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Home My WebLink AboutWQ0006018_2023 Residual Annual Report_20240219 (2)Initial Review Reviewer nathaniel.thornburg Is this submittal an application? (Excluding additional information.) * Yes No If not an application what is the submittal type?* Annual Report Residual Annual Report Additional Information Other Annual Report Year* 2023 Permit Number (IR) * WQ0006018 Applicant/Permittee Town of Morehead City Email Notifications Does this need review by the hydrogeologist? * Yes No Regional Office Wilmington CO Reviewer Admin Reviewer Wanda Gerald Submittal Form Project Contact Information Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence. Name* Lysa Finnerty Email Address* Ifinnerty@SYNAGRO.com Project Information ......................... Application/Document Type* New (Fee Required) Modification - Major (Fee Required) Renewal with Major Modification (Fee Required) Annual Report Additional Information Other Phone Number* 4105376150 Modification - Minor Renewal GW-59, NDMR, NDMLR, NDAR-1, N DAR-2 Residual Annual Report Change of Ownership We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type:* Wastewater Irrigation High -Rate Infiltration Other Wastewater Reclaimed Water Closed -Loop Recycle Residuals Single -Family Residence Wastewater Other Irrigation Permit Number:* WQ0006018 Has Current Existing permit number Applicant/Permittee Address* 435 Williams Court, Ste 100, Baltimore, MD 21220 Facility Name* Town of Morehead City Class B Residuals Program Please provide comments/notes on your current submittal below. Submission of the 2023 Annual Report for Town of Morehead City, NC At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here. (Application Form, Engineering Plans, Specifications, Calculations, Etc.) Morehead City NC 2023 Annual Report FINAL.pdf 3.16MB Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger than upload limit. * By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Mail payment to: NCDEQ — Division of Water Resources Attn: Non -Discharge Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Signature Alva �Cit'wt%tt, Submission Date 2/19/2024 435 Williams Court, Suite 100 Baltimore, MD 21220 www.synagro.com FEBRUARY 17, 2024 NCDEQ Division of Water Resources Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: 2023 Annual Report for Permit No. WQ0006018 Dear NCDEQ: SYNAGRO Synagro is submitting one electronic copy of the above referenced report on behalf of the Town of Morehead City, NC. If you have any questions or need additional information, please do not hesitate to contact Daniel Williams at (252) 726-6848 or Matthew Carter at (336) 705-9886. Sincerely, Derrick Shivar Environmental Compliance Manager Enclosures cc: Daniel Williams, Town of Morehead City Matthew Carter, Synagro YOUR PARTNER FORA CLEANER, GREENERWORLD TOWN OF MOREHEAD CITY, NC RESIDUALS LAND APPLICATION PROGRAM Permit No. WQ0006018 2023 ANNUAL REPORT Town of Morehead City, NC Residuals Land Application Program 2023 Annual Report TABLE OF CONTENTS 1. Certification Form and Annual Operations Summary 2. Annual Residual Sampling Summary Forms and Residuals Analyses 3. Annual Land Application Field Summary Forms 4. TCLP Analysis 5. Pathogen Reduction/Vector Attraction Reduction 6. Soil pH & Lime Application Records 7. Soil Analyses SECTION 1 ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit #: W00006018 County Carteret Year 2023 Facility Name (as shown on permit) Town of Morehead City WWTP NPDES No. NCO026611 Land Application Operator_ Svnagro Phone# 036) 998-7150 Land application of residuals as allowed by the above permit occurred during the past calendar year? X YES NO. If NO, skip Part A, and Part B and proceed to Part C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A — Residuals Application Summary: Total number of application fields in the permit: 7 Total number of fields utilized for land application during the year. I Total amount of dry tons applied during the year for all application sites: 55.36 Total number of acres utilized for land application during the year: 20.60 Part B — Annual Compliance Statement: Facility was compliant during calendar year 2023 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water QualityX YES NO. If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading Rates in 15A NCAC 02T .1105(b) (Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C — Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. am aware that there are significant penalties for submitting false information, including t possibility of fines and imprisonment for knowing violations." Daniel Williams. Utilities Director /C 43 - Permittee Name and Title (type or print) Signature of P 'ttee Date Signature of Preparer* Date Date 024 g P S o Lan pplier Date (if different from Permittee) (if different om Permittee and Preparer) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006) OPERATIONS SUMMARY - LAND APPLICATION - NORTH CAROLINA ALL COUNTIES - ALL SITES DATE RANGE: 1/1/2023 - 12/31/2023 MOREHEAD CITY, NC MOREHEAD CITY, NC CAKE MONTH/YEAR May 2023 TOTAL Units Key: D - Dry Tons; G — Gallons; W — Wet Tons; Y — Cubic Yards Report Date: 2/2/2024 7:38:00 PM AMOUNT UNIT DRY TONS UNIT DRY METRIC TONS 275.00 Y 55.36 D 50.21 275.00 Y 55.36 D 50.21 SECTION 2 ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: WQ0006018 Laboratory: Facility Name: MOREHEAD CITY, NC ENVIRONMENTAL CHEMISTS, INC Residual Source WQ # or NPDES#: NCO026611 WWTP Name: MOREHEAD CITY Residual Analysis Data Product Type Sample or Composite Date CAK 03/14/23 Parameter (mglkg dry weight) Ceiling Conc. Limit Percent Solids {%) NA 23.90 Arsenic 75 10.9 Cadmium 85 <6.19 Copper 4300 807 Chromium NA 14.5 Lead 840 15.8 Mercury 57 0.988 Molybdenum 75 <6.19 Nickel 420 13.5 Selenium 100 <6.19 Zinc 7500 1240 Total Phosphorus NA 35200 TKN NA 51000 Ammonia -Nitrogen NA 622 Nitrate and Nitrite NA 1200 For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and a luated the information submitted. I am aware that there are significant penalties for submitting false information, including the of fines d imprison en for knowing violations." r Signature of Preparer* Date *Preparer is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2T.1102(26) DENR FORM RSSF (1212006) Printed: 2/2/2024 7:29:52 PM For: 2252 01 ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WO permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ Permit Number: WQ0006018 Laboratory: Facility Name: MOREHEAD CITY, NC ENVIRONMENTAL CHEMISTS, INC Residual Source NPDES # or WQ#: NCO026611 WWTP Name: MOREHEAD CITY Residual Analysis Data Product Type CAK Sample or Composite Date 03/14/23 Parameters (mg/kg dry weight) Aluminium 16900 Calcium 57700 Magnesium 4430 pH (s.u.) 7.12 3820 Potassium Sodium 4470 16624 PAN SAR (Ratio) 2.3554 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordiance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and impris ant for knowing violations." _ 2 �3.24� Signature of Preparer' Date 'Preparer is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2T.1102(26) DENR FORM RSSF-B (1212006) Printed: 2/2/2024 7:30:58 PM For: 2252 01 6enviroche]mj ANALYTICAL & CONSULTING CHEMISTS Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 • 910-392.0223 Lab - 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax info -a environmentaichemists.com Town Of Morehead City Date of Report: Apr 17, 2023 1100 Bridges Street Customer PO #: Morehead City NC 28557 Customer ID: 09020011 Attention: Report #: 2023-05103 Project ID: Sludge Lab ID Sample ID: Collect Date/Time Matrix Sampled by 23-12698 Site: Sludge 3/14/2023 10:10 AM Solid/Sludge Nate Johnson Test Method Results Date Analyzed C C E AOAC 1 005 0.0 % 04/ 13/2023 Paint Filter Test SW 846 Method 9095 A pass 04/14/2023 Chlordane (TCLP) SW-846 8081 B <0.005mg/L 03/20/2023 Endrin (TCLP) SW-846 8081 B <0.00005 mg/L 03/20/2023 Heptachlor (TCLP) SW-846 8081 B <0.00005 mg/L 03/20/2023 Heptachlor epoxide (TCLP) SW446 8081 B <0.00005 mg/L 03/20/2023 Lindane (TCLP) SW-846 8081 a <0.00005 mg/L 03/20/2023 Methoxychlor (TCLP) Sw446 8081 B <0.00005 mg/L 03/20/2023 Toxaphene (TCLP) SW-846 8081 B <0.005 mg/L 03/20/2023 2,4,5-TP (TCLP) SW-846 8151 A <0.003 mg/L 03/17/2023 2,4-D (TCLP) SW-846 8151 A <0.003 mg/L 03/17/2023 1,4-Dichlorobenzene (TCLP) SW-846 8270 E <0.050 mg/L 03/20/3023 2,4,5-Trichlorophenol (TCLP) SW 846 8270 E <0.050 mg/L 03/20/3023 2,4,6-Trlchlorophenol (TCLP) SW-846 8270 E <0.050 mg/L 03/20/3023 2,4-Dinitrotoluene (TCLP) SW-846 8270 E <0.050 mg/L 03/20/3023 Cresol (TCLP) SW-846 8270 E <0.050 mg/L 03/20/3023 Hexachloro-1,3-butadtene (TCLP) SW 846 8270 E <0.050mg/L 03/20/3023 F{exachlorobenzene (TCLP) SW 846 8270 E <0.050 mg/L 03/20/3023 Hexachloroethane (TCLP) SW 846 8270 E <0.050 mg/L 03/20/3023 m + p-Cresol (TCLP) SW-846 8270 E <0.050 mg/L 03/20/3023 Nitrobenzene (TCLP) SW-846 8270 E <0.050 mg/L 03/20/3023 o-Cresol (TCLP) SW-846 8270 E <0.050 mg/L 03/20/3023 Pentachlorophenol (TCLP) SW-846 8270 E <0.250 mg/L 03/20/3023 Pyridine (TCLP) SW-846 8270 E <0.050 mg/L 03/20/3023 1, 1 -Dichloroethylene (TCLP) SW-846 Method 8260D < 0.01 mg/L 3/21/2023 1,2-Dichloroethane (TCLP) SW-846 Method8260D < 0.01 mg/L 3/21/2023 Report # 2023-05103 Page 1 of 5 envirochem ANALYTICAL_ & CONSULTING CHEMISTS Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 • 910.392.0223 Lab • 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax info;a environmentalchemists.com Town Of Morehead City 1100 Bridges Street Morehead City NC Attention: 28557 Date of Report: Apr 17, 2023 Customer PO #: Customer ID: 09020011 Report #: 2023-05103 Project ID: Sludge Benzene (TCLP) SW-846 Method 8260D < 0.01 mg/L 3/21/2023 Carbon Tetrachloride (TCLP) SW-846 Method 8260D < 0.01 mg/L 3/21/2023 Chlorobenzene (TCLP) SW-846 Method 8260D < 0.01 mg/L 3/21/2023 Chloroform (TCLP) SW-846 Method 8260D < 0.01 mg/L 3/21/2023 Methyl ethyl ketone (TCLP) SW-846 Method 8260D 0.05 mg/L 3/21/2023 Tetrachloroethylene (TCLP) SW-846 Method 8260D < 0.01 mg/L 3/21/2023 Trichloroethylene (TCLP) SW-846 Method 8260D < 0.01 mg/L 3/21/2023 Vinyl Chloride (TCLP) SW-846 Method 826oD < 0.01 mg/L 3/21/2023 RCI Ignitability EPA 1030 <0.8 mm/sec 03/21/2023 Cyanide SM 4500 CN o-2016 2.99 mg/kg 03/21 /2023 Sulfide SM 4500 S D <0.37 mg/kg 03/24/2023 Sludge Residuals Aluminum EPA 200.7, Rev 4.4, 1994 16900mg/kg 03/22/2023 Arsenic EPA 200.7,Rev 4.4 1994 10.9mg/kg 03/22/2023 Cadmium EPA 200.7, Rev 4.4, 1994 <6.19mg/kg 03/22/2023 Calcium EPA 200.7, Rev 4.4, 1994 57700mg/kg 03/22/2023 Chromium EPA 200.7, Rev 4.4, 1994 14.5 mg/kg 03/22/2023 Copper EPA 200.7, Rev 44, 1994 807 mg/kg 03/22/2023 Lead EPA 200.7, Rev 44 1994 15.8 mg/kg 03/22/2023 Magnesium EPA 200.7, Rev 4 4,1994 4430 mg/kg 03/22/2023 Molybdenum EPA 200.7, Rev 44 1994 <6.19 mg/kg 03/22/2023 Nickel EPA 200.7. Rev 44 1994 13.5 mg/kg 03/22/2023 Potassium EPA 200.7.Rev 4.4 1994 3820mg/kg 03/22/2023 Selenium EPA 200.7, Rev. 4.4, 1994 <6.19 mg/kg 03/22/2023 Sodium EPA 2007,.Rev. 4.4, 1994 4470 mg/kg 03/22/2023 Zinc EPA 200.7, Rev. 4.4. 1994 1240 mg/kg 03/22/2023 Nitrate+ N itrite-N itrogen EPA 353 2 1200 mg/kg 03/17/2023 Total Solids (%) SM 2540 a 23.9 % 03/15/2023 Ammonia Nitrogen SM 450o NH3 C-2011 622 mg/kg 03/15/2023 Report # 2023-05103 Page 2 of 5 Environmental Chemists, Inc. envirochem 6602 Windmill Way, Wilmington, NC 28405 , 910-392-0223 Lab • 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax ANALYTICAL & CONSULTING CHEMISTS info(a-environmentalchemists.com Town Of Morehead City 1100 Bridges Street Morehead City NC 28557 Attention: Date of Report: Apr 17, 2023 Customer PO #: Customer ID: 09020011 Report #: 2023-05103 Project ID: Sludge Total Kjeldahl Nitrogen (TKN) SM 4500 Norg B-2011 51000 mg/kg 03/15/2023 Total Phosphorus SM 4500 P (F-H)-2011 35200 mg/kg 03/23/2023 pH SW 846 Method 9045D 7.12 units 03/31 /2023 Result estimated. Analyzed out of 15 minutes hold time. Mercury SW-846 7471 B 0.988 mg/kg 03/17/2023 TCLP Metals Arsenic (TCLP) EPA 200.7. Rev. 4.4. 1994 <1.0 mg/L 03/22/2023 Barium (TCLP) EPA 200.7. Rev. 4.4. 1994 <1.0 mg/L 03/22/2023 Cadmium (TCLP) EPA 200.7, Rev. 4.4. 1994 <1.0 mg/L 03/22/2023 Chromium (TCLP) EPA 200.7. Rev. 4.4, 1994 <1.0 mg/L 03/22/2023 Lead (TCLP) EPA 200.7, Rev. 4.4,1994 <1.0 mg/L 03/22/2023 Selenium (TCLP) EPA 200.7, Rev. 4.4.1994 <1.0 mg/L 03/22/2023 Silver (TCLP) EPA 200.7, Rev. 4.4,1994 <1.0 mg/L 03/24/2023 Mercury (TCLP) EPA 245.1 <0.0002 mg/L 03/30/2023 Lab ID Sample ID: Collect Date/Time Matrix Sampled by 23-12699 Site: Sludge 1 3/14/2023 10:11 AM Solid/Sludge Nate Johnson Test Method Results Date Analyzed Total Solids (%) SM 2540 B 202 % 03/15/2023 Fecal Density SM 9221C E-2014 65 MPN/g 03/14/2023 Lab ID Sample ID: Collect DatelTime Matrix Sampled by 23-12700 Site: Sludge 2 3/14/2023 10:12 AM Solid/Sludge Nate Johnson Test Method Results Date Analyzed Total Solids (%) SM 2540 B 20.0 % 03/15/2023 Fecal Density SM 9221C E-2014 10 MPN/g 03/14/2023 Report # 2023.05103 Page 3 of 5 [en7virochem ANALYTICAL & CONSULTING CHEMISTS Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 • 910.392.0223 Lab • 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax info;, �environmentalchemists.com Town Of Morehead City Date of Report: Apr 17, 2023 1100 Bridges Street Customer PO #: Morehead City NC 28557 Customer ID: 09020011 Attention: Report #: 2023-05103 Project ID: Sludge Lab ID Sample ID: Collect DatelTime Matrix Sampled by 23-12701 Site: Sludge 3 3/14/2023 10:13 AM Solid/Sludge Nate Johnson Test Method Results Date Analyzed Total Solids (%) SM 2540 B 20.8 % 03/15/2023 Fecal Density SM 9221C E-2014 10 MPN/g 03/14/2023 Lab ID Sample ID: Collect Date/Time Matrix Sampled by 23-12702 Site: Sludge 4 3/14/2023 10:14 AM Solid/Sludge Nate Johnson Test Method Results Date Analyzed Total Solids (%) SM 2540 B 23.1 % 03/15/2023 Fecal Density SM 9221C E-2014 <8 MPN/g 03/14/2023 Lab ID Sample ID: Collect Date/Time Matrix Sampled by 23-12703 Site: Sludge 5 3/14/2023 10:15 AM Solid/Sludge Nate Johnson Test Method Results Date Analyzed Total Solids (%) SM 2540 B 20.5 % 03/15/2023 Fecal Density SM 9221C E-2014 <9 MPN/g 03/14/2023 Lab ID Sample ID: Collect DatelTime Matrix Sampled by 23-12704 Site: Sludge 6 3/14/2023 10:16 AM Solid/Sludge Nate Johnson Test Method Results Date Analyzed Total Solids (%) SM 2540 B 20.7 % 03/15/2023 Fecal Density SM 9221C E-2014 38 MPN/g 03/14/2023 Lab ID Sample ID: Collect Date/Time Matrix Sampled by 23-12705 Site: Sludge 7 3/14/2023 10:17 AM Solid/Sludge Nate Johnson Test Method Results Date Analyzed Total Solids (%) SM 2540 B 20.6 % 03/15/2023 Fecal Density SM 9221C E-2014 <9 MPN/g 03/14/2023 Report #: 2023-05103 Page 4 of 5 envirochem ANALYTICAL & CONSULTING CHEMISTS Town Of Morehead City 1100 Bridges Street Morehead City NC Attention: Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 • 910.392.0223 Lab • 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax info@environmentalchemists.com Date of Report: Apr 17, 2023 Customer PO #: 28557 Customer ID: 09020011 Report #: 2023-05103 Project ID: Sludge Comment: Sludge residuals, except pH, reported on a dry weight basis. pH reported on an as received basis. Reviewed by: �- Report #:: 2023-05103 Page 5 of 5 Environmental Chemist, Inc., Wilmington, NC Lab #94 6602 Windmill Way Wilmington, NC 28405 910,392.0223 Sample Receipt Checklist Client: Date: 1 Report Number: _ 2023- 0510 W Receipt of sample: ECHEM Pickup-19 Client Delivery ❑ IUPS ❑ Fed Ex ❑ Other ❑ ❑ YES ❑ NO JEO N/A If. Were custody seals present on the cooler? ❑ YES ID NO N/A 12, If custody seals were present, were they intact/unbroken? Original temperature upon receipt 'C Corrected temperature upon receipt °C How temperature taken: ❑ Temperature Blank 14 Against Bottles IR Gun ID: Thomas Traceable S/N 210886869 lR Gun Correction Factor `C: 0.0 YES YES ❑ NO ❑ NO 3. If temperature of cooler exceeded 6°C, was Project Mgr./QA notified? 4. Were proper custody procedures (relinquished/received) followed? YES ❑ NO 5. Were sample ID's listed on the COC? YES ❑ NO 6. Were samples ID's listed on sample containers? YES ❑ NO 7. Were collection date and time listed on the COC? YES ❑ NO 8. Were tests to be performed listed on the COC? Y:ES ❑ NO 9. Did samples arrive in proper containers for each test? J1 YES ❑ NO 10. Did samples arrive in good condition for each test? YES ❑ NO 11. Was adequate sample volume available?' YES ❑ YES ❑ NO ❑ NO 12. Were samples received within proper holding t me for requested tests? 13. Were acid preserved samples received at a pH of <2? ❑ YES ❑ NO 14. Were cyanide samples received at a pH >12? ❑ YES ❑ NO 15. Were sulfide samples received at a pH >9? ❑ YES ❑ NO 16. Were NH3/TKN/Phenol received at a chlorine residual of <0.5 m/L? ❑ YES ❑ NO 17. Were Su'fide/Cyanide received at a chlorine res dual of <0.5 m/L? ❑ YES ❑ NO 18. Were orthophosphate samples f Itered in the field within 15 minutes? * TOC/Volatiles are pH checked at time of analysis and recorded on the benchsheet ** Bacteria samples are checked for Chlorine at time of analysis and recorded on the benchsheet. Sample Preservation: (Must be completed for any sample(s) incorrectly preserved or with headspace) Sample(s) were received incorrectly preserved and were adjusted accord ngly by adding (circle one): HzSO, HNO3 HCI NaOH Time of preservation: If more than one preservative is needed, notate in comments below Note Not'fy custome� sery ce immed ate y for ncorrectly preserved samp es Obtain a new sample or notify the state lab f d rected to a la yzed by the customer who was not fled date and t me Volatiles Samples) were received with headspace COMMENTS: DOC. QA.002 Rev 1 Fd� s = ' - 3 i d jF3, 2 r -e _� S i i 3 C� ! r }' 4 f }it ~^ A ..r=• f if g aa ,W W F qmn E = 31Y; .. w' j yr i Jratf 13 Ju IVs � � � SECTION 3 FACILITY NAME: MOREHEAD CITY, NO LANDOWNER: DEBRA JO WETHERINGTON OPERATOR: ROBERT M. RIGGS CROP 1 NAME: SOYBEANS (SB) RESIDUAL SOU RCE(S): ' See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: WQ0006018 FIELD#: NC-CR-00007-0-0002- ANNUAL DRY TONS APPLIED: 55.36 SITE #: NO CR 00007 PREDOMINANT SOIL SERIES: AUTRYVILLE CROP 1 MAX. PAN: 137 CROP 2 NAME: ACRES UTILIZED: 20.6 ACRES PERMITTED: 20.6 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Page: 1 Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (lbs/acre) Application Month Solids Dry Tons/Ao Source Moist Inches Method' Rate— Rate— mg/kg mglkg mg/kg Amount UOM Crop 1 Crop 2 Crop 1 Crap 2 5/3/2023 200.00 (Y) 23.900 1.954 MOCC DRY 0-<1/2"" SURIN 1,0 0.30 51,000.00 622.00 1,200.00 66,194 SB 5/4/2023 75,00 (Y) 23.900 0.733 MOCC DRY 0-<1/2"" SURIN 1.0 0.30 51,000.00 622.00 1,200.00 24.823 SB May-23 275.00 (Y) I UWE `•O°` Total 91.017 0.000 AS CD CU CR PB HG MO NI SE ZN P FLime Applied LAnuallbs/acre Applied 0.059 0.033 4.337 0.078 0.085 0.005 D.033 0.073 0.033 6.664 189.177 Date LbslAc Cumulative Ibs/acreApplied — 0.401 1 0A67 1 54,289 2.632 1 1.024 j 0.125 j 0.343 I 1,306 0.300 54.899 Permit PAN Limit (Ibslacre) 1st CropE I I J 1 I 137 Federal C.P.L.R. (lbs/acre)*"" 36.6 34.8 1,339.0 267.9 15.0 375.0 89.0 2,500.0 MOCC = MOREHEAD CITY, NO CAKE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are signific t e pities for submitting false information, including the possibility of fines and imprisonment for knowing violations." SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, iNJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * ** See Site pH & Lime Application Records Section of Report Printed: 2/2/2024 DENR FORM FSF (12/2006) SECTION 4 6enviroche]mj ANALYTICAL & CONSULTING CHEMISTS Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 • 910-392.0223 Lab - 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax info -a environmentaichemists.com Town Of Morehead City Date of Report: Apr 17, 2023 1100 Bridges Street Customer PO #: Morehead City NC 28557 Customer ID: 09020011 Attention: Report #: 2023-05103 Project ID: Sludge Lab ID Sample ID: Collect Date/Time Matrix Sampled by 23-12698 Site: Sludge 3/14/2023 10:10 AM Solid/Sludge Nate Johnson Test Method Results Date Analyzed C C E AOAC 1 005 0.0 % 04/ 13/2023 Paint Filter Test SW 846 Method 9095 A pass 04/14/2023 Chlordane (TCLP) SW-846 8081 B <0.005mg/L 03/20/2023 Endrin (TCLP) SW-846 8081 B <0.00005 mg/L 03/20/2023 Heptachlor (TCLP) SW-846 8081 B <0.00005 mg/L 03/20/2023 Heptachlor epoxide (TCLP) SW446 8081 B <0.00005 mg/L 03/20/2023 Lindane (TCLP) SW-846 8081 a <0.00005 mg/L 03/20/2023 Methoxychlor (TCLP) Sw446 8081 B <0.00005 mg/L 03/20/2023 Toxaphene (TCLP) SW-846 8081 B <0.005 mg/L 03/20/2023 2,4,5-TP (TCLP) SW-846 8151 A <0.003 mg/L 03/17/2023 2,4-D (TCLP) SW-846 8151 A <0.003 mg/L 03/17/2023 1,4-Dichlorobenzene (TCLP) SW-846 8270 E <0.050 mg/L 03/20/3023 2,4,5-Trichlorophenol (TCLP) SW 846 8270 E <0.050 mg/L 03/20/3023 2,4,6-Trlchlorophenol (TCLP) SW-846 8270 E <0.050 mg/L 03/20/3023 2,4-Dinitrotoluene (TCLP) SW-846 8270 E <0.050 mg/L 03/20/3023 Cresol (TCLP) SW-846 8270 E <0.050 mg/L 03/20/3023 Hexachloro-1,3-butadtene (TCLP) SW 846 8270 E <0.050mg/L 03/20/3023 F{exachlorobenzene (TCLP) SW 846 8270 E <0.050 mg/L 03/20/3023 Hexachloroethane (TCLP) SW 846 8270 E <0.050 mg/L 03/20/3023 m + p-Cresol (TCLP) SW-846 8270 E <0.050 mg/L 03/20/3023 Nitrobenzene (TCLP) SW-846 8270 E <0.050 mg/L 03/20/3023 o-Cresol (TCLP) SW-846 8270 E <0.050 mg/L 03/20/3023 Pentachlorophenol (TCLP) SW-846 8270 E <0.250 mg/L 03/20/3023 Pyridine (TCLP) SW-846 8270 E <0.050 mg/L 03/20/3023 1, 1 -Dichloroethylene (TCLP) SW-846 Method 8260D < 0.01 mg/L 3/21/2023 1,2-Dichloroethane (TCLP) SW-846 Method8260D < 0.01 mg/L 3/21/2023 Report # 2023-05103 Page 1 of 5 envirochem ANALYTICAL_ & CONSULTING CHEMISTS Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 • 910.392.0223 Lab • 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax info;a environmentalchemists.com Town Of Morehead City 1100 Bridges Street Morehead City NC Attention: 28557 Date of Report: Apr 17, 2023 Customer PO #: Customer ID: 09020011 Report #: 2023-05103 Project ID: Sludge Benzene (TCLP) SW-846 Method 8260D < 0.01 mg/L 3/21/2023 Carbon Tetrachloride (TCLP) SW-846 Method 8260D < 0.01 mg/L 3/21/2023 Chlorobenzene (TCLP) SW-846 Method 8260D < 0.01 mg/L 3/21/2023 Chloroform (TCLP) SW-846 Method 8260D < 0.01 mg/L 3/21/2023 Methyl ethyl ketone (TCLP) SW-846 Method 8260D 0.05 mg/L 3/21/2023 Tetrachloroethylene (TCLP) SW-846 Method 8260D < 0.01 mg/L 3/21/2023 Trichloroethylene (TCLP) SW-846 Method 8260D < 0.01 mg/L 3/21/2023 Vinyl Chloride (TCLP) SW-846 Method 826oD < 0.01 mg/L 3/21/2023 RCI Ignitability EPA 1030 <0.8 mm/sec 03/21/2023 Cyanide SM 4500 CN o-2016 2.99 mg/kg 03/21 /2023 Sulfide SM 4500 S D <0.37 mg/kg 03/24/2023 Sludge Residuals Aluminum EPA 200.7, Rev 4.4, 1994 16900mg/kg 03/22/2023 Arsenic EPA 200.7,Rev 4.4 1994 10.9mg/kg 03/22/2023 Cadmium EPA 200.7, Rev 4.4, 1994 <6.19mg/kg 03/22/2023 Calcium EPA 200.7, Rev 4.4, 1994 57700mg/kg 03/22/2023 Chromium EPA 200.7, Rev 4.4, 1994 14.5 mg/kg 03/22/2023 Copper EPA 200.7, Rev 44, 1994 807 mg/kg 03/22/2023 Lead EPA 200.7, Rev 44 1994 15.8 mg/kg 03/22/2023 Magnesium EPA 200.7, Rev 4 4,1994 4430 mg/kg 03/22/2023 Molybdenum EPA 200.7, Rev 44 1994 <6.19 mg/kg 03/22/2023 Nickel EPA 200.7. Rev 44 1994 13.5 mg/kg 03/22/2023 Potassium EPA 200.7.Rev 4.4 1994 3820mg/kg 03/22/2023 Selenium EPA 200.7, Rev. 4.4, 1994 <6.19 mg/kg 03/22/2023 Sodium EPA 2007,.Rev. 4.4, 1994 4470 mg/kg 03/22/2023 Zinc EPA 200.7, Rev. 4.4. 1994 1240 mg/kg 03/22/2023 Nitrate+ N itrite-N itrogen EPA 353 2 1200 mg/kg 03/17/2023 Total Solids (%) SM 2540 a 23.9 % 03/15/2023 Ammonia Nitrogen SM 450o NH3 C-2011 622 mg/kg 03/15/2023 Report # 2023-05103 Page 2 of 5 Environmental Chemists, Inc. envirochem 6602 Windmill Way, Wilmington, NC 28405 , 910-392-0223 Lab • 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax ANALYTICAL & CONSULTING CHEMISTS info(a-environmentalchemists.com Town Of Morehead City 1100 Bridges Street Morehead City NC 28557 Attention: Date of Report: Apr 17, 2023 Customer PO #: Customer ID: 09020011 Report #: 2023-05103 Project ID: Sludge Total Kjeldahl Nitrogen (TKN) SM 4500 Norg B-2011 51000 mg/kg 03/15/2023 Total Phosphorus SM 4500 P (F-H)-2011 35200 mg/kg 03/23/2023 pH SW 846 Method 9045D 7.12 units 03/31 /2023 Result estimated. Analyzed out of 15 minutes hold time. Mercury SW-846 7471 B 0.988 mg/kg 03/17/2023 TCLP Metals Arsenic (TCLP) EPA 200.7. Rev. 4.4. 1994 <1.0 mg/L 03/22/2023 Barium (TCLP) EPA 200.7. Rev. 4.4. 1994 <1.0 mg/L 03/22/2023 Cadmium (TCLP) EPA 200.7, Rev. 4.4. 1994 <1.0 mg/L 03/22/2023 Chromium (TCLP) EPA 200.7. Rev. 4.4, 1994 <1.0 mg/L 03/22/2023 Lead (TCLP) EPA 200.7, Rev. 4.4,1994 <1.0 mg/L 03/22/2023 Selenium (TCLP) EPA 200.7, Rev. 4.4.1994 <1.0 mg/L 03/22/2023 Silver (TCLP) EPA 200.7, Rev. 4.4,1994 <1.0 mg/L 03/24/2023 Mercury (TCLP) EPA 245.1 <0.0002 mg/L 03/30/2023 Lab ID Sample ID: Collect Date/Time Matrix Sampled by 23-12699 Site: Sludge 1 3/14/2023 10:11 AM Solid/Sludge Nate Johnson Test Method Results Date Analyzed Total Solids (%) SM 2540 B 202 % 03/15/2023 Fecal Density SM 9221C E-2014 65 MPN/g 03/14/2023 Lab ID Sample ID: Collect DatelTime Matrix Sampled by 23-12700 Site: Sludge 2 3/14/2023 10:12 AM Solid/Sludge Nate Johnson Test Method Results Date Analyzed Total Solids (%) SM 2540 B 20.0 % 03/15/2023 Fecal Density SM 9221C E-2014 10 MPN/g 03/14/2023 Report # 2023.05103 Page 3 of 5 [en7virochem ANALYTICAL & CONSULTING CHEMISTS Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 • 910.392.0223 Lab • 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax info;, �environmentalchemists.com Town Of Morehead City Date of Report: Apr 17, 2023 1100 Bridges Street Customer PO #: Morehead City NC 28557 Customer ID: 09020011 Attention: Report #: 2023-05103 Project ID: Sludge Lab ID Sample ID: Collect DatelTime Matrix Sampled by 23-12701 Site: Sludge 3 3/14/2023 10:13 AM Solid/Sludge Nate Johnson Test Method Results Date Analyzed Total Solids (%) SM 2540 B 20.8 % 03/15/2023 Fecal Density SM 9221C E-2014 10 MPN/g 03/14/2023 Lab ID Sample ID: Collect Date/Time Matrix Sampled by 23-12702 Site: Sludge 4 3/14/2023 10:14 AM Solid/Sludge Nate Johnson Test Method Results Date Analyzed Total Solids (%) SM 2540 B 23.1 % 03/15/2023 Fecal Density SM 9221C E-2014 <8 MPN/g 03/14/2023 Lab ID Sample ID: Collect Date/Time Matrix Sampled by 23-12703 Site: Sludge 5 3/14/2023 10:15 AM Solid/Sludge Nate Johnson Test Method Results Date Analyzed Total Solids (%) SM 2540 B 20.5 % 03/15/2023 Fecal Density SM 9221C E-2014 <9 MPN/g 03/14/2023 Lab ID Sample ID: Collect DatelTime Matrix Sampled by 23-12704 Site: Sludge 6 3/14/2023 10:16 AM Solid/Sludge Nate Johnson Test Method Results Date Analyzed Total Solids (%) SM 2540 B 20.7 % 03/15/2023 Fecal Density SM 9221C E-2014 38 MPN/g 03/14/2023 Lab ID Sample ID: Collect Date/Time Matrix Sampled by 23-12705 Site: Sludge 7 3/14/2023 10:17 AM Solid/Sludge Nate Johnson Test Method Results Date Analyzed Total Solids (%) SM 2540 B 20.6 % 03/15/2023 Fecal Density SM 9221C E-2014 <9 MPN/g 03/14/2023 Report #: 2023-05103 Page 4 of 5 envirochem ANALYTICAL & CONSULTING CHEMISTS Town Of Morehead City 1100 Bridges Street Morehead City NC Attention: Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 • 910.392.0223 Lab • 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax info@environmentalchemists.com Date of Report: Apr 17, 2023 Customer PO #: 28557 Customer ID: 09020011 Report #: 2023-05103 Project ID: Sludge Comment: Sludge residuals, except pH, reported on a dry weight basis. pH reported on an as received basis. Reviewed by: �- Report #:: 2023-05103 Page 5 of 5 Environmental Chemist, Inc., Wilmington, NC Lab #94 6602 Windmill Way Wilmington, NC 28405 910,392.0223 Sample Receipt Checklist Client: Date: 1 Report Number: _ 2023- 0510 W Receipt of sample: ECHEM Pickup-19 Client Delivery ❑ IUPS ❑ Fed Ex ❑ Other ❑ ❑ YES ❑ NO JEO N/A If. Were custody seals present on the cooler? ❑ YES ID NO N/A 12, If custody seals were present, were they intact/unbroken? Original temperature upon receipt 'C Corrected temperature upon receipt °C How temperature taken: ❑ Temperature Blank 14 Against Bottles IR Gun ID: Thomas Traceable S/N 210886869 lR Gun Correction Factor `C: 0.0 YES YES ❑ NO ❑ NO 3. If temperature of cooler exceeded 6°C, was Project Mgr./QA notified? 4. Were proper custody procedures (relinquished/received) followed? YES ❑ NO 5. Were sample ID's listed on the COC? YES ❑ NO 6. Were samples ID's listed on sample containers? YES ❑ NO 7. Were collection date and time listed on the COC? YES ❑ NO 8. Were tests to be performed listed on the COC? Y:ES ❑ NO 9. Did samples arrive in proper containers for each test? J1 YES ❑ NO 10. Did samples arrive in good condition for each test? YES ❑ NO 11. Was adequate sample volume available?' YES ❑ YES ❑ NO ❑ NO 12. Were samples received within proper holding t me for requested tests? 13. Were acid preserved samples received at a pH of <2? ❑ YES ❑ NO 14. Were cyanide samples received at a pH >12? ❑ YES ❑ NO 15. Were sulfide samples received at a pH >9? ❑ YES ❑ NO 16. Were NH3/TKN/Phenol received at a chlorine residual of <0.5 m/L? ❑ YES ❑ NO 17. Were Su'fide/Cyanide received at a chlorine res dual of <0.5 m/L? ❑ YES ❑ NO 18. Were orthophosphate samples f Itered in the field within 15 minutes? * TOC/Volatiles are pH checked at time of analysis and recorded on the benchsheet ** Bacteria samples are checked for Chlorine at time of analysis and recorded on the benchsheet. Sample Preservation: (Must be completed for any sample(s) incorrectly preserved or with headspace) Sample(s) were received incorrectly preserved and were adjusted accord ngly by adding (circle one): HzSO, HNO3 HCI NaOH Time of preservation: If more than one preservative is needed, notate in comments below Note Not'fy custome� sery ce immed ate y for ncorrectly preserved samp es Obtain a new sample or notify the state lab f d rected to a la yzed by the customer who was not fled date and t me Volatiles Samples) were received with headspace COMMENTS: DOC. QA.002 Rev 1 Fd� s = ' - 3 i d jF3, 2 r -e _� S i i 3 C� ! r }' 4 f }it ~^ A ..r=• f if g aa ,W W F qmn E = 31Y; .. w' j yr i Jratf 13 Ju IVs � � � SECTION 5 ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Town of Morehead City WQ Permit Number: W00006018 WWTP Name: Town of Morehead City WWTP NPDES Number: NCO026611 Monitoring Period: From 01/01/2023 To 12/31/2023 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. I/A (time/temp) Alt. 2B (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion If annlicahle to alternative nerfarmed 11'1asc A nr Clacc Rl ommnlete the fallnwina mnnitnrina datw Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units dences Analysis Fecal 2x10to the 61 MPN 8 14.86 65 MPN/g 0 Annually Grab SM922ICE Coliform power per gram of total solids MPN 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503-33/15A NCAC 02T.1107) - Please indicate option/alternative performed: Option/Alt. 1 Option/Alt. 2 Option/Alt. 3 Option/Alt. 4 (VS reduction) (40-day bench) (30-day bench) (Spec. 02 uptake) 0ption/Alt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) X No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Daniel Williams, Public Utilities Director Todd Larson Operations Director pare and t (type or print) Land App per Name an Title applicable) (type or pent 2- 13 - Zt% 2/01/2024 Signature of Preparer* Date Signatur App ' r (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) 6enviroche]mj ANALYTICAL & CONSULTING CHEMISTS Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 • 910-392.0223 Lab - 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax info -a environmentaichemists.com Town Of Morehead City Date of Report: Apr 17, 2023 1100 Bridges Street Customer PO #: Morehead City NC 28557 Customer ID: 09020011 Attention: Report #: 2023-05103 Project ID: Sludge Lab ID Sample ID: Collect Date/Time Matrix Sampled by 23-12698 Site: Sludge 3/14/2023 10:10 AM Solid/Sludge Nate Johnson Test Method Results Date Analyzed C C E AOAC 1 005 0.0 % 04/ 13/2023 Paint Filter Test SW 846 Method 9095 A pass 04/14/2023 Chlordane (TCLP) SW-846 8081 B <0.005mg/L 03/20/2023 Endrin (TCLP) SW-846 8081 B <0.00005 mg/L 03/20/2023 Heptachlor (TCLP) SW-846 8081 B <0.00005 mg/L 03/20/2023 Heptachlor epoxide (TCLP) SW446 8081 B <0.00005 mg/L 03/20/2023 Lindane (TCLP) SW-846 8081 a <0.00005 mg/L 03/20/2023 Methoxychlor (TCLP) Sw446 8081 B <0.00005 mg/L 03/20/2023 Toxaphene (TCLP) SW-846 8081 B <0.005 mg/L 03/20/2023 2,4,5-TP (TCLP) SW-846 8151 A <0.003 mg/L 03/17/2023 2,4-D (TCLP) SW-846 8151 A <0.003 mg/L 03/17/2023 1,4-Dichlorobenzene (TCLP) SW-846 8270 E <0.050 mg/L 03/20/3023 2,4,5-Trichlorophenol (TCLP) SW 846 8270 E <0.050 mg/L 03/20/3023 2,4,6-Trlchlorophenol (TCLP) SW-846 8270 E <0.050 mg/L 03/20/3023 2,4-Dinitrotoluene (TCLP) SW-846 8270 E <0.050 mg/L 03/20/3023 Cresol (TCLP) SW-846 8270 E <0.050 mg/L 03/20/3023 Hexachloro-1,3-butadtene (TCLP) SW 846 8270 E <0.050mg/L 03/20/3023 F{exachlorobenzene (TCLP) SW 846 8270 E <0.050 mg/L 03/20/3023 Hexachloroethane (TCLP) SW 846 8270 E <0.050 mg/L 03/20/3023 m + p-Cresol (TCLP) SW-846 8270 E <0.050 mg/L 03/20/3023 Nitrobenzene (TCLP) SW-846 8270 E <0.050 mg/L 03/20/3023 o-Cresol (TCLP) SW-846 8270 E <0.050 mg/L 03/20/3023 Pentachlorophenol (TCLP) SW-846 8270 E <0.250 mg/L 03/20/3023 Pyridine (TCLP) SW-846 8270 E <0.050 mg/L 03/20/3023 1, 1 -Dichloroethylene (TCLP) SW-846 Method 8260D < 0.01 mg/L 3/21/2023 1,2-Dichloroethane (TCLP) SW-846 Method8260D < 0.01 mg/L 3/21/2023 Report # 2023-05103 Page 1 of 5 envirochem ANALYTICAL_ & CONSULTING CHEMISTS Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 • 910.392.0223 Lab • 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax info;a environmentalchemists.com Town Of Morehead City 1100 Bridges Street Morehead City NC Attention: 28557 Date of Report: Apr 17, 2023 Customer PO #: Customer ID: 09020011 Report #: 2023-05103 Project ID: Sludge Benzene (TCLP) SW-846 Method 8260D < 0.01 mg/L 3/21/2023 Carbon Tetrachloride (TCLP) SW-846 Method 8260D < 0.01 mg/L 3/21/2023 Chlorobenzene (TCLP) SW-846 Method 8260D < 0.01 mg/L 3/21/2023 Chloroform (TCLP) SW-846 Method 8260D < 0.01 mg/L 3/21/2023 Methyl ethyl ketone (TCLP) SW-846 Method 8260D 0.05 mg/L 3/21/2023 Tetrachloroethylene (TCLP) SW-846 Method 8260D < 0.01 mg/L 3/21/2023 Trichloroethylene (TCLP) SW-846 Method 8260D < 0.01 mg/L 3/21/2023 Vinyl Chloride (TCLP) SW-846 Method 826oD < 0.01 mg/L 3/21/2023 RCI Ignitability EPA 1030 <0.8 mm/sec 03/21/2023 Cyanide SM 4500 CN o-2016 2.99 mg/kg 03/21 /2023 Sulfide SM 4500 S D <0.37 mg/kg 03/24/2023 Sludge Residuals Aluminum EPA 200.7, Rev 4.4, 1994 16900mg/kg 03/22/2023 Arsenic EPA 200.7,Rev 4.4 1994 10.9mg/kg 03/22/2023 Cadmium EPA 200.7, Rev 4.4, 1994 <6.19mg/kg 03/22/2023 Calcium EPA 200.7, Rev 4.4, 1994 57700mg/kg 03/22/2023 Chromium EPA 200.7, Rev 4.4, 1994 14.5 mg/kg 03/22/2023 Copper EPA 200.7, Rev 44, 1994 807 mg/kg 03/22/2023 Lead EPA 200.7, Rev 44 1994 15.8 mg/kg 03/22/2023 Magnesium EPA 200.7, Rev 4 4,1994 4430 mg/kg 03/22/2023 Molybdenum EPA 200.7, Rev 44 1994 <6.19 mg/kg 03/22/2023 Nickel EPA 200.7. Rev 44 1994 13.5 mg/kg 03/22/2023 Potassium EPA 200.7.Rev 4.4 1994 3820mg/kg 03/22/2023 Selenium EPA 200.7, Rev. 4.4, 1994 <6.19 mg/kg 03/22/2023 Sodium EPA 2007,.Rev. 4.4, 1994 4470 mg/kg 03/22/2023 Zinc EPA 200.7, Rev. 4.4. 1994 1240 mg/kg 03/22/2023 Nitrate+ N itrite-N itrogen EPA 353 2 1200 mg/kg 03/17/2023 Total Solids (%) SM 2540 a 23.9 % 03/15/2023 Ammonia Nitrogen SM 450o NH3 C-2011 622 mg/kg 03/15/2023 Report # 2023-05103 Page 2 of 5 Environmental Chemists, Inc. envirochem 6602 Windmill Way, Wilmington, NC 28405 , 910-392-0223 Lab • 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax ANALYTICAL & CONSULTING CHEMISTS info(a-environmentalchemists.com Town Of Morehead City 1100 Bridges Street Morehead City NC 28557 Attention: Date of Report: Apr 17, 2023 Customer PO #: Customer ID: 09020011 Report #: 2023-05103 Project ID: Sludge Total Kjeldahl Nitrogen (TKN) SM 4500 Norg B-2011 51000 mg/kg 03/15/2023 Total Phosphorus SM 4500 P (F-H)-2011 35200 mg/kg 03/23/2023 pH SW 846 Method 9045D 7.12 units 03/31 /2023 Result estimated. Analyzed out of 15 minutes hold time. Mercury SW-846 7471 B 0.988 mg/kg 03/17/2023 TCLP Metals Arsenic (TCLP) EPA 200.7. Rev. 4.4. 1994 <1.0 mg/L 03/22/2023 Barium (TCLP) EPA 200.7. Rev. 4.4. 1994 <1.0 mg/L 03/22/2023 Cadmium (TCLP) EPA 200.7, Rev. 4.4. 1994 <1.0 mg/L 03/22/2023 Chromium (TCLP) EPA 200.7. Rev. 4.4, 1994 <1.0 mg/L 03/22/2023 Lead (TCLP) EPA 200.7, Rev. 4.4,1994 <1.0 mg/L 03/22/2023 Selenium (TCLP) EPA 200.7, Rev. 4.4.1994 <1.0 mg/L 03/22/2023 Silver (TCLP) EPA 200.7, Rev. 4.4,1994 <1.0 mg/L 03/24/2023 Mercury (TCLP) EPA 245.1 <0.0002 mg/L 03/30/2023 Lab ID Sample ID: Collect Date/Time Matrix Sampled by 23-12699 Site: Sludge 1 3/14/2023 10:11 AM Solid/Sludge Nate Johnson Test Method Results Date Analyzed Total Solids (%) SM 2540 B 202 % 03/15/2023 Fecal Density SM 9221C E-2014 65 MPN/g 03/14/2023 Lab ID Sample ID: Collect DatelTime Matrix Sampled by 23-12700 Site: Sludge 2 3/14/2023 10:12 AM Solid/Sludge Nate Johnson Test Method Results Date Analyzed Total Solids (%) SM 2540 B 20.0 % 03/15/2023 Fecal Density SM 9221C E-2014 10 MPN/g 03/14/2023 Report # 2023.05103 Page 3 of 5 [en7virochem ANALYTICAL & CONSULTING CHEMISTS Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 • 910.392.0223 Lab • 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax info;, �environmentalchemists.com Town Of Morehead City Date of Report: Apr 17, 2023 1100 Bridges Street Customer PO #: Morehead City NC 28557 Customer ID: 09020011 Attention: Report #: 2023-05103 Project ID: Sludge Lab ID Sample ID: Collect DatelTime Matrix Sampled by 23-12701 Site: Sludge 3 3/14/2023 10:13 AM Solid/Sludge Nate Johnson Test Method Results Date Analyzed Total Solids (%) SM 2540 B 20.8 % 03/15/2023 Fecal Density SM 9221C E-2014 10 MPN/g 03/14/2023 Lab ID Sample ID: Collect Date/Time Matrix Sampled by 23-12702 Site: Sludge 4 3/14/2023 10:14 AM Solid/Sludge Nate Johnson Test Method Results Date Analyzed Total Solids (%) SM 2540 B 23.1 % 03/15/2023 Fecal Density SM 9221C E-2014 <8 MPN/g 03/14/2023 Lab ID Sample ID: Collect Date/Time Matrix Sampled by 23-12703 Site: Sludge 5 3/14/2023 10:15 AM Solid/Sludge Nate Johnson Test Method Results Date Analyzed Total Solids (%) SM 2540 B 20.5 % 03/15/2023 Fecal Density SM 9221C E-2014 <9 MPN/g 03/14/2023 Lab ID Sample ID: Collect DatelTime Matrix Sampled by 23-12704 Site: Sludge 6 3/14/2023 10:16 AM Solid/Sludge Nate Johnson Test Method Results Date Analyzed Total Solids (%) SM 2540 B 20.7 % 03/15/2023 Fecal Density SM 9221C E-2014 38 MPN/g 03/14/2023 Lab ID Sample ID: Collect Date/Time Matrix Sampled by 23-12705 Site: Sludge 7 3/14/2023 10:17 AM Solid/Sludge Nate Johnson Test Method Results Date Analyzed Total Solids (%) SM 2540 B 20.6 % 03/15/2023 Fecal Density SM 9221C E-2014 <9 MPN/g 03/14/2023 Report #: 2023-05103 Page 4 of 5 envirochem ANALYTICAL & CONSULTING CHEMISTS Town Of Morehead City 1100 Bridges Street Morehead City NC Attention: Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 • 910.392.0223 Lab • 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax info@environmentalchemists.com Date of Report: Apr 17, 2023 Customer PO #: 28557 Customer ID: 09020011 Report #: 2023-05103 Project ID: Sludge Comment: Sludge residuals, except pH, reported on a dry weight basis. pH reported on an as received basis. Reviewed by: �- Report #:: 2023-05103 Page 5 of 5 Environmental Chemist, Inc., Wilmington, NC Lab #94 6602 Windmill Way Wilmington, NC 28405 910,392.0223 Sample Receipt Checklist Client: Date: 1 Report Number: _ 2023- 0510 W Receipt of sample: ECHEM Pickup-19 Client Delivery ❑ IUPS ❑ Fed Ex ❑ Other ❑ ❑ YES ❑ NO JEO N/A If. Were custody seals present on the cooler? ❑ YES ID NO N/A 12, If custody seals were present, were they intact/unbroken? Original temperature upon receipt 'C Corrected temperature upon receipt °C How temperature taken: ❑ Temperature Blank 14 Against Bottles IR Gun ID: Thomas Traceable S/N 210886869 lR Gun Correction Factor `C: 0.0 YES YES ❑ NO ❑ NO 3. If temperature of cooler exceeded 6°C, was Project Mgr./QA notified? 4. Were proper custody procedures (relinquished/received) followed? YES ❑ NO 5. Were sample ID's listed on the COC? YES ❑ NO 6. Were samples ID's listed on sample containers? YES ❑ NO 7. Were collection date and time listed on the COC? YES ❑ NO 8. Were tests to be performed listed on the COC? Y:ES ❑ NO 9. Did samples arrive in proper containers for each test? J1 YES ❑ NO 10. Did samples arrive in good condition for each test? YES ❑ NO 11. Was adequate sample volume available?' YES ❑ YES ❑ NO ❑ NO 12. Were samples received within proper holding t me for requested tests? 13. Were acid preserved samples received at a pH of <2? ❑ YES ❑ NO 14. Were cyanide samples received at a pH >12? ❑ YES ❑ NO 15. Were sulfide samples received at a pH >9? ❑ YES ❑ NO 16. Were NH3/TKN/Phenol received at a chlorine residual of <0.5 m/L? ❑ YES ❑ NO 17. Were Su'fide/Cyanide received at a chlorine res dual of <0.5 m/L? ❑ YES ❑ NO 18. Were orthophosphate samples f Itered in the field within 15 minutes? * TOC/Volatiles are pH checked at time of analysis and recorded on the benchsheet ** Bacteria samples are checked for Chlorine at time of analysis and recorded on the benchsheet. Sample Preservation: (Must be completed for any sample(s) incorrectly preserved or with headspace) Sample(s) were received incorrectly preserved and were adjusted accord ngly by adding (circle one): HzSO, HNO3 HCI NaOH Time of preservation: If more than one preservative is needed, notate in comments below Note Not'fy custome� sery ce immed ate y for ncorrectly preserved samp es Obtain a new sample or notify the state lab f d rected to a la yzed by the customer who was not fled date and t me Volatiles Samples) were received with headspace COMMENTS: DOC. QA.002 Rev 1 Fd� s = ' - 3 i d jF3, 2 r -e _� S i i 3 C� ! r }' 4 f }it ~^ A ..r=• f if g aa ,W W F qmn E = 31Y; .. w' j yr i Jratf 13 Ju IVs � � � SECTION 6 Agricultural Lime Application Log Year2023 Project Morehead City Fields Soil Lime Requirements Tons/Acre Date ICR-7-2 I 1 1 5.41 10.7 T I N/A N/A -Did not apply in 2023 SECTION 7 NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/agronomi/ Report No. FY24-SL002245 Predictive Client: Bobby Riggs 483 Weatherington Landing Rd Advisor: Matthew Carter 4894 Liddell Rd £ x Soil Report Mehlich-3 Extraction Stella, NC 28582 Seven Springs, NC 28578 Sampled County: Craven „r Links to Helpful Information Client ID: 467267 Advisor ID: 546169 Sampled: Received: 08/18/2023 Completed: 08/29/2023 Farm: Sample ID: CR73A Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Corn, grain 0.0 120 - 160 0 40 0 0 0 0 0 0 Note: 3 2- 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS -I NO3-N 1.02 1.19 6.4 81 1.2 6.0 220 53 52 25 50 47 45 206 206 287 0.1 2 Sample ID: CR73B Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Corn, grain 0.8 120 - 160 0 40 0 0 0 0 0 0 Note: 3 2- 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 1.08 1.23 5.5 69 1.7 5.5 300 49 50 14 56 53 49 316 316 398 0.1 2 North Carolina f. 1 ' > I0WOOLO iiu%t lLaW Ctwnawukm Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler. Commissioner of Agriculture NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/agronomi/ Report No. FY24-SL002245 Bobby Riggs Page 2 of 3 Sample ID: CR702 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Corn, grain 0.7 120 - 160 0 60 0 0 0 0 0 0 Note: 3 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm): Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.71 1.37 3.8 67 1.3 5.4 272 39 47 14 48 41 42 157 157 244 0.1 3 NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/agronomi/ Report No. FY24-SL002245 Bobby Riggs Page 3 of 3 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at on Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-I potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients. In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft. If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/apronomi/obpart4.htm1 #sfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-I zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-AI2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit www.ncapr.gov/agronomi/uyrst.htm