Nitrate mg/L 0.77 0.77 0
Nitrogen, Nitrite mg/L ND ND
Nilrogerl plus NO3 mg/L 0.77 0.77 0
Date: 0111 SQ011 09:10 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced. except in full,
without the written consent of�Pace
iAnalytkal Services, Inc..
51�.mO6,.ta
Page 23 of 28

Pace Ana"cal Services, Inc. Pace Analytical Services, Inc.
CBA�/���//��..�.� • 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
R2rJ�w� Asheville. NC 28804 Huntersville, NC 28078
•e+ePecb•eme
f (828)2547176 (704)8759092
QUALITY CONTROL DATA
Project: PPA 116111
Pace Project No.: 9285382
SAMPLE DUPLICATE: 549596
9285290010 Dup
Parameter Units Result Result RPD Qualifiers
Nitrogen,,Nitrate mg/L ND ND
Nitrogen, Nitrite mg/L ND ND
Nitrogen, NO2 plus NO3 mg/L ND ND
)ate: 01/19/2011 09:10 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
wi8wut the written consent
of PPaac�e�.Anal0cal Services, Inc..
LLl�i
Page 24 of 28

Pea Am"Cal Services, Inc. Pace Analytical Services, Inc.
2225 Riverside Dr. 9800 K.ncey Ave. Suite 1 W
aceAnalytical • Asheville. NC 28804 Huntersville, NC 28078
xwx.remlan5 am
(828)2547176 [phone]
QUALITY CONTROL DATA
Project PPA 1/6/11
Pace Project No.: 9285382
QC Batch: WETA/8959 Analysis Method: EPA 365.1
OC Batch Method: EPA 365.1 Analysis Description: 365.1 Phosphorus, Total
Associated Lab Samples: 9285382001
METHOD BLANK: 552097 Matrix: Water
Associated Lab Samples: 9285382001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phosphorus mg/L ND 0.10 0111811110:03
LABORATORY CONTROL SAMPLE:
552098
Spike LCS
LCS
%Roe
Parameter
Units
Conc. Result
%Rec
Limits
Qualifiers
Phosphorus
mg/L
2.5 2.7
107
90-110
MATRIX SPIKE SAMPLE:
552099
9285382001 Spike
MS
MS
%Rec
Parameter
Units
Result Conc.
Result
%Rec
Limits Qualifiers
Phosphorus
mg/L
0.64 2.5
3.2
102
90-110
SAMPLE DUPLICATE: 552100
9285388001 Dup
Parameter Units Result Result RPD Qualifiers
Phosphorus mg/L 4.8 4.6 4
Date: 01/19/2011 09:10 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace
e+Analytical Services, Inc..
11_I�da�.,rf:
Page 25 of 28

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
/1 ,,,, • 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
�+A r to alAsheville, NC 28804 Huntersvllle, NC 28078
www.peoe4eawm
(828)2547176 [phone]
QUALITY CONTROL DATA
Project: PPA 116/11
Pace Project No.: 9285382
QC Balch: WETA/8922
Analysis Method:
EPA 420A
QC Batch Method: EPA 420.4
Analysis Description:
420.4 Phenolics
Associated Lab Samples: 9285382001
METHOD BLANK: 55D077
Matrix: Water
Associated Lab Samples: 9285382001
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Phenol ! mg/L
ND 0.010 01/09/1117:41
LABORATORY CONTROL SAMPLE: 550078
Spike LCS
1-CS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Phenol mg/L
.25 0.27
107 90-110
MATRIX §PIKE SAMPLE:
Parameter
550079
Units
9286229002
Result
Spike MS MS % Rec
Conc. Result %Rec Limits Qualifiers
Phenol
mg/L
ND
.25 0.26 104 90-110
SAMPLE DUPLICATE: 550080
9285319002
Dup
Parameter
Units
Result
Result RPD Qualifiers
Phenol ,
mg/L
0.087
0.090 3
,
Date: 01119/201109:10 AM REPORT OF LABORATORY ANALYSIS Page 26 of 28
This report shall not be reproduced, except in full,
without the written consent
of Pace Analytical Services, Inc..
5(it

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
• 2225 Riverside Dr. 9800 Kincey Ave. Suite /00
aceMalytical Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone]
QUALITY CONTROL DATA
Project: PPA 1/6/11
Pace Project No.: 9285382
QC Batch: WETA/8948 Analysis Method: SM 4500-CN-E
QC Batch Method: SM 4500-CN-E Analysis Description: 450OCNE Cyanide, Total
Associated Lab Samples: 9285382001
METHOD BLANK: 551930 Matrix: Water
Associated Lab Samples: 9285382001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Cyanide mg/L ND 0.0050 01/1611112:08
LABORATORY CONTROL SAMPLE: 551931
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Cyanide mg/L .1 0.12 116 80-120
MATRIX SPIKE SAMPLE:
Parameter
551932
Units
9285612001
Result
Spike MS MS %Rec
Conc. Result %Rec Limits Qualifiers
Cyanide
mg/L
NO
.1 0.021 18 75-125 J(Mt)
SAMPLE DUPLICATE: 551933
9285492001
Dup
, Parameter
Units
Result
Result RPD Qualifiers
Cyanide
mg/L
0.0097
0.011 10
)ate: 01/19/2011 09:10 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services. Inc..
Page 27 of 28

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
2225 Riverside Dr. 980010ncey Ave. Suite 100
iZAnalytiol Asheville, NC 28804 Huntersville, NC 28078
ww+vww4esmm
1 [phone] [phone]
QUALIFIERS
Project: " PPA 116/11
Pace Project No.: 9285382
DEFINITIONS
OF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
NO - Not Detected at or above adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
S ;Surrogate
1,2-0iphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
N-Nltrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes.
LABORATORIES
PAST -A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
PASI-G Pace Analytical Services - Green Bay
ANALYTE QUALIFIERS
tg Sample was received in a Non Pace Green Bay LLHg bottle.
I The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit.
J(W) Estimated Value. Matrix spike recovery was outside laboratory control limits.
J(M1) Estimated Value. Matrix spike recovery exceeded OC limits. Balch accepted based on laboratory control sample (LCS)
recovery.
J(P5) Estimated Value. The EPA or method required sample preservation degrades this compound, therefore acceptable
recoveries may not be achieved in sample matrix spikes.
J(R1) Estimated Value. RPD value was outside control limits.
J(Sr0) Estimated Value. Surrogate recovery outside laboratory control limits.
Date: 01/19/2011 09:10 AM REPORT OF LABORATORY ANALYSIS Page 28 of 28
This report shall not be reproduced, except In full.
without the written consent of Pace Analytical Services, Inc..
-rheki

2ceAnalytical'
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. 2ceAna/y4ica1e
w. picalwa.
June 06, 2012
Mr. Mike Allen
Town of Tarboro
506 Dowd Street
PO Box 220
Tarboro, NC 27886
Pace Analytical Services, Inc.
206 East Meadow Road - Suite A
Eden, NC 27288
(336)6238921
RE: Project: WASTEWATER EFF PPA 5/21
Pace Project No.: 92119138
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville. NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Dear Mr. Allen:
Enclosed are the analytical results for sample(s) received by the laboratory on May 22, 2012. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
Some analyses have been subcontracted outside of the Pace Network. The subcontracted
laboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
FArr Wad n
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in lull,
without the wn"an consent of Pace Analytical Services, Inc..
Page 1 of 28

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
11!e 205 East Meadow Road - Suite A 2225 Riverside Dr.
aceAnalytical Eden. NC 27288 Asheville, NC 28804
[phone] [phone]
CERTIFICATIONS
Project: WASTEWATER EFF PPA 5/21
Pace Project No.: 92119138
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville. NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification* 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification M 99006001
South Carolina Drinking Water Cart. M 9NO6003
Virginia Drinking Water Certification #: 00213
Asheville Certification IDs
2225 Riverside Dr., Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification M WNC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastevater Certification M 40
Connecticut Certification M PH-0104
FloridalNELAP Certification #: E87627
Kentucky LIST Certification #: 84
Louisiana DHH Drinking Water # LA 100031
West Virginia Certification #: 357
Vlrginla/VELAP Certification #: 460144
South Carolina Certification M 99030001
Virginia Certification M 00072
West Virginia Certification If: 356
Virgina/VELAP Certification #: 460147
REPORT OF LABORATORY ANALYSIS
This report shall not he reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville. NC 28078
[phone]
Page 2 of 28

Pecs Analytical Services, Inc.
Pace Analytical Services, Inc.
Paco Analytical Services, Inc.
AA,�„ � ^,�I•
m LQ!
205 East Meadow Road - Suite A
2225 Riverside Dr.
Moo Kincey Ave. Suite 100
Eden, NC 27288
Asheville, NC 28804
Huntersville, NC 28078
waw.psasaas.nan
[phone]
[phone]
[phone]
SAMPLE ANALYTE COUNT
Project: WASTEWATER EFF PPA 5121
Pace Project No.: 92119138
Anaytes
Lab ID Sample 1D
Method
Analysts
Reported Laboratory
92119138001 WASTEWATER EFF
EPA 1664A
AM1
1 PASI-C
EPA 200.7
JMW
15 PASI-A
EPA 245.1
SHB
1 PASI-A
EPA 625
PPM
60 PASI-C
EPA 624
KJM
40 PASI-C
SM 2540C
LIVID
1 PASI-A
EPA 350.1
SDH
1 PASI-A
EPA 351.2
JDA
1 PASI-A
EPA 353.2
LIVID
3 PASI-A
EPA 365.1
JDA
1 PASI-A
EPA 420.4
SDH
1 PASI-A
SM 4500-CN-E
JDA
1 PASI-A
REPORT OF LABORATORY ANALYSIS Page 3 of 28
This report shall not be reproduced, except in full,
without Me written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
°
2ceAnalyhcal
205 East Meadow Road - Suite A
2225 Riverside Dr.
9800 IOncey Ave. Suite 100
www.P�..
Eden, NC 27288
Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
(704)87fi-9092
ANALYTICAL
RESULTS
Project: WASTEWATER EFF PPA 5/21
Pace Project No.: 92119138
Sample: WASTEWATER EFF
Lab ID: 921191380DI Collected:
05/22/12 11:00 Received: 05/22/12 17:15
Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
HEM, Oil and Grease
Analytical Method: EPA 1664A
Oil and Grease
NO mg/L
5.0
1
05124/12 13:11
200.7 MET ICP
Analytical Method: EPA 200.7 Preparation Method: EPA 200.7
Antimony
NO ug/L
5.0
1
05/23/1210:D0 05/24/12 01:09 744D-36-0
Arsenic
NO ug/L
5.0
1
05123/12 10:00 05/24/12 01:09 7440-38-2
Beryllium
NO ug/L
1.0
1
05/23/12 10:00 05/24/12 01:09 744041-7
Cadmium
NO ug/L
1.0
1
0512311210:00 05124/12 01:09 7440-43-9
Calcium
8920 ug/L
100
1
05/23112 10:00 05/24/12 01:09 7440-70-2
Chromium
NO ug/L
5.0
1
05/23/1210:00 05/24/12 01:09 744047-3
Copper
NO ug/L
5.0
1
05(23/12 10:00 05124/12 01:09 7440-50-8
Lead
NO ug/L
5.0
1
05123/12 10:00 05/24/12 01:09 7439-92-1
Magnesium
2410 ug/L
100
1
05/23/1210:00 05/24/1201:09 7439-954
Nickel
NO u9/L
5.0
1
05/23112 10:00 05/24/12 01:09 744M2-0
Selenium
NO ug/L
10.0
1
05123/1210:00 05/24/12 01:09 778249-2
Silver
NO ug/L
5.0
1
05/23/12 10:00 05/24112 01:09 7440-224
Thallium
NO ug/L
10.0
1
06/23/12 10:00 05/24/12 01:09 744U-28-0
Total Hardness
322DD ug/L
662
1
05/2311210:D0 05/24/12 01:09
Zinc
11.6 ug/L
10.0
1
05/23/12 10:00 05/24/12 01:09 7440-66-6
245.1 Mercury
Analytical Method: EPA 245.1 Preparation Method: EPA 245.1
Mercury
NO ug/L
0.20
1
05/25/12 10:55 05/25/12 15:06 7439.97-6
625 MSSV
Analytical Method: EPA 625 Preparation Method: EPA 625
Acenaphthene
NO ug/L
5.0
1
05/23/12 10:00 05/2411210:37 8332-9
Acenaphthylene
NO ug/L
5.0
1
05/23112 10:00 05/24112 10:37 208-96-8
Anthracene
NO ug/L
5.0
1
05/23/12 10:00 05/24112 10:37 120-12-7
Benzo(a)an0vacene
NO ug/L
5.0
1
05/23/12 10:00 05/24/12 10:37 56-55-3
Benzo(a)pyrene
NO ug/L
5.0
1
05/23/12 10:00 05/24/12 10:37 50-32-8
Benzo(b)Buoranthene
NO ug/L
5.0
1
05123/12 10:00 05/24/12 10:37 205-99-2
Benzo(g,h,i)perylene
NO ug/L
5.0
1
0512311210:00 05/24/12 10:37 191-24-2
Benzo(k)Buoranthene
NO ug/L
5.0
1
05/23/12 10:00 05/24/12 10:37 207-08.9
4-Bromophenylphenyl ether
NO ug/L
5.0
1
05/23M2 10:00 05124/12 10:37 101-55-3
Butylbenzylphthalate
NO ug/L
5.0
1
05123/1210:D0 05/24/1210:37 85-68-7
4-Chloro-3-methylphenol
NO ug/L
5.0
1
05/23/12 10:00 05/24/12 10:37 59-50-7
bis(2-Chloroethoxy)melhane
NO ug/L
10.0
1
05/23/12 10:00 05/24/12 10:37 111-91-1
bis(2-Chloroethyi) ether
NO ug/L
5.0
1
05/23(12 10:00 05/24/12 10:37 111 44 4
bis(2-CNoroisopropyl) ether
NO ug/L
5.0
1
05123/12 10:00 05/24/12 10:37 108-60-1
2-Chloronaphthalene
NO ug/L
5.0
1
05/2311210:00 D5/24/1210:37 91-58-7
2-Chlorophenol
NO ug(L
5.0
1
05/23/12 10:00 0512411210:37 9557-8
4-Chlorophenylphenyl ether
NO ug/L
5.0
1
05/2311210:D0 05/24/12 10:37 7005-72-3
Chrysene
NO ug/L
5.0
1
0512311210:00 05/24/12 10:37 218-01-9
Dibera(a,h)anthracene
NO uWL
5.0
1
05/23/12 10:00 05/24/12 10:37 53-70-3
1,2-DicNorobenzene
NO ugr-
5.0
1
05/23/12 10:00 05/24112 10:37 95-50-1
1,3-Dichlorobenzene
NO ug/L
5.0
1
05/23/12 10:D0 05/24/12 10:37 541-73-1
1,4-Dichlorobenzene
NO ug/L
5.0
1
05/23/12 10:00 05124/12 10:37 1106-46-7
3,3'-Dichlorobenzidine
NO ug/L
25.0
1
05/2311210:00 M2411210:37 91-94-1
)ate: 06/06/2012 D8:47 AM REPORT OF LABORATORY ANALYSIS Page 4 of 28
This report shall not be reproduced, except in full.
without the written consent of Pace Analytical Services, Inc..

-�aceMalXkal a
wmr.pcslWamn
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: WASTEWATER EFF PPA 5/21
Pace Project No.. 92119138
Sample: WASTEWATER EFF Lab ID: 92119138001 Collected: 05/22/12 11:00 Received: 05/22/12 17:15
Pace Analytical Services, Inc.
9800 IGncey Ave. Suite 100
Hunlersville, NC 28078
[phone]
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
2,4-Dichlorophenol
NO ug/L
5.0
1
05/23/1210:00 052411210:37 120-83-2
Diethylphthalate
NO ug/L
5.0
1
05123/1210:00 D5124/1210:37 84-66-2
2,4-Dimethylphenol
NO ug/L
10.0
1
05123/12 10:00 05124112 10:37 105.67-9
Dimethylphthalate
NO ug/L
5.0
1
0523/1210:00 05/24/12 10:37 131-11-3
Di-n-butylphthalate
NO ug/L
5.0
1
05d2311210:00 05124/1210:37 84-74-2
4,6-Dinitro-2-methylphenol
NO ug/L
20.0
1
05/23/12 10:00 05/24/12 10:37 534-52-1
2,4-Dinitrophenol
NO uglL
50.0
1
05/23/12 10:00 05/24112 10:37 51-285
2,4-0Initrotoiuene
NO uglL
5.0
1
05/2311210:00 052411210:37 121-14-2
2,6-Dinitrotoluene
NO ug/L
5.0
1
05123/1210:00 05/24/12 10:37 606-20-2
Di-n-octylphthalate
NO ug/L
5.0
1
052311210:00 05/2411210:37 117-84-0
1,2-Diphenylhydrazine
NO ug/L
5.0
1
052311210:00 05124/1210:37 122-66.7
bis(2-Ethylhexyt)phthalate
NO ug/L
5.0
1
05/23/12 10:00 052411210:37 117-81-7
Fluoranthene
NO ug/L
5.0
1
05/23/1210:00 052411210:37 20644-0
Fluorene
NO ug/L
5.0
1
0523/1210:00 052411210:37 W73-7
Hexachlorobenzene
NO ug/L
5.0
1
05/2311210:00 05/2411210:37 118-74-1
Hexachlorocyclopentadiene
NO ug/L
10.0
1
05123/1210:00 052411210:37 77-474
Hexachloroethane
NO ug/L
5.0
1
0523/12 10:00 05/24/12 10:37 67-72-1
Indeno(1,2,3cd)pyrene
NO ug/L
5.0
1
052311210:00 05/24/12 10:37 193-39-5
Isophorone
NO ug/L
10.0
1
05123/12 10:00 05124112 10:37 78-59-1
Naphthalene
NO ug/L
5.0
1
05/2311210:00 0524/1210:37 91-2D-3
Nitrobenzene
NO ug/L
5.0
1
05/23112 10:00 05/24/12 10:37 98-95-3
2-Nitrophenol
NO ug/L
5.0
1
05/23/12 10:00 05/24112 10:37 88-75-5
4-Nitrophenol
NO ug/L
50.0
1
05/23/12 10:00 052411210:37 100-02-7
N-Nitrosodimethylamine
NO ug/L
5.0
1
05/23/12 10:00 0524/12 10:37 62-75-9
N-Nitroso-di-n-propylamine
NO ug/L
5.0
1
05/23/12 10:00 05/24/12 10:37 621-64-7
N-Nitrosodipherlylamine
NO ug/L
10.0
1
05/2311210:D0 0512411210:37 86-306
Pentachlorophenol
NO ug/L
25.0
1
05/23/12 10:00 0524(1210:37 87-86-5
Phenanthrene
NO uglL
5.0
1
05/23/1210:D0 05124/1210:37 86-01-8
Phenol
NO ug/L
5.0
1
05/23(1210:00 05124/1210:37 108-95-2
Pyrene
NO ug/L
5.0
1
05123/12 10:00 05/24/12 10:37 129-00-0
2,4,6-Trichlorophenol
NO ug/L
10.0
1
D5/23(12 10:00 05/241121037 88-06-2
Surrogates
Nitrobenzene-d5 (S)
44 %
10-120
1
05/23/12 10:00 05/24/12 10:37 4165-60-0
2-Fluorobiphenyl(S)
40 %
15-120
1
05/23/12 10:00 0524/12 10:37 321-60-8
Terphenyl-d14(S)
59 %
11-131
1
D5/23/1210:00 05/2411210:37 1718-51-0
Phenol-06 (S)
12 %
10-120
1
0523112 10:00 0524112 10:37 13127-W3
2-Fluorophenol (S)
21 %
10-120
1
052311210:00 0524/1210:37 367-124
2,4,6•Tribromophenol(S)
68 %
1D-137
1
05/23/12 10:00 05/24/12 10:37 118-79-6
624 Volatile Organics Analytical Method: EPA 624
Acrolein
NO ug/L 100 1
05/30/1212:56 107-02-8
Acrylonnrile
NO ug/L 100 1
05/30/12 12:56 107-13-1
Benzene
NO ug/L 5.0 1
05130/12 12:56 71-43-2
Bromodichloromethane
NO ug/L 5.0 1
05/30/1212:56 75-274
Bromofonn
NO ug/L 5.0 1
05/30/1212:56 75-25-2
Bromomethane
NO ug/L 10.0 1
0513011212:56 74.83-9
Carbon tetrachloride
NO ug/L 5.0 1
05/30112 12:56 56-23-5
)ate:06/06201208:47AM
REPORT OF LABORATORY ANALYSIS
Page5o128
This report shall net be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

I�AZAnalytical'
www.pe Nebe.mm
/
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pecs Analytical SerNces, Inc.
9800 K ricey Ave. Suite 100
Huntersvllle, NC 28078
[phone]
Project: WASTEWATER EFF PPA 5121
Pace Project No.: 92119138
Sample: WASTEWATER EFF Lab ID: 92119138001 Collected: 05/22/1211:00 Received: 05/22M217*15 Matnx. Water
Parameters
624 Volatile Organics
Chlorobenzene
Chloroethane
2-Chlomethytvinyl ether
Chloroform
Chloromethane
Dibromochloromethane
1,2-Dichlorobenzene
1,3-DicNorobenzene
1,4-Dichlorobenzene
1,1-DicNoroethane
1,2-Dichloroethane
1,1-0ichloroethene
trans-1,2-0ichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hezachloro-1 ,3-butadlene
Methylene Chloride
Naphthalene
1, 1,2,2-Tetrachloroethane
Tetrachlorcethene
Toluene
1, 2,4-Trichlombenze ne
1, 1, 1 -Trichloroethane
11,2-Trichloroethane
Trichloroethene
Trichlorofluorometha ne
Vinyl chloride
Surrogates
Dibromofluoromethane (S)
4-Bromofluorobenzene (S)
Toluene -de (S)
1,2-Dichloroethane-d4 (S)
2540C Total Dissolved Solids
Total Dissolved Solids
350.1 Ammonia
Nitrogen, Ammonia
351.2 Total Kjeldahi Nitrogen
Nitrogen, Kjeldahl, Total
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
)ale: 06/06/2012 08:47 AM
Results Units Report Limit DF
Analytical Method: EPA 624
Prepared Analyzed CAS No. Qual
NO 1g/1-
5.0
1
05/30/12 12:56 108-90-7
NO U91L
10.0
1
05130/12 12:56 75-M3
NO uglL
10.0
1
05/30/1212:56 110-7541
NO ug/L
5.0
1
05/30/1212:56 67-66-3
ND ug/L
5.0
1
0513011212:56 74-87-3
ND ug/L
5.0
1
05/3011212:56 124-08A
ND ug/L
5.0
1
0513011212:56 95-50-1
NO ug/L
5.0
1
05/3011212:56 541-73-1
NO ug/L
5.0
1
05/30/1212:56 106-46-7
NO u9/1-
5.0
1
05/30/1212:56 75-34-3
NO u91L
5.0
1
05130/1212:56 107-06-2
NO u9/1-
5.0
1
05130/1212:56 75-35-4
NO ug/L
5.0
1
05/30/1212:56 156.60.5
ND ug/L
5.0
1
05/30/1212:56 78-87-5
NO ug/L
5.0
1
05/30/1212:66 10061-01-5
NO ug/L
5.0
1
05/3011212:56 10061-02-6
NO ug/L
5.0
1
05/30/12 12:56 100-41-4
NO ug/L
5.0
1
05/3011212:56 87-68-3
NO IgIL
5.0
1
0513011212:56 75-09-2
NO ug/L
5.0
1
05/3011212:56 91-2D-3
NO ug/L
5.0
1
05/30/12 12:56 79-34-5
NO ug/L
5.0
1
05130/1212:56 127-18-4
ND ug/L
5.0
1
05/30/12 12:66 108-88-3
NO ug/L
5.0
1
05/30/12 12:56 1211-82-1
NO ug/L
5.0
1
0513011212:56 71-556
NO ug/L
5.0
1
05/30112 12:56 79-00-5
NO ug/L
5.0
1
05/3011212:56 79-01-6
NO ug/L
10.0
1
05/30/12 12:56 75-69-4
NO ug/L
5.0
1
OWW/1212:56 75-01.4
109 %
70-130
1
05/30/1212:56 IW&53-7
95 %
70-130
1
OSM1212:56 460-00.4
96 %
70-130
1
05/30/1212:56 2037-215-5
118 %
70-130
1
0513011212:56 17060-07-0
Analytical Method: SM 2540C
267 mg/L
25.0
1
05(22l12 21:14
Analytical Method: EPA 350.1
ND mg/L
0.10
1
06/05/1212:48 7664-41-7
Analytical Method: EPA 351.2
0.86 mg/L
0.50
1
06(02J1209:11 7727-37-9
Analytical Method: EPA 353.2
8.5 mg/L
0.20
1
05/23/1219:55
REPORT OF LABORATORY ANALYSIS
This repon shall not be reproduced, except in lull,
without the written consent of Pace Analytical Services, Inc..
Page 6 of 28

,/ -2ceAnalydical'
..MLlIab$.W
Pace Analytical Services. Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 26078
[phone]
Project: WASTEWATER EFF PPA 5/21
Pace Project No.: 92119138
Sample: WASTEWATER EFF
Lab 10: 92119138MI Collected:
05/22/12 11:00
Received: 05/22/12 17:15 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed CAS No. Qual
353.2 Nitrogen, NO2/11,103 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrite
ND mg/1-
0.10
1
05/23/12 19:55
Nitrogen, NO2 plus NO3
8.5 mg/L
0.20
1
05/23M2 19:55
365.1 Phosphorus, Total
Analytical Method: EPA 365.1
Phosphorus
0.20 mg/L
0.050
1
M01/1213:06 7723-14-0
420.4 Phenolics, Total
Analytical Method: EPA 420.4
Phenol
0.035 mil
0.010
1
05131/1211:21 108.95.2
450OCNE Cyanide, Total
Analytical Metfad: SM 4500-CN-E
Cyanide
0.0055 mg/L
0.0050
1
06101/12111:37 57-12-5
Date: 06/06/2012 08:47 AM REPORT OF LABORATORY ANALYSIS Page 7 of 28
This report shall not be reproduced, except in full,
w8rl the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc.
A,,,,a, �;��, • 205 East Meadow Road - Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
Eden, NC 27288 Asheville. NC 28804 Runtersville, NC 2807E
wew.psos,Ybawm
[phone] (828)2547176 [phone]
QUALITY CONTROL DATA
Project: WASTEWATER EFF PPA 5/21
Pace Project No.: 92119138
OC Batch: GCSV/12070 Analysis Method: EPA 1664A
OC Batch Method: EPA 1664A Analysis Description: 1664 HEM, O0 and Grease
Associated Lab Samples: 92119138001
METHOD BLANK: 768497 Matrix: Water
Associated Lab Samples: 92119138001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Oil and Grease mg/L ND 5.0 05/24/12 13:07
LABORATORY CONTROL SAMPLE:
768498
Spike LCS
LCS
% Rec
Parameter
Units
Cone. Result
%Rec
Limits
Qualifiers
ON and Grease
mg/L
40 37.1
93
78-114
MATRIX SPIKE SAMPLE:
768499
92119188005 Spike
MS
MS
% Rec
Parameter
Units
Result Conc.
Result
%Rec
Limits Qualifiers
Oil and Grease
mg/L
ND 40
37.3
93
78-114
)ate: 06106/2012 08.47 AM REPORT OF LABORATORY ANALYSIS Page 8of28
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

2 AnaVAml
waw.pew40aosm
Paw AnWi cal Services, Inc.
205 Past Meadow Read - Suite A
Eden, NC 27288
[phone]
Project: WASTEWATER EFF PPA 5121
Pace Project No.: 92119138
QC Batch: MERP/4249
OC Batch Method: EPA 245.1
Associated Lab Samples: 92119138001
METHOD BLANK: 768295
Associated Lab Samples: 92119138001
Parameter Units
Mercury
ug/L
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA 245.1
Analysis Description: 245.1 Mercury
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
NO 0.20 05/25/1214:45
Pace Analytical Services, Inc.
9800 Kincey Ave, Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 768296
Spike LCS LCS %Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 2.5 2.4 94 85-115
MATRIX SPIKE SAMPLE: 768297
92119157001 Spike MS MS % Rec
Parameter Units Result Conc. Result % Rec Limits Qualifiers
Mercury ug/L NO 2.5 1.1 41 70-130 J(Mt)
SAMPLE DUPLICATE: 76829E
Parameter
Mercury
92119167002 Dup
Units Result Result
ug/L 136 2.8
RPD Qualifiers
192 J(D6)
)ate:0&06,2012 08:47 Aral REPORT OF LABORATORY ANALYSIS Page 9of28
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services. Inc..

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
•
/t �•
ce^d�s'r &ftal
205 East Meadow Road - Suite A
2225 Riverside Dr.
9800 Kincey Ave. Suile 100
Eden, NC 27288
Asheville, NC
28804
Huntersville, NC 28078
wew.pwW.mm
f
[phone]
[phone]
[phone]
QUALITY CONTROL DATA
Project: WASTEWATER EFF PPA 5/21
Pace Project No.: 92119138
QC Batch: MPRPll D650
Analysis Method: EPA 200.7
QC Batch Method: EPA 200.7
Analysis Description: 200.7 MET
Associated Lab Samples: 92119138001
METHOD BLANK: 767624
Matrix: Water
Associated Lab Samples: 92119138001
Blank Reporting
Parameter
Units
Result Limit
Analyzed
Qualifiers
Antimony
ug/L
ND 5.0
05/2411200:20
Arsenic
ug/L
NO 5.0
0512411200:20
Beryllium
ug/L
NO 1.0
05/241120020
Cadmium
ug/L
ND 1.0
0512411200:20
Calcium
ug/L
NO 100
05124/1200:20
Chromium
ug/L
ND 5.0
05/24112 00:20
Copper
ug/L
NO 5.0
05/24/120020
Lead
ug/L
NO 5.0
05/24112 00:20
Magnesium
ug/L
ND 100
05/241120020
Nickel
ug/L
NO 5.0
05124/1200:20
Selenium
ug/L
ND 10.0
05/2411200:20
Silver
ug/L
ND 5.0
05/24/1200:20
Thallium
ug/L
NO 10.0
05/2411200:20
Total Hardness
ug/L
NO 662
05/24112 00:20
Zinc
ug/L
NO 10.0
D504112 002D
LABORATORY CONTROL SAMPLE:
767625
Spike LCS
LCS %Rec
Parameter
Units
Cone. Result
% Rec Limits Qualifiers
Antimony
ug1L
500 473
95
85-115
Arsenic
ug/L
500 477
95
85-115
Beryllium
ug/L
500 486
97
85-115
Cadmium
ug/L
500 479
96
85-115
Calcium
ug/L
5000 4940
99
85.115
Chromium
ug/L
500 492
98
85-115
Copper
uglL
500 474
95
85-115
Lead
ug/L
500 475
95
85-115
Magnesium
ug/L
5000 4900
98
85-115
Nickel
ug/L
500 479
96
85-115
Selenium
ug/L
500 478
96
85-115
Silver
ug/L
250 242
97
85-115
Thallium
ug/L
Soo 471
94
85-115
Total Hardness
ug/L
32500
Zinc
ug/L
500 472
94
86-115
MATRIX SPIKE SAMPLE:
767626
92119066002 Spike
MS
MS
% Rae
Parameter
Units
Result Cone.
Result
%Rec
Limits Qualifiers
Antimony
ug/L
NO 500
526
105
70-130
Arsenic
ug/L
NO 500
573
115
70-130
Date: 06/06/2012 08:47 AM
REPORT OF LABORATORY ANALYSIS
Page 10 of 28
This report shall not be reproduced. except in full,
without the widen consent of Pace Analytical Services. Inc

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�eAnalytical e
w.w.a+eeMemn
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Anatytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 2807E
[phone]
Project:
WASTEWATER EFF PPA 5121
Pace Project No.:
92119138
QC Balch:
MSV/19265 Analysis Method: EPA 624
QC Balch Method:
EPA 624 Analysis Description: 624 MSV
Associated Lab Samples: 92119138001
METHOD BLANK: 769832
Associated Lab Samples:
Parameter
92119138001
Units
Matrix:
Blank
Result
Water
Reporting
Limit
Analyzed
1,1,1-Trichioroethane
ug/L
ND
5.0
06/30/1212:01
1,1,2,2-Tetrachloroethane
ug/L
ND
5.0
05/30/1212:01
1,1,2-Trichloroethane
ug/L
ND
5.0
05/30/1212:01
1,1-Dichloroethane
ug/L
ND
5.0
05/30/1212:01
1,1-Dichloroethene
ug/L
ND
5.0
05/30/1212:01
1,2,4-Trichlorobenzene
ug/L
ND
5.0
05/30/1212:01
1,2-Dichlorobenzene
ug/L
ND
5.0
06/30/1212:01
1,2-Dichloroethane
ug/L
ND
5.0
05/3011212:01
1,2-Dichloropropane
ug/L
ND
5.0
05/3011212:01
1,3-Dichlorobenzene
ug/L
ND
5.0
05/30/1212:01
1,4-Dichlorobenzene
ug/L
ND
5.0
05/30/12 12:01
2-Chloroethylvinyl ether
ug/L
ND
10.0
05/30/12 12:01
Acrolein
ug/L
ND
100
05/3011212:01
Acrylonitrlle
ug/L
ND
100
0613011212:01
Benzene
ug/L
ND
5.0
0513011212:01
Bromodichloromethane
ug/L
ND
5.0
05130/1212:01
Bromoform
ug/L
ND
5.0
05/30/1212:01
Bromomelhane
ug/L
ND
10.0
05/3011212:01
Carbon tetrachloride
ug/L
ND
5.0
05/30/12 12:01
Chlorobenzene
ug/L
ND
5.0
05/30/12 12:01
Chloroethane
ug/L
ND
10.0
05/30/1212:01
Chloroform
ug/L
ND
5.0
05/30/1212:01
Chloromethane
ug/L
ND
5.0
05130/1212:01
cis-1,3-Dichloropropene
ug/L
ND
5.0
05/30/1212:01
Dibromochloromethane
ug/L
ND
5.0
05/30/1212:01
Ethylbenzene
ug/L
ND
5.0
05130/12 12:01
Hexachloro-1,3-butadiene
ug/L
ND
5.0
05130/1212:01
Methylene Chloride
u91L
ND
5.0
05/30/12 12:01
Naphthalene
ug/L
ND
5.0
05/30/1212:01
TetracNcroethene
ug/L
ND
5.0
06/30/1212:01
Toluene
ug/L
NO
5.0
05/30/12 12:01
trans-1,2-Dichloroethene
ug/L
NO
5.0
05/30/12 12:01
trans-1,3-Dichloropropene
ug/L
ND
5.0
05/30/12 12:01
Trcchloroethene
uglL
NO
5.0
05/30/12 12:01
Trichlorofluoromethane
ug/L
ND
10.0
05/30/1212:01
Vinyl chloride
ug/L
ND
5.0
05/30/12 12:01
1,2-Dichoroethane-d4 (S)
%
113
70-130
05/30112 12:01
4-Bromfluorobenzene(S)
%
97
70-130
05/30/12 12:01
Dibromofluoromathane (S)
%
105
70-130
05/30/12 12:01
Toluened8(S)
%
95
70-130
06/30/'12 12:01
Date: 06I06/2012 08:47 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services. Inc..
Qualifiers
Page 12 of 28

Pace Analytical Services, Inc. Pace Analocal Services, Inc. Pace Analytical Services, Inc.
205 East Meadow Road - Suite A 2225 Riverside Or. 9800 Kincey Ave. Suite 100
_ 2-CeAmOol*
Eden, NC 27288 Asheville. NC 28804 Huntersville, NC 28078
/ ww.'eaafheaa•in
[phone] [phone] [phone]
QUALITY CONTROL DATA
Project: WASTEWATER EFF PPA 5/21
Pace Project No.: 92119138
LABORATORY CONTROL SAMPLE: 769833
Spike
LCS
LCS
% Rec
Parameter
Units
Conic.
Result
% Rec
Limits Qualifiers
1,1,1-Trichlomethane
ug/L
20
15.2
76
52-162
1,1,2,2-Tetrachloroethane
1
20
14.6
73
46-157
1,1,2-Trichloroethane
ug/L
20
17.0
85
52-150
11,1-Dichlomethane
ug/L
20
15.2
76
59-155
1,1-Dichloroethene
ug/L
20
17.3
87
1-234
1,2,4-Trichlorobenzene
ug/L
20
16.6
83
70-130
1,2-Dichlorobenzene
ug/L
20
16.4
82
18-190
1,2-DicNoroethane
ug/L
20
16.8
84
49-155
1.2-DicNoropropane
ug/L
20
16.3
81
1-210
1,3-Dichlorobenzene
ug/L
20
16.3
81
59-156
1,4-Dichlorobenzene
ug/L
20
16.3
81
18-190
2-Chloroethylvinyt ether
ug/L
40
13.2
33
1-305
Acrolein
ug1L
100
7161
74
15-152
Acrylonitrile
ug/L
100
93.21
93
75-132
Benzene
ug/L
20
16.6
83
37-151
Bromodichloromethane
ug/L
20
14.6
73
35-155
Bromoform
ug/L
20
14.0
70
45-169
Bromomethane
ug/L
20
10A
52
1-242
Carbon tetrachloride
ug/L
20
15.2
76
70-140
Chlorobenzene
ug/L
20
16.4
82
37-160
Chloroethane
ug/L
20
15.8
79
14-230
Chloroform
ug/L
20
16.4
82
51-138
Chloromethane
ug/L
20
16.8
84
1-273
cis-1,3-Dichloropropene
ug/L
20
14.3
71
1-227
Dibromochloromethane
ug/L
20
15.8
79
53-149
Ethylbenzene
ug/L
20
16.4
82
37-162
Hexachloro-1,3-butadiene
ug/L
20
15.4
77
70-130
Methylene Chloride
ug/L
20
17.0
85
1-221
Naphthalene
ug/L
20
17.8
89
70-130
Tetrachloroethene
ug/L
20
16.1
80
64-148
Toluene
ug/L
20
15.9
80
47-150
trarhs-1,2-Dichloroethene
ug/L
20
17.0
85
54-156
trans-1,3-Dichioropropene
ug/L
20
14.3
72
17-183
Trichlomethene
ug/L
20
16.6
83
71-157
Trichloro8 uoromethane
ug/L
20
14.7
74
17-181
Vinyl chloride
ug/L
20
14.4
72
1-251
1,2-Dichloroethaned4(S)
%
101
70-130
4-Bromoltuorobenzene(S)
%
92
70-130
Dibromo0uoromethane (S)
%
99
70-130
Toluened8 (S)
%
98
70-130
MATRIX SPIKE 8 MATRIX SPIKE DUPLICATE: 769834
769835
MS
MSD
92119138001
Spike
Spike MS
MSD
MS MSD
%Rec
Parameter
Units Result
Conic.
Conc. Result
Result
%Rec %Rec
Limits RPD Qual
1,1,1-Trichloroethane
ug/L NO
20
20 18.8
18.9
94 94
46-171 1
1,1,2,2-Tetrachloroethane
ug/L NO
20
20 19.7
19.0
98 95
73-159 3
tale: 06/06/2012 06:47 AM REPORT OF LABORATORY ANALYSIS Page 13 of 28
This report shall not he reproduced, except in full,
without the written consent of Pace Analytical Services. Inc

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Pecs Analytical Servlcn, Inc.
Pace
Analytical Services, Inc.
Pace Analytical Services, Inc.
•
aceAnallj tical
205 Fast Meadow Road - Suite A
2225 Riverside Dr.
9800 Kincey Ave. Suite 100
Eden. NC 27288
Asheville. NC 28804
Huntersville, NC 28078
woes
[phone]
(828)2547176
[phone]
QUALITY CONTROL
DATA
Project: WASTEWATER EFF PPA 5/21
Pace Project No.: 92119138
QC Batch: OEXT117593
Analysis Method:
EPA 625
QC Batch Method: EPA 625
Analysis Description:
625 MSS
Associated Lab Samples: 92119138001
METHOD BLANK: 767711
Matrix: Water
Associated Lab Samples: 92119138001
Blank Reporting
Parameter
units Result Limit
Analyzed Qualifiers
1,2-Dichlorobenzene
ug/L
NO
5.0
05/24/12 07:20
1,2-Dlphenylhydrazine
ug/L
NO
5.0
05/24/11207:20
1,3-Dichlorobenzene
ug/L
NO
5.0
05124/12 07:20
IIA-Dichlorobenzene
ug/L
NO
5.0
05124/12 07:20
2.4,6-Tdchlorophenol
ug/L
NO
10.0
05/24/12 07:20
2,4-Dichlomphenol
ug/L
NO
5.0
05(24112 07:20
2,4-Dimethylphenol
ug/L
NO
10.0
05/24/1207:20
2,4-Dinitmphenol
ug/L
NO
50.0
05/24/12 07:20
2,4-Dinitrotoluene
ug/L
NO
5.0
0512411207:20
2,6-Dinitrotoluene
ug/L
NO
5.0
05124/12 07:20
2-Chloronaphthalene
ug/L
NO
5.0
05124/12 07:20
2-Chlorophenol
ug/L
NO
5.0
05/241207:20
2-Nitropheral
ug/L
NO
5.0
05/24/12 07:20
3,3'-Dichlombenzidine
ug/L
NO
25.0
05/24112 07:20
4,6-Dinitro-2-methylphenoi
ug/L
NO
20.0
05/24/12 07:20
4-Brornophenylphenyl ether
ug/L
NO
5.0
05/24/12 07:20
4-Chloro-3-methylphenol
ug/L
NO
5.0
05/24/12 07:20
4-Chlorophenylphenyl ether
ug/L
NO
5.0
06/24/12 07:20
4-Nitrophenol
ug/L
NO
50.0
05/24/12 07:20
Acenaphthene
ug/L
NO
5.0
05/24/12 07:20
Acenaphthylene
ug/L
NO
5.0
0512NI2 07:20
Anthracene
ug/L
NO
5.0
06/24/12 07:20
Benzo(a)anthracene
ug/L
NO
5.0
05/24/12 07:20
Benzo(a)pyrene
ug/L
NO
6.0
05/24/12 07:20
Benzo(b)Buoranthene
ug/L
NO
5.0
0512411207:20
Benzo(g,h,i)perylene
ug/L
NO
5.0
05/24/12 07:20
Benzo(k)8uoranthene
ug/L
NO
5-0
05/24/12 07:20
bis(2-Chloroethoxy)methane
ug/L
NO
10.0
05/24/12 07:20
bis(2-Chloroethyl) ether
ug/L
NO
5.0
05/24/12 07:20
bis(2-Chloroisopropyl) ether
ug/L
NO
5.0
05/2411207:20
bis(2-Ethylhexyl)phthalate
ug/L
NO
5.0
05124/12 07:20
Butylbenzylphthalate
ug/L
NO
5.0
0512411207:20
Chrysene
ug/L
NO
5.0
05/24/12 07:20
Di-n-butylphthalate
ug/L
NO
5.0
05/24/1207:20
Di-n-octyiphthalate
ug/L
NO
5.0
05/24/12 07:20
Dibenz(a,h)anthracene
ug/L
NO
5.0
05/24/12 07:20
Diethylphthalate
ug/L
NO
5.0
05/24/12 07:20
Dimethylphthalate
ug/L
NO
5.0
05/24/12 07:20
Fluoranthene
ug/L
NO
5.0
05/24/12 07:20
Fluorene
ug/L
NO
5.0
05/24/12 07:20
Hexachlorobenzene
ug/L
NO
5.0
05/24/12 07:20
Hexachlorocyclopentadiene
ug/L
NO
10.0
05/24/12 07:20
Hexachloroethane
ug/L
NO
5.0
05/24/12 0720
)ate: 06106/2012 08:47 AM
REPORT OF LABORATORY ANALYSIS
Page 15 of 28
This report shall not be reproduced, except in full,
wilhout the written consent of Pace Analytical Services, Inc

�eAnalytical
ewe.pawNesmn
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr,
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: WASTEWATER EFF PPA 5/21
Pace Project No.: 92119138
METHOD BLANK: 767711
Matrix:
Water
Associated Lab Samples: 92119138001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Indeno(1,2,3-cd)pyrene
ug/L
ND
5.0
05124/12 07:20
Isophorone
ug/L
ND
10.0
05/24/12 07:20
N-Nitroso-di-n-propylamine
ug/L
ND
5.0
0512411207:20
N-Nitrosodimethylamine
ug/L
ND
5.0
05/24/12 07:20
N-Nitrosodiphenylamine
ug/L
NO
10.0
06/24/12 07:20
Naphthalene
ug/L
ND
5.0
05/24112 07:20
Nitrobenzene
ug/L
ND
5.0
05/24112 07:20
Pentachlorophenol
ug/L
ND
25.0
05/24/1207:20
Phenanthrene
ug/L
ND
5.0
05/24112 07:20
Phenol
ug/L
ND
5.0
05/24/12 07:20
Pyrene
U91L
ND
5.0
05/24/12 07:20
2,4,6-Tribromophenol(S)
%
63
1D-137
0512411207:20
2-Fluorobiphenyl (S)
%
53
15-120
0524112 07:20
2-Fluorophenol(S)
%
29
10-120
0512411207:20
Nitrobenzene-d5 (S)
%
54
10-120
0524/12 07:20
Phenol-d6(S)
e/
21
10-120
05/24/1207:20
Terphenyl-d14 (S)
%
69
11-131
05/24/12 07:20
Pace Analytical Services, Inc.
9800 Kmcey Ave. Suite 100
Huntersville, NC 28078
(704)B75-9092
LABORATORY CONTROL SAMPLE:
Parameter
767712
Units
Spice
Conc.
LCS
Result
LCS
%Rec
% Rec
Limits Oualifiers
1,2-Dlchlorobenzene
ug/L
50
29.0
58
32-129
1,2-Diphenylhydrazine
ug/L
50
29.3
59
25-150
1,3-Dichlorobenzene
ug/L
50
27.5
55
1-172
1,4-Dichlombenzene
ug/L
50
27.9
56
20-124
2,4,6-Trichlorophenol
ug/L
50
35.2
70
37-144
2,4-Dichlorophenol
ug/L
50
34.3
69
1-191
2,4-Dimethylphenol
ug/L
50
31.8
64
32-119
2,4-Dinitrophenol
ug/L
250
275
110
1-181
2,4-Dinitrotoluene
ug/L
50
34.5
69
39.139
2,6-Dindmtoluene
ug/L
50
32.5
65
50-158
2-Chloronaphthalene
ug/L
50
29.8
60
60-118
2-Chlorophenol
ug/L
5o
32.5
65
23-134
2-Nitrophenol
ug/L
50
34.6
69
29-182
3,T-Dichlorobenzidine
ug/L
100
67.3
67
1-262
4,6-Dlnibro-2-methylphenol
ug/L
100
100
100
1-181
4-Bromophenylphenyl ether
ug/L
50
33.8
68
53-127
4-CNoro-3-methylphenol
ug/L
100
65.1
65
22-147
4-CNorophenylphenyl ether
ug/L
50
35.8
72
25-158
4-Nitrophenol
ug/L
250
98.6
39
1-132
Acenaphthene
ug/L
50
34.5
69
47-W
Acenaphthylene
ug/L
50
33.6
67
33.145
Anthracene
ug/L
50
38.7
77
1-166
Benzo(a)anthracene
ug/L
50
38.0
76
33-143
Benzo(a)pyrene
ug/L
50
39.1
78
17-163
Date: 06/06201208:47 AM REPORT OF LABORATORY ANALYSIS Page 16 of 28
This report shall not be reproduced. except in full,
without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc.
d�r.�/r • 205 East Meadow Road - Suite A 2225 Riverside Dr. 98001ancey Ave. Suite 100
`lcal Eden, NC 27286 Asheville, NC 28804 Huntersville, NC 28078
[phone] (82a)2547176 [phone]
QUALITY CONTROL DATA
Project: WASTEWATER EFF PPA 5121
Pace Project No.: 92119138
LABORATORY CONTROL SAMPLE: 767712
Parameter
Units
Spike
Conic.
LCS
Result
LCS
%Rec
%Roo
Limits Qualifiers
Benzo(b)fluoranthene
ug/L
50
37.8
76
24-159
Benz-o(g,h,i)perylene
ug/L
50
42.5
85
1-219
Benzn(k)fluoranthene
ug/L
50
37.1
74
11.162
bis(2-Chloroethoxy)methane
ug/L
50
32.3
65
33-184
bis(2-Chloroethyl) ether
ug/L
50
33.8
68
12-158
bis(2-Chioroisopropyl) ether
ug/L
50
33.1
66
36-166
bis(2-Ethyihexyl)phthelate
ug/L
50
30.0
60
B-158
Butylbenzylphthaiate
ug/L
50
30.0
60
1-152
Chrysene
ug/L
50
38.6
77
17-168
Di-n-butylphthalate
ug/L
50
35.0
70
1-118
Di-n-octylphthalate
ug/L
50
31.4
63
4-146
Dibenz(a,h)anthracene
ug/L
50
41.4
83
1-227
Diethyiphthalate
ug/L
50
34.0
68
1-114
Dimethylphthalate
ug/L
50
31.8
64
1-112
Fluoranthene
ug/L
50
44.9
90
26-137
Fluorene
ug/L
50
36.1
72
59.121
Hexachlorobenzene
ug/L
50
33.6
67
1-152
Hexachlorocyclopentadiene
ug/L
50
32.0
64
25-150
Hexachloroethane
ug/L
50
28.4
57
40-113
Indeno(1,2,3-cd)pymne
ug/L
50
43.4
87
1-171
Isophorone
ug/L
50
26.6
53
21-196
N-Nitroso-6n-propNamine
ug/L
50
37.9
76
1-230
N-Nitrosodimethylamine
ug/L
50
20.0
40
25-150
N-Nitrowdiphenylamine
ug/L
50
32.7
65
25-150
Naphthalene
ug/L
50
31.1
62
21-133
Nitrobenzene
ug/L
50
25.3
51
35-180
Pentachlorophenol
ug/L
100
99.0
99
14-176
Phenanthrene
ug/L
50
37.3
75
54-120
Phenol
ug/L
50
15.3
31
5-112
Pyrene
ug/L
50
34.4
69
52-115
2,4,6-Tribromophenol (S)
%
90
10-137
2-Fluorobiphenyl (S)
%
62
15-120
2-Fluorophenol IS)
%
34
10-120
Nitrobenzene-05 (S)
%
61
10-120
Phenol-d6(S)
%
25
10-120
Terpherry4-0'14 (S)
%
66
11-131
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 767713 767714
MS MSD
92119122001 Spike Spike MS MSD
MS
MSD
%Rao
Parameter
Units
Result Conc. Conc. Result Result %Rec
%Rec
Limits
RPD Qual
1,2-0icMorobenzene
ug/L
ND 100 100 67.8 60.7
68
61
32.129
11
1,2-0ipheny1hydrazirte
ug1L
ND 100 100 67.9 65.7
68
66
25-150
3
1,3-0ichlorobenzene
ug/L
ND 100 100 66.3 59.8
66
60
1-172
10
1,4-0ichlorobenzene
ug/L
NO 100 100 65.8 59.4
66
59
20-124
10
2,4,6-Trichlorophenol
ugfL
NO 100 100 78.8 68.8
79
69
37-144
14
2,4-0icHorophenol
ug(L
ND 100 100 75.5 71.2
75
71
1-191
6
3ate:06106/201208:47AM
REPORT OF LABORATORY ANALYSIS
Page 17or28
This report shall not be reproduced, except in full,
Without the written consent of Pace Analytical Services, Inc..

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eAnalydcal
pxerea mm
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden. NC 27288
(336)623A921
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville. NC 28804
[phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Hunter=_ville. NC 28078
704,875-9092
Project: WASTEWATER EFF PPA 5121
Pace Project No.: 92119138
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 767713
767714
MS
MSD
92119122001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units Result
Cone.
Conc.
Result
Result
%Rec
%Rec
Limits RPD Qual
Phenol Ig/L ND
100
100
41A
41.1
41
41
5-112 1
Pyrene ug/L ND
100
100
72.5
63.8
73
64
52-115 13
2,4,6-Tribromophenol (S) %
86
75
10.137
2-Fluorobiphenyl (S) %
71
64
15120
2-Fluorophenol(S) %
46
44
10-120
Nltrobenzened5 (S) %
68
64
10-120
Phenold6 (S) %
33
34
10-120
Terphenyl-d14(S) %
70
61
11-131
)ate 06/06/2012 08.47 AM REPORT OF LABORATORY ANALYSIS Page 19 of 28
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services. Inc..

.2eA Kloca
w.aPsoYlia n
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services. Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Analytical Services. Inc.
9800 Kincey Ave. Suite 100
Huntersville. NC 28078
[phone]
Project:
WASTEWATER EFF PPA 5121
Pace Project No.:
92119138
QC Batch:
WET/20951 Analysis Method: SM 2540C
QC Batch Method:
SM 2540C Analysis Description: 2540C Total Dissolved Solids
Associated Lab Samples: 92119138001
METHOD BLANK: 767568
Associated Lab Samples: 92119138001
Parameter
Units
Total Dissolved Solids
mg/L
LABORATORY CONTROL SAMPLE:
767569
Parameter
Units
Total Dissolved Solids
mg/L
SAMPLE DUPLICATE: 767570
Parameter
Total Dissolved Solids
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 25.0 05/22/12 21:11
Spike LCS LCS % Rec
Cone. ResuB %Rec Limits Qualifiers
250 250 100 80-120
92119098001 Dup
Units Result Result
mg/L ND ND
RPD Qualifiers
)ate: 06/06/2012 08:47 AM REPORT OF LABORATORY ANALYSIS Page 20 of 28
This report shall not be reproduced, except in full.
without the written consent of Pace Analytical Services. Inc.,

aceAnalj ticale
� - ..ww pexre>ccom
Pecs Analytical Services, Inc.
205 East Weadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
98c0 Kincey Ave. Suite 100
Hunlersvflle, NC 28078
[phone]
Project:
WASTEWATER EFF PPA 5/21
Pace Project No.:
92119138
QC Batch:
WETA/12254 Analysis Method: EPA 350.1
OC Batch Method:
EPA 350.1 Analysis Description: 350.1 Ammonia
Associated Lab Samples: 92119138001
METHOD BLANK: 772872
Associated Lab Samples: 92119138001
Parameter Units
Nitrogen, Ammonia mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.10 06/0611212:43
LABORATORY CONTROL SAMPLE: 772873
Spike LCS LCS % Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen, Ammonia mg(L 5 5.2 103 90-110
MATRIX SPIKE SAMPLE: 772875
92119129001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Nitrogen, Ammonia M91L 1.1 5 5.9 96 9D-110
MATRIX SPIKE SAMPLE: T72877
92119366008 Spike MS MS % Rec
Parameter Units Result Cone. Result %Rec Limits Qualifiers
Nitrogen, Ammonia mg/L 1.4 5 62 96 90-110
SAMPLE DUPLICATE: 772874
92119129001 Dup
Parameter Units Result Result RPD Qualifiers
Nitrogen, Ammonia mg/L 1.1 1.1 2
SAMPLE DUPLICATE: 772876
92119366008 Dup
Parameter Units Result Result RPD Qualifiers
Nitrogen, Ammonia mg/L 1.4 1.4 0
Date. 06/06/2012 08:47 AM REPORT OF LABORATORY ANALYSIS Page 21 of 28
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

aceAna&1iGal e
/ ,o•arNe mrn
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project:
WASTEWATER EFF PPA 5/21
Pace Project No.:
92119138
QC Batch:
WETA/12234 Analysis Method: EPA 351.2
QC Batch Method:
EPA 351.2 Analysis Description: 351.2 TKN
Associated Lab Samples:
92119138001
METHOD BLANK: 771457
Associated Lab Samples: 92119138001
Parameter Units
Nitrogen, Kjeldahl, Total
mg/L
LABORATORY CONTROL SAMPLE:
Parameter
771458
Units
Nitrogen, Kjeldahl, Total
mg/L
MATRIX SPIKE SAMPLE:
Parameter
771459
Units
Nitrogen, Kjeldahl, Total
mg/L
MATRIX SPIKE SAMPLE:
Parameter
771461
Units
Nitrogen, Kjeldahl, Total
mg/L
SAMPLE DUPLICATE: T71460
Parameter
Units
Nitrogen, Kjeldahl, Total
ni
SAMPLE DUPLICATE: 771462
Parameter
Units
Nitrogen, Kjeldahl, Total
mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
NO 0.50 06/02/12 08:59
Spike LCS LCS %Rec
Conc. Result %Rec Limits Qualifiers
10 10.0 100 90-110
92119148001
Spike
MS
MS
% Rao
Result
Conc.
Result
%Rec
Limits Qualifiers
46.1
10
63.3
172
90-110 J(M1)
92119368002
Spike
MS
MS
% Rec
Result
Core.
Result
%Rec
Limits Qualifiers
9.6
10
24.4
148
90-110 i(MI)
92119493001
Dup
Result
Result
RPD
Qualifiers
320
304
5
92119366003
Dup
Result
Result
RPD
Qualifiers
NO
NO
Date: D6/06/201208:47AM REPORT OF LABORATORY ANALYSIS Page 22of28
This report shall rot be reproduced, except in full.
without the written consent of Pace Analytical Services, Inc..

e
ceAnalytical
,Y,�n PBGMOSC9T
Pace Analytical services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services. Inc.
2225 Riverside Dr.
Asheville, INC 28804
(828)2547176
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875 'J092
Project:
WASTEWATER EFF PPA 5/21
Pace Project No.:
92119138
QC Batch:
WETA112184
Analysis Method: EPA 353.2
QC Batch Method:
EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92119138001
METHOD BLANK:
768222
Matrix: Water
Associated Lab Samples: 92119138001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate
mg/L
ND 0.20
05/23/12 19:40
Nitrogen, Nitrite
mg/L
NO 0.10
05(23/12 19:40
Nitrogen, NO2 plus NO3
mg/L
NO 0.20
05/23112 19:40
LABORATORY CONTROL SAMPLE: 768223
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L 5 5.1 103 90-110
Nitrogen, Nitrite mg(L 1 0.93 93 90-110
Nitrogen, NO2 plus NO3 mg/L 5 5.1 103 90-110
MATRIX SPIKE SAMPLE:
768224
92119115004 Spike
MS MS %Rec
Parameter
Units
Result Conc.
Result %Rec Limits Qualifiers
Nitrogen, Nitrate
mg(L
NO 5
5.9 118 90-110 J(M1)
Nitrogen, Nitrite
mg/L
NO 1
1.0 101 90-110
Nitrogen, NO2 plus NO3
mglL
NO 5
5.9 118 90-110 J(M1)
SAMPLE DUPLICATE: 768225
92119115004 Dup
Parameter Units Result Result RPD Qualifiers
Nitrogen, Nitrate mg/L ND NO
Nitrogen, Nitrite mg/L NO ND
Nitrogen, NO2 plus NO3 mg/L NO ND
Date: 06/06/2012 08:47 AM REPORT OF LABORATORY ANALYSIS Page 23 of 28
This report shall not be reproduced, except In full,
wrlhout the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc.
' 205 East Meadow Road - Suite A 2225 Riverside Dr. 9800 Kinsey Ave. Suite 100
0Am `/r�► icaI Eden, NC 27288 Asheville, NC 28804 Huntemville, NC 29078
.�.wpamNos.axr,
[phone] (e2e)254-I176 [phone]
QUALITY CONTROL DATA
Project: WASTEWATER EFF PPA 5/21
Pace Project No.: 92119138
QC Batch: WETA/12227 Analysis Method: EPA 365.1
OC Batch Method: EPA 365.1 Analysis Descripbon: 365.1 Phosphorus, Total
Associated Lab Samples: 92119138001
METHOD BLANK: 771354 Matrix: Water
Associated Lab Samples: 92119138001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phosphorus mg/L NO 0.050 0610111212:51
LABORATORY CONTROL SAMPLE: 771365
Spike LCS LCS %Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Phosphorus mg/L 2.5 2.6 102 90-11D
MATRIX SPIKE SAMPLE: 771356
92118638003 Spike MS MS %Rec
Parameter Units Result Cone. Result %Res Limits Qualifiers
Phosphorus mg/L 0.14 2.5 3.2 123 90-110 J(M1)
MATRIX SPIKE SAMPLE: 771358
921188840D2 Spike MS MS % Rao
Parameter Units Result Cont. Result %Rec Limits Qualifiers
Phosphorus mg/L 0.54 2.5 3.1 104 90-110
SAMPLE DUPLICATE: 771
Parameter
Phosphonus
92118636003 Dup
Units Result Result
mg/L 0.14 0.15
RPD Qualifiers
6
SAMPLE DUPLICATE: 771359
92118884002 Dup
Parameter Units Result Result RPD Qualifiers
Phosphorus mg/L 0.54 0.55 1
Date: 06/06/201208:47 AM REPORT OF LABORATORY ANALYSIS Page 24 of 28
This report shall not be reproduced, except in full,
without the wriaen consent of Para Analytical Services. Inc..

_!PaceAnalytical e
wwwpacerebs "
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
1828)2544176
QUALITY CONTROL DATA
Project: WASTEWATER EFF PPA 5/21
Pace Project No.: 92119138
OC Batch: WETA112214 Analysis Method: EPA 420.4
QC Batch Method: EPA 420.4 Analysis Description: 420.4 Phenolics
Associated Lab Samples: 92119138001
Pace Analytical Services, Inc.
9600 Kincey Ave. Suite 100
Huntersvllle. NC 28078
[phone]
METHOD BLANK: 769867
Matrix: Water
Associated Lab Samples: 92119138001
Blank Reporting
Parameter
Units
Result Limit
Analyzed
Qualifiers
Phenol
mg1L
ND 0.010
05/31/12 11:10
LABORATORY CONTROL SAMPLE:
769868
Spike LCS
LCS
%Rec
Parameter
Units
Conc. Result
%Rec
Limits Qualifiers
Phenol
mg/L
.1 0.098
98
90-110
MATRIX SPIKE SAMPLE:
769870
92118587002 Spike
MS
MS
% Rec
Parameter
Units
Result Conc.
Result
% Rec
Limits Qualifiers
Phenol
mg/L
0.010 .1
0.087
77
90-110 J(M1)
MATRIX SPIKE SAMPLE: 769872
92119435002 Spike MS MS % Rec
Parameter Units Result Conc. Result % Rec Limits Oualifiers
Phenol mg/L 0.056 .1 0.20 140 90-110 J(Ml)
SAMPLE DUPLICATE: 769869
92118587002 Dup
Parameter Units Result Result RPD Qualifiers
Phenol mg/L 0.010 0.011 7
SAMPLE DUPLICATE: 769871
92119435002 Dup
Parameter Units Result Result RPD Qualifiers
Phenol mg/L 0.056 0.036 45 J(R1)
Date: 06/06/2012 08:47 AM REPORT OF LABORATORY ANALYSIS Page 25 of 28
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

i &Wcal
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27280
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: WASTEWATER EFF PPA 5/21
Pace Project No.: 92119138
QC Batch: WETA/12233 Analysis Method: SM 4500-CN-E
QC Batch Method: SM 4500-CN-E Analysis Description: 450OCNE Cyanide, Total
Associated Lab Samples: 92119138001
METHOD BLANK: 771451 Matrix: Water
Associated Lab Samples: 92119138001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Cyanide mg/L ND
LABORATORY CONTROL SAMPLE: 771452
Spike
Parameter Units Conc.
Cyanide mg/L .1
Pace Analytical Services, Inc.
9800 Kinsey Ave. Suite 100
Huntersville, NC 28078
[phone]
0.00.50 06101/1211:32
LOS LCS % Rec
Result %Rec Limits Qualifiers
0.11 107 80-120
MATRIX SPIKE SAMPLE:
771454
92119176013
Spike MS MS % Rao
Parameter
Units
Result
Conc. Result %Res Limits Qualifiers
Cyanide
mg/L
ND
.1 0.093 89 75-125
SAMPLE DUPLICATE: 771453
92119176013
Dup
Parameter
Units
Result
Result RPD Qualifiers
Cyan
L
ND
0.0056
Date: 06/06/2012 08:47 AM REPORT OF LABORATORY ANALYSIS Page 26 of 28
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

,I�Z
WWwp�0.GOT
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pau Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 21IN4
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: WASTEWATER EFF PPA 5/21
Pace Project No.: 92119138
Pace Analytical Services, Inc.
9800 IOncey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
92119138001
WASTEWATER EFF
EPA 1664A
GCSV/12070
92119138001
WASTEWATER EFF
EPA 200.7
MPRP/10650
EPA 200.7
92119139001
WASTEWATER EFF
EPA 245.1
MERP/4249
EPA 245.1
92119139001
WASTEWATER EFF
EPA 625
0EXT117593
EPA 625
92119138001
WASTEWATER EFF
EPA 624
MSV/19265
92119138001
WASTEWATER EFF
SM 2540C
WET/20951
92119138001
WASTEWATER EFF
EPA 350.1
WETA/12254
92119138001
WASTEWATER EFF
EPA 351.2
WETA/12234
92119138001
WASTEWATER EFF
EPA 353.2
WETA/12184
92119138001
WASTEWATER EFF
EPA 365.1
WETA/12227
92119138001
WASTEWATER EFF
EPA 420.4
WETA/12214
92119135001
WASTEWATER EFF
SM 4500-CN-E
W ETA/12233
Analytical
Batch
ICP/9796
MERC/4170
MSSV/6315
Date: 06106/2012 08:47 AM REPORT OF LABORATORY ANALYSIS Page 28 of 28
This report shall not ce reproduced, except in full.
without the written consent of Pace Analytical Services, Inc..

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CHAIN -OF -CUSTODY / Analytical Request Document
The Chrhrof-Custody is a LEGAL DOCUMENT. AI relevant fields must he comdeted amuralely
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.ar°—e 10 uu a iWs a 1 sw Paf m°nm a .. na ww.,hm 30 aan F-ALL-0-020rev.07, 15.

aceAnalylical e
..PeoWea
January 19, 2011
Mr. Hubert Whitehead
ToWn of Tarboro
506 Dowd Street
PO Box 220
Tarboro, NC 27886
RE: Project: PPA 1/6/11
' Pace Project No.: 9285382
Dear Mr. Whitehead:
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on January 06, 2011.
The results relate only to the samples included in this report. Results reported herein conform to the
most current NELAC standards, where applicable, unless otherwise narrated in the body of the
report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
7Sinc ly,
1
rri atP ton
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 28

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
2225 Riverside Of. 9800 Kincey Ave. Suite 100
aceAnaiytical Asheville, NC 28804 Huntersville, NC 28078
w m,�
[phone] [phone]
Project: PPA 116/11
Pace Project No.: 9285382
Green Bay Certification IDs
1241 Bellevue Street, Green Bay, WI 54302
California CeAifcation #: 09268CA
Florida/NELAP Certification fk E87948
Illinois Certification #: 20DO50
Kentucky Certification #: 82
Louisiana Certification #: D4168
Minnesota Certification #: 055-999-334
New York Certification #: 11888
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersvllle, NC 28078
Louisiana/LELAP Certification #: 04034
New Jersey Certification #: NC012
North Carolina Drinking Water Certification M 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pennsylvania Certification #: 68-D0784
South Carolina Certification #: 99006001
Asheville CeNfication IDs
2225 Riverside Dr., Asheville, NC 28804
Connecticut Certification M PH-0106
Florida/NELAP Certification M E87648
Massachusetts Certification #: M-NC030
New Jersey Certification M NC011
North Carolina Bioassay Certification #: 9
North Carolina Drinking Water Certification 111: 37712
CERTIFICATIONS
New York Certification M 11888
North Carolina Certification #: 503
North Dakota Certification #: R-150
South Carolina Certification #: 83006001
US Dept of Agriculture #: S-76505
Wisconsin Certification #: 405132750
Wisconsin DATCP Certification It: 105-444
South Caroline Drinking Water Cart. M 99006003
Virginia Certification #: 00213
Connecticut Certification M PH-0104
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DHH Drinking Water # LA 100031
West Virginia Certification #: 357
North Carolina Wastewater Certification #. 40
Pennsylvania CeNfication #: 68-03578
South Carolina Bioassay Certification M 99030002
South Carolina Certification #: 99030001
Virginia Certification #: 00072
West Virginia Certification #: 356
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytcal Services, Inc..
s:
Page 2 of 28

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
2
^,Ml,,,'�e 2225 Rlverside Dr_ 9800 Kincey Ave. Suite 100
e..eea Asheville. NC 28804 Huntmsville, NC 2807e
J [phone] [phone]
Projel PPA 1/6111
Pace Project No.: 9285382
Lab ID Sample ID
9285382001 Wastewater Eff
SAMPLE ANALYTE COUNT
Method
EPA 1631 E
EPA 1664A
EPA 200.7
SM 2340B
EPA 625
EPA 624
SM 2540C
EPA 351.2
EPA 353.2
EPA 365.1
EPA 420.4
SM 4500-CN-E
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent
of Paw Analytical Services. Inc..
Analysts
GMW
EAJ
SHB
SHB
Bpi
MCK
MLM
JDA
RAB
JDA
JDA
JDA
Analytes
Reported
Laboratory
1
PASI-G
1
PASI-C
14
PASI-A
1
PASI-A
60
PASI-C
40
PASI-C
1
PASI-A
1
PASI-A
3
PASI-A
1
PASI-A
1
PASI-A
1
PASI-A
Page 3 of 28

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
e 2225 Riverside Dr. 9800 IOncey Ave. Suite 100
aceAnalytical Asheville, INC 26804 Huntersville, NC 28078
awa.yemraGa.rom
[phone] [phone]
QUALITY CONTROL DATA
Project:
WASTEWATER EFF
Pace Project No.:
9267233
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
429680
429681
MS
MSD
9267441001
Spike
Spike
MS
MSD
MS
MSD
% Rao
Parameter Units
Result
Conc.
Cone,
Result
Result
% Rec
% Roo
Umits
RPD Qual
Cadmium
ug/L
NO
500
500
493
481
98
96
70-130
2
Calcium
ug/L
2550000
2470000
3 J(MO)
Chromium
ug/L
7.5
500
500
512
500
101
99
70-130
2
Copper
ug/L
ND
500
500
506
494
101
99
70-130
2
Lead
ug/L
ND
500
5DO
465
453
93
91
7D-130
3
Magnesium
ug/L
494000
479000
3 J(MO)
Nickel
ug/L
ND
500
500
394
304
79
77
70-130
3
Selenium
ug/L
214
500
500
777
731
113
103
70-130
6
Silver
ug/L
ND
250
250
286
279
113
110
70-130
2
Thallium
ug/L
40.2
500
500
442
437
80
79
70-130
1
Zinc
ug/L
ND
500
5DO
497
479
99
96
70-130
4
SAMPLE DUPLICATE: 429682
Parameter
Units
9267255001
Result
Dup
Result
RPD Qualifiers
Antimony
ug/L
ND
ND
Arsenic
ug/L
ND
ND
Beryllium
ug/L
ND
ND
Cadmium
ug/L
ND
ND
Calcium
ug/L
3.2 mg/L
3250
3
Chromium
ug/L
ND
.451
Copper
ug/L
0.27 mg/L
28D
3
Lead
ug/L
0.037 mg/L
37.3
2
Magnesium
ug/L
1.7 mg/L
1740
3
Nickel
ug/L
0.0085 mg/L
10.4
20
Selenium
ug/L
ND
5.21
Silver
ug/L
0.083 mg/L
78.5
5
Thallium
ug/L
ND
ND
Zinc
ug/L
0.033 mg/L
32.7
0
late: 04/26/2010 04:59 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
r(LL�Pl.ii
Page 9 of 25

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
Ce ^,�„I, y,�, I ® 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
/'V /Q Am Asheville. NC 28804 Huntersville, NC 28078
1 [phone] (704(875-9092
QUALITY CONTROL DATA
Project: WASTEWATER EFF
Pace Project No.: 9267233
QC Batch: MERP/2765 Analysis Method: EPA 245.1
QC Batch Method: EPA 245.1 Analysis Description: 245.1 Mercury
Associated Lab Samples: 9267233001
METHOD BLANK: 428949
Associated Lab Samples: 9267233001
Parameter Units
ug/L
Mercury
Matrix: Water
Blank Reporting
Result Limit Analyzed QuallBers
ND 0.20 04/16/10 21:21
LABORATORY CONTROL SAMPLE: 428950
Spike LCS LOS % Rec
Parameter Units Cori Result % Rec Limits Qualifiers
Mercury ug/L 2.5 2.5 100 85-115
MATRIX SPIKE 8 MATRIX SPIKE DUPLICATE: 428951
428952
MS
MSD
9267110001
Spike
Spike MS
MSD MS MSD % Rec
Parameter Units Result
Conc.
Conc. Result
Result %Rec %Rec Limits RPD Qual
Mercury ug/L NO
2.5
2.5 NO
2.5 -2 97 70-130 J(M0)
SAMPLE DUPLICATE: 428953
Parameter
Mercury
late: 04/26/2010 04:59 PM
9267173001 Dup
Units Result Result
ug/L ND NO
RPD Qualifiers
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced. except in full,
without the written consent of Pace Analytical Services, Inc..
Page 10 of 25

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
/���/r�►j/��/• 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
Ce^t '�.1'r•`a Asheville, NC 28804 Huntersvile, NC 28078
rW-P as6naaan
[phone] [phone]
QUALITY CONTROL DATA
Project: WASTEWATER EFF
Pace Project No.: 9267233
QC Batch: OEXT/97'/1 Analysis Method: EPA 625
QC Batch Method: EPA 625 Analysis Description: 625 MSS
Associated Lab Samples: 9267233001
METHOD BLANK: 430941
Associated Lab Samples:
Parameter
9267233001
Matrix:
Blank
Units Result
Water
Reporting
Limit
Analyzed
1,2-Dichlorobenzene
ug/L
NO
5.0
04/23/10 21:33
1,2-Diphenyihydrazine
ug/L
NO
5.0
04/2311021:33
1,3-Oichlorobenzene
ug/L
NO
5.0
042311021:33
1,4-Dichlorobenzene
ug/L
NO
5.0
04/23/1021:33
2,4,6-Tdchlomphenol
ug/L
NO
10.0
04/23/1021:33
2,4-DicNorophenol
ugll
NO
5.0
04/2311021:33
2,4-Dimethylphenol
ug/L
NO
10.0
04/2311021:33
2,4-Dinitmphenol
ug/L
NO
50.0
0423/1021:33
2,4-DiNtrotoluene
ug/L
NO
5.0
04/23/1021:33
2,6-Dinitrotoluene
ug/L
NO
5.0
04/2311021:33
2-Chlomnaphthalene
ug/L
NO
5.0
04/2311021:33
2-Chlorophenol
ug/L
NO
5.0
04/2311021:33
2-Nitrophenol
ug/L
NO
6.0
04123/1021:33
3,T-Dichlorober ldine
ug/L
NO
5.0
04/2311021:33
4,6-Dinitro-2-methylphenol
ug/L
NO
20.0
04/2311021:33
4-Bromophenylphenyl ether
ug/L
NO
5.0
0412311021:33
4-Chbro-3-methylphenol
ug/L
NO
5.0
0412311021:33
4-Chlorophenylphenyl ether
ug/L
NO
5.0
042311021:33
4-Nltrophenol
ug/L
NO
50.0
042311021:33
Acenaphthene
ug/L
NO
5.0
04=1021:33
Acenaphthylene
ug/L
NO
5.0
04123/1021:33
Anthracene
ug/L
NO
5.0
0423/10 21:33
Benzo(a)anthracene
ug/L
NO
5.0
0423/10 21:33
Benzo(a)pyrene
ug/L
NO
5.0
0423/10 21:33
Benzo(b)fluoranthene
ug/L
NO
5.0
0423110 21:33
Benzo(g,h,i)perylene
ug/L
NO
5.0
04/23/1021:33
Benzo(k)fluoranthene
ug/L
ND
5.0
04123/1021:33
bis(2-Chloroethoxy)methane
ug/L
ND
10.0
04/2311021:33
bis(2-Chloroethyl) ether
ug/L
NO
5.0
042311021:33
bis(2-Chloroisopropyl) ether
ug/L
ND
5.0
04/2311021:33
bis(2-Ethylhexyl)phthalate
ug/L
ND
5.0
04/23/1021:33
Butylbenzylphthalate
ug/L
ND
5.0
0423/1021:33
Chrysene
ug/L
ND
5.0
04123/1021:33
Di-n-butylphthelate
ug/L
NO
5.0
0423110 21:33
DI-noctylphlhalate
ug/L
NO
5.0
04/23/10 21:33
Dibenz(a,h)anthfacene
ug/L
NO
5.0
0423110 21:33
Diethylphthalate
ug/L
NO
5.0
04/23/1021:33
Dimethylphthalate
ug/L
NO
5.0
04/23/10 21:33
Fluoranthene
ug/L
NO
5.0
04123/1021:33
Fluorene
ug/L
NO
5.0
04123110 21:33
Hexachlorobenzene
ug/L
NO
5.0
04/23/10 21:33
Hexachlorocyclopentadiene
ug/L
NO
10.0
0412311021:33
Hexachloroethane
ug/L
ND
5.0
04/23/10 21:33
)ate:0426/201004:59PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except
in full,
without the written consent of Pace Analytical
Services, Inc -
Qualifiers
Page 11 of 25
(

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalyticai a 2225 Riverside Dr. 9800 IOncey Ave. Suite 100
Asheville, NC 28804 Huntersville, NC 28078
�wvpwNe6tmn
[phone] [phone]
QUALITY CONTROL DATA
Project: WASTEWATER EFF
Pace Project No.: 9267233
METHOD BLANK: 430941
Matrix:
Water
Associated Lab Samples: 9267233001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Indeno(1,2,3-cd)pyrene
ug/L
ND
5.0
04/2311021:33
Isophorone
ug/L
NO
10.0
04/2311021:33
N-Nhroso-di-n-propylamine
ug/L
NO
5.0
04/2311021:33
N-Nitrosodimethylamine
ug/L
NO
5.0
04/2311021:33
N-Nitrosodiphenylamine
ug/L
ND
10.0
0412311021:33
Naphthalene
ug/L
ND
5.0
04/23/10 21:33
Nitrobenzene
ug/L
NO
5.0
0412311021:33
Pentachlorophencl
ug/L
NO
25.0
0423/1021:33
Phenanthrene
ug/L
ND
5.0
042311021:33
Phenol
ug/L
ND
5.0
042311021:33
Pyrene
ug/L
ND
5.0
0423/1021:33
2,4,6-Tribromophenol(S)
%
71
10-137
042311021:33
2-Fluorobiphenyl (S)
%
38
15.120
0423110 21:33
2-Fluorophenol IS)
%
25
10-120
042311021:33
Nitrobenzene-d5(S)
%
38
10-120
0412311021:33
Phenol-d6(S)
%
16
10.120
04/2311021:33
Terphenyl-d14 (S)
%
77
11-131
0423/10 21:33
LABORATORY CONTROL SAMPLE:
Parameter
430942
Units
Spike
Conc.
LCS
Result
LOS
%Rec
% Rec
Limits Qualifiers
1,2-DicNorobenzene
ug/L
50
22.9
46
32-129
1,2-Diphenylhydrazine
ug/L
50
40.3
81
25-150
1,3-Dichlorobenzene
ug/L
50
21-5
43
1-172
1,4-Di0lorobenzene
ug/L
50
22.0
44
20-124
2.4,6-Trichlorophenol
ug/L
50
35.9
72
37-144
2,4-Dichlorophenol
ug/L
50
34.7
69
1-191
2,4-Dimethylpheml
ug/L
50
32.1
64
32-119
2,4-Dinitrophenol
ug/L
250
159
64
1-181
2,4-Dnitrotoluene
ug/L
50
37.9
76
39-139
2,6-Dinitrotoluene
ug/L
50
38.0
76
50-158
2-Chloromphthalene
ug/L
50
32.8
66
60-118
2-Chlorophenol
ug/L
50
28.8
58
23-134
2-Nirophenol
ug/L
50
32.2
64
29-182
3,3'-Dichlorobenzidine
ug/L
250
168
67
1-262
4,6-Dinitro-2-methylphenol
ug/L
1D0
82.1
82
1-181
4-Bromophenylphenyl ether
ug/L
50
34.3
69
53-127
4-Chloro-3-methylphenol
ug/L
100
76.9
77
22-147
4-Chlorophenylphenyl ether
ug/L
50
33.7
67
25-168
4-Nitrophenol
ug/L
250
92.4
37
1-132
Acenaphthene
ug/L
50
34.9
70
47-145
Acenaphthylene
ug/L
50
34.8
70
33-145
Amhracene
ug/L
50
38.4
77
1-166
Bemo(a)anthracene
ug/L
50
37.4
75
33-143
Benzo(a)pyrene
ug/L
50
34.3
69
17-163
)ate: 04/26/2010 04:59 PM REPORT OF LABORATORY ANALYSIS Page 12 of 25
This report shall not be reproduced, except in full,
without the written consent ofPace
Analytical Services, Inc..
Y

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
A^,�I- i% , I • 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
ICI g Asheville, NC 28804 Hunlersvide, NC 20078
w.wpeceHexmn
I [phone] [phone]
QUALITY CONTROL DATA
Project: WASTEWATER EFF
Pace Project No.: 9267233
LABORATORY CONTROL SAMPLE: 430942
Spike
LCS
LCS
% Rea
Parameter
Units
Conc.
Result
%Rec
Limits
Qualifiers
Benzo(b)fluoranthene
ug/L
50
36.2
70
24-159
Benzo(g,h,i)perylene
ug/L
50
35.9
72
1-219
Benzo(k)Auoranthene
ug/L
50
34.9
70
11-162
bis(2-Chloroethoxy)methane
ug/L
50
31.7
63
33.184
bis(2-Chloroethyl) ether
ug/L
50
30.0
60
12-158
bis(2-Chloroisopropyi) ether
ug/L
50
30.6
61
36-166
bis(2-Ethylhexyl)phthalate
ug/L
50
38.6
77
B-158
Bulylbenzylphthalate
ug/L
50
37.4
75
1-152
Chrysene
ug/L
50
36.2
72
17-168
Dl-n-butylphthalate
ug/L
50
38.2
76
1-118
Di-n-octylphthalate
ug/L
50
40.4
81
4-146
Dibenz(a,h)anthracene
ug/L
50
34.1
68
1-227
Diethylphthalate
ug/L
50
36.5
73
1-114
Dimethylphthalate
ug/L
50
34.3
69
1-112
Fluoranthene
ug/L
50
38.7
77
26-137
Fluorene
ug/L
50
36.8
74
59.121
Hexachlorobenzene
ug/L
50
37.2
74
1-152
Hexachlorocyclopentadiene
ug/L
50
25.2
50
25-150
Hexachloroethane
ug/L
50
20.2
40
40-113
Indeno(1,2,3-od)pyrene
ug/L
50
34.6
69
1-171
Isophorone
ug/L
50
35.2
70
21-196
N-Nitrosot)i-n-propylamine
ug/L
50
36.5
73
1-230
N-Nitrosodimethylamine
ug/L
50
19.3
39
25-150
N-Nitrosodiphenylamine
ug/L
60
37.6
75
25-150
Naphthalene
ug/L
50
26.6
53
21-133
Nitrobenzene
ug/L
50
30.1
60
35180
Pentachlorophenol
ug/L
250
174
70
14-176
Phenanthrene
ug/L
50
36.7
73
54-120
Phenol
ug/L
50
14.3
29
5-112
Pyrene
ug/L
50
36.5
73
52-115
2,4,6-Tribromophenol (S)
%
75
10-137
2-Fluorobiphenyl(S)
%
60
15-120
2-Fiuorophenol IS)
%
34
10-120
Nitrobenzene-c15 (S)
%
58
10-120
Phenol-d6 (S)
%
24
10-120
Terphenyl-d 14(S)
%
71
11-131
MATRIX SPIKE 8 MATRIX SPIKE DUPLICATE:
430943
430944
MS
MSD
9267364002
Spike
Spike
MS
MSD
MS MSD % Rec
Parameter
Units
Result
Cana.
Cone.
Result
Result %Rec %Rec Limits RPD Qual
1,2-Dichiorobenzene
U91L
ND
102
102
54.0
70.5
53
69 32-129 27
1,2-Diphenyihydrazine
ug/L
ND
102
102
89.2
102
87
100 25-150 13
1,3-Oichiorobenzene
ug(L
ND
102
102
51.0
67.4
50
66 1.172 28
1,4-Dichiorobenzene
uWL
ND
102
102
51.5
67.8
50
66 20-124 27
2,4,6-Trichlonaphenol
ug/L
ND
102
102
68.9
85.3
68
84 37-144 21
2,4-Dichlorophenol
ug/L
ND
102
102
63.7
90.0
62
88 1-191 34 J(R1)
)ate: 04r26=110 D4:59 PM
REPORT
OF LABORATORY
ANALYSIS
Page 13 of 25
This report shall not be reproduced, e.cept in full,
without the written consent of Pace Analytical Services, Inc
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Pace Analytical Services, Inc. Paw Analytical services, Inc.
° 2225 Riverside Dr. 980010ncey Ave. Suite 100
ceAnalytical Asheville. NC 28804 Huntersville, NC 28078
wewgcNMs.mm
j (82e)254-7176 p04je75-9092
QUALITY CONTROL DATA
Project: WASTEWATER EFF
Pace Project No.: 9267233
MATRIX SPIKE 8 MATRIX SPIKE DUPLICATE: 430943
430944
MS
MSD
9267364002
Spike
Spike
Ms
MSD MS
MSD
% Rec
Parameter Units Result
Cone.
Cono.
Result
Result % Rao
% Rec
Limits RPD Qual
Pyrene ug/L ND
102
102
83.2
86.2 82
84
52-115 4
2,4,6-Tdbromophenol (S) %
82
83
10-137
2-Fluorobiphenyl(S) %
52
73
15-120
2-Fluorophenol(S) %
49
63
10-120
Nitrobenzene-d15(S) %
58
78
10-120
Phenol-c16 (S) %
38
53
10-120
TerphenyW14(S) %
78
81
11-131
Date: 04/26/2010 04:59 PM REPORT OF LABORATORY ANALYSIS Page 15 cf 25
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
"s

CAnalytical'
wew,0eeersEseam
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
QUALITY CONTROL DATA
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville. NC 28078
[phone]
Project:
WASTEWATER EFF
Pace Project No.:
9267233
QC Batch:
MSV/10612 Analysis Method: EPA 624
QC Batch Method:
EPA 624 Analysis Description: 624 MSV
Associated Lab Samples: 9267233001
METHOD BLANK: 428478 Matrix: Water
Associated Lab Samples: 9267233001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
1,1,1-Tdchloroethane
ug/L
NO
5.0
04115/1011:16
1,1,2,2-Tetrachloroethane
ug/L
NO
5.0
04/15110 11:16
1, 1,2-Tdchloroethane
ug/L
NO
5.0
04/15110 11:16
1,1-Dichloroethane
ug/L
NO
5.0
04/15/1011:16
1,1-Dichloroethene
ug/L
NO
5.0
04/15/1011:16
1,2,4-Trichlorobenzene
ug/L
NO
5.0
04/15110 11:16
1,2-DChlorobenzene
ug/L
NO
5.0
04/15/10 11:16
1,2-Dichloroethane
ug/L
NO
5.0
04/15/1011:16
1,2-Dichloropropane
ug/L
NO
5.0
04115/1011:16
1,3-Dichlorobenzene
ug/L
NO
5.0
04/15/10 11:16
1,4-Dichlorobenzene
ug/L
NO
5.0
04/15/1011:16
2-Chloroethylvinyl ether
ug/L
NO
10.0
04/15/10 11:16
Acrolein
ug/L
ND
100
04/15/1011:16
Acrylonitrile
ug/L
NO
100
04/15/1011:16
Benzene
ug/L
NO
5.0
04/15/10 11:16
Bromodichloromethane
uglL
NO
5.0
04/15/1011:16
Bromoform
ug/L
NO
5.0
04/1511D 11:16
Bromomethane
ug/L
NO
10.0
04/15/1011:16
Carbon tetrachloride
ug/L
NO
5.0
04116/1011:16
Chlorobenzene
ui
NO
5.0
04/15(10 11:16
Chloroethane
ug/L
NO
10.0
04/15/10 11:16
Chloroform
ug/L
NO
5.0
04/15(1011:16
Chloromethane
tg/L
NO
5.0
0411511011:16
cis-1,3-DIchloropropene
ug/L
NO
5.0
04/15/1011:16
Dibromochloromethane
ug/L
NO
5.0
04/15/1011:16
Ethylbenzene
ug/L
NO
5.0
04/15/10 11:16
HexacNoro-1,3-butadiene
ug/L
NO
5.0
M15110 11:18
Methylene Chloride
ug/L
ND
5.0
04/15/10 11:16
Naphthalene
ug/L
NO
5.0
04/15/1011:16
Tetrachloroethene
ug/L
NO
5.0
04/1511011:16
Toluene
ug/L
NO
5.0
04/15/10 11:16
trans-1,2-Dichloroethene
ug/L
NO
6.0
04/15110 11:16
trans-1,3-Dichloropropene
ug/L
NO
5.0
04/15/10 11:16
Trichloroethene
ug/L
NO
5.0
04/15/1011:16
Trichlorofluoromethane
ug/L
NO
10.0
0411511011:16
Vinyl chloride
ug/L
NO
5.0
04/16/10 11:16
1,2-Dichloroethane-d4 (S)
%
104
70-130
04/15/10 11:16
4-Bromofluorobenzene (S)
%
97
86-111
04/15/10 11:16
Dibromofluoromethane (S)
%
102
88-113
04/15/10 11:16
Toluene-d8(S)
%
100
92-105
04/15/10 11:16
)ate: 04/26/201004:59 PM REPORT OF LABORATORY ANALYSIS Page 16 of 25
This report shall not be reproduced, except in full,
without the written consent of PP�acee. Analytical Services, Inc..

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
e 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
ace Analytical Asheville, NC 28804 Hunterevllle, NC 28078
wwwpseebDa.mm
(828)2547176 [phone]
QUALITY CONTROL DATA
Project: WASTEWATER EFF
Pace Project No.: 9267233
LABORATORY CONTROL SAMPLE: 428479
Parameter
Units
Spike
Cone.
LCS
Result
LCS
%Rec
% Rec
Limits Qualifiers
1,1,1-Trichloroethane
ug/L
20
23.6
118
52-162
1,1,2,2-Tetrachloroethene
ug(L
20
19.7
98
46-157
1,1,2-Trichloroethane
ug/L
20
21.0
105
52-150
1,1-Dichloroethane
ug/L
20
23.4
117
59-155
1,1-Dichloroethene
ug/L
20
26.1
131
1-234
1,2,4-Trichlorobenzene
ug/L
20
23.3
116
7D-130
1,2-Dichlorobenzene
ug/L
20
21.2
1D6
18-190
1,2-Dichloroethane
ug/L
20
22.5
112
49-155
1,2-DicNoropropane
ug/L
20
21.4
107
1-210
1,3-Dichlorobenzene
ug/L
20
20.8
104
59-156
1,4-Dichlorobenzene
ug/L
20
20.7
103
18-190
2-Chloroethylvinyl ether
uglL
40
42.7
107
1-305
Benzene
ug/L
20
22.3
111
37-151
Bromodlchloromethane
ug/L
20
20.6
103
35-155
Bromoform
ug/L
20
19.9
100
45-169
Bromomethane
ug/L
2D
16.8
84
1-242
Carbon tetrachloride
ug/L
2D
27.6
138
70-140
Chlorobenzene
ug/L
20
21.5
108
37-160
CNoroethane
ug/L
20
21.2
106
14-230
Chloroform
ug/L
20
21.5
107
51-138
Chloromethane
ug/L
20
18.6
93
1-273
cis-1,3-Dichloropmpene
ug/L
20
21.3
107
1-227
Dibromochloromethane
ug/L
20
20.9
104
53-149
Ethylbenzene
ug/L
20
21.1
106
37-162
Hexachloro-1,3-butadiene
ug/L
20
27.8
139
70-130 L3
Methylene Chloride
ug/L
20
21.1
105
1-221
Naphthalene
ug/L
20
22.7
114
70-130
7etrachioroethene
ug/L
20
21.6
108
64-148
Toluene
ug/L
20
21.1
106
47-150
trans-1,2-Dichloroethene
ug/L
20
22.5
113
54-156
trans-1,3-Dichloropropene
ug/L
20
20.6
103
17-183
Trichloroethene
ug/L
20
22.0
110
71-157
TricNorofluoromethane
ug/L
20
19.5
98
17-181
Vinyl chloride
ug/L
20
18.8
94
1-251
12-0ichloroethane-0(S)
%
1D6
70-130
4-Bromofluorobenzene (S)
%
100
86-111
Dibromofluoromethane (S)
%
101
88-113
Toluene-d8 (S)
%
99
92-105
MATRIX SPIKE 8 MATRIX SPIKE DUPLICATE:
42848D
428481
MS
MSD
9266914004
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conic.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
1,1,1-Trichloroethane
ug/L
NO
20
20
23.1
23.5
116
118
46-171
2
1,1,2,2-Tatrachioroethane
ug/L
NO
20
20
20.2
21.0
101
105
73-159
4
1,1,2-Trichloroethane
ug/L
NO
20
20
20.3
21.8
101
109
64-152
7
1,1-0ichloroethane
ug/L
ND
20
20
22.6
23.6
113
118
43-172
4
)ate: 04/26/2010 04:59 PM REPORT OF LABORATORY ANALYSIS Page 17 of 25
This report shall not be reproduced. except in full,
without the wraten consenttoof Pace Analytical Services, Inc
x"" 2

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Pace Analytical Services, Inc. Pace Analytical Services, Inc.
�ri
• 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
CeA�1*ica� Asheville, NC 28804 Huntersville. NC 28078
awnpaolha amn
[phone] [phone]
QUALITY CONTROL DATA
Project: WASTEWATER EFF
Pace Project No.: 9267233
QC Batch: WET/12052 Analysis Method: SM 2540C
GC Batch Method: SM 2540C Analysis Description: 2540C Total Dissolved Solids
Associated Lab Samples: 9267233001
METHOD BLANK: 428658 Matrix: Water
Associated Lab Samples: 9267233001
Blank Reporting
Parameter UNts Result Limit Analyzed Qualifiers
Total Dissolved Solids mg/L ND 20.0 04/14/1019:31
LABORATORY CONTROL SAMPLE: 428659
Parameter Units
Total Dissolved Solids ni
SAMPLE DUPLICATE: 428660
Parameter
Total Dissolved Solids
Units
mg/L
Spike LCS LCS % Rec
Conc. Result % Rec Limits Oualifers
250 246 98 80-120
9267082004 Dup
Result Result RPD Qualifiers
102 86.0 17
late: 04l26/201004:59 PM REPORT OF LABORATORY ANALYSIS Page 19 of 25
This report shall not be reproduced, except in full,
without the written consentof Pacee/Analytical Services, Inc..
Y`,

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
p���,/ • 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
ce^t Wlca' Asheville, NC 28804 Huntersville, NC 28070
wwwpecole •aan
[phone] [phone]
QUALITY CONTROL DATA
Project: WASTEWATER EFF
Pace Project No.: 9267233
QC Batch: WETA/7216 Analysis Method: EPA 351.2
QC Batch Method: EPA 351.2 Analysis Description: 351.2 TKN
Associated Lab Samples: 9267233001
METHOD BLANK: 432584
Associated Lab Samples: 9267233001
Parameter Units
Nitrogen, Kjeldahl, Total mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
NO 0.50 04/23/10 13:50
LABORATORY CONTROL SAMPLE: 432585
Spike LCS LCS % Roe
Parameter Units Cone. Result %Rec Limits Qualifiers
Nitrogen, Kjeldahl. Total mg/L 5 5.5 109 90-110
MATRIX SPIKE SAMPLE: 432586
9267224003 Spike MS MS %Rec
Parameter Units Result Cone. Result %Rec Limits Qualifiers
Nitrogen, KjeldaN, Total mg/L 2.0 5 6.8 97 90-110
SAMPLE DUPLICATE: 432587
Parameter
9267232004 Dup
Units Result Result RPD
Nitrogen, Kjeldahl, Total
mg/L 2.1 1.9 11
late: 04/2612010 04:59 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written conse{nt�t of PamAnalytical Services, Inc..
r`LLJa06.t5
Qualifiers
Page 20 of 25

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
� /r�/r/���• 2225 Riverside Dr. 9800 Kse iny Ave. Suite 100
�^r�./'�`^"' Asheville, NC 28804 Huntersville, NC 28078
.pecobt.oxv
[phone] [phone]
QUALITY CONTROL DATA
Project:
WASTEWATER EFF
Pace Project No.:
9267233
OC Batch:
WETA/7147
Analysis Method: EPA 353.2
QC Batch Method:
EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 9267233001
METHOD BLANK:
428180
Matrix: Water
Associated Lab Samples: 9267233001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate
mg/L
ND 0.10
D4113/10 23:36
Nitrogen, Nitrite
mg/L
NO 0.10
04/13110 23:36
Nitrogen, NO2 plus NO3
mg/L
NO 0.10
04113110 23:36
LABORATORY CONTROL SAMPLE: 428181
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen, Nitrate mg/L 5 4.9 99 90-110
Nitrogen, Nitrite mg/L 1 0.98 98 90-110
Nitrogen, NO2 plus NO3 mg/L 5 4.9 99 9D-110
MATRIX SPIKE SAMPLE:
428182
9267158001 Spike
MS MS %Rec
Parameter
Units
Result Conc.
Result %Rec Limits Qualifiers
Nitrogen, Nitrate
mg/L
ND 5
6.0 120 90-110 J(M0)
Nitrogen, Nitrite
mg/L
NO 1
1.2 115 90-110 Jim)
Nitrogen, NO2 plus NO3
mg/L
ND 5
6.0 120 9D-110 J(M0)
SAMPLE DUPLICATE: 428183
9267158002 Dup
Parameter Units Result Result RPD Qualifiers
Nitrogen, Nitrate mg/L 9.8 9.7 0
Nitrogen, Nitrite mg/L NO ND
Nitrogen, NO2 plus NO3 mg/L 9.8 9.7 0
)ate: 04/26/2010 D4:59 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent
of Pam Analytical Services, Inc..
?il.lCT06..1i
Page 21 of 25

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
• 2225 Riverside Dr. 9800 Kncey Ave. Suite 100
ace Analytical Asheville, NC 28804 Huntemville, NC 28078
w.n.w mr.
(828)2547176 [phone]
QUALITY CONTROL DATA
Project: WASTEWATER EFF
Pace Project No.: 9267233
QC Batch: WETAf7186 Analysis Method: EPA 365.1
QC Batch Method: EPA 365.1 Analysis Description: 365.1 Phosphorus, Total
Associated Lab Samples: 9267233001
METHOD BLANK 430551
Matrix:
Water
Associated Lab Samples: 9267233001
Blank
Reporting
Parameter
Units
Result
Limit Analyzed Qualifiers
Phosphorus
mg/L
ND
0.10 04=11011:58
LABORATORY CONTROL SAMPLE:
430552
Spike
LCS LCS % Rec
Parameter
Units
Conc.
Result %Res Limits Qualifiers
Phosphorus
mg/L
1
0.98 98 90-110
MATRIX SPIKE SAMPLE: 430553
9267571001 Spike MS MS %Rao
Parameter Units Result Conc. Result %Rec Limits Quallfers
Phosphorus mg/L 4.7 1 5.4 75 90-110 J(M0)
MATRIX SPIKE SAMPLE:
Parameter
430555
Units
9267224003
Result
Spike MS
Conc. Result
MS % Rec
%Rec Limits Qualifiers
Phosphorus
mg/L
1.5
1 2.3
81 90-110 J(M0)
SAMPLE DUPLICATE: 430554
9267571002
Dup
Parameter
Units
Result
Result RPD
Qualifiers
Phosphorus
mg/L
0.12
ND
SAMPLE DUPLICATE: 430556
9267232004 Dup
Parameter Units Result Result RPD Qualifiers
Phosphorus mg/L 6.47 0.50 6
)ate: 04/2612010 04:59 PM REPORT OF LABORATORY ANALYSIS Page 22of25
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
e.

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
�__i y.__�• 2225 Riverside Or. 9800 Kincey Ave. Suits 100
Asheville, NC 28804 Huntersville, NC 28078
ewapaceelxrm
Ce [phone] [phone]
Project: WASTEWATER EFF
Pace Project No.: 9267233
QC Batch Method: EPA 420.4
Associated Lab Samples: 9267233001
METHOD BLANK: 430887
Associated Lab Samples: 9267233001
Parameter Units
rt1gIL
Phenol
QUALITY CONTROL DATA
Analysis Method: EPA 420.4
Analysis Description: 420.4 Phenolics
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
NO 0.010 04120/1014:56
LABORATORY CONTROL SAMPLE: 430888
Spike LCS LCS %Rec
Parameter Units Conc. Result % Rao Limits Qualifiers
Phenol mg/L .25 0.23 90 90-110
MATRIX SPIKE SAMPLE:
430689
9267310001
Spike MS MS
% Rec
Parameter
Units
Result
Cone. Result %Rec
Limits Qualifiers
Phenol
mg/L
0.010
.25 0.20 77
90-110 J(M0)
SAMPLE DUPLICATE: 430890
9267233001
Dull
Parameter
Units
Result
Result RPD Qualifiers
Phenol
mg/L
NO
ND
)ate: 0426/2010 04:59 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc..
i
Page 23 of 25

Pace Analytical services, Inc. Pace Analytical Services, Inc.
�CeAmlXical*
2225 Riverside Dr. 9800 Kincey Ave. Suite 100
Asheville, NC 28804 Huntersville, NC 28078
www.pe albs cxvn
I [phone] [phone]
Project: WASTEWATER EFF
Pace Project No.: 9267233
QC Batch: WETA/7194
QC Batch Method: SM 4500-CN-E
Associated Lab Samples: 9267233001
METHOD BLANK 431022
Associated Lab Samples: 9267233001
Parameter Units
mg/L
Cyanide
QUALITY CONTROL DATA
Analysis Method: SM 4500-CN-E
Analysis Description: 450OCNE Cyanide, Total
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
NO 0.0050 04/21/1017:43
LABORATORY CONTROL SAMPLE: 431023
Spike LCS LCS % Rac
Parameter Units Conc. Result %Rec Limits Qualifiers
Cyanide ni .1 0.093 93 80-120
MATRIX SPIKE SAMPLE: 431024
9267487006 Spike MS MS % Rec
Parameter Units Result Cant. Result %Rec Limits Qualifiers
Cyanide mg/L NO .1 0.11 105 75-125
SAMPLE DUPLICATE: 431025
9267487006 Dup
Parameter Units Result Result RPD
Cyanide mg/L NO NO
)ate: 04126=10 04:59 PM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced. except in full,
without the written consent of Pam Analytical Services, Inc..
Qualifiers
Page 24 of 25

Pace Analytical Services, Inc. Pace Analytical services, Inc.
• 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
% aceAmlytical Asheville, NC 28804 Huntersville, NC 28078
xvwpeceleDswm
I [phone] [phone]
QUALIFIERS
Project: WASTEWATER EFF
Pace Project No.: 9267233
19149111101ZIZJ
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenyihydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP -Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
Pace Analytical Is NELAP accredited. Contact your Pace PM for the current list of accredited analytes.
U - Indicates the compound was analyzed for, but not detected.
ANALYTE QUALIFIERS
I The reported value is between the laboratory method detection limit and the laboratory practical quantltation limit.
J(MO) Estimated Value. Matrix spike recovery was outside laboratory control limits.
J(P5) Estimated Value. The EPA or method required sample preservation degrades this compound, therefore acceptable
recoveries may not be achieved in sample matrix spikes.
J(R1) Estimated Value. RPD value was outside control limits.
L3 Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in
associated samples. Results unaffected by high blas.
)ate: 04/26/2010 04:59 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace
Analytical services, Inc..
YLL11�:
Page 25 of 25

�P ceAnalytical
CHAIN -OF -CUSTODY / Analytical Request Document
The Chain-cf-Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Section A Sectl0n B Section C
Page: of
Required CIIent Information: Required Pmect laidwatlon: aviel Information.
Company -Town v-�T rbar R°°°"T°' eY Vr ; ea. A�"a°". u.Y� as I n CA
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Manager.
Sib Location
STATE:
Requaeted Due DateRAT:
PmRdt Number
Pep PrdftleR
Requested
Analysis
FlQared
(YIN)
Section Mal Codes
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Regalrad Clicntlydamatioo MATRIX t CODE
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DATE
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SAMPLE CONDITIONS
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Instructions for completing Chain of Custody (COC)
1. Section A and B: Complete all Client information at top of sheet: company name, address, phone, fax, contact (the person to contact if there are
questions, and who will receive the final report.), e-mail address (if available), PO#, Project Name and/or Project Number as you would like to see it
appear on the report.
2. Section C: Invoice Information: Billing information is included in this section. This information should include the name and address of the person
receiving the invoice.
3. Quote Reference should be completed if a quotation was provided by Pace Analytical. The Project Manager, and Profile No. will be completed by
Pace Analytical Services.
4. Site Location: A separate COC must be filled out for each day of sample collection. Record the two letter postal code for the US state in which the
samples were collected.
5. Regulatory Agency. List the program that is guiding the work to ensure proper regulations are followed.
6. ' Section D: Complete a Sample Description in the "SAMPLE ID' section at you would like it to appear on the laboratory report. The following
information should also be included: the sample matrix, sample type (G (grab) or C (composite). When collecting a composite. the start time and end
time should be documented in the respective boxes. The collection time for a grab (G) sample should be entered in the boxes marked -Composite
End/Grab'), Sample+temp at collection (if required by state), the total number of containers, and preservative used.
7. Mark if the sample was filtered in the field by marking Y or N in 'Filtered' row by the Analysis requested.
8. Requested Analysis: List the required analysis and methods on the lines provided and place a check in the column for the samples requiring the
analysis. Additional comments should be referenced in the bottom left hand comer or include attachments for extended lists of parameters.
9. The sampler should print their name in the space provided and sign their name followed by the date of the sampling event at the bottom of the COC in
the spaces designated for -SAMPLER NAME AND SIGNATURE'.
10. When relinquishing custody of the samples to a representative of the laboratory or other organization, indicate the Item Numbers of those samples
being transferred, sign relinquished by, date and time, and include your affiliation.
'Important Note:
Standard Turnaround Time is 2 Weeks/IO business 4aye: Results will**Avered by end of business on the date due unless other arrangements
have been made with your project manager.
Special Project Requirements such as Low Level Detection Limits or level of QC reported must be included on the chain of custody in the Additional
Comments section.
0

Subcontracted Results
Pace Project #
This report includes
page 1 to

Telephone: [phone]
Fax: [phone]
J
-� � ,,�,JTEST
6701 Conference Drive
Raleigh, NC 27607
Laboratory Report
— Prepared for ---
LORRIPATTON
PACE ANALYTICAL / ASHEVILLE
2225 RIVERSIDE DRIVE
ASHEVILLE, NC 28804
Project No. 01
Project ID: 92119138
No. Sample ID
001 92119138001
Page 1 of 1
NCAVW Cart, 4: 067
NCIDW Cart. M 37731
Report Date: 5/31/2012
Date Received: 5/24/2012
Work Orderk 1205-01627
Cust. Codes PA7176
Cust P.O.#AS9108
Date Sampled Time Sampled Matrix Sample Type Condition
5/22/2012 11:00 WW Grab Ambient
Analyzed
Test Performed
Method
Results
Date Time Qualifier
Low Level Mercury
EPA 1631
1.05 nglL
5/29/12 8:14
No. Sample ID
Date Sampled
Time Sampled Matrix
Sample Type Condition
002 92119138002
5/22/2012
11:00 OT
Grab Ambient
Analyzed
Test Performed Method Results Date Time Qualifier
Low Level Mercury EPA 1631 <1.0 ng/L 5129/12 8:14
Reviewed by:
for Tritest, Inc.

/AnaVicala
� ssw.pasNsOamn
I
October 23, 2013
Mr. Mike Allen
Town of Tarboro
506 Dowd Street
PO Box 220
Tarboro, NC 27886
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
RE: Project: PPA 1017/13
Pace Project No.: 92175127
Dear Mr. Allen:
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28004
[phone]
Pap Analytical Services, Inc.
9800 Kincey Ave. Suits 100
Huntersvills, NC 28078
(704)B75-9092
Enclosed are the analytical results for sample(s) received by the laboratory on October 08, 2013.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lord Patton
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall rot be reproduced. except in full,
without the written consent of Pace Analytical Services, Inc..

/-2ceAnalyticale
n'wrv.pacaraac Cam
r
Project: PPA 10/7/13
Pace Project No.: 92175127
Pape Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersvllle, NC 28078
North Carolina Drinking Water Certification 11137706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Asheville Certification IDs
(336{823-8921
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
CERTIFICATIONS
Flodda/NELAP Certification #: E87627
Kentucky UST Certification #: 84
West Virginia Certification #: 357
Vlrglnia/VELAP Certification #: 460221
2225 Riverside Dr., Asheville, NC 28804 North Carolina Wastewater Certification #: 40
Florda/NELAP Certification #: E87648 South Carolina Certification #: 99030001
Massachusetts Certification #: M-NCO30 West Virginia Certification #: 356
North Carolina Drinking Water Certification #: 37712 Vlrginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, eacepl In full,
will the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
96001(incey Ave. Suite 100
Huntersville, NC 28078
[phone]

/ aewpemr/eM.em
Project PPA 1017/13
Pace Project No.: 92175127
Lab ID Sample ID
92175127001 Wastewater Effluent
92175127002 Field Blank Effluent
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden. NC 27298
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville. NC 28804
[phone]
SAMPLE ANALYTE COUNT
Method
EPA 1664E
EPA 200.7
EPA 1631E
EPA 625
EPA 624
SM 2540C
EPA 350.1
EPA 351.2
EPA 353.2
EPA 365.1
EPA 420.4
SM 4500-CN-E
EPA 1631E
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, mcepl In full,
without the wd8en consent of Pace Analytical Services, Inc..
Analysts
CLW
JMW
SH1
RES
CAM
MDW
JTM
JDA
DMN
JDA
JTM
JDA
SHt
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
HUMersville, NC 28078
(704A75-9092
Analysts
Reported
Laboratory
1
PASI-C
15
PASI-A
1
PASI-A
60
PASI-C
39
PASI-C
1
PASI-A
1
PASI-A
1
PASI-A
1
PASI-A
1
PASI-A
1
PASI-A
1
PASI-A
1
PASI-A

7CeAnalytical a
1 wwwPace/aDr cwn
Project: PPA 10/7/13
Pace Project No.: 92175127
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersvllls, NC 28078
[phone]
Sample: Wastewater Effluent Lab ID: 92175127001 Collected: 10/07/13 11:00 Received: 10/08/13 18:45 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qua(
HEM, Oil and Grease
Analytical Method: EPA 16648
Oil and Grease
NO mg/L
5.0
1
10/15/13 13:00
200.7 MET ICP
Analytical Method: EPA 200.7 Preparation Method: EPA 200.7
Antimony
ND ug/L
5.0
1
10/11/13 09:25
10/1611314:05
7440-36-0
Arsenic
ND ug/L
10.0
1
10/11/13 09:25
10116/1301:38
7440-38-2
Beryllium
NO ug/L
1.0
1
10111/1309:25
10116/1301:38
744041-7
Cadmium
NO ug/L
1.0
1
10/11/13 09:25
10/16113 01:38
744D-43-9
Calcium
11000 ug/L
100
1
10/11/13 09:25
10/16/1301:38
7440-70-2
Chromium
NO ug/L
5.0
1
10/11/13 09:25
10/16/13 01:38
744047-3
Copper
NO ug/L
5.0
1
10/11113 09:25
10116/1301:38
7440-50-8
Lead
NO ug/L
5.0
1
10/11/13 09:25
10/16/13 01:38
7439.92-1
Magnesium
3100 ug/L
100
1
10/11/13 09:25
10/1611301:38
7439.95-4
Nickel
NO ug/L
5.0
1
10/11113 09:25
1011611301:38
7440-02-0
Selenium
NO ug/L
10.0
1
10/11/13 09:25
1Ott 6113 01:38
7782-49-2
Silver
ND ug/L
5.0
1
1011111309:25
10/16(1301:38
7440-22-4
Thallium
NO ug/L
10.0
1
10/11/13 09:25
10/16/13 01:38
7440-28-0
Total Hardness
40200 ug/L
662
1
10/11/13 09:25
10/16/13 01:38
Zinc
19.2 uglL
10.0
1
VV11I1309:26
10/16/1301:38
7440-66-6
1631E Memury,Low Level
Analytical Method: EPA 1631E Preparation Method:
EPA 1631E
Mercury
1.39 nglL
0.50
1
10/21/13 19:00
10IM13 13:31
7439-97-6
625 MSSV
Analytical Method: EPA 625 Preparation Method: EPA 625
Acenaphthene
NO ug/L
5.0
1
10/11/1311.50
10114/1322:07
83-32-9
Acenaphthylene
NO ug/L
5.0
1
10/11/13 11:50
10114/1322:07
208-96-8
Anthracene
NO ug/L
5.0
1
10/11/13 11:50
1011411322:07
120-12-7
Benzo(a)enthracene
NO ug/L
5.0
1
1011111311:50
10/14/1322:07
56-55-3
Senzo(a)pyrene
NO uglL
5.0
1
10/1111311.50
10114/1322:07
50-32-8
Benzo(b)fluoranthene
NO ug/L
5.0
1
10/11113 11:50
10114/1322:07
205-99-2
Benzo(g,h,i)perylene
NO ug/L
5.0
1
10/11/13 11:50
10/1411322:07
191-24-2
Benzo(k)Puoranthene
NO ug/L
5.0
1
10/11/13 11:50
10/1411322:07
207-08-9
4-Bromophenylphenyl ether
NO uglL
5.0
1
10/11113 11:50
10/14/13 22:07
101-55-3
Butylbenzylphthalate
NO ug/L
5.0
1
10/11113 11:50
10/14/13 22:07
85-68-7
4Chloro-3-methylphenol
NO ug/L
5.0
1
1011111311:50
10/14/13 22:07
59.50.7
bis(2-Chloroethoxy)methane
NO ug/L
10.0
1
10/11/1311:50
10/14/13 22:07
111-91-1
bis(2-Chlmoethyl) ether
NO ug/L
5.0
1
10/1111311:50
10/14/13 22:07
111-444
bis(2-Chloroisopropyl) ether
NO ug/L
5.0
1
10/11113 11:50
10/14113 22:07
108-60-1
2-Chloronaphthalene
NO ug/L
5.0
1
10/11/13 11:50
10/14/13 22:07
91-58-7
2Chlomphenol
NO ug/L
5.0
1
10/11113 11:50
10114/13 22:07
95-57-8
4-Chlorophenylphenyl ether
NO uglL
5.0
1
10/11113 11:50
10/14/13 22:07
7005-72-3
Chrysene
NO ug/L
5.0
1
10/1111311.50
10/14/13 22:07
218-01-9
Dibenz(a,h)anthracene
NO ug/L
5.0
1
10/11/13 11:50
10/14/1322:07
53-70-3
1,2-0Ichlorobenzene
NO ug/L
5.0
1
10/11/13 11:50
10/14/13 22:07
95-50-1
1,3-Dichlombenzene
NO ug/L
5.0
1
10/11/13 11:50
10/14/13 22:07
541.73.1
1,4-Dichlorobenzene
NO ug/L
5.0
1
10/11/13 11:50
10/14/13 22:07
106-46-7
3,3'-Dichlorobenzidine
NO ug/L
25.0
1
10/11113 11:50
10/14/13 22:07
91-94-1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 10/23/2013 12:37 PM without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc.
° 205 East Meadow ers Road - Suite A 2225 Rivide Dr. 9800 10ncey Ave. Suite 100
aceAnalytrcal Eden. NC 27288 Asheville. NC 28804 Huntarsville, NC 28078
[phone] [phone] [phone]
ANALYTICAL RESULTS
Project: PPA 1017/13
Pace PntJect No.: 92175127
Sample: Wastewater Effluent Lab IO: 92175127001 Collected: 10107/1311:00 Received: 10108/1318:45 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Dual
625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625
2,4-Dichlomphenol
NO ug/L
5.0
1
10/11113 11:50
10114/1322:07 120E32
Dlethylphthalate
NO ug/L
5.0
1
10/11/1311:50
10/14/13 22:07 84-W2
2,4-Dimethylphenol
NO ug/L
10.0
1
10111/1311:50
10/14/13 22:07 105.67-9
Oimethylphthalate
NO ug/L
5.0
1
1011111311:50
10/14/13 22:07 131-11-3
Di-n-butylphthalate
NO ug/L
5.0
1
10111/1311:50
10/14/13 22:07 84-74-2
4,6-Dinitro-2-methylphenol
NO ug/L
20.0
1
10/11113 11:50
10/14/13 22:07 534-52-1
2,4-Dinitrophenol
ND ug/L.
50.0
1
10/11113 11:50
10/14/13 22:07 51-285
2,4-Dinitrotoluene
NO ug/L
5.0
1
10/11/13 11:50
10/14/13 22:07 121-14-2
2,6-Dinitrotoluene
NO ug/L
5.0
1
10/11/13 11:60
10/14/13 22:07 60&20-2
Di-n-octylphthalate
ND uglL
5.0
1
10111/1311:50
10/1411322:07 117-84-0
1,2-Diphenylhydrazine
ND ug/L
5.0
1
10/11113 11:50
10/14/13 22:07 122E6.7
bis(2-Ethylhexyl)phthalate
NO ug/L
5.0
1
10/11/13 11:50
10/14/13 22:07 117-W-7
Fluorsnthene
NO ug/L
5.0
1
10/11113 11:50
10/14/13 22:07 20SA4-0
Fluorene
ND ug/L
5.0
1
10/11/13 11:50
10/14/13 22:07 86-73-7
Hexachlorobenzene
ND ug/L
5.0
1
10/11/1311:50
10114/1322:07 118-74-1
Hexachlorocyclopentadiene
NO ug/L
10.0
1
10/11/13 11:50
10/14/13 22:07 77474
Hexachloroethane
NO ug/L
5.0
1
1011111311:50
10/1411322:07 67-72-1
Indeno(1,2,3-cd)pyrene
ND ug/L
5.0
1
10/11/1311:50
10/14/13 22:07 193-395
Isophorone
NO ug/L
10.0
1
10/11/1311:50
10/14/13 22:07 78.59.1
Naphthalene
NO ug/L
5.0
1
10/11/1311:50
10114/1322:07 91-203
Nitrobenzene
NO ug/L
5.0
1
10/11/1311:50
10/14/13 22:07 W95-3
2-Nitrophenol
NO ug/L
5.0
1
10/11/1311:50
10114/1322:07 88-75-5
4-Nitrophenol
NO ug/L
50.0
1
10111/1311:50
10/14/13 22:07 100-02-7
N-Nitrosodimethylamine
NO uglL
5.0
1
10/11113 11:50
10/14/13 22:07 62-75.9
N-Nitroso-di-n-propylamine
ND ug1L
5.0
1
10/11113 11:50
10/14/13 22:07 621-64-7
N-Nitrosodiphenylamine
NO ug/L
10.0
1
10/11113 11:50
10/14/13 22:07 8630E
Pentechlorophenol
ND ug/L
10.0
1
10/11113 11:50
10/1411322:07 8741&5
Phenanthrene
NO ug/L
5.0
1
10/11/1311:50
10/14/13 22:07 85-01-8
Phenol
NO ug/L
5.0
1
10/11/1311:50
10114/1322:07 108-95-2
Pyrene
NO ug/L
5.0
1
10/11/1311:50
10/1411322:07 129-00-0
2,4,6-Trichlorophencl
NO ug/L
10.0
1
10/11/1311:50
10/14/13 22:07 88-06-2
Surrogates
Nitrobenzene-05 (S)
30 %
10-120
1
10/11/13 11:50
10/14/13 22:07 4165-60-0 P2
2-Fluorobiphenyl (S)
28 %
15-120
1
10/11/13 11:50
10/14/13 22:07 321-60-8
Terphenyl-d14(S)
57%
11-131
1
10/11/1311:50
1011411322:07 1718-51-0
Phenol-d6 (S)
11 %
10-120
1
10/11/13 11:50
10/14/13 22:07 13127-883
2-Fluorophenol(8)
17%
10-120
1
10/11/1311:50
10/1411322:07 367-124
2,4,6-Tribromophenol(S)
43 %
10-137
1
1011111311:50
10/1411322:07 118-79-6
624 Volatile Organics Analytical Method: EPA 624
Acrolein
ND ug/L
100
1
10/16/13 00:51
107-02-8
Acrylonitdle
ND ug/L
50.0
1
10116/1300:51
107-13-1
Benzene
NO ug/L
5.0
1
1011&1300:51
7143-2
Bromodichloromethane
NO uglL
5.0
1
10/16/13 00:51
76-274
Bromoforrn
NO ug/L
5.0
1
10/16/13 00:51
75-25-2
Bromomethane
ND ug/L
10.0
1
10116/1300:51
74-83-9
Carbon tetrachloride
NO ug/L
5.0
1
10/16/13 00:51
56-235
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 10/23/2013 12:37 PM without the written consent of Paco Analytical Services, Inc..

�eAnaocajl'_
wx-x.pecNaeo can
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2226 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pecs Analytical services, Inc.
9800 Kincey Ave. Suite 100
Huntersvilie, NC 28078
[phone]
Project: PPA 10/7113
Pace Project No.: 92175127
Sample: Wastewater Effluent
Lab ID: 92175127001 Collected: 1010711311:00 Received:
10/08/1318:45 Matrix: Water
Parameters
Results Units
Report Limit
DF Prepared
Analyzed
CAS No. 0ual
624 Volatile Organics
Analytical Method: EPA 624
Chlorobenzene
NO ug/L
5.0
1
10/1611300:51
108-90.7
Chloroethane
NO ug/L
10.0
1
10/1611300:51
75-00-3
2-Chloroethylvinyl ether
NO ug/L
10.0
1
10/1611300:51
110-75-8 J(M1)
Chloroform
ND ug/L
5.0
1
10/16/13 00:51
67-66-3
Chloromethane
NO ug/L
5.0
1
10/16/13 00:51
74.87-3
Dibromochloromethane
NO ug/L
5.0
1
10116/1300:51
124-48-1
1,2-0ihlorobenzene
NO ug/L
5.0
1
1011611300:51
95-50.1
1,3-Dichlombenzene
NO ug/L
5.0
1
10/1611300:51
541-73.1
1,4-Dichlorobenzene
NO ug/L
5.0
1
10/1611300:51
106-46.7
1,1-Dichloroethane
NO ug/L
5.0
1
10/16/13 00:51
75-34-3
1,2-Dichloroethane
NO ug/L
5.0
1
10/16/13 00:51
107-06-2
1,1-Dichloroethene
NO ug/L
5.0
1
10/16J1300:51
75-35-4
trans-1,2-Dichloroethene
NO ug/L
5.0
1
10/16/1300:51
156-60-5
1,2-Dichloropropane
NO ug/L
5.0
1
10/16/13 00:51
78-87-5
cis-1,3-Dichloropropene
NO ug/L
5.0
1
10/1611300:51
10061-015
trans-1,3-Dichloropropene
NO ug/L
5.0
1
10/16/13 00:51
10061-02-6
Ethylbenzene
NO ug/L
5.0
1
10/16/13 00:51
100414
Hexachloro-1,3-butadiene
NO ug/L
5.0
1
10/16/13 00:51
87-68-3
Methylene Chloride
NO ug/L
5.0
1
10/16M300:51
75-09-2
Naphthalene
NO ug/L
5.0
1
10116/1300:51
91-20-3
1,1,2,2-Tetrachloroethane
NO ug/L
5.0
1
10/1611300:61
79-34-5
Tetrachloroethene
NO ug/L
5.0
1
10/16/1300:51
127-18-4
Toluene
NO ug/L
5.0
1
10/16(1300:51
108-88-3
1,2,4-Trichlorobenzene
NO ug/L
5.0
1
10/16/1300:51
120.82-1
1,1,1-Trichiomethane
NO ug/L
5.0
1
10/1611300:51
71-55-6
1,1,2-Trichloroethane
NO ug/L
5.0
1
10/16/13 00:51
79-MS
Trichloroethene
NO ug/L
5.0
1
10116/1300:51
79-01-6
Trichlorofluoromethane
NO ug/L
10.0
1
10/16/13 00:51
75-694
Vinyl chloride
NO ug/L
5.0
1
10116/1300:51
75-014
Surrogates
4-Bromofluorobenzene(S)
100 %
70-130
1
10116/1300:51
460-004
Toluene-08(S)
96 %
70.130
1
10/1611300:51
2037.26.5
1,2-Dichloroethane-d4 (S)
91 %
M130
1
10/18/13 00:51
17060-07-0
2540C Total Dissolved Solids
Analytical Method: SM 2540C
Total Dissolved Solids
338 mg/L
25.0
1
10/11/13 06:59
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
0.13 mg/L
0.10
1
10/11/13 13:57
766441-7
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2
Nitrogen, Kjeldahl, Total
1.4 mg/L
0.50
1
10/22/13 12:09
7727-37-9
353.2 Nitrogen, NO2tNO3 pros.
Analytical Method: EPA 353.2
Nitrogen, NO2 plus NO3
6.8 mg/L
0.080
4
10/22/13 18:58
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 10/23/2013 12:37 PM
without Ne hfan consent of Pace AnaMicat Services. Inc..

/�2ceAnalytical e
� eww:pedNrEaoom
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Hunterevllle, NC 28078
[phone]
Project PPA 1017113
Pace Project No.: 92175127
Sample: Wastewater Effluent
Lab ID: 92175127001 Collected:
10/07/13 11:00
Received: 10/08/13 18:45 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
365.1 Phosphorus, Total
Analytical Method: EPA 365.1
Phosphorus
0." mg/L
0.050
1
10/2211315:19
7723-14-0
420.4 Phenolics, Total
Analytical Method: EPA 420.4
Phenol
0.010 mg/L
0,0050
1
1011711314:30
108-95-2
4500CNE Cyanide, Total
Analytical Method: SM 4500-CN-E
Cyanide
ND ni
0.0050
1
10121/1314:57
57-12-5
Sample: Field Blank Effluent Lab ID: 92175127002 Collected: 10/07/13 11:00 Received: 101'0811318:45 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1631E Mercury,Low Level Analytical Method: EPA 1631E Preparation Method: EPA 1631E
Mercury ND ng/L 0.50 1 10/2111319:00 10/2211312:35 7439-97-6
Date: 10/23/2013 12:37 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

! aceAnalytrcal a
/ - m.w.onulaDszm
Pees AnalyBcd Services, In.
205 Feet Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services. Inc.
2225 Riverside Or.
Asheville, NC 28W4
(828)2547178
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kmcey Ave. Suits 100
Huntersville, NC 28078
[phone]
Project: PPA 10/7/13
Pace Project No.: 92175127
QC Batch: GCSW15742
Analysis Method:
EPA 1664E
QC Batch Method: EPA 1664E
Analysis Description:
1664 HEM, Oil and Grease
Assocated Lab Samples: 92175127001
METHOD BLANK: 1065667
Mal Water
Associated Lab Samples: 92175127001
Blank Reporting
Parameter
Unite
Result Limit
Analyzed Qualifiers
Oil and Grease
mg/L
ND 5.0 10/15/13 12:56
LABORATORY CONTROL SAMPLE:
1065668
Spike LCS
LCS % Rea
Parameter
Units
Conc. Result
%Rao Limits Qualifiers
Oil and Grease
mg/L
40 36.2
90 78-114
MATRIX SPIKE SAMPLE:
1065669
92175552001 Spike
Ms MS % Rec
Parameter
Units
Result Conc.
Result % Roe Limits Qualfiam
Oil and Grease
mg/L
ND 40
37.7 90 78-114
Date: 10/23/2013 12:37 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the writer, consent of Pecs Analytical Services, Inc..

ceAnalytifcal
� aawP�.�ea�e
Pace Analytical services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Anat"cal Sarvlces, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Hunlersville, NC 28078
[phone]
Project: PPA 10/7/13
Pace Project No.: 92175127
OC Batch: MERP/5721
Analysis Method: EPA 1631E
QC Batch Method: EPA 1631E
Analysis Description: 1631E Mercury.Low Level
Associated Lab Samples: 92175127001. 92175127002
METHOD BLANK: 1069944
Matrix: Water
Associated Lab Samples: 92175127001. 92175127002
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ri
NO 0.50
10/22/1311:43
METHOD BLANK: 1069946
Matrix: Water
Associated Lab Samples: 92175127001, 92175127002
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ng/L
NO 0.50
10/22/13 14:25
METHOD BLANK: 1069946
Matrix: Water
Associated Lab Samples: 92175127001, 92175127002
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ng/L
NO 0.50
10/22/1316:28
LABORATORY CONTROL SAMPLE: 1069947
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mercury ng/L
5 4.95
99 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1070134 1070135
MS MSD
92175017003
Spike Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec
Limits RPD Qual
Mercury ng/L 1.28
25 25 2.2.8
23.1 86 87
71-M 1
MATRIX SPIKES, MATRIX SPIKE DUPLICATE: 1070136 1070137
MS MSD
92175127001
Spike Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec
Limits RPD Qual
Mercury ng/L 1.39
25 25 21.5
20.3 80 76
71.125 6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/23/2013 12:37 PM without the written consent of Pace Analytical Services, Inc..

1�2ceAnaotal e
»..,.eaxreeamm
Project: PPA 10/7/13
Pace Project No.: 92175127
Pace Analytical Services, Inc.
205 East Meadow Road - Suke A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Ashew ile. NC 28804
[phone]
QUALITY CONTROL DATA
QC Batch: MPRP/14404 Analysis Method: EPA 200.7
OC Batch Method: EPA 200.7 Analysis Description: 200.7 MET
Associated Lab Samples: 92175127001
METHOD BLANK: 1064084
Associated Lab Samples: 92175127001
Parameter Units
Matrix: Water
Blank Reporting
Result Limit
Analyzed
Antimony
ug/L
NO
5.0
1 D116113 01:00
Arsenic
ug/L
NO
10.0
10/16/13 01:00
Beryllium
ug/L
NO
1.0
10(16/13 01:00
Cadmium
ug/L
NO
1.0
10/16/13 01:00
Calcium
ug/L
NO
100
10116113 01:00
Chromium
ug/L
NO
5.0
10/16/13 01:00
Copper
ug/L
NO
5.0
10/16/1301:00
Lead
ug/L
NO
5.0
10/16/13 01:00
Magnesium
ug/L
NO
100
10(16/13 01:00
Nickel
ug/L
NO
5.0
10116/13 01:00
Selenium
ug/L
NO
10.0
10/16/13 01:00
Silver
ug/L
NO
5.0
10116113 01:00
Thallium
ug/L
NO
10.0
10/16113 01:00
Total Hardness
ug/L
NO
662
10/16113 01:00
Zinc
ug/L
NO
10.0
10/16/13 01:00
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1064085
Units
Spike
Conic.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
500
500
100
85-115
Arsenic
uglL
500
486
97
85-115
Beryllium
ug/L
500
481
96
85-115
Cadmium
ug/L
500
493
99
85-115
Calcium
ug/L
5000
5020
100
85-115
Chromium
u9/L
500
509
102
85-115
Copper
ug/L
500
497
99
85-115
Lead
ug/L
500
490
98
85-115
Magnesium
ug/L
5000
4970
99
85-115
Nickel
ug/L
500
499
100
85-115
Selenium
ug/L
500
494
99
85-115
Silver
ug/L
250
243
97
85-115
Thallium
ug/L
Soo
476
95
85-115
Total Hardness
ug/L
33000
Zinc
ug/L
500
488
98
85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1064086 1064087
MS MSD
92175128001 Spike Spike MS MSO MS
Parameter Units Result Cone. Conic. Result Result % Rec
Antimony ug/L NO 500 500 568 565 113
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
Date: 10/23/2013 12:37 PM without the written consent of Pace Analytical Services, Inc..
Pecs Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
MSD % Rec
% Rec Limits RPD Qual
112 70-130 1

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�PaceAnalytical s
www➢acvle4o-wm
Project PPA 10/7/13
Pace Project No.: 92175127
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville. NC 28804
[phone]
QUALITY CONTROL DATA
OC Batch: MSV/24563 Analysis Method: EPA 624
OC Batch Method: EPA 624 Analysis Descriptton: 624 MSV
Associated Lab Samples: 92175127001
METHOD BLANK: 1066373
Associated Lab Samples: 92175127001
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
Analyzed
1, 1. 1 -Trichloroethane
ug/L
NO
5.0
1N16/13 00:20
1, 1,2,2-Tetrachloroethane
ug/L
NO
5.0
1&16/1300:20
1,1,2-Trichloroethane
ug/L
NO
6.0
1011611300:20
1,1-Dichloroethane
ug/L
NO
5.0
10/16/13 00:20
1,1-Dichloroethene
ug/L
NO
5.0
1011&1300:20
1,2,4-Trichlorobenzene
ug/L
NO
5.0
10116/13 D0:20
1,2-Dichlorobenzene
ug/L
NO
5.0
10/16/13 D0:20
1,2-Dichloroethane
uglL
NO
5.0
10/1611300:20
1,2-Dichloropropane
ug/L
NO
5.0
10/1611300:20
1,3-Dichlorobenzene
ug/L
NO
5.0
10/18H3 00:20
1,4-Dichlorobenzene
ug/L
NO
5.0
10/16/13 00:20
2-Chloroethylvinyl ether
ug/L
NO
10.0
10/16/13 00:20
Acrolein
ug/L
NO
100
10/16/13 D0:20
Acrylonitrile
uglL
NO
50.0
10/16/13 D0:20
Benzene
ug/L
NO
5.0
10/16/13 00:20
Bromodichloromethane
ug/L
NO
5.0
10/16113 00:20
Bromoform
ug/L
NO
5.0
10/16/13 00:20
Bromomethane
ug/L
NO
10.0
10/1&1300:20
Carbon tetrachloride
uglL
NO
5.0
10/16113 D020
Chlorobenzene
ug1L
NO
5.0
1&16(13 D0:20
Chloroethane
ug/L
NO
10.0
10/16/13 00:20
Chloroform
ug/L
NO
5.0
10/16/13 00:20
Chlorornethane
ug/L
NO
5.0
10/16113 00:20
cis-1,3-Dichloropropene
ug/L
NO
5.0
10/16/13 00:20
Dibromochlommethane
ug/L
NO
5.0
10/16/13 00:20
Ethylbenzene
ug/L
NO
5.0
10116/13 00:20
Hexachloro-1,3-butadlene
ug/L
NO
5.0
1011611300:20
Methylene Chloride
ugll-
NO
5.0
1016I1300:20
Naphthalene
ug/L
NO
5.0
10/16113 00:20
Tetrachlomethene
ug/L
NO
5.0
10/16113 00:20
Toluene
ug/L
NO
5.0
10/16/13 00:20
trans-1,2-Dichloroathene
ug/L
NO
5.0
10f1611300:20
bens-1,3-Dichlompropene
ug/L
NO
6.0
10/16/13 00:20
Trlchloroethene
ug/L
NO
5.0
10/16113 00:20
Trichlorofluoromethane
ug/L
NO
10.0
10116/1300:20
Vinyl chloride
ug/L
NO
5.0
10/16/13 00:20
1,2-Dichloroethane-d4(S)
%
91
70-130
10/16113 00:20
4-Bromofluombenzene (S)
%
101
70.130
10/16113 00:20
Tokiene-d8 (S)
%
98
70-130
10/16/13 00:20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/23/2013 12:37 PM without the written consent of Pace Analytical Services, Inc..
Qualiflem
Pace Analytical Services, Inc.
9800Kncey Ave. Suite too
HuntersAlle, NC 28078
[phone]

An*VW*
wxvrpcMWaeen
Pecs Analytical Services, Inc.
206 East Meadow Road - Suite A
Eden, NC 272aa
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: PPA 1077/13
Pace Project No.: 92175127
LABORATORY CONTROL SAMPLE:
1066374
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
1,1,1-Trichloroethane
ug/L
20
17.8
89
52-162
1,1,2,2-Tetrachloroethane
ug/L
20
19.9
99
46-157
1,1,2-Trichloroethane
ug/L
20
20.0
100
52-150
1,1-Dichloroethane
ug/L
20
16.9
85
59-155
1,1-Dichloroethene
ug/L
20
17.7
88
1-234
1,2,4-Tdchlorobenzene
ug/L
20
18.2
91
70-130
1,2-Dichlorobenzene
ug/L
20
20.2
101
18-190
1,2-Dichloroethane
ug/L
20
17.8
89
49-155
1,2-Dichloropropane
ug/L
20
19.3
96
1-210
1,3-Dichlorobenzene
ug/L
20
19.7
99
59-156
IA-Dichlorobenzene
ug/L
20
20.4
102
18-190
2-Chloroethylvinyl ether
ug/L
40
39.6
99
1-305
Acrolein
ug/L
100
93.21
93
15-152
Acrylonibile
ug/L
100
86.5
87
75-132
Benzene
ug/L
20
19.4
97
37-151
Bromodichloromethane
ug/L
20
19.9
100
35-155
Bromoform
ug/L
20
20.9
105
45-169
Bromomethane
ug/L
20
18.4
92
1-242
Carbon tetrachloride
ug/L
20
18.5
93
70-140
Chlorobenzene
ug/L
20
19.6
98
37-160
Chloroethane
ug/L
20
18.0
90
14-230
Chloroform
ug/L
20
18.3
91
51-138
Chloromethane
uglL
20
14.5
72
1-273
cis-1,3-Dichloropropene
ug/L
20
20.7
104
1.227
Dibromochloromethene
uglL
20
19.8
99
53-149
Ethylbenzene
uglL
20
18.6
93
37-162
Hexachloro-1,3-butadiene
uglL
20
17.5
87
70-130
Methylene Chloride
uglL
20
20.3
102
1-221
Naphthalene
ug/L
20
18.1
90
70-130
Tetrachloroethene
ug/L
20
19.7
98
64-148
Toluene
ug/L
20
19.3
97
47-150
trans-1,2-Dichloroethene
ug/L
20
17.4
87
54-156
trans-1,3-Dlchloropropene
ug/L
20
22.1
ill
17-183
Trichloroethene
uglL
20
19.3
96
71-157
Trichlorofluoromethane
ug/L
20
17.7
89
17-181
Vinyl chloride
ug/L
20
15.1
76
1-251
1,2-Dlchloroethane-d4 (S)
%
91
70-130
4-Bromofluorobenzene (S)
%
103
70-130
Toluerl(S)
%
98
70-130
Pace Analytical Services, Inc.
9800Kincey Ave. Suite too
Huntersville, NC 28078
[phone]
Qualifiers
MATRIX SPIKE SAMPLE:
1066631
92175127001
Spike
MS
MS
%Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
1,1,1-Trichloroethane
ug/L
NO
20
16.7
84
46-171
1,1,22-Tetrachloroethane
ug/L
NO
20
16.6
83
73-159
1,1,2-Trichloroethane
ug/L
NO
20
16.8
84
64-152
1,1-Dichioroethane
ug/L
ND
20
15.2
76
43-172
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
Date: 10/23/2013 12:37 PM without the written consent of Pace Analytical Services, Inc..

ace Analytical
/, wmv.paceboscan
Project: PPA 10/7113
Pace Project No.: 92175127
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Ede, NC 27288
(336)62"921
MATRIX SPIKE SAMPLE: 1066631
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)878&092
Parameter
Units
92175127001
Result
Spike
Conic.
MS
Result
MS
% Rao
% Roo
Limits Qualifiers
1,1-Dichloroethene
ug/L
NO
20
17.1
86
48-189
1,2,4-Trichlombenzene
ug/L
NO
20
15.4
77
70-130
1,2-Dichlorobenzene
ug/L
NO
20
17.1
85
54-154
1,2-Dichloroethane
ug/L
NO
20
15.5
77
42-171
1,2-Dichloropropane
ug/L
NO
20
16.6
83
55-157
1,3-Diohlorobenzene
ug/L
NO
20
17.3
86
57-148
1,4-Dichlorobenzene
ug/L
NO
20
17.4
87
58-149
2-Chioroethylvinyl ether
ug/L
NO
40
NO
0
70-130 J(M1)
Acroleln
ug/L
NO
100
75.71
76
70-130
Acrylonitrile
ug/L
NO
100
73.5
74
70-130
Benzene
ug/L
NO
20
17.0
85
54-163
Bromodichloromethane
ug/L
NO
20
17.0
85
56-152
Bromoform
ug/L
NO
20
17.9
90
53-151
Bromomethane
ug/L
NO
20
18.2
91
10-200
Carbon tetrachloride
ug/L
NO
20
18.0
90
41-175
Chlorobenzene
ug/L
NO
20
16.9
84
67-152
Chloroethane
ug/L
NO
20
16.7
84
23-200
Chloroform
ul
NO
20
17.2
82
51-166
Chloromethane
ug/L
NO
20
13.4
67
40-175
cis-1,3-Dichioropropene
ug/L
NO
20
17.8
89
38-146
Dibromochloromethane
ug/L
NO
20
17.3
87
65-144
Ethylbenzene
ug/L
NO
20
16.5
83
57-152
Hexachloro-1,3-butadiene
ug/L
NO
20
21.3
106
70-130
Methylene Chloride
ug/L
NO
20
13.7
52
40-167
Naphthalene
ug/L
NO
20
15.2
76
70-130
Tetrachloroethene
ug/L
NO
20
18.4
92
59-155
Toluene
ug/L
NO
20
16.9
84
47-162
trans-1,2-Dichloroethene
ug/L
NO
20
16.4
82
47-178
trans-1,3-Dichloropropene
ug/L
NO
20
19.5
97
30-148
Trichloroethene
ug/L
NO
20
17.4
87
60-153
Tdchlorofluoromethane
ug/L
NO
20
17.1
86
42-199
Vinyl chloride
ug/L
NO
20
14.5
73
46-176
1,2-0Ichloroethane-d4 (S)
%
90
7l
4-0romofluorobenzene (S)
%
102
70-130
Toluene-d8 (S)
%
97
70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced. except in full,
Date: 10/23/2013 12:37 PM without the written consent cr Pace Analytical Services, Inc..

PaceAnaVical e
i rim
Project: PPA 1017/13
Pace Project No.: 92175127
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville. NC 28804
[phone]
QUALITY CONTROL DATA
QC Batch: OEXT124193 Analysis Method: EPA 625
OC Batch Method: EPA 625 Analysis Description: 625 MSS
Associated Lab Samples: 92175127001
METHOD BLANK: 1063373
Associated Lab Samples: 92175127001
Parameter Units
Matrix: Water
Blank Reporting
Result Limit
Analyzed
1,2-Dichlorobenzene
ug/L
NO
5.0
101111/1320:08
1,2-Diphenylhydrazine
ug/L
NO
5.0
10/11113 20:08
1,3-Dichlorobenzene
ug/L
NO
5.0
10/11/13 20:08
1,4-Dichlorobenzene
ug/L
NO
5.0
10/11/13 20:08
2,4,6-Tri&lorophenol
ug/L
NO
10.0
10/11/13 20:08
2,4-Dichlorophenol
ug/L
NO
5.0
10/11/13 20:08
2,4-Dimethylphenol
ug/L
NO
10.0
10/11/13 20:08
2,4-Dinitrophenol
ug/L
NO
50.0
10111/1320:08
2,4-Dinitrotoluene
ug/L
NO
5.0
10/11/13 20:08
2,6-Dinitrotoluene
ug/L
NO
5.0
10/11/13 20:08
2-Chloronaphthalene
ug/L
NO
5.0
10/11113 20:08
2-Chlorophenol
uglL
NO
5.0
10/11113 20:08
2-Nitrophenol
ug/L
NO
5.0
10/11/13 20:08
3,3' Dichlorobenzidine
ug/L
NO
25.0
10/11/13 20:08
4,6-Dinitro-2-methylphenol
ug/L
NO
20.0
10/11/13 20:08
4-Bromophenylphenyl ether
ug/L
NO
5.0
10/11/13 20:08
4-Chloro-3-methylphenol
ug/L
NO
5.0
10/11/13 20:08
4-Chlarophenylphenyl ether
ug/L
NO
5.0
10111/13 20:08
4-Nitrophenol
ug/L
NO
50.0
10111/13 20:08
Acenaphthene
ug/L
NO
5.0
10/11/13 20:08
Acenaphthylene
ug/L
NO
5.0
10/11113 20:08
Anthracene
ug/L
NO
5.0
10/11113 20:08
Benzo(a)enthmcene
ug/L
NO
5.0
10111/1320:08
Benzo(a)pyrene
ug/L
NO
5.0
1011111320:08
Benzo(b)nuoranthene
ug/L
NO
5.0
10111/1320:08
Benzo(g,h,l)perylene
ug/L
NO
5.0
10111/1320:08
Benzo(k)fiuoranthene
ug/L
NO
5.0
1011111320:08
bis(2-Chlaroethoxy)methane
ug/L
NO
10.0
10/11/13 20:08
bis(2-Chloroethyl) ether
ug/L
NO
5.0
10/11/13 20:08
bis(2-Chloroisopropyl) ether
ug/L
NO
5.0
10/11113 20:08
bis(2-Ethylhexyl)phthalate
ug/L
NO
5.0
10111/13 20:08
Butylbenzylphthalate
ug/L
NO
5.0
10/11113 20:08
Chrysene
ug/L
NO
5.0
10/11/13 20:08
Di-n-butylphthalate
ug/L
NO
5.0
10/11/13 20:08
Di-n-octylphthalate
ug/L
NO
5.0
10/11/13 20:08
Dibenz(a,h)anthracene
ug/L
NO
5.0
10/11/13 20:08
Diethylphthalate
ug/L
NO
5.0
10/11/13 20:08
Dimethylphthalate
uglL
NO
5.0
10/11/13 20:08
Fluoranthene
ug/L
NO
5.0
10M111320:08
Fluorene
ug/L
NO
5.0
10/11/13 20:08
Hexachlorobenzene
ug/L
NO
5.0
10/11/13 20:08
Hexachlorocyclopentadiene
ug/L
NO
10.0
10111/1320:08
Hexachloroethane
ug/L
NO
5.0
10/11113 20:08
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/23/2013 12:37 PM without the written consent of Pace Analytical Services, Inc..
Qualifiers
Pace Analytical Services, Inc.
980010noey Ave, Suite 100
Huntersville, NC 28078
[phone]

- aceAnal(Xical
Project: PPA 1017/13
Pace Project Nm: 92175127
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NO 28804
[phone]
QUALITY CONTROL DATA
METHOD BLANK: 1063373
A n;oclated Lab Samples: 92175127001
Parameter Units
Matrix: Water
Blank Reporting
Result Limit
Analyzed
Indeno(1,2,3-od)pyrene
ug/L
NO
5.0
10M1/13 20:08
Isophorone
ug/L
NO
10.0
10/11/13 20:08
N-Nitroso-di-n-propylarrine
ug/L
NO
5.0
10/11/13 20:08
N-Nltrosodimethylamine
ug/L
NO
5.0
10111/1320:08
N-Nitrosodiphenylamine
ug/L
NO
10.0
10/11/13 20:08
Naphthalene
ug/L
NO
5.0
10/11/13 20:08
Nitrobenzene
ug/L
NO
5.0
10111/1320:08
Pentachlorophenol
ug/L
NO
10.0
10/11/13 20:08
Phenanthrene
ug/L
NO
5.0
10111/13 20:08
Phenol
ug/L
NO
5.0
10/11/13 20:08
Pyrene
ug/L
NO
5.0
10/11/13 20:08
2,4,6-Tdbromophenol(S)
%
66
10-137
10/11/13 20:08
2-Fluorobiphenyl(S)
e/
61
15-120
10/11/13 20:08
2-Fluorophenol(S)
%
37
10-120
10/11/1320:08
Nitrobenzene-d5(S)
%
61
10-120
10/1111320:08
Phenol-d6(S)
%
25
10-120
10111/1320:08
Terphenyl-d14(S)
%
82
11-131
10/1111320:08
LABORATORY CONTROL SAMPLE: 1063374
Parameter
Qualiflers
Pace Analytical Services, Inc.
9800 Kinsey Ave. Suite 100
Huntersvllle, NC 28078
[phone]
Spike LCS LCS % Res
Units Cone. Result % Rae Limits Qualifiers
1,2-Dichlorobenzene
ug/L
50
14.8
30
32-129 J(1-2)
1,2-Diphenylhydrazine
ug/L
50
17.1
34
25-150
1,3-Dichlombenzene
ug/L
50
14.1
28
1-172
1,4-Dichiorobenzene
ug/L
50
14.0
28
20-124
2,4,6-Tdchlorophenol
ug/L
50
16.1
32
37-144 J(1-2)
2,4-Dichlorophenol
ug/L
50
17.3
35
1-191
2,4-Dimethylphenol
ug/L
50
16.6
33
32-119
2,4-Dlnitrophenol
ug/L
250
123
49
1-181
2,4-0Initrotoiuene
ug/L
50
33.8
68
39-139
2,6-Dinitrotoluene
ug/L
50
26.0
52
50-158
2-Chlomnaphthalene
ug/L
50
15.0
30
60-118 J(1-2)
2-Chlorophenol
ug/L
50
16.7
33
23-134
2-1,11trophenol
uglL
50
16.6
33
29-182
3,T-Dichlorobenzidine
ug/L
100
69.4
59
1-262
4,6-Dinitm-2-methylphenol
ug/L
100
55.5
55
1-181
4-Bmmophenyiphenyl ether
ug/L
50
21.5
43
53-127 J(1-2)
4-Chloro-3-methylphenol
ug/L
100
38.5
38
22-147
4-Chlorophenylphenyl ether
ug/L
50
21.3
43
25-150
4-Nitrophenol
ug/L
250
70.5
28
1-132
Acenaphthene
ug/L
50
18.1
36
47-145 J(1-2)
Acenaphthylene
ug/L
50
17.6
35
33-145
Anthracene
ug/L
50
29.1
58
1-166
Benzo(a)anthracene
ug/L
50
32.5
65
33-143
Benzo(a)pyrene
ug/L
50
32.6
65
17-163
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/23/2013 12:37 PM without the written consent of Pace Analytical Services, Inc..

26AnaVical e
/, � xwx'.pBnlaOe.'.nm
I
Project: PPA 1017/13
Pace Project No.: 92175127
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
(336)6218921
LABORATORY CONTROL SAMPLE: 1063374
Parameter
Pace Analytical Services, Inc.
2225 Rlverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Ave, Suite 100
Huntersville, NC 28078
[phone]
Spike LOS LCS % Rec
Units Conc. Result % Rec Limits Quallflers
Benzo(b)fluoranthene
ug/L
50
33.9
68
24-159
Benzo(g,h,i)perylene
ug/L
50
29.4
59
1-219
Benzo(k)fluoranthene
ug/L
50
31.4
63
11-162
bis(2-Chloroethoxy)methane
ug/L
50
15.6
31
33-184 J(L2)
bls(2-CAlonder") ether
ug/L
50
18.6
37
12-158
bis(2-Chlomisopmpyl) ether
ug/L
50
14.5
29
36-166 J(1-2)
bis(2-Ethyihexyl)phthalate
ug/L
50
41.0
82
8-158
Butylbenzylphthalate
ug/L
50
37.7
75
1-152
Chrysene
ug/L
50
32.9
66
17-168
Di-n-butylphthalate
ug/L
50
31.8
64
1-118
Di-n-ocylphthalate
ug/L
50
39.4
79
4-146
Dibenz(a,h)anthracene
ug/L
50
30.5
61
1-227
Diethylphthalate
ug/L
50
30.2
60
1-114
Dimethylphthalate
ug/L
50
26.7
53
1-112
Fluoranthene
ug/L
50
32.7
65
26-137
Fluorene
ug/L
50
23.5
47
59-121 J(1-2)
Hexachlorobenzene
ug/L
50
22.2
44
1-152
Hexachlorocyclopentadiene
ug/L
50
10.9
22
25-150 J(1-2)
Hexachloreethane
ug/L
50
12.4
25
40-113 J(L2)
Indeno(1,2,3-cd)pyrene
uglL
50
30.7
61
1-171
Isophorone
ug/L
50
16.6
33
21-196
N-Nitroso-di-n-propylamine
ug/L
50
14.4
29
1-230
N-Nitrosodimethylamine
ug/L
50
10.5
21
25.150 J(1-2)
N-Nitrosodlphenylamine
ug/L
50
19.6
39
25-150
Naphthalene
ug/L
50
17.0
34
21-133
Nitrobenzene
ug/L
50
18.2
36
35-180
Pentachlorophenol
ug/L
100
47.3
47
14-176
Phenanthrene
ug/L
50
29.2
58
54-120
Phenol
ug/L
50
9.1
18
5-112
Pyrene
ug/L
50
35.2
70
52-115
2,4,6-Tnbromophenol (S)
%
63
10.137
2-Fluorobiphenyl (S)
%
32
15-120
2-Fluorophenol (S)
%
22
10-120
Nitrobenzene-d5 (S)
%
35
10-120
Phenol-06 (S)
%
14
1D-120
Terphenyl-d14 (S)
%
61
11-131
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1063375
MS MSD
92175311002 Spike Spike
Parameter Units Result Conc. Conc.
1063376
MS MSD MS MSD % Rec
Result Result % Rec % Rec Limits RPD Qual
1,2-Dichlorobenzene
ug/L
NO
100
100
38.1
31.9
38
32
32-129 18
1,2-Dipheny1hydnazine
ug/L
NO
100
100
39.7
41.7
40
42
25-150 5
1,3-Dichlorobenzene
ug/L
NO
100
100
35.9
29.8
36
30
1-172 19
1,4-Dichlorobenzene
uglL
NO
100
100
36.2
31.3
36
31
20-124 15
2,4,5-Tnchiorophenol
ug/L
NO
100
100
54.2
47.8
54
48
37-144 13
2,4-Dichlorophenol
ug/L
NO
100
100
49.2
43.4
49
43
1-191 12
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced. except In full,
Date: 10/23/2013 12:37 PM without the written consent of Pace Analytical Services, Inc..

.2eAnalytical -
www.purolaGe mm
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kinsey Ave. Suite too
Huntersville, NC 28078
[phone]
Project: PPA 1017/13
Pace Project No.: 92175127
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1063375
1063376
MS
MSD
92175311002
Spike
Spike
MS
MSD
MS
MSD
%Rec
Parameter
Units
Result
Conc.
Cons.
Result
Result
%Rec
%Rec
Limits
RPO Dust
2,4-Dimethylphenol
ug/L
NO
100
100
44.1
38.2
44
38
32-119
14
2,4-Dinitrophenol
ug/L
NO
500
500
347
313
69
63
1-181
10
2.4-Dinitrotoluene
ug/L
NO
100
100
68.2
58.6
68
59
39-139
15
2,6-Dinitrotoluene
ug/L
NO
100
100
56.2
50.1
56
50
50-158
11
2-Chloronaphthalene
ug/L
NO
100
100
38.2
35.1
38
35
60-118
8 J(MO)
2-Chlorophenol
ug/L
NO
100
100
47.8
38.1
48
38
23-134
23
2-Nitrophenol
ug/L
NO
100
1DO
40.5
34.0
40
34
29-182
17
3,3'-Dichlorobenzidlne
ug/L
NO
200
2DO
98.0
89.7
49
45
1-262
9
4,6-Dinitro-2-methylphenol
ug/L
ND
200
200
125
128
63
64
1-181
2
4-Bromophenylphenyl ether
ug/L
ND
100
100
52.9
53.0
53
53
53-127
0
4-Chloro-3-methylphenol
ug/L
ND
200
200
137
119
68
60
22-147
14
4-Chlorophenylphenyl ether
ug/L
ND
100
1Do
55.6
53.5
56
53
25-158
4
4-Nitrophenol
ug/L
ND
500
Soo
378
252
76
50
1-132
40 J(RI)
Acenaphthene
uglL
NO
100
100
46.1
43.2
46
43
47-145
7 J(MO)
Acenaphthylene
ug/L
NO
100
100
44.8
41.5
45
41
33-145
8
Anthracene
ugll
NO
100
100
64.8
58.7
65
59
1-166
10
Benzo(a)anthracene
ug/L
ND
100
100
68.6
60.7
69
61
33-143
12
Benzo(a)pyrene
ug/L
NO
100
100
69.7
63.9
70
64
17-163
9
Benzo(b)fluoranthene
ug/L
NO
100
100
68.9
63.2
69
63
24-159
9
Benzo(g,h,i)perylene
ug/L
NO
100
100
66.9
60.6
67
61
1-219
10
Senzo(k)fluoranthene
ug/L
NO
100
100
64.3
58.8
64
59
11-162
9
bis(2-Chlemethoxy)methane
ug/L
NO
100
100
38.3
34.8
38
35
33-184
10
bis(2-Chloroethyi) ether
ug/L
NO
100
100
45.0
38.3
45
38
12-158
16
bis(2-Chloroisopropyl) ether
ug/L
ND
100
100
37.3
33.0
37
33
36-166
12 J(MO)
bis(2-Ethylhexyl)phthalate
ug/L
6.4
100
100
96.8
81.2
90
75
8-158
18
Buylbenzylphthalate
ug/L
NO
100
100
79.8
68.2
80
68
1-152
16
Chrysene
ug/L
NO
100
100
71.0
64.0
71
64
17-168
10
Di-n-butylphthalate
ug/L
NO
100
100
70.6
63.4
71
63
1-118
11
DI-noctylphthalate
ug/L
NO
100
100
85.7
78.4
86
78
4.146
9
Dibenz(a,h)anthmcene
ug/L
NO
100
100
69.2
64.1
69
64
1-227
8
Dlethylphthalate
ug/L
ND
100
100
66.5
62.1
64
60
1-114
7
Dimethylphthatate
ug/L
NO
100
100
53.3
49.9
53
50
1-112
7
Fluoranthene
ug/L
ND
100
100
81.1
62.3
81
62
26-137
26
Fluorene
ug/L
ND
100
100
57.1
52.1
57
52
59-121
9 J(MO)
Hexachlorobenzene
ug/L
ND
100
100
47.0
47.5
47
47
1-152
1
Hexachlorocyclopentadiene
ug/L
NO
100
100
22.6
25.7
23
26
25-150
13 J(MO)
Hexachloroethane
ug/L
ND
100
100
33.0
28.5
33
29
40.113
15 J(MO)
Indeno(1,2,3-od)pyrene
ug/L
NO
1DO
100
69.0
62.6
69
63
1-171
10
Is iphorone
uglL
NO
100
100
41.7
37.6
42
38
21-196
10
N-Nitroso-dl-n-propylamine
ug/L
NO
100
100
41.0
35.3
41
35
1-230
15
N-Nitrosodlmethylamine
ug/L
NO
100
100
26.7
24.6
27
25
25-150
8
N-Nibrosodiphenylamine
ug/L
NO
100
100
46.1
45.1
46
45
25.150
2
Naphthalene
uglL
NO
100
100
40.8
34.5
41
34
21-133
17
Nitrobenzene
ug/L
NO
100
100
41.8
34.4
42
34
35-180
20 J(MO)
Pentachlorophenol
ug/L
NO
200
200
137
119
69
60
14-176
14
Phenanthrene
ug/L
NO
100
100
64.2
59.0
64
59
54-120
8
Phenol
ug/L
ND
100
100
40.9
33.0
41
33
5-112
21
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Dale: 10/23/2013 12:37 PM without the written consent of Pace Analytical Services. Inc..

ace Analytical e
/� wmvps,ateos:am
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, fnc.
2225 Riverside Dr.
Asheville. NC 28804
[phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 26078
[phone]
Project: PPA 1017113
Pace Project No.: 92175127
MATRIX SPIKE 8 MATRIX SPIKE DUPLICATE: 1063375
1063376
MS
MSD
92175311002 Spike
Spike
MS
MSD MS
MSO
% Rao
Parameter
Units Result Conn.
Conc.
Result
Result % Rec
% Rec
Limits RPO Qual
Pyrene
ug/L NO 100
100
65.2
67.6 65
58
52-115 12
2,4,6-Tribromophenol(S)
%
83
69
10-137
2-Fluorobiphanyl(S)
%
36
36
15-120
2-Fiuorophenol (S)
%
34
27
10.120
Nitrobenzene-d5 (S)
%
39
34
10-120
Phenol-d6 (S)
%
31
26
10-120
Terphenyl-d14 (S)
%
53
52
11-131
Date: 10/23/2013 12:37 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced. except in full,
without the wn0en consent of Pace Analytical Services, Inc..

ace Analytical
wWH.GtlCMea B..M1VII
Project: PPA 10/7/13
Pace Project No.: 92175127
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
(336)623A921
QC Balch: WET/27544
OC Batch Method: SM 2540C
Associated Lab Samples: 92175127001
METHOD BLANK: 1064056
Associated Lab Samples: 92175127001
Parameter Units
Total Dissolved Solids mg/L
LABORATORY CONTROL SAMPLE: 1064057
Parameter Units
Total Dissolved Solids mg/L
Pace Analytical Serilcee, Inc.
2225 Riverside Dr.
Ashev111e. NC 28804
[phone]
QUALITY CONTROL DATA
Analysis Method: SM 2540C
Analysis Description: 2540C Total Dissolved Solids
Matrix: Water
Blank Reporting
Result Limit Analyzed Ousll6ers
NO 26.0 10/11/13 06:54
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Hunterswlle, NC 2807E
(704)8759092
Spike LCS LCS % Rec
Conic. Result % Rec Limits Qualifier
250 258 103 80-120
SAMPLE DUPLICATE: 1064058
92175356003 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 455 464 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
Data: 10/23/2013 12:37 PM without the written consent of Pace Analytical Services, Inc.

�/ a
. Pace Analytical
,mwparoleds. ^>m
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
;336J823-8921
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
(828)7-%7176
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville. INC 28078
i704)578-9092
Project
PPA 10/7113
Pace Project No.:
92175127
QC Batch:
WETA/16720 Analysis Method: EPA 350.1
OC Batch Method:
EPA 350.1 Analysis Description: 350.1 Ammonia
Associated Lab Samples: 92175127001
METHOD BLANK: 1064419
Associated Lab Samples: 92175127001
Parameter Units
Nitrogen, Ammonia mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
NO 0.10 10/11/13 13:50
LABORATORY CONTROL SAMPLE: 1064420
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Nitrogen, Ammonia mg/L 5 5.2 104 90-110
MATRIX SPIKE 8 MATRIX SPIKE DUPLICATE: 1064421 1064422
MS MSD
92175051005 Spike Spike MS MSD MS MSD %Rae
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPO Qual
Nitrogen, Ammonia mglL ND 5 5 2.4 0.96 48 19 90-110 86 J(M1),J(R7)
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1064423 1064424
MS MSD
92175228001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Cone. Cone. Result Result %Rae %Rec Limits RPO Qual
Nitrogen, Ammonia ni 0.18 5 5 5.7 5.5 111 107 90-110 3 J(M1)
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
Date: 10/23/2013 12:37 PM without the written consent or Pace Analytical Services, Inc..

Pace Analytical Services, Inc.
205 East Meadow Road Suite A
Eden, NC 27288
(3361623-8921
Project: PPA 1017/13
Pace Project No.: 92175127
QC Batch: WETA/16804
CC Batch Method: EPA 351.2
Associated Lab Samples: 92175127001
METHOD BLANK: 1069631
Associated Lab Samples: 92175127001
Parameter Units
Nitrogen, Kjeldahl, Total mg/L
Pace Analytical Services, Inc.
2225 Riverside 0,.
Asheville, NC 28904
(828)2547176
QUALITY CONTROL DATA
Analysis Method: EPA 351.2
Analysis Description: 351.2 TKN
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
NO 0.50 10/22/13 12:03
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Hunlersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 1069632
Spike LCS 1-CS % Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen, Kjeldahl, Total mg/L 10 10.1 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1069633 1069634
MS MSD
92175947002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conic. Result Result % Rec % Rec Limits RED Qual
Nitrogen, Kjeldahl, Total mg/L 1280 5000 5000 2210 2200 18 18 90-110 0 M6
Date: 10/23/2013 12:37 PM
REPORT OF LABORATORY ANALYSIS
This report shell not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

�aceAnalytical D
aww.aenrmawr,
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Project. PPA 1017/13
Pace Project No.: 92175127
OC Batch: WETA116817
QC Batch Method: EPA 353.2
Associated Lab Samples: 92175127001
METHOD BLANK: 1070446
Associated Lab Samples: 92175127001
Parameter Units
Nitrogen, NO2 plus NO3 mg/L
LABORATORY CONTROL SAMPLE: 1070447
Parameter Units
Nitrogen, NO2 plus NO3 mg/L
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite, preserved
Matrix: Water
Blank Reporting
Result Umit Analyzed Qualifiers
ND 0.020 10/22/13 17:41
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 1 DO
Huntersvill9, NC 28078
[phone]
Spike LCS LCS % Rise
Cone. Result % Rae Limits Oualifiers
2.5 2.5 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1070448 1070449
MS MSD
92174957001 Spike Spike MS MSD MS MSD % Rae
Parameter Units Result Cane. Cone. Result Result % Rae % Rea Limits RPD Qual
Nitrogen, NO2 plus NO3 mg/L 3.2 2.5 2.5 5.9 5.9 107 108 75-125 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1070450
1070451
MS
MSD
92174960001 Spike
Spike
MS
MSD MS MSD % Rise
Parameter Units Result Cone.
Cone.
Result
Result % Rae % Rae Limits RPD Dual
Nitrogen. NO2 plus NO3 mg/L 10.7 2.5
2.5
13.3
14.1 102 132 75-125 6 J(M1)
Date: 10/23/2013 12:37 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced except in full,
.Rhoul the written consent of Pace Analytical Services, Inc..

aceAnalytical*
/. aiaos +Jn
Project: PPA 100113
Pace Project No.: 92175127
Pace Analytical Services, Inc.
205 East Meadcw Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville. NC 28804
(828)25a7176
QUALITY CONTROL DATA
QC Batch: WETA/16810 Analysis Method: EPA 365.1
OC Batch Method: EPA 365.1 Analysis Description: 365.1 Phosphorus, Total
Associated Lab Samples: 92175127001
METHOD BLANK: 1069990
Associated Lab Samples: 92175127001
Parameter Units
Phosphorus mg/L
LABORATORY CONTROL SAMPLE: 1069991
Parameter Units
Phosphorus mg/L
Pace Analytical Services, Inc.
98(IO Kincey Ave. Suite 100
Huntersvdle. NC 28078
[phone]
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
NO 0,050 10/2211315:14
Spike LCS LCS % Rec
Cone. Result %Rec Limits Qualifiers
2.5 2.6 104 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1069992 1069993
MS MSD
92175947002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Oual
Phosphorus mg/L NO 2.5 2.5 2.6 2.5 103 102 90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1069994 1069995
MS MSD
92175265002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual
Phosphorus ni 0.089 2.5 2.5 2.8 2.7 107 106 90-110 0
Date: 10/23/2013 12:37 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

PaceAnalytical
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
(336)623A921
Pace Analytical Servlcea, Inc.
2225 Riverside Or.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: PPA 10/7113
Pace Project No.: 92175127
OC Batch: WETA116771 Analysis Method: EPA 420.4
QC Batch Method: EPA 420.4 Analysis Description: 420.4 Phenolics
Associated Lab Samples: 92175127001
METHOD BLANK: 1067587
Associated Lab Samples: 92175127001
Parameter Units
mg1L
Phenol
LABORATORY CONTROL SAMPLE: 10675M
Parameter Units
Phenol mglL
Matrix: Water
Pace Analytical Servlcea, Inc.
9800 IGncey Ave. Suite 100
Huntersville, NC 28078
[phone]
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.0050 10/17/1314:34
Spice LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
.D5 0.051 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1067589 1067590
MS MSD
92175552001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rao %Rec Limits RPD Qual
Phenol mg/L 0.14 .05 .05 0.18 0.18 83 90 90-110 2 J(Mt)
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1067593
1067594
MS
MSD
92175203002 Spike
Spike
MS
MSD MS MSD %Rec
Parameter Units Result Conc.
Conc.
Result
Result %Rec %Rec Limits RPD Quill
Phenol mg/L 0.014 .05
.05
0.070
0.065 112 102 90-110 7 J(M1)
Date: 10/23/2013 12:37 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced. except in full,
without the writer, consent of Pace Analytical Services, Inc..

zl aceAnalyticaln
/ s+wpaoYssaapm
Project: PPA 1017/13
Pace Project No.: 92175127
QC Batch: WETA/16798
QC Batch Method: SM 4500-CN-E
Associated Lab Samples: 92175127001
METHOD BLANK: 1069431
Associated Lab Samples: 92175127001
Parameter Units
mg/L
Cyanide
Pace Analytical servkq, Inc.
205 East Meadow Road -Suite A
Eden, NC 27288
[phone]
Pace Analytical services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Analysis Method: SM 4500-CN-E
Analysis Description: 450OCNE Cyanide, Total
Matrix: Water
Blank Reporting
Result Limit Analyzed QuallBers
ND 0.0050 10121/1314:47
Pace Analytical services, Ina
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 1069432
Spike LCS LCS % Rao
Parameter Units Conc. Result % Rec Limits Qualifiers
Cyanide mg/L .1 0.11 110 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 10&M33 1069434
MS MSD
92174908001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conic. Conc. Result Result % Rec % Rec Limits RPD Qual
Cyanide mg/L 0.0058 A .1 0.0057 0.0059 0 0 75-125 3 J(Mi)
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1069435 1069436
MS MSD
92175157005 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Dual
Cyanide ni ND .1 .1 0.11 0.12 108 116 75-125 6
Date: 10/23/2013 12:37 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

FceArWcal*
a»+cpeosabir mc,
Project: PPA 10/7M3
Pace Project No.: 92175127
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside D,.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pecs Analytical Services, Inc.
9800 Kinsey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
92175127001
Wastewater Effluent
EPA 1664E
GCSV/15742
92175127001
Wastewater Effluent
EPA 200.7
MPRP114404
EPA 200.7
92175127001
Wastewater Effluent
EPA 1631E
MERP/5721
EPA 1631E
92175127002
Field Blank Effluent
EPA 1631E
MERP/5721
EPA 1631E
92175127001
Wastewater Effluent
EPA 625
OEXT/24193
EPA 625
92175127001
Wastewater Effluent
EPA 624
MSV/24563
92175127001
Wastewater Effluent
SM 2540C
WET/27544
92175127001
Wastewater Effluent
EPA 350.1
WETA/16720
92175127001
Wastewater Effluent
EPA 351.2
WETA116804
92175127001
Wastewater Effluent
EPA 353.2
WETA/16817
92175127001
Wastewater Effluent
EPA 365.1
WETA116810
92175127001
Wastewater Effluent
EPA 420.4
WETA/16771
921T5127001
Wastewater Effluent
SM 4500-CN-E
WETA/16798
Date: 10/23/2013 12:37 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the writer, consent of Pace Analytical Services, Inc..
Analytical
Batch
ICP/13094
MERC/5538
MERC/5538
MSSV/8297

)11
Pace 4nalytic2.
CHAIN -OF -CUSTODY ! Analytical Request Document
The Chala fCustody is a LEGAL DOCUMENT. All relevant fiefds must be completed aecvMWN.
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F-ALL-0-020M 07. I&May-2007

Toxicity Testing
Ceriodaphnia dubia

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP, NCO020605 Renewal Tar -Pam[
Part EA Toxicity Testing Data
Summary of Submitted Biomonitoring Test Information
Organism: Ceriodaphnia Dubia
Date
Pipe
Collection
Testing
Submitted
Number
Date
Date
Method
Summary
02/11/09
001
01/12/09
01/14/09
Chronic Pass/Fail
PASS
04/24/09
001
04/13/09
04/15/09
Chronic Pass/Fail
PASS
07/31/09
001
07/20/09
07/22/09
Chronic Pass/Fail
PASS
10/30/09
001
10/19/09
10/21/09
Chronic Pass/Fail
PASS
01/28/10
001
01/18/10
01/20/10
Chronic Pass/Fail
PASS
04/22/10
001
04/12/10
04/14/10
Chronic Pass/Fail
PASS
08/04/10
001
07/26/10
07/28/10
Chronic Pass/Fad
PASS
10/29/10
001
10/I8/10
10/20/10
Chronic Pass/Fail
PASS
01/13/11
001
01/03/11
01/05/11
Chronic Pass/Fail
PASS
04/29/11
001
04/04/11
04/06/11
Chronic Pass/Fail
PASS
08/04/11
001
07/18/11
07/20/11
Chronic Pass/Fail
PASS
11/04/11
001
10/10/11
10/12/11
Chronic Pass/Fail
PASS
02/15/12
001
01/23/12
01/25/12
Chronic Pass/Fail
PASS
04/30/12
001
04/09/12
04/11/12
Chronic Pass/Fail
PASS
07/31/12
001
07/16/12
07/18/12
Chronic Pass/Fail
PASS
10/18/12
001
10/08/12
10/10/12
Chronic Pass/Fail
PASS
01/24/13
001
01/14/13
01/16/13
Chronic Pass/Fail
PASS
04/25/13
001
04/15/13
04/17/13
Chronic Pass/Fail
PASS
07/18/13
001
07/08/13
07/10/13
Chronic Pass/Fail
FAIL
10/17/13
001
10/07/13
10/09/13
Chronic Pass/Fail
PASS

NCDENR
North Carolina Department of Environment and
Division of Water Quality
Beverly Eaves Perdue Coleen H. Sullins
Governor Director
April 6, 2009
SAMUEL W NOBLE JR
TOWN MANAGER
TOWN OF TARBORO
PO BOX 220
TARBORO NC 27886
Natural Resources
Dee Freeman
Secretary
Subject: Receipt of permit renewal application
NPDES Permit NCO020605
Tarboro WWTP
Edgecombe County
Dear Mr. Noble:
The NPDES Unit received your permit renewal application on April 6, 2009. A member of the NPDES
Unit will review your application. They will contact you if additional information is required to complete your
permit renewal. You should expect to receive a draft permit approximately 30-45 days before your existing permit
expires.
If you have any additional questions concerning renewal of the subject permit, please contact Ron Berry at
[phone].
4394
Sincerely,
Dina Sprinkle
Point Source Branch
cc: CENTRAL FILES
Raleigh Regional Office/Surface Water Protection
NPDES Unit
J. Randall Jones, Jr., EI, The Wooten Company, 301 W. 14" Street, Greenville, NC 27834
1617 Mail Service Center, Raleigh, North Carolina 27699-1617
Location: 512 N. Salisbury St. Raleigh, North Carolina 27604
Phone: [phone] FAX: [phone] Customer Service: 1-877-623-6748
Internet www.ncwaterquality.org
An Equal Opportunity 1 Affirmative Action Employer
No ehCarolina
Natura!!Y

Application for Renewal of
NPDES Permit No. NCO020605
Town of Tarboro, North Carolina
.o.fl 209 RECEIVED
APR - G L`: "9
DENR - WATER QUALITY
POINT SOURCE BRANCH
Prepared by:
The Wooten Company
301 West 14th Street
Greenville, North Carolina 27834
[phone]

Town of Tarboro
@17160)
P. O. Box 220 - 500 Main Street
Tarboro, NC 27886-0220
Telephone [phone]
Fax [phone]
www.tarboro-ne.com
March 30, 2009
NC DENR
Division of Water Quality, NPDES Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Re: NPDES Permit Renewal Application
Permit No. NC0020605
Dear Application Reviewer:
The letter is to confirm that The Wooten Company is the Town of Tarboro's Authorized
Representative in preparing the NPDES Permit Renewal Application.
I certify under penalty of law that this document and all attachments were prepared under
my direction and supervision in accordance with a system designed to assure that
qualified personnel properly gather and evaluated the information submitted. Based on
my inquiry of the person or persons who manage the system or those persons directly
responsible for gathering the information, the information is, to the best and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting
false information, including the possibility of fine and imprisonment for knowing
violations.
If you need additional information, please contact me at [phone].
Tly,
,,,
Samuel W. Noble, Jr.
Town Manager

Application for Renewal of
NPDES Permit No. NCO020605
Town of Tarboro, North Carolina
April 2009
Prepared by:
The Wooten Company
301 West 14th Street
Greenville, North Carolina 27834
[phone]

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP, NCO020605 Renewal Tar -Pamlico
FORM
2A
NPDES
NPDES FORM 2A APPLICATION OVERVIEW
APPLICATION OVERVIEW
Form 2A has been developed in a modular format and consists of a 'Basic Application Information" packet
and a "Supplemental Application Information" packet. The Basic Application Information packet is divided
into two parts. All applicants must complete Parts A and C. Applicants with a design flow greater than or
equal to 0.1 mgd must also complete Part B. Some applicants must also complete the Supplemental
Application Information packet. The following items explain which parts of Form 2A you must complete.
BASIC APPLICATION INFORMATION:
A. Basic Application Information for all Applicants. All applicants must complete questions A.1 through A.B. A treatment works
that discharges effluent to surface waters of the United States must also answer questions A.9 through A.12.
B. Additional Application Information for Applicants with a Design Flow 2 0.1 mgd. All treatment works that have design flows
greater than or equal to 0.1 million gallons per day must complete questions B.1 through B.6.
C. Certification. All applicants must complete Part C (Certification)
SUPPLEMENTAL APPLICATION INFORMATION:
D. Expanded Effluent Testing Data. A treatment works that discharges effluent RECEIVElYs
one or more of the following criteria must complete Part D (Expanded Effluent
1. Has a design flow rate greater than or equal to 1 mgd,
2. Is required to have a pretreatment program (or has one in place), or
3. Is otherwise required by the permitting authority to provide the information.
E. Toxicity Testing Data. A treatment works that meets one or more of the following criteria must complete Part E (Toxicity Testing
Data): DENR - WATER QUALITY
1. Has a design flow rate greater than or equal to 1 mgd, POINT SOURCE BRANCH
2. Is required to have a pretreatment program (or has one in place), or
3. Is otherwise required by the permitting authority to submit results of toxicity testing.
F. Industrial User Discharges and RCRA/CERCLA Wastes. A treatment works that accepts process wastewater from any
significant industrial users (SIUs) or receives RCRA or CERCLA wastes must complete Part F (Industrial User Discharges
and RCRA/CERCLA Wastes). SIUs are defined as:
1. All industrial users subject to Categorical Pretreatment Standards under 40 Code of Federal Regulations (CFR) 403.6 and
40 CFR Chapter 1, Subchapter N (see instructions); and
2. Any other industrial user that:
a. Discharges an average of 25,000 gallons per day or more of process wastewater to the treatment works (with certain
exclusions); or
b. Contributes a process wastestream that makes up 5 percent or more of the average dry weather hydraulic or organic
capacity of the treatment plant; or
G. Is designated as an SIU by the control authority.
G. Combined Sewer Systems. A treatment works that has a combined sewer system must complete Part G (Combined Sewer
Systems).
ALL APPLICANTS MUST COMPLETE PART C (CERTIFICATION)
EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 A 7550-22. Page 1 of 25

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
BASIC APPLICATION INFORMATION
PART A. BASIC APPLICATION INFORMATION FOR ALL APPLICANTS:
All treatment works must complete questions A.1 through A.8 of this Basic Application Information Packet
A.I. Facility Information.
Facility Name Town of Tarboro Wastewater Treatment Plant
Mailing Address Post Office Box 220
Tarboro Norm Carolina 27886
Contact Person Samuel W. Noble Jr.
Title Town Manager
Telephone Number [phone]
Facility Address Service Road off SR 268/Highwav 64 Junction
(not P.O. Box) Tarboro, North Carolina 27886
A.2. Applicant Information. If the applicant is different from the above, provide the following:
Applicant Name Town of Tarboro
Mailing Address Post Office Box 220
Tarboro, North Carolina 27886
Contact Person Samuel W. Noble Jr.
Title Town Manager
Telephone Number [phone]
Is the applicant the owner or operator (or both) of the treatment works?
N owner ® operator
Indicate whether correspondence regarding this permit should be directed to the facility or the applicant.
❑ facility ® applicant
A.3. Existing Environmental Permits. Provide the permit number of any existing environmental permits that have been issued to the treatment works
(include state -issued permits).
NPDES NCO020605 PSD WA
UIC N/A Other WQOD03047
RCRA WA Other WA
A.4. Collection System Information. Provide information on municipalities and areas served by the facility. Provide the name and population of each
entity and, if known, provide information on the type of collection system (combined vs. separate) and its ownership (municipal, private, etc.).
Name Population Served Type of Collection System Ownership
Town of Tarboro 10,505 Separate Sanitary Municipal
Town of Princeville 2,226 Separate Sanitary Municipal
Total population served 12,144
EPA Forth 3510-2A (Rev. 1-99). Replaces EPA farms 7550-6 A 7550.22. Page 2 of 25

FACILITY NAME AND PERMIT NUMBER:
Tarboro WWTP, NCO020605
A.5. Indian Country.
a. Is the treatment works located in Indian Country?
❑ Yes ® No
PERMIT ACTION REQUESTED: RIVER BASIN:
Renewal Tar -Pamlico
b. Does the treatment works discharge to a receiving water that is either in Indian Country or that is upstream from (and eventually flows
through) Indian Country?
❑ Yes ® No
A.B. Flow. Indicate the design flow rate of the treatment plant (i.e., the wastewater flow rate that the plant was built to handle). Also provide the
average daily flow rate and maximum daily flow rate for each of the last three years. Each years data must be based on a 12-month time period
with the 121" month of "this year' occurring no more than three months prior to this application submittal.
a. Design flow rate 5.0 mgtl
Two Years Aao Last Ye r This Year
b. Annual average daily flow rate 2.336 1.937 1.898
C. Maximum daily flow rate 8.112 4.329 3.579
A.7. Collection System. Indicate the type(s) of collection systems) used by the treatment plant. Check all that apply. Also estimate the percent
contribution (by miles) of each.
® Separate sanitary sewer 1 DO %
❑ Combined storm and sanitary sewer WA %
A.S. Discharges and Other Disposal Methods.
a. Does the treatment works discharge effluent to waters of the U.S.? ® Yes ❑ No
If yes, list how many of each of the following types of discharge points the treatment works uses:
I. Discharges of treated effluent 1
it. Discharges of untreated or partially treated effluent
III. Combined sewer overflow points
iv. Constructed emergency overflows (prior to the headworks) 0
V. Other WA N/A
b. Does the treatment works discharge effluent to basins, ponds, or other surface Impoundments
that do not have outlets for discharge to waters of the U.S.? ❑ Yes ® No
If yes, provide the following for each surface impoundment:
Location:
Annual average daily volume discharge to surface impoundment(s) N/A mgtl
Is discharge ❑ continuous or ❑ intermittent?
C. Does the treatment works land -apply treated wastewater? ❑ Yes ® No
If yes, provide the following for each land application site:
Location:
Number of acres:
Annual average daily volume applied to site: WA mgd
Is land application ❑ continuous or ❑ intermittent?
d. Does the treatment works discharge or transport treated or untreated wastewater to another
treatment works? ❑ Yes ® No
EPA For 3510-2A (Rev. 1-99). Replaces EPA fors 7550-68 7550-22. Page 3 of 25

FACIUTY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
If yes, describe the mean(s) by which the wastewater from the treatment works is discharged or transported to the other treatment works
(e.g., tank truck, pipe).
N/A
If transport is by a party other than the applicant. provide:
Transporter Name N/A
Mailing Address N/A
N/A
Contact Person N/A
Title N/A
Telephone Number ( )N/A
For each treatment works that receives this discharge, provide the following:
Name N/A
Mailing Address N/A
NIA
Contact Person N/A
Title N/A
Telephone Number ( )N/A
If known, provide the NPDES permit number of the treatment works that receives this discharge N/A
Provide the average daily flow rate from the treatment works into the receiving facility. N/A
mgd
e. Does the treatment works discharge or dispose of its wastewater in a manner not included
in A.8. through AAA above (e.g., underground percolation, well injection): ❑ Yes
® No
If yes, provide the following for each disposal method:
Description of method (including location and size of site(s) if applicable):
N/A
Annual daily volume disposed by this method: N/A
Is disposal through this method ❑ continuous or ❑ intermittent?
EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 8 7550-22. Page 4 of 25

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
Tarboro WWTP, NCO020605 I F I Tar -Pamlico
WASTEWATER DISCHARGES:
If you answered "Yes" to question A.8.a, complete questions A.9 through A.12 once for each outfall (including bypass points) through
which effluent is discharged. Do not include information on combined sewer overflows in this section. If you answered "No" to question
A.B.a, go to Part B, "Additional Application Information for Applicants with a Design Flow Greater than or Equal to 0.1 mgd."
A.9. Description of Ouflall.
a. Outfall number
b. Location
(City or town, if applicable)
(County)
(Latitude)
C. Distance from shore (if applicable)
d. Depth below surface (if applicable)
e. Average daily flow rate
I. Does this outfall have either an intermittent or a periodic discharge?
If yes, provide the following information:
Number f times per year discharge occurs:
Average duration of each discharge:
Average flow per discharge:
Months in which discharge occurs:
g. Is outfall equipped with a diffuser?
(Zip Code)
(State)
(Longitude)
WA - cascade aeration into river ft.
WA ft.
I mgd
❑ Yes ® No (go to A.9.g.)
WA
WA mgd
❑ Yes ® No
A.10. Description of Receiving Waters.
a. Name of receiving water Tar River
b. Name of watershed (if known) Lower Tar
United States Soil Conservation Service 14-digit watershed code (if known):
C. Name of State Management/River Basin (if known):Tar-Pamlico
United States Geological Survey 8-digit hydrologic cataloging unit code (if known):
d. Critical low flow of receiving stream (if applicable)
03020103010020
03020103
acute WA cfs chronic WA cfs
e. Total hardness of receiving stream at critical low flow (if applicable): WA myl of CaCO3
EPA Fonn 3510-2A (Rev. 1-99). Replaces EPA forms 7550-68 7550-22. Page 5 of 25

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
A.11. Description of Treatment
a. What level of treatment are provided? Check all that apply.
® Primary ® Secondary
® Advanced ❑ Other. Describe: WA
b. Indicate the following removal rates (as applicable):
Design BOD5 removal or Design CBOD5 removal 95 + %
Design SS removal 85 %
Design P removal 80 %
Design N removal 75 %
Other N/A N/A %
C. What type of disinfection is used for the effluent from this outfall? If disinfection varies by season, please describe:
Chlorine Gas
If disinfection is by chlorination is dechlorination used for this ouffall? to Yes ❑ No
Does the treatment plant have post aeration? M Yes ❑ No
A.12. Effluent Testing Information. All Applicants that discharge to waters of the US must provide effluent testing data for the following
parameters. Provide the indicated effluent testing required by the permitting authority for each outfall through which effluent is
discharged. Do not include information on combined sewer overflows in this section. All information reported must be based on date
collected through analysis conducted using 40 CFR Part 136 methods. In addition, this data must comply with QA/OC requirements of
40 CFR Part 136 and other appropriate OA/QC requirements for standard methods for analytes not addressed by 40 CFR Part 136. At a
minimum, effluent testing data must be based on at least three samples and must be no more than four and one-half years apart.
Ouffall number: of
MAXIMUM DAILY VALUE
AVERAGE DAILY VALUE
PARAMETER
Value
Units
Value
Units
Number of Samples
pH (Minimum)
5.2
S.U.
pH (Maximum)
7.5
s.u.
365
Flow Rate
3.579
mgd
1.898
mgd
Temperature (Winter)
24.0
C'
15.5
C'
182
Temperature (Summer)
28.0
C'
23.7
C'
183
' For pH please, report a minimum
and a maximum daily value
MAXIMUM DAILY
AVERAGE DAILY DISCHARGE
POLLUTANT
DISCHARGE
ANALYTICAL
MLIMDL
C.
Unify
Conc.
Units
Number of
METHOD
Samples
CONVENTIONAL AND NON CONVENTIONAL COMPOUNDS
BIOCHEMICAL OXYGEN
�SOD5
8.40
m
3.43
m
365
DEMAND (Report one)
BOD5
WA
WA
WA
WA
WA
FECAL COLIFORM
1,300
• /100 mL
15.86
N /100 mL
365
TOTAL SUSPENDED SOLIDS (TSS)
50.0
m /L
7.38
m
365
END OF PART A.
REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE
EPA Form 3510-2A (Rev. 1-99). Replaces EPA fors 7550-68 7550.22. 1'-i'w 60 ]6

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
BASIC APPLICATION INFORMATION
PART B. ADDITIONAL APPLICATION INFORMATION FOR APPLICANTS WITH A DESIGN FLOW GREATER THAN OR
EQUAL TO 0.1 MGD (100,000 gallons per day).
All applicants with a design flow rate 2 0.1 mild must answer questions B.1 through B.6. All others go to Part C (Certification).
B.I. Inflow and Infiltration. Estimate the average number of gallons per day that flow into the treatment works from inflow and/or infiltration.
135,000 gpd
Briefly explain any steps underway or planned to minimize inflow and infiltration.
The Town budoets $100 000 annually for any sewer line and manhole rehabilitation and replacement
B.2. Topographic Map. Attach to this application a topographic map of the area extending at least one mile beyond facility property boundaries. This
map must show the outline of the facility and the following information. (You may submit more than one map 0 one map does not show the entire
area.)
a. The area surrounding the treatment plant, including all unit processes.
b. The major pipes or other structures through which wastewater enters the treatment works and the pipes or other structures through which
treated wastewater is discharged from the treatment plant. Include oudalls from bypass piping, if applicable.
c. Each well where wastewater from the treatment plant is injected underground.
d. Wells, springs, other surface water bodies, and drinking water wells that are: 1) within % mile of the property boundaries of the treatment
works, and 2) listed in public record or otherwise known to the applicant.
e. Any areas where the sewage sludge produced by the treatment works is stored, treated, or disposed.
I. If the treatment works receives waste that is classified as hazardous under the Resource Conservation and Recovery Act (RCRA) by truck, rail,
or special pipe, show on the map where the hazardous waste enters the treatment works and where it is treated stored, and/or disposed.
B.3. Process Flow Diagram or Schematic. Provide a diagram showing the processes of the treatment plant, including all bypass piping and all
backup power sources or redundancy in the system. Also provide a water balance showing all treatment units, including disinfection (e.g.,
chlorination and dechlorination). The water balance must show daily average flow rates at influent and discharge points and approximate daily flow
rates between treatment units. Include a brief narrative description of the diagram.
B.4. Operation/Maintenance Performed by Contractm(a).
Are any operational or maintenance aspects (related to wastewater treatment and effluent quality) of the treatment works the responsibility of a
contractor! ❑ Yes ® No
If yes, list the name, address, telephone number, and status of each contractor and describe the contractor's responsibilities (attach additional
pages if necessary).
Name: N/A
Mailing Address: N/A
N/A
Telephone Number. ( W/A
Responsibilities of Contractor: WA
B.5. Scheduled Improvements and Schedules of Implementation. Provide information on any uncompleted implementation schedule or
uncompleted plans for improvements that will affect the wastewater treatment, effluent quality, or design capacity of the treatment works. If the
treatment works has several different implementation schedules or is planning several improvements, submit separate responses to question B.5
for each. (If none, go to question B.6.)
a. List the oudall number (assigned in question A.9) for each oudall that is covered by this implementation schedule.
N/A
b. Indicate whether the planned improvements or implementation schedule are required by local, State, or Federal agencies.
❑ Yes ® No
EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550.6 6 7550-22. Page 7 of 25

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
C. If the answer to B.S.b is "Yes," briefly describe, including new maximum daily inflow rate (if applicable).
WA
d. Provide dates imposed by any compliance schedule or any actual dates of completion for the implementation steps listed below, as
applicable. For improvements planned independently of local, State, or Federal agencies, indicate planned or actual completion dates, as
applicable. Indicate dates as accurately as possible.
Schedule Actual Completion
Implementation Stage MM/DD/YVVY MM/DD/YVYY
- Begin Construction WA WA
- End Construction WA WA
- Begin Discharge WA WA
- Attain Operational Level WA NIA
e. Have appropriate permits/clearances conceming other Federal/State requirements been obtained? Yes ® No
Describe briefly: WA
B.6. EFFLUENT TESTING DATA (GREATER THAN 0.1 MGD ONLY).
Applicants that discharge to waters of the US must provide effluent testing data for the following parameters. Provide the indicated
effluent testing required by the permitting authority for each outfall through which effluent is discharoed. Do not include information
on combine sewer overflows in this section. All information reported must be based on data collected through analysis conducted
using 40 CFR Part 136 methods. In addition, this data must comply with QAIQC requirements of 40 CFR Pert 136 and other appropriate
QA/QC requirements for standard methods for analytes not addressed by 40 CFR Part 136. Al a minimum effluent testing data must be
based on at least three pollutant scans and must be no more than four and one-half years old.
Outfall Number: 001
MAXIMUM DAILY
DISCHARGE
AVERAGE DAILY DISCHARGE
POLLUTANT
ANALYTICAL
ML/MOL
Conc.
Units
Conc.
Units
Number of
METHOD
Samples
CONVENTIONAL AND NON CONVENTIONAL
COMPOUNDS
AMMONIA (as N)
< 5.0
mgfL
< 5.0
mWL
260
EPA 3532
5
CHLORINE (TOTAL
RESIDUAL, TRC)
42.0
ugll
3.5
uglL
156
DISSOLVED OXYGEN
16.2
mg(L
9.3
m91L
365
TOTAL KJELDAHL
NITROGEN (TKN)
WA
WA
WA
WA
WA
EPA 3512
0.5
NITRATE PLUS NITRITE
NITROGEN
WA
WA
WA
WA
WA
EPA 353.2
0.1
OIL and GREASE
WA
WA
WA
WA
WA
EPA 1664A
5
PHOSPHORUS (Total)
2.86
moll
0.91
mWL
52
EPA 365.1
0.1
TOTAL DISSOLVED
SOLIDS (TDS)
WA
WA
WA
WA
WA
OTHER: NITROGEN (Total)
29.08
MOIL
15.64
mg/L
52
END OF PART B.
REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE
EPA Fonn 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 & 7550-22. Page 8 of 25

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
BASIC APPLICATION INFORMATION
PART C. CERTIFICATION
All applicants must complete the Certification Section. Refer to instructions to determine who is an officer for the purposes of this
certification. All applicants must complete all applicable sections of Form 2A, as explained in the Application Overview. Indicate below which
parts of Form 2A you have completed and are submitting. By signing this certification statement, applicants confirm that they have reviewed
Form 2A and have completed all sections that apply to the facility for which this application is submitted.
Indicate which parts of Form 2A you have completed and are submitting:
® Basic Application Information packet Supplemental Application Information packet:
® Part D (Expanded Effluent Testing Data)
® Part E (Toxicity Testing: Biomonitonng Data)
® Part F (Industrial User Discharges and RCRA/CERCLA Wastes)
❑ Part G (Combined Sewer Systems)
ALL APPLICANTS MUST COMPLETE THE FOLLOWING CERTIFICATION.
I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who
manage the system or those persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment
for knowing violations.
Name and official title G D. Hann P.E. optenCompany
Signature
Telephone number 252 77 7-1
9
Date signed
Upon request of the permitting authority, you must submit any other Information necessary to assure wastewater treatment practices at the treatment
works or identity appropriate permitting requirements.
SEND COMPLETED FORMS TO:
NCDENR/ DWO
Attn: NPDES Unit
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
EPA Form 351n-2A (Rev. 1-99). Replaces EPA forms 75566 & 7550-22. Page 9 of 27

FACILITY NAME AND PERMIT NUMBER:
Tarboro WWTP, NCO020605
PERMIT ACTION REQUESTED:
Renewal
RIVER BASIN:
Tar -Pamlico
SUPPLEMENTAL APPLICATION INFORMATION
PART D. EXPANDED EFFLUENT TESTING DATA
Refer to the directions on the cover page to determine whether this section applies to the treatment works.
Effluent Testing: 1.0 mgd and Pretreatment Works. If the treatment works has a design flow greater than or equal to 1.0 mgd or it has (or is required
to have) a pretreatment program, or is otherwise required by the permitting authority to provide the data, then provide effluent testing data for the following
pollutants. Provide the indicated effluent testing information and any other information required by the permitting authority for each outfall thouah which
effluent is discharged. Do not include information on combined sewer overflows in this section. All information reported must be based on data collected
through analyses conducted using 40 CFR Part 136 methods. In addition, these data must comply with OA/OC requirements of 40 CFR Part 136 and
other appropriate QA/OC requirements for standard methods for analytes not addressed by 40 CFR Part 136. Indicate in the blank rows provided below
any data you may have on pollutants not specifically listed in this forth. At a minimum, effluent testing data must be based on at least three pollutant
scans and must be no more than four and one-half years old.
Oulfall number: 001 (Complete once for each outall discharging effluent to waters of the United States.)
POLLUTANT
MAXIMUM DAILY DISCHARGE
AVERAGE DAILY DISCHARGE
ANALYTICAL
METHOD
ML/MOL
Cane.
Units
Mass
Units
Cone.
Units
Mass
Units
Number
of
Samples
METALS (TOTAL RECOVERABLE), CYANIDE, PHENOLS, AND HARDNESS.
ANTIMONY
NO
ug1L
3
EPA 2DD.7
5
ARSENIC
<5.0
u9t.
<5.0
U91L
3
EPA 200.7
5
BERYLLIUM
NO
ugfL
3
EPA 200.7
1
CADMIUM
< 1.0
ugfL
< 1.0
U91L
3
EPA 200.7
1
CHROMIUM
<5.0
ugfL
<5.0
uglL
3
EPA 200.7
5
COPPER
15.0
ugll.
6.5
U91L
3
EPA 200.7
5
LEAD
<5.0
ugfL
<5.0
ug1L
3
EPA 200.7
5
MERCURY
2.3
u91L
1.34
US&
3
EPA 245.1
0.2
NICKEL
< 10.0
ug1L
< 10.0
U91L
3
EPA 200.7
10
SELENIUM
< 10.0
uglL
< 10.0
u91L
3
EPA 200.7
10
SILVER
<5.0
ug1L
<5.0
U91L
3
EPA 200.7
5
THALLIUM
NO
uglL
3
EPA 200.7
10
ZINC
55.0
ug1L
26.0
U91L
3
EPA 200.7
10
CYANIDE
<0.005
mg1L
<0.005
m91L
3
SM 4501
0.005
TOTAL PHENOLIC
COMPOUNDS
NO
mglL
3
EPA 420.4
0.01
HARDNESS (as CaCO3)
41.3
mg1L
36.9
ri
3
SM 2340E
0.65
Use this space (or a separate sheet) to provide information on other metals requested by the permit writer
EPA Fomr 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 & 7550-22. Page 10 of 25

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
Oulfall number: 001 (Complete once for each outfall discharging effluent to waters of the United States.)
MAXIMUM DAILY DISCHARGE
AVERAGE DAILY DISCHARGE
POLLUTANT
ANALYTICAL
MLIMDL
Number
Conic.
Units
Maas
Units
Cone.
Units
Mass
Units
of
METHOD
Samples
VOLATILE ORGANIC COMPOUNDS
ACROLEIN
ND
ugfL
3
EPA 624
100
ACRYLONITRILE
NO
ug1L
3
EPA 624
100
BENZENE
NO
Ugfl-
3
EPA 624
5
BROMOFORM
NO
ugfL
3
EPA 624
5
CARBON
TETRACHLORIDE
NO
ug1L
3
EPA 624
5
CHLOROBENZENE
NO
uglL
3
EPA 624
5
CHLORODIBROMO-
NO
ug1L
3
EPA 624
5
METHANE
CHLOROETHANE
NO
ugfL
3
EPA 624
10
2-CHLOROETHYLVINYL
NO
ug/L
3
EPA 624
10
ETHER
CHLOROFORM
NO
uglL
3
EPA 624
5
DICHLOROBROMO-
NO
ug1L
3
EPA 624
5
METHANE
1,1-DICHLOROETHANE
NO
ug1L
3
EPA 624
5
1,2-DICHLOROETHANE
ND
ugfL
3
EPA 624
5
TRANS-I,2-DICHLORO-
ND
ugfL
3
EPA 624
5
ETHYLENE
1,1-DICHLORO-
ETHYLENE
NO
ugfL
3
EPA 624
5
1,2-DICHLOROPROPANE
NO
ugfL
3
EPA 624
5
1,3-DICHLORO-
NO
ugfL
3
EPA 624
5
PROPYLENE
ETHYLBENZENE
NO
ug1L
3
EPA 624
5
METHYL BROMIDE
NO
ug/L
3
EPA 624
5
METHYL CHLORIDE
NO
ugrL
3
EPA 624
5
METHYLENE CHLORIDE
NO
ug/L
3
EPA 624
5
1,1,2,2-TETRA-
NO
ugfl-
3
EPA 624
5
CHLOROETHANE
TETRACHLORO-
ND
ug(L
3
EPA 824
5
ETHYLENE
TOLUENE
NO
ugfL
3
EPA 624
5
EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550.6 & 7550-22. Page 11 of 25

FACILITY NAME AND PERMIT NUMBER:
Tarboro WWTP, NCO020605
PERMIT ACTION REQUESTED:
Renewal
RIVER BASIN:
Tar -Pamlico
Outfall number: 001 (Complete once for each oudall discharging effluent to waters of the United States.)
POLLUTANT
MAXIMUM DAILY DISCHARGE
AVERAGE DAILY DISCHARGE
ANALYTICAL ML/MDL
METHOD
Cone.
Units
Mass
Units
Cone.
Units
Mass
Units
Number
of
Samples
TRICHLOROE7HANE
NO
uglL
3
EPA 824
5
TRIOHLOROETHANE
RIC
NO
uglL
3
EPA 624
5
TRICHLOROETHYLENE
NO
ug(L
3
EPA 624
5
VINYL CHLORIDE
NO
ugfL
3
EPA 624
5
Use this space (or a separate sheet) to provide information on other volatile organic compounds requested by the permit writer
ACID -EXTRACTABLE COMPOUNDS
P-CHLORO-M-CRESOL
NO
uglL
3
EPA 624
10
2-CHLOROPHENOL
NO
ugn.
3
EPA 624
10
2.4-DICHLOROPHENOL
NO
uglL
3
EPA 624
10
2,4-DIMETHYLPHENOL
ND
ugfL
3
EPA 624
10
4,6-DINITRO-0-CRESOL
ND
uglL
3
EPA 624
50
2.4-DINITROPHENOL
NO
uglL
3
EPA 624
50
2-NRROPHEN0L
NO
uglL
3
EPA 624
10
4-NITROPHENOL
NO
ug(L
3
EPA 624
50
PENTACHLOROPHENOL
ND
uglL
3
EPA 624
50
PHENOL
NO
u9fL
3
EPA 624
10
2,4,6-
TRICHLOROPHENOL
NO
uglL
3
EPA 624
10
Use this space (or a separate sheet) to provide information on other acid -extractable compounds requested by the permit writer
BASE -NEUTRAL COMPOUNDS
ACENAPHTHENE
ND
ugA.
3
EPA 625
6.4
ACENAPHTHYLENE
NO
uglL
3
EPA 625
6.4
ANTHRACENE
ND
ugfL
3
EPA 625
6.4
BENZIDINE
NO
ugfL
3
EPA 625
6.4
BENZO(A)ANTHRACENE
NO
uglL
3
EPA 625
6.4
BENZO(A)PYRENE
NO
uglL
3
EPA 625
6.4
EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 6 7550-22. Page 12 of 25

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
Ouffall number. 001 (Complete once for each ouffall discharging effluent to waters of the United States.)
MAXIMUM ONLY DISCHARGE
AVERAGE DAILY DISCHARGE
POLLUTANT
Number
ANALYTICAL
ML/MDL
Conc.
Unite
Mass
Units
Conc.
Units
Maas
Units
of
METHOD
Samples
3.4 BENZO-
FLUORANTHENE
ND
ug/L
3
EPA 825
8.4
SENZO(GHI)PERYLENE
NO
ug1L
3
EPA 625
6.4
BENZO(K)
FLUORANTHENE
NO
ugfL
3
EPA 625
6.4
BIS (2-CHLOROETHOXY)
NO
ug1L
METHANE
3
EPA 625
12.8
BIS (2-CHLOROETHYL)-
NO
�
ETHER
3
EPA 625
6.4
BIS (2-CHLOROISO-
PROPYL) ETHER
NO
ug(L
3
EPA 625
6.4
BIS (2-ETHYLHEXYL)
PHTHALATE
NO
ugll
3
EPA 625
6.4
4-BROMOPHENYL
PHENYL ETHER
NO
ug/L
3
EPA 625
6.4
BUTYL BENZYL
PHTHALATE
NO
uglL
3
EPA 625
6.4
2-CHLORO-
NAPHTHALENE
NO
ugfL
3
EPA 625
6.4
4-CHLORPHENYL
PHENYL ETHER
NO
uWI.
3
EPA 625
6.4
CHRYSENE
NO
ugfL
3
EPA 625
6.4
DI-N-BUTYL PHTHALATE
ND
ug(L
3
EPA 625
6.4
DI-N-OCTYL PHTHALATE
NO
ugfL
3
EPA 625
6.4
DISENZO(A,H)
ANTHRACENE
NO
uglL
3
EPA 825
8.4
1,2-DICHLOROBENZENE
ND
u91L
3
EPA 625
6.4
1,3-DICHLOROBENZENE
ND
ug(L
3
EPA 625
6.4
1,4-DICHLOROBENZENE
ND
ugfL
3
EPA 625
6.4
3,3-DICHLORO-
BENZIDINE
NO
uglL
3
EPA 825
8.4
DIETHYL PHTHALATE
ND
ug/L
3
EPA 625
6.4
DIMETHYL PHTHALATE
ND
ug/L
3
EPA 625
6.4
2.4-DINITROTOLUENE
NO
ug/L
3
EPA 625
6.4
2,6-DINRROTOLUENE
NO
ug/L
3
EPA 625
6.4
1,2.DIPHENYL-
HYDRAZINE
ND
ug/L
3
EPA 625
6.4
EPA For 3510-2A (Rev. 1-99). Replaces EPA fors 7550-68 755622. Page 13 of 25

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
Oudall number. 001 (Complete once for each outfall discharging effluent to waters of the United States.)
MAXIMUM DAILY DISCHARGE
AVERAGE DAILY DISCHARGE
POLLUTANT
Number
ANALYTICAL
MLIMDL
Conc.
Unite
Mass
Units
Conc.
Units
Mass
Units
of
METHOD
Samples
FLUORANTHENE
NO
ug1L
3
EPA 625
6.4
FLUORENE
NO
ugfL
3
EPA 625
6.4
HEXACHLOROBENZENE
NO
ug/L
3
EPA 625
6.4
HEXACHLORO-
BUTADIENE
ND
ug/L
3
EPA 825
8.4
HEXACHLOROCYCLO-
PENTADIENE
NO
uglL
3
EPA 625
12.8
HEXACHLOROETHANE
NO
ugrL
3
EPA 625
6.4
INDENO(1,2,3-CD)
PYRENE
NO
ug/L
3
EPA 625
6.4
ISOPHORONE
NO
uglL
3
EPA 625
12.8
NAPHTHALENE
ND
uglL
3
EPA 625
6.4
NITROBENZENE
NO
ug1L
3
EPA 625
6.4
N-NITROSODI-N-
PROPYLAMINE
ND
uglL
3
EPA 625
6.4
N-NITROSODI-
METHYLAMINE
NO
uglL
3
EPA 625
6.4
N-NITROSODI-
PHENYLAMINE
NO
u911.
3
EPA 625
12.8
PHENANTHRENE
ND
uglL
3
EPA 625
6.4
PYRENE
NO
ug/L
3
EPA 525
6.4
1,2,4-
TRICHLOROBENZENE
NO
ug2
3
EPA 625
6.4
Use this space (or a separate sheet) to provide information on other base -neutral compounds requested by the permit writer
Use this space (or a separate sheet) to provide information on other pollutants (e.g., pesticides) requested by the permit writer
END OF PART D.
REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE
EPA Forth 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 6 7550-22. Page 14 of 25

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
SUPPLEMENTAL APPLICATION INFORMATION
PART E. TOXICITY TESTING DATA
POTWs meeting one or more of the following criteria must provide the results of whole effluent toxicity tests for acute or chronic toxicity for each of the
facility's discharge points: 1) POTWs with a design flow rate greater than or equal to 1.0 mgd; 2) POTWs with a pretreatment program (or those that are
required to have one under 40 CFR Part 403); or 3) POTWs required by the permitting authority to submit data for these parameters.
• At a minimum, these results must include quarterly testing for a 12-month period within the past 1 year using multiple species (minimum of two
species), or the results from four tests performed at least annually in the four and one-half years prior to the application, provided the results
show no appreciable toxicity, and testing for acute and/or chronic toxicity, depending on the range of receiving water dilution. Do not include
information on combined sewer overflows in this section. All information reported must be based on data collected through analysis conducted
using 40 CFR Part 136 methods. In addition, this data must comply with QA/QC requirements of 40 CFR Part 136 and other appropriate QA/QC
requirements for standard methods for analytes not addressed by 40 CFR Part 136.
• In addition, submit the results of any other whole effluent toxicity tests from the past four and one-half years. If a whole effluent toxicity test
conducted during the past four and one -halt years revealed toxicity, provide any information on the cause of the toxicity or any results of a
toxicity reduction evaluation, if one was conducted,
• If you have already submitted any of the information requested In Part E, you need not submit it again. Rather, provide the information
requested in question EA for previously submitted information. If EPA methods were not used, report the reasons for using alternate methods.
If test summaries are available that contain all of the information requested below, they may be submitted in place of Part E.
If no biomonitoring data is required, do not complete Part E. Refer to the Application Overview for directions on which other sections of the forth to
complete.
E.1. Required Tests.
Indicate the number of whole effluent toxicity tests conducted in the past four and one-half years.
❑ chronic ❑ acute
E.2. Individual Test Data. Complete the following chart for each whole effluent toxicity test conducted in the last four and one -hall years. Allow one
column per test (where each species constitutes a test). Copy this page if more than three tests are being reported.
Test number: Test number: Test number:
a. Test information.
Test Species & test method number
Age at initiation of test
Oudall number
Dates sample collected
Date test started
Duration
b. Give toxicity test methods followed.
Manual title
Edition number and year of publication
Page number(s)
c. Give the sample collection method(s) used. For multiple grab samples, indicate the number of grab samples used.
24-Hour composite
Grab
d. Indicate where the sample was taken in relation to disinfection. (Check all that apply for each.
Before disinfection
After disinfection
After dechlorination
EPA Forth 3510-2A (Ray. 1-99). Replaces EPA forms 7550.6 & 7550-22. Page 15 of 25

FACILITY NAME AND PERMIT NUMBER:
Tarboro WWTP, NCO020605
PERMIT ACTION REQUESTED:
Renewal
RIVER BASIN:
Tar -Pamlico
Test number: Test number: Teat number:
e. Describe the point in the treatment process at which the sample was collected.
Sample was collected:
I. For each test, include whether the test was intended to assess chronic toxicity, acute toxicity, or both
Chronic toxicity
Acute toxicity
g. Provide the type of test performed.
Static
Static -renewal
Flow -through
h. Source of dilution water. If laboratory water, specify type; if receiving water, specify source.
Laboratory water
Receiving water
i. Type of dilution water. If salt water, specify 'natural" or type of artificial sea salts or brine used.
Fresh water
Salt water
j. Give the percentage effluent used for all concentrations in the test series.
k. Parameters measured during the test. (State whether parameter meets test method specifications)
pH
Salinity
Temperature
Ammonia
Dissolved oxygen
I. Test Results.
Acute:
Percent survival in 100%
effluent
%
%
%
LCw
95% C.I.
%
%
%
Control percent survival
%
%
%
Other (describe)
EPA Form 35162A (Rev. 1-99). Replaces EPA forms 7550-6 & 7550-22. Page 16 of 25

FACILITY NAME AND PERMIT NUMBER:
Tarboro WWTP, NCO020605
PERMIT ACTION REQUESTED:
Renewal
RIVER BASIN:
Tar -Pamlico
Chronic:
NOEC
%
%
IC2s
%
%
Control percent survival
%
%
Other (describe)
In. Quality Control/Ouality, Assurance.
Is reference toxicant data available?
Was reference toxicant test within
acceptable bounds?
What date was reference toxicant test
run (MM/DDNYYY)?
'
Other (describe)
E.3. Toxicity Reduction Evaluation. Is the treatment works involved in a Toxicity Reduction Evaluation?
❑ Yes ❑ No If yes, describe:
EA. Summary of Submitted Biomonitoring Test Information. If you have submitted biomonitoring test information, or information regarding the
cause of toxicity, within the past four and one-half years, provide the dates the information was submitted to the permitting authority and a summary
of the results.
Date submitted: / / (MM/DDNYYY)
Summary of results: (see instructions)
Please see attached summary.
END OF PART E.
REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE.
EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 & 7550-22. i ,,,, i / ,d �s

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REOUESTED: RIVER BASIN:
Tarboro WWTP, NCO020605 Renewal Tar -Pamlico
Part EA Toxicity Testing Data
Summary of Submitted Biomonitoring Test Information
Organism: Ceriodaphnia Duhia
Date
Pipe
Collection
Testing
Submitted
Number
Date
Date
Method
Summary
01/26/05
001
01/10/05
01/13/05
Chronic Pass/Fail
PASS
05/02A)5
W1
04/18/05
04/21/05
Chronic Pass/Fail
PASS
08/31/05
001
08/15/05
08/18/05
Chronic Pass/Fail
PASS
10/26/05
001
10/10/05
10/13/05
Chronic Pass/Fail
PASS
01/31/06
001
01/16/06
01/19/06
Chronic Pass/Fail
PASS
0425/06
001
04/10/06
04/13/06
Chronic Pass/Fail
PASS
08/01/06
001
07/17/06
0720/06
Chronic Pass/Fail
PASS
10/17/06
001
10/02/06
10/05/06
Chronic Pass/Fail
FAIL
01/11/07
001
01/15/07
01/18/07
Chronic Pass/Fail
PASS
0425/07
001
04/09/07
04/12/07
Chronic Pass/Fail
PASS
0724/07
001
07/19/07
0721/07
Chronic Pass/Fail
PASS
1022/07
001
10/08/07
10/11/07
Chronic Pass/Fail
PASS
01/09/08
001
01/07/08
01/10/08
Chronic Pass/Fail
PASS
04/30/08
001
04/14/08
04/17/08
Chronic Pass/Fail
PASS
0722/08
001
07/07/08
07/10/08
Chronic Pass/Fail
PASS
1029/08
Wl
10/13/08
10/16/08
Chronic Pass/Fail
PASS
01/31/09
001
01/12/09
01/15/09
Chronic Pass/Fail
PASS

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
SUPPLEMENTAL APPLICATION INFORMATION
PART F.INDUSTRIAL USER DISCHARGES AND RCRA/CERCLA WASTES
All treatment works receiving discharges from significant industrial users or which receive RCRA,CERCLA, or other remedial wastes must
complete part F.
GENERAL INFORMATION:
FA. Pretreatment program. Does the treatment works have, or is subject to, an approved pretreatment program?
® Yes ❑ No
F.2. Number of Significant Industrial Users (SlUs) and Categorical Industrial Users (CIUs). Provide the number of each of the following types of
industrial users that discharge to the treatment works.
a. Number of non -categorical SIUs. i
b. Number of ClUs. 3
SIGNIFICANT INDUSTRIAL USER INFORMATION:
Supply the following Information for each SIU. If more than one SIU discharges to the treatment works, copy questions F.3 through F.8 and
provide the information requested for each SIU.
F.3. Significant Industrial User Information. Provide the name and address of each SIU discharging to the treatment works. Submit additional pages
as necessary.
Name: Air System Components
Mailing Address: 3301 Main Street
Tarboro North Carolina 27886
FA. Industrial Processes. Describe all the industrial processes that affect or contribute to the SIU's discharge.
Manufacturing of metal anlls for air conditioning registers
F.S. Principal Product(s) and Raw Material(s). Describe all of the principal processes and raw materials that affect or contribute to the SIU's
discharge.
Principal product(s): Air Duct Registers
Raw material(s): Sheet Metal, Paint
F.B. Flow Rate.
a. Process wastewater flow rate. Indicate the average daily volume of process wastewater discharge into the collection system in gallons per
day (gpd) and whether the discharge is continuous or intermittent.
40.000 gpd (100% continuous or intermittent)
b. Non -process wastewater flow rate. Indicate the average daily volume of non -process wastewater flow discharged into the collection system
in gallons per day (gpd) and whether the discharge is continuous or intermittent.
0 gpd (100% continuous or intermittent)
F.7. Pretreatment Standards. Indicate whether the SIU is subject to the following:
a. Local limits ® Yes ❑ No
b. Categorical pretreatment standards ® Yes ❑ No
If subject to categorical pretreatment standards, which category and subcategory?
40 CFR 433. subpart A
EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-88 7550-22. Page 18 of 25

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
F.S. Problems at the Treatment Works Attributed to Waste Discharge by the SIU. Has the SIU caused or contributed to any problems (e.g.,
upsets, interference) at the treatment works in the past three years?
❑ Yes ® No If yes, describe each episode.
N/A
RCRA HAZARDOUS WASTE RECEIVED BY TRUCK, RAIL, OR DEDICATED PIPELINE:
F.9. RCRA Waste. Does the treatment works receive or has it In the past three years received RCRA hazardous waste by truck, rail or dedicated pipe?
❑ Yes ® No (go to F.12)
F.10. Waste transport. Method by which RCRA waste is received (check all that apply):
❑ Truck ❑ Rail ❑ Dedicated Pipe
F.11. Waste Description. Give EPA hazardous waste number and amount (volume or mass, specify units).
EPA Hazardous Waste Number Amount Units
N/A N/A WA
N/A N/A WA
N/A WA WA
CERCLA (SUPERFUND) WASTEWATER, RCRA REMEDIATION/CORRECTIVE ACTION
WASTEWATER, AND OTHER REMEDIAL ACTIVITY WASTEWATER:
F.12. Remedistion Waste. Does the treatment works currently (or has it been notified that it will receive waste from remedial activities?
❑ Yes (complete F.13 through F.15.) ® No
F.13. Waste Origin. Describe the she and type of facility at which the CERCLA/RCRA/or other remedial waste originates (or is excepted to origniate in
the next five years).
WA
F.14. Pollutants. List the hazardous constituents that are received (or are expected to be received). Include data on volume and concentration, if
known. (Attach additional sheets If necessary.)
NIA
F.15. Waste Treatment
a. Is this waste treated (or will be treated) prior to entering the treatment works?
❑ Yes ❑ No
If yes, describe the treatment (provide information about the removal efficiency):
N/A
b. Is the discharge (or will the discharge be) continuous or intermittent?
❑ Continuous ❑ Intermittent If intermittent, describe discharge schedule.
N/A
END OF PART F.
REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE
EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 755e-6 & 755P22. Page 19 of 25

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REOUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
SUPPLEMENTAL APPLICATION INFORMATION
PART F.INDUSTRIAL USER DISCHARGES AND RCRA/CERCLA WASTES
All treatment works receiving discharges from significant industrial users or which receive RCRA,CERCLA, or other remedial wastes must
complete part F.
GENERAL INFORMATION:
F.I. Pretreatment program. Does the treatment works have, or is subject to, an approved pretreatment program?
® Yes ❑ No
F.2. Number of Significant Industrial Users (SIUs) and Categorical Industrial Users (CIUs). Provide the number of each of the following types of
industrial users that discharge to the treatment works.
C. Number of non -categorical SIUs. 1
d. Number of CIUs. 3
SIGNIFICANT INDUSTRIAL USER INFORMATION:
Supply the following Information for each SIU. If more than one SIU discharges to the treatment works, copy questions F.3 through F.8 and
provide the information requested for each SIU.
F.3. Significant Industrial User Information. Provide the name and address of each SIU discharging to the treatment works. Submit additional pages
as necessary.
Name: Glenoit Mills. Inc.
Mailing Address: 3001 N. Main Street
Tarboro, North Carolina 27886
FA. Industrial Processes. Describe all the industrial processes that affect or contribute to the SIU's discharge.
Raw Stock Dvemo Fiber Preparation Silver Knitting CoatinNHeat SeMng Finishing and Inspection
F.5. Principal Products) and Raw Material(a). Describe all of the principal processes and raw materials that affect or contribute to the SIU's
discharge.
Principal product(s): Silver Knitted Fabrics and Coated Base Rug Fabrics
Raw material(s): Polvprophvlene Acrylic Modacrylic Polyester Nylon Staple Fibers Polvoronhvlene & Polyester Yams Acrylic & Rubber
Coatings
F.6. Flow Rate.
C. Process wastewater flow rate. Indicate the average daily volume of process wastewater discharge into the collection system in gallons
per
day (gpd) and whether the discharge is continuous or intermittent.
188,000 gpd (30% continuous or 70% Intermittent)
d. Non -process wastewater flow rate. Indicate the average daily volume of non -process wastewater flow discharged into the collection system
in gallons per day (gpd) and whether the discharge is continuous or intermittent.
47,000 gpd (100% continuous or inte"ittenq
F.7. Pretreatment Standards. Indicate whether the SIU is subject to the following:
a. Local limits ® Yes ❑ No
b. Categorical pretreatment standards ® Yes ❑ No
If subject to categorical pretreatment standards, which category and subcategory?
40 CFR 410. subpart E
EPA Forth 351p-2A (Rev. 1-99). Replaces EPA forms 75506 & 7550-22. Page 20 of 25

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
F.S. Problems at the Treatment Works Attributed to Waste Discharge by the SIU. Has the SIU caused or contributed to any problems (e.g.,
upsets, interference) at the treatment works in the past three years?
❑ Yes ® No If yes, describe each episode.
N/A
RCRA HAZARDOUS WASTE RECEIVED BY TRUCK, RAIL, OR DEDICATED PIPELINE:
F.9. RCRA Waste. Does the treatment works receive or has it In the past three years received RCRA hazardous waste by truck, rail or dedicated pipe?
❑ Yes ® No (go to F.12)
F.10. Waste transport Method by which RCRA waste is received (check all that apply):
❑ Truck ❑ Rail ❑ Dedicated Pipe
F.11. Waste Description. Give EPA hazardous waste number and amount (volume or mass, specify units).
EPA Hazardous Waste Number Amount Units
N/A N/A WA
N/A N/A WA
N/A N/A WA
CERCLA (SUPERFUND) WASTEWATER, RCRA REMEDIATIOWCORRECTIVE ACTION
WASTEWATER, AND OTHER REMEDIAL ACTIVITY WASTEWATER:
F.12. Rennediation Waste. Does the treatment works currently (or has it been notified that it will receive waste from remedial activities?
❑ Yes (complete F.13 through F.15.) ® No
F.13. Waste Origin. Describe the site and type of facility at which the CERCLA/RCRA/or other remedial waste originates (or is excepted to origniate in
the next five years).
WA
F.14. Pollutants. List the hazardous constituents that are received (or are expected to be received). Include data on volume and concentration, it
known. (Attach additional sheets it necessary.)
WA
F.15. Waste Treatment.
C. Is this waste treated (or will be treated) prior to entering the treatment works?
❑ Yes ❑ No
If yes, describe the treatment (provide information about the removal efficiency):
N/A
d. Is the discharge (or will the Discharge be) continuous or intermittent?
❑ Continuous ❑ Intermittent If intermittent, describe discharge schedule.
WA
END OF PART F.
REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE
EPA Forth 35 f 0-2A (Rev. 1.99). Replaces EPA forms 7550-6 & 7550-22. Page 21 of 25

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
SUPPLEMENTAL APPLICATION INFORMATION
PART F.INDUSTRIAL USER DISCHARGES AND RCRA/CERCLA WASTES
All treatment works receiving discharges from significant industrial users or which receive RCRA,CERCLA, or other remedial wastes must
complete part F.
GENERAL INFORMATION:
F.I. Pretreatment program. Does the treatment works have, or is subject to, an approved pretreatment program?
® yes ❑ No
F.2. Number of Significant Industrial Users (SIUs) and Categorical Industrial Users (CIUs). Provide the number of each of the following types of
industrial users that discharge to the treatment works.
e. Number of non -categorical SIUs. ]
I. Number of CIUs. 3
SIGNIFICANT INDUSTRIAL USER INFORMATION:
Supply the following information for each SIU. ff more than one SIU discharges to the treatment works, copy questions F.3 through F.8 and
provide the Information requested for each SIU.
F.3. Significant Industrial User Information. Provide the name and address of each SIU discharging to the treatment works. Submit additional pages
as necessary.
Name: Kitchens of Sara Lee
Mailing Address: 110 Sara Lee Road
Tarboro, North Carolina 27886
FA. Industrial Processes. Describe all the industrial processes that affect or contribute to the SIU's discharge.
Production of consumable basic food and dessert pastries.
F.S. Principal Product(s) and Raw Material(s). Describe all of the principal processes and raw materials that affect or contribute to the SIU's
discharge.
Principal product(s): Pound Cake, Muffins, Danish. Laver Cakes
Raw material(s): Flour. Epos. Milk, Sugar. Spices. Stabilizers, Colorings Flavorings
F.6. Flow Rate.
e. Process wastewater flow rate. Indicate the average daily volume of process wastewater discharge into the collection system in gallons per
day (gpd) and whether the discharge is continuous or intermittent.
300,000 gpd ( continuous or 100% intermittent)
f. Non -process wastewater flow rate. Indicate the average daily volume of non -process wastewater flow discharged into the collection system
in gallons per day (gpd) and whether the discharge is continuous or intermittent.
50,000 gpd (100% continuous or intermittent)
F.7. Pretreatment Standards. Indicate whether the SIU is subject to the following:
a. Local limits ® yes ❑ No
b. Categorical pretreatment standards ❑ yes ® No
If subject to categorical pretreatment standards, which category and subcategory?
N/A
EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 6 7550-22. Page 22 of 25

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
F.S. Problems at the Treatment Works Attributed to Waste Discharge by the SIU. Has the SIU caused or contributed to any problems (e.g.,
upsets. interference) at the treatment works in the past three years?
❑ Yes ® No If yes, describe each episode.
N/A
RCRA HAZARDOUS WASTE RECEIVED BY TRUCK, RAIL, OR DEDICATED PIPELINE:
F.9. RCRA Waste. Does the treatment works receive or has it in the past three years received RCRA hazardous waste by truck, rail or dedicated pipe?
❑ Yes ® No (go to F.12)
F.10. Waste transport. Method by which RCRA waste is received (check all that apply):
❑ Truck ❑ Rail ❑ Dedicated Pipe
F.11. Waste Description. Give EPA hazardous waste number and amount (volume or mass, specity units).
EPA Hazardous Waste Number Amoun Uni
N/A WA WA
N/A N/A WA
N/A N/A WA
CERCLA (SUPERFUND) WASTEWATER, RCRA REMEDIATIOWCORRECTIVE ACTION
WASTEWATER, AND OTHER REMEDIAL ACTIVITY WASTEWATER:
FA 2. Remediation Waste. Does the treatment works currently (or has It been notified that it will) receive waste from remedial activities?
❑ Yes (complete F.13 through F.15.) ® No
F.13. Waste Origin. Describe the site and type of facility at which the CERCLA/RCRA/or other remedial waste originates (or is excepted to origniate in
the next five years).
N/A
F.14. Pollutants. List the hazardous constituents that are received (or are expected to be received). Include data on volume and concentration, if
known. (Attach additional sheets it necessary.)
N/A
F.15. Waste Treatment.
e. Is this waste treated (or will be treated) prior to entering the treatment works?
❑ Yes ❑ No
If yes, describe the treatment (provide information about the removal efficiency):
WA
I. Is the discharge (or will the discharge be) continuous or intermittent?
❑ Continuous ❑ Intermittent If intermittent, describe discharge schedule.
N/A
END OF PART F.
REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE
EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550.6 & 755422. Page 23 of 25

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
SUPPLEMENTAL APPLICATION INFORMATION
PART F.INDUSTRIAL USER DISCHARGES AND RCRAICERCLA WASTES
All treatment works receiving discharges from significant industrial users or which receive RCRA,CERCLA, or other remedial wastes must
complete part F.
GENERAL INFORMATION:
F.I. Pretreatment program. Does the treatment works have, or is subject to, an approved pretreatment program?
® Yes ❑ No
F.2. Number of Significant Industrial Users (SIUs) and Categorical Industrial Users (CIUS). Provide the number of each of the following types of
industrial users that discharge to the treatment works.
g. Number of non -categorical SIUs. t
h. Number of CIUs. 3
SIGNIFICANT INDUSTRIAL USER INFORMATION:
Supply the following information for each SIU. If more than one SIU discharges to the treatment works, copy questions F.3 through F.8 and
provide the information requested for each SIU.
F.3. Significant Industrial User Information. Provide the name and address of each SIU discharging to the treatment works. Submit additional pages
as necessary.
Name: Mayo Knittino Mill Inc
Mailing Address: P.O. Box 160
Tarboro, North Carolina 27886
F.4. Industrial Processes. Describe all the industrial processes that affect or contribute to the SIU's discharge.
Knittino Dveino Finishing Packaoino and Shiooino of Hosiery
F.5. Principal Product(s) and Raw Material(s). Describe all of the principal processes and raw materials that affect or contribute to the SIU's
discharge.
Principal product(s): Hosiery
Raw matenal(s): Yams. Dyes, Chemicals
F.B. Flow Rate.
g. Process wastewater flow rate. Indicate the average daily volume of process wastewater discharge into the collection system in gallons per
day (gptl) and whether the discharge is continuous or intermittent.
250.000 gptl ( continuous or 10(96 intermittent)
h. Non -process wastewater flow rate. Indicate the average daily volume of non -process wastewater flow discharged into the collection system
in gallons per day (gptl) and whether the discharge is continuous or intermittent.
1,000 gpd (1(>0% continuous or intermittent)
F.7. Pretreatment Standards. Indicate whether the SIU is subject to the following:
a. Local limits ® Yes ❑ No
b. Categorical pretreatment standards ® Yes ❑ No
If subject to categorical pretreatment standards, which category and subcategory?
40 CFR 410, suboart O
EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 8 7550-22. Page 24 of 25

FACILITY NAME AND PERMIT NUMBER:
PERMIT ACTION REQUESTED:
RIVER BASIN:
Tarboro WWTP, NCO020605
Renewal
Tar -Pamlico
F.B. Problems at the Treatment Works Attributed to Waste Discharge by the SIU. Has the SIU caused or contributed to any problems (e.g..
upsets, interference) at the treatment works in the past three years?
❑ Yes ® No If yes, describe each episode.
N/A
RCRA HAZARDOUS WASTE RECEIVED BY TRUCK, RAIL, OR DEDICATED PIPELINE:
F.9. RCRA Waste. Does the treatment works receive or has it in the past three years received RCRA hazardous waste by trick, rail or dedicated pipe?
❑ Yes ® No (go to F.12)
F.10. Waste transport. Method by which RCRA waste is received (check all that apply):
❑ Truck ❑ Rail ❑ Dedicated Pipe
F.11. Waste Description. Give EPA hazardous waste number and amount (volume or mass, specify units).
EPA Hazardous Waste Number Amount Units
N/A N/A WA
N/A N/A WA
WA WA WA
CERCLA (SUPERFUND) WASTEWATER, RCRA REMEDIATIONIXORRECTIVE ACTION
WASTEWATER, AND OTHER REMEDIAL ACTIVITY WASTEWATER:
F.12. Remedlation Waste. Does the treatment works currently (or has it been notified that it will) receive waste from remedial activities?
❑ Yes (complete F.13 through F.15.) ® No
F.13. Waste Origin. Describe the site and type of facility at which the CERCLA/RCRA/or other remedial waste originates (or is excepted to ongniate in
the next We years).
WA
F.14. Pollutants. List the hazardous constituents that are received (or are expected to be received). Include data on volume and concentration, if
known. (Attach additional sheets if necessary.)
WA
F.15. Waste Treatment.
g. Is this waste treated (or will be treated) prior to entering the treatment works?
❑ Yes ❑ No
If yes, describe the treatment (provide information about the removal efficiency):
N/A
It. Is the discharge (or will the discharge be) continuous or intermittent?
❑ Continuous ❑ Intermittent If intermittent, describe discharge schedule.
WA
END OF PART F.
REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE
EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 a 7550-22. Page 25 of 25

Topographic Map &
Process Flow Diagram

G Olf
Course f�
80
ng
Ir
X .-N,
oT w'
0 Af W.U. 1.
A
Influ nf Lines
09
S emw& ra Penn v.
"aa FAuk
0
Tarboro WWTP Discharge
Outfall 001 r:
27.9
Vs
­12
A -
It t
Town of Tarboro WWTP N
NPIDES Permit No. NCO020605
Non -Discharge Permit No. WQ0002047
USGS Quads:
Tarboro, NC 1981
0 500, low- 2M) Rocky Mount, NC 1985
Scale: E_�_

Town of Tarboro Wastewater Treatment Plant
Process Flow Diagram
1, Primary Clarifiers
Anaerobic Digesters Ono*, y
Sludge Drying Beds
I�r
Aerobic Digesters
Aerated Sludge Holding Lagoon
Trickling Filters
Secondary Clarifiers
Activated Sludge
Aeration Basins
` . \ 'al
as
Dre nfection Cascade
Aeration
A
Io

Sludge Management Plan

Sludge Management Plan
Town of Tarboro Wastewater Treatment Plant
NPDES Permit No. NC0020605
Non -Discharge Permit No. WQ0002047
The Town of Tarboro operates a 5.0 mgd modified biological nutrient removal (BNR) plant
which discharges its effluent into the Tar River in the Tar -Pamlico River Basin under NPDES
Permit No. NC0020605. Waste sludge from the primary clarifiers is discharged into two (2)
anaerobic digesters for sludge stabilization while waste activated sludge from the modified BNR
system is pumped to the aerobic sludge digester for stabilizet' . The anaerobically and
aerobically stabilized sludges are later pumped to the aerated sludg basin for further long term
stabilization and storage prior to disposal by land application. Periodically, supernatant from the
anaerobic digester, aerobic digester, and sludge stabilization/storage basin is withdrawn and
recycled back to the plant headworks for reprocessing. Sludge can also be dewatered using
sludge drying beds prior to disposal by land application.
The stabilized sludge that meets pollutant limits and Class B pathogen reduction and vector
attraction reduction requirements is disposed of in accordance with Non -Discharge Permit No.
WQ0002047. The Class B pathogen reduction requirement is met using Alternative 1 and the
vector attraction reduction requirement is met performing Option 9. Pathogen reduction is
verified through in-house monitoring of fecal coliform bacteria. Sludge is land applied on five
sites (37 fields) totaling 828 acres. The 200 acre Tarboro Farm site is owned by the Town while
the Boume Farm and Taylor Farm sites are owned by private parties.

Priority Pollutant Analyses

/ Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceMalytical 2225Riverside 9800 ney Ave. Suite 100
Asheville, NC 28804 Huntersville, NC 28078
wwwpsceNes.com078
[phone] [phone]
January 27, 2009
Mr. Hubert Whitehead
Town of Tarboro
506 Dowd Street
PO Box 220
Tarboro, NC 27886
RE: Project: PPA
Pace Project No.: 9235982
Dear Mr. Whitehead:
Enclosed are the analytical results for sample(s) received by the laboratory on January 13, 2009.
The results relate only to the samples included in this report. Results reported herein conform to the
most current NELAC standards, where applicable, unless otherwise narrated in the body of the
report.
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All
Microbiological analyses were performed at the laboratory where the samples were received.
If you have any questions concerning this report, please feel free to contact me.
ince '
ely,
i
L�rri at��
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
�erA�
Page 1 of 26

aceAnalytical'
.pe .bb..
race Analytical services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: PPA
Pace Project No.: 9235982
Green Bay Certification IDs
Wisconsin DATCP Certification M 105-444
Wisconsin DATCP Certification #: 105-444
Wisconsin Certification #: 405132750
Wisconsin Certification #: 405132750
South Carolina Certification #: 83006001
South Carolina Certification #: 83006001
North Dakota Certification #: R-200
North Dakota Certification M R-150
North Carolina Certification #: 503
North Carolina Certification #: 503
New York Certification #: 11888
Charlotte Certification IDs
West Virginia Certification #: 357
Virginia Certification #: 00213
Tennessee Certification M 04010
South Carolina Drinking Water Cart. #: 990060003
South Carolina Certification #: 990060001
Pennsylvania Certification #: 68-00784
North Carolina Wastewater Certification M 12
Asheville Certification We
West Virginia Certification #: 356
Virginia Certification #: 00072
Tennessee Certification #: 2980
South Carolina Certification #: 99030001
South Carolina Bioassay Certification #: 99030002
Pennsylvania Certification #: 68-03578
North Carolina Wastewater Certification M 40
Eden Certification IDs
Virginia Drinking Water Certification M 00424
North Carolina Wastewater Certification M 633
CERTIFICATIONS
New York Certification #: 11887
Minnesota Certification #: 055-999-334
Minnesota Certification #: 055-999-334
Louisiana Certification M 04169
Louisiana Certification #: 04168
Kentucky Certification #: 83
Kentucky Certification tk 82
Illinois Certification #: 200051
Illinois Certification M 200050
FforidalNELAP Certification M E87951
Floridd/NELAP Certification #: E87948
North Carolina Field Services Certification #: 5342
North Carolina Drinking Water Certification #: 37706
New Jersey Certification M NC012
Louisiana/LELAP Certification #: 04034
Kentucky LIST Certification M 84
Florida/NELAP Certification M E87627
Connecticut Certification #: PH-0104
North Carolina Drinking Water Certification M 37712
North Carolina Bioassay Certification #: 9
New Jersey Certification M NC011
Massachusetts Certification #: M-NC030
Louisiana/LELAP Certification #: 03095
Florida/NELAP Certification #: E87648
Connecticut Certification #: PH-0106
North Carolina Drinking Water Certification #: 37738
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace
eerAnalytical Services, Inc..
Page 2 of 26

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
Or, ^,,,,I„yl�, / s 2225 Riverside Dr. 9800 Kincey Ave. Suite too
IAA /` wly Asheville, NC 28804 Huntersville, NC 28078
a .Pscwm&oxn
[phone] [phone]
Project: PPA
Pace Project No.: 9235982
Lab ID Sample ID
9235982001 Waste Water EFF
SAMPLE ANALYTE COUNT
Method
EPA 1631E
EPA 1664A
EPA 200.7
EPA 245.1
EPA 351.2
EPA 353.2
EPA 365.1
EPA 420.4
EPA 624
EPA 625
SM 2340B
SM 2540C
SM 4500-CN-E
rji_
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of�Pace
+Analytical Services, Inc..
iinte~ 't.
Analysts
GMW
DNP
SHB
EWS
LEP
DMN
JDA
LEP
DJM
BET
SHB
DMN
LEP
Analytes
Reported Laboratory
1
PASI-G
1
PASI-C
14
PASI-A
1
PASI-A
1
PASI-A
3
PASI-A
i
PASI-A
1
PASI-A
40
PASI-C
60
PASI-C
1
PASI-A
1
PASI-A
1
PASI-A
Page 3 of 26

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
' aceAnalytical 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
Asheville, NC 28804 Huntersville. NC 28078
mvw pace�ebamn
[phone] [phone]
ANALYTICAL RESULTS
Project: PPA
Pace Project No.: 9235982
Sample: Waste Water EFF Lab ID: 9235982001 Collected: 01/13/09 08:00 Received: 01/13/09 15:10 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
1631E Mercury, Low Level
Analytical Method: EPA 1631E
Mercury
8.79 ng/L
0.50
1
01/20/0906:00
0112110912:55
7439-97-6
HEM, Oil and Grease
Analytical Method: EPA 1664A
Oil and Grease
NO mg/L
5.0
1
01/18/09 12:03
200.7 MET ICP
Analytical Method: EPA 200.7 Preparation
Method:
EPA 2D0.7
Antimony
NO ug/L
5.0
1
01/19/0910:00
01/22/0917:38
7440-36-0
Arsenic
ND ug/L
5.0
1
01/1910910:00
01/22/0917:38
7440-38-2
Beryllium
NO ug/L
1.0
1
01/19/0910:00
0112210917:38
744041-7
Cadmium
NO ug/L
1.0
1
01/19/0910:00
01/22/0917:38
7440-43-9
Calcium
7890 ug/L
100
1
01/19/0910:00
01/22/0917:38
7440-70-2
Chromium
NO ug/L
5.0
1
01/19/0910:00
01/2210917:38
744047-3
Copper
8.4 ug/L
5.0
1
01/19/0910:00
01/2210917:38
7440-50-8
Lead
NO ug/L
5.0
1
01/19/0910:00
01122/0917:38
7439-92-1
Magnesium
2060 ug/L
100
1
01/1910910:00
01/22/0917:38
7439-954
Nickel
NO ug/L
5.0
1
01/1910910:00
01/22/0917:38
7440-02-0
Selenium
NO ug/L
10.0
1
01/19/0910:00
01/22/0917:38
T78249-2
Silver
NO ug/L
5.0
1
01/19/0910:00
01/2210917:38
744D-224
Thallium
NO uglL
10.0
1
01/1910910:00
01/22/0917:38
7440-28-0
Zinc
28.0 ug/L
_
;10;0.
1
01119/0910:00
01/22/0917:38
7440-66-6
2340E Hardness, Total (Calc.)
Analytical Method: SM 2340B
. .
Total Hardness
32.4 mgll-
0.65
1
01/22/09 17:38
245.1 Mercury
Analytical Method: EPA 245.1 Preparation Method: EPA 245.1
Mercury
NO ug/L
0.20
1
01/14/0911:25
01/1510913:18
7439-97-6
625 MSSV
Analytical Method: EPA 625 Preparation
Method: EPA 625
Acenaphthene
NO ug/L
6.4
1
01/15/09 09:30
01/17/09 04:02
83-32-9
Acenaphthylene
NO ug/L
6.4
1
01115/0909:30
01/17/09 04:02
208-96-8
Anthracene
NO ug/L
6.4
1
01/15/09 09:30
01/17/09 04:02
120-12-7
Senzo(a)anthracene
NO ug/L
6.4
1
01/15/09 09:30
01/17/09 04:02
56.55-3
Benzo(a)pyrene
NO ug/L
6.4
1
01/15/09 09:30
01/1710904:02
50-32-8
Benzo(b)fluoranthene
NO ug/L
6.4
1
01/1510909:30
01/17/09 04:02
205-99-2
Benzo(g,h,i)perylene
NO ug/L
6.4
1
01/15/0909:30
01/1710904:02
191-24-2
Benzo(k)fluoranthene
ND ug/L
6.4
1
0111510909:30
01/17/09 04:02
207-08-9
4-Bromophenylphenyl ether
NO ug/L
6.4
1
01115/0909:30
01/17/09 04:02
101-55.3
Butylbenzylphthalate
NO ug/L
6.4
1
01/15/09 09:30
01/17/09 04:02
85-68-7
4-Chloro-3-methylphenoi
NO ug/L
8.4
1
01/15109 09:30
01/17/09 04:02
59-50-7
bis(2-Chlomethoxy)methane
NO uglL
12.8
1
01115/09 09:30
01/17/09 04:02
111-91-1
bis(2-Chloroethyl) ether
NO ug/L
6.4
1
01/15/09 09:30
01/17/09 04:02
111.44-4
bis(2-Chloroisopropyl) ether
NO ug/L
6.4
1
01/15/09 09:30
01/17/09 04:02
108.60-1
2-Chloronaphthalene
NO ug/L
6.4
1
01/15/09 09:30
01/17/09 04:02
91-58-7
2-Chlorophenol
NO uglL
6.4
1
01/15/09 09:30
01/17/09 04:02
95-57-8
4-Chlorophenylphenyl ether
NO ug/L
6.4
1
01/1510909:30
01/17/09 04:02
7005.72-3
Chrysene
NO ug/L
6.4
1
01/1510909:30
01/17/09 04:02
218-01-9
Date: 01/27/2009 03:37 PM
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except in
full,
without the written consentof
Analytical Services, Inc..
■Pace
�/11Q04:
1g
Page 4 of 26

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalyticals
2225 Riverside 9800 ncey Ave. Suite 100
Asheville, NC 28804 Huntersville, NC 28078078
wxw.nacMeDsmm
[phone] [phone]
ANALYTICAL RESULTS
Project: PPA
Pace Project No.: 9235982
Sample: Waste Water EFF Lab ID: 9235982001 Collected: 01113/09 08:00 Received: 01113109 15:10 Matrix: Water
Parameters
Results Units
Report Limit
OF
Prepared
Analyzed
CAS No. Oual
625 MSSV
Analytical Method: EPA 625
Preparation Method: EPA 625
Dibenz(a,h)anthracene
NO ug/L
6.4
1
01/15109 09:30
01/1710904:02
53-70-3
1,2-Dichlorobenzene
NO ug/L
6.4
1
01/15109 09:30
01/1710904:02
95-50-1
1,3-Dichlorobenzene
NO ug/L
6.4
1
01/15109 09:30
01/17/09 04:02
541-73-1
1,4-Dichlorobenzene
NO ug/L
6.4
1
01/15/09 09:30
01/17/09 04:02
10646-7
3,3'-Dichlorobenzidine
NO ug/L
6.4
1
01/15109 09:30
01/17/09 04:02
91-94-1
2,4-Dichlorophenol
NO ug/L
.Q.4
1
01/1610909:30
01/17/09 04:02
120-83-2
Diethylphthalate
NO ug/L
''' 6.4
1
01/15/09 09:30
01/17/09 04:02
84-66-2
2,4-Dimethylphenol
NO ug/L
12.8
1
01/15/09 09:30
01/17/09 04:02
105-67-9
Dimethylphthalate
NO ug/L
6.4
1
01/15109 09:30
01/1710904:02
131-11-3
Di-n-butylphthalate
NO ug/L
6.4
1
0111510909:30
01/1710904:02
84-74-2
4,6-Dinitro-2-methylphenol
NO ug/L
25.6
1
01/16/09 09:30
01/17/09 04:02
534-52-1
2,4-Dinitrophenol
NO ug/L
64.1
1
0111510909:30
01117/0904:02
51-28-5
2,4-Dinitrotoluene
NO ug/L
6.4
1
01/15109 09:30
01/17/09 04:02
121-14-2
2,6-Dinitrotoluene
NO ug/L
6.4
1
01/15/0909:30
01/17/09 04:02
606-20-2
Din-octylphthalate
NO ug/L
6.4
1
01/15/09 09:30
01/17/09 04:02
117-84-0
1,2-Diphenylhydrazine
NO ug/L
6.4
1
01/15/09 09:30
01/17/09 04:02
122-66-7
bis(2-Ethylhexyl)phthalate
NO ug/L
6.4
1
01/15/09 09:30
01/17/09 04:02
117-81-7
Fluoranlhene
NO ug/L
6.4
1
01/15/09 09:30
01/17/09 04:02
206.44-0
Fluorene
NO uglL
6.4
1
01/15109 09:30
01/17/09 04:02
86-73-7
Hexachlorobenzene
NO ug/L
6.4
1
01/15/09 09:30
01/1710904:02
118-74-1
Hexachlorocyclopentadiene
NO ug/L
12.8
1
01/15/0909:30
01/17/09 04:02
77-47-4
Hexachloroethane
NO ug/L
6.4
1
01/15109 09:30
01/17/09 04:02
67-72-1
Indeno(1,2,3-cd)pyrene
NO ug/L
6.4
1
01/15109 09:30
01/17/09 04:02
193-39-5
Isophorone
NO ug/L
12.8
1
01/15109 09:30
01/17/09 04:02
78-59-1
Naphthalene
NO ug/L
6.4
1
01/15/09 09:30
01/17/09 04:02
91-20-3
Nitrobenzene
ND ug/L
6.4
1
01/15109 09:30
01/17/09 04:02
98-95-3
2-Nitrophenol
NO ug/L
6.4
1
01/15109 09:30
01/1710904:02
88.75-5
4-Nitrophenol
NO ug/L
64.1
1
01/15109 09:30
01/17/09 04:02
100-02-7
N-Nitrosodimethylamine
ND ug/L
6.4
1
01/15/0909:30
01/17/09 04:02
62-75-9
N-Nitrosodi-n-propylamine
NO uglL
6.4
1
0111510909:30
01/17/09 04:02
621-64-7
N-Nitrosodiphenylamine
NO ug/L
12.8
1
01/15109 09:30
01/17/09 04:02
86-30-6
Pentachlorophenol
NO ug/L
3i1
1
01/15109 09:30
01/17/09 04:02
87-86-5
Phenanthrene
ND ug/L
6.4
1
01/15/09 09:30
01/17/09 04:02
85-01-8
Phenol
NO ug/L
6.4
1
01/15/09 09:30
01/17/0904:02
108-95-2
Pyrene
ND ug/L
6.4
1
0111510909:30
01117/0904:02
129-00-0
2,4,6-Trichlorophenol
ND ug/L
12.8
1
01/15/09 09:30
01/1710904:02
88-06-2
Nitrobenzened5 (S)
50 %
10-120
1
01/15/09 09:30
01/17/09 04:02
4165-60-0
2-Fluorobiphenyl(S)
64 %
15-120
1
01/15/09 09:30
01/1710904:02
321-60-8
Terphenyld14(S)
101 %
11-131
1
0111510909:30
01/17/09 04:02
1718-51-0
Phenold6 (S)
21 %
1D-120
1
01/15/09 09:30
01/17/09 04:02
13127-88-3
2-Fluorophenol(S)
33 %
10-120
1
01/15109 09:30
01/1710904:02
367-12.4
2,4,6-Tribromophenol (S)
93 %
10-137
1
01/15109 09:30
01/17/09 04:02
118-79-6
624 Volatile Organics
Analytical Method: EPA 624
Acrolein
NO ug/L
100
1
01/19/0917:29
107-02-8
Acrylonitrile
NO ug/L
100
1
01119/0917:29
107-13-1
Benzene
NO ug/L
5.0
1
01119/0917:29
7143.2
Oate: 01/27/2009 03:37 PM
REPORT OF LABORATORY
ANALYSIS
Page 5 of 26
This report shall not be reproduced, except in full,
without the written consent
of Pam Analytical Services, Inc
5i 1 ICl4�.,ls

Pace Analytical services, Inc. Pace Analytical services, Inc.
' 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
114�51ce Analytical
Asheville. NC 28804 Huntersville, NC 28078
w.vw.pecelebicwn -
[phone] [phone]
ANALYTICAL RESULTS
Project: PPA
Pace Project No.: 9235982
Sample: Waste Water EFF Lab ID: 9235982001 Collected: 01113/09 08:00 Received: 01/13/0915:10 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
624 Volatile Organics Analytical Method: EPA 624
Bromodichloromethane
ND ug/L
5.0
1
01/19/0917:29
75-274
Bromoform
NO ug/L
5.0
1
01/19/0917:29
75-25-2
Bromomethane
NO ug/L
10.0
1
01/19/0917:29
74-83-9
Carbon tetrachloride
ND ug/L
5.0
1
01/19/09 17:29
56-23-5
Chlorobenzene
ND ug/L
5.0
1
01/19/0917:29
108-90-7
Chloroethane
NO uglL
10.0
1
01/19/0917:29
75-00-3
2-Chloroethylvinyl ether
NO ug/L
10.0
1
01/19/'09 17:29
110-75-8
Chloroform
NO ug/L
5.0
1
01/19/0917:29
67-66-3
Chloromethane
NO ug/L
5.0
1
01/19/0917:29
74-87-3
Dibromochloromethane
ND ug/L
5.0
1
01119/0917:29
124-48-1
1,2-Dichlorobenzene
NO ug/L
5.0
1
01/19/0917:29
95-50.1
1,3-Dichlorobenzene
ND ug/L
5.0
1
01/19/09 17:29
541-73-1
1,4-Dichlorobenzene
NO ug/L
5.0
1
01119/0917:29
106-46-7
1,1-Dichloroethane
ND ug/L
5.0
1
01/19/0917:29
75-34-3
1,2-Dihloroethane
NO ug/L
5.0
1
01119/0917:29
107-06-2
1,1-Dichloroethene
NO ug/L
5.0
1
01/19/0917:29
75-354
trans-1,2-Dichloroethene
ND ug/L
5.0
1
01/19/0917:29
156-60-5
1,2-Dichloropropane
NO ug/L
5.0
1
01/1910917:29
78-87-5
cis-1,3-Dichloropropene
NO ug/L
5.0
1
01/19/0917:29
10061-01-5
trans-1,3-Dichloropropene
ND ug/L
5.0
1
01/19/0917:29
10061-02-6
Ethylbenzene
NO ug/L
5.0
1
0111910917:29
100-41-4
Hexachioro-1,3-butadiene
NO ug/L
5.0
1
01119/0917:29
87-68-3
Methylene Chloride
NO ug/L
5.0
1
01/19/09 17:29
75-09-2
Naphthalene
NO ug/L
5.0
1
01/19/0917:29
91-20-3
1, 1,2,2-Tetrachloroethane
NO ug/L
5.0
1
01/19/0917:29
79-34-5
Tetrachloroethene
NO ug/L
5.0
1
01/19/0917:29
127-184
Toluene
NO ug/L
5.0
1
01/1910917:29
108-W3
1,2,4-Trichlorobenzene
NO ug/L
5.0
1
01/1910917:29
120-82-1
1,1,1-Trichloroethane
NO ug/L
5.0
1
01/19/0917:29
71-55-6
1,1,2-Trichloroethane
NO ug/L
5.0
1
01/19/0917:29
79-00-5
Tdchloroethene
NO ug/L
5.0
1
01/1910917:29
79-01-6
Tdchlorofluoromethane
NO ug/L
10.0
1
01/19/0917:29
75-694
Vinyl chloride
NO ug/L
5.0
1
01/19/09 17:29
75-014
Dibromofluoromethane (S)
106 %
88-113
1
01/19/09 17:29
1868-53-7
4-Bromofluorobenzene (S)
103 %
86-111
1
01119/09 17:29
460-004
Toluened8 (S)
104 %
92-105
1
01/19/09 17:29
2037-26-5
1,2-Dichloroethaned4 (S)
98 %
70-130
1
01/19/09 17:29
17060-07-0
2540C Total Dissolved Solids
Analytical Method: SM 2540C
,
Total Dissolved Solids
294 mg/L
26.b
1
01/14/09 18:29
351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2
Nitrogen, Kjeldahl, Total 3.2 mg/L 0.50 1 01/27/09 12:27 7727-37-9
353.2 Nitrogen, NO2IN03 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 16.3 mg/L 0.10 1 01/13/0923:02
Date: 01/27/2009 03:37 PM REPORT OF LABORATORY ANALYSIS Page 6 of 26
This report shall not be reproduced, except in full,
without the written consent
of Pace
Analytical Services, Inc..

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
' 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
aceAnalytical Asheville, NC 28804 Huntersvtlle, NC 28078
www oecereescwn
[phone] [phone]
ANALYTICAL RESULTS
Project: PPA
Pace Project No.: 9235982
Sample: Waste Water EFF
Lab ID: 9235982001 Collected:
01113/09 08:00
Received: 01/13/09 15:10 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrite
ND mg/L
0.10
1
01/1310923:02
Nitrogen, NO2 plus NO3
16.3 mg/L
0.10
1
01/13109 23:02
365.1 Phosphorus, Total
Analytical Method: EPA 365.1
Phosphorus
0.95 mg/L
0.10
1
01/24/09 11:03
7723-14-0
420.4 Phenolics, Total
Analytical Method: EPA 420.4
Phenol
ND mg/L
0.010
1
01/19/0915:40
108-95-2
450OCNE Cyanide, Total
Analytical Method: SM 4500-CN-E
Cyanide
ND mg/L
0.0050
1
01/22/0920:57
57-12-5
Date: 01/27/2009 03:37 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
wi0wut the written consent
of Pace Analytical Services, Inc..
ii 1. 1G161._
Page 7 of 26

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
' 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
aceAnalytical
Asheville, NC 28804 Huntersville, NC 28078
www pe�aleDt.com
[phone] [phone]
QUALITY CONTROL DATA
Project: PPA
Pace Project No.: 9235982
QC Batch: CVFS/1410 Analysis Method: EPA 1631 E
QC Balch Method: EPA 1631E Analysis Description: 1631E Mercury
Associated Lab Samples: 9235982001
METHOD BLANK: 121020
Associated Lab Samples: 9235982001
Parameter Units
ng/L
Mercury
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
NO 0.50 01/21/0910:44
METHOD BLANK: 121021 Matrix: Water
Associated Lab Samples: 9235982001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 01/21/0910:49
METHOD BLANK: 121022
Associated Lab Samples: 9235982001
Parameter Units
ng/L
Mercury
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
NO 0.50 01/21/0911:18
LABORATORY CONTROL SAMPLE & LCSD: 121023
121024
Spike
LCS
LCSD
LCS LCSD
% Rae Max
Parameter Units
Cone.
Result
Result
%Rae %Rec
Limits RPD RPD Qualifiers
Mercury ng/L
5
4.11
4.13
82 83
79-121 .5 24
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 121027
121028
MS
MSD
4013262001
Spike
Spike
MS
MSD MS
MSD %Rec
Parameter Units Result
Cone.
Cone.
Result
Result % Rec % Rae Limits RPD Qual
Mercury ng/L 3.78
15
15
16.2
16.8
83 87 75-125 3
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 121029
121030
MS
MSD
4013282002
Spike
Spike
MS MSD MS MSD % Rae
Parameter Units Result
Cone.
Cone.
Result Result %Rec %Rae Limits RPD Qual
Mercury ng/L 1.28
5
5
5.57 5.66 86 88 75-125 2
Date: 01127/2009 03:37 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 8 of 26

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
' 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
.� c7Ce Alla�ytlCB� Asheville, NC 28804 Huntersville, NC 28078
»ww.petelebacwn
[phone] [phone]
QUALITY CONTROL DATA
Project: PPA
Pace Project No.: 9235982
OC Batch: WETAA233 Analysis Method: EPA 353.2
OC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 9235982001
METHOD BLANK: 222662 Matrix: Water
Associated Lab Samples: 9235982001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate
mg/L
NO 0.10
01/13/0923:02
Nitrogen, Nitrite
mg/L
NO 0.10
01/1310923:02
Nitrogen, NO2 plus NO3
mglL
NO 0.10
01/13109 23:02
LABORATORY CONTROL SAMPLE: 222663
Spike LCS LCS %Rec
Parameter Units Conc. Result % Rao Limits Qualifiers
Nitrogen, Nitrate mg/L 5 5.2 105 90-110
Nitrogen, Nitrite mg/L 1 1.1 107 913-110
Nitrogen, NO2 plus NO3 mg/L 5 5.2 105 90-110
MATRIX SPIKE SAMPLE:
222664
9235851009 Spike
MS MS %Rao
Parameter
Units
Result Conc.
Result %Rao Limits Qualifiers
Nitrogen, Nitrate
mglL
ND 5
5.9 118 90-110 J
Nitrogen, Nitrite
mg/L
0.10 1
1.2 109 90.110
Nitrogen, NO2 plus NO3
mg/L
ND 5
5.9 118 90-110 J
SAMPLE DUPLICATE: 222665
9235851024 Dup
Parameter Units Result Result RPD Qualifiers
Nitrogen, Nitrate mgt- NO NO
Nitrogen, Nitrite mglL 0.14 NO
Nitrogen, NO2 plus NO3 mg/L NO NO
Date: 01/27/2009 03:37 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pam Analytical Services, Inc..
'ia1 IGIW.
Page 9 of 26

�i
alceAnalytical
www perolabs com
Pace Analytical Services, Inc. Pace Analytical Services, Inc.
2225 Riverside Dr. 9800 Kincey Ave. Suite 100
Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone]
Project: PPA
Pace Project No.: 9235982
QC Balch: MERP/1908
QC Batch Method: EPA 245.1
Associated Lab Samples: 9235982001
METHOD BLANK: 222704
Associated Lab Samples: 9235982001
Parameter Units
ug/L
Mercury
LABORATORY CONTROL SAMPLE: 222705
Parameter Units
Mercury ug/L
QUALITY CONTROL DATA
Analysis Method: EPA 245.1
Analysis Description: 245.1 Mercury
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.20 01115/0912:29
Spike LCS LCS % Rep
Conc. Result % Rec Limits Qualifiers
2.5 2.4 97 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 222706
222707
MS
MSD
,r .
9235856001
Spike
Spike
MS MSD MS MSD % Rec
Parameter Units Result
Conc.
Conc.
Result Result %Rec %Rec Limits RPD Qual
Mercury ug/L ND
2.5
2.5
1.5 1.7 60 66 70-130 9 J
SAMPLE DUPLICATE: 222708
9235957001 Dup
Parameter Units Result Result
Mercury ug/L 0.30 NO
')ate: 01/27/2009 03:37 PM
RPD Qualifiers
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consentofPaw Analytical Services, Inc..
Page 10 of 26

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
' 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
aceAna/ytical Asheville. NC 28804 Huntersville, NC 28078
wrvw pecelebscwn
[phone] [phone]
QUALITY CONTROL DATA
Project: PPA
Pace Project No.: 9235982
OC Batch: WET/6912 Analysis Method: SM 2540C
QC Batch Method: SM 2540C Analysis Description: 2540C Total Dissolved Solids
Associated Lab Samples: 9235982001
Mt I HOD BLANK: 223254
Associated Lab Samples: 9235982001
Parameter Units
Total Dissolved Solids mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed
NO 1.0 01/14/0918:27
Qualifiers
LABORATORY CONTROL SAMPLE: 223255
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Total Dissolved Solids mg/L 250 220 88 80-120
SAMPLE DUPLICATE: 223256
Parameter
Total Dissolved Solids
Date: 01/27/2009 03:37 PM
9235727002 Dup
Units Result Result
mg/L 206 232
RPD Qualifiers
12
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent
of Pace Analytical Services, Inc..
Page 11 of 26

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalyticalJ 2225 Riverside Dr. 9800 Kincey Ave. Suite too
xww.pecNJbsmm
Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone]
QUALITY CONTROL DATA
Project: PPA
Pace Project No.: 9235982
OC Batch: OEXT/5581
Analysis Method:
EPA 625
OC Batch Method: EPA 625
Analysis Description:
625 MSS
Associated Lab Samples: 9235982001
METHOD BLANK: 223337
Matrix: Water
Associated Lab Samples: 9235982001
Blank Reporting
Parameter
Units Result Limit
Analyzed
1,2-Dichlorobenzene
ug/L
NO
5.0
01/1610916:35
1,2-Diphenylhydrazine
ug/L
NO
5.0
01/16/09 16:35
1,3-Dichlorobenzene
ug/L
NO `I
- 5.0
01/16/09 16:35
1,4-Dichlorobenzene
ug/L
NO
5.0
01/1610916:35
2,4,6-Tdchlorophenol
ug/L
NO
10.0
01/1610916:35
2,4-Dichlorophenol
ug/L
NO
5.0
01116/0916:35
2,4-Dimethylphenol
ug/L
NO
10.0
01/16/09 16:35
2,4-Dinitrophenol
ug/L
NO
50.0
01/16/09 16:35
2,4-Dinitrotoluene
ug/L
NO
5.0
0111610916:35
2,6-Dinitrotoluene
ug/L
NO
5.0
01/16/0916:35
2-Chloronaphthalene
ug/L
NO
5.0
01/16/09 16:35
2-Chlorophenol
ug/L
NO
5.0
01/16/0916:35
2-Nitrophenol
ug/L
NO
5.0
01116/0916:35
3,3'-Dichlorobenzidine
ug/L
NO
5.0
01/16/0916:35
4,6-Dinitro-2-methylphenol
ug/L
NO
20.0
01/16(0916:35
4-Bromophenylphenyl ether
ug/L
NO
5.0
01/16/0916:35
4-Chioro-3-methylphenol
ug/L
NO
5.0
01/16/09 16:35
4-Chlorophenylphenyl ether
ug/L
NO
5.0
01/16/09 16:35
4-Nitrophenol
ug/L
NO
50.0
01/16/09 16:35
Acenaphthene
ug/L
NO
5.0
01/1610916:35
Acenaphthylene
ug/L
NO
5.0
01/1610916:35
Anthracene
ug/L
NO
5.0
01116/0916:35
Benzo(a)anthracene
ug/L
NO
5.0
01/16/09 16:35
Benzo(a)pyrene
ug/L
NO
5.0
01/16/0916:35
Benzo(b)8uoranthene
ug/L
NO
5.0
01116/0916:35
Benzo(g,h,i)perylene
ug/L
NO
5.0
01/1610916:35
Benzo(k)fiuoranthene
ug/L
NO
5.0
01/16/09 16:35
bis(2-Chioroethoxy)methane
ug/L
NO
1b.0
01116/0916:35
bis(2-Chloroethyl) ether
u9/1-
NO
5.0
01/1610916:35
bis(2-Chioroisopropyl) ether
ug/L
NO
5.0
01/16/09 16:35
bis(2-Ethylhexyl)phthalate
ug/L
NO
5.0
01/16t0916:35
Butylbenzylphthatate
ug/L
NO
5.0
01116/0916:35
Chrysene
ug/L
NO
5.0
01/16t0916:35
Di-n-butylphthalate
ug/L
NO
5.0
01/1610916:35
Di-noctylphthalate
ug/L
NO
5.0
01/16/09 16:35
Dibenz(a,h)anthracene
ug/L
NO
5.0
01/16/0916:35
Diethylphthalate
ug/L
NO
5.0
01/16/09 16:35
Dimethylphthalate
uglL
NO
5.0
01/16/09 16:35
Fluoranthene
ug/L
NO
5.0
01/16/0916:35
Fluorene
ug/L
NO
5.0
01/1610916:35
Hexachlorobenzene
ug/L
NO
5.0
01/16/0916:35
Hexachlorocyclopentadiene
ug/L
NO
10.0
01/1610916:35
Hexachloroethane
ug/L
NO
5.0
01/1610916:35
'late: 01/27/2009 03:37 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of PaceAnalytical Services, Inc..
Qualifiers
Page 12 of 26

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
2225 Riverside Dr. 9800 Kincey Ave. Suite 100
ace Analytical Asheville, NC 28804 Huntersville, NC 28078
www pecelebs.rom
[phone] [phone]
QUALITY CONTROL DATA
Project: PPA
Pace Project No.: 9235982
METHOD BLANK: 223337
Matrix:
Water
Associated Lab Samples: 9235982001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Irideno(1,2,3-cd)pyrene
ug/L
ND
5.0
0111610916:35
Isophorone
ug/L
NO
10.0
01/16/09 16:35
N-Nitroso-di-n-propylamine
ug/L
ND
5.0
0111610916:35
N-Nitrosodimethylamine
ug/L
NO
5.0
01/16/09 16:35
N-Nitrosodiphenylamine
ug/L
ND
10.0
01116/0916:35
Naphthalene
ug/L
NO
5.0
01/16/0916:35
Nitrobenzene
ug/L
NO
5.0
01/1610916:35
Pentachlorophenol
ug/L
ND
25.0
01/16/09 16:35
Phenanthrene
ug/L
ND
5.0
01/1610916:35
Phenol
ug/L
NO
5.0
0111610916:35
Pyrene
ug/L
NO
5.0
01/1610916:35
2,4,6-Tribromophenol(S)
%
25
10-137
01/16/09 16:35
2-Fluorobiphenyl (S)
%
74
15-120
01/16/09 16:35
2-Fluorophenol (S)
%
23
10-120
01/16/09 16:35
Nitrobenzened5(S)
%
69
ID-120
01/16/09 16:35
Phenold6(S)
%
17
I'4120
01/16/09 16:35
Terphenyldl4(S)
%
91
11-131
01/16t0916:35
LABORATORY CONTROL SAMPLE: 223338
Qualifiers
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
%Rao
Limits Qualifiers
1,2-Dichlorobenzene
ug1L
50
22.5
45
32-129
1,2-Diphenylhydrazine
ug/L
50
29.9
60
25-150
1,3-Dichlorobenzene
ug/L
50
21.8
44
1-172
1,4-Dichlorobenzene
ug/L
50
22.3
45
20-124
2,4,6-Trichlorophenol
ug/L
50
34.0
68
37-144
2,4-Dichlorophenol
ug/L
50
28.7
57
1-191
2,4-Dimethylphenol
ug/L
50
17.4
35
32-119
2,4-Dinitrophenol
ug/L
50
29.41
59
1-181
2,4-Dinitrotoluene
ug/L
50
28.0
56
39-139
2,6-Dinitrotoluene
ug/L
50
30.9
62
50-158
2-Chloronaphthalene
ug/L
50
35.8
72
60-118
2-Chlorophenol
ug/L
50
29.3
59
23-134
2-Nitrophenol
ug/L
50
28.6
57
29-182
3,3'-Dichlorobenzidine
ug/L
50
NO
2
1-262
4,6-Dinitro-2-methylphenol
ug/L
50
31.6
63
1-181
4-Bromophenylphenyt ether
ug/L
50
35.1
70
53-127
4-Chloro-3-methylphenol
ug/L
50
30.2
60
22-147
4-Chlorophenylphenyl ether
ug/L
50
34.1%
70
25-158
4-Nitrophenol
uglL
50
17A
35
1-132
Acenaphthene
ug/L
50
28.6
57
47-145
Acenaphthylene
ug/L
50
29.2
58
33-145
Anthracene
ug/L
50
22.3
45
1-166
Benzo(a)anthracene
ug/L
50
28.8
58
33.143
Benzo(a)pyrene
ug/L
50
23.8
48
17-163
late: 01/27/2009 03:37 PM REPORT OF LABORATORY ANALYSIS Page 13 of 26
This report shall not be reproduced, except in full,
without the written consent
of�Pace
+Analytical Services, Inc..
4Y 1. lGa4l.:

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
2225 Riverside Dr, 9800 Kincey Ave. Suite 100
aceAnalytical Asheville, NC 28804 Hunlersville, NC 28078
vw,r peceleGs mm
[phone] [phone]
QUALITY CONTROL DATA
Project: PPA
Pace Project No.: 9235982
LABORATORY CONTROL SAMPLE: 223338
Parameter
Benzo(b)fluoranlhene
ug/L
Berizo(g,hJ)perylene
ug/L
Senzo(k)fluoranthene
ug/L
bis(2-Chloroethoxy)methane
ug/L
bis(2-Chloroelhyl) ether
ug/L
bis(2-Chloroisopropyl) ether
ug/L
bis(2-Ethyihexyl)phlhalate
ug/L
Butylbenzylphlhalate
ug/L
Chrysene
ug/L
Di-n-butylphthatale
ug/L
Di-noctylphthalate
ug/L
Dibenz(a,h)anthracene
ug/L
Diethylphthalate
ug/L
Dimethylphthalate
ug/L
Fluoranthene
ug/L
Flucrene
ug/L
Hexachlorobenzene
ug/L
Hexachlorocyclopentadiene
ug/L
Hexachloroethane
ug/L
Indeno(1,2,3-cd)pyrene
ug/L
Isophorone
ug/L
N-Nitrosodi-n-propylamine
ug/L
N-Nitrosodimethylamine
ug/L
N-Nitrosodiphenylamine
ug/L
Naphthalene
ug/L
Nitrobenzene
ug/L
Pentachlorophenol
ug/L
Phenanthrene
ug/L
Phenol
ug/L
Pyrene
ug/L
2,4,6-Tribromophenol(S)
%
2-Fluorobiphenyl (S)
%
2-Fluorophenol (S)
%
Nitrobenzened5 (S)
%
Phenold6 (S)
%
Terphenyldl4 (S)
%
Spike
Units Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
50
28.7
57
24-159
50
31.3
63
1-219
50
34.0
68
11-162
50
32.8
66
33-184
50
33.0
66
12-158
50
57.5
115
36-166
50
33.9
68
8-158
50
34.2
68
1-152
50
31.0
62
17-168
50
34.9
70
1-118
50
34.0
68
4-146
50
33.3
67
1-227
50
35.6
71
1-114
50
35.7
71
1-112
50
30.0
60
26-137
50
33.8
68
59-121
50
29.0
58
1-152
50
33.6
67
25-150
50
22.7
45
40-113
50
32.9
66
1-171
50
51.2
102
21-196
50
32.9
66
1-230
50
24.5
49
25-150
50
22.8
46
25-150
50
27.4
55
21-133
50
Y§J
58
35-180
50
38.3
77
14-176
50
3f.b
62
54-120
50
'9.8
20
5.112
50
21.4
55
52-115
82
10-137
56
15-120
35
10-120
58
10-120
20
1D-120
63
11-131
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 223339 223340
MS
MSD
9235982001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Cono,
Result
Result
%Rec
%Rec
Limits
RPD Qual
1,2-Dichlorobenzene
ug/L
NO
111
111
65.9
48.3
59
43
32-129
31 J
1,2-Diphenylhydrazine
ug/L
ND
111
111
96.4
79.5
87
72
25-150
19
1,3-Dichiorobenzene
ug/L
ND
111
111
64.6
45.6
58
41
1-172
34 J
1,4-Dichiorobenzene
ug/L
ND
711
111
66.1
47.1
59
42
20-124
34 J
2,4,6-Trichlorophenol
ug/L
ND
111
111
100
91.8
90
83
37-144
9
2,4-Dichlorophenol
ug/L
ND
111
111
61.8
53.3
56
48
1-191
15
Date: 01/27/2009 03:37 PM REPORT OF LABORATORY ANALYSIS Page 14 of 26
This report shall not be reproduced, except in full,
without the written consent
of PPaac�e+Analytical Services, Inc..
.�I.IGIO.4

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
' 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
117�ace Analytical Asheville. NC 28804 Hunlersville, NC 28078
www.peab09 am
[phone] [phone]
QUALITY CONTROL DATA
Project: PPA
Pace Project No.: 9235982
MATRIX SPIKE 8 MATRIX SPIKE DUPLICATE: 223339 2233Q
MS
MSD
9235982001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
%Rec
%Rao
Limits
RPD Qual
2,4-Dimethylphenol
ug/L
ND
111
111
66.6
50.3
60
45
32-119
28
2,4-Dinitrophenot
ug/L
NO
111
111
25.41
35.71
23
32
1-181
2,4-Dinitrololuene
ug/L
NO
111
ill
81.1
70.8
73
64
39-139
14
2,6-Dinitrotoluene
ug/L
NO
111
111
89.8
78.3
81
70
50-158
14
2-Chloronaphthalene
ug/L
NO
111
111
87.6
72.2
79
65
60-118
19
2-Chlorophenol
ug/L
NO
111
111
90.3
71.8
81
65
23-134
23
2-Nitrophenol
ug/L
ND
111
111
62.6
t-33.7
53.9
56
49
29-182
15
3,3'-Dichlorobenzidine
ug/L
ND
111
111
13.5
30
12
1-262
85 J
4,6-Dinitro-2-methylphenol
ug/L
NO
111
117
40.51
46.3
36
42
1-181
4-Bromophenylphenyl ether
ug/L
NO
111
111
- 106
93.1
95
84
53-127
13
4-Chloro-3-methylphenol
ug/L
NO
111
111
69.9
62.4
63
56
22-147
11
4-Chlorophenylphenyl ether
ug/L
ND
111
111
105
93.0
94
84
25-158
12
4-Nitrophenol
ug/L
NO
111
ill
44.71
40.21
40
36
1-132
Acenaphthene
ug/L
NO
111
111
97.4
82.7
88
74
47-145
16
Acenaphthylene
ug/L
ND
111
111
104
81.3
94
73
33.145
25
Anthracene
ug/L
NO
111
111
95.9
82.8
86
75
1-166
15
Benzo(a)anthracene
ug/L
NO
111
111
93.2
80.2
84
72
33.143
15
Benzo(a)pyrene
ug1L
NO
111
111
105
86.1
94
78
17-163
19
Benzo(b)fluoranlhene
ug/L
ND
111
111
119
102
107
92
24-159
15
Benzo(g,hJ)perylene
ug/L
NO
111
111
53.7
49.4
48
44
1-219
8
Benzo(k)fluoranthene
ug/L
NO
111
111
95.5
116
86
104
11-162
19
bis(2-Chloroethoxy)methane
ug/L
NO
111
111
74.5
64.4
67
58
33.184
15
bis(2-Chloroethyl) ether
ug/L
NO
111
111
92.0
76.6
83
69
12-158
18
bis(2-Chioroisopropyl) ether
ug/L
NO
111
111
108
73.3
97
66
36-166
38 J
bis(2-Ethylhexyl)phthalate
ug/L
NO
111
111
106
121
95
109
8-158
13
Butylbenzylphthalate
ug/L
NO
111
111
95.2
112
86
101
1-152
16
Chrysene
ug/L
NO
111
Ill
87.7
79.6
79
72
17-168
10
Di-n-butylphthalate
ug/L
NO
111
111
99.9
90.9
90
82
1-118
9
Di-noctylphthalate
ug/L
NO
111
ill
102
108
92
97
4-146
6
Dibenz(a,h)anthracene
ug/L
ND
111
111
53.5
48.9
48
44
1-227
9
Diethylphthalate
ug/L
NO
111
111
103
90.7
92
82
1-114
12
Dimethylphthalate
ug/L
NO
111
111
95.4
84.0
86
76
1-112
13
Fluoranthene
ug/L
NO
711
111
16.2
68.9
69
62
26-137
10
Fluorene
ug/L
NO
111
111
109
93.4
98
84
59-121
16
Hexachlorobenzene
ug/L
ND
111
111
90.7
81.1
82
73
1-152
11
Hexachlorocyclopentadiene
ug/L
NO
111
111
49.6
37.5
45
34
25-150
28
Hexachloroethane
ug/L
NO
111
111
62.5
45.1
56
41
40-113
32 J
Indeno(1,2,3-cd)pyrene
ug/L
NO
111
111
54.5
49.3
49
44
1-171
10
Isophorone
ug/L
ND
111
111
90.7
100
82
90
21-196
10
N-Nitroso-0I-n-propylamine
ug/L
NO
111
111
108
92.3
97
83
1-230
16
N-Nitrosodimethylamine
ug/L
NO
111
111
88.3
70.1
79
63
25-150
23
N-Nitrosodiphenylamine
ug/L
ND
111
111
103
96.0
93
86
25-150
7
Naphthalene
ug/L
NO
111
111
66.3
54.0
60
49
21-133
21
Nitrobenzene
ug/L
ND
111
111
61.4
53.0
55
48
35-180
15
Pentachlorophenol
ug/L
NO
171
111
73.6
76.3
66
69
14-176
4
Phemnthrene
ug/L
NO
111
111
85.6
82.0
77
74
54-120
4
Phenol
ug/L
NO
111
111
54.6
45.0
49
41
5-112
19
Date: 01/27/2009 03:37 PM
REPORT OF LABORATORY ANALYSIS
Page 15 of 26
This report shall not be reproduced, except in full,
without the written consent
of Paw Analytical Services, Inc..

�PaceAnalytical o
. pecNebs.c
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite too
Hunlersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: PPA
Pace Project No.: 9235982
MATRIX SPIKE 8 MATRIX SPIKE DUPLICATE: 223339
223340
MS
MSD
9235982001 Spike
Spike
MS
MSD MS
MSD
%Rec
Parameter
Units Result Conc.
Conc.
Result
Result % Rec
% Rec
Limits RPD Qual
Pyrene
ug/L ND 111
111
95.5
107 86
96
52-115 11
2,4,6-Tribromophenol(S)
%
92
94
10-137
2-Fluorobiphenyl (S)
%
86
75
15-120
2-Fluorophenol (S)
%
61
49
10-120
Nitrobenzene-d5 (S)
%
59
52
10-120
Phenol-d6 (S)
%
46
39
10-120
Terphenyl-dl4 (S)
%
111
100
11-131
Date: 01/27/2009 03:37 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Paw Analytical Services, Inc..
ii1.I4144.�:
Page 16 of 26

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalytical 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
www perolebsmm
Asheville. NC 28804 Huntersville, NC 28078
[phone] [phone]
QUALITY CONTROL DATA
Project: PPA
Pace Project No.: 9236982
QC Batch: MPRP/3679
Analysis Method: EPA 200.7
QC Batch Method: EPA 200.7
Analysis Description: 200.7 MET
Associated Lab Samples: 9235982001
METHOD BLANK: 224424
Matrix: Water
Associated Lab Samples: 9235982001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Qualifiers
Antimony
ug/L
ND
5.0
01/2210915:21
Arsenic
ug/L
ND
5.0
01/22/0915:21
Beryllium
ug/L
NO
1.0
01/2210915:21
Cadmium
ug/L
NO
1.0
01/2210915:21
Calcium
ug/L
ND
100
01/22/0915:21
Chromium
ug/L
NO
5.0
01/2210915:21
Copper
ug/L
ND
5.0
01/2210915:21
Lead
ug/L
NO
5.0
01/22/0915:21
Magnesium
ug/L
NO
100
01/22/0915:21
Nickel
ug/L
ND
5.0
01/22/0915:21
Selenium
ug/L
NO
10.0
01/22/0915:21
Silver
ug/L
NO
5.0
01/22/0915:21
Thallium
ug/L
ND
10.0
01/22/0915:21
Zinc
ug/L
NO
10.0
01/22/09 15:21
LABORATORY CONTROL SAMPLE:
224425
Spike
LCS
LCS %Roo
Parameter
Units
Conc.
Result % Rec Limits Qualifiers
Antimony
ug/L
500
- . 521
104
85-115
Arsenic
ug/L
500
470
94
85-115
Beryllium
ug/L
500
479
96
85-115
Cadmium
ug/L
500
480
96
85-115
Calcium
ug/L
5000
4750
95
85-115
Chromium
ug/L
500
471
94
85-115
Copper
ug/L
500
463
93
85-115
Lead
ug/L
500
486
97
85-115
Magnesium
ug/L
5000
4720
94
85-115
Nickel
ug/L
500
472
94
85-115
Selenium
ug/L
500
473
95
85-115
Silver
ug/L
250
238
95
85-115
Thallium
ug/L
500
448
90
85-115
Zinc
ug/L
500
476
95
85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 224515
224516
MS
MSD
9236116001
Spike
Spike
MS
MSD MS
MSD
% Rao
Parameter Units Result
Conc.
Conc.
Result
Result % Rec % Rec
Limits RPD Qual
Antimony ug/L
NO
500
500
524
512 105 102
70-130 2
Arsenic ug/L
ND
500
500
475
465
95 93
70-130 2
Beryllium ug/L
NO
500
500
475
457
95 91
70-130 4
rate: 01/27/2009 03:37 PM
REPORT OF LABORATORY ANALYSIS
Page 17 of 26
This report shall not be reproduced, except in full,
without the written consent of Pam Analytical Services, Inc
1 `1 ielk �

Pace Analytical Services, Inc
2225 Riverside Or
"" "" —J ""'"" Asheville, NC 28804
www pecelaDsc°m
[phone]
Pace Analytical Services, Inc.
9800 Kmcey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: PPA
Pace Project No.: 9235982
MATRIX SPIKE 8 MATRIX SPIKE DUPLICATE: 224515
224516
MS
MSD
9236116001
Spike
Spike
MS
MSD
MS
MSD
%Rec
Parameter
Units
Result
Conic.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Cadmium
ug/L
NO
500
500
478
463
96
93
70-130
3
Calcium
ug/L
9210
5000
5000
13800
13400
91
83
70-130
3
Chromium
ug/L
NO
500
500
465
446
93
89
70-130
4
Copper
ug/L
14.4
500
500
472
460
92
89
70-130
3
Lead
ug/L
NO
500
500
482
468
96
93
70-130
3
Magnesium
ug/L
3750
5000
5000
8370
8200
92
89
70-130
2
Nickel
ug/L
NO
500
500
463
448
92
89
70-130
3
Selenium
ug/L
ND
500
500
468
460
94
92
70-130
2
Silver
ug/L
NO
250
250
238
232
95
93
70-130
3
Thallium
ug/L
ND
500
500
440
430
88
86
70-130
2
Zinc
ug/L
58.9
500
500
537
525
96
93
70-130
2
SAMPLE DUPLICATE: 224428
Parameter
Units
9235983003
Result
Dup
Result
Antimony
ug/L
NO
NO
Arsenic
ug/L
0.0071 mg/L
6.4
Beryllium
ug/L
NO
NO
Cadmium
ug/L
0.0019 mg/L
1.9
Calcium
ug/L
28.9 mg/L
29100
Chromium
ug/L
0.019 mg/L
18.5
Copper
ug/L
0.042 ni
42.2
Lead
ug/L
NO
NO
Magnesium
ug/L
1.5 mg/L
1550
Nickel
ug/L
0.048 mg/L
47.9
Selenium
ug/L
NO
NO
Silver
ug/L
NO
.391
Thallium
ug/L
NO
NO
Zinc
ug/L
0.35 mg(L
353
Date: 01/27/2009 03:37 PM
RPD Qualifiers
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent
of Pace
Analytical Services, Inc..
10
.5
.4
.5
.5
1
4
1
Page 18 of 26

I'W aceAnalyticaI
. pBLeMUs.c
Pace Analytical Services, Inc. Pace Analytical Services, Inc.
2225 Riverside Dr. 9800 Kincey Ave. Suite 100
Asheville. NC 28804 Hunlersville, NC 28078
[phone] [phone]
Project: PPA
Pace Project No.: 9235982
QC Batch: GCSV/4561
OC Batch Method: EPA 1664A
Associated Lab Samples: 9235982001
METHOD BLANK: 224740
Associated Lab Samples: 9235982001
Parameter Units
Oil and Grease mg/L
LABORATORY CONTROL SAMPLE: 224741
Parameter Units
Oil and Grease mg/L
QUALITY CONTROL DATA
Analysis Method: EPA 1664A
Analysis Description: 1664 HEM, Oil and Grease
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
NO 5.0 01/18/0912:03
Spike LCS LCS %Rec
Conc. Result %Rec Limits Qualifiers
40 35.8 90 78-114
MATRIX SPIKE SAMPLE: 224742
9236051001 + • $jltke MS MS % Rec
Parameter Units Result Conc. Result % Rec Limits Qualifiers
Oil and Grease mg/L ND 40 38.5 93 78-114
Oate: 01/27/2009 03:37 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace AnalyBcal Services, Inc..
Page 19 of 26

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
Ce ^,,,,r, y,G„�/• 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
A I ly Asheville, NC 28804 Huntersville, NC 28078
i~peceisli
[phone] [phone]
QUALITY CONTROL DATA
Project: PPA
Pace Project No.: 9235982
QC Batch: MSW5889 Analysis Method: EPA 624
QC Batch Method: EPA 624 Analysis Description: 624 MSV
Associated Lab Samples: 9235982001
METHOD BLANK: 224749
Associated Lab Samples:
Parameter
9235982001
Units
Matrix:
Blank
Result
Water
Reporting
Limit
Analyzed
1,1,1-Trichloroelhene
ug/L
NO
5.0
01119/0915:30
1.1,2,2-Tetrachioroelhane
ug/L
NO
5.0
01/19/09 15:30
1,1,2-Trichioroethane
ug/L
ND
5.0
01/19/09 15:30
1,1-Dichloroethane
ug/L
NO
5.0
01/19/09 15:30
1,1-Dichloroethene
ug/L
NO
5.0
01119/0915:30
1,2,4-Trichlorobenzene
ug/L
NO
5.0
01119/0915:30
1,2-Dichlorobenzene
ug/L
NO
5.0
01/19/09 15:30
1,2-Dichloroethane
ug/L
NO
5.0
01/19/09 15:30
1,2-Dichloropropane
ug/L
ND
5.0
01/19/09 15:30
1,3-Dichlorobenzene
ug/L
NO
5.0
01/1910915:30
1,4-Dichlorobenzene
ug/L
NO
5.0
01/19/09 15:30
2-Chloroethylvinyl ether
ug/L
NO
10.0
01/19/09 15:30
Acrolein
ug/L
NO
100
01/19/0915,30
Acrylonitrile
ug/L
NO
100
01/19/0915:30
Benzene
ug/L
NO
5.0
01/19/0915:30
Bromodichloromethane
ug/L
NO
- 5.0
01/19/09 15:30
Bromoform
ug/L
NO
5.0
01/19/09 15:30
Bromomethane
ug/L
ND',
10.0
01/19/09 15:30
Carbon tetrachloride
ug/L
NO
5.0
01/19/09 15:30
Chlorobenzene
ug/L
NO
5.0
01119/0915:30
Chloroethane
ug/L
ND
10.0
01/19/09 15:30
Chloroform
ug/L
NO
5.0
01/19/09 15:30
Chloromethane
ug/L
NO
5.0
01/19/09 15:30
cis-1,3-Dichloropropene
ug/L
ND
5.0
01/19/09 15:30
Dibromochoromethane
ug/L
NO
5.0
01/19/09 15:30
Ethylbenzene
ug/L
NO
5.0
01/1910915:30
Hexachloro-1,3-buladiene
ug/L
NO
5.0
01/19/09 15:30
Methylene Chloride
ug/L
NO
5.0
01/19/09 15:30
Naphthalene
ug/L
NO
5.0
01/1910915:30
Tebachloroethene
ug/L
NO
5.0
01/19/09 15:30
Toluene
ug/L
NO
5.0
01119/0915:30
trans-1,2-Dichloroethene
ug/L
NO
5.0
01/1910915:30
trans-1,3-Dichloropropene
ug/L
NO
5.0
01/19/09 15:30
Trichloroethene
ug/L
NO
5.0
01/19/09 15:30
Trichlorofluoromelhans
ug/L
NO
10.0
01/19/09 15:30
Vinyl chloride
ug/L
NO
5.0
01/19/09 15:30
1,2-Dichloroethane-d4 (S)
%
99
70-130
01/19/09 15:30
4-Bromofluorobenzene (S)
%
103
86-111
01/19/09 15:30
Dibromofluoromethane (S)
%
98
88-113
01/19/09 15:30
Toluene-d8 (S)
%
97
92-105
01/19/09 15:30
Qualifiers
Date: 01/27/2009 03:37 PM REPORT OF LABORATORY ANALYSIS Page 20 of 26
This report shall not be reproduced, except in full,
without the written consent
of Pace Analytical Services, Inc..
i�4vAMf �e.

Pace Analytical Services, Inc.
aceAnalytical a 2225 Riverside Asheville, NC 2880404
www.{acxlebs. com
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite too
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: PPA
Pace Project No.: 9235982
LABORATORY CONTROL SAMPLE:
Parameter
224750
Units
Spike
Conc.
LCS
Result
LCS
% Rao
% Rec
Limits
1,1,1-Trichloroethane
ug/L
20
19.8
99
52-162
1,1,2,2-Tetrachloroethane
ug/L
20
16.4
82
46-157
1,1,2-Trichloroethane
ug/L
20
20.4
102
52-150
1,1-Dichloroethane
ug/L
20
20.5
103
59-155
1,1-Dichloroethene
ug/L
20
19.3
96
1-234
1,2,4-Trichlorobenzene
ug/L
20
19.5
97
70-130
1,2-Dichlorobenzene
ug/L
20
19.6
98
18-190
1,2-Dichloroethane
ug/L
20
20.1
100
49-155
1,2-Dichloropropane
ug/L
20
18.9
95
1-210
1,3-Dichlorobenzene
ug/L
20
19.6
98
59-156
1,4-Dichlorobenzene
ug/L
20
19.8
99
18-190
2-Chloroethylvinyl ether
ug/L
40
35.2
88
1-305
Acrolein
ug/L
100
ND
65
15-152
Acrylonitrile
ug/L
100
102
102
75-132
Benzene
ug/L
20
20.4
102
37-151
Bromodichloromethane
ug/L
20
20.1
101
35-155
Bromoform
ug/L
20
21.3
107
45-169
Bromomethane
ug/L
20
22.5
112
1-242
Carbon tetrachloride
ug/L
20
20.1
101
70-140
Chlorobenzene
ug/L
20
21.0
105
37-160
Chloroethane
ug/L
20
19.7
98
14-230
Chloroform
ug/L
20
19.8
99
51-138
Chloromethane
ug/L
20
15.0
75
1-273
cis-1,3-Dichloropropene
ug/L
20
17.6
88
1-227
Dibromochloromethane
ug/L
20
20.8
104
53-149
Ethylbenzene
ug/L
20
20.7
104
37-162
Hexachloro-1,3-butadiene
ug/L
20
17.4
87
70-130
Methylene Chloride
ug/L
20
16.8
84
1-221
Naphthalene
ug/L
20
10.2
101
70-130
Tetrachloroethene
ug/L
20
21A
105
64-148
Toluene
ug/L
20
45
97
47-150
trans-1,2-Dichloroethane
ug/L
20
18.6
93
54-156
trans-1,3-Dichloropropene
ug/L
20
18.3
92
17-183
Trichloroethane
ug/L
20
23.1
115
71-157
Trichlomfluoromethane
ug/L
20
21.2
106
17-181
Vinyl chloride
ug/L
20
18.8
94
1-251
1,2-Dichloroethane-d4 (S)
%
103
70-130
4-Bromofluorobenzene (S)
%
107
86-111
Dibromofluoromethane (S)
%
97
88-113
Toluene-d8 (S)
%
97
92-105
Qualifiers
Oate: 01/27/2009 03:37 PM REPORT OF LABORATORY ANALYSIS Page 21 of 26
This report shall not be reproduced. except in full.
without the written consent of Pace Analytical Services. Inc..

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
• 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
117;ace Analytical Asheville, NC 28804 Huntersville, NC 28078
�,, oer„•e, �m
[phone] [phone]
Project: PPA
Pace Project No.: 9235982
QC Balch: WETA/4272
OC Batch Method: EPA 420.4
Associated Lab Samples: 9235982001
METHOD BLANK: 224839
Associated Lab Samples: 9235982001
Parameter Units
mg/L
Phenol
QUALITY CONTROL DATA
Analysis Method: EPA 420.4
Analysis Description: 420.4 Phenolics
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.010 01/19/0915:33
LABORATORY CONTROL SAMPLE:
224840
Spike LCS
LCS
% Rec
Parameter
Units
Conc. Result
%Rec
Limits
Qualifiers
Phenol
mg/L
.25 0.25
98
90-110
MATRIX SPIKE SAMPLE:
224841
9235821002 Spike
MS
MS
% Rec
Parameter
Units
Result Conc.
Result
%Rec
Limits Qualifiers
Phenol
mg/L
0.016 .25
0,057
17
90-110 J
MATRIX SPIKE SAMPLE:
224846
9236070001
Spike
MS
MS
% Rao
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
Phenol
mg/L
ND
.25
0,030
12
90-110 J
SAMPLE DUPLICATE: 224845
9235821003
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Phenol
mg/L
0.29
0.090
104 J
SAMPLE DUPLICATE: 224847
9236173002
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Phenol
mg/L
NO
NO
Date: 01/27/2009 03:37 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 22 of 26

PaceAnaVical
."e bs.c
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite too
Huntersville, NC 28078
[phone]
Project: PPA
Pace Project No.: 9235982
QUALITY CONTROL DATA
QC Batch: WETA/4289 Analysis Method: SM 4500-CN-E
QC Balch Method: SM 4500-CN-E Analysis Description: 450OCNE Cyanide, Total
Associated Lab Samples: 9235982001
METHOD BLANK: 226205
Associated Lab Samples: 9235982001
Parameter Units
mg/L
Cyanide
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.0050 01/2210920:36
LABORATORY CONTROL SAMPLE:
226206
Spike LCS
LCS
%Rec
Parameter
Units
Conc. Result
%Rec
Limits
Qualifiers
Cyanide
mg/L
.1 0.095
95
80-120
MATRIX SPIKE SAMPLE:
226207
9235855001 Spike
MS
MS
% Rec
Parameter
Units
Result Conc.
Result
%Rec
Limits Qualifiers
Cyanide
mg/L
NO A
0.084
81
75-125
MATRIX SPIKE SAMPLE:
226210
9235952001 'Spike
MS
Ms
% Rao
Parameter
Units
Result Conc.
Result
%Rec
Limits Qualifiers
Cyanide
mg/L
ND .1
0.11
102
75-125
SAMPLE DUPLICATE: 226209
9236309005 Dup
Parameter Units Result Result RPD Qualifiers
Cyanide mg/L 0.028 0.025 12
SAMPLE DUPLICATE: 226211
9235971001 Dup
Parameter Units Result Result RPD Qualifiers
Cyanide mg/L 0.030 0.029 5
Date: 01/27/2009 03:37 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace
+Analytical Services, Inc..
Page 23 of 26

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
' 2225 Riverside Dr. 9800 Kincey Ave. Suite 10o
aceAnalytical Asheville, NC 28804 Huntersville, NC 28078
www.pece/ebscdn
[phone] [phone]
QUALITY CONTROL DATA
Project: PPA
Pace Project No.: 9235982
QC Batch: WETA/4293 Analysis Method: EPA 351.2
OC Batch Method: EPA 351.2 Analysis Description: 351.2 TKN
Associated Lab Samples: 9235982001
METHOD BLANK: 226465 Matrix: Water
Associated Lab Samples: 9235982001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Qualifiers
Nitrogen, Kjeldahl, Total
mg/L
NO 0.50
01/26/09 19:36
LABORATORY CONTROL SAMPLE:
226466
Spike
LCS
LCS
% Rao
Parameter
Units
Conc.
Result
%Rec
Limits Qualifiers
Nitrogen, Kjeldahl, Total
ril
5
5.2
105
90-110
MATRIX SPIKE SAMPLE:
226467
9236189012 Spike
MS
MS % Rao
Parameter
Units
Result
Conc.
Result
%Rec Limits Qualifiers
Nitrogen, Kjeldahl, Total
ril
1.9 5
6.3
87 90-110 J
MATRIX SPIKE SAMPLE: 226472
9235974001 Spike MS MS % Roo
Parameter Units Result Conc. Result % Roo Limits Qualifiers
Nitrogen, Kjeldahl, Total mg/L 1.9 5 7.4 109 90-110
SAMPLE DUPLICATE: 226471 t
9236189013 bup
Parameter Units Result Result RPD Qualifiers
Nitrogen, Kjeldahl, Total mg/L 1.5 1.6 5
DUPLICATE: 226473
Parameter
Nitrogen, Kjeldahl, Total
Date: 01/27/2009 03:37 PM
9235976001 Dup
Units Result Result
ri 9.4 8.6
RPD Qualifiers
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wntten consent of Pace
Analytcal Services, Inc..
8
Page 24 of 26

Pace Analytical Services, Inc. Pace Analytical Servicef, Inc.
e 2225 Riverside Dr. 9800 Kincey Ave. Suite 10o
aceAnalytical _
- Asheville. NC 28804 Huntersville, NC 28078
[phone] [phone]
QUALITY CONTROL DATA
Project: PPA
Pace Project No.: 9235982
QC Batch: WETA/4297 Analysis Method: EPA 365.1
QC Batch Method: EPA 365.1 Analysis Description: 365.1 Phosphorus, Total
Associated Lab Samples: 9235982001
METHOD BLANK: 226516 Matrix: Water
Associated Lab Samples: 9235982001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phosphorus mg/L ND 0.10 01/24/0910:59
LABORATORY CONTROL SAMPLE: 226517
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Phosphorus mg/L 1 0.91 91 90-110
MATRIX SPIKE SAMPLE: 226518
9235983003 Spike MS MS % Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Phosphorus mg/L 208 100 209 1 90-110 J
MATRIX SPIKE SAMPLE: 226520
9235974001 Spike MS MS % Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Phosphorus mg/L 3.2 1 4.0 78 90-110 J
SAMPLE DUPLICATE: 226519
9236186006 Dup
Parameter Units Result Result RPD Qualifiers
Phosphorus mg/L 3.1 2.0 45 J
SAMPLE DUPLICATE: 226521
9235978001 Cup
Parameter Units Result Result RPD Qualifiers
Phosphorus mg/L 1.6 1.6 3
Date: 01/27/2009 03:37 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 25 of 26

17 aceAnalytical
/ w»w.peceleEs mm
i
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
project: PPA
'ace Project No.: 9235982
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
NO - Not Detected at or above adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes.
U - Indicates the compound was analyzed for, but not detected.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
PAST-G Pace Analytical Services Green Bay
NALYTE QUALIFIERS
1 g Sample appears to have been received In a Non Pace-G8 LLHg Container.
I The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit.
J Estimated value.
Date: 01/27/2009 03:37 PM REPORT OF LABORATORY ANALYSIS Page 26 of 26
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services. Inc..
1 Rr1CLl.'�.

S.eeAlfv- s-C6,,,%dD\ , eeeiWyee.eoG RELluast L.,....me,IL
PaeeAnalytieal The Cnainof-Custody is a LEGAL DOCUMENT. A l relevant fields must be completed accurately.
ee....a.MN.me
Secton A Section B Section C
Pap: at
Required Ci ant Information: Required Pro�jejct,Information: Invoice information:
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Pace Analytical Services, Inc. Pace Analytical Services, Inc.
e 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
aceAn0l .bs al Asheville, NC 28804 Huntersville, NC 28078
wwwpeceleGtmvn
[phone] [phone]
October 30, 2008
Mr. Hubert Whitehead
Town of Tarboro
506 Dowd Street
PO Box 220
Tarboro, NC 27886
RE: Project: WASTEWATER EFF
Pace Project No.: 9230081
Dear Mr. Whitehead:
Enclosed are the analytical results for sample(s) received by the laboratory on October 15, 2008.
The results relate only to the samples included in this report. Results reported herein conform to the
most current NELAC standards, where applicable, unless otherwise narrated in the body of the
report.
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All
Microbiological analyses were performed at the laboratory where the samples were received.
If you have any questions concerning this report, please feel free to contact me.
7Sin r ly,
m uto
[e-mail]
Project Manager
Enclosures
M
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
5/:c
Page i of 21

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
I�Falce Analytical 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
www penlebs rom
Asheville. NC 28804 Huntersville. NC 28078
[phone] [phone]
Project: WASTEWATER EFF
Pace Project No.: 9230081
Green Bay Certification IDe
Louisiana Certification M 04169
Louisiana Certification M 04168
Kentucky Certification M 83
Kentucky Certification #: 82
Wisconsin DATCP Certification #: 105-444
Wisconsin DATCP Certification #: 105-444
Wisconsin Certification #: 405132750
Wisconsin Certification #: 405132750
South Carolina Certification #: 83006001
South Carolina Certification M 83006001
Minnesota Certification #: 055-999-334
Charlotte Certification We
Connecticut Certification Number: PH-0104
Pennsylvania Certification Number: 68-00784
West Virginia Certification Number: 357
Virginia Certification Number. 00213
Tennessee Certification Number: 04010
South Carolina Drinking Water Cert. Number: 990060003
South Carolina Certification Number: 990060001
Asheville Certification We
Connecticut Certification Number: PH-0106
Massachusetts Certification Number: M-NC030
West Virginia Certification Number: 356
Virginia Certification Number: 00072
Tennessee Certification Number: 2980
South Carolina Bioassay Certification Number: 99030002
South Carolina Certification Number: 99030001
Eden Certification We
Virginia Drinking Water Certification Number: 00424
North Carolina Wastewater Certification Number: 633
CERTIFICATIONS
Minnesota Certification #: 055-999-334
North Carolina Certification #: 503
North Carolina Certification M 503
North Dakota Certification Of: R-200
North Dakota Certification #: R-150
New York Certification #: 11888
New York Certification M 11887
Illinois Certification #: 200051
Illinois Certification #: 200050
Florida (NELAP) Certification M E87951
Florida (NELAP) Certification #: E87948
North Carolina Field Services Certification Number: 5342
North Carolina Wastewater Certification Number: 12
North Carolina Drinking Water Certification Number: 37706
Louisianall-ELAP Certification Number: 04034
Kentucky UST Certification Number: 84
New Jersey Certification Number: NC012
Florida/NELAP Certification Number: E87627
Pennsylvania Certification Number: 68-03578
North Carolina Bioassay Certification Number: 9
North Carolina Wastewater Certification Number: 40
North Carolina Drinking Water Certification Number: 37712
New Jersey Certification Number: NC011
Louisiana/LELAP Certification Number: 03095
Florida/NELAP Certification Number. E87648
North Carolina Drinking Water Certification Number: 37738
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 21

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
2225 Riverside Dr. 9800 Kincey Ave. Suite too
aceAnalytical Asheville, NC 28804 Huntersville, NC 28078
WNW FaCMlb9. ttYr1
[phone] [phone]
SAMPLE ANALYTE COUNT
Project: WASTEWATER EFF
Pace Project No.: 9230081
Lab ID
Sample ID
Method
Analysts
Analysts
Reported
Laboratory
9230081001
WASTEWATER EFF.
EPA 1631E
GMW
1
PASI-G
EPA 1664A
DNP
i
PASI-C
EPA 351.2
SHB
1
PASI-A
EPA 365.1
ADN
1
PASI-A
EPA 420.4
JDA
1
PASI-A
EPA 624
MCK
40
PASI-C
EPA 625
BET
60
PASI-C
SM 2540C
TEE
1
PASI-A
SM 4500-CN-E
ADN
1
PASI-A
9230081002
WASTEWATER BLANK
EPA 1631E
GMW
1
PASI-G
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent
of Pace Analytical Services, Inc..
s ll_1G14C 9
Page 3 of 21

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
ace /-1 pnal��Ca�a 2225 Riverside 9800 Kincey Ave. Suite 100
Asheville, NC 2880404 Huntersville, NC 28078
www pacdebs mm
(828)2547176 [phone]
ANALYTICAL RESULTS
Project: WASTEWATER EFF
Pace Project No.: 9230081
Sample: WASTEWATER EFF. Lab ID: 9230081001 Collected: 10/15/08 08:00 Received: 10/15/08 15:25 Matrix: Water
Parameters
Results Units
Report Limit
DF
Prepared
Analyzed
CAS No. Oual
1631E Mercury, Low Level
Analytical Method: EPA 1631E
Mercury
1.94 ng/L
0.50
1
10/21/0807:30
10/22/0812:41
7439-97-6
HEM, Oil and Grease
Analytical Method: EPA 1664A
Oil and Grease
NO mg/L
5.0
1
1012310810:34
625 MSSV
Analytical Method: EPA 625 Preparation Method: EPA 625
Acenaphthene
NO ug/L
5.6
1
10/22/08 00:00
10/24/08 21:25
83-32-9
Acenaphthylene
NO ug/L
6.6
1
10/22/08 00:00
10/24/08 21:25
208-96-8
Anthracene
NO ug/L
5.6
1
10/22/08 00:00
10/24/08 21:25
120.12-7
Benzo(a)anthracene
NO ug/L
5.6
1
10/22/08 00:00
10/24/08 21:25
56-55-3
Benzo(a)pyrene
NO ug/L
5.6
1
10/2210800:00
10/24/08 21:25
50-32-8
Benzo(b)fluoranthene
NO ug/L
5.6
1
10/22/08 00:00
10124/0821:25
205-99-2
Benzo(g,h,i)perylene
NO ug/L
5.6
1
10/2210800:00
10/2410821:25
191-24-2
Benzo(k)fluoranlhene
NO ug/L
5.6
1
10/22/08 00:00
10/24/08 21:25
207-08-9
4-Bromophenylphenyl ether
NO ug/L
5.6
1
10/22/08 00:00
10/24/08 21:25
101-55-3
Butyibenzylphlhalate
NO ug/L
5.6
1
10/22/08 00:00
10/24/08 21:25
85-68-7
4-Chloro-3-methylphenol
NO ug/L
5.6
1
10/22/08 00:00
10/24/08 21:25
59-50-7
bis(2-Chloroethoxy)methane
NO ug/L
11.1
1
10/2210800:00
1012410821:25
111-91-1
bis(2-Chloroelhyl) ether
ND ug/L
5.6
1
10/22108 00:00
10/24/08 21:25
111-44 4
bis(2-Chloroisopropyl) ether
NO ug/L
5.6
1
10/22/08 00:00
10/24/08 21:25
108.60-1
2-Chloronaphthalene
NO ug/L
5.6
1
10/22/08 00:00
10/24/08 21:25
91-58.7
2-Chlorophenol
NO ug/L
5.6
1
10/2210800:00
10/24/08 21:25
95-57-8
4-Chlorophenylphenyl ether
NO ug/L
5.6
1
10/22/08 00:00
10/24/08 21:25
7005-72-3
Chrysene
NO ug/L
5.6
1
10/22/08 00:00
10/24/08 21:25
218-01-9
Dibenz(a,h)anthracene
NO ug/L
5.6
1
10/22/0800:00
10/24/08 21:25
53.70-3
1,2-Dichlorobenzene
NO ug/L
5.6
1
10/22J0800:00
10/2410821:25
95-50-1
1,3-Dichlorobenzene
ND ug/L
5.6
1
1012210800:00
10/24/08 21:25
541-73-1
1,4-Dichlorobenzene
NO ug/L
5.6
1
10/22/08 00:00
10/24/08 21:25
106-46-7
3,3' Dichlorobenzidine
NO ug/L
5.6
1
10/22/08 00:00
10/24/08 21:25
91-94-1
2,4-Dichlorophenol
NO ug/L
5.6
1
10122/0800:00
10/2410821:25
120-83-2
Diethylphthalate
NO ug/L
5.6
1
10/22/08 00:00
10/24/08 21:25
84-66-2
2,4-Dimethylphenol
NO ug/L
11.1
1
10/22/08 00:00
10/24/08 21:25
105-67-9
Dimethylphthalate
NO ug/L
5.6
1
10/22/08 00:00
10/24/08 21:25
131-11J
Di-n-butylphthalate
NO ug/L
5.6
1
10/2210800:00
10/24/08 21:25
84-74-2
4,6-Dinitro-2-melhylphenol
NO ug/L
22.2
1
10/22/08 00:00
10/24/08 21:25
534-52-1
2,4-Dinitrophenol
NO ug/L
55.6
1
10/22/08 00:00
10/24/08 21:25
51-28-5
2,4-Dinitrotoluene
NO ug/L
5.6
1
10/22/0800:00
10/2410821:25
121-14-2
2,6-Dinitrotoluene
NO ug/L
5.6
1
10/22/08 00:00
10/24/08 21:25
606-20-2
Di-n-octylphthalate
ND ug/L
5.6
1
10/22/08 00:00
10/24/08 21:25
117-84-0
1,2-Diphenylhydrazine
NO ug/L
5.6
1
10/22/08 00:00
10/24/08 21:25
1224%-7
bis(2-Ethylhexyl)phthalate
NO ug/L
5.6
1
10/22/08 00:00
10/24/08 21:25
117-81-7
Fluoranthene
NO ug/L
5.6
1
10/22/'08 00:00
10/24/08 21:25
20644-0
Fluorene
NO ug/L
5.6
1
10/2210800:00
10/24/08 21:25
86-73-7
Hexachlorobenzene
ND ug/L
5.6
1
10/2210800:00
10/2410821:25
118-74-1
Hexachlorocyclopentadiene
NO ug/L
11.1
1
10/22/08 00:00
10/24/08 21:25
77474
Hexachloroethane
NO ug/L
5.6
1
10/22/08 00:00
10/24/08 21:25
67-72-1
Date: 10/30/2008 03:22 PM
REPORT OF LABORATORY
ANALYSIS
Page 4 of 21
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
11�0s 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
»ww.aMWaam
aceAn csw& al Asheville, NC 28804 Huntersville, NC 28078
[phone] (704A75-9092
ANALYTICAL RESULTS
Project: WASTEWATER EFF
Pace Project No.: 9230081
Sample: WASTEWATER EFF. Lab ID: 9230081001 Collected: 10/15/08 08:00 Received: 10/15/08 15:25 Matrix: Water
Parameters
Results Units
Report Limit
DF
Prepared
Analyzed
CAS No. Qual
625 MSSV
Analytical Method: EPA 625 Preparation Method: EPA 625
Indeno(1,2,3cd)pyrene
NO ug/L
5.6
1
10/2210800:00
10/24/0621:25
193-39-5
Isophorone
NO ug/L
11.1
1
10/22/0600:00
10/24/08 21:25
78-59.1
Naphthalene
NO ug/L
5.8
1
10/2210800:00
10/2410621:25
91-20-3
Nitrobenzene
ND ug/L
5.6
1
10/22/08 00:00
10/2410821:25
98.95-3
2-Nitrophenol
NO ug/L
5.6
1
1012210800:00
10/24/08 21:25
88-75.5
4-Nitrophenol
ND ug/L
55.6
1
10/22/08 00:00
10/24/08 21:25
100-02.7
N-Nitrosodimethylamine
NO ug/L
5.6
1
10/22/08 00:00
10/24/08 21:25
62-75-9
N-Nitroso-di-propylamine
ND ug/L
5.6
1
10/2210800:00
10/24/08 21:25
621.64-7
N-Nitrosodiphenylamine
ND ug/L
11.1
1
10/22/08 00:00
10/24/08 21:25
86-30-6
Pentachlorophenol
ND ug/L
27.8
1
10/2210800:00
10/24/08 21:25
87-86.5
Phenanthrene
NO ug/L
5.6
1
10/2210800:00
10/24/08 21:25
85-01-8
Phenol
NO ug/L
5.6
1
10/22/08 00:00
10/24/08 21:25
108-95-2
Pyrene
NO ug/L
5.6
1
10/22/08 00:00
10/24/08 21:25
129-00-0
2,4,6-Trichlorophenol
NO ug/L
11.1
1
10122/0800:00
10/2410821:25
88-06-2
Nitrobenzened5(S)
75 %
10-120
1
10/22/08 00:00
10/24/08 21:25
4165.60-0
2-Fluorobiphenyl (S)
76 %
15.120
1
10/22/08 00:00
10/24/08 21:25
321-60-8
Terpherlyld114(S)
111 %
11-131
1
10/22t0800:00
10/24/0821:25
1718-51-0
Phenold6 (S)
30 %
10-120
1
10/22/08 00:00
10/24/08 21:25
13127-88.3
2-Fluoropherlol (S)
45 %
10-120
1
10/22/08 00:00
10/24/08 21:25
367-12-4
2,4,6-Tribromophenol (S)
93 %
10.137
1
10/22/08 00:00
10/24/08 21:25
118.79-6
624 Volatile Organics
Analytical Method: EPA 624
Acrolein
ND ug/L
100
1
10/2910812:46
107-02-8
Acrylonitrile
ND ug/L
100
1
10/29/08 12:46
107-13.1
Benzene
ND ug/L
5.0
1
10/29/08 12:46
71-43.2
Bromodlchloromelhane
ND ug1L
5.0
1
10/2910812:46
75.27-4
Bromoform
NO ug/L
5.0
1
10129/0812:46
75-25-2
Bromomethane
NO ug/L
10.0
1
10/2910812:46
74-83-9
Carbon tetrachloride
NO ug/L
5.0
1
10/29/08 12:46
W23-5
Chlorobenzene
ND ug/L
5.0
1
10/29/08 12:46
108-90-7
Chloroethane
NO ug/L
10.0
1
10/29(0812:46
75-00-3
2-Chloroethylvinyl ether
ND ug/L
10.0
1
10/29/08 12:46
110.75-8
Chloroform
NO ug/L
5.0
1
10/29/0812:46
67-66-3
Chloromethane
ND ug/L
5.0
1
10/29/08 12:46
74-87-3
Dibromochloromethane
ND ug/L
5.0
1
10/29/08 12:46
12448-1
1,2-Dichlorobenzene
ND ug/L
5.0
1
10/29/0812:46
95.50-1
1,3-Dichlorobenzene
NO ug/L
5.0
1
10/29/08 12:46
541-73-1
1,4-Dichlorobenzene
ND ug/L
5.0
1
10/2910812:46
106-46.7
1,1-Dichloroethane
ND ug/L
5.0
1
10/2910812:46
75-34-3
1,2-0ichloroethane
NO ug/L
5.Q
1
10129/0812:46
107-06-2
1,1-Dichloroethene
NO ug/L
5:0
1
10/2910812:46
75-35-4
trans-1,2-Dichloroethene
NO ug/L
h.0
1
10/2910812:46
156-60-5
1,2-Dichloropropane
ND ug/L
r, 5.0
1
10/2910812:46
78-87-5
cis-1,3-Dichloropropene
ND ug/L
5.0
1
10/2910812:46
10061-01-5
trans-1,3-Dichloropropene
NO ug/L
'� 5.0
1
10/29/08 12:46
10061412-6
Elhylbenzene
NO ug/L
5.0
1
10/29/08 12:46
100-414
Hexachloro-1,3-butadiene
NO ug/L
5.0
1
10/29/08 12:46
87-68-3
Date: 10/30/2008 03:22 PM
REPORT OF LABORATORY
ANALYSIS
Page 5 of 21
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalytical 2225 Riverside 9800 ncey Ave. Suite
- Asheville, NC 28804 04 Huntersville, NC 28078078
xww.pa�eleDs.com
[phone] [phone]
ANALYTICAL RESULTS
Project: WASTEWATER EFF
Pace Project No.: 9230081
Sample: WASTEWATER EFF. Lab ID: 9230081001 Collected: 10/15/08 08:00 Received: 10/15/08 15:25 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
624 Volatile Organics
Methylene Chloride
Naphthalene
1,1,2, 2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroetha ne
1.1,2-Trichloroetha ne
Trichloroethene
Trichlorofluorometha ne
Vinyl chloride
Dibromofluoromethane (S)
4-Bromofluorobenzene (S)
Toluene-08 (S)
1,2-Dichloroethane-d4 (S)
2540C Total Dissolved Solids
Total Dissolved Solids
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total
365.1 Phosphorus, Total
Phosphorus
420.4 Phenolics, Total
Phenol
450OCNE Cyanide, Total
Cyanide
Analytical Method: EPA 624
NO ug/L
5.0
1
10/29/08 12:46
75-09-2
ND ug/L
5.0
1
10/29/08 12:46
91-20-3
NO ug/L
5.0
1
10/29/08 12:46
79-34-5
NO ug/L
5.0
1
10/29/08 12:46
127-18-4
NO ug/L
5.0
1
10/29/08 12:46
108-88-3
ND ug/L
5.0
1
10/29/08 12:46
120-82-1
NO ug/L
5.0
1
10/2910812:46
71-55-6
NO ug/L
5.0
1
10/29/08 12:46
79-00-5
NO ug/L
5.0
1
10/2910812:46
79-01-6
NO ug/L
10.0
1
10129/0812:46
75-69-4
NO ug/L
5.0
1
10/29/08 12:46
75-01-4
89 %
88-113
1
10/29/08 12:46
1868-53-7
96 %
86-111
1
10/29/08 12:46
460-00-4
103 %
92-105
1
10/29/08 12:46
2037-26-5
94 %
70-130
1
10/29/08 12:46
17060-07-0
Analytical Method: SM 2540C
520 mg/L
20.0
1
10/21/08 15:32
Analytical Method: EPA 351.2
1.5 mg/L
0.50
1
10/28/08 11:25
7727-37-9
Analytical Method: EPA 365.1
1.6 mg/L
0.10
1
10/29/08 10:55
7723-14-0
Analytical Method: EPA 420.4
NO mg/L
0.010
1
10/24/0812:36
108-95-2
Analytical Method: SM 4500-CN-E
NO mg/L
0.0050
1
10/23/0811:29
57-12-5
Sample: WASTEWATER BLANK Lab ID: 9230081002 Collected: 10/16/08 00:00 Received: 10/15/08 15:25 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1631E Mercury, Low Level Analytical Method: EPA 1631E
Mercury 0.1173J ng/L 0.50 1 10121/0807:30 10/2210812:36 7439-97-6
gate: 10/30/2008 03:22 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
'i�elaC`
Page 6 of 21

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
a 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
aceAnalytical Asheville, NC 28804 Huntersville, NC 28078
www pecele6scwn
[phone] [phone]
QUALITY CONTROL DATA
Project: WASTEWATER EFF
Pace Project No.: 9230081
QC Batch: CVFS/1284 Analysis Method: EPA 1631E
QC Batch Method: EPA 1631E Analysis Description: 1631E Mercury
Associated Lab Samples: 9230081001, 9230081002
METHOD BLANK: 92543 Matrix: Water
Associated Lab Samples: 9230081001, 9230081002
Parameter Units
Mercury ng/L
METHOD BLANK: 92544
Associated Lab Samples: 9230081001, 9230081002
Parameter Units
Mercury ng/L
Blank Reporting
Result Limil Analyzed Qualifiers
ND 0.50 10/22/08 09:55
I•.
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
NO 0.50 10/22/0810.00
Mt I MUu BLANK: U2545 Matrix: Water
Associated Lab Samples: 9230081001.9230081002
Parameter Units
Mercury ng/L
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.50 10/22/0810:24
LABORATORY CONTROL SAMPLE &LCSD: 92546 92547
Spike LCS LCSD LCS LCSD % Rec Max
Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers
Mercury ng/L 5 5.04 5.40 101 108 79-121 7 24
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 92548
92549
MS
MSD
1,
4010386001
Spike
Spike
MS MSD MS MSD % Rec
Parameter Units Result
Conc.
Conc.
Result Result % Rec % Rec Limits RPD Qual
Mercury ng/L 9.38
40
40
48.2 42.3 97 82 75-125 13
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 92550
92551
MS
MSD
4010391003
Spike
Spike
MS MSD MS MSD %Rec
Parameter Units Result
Conc.
Conc.
Result Result % Red % Rec Limits RPD Qual
Mercury ng/L 95.5
450
450
550 514 101 93 75-125 7
Date: 10/30/2008 03:22 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent
of Paw Analytical Services, Inc..
Page 7 of 21

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
' 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
aceAnalyt/cal Asheville, NC 28804 Hunlersville, NC 28078
wwwpecNaEsmm
[phone] [phone]
QUALITY CONTROL DATA
Project: WASTEWATER EFF
Pace Project No.: 9230081
QC Batch: OEXT/4744 Analysis Method: EPA 625
OC Batch Method: EPA 625 Analysis Description: 625 MSS
Associated Lab Samples: 9230081001
METHOD BLANK: 184720 Matrix: Water
Associated Lab Samples: 9230081001
Blank Reporting
Parameter
Units Result Limit
Analyzed
1,2-Dichlorobenzene
ug/L
NO
5.0
10/24/08 12:05
1,2-Diphenylhydrazine
ug/L
NO
5.0
10/24/08 12:05
1,3-Dichlorobenzene
ug/L
NO
5.0
10/24/08 12:05
1,4-Dichlorobenzene
ug/L
NO
5.0
10/2410812:05
2,4,6-Trichlorophenol
ug/L
NO
10.0
10/24/08 12:05
2,4-Dichlorophenol
ug/L
NO
5.0
10/24/08 12:05
2,4-Dimethytphenol
ug/L
NO
10.0
10/2410812:05
2,4-Dinitrophenol
ug/L
NO
50.0
10/2410812:05
2,4-Dinitrotoluene
ug/L
NO
5.0
10124/0812:05
2,6-Dinitrotoluene
ug/L
NO
5.0
10/2410812:05
2-Chloronaphthalene
ug/L
NO
5.0
10/24/08 12:05
2-Chlorophenol
ug/L
NO
` 1.5.0
10/24/08 12:05
2-Nitrophenol
ug/L
NO
5.0
10/24/08 12:05
3,3'-Dichlorobenzidine
ug/L
NO
5.0
10/24/08 12:05
4,6-Dinitro-2-methylphenol
ug/L
NO
20.0
10/2410812:05
4-Bromophenylphenyl ether
ug/L
NO
5.0
10/24/08 12:05
4-Chloro-3-methylphenol
ug/L
NO
5.0
10/2410812:05
4-Chlorophenylphenyt ether
ug/L
NO
5.0
10/24/08 12:05
4-Nitrophenol
ug/L
NO
50.0
10/24/08 12:05
Acenaphthene
ug/L
NO
5.0
10/24/0812:05
Acenaphthylene
ug/L
NO
5.0
1012410812:05
Anthracene
ug/L
NO
5.0
10/24/08 12:05
Benzo(a)anthracene
ug/L
NO
5.0
10/2410812:05
Benzo(a)pyrene
ug/L
NO
5.0
10/2410812:05
Benzo(b)fluoranthene
ug/L
NO
5.0
10/2410812:05
Benzo(g,h,i)perylene
ug/L
NO
5.0
10/24/0812:05
Benzo(k)fluoranthene
ug/L
NO
5.0
10/24/08 12:05
bis(2-Chloroethoxy)methane
ug/L
NO
10.0
10/2410812:05
bis(2-Chloroethyl) ether
ug/L
NO
5.0
10/24/08 12:05
bis(2-Chloroisopropyl) ether
ug/L
NO
5.0
10/24/08 12:05
bis(2-Ethylhexyl)phthalate
ug/L
NO
5.0
10/24/08 12:05
Bulylbenzylphthalate
ug/L
NO
5.0
10/24/08 12:05
Chrysene
ug/L
ND
5.0
10/24/08 12:05
Di-n-butyiphthalale
ug/L
NO
5.0
10/24/08 12:05
DI-noctylphthalate
ug/L
NO
5.0
10/24/08 12:05
Dibenz(a,h)anthracene
ug/L
NO
5.0
10/24/08 12:05
Diethylphthalate
ug/L
NO
5.0
10/24/0812:05
Dimethylphthalate
ug/L
NO
5.0
10/24/08 12:05
Fluoranthene
ug/L
NO
5.0
10/2410812:05
Fiuorene
ug/L
NO
5.0
10/24/08 12:05
Hexachlorobenzene
ug/L
NO
5.0
10/24/08 12:05
Hexachlorocyclopentadiene
ug/L
NO
10.0
10/24/08 12:05
Hexachloroethane
ug/L
NO
5.0
10/2410812:05
Date: 10/30/2008 03:22 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of PaceAnalytical Services, Inc..
Qualifiers
Page 8 of 21

Pace Analytical Services, Inc. Pace Analytical Services, Ine.
/711`s
aceAnalytical 2225 Riverside 9800 Kinsey Ave. Suite 100
- Asheville, NC 2880404 Hunlersville, NC 28078
www pecNaOi. cvm
[phone] [phone]
QUALITY CONTROL DATA
Project: WASTEWATER EFF
Pace Project No.: 9230081
METHOD BLANK: 184720
Matrix:
Water
Associated Lab Samples: 9230081001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Indeno(1,2,3-cd)pyrene
ug/L
ND
5.0
10/24/08 12:05
Isophorone
ug/L
NO
10.0
10/24/08 12:05
N-Nitroso-di-n-propylamine
ug/L
ND
5.0
10/2410812:05
N-Nitrosodimethylamine
ug/L
ND
5.0
1012410812:05
N-Nitrosodiphenylamine
ug/L
ND
10.0
10/24/08 12:05
Naphthalene
ug/L
NO
5.0
10/24/08 12:05
Nitrobenzene
ug/L
NO
5.0
10/2410812:05
Pentachlorophenol
ug/L
ND
25.0
10/2410812:05
Phenanthrene
ug/L
NO
5.0
10/2410812:05
Phenol
ug/L
ND
5.0
10/24/08 12:05
Pyrene
ug/L
ND
5.0
10/24/08 12:05
2,4,6-Tribromophenol (S)
%
85
10-137
10/24/08 12:05
2-Fluorobiphenyl (S)
%
72
15-120
10/24/08 12:05
2-Fluorophenol (S)
%
42
10-120
10/24/08 12:05
Nitrobenzene-d5 (S)
%
80
10-120
10/2410812:05
Phenol-c!6 (S)
%
28
10-120
10124/0812:05
Terphenyl-d14 (S)
%
86
11-131
10/24/08 12:05
LABORATORY CONTROL SAMPLE: 184721
Qualifiers
Spike
LCS
LCS
%Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,2-Dichlorobenzene
ug/L
50
28.4
57
32-129
1,2-Diphenylhydrazine
ug/L
50
32.2
64
25-160
1,3-Dichlorobenzene
ug/L
50
28.0
56
1-172
1,4-Dichlorobenzene
ug/L
50
26.6
53
20-124
2,4,6-Trichlorophenol
ug/L
50
24.1
48
37-144
2,4-Dichlorophenol
uglL
50
29.2
58
1-191
2,4-Dimethylphenol
ug/L
50
32.1
64
32-119
2,4-Dinitrophenol
ug/L
50
NO
16
1-181
2,4-Dinitrotoluene
ug/L
50
24.9
50
39-139
2.6-Dinitrotoluene
ug/L
50
25.8
52
50-158
2-Chloronaphthalene
ug/L
50
35.6
71
60-118
2-Chlorophenol
ug/L
50
19.7
39
23-134
2-Nitrophenol
ug/L
50
21.0
42
29-182
3,3'-Dichlorobenzidine
ug/L
50
39.3
79
1-262
4,6-Dinitro-2-methylphenol
ug/L
50
15.6.1
31
1-181
4-Bromophenylphenyl ether
ug/L
50
29.7
59
53-127
4-Chloro-3-methylphenol
ug/L
50
34.5
69
22-147
4-Chlorophenylphenyl ether
ug/L
50
30.7
61
25-158
4-Nitrophenol
ug/L
50
8.2J
16
1-132
Acenaphthene
ug/L
50
26.0
52
47-145
Acenaphthylene
ug/L
50
27.0
54
33-M
Anthracene
ug/L
50
32.0
64
1-166
Benzo(a)anthracene
ug/L
50
30.2
60
33-143
Benzo(a)pyrene
ug/L
50
26.8
54
17-163
Date: 10/30/2008 03:22 PM REPORT OF LABORATORY ANALYSIS Page 9 of 21
This report shall not be reproduced, except in full,
without the written consent offPPace
.Analytical Services, Inc..

Pace Analytical Services, Inc. Pace Ana"cal Services, Inc.
lace Analytical 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
.vww pacNne: mm
Asheville. NC 28804 Huntersville, NC 28078
[phone] [phone]
QUALITY CONTROL DATA
Project: WASTEWATER EFF
Pace Project No.: 9230081
LABORATORY CONTROL SAMPLE: 184721
Parameter
Units
Spike
Conc.
LCS
Result
LCS
%Rao
% Rec
Limits qualifiers
Benzo(b)fluoranthene
ug/L
50
23.2
46
24-159
Benzo(g,hJ)perylene
ug/L
50
24.9
50
1.219
Benzo(k)fluoranthene
ug/L
50
30.6
61
11-162
bis(2-Chloroethoxy)methane
ug/L
50
29.1
58
33-184
bis(2-Chloroethyl) ether
ug/L
50
18.9
38
12-158
bis(2-Chloroisopropyp ether
ug/L
50
56.0
112
36-166
bis(2-Ethyihexyl)phthalate
ug/L
50
37.7
75
8-158
Bulylbenzyfphthalate
ug/L
50
33.7
67
1-152
Chrysene
ug/L
50
31.0
62
17-168
Di-n-butylphthalate
ug/L
50
33.3
67
1-118
Di-n-octylphthalate
ug/L
50
35.5
71
4-146
Dibenz(a,h)anthracene
ug/L
50
26.1
52
1-227
Diethylphthalale
ug/L
50
30.5
61
1-114
Dimethylphthalate
ug/L
50
29.6
59
1-112
Fluoranthene
ug/L
50
29.6
59
26-137
Fluorene
ug/L
50
30.7
61
59-121
Hexachlorobenzene
ug/L
50
25.7
51
1-152
Hexachlorocyclopentadiene
ug/L
50
15.6
31
25-150
Hexachloroethane
ug/L
50
27.1
54
40-113
I ndeno(1,2,3-cd)pyrene
ug/L
50
25.8
51
1-171
Isophorone
ug/L
50
51.8
104
21-196
N-Nitrosodi-n-propylamine
ug/L
50
49.2
98
1-230
N-Nitrosodimelhylamine
ug/L
50
16.6
33
25-150
N-Nitrosodiphenylamine
ug/L
50
31.0
62
25-150
Naphthalene
ug/L
50
21.8
44
21-133
Nitrobenzene
ug/L
50
32.7
65
35-180
Pentachlorophenol
ug/L
50
14.6J
29
14-176
Phenanthrene
ug/L
50
27.6
55
54-120
Phenol
ug/L
50
13.8
28
5-112
Pyrene
ug/L
50
29.7
59
52-115
2,4,6-Tribromophenol(S)
%
61
10-137
2-Fluorobiphenyl(S)
%
50
15-120
2-Fluorophenol (S)
%
19
10-120
Nitrobenzened5 (S)
%
42
10-120
Phenold6 (S)
%
-
24
10-120
Terphenyldl4 (S)
%
-
65
11-131
MATRIX SPIKE SAMPLE:
Parameter
185879
9230077001 Spike MS
Units Result Conc. Result
MS
% Rec
%Rec
Limits qualifiers
1,2-Dichiorobenzene
ug/L
NO 114 69.0
61
32-129
1,2-Diphenythydrazine
ug/L
NO 114 78.3
69
25-150
1,3-Oichlorobenzene
ug/L
NO 114 64.7
57
1-172
1,4-Dichlorobenzene
ug/L
NO 114 67.1
59
20-124
2,4,6-Trichlorophenol
ug/L
NO 114 93.6
82
37-144
2,4-Dichlorophenol
ug/L
NO 114 91.1
80
1-191
2,4-Dimethylphenol
ug/L
NO 114 93.8
83
32-119
Date: 10/30/2008 03:22 PM
REPORT OF LABORATORY ANALYSIS
Page 10 of 21
This report shall not be reproduced, except in full,
without the written consent of Paw Analytical Services, Inc..
Il IGaat.i5

� -UT AA01y60815fr7 ti, (R. Pace Analytical Services, Inc.
P'aceAnalytical . 2225 Riverside Or. 9800 Kincey Ave. Suite 100
Asheville, NC 28004 Huntersville, NC 28078
www pecNabs :»m
[phone] [phone]
QUALITY CONTROL DATA
Project: WASTEWATER EFF
Pace Project No.: 9230081
MATRIX SPIKE SAMPLE:
185879
9230077001
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
%Rec
Limits Qualifiers
2,4-Dinitrophenol
ug/L
ND
114
104J
91
1-181
2,4-Dinitrololuene
ug/L
NO
114
94.6
83
39.139
2,6-Dinitrololuene
ug/L
NO
114
93.4
82
50-158
2-Chloronaphthalene
ug/L
NO
114
83.8
74
60-118
2-Chlorophenol
ug/L
NO
114
74.5
66
23-134
2-Nitrophenol
ug/L
NO
114
88.1
78
29-182
3,3'-Dichlorobenzidine
ug/L
ND
114
75.4
66
1-262
4,6-Dinitro-2-methylphenol
ug/L
NO
114
97.5
86
1-181
4-Bromophenylphenyl ether
ug/L
NO
114
87.2
77
53-127
4-Chloro-3-methylphenol
ug/L
NO
114
89.3
79
22-147
4-Chlorophenylphenyl ether
ug/L
ND
114
99.1
87
25-158
4-Nitrophenol
ug/L
NO
114
44.8J
39
1-132
Acenaphthene
ug/L
NO
114
95.5
84
47-145
Acenaphthylene
ug/L
ND
114
96.9
85
33-145
Anthracene
ug/L
NO
114
91.7
81
1-166
Senzo(a)anthracene
ug/L
NO
114
91.4
80
33-143
Benzo(a)pyrene
ug/L
NO
114
99.5
88
17-163
Benzo(b)fluoranthene
ug/L
NO
114
88.5
78
24-159
Benzo(g,h,i)perylene
ug/L
NO
114
94.4
83
1-219
Benzo(k)fluoranthene
ug/L
NO
114
102
90
11-162
bis(2-Chloroethoxy)methane
ug/L
NO
114
83.0
73
33-184
bis(2-Chloroelhyl) ether
ug/L
ND
114
52.1
46
12-158
bis(2-Chloroisopropyl) ether
ug/L
NO
114
57.0
50
36-166
bis(2-Ethylhexyl)phthalate
ug/L
NO
114
114
100
8-158
Butylbenzylphthalate
ug/L
ND
114
111
98
1-152
Chrysene
ug/L
ND
114
103
90
17-168
Di-n-butylphthalate
ug/L
NO
114
98.6
87
1-118
Di-n-ocrylphthalate
ug/L
NO
114
109
96
4-146
Dibenz(a,h)anthracene
ug/L
NO
114
90.7
80
1-227
Diethylphthalate
ug/L
NO
114
102
90
1-114
Dimethylphthalate
ug/L
ND
114
108
95
1-112
Fluoranthene
ug/L
NO
114
94.9
84
26-137
Fluorene
ug/L
NO
114
103
91
59-121
Hexachlorobenzene
ug/L
NO
114
69.3
61
1-152
Hexachlorocyclopentadiene
ug/L
NO
114
30.9
27
25-150
Hexachloroethane
ug/L
ND
114
74.0
65
40-113
Indeno(1,2,3-W)pyrene
ug/L
NO
114
90.9
80
1-171
Isophorone
ug/L
NO
114
117
103
21-196
N-Nitroso-di-n-propylamine
ug/L
NO
114
78.1
69
1-230
N-Nitrosodimethylamine
ug/L
NO
114
65.9
58
25-150
N-Nitrosodlphenylamine
ug/L
ND
114
101
89
25-150
Naphthalene
ug/L
40.9
114
116
66
21-133
Nitrobenzene
ug/L
NO
114
60.4
53
35-180
Pentachlorophenol
ug/L
NO
114
100
88
14-176
Phenanthrene
ug/L
NO
114
90.9
80
54-120
Phenol
ug/L
39.2
114
162
108
5-112
Pyrene
ug/L
NO
114
96.7
85
52-115
2,4,6-Tribromophenol (S)
%
71
10-137
Date: 10/30/2008 03:22 PM REPORT OF LABORATORY ANALYSIS Page 11 of 21
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

na APPegnem survim me. P'dta Atli ical Jelvlcee, Inc.
-/ ' 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
i PaceAnalytical Asheville, NC 28804 Nuntersville, NC 28078
xww ppceleDs cnm
[phone] [phone]
QUALITY CONTROL DATA
Project: WASTEWATER EFF
Pace Project No.: 9230081
MATRIX SPIKE SAMPLE: 185879
9230077001 Spike MS MS
%RteC
Parameter Units
Result Conc. Result % Rec
Limits Qualifiers
2-Fluorobiphenyl (S) %
84
15-120
2-Fluorophenol (S) %
44
10.120
Nitrobenzene-d5 (S) %
66
10-120
Phenol-d6 (S) %
44
10-120
Terphenyl-d14 (S) %
81
11-131
Date: 10/30/2008 03:22 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace
rAnalytical Services, Inc..
Page 12 of 21

Pace Analytical Services, Inc. Face Analytical §ervices, Inc.
aceAnalyticala 2225 Riverside Dr. 9800 Kincey Ave. Suite too
.wwve�arees.�
Asheville, NC 28804 Huntersville, NC 28078
(828)2544176 [phone]
QUALITY CONTROL DATA
Project: WASTEWATER EFF
Pace Project No.: 9230081
OC Batch: WET15921 Analysis Method: SM 2540C
QC Batch Method: SM 2540C Analysis Description: 2540C Total Dissolved Solids
Associated Lab Samples: 9230081001
METHOD BLANK: 185710 Matrix: Water
Associated Lab Samples: 9230081001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Dissolved Solids mg/L ND 20.0 10/21/08 15:31
LABORATORY CONTROL SAMPLE: 185711
Spike LOS LCS %Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Dissolved Solids mg/L 250 262 105 80-120
SAMPLE DUPLICATE: 185712
Parameter
Total Dissolved Solids
Date: 10/30/2008 03:22 PM
9230081001 Dup
Units Result Result
mg/L 520 528
RPD Qualifiers
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
without the written consent of Paw Anaytical Services, Inc..
`iL6sOl�.i°
2
Page 13 of 21

- PaceAnalytical "
www pecHebs cvm
"M SUMM me. PM Atld17MM 5RVIces, Inc.
2225 Riverside Dr. 9800 Kincey Ave. Suite 100
Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone]
QUALITY CONTROL DATA
Project:
WASTEWATER EFF
Pace Project No.:
9230081
OC Batch:
WETA/3708 Analysis Method: SM 4500-CN-E
QC Batch Method:
SM 4500-CN-E Analysis Description: 450OCNE Cyanide, Total
Associated Lab Samples: 9230081001
METHOD BLANK: 185846
Associated Lab Samples: 9230081001
Parameter Units
Cyanide mg/L
Matrix: Water
Blank Reporting
Result Lima Analyzed Qualifiers
NO 0.0050 10/23/0811:13
LABORATORY CONTROL SAMPLE:
185847
Spike LCS
LCS
% Rec
Parameter
Units
Conc. Result
%Rec
Limits
Qualifiers
Cyanide
mg/L
.1 0.12
115
80-120
MATRIX SPIKE SAMPLE:
185849
9230173007 Spike
MS
MS
% Rec
Parameter
Units
Result Conc.
Result
%Rec
Limits Qualifiers
Cyanide
mg/L
ND .1
0.11
106
75-125
SAMPLE DUPLICATE: 185848
9230412001 Dup
Parameter Units Result Result RPD Qualifiers
Cyanide mg/L 0.0095 0.0089 7
Date: 10/30/2008 03:22 PM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
�IL6�Oti.:
Page 14 of 21

/ FM AlialPM sar rm, me. r0ce Anaryf ill 8arvlces, Inc.
aceAnalyticalA
2225 Riverside 9800 ncey Ave. Suite 100
' Asheville, NC 28804 Huntersville, NC 28078
.vww pacalabs mm
[phone] [phone]
QUALITY CONTROL DATA
Project: WASTEWATER EFF
Pace Project No.: 9230081
OC Balch: GCSV/4006 Analysis Method: EPA 1664A
OC Balch Method: EPA 1664A Analysis Description: 1664 HEM, Oil and Grease
Associated Lab Samples: 9230081001
METHOD BLANK: 186618
Associated Lab Samples: 9230081001
Parameter Units
Oil and Grease mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed
NO 5.0 10/23/0810:30
Qualifiers
LABORATORY CONTROL SAMPLE: 186619
Spike LCS LCS % Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Oil and Grease mg/L 40 38.9 97 78-114
MATRIX SPIKE SAMPLE: 186620
9230548001 Spike MS MS % Rec
Parameter Units Result Conc. Result % Rec Limits Qualifiers
Oil and Grease mg/L NO 40 38.4 93 78-114
Date: 10/30/2008 03:22 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Paw Analytical Services, Inc..
Page 15 of 21

ea1:b ARalj'R M bi}OiM. ift. Pace Analytical Services, Inc.
1—gl,, ,eAnalytical' 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
Asheville, NC 28804 Huntersville, NC 28078
•wax PaceWs cum
[phone] [phone]
QUALITY CONTROL DATA
Project: WASTEWATER EFF
Pace Project No.: 9230081
QC Batch: WETA/3736 Analysis Method: EPA 420.4
QC Batch Method: EPA 420.4 Analysis Description: 420.4 Phenolics
Associated Lab Samples: 9230081001
METHOD BLANK: 187500 Matrix: Water
Associated Lab Samples: 9230081001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phenol mg/L ND 0.010 10/24/0812:29
LABORATORY CONTROL SAMPLE: 187501
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Phenol mg/L .25 0.25 100 90-110
MATRIX SPIKE SAMPLE:
Parameter
187502
Units
9230240001
Result
Spike MS MS % Rec
Cone. Result % Rec Limits Qualifiers
Phenol
mg/L
0.066
.25 0.20 52 90-110 MO
SAMPLE DUPLICATE: 187503
9230240002
Dup
Parameter
Units
Result
Result RPD Qualifiers
Phenol
mg/L
0.026
0.011 82 R1
Date: 10/30/2008 03:22 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of PPaac,erAnalylical Services, Inc..
Page 16 of 21

l°aceAnalytical
.vwwpecelabsmm
TM& Jervic", me. Pal.'! M111115IMM Services, Inc.
2225 Riverside Dr. 9800 Kincey Ave. Suite 100
Asheville, NC 28804 Huntersville. NC 28078
[phone] [phone]
QUALITY CONTROL DATA
Project:
WASTEWATER EFF
Pace Project No.:
9230081
OC Batch:
WETA/3750 Analysis Method: EPA 351.2
OC Batch Method:
EPA 351.2 Analysis Description: 351.2 TKN
Associated Lab Samples: 9230081001
METHOD BLANK: 188482
Matrix:
Water
Associated Lab Samples: 9230081001
Blank
Reporting
Parameter
Units
Result
Limit Analyzed Qualifiers
Nitrogen, Kjeldahl, Total
mg/L
ND
0.50 10/28/0811:13
LABORATORY CONTROL SAMPLE:
188483
Spike
LCS LCS %Rec
Parameter
Units
Cone.
Result %Rec Limits Qualifiers
Nitrogen, Kjeldahl, Total
mg/L
5
4.8 95 90-110
MATRIX SPIKE SAMPLE:
188484
9230277001
Spike
MS
MS
%Rec
Parameter
Units
Result
Cone.
Result
% Rae
Limits Qualifiers
Nitrogen, Kjeldahl, Total
mg/L
103
100
196
93
90-110
MATRIX SPIKE SAMPLE:
188486
9230168003
Spike
MS
MS
% Rec
Parameter
Units
Result
Cone.
Result
% Rae
Limits Qualifiers
Nitrogen, Kjeldahl, Total
mg/L
9.0
5
12.9
80
90-110 MO
SAMPLE DUPLICATE: 188485
9230243001 Oup
Parameter Units Result Result RPD Qualifiers
Nitrogen, Kjeldahl, Total mg/L 394 405 3
SAMPLE DUPLICATE: 188487
9230182001 Dup
Parameter Units Result Result RPD Qualifiers
Nitrogen, Kjeldahl, Total mg/L 14.5 14.6 .3
Date: 10/30/2008 03:22 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 17 of 21

I= Alrimstrin 371mm. ale. Pace Analytical Services, Inc.
'r 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
,PaceAnalytical Asheville, NC 28804 Huntersville, NC 28078
www.pecNebsmm
[phone] [phone]
Project: WASTEWATER EFF
Pace Project No.: 9230081
QC Batch: WETA13756
QC Batch Method: EPA 365.1
Associated Lab Samples: 9230081001
METHOD BLANK: 188900
Associated Lab Samples: 9230081001
Parameter Units
Phosphorus mg/L
LABORATORY CONTROL SAMPLE: 188901
Parameter Units
Phosphorus mg/L
QUALITY CONTROL DATA
Analysis Method: EPA 365.1
Analysis Description: 365.1 Phosphorus, Total
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.10 10/29/0810:55
Spike LCS LCS %Rec
Conc. Result %Rao Limits Qualifiers
1 1.1 106 90-110
MATRIX SPIKE SAMPLE: 188902
9230060001 Spike MS MS % Rec
Parameter Units Result Conc. Result % Rec Limits Qualifiers
Phosphorus mg/L NO 1 1.1 106 90-110
MATRIX SPIKE SAMPLE:
Parameter
188904
Units
9230182001
Result
Spike MS MS % Rec
Conic. Result % Rec Limits Qualifiers
Phosphorus
mg/L
7.1
1 8.0 90 90-110
SAMPLE DUPLICATE: 188903
9230059003
Dup
Parameter
Units
Result
Result RPD Qualifiers
Phosphorus
mg/L
1.9
1.9 A
SAMPLE DUPLICATE: 188905
9230185001 Dup
Parameter Units Result Result RPD Qualifiers
Phosphorus mg/L 0.16 0.14 9
Date: 10/30/2008 03:22 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent
of `Paw Analytical Services, Inc..
Page 18 of 21

race Analytical Services, Inc. Pace Analytical Sq"I06a, Inc.
- aceAnalytical 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
www.OviceleDs. Qom
Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone]
QUALITY CONTROL DATA
Project:
WASTEWATER EFF
Pace Project No.:
9230081
QC Batch:
MSV/5068
Analysis Method: EPA 624
QC Batch Method:
EPA 624
Analysis Description: 624 MSV
Associated Lab Samples: 9230081001
METHOD BLANK: 189879
Associated Lab Samples:
Parameter
9230081001
Units
Matrix:
Blank
Result
Water
Reporting
Limit
Analyzed
1,1,1-Tdchloroethane
ug/L
NO
5.0
10/2910812:22
1,1,2,2-Telrachloroethane
ug/L
NO
5.0
10/29/08 12:22
1,1,2-Trichloroethane
ug/L
NO
5.0
10/29/08 12:22
1,1-Dichloroelhane
ug/L
NO
5.0
10/29/08 12:22
1,1-Dichloroethene
ug/L
NO
5.0
10/29/08 12:22
1,2,4-Tdchlorobenzene
ug/L
NO
5.0
10/29/08 12:22
1,2-Dichlorobenzene
ug/L
NO
5.0
10/2910812:22
1,2-Dichloroethane
ug/L
NO
5.0
10/29/08 12:22
1,2-Dichloropropane
ug/L
NO
5.0
10/29/08 12:22
1,3-Dichlorobenzene
ug/L
ND
5.0
10/29/08 12:22
1,4-Dichlorobenzene
ug/L
NO
5.0
10/29/08 12:22
2Chloroethylvinyl ether
ug/L
NO
10.0
10/29/08 12:22
Acrolein
ug/L
ND
100
10/29/08 12:22
Acrylonitrile
ug/L
NO
100
10/29/08 12:22
Benzene
ug/L
NO
5.0
10/29/08 12:22
Bromodichloromethane
ug/L
NO
5.0
10/29/08 12:22
Bromoform
ug/L
NO
5.0
10/2910812:22
Bromomethane
ug/L
NO
10.0
10/2910812:22
Carbon tetrachloride
ug/L
NO
5.0
10/29/08 12:22
Chlorobenzene
ug/L
NO
5.0
10129/0812:22
Chloroethane
ug/L
NO
10.0
10/29/08 12:22
Chloroform
ug/L
NO
5.0
10/29/08 12:22
Chioromethane
ug/L
NO
5.0
10/29/08 12:22
cis-1,3-Dichloropropene
ug/L
NO
5.0
10/29/08 12:22
Dibromochloromethane
ug/L
NO
,
5.0
10/29/08 12:22
Ethylbenzene
ug/L
NO
5.0
10129/0812:22
Hexachloro-1,3-butadiene
ug/L
NO
5.0
10/2910812:22
Methylene Chloride
ug/L
NO
5.0
10/29/08 12:22
Naphthalene
ug/L
NO
5.0
10/29/08 12:22
Tebachloroethene
ug/L
NO
5.0
1012910812:22
Toluene
ug/L
NO
5.0
10/2910812:22
trans-1,2-Dichloroethene
ug/L
NO
5.0
10/29/08 12:22
trans-1,3-Dichloropropene
ug/L
NO
5.0
10/29/08 12:22
Tdchloroethene
ug/L
ND
5.0
10129/0812:22
Trichlorofluoromethane
ug/L
ND
10.0
10/29/08 12:22
Vinyl chloride
ug/L
NO
5.0
10/29/08 12:22
1,2-Dichloroelhane-d4 (S)
%
93
70-130
10/29/08 12:22
4-Bromofluorobenzene (S)
%
96
86-111
10/29/08 12:22
Dibromofluoromethane (S)
%
88
88.113
10/29/08 12:22
Toluene-d8 (S)
%
102
92-105
10/29/08 12:22
Qualifiers
Date: 10/30/2008 03:22 PM REPORT OF LABORATORY ANALYSIS Page 19 of 21
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
laceAnalytical: 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
Asheville, NC 28804 Huntersville, NC 28078
www parolebs cwn
[phone] [phone]
QUALITY CONTROL DATA
Project: WASTEWATER EFF
Pace Project No.: 9230081
LABORATORY CONTROL SAMPLE:
189880
Spike
LCS
LCS
%Roo
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,1,1-Trichloroethane
ug/L
20
17.6
88
52-162
1,1,2,2-Tetrachloroelhane
ug/L
20
16.8
84
46-157
1,1,2-Trichloroethane
ug/L
20
17.8
89
52-150
1,1-Dichloroethane
ug/L
20
18.1
90
59.155
1,1-Dichloroelhene
ug/L
20
20.1
100
1-234
1,2,4-Trichlorobenzene
ug/L
20
18.3
92
70-130
1,2-Dichlorobenzene
ug/L
20
19.2
96
18-190
1,2-Dichloroethane
ug/L
20
16.6
83
49-155
1,2-Dichloropropane
ug/L
20
18.2
91
1-210
1,3-Dichlorobenzene
ug/L
20
19.2
96
59-156
1,4-Dichlorobenzene
ug/L
20
19.6
98
18-190
2-Chloroethylvinyl ether
ug/L
40
33.2
83
1-305
Acrolein
ug/L
100
89.51
90
15-152
Acrylonitrile
ug/L
100
178
178
75-132 L3
Benzene
ug/L
20
18.4
92
37-151
Bromodichloromethane
ug/L
20
17.3
87
35-155
Bromoform
ug/L
20
16.9
84
45-169
Bromomethane
ug/L
20
18.2
91
1-242
Carbon tetrachloride
ug/L
20
17.5
88
70-140
Chlorobenzene
ug/L
20
19.7
99
37-160
Chloroethane
ug/L
20
20.8
104
14-230
Chloroform
ug/L
20
16.2
81
51-138
Chloromethane
ug/L
20
16.4
82
1-273
cis-1,3-Dichloropropene
ug/L
20
18.1
90
1-227
Dibromochloromethane
ug/L
20
16.8
84
53-149
Ethylbenzene
ug/L
20
19.9
99
37-162
Hexachioro-1,3-butadiene
ug/L
20
18.7
93
70-130
Methylene Chloride
ug/L
20
19.2
96
1-221
Naphthalene
ug/L
20
19.7
98
70-130
Tetrachlomethene
ug/L
20
19.1
95
64-148
Toluene
ug/L
20
18.9
94
47-150
trans-1,2-Dichloroethene
ug/L
20
17.0
85
54-156
trans-1,3-Dichloropropene
ug/L
20
17.7
88
17-183
Trichloroethene
ug/L
20
18.2
91
71-157
Trichlorofluoromethane
ug/L
20
18.8
94
17-181
Vinyl chloride
ug/L
20
19.2
96
1-251
1,2-Dichloroethane-d4(S)
%
92
70-130
4-Bromofluorobenzene (S)
%
98
86-111
Dibromofiuoromethane (S)
%
95
88-113
Toluene-d8 (S)
%
103
92-105
Date: 10/30/2008 03:22 PM REPORT OF LABORATORY ANALYSIS Page 20 of 21
This report shall not be reproduced, except in full,
without the written consent of Pam Analytical Services, Inc..
III

Faca Alla YMM 941v11t"g! Mt. Pace Analytical Services, Inc.
/ aceAnalytical' 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
+,�.nacereesm� Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone]
QUALIFIERS
Project: WASTEWATER EFF
Pace Project No.: 9230081
DEFINITIONS
OF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
NO - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MOIL - Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
PASI-G Pace Analytical Services - Green Bay
ANALYTE QUALIFIERS
L3 Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in
associated samples. Results unaffected by high bias.
Mo Matrix spike recovery was outside laboratory control limits.
R1 RPD value was outside control limits.
Date: 10/30/2008 03:22 PM REPORT OF LABORATORY ANALYSIS Page 21 of 21
This report shall not be reproduced, except in full,
without the written consent of `Pam Analytical Services, Inc..
�11_mOL.I

• .;HA...-,dF-Lwv ; OL a , Ana al kequest uocument
PaeeAnalytical The Chainof-Custody is a LEGAL DOCUMENT All relevant fields must he completed accurately
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is
'IT

71,, 2225 Riverside n. 9 A KMY'ce 511791Me. ul a 1f0p
8C8/'U I[7IICC7I Asheville, NC 28804 Huntersville, NC 28078
wwwpacelebs.tdn
[phone] [phone]
August 07, 2008
Mr. Lynwood Sessoms
Town of Tarboro
506 Dowd Street
PO Box 220
Tarboro, NC 27886
RE: Project: PPA 7/24/08
Pace Project No.: 9224125
Dear Mr. Sessoms:
Enclosed are the analytical results for sample(s) received by the laboratory on July 24, 2008. The
results relate only to the samples included in this report. Results reported herein conform to the
most current NELAC standards, where applicable, unless otherwise narrated in the body of the
report.
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All
Microbiological analyses were performed at the laboratory where the samples were received.
If you have any questions concerning this report, please feel free to contact me.
Sinc rely,
_Orr on
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent
of Pace Analytical Services, Inc..
ar IGIO.\..
Page 1 of 28

�v .vn wwfi SHrtrtm. i1R. Mace Analytical Services, Inc.
2225 Riverside Dr. 9800 Kincey Ave. Suite 100
aceAnalytical a Asheville, NC 28804 Hunlersville, NC 28078
www.peaWOs can
[phone] [phone]
Project: PPA 7/24/08
Pace Project No.: 9224125
Charlotte Certification IDs
Virginia Certification Number: 00213
Tennessee Certification Number: 04010
South Carolina Bioassay Certification Number: 990060003
South Carolina Certification Number: 990060001
North Carolina Field Services Certification Number: 5342
Asheville Certification IDs
Virginia Certification Number: 00072
Tennessee Certification Number: 2980
South Carolina Bioassay Certification Number: 99030002
South Carolina Certification Number: 99030001
Pennsylvania Certification Number: 68-03578
North Carolina Bioassay Certification Number: 9
Eden Certification IDs
North Carolina Wastewater Certification Number: 633
Virginia Drinking Water Certification Number: 00424
CERTIFICATIONS
North Carolina Wastewater Certification Number: 12
North Carolina Drinking Water Certification Number: 37706
Louisiana/LELAP Certification Number: 04034
Kansas Certification Number: E-10364
Florida/NELAP Certification Number: E87627
North Carolina Wastewater Certification Number: 40
North Carolina Drinking Water Certification Number: 37712
New Jersey Certification Number: NC011
Louisiana/LELAP Certification Number: 03095
Florida/NELAP Certification Number: E87648
North Carolina Drinking Water Certification Number: 37738
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of�Pace
.Analytical Services, Inc..
Page 2 of 28

I'M dAl sAMces, Inc. Pace Analytical Services, Inc.
e 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
BCEAnalytiCalAsheville, NC 28804 Huntersville, NC 28078
www.pecebOs cm,
[phone] [phone]
ANALYTICAL RESULTS
Project: PPA 7/24/08
Pace Project No.: 9224125
Sample: Wastewater Effluent Lab ID: 9224125003 Collected: 07/2410808:00 Received: 07/24/0813:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
HEM, Oil and Grease
Analytical Method: EPA 1664A
Oil and Grease
NO mg/L
5.0
1
07/28/08 10:49
200.7 MET ICP
Analytical Method: EPA 200.7 Preparation Method:
EPA 200.7
Antimony
NO ug/L
5.0
1
07/28/08 16:30 07/30/08 01:08
7440-36-0
Arsenic
NO ug/L
5.0
1
07/28/08 16:30
07/30/08 01:08
7440-38-2
Beryllium
NO ug/L
1.0
1
07/2810816:30
07/30/08 01:08
744041-7
Cadmium
NO ug/L
1.0
1
07/28/08 16:30
07/30/08 01:08
744043-9
Calcium
11500 ug/L
100
1
07/28/08 16:30
07/30/08 01:08
7440-70-2
Chromium
NO ug/L
5.0
1
07/28/08 16:30
07/30/08 01:08
744047-3
Copper
NO ug/L
5.0
1
07/28/08 16:30
07/30/08 01:08
7440-50-8
Lead
NO ug/L
5.0
1
07/28/08 16:30
07/30/08 01:08
7439-92-1
Magnesium
3070 ug/L
100
1
07/28/08 16:30
07/30/08 01:08
7439-954
Nickel
NO ug/L
5.0
1
0712810816:30
07/30/0801:08
7440-02-0
Selenium
NO ug/L
10.0
1
07/28/08 16:30
07/30/08 01:08
778249-2
Silver
NO ug/L
5.0
1
0712810816:30
07/30/08 01:08
7440-224
Thallium
NO ug/L
10.0
1
07/28/08 16:30
07/30/08 01:08
7440-28-0
Zinc
25.4 ug/L
10.0
1
07/28/08 16:30
07/30/08 01:08
7440-66-6
2340B Hardness, Total (Calc.)
Analytical Method: SM 2340B
Total Hardness
41.3 mg/L
0.65
1
07/30I08 01:08
245.1 Mercury
Analytical Method: EPA 245.1 Preparation Method: EPA 245.1
Mercury
NO ug/L
0.20
1
07/25/0809:30
07/25/0816:46
7439-97-6
125 MSSV
Analytical Method: EPA 625 Preparation
Method: EPA 625
Acenaphthene
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
83-32-9
acenaphthylene
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
208-96-8
knlhracene
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
120-12-7
3enzo(a)anthracene
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
56-55-3
Benzo(a)pyrene
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
50-32-8
3enzo(b)8uoranthene
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
205-99-2
3enzo(g,h,i)perylene
NO ug/L
6.8
1
07/2510800:00
07/29/08 09:47
191-24-2
denzo(k)0uoranthene
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
207-08-9
4-Brmophenylphenyl ether
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
101-55-3
3utylbenzylphthalale
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
85-68-7
I-Chloro-3-methylphenol
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
59.50-7
bis(2-Chloroethoxy)methane
NO ug/L
13.5
1
07/25/08 00:00
07/29/08 09:47
111-91-1
his(2-Chloroethyl) ether
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
11144-4
lis(2-Chloroisopropyl) ether
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
108-60-1
-Chloronaphthalene
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
91-58-7
2-Chlorophenol
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
95-57-8
-Chlorophenylphenyl ether
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
7005-72-3
:hrysene
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
218-01-9
Jibenz(a,h)anthracene
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
53-70-3
1,2-Dichlorobenzene
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
95-50-1
,3-Dichlorobenzens
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
541-73-1
Date: 08/071200812:48 PM
REPORT OF LABORATORY
ANALYSIS
Page 3 of 28
This report shall not be reproduced, except in full,
without the written consent
of Pace Analytical Services, Inc
ill IG14C �.

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
2225 Riverside Dr. 9800 Kincey Ave. Suite 100
aceAnalytical Asheville, NC 28804 Huntersville, NC 28078
www.pecelabsmm
[phone] [phone]
ANALYTICAL RESULTS
Project: PPA 7/24/08
Pace Project No.: 9224125
Sample: Wastewater Effluent Lab ID: 9224125003 Collected: 07/24/08 08:00 Received: 07/24/08 13:30 Matrix: Water
Parameters
Results Units
Report Limit
OF
Prepared
Analyzed
CAS No. Qual
625 MSSV
Analytical Method: EPA 625 Preparation Method: EPA 625
1,4-Dichlorobenzene
ND ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47 10646-7
3,3'-Dichlorobenzidine
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
91-94-1
2,4-Dichlorophenol
ND ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
120-83-2
Diethylphthalate
NO ug/L
6.8
1
07/25108 00:00
07/29/08 09:47
84-66-2
2,4-Dimethylphenol
NO ug/L
13.5
1
07/25/08 00:00
07/29/08 09:47
105-67-9
Dimethylphthalate
ND ug/L
6.8
1
07125/08 00:00
07/29/08 09:47
131-11-3
Di-n-butylphthalate
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
8474-2
4,6-Dinitro-2-methylphencl
NO ug/L
27.0
1
07/25/08 00:00
07/29/08 09:47
534-52-1
2,4-Dinitrophenol
ND ug/L
67.6
1
07/25/08 00:00
07/29/08 09:47
51-28-5
2,4-Dinitrotoluene
NO ug/L
6.8
1
07/25108 00:00
07/29/08 09:47
121-14.2
2,6-Dinitrotoluene
ND ug/L
6.8
1
07/25108 00:00
07/29/08 09:47
606-20-2
Di-noctyiphthalate
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
117-84-0
1,2-Diphenylhydrazine
ND ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
122-66-7
bis(2-Ethylhexyl)phthalate
NO ug/L
6.8
1
07/25/0800:00
07/29/08 09:47
117-81-7
Fluoranthene
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
20644-0
Fluorene
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
86-73-7
-lexachlorobenzene
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
118-741
-fexachlorocyclopentadiene
ND ug/L
13.5
1
07/25/08 00:00
07/29/08 09:47
77-47-4
Hexachloroethane
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
67-72-1
'ndeno(1,2,3-cd)pyrene
ND ug/L
6.8
1
07/25108 00:00
07/2910809:47
193-39.5
sophorone
NO ug/L
13.5
1
07/25/08 00:00
07/29/08 09:47
78-59-1
laphthalene
ND ug/L
6.8
1
07/25/0800:00
07/29/08 09:47
91-20-3
Nitrobenzene
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
98-95-3
'.-Nitrophenol
NO ug/L
6.8
1
07125/08 00:00
07/29/08 09:47
88-75-5
I-Nitrophenol
ND ug/L
67.6
1
07/25/08 00:00
07/29/08 09:47
100-02-7
,J-Nitrosodimethylamine
NO ug/L
6.8
1
07125/0800:00
07/2910809:47
62-75-9
N-Nitroso-di-rrpropylamine
ND ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
621-64-7
1-Nitrosodiphenylamine
NO ug/L
13.5
1
07/25/08 00:00
07/29/08 09:47
86-30-6
'entachlorophenol
ND ug/L
33.8
1
07/25/08 00:00
07/29/08 09:47
87-86-5
Phenanthrene
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
85-01-8
Phenol
NO ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
108-95-2 -
ryrene
ND ug/L
6.8
1
07/25/08 00:00
07/29/08 09:47
12900-0
I,4,6-Trichlorophenol
NO ug/L
13.5
1
07/25/08 00:00
07/29/08 09:47
88-06-2
Nitrobenzene-d5 (S)
31 %
10-120
1
07/25/'08 00:00
07/29/08 09:47
4165-60-0
"-Fluorobiphenyl (S)
31 %
15-120
1
07/25/08 00:00
07/29/08 09:47
321-60.8
erphenyl-d14 (S)
33 %
11-131
1
07/25/08 00:00
07/29/08 09:47
1718-51-0
'henol-06 (S)
12 %
10-120
1
07/25/08 00:00
07/29/08 09:47
13127-88-3
2-Fluorophenol (S)
17 %
10-120
1
07/25/08 00:00
07/29/08 09:47
367-124
,4,6-Tribromophenol (S)
41 %
10-137
1
07/25/08 00:00
07/29/08 09:47
118-79-6
24 Volatile Organics
Analytical Method: EPA 624
4crolein
NO ug/L
100
1
08/04/0816:24
107-02-8
crylonilrile
ND ug/L
100
1
0B/04/0816:24
107-13-1
enzene
NO ug/L
5.0
1
08104/0816:24
71-43-2
Bromodichloromethane
NO ug/L
5.0
1
08/04/0816:24
75-27-4
"romoform
ND ug/L
5.0
1
08/04/08 16:24
75-25-2
romomethane
NO ug/L
10.0
1
08/04/0816:24
74-83-9
Date: 08/07/2008 12:48 PM
REPORT OF LABORATORY
ANALYSIS
Page 4 of 28
This report shall
not be reproduced, except in
full,
without the written consent of PaceAnalytical Services, Inc..

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
/ s 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
aceAnalytical Asheville, NC 28804 Hunlersville, NC 28078
[phone] [phone]
ANALYTICAL RESULTS
Project: PPA 7/24/08
Pace Project No.: 9224125
Sample: Wastewater Effluent Lab ID: 9224125003 Collected: 07/24/08 08:00 Received: 07124/08 13:30 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qua[
624 Volatile Organics
Analytical Method: EPA 624
Carbon tetrachloride
NO ug/L
5.0
1
08/04/08 16:24
56-23-5
Chlorobenzene
NO ug/L
5.0
1
08104/0816:24
108.90-7
Chloroelhane
NO ug/L
10.0
1
08/04/08 16:24
75-00-3
2-Chloroethylvinyl ether
NO ug/L
10.0
1
08/04/08 16:24
110-75-8
Chloroform
NO ug/L
5.0
1
Oa/04/0816:24
67-66-3
Chloromethane
NO ug/L
5.0
1
08/0410816:24
74-87-3
Dillromochloromethane
NO ug/L
5.0
1
08/04/08 16:24
124-48-1
1,2-Dichlorobenzene
NO ug/L
5.0
1
08/04/08 16:24
95-50-1
1,3-Dichlorobenzene
NO ug/L
5.0
1
08/0410816:24
541-73-1
1,4-Dichlorobenzene
NO ug/L
5.0
1
Oa/04/0816:24
106-46-7
1,1-Dichloroethane
NO ug/L
5.0
1
011/04/0816:24
75-34-3
1,2-Dichloroethane
NO ug/L
5.0
1
08/04/08 16:24
1074)6-2
1,1-Dichloroethene
NO ug/L
5.0
1
08I04/0816:24
75-354
trans-1,2-Dichloroethene
NO ug/L
5.0
1
0a/04/0816:24
156-60-5
1,2-Dichloropropane
NO ug/L
5.0
1
08/0410816:24
78-87-5
cis-1,3-Dichloropropene
NO ug/L
5.0
1
08/04/0816:24
10061-01-5
trans-1,3-Dichloropropene
NO ug/L
5.0
1
08/04/08 16:24
10061-02-6
Ethylbenzene
NO ug/L
5.0
1
08/04/0816:24
1OD-41-4
Hexachloro-1,3-butediene
NO ug/L
5.0
1
08/04/08 16:24
87-M3
Methylene Chloride
NO ug/L
5.0
1
Oa104/08 16:24
75-09-2
Naphthalene
NO ug/L
5.0
1
Oa/04/0816:24
91-20-3
1,1,2,2-Tetrachloroethane
NO ug/L
5.0
1
08/04/08 16:24
79-34-5
Tebachloroethene
NO ug/L
5.0
1
08/04/08 16:24
127-184
Toluene
NO ug/L
5.0
1
08/04/08 16:24
108.88-3
1,2,4-Trichlorobenzene
NO ug/L
5.0
1
08/04/08 16:24
120-82-1
1,1,1-Trichloroethane
NO ug/L
5.0
1
08/04/08 16:24
71-55-6
1, 1,2-Trichloroethane
NO ug/L
5.0
1
08/04/08 16:24
79-00-5
Trichloroethene
NO ug/L
5.0
1
08/04/08 16:24
79-01.6
Trichlorofluoromethane
NO ug/L
10.0
1
08/04/08 16:24
75.694
Vinyl chloride
NO ug/L
5.0
1
08/04/08 16:24
75-014
Dibromofluoromelhane (S)
99 %
88-113
1
08/04/08 16:24
1868-53-7
4-BromoOuorobenzene (S)
101 %
86-111
1
08/04/08 16:24
460-00-4
Toluened8 (S)
100 %
92-105
1
08/04/08 16:24
2037-26-5
1,2-Dichloroethane-d4(S)
99 %
70-130
1
08/0410816:24
17060-07-0
2540C Total Dissolved Solids
Analytical Method: SM 2540C
Total Dissolved Solids
562 mg/L
20.0
1
07/2a/0820:54
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
0.19 mg/L
0.10
1
07/31/08 20:21
7764-41-7
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2
Nitrogen, Kjeldahl, Total
2.4 mg/L
0.50
1
08/05/08 19:53
7727-37-9
353.2 Nitrogen, N021NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
16.4 mg/L
0.10
1
07/25/08 23:06
Date: 08107/200812:48 PM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 5 of 28

l f°aceAnalytical
w,w-pecebbs can
Project: = PPA 7/24/08 -
Pace Project N(% 9224t25
Sample: Wastewater Effluent
Parameters
353.2 Nitrogen, ll02lNO3 unpres
Nitrogen, Nitrite-
Nitrogen, NO2 pfus NO3 -
365.1 Phosphorus, Total
Phosphorus ;
420-4.Phenoflcs Total --
Pheg01
450OCNE Cyanide, Total
Cyanide -
r'M Affff M Sehnees, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Lab ID: 9224125003 Collected: 07/24/OB
Results Units 1 Report Limit
Analytical Method: EPA 353.2
NO mg/L
16.4 mg/L-
Analytical Method: EPA054
0,43 mglL
Analytical Method;. EPA 420-
NO mg/L-=-
Anal tical Method SM 4500IN-E
0.10
0.10
0.10
y-
NO mg/L_ _ - 0.00150
OF
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
eceived: 07/24/0813:30 Ms}atic Water
Prepared Analyzed CAS No: Qual
- j
07/25/08 23:06
_07/25/08 23:06 =
--108/04/08 10:59 1723-14-0=
i
08/06/08 12:50 -�108-05-2
07/28/0815:28 57-12-5 c:
Sample: Trip 1pank -
= Lab ID: 92241211004 Collected: 07/24/08 00:00
Releeived:
07P14M8 13:30 M36ix: Watet
Aatjumeters _
` ResuB.i :-FJnlls
:. = Report Lirrgt
fjF ��
Prepared
= ---"Analyzed -� CAS WEQual
124 Volatile Orionies %
z! Analytical MethodlrEPA 824--
Acrolein-ND
ug/L -
1180
_3: =
-
004/0816:41 ,107-02-8
4cryloniVile-ND
ug/L -'
' = - 100
Y c
-
08104/0816:41-j07-13-1.-
3enzene
_ ND ug/L
- ., :, !E0
-_-
--_ 08M4/08 16:41-1143-2 .
Bromodichloromethane ---
_ NO ug/L
_ = ' iG0
3
08104/08 16:41 75-27-4 -_
9romoform -
=_ ND ug/L
5:0
-4
08104/08 16:41 45-25-2
3romomethane..' -=
NO ug/L_
-_ " 10-0
A+ _
OS(04/08 16:41 a4-83-9
:arbon tetrachloride -
-ND ug/L
08/04/08 16:41 b6-23-5 -
Chlorobenzene -
- --ND ug/L_-
Zo
-1
-
08f04/0816:41 J08-90-7-
:hloroethane
-ND ug/L
08104I08 16:41 j5-00-3
t-Chloroeth Ivi ether -
Y nYl
- ;ND ug/L
_
� �,= . J iff0
� .�
08104I0816:41 J10.75-8
chloroform - _
_ _--ND ug/L _
- � $0
,I,
.,
,- �
Oa/04/08 16:41 :S7-06-3
Chloromethane - --
NO ug/L-_
_ '� = _ MO
3 �
'� �
081"08 16:41 -74-a7-3
)ibromochloromethane -
__ _. NO ug/L -
- -� _ &g
1
Y
-08/04/08 16:41 -_12448-1 -
1,2-Dichlorobenzene -
NO ug/L ;
; .. -, 59
�
-
Otbd4/08 16:41 95-60-1
1,3-Dichlorobenaene
_ :.ND ug/L :
u .
�� ` 5:0
,'-`6
j __
_ _
:08104/08 16:41-541-73-1
14-Dichlorobeniene
= NO ug/L
10
S ,
--
= Oft4/O8 16:41 ,106-46-7
1,1-Dichloroethane
=. NO ug/L t
-� � 5
1 c
=
-01�04/0816:41'315$4-3
1,2-Dichloroethane
NO ug/L
-_
�01#04108 16:41 g0$06-2 '
_
1,1-Dichloroethene
- -.ND ug/L
i = = S.0
=
c
.:08104/0816:41 h5415+1 e
'cans-1,2-Dichloroethene '
-NO ug/L-_
� 08f04l0816:41 �5"&5 =
1,2-Dichloropropane.
= -Nli ug/L
SO
1
-
,0Ql04/0816:41 78d17-5
,Is-1,3-Dichorepropene
-NQ ug/L
-0SSp4/0816:41 y0961-0190 -"
trans-1,3-Diehloroprbpene ,.
-e Dug/L
&O
2-,
uglL
,gQWI-0
=0Q4/0816:41gOQ+414,=ithylbenzena
Qug/L
*0
_O&D4/0816:41
=§
0804/08J6:41 37 63iexachloro-1;3-butadiene
Aethylene Chloride -I =-
7
�0
Ou9/L Q04/006:41 315W2
:
Na hlhalen .
y
0�16:41 �120.3g
,1,2,2-Telrac♦loroethane
_ ..16 ug/L
5:0
Of4/08136:41 79,44-5`
_
.
Date: 08/07l2008 12:48 PM
REPORT OF LABORATORY
ANALYSIS
- Page 6 of 28
This report shall not be reproduced, except In lull,
C
without the written consent of Pace Analytical Services, Inc..

raEe AnWiiElli SIRM61, the. Pace Analytical Services, Inc.
e 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
ace Analytical Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone]
ANALYTICAL RESULTS
Project: PPA 7/24/08
Pace Project No.: 9224125
Sample: Trip Blank Lab ID: 9224125004 Collected: 07/24/08 00:00 Received: 07/24/08 13:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
624 Volatile Organics Analytical Method: EPA 624
Telrachloroethene
NO ug/L
5.0
1
08/04/08 16:41
127-18-4
Toluene
NO ug/L
5.0
1
08/04/08 16:41
108-88-3
1,2,4-Trichlorobenzene
NO ug/L
5.0
1
08/04/08 16:41
120-82-1
1,1,1-Tdchloroethane
NO ug/L
5.0
1
08104/0816:41
71-55-6
1,1,2-Trichloroethane
NO ug/L
5.0
1
08/04/08 16:41
79-00-5
Trichloroethene
NO ug/L
5.0
1
08104/0816:41
79-01-6
Trichlorofluoromethane
ND ug/L
10.0
1
08/04/08 16:41
75-69-4
Vinyl chloride
ND ug/L
5.0
1
08/0410816:41
75-014
Dibromofluoromethane (S)
101 %
88-113
1
08/04/08 16:41
1868-53-7
4-Bromofluorobenzene (S)
100 %
86-111
1
08/04/08 16:41
460-00-4
Toluene-d8 (S)
100 %
92-105
1
08/04/08 16:41
2037-26-5
1,2-Dichloroethane-d4 (S)
102 %
70-130
1
08/04/08 16:41
17060-07-0
Date: 08/07/2008 12:48 PM REPORT OF LABORATORY ANALYSIS Page 7 of 28
This report shall not be reproduced, except in full,
without the written consent
of Pace
eerAnalytical Services, Inc..
Pa
1 IG14e

Fab AnJTIM 31frOM, R2. rice Analytical Servces, Inc.
2225 Riverside Dr, 9800 Kince Ave. Suite too
aceAnalytical Asheville, NC 28804 Hunte sville, NC 28078
www pecele6s mm
[phone] [phone]
QUALITY CONTROL DATA
Project: PPA 7/24108
Pace Project No.: 9224125
OC Batch: MERP/1607 Analysis Method: EPA 245.1
QC Batch Method: EPA 245.1 Analysis Description: 245.1 Mercury
Associated Lab Samples: 9224125003
METHOD BLANK: 144440
Associated Lab Samples: 9224125003
Blank Reporting
Parameter Units Result Limit Qualifiers
Mercury ug/L ND 0.20
LABORATORY CONTROL SAMPLE: 144441
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 2.5 2.2 89 85-116
MATRIX SPIKE SAMPLE: 144442
9224084001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Mercury ug/L NO 2.5 2.0 79 70-130
SAMPLE DUPLICATE: 144443
9224084002 Dup
Parameter Units Result Result
Mercury ug/L ND NO
Date: 08/07/2008 12:48 PM
RPD Qualifiers
57
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 8 of 28

Ice Analytical 2225 Riverside Or. 9800 Kincey Ave. Suite 100
www.pe eb05 mn
Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone]
QUALITY CONTROL DATA
Project: PPA 7/24/08
Pace Project No.: 9224125
OC Batch: OEXT/3879 Analysis Method: EPA 625
OC Balch Method: EPA 625 Analysis Description: 625 MSS
Associated Lab Samples: 9224125003
METHOD BLANK: 144458
Associated Lab Samples:
9224125003
Blank
Reporting
Parameter
Units
Result
Limit Qualifiers
1,2-Dichiorobenzene
ug/L
ND
5.0
1,2-Diphenylhydrazine
ug/L
ND
5.0
1,3-Dichlorobenzene
ug/L
NO
5.0
1,4-Dichiorobenzene
ug/L
ND
5.0
2,4,6-Trichlorophenol
ug/L
NO
10.0
2,4-Dichlorophenol
ug/L
NO
5.0
2,4-Dimethylphenol
ug/L
ND
10.0
2,4-Dinitrophenol
ug/L
NO
50.0
2,4-Dinitrotoluene
ug/L
ND
5.0
2,6-Dinitrotoluene
ug/L
NO
5.0
2-Chioronaphthalene
ug/L
ND
5.0
2-Chiorophenol
ug/L
ND
5.0
2-Nitrophenol
ug/L
NO
5.0
3,3'-Dichlorobenzidine
ug/L
ND
5.0
4,6-Dinitro-2-methylphenol
ug/L
ND
20.0
4-Bromophenylphenyl ether
ug/L
NO
5.0
4-Chloro-3-methylphenol
ug/L
NO
5.0
4-Chiorophenyiphenyl ether
ug/L
ND
5.0
4-Nitrophenol
ug/L
NO
50.0
4cenaphthene
ug/L
NO
5.0
4cenaphthylene
ug/L
ND
5.0
Anthracene
ug/L
ND
5.0
Benzo(a)anthracene
ug/L
ND
5.0
3enzo(a)pyrene
ug/L
NO
5.0
3enzo(b)fluoranthene
ug/L
NO
5.0
Senzo(g,h,i)perylene
ug/L
ND
5.0
Benzo(k)fluoranthene
ug/L
ND
5.0
3is(2-Chioroelhwry)methane
ug/L
NO
10.0
3is(2-Chloroelhyl) ether
ug/L
NO
5.0
bis(2-Chloroisopropyl) ether
ug/L
ND
5.0
'Dis(2-Ethylhexyl)phthalale
ug/L
ND
5.0
3utyibenzylphthalate
ug/L
NO
5.0
:;hrysene
ug/L
NO
5.0
Di-n-butylphthalate
ug/L
ND
5.0
)I-n-octylphthalate
ug/L
ND
5.0
)ibenz(a,h)anthracene
ug/L
ND
5.0
Jiethylphthalate
ug/L
NO
5.0
Dimethylphthalate
ug/L
NO
5.0
=luoranthene
ug/L
ND
5.0
-luorene
ug/L
ND
5.0
Hexachlorobenzene
ug/L
NO
5.0
4exachlorocyclopentadiene
ug/L
NO
10.0
iexachloroethane
ug/L
ND
5.0
Date: 081071200812:48 PM REPORT OF LABORATORY ANALYSIS Page 9 of 28
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

ran AR01yIRtfi SlirviLes, Inc. Pace Analytical Services, Inc.
/ 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
aceAnalytical Asheville, NC 28804 Huntersville, NC 28078
www.paMebs can
[phone] [phone]
QUALITY CONTROL DATA
Project: PPA 7/24/08
Pace Project No.: 9224125
METHOD BLANK: 144458
Associated Lab Samples: 9224125003
Blank
Reporting
Parameter
Units
Result
Limit Qualifiers
Indeno(1,2,3-cd)pyrene
ug/L
NO
5.0
Isophorone
ug/L
NO
10.0
N-Nitroso-di-n-propylamine
ug/L
NO
5.0
N-Nitrosodimethylamine
ug/L
NO
5.0
N-Nitrosodiphenylamine
ug/L
NO
10.0
Naphthalene
ug/L
NO
5.0
Nitrobenzene
ug/L
NO
5.0
Pentachlorophenol
ug/L
NO
25.0
Phenanthrene
ug/L
NO
5.0
Phenol
ug/L
NO
5.0
Pyrene
ug/L
NO
5.0
2,4,6-Tribromophenol(S)
%
86
10-137
2-Fluorobiphenyl (S)
%
57
15-120
2-Fluorophenol (S)
%
37
10-120
Nitrobenzene-d5 (S)
%
64
10-120
Phenol-d6 (S)
%
21
10-120
Terphenyl-c!14 (S)
%
68
11-131
LABORATORY CONTROL SAMPLE:
Parameter
144459
Units
Spike
Conc.
LCS
Result
LCS
%Rec
%Rec
Limits Qualifiers
1,2-Dichlorobenzene
ug/L
50
24.8
50
32-129
1,2-Diphenyihydrazine
ug/L
50
49.7
99
25-150
1,3-Dichlorobenzene
ug/L
50
24.3
49
1-172
1,4-Dichlorobenzene
ug/L
50
24.8
50
20-124
2,4,6-Trichlorophenol
ug/L
50
37.1
74
37-144
2,44)ichlorophenol
ug/L
50
53.0
106
1-191
2,4-Dimethylphenol
ug/L
50
35.0
70
32-119
2,4-Dinitrophenol
ug/L
50
29.11.1
58
1-181
2,4-Dinitrotoluene
ug/L
50
35.8
72
39-139
2,6-Dinitrotoluene
ug/L
50
39.0
78
50-158
2-Chloronaphthalene
ug/L
50
31.2
62
60-118
2-Chiorophenol
ug/L
50
31.2
62
23-134
2-Nitrophenol
ug/L
50
37.0
74
29-182
3,3'-Dichlorobenzidine
ug/L
50
47.4
95
1-262
4,6-Dinitro-2-methylphenol
ug/L
50
39.4
79
1-181
4-Bromophenylphenyl ether
ug/L
50
48.4
97
53-127
I-Chioro-3methylphenol
ug/L
50
40.1
80
22-147
I-Chlorophenyiphenyl ether
ug/L
50
35.1
70
25-158
4-Nitrophenol
ug/L
50
181
36
1-132
'lcenaphthene
ug/L
50
37.8
76
47-145
lcenaphthylene
ug/L
50
39.5
79
33-145
tnthracene
ug/L
50
41.3
83
1-166
Benzo(a)anthracene
ug/L
50
38.0
76
33-143
lenzo(a)pyrene
ug/L
50
39.4
79
17-163
Date: 08/07/200812:48 PM REPORT OF LABORATORY ANALYSIS Page 10 of 28
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
�fielac'.

race Analytical Services, Inc. Pace Analytical Services, Inc.
2225 Riverside Dr. 9800 Kincey Ave. Suite 100
.lace Analytical Asheville, NC 28804 Huntersville, NC 28078
www.pedbbscam
[phone] [phone]
QUALITY CONTROL DATA
Project: PPA 7/24/08
Pace Project No.: 9224125
LABORATORY CONTROL SAMPLE: 144459
Parameter
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Benzo(b)fluoranthene
ug/L
50
37.0
74
24-159
Benzo(g,h,)perylene
ug/L
50
39.4
79
1-219
Benzo(k)fluoranthene
ug/L
50
47.0
94
11-162
bis(2-Chloroethoxy)methane
ug/L
50
39.9
80
33.184
bis(2-Chloroethyl) ether
ug/L
50
33.4
67
12-158
bis(2-Chloroisopropyl) ether
ug/L
50
37.9
76
36-166
bis(2-Ethylhexyl)phthalate
ug/L
50
42.1
84
8-158
Butylbenzylphthalate
ug/L
50
42.7
85
1-152
Chrysene
ug/L
50
37.9
76
17-168
Di-o-butylphthalate
ug/L
50
49.4
99
1-118
Di-noctylphthalate
ug/L
50
42.0
84
4-146
Dibenz(a,h)anthracene
ug/L
50
38.1
76
1-227
Diethylphthalate
ug/L
50
43.7
87
1-114
Dimethylphthalate
ug/L
50
38.0
76
1-112
Fluoranlhene
ug/L
50
44.4
89
26-137
Fluorene
ug/L
50
37.9
76
59-121
Hexachlorobenzene
ug/L
50
41.8
84
1-152
Hexachlorocyclopentadiene
ug/L
50
8.2.1
16
25-150 L2
Hexachloroethane
ug/L
50
25.7
51
40-113
Indeno(1,2,3-cd)pyrene
ug/L
50
38.3
77
1-171
Isophorone
ug/L
50
67.0
134
21-196
N-Nitrosodi-n-propylamine
ug/L
50
39.1
78
1-230
N-Nitrosodimethylamine
ug/L
50
31.8
64
25-150
N-Nitrosodiphenylamine
ug/L
50
48.5
97
25-150
Naphthalene
ug/L
50
32.1
64
21-133
Nitrobenzene
ug/L
50
35.8
72
35-180
Pentachlorophenol
ug/L
50
27.6
55
14-176
Phenanthrene
ug/L
50
45.6
91
54-120
Phenol
ug/L
50
13.8
28
5-112
Pyrene
ug/L
50
37.7
75
52-115
2,4,6-Tribromophenol (S)
%
100
10-137
2-Fluorobiphenyl(S)
%
72
15-120
2-Fluorophenoi (S)
%
45
1D-120
Vitrobenzened5 (S)
%
81
10-120
Phenold6 (S)
%
27
1D-120
Terphenyld14(S)
%
76
11-131
MATRIX SPIKE SAMPLE:
Parameter
144460
9224136002 Spike MS
Units Result Conc. Result
MS
% Rec
%Rec
Limits Qualifiers
1,2-Dichlorobenzene
ug/L
NO 1D0 57.1
57
32-129
1,2-Diphenylhydrazine
ug/L
NO 100 87.1
87
25-150
,3-Dichlorobenzene
ug/L
NO 100 54.5
55
1-172
,4-Dichlorobenzene
ug/L
NO 100 55.5
56
20-124
2,4,6-Trichlorophenol
ug/L
NO 100 75.9
76
37-144
".,4-Dichlorophenol
ug/L
NO 100 147
147
1-191
A-Dimethylphenol
ug/L
NO 100 66.2
66
32-119
Date: 08/07/200812:48 PM
REPORT OF LABORATORY ANALYSIS
Page 11 of28
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services. Inc..
�I I_61Qt.!i

I = Qfta7ytR71'9rWM, M.
race Analytical services, Inc.
2225 Riverside Dr.
aceAnalytical
9800 Kincey Ave. Suite 100
Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
QUALITY CONTROL DATA
Project: PPA 7/24108
Pace Project No.: 9224125
MATRIX SPIKE SAMPLE:
144460
9224136002
Spike
MS
MS
% Rec
Parameter
Units Result
Conc.
Result
% Rec
Limits Qualifiers
2,4-Dinitrophenol
ug/L
NO
100
60.3.1
60
1-181
2,4-Dinitrololuene
ug/L
NO
100
69.2
69
39-139
2,6-Dinitrotoluene
ug/L
NO
100
62.1
62
50-158
2-Chloronaphthalene
ug/L
NO
100
63.9
64
60-118
2-Chlorophenol
ug/L
NO
100
66.2
66
23-134
2-Nitrophenol
ug/L
NO
100
73.9
74
29-182
3,3'-Dichlorobenzidine
ug/L
NO
100
55.1
55
1-262
4,6-Dinitro-2-methylpherlol
ug/L
NO
100
71.5
71
1-181
4-Bromophenylphenyl ether
ug/L
NO
100
94.0
94
53-127
4-Chloro-3-methylphenol
ug/L
NO
100
81.5
82
22-147
4-Chlorophenylphenyl ether
ug/L
NO
100
77.3
77
25-158
4-Nitrophenol
ug/L
NO
100
47.5J
47
1-132
Acenaphthene
ug/L
NO
100
76.3
76
47-145
Acenaphthylene
ug/L
NO
100
75.4
75
33-145
Anlhracene
ug/L
NO
100
83.9
84
1-166
Benzo(a)anthracene
ug/L
NO
100
71.7
72
33-143
Benzo(a)pyrene
ug/L
NO
100
76.7
77
17-163
Benzo(b)fluoranlhene
ug/L
ND
100
65.0
65
24-159
Benzo(g,h,I)perylene
ug/L
NO
100
53.3
53
1-219
Benzo(k)fluoranthene
ug/L
NO
100
89.3
89
11-162
bls(2-Chloroethoxy)methane
ug/L
NO
100
77.8
78
33-184
bis(2-Chloroethyl) ether
ug/L
NO
100
72.6
73
12-158
bis(2-Chloroisopropyl) ether
ug/L
NO
100
80.8
81
36-166
bis(2-Ethylhexyl)phthalate
ug/L
NO
100
78.6
79
8-158
Butylbenzylphthalate
ug/L
NO
100
84.1
84
1-152
Chrysene
ug/L
NO
100
73.1
73
17-168
Di-n-butylphthalate
ug/L
NO
100
97.5
98
1-118
Di-noctylphthalate
ug/L
NO
100
79.5
79
4-146
Dibenz(a,h)anthracene
ug/L
NO
100
59.8
60
1-227
Diethylphthalate
ug/L
NO
100
86.9
87
1-114
Dimethylphthalate
ug/L
NO
100
76.7
77
1-112
Fluoranthene
ug/L
NO
100
85.1
85
26-137
=luorene
ug/L
NO
100
74.5
75
59-121
-lexachlorobenzene
ug/L
NO
100
81.0
81
1-152
Hexachlorocyclopentadiene
ug/L
NO
100
1111.1
11
25-150 MO
Hexachloroethane
ug/L
NO
100
58.6
59
40-113
ndeno(1,2,3-cd)pyrene
ug/L
NO
100
57.4
57
1-171
sophorone
ug/L
NO
100
131
131
21-196
N-Nitroso-di-n-propylamine
ug/L
NO
100
78.6
79
1-230
N-Nitrosodimethylamine
ug/L
NO
100
85.1
85
25-150
J-Nitrosodiphenylamine
ug/L
NO
100
82.0
82
25-150
Japhthalene
ug/L
NO
100
67.3
67
21-133
Nitrobenzene
ug/L
NO
100
70.5
70
35-180
'entachlorophenol
ug/L
NO
100
68.4
68
14-176
'henanthrene
ug/L
NO
100
86.8
87
54-120
2henol
ug/L
NO
100
44.1
44
5-112
Pyrene
ug/L
ND
100
72.9
73
52-115
!,4,6-Tribromophenol (S)
%
100
10-137
Date: 08/07/200812:48 PM
REPORT OF LABORATORY ANALYSIS
Page 12 of 28
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc

� Pab9 Analtrudifl Services, Inc. Pace Analytical Services, Inc.
f°aceAnalytical a 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
wwv.paceleDs cwn
Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone]
QUALITY CONTROL DATA
Project: PPA 7/24/08
Pace Project No.: 9224125
MATRIX SPIKE SAMPLE:
144460
9224136002 Spike MS MS
% Rec
Parameter
Units
Result Conc. Result %Rec
Limits Qualifiers
2-Fluorobiphenyl (S)
%
73
15-120
2-Fluorophenol(S)
%
59
10-120
Nitrobenzene-d5 (S)
%
81
10-120
Phenol-d6 (S)
%
41
10-120
Terphenyl-d 14 (S)
%
74
11-131
Date: 08/07/2008 12:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent
of Pace
Analytical Services. Inc..
Page 13 of 28

ese rmeiymefl aeroao M. Paae m ET111Cdl STMes, Inc.
° 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
�. aceAnalylical Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone]
QUALITY CONTROL DATA
Project: PPA 7/24/08
Pace Project No.: 9224125
QC Batch: WETA/3148 Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 9224125003
Mt I HUD BLANK: 145030
Associated Lab Samples:
9224125003
Parameter
Units
Nitrogen, Nitrate
mg/L
Nitrogen, Nitrite
mg/L
Nitrogen, NO2 plus NO3
mg/L
Blank Reporting
Result Limit Qualifiers
ND 0.10
ND 0.10
ND 0.10
LABORATORY CONTROL SAMPLE: 145031
Spike LCS LCS %Rec
Parameter Units Conic. Result %Rec Limits Qualifiers
Nitrogen, Nitrate mg/L 5 4.8 96 90-110
Nitrogen, Nitrite mg/L 1 1.0 102 90-110
Nitrogen, NO2 plus NO3 mg/L 5 4.8 96 90-110
MATRIX SPIKE SAMPLE:
145032
9224182023 Spike
MS MS %Rae
Parameter
Units
Result Conic.
Result %Rae Limits Qualifiers
Nitrogen, Nitrate
mg/L
0.12 5
5.0 97 90-110
Nitrogen, Nitrite
mg/L
ND 1
1A 106 90-110
Nitrogen, NO2 plus NO3
mg/L
0.12 5
5.0 97 90-110
MATRIX SPIKE SAMPLE:
145034
9224125003 Spike MS MS
% Rae
Parameter
Units
Result Conc. Result % Rec
Limits Qualifiers
Nitrogen, Nitrate
mg/L
16.4 5 17.7 26
90-110 M1
Nitrogen, Nitrite
mg/L
ND 1 1.1 108
90-110
Vitrogen, NO2 plus NO3
mg/L
16.4 5 17.7 26
90-110 Mt
SAMPLE DUPLICATE: 145036
Parameter
Vitrogen, Nitrate
Nitrogen, Nitrite
Nitrogen, NO2 plus NO3
Date: 08/07/2008 12:48 PM
Units
mg/L
mg/L
mg/L
9224182024 Delp
Result Result RPD Qualifiers
ND ND 0
ND ND 0
NO ND 0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
'heidC'.
Page 14 of 28

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalyticale 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
cacao peceiaescwn
Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone]
QUALITY CONTROL DATA
Project:
PPA 7/24/08
Pace Project No.:
9224125
QC Batch:
WETA13162 Analysis Method: SM 4500-CN-E
QC Batch Method:
SM 4500-CN-E Analysis Description: 450OCNE Cyanide, Total
Associated Lab Samples: 9224125003
METHOD BLANK: 145200
Associated Lab Samples: 9224126003
Blank
Reporting
Parameter
Units
Result
Limit Qualifiers
Cyanide
mg/L
NO 0.0050
LABORATORY CONTROL SAMPLE:
145201
Spike
LCS LCS % Rao
Parameter
Units
Conc.
Result %Rec Limits Qualifiers
Cyanide
mg/L
.1
0.084 84 80-120
MATRIX SPIKE SAMPLE:
Parameter
145202
Units
9224005001
Result
Spike MS MS % Rec
Conc. Result %Rec Limits Qualifiers
Cyanide
mg/L
0.0057
.1 0.094 88 75-125
SAMPLE DUPLICATE: 145203
9223857004
Dup
Parameter
Units
Result
Result RPD Qualifiers
Cyanide
mg/L
ND
ND 0
Date: 08/07/2008 12:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced. except In full,
without the written consent of Pace Analytical Services, Inc..
J
Page 15 of 28

Ace Analytical
•.�+'.vemleos can
7ma� ,� mae atE. ►aea MIIIMM S710fts Inc.
2225 Riverside Dr. 9800 Kincey Ave. Suite 10o
Asheville, NC 28804 Huntersvllle, NC 28078
[phone] (704)e75-9092
QUALITY CONTROL DATA
Project: PPA 7/24/08
Pace Project No.: 9224125
QC Batch: GCSV/3336 Analysis Method: EPA 1664A
QC Batch Method: EPA 1664A Analysis Description: 1664 HEM, Oil and Grease
Associated Lab Samples: 9224125003
Mt I HOD BLANK: 145224
Associated Lab Samples: 9224125003
Parameter
Units
Oil and Grease
mg/L
LABORATORY CONTROL SAMPLE:
145225
Parameter
Units
Oil and Grease
mg/L.
MATRIX SPIKE SAMPLE:
146226
Parameter
Units
Oil and Grease
mg/L
sate: 08/07/2008 12:48 PM
Blank Reporting
Result Umil Qualifiers
ND 5.0
Spike LCS LCS % Rec
Conc. Result %Rec Limits Qualifiers
40 38.9 97 78-114
9224125003 Spike MS MS %Rec
Result Conc. Result % Rec Limits Qualifiers
NO 40 41.5 99 78-114
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent
of Pace Analytical Services, Inc..
Page 16 of 28

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X Pace Analytical Services, Inc. Pace Analytical Services, Inc.
/ . ace Analytical • 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
wrwpcelebs.com
Asheville, NC 28804 Hunlersville, NC 28078
[phone] [phone]
QUALITY CONTROL DATA
Project: PPA 7/24108
Pace Project No.: 9224125
MATRIX SPIKE SAMPLE:
145259
9224063004
Spike
MS
MS
%Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
Calcium
ug/L
35600
5000
38300
54
70-130 M3
Chromium
ug/L
NO
500
462
92
70-130
Copper
ug/L
NO
500
494
99
70-130
Lead
ug/L
NO
500
430
86
70-130
Magnesium
ug/L
2830
5000
6920
82
70-130
Nickel
ug/L
NO
500
440
88
70-130
Selenium
ug/L
NO
500
481
96
70-130
Silver
ug/L
NO
250
239
96
70-130
Thallium
ug/L
NO
500
415
82
70-130
Zinc
ug/L
10.2
500
521
102
70-130
SAMPLE DUPLICATE: 145403
9223857007
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Antimony
ug/L
NO
NO
35 R3
Arsenic
ug/L
0.012 mg/L
12.3
4
Beryllium
ug/L
NO
.51
6
Cadmium -
ug/L
NO
AW
6
Calcium
ug/L
39.6 mg/L
42300
7
Chromium
ug/L
0.055 mg/L
57.1
4
Copper
ug/L
0.10 mg/L
110
6
Lead
ug/L
NO
NO
17
Magnesium
ug/L
3.4 mg/L
3580
5
Nickel
ug/L
0.060 mg/L
63.0
5
Selenium
ug/L
NO
NO
0
Silver
ug/L
NO
1.3.1
2
Thallium
ug/L
NO
3.2J
28 R3
Zinc
ug/L
0.70 mg/L
769
9
Date: 08/07/2008 12:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced. except in full,
without the written consent of Paw Analytical Services, Inc..
Page 18 of 28

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
2225 Riverside Dr. 9800 Kincey Ave. Suite 1o0
aceAnalytical Asheville, NC 28804 Huntersville, NC 28078
www pecnlebscum
[phone] [phone]
QUALITY CONTROL DATA
Project: PPA 7124/08
Pace Project No.: 9224125
QC Batch: WET/4851 Analysis Method: SM 2540C
QC Batch Method: SM 2540C Analysis Description: 2540C Total Dissolved Solids
Associated Lab Samples: 9224125003
Mt I NUU ISLAM: 145446
Associated Lab Samples: 9224125003
Blank Reporting
Parameter Units Result Limit Qualifiers
Total Dissolved Solids mg/L ND 20.0
LABORATORY CONTROL SAMPLE: 145447
Spike LCS LCS %Rao
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Dissolved Solids mg/L 250 270 108 80-120
SAMPLE DUPLICATE: 145448
Parameter
Total Dissolved Solids
Date: 08/07/2008 12:48 PM
9223804002 Dup
Units Result Result
mg/L 314 326
RPD Qualifiers
4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace
eerAnalytical Services, Inc..
Page 19 of 28

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
2225 Riverside Dr. 9800 Kincey Ave. Suite 100
aceAnalytical Asheville, NC 28804 Huntersville, NC 28078
www peaNees cdn
[phone] [phone]
Project: PPA 7/24/08
Pace Project No.: 9224125
QC Batch: WETA13186
OC Batch Method: EPA 350.1
Associated Lab Samples: 9224125003
METHOD BLANK: 147602
Associated Lab Samples: 9224125003
Parameter Units
Nitrogen, Ammonia mg/L
LABORATORY CONTROL SAMPLE: 147603
Parameter Units
Nitrogen, Ammonia mg/L
QUALITY CONTROL DATA
Analysis Method: EPA 350.1
Analysis Description: 350.1 Ammonia
Blank Reporting
Result Limit Qualifiers
ND 0.10
Spike LCS LCS %Rec
Conc. Result %Rec Limits Qualifiers
5 5.0 101 90-110
MATRIX SPIKE SAMPLE:
147604
9224284001
Spike
MS
MS
% Rae
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/L
0.27
5
6.0
114
90-110 MO
MATRIX SPIKE SAMPLE:
147605
9223856005
Spike
MS
MS
%Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/L
ND
5
5.5
109
90-110
SAMPLE DUPLICATE: 147606
9223813001 Dup
Parameter Units Result Result RPD Qualifiers
Nitrogen, Ammonia mg/L 0.95 0.98 3
SAMPLE DUPLICATE: 147633
Parameter
Nitrogen, Ammonia
Dale: 08/07/2008 12:48 PM
9224284002 Dup
Units Result Result
mg/L ND NO
RPD Qualifiers
100 R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced. except in full,
without the wr iten consent of Pace Analytical Services, Inc..
Page 20 of 28

� Paco Analytical Services, Inc. Pace Analytical Services, Inc.
� "eAnalytical 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
w..w pecN.esmm Asheville, NC 28804 Huntersville, NC 28078
[phone] (704)e75-9092
Project: PPA 7124/08
Pace Project No.: 9224125
OC Batch: WETA/3197
QC Balch Method: EPA 365.1
Associated Lab Samples: 9224125003
METHOD BLANK: 148313
Associated Lab Samples: 9224125003
Parameter Units
Phosphorus mg/L
QUALITY CONTROL DATA
Analysis Method: EPA 365.1
Analysis Description: 365.1 Phosphorus, Total
Blank Reporting
Result Limit Qualifiers
ND 0.10
LABORATORY CONTROL SAMPLE:
148314
Spike LCS
LCS
% Rec
Parameter
Units
Cone. Result
% Rec
Limits
Qualifiers
Phosphorus
mg/L
1 1.0
100
90-110
MATRIX SPIKE SAMPLE:
148315
9224668001 Spike
MS
MS
% Rec
Parameter
Units
Result Cone.
Result
% Rec
Limits Qualifiers
Phosphorus
mg/L
1.8 1
6.2
446
90-110 MO
MATRIX SPIKE SAMPLE:
W317
9224214012
Spike MS MS %Rae
Parameter
Units
Result
Cone. Result % Rec Limits Qualifiers
Phosphorus
mg/L
0.20
1 0.60 41 90-110 MO
SAMPLE DUPLICATE: 148316
9224668002
Dup
Parameter
Units
Result
Result RPD Qualifiers
Phosphorus
mg/L
ND
0.11 22
SAMPLE DUPLICATE: 148318
Parameter
Phosphorus
Date: 08/07/2008 12:48 PM
9224076001
Units Result
mg/L 0.42
Dup
Result RPD Qualifiers
0.37 14
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 21 of 28

� Pace Analytical Services, Inc. Pace Analytical Services, Inc.
�. Pace Analytical • 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
www.pecelebscam
Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone]
Project: PPA 7124/08
Pace Project No.: 9224125
QC Batch: MSV/4160
QC Batch Method: EPA 624
Associated Lab Samples: 9224125003, 9224125004
QUALITY CONTROL DATA
Analysis Method: EPA 624
Analysis Description: 624 MSV
METHOD BLANK: 148606
Associated Lab Samples:
9224125003, 9224125004
Blank
Reporting
Parameter
Units
Result
Limit Qualifiers
1, 1, 1 -Trichloroethane
ug/L
NO
5.0
1,1,2,2-Tetrachloroethane
ug/L
NO
5.0
1,1,2-Trichloroethane
ug/L
NO
5.0
1,1-Dichloroethane
ug/L
ND
5.0
1,1-Dichloroelhene
ug/L
NO
5.0
1,2,4-Trichlorobenzene
ug/L
NO
5.0
1,2-Dichlorobenzene
ug/L
NO
5.0
1,2-0ichloroethane
ug/L
NO
5.0
1,2-Dichloropropane
ug/L
NO
5.0
1,3-Dichlorobenzene
ug/L
NO
5.0
1,4-0ichlorobenzene
ug/L
NO
5.0
2-Chloroethylvinyl ether
ug/L
NO
10.0
Acrolein
ug/L
NO
100
Acrylonitrile
ug/L
ND
100
Benzene
ug/L
NO
5.0
Bromodichloromethane
ug/L
NO
5.0
Bromoform
ug/L
NO
5.0
Bromomethane
ug/L
NO
10.0
Carbon tetrachloride
ug/L
ND
5.0
Chlorobenzene
ug/L
NO
5.0
Chloroethane
ug/L
NO
10.0
Chloroform
ug/L
NO
5.0
Chloromethane
ug/L
NO
5.0
cis-1,3-Dichloropropane
ug/L
NO
5.0
Dibromochloromethane
ug/L
NO
5.0
Ethylbenzene
ug/L
ND
5.0
Hexachloro-1,3-butadiene
ug/L
NO
5.0
Methylene Chloride
ug/L
NO
5.0
Naphthalene
ug/L
ND
5.0
Tetrachloroethene
ug/L
NO
5.0
Toluene
ug/L
NO
5.0
trans-1,2-Dichloroethene
ug/L
ND
5.0
4rans-1,3-Dichloropropene
ug/L
NO
5.0
Trichloroethene
ug/L
NO
5.0
rrichlorofluoromethane
ug/L
NO
10.0
Vinyl chloride
ug/L
NO
5.0
1,2-Dichlorcethane-d4 (S)
%
102
70-130
4-Bromofluorobenzene (S)
e/
98
86-111
)ibromofluoromethane (S)
%
99
88-113
"oluene-d8 (S)
%
100
92-105
Date: 08/07/2008 12:48 PM REPORT OF LABORATORY ANALYSIS Page 22 of 28
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
pero)eDs
2225 Riverside Dr. 9800 Kincey Ave. Suite too
www
aceAnal .bs mn al Asheville, NC 28804 Huntersville, NC 28078
.
[phone] [phone]
QUALITY CONTROL DATA
Project: PPA 7/24/08
Pace Project No.: 9224125
LABORATORY CONTROL SAMPLE:
148607
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifier;
1,1,1-Trichloroethane
ug/L
20
21.9
109
52-162
1,1,2,2-Tetrachloroelhane
ug/L
20
21.6
108
46-157
1,1,2-Trichloroethane
ug/L
20
22.4
112
52-150
1,1-Dichloroethane
ug/L
20
21.9
110
59-155
1,1-Dichloroethene
ug/L
20
23.3
117
1-234
1,2,4-Trichlorobenzene
ug/L
20
23.0
115
70-130
1,2-Dichlorobenzene
ug/L
20
23.6
118
18-190
1,2-Dichloroethane
ug/L
20
21.4
107
49-155
1,2-Dichloropropane
ug/L
20
21.9
110
1-210
1,3-Dichlorobenzene
ug/L
20
22.7
114
59-156
1,4-Dichlorobenzene
ug/L
20
22.7
113
18-190
2-Chloroethyivinyl ether
ug/L
40
46.5
116
1-305
Aarolein
ug/L
100
115
115
15-152
Acrylonitrile
ug/L
100
129
129
75-132
Benzene
ug/L
20
22.0
110
37-151
Bromodichloromethane
ug/L
20
22.3
111
35-155
Bromoform
ug/L
20
23.2
116
45-169
Bromomethane
ug/L
20
31.7
159
1-242
Carbon tetrachloride
ug/L
20
22.6
113
70-140
Chlorobenzene
ug/L
20
22.3
112
37-160
Chloroethane
ug/L
20
25.7
129
14-230
Chloroform
ug/L
20
23.2
116
51-138
Chloromethane
ug/L
20
30.5
153
1-273
cis-1,3-Dichloropropene
ug/L
20
24.5
122
1-227
Dibromochloromethans
ug/L
20
22.3
111
53-149
Ethylbenzene
ug/L
20
21.6
108
37-162
Hexachloro-1,3-butadiene
ug/L
20
24.3
121
70-130
Methylene Chloride
ug/L
20
19.7
98
1-221
Naphthalene
ug/L
20
29.2
146
70-130 L3
Tetrachloroethene
ug/L
20
21.4
107
64-148
Toluene
ug/L
20
22.0
110
47-150
trans-1,2-Dichloroethene
ug/L
20
21.7
108
54-156
trans-1,3-Dichloropropene
ug/L
20
24.3
121
17-183
Trichloroethene
ug/L
20
22.5
113
71-157
Trichlorofluoromethane
ug/L
20
25.1
125
17-181
Vinyl chloride
ug/L
20
30.7
154
1-251
1,2-Dichloroethane-d4 (S)
%,
100
70-130
4-Bromofluorobenzene (S)
%
99
86-111
Dibromofluoromethane (S)
%
101
88-113
Toluene-d8 (S)
%
101
92-105
MATRIX SPIKE SAMPLE:
148692
9224274001 Spike MS MS
% Rec
Parameter
Units
Result Conc. Result % Rao
Limits Qualifiers
1,1,1-Trichloroethane
ug/L
ND 20 14.4 72
46-171
1,1,2,2-Tetrachloroethane
ug/L
ND 20 12.8 64
73-159 MO
1,1,2-Trichloroethane
ug/L
ND 20 14.1 70
64-152
Date: 08/07/200812:48 PM
REPORT OF LABORATORY ANALYSIS
Page 23 of 28
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
e 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
aceAnalytical Asheville, NC 28804 Huntersville, NC 28078
www pevalabs cwn
[phone] [phone]
Project: PPA 7/24/08
Pace Project No.: 9224125
MATRIX SPIKE
Parameter
QUALITY CONTROL DATA
148692
9224274001 Spike MS MS
Units Result Conc. Result % Rec
% Rec
Limits Qualifiers
1,1-Dichloroethane
ug/L
ND
20
14.5
72
43-172
1,1-Dichloroethane
ug/L
ND
20
15.5
78
48-189
1,2,4-Trichlorobenzene
ug/L
ND
20
13.0
65
70-130 MO
1,2-Dichlorobenzene
ug/L
ND
20
14.2
71
54-154
1,2-Dichloroethane
ug/L
ND
20
13.9
70
42-171
1,2-Dichloropropane
ug/L
ND
20
14.6
73
55-157
1,3-Dichlorobenzene
ug/L
ND
20
13.8
69
57-148
1,4-Dichlorobenzene
ug/L
ND
20
13.7
68
58-149
2-Chloroethylvinyl ether
ug/L
ND
40
2.7J
7
70-130 P5
Acrolein
ug/L
ND
100
ND
76
70-130
Acrylonitrile
ug/L
ND
100
ND
72
70-130
Benzene
ug/L
ND
20
14.6
73
54-163
Bromodichloromethane
ug/L
ND
20
14.8
74
56-152
Bromoform
ug/L
ND
20
13.4
67
53-151
Bromomethane
ug/L
ND
20
22.9
114
10-200
Carbon tetrachloride
ug/L
ND
20
15.1
75
41-175
Chlorobenzene
ug/L
ND
20
14.5
72
67-152
Chloroethane
ug/L
ND
20
18.8
94
23-200
Chloroform
ug/L
ND
20
14.8
74
51-166
Chloromethane
ug/L
ND
20
20.8
104
40-175
cis-1,3-Dichloropropene
ug/L
ND
20
16.2
81
38-146
Dibromochloromethane
ug/L
ND
20
13.5
68
65-144
Ethylbenzene
ug/L
ND
20
14.1
71
57-152
Hexachloro-1,3-butadiene
ug/L
ND
20
14.1
71
70-130
Methylene Chloride
ug/L
ND
20
13.0
63
40-167
Naphthalene
ug/L
ND
20
14.7
74
70-130
Tebachloroethene
ug/L
ND
20
14.2
71
59-155
Toluene
ug/L
ND
20
14.5
72
47_162
trans-1,2-Dichloroethene
ug/L
ND
20
14.3
72
47-178
Vans-1,3-Dichloropropene
ug/L
ND
20
15.4
77
39-148
TrIchlomethene
ug/L
ND
20
14.8
74
60.153
Trichlorofluoromethane
ug/L
ND
20
16.7
83
42-199
Vinyl chloride
ug/L
ND
20
21.0
105
46-176
1,2-Dichloroethane-d4 (S)
%
98
70-130
4-Bromo0uorobenzene (S)
%
99
86-111
Dibromo0uoromelhane (S)
%
99
88-113
Toluene-d8 (S)
%
101
92-105
SAMPLE DUPLICATE: 148711
9224214014 Dup
Parameter
Units Result Result RPD
Qualifiers
1,1,1-Trichloroethane
ug/L
ND ND
0
1,1,2,2-Tetrachloroethane
ug/L
ND ND
0
1,1,2-Trichloroelhane
ug/L
ND ND
0
1,1-Dichloroethane
ug/L
ND ND
0
1,1-Dichloroethene
ug/L
ND ND
0
1,2,4-Trichlorobenzene
ug/L
ND ND
0
Date: 08/07/2008 12:48 PM
REPORT OF LABORATORY ANALYSIS
Page 24 of 28
This report shall not be reproduced. except in full,
without the written consent of PaceAnalyticalAnalytical Services, Inc

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
e 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
aceAnalytical Asheville. NC 28804 Huntersville, NC 28078
+Mss'WMebs mn
[phone] [phone]
QUALITY CONTROL DATA
Project: PPA 7/24/08
Pace Project No.: 9224125
SAMPLE DUPLICATE: 148711
9224214014
Dup
Parameter
Units
Result
Result
RPD Qualifiers
1,2-Dichlorobenzene
ug/L
NO
NO
0
1,2-Dichloroethane
ug/L
NO
NO
0
1,2-Dichloropropane
ug/L
NO
NO
0
1,3-Dichlorobenzene
ug/L
NO
NO
0
1,4-Dichlorobenzene
ug/L
NO
NO
0
2-Chloroethylvinyl ether
ug/L
NO
NO
0
Acrolein
ug/L
NO
NO
0
Acrylonitrile
ug/L
NO
NO
0
Benzene
ug/L
NO
NO
0
Bromodichloromethane
ug/L
NO
NO
0
Bromoform
ug/L
NO
NO
0
Bromomethane
ug/L
NO
NO
0
Carbon tetrachloride
ug/L
NO
NO
0
Chlorobenzene
ug/L
NO
NO
0
Chloroethane
ug/L
NO
NO
0
Chloroform
ug/L
NO
ND
1
Chloromethane
ug/L
NO
NO
0
cis-1,3-Dichloropropene
ug/L
NO
ND
0
Dibromochloromethane
ug/L
NO
ND
0
Ethylbenzene
ug/L
NO
ND
29
Hexechloro-1,3-butadiene
ug/L
NO
ND
0
Methylene Chloride
ug/L
NO
ND
200
Naphthalene
ug/L
NO
NO
200
Tebachloroethene
ug/L
NO
ND
0
Toluene
ug/L
7.6
5.2
38 R3
trans-1,2-Dichloroethene
ug/L
NO
ND
0
trans-1,3-Dichloropropene
ug/L
NO
ND
0
Trichloroethene
ug/L
NO
NO
0
Trichlorolluoromethane
ug/L
NO
ND
0
Vinyl chloride
ug/L
NO
ND
0
1,2-Dichloroethane-d4 (S)
%
102
98
4
4-13romofluorobenzene(S)
%
100
96
4
Dibromocuoromethane (S)
%
98
95
3
Toluene-d8 (S)
%
100
99
1
Date: 08/07/2008 12:48 PM REPORT OF LABORATORY ANALYSIS Page 25 of 28
This report shall not be reproduced, except in full,
without the written consent of
Pace
Analytical Services, Inc..

rncu A a' to oelvit9s, io. Pace Analytical Serviaee, Inc.
aceAnalytical 2225 Riverside Dr, 9800 Kincey Ave. Suite too
wrw,perola�:.am Asheville, NC 28604 Hunlersville, NC 28078
[phone] [phone]
Project: PPA 7124/08
Pace Project No.: 9224125
OC Batch: WETA/3202
OC Batch Method: EPA 351.2
Associated Lab Samples: 9224125003
METHOD BLANK: 148642
Associated Lab Samples: 9224125003
Parameter Units
Nitrogen, Kjeldahl, Total mg/L
QUALITY CONTROL DATA
Analysis Method: EPA 351.2
Analysis Description: 351.2 TKN
Blank Reporting
Result Limit Qualifiers
ND 0.50
LAttUKA I UKY UUNTROL SAMPLE:
148643
Spike LCS
LCS
%Rec
Parameter
Units
Conc. Result
%Rec
Limits
Qualifiers
Nitrogen, Kjeldahl, Total
mg/L
5
5.4
108
90-110
MATRIX SPIKE SAMPLE:
148644
9224261001
Spike
MS
MS
% Rec
Parameter
Units
Result
Cone.
Result
%Rec
Limits Qualifiers
Nitrogen, Kjeldahl, Total
mg/L
1.1
5
7.1
120
90-110 Mo
MATRIX SPIKE SAMPLE:
148646
9224082002
Spike
MS
MS
% Rec
Parameter
Units
Result
Cone.
Result
%Rec
Limits Qualifiers
Nitrogen, Kjeldahl, Total
hill
1.3
5
6.8
110
90-110
SAMPLE DUPLICATE: 148645
9224261002
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Nitrogen, Kjeldahl, Total
mg/L
1.4
1.4
.4
SAMPLE DUPLICATE: 148647
9224126003 Dup
Parameter Units Result Result RPD Qualifiers
Nitrogen, Kjeldahl, Total mg/L 2.4 2A .7
gate: 08/07/2008 12:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 26 of 28

race Analyticai Services, Inc. Pace Analytical Services, Inc.
a 2225 Riverside Dr. 980010nce Ave. Suite 100
ace Analytical wwwpecNebSAsheville, NC 28804 Huntersville, NC 28078
..mn
[phone] [phone]
QUALITY CONTROL DATA
Project:
PPA 7/24/08
Pace Project No.:
9224125
OC Batch:
WETA13206 Analysis Method: EPA 420.4
QC Batch Method:
EPA 420.4 Analysis Description: 420.4 Phenolics
Associated Lab Samples: 9224125003
METHOD BLANK: 148704
Associated Lab Samples: 9224125003
Blank
Reporting
Parameter
Units
Result
Limit Qualifiers
Phenol
mglL
ND 0.010
LABORATORY CONTROL SAMPLE:
148705
Spike
LCS LCS % Rec
Parameter
Units
Conc.
Result % Rec Limits Qualifiers
Phenol
m9/L
.25
0.24 96 90-110
MATRIX SPIKE SAMPLE: 148706
9223907002 Spike MS MS % Rec
Parameter Units Result Conc. Result % Rec Limits Qualifiers
Phenol mg/L NO .25 0.24 90 90-110
SAMPLE DUPLICATE: 148707
Parameter Units
Phenol mg/L
Uate: 08/07/2008 12:48 PM
9224007001 Dup
Result Result RPD Qualifiers
ND ND 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced. except in full,
without the written consent
of Pace
eerAnalytical Services, Inc..
�1L1GKN.,:
Page 27 of 28

Fn%Nnillyfful Semmes, Inc. Pace Analytical Services, Inc.
ace Analytical a 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
xww.pemleba.can Asheville. NC 28804 Hunlersville, NC 28078
[phone] [phone]
QUALIFIERS
Project: PPA 7/24/08
Pace Project No.: 9224125
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
NO - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable,
Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes
ANALYTE QUALIFIERS
L2 Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated
samples may be biased low.
L3 Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in
associated samples. Results unaffected by high bias.
MO Matrix spike recovery was outside laboratory control limits.
Mt Matrix spike recovery exceeded OC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M3 Matrix spike recovery was outside laboratory control limits due to matrix interferences.
P5 The EPA or method required sample preservation degrades this compound, therefore acceptable recoveries may not be
achieved in sample matrix spikes.
Rt RPD value was outside control limits.
R3 RPD value was outside control limits due to uncertainty of values at or near the PRL.
Ovate: 08/07/2008 12:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
`rh�C
Page 28 of 28

! :H, )F- f0_ _ . _AnL-,—. al .-_.,jes tun
FaeeAnalytieal The Chainaf-Custody is a LEGAL DOCUMENT. All relevant fields must he completed accurately.
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Pace F,Vd.#:
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SAMPLE CONDITIONS
SAMPLER NAME AND SIGNATURE
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Subcontracted Results
Pace Project #
9)aq/aS
This report includes
page 1 to

PaceAnalytical
.;xice/abs ccm
August 06, 2008
Lord Patton
Pace Analytical Ashville
2225 Riverside Dr.
Asheville, NC 28804
RE: Project: 9224125 PPA 7/24/08
Pace Project No.: 406865
Dear Lord Patton:
Pace Anatytical Services, Inc.
1241 Bellevue Street
Green Bay, WI 54302
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on July 25, 2008. The
results relate only to the samples included in this report. Results reported herein conform to the
most current NELAC standards, where applicable, unless otherwise narrated in the body of the
report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Eric Wied
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent
of Pam Analytical Services, Inc..
1 LG C
Page 1 of 9

PaceAnalytical
av wpe[elabs x,
CERTIFICATIONS
Project: 9224125 PPA 7/24/08
Pace Project No.: 406865
Pace Analytical Services, Inc.
1241 Bellevue Street
Green Bay, WI 54302
[phone]
Green Bay Certification IDs
Florida (NELAP) Certification #: E87948
South Carolina Certification #: 83006001
Illinois Certification #: 200050
Wisconsin Certification M 405132750
New York Certification #: 11888
Wisconsin DATCP Certification It: 105444
North Dakota Certification #: R-150
Kentucky Certification #: 82
North Carolina Certification It: 503
Louisiana Certification #: 04168
Minnesota Certification #: 055-999-334
Green Bay Volatiles Certification IDa
Florida (NELAP) Certification #: E87951
South Carolina Certification #: 83006001
Illinois Certification #'. 200051
Wisconsin Certification #: 405132750
New York Certification #: 11887
Wisconsin DATCP Certification #: 105-444
North Dakota Certification #: R-200
Kentucky Certification #: 83
North Carolina Certification #: 503
Louisiana Certification #: 04169
Minnesota Certification #: 055-999-334
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Mhout the written consent of PPaam Analytical Services, Inc..
:'neln
Page 2 of 9

72ceAnapical
NMW p9[PId�S.COT
SAMPLE SUMMARY
Project: 9224125 PPA 7/24108
Pace Project No.: 406865
Lab ID
Sample ID
Matrix
Date Collected
9224125001
9224125002
FIELD BLANK
WASTEWATER EFFLUENT LLHG
Water
Water
0712410807:50
07124/0807:50
REPORT OF LABORATORY ANALYSIS
Date Received
07/25/08 11:00
07/25/08 11:00
This report shall not be reproduced, except in full,
without the written consent of Pace/.Analytical Services, Inc..
Pace Analytical Services, Inc.
1241 Bellevue Street
Green Bay, WI 54302
[phone]
Page 3 of 9

aceAnalj6cal e
awwpecelabs.wm
SAMPLE ANALYTE COUNT
Pace Analytical Services, Inc.
1241 Bellevue Street
Green Bay, Wt 54302
[phone]
Project:
9224125 PPA 7/24/08
Pace Project No.:
406865
Analytes
Lab ID
Sample ID
Method Analysts Reported
Laboratory
9224125001
FIELD BLANK
EPA 1631E GMW 1
PASI-G
9224125002
WASTEWATER EFFLUENT LLHG
EPA 1631E GMW 1
PASI-G
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Paw Arlwybcal Services, Inc..
Page 4 of 9

aceAnalytical'
NNM1¢p cebb3tvrn
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
1241 Bellevue Street
Green Bay, WI 54302
[phone]
Project: 9224125 PPA 7124/O8
Pace Project No.: 406865
Sample: FIELD BLANK Lab ID: 9224125001 Collected: 07124/O8 07:50 Received: 07/25/08 11:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1631E Mercury, Low Level Analytical Method: EPA 1631E Preparation Method: EPA 1631E
Mercury 0.269J ng/L 0.50 1 07/29/08 08:30 08/04/08 10:14 7439-97-6
Date: 08/0612008 02:30 PM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wnllen consent of Paw Analytical Services, Inc..
�11G14�..5
Page 5 of 9

;aceAnalylical j
w ;vicelatistom
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
1241 Bellevue Street
Green Bay, WI 54302
[phone]
Project: 9224125 PPA 7124/08
Pace Project No.: 406865
Sample: WASTEWATER EFFLUENT Lab ID: 9224125002 Collected: 07/24/08 07:50 Received: 07/25/08 11.00 Matrix. Water
LLHG
Parameters
1631E Mercury, Low Level
Mercury
Date: 081062008 D2:30 PM
Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Analytical Method: EPA 1631 E Preparation Method: EPA 1631E
4.14 ng/L 0.50 1 07/29/08 08:30 08/04/08 10.34 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace
Analytical Services, Inc..
[LIDO
Page 6 of 9

'//�Analytical •
VG
�x0e�*ee4cdn
Project: M4125 PPA 7/24/08
Pace Project No.: 406065
QC Batch: CVFS/1170
QC Batch Method: EPA 1631E
Associated Lab Samples: 9224125001, 9224125002
METHOD BLANK: 60203
Associated Lab Samples: 9224125001, 9224125002
Parameter Units
Mercury ng/L
QUALITY CONTROL DATA
Analysis Method: EPA 1631E
Analysis Description 1631 E Mercury
Blank Reporting
Result Limit Qualifiers
0.204J 0.50
METHOD BLANK: 60204
Associated Lab Samples: 9224125001, 9224125002
Blank Reporting
Parameter Units Result Limit Qualifiers
Mercury n9/L 0.393J 0.50
METHOD BLANK: 60205
Associated Lab Samples: 9224125001, 9224125002
Blank Reporting
Parameter Units Result Limit Qualifiers
Mercury ng/L NO 0.50
Pace Analytical Services, Inc.
1241 Bellevue Street
Green Bay, WI 54302
[phone]
LABORATORY CONTROL SAMPLE & LCSD: 60206
60207
Spike
LCS
LCSD
LCS LCSD % Rec Max
Parameter Units
Cone.
Result
Result
% Rec % Rec Limits RPD RPD Qualifiers
Mercury ng/L
5
6.33
5.24
107 105 79-121 2 24
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 60208
60209
MS
MSD
406783001
Spike
Spike
MS
MSD MS MSD % Rec Max
Parameter Units Result
Cone.
Cone.
Result
Result % Rec % Rec Limits RPD RPD Qual
Mercury ng/L 4,88
20
20
28.1
25.8 116 104 75-125 9 24
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 60210
60211
MS
MSD
406785001
Spike
Spike
MS MSD MS MSD %Rec Max
Parameter Units Result
Cone,
Cone.
Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ng/L 2.68
10
10
13.3 13.3 106 106 75-125 .01 24
Dale: 08/06/2008 02:30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
w4houl the written consent of Patx/
s.Analocal Services, Inc-
f1.6 Mae.
Page 7 of 9

PaceAnalytical t
a oscelabs cam
QUALIFIERS
Project: 9224125 PPA 7/24/08
Pace Project No.: 406865
DEFINITIONS
Pace Analytical Services, Inc.
1241 Bellevue Street
Green Bay, WI 54302
[phone]
OF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes.
LABORATORIES
PAST-G Pace Analytical Services - Green Bay
Date: 08/06/2008 02:30 PM REPORT OF LABORATORY ANALYSIS Page 8 of 9
This report shall not be reproduced, except in full,
without the written consent of Pam
/+Analytical Services, Inc..

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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: 9224125 PPA 7124108
Pace Project No.: 406865
Pace Analytical Services, Inc.
1241 Bellevue Street
Green Bay, WI 54302
[phone]
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
9224125001
9224125002
FIELD BLANK
WASTEWATER EFFLUENT LLHG
EPA 1631E
EPA 1631E
CVFS/1170
CVFS/1170
EPA1631E
EPA 1631E
Analytical
Batch
CVFS/1171
CVFS/1171
Date: 08/06/2008 07,30 PM REPORT OF LABORATORY ANALYSIS Page 9 of 9
This report shall not be reproduced, except in full,
without the Written consent of Pace
+Analytical Services, Inc..

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