WQ0011431_2023 Residual Annual Report_20240221 (2)

Initial Review
Reviewer
nathaniel.thorn burg
Is this submittal an application? (Excluding additional information.) *
Yes No
If not an application what is the submittal type?* Annual Report
Residual Annual Report
Additional Information
Other
Annual Report Year* 2023
Permit Number (IR) * WQ0011431
Applicant/Permittee Town of Cleveland
Email Notifications
Does this need review by the hydrogeologist? * Yes No
Regional Office Mooresville
CO Reviewer
Admin Reviewer Wanda Gerald

Submittal Form
Project Contact Information
Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence.
Name* Rob Willcox
Email Address*
[e-mail]
Project Information
Application/Document Type*
New (Fee Required)
Modification - Major (Fee Required)
Renewal with Major Modification (Fee
Required)
Annual Report
Additional Information
Other
Phone Number*
3363399128
Modification - Minor
Renewal
GW-59, NDMR, NDMLR, NDAR-1,
N DAR-2
Residual Annual Report
Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:* Wastewater Irrigation High -Rate Infiltration
Other Wastewater Reclaimed Water
Closed -Loop Recycle Residuals
Single -Family Residence Wastewater Other
Irrigation
Permit Number:* WQ0011431
Has Current Existing permit number
Applicant/Permittee Address* Post Office Box 429; Cleveland, N.C. 27013
Facility Name* Town of Cleveland Class B Residuals Program
Please provide comments/notes on your current submittal below.
2023 Annual Report - Town of Cleveland - Permit No. WQ0011431
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.
(Application Form, Engineering Plans, Specifications, Calculations, Etc.)
2023 ANNUAL REPORT -Town of Cleveland -Permit No.
24.67MB
WQ0011431.pdf
Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger
than upload limit.
* By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has
been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the
North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts
of the application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
Signature
Submission Date 2/21/2024

2023 ANNUAL REPORT
TOWN OF CLEVELAND
RESIDUALS LAND APPLICATION PROGRAM
NON -DISCHARGE PERMIT #WQ0011431
Prepared For:
Bio-Green Services, Inc.
383 Potts Road
Advance, North Carolina 27006
Compiled By:
Willcox & Mabe Soil Solutions, PLLC
7231 B Summerfield Road
Summerfield, North Carolina 27358
February 2024

�Wlt W6100
SOIL SOLUTIONS,
February 21, 2024
N.C. Department of Environmental Quality
Division of Water Resources — Information Processing Unit
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
Attention: Information Processing Unit
Reference: 2023 LAND APPLICATION ANNUAL REPORT
Town of Cleveland
Non -Discharge Permit No. WQ0011431
WMSS Project No. 15-03 Phase: 01
Information Processing Unit:
Willcox & Mabe Soil Solutions, PLLC (WMSS) is submitting all monitoring and reporting
requirements as specified in the above referenced permit on behalf of the Town of
Cleveland and Bio-Green Services, Inc. (Bio-Green). WMSS compiled this report using
data gathered during the compliance year by the Town of Cleveland and Bio-Green. This
data includes: 1) land application certification forms, 2) annual residual sampling summary
forms, 3) annual pathogen and vector attraction reduction forms, 4) annual field summary
forms and metals field loading summary forms, 5) lab sheets, and 6) soil analysis reports.
Bio-Green land applied a total of 9.84 dry tons of biosolids for the Town of Cleveland under
Permit No. WQ0011431 during the 2023 calendar year.
If there is any further information required or questions regarding this annual report please
do not hesitate to contact Mr. Ray Gambill with Bio-Green at [phone] or Rob
Willcox with WMSS for further assistance.
Sincerely,
Willcox & Mabe Soil Solutions, PLLC
Martin Mabe
Agronomist/Partner
Enclosures
Rob Willcox, L.S.S.
Soil Scientist/Partner
Shared\WMSS Projects\2015\15-03 Bio-Green Services\Town of Cleveland\2023 Annual Report\2023 ANNUAL REPORT -Town of Cleveland -
Permit No. WQ0011431.doc
Willcox & Mabe Soil Solutions, PLLC / 7231 B Summerfield Road / Summelfield, NC 27358 / Rob 336.339.9128 or
Martin 336.312.1396 / www.willcoxmabesoil.com

TABLE OF CONTENTS
SECTION NO. TITLE
Annual Land Application Certification Form
(Form ACF)
II Annual Residual Sampling Summary Form
(Form RSSF)
III Annual Pathogen and Vector Attraction Reduction Form
(Form PVRF 503)
IV Annual Land Application Field Summary Forms and Annual
Metals Field Loading Summary Forms
(Form FSF and MFLSF)
V Lab Sheets
VI Soil Analysis Reports

Bio-Green Services, Inc.
383 Potts Road
Advance, North Carolina 27006
TOWN OF CLEVELAND
RESIDUALS LAND APPLICATION PROGRAM
CLASS B RESIDUALS
PERMIT NO. WQ0011431
TOWN OF CLEVELAND WWTP
NON -DISCHARGE PERMIT NO. WQ0011431
2023 Town of Cleveland WWTP Dry Tons - 9.84
2023 Town of Cleveland WWTP Dry Metric Tons - 8.93

SECTION I
ANNUAL LAND APPLICATION CERTIFICATION FORM
(Form ACF)

WQ Permit#: WQOO 11431 County: Rowan Year: 2023
Facility Name (as shown on permit): Town of Cleveland
Land Application Operator: Bio-Green Services, Inc. Phone: [phone]
Land application of residuals, as allowed by the permit occurred during the past calendar year?
El Yes M No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Total number of 2p2lication fields in the permit: I I
Total number of fields utilized for land application during the year:
Total amount of dry tons applied during the year for all application sites: 9.84
Total number of acres utilizes for land application during the year: 10
Part B - Annual Compiance Statement:
Facility was compliant during calendar year 2023 with all conditions of the land application permit
(including but not limited to items 1-13 below) issued by the Division of Water Resources. B Yes [3 No
If no please, provide a written description why the facility was not compliant, the dates, and explain corrective
action taken.
1) Only residuals approved for this permit were applied to the permitted sites.
2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or
the limit specified in the pen -nit.
3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies
of laboratory results are attached.
4) Annual TCLP analysis (if required) was perfonned and three (3) copies of certified laboratory results are attached.
5) All other monitoring was performed in accordance with the permit and reported during the year as required and three
(3) copies of certified laboratory results are attached.
6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T.1 105(a) or the Pollutant
Loading Rates in 15A NCAC 02T.1 105(b) (applicable to 40 CFR Part 503 regulated facilities),
7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part
503 regulated facilities).
8) All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part
503 regulated facilities).
9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior
authorization was received from the Division of Water Resources.
10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations.
11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as
specified in the permit,
12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred,
13) All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C - Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate,
and complete. I am aware that there are significant penalties for submitti false information, including the
possibility of fines and imprisonment for knowing violations." 17/ J 1/Z 11
Patrick Phifer, Mayor
Permittee Name and Title (type or print) Signature of Permitt6 Date
�0 2/20/24
Signature of Preparer* Date Signature of Land Applier Date
(if different from Permittee) (if different from Permittee and Preparer)
Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26)
DENR FORM A (12/2006)

SECTION II
ANNUAL RESIDUAL SAMPLING SUMMARY FORM
(Form RSSF)

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SECTION III
ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM
(Form PVRF 503)

1111111111:11111111 1101111''
OEM=,
Facility Name: Town of Cleveland WQ Permit Number: WQOO 114 -)1
WWTP Name: Cleveland WWTP NPDES Number: NCO049867
Monitoring Period: From 1/1/2023 To 12/31/2023
Pathogen Reduction (40 CFR 503.32) - Please indicate level achieved and alternative performed:
Class A:
T—Alternative 1 0
Alternative 2 Alternative 3 El
I Alternative 4 0
-0
�—Alternative 5 []--[— Alternative 0
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost 01
Fleat Drying 11
Heat Treatment 0
Therrnophilie 0
Beta Ray El
Gamma Ray 13
Pasteurization 11-4—
Class B:
Alternative I El
Alternative 2 -----T-
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization 0
[—Air Drying®
Com2osting 0 _ ]Aerobic
Digestion 13
Anaerobic Digestion El
I
If applicable to alternative performed (Class A or Class B) complete the following
monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
N umber 01
Excee-
dences
Frequency
of Analysis
Sample
Type
AnalTical
Tech-
nimio.
Minimurr
Geo. Mean
Maxirnun�
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
17,557
29,948
39,370
MPN/gram0
Annual
Grab
SM92210E
CFU
1000 mpn per gram
of total solid (dry
wei ht)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (40 CFR 503.33) - Please indicate option performed:
Alt. I (VS reduction) 0
Alt. 2 (40-day bench) 0
Alt. 3(330-daybench) 0
1 Alt. 4 (Spec. 02 uptake) [J
Alt, 5 (14-Day Aerobic) C
Alt. 6 (Alk. Stabilization E]
Alt 7 (Drying - Stable) 1:1
Alt. 8 (Drying - Unstable) EJ
Alt, 9 (Injection)
Alt, 10 (Incorporation) [I
No vector attraction reduction alternatives were performed 0
CERTIFICATION STATEMENT (please check the appropriate statement)
El "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have been met."
El "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check
this statement attach an explanation why you have not met one or both of the requirements.)
"'This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Patrick Phifer, Mayor
Prepare a e and T* e type or print) Land Applier Name and Title (if applicable)(type or print)
Signature of PrcpA'r* Date Signature of Land Applier (if applicable)
*Preparer is defined in 40 CFR Part 503,9(r) and 15A NCAC 2T.1 102 (26)
Date
DENR FORM PVRF 503 (1212006)

SECTION IV
ANNUAL LAND APPLICATON FIELD SUMMARY FORM
ANNUAL METALS LOADING SUMMARY FORM
(Form FSF and MFLSF)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Town of Cleveland
WQ0011431
Town of Cleveland Owner:
10 Acres Permitted:
Total Dry Tons Applied (Annual):
Cation Exchange Capacity (non 503 only):
Town of Cleveland Predominant Soil Series:
10 Site #: NC-RA-01 Field #:
9.84
Enon
1
Residual Analvsis Data (Heavv Metals and Total Phosphorus use m2/k2, % Solids use Raw Percent ft
Sample or
Com-
posite
Date
......1......
2.....
31
7/11/23
.....4.....
5....
7/11/23
6.....
7/11/23
..........
8.....
7/11/23
.....9.....
1......
11
7/11/23
12
% Solids
1
0.61
1
0.61
0.61
1
0.61
0.61
Arsenic
0.986
0.986
0.986
0.986
0.986
Cadmium
0.443
0.443
0.443
0.443
0.443
Copper
4.85
4.85
4.85
4.85
4.85
Chromium
Lead
0.443
0.443
0.443
0.443
0.443
Mercury
2.84
2.84
2.84
2.84
2.84
Molyb-
denum
0.443
0.443
0.443
0.443
0.443
Nickel
0.443
0.443
0.443
0.443
0.443
Selenium
0.443
0.443
0.443
0.443
0.443
Zinc
11.6
11.6
11.6
11.6
11.6
Total
Phos-
horus
145
145
145
145
145
Annual Heavv N1etal Wield Loadings (Ualculatecl in lbs/acre):
Total
1
2.....
37.....4.....
5.
6.....
77
8.....
1..0....
11.....
1.2....
DT/Ac./
.....9.....
0
App.
Event
2.518
1.831
0.572
2.404
2.518
Arsenic
0.000
0.000
0.005
0.000
0.004
0.001
0.000
0.005
0.000
0.000
0.005
0.000
0.019
Cadmium
0.000
0.000
0.002
0.000
0.002
0.001
0.000
0.002
0.000
0.000
0.002
0.000
0.009
Copper
0.000
0.000
0.024
0.000
0.018
0.006
0.000
0.023
0.000
0.000
0.024
0.000
0.095
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.000
0.000
0.002
0.000
0.002
0.001
0.000
1 0.002
0.000
0.000
0.002
0.000
1 0.009
Mercury
0.000
0.000
0.014
0.000
0.010
0.003
0.000
0.014
0.000
0.000
0.014
0.000
0.056
Molyb-
0.000
0.000
0.002
0.000
0.002
0.001
0.000
0.002
0.000
0.000
0.002
0.000
0.009
denum
Nickel
0.000
0.000
0.002
0.000
0.002
0.001
0.000
0.002
0.000
0.000
0.002
0.000
0.009
Selenium
0.000
0.000
0.002
0.000
0.002
0.001
0.000
0.002
0.000
0.000
0.002
0.000
0.009
Zinc
0.000
0.000
0.058
0.000
0.042
0.013
0.000
1 0.056
0.000
0.000
0.058
0.000
0.228
Total
Phos-
0.000
0.000
0.730
0.000
0.531
0.166
0.000
0.697
0.000
0.000
0.730
0.000
2.854
horus
­i certuy, unaer penalty of iaw, tnat tnis aocument was preparea unaer my airection or supervision in accoraance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
2/20/24
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

SECTION V

CLEVELAND WWTP
LAND APPLICATION PROGRAM
RESIDUALS ANALYSIS
Residual Type: Wastewater Treatment Plant
Date Sampled: July 11, 2023
Date Reported: August 29, 2023
Cleveland WWTP Permit No. WQ0011431
Mineralization Rate 0.3 0.61 % Solids
6.42 pH
Parameter
%
Mg/Kg Dry Weight
(% x 10,000)
Pounds/Dry Ton
[-....(Mg/Kg x 0.002)
Nitrogen (TKN)
0.029
292.000
0.584
Phosphorus
0.015
145.000
0.290
Potassium
0.003
33.000
0.066
PAN (injected)*
0.015
149.170
0.298
PAN (surface)*
0.015
149.120
0.298
Ammonia Nitrogen
0.000
0.100
0.000
Calcium
0.029
286.000
0.572
Calcium Carbonate Eq.
---
---
---
Magnesium
---
23.200
0.046
Sodium
---
318.000
0.636
Sulfur
---
___
Nitrate N / Nitrite N
---
61.500
0.123
Barium
Chloride
---
---
---
___
SAR
0.38
Iron
---
---
---
Ceiling Concen.
(Mg/Kg)
Aluminum
---
190.00
0.380
Arsenic
---
0.986
---
75
Cadmium
---
0.443
0.001
85
Chromium
---
___
Copper
---
4.85
0.010
4,300
Lead
---
0.443
0.001
840
Mercury
---
2.840
---
57
Molybdenum
---
0.443
---
75
Nickel
---
0.443
0.001
420
Selenium
---
0.443
---
100
Zinc
---
11.60
0.023
7,500
Envirochem 2023-14601
*Determination of Plant Available Nitrogen (PAN):
Injected Application:
(Mineralization Rate)(TKN-Ammonia N) + Ammonia N + Nitrate N + Nitrite N = % PAN
Surface Application:
(Mineralization Rate)(TKN-Ammonia N) + (0.5)(Ammonia N) + Nitrate N + Nitrite N = % PAN
Note: Constituents N.D. (Not Detected) or < detection limits are listed as detection limits
for calculation purposes.

Bio Green
383 Pott's Road
Advance NC 28112
Attention: Daniel Burgess
Revised Report: Aug 29, 2023
Original Report Date: Aug 25, 2023
Report #: 2023-14601
Customer ID: 23070070
Project ID: Cleveland
Lab ID Sample ID:
Collect Date/Time Matrix Sampled by
23-36258 Site: Cleveland
7/11/2023
3:00 PM Solid/Sludge Client
Test
Method
Results
Date Analyzed
PAN Used 30% Mineralization Rate.
Calculation
149 mg/kgi
08/21/2023
SAR
Calculation
4.85
08/21/2023
Aluminum
EPA 200.7, Rev. 4A, 1994
190 mg/kg
08/16/2023
Arsenic
EPA 200.7, Rev. 4.4, 1994
0.986 mg/kg
08/16/2023
Cadmium
EPA 200.7, Rev. 4.4,1994
<0.443 mg/kg
08/16/2023
Lead
EPA 200.7, Rev. 4.4, 1994
<0.443 mg/kg
08/16/2023
Molybdenum
EPA 200.7, Rev. 4.4, 1994
<0.443 mg/kg
08/1612023
Nickel
EPA 200.7, Rev. 4.4, 1994
<0.443 mg/kg
08/16/2023
Selenium
EPA 200.7, Rev. 4.4, 1994
<0.443 mg/kg
08/16/2023
Nitrate+Nitrite-Nitrogen
EPA 353.2
61.5 mg/kg
08/15/2023
Ammonia Nitrogen
SM 4500 NH3 C-2011
<0.1 mg/kg
08/17/2023
Total Kjeldahl Nitrogen (TKN)
SM 4500 Norg B-201 1
292 mg/kg
08/17/2023
Mercury
SW-846 74718
<2.84 mg/kg
08/22/2023
=L=�
Calcium
EPA 200.7
286 mg/kg
08/01/2023
Copper
EPA 200.7
4.85 mg/kg
08/01/2023
Magnesium
EPA200.7
23.2 mg/kg
08/01/2023
Potassium
EPA 200.7
33.0 mg/kg
08/01/2023
Sodium
EPA200.7
318 mg/kg
08/16/2023
Zinc
EPA 200.7
11.6 mg/kg
08/01/2023
Total Solids (%)
SM 2540 B
0.61%
07/14/2023
Total Phosphorus
SM 4500 P F
145 mg/kg
07/2512023
pH
Resuft estimated.
SW 846 Method 9045D
Analyzed out of 15 minutes hold time.
6.42 units
07/21/2023
Report #:: 2023-14601 Page 1 of 2

Blo Green Revised Report: Aug 29, 2023
383 Pott's Road Original Report Date: Aug 25, 2023
Advance NC 28112 Report #: 2023-14601
Attention: Daniel Burgess Customer ID: 23070070
Project ID: Cleveland
Comment: Results, except pH, reported on a dry weight basis. pH reported on an as received basis.
AMENDED 08/29/2023 (Mn, PAN)
1 0
Report #:: 2023-14601 Page 2 of 2

-.Up %.F1C"1131,,nc_ Wilmington, NC Lab 094
6602 Windmij
Wilmington, NC 2
r Sample Receipt Checklist 910-392.
Client: B, G
Date: -d ((
Receipt of sample:
Z3 Report Number;
❑ YES No ECHEM Pickup Client Dc-liver❑ y 7-1 ------
YES p NO N/A 1. Were custod seals esent LX 0 Ui TI, '[J
Original temperature upon recei N/A 2. if custody00 the cooler?
----------- = pt s were Preserlt,.were they in I -------
How temperature taken: 1C Corrected temperature Temperature Blank Mperature upon receipt
en?
111k9ainsr ottles
IR Gun ID: Thomas Traceable � N 2108 6 69 IR Gun Corr ' ecti0h Factor *C: 0.0
YES CJ No 3. If temperature o
YES f cooler exceeded 60c, was 7 tQA notified?
13 NO 4. Were proper custody Procedures (relinquished/received} YES 11 N 0 5. Were sample ID's listed on the Project Mgr,,,, followed? YES ❑ A 0 6. Were samples ID, COC?
S listed on sample container..... .. ...
. ................ ...................... -.11
YES 11 NO 7. Were ... ........ . S.
collection date and time listed on the
YES 11 NO 8. Were test's 71111111 .. .. .... . .
YES 11 NO to be performei:!fl ed on tii' e" COC?
ES 0 No 9. Did samples arrive in proper containers for each
YES ❑
0. Did samples arrive in good condi' ­ I
0 NO tion � or each
-11. Was adequate sample volume available?
YES Cl NO
12. Were sam❑ ples MPIes received within proper holdl ..... .... ......... .. .......
ng time for requested tests?
NO 13 . ....... Were acid preserved samples received at a PH of <2?
❑ YES
0 No 14. Were cyan ......... . ... ...
13 YES 111 ''111 . . ''I ....... .. . :iesamj:iles
0 NO --------- =_ received
at a PH >12?
5, Were sulfide samples received at a
- PH >9?
C1 YES 0 No 16. -Were NH3_
L1 YES /TKN/Phenoi—
0 N ------- received at a chlorine
ES ❑
-17. Were Sulfide . a 1 e reC941 ed at a chlMh residual of <0. 5 m ' /L ? ,
El No 18. We
We resill ua I of <0.5 MA?
ort oPhOsPhate sar6pfes tiltered in the field within 15 minutes?
C/Volat'les are PH checked at time of analysis and recorded on the tlesheet.
Bacteria samples are checked for Chlorine at titne of analysis and le&on the benchsheet.
SMifte Pre e o1q: (Must be UX
Sampfe(s) C0fhPlet6d for any sampg(sj incorrectly Pfeserved or with headspace)
by adding (circle one): were received incorrectly preserved and were a
Time of Preservation: H2504 HNO3 HCI NaOH adjusted accordingly
Note: Not If more than one preservative is needed. notate in com
ffyctistamerservice immediately for Incorrectly
notify the state tab if -diPreserved samples. obtain a new sample or menu below
rected to analyzed by the customer. Who was notified, date and time.
Volatiles Sample(s)
COMMENTS: were received with headSPa . c . e . . ..................

IWL

�ntaln
for ,.
a �the
vi
u
d
„a
� 0 CIIUXC►
ArCnlc `.
Nickel Wenium
Cadmium s '
^„, Sodium
I�Iitra N '
R Nitro °�
g� Ad ��
o"
SAR
TotalSolids pH
�
zinc
pph
!. aresM� ..W
^ Magnesium PlantA table
Nitrogen
calculation) en
calculation
siduals shall be monitored for compliancewith pathogen and vector attraction reduc I dw
uirements at the frequency specified in Attachment A, and at the time indicated in the sampling
�ilization
monitoring sections of the approved O&M plan, The required data shall W Specific to the
process utilized, and sufficient to demonstrate compliance with the Class B peften
Ruction requirements in 15A NCAC 02T .1106 (a) and (bX2), and one vector attracdon reduction.
Puirernent in 15A NCAC 02T .1107 (a) shall be met. Any exceptions from tho rcquiremcnts in this "'``

Town of Cleveland
Non -Discharge Permit No. WQ001 1431
2023
Sample Date
Fecal Coliform
MPN/gram dry weight
Log
02/14/23
39,370
4.60
02/14/23
39,063
4.59
02/14/23
17,557
4.24
02/14/23
23,077
4.36
02/14/23
39,063
4.59
02/14/23
23,256
4.37
02/14/23
38,168
4.58
Statesville Analytical - 230214-22-01 thru 22-07
Total 31.33
Average 4.48
Geometric Mean 29,948 Fecal Coliform - MPN/gram dry weight
Geometric Mean of Less than 2,000,000 mets Class B -Alternative I Pathogen Reduction
Fecals 2023.xis Page 1

Analytical Results d
Bio Green Services
383 Potts Road
Advance, NC 27006
Receive Date: 02/14/2023
Reported: 07/10/2023
For: Cleveland
Comments: GEOMETRIC MEAN: 29,948 MPN/g
Sample Number Parameter Sample ID Result
Unit Method Analyzed Analyst
230214-22-01
Fecal Coliforms
1
39370
MPN/g
SM9221 CE-2014
02/14/2023
MD
230214-22-01
Percent Solids
1
1.27
%
SM254OB-2011
02/14/2023
MD
230214-22-02
Fecal Coliforms
2
39063
MPN/g
SM9221 CE-2014
02/14/2023
MD
230214-22-02
Percent Solids
2
1.28
%
SM254OB-2011
02/14/2023
MD
230214-22-03
Fecal Coliforms
3
17557
MPN/g
SM9221 CE-2014
02/14/2023
MD
230214-22-03
Percent Solids
3
1.31
%
SM2540B-2011
02/14/2023
MD
230214-22-04
Fecal Coliforms
4
23077
MPN/g
SM9221 CE-2014
02/14/2023
MD
230214-22-04
Percent Solids
4
1.30
%
SM254OB-2011
02/14/2023
MD
230214-22-05
Fecal Coliforms
5
39063
MPN/g
SM9221 CE-2014
02/14/2023
MD
230214-22-05
Percent Solids
5
1.28
%
SM254OB-2011
02/14/2023
MD
230214-22-06
Fecal Coliforms
6
23256
MPN/g
SM9221 CE-2014
02/14/2023
MD
230214-22-06
Percent Solids
6
1.29
%
SM254OB-2011
02/14/2023
MD
230214-22-07
Fecal Coliforms
7
38168
MPN/g
SM9221 CE-2014
02/14/2023
MD
230214-22-07
Percent Solids
7
1.31
%
SM2540B-2011
02/14/2023
MD
E
Solids
Respectfully submitted,
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 42

Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 42

Condition of Receipt
Sample Number 230214-22-01 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Feom|Cm|iforms
SodumThionuKah* Received onIce
Chemicals incontainers, lab
Sample Number 230214-22-02 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received onIce
Parameter Schedule: Faco|Cu|iforma
SodumThioauUehe Received onIce
Chemicals incontainers, lab
Sample Number 230214-22-03 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received onIce
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals incontainers, lab
Sample Number 230214-22-04 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Feum|Cm|Kornma
Sodium Thiosulfate Received on Ice
Chemicals incontainers, lab
Sample Number 230214-22-05 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
POBox 228°Statesville, NC%86879704/872/4697
Page oof 42

Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230214-22-06 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230214-22-07 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230214-22-08 Temp on Arrival: 2.3
Parameter Schedule:
Received on Ice
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: TCLP
Received on Ice
pH on Arrival: <2
Parameter Schedule:
Ammonia Nitrogen
Sulfuric Acid
Received on Ice
Chemicals in containers, lab
pH on Arrival: <2
Parameter Schedule:
Nitrate/Nitrite
Sulfuric Acid
Received on Ice
Chemicals in containers, lab
pH on Arrival: <2
Parameter Schedule:
Nitrate/Nitrite - Solids
Sulfuric Acid
Chemicals in containers, lab
Received on Ice
pH on Arrival: <2
Parameter Schedule:
TKN
Sulfuric Acid
Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 4 of 42

Chemicals in containers, lab
pH on Arrival: <2 Parameter Schedule: Phosphate, Total as P
Sulfuric Acid Received onIce
Chemicals incontainers, lab
POBox JJ8°Statesville, NC28687°704/O72/4697
Page am42

to
17�
(Z7
S
.... . . .. . .
.emu. .. . .....
t
J
9— an to logo
PO Box 228 * Statesville, NC 28687 a 704/872/4697
Page 6 of 42

.,Pace Analytical"
www.pacelabs.com
March 07, 2023
Crystal Little
Statesville Analytical, Inc.
122 Court Street
PO Box 228
Statesville, NC 28687
RE: Project: BIOGREEN
Pace Project No.: 92652879
Dear Crystal Little:
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on February 17, 2023. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
Some analyses were subcontracted outside of the Pace Network. The test report from the external subcontractor is
attached to this report in its entirety.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
Pace Analytical Services - Charlotte
Pace Analytical Services - Ormond Beach
Pace Analytical Services - Greensburg
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
L
Tyriek Hooks
[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
fA' This report shall not be reproduced, except in full,
,q without the written consent of Pace Analytical Services, LLC.
eoRt�o
Page 1 of 34
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 7 of 42

mol
!� 2 aceAnalytical "
www.pacelabs.com
Project: BIOGREEN
Pace Project No.: 92652879
Pace Analytical Services Pennsylvania
1638 Roseytown Rd Suites 2,3&4, Greensburg, PA 15601
ANAB DOD-ELAP Rad Accreditation #: L2417
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Guam Certification: FL NELAC Reciprocity
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Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maine Certification #: FLO1264
Maryland Certification: #346
Massachusetts Certification #: M-FL1264
Michigan Certification #: 9911
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
CERTIFICATIONS
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Ohio EPA Rad Approval: #41249
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South Dakota Certification
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REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, -LC.
Page 2 of 34
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 8 of 42

%' ,� °aceAnalXical
www.pacelabs.com
Project: BIOGREEN
Pace Project No.: 92652879
Pace Analytical Services Ormond Beach
Wisconsin Certification #: 399079670
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
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North Carolina Wastewater Certification #: 40
CERTIFICATIONS
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Louisiana DoH Drinking Water #: LA029
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South Carolina Laboratory to: 99030
South Carolina Certification # 99030001
VirginiaNELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
980C Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 34
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 9 of 42

"* 2ceAnalytica('
www.pacelabs.com
SAMPLE ANALYTE COUNT
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Hu tersville, NC 28078
[phone]
Project:
Pace Project No.:
BIOGREEN
92652879
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92652879001
230214.22.08
EPA 8081B
SEM
9
PASI-C
EPA 8082A
SEM
8
PASI-C
EPA6010
KC2
7
PASI-0
EPA 7470
JNK
1
PAS I-O
EPA 8270E
PKS
18
PASI-C
EPA 8260D
SAS
14
PAS(-C
EPA 1010B
MJP
1
PASI-A
EPA 9045D
YEG
1
PASI-A
EPA9095B
YEG
1
PASI-A
EPA 9014
PAS
1
PASI-PA
SM 4500-S2-F-2011
PAS
1
PASI-PA
PAS I -A = Pace Analytical Services - Asheville
PAS I-C = Pace Analytical Services - Charlotte
PASI-O = Pace Analytical Services - Ormond Beach
PASI-PA = Pace Analytical Services - Greensburg
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC-
Page 4 of 34
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 10 of 42

Pace Analytical Services, LLC
aceAnalyticai ., 9800 Kincey Ave. Suite 100
www.pacalabe.cam Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BIOGREEN
Pace Project No.: 92652879
Sample: 230214.22.08 Lab ID: 92652879001 Collected: 02/14/23 09:25 Received: 02/17/23 12:12 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua]
8081 TCLP Pesticides RVE
Analytical Method: EPA 8081B Preparation Method: EPA 3510C
Leachate Method/Date: EPA 1311, 02/23/23 13:27 Initial
pH: 6.4; Final pH: 5
Pace Analytical Services - Charlotte
gamma-BHC (Lindane)
ND ug/L 0.50 1
03/01/23 11:54 03/02/23 17:25 58-89-9
Chlordane (Technical)
ND ug/L 3.0 1
03/01/23 11:54 03/02/23 17:25 57-74-9
Endrin
NO ug/L 0,50 1
03101/2311:54 03102/231T25 72-20-8
Heptachlor
NO ug/L 0.50 1
03/01/23 11:54 03/02/23 17:25 76-44-8
Heptachlor epoxide
ND ug/L 0.50 1
03/01/23 11:54 03/0212317:25 1024-57-3
Methoxychlor
ND ug/L 1000 1
03/0112311:54 03102/2317:25 72-43.5
Toxaphene
ND ug/L 3.0 1
03/01/23 11:54 03102/2317:25 8001-35-2
Surrogates
Decachlorobiphenyl (S)
135 % 10-200 1
03/01/23 11:54 03/02/23 17:25 2051-24-3
Tetrachlom-m-xylene (S)
89 % 10-182 1
03/01/23 11:54 03/02/23 17:25 877-09-B
8082 TCLP PCBs RVE
Analytical Method: EPA 8082A Preparation Method: EPA 3510C
Leachate Method/Date: EPA 1311, 02/23/23 13:27 Initial
pH: 6.4, Final pH: 5
Pace Analytical Services - Charlotte
PCB-1016 (Aroclor 1016)
ND ug/L 1000 1
03101/23 11:54 03/03/23 06:05 12674-11-2
PCB-1221 (Aroclor 1221)
ND ug/L 1000 1
03/01/23 11:54 03/03/23 06:05 11104-28-2
PCB-1232 (Aroclor 1232)
ND ug/L 1000 1
03/01/23 11:54 03/03/23 06:05 11141-16-5
PCB-1242 (Aroclor 1242)
ND ug/L 1000 1
03/01/23 11:54 03/03/23 06:05 53469-21-9
PCB-1248 (Aroclor 1248)
ND ug/L 1000 1
03/01/23 11:54 03/03/23 06:05 12672-29-6
PCB-1254 (Aroclor 1254)
ND ug/L 1000 1
03/D1/23 11:54 03/03/23 06:05 11097-69-1
PCB-1260 (Aroclor 1260)
NO ug/L 1000 1
03/01/23 11:54 03/03/23 06:05 11096-82-5
Surrogates
Decachlorobiphenyl (S)
128 % 10-181 1
03/01/23 11:54 03/03/23 06:05 2051-24-3
6010 MET ICP, TCLP
Analytical Method: EPA 6010 Preparation Method; EPA 3010
Leachate Method/Date: EPA 1311; 02/28/23 13:30
Pace Analytical Services - Ormond Beach
Arsenic
ND mg/L 0.10 1
03/01/23 16:03 03/02/23 07:53 7440-38-2
Barium
ND mg/L 0.10 1
03/01/23 16:03 03/02/23 07:53 7440-39-3
Cadmium
ND mg/L 0.010 1
03/01/23 16:03 03/02/23 07:53 7440-43-9
Chromium
ND mg/L 0.050 1
03/01/23 16:03 03/02/23 07:53 7440-47-3
Lead
ND mg/L 0.10 1
03/01/23 16:03 03/02/23 07:53 7439-92-1
Selenium
ND mg/L 0.15 1
03/01/23 16:03 03/02/23 07:53 7782-49-2
Silver
ND mg/L 0.050 1
03/01/23 16:03 03/02/23 07:53 7440-22-4
7470 Mercury, TCLP
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Leachate Method/Date: EPA 1311; 02/28/23 13:30
Pace Analytical Services - Ormond Beach
Mercury ND mg/L 0.0020 1 03/02/23 08:08 03/02/23 11:52 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/07/2023 05:04 PM without the written consent of Pace Analytical Services, LLC,
Page 5 of 34
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 11 of 42

01007
' ,..'ceAnall
www.pacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: BIOGREEN
Pace Project No.: 92652879
Sample: 230214.22.08
Lab ID: 92652879001
Collected:
02/14/23 09:25
Received: 02/17/23 12:12 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted forpercent moisture,
sample
size and any dilutions.
Parameters
Results
Units Report Limit
DF
Prepared Analyzed CAS No. Quaff
8270E TCLP RVE
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Leachate Method/Date:
EPA 1311; 02/23/23 13:27
Initial
pH: 6.4; Final pH: 5
Pace Analytical Services - Charlotte
1,4-Dichlorobenzene
ND
ug/L
50.0
1
02/27/23 10:31 02/28/23 14:35 106-46-7
2,4-Dinitrotoluene
ND
ug/L
50.0
1
02/2712310:31 02128/2314:35 121-14-2
Hexachloro-1,3-butadiene
ND
ug/L
50.0
1
02/27/23 10:31 02128/2314:35 87-68-3
Hexachlorobenzene
ND
uglL
50.0
1
02/27/23 10:31 02/2812314:35 118-74-1
Hexachloroethane
ND
ug/L
50.0
1
02127/2310:31 02/28/23 14:35 67-72-1
2-Methylphenol(o-Cresol)
ND
ug/L
50.0
1
02/27/23 10:31 02128/2314:35 95-48-7
3&4-Methylphenol(m&p Cresol)
ND
ug/L
50.0
1
02/27/23 10:31 02/28/23 14:35 15831-10-4
Nitrobenzene
ND
ug/L
50.0
1
02/2712310:31 02/28/23 14:35 98-95-3
Pentachlorophenol
ND
ug/L
100
1
02/27/23 10:31 02/2812314:35 87-86-5
Pyridine
ND
ug/L
50.0
1
02/27/2310:31 02/2812314:35 110-86-1 L2
2,4,5-Trichlorophenol
ND
ug/L
50.0
1
02127/2310:31 02/2812314:35 95-95-4
2,4,6-Trichlorophenol
ND
ug/L
50.0
1
02/27/23 10:31 02/28/23 14:35 88-06-2
Surrogates
Nitrobenzene-d5 (S)
129
%
10-138
1
02/27/23 10:31 02/28/23 14:35 4165-60-0
2-Fluorobiphenyl(S)
99
%
10-130
1
02/27/23 10:31 02/28/23 14:35 321-60-8
Terphenyl-d14 (S)
113
%
19-191
1
02/27/23 10:31 02/28/23 14:35 1718-51-0
Phenol-d6 (S)
73
%
10-130
1
02/27/23 10:31 02/28/23 14:35 13127-88-3
2-Fluorophenol (S)
80
%
10-130
1
02/27/23 10:31 02/28/23 14:35 367-12-4
2,4,6-Tribromophenol (S)
101
%
10-164
1
02/27/23 10:31 02/28/23 14:35 118-79-6
8260D MSV TCLP
Analytical Method:
EPA 8260D Leachate
Method/Date:
EPA 1311; 02/20/23 14,12
Pace Analytical
Services - Charlotte
Benzene
ND
ug/L
100
20
02/21/23 19:06 71-43-2
2-Butanone (MEK)
ND
ug/L
200
20
02/21/23 19:06 78-93-3
Carbon tetrachloride
ND
ug/L
100
20
02/21/23 19:06 56-23-5
Chlorobenzene
ND
ug/L
100
20
02/21/23 19:06 108-90-7
Chloroform
ND
ug/L
100
20
02/21/23 19:06 67-66-3
1,4-Dichlorobenzene
ND
ug/L
100
20
02/21/23 19:06 106-46-7
1,2-Dichloroethane
ND
ug/L
100
20
02/21/23 19:06 107-06-2
1,1-Dichloroethene
ND
ug/L
100
20
02/21/231906 75-35-4
Tetrachloroethene
ND
ug/L
100
20
02/2112319:06 127-18-4
Trichloroethene
ND
ug/L
100
20
02121/2319:06 79-01-6
Vinyl chloride
ND
ug/L
100
20
02/21/23 19:06 75-01-4
Surrogates
1,2-Dichloroethane-d4 (S)
104
%
70-130
20
02/21/23 19:06 17060-07-0
Toluene-d8 (S)
108
%
70-130
20
02/21/23 19:06 2037-26-5
4-Bromofluorobenzene (S)
100
%
70-130
20
02/21/23 19:06 460-00-4
1010 Flashpoint,Closed Cup
Analytical Method:
EPA 1010B
Pace Analytical
Services - Asheville
Flashpoint
a200
deg F
70.0
1
02/23/23 14:46
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/07/2023 05:04 PM without the written consent of Pace Analytical Services, LLC.
Page 6 of 34
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 12 of 42

Pace Analytical Services, LLC
y raceAnalytical rr 9800 KinceyAve. Suite 100
,
www.pacelabs.com Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BIOGREEN
Pace Project No.: 92652879
Sample: 230214.22.08 Lab ID: 92652879001 Collected: 02/14/23 09:25 Received: 02/17/23 12:12 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[
9045 pH Soil
Analytical Method: EPA 9045D
Pace Analytical Services - Asheville
pH at 25 Degrees C
5.7 Sid. Units 0.10 1 02/24/23 15:06 H3
9095 Paint Filter Liquid Test
Analytical Method: EPA 9095B
Pace Analytical Services - Asheville
Free Liquids
FAIL 1.0 1 02/28/23 10:50
733C S Reactive Cyanide
Analytical Method: EPA 9014 Preparation Method: SW-846 7.3.3.2
Pace Analytical Services - Greensburg
Cyanide, Reactive
ND mg/kg 1.0 1 02/22/23 17:35 02/22/23 17:57
734S Reactive Sulfide
Analytical Method: SM 4500-S2-F-2011 Preparation Method: SW-846 7.3.4.2
Pace Analytical Services - Greensburg
Sulfide, Reactive
ND mg/kg 10.0 1 02/22/23 17:35 02/22/23 17:40 H1,H2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/07/2023 05:04 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 34
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 13 of 42

f '
,.,6ceAna1ytica1"
www.pacelabs.com
I
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Hmttersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: BIOGREEN
Pace Project No.: 92652879
QC Batch: 898371
Analysis Method: EPA 7470
QC Batch Method: EPA 7470
Analysis Description: 7470 Mercury TCLP
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 92652879001
METHOD BLANK: 4936517
Matrix: Water
Associated Lab Samples: 92652879001
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Mercury mg/L
NO 0.00020 03/02/2311:06
LABORATORY CONTROL SAMPLE: 4938870
Spike LCS LCS % Rec
Parameter Units
Cone. Result % Rec Limits Qualifiers
Mercury mg/L
0.002 0,0020 102 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4938871 4938872
MS MSD
35780391020
Spike Spike MS MSD MS MSD % Rec
Parameter Units Result
Cone. Cone. Result Result % Rec % Rec Limits RPD Qual
Mercury mg/L 0.00090
0.02 0.02 0.020 0.020 102 102 75-125 0
U
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/07/2023 05:04 PM without the written consent of Pace Analytical Services, LLC,
Page 8 of 34
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 14 of 42

r� keAnalXical"
www.pacelabs.com
i
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project:
BIOGREEN
Pace Project No.:
92652879
QC Batch:
898379
Analysis Method: EPA 6010
QC Batch Method:
EPA 3010
Analysis Description: 6010 MET TCLP
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 92652879001
METHOD BLANK: 4936517
Associated Lab Samples: 92652879001
Parameter
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
Matrix: Water
Blank
Reporting
Units
Result
Limit
Analyzed Qualifiers
mg/L
ND
0.010
03/02/23 07:23
mg/L
ND
0.010
03/02/23 07:23
mg/L
ND
0.0010
03/02/23 07:23
mg/L
ND
0.0050
03/02/23 07:23
mg/L
ND
0.010
03/02/23 07:23
mg/L
ND
0,015
03/02/23 07:23
mg/L
ND
0.0050
03/02/23 07:23
LABORATORY CONTROL SAMPLE:
4938920
Spike
LCS
LCS
% Rec
Parameter
Units
Conc,
Result
% Rec
Limits Qualifiers
Arsenic
mg/L
0.25
0.26
104
80-120
Barium
mg/L
025
0.24
96
60-120
Cadmium
mg/L
0,025
0.026
103
BO-120
Chromium
mg/L
0.25
0.26
102
80-120
Lead
mg/L
0.25
0.25
99
80-120
Selenium
mg/L
0.25
0.27
109
80-120
Silver
mg/L
0,025
0.025
100
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
4938921
4938922
MS
MSD
92653402001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
e/ Rec
% Rec
Limits
RPD Qual
Arsenic
mg/L
ND
2.5
2.5
2.4
2.5
98
99
75-125
1
Barium
mg/L
0.18
2.5
2.5
2.8
2.8
103
104
75-125
1
Cadmium
mg/L
NO
0.25
0.25
0.25
0,26
102
103
75-125
1
Chromium
mg/L
ND
25
2.5
2.6
2.6
104
104
75-125
1
Lead
mg/L
ND
2.5
2.5
2.6
2.6
103
104
75-125
1
Selenium
mg/L
ND
2.5
2.5
2.5
2.5
100
101
75-125
1
Silver
mg/L
ND
0.25
0.25
0.24
0.24
96
97
75-125
1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/07/2023 05:04 PM without the written consent of Pace Analytical Services. L-C. Page 9 of 34
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 15 of 42

�`�r�aceAnaly�ical
www.pacelabs.com
QUALITY CONTROL DATA
Project: BIOGREEN
Pace Project No.: 92652879
QC Batch: 757269 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV TCLP
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92652879001
METHOD BLANK: 3934049
Associated Lab Samples: 92652879001
Parameter
1,1-Dichloroethene
1, 2-Dichloroethane
1,4-Dichlorobenzene
2-Butanone (MEK)
Benzene
Carbon tetrachloride
Chlorobenzene
Chloroform
Tetrachloroethene
Trichloroethene
Vinyl chloride
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Toluene-d8 (S)
Matrix: Water
Units
Blank
Result
Reporting
Limit
Analyzed
ug/L
ND
5.0
02121/2316:42
ug/L
ND
5.0
02/21/2316:42
ug/L
ND
5.0
02/2112316:42
ug/L
24.1
10.0
02121/2316:42
ug/L
ND
5.0
02/21/2316:42
ug/L
ND
5.0
02/2112316:42
ug/L
ND
5.0
02/21/2316:42
ug/L
ND
5.0
02/21/2316:42
ug/L
ND
5.0
02/21/2316:42
ug/L
ND
5.0
02/21/2316:42
ug/L
ND
5.0
02/21/2316:42
%
99
70-130
02/21/2316:42
%
99
70-130
02/21/2316:42
%
110
70-130
02/21/2316:42
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
3934048
Units
Spike
Conc,
LCS
Result
LCS
% Rec
% Rec
Limits
1,1-Dichloroethene
ug/L
20
21.2
106
70-130
1,2-Dichloroethane
ug/L
20
19.6
98
70-130
1,4-Dichlorobenzene
ug/L
20
20.6
103
70-130
2-Butanone (MEK)
ug/L
40
41.3
103
70-134
Benzene
ug/L
20
19.8
99
70-130
Carbon tetrachloride
ug/L
20
21.4
107
70.130
Chlorobenzene
ug/L
20
20.2
101
70-130
Chloroform
ug/L
20
19.7
99
70-130
Tetrachloroethene
ug/L
20
21.0
105
70-130
Trichloroethene
ug/L
20
21.1
106
70-130
Vinyl chloride
ug/L
20
20A
102
62-130
1,2-Dichloroethane-d4 (S)
%
96
70-130
4-Bromofluorobenzene(S)
%
101
70-130
Toluene-d8 (S)
%
98
70-130
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/07/2023 05:04 PM without the written consent of Pace Analytical Services, I.I.C.
Page 10 of 34
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 16 of 42

;aceAna1jdica1'
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: BIOGREEN
Pace Project No.: 92652879
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3934050
3934051
MS
MSD
92652835001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits RPD
Qual
1,1-Dichloroethene
ug/L
ND
400
400
ND
ND
1
1
70-156
M1
1,2-Dichloroethane
ug/L
ND
400
400
ND
ND
6
5
69-143
M1
1,4-Dichlorobenzene
uglL
NO
400
400
ND
ND
7
8
70-142
M1
2-Butanone (MEK)
ug/L
NO
800
800
NO
ND
4
6
60-157
M1
Benzene
ug/L
ND
400
400
ND
NO
3
4
70-142
M1
Carbon tetrachloride
ug/L
ND
400
400
NO
ND
4
4
70-148
M1
Chlorobenzene
ug/L
ND
400
400
ND
ND
7
7
70-141
M1
Chloroform
ug/L
NO
400
400
ND
ND
5
5
70-148
M1
Tetrachloroethene
ug/L
NO
400
400
NO
ND
5
5
70-145
M1
Trichloroethene
ug/L
ND
400
400
NO
ND
4
5
62-146
M1
Vinyl chloride
ug/L
ND
400
400
ND
NO
0
0
61-163
M1
1,2-Dichloroethane-d4 (S)
%
105
106
70-130
4-Bromofluorobenzene (S)
%
96
99
70-130
Toluene-d8(S)
%
109
104
70-130
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/07/2023 05:04 PM without the written consent of Pace Analytical Services, LLC_
Page 11 of 34
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 17 of 42

2eAnalXical"
www.pacelabs.com
QUALITY CONTROL DATA
Project: BIOGREEN
Pace Project No.: 92652879
UU hatch: 758730 Analysis Method: EPA 8081E
QC Batch Method: EPA 3510C Analysis Description: 8081 TCLP Pesticides RV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92652879001
METHOD BLANK: 3940864
Associated Lab Samples: 92652879001
Parameter
Chlordane (Technical)
Endrin
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
Decachlorobiphenyl (S)
Tetrachloro-m-xylene (S)
Matrix: Water
Blank
Reporting
Units
Result
Limit
Analyzed Qualifiers
ug/L
ND
3.0
03/02/2319:19
ug/L
ND
0.50
03/0212319:19
ug/L
ND
0.50
03/02/2319:19
ug/L
ND
0.50
03/02/2319.19
ug/L
ND
0.50
03/02/2319:19
ug/L
NO
1000
03/02/23 1919
ug/L
ND
3.0
03/02/2319:19
%
116
10-200
03/02/2319.19
%
75
10-182
03/02/2319.19
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Hunlersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
3940861
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Endrin
ug/L
1.2
1.5
119
46-178
gamma-BHC (Lindane)
ug/L
1.2
1.2
95
38-162
Heptachlor
ug/L
1.2
1.2
93
25-153
Heptachlor epoxide
ug/L
1.2
1.2
95
43-170
Methoxychlor
ug/L
3.8
3.7J
100
37-187
Decachlorobiphenyl (S)
%
139
10-200
Tetrachloro-m-xylene (S)
%
103
10-182
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3940862
3940863
MS
MSD
92653267001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Endrin
ug/L
ND
1.2
1.2
1.1
1.5
87
121
11-193
33 R1
gamma-BHC (Lindane)
ug/L
ND
1.2
1.2
0.91
1.2
73
93
10-190
24
Heptachlor
ug/L
ND
1.2
1.2
0.89
1.2
71
93
13-166
27
Heptachlor epoxide
ug/L
ND
1.2
1.2
0,91
1.2
73
96
10-200
27
Methoxychlor
ug/L
ND
3.8
3.8
2.5J
3.9J
67
104
10-200
Decachlorobiphenyl (S)
%
89
130
10-200
Tetrachloro-m-xylene (S)
%
77
92
10-182
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/07/2023 05:04 PM without the written consent of Pace Analytical Services, LLC.
Page 12 of 34
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 18 of 42

.. ceAnalytical "
www.pacelabs.com
Project: BIOGREEN
Pace Project No.: 92652879
uu Catch: 758731
QC Batch Method: EPA 3510C
Associated Lab Samples: 92652879001
METHOD BLANK: 3940874
Associated Lab Samples: 92652879001
Parameter
PCB-1016 (Aroclor 1016)
PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
Decachlorobiphenyl (S)
QUALITY CONTROL DATA
Analysis Method: EPA 8082A
Analysis Description: 8082 TCLP PCB RV
Laboratory: Pace Analytical Services - Charlotte
Matrix: Water
Blank
Reporting
Units
Result
Limit
Analyzed Qualifiers
ug/L
ND
1000
03/03/23 07,22
ug/L
ND
1000
03/03/23 07:22
ug/L
ND
1000
03/03/23 07:22
ug/L
ND
1000
03/03/23 07:22
ug/L
ND
1000
03/03/23 07:22
ug/L
ND
1000
03/03/23 07:22
ug/L
ND
1000
03/03/23 07:22
%
107
10-181
03/03/23 07:22
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 3940871
Spike LCS LIDS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
PCB-1016 (Aroclor 1016) ug/L 25 ND 81 33-160
PCB-1260 (Aroclor 1260) ug/L 25 ND 85 40-157
Decachlorobiphenyl (S) % 136 10-181
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3940872
3940873
MS
MSD
92653457001 Spike
Spike MS
MSD
MS
MSD
% Rec
Parameter
Units
Result Conc.
Conic. Result
Result
% Rec
% Rec
Limits RPD Qual
PCB-1016 (Aroclor 1016)
ug/L
ND 25
25 ND
ND
73
59
16-178
PCB-1260 (Aroclor 1260)
ug/L
ND 25
25 ND
ND
58
56
10-171
Decachlorobiphenyl (S)
%
77
82
10-181
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/07/2023 05:04 PM without the written consent of Pace Analytical Services, LLC.
Page 13 of 34
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 19 of 42

,'PaceAna1ytica1
www.pacelabs.com
QUALITY CONTROL DATA
Project: BIOGREEN
Pace Project No.: 92652879
U(O Batch: 758228 Analysis Method: EPA 8270E
QC Batch Method: EPA 3510C Analysis Description: 8270E TCLP MSSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92652879001
METHOD BLANK: 3935832
Matrix: Water
Associated Lab Samples: 92652879001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
1,4-Dichlorobenzene
ug/L
ND
50.0
02/28/23 11:11
2,4,5-Trichlorophenoi
ug/L
ND
50.0
02/28/23 11:11
2,4,6-Trichlorophenol
ug/L
ND
50.0
02/28/2311.11
2,4-Dinitrotoluene
ug/L
ND
50.0
02/28/2311.11
2-Methylphenol(o-Cresol)
ug/L
ND
50.0
02/28/23 11:11
3&4-Methyiphenol(m&p Cresol)
ug/L
ND
50.0
02/28/23 11:11
Hexachloro-1,3-butadiene
ug/L
ND
50.0
02/28/23 11:11
Hexachlorobenzene
ug/L
ND
50.0
02128/231111
Hexachloroethane
ug/L
ND
50.0
02/2812311:11
Nitrobenzene
ug/L
ND
50.0
02128/2311:11
Pentachlorophenol
ug/L
ND
100
02128/2311:11
Pyridine
ug/L
ND
50.0
02/2812311:11
2,4,6-Tribromophenol (S)
%
74
10-164
02/28/23 11:11
2-Fluorobiphenyl (S)
%
78
10-130
02/28/23 11:11
2-Fluorophenol (S)
%
66
10-130
02/28/23 11:11
Nitrobenzene-d5 (S)
%
101
10-138
02/28/23 11:11
Phenol-d6 (S)
%
59
10-130
02/28/23 11:11
Terphenyl-d14 (S)
%
94
19-191
02/28/23 11:11
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
3938488
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rao
Limits Qualifiers
1,4-Dichlorobenzene
ug/L
500
290
58
10-130
2,4,5-Trichlorophenol
ug/L
500
525
105
38-147
2,4,6-Trichlorophenoi
ug/L
500
530
106
34-142
2,4-Dinitrotoluene
ug/L
500
606
121
44.154
2-Methylphenot(o-Cresol)
ug/L
500
502
100
31-130
3&4-Methylphenol(m&p Grego])
ug/L
500
484
97
30-130
Hexachloro-1,3-butadiene
ug/L
500
259
52
10-136
Hexachlorobenzene
ug/L
500
459
92
44-138
Hexachloroethane
ug/L
500
267
53
10.130
Nitrobenzene
ug/L
500
621
124
33-133
Pentachlorophenol
ug/L
1000
932
93
21-163
Pyridine
ug/L
500
17AJ
3
16-130 L2
2,4,6-Tribromophenol(S)
%
107
10-164
2-Fluorobiphenyl (S)
%
96
10.130
2-Fluorophenol(S)
%
86
10-130
Nitrobenzene-d5(S)
%
127
10-138
Phenol-d6 (S)
%
81
10-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/07/2023 05:04 PM without the written consent of Pace Analytical Services, LLC.
Page 14 of 34
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 20 of 42

/" ,�,,FkeAnaiytical
www.pacelabs.com
I
QUALITY CONTROL DATA
Project: BIOGREEN
Pace Project No.: 92652879
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 3938488
Spike LCS 1-CS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Terphenyl-d14(S) % 107 19-191
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3938489
3938490
MS
MSD
92652959001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc,
Result
Result
% Rec
% Rec
Limits
RPD Qual
1,4-Dichlorobenzene
ug/L
ND
500
500
348
305
70
61
10-130
13
2,4,5-Trichlorophenol
ug/L
ND
500
500
503
562
101
112
10-170
11
2,4,6-Trichlorophenol
ug/L
NO
500
500
503
588
101
118
10-166
16
2,4-Dinitrotoluene
ug/L
NO
500
500
585
645
117
129
30-164
10
2-Methylphenol(o-Cresol)
ug/L
ND
500
500
465
561
93
112
19-132
19
3&4-Methylphenol(m&p
ug/L
ND
500
500
459
530
92
106
13-136
14
Cresol)
Hexachloro-1,3-butadiene
ug/L
NO
500
500
294
271
59
54
10-130
8
Hexachlorobenzene
ug/L
NO
500
500
447
511
89
102
32-145
13
Hexachloroethane
ug/L
NO
500
500
326
272
65
54
10-130
18
Nitrobenzene
ug/L
ND
500
500
608
665
122
133
19-145
9
Pentachlorophenol
ug/L
ND
1000
1000
882
1060
88
106
10-188
18
Pyridine
ug/L
ND
500
500
250
10.91
50
2
10-130
2,4,6-Tribromophenol (S)
%
91
107
10-164
2-Fluorobiphenyt(S)
%
83
94
10-130
2-Fluorophenol(S)
%
75
91
10-130
Nitrobenzene-d5(S)
%
112
123
10-138
Phenol-d6 (S)
%
64
89
10-130
Terphenyl-dl4(S)
%
95
106
19-191
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/07/2023 05:04 PM without the written consent of Pace Analytical Services, LLC.
Page 15 of 34
PO Box 228 e Statesville, NC 28687 • 704/872/4697
Page 21 of 42

2neAnalytiil
www.pacelabs.com
I
QUALITY CONTROL DATA
Project: BIOGREEN
Pace Project No.: 92652879
UL; Batch: 757771 Analysis Method: EPA 10108
QC Batch Method: EPA 1010B Analysis Description: 1010 Flash Point, Closed Cup
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92652879001
SAMPLE DUPLICATE: 3936481
92652444003 Dup
Parameter Units Result Result RPD Qualifiers
Flashpoint deg F >200 >200
Pace Analytical Services, LLC
9800 KinceyAve. Suite too
Huntersville, NC 28078
[phone]
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/07/2023 05:04 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 34
PO Box 228 • Statesville, NC 28687 e 704/872/4697
Page 22 of 42

PaceAnalytical"
www.pacetabs.com
QUALITY CONTROL DATA
Project: BIOGREEN
Pace Project No. 92652879
QC Batch: 757987 Analysis Method: EPA 9045D
QC Batch Method: EPA 9045D Analysis Description: 9045 pH
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92652879001
SAMPLE DUPLICATE: 3937486
92653161001 Cup
Parameter Units Result Result RPD Qualifiers
pH at 25 Degrees C Std. Units 6.8 6.8 1 H3
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/07/2023 05:04 PM without the written consent of Pace Analytical Services, LLC,
Page 17 of 34
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 23 of 42

r aceAnalytical
www.pacelabs.com
i
QUALITY CONTROL DATA
Project: BIOGREEN
Pace Project No.: 92652879
QC Batch: 758467 Analysis Method: EPA 9095E
QC Batch Method: EPA 9095E Analysis Description: 9095 PAINT FILTER LIQUID TEST
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92652879001
SAMPLE DUPLICATE: 3939648
92652879001 Dup
Parameter Units Result Result RPD Qualifiers
Free Liquids FAIL FAIL
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/07/2023 05:04 PM without the written consent of Pace Analytical Services, LLC,
Page 18 of 34
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 24 of 42

011
07
ceAnalytical
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave, Suite 100
Huntersville, NC 28078
[phone]
Project: BIOGREEN
Pace Project No.: 92652879
QC Batch: 568936
Analysis Method:
EPA 9014
QC Batch Method: SW-846 7.3.3.2
Analysis Description:
733C Reactive Cyanide
Laboratory:
Pace Analytical Services - Greensburg
Associated Lab Samples: 92652879001
METHOD BLANK: 2762954
Matrix: Solid
Associated Lab Samples: 92652879001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Cyanide, Reactive
mg/kg
ND
1.0 02/22/23 17:52
LABORATORY CONTROL SAMPLE: 2762955
Spike LCS
LCS % Rec
Parameter
Units
Conic. Result
% Rec Limits Qualifiers
Cyanide, Reactive
mg/kg
99.4 ND
3 0-8
SAMPLE DUPLICATE: 2762960
30564022001 Dup
Parameter
Units
Result Result
RPD Qualifiers
Cyanide, Reactive
mg/kg
ND
ND H1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/07/2023 05:04 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 34
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 25 of 42

`"� .- °aceAnalytical i�
www.pacelabs.com
QUALITY CONTROL DATA
Project: BIOGREEN
Pace Project No.: 92652879
QC Batch: 568935 Analysis Method: SM 4500-S2-F-2011
QC Batch Method: SW-846 7.3.4.2 Analysis Description: 734S Reactive Sulfide
Laboratory: Pace Analytical Services - Greensburg
Associated Lab Samples: 92652879001
METHOD BLANK: 2762951
Associated Lab Samples: 92652879001
Parameter Units
Sulfide, Reactive mg/kg
LABORATORY CONTROL SAMPLE: 2762952
Parameter Units
Sulfide, Reactive mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 10A 02/22/2317:40
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
199 15.9 8 0-52
SAMPLE DUPLICATE: 2762953
30564022001 Dup
Parameter Units Result Result
Sulfide, Reactive mg/kg ND ND
RPD Qualifiers
H3
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/07/2023 05:04 PM without the written consent of Pace Analytical Services, LLC, Page 20 of 34
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 26 of 42

o"n��aceo
-� Analytical:.
' www.pacelabs.com
QUALIFIERS
Project: BIOGREEN
Pace Project No.: 92652879
DEFINITIONS
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
OF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unfounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TIN -The NELAC Institute.
ANALYTE QUALIFIERS
H1 Analysis conducted outside the EPA method holding time.
H2 Extraction or preparation conducted outside EPA method holding time.
H3 Sample was received or analysis requested beyond the recognized method holding time.
L2 Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated
samples may be biased low.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/07/2023 05:04 PM without the written consent of Pace Analytical Services, LLC.
Page 21 of 34
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 27 of 42

/1
'I Pace Analytical Services, LLC
CZCi�I'1%�[�1 ��iC7�o 9800KinceyAve. Suite100
_- V n }' c Huntersville, NC 28078
www.pacolabs.com
[phone]
i
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
BIOGREEN
92652879
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92652879001
230214.22.08
EPA 3510C
758730
EPA 8081B
759017
92652879001
230214.22.08
EPA 3510C
758731
EPA 8082A
759018
92652879001
230214.22.08
EPA 3010
898379
EPA 6010
898441
92652879001
230214.22.08
EPA 7470
898371
EPA 7470
898539
92652879001
230214.22.08
EPA 3510C
758228
EPA 8270E
758505
92652879001
230214.22.08
EPA 8260D
757269
92652879001
230214.22.08
EPA 1010B
757771
92652879001
230214.22.08
EPA 9045D
757987
92652879001
230214.22.08
EPA 9095E
758467
92652879001
230214.22.08
SW-846 7.3.3.2
568936
EPA 9014
569206
92652879001
230214.22.08
SW-846 7.3.4.2
568935
SM 4500-S2-F-2011
569208
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/07/2023 05:04 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 34
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 28 of 42

I DC# Title: ENV-FRM-HUN1-0083 v02—Sample Condition Upon Receipt
Pace
Effective Date: 11/14/2022
Laboratory receiving samples:
-- Asheville [:1 Eden F] Greenwood []
/
Huntersville LJ
RaleighF-1
MechanicsvilleFl AtlantaEl KernersvilleE]
Client Name: EM
OR
I
Project
it: WO#:92652879
Courier: E)Fed Ex LJUPS
EIUSPS
—E❑I El `ie—nt
E] Commercial opace
E]Other:_
92652679
Custody Seal Present? nYes dN. Seals
Intact? Dyes
d1N.
-"`""Wte/Initials Person Examining ceintew.-
Packing Material; F]Bubble Wrap
�Jone
-7
E]Bubble
Bags
El Other
Biological Tissue Frozen?
Thermom r:
nYes F]No ��N/A
[?IR Gun ID:
Type of Ice: OWet
E113lue
O,4one
(1, Correction Factor;
Cooler Temp: '41 Add/Subtract (*C) Temp should be above freezing to 6°C
EISMPICS Outof temp Criteria. Samples on ice, cooling process
Cooler Temp Corrected ('C): his begun
USDA Regulated Soil ( EJ N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC Did samp!es originate from a foreign source (internationally,
Fri-rk mood? nV— Mhf„
--ffYCS
vivo
Connrnenls/Cdscrepancy:_____
Chain of Custody Present?
ONO
ON/A
1. _
Samples Arrived withinHold Time?
Yes
.ONo
-ON/A
2.
Short Hold Time Analysis (02 hr.)?
nyes
ONo
ON/A
3,
Rush Turn Around Time Requested?
Oyes
No
ON/A
4.
Sufficient Volume?
[dyes
—tyye"RN-o-
ON.
ON/A
S.
Correct Containers Used?
-Pace Containers Used?
ON/A
IN/A
6.
Containers Intact?
•ONI)
ON/A
T
Dissolved analysis: Samples Field Filtered?
— —
Dyes
— — — —
ON.
dN/A
8.
Sample Labels Match COC?
-includes Date/Time/ID/Analysis Matrix;
Headspace In VOA Vials (>5-6nun)?
6-
OYes
ON.
ONo
6N/A
6NIA
9.
10,
Trip Blank Present?
Trip Blank Custody Seals Present?
[]yes
QYe5
ON.
(:]No
O(N/A
dN/A
11.
COMMENTS/SAMPLE DISCREPANCY
Lot ID of split containers:
-CLIENT —NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
Project Manager SRF Review:
Qualtrax ID: 69614
Date/Time
Field Data Required? LJYcS "No
Date:
Date:
Page 23 of 34
Page 1 of 2
PO Box 228 * Statesville, NC 28687 9 704/872/4697
Page 29 of 42

DC#_Title: ENV-FRM-HUN1-00a3 v02 -Sample Condition Upon Receipt
-ace
Effective Date: 11/14/2022
*Check mark top half of box if pH and/or dechlorination is verified and
within the acceptance range for preservation samples.
Exceptions: VOA, Colifonn, TOC, Oil and Grease, DRO/8015 (water) OOC, Wig
**Bottom half of box is to list number of bottles
***Check all unpreserved Nitrates for chlorine
Project# W1O : 92652879
PM: TIN Due Date': 03/03/23
CLIENT: 92-5tatesvil
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Note: Wltnnnver
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Out of hold, incorrect preservative, out of temp, incorrect containers.
Qualtrax ID: 69614 Page 2 of 2 Page 24 of 34
PO Box 228 - Statesville, NC 28687 - 704/872/4697
Page 30 of 42

Page 25 of 34
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 31 of 42

II "»I IRi:W\NII N' . i ill Sf In II.Is N
March 06, 2023
Tyriek Hooks
Pace Analytical Services, lnc.
9800 Kinccy Ave Suite 100
hluntersvitle NC 28078-8400
RE: 92652879
Dear TyriekHooks: Order No: 2302N56
Analytical Environmental Services, fnc. received 1 samples on February 21, 2023 10:10 am
for the analyses presented in following report.
`No problems were encountered during the analyses except as noted in the Case Narrative or by qualifiers in
the report or QC Summary. Additionally, all results for the associated Quality Control samples were within
EPA and/or AES established limits.
AES' certifications are as follows:
-NELAP/Florida State Laboratory ID E87582 for analysis of Non -Potable Water, Solid & Chemical Materials,
Air & Emissions for Organics, and Drinking Water Microbiology & Metals, effective 07/01/22-06130/23.
-North Carolina Certification number 562 for analysis of Surface Water, Groundwater, Effluent, effective until
12/31/23.
-South Carolina Environmental Laboratory Certification number 99016003 effective until 6/30/23.
These results relate only to the items tested as received. This report may only be reproduced in frill and with
written permission from the laboratory.
If you have any questions regarding these test results, please feel free to call.
Sincerely,
Haris Bejdic
Project Manager
Page t oP,age 26 of 34
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 32 of 42

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PO Box 228 e Statesville, NC 28687 * 704/872/4697
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PO Box 228 9 Statesville, NC 28687 9 704/872/4697
Page 34 of 42

Analytical Environmental Services, Inc
Date: 6-Mar-23
Client:
Pace Analytical Services. Ina
Client Sample 11):
230214.22.08
Project Name:
92652879
Collection Date:
2/14/2023 9:25:00 AM
Lab ID:
2302N56-001
Matrix:
Solid
Analyses
Result'
Reporting
Units Batch[D
Dilution
Date Analyzed Analyst
Limit
FactorQual
HERBICIDES,TCLP SW1311/8151A
(SW3510C)
2,4,5-TP(Silvcx)
BRL
020
mg!L 351813
1 02/28/202317:47 TB
2.4-D
BRL
0.20
mg/L 3]1813
1 02/28f22317:47 TB
SUIT: DCAA
61.5
48-120
°.;,RFC 351813
1 02/28/2023 17A7 TB
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PO Box 228 * Statesville, NC 28687 * 704/872/4697
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PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 36 of 42

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PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 37 of 42

Analytical Environmental Services, Inc
Data: 6-Ma123
client: Pace Analytical Services, Inc.
Project Na— 92652879 Dates Report
Lab Order: 2302Ne56 p
Lab Sample ID Client Sample ID Collection Date Matrix Test Name TCLP Data Prep Data Analysis Date
2302N56-001A 230214.22,08 2/14/2023 9:25:OOAM Solid HERBICIDES, TCLP Leached 02/27/2023 2/2812023 11:45:11AM 02/26/2023
Page 7 ofqige 32 of 34
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 38 of 42

Analytical Environmental Services, Inc
Client: Pace Analytical Service, Inc.
Project Name: 92652879
Warlord— 2302N56
Aate: 6-Mar-23
ANALYTICAL QC SUMMARY REPORT
BatchlD; 351813
9: M11-351813 Client ID: Units: mg/L Prep Date: 02f28/2023 Rwt ND: 5099.
'j— M13LK Te,a('ode: FIERRICIDrs.TCLP SWI311AISIA B,,IchID: 351813 Analysis Date: 02/28/2023 Seq No* 1198'
Result RPT Limit SPK value SPK Ref Val '%,REC Loa Limit High Limit RPD Ref Val '95RPD RPD Limit
�,a,�-II•tanvcx) KKL 0.20
2,44) BRL 0.20
Sun: DCAA 0.2813 0 0.5000 56.3 48 120
Sample ID: LCS-351813 Client ID: Units. mWL Plop Date: 02/28/2023 Ron No: 509933
SamplcTvpe LCS TeslCode: neuxlCIDtS-Tcl.r SWI1IIIa151A BatchID: 351813 Analysis Date: 02/28/2023 Seq No: 11989903
Anolyte Result RPT Limit SPK value SPK Rcf Val l,REC Low Limit High Limit RPD Ref Val '%,RPD RPD Limit Quel
2,4.>-1P(Snvex) 0.3721 0.20 0.5000 74.5 50.8 120
2,4-D 0,3577 020 0.5000 71.5 50 120
Su- DCAA 0.3371 0 0.5000 67.4 48 120
Sample ID: 2302S75-001BMS
Client ID:
Units: mg/L
Prep Date: 02/28/2023
Run No: 509933
SalnpleTypc: MS
TestCode: t1EmES 0.CID.TC1-P SWI311I8151A
BatchID: 351813
Analysis Date: 02/28/2023
Seq No: 11989906
Analytc
Result RPT Limit SPK value SPK Ref Val
%REC I —Limit High Limit
RPD R,f Val %RPD
RPD Limit Qual
G ,>-I t'I.JIIveC) 11:i788 0.20 0.5000
2,4-D 0.3635 0.20 0.5000
Sure DCAA 0,3388 0 0.5000
7i.8 50.5 120
72.7 47.1 120
67.8 48 120
BILL dauurry,.nl gi'nu, r, ae,ini.iiwJ:reltn elw itnu„n : mm� ora � 1 F.uinuinl r�Hw J.ncvW hau:. If�lvatinyt Linni � Anul�,v not NCLAI'rvrlili.,l Id IYI'U :wyi4v i�mii. au. u, innr,a
erl c�n� rzror,�,ln. t,,:,�1 s sra<x,«�,.ry om,m. Ilmtu Jm m �nu,a.r Page 8 oge 33 of 34
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 39 of 42

End of Report
Page 9 oR�gige 34 of 34
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 40 of 42

At tri: RAY LAMB I Li,
T3110 GREEN SERVICES, INC.
383 PO'I'T'S RD.
ADVANCE, N(27U06 '/874
SAMPLE N"UMBER- 1 4'/'6 4 8 SAMZPLJ"� 1-D
DATE, SAMPLED 07112/23
DATE RECEIVED- 071' 4/23 S tl,'.%a 7
TIME RECEIVED- 10 1 D ,,' LL 1 V,. JR, i,,, . D i3Y RE,
Page 1 of 1
O8/22/23
MKIJ4!X- WW
Pl.ME SAMPLE;D 1400
P,ECEIVED I3Y Dd
"YFIE, SAMPLE- Grab
A N'A , �' (- 1
ANAL Y ' I S ll'ImF BY PE'S)ULT UN[TS
30 DAY BEN(711 ESK,Al,r,' T]ES'T 3
P.

,—.A 1-1 C.) RA'FC) R I FS, I N C
WWW.PARLABS.COM
30 Day Bench Scale Extended Aeration Test
Percent Volatile Solids Reduction
BIO GREEN SERVICES
112"Imm
- -- - — ---- -- - - -
MUMMA"# Rg
TS (g)
0.0951
0.0977
TS%
0.91%
0,92%
VS (9)
0.0649
0.0633
VS%
68.24%
64.79%
y Mass Fraction of Volatile Solids in Liquid Sludp_
&0061949
0.0059634
x Mass Fraction of Fixed Solids in Liquid Sled
0.0028827
0.0032408
FSVR (Mass Balance)
3,72%
FSVR (Van Kleeck)
3.73%
FSVR (Mass Balance) <15%
YES
,FSVR (Van Kleeck) <15%
YES
P.O. box,fl tl; N(, 2S 2 -11 -148�

PIXOR
iliqUJ M PT, A GUL)RAI E- RCL I A UL L
LABORATORIES, INC
WWW.PARLASS.COM
Collected
D.O.
Crucible
Tare VVt (g)
Sample VVt +
'rare VVt (9)
Liquid Sludge VV,
(g)
Oven Temp 'C,
Bate/Time In
Date/Time Out
Dried Sample Wi
t. Tare VVt (q)
Died Sludge, VA (g
Fixed Solids VVt (g
Furnace Ternp `C
Date/Time In
Date/Tirne Out
Burned Sample
VVt + Tare Wt (g)
Volatile Solids VVt (9)
TS%
VS0/11
30 Day Beh Scale Extended Aeraborl rest
As P'R: e c e ri pe E)�,q (,,} I ') a ~ 7 L) a,,,, 14 Uay 2 1, Day 28
07/14/2,3, (17 14r2:. f,17 26>3 r1, 7,1 7,,) 1, "1 �11Z;A,, 11 ("t t:,I;,f ("I I "i ",
233
317
3.68
4.21
4.88
X z
KA
K 7
41
x Fti
K 15
20+3667
20,3667
1 92868
21.6917
17.1108
23.1884
30.8430
30,8430
296674
322694
27,4559
33.8032
10.4763 .10.4763
10,3806
10.5777
10,3451
10.6148
106
105
106
107
106
1 u(3
07/14/23 15 10
07,14/23 1510
07/20/23 1000
071 7 123 2, 09:15
08103/23 09:50
08/10/23 10:10
.07115/23 15:30
07/15/23 1530
(,'7121,123 09 50
07iM23 0920
08,104/23 10,10
08/1 1/23 1030
20.4618
20,46-18
193792
21.7922
17,2070
23,2861
0.7951
0,0951
0924
01005
0.0962
0,0977
0,0302
0 0299
0.0347
0.0336
0.0344
550
550
550
550
5150
07/17123 14:45
0-7/2V23 15: 15
0',,',128/23 14:40
08/04/23 14M
08/11/23 14.50
07/17/23 15:50
07/21,23 lf.5:30
07,128/23 15:50
08/04/23 15A5
0 8 /11 /2,3 16:00
20,3969
19-3167
21.7264
17,1444
23,2228
04064-)
3,3625
0.0658
0.0626
0.0633
0.91%
0,91%
0.951%
0. 93,11/0
0.92%
68.24%
564
65.47Yc,
65.07%
64.79%
Yf M,hs, P,wno, I tf V)Iat,le eeT
Y3 10as"', 0
'I ,it
0.006 1949
siudqe w ,
0,0059634
;),dge
'(D MB1,5 1,okor
atT
0,0028827
f esi
0.0032408
TS O
0 0951
TS (9)1
0.09771
VS
9
9
VS (9)
0.0633
Volatile Fraction 1 9 87P
! I ;S ; & ( iI ,!% \1 .1�241-1
—04
C,uAOillalO MW
IVolatile Fractli,1-10J— 0.70424

(CHAIN OF CUSTODY
... .. . . . . ..
Ph= =41 588 833
u R A I u 117!11 Fax [phone]
TpWrl & Mkhnq�
22� 7 Gaham Pla,,'k Dwo-
OwskAw N( 28113,
PAR
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LtL,1,StrucV0rVS
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Sarnple
I S<143NRE
ARE SAMPLES FOR STA-rE or
sarv%pte'ryj,,wv� [M ww HVIV
Sample *Temp at firne of saonplmg� CI' Sarnp�e Temp upon recfipl� C
F jeNJ Preseroed: Yes No TOW L ineVera Heyispace: Yes No wa
Rewdual ChWhne checked athme ofsamphng QN): /I/— DmAkAmolon Necessarg (YIN):
How qumh"d by WW
i uiY M W
.. .... . . ...... Y
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SECTION VI
SOIL ANALYSIS REPORTS

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