WQ0006245_2023 Residual Annual Report_20240213 (2)

Initial Review
Reviewer
nathaniel.thorn burg
Is this submittal an application? (Excluding additional information.) *
Yes No
If not an application what is the submittal type?* Annual Report
Residual Annual Report
Additional Information
Other
Annual Report Year* 2023
Permit Number (IR) * WQ0006245
Applicant/Permittee City of Statesville
Email Notifications
Does this need review by the hydrogeologist? * Yes No
Regional Office Mooresville
CO Reviewer
Admin Reviewer Wanda Gerald

Submittal Form
Project Contact Information
Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence.
Name* Ken Galloway
Email Address*
[e-mail]
Project Information
.........................
Application/Document Type*
New (Fee Required)
Modification - Major (Fee Required)
Renewal with Major Modification (Fee
Required)
Annual Report
Additional Information
Other
Phone Number*
7048783438
Modification - Minor
Renewal
GW-59, NDMR, NDMLR, NDAR-1,
N DAR-2
Residual Annual Report
Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:*
Wastewater Irrigation
High -Rate Infiltration
Other Wastewater
Reclaimed Water
Closed -Loop Recycle
Residuals
Single -Family Residence Wastewater
Other
Irrigation
Permit Number:*
WQ0006245
Has Current Existing permit number
Applicant/Permittee Address*
PO Box 1111 Statesville, NC 28687
Facility Name*
City of Statesville Class A Residuals Program
Please provide comments/notes on your current submittal below.
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.
(Application Form, Engineering Plans, Specifications, Calculations, Etc.)
Complete AR 2023 StaLime.pdf 13.91 MB
Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger
than upload limit.
* By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has
been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the
North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts
of the application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
Signature
04;;C6r
Submission Date 2/13/2024

February 13, 2024
Attention: NCDWR
Water Quality Non -Discharge Permitting Unit
1617 Mail Service Center
Raleigh, North Carolina 27699-1636
RE: Annual Report for 2023
Alkaline Stabilization (WQ0006245)
To Whom It May Concern:
Enclosed, you will find a copy of the required forms and lab data for the Alkaline Stabilization
program. Permit # WQ0006245.
Should you require more information, or if further action is required, please contact me at 704- 878-3438.
Si4ay
l
WWTP Supervisor, Fourth Creek WWTP

GENERAL INFORMATION
ALKALINE STABLIZATION REPORT
CALENDER YEAR 2023
PERMIT NO. WQ0006245
FACILITY NAME: Fourth Creek WWTP NPDES NCO031836
LOCATION: 693 Bell Farm Road
MAILING ADDRESS: P.O. Box 1111
Statesville, NC 28687-1111
[phone]
RESPONSIBLE OFFICIAL: Andy Smith, Operations Manager
Water Resources
P.O. Box 1111
Statesville, NC 28687-1111
[phone]
FACILITY OPERATOR: Ken Galloway
Plant Supervisor
P.O. Box 1111
Statesville, NC 28687-1111
[phone]
RESIDUALS ORC: Ken Galloway
Plant Supervisor
P.O. Box 1111
Statesville, NC 28687-1111
APPLICATION: Class A Exceptional Quality Product
Test Data and Summary Operations
Attached

CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM
WQ PERMIT #: WQ0006245 FACILITY NAME:
PHONE: [phone] COUNTY:
FACILITY TYPE (please check one):
Iredell
Fourth Creek Alkaline Stabilization
OPERATOR:
David Earnhardt
E3 Surface Disposal (complete Part A (Source(s) and "Residual In" Volume only) and Part C)
0 Distribution and Marketing (complete Parts A, B, and C)
Was the facility in operation during the Past calendar vear? Yes FV0l Na n —► rsw„ nor.- -- F� A n r --A r__W L_,
— -- �
Part A*:
uts �uu a� ram, L, t. a111U C:C.1 L11J' 1V1 L1 VC1VW
Part B*:
Month
Sources(s) (include NPDES # if
applicable)
Volume (dry tons)
Recipient Information
Amendment/
Bulking Agent
Residual In
Product Out
Name(s)
Volume (dry tons)
Intended use(s)
January
4th Creek WWTP
0
0
0
February
March
NPDES# NCO031836
4th Creek WWTP
0
86.75
0
173.25
0
260
Soil Supply
125
Soil Amendment
April
NPDES# NCO031836
96.5
156.S
253
Soil Suply
119
Soil Amendment
May
4th Creek WWTP
0
0
0
June
NPDES# NCO031836
0
0
0
July
4th Creek WWTP
0
0
0
Leatherwood Fanns
2.5
August
NPDES# NCO031836
0
0
0
September
October
November
December
4th Creek WWTP
NPDES# NCO031836
4th Creek WWTP
NPDES# NC0031836
0
0
0
0
0
0
0
0
0
0
0
0
Various Haulers
Various Haulers
Various Haulers
32.25
124
51
Agricultural
Agricultural
Agricultural
Total from FORM DMSDF (sup)
Totals: Annual (dry tons):
AmenrlmPntk) ncerl•
0
183.25
0
329.75
0
513
0
453.75
- it more space is required, attach additional information sheets (FORM DMSDF (supp)): Total Number of Form DMSDF (Supp)�--,
Part C:
Facility was compliant during the past calendar year with all conditions of the land application permit 21 Yes
(including but not limited to items 1-3 below) issued by the Division of Water Quality: © No ► If No, Explain in Narritive
1. All monitoring was done in accordance with the pen -nit and reported for the year as required and three (3) copies of certified laboratory results are attached.
2. All operation and maintenance requirements were compiled with or, in the case of a deviation, prior authorization was received from the Division of Water Quality.
3. No contravention of Ground Water Quality Standards occurred at a monitoring well.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Signature of Permittee
Date
**Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Signature�ofPrep�arer
(if different from Penmittee)
y
Date
DENR FORM DMSDF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number: WQ0006245
Facility Name: Fourth Creek WWTP
Residual Source WQ # or NPDES # NCO031836
NPDES #:
WWTP Name:
Residn;tl Angivcic iDgtq
Laboratory: 1) Waypoint Analytical
2)
3)
4)
5)
Parameter
(mg/kg)
Conc.
Limit
m /k 7)a
Sample or Composite Date
3/13/23
4/27/23
4/17/23
TCLP
Percent Solids (%)
NA
87.00%
87%
91%
Arsenic
75
35.7
7.88
<0.250
Cadmium
85
0.915
<0.120
<0.05
Copper
4,300
223
30.6
Chromium
NA
NA
NA
<0.1
Lead
840
49.1
6.16
<0.1
Mercury
57
<1.28
<0.217
<0.02
Molybdenum
75
12
0.793
Nickel
420
59.6
9.47
Selenium
100
25.8
1.99
<0.05
Zinc
7,500
359
39
Total Phosphorus
NA
18,000
2,110
TKN
NA
24,100
3,920
Ammonia -Nitrogen
NA
399
51.1
Nitrate and Nitrite
NA
202
<12
___ _ _- ---- __ ..... -- .,.,.­5 tulllL, ll,«u lll un, 101111 are not applicanie. tceterence the mcitvidual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties for submi b false information, including the possibility of fines and imprisonment for knowing violations."
Signature of Preparer *
Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM RSSF (12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Fourth Creek WWTP Alkaline Stabilization
WWTP Name: Fourth Creek WWTP
WQ Permit Number: WQ0006245
NPDES Number: NCO031836
Monitoring Period: From l/l/2023 To 12/31/2023
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/tem) [3Alt
B (Alk Treatment) p
Alt. C (Prior Testin )❑
A1t.D (No Prior Test) ❑
Process to Further Reduce Pathogengs ❑
If applicable to alternative
performed Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
Heat Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
GammRa ❑
a
Pasteurization
Class B:
jAlt. (1) Fecal Density ❑
Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative
performed (Class
B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
Air D! 2ng ❑
ComRostina ❑
JAerobic Digestion ❑
Anaerobic Digestion n
If applicable to alternative performed (Class A or Class B) complete the following
monitoring data:
Parameter
Allowable Level
in Sludge
in —Minimum
Pathogen Density
Number of
Excee-
dence
Frequency
of Analysis
y
Sample
Type
Analytical
Tech -
maue
Geo. Mean
aximu
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
<2 2
<2.4
mpn/g
Quarterly
grab
sm9221
CFU
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 WN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt.1 (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) ❑
Alt. 4 (Spec. Oz uptake) 0
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization 21
Alt 7 (Drying - Stable) ❑
jAlt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
(� "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Ken Galloway WWTP Supervisor
Preparer Name and ' e pe or print)
Signature of Prepare
Land Applier Name and Title (if applicable)(type or print)
t-15-Zy
Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

City Of Stat wille Alkaline to I Izatlon ecord For
Process To Further Reduce Pathogens (PFRP)
BIN #
Setup Date:
Removal From Bin Date:
Date
Time
pH >12. —For 72 Hrs.
TEMP. >52 Deg. C For 12 Hrs.
operator
Y-A-23
9113 "_
Initial pH: "7
cj �d
��vC
v ,,
Corrected pH: j Z `
�i
Final pH: I G�
S
Corrected pH: 1�r
Has 37 Hour-T—effi—pCriteria
Been et, R6N
Has Hour p Criteria een et.
BIN #
Setup Date:
Removal From Bin Date:
Date
Time
pH >12.0 For 72 Hrs.
TEMP. >52 Deg. C For 12 Hrs.
operator
'Jq5AA
Initial pH:
Corrected p 2
q� �^,1�
Final pH::
�•,
Corrected pH: ,
Has 12 Hour Ternp Criteria
Been et. L Y
Has 72 Hour pH Criteria Been —Met?.
BIN #
Setup Date:
Removal From Bin Date:
Date
Time
pH >12.0 For 72 Hrs.
TEMP. >52 Deg. C For 12 Hrs.
operator
Initial pH:
Corrected pH: U�y1 r
50C X-16
qYc T f6
Final pH: �2 s
Corrected pH:
`�-
as our Ternp Criteria Been
Met?
Has 72 Hour pH Criteria Been et.
BIN #
Setup Date:
Removal From Bin Date:
Date
Time
pH >12.0 For 72 Hrs.
TEMP. >52 Deg. C For 12 Hrs.
operator
Initial pH: 4!
Corrected pH: x � r
114
�s �.
Zd�
'
S
Final pH:
, y_
Corrected pH: � j � • � �
Has 12 Hour Ternp Criteria Been
Met.
Has 72 Hour pH Criteria Been Mev
BIN #
Setup Date:
Removal From Bin Date:
Date
Time
pH >12.0 For 72 Hrs.
TEMP. >52 Deg. C For 12 Hrs.
operator
Initial pH:
Corrected pH:
- 'i1 V
IG.L�,�-
Final pH: 12� ��
0
Corrected pH: l2 ,
Has 12 Hour Temp Criteria Been
Met. N
Has 72 Hour pH Criteria Been Met, Y` N

City 0 On Record For
Process To Further Reduce Pathogens (PFRP)
BIN # Isetup Date: Removal From Bin Date:
Date Time pH >12.0 For 72 Hrs. TEMP. >52 Deg. C For 12 Hrs. Operator
1.11-23
J-S6 X.
Initial pH: 1z ` ? c-)
15.4.
D
Corrected pH: 2
'3. 2 - )3
4
w��2 �j-
,`f'd
e.�.
Final pH: io
�y t lei
1 � �
` j
4
� ��
Corrected pH:
Has 12 Hour Temp Criteria
Been et. Y
Has our p rlterla Been Met.
BIN # Z
Setup Date:
Removal From Bin Date:
Date
Time
pH >12.0 For 72 Hrs.
TEMP. >52 Deg. C For 12 Hrs.
Operator
z- 3
6 4 ib
Initial pH: Y`:
�
9ri-OC
2c
`�
Corrected pH: �q
j�
Final pH: f . T"P
"l' p�
y
Corrected pH: 1 11 5
Has 12 Hour Temp rlterla
Been et.
Has 72 Hour pH Criteria Been et
BIN #
Setup Date:
Removal From Bin Date:
Date
Time
pH >12.0 For 72 Hrs.
TEMP. >52 Deg. C 12 Hrs.
Operator
Initial pH:
jFor
'
Corrected pH:'
Final pH:
r
Corrected pH: }.
Has 12 Hour Ternp Criteria
een Met?
Has 72 Hour pH Criteria Been Met? N
BIN #
Setup Date:
Removal From Bin Date:
Date
Time
pH >12.0 Fo i2 Hrs,
TEMP. >52 Deg. C For 12 Hrs.
Operator
°' •-2
�'
Initial pH: 2 r 5
yl
Corrected pH: = `�
�'
t ? a
^�
'r
Final pH:
A.
Corrected pH:
Has 12 Hour Ternp Criteria Been
et.
as 72 Hour pH Criteria Been et,
BIN # �.
Setup Date:
Removal From Bin Date:
Date
Time
' pH >12.0 For 72 Hrs.
TEMP. >52 Deg. C For 12 Hrs.
Operator
��
Initial
pH: (
i6.��,
'
Corrected pH: 0
Final pH: rG-1
fl�v-r
Corrected pH: r
Has ff Hour Temp Criteria Been
Met. N
PY"N
Has 72 Hour pH Criteria Been Met,

Waypoint.0
ANALYTICAL
4/3/2023
City of Statesville, NC
Ken Galloway
693 Bell Farm Road
Statesville, NC, 28625
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Ref: Analytical Testing
Revised Lab Report Number: 23-072-9013 (Original Report 23-072-0013)
Client Project Description: Quarterly Stalime
Dear Ken Galloway:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 3/13/2023 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136
Method Update Rule May 2021) unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
co'pi� wc:��.
Terri W Cole
Laboratory Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 17

Waypoint
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytica I.tom
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State
Program
Lab ID
Expiration Date
North Carolina
State Program
37735
07/31/2023
North Carolina
State Program
402
12/31/2023
South Carolina
State Program
99012
07/31/2023
South Carolina
State Program
99012
12/31/2022
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/29/2024
Arkansas
State Program
88-0650
02/07/2024
California
State Program
2904
06/30/2023
Florida
State Program - NELAP
E871157
06/30/2023
Georgia
State Program
C044
11/14/2025
Georgia
State Program
04015
06/30/2023
Illinois
State Program
- NELAP
200078
10/10/2023
Kentucky
State Program
80215
06/30/2023
Kentucky
State Program
KY90047
12/31/2023
Louisiana
State Program
- NELAP
LA037
12/31/2023
Louisiana
State Program
- NELAP
04015
06/30/2023
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
47701
07/31/2023
North Carolina
State Program
415
12/31/2023
Pennsylvania
State Program
- NELAP
68-03195
05/31/2023
South Carolina
State Program
84002
06/30/2023
Tennessee
State Program
02027
11/14/2025
Texas
State Program
- NELAP
T104704180
09/30/2023
Virginia
State Program
00106
06/30/2023
Virginia
State Program
- NELAP
460181
09/14/2023
Page 1 of 1 00016/23-072-9013
Page 2 of 17

waypoint (D 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
Sample Summary Table
Report Number: 23-072-9013
Client Project Description: Quarterly Stalime
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
91006
Stalime
Solids
03/13/2023 11:40
03/13/2023 12:58
91006
Stalime
Solids
03/13/2023 11:40
03/13/2023 12:58
350.1
AES
91006
Stalime
Solids
03/13/2023 11:40
03/13/2023 12:58
4500NORGD-2011
WP MTN
91006
Stalime
Solids
03/13/2023 11:40
03/13/2023 12:58
7471A
WP MTN
91006
Stalime
Solids
03/13/2023 11:40
03/13/2023 12:58
6010D
WP MTN
91007
Stalime SAR
Solids
03/13/2023 11:40
03/13/2023 12:58
91007
Stalime SAR
Solids
03/13/2023 11:40
03/13/2023 12:58
Saturate Paste
WP MTN
91008
F4
Solids
03/13/2023 11:45
03/13/2023 12:58
91009
2
Solids
03/13/2023 11:50
03/13/2023 12:58
91010
F5
Solids
03/13/2023 11:45
03/13/2023 12:58
91011
Bin 1
Solids
03/13/2023 11:45
03/13/2023 12:58
91012
Bin 3
Solids
03/13/2023 11:50
03/13/2023 12:58
91013
Bin 7
Solids
03/13/2023 11:50
03/13/2023 12:58
91014
Bin 8
Solids
03/13/2023 11:45
03/13/2023 12:58
AES: Analytical Environmental Services, Inc., Atlanta, GA
WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN
Page 3 of 17

Waypointo
ANALYTICAL
Client: City of Statesville, NC
Project: Quarterly Stalime
Lab Report Number: 23-072-9013
Date: 3/31 /2023
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
CASE NARRATIVE
This is a revised report and supersedes the original laboratory report dated 3/30/23. Calculations have
been added to the case narrative.
Report Comments
Metals, mercury, TKN, and total phosphorus analyzed at Waypoint Memphis TN.
Ammonia subcontracted to Analytical Environmental Services.
Metals Analysis Method 6010D
Sample 91006 (Stalime)
Analyte: Aluminum
QC Batch No: L670995/L670303
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 91006
Analyte: Calcium
QC Batch No: L671277/L670303
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 91006
Analyte: Potassium
QC Batch No: L671277/L670303
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 91006 (Stalime)
Analyte: Phosphorus
QC Batch No: L670995/L670303
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Solids Total Mercury Analysis - CVAA Method 7471A
Sample 81482 (Frederick City)
Analyte: Mercury
QC Batch No: L670910/L670598
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
SAR=[3.41 ]/SQRT{([68]+[0.095])/2}
SAR=[3.41 ]/SQRT{(68.095)/2}
SAR=[3.41 ]/SQRT{34.04}
SAR = 0.585
Page 4 of 17

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Concentrations for Na, Ca, and Mg are expressed in mill iequivalents per liter, and SQRT designates taking the
square root of the operand in parentheses.
PAN Equation = 0.3 * (TKN — Ammonia) + 0.5 * (Ammonia) + Nitrate -Nitrite
PAN = 0.3 * (3130-399) + 0.5 * (399) + 26.3
PAN = 1031.95
Page 5 of 17

�n
W�ypOI ■ ■� . 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01050
City of Statesville, NC Project Quarterly Stalime Original Report Date : 03/30/2023
Ken Galloway Revised Report Date: 04/03/2023
693 Bell Farm Road Information : Received : 03/13/2023
Statesville , NC 28625
Report Number : 23-072-9013 REPOR T OF A NA L YSIS
Lab No : 91006
Matrix: Solids
Sample ID: Stalime
Sampled:
3/13/2023 11:40
Test
Results
Units
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Plant Available Nitrogen
1031.95
1
CALCULATION
Moisture
87.0
%
1
03/20/2318:38
AMB
SW-DRYWT
Ammonia Nitrogen
399
mg/Kg AR
1
350.1
Nitrate (NO3-N)
202
mg/Kg - dry
154
10
03/20/23 18:03
CMJ
9056A
Nitrite (NO2-N)
<76.9
mg/Kg - dry
76.9
10
03/20/23 18:03
CM]
9056A
Nitrate+Nitrite-N
202
mg/Kg - dry
76.9
10
03/20/23 18:03
9056A
Total Solids
81.2
%
0.010
1
03/15/23 11:36
AMB
2540G-2011
Total Kjeldahl Nitrogen
24100
mg/Kg - dry
1230
1
03/21/23 14:24
ANH 4500NORGD-2011
Phosphorus
18000
mg/Kg - dry
38.5
1
03/21/23 04:47
BKN
6010D
Aluminum
66200
mg/Kg - dry
38.5
1
03/21/23 04:47
BKN
6010D
Arsenic
35.7
mg/Kg - dry
3.85
1
03/21/23 16:05
TJS
6010D
Cadmium
0.915
mg/Kg - dry
0.769
1
03/21/23 04:47
BKN
6010D
Calcium
2270000
mg/Kg - dry
38500
100
03/21/23 17:00
TJS
6010D
Copper
223
mg/Kg - dry
3.85
1
03/21/23 04:47
BKN
6010D
Lead
49.1
mg/Kg - dry
2.31
1
03/21/23 04:47
BKN
6010D
Magnesium
19200
mg/Kg - dry
38.5
1
03/21/23 04:47
BKN
6010D
Mercury (Total)
<1.28
mg/Kg - dry
1.28
1
03/20/23 15:13
FDS
7471A
Molybdenum
12.0
mg/Kg - dry
1.92
1
03/21/23 04:47
BKN
6010D
Nickel
59.6
mg/Kg - dry
1.92
1
03/21/23 04:47
BKN
6010D
Potassium
20100
mg/Kg - dry
769
10
03/21/23 16:25
TJS
6010D
Selenium
25.8
mg/Kg - dry
3.85
1
03/21/23 16:05
TJS
6010D
Sodium
6500
mg/Kg - dry
192
1
03/21/23 04:47
BKN
6010D
Qualifiers/ DF
Dilution Factor
MQL Method Quantitation Limit
Definitions
Page 6 of 17

Waypointo.
ANALYTICAL
01050
City of Statesville, NC
Project
Ken Galloway
693 Bell Farm Road
Information
Statesville , NC 28625
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypoi nta na lytica Isom
Quarterly Stalime Original Report Date : 03/30/2023
Revised Report Date: 04/03/2023
Received : 03/13/2023
Report Number : 23-072-9013 REPOR T OF A NA L YSIS
Lab No : 91006 Matrix: Solids
Sample ID: Stalime Sampled: 3/13/2023 11:40
Test Results Units MQL DF Date / Time By Analytical
Analyzed Method
Zinc 359 mg/Kg - dry 9.62 1 03/21/23 04:47 BKN 6010D
Qualifiers/ DF Dilution Factor MQL Method Quantitation Limit
Definitions
Page 7 of 17

Waypointo
ANALYTICAL
01050
City of Statesville, NC Project
Ken Galloway
693 Bell Farm Road Information
Statesville , NC 28625
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypoi nta na lytica Isom
Quarterly Stalime Original Report Date : 03/30/2023
Revised Report Date: 04/03/2023
Received : 03/13/2023
Report Number : 23-072-9013 REPOR T OF A NA L YSIS
Lab No : 91007
Sample ID: Stalime SAR
Matrix: Solids
Sampled: 3/13/2023 11:40
Test
Results
Units
MQL
DF
Date / Time By
Analytical
Analyzed
Method
Calcium (saturated paste)
68.0
meq/L
0.005
1
03/29/23 14:20 SWL
Saturate Paste
Magnesium (saturated paste)
0.095
meq/L
0.008
1
03/29/23 14:20 SWL
Saturate Paste
Sodium (saturated paste)
3.41
meq/L
0.004
1
03/29/23 14:20 SWL
Saturate Paste
Sodium Absorption Ratio
0.585
1
03/29/23 14:20 SWL
Saturate Paste
Moisture
16.2
%
1
03/20/2318:38 AMB
SW-DRYWT
Qualifiers/ DF Dilution Factor MQL Method Quantitation Limit
Definitions
Page 8 of 17

Waypointo
ANALYTICAL
01050
City of Statesville, NC Project
Ken Galloway
693 Bell Farm Road Information
Statesville , NC 28625
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypoi nta na lytica Isom
Quarterly Stalime Original Report Date : 03/30/2023
Revised Report Date: 04/03/2023
Received : 03/13/2023
Report Number : 23-072-9013 REPOR T OF A NA L YSIS
Lab No : 91008 Matrix: Solids
Sample ID : F4 Sampled: 3/13/2023 11:45
Test Results Units MQL DF Date / Time By Analytical
Analyzed Method
Fecal Coliform MPN/g <2.4 MPN/g - dry
Moisture 17.6 %
Qualifiers/ DF Dilution Factor
Definitions
2.4 1 03/13/23 14:15 SMW 9221E-2011
1 03/20/2318:38 AMB SW-DRYWT
MQL Method Quantitation Limit
Page 9 of 17

Waypointo
ANALYTICAL
01050
City of Statesville, NC Project
Ken Galloway
693 Bell Farm Road Information
Statesville , NC 28625
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypoi nta na lytica Isom
Quarterly Stalime Original Report Date : 03/30/2023
Revised Report Date: 04/03/2023
Received : 03/13/2023
Report Number : 23-072-9013 REPOR T OF A NA L YSIS
Lab No : 91009 Matrix: Solids
Sample ID : 2 Sampled: 3/13/2023 11:50
Test Results Units MQL DF Date / Time By Analytical
Analyzed Method
Fecal Coliform MPN/g <2.6 MPN/g - dry
Moisture 25,8 %
Qualifiers/ DF Dilution Factor
Definitions
2.6 1 03/13/23 14:15 SMW 9221E-2011
1 03/20/2318:38 AMB SW-DRYWT
MQL Method Quantitation Limit
Page 10 of 17

Waypointo
ANALYTICAL
01050
City of Statesville, NC Project
Ken Galloway
693 Bell Farm Road Information
Statesville , NC 28625
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypoi nta na lytica Isom
Quarterly Stalime Original Report Date : 03/30/2023
Revised Report Date: 04/03/2023
Received : 03/13/2023
Report Number : 23-072-9013 REPOR T OF A NA L YSIS
Lab No : 91010 Matrix: Solids
Sample ID : F5 Sampled: 3/13/2023 11:45
Test Results Units MQL DF Date / Time By Analytical
Analyzed Method
Fecal Coliform MPN/g <2.4 MPN/g - dry
Moisture 16.9 %
Qualifiers/ DF Dilution Factor
Definitions
2.4 1 03/13/23 14:15 SMW 9221E-2011
1 03/20/2318:38 AMB SW-DRYWT
MQL Method Quantitation Limit
Page 11 of 17

Waypointo
ANALYTICAL
01050
City of Statesville, NC Project
Ken Galloway
693 Bell Farm Road Information
Statesville , NC 28625
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypoi nta na lytica Isom
Quarterly Stalime Original Report Date : 03/30/2023
Revised Report Date: 04/03/2023
Received : 03/13/2023
Report Number : 23-072-9013 REPOR T OF A NA L YSIS
Lab No : 91011 Matrix: Solids
Sample ID : Bin 1 Sampled: 3/13/2023 11:45
Test Results Units MQL DF Date / Time By Analytical
Analyzed Method
Fecal Coliform MPN/g <2.4 MPN/g - dry
Moisture 16.9 %
Qualifiers/ DF Dilution Factor
Definitions
2.4 1 03/13/23 14:15 SMW 9221E-2011
1 03/20/2318:38 AMB SW-DRYWT
MQL Method Quantitation Limit
Page 12 of 17

Waypointo
ANALYTICAL
01050
City of Statesville, NC Project
Ken Galloway
693 Bell Farm Road Information
Statesville , NC 28625
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypoi nta na lytica Isom
Quarterly Stalime Original Report Date : 03/30/2023
Revised Report Date: 04/03/2023
Received : 03/13/2023
Report Number : 23-072-9013 REPOR T OF A NA L YSIS
Lab No : 91012 Matrix: Solids
Sample ID : Bin 3 Sampled: 3/13/2023 11:50
Test Results Units MQL DF Date / Time By Analytical
Analyzed Method
Fecal Coliform MPN/g <2.3 MPN/g - dry
Moisture 13.8 %
Qualifiers/ DF Dilution Factor
Definitions
2.3 1 03/13/23 14:15 SMW 9221E-2011
1 03/20/2318:38 AMB SW-DRYWT
MQL Method Quantitation Limit
Page 13 of 17

Waypointo
ANALYTICAL
01050
City of Statesville, NC Project
Ken Galloway
693 Bell Farm Road Information
Statesville , NC 28625
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypoi nta na lytica Isom
Quarterly Stalime Original Report Date : 03/30/2023
Revised Report Date: 04/03/2023
Received : 03/13/2023
Report Number : 23-072-9013 REPOR T OF A NA L YSIS
Lab No : 91013 Matrix: Solids
Sample ID : Bin 7 Sampled: 3/13/2023 11:50
Test Results Units MQL DF Date / Time By Analytical
Analyzed Method
Fecal Coliform MPN/g <2.3 MPN/g - dry
Moisture 16.4 %
Qualifiers/ DF Dilution Factor
Definitions
2.3 1 03/13/23 14:15 SMW 9221E-2011
1 03/20/2318:38 AMB SW-DRYWT
MQL Method Quantitation Limit
Page 14 of 17

Waypointo
ANALYTICAL
01050
City of Statesville, NC Project
Ken Galloway
693 Bell Farm Road Information
Statesville , NC 28625
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypoi nta na lytica Isom
Quarterly Stalime Original Report Date : 03/30/2023
Revised Report Date: 04/03/2023
Received : 03/13/2023
Report Number : 23-072-9013 REPOR T OF A NA L YSIS
Lab No : 91014 Matrix: Solids
Sample ID : Bin 8 Sampled: 3/13/2023 11:45
Test Results Units MQL DF Date / Time By Analytical
Analyzed Method
Fecal Coliform MPN/g <2.2 MPN/g - dry
Moisture 11.7 %
Qualifiers/ DF Dilution Factor
Definitions
2.2 1 03/13/23 14:15 SMW 9221E-2011
1 03/20/2318:38 AMB SW-DRYWT
MQL Method Quantitation Limit
Page 15 of 17

(2)
WayPAo0nt..
NALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 01050
Customer Name: City of Statesville, NC
Report Number: 23-072-0013
Shipping Method
0 Fed Ex 0 US Postal U Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IRT15 2.5C
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
F
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
Yes
0 No
COC agrees with sample Iabel(s)?
U Yes
0 No
COC properly completed
U Yes
0 No
Samples in proper containers?
U Yes
0 No
Sample containers intact?
Yes
0 No
Sufficient sample volume for indicated test(s)?
Yes
0 No
All samples received within holding time?
Yes
0 No
Cooler temperature in compliance?
Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
0 N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr) F Low concentration EnCore samplers (48 hr)
F_ High concentration pre -weighed (methanol -14 d) Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included?
0 Yes
0 No
Comments:
Signature: Angelo Norvell Date & Time: 03/13/2023 13:04:00
Page 16 of 17

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Page 17 of 17 1

Waypoint
ANALYTICAL
5/16/2023
City of Statesville, NC
Ken Galloway
693 Bell Farm Road
Statesville, NC, 28625
Ref: Analytical Testing
Lab Report Number: 23-117-0008
Client Project Description: Quarterly Stalime
Fourth Creek WWTP
Dear Ken Galloway:
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Waypoint Analytical, LLC (Charlotte) received sample(s) on 4/27/2023 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136
Method Update Rule May 2021) unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Terri W Cole
Laboratory Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 22

Waypoint
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytica I.tom
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State
Program
Lab ID
Expiration Date
North Carolina
State Program
37735
07/31/2023
North Carolina
State Program
402
12/31/2023
South Carolina
State Program
99012
07/31/2023
South Carolina
State Program
99012
12/31/2022
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/29/2024
Arkansas
State Program
88-0650
02/07/2024
California
State Program
2904
06/30/2023
Florida
State Program - NELAP
E871157
06/30/2023
Georgia
State Program
C044
11/14/2025
Georgia
State Program
04015
06/30/2023
Illinois
State Program
- NELAP
200078
10/10/2023
Kentucky
State Program
80215
06/30/2023
Kentucky
State Program
KY90047
12/31/2023
Louisiana
State Program
- NELAP
LA037
12/31/2023
Louisiana
State Program
- NELAP
04015
06/30/2023
Mississippi
State Program
MS
11/14/2025
North Carolina
State Program
47701
07/31/2023
North Carolina
State Program
415
12/31/2023
Pennsylvania
State Program
- NELAP
68-03195
05/31/2024
South Carolina
State Program
84002
06/30/2023
Tennessee
State Program
02027
11/14/2025
Texas
State Program
- NELAP
T104704180
09/30/2023
Virginia
State Program
00106
06/30/2023
Virginia
State Program
- NELAP
460181
09/14/2023
Page 1 of 1 00016/23-117-0008
Page 2 of 22

(2)
YPO•*nt 449 Springbrook Rd, Charlotte, 28217
Wa Main 704.5.529.6364
64
ANALYTICAL www.waypointanalytical.com
Sample Summary Table
Report Number: 23-117-0008
Client Project Description: Quarterly Stalime
Fourth Creek WWTP
Lab No
Client Sample ID
Matrix
Date Collected
Date Received
Method
Lab ID
94958
Fecal 1
Solids
04/27/2023 09:41
04/27/2023 11:37
94959
Fecal 2
Solids
04/27/2023 09:42
04/27/2023 11:37
94960
Fecal 3
Solids
04/27/2023 09:43
04/27/2023 11:37
94961
Fecal 4
Solids
04/27/2023 09:44
04/27/2023 11:37
94962
Fecal 5
Solids
04/27/2023 09:45
04/27/2023 11:37
94963
Fecal 6
Solids
04/27/2023 09:46
04/27/2023 11:37
94964
Fecal 7
Solids
04/27/2023 09:47
04/27/2023 11:37
94965
Stalime
Solids
04/27/2023 09:40
04/27/2023 11:37
94965
Stalime
Solids
04/27/2023 09:40
04/27/2023 11:37
350.1
AES
94965
Stalime
Solids
04/27/2023 09:40
04/27/2023 11:37
7471A
WP MTN
94965
Stalime
Solids
04/27/2023 09:40
04/27/2023 11:37
6010D
WP MTN
94965
Stalime
Solids
04/27/2023 09:40
04/27/2023 11:37
4500NORGD-2011
WP MTN
94966
Stalime SAR
Solids
04/27/2023 09:40
04/27/2023 11:37
94966
Stalime SAR
Solids
04/27/2023 09:40
04/27/2023 11:37
Saturate Paste
WP MTN
AES: Analytical Environmental Services, Inc., Atlanta, GA
WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN
Page 3 of 22

Waypoint
ANALYTICAL
Client: City of Statesville, NC
Project: Quarterly Stalime
Lab Report Number: 23-117-0008
Date: 5/11 /2023
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
CASE NARRATIVE
Ammonia subcontracted to Analytical Environmental Services.
Metals Analysis Method 6010D
Sample 84307 (Apr. 23 Monthly Comp)
Analyte: Aluminum
QC Batch No: L679685/L679279
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 84307 (Apr. 23 Monthly Comp)
Analyte: Potassium
QC Batch No: L679685/L679279
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 94965 (Stalime)
Analyte: Potassium
QC Batch No: L679685/L679279
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 84307 (Apr. 23 Monthly Comp)
Analyte: Phosphorus
QC Batch No: L679685/L679279
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Solids Total Mercury Analysis - CVAA Method 7471A
Sample 87292 (Ballenger Creek)
Analyte: Mercury
QC Batch No: L680933/L680730
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Anions by Ion Chromatography Method 9056A
Sample 94965 (Stalime)
Analyte: Nitrate-N
QC Batch No: V32910/V32907
CCV failed high. Sample concentration BRL. Results not affected.
Sample 94965 (Stalime)
Analyte: Nitrate-N
QC Batch No: V3291 ON32907
Matrix spike/matrix spike duplicate recoveries are outside of control limits. Acceptable LCS recovery indicates the
system was in control, but the reported result could be affected by matrix interference.
Page 4 of 22

Waypointo
ANALYTICAL
SAR=[Na]/SQRT{([Ca]+[Mg])/2}
SAR=[15.4]/SQRT{([104]+[0.125])/2}
SAR=[15.4]/SQRT{52.1}
SAR = 2.14
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Concentrations for Na, Ca, and Mg are expressed in mill iequivalents per liter, and SQRT designates taking the
square root of the operand in parentheses.
PAN Equation = 0.3 * (TKN — Ammonia) + 0.5 * (Ammonia) + Nitrate -Nitrite
PAN = 0.3 * (3250-51.1) + 0.5 * (51.1) + 10
PAN = 0.3 * 956.97 + 0.5 * 61.1
PAN = 987.52
Page 5 of 22

Waypointo
ANALYTICAL
01050
City of Statesville, NC
Ken Galloway
693 Bell Farm Road
Statesville , NC 28625
Report Number : 23-117-0008
Lab No : 949SS
Sample ID : Fecal 1
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypoi nta na lytica Isom
Project Quarterly Stalime
Information : Fourth Creek WWTP
REPORT OF ANAL YSIS
Report Date : 05/16/2023
Received I: j04�/27/20�23
JM wu'
Terri W Cole
Laboratory Project Manager
Matrix: Solids
Sampled: 4/27/2023 9:41
Test Results Units MQL DF Date / Time By Analytical
Analyzed Method
Fecal Coliform MPN/g <2.3 MPN/g - dry
Moisture 13.2 %
Qualifiers/ DF Dilution Factor
Definitions
2.3 1 04/27/23 12:38 SMW 9221E-2011
1 04/30/2312:45 PEB SW-DRYWT
MQL Method Quantitation Limit
Page 6 of 22

Waypointo
ANALYTICAL
01050
City of Statesville, NC
Ken Galloway
693 Bell Farm Road
Statesville , NC 28625
Report Number : 23-117-0008
Lab No : 94959
Sample ID : Fecal 2
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypoi nta na lytica Isom
Project Quarterly Stalime
Information : Fourth Creek WWTP
REPORT OF ANAL YSIS
Report Date : 05/16/2023
Received I: j04�/27/20�23
JM wu'
Terri W Cole
Laboratory Project Manager
Matrix: Solids
Sampled: 4/27/2023 9:42
Test Results Units MQL DF Date / Time By Analytical
Analyzed Method
Fecal Coliform MPN/g <2.2 MPN/g - dry
Moisture 12.3 %
Qualifiers/ DF Dilution Factor
Definitions
2.2 1 04/27/23 12:38 SMW 9221E-2011
1 04/30/2312:45 PEB SW-DRYWT
MQL Method Quantitation Limit
Page 7 of 22

Waypointo
ANALYTICAL
01050
City of Statesville, NC
Ken Galloway
693 Bell Farm Road
Statesville , NC 28625
Report Number : 23-117-0008
Lab No : 94960
Sample ID : Fecal 3
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypoi nta na lytica Isom
Project Quarterly Stalime
Information : Fourth Creek WWTP
REPORT OF ANAL YSIS
Report Date : 05/16/2023
Received I: j04�/27/20�23
JM wu'
Terri W Cole
Laboratory Project Manager
Matrix: Solids
Sampled: 4/27/2023 9:43
Test Results Units MQL DF Date / Time By Analytical
Analyzed Method
Fecal Coliform MPN/g <2.2 MPN/g - dry
Moisture 9.48 %
Qualifiers/ DF Dilution Factor
Definitions
2.2 1 04/27/23 12:38 SMW 9221E-2011
1 04/30/2312:45 PEB SW-DRYWT
MQL Method Quantitation Limit
Page 8 of 22

Waypointo
ANALYTICAL
01050
City of Statesville, NC
Ken Galloway
693 Bell Farm Road
Statesville , NC 28625
Report Number : 23-117-0008
Lab No : 94961
Sample ID : Fecal 4
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypoi nta na lytica Isom
Project Quarterly Stalime
Information : Fourth Creek WWTP
REPORT OF ANAL YSIS
Report Date : 05/16/2023
Received I: j04�/27/20�23
JM wu'
Terri W Cole
Laboratory Project Manager
Matrix: Solids
Sampled: 4/27/2023 9:44
Test Results Units MQL DF Date / Time By Analytical
Analyzed Method
Fecal Coliform MPN/g <2.2 MPN/g - dry
Moisture 11.4 %
Qualifiers/ DF Dilution Factor
Definitions
2.2 1 04/27/23 12:38 SMW 9221E-2011
1 04/30/2312:45 PEB SW-DRYWT
MQL Method Quantitation Limit
Page 9 of 22

Waypointo
ANALYTICAL
01050
City of Statesville, NC
Ken Galloway
693 Bell Farm Road
Statesville , NC 28625
Report Number : 23-117-0008
Lab No : 94962
Sample ID : Fecal 5
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypoi nta na lytica Isom
Project Quarterly Stalime
Information : Fourth Creek WWTP
REPORT OF ANAL YSIS
Report Date : 05/16/2023
Received I: j04�/27/20�23
JM wu'
Terri W Cole
Laboratory Project Manager
Matrix: Solids
Sampled: 4/27/2023 9:45
Test Results Units MQL DF Date / Time By Analytical
Analyzed Method
Fecal Coliform MPN/g <2.2 MPN/g - dry
Moisture 12.3 %
Qualifiers/ DF Dilution Factor
Definitions
2.2 1 04/27/23 12:38 SMW 9221E-2011
1 04/30/2312:45 PEB SW-DRYWT
MQL Method Quantitation Limit
Page 10 of 22

Waypointo
ANALYTICAL
01050
City of Statesville, NC
Ken Galloway
693 Bell Farm Road
Statesville , NC 28625
Report Number : 23-117-0008
Lab No : 94963
Sample ID : Fecal 6
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypoi nta na lytica Isom
Project Quarterly Stalime
Information : Fourth Creek WWTP
REPORT OF ANAL YSIS
Report Date : 05/16/2023
Received I: j04�/27/20�23
JM wu'
Terri W Cole
Laboratory Project Manager
Matrix: Solids
Sampled: 4/27/2023 9:46
Test Results Units MQL DF Date / Time By Analytical
Analyzed Method
Fecal Coliform MPN/g <2.3 MPN/g - dry
Moisture 16.3 %
Qualifiers/ DF Dilution Factor
Definitions
2.3 1 04/27/23 12:38 SMW 9221E-2011
1 04/30/2312:45 PEB SW-DRYWT
MQL Method Quantitation Limit
Page 11 of 22

Waypointo
ANALYTICAL
01050
City of Statesville, NC
Ken Galloway
693 Bell Farm Road
Statesville , NC 28625
Report Number : 23-117-0008
Lab No : 94964
Sample ID : Fecal 7
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypoi nta na lytica Isom
Project Quarterly Stalime
Information : Fourth Creek WWTP
REPORT OF ANAL YSIS
Report Date : 05/16/2023
Received I: j04�/27/20�23
JM wu'
Terri W Cole
Laboratory Project Manager
Matrix: Solids
Sampled: 4/27/2023 9:47
Test Results Units MQL DF Date / Time By Analytical
Analyzed Method
Fecal Coliform MPN/g <2.3 MPN/g - dry
Moisture 13.7 %
Qualifiers/ DF Dilution Factor
Definitions
2.3 1 04/27/23 12:38 SMW 9221E-2011
1 04/30/2312:45 PEB SW-DRYWT
MQL Method Quantitation Limit
Page 12 of 22

• nt�/aJ/pOI ■ ■ •r , 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01050
City of Statesville, NC Project Quarterly Stalime
Ken Galloway Report Date : 05/16/2023
693 Bell Farm Road Information : Fourth Creek WWTP Received : 04/27/2023
Statesville , NC 28625 JM
W��
Terri W Cole
Report Number : 23-117-0008 REPOR T OF A NA L YSIS Laboratory Project Manager
Lab No : 94965
Matrix: Solids
Sample ID: Stalime
Sampled:
4/27/2023 9:40
Test
Results
Units
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Plant Available Nitrogen
1190
mg/Kg - dry
12.0
1
05/01/23 15:13
CALCULATION
Moisture
17.0
%
1
04/30/2313:00
PEB
SW-DRYWT
Ammonia Nitrogen
51.1
mg/Kg AR
1
350.1
Nitrate+Nitrite-N
<12.0
mg/Kg - dry
12.0
10
05/08/23 16:41
9056A
Total Solids
83.0
%
0.010
1
04/30/23 13:00
PEB
2540G-2011
Total Kjeldahl Nitrogen
3920
mg/Kg - dry
353
1
05/01/23 15:13
ANH 4500NORGD-2011
Phosphorus
2110
mg/Kg - dry
6.02
1
05/02/23 22:32
TJS
6010D
Aluminum
9890
mg/Kg - dry
6.02
1
05/02/23 22:32
TJS
6010D
Arsenic
7.88
mg/Kg - dry
0.602
1
05/02/23 22:32
TJS
6010D
Cadmium
<0.120
mg/Kg - dry
0.120
1
05/02/23 22:32
TJS
6010D
Calcium
416000
mg/Kg - dry
6020
100
05/15/23 11:50
TJS
6010D
Copper
30.6
mg/Kg - dry
0.602
1
05/02/23 22:32
TJS
6010D
Lead
6.16
mg/Kg - dry
0.361
1
05/02/23 22:32
TJS
6010D
Magnesium
3280
mg/Kg - dry
6.02
1
05/02/23 22:32
TJS
6010D
Mercury (Total)
<0.217
mg/Kg - dry
0.217
1
05/09/23 13:08
FDS
7471A
Molybdenum
0.793
mg/Kg - dry
0.301
1
05/02/23 22:32
TJS
6010D
Nickel
9.47
mg/Kg - dry
0.301
1
05/02/23 22:32
TJS
6010D
Potassium
4060
mg/Kg - dry
241
20
05/03/23 13:45
TJS
6010D
Selenium
1.99
mg/Kg - dry
0.602
1
05/02/23 22:32
TJS
6010D
Sodium
1480
mg/Kg - dry
30.1
1
05/02/23 22:32
TJS
6010D
Zinc
39.0
mg/Kg - dry
1.51
1
05/02/23 22:32
TJS
6010D
Qualifiers/ DF
Dilution Factor
MQL Method Quantitation Limit
Definitions
Page 13 of 22

Waypointo
ANALYTICAL
01050
City of Statesville, NC
Ken Galloway
693 Bell Farm Road
Statesville , NC 28625
Report Number : 23-117-0008
Lab No : 94966
Sample ID: Stalime SAR
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypoi nta na lytica Isom
Project Quarterly Stalime
Information : Fourth Creek WWTP
REPORT OF ANAL YSIS
Report Date : 05/16/2023
Received I: j04�/27/20�23
JM wu'
Terri W Cole
Laboratory Project Manager
Matrix: Solids
Sampled: 4/27/2023 9:40
Test
Results
Units
MQL
DF
Date / Time
Analyzed
By
Analytical
Method
Calcium (saturated paste)
104
meq/L
0.005
1
05/08/23 13:59
SWL
Saturate Paste
Magnesium (saturated paste)
0.125
meq/L
0.008
1
05/08/23 13:59
SWL
Saturate Paste
Sodium (saturated paste)
15.4
meq/L
0.004
1
05/08/23 13:59
SWL
Saturate Paste
Sodium Absorption Ratio
2.14
1
05/08/23 13:59
SWL
Saturate Paste
Moisture
24.5
%
1
04/30/2313:00
PEB
SW-DRYWT
Qualifiers/ DF Dilution Factor
Definitions
MQL Method Quantitation Limit
Page 14 of 22

ACCESS
ANALYTICAL, INC.
ANALYTICAL REPORT
CLIENT
Way -point Analytical, LLC (Charlotte)
449 Springbrook Road
Charlotte NC 28217
ATTENTION
Terri W Cole
PROJECT ID
23-117-0008
LABORATORY REPORT NUMBER
2304U07
DATE
May 08, 2023
Primary Data Review By Secondary Data Review By
C f�1-
Ashley Amick
Chris Pafford Project Manager, Access Analytical
Project Manager, AES [e-mail]
PLEASE NOTE:
- Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc),
3080 Presidential Drive, Atlanta, GA 30340.
- AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582,
NELAP certified laboratory # E87582
AIHA-LAP,LLC Laboratory ID:100671 for Industrial Hygiene samples (Organics, Metals, PCM Asbestos,
Gravimetric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental Microbiology (Fungal)
Direct Examination.
- Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a
representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed
to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243
Page 15 of 22 Page 1 of 6

.0
Waypoi nt'
04/27/2023 12:51:48 ANALYTICAL
Export Batch Report
Export Batch Id : 3518EXP
To: Analytical Environmental Services, Inc.
3080 Presidential Drive
Atlanta, GA 30340
Report No Due Date SamR1e pate Customer Sample No
23-11/-0008 05/08/2023 04/27/2023 09:40 Stalime
NC Certs
Standard TAT
Sampled By
Remarks
relinquished By (sign)
quished By n)
r
thod of 5 ent
Date :/Time
Date / Tim
Ship via Standard Overnight
449 5pringbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Created: 4/2 7/2 023 12: 51: 24
Computer: WPALMS-117
User: Terri W Cole
Project Manager Terri W Cole
From: Waypoint Analytical, LLC (Charlotte)
449 Springbrook Road
Charlotte, NC 28217
704-529-6364
R hM
3oti U� ,
Page 1 of 1
us arm Lab No Method No _Fee Code Description
SOL 94965 EPA-350. i Ammonia -Nitrogen sub to AES 2 oz glass jar
Blank / Cooler Temp.
Received By (sign) Date /Time
c' 1S
Received BY (sign) Date / Time
Page 16 of 22 Page 2 of 6

Analytical Environmental Services, Inc
Date: 8-May-23
Client:
Waypoint Analytical, LLC (Charlotte)
Client Sample ID:
94965
Lab Order
2304U07
Tag Number:
Stalime
Project Name:
23-117-0008
Collection Date:
4/27/2023 9:40:00 AM
Lab ID:
2304U07-001A
Matrix:
Solid
n
Analyses Result Qual MDL ReportiDatdA&zlyzB&tchID DF Analyst
Limit
Nitrogen, Ammonia (as N) Extractable E350.1 MOD
Nitrogen, Ammonia (As N) Extractable 51.1
PERCENT MOISTURE D2216
Percent Moisture 8.98
Qualifiers: * Value exceeds maximum contaminant level
BRL Not Detected at MDL
H Holding times for preparation or analysis exceeded
N Analyte not NELAC certified
B Analyte detected in the associated method blank
(E350.1)
6.42 10.9 mg/Kg-drY 355704 1 05/08/202314:12 TL
0 0 WON R514982 1 04/30/2023 00:00 JW
E Estimated value above quamitation range
S Spike Recovery outside limits due to matrix
> Greater than Result value
J Estimated value detected below Reporting Limit
< Less than Result value
Page 17 of 22
Page 3 of 6

ANALyiicAL
JENvtRoNmENTAL
AES SER%gCFS, INC.
1. Client Name: Access Analytical, Inc
2. Carrier: FedEx ❑• UPS ❑ USPS ❑ Client ❑ Courier[—] Othei
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
Clear
SAMPLE/COOLER RECEIPT CHECKLIST
AES Work Order Number: 2304U07
Yes No N/A Details Comments
Save as
Shipping container/cooler received in good condition?
U
damaged ❑ leaking ❑ other❑
Custody seals present on shipping container?
•
Custody seals intact on shipping container?
•
Temperature blanks present?
0•
Cooler temperature(s) within limits of 0-6°C? [See item 13 and 14 for
temperature recordings.]
O
O
O
Cooling initiated for recently collected samples / ice
present ❑
Chain of Custody (COC) present?
•
Chain of Custody signed, dated, and timed when relinquished and received?
Sampler name and/or signature on COC?•Were
all samples received within holding time?TAT
i
marked on the COC?
If no TAT indicated, proceeded with standard TAT per Terms & Conditions. ❑
13. Cooler 1 Temperature 0.3 °C Cooler 2 Temperature
14. Cooler 5 Temperature °C Cooler 6 Temperature
15. Comments:
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
°C Cooler 3 Temperature °C Cooler 4 Temperature °C
°C Cooler 7 Temperature °C Cooler 8 Temperature °C
I certify that I have completed sections 1-15 (dated initials). DG 4/29/23
Yes No N/A Details Comments
Were sample containers intact upon receipt?
•
Custody seals present on sample containers?
•
Custody seals intact on sample containers?
•
Do sample container labels match the COC?
O
O
O
incomplete info ❑ illegible ❑
no label ❑ other ❑
Are analyses requested indicated on the COC?
•
Were all of the samples listed on the COC received?
O
O
O
samples received but not listed on COC ❑
samples listed on COC not received ❑
Was the sample collection date/time noted?
•
Did we receive sufficient sample volume for indicated analyses?
•
Were samples received in appropriate containers?
•
Q
Were VOA samples received without headspace (< 1/4" bubble)?
•
Were trip blanks submitted?
-8-0
no
listed on COC ❑ not listed on COC ❑
27. Comments:
This section only applies to samples where pH can be I certify that I have completed sections 16-27 (dated initials). DG 4/29/23
checked at Sample Receipt. Yes No N/A Details Comments
Have containers needing chemical preservation been checked? * •
Containers meet preservation guidelines? I•
Was pH adjusted at Sample Receipt? •
' Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Coliforms, VOCs and Oil & Grease/TPH.
This also excludes metals by EPA 200.7, 200.8 and 245.1 which will be verified between 16 and 24 hours after preservation.
I certify that I have completed sections 28-30 (dated initials). DG 4/29/23
Checklist 7.9.20 Rev 3
Page 18 of 22 M Page 4 of 6

Analytical Environmental Services, Inc Date: 8-May-23
Client: Waypoint Analytical, LLC (Charlotte) ANALYTICAL QC SUMMARY REPORT
Project Name: 23-117-0008
Workorder: 2304U07 BatchID• 355704
Sample ID: MB-355704
Client ID:
Units:
mg/Kg Run No: Prep Date: 05/05/2023
515637
SampleType: MBLK
TestCode:
Nitrogen, Ammonia (as N) Extractable E350.1 MOD BatchID05/08/2023
355V"ysis Date: Seq No:
12152868
Analyte
Result
RPT Limit SPK value SPK Ref Val %REC
Low Limit High Limit RPQ4Wf Val %RPD
RPD Limit
Nitrogen, Ammonia (As N) Extractable BRL 10.0
Sample ID: LCS-355704
Client ID:
Units:
mg/Kg Run No: Prep Date: 05/05/2023
515637
SampleType: LCS
TestCode:
Nitrogen, Ammonia (as N) Extractable E350.1 MOD BatcIM08/2023
3557"ysis Date: Seq No:
12152870
Analyte
Result
RPT Limit SPK value SPK Ref Val %REC
Low Limit High Limit RPQdWf Val %RPD
RPD Limit
Nitrogen, Ammonia (As N) Extractable 99.50 10.0 100.0 99.5 90 110
Sample ID: 2305182-001AMS Client ID: Units: mg/Kg-dry Prep Date: 05/05/2023 Run No: 515637
SampleType: MS TestCode: Nitrogen, Ammonia (as N) Extractable E350A MOD BatchID: 355704 Analysis Date: 05/08/2023 Seq No: 12152875
Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual
Nitrogen, Ammonia (As N) Extractable 2220 54.1 541.2 2018 37.5 90 110 S
Sample ID: 2305182-001AMSD
Client ID:
Units: mg/Kg-dry Prep Date: 05/05/2023
Run No: 515637
SampleType: MSD
TestCode: Nitrogen, Ammonia (as N) Extractable E350.1 MOD
BatchID: 355704 Analysis Date: 05/08/2023
Seq No: 12152877
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit High Limit RPD Ref Val %RPD
RPD Limit Qual
Nitrogen, Ammonia (As N) Extractable 2600
Qualifiers: > Greater than Result value
BRL Below reporting limit
J Estimated value detected below Reporting Limit
Rpt Lim Reporting Limit
54.1 541.2 2018 108 90 22.4 110
< Less than Result value
E Estimated (vabe a46wW pg eoneam6mrpngWation or analysis exceeded
N Analyte not NELAC certified
S Spike Recovery outside limits due to matrix
2220 15.8
B Analyte detected in the associated method blank
R RPD outside limits due to matrix
Page 19 of 22 Page 5 of 6

End of Report
Page 20 of 22 Page 6 of 6

(2)
WayPAo0nt..
NALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 01050
Customer Name: City of Statesville, NC
Report Number: 23-117-0008
Shipping Method
0 Fed Ex 0 US Postal U Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IRT15 2.6C
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
F
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
Yes
0 No
COC agrees with sample Iabel(s)?
U Yes
0 No
COC properly completed
U Yes
0 No
Samples in proper containers?
U Yes
0 No
Sample containers intact?
Yes
0 No
Sufficient sample volume for indicated test(s)?
Yes
0 No
All samples received within holding time?
Yes
0 No
Cooler temperature in compliance?
Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
0 N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr) F Low concentration EnCore samplers (48 hr)
F_ High concentration pre -weighed (methanol -14 d) Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included?
0 Yes
0 No
Comments:
Signature: Angelo Norvell Date & Time: 04/27/2023 11:50:34
Page 21 of 22

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Page 22 of 22

Waypoeinto
ANALYTICAL
2/6/2024
City of Statesville, NC
Ken Galloway
693 Bell Farm Road
Statesville, NC, 28625
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Ref: Analytical Testing
Lab Report Number: 24-022-0014
Client Project Description: 3rd Creek/4th Creek/Stalime
Dear Ken Galloway:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 1/22/2024 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136
Method Update Rule May 2021) unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Terri W Cole
Laboratory Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 23

Waypoint
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytica I.tom
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State
Program
Lab ID
Expiration Date
North Carolina
State Program
37735
07/31/2024
North Carolina
State Program
402
12/31/2024
South Carolina
State Program
99012
07/31/2024
South Carolina
State Program
99012
12/31/2023
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/29/2024
Arkansas
State Program
88-0650
02/07/2025
California
State Program
2904
06/30/2024
Florida
State Program - NELAP
E871157
06/30/2024
Georgia
State Program
C044
11/14/2025
Georgia
State Program
04015
06/30/2024
Illinois
State Program
- NELAP
200078
10/31/2024
Kentucky
State Program
80215
06/30/2024
Kentucky
State Program
KY90047
12/31/2024
Louisiana
State Program
- NELAP
LA037
12/31/2024
Louisiana
State Program
- NELAP
04015
06/30/2024
Mississippi
State Program
MS
11/14/2025
North Carolina
State Program
47701
07/31/2024
North Carolina
State Program
415
12/31/2024
Pennsylvania
State Program
- NELAP
68-03195
05/31/2024
South Carolina
State Program
84002
06/30/2024
Tennessee
State Program
02027
11/14/2025
Texas
State Program
- NELAP
T104704180
09/30/2024
Virginia
State Program
00106
06/30/2024
Virginia
State Program
- NELAP
460181
09/14/2024
Page 1 of 1 00016/24-022-0014
Page 2 of 23

Waypoint (D 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
Sample Summary Table
Report Number: 24-022-0014
Client Project Description: 3rd Creek/4th Creek/Stalime
Lab No
Client Sample ID
Matrix
Date Collected
Date Received
Method
Lab ID
94822
Stalime
TCLP
01/22/2024 10:05
01/22/2024 12:15
94822
Stalime
TCLP
01/22/2024 10:05
01/22/2024 12:15
8151A
WP MTN
94822
Stalime
TCLP
01/22/2024 10:05
01/22/2024 12:15
SW-1311
WP MTN
94822
Stalime
TCLP
01/22/2024 10:05
01/22/2024 12:15
8270C
WP MTN
94822
Stalime
TCLP
01/22/2024 10:05
01/22/2024 12:15
8081E
WP MTN
94822
Stalime
TCLP
01/22/2024 10:05
01/22/2024 12:15
6010D
WP MTN
94822
Stalime
TCLP
01/22/2024 10:05
01/22/2024 12:15
7470A
WP MTN
94823
Stalime
Solids
01/22/2024 10:05
01/22/2024 12:15
94823
Stalime
Solids
01/22/2024 10:05
01/22/2024 12:15
SW-7.3.4
WP MTN
94823
Stalime
Solids
01/22/2024 10:05
01/22/2024 12:15
SW-7.3.3
WP MTN
94824
3rd Creek
TCLP
01/22/2024 10:10
01/22/2024 12:15
94824
3rd Creek
TCLP
01/22/2024 10:10
01/22/2024 12:15
7470A
WP MTN
94824
3rd Creek
TCLP
01/22/2024 10:10
01/22/2024 12:15
SW-1311
WP MTN
94824
3rd Creek
TCLP
01/22/2024 10:10
01/22/2024 12:15
8081E
WP MTN
94824
3rd Creek
TCLP
01/22/2024 10:10
01/22/2024 12:15
6010D
WP MTN
94824
3rd Creek
TCLP
01/22/2024 10:10
01/22/2024 12:15
8270C
WP MTN
94824
3rd Creek
TCLP
01/22/2024 10:10
01/22/2024 12:15
8151A
WP MTN
94825
3rd Creek
Solids
01/22/2024 10:10
01/22/2024 12:15
94825
3rd Creek
Solids
01/22/2024 10:10
01/22/2024 12:15
SW-7.3.4
WP MTN
94825
3rd Creek
Solids
01/22/2024 10:10
01/22/2024 12:15
SW-7.3.3
WP MTN
94826
4th Creek
TCLP
01/22/2024 10:15
01/22/2024 12:15
94826
4th Creek
TCLP
01/22/2024 10:15
01/22/2024 12:15
8151A
WP MTN
94826
4th Creek
TCLP
01/22/2024 10:15
01/22/2024 12:15
8081E
WP MTN
94826
4th Creek
TCLP
01/22/2024 10:15
01/22/2024 12:15
7470A
WP MTN
94826
4th Creek
TCLP
01/22/2024 10:15
01/22/2024 12:15
6010D
WP MTN
94826
4th Creek
TCLP
01/22/2024 10:15
01/22/2024 12:15
8270C
WP MTN
94826
4th Creek
TCLP
01/22/2024 10:15
01/22/2024 12:15
SW-1311
WP MTN
WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN
Page 3 of 23

waypoint (D 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
Sample Summary Table
Report Number: 24-022-0014
Client Project Description: 3rd Creek/4th Creek/Stalime
Lab No
Client Sample ID
Matrix
Date Collected
Date Received Method Lab ID
94827
4th Creek
Solids
01/22/2024 10:15
01/22/2024 12:15
94827
4th Creek
Solids
01/22/2024 10:15
01/22/2024 12:15 SW-7.3.4 WP MTN
94827
4th Creek
Solids
01/22/2024 10:15
01/22/2024 12:15 SW-7.3.3 WP MTN
WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN
Page 4 of 23

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Client: City of Statesville, NC CASE NARRATIVE
Project: 3rd Creek/4th Creek/Stalime
Lab Report Number: 24-022-0014
Date: 2/2/2024
Separatory Funnel Extraction 8270 Method 3510C
Sample 94824 (3rd Creek)
QC Batch No: L730209/L730209
The weight/volume extracted was reduced during the extraction procedure due to the nature of the sample.
Reporting limits are factored for the sample size reduction.
Sample 94826 (4th Creek)
QC Batch No: L730209/L730209
The weight/volume extracted was reduced during the extraction procedure due to the nature of the sample.
Reporting limits are factored for the sample size reduction.
Sulfide Reactivity Method SW-7.3.4
Analyte: Sulfide
QC Batch No: L729844
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the
batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Total Aqueous Mercury Analysis - CVAA (TCLP) Method 7470A
Sample 94826 (4th Creek)
Analyte: Mercury
QC Batch No: L730093/L729992
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Volatile Organic Compounds - GUMS (TCLP) Method 8260D
Analyte: Carbon Tetrachloride
QC Batch No: V42848/V42847
This target analyte was flagged for recoveries outside QC limits in the associated LCS/LCSD. Data for this
analyte is flagged "M" to indicate that results should be considered minimum concentration due to the potential for
a low bias.
Semivolatile Organic Compounds - GC/MS (TCLP) Method 8270D
Sample 94822 (Stalime)
QC Batch No: L730453/L730209
The sample was diluted due to the nature of the sample matrix. Reporting limits have been adjusted accordingly.
Sample 94826 (4th Creek)
QC Batch No: L730453/L730209
The sample was diluted due to the nature of the sample matrix. Reporting limits have been adjusted accordingly.
Sample 94822 (Stalime)
Analyte: 2,4,6-Tribromophenol
QC Batch No: L730453/L730209
Page 5 of 23

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Surrogate(s) exhibited a high bias in this project sample where no target analytes were detected. The high
recovery(s) had no impact on the data. Batch QC samples (method blank and laboratory control samples) all
showed surrogates within QC limits.
Page 6 of 23

Waypointo
ANALYTICAL
01050
City of Statesville, NC
Ken Galloway
693 Bell Farm Road
Statesville , NC 28625
Report Number : 24-022-0014
Lab No : 94822
Sample ID: Stalime
Project
Information
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypoi nta na lytica Isom
3rd Creek/4th Creek/Stalime
REPORT OF ANAL YSIS
Report Date : 02/06/2024
Received I: j01�/22/2024 �
Terri W Cole
Laboratory Project Manager
Matrix: TCLP
Sampled: 1/ 22/ 2024 10:05
Test Results Units MQL DF Date / Time By Analytical
Analyzed Method
TCLP Herbicide Extraction
Leachate
1
01/29/24 15:00
TIT
SW-1311
TCLP Metals Extraction
Leachate
1
01/29/24 15:00
TJT
SW-1311
TCLP Pesticide Extraction
Leachate
1
01/29/24 15:00
TJT
SW-1311
TCLP SVOC Extraction
Leachate
1
01/29/24 15:00
TJT
SW-1311
TCLP VOC ZHE Extraction
Leachate
1
01/24/24 19:30
TBL
SW-1311 (ZHE)
Analytical Method: 6010D
Prep Batch(es):
L729970
01/30/24 11:46
Prep Method: 3015A
Test
Results
Units
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
TCLP Arsenic
<0.250
mg/L
0.250
1
01/30/24 15:27
BKN
L730052
TCLP Barium
0.928
mg/L
0.250
1
01/30/24 15:27
BKN
L730052
TCLP Cadmium
<0.0500
mg/L
0.0500
1
01/30/24 15:27
BKN
L730052
TCLP Chromium
<0.100
mg/L
0.100
1
01/30/24 15:27
BKN
L730052
TCLP Lead
<0.100
mg/L
0.100
1
01/30/24 15:27
BKN
L730052
TCLP Selenium
<0.500
mg/L
0.500
1
01/30/24 15:27
BKN
L730052
TCLP Silver
<0.0500
mg/L
0.0500
1
01/30/24 15:27
BKN
L730052
Qualifiers/ * Outside QC Limit DF Dilution Factor
Definitions H Beyond holding time M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 7 of 23

0
• nt�/aJ/pOI
449 Springbrook
Rd, Charlotte, NC 28217
■ ■ •r ,
Main 704.529.6364
ANALYTICAL
www.waypointanalytical.com
01050
City of Statesville, NC Project 3rd Creek/4th Creek/Stalime
Ken Galloway
Report Date : 02/06/2024
693 Bell Farm Road Information :
Received : 01/22/2024
Statesville , NC 28625
JM W��
Terri W Cole
Report Number : 24-022-0014
REPOR T OF A NA L YSIS
Laboratory Project Manager
Lab No : 94822
Matrix: TCLP
Sample ID: Stalime
Sampled: 1/22/2024 10:05
Analytical Method: 7470A
Prep Batch(es):
L729992
01/30/24 11:40
Prep Method: 7470A
Test Results
Units
MQL
DF Date / Time By Analytical
Analyzed Batch
TCLP Mercury <0.0200
mg/L
0.0200
1 01/30/24 15:09 FDS L730093
Analytical Method: 8081E
Prep Batch(es):
L730527
02/01/24 13:30
Prep Method: 3510C
Test Results
Units
MQL
DF Date / Time By Analytical
Analyzed Batch
TCLP Endrin <0.001600
mg/L
0.001600
10 02/01/24 19:37 VIC L730745
TCLP gamma-BHC <0.001600
mg/L
0.001600
10 02/01/24 19:37 VIC L730745
TCLP Methoxychlor <0.001600
mg/L
0.001600
10 02/01/24 19:37 VIC L730745
TCLP Toxaphene <0.01200
mg/L
0.01200
10 02/01/24 19:37 VIC L730745
TCLP Chlordane <0.008000
mg/L
0.008000
10 02/01/24 19:37 VIC L730745
TCLP Heptachlor Epoxide <0.001600
mg/L
0.001600
10 02/01/24 19:37 VIC L730745
TCLP Heptachlor <0.001600
mg/L
0.001600
10 02/01/24 19:37 VIC L730745
Surrogate: Decachlorobiphenyl
80.04
Limits: 36-116% 10 02/01/24 19:37 L730745
Surrogate: Tetrachloro-m-xylene
57.92
Limits: 25-123% 10 02/01/24 19:37 L730745
Analytical Method: 8151A
Prep Batch(es):
L730318
01/31/24 16:00
Prep Method: 8151A
Test Results
Units
MQL
DF Date / Time By Analytical
Analyzed Batch
TCLP 2,4-D <0.0200
mg/L
0.0200
1 02/02/24 01:08 VIC L730742
TCLP 2,4,5-TP (Silvex) <0.0020
mg/L
0.0020
1 02/02/24 01:08 VIC L730742
Surrogate: DCAA
54.60
Limits: 20-120% 1 02/02/24 01:08 L730742
Qualifiers/ * Outside QC Limit
DF Dilution Factor
Definitions H Beyond holding time
M Minimum value
MQL Method Quantitation Limit
Q RPD >40% dual column results
Page 8 of 23

�n
W�ypOI ■ ■� . 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01050
City of Statesville, NC Project 3rd Creek/4th Creek/Stalime
Ken Galloway
Report Date : 02/06/2024
693 Bell Farm Road
Information :
Received : 01/22/2024
Statesville , NC 28625
I I ,
W
V0
Terri W Cole
Report Number : 24-022-0014
REPOR T OF A
NA L YSIS
Laboratory Project Manager
Lab No : 94822
Matrix:
TCLP
Sample ID: Stalime
Sampled:
1/22/2024 10:05
Analytical Method: 8260D
Prep Batch(es):
V42847 01/26/24 09:00
Prep Method: 5030E
Test
Results
Units
MQL
DF
Date / Time
By Analytical
Analyzed
Batch
TCLP Benzene
<0.0050
mg/L
0.0050
10
01/26/24 18:27
MSA V42848
TCLP Carbon Tetrachloride
<0.0200 M
mg/L
0.0200
10
01/26/24 18:27
MSA V42848
TCLP Chlorobenzene
<0.0050
mg/L
0.0050
10
01/26/24 18:27
MSA V42848
TCLP Chloroform
<0.0050
mg/L
0.0050
10
01/26/24 18:27
MSA V42848
TCLP 1,4-Dichlorobenzene
<0.0050
mg/L
0.0050
10
01/26/24 18:27
MSA V42848
TCLP 1,2-Dichloroethane
<0.0050
mg/L
0.0050
10
01/26/24 18:27
MSA V42848
TCLP 1,1-Dichloroethene
<0.0050
mg/L
0.0050
10
01/26/24 18:27
MSA V42848
TCLP Methyl Ethyl Ketone (MEK)
0.105
mg/L
0.0500
10
01/26/24 18:27
MSA V42848
TCLP Tetrachloroethene
<0.0050
mg/L
0.0050
10
01/26/24 18:27
MSA V42848
TCLP Trichloroethene
<0.0050
mg/L
0.0050
10
01/26/24 18:27
MSA V42848
TCLP Vinyl Chloride
<0.0050
mg/L
0.0050
10
01/26/24 18:27
MSA V42848
Surrogate:4-Bromofluorobenzene
98.0
Limits: 80-124%
10 01/26/24 18:27 MSA V42848
Surrogate: Dibromofluoromethane
83.2
Limits: 75-129%
10 01/26/24 18:27 MSA V42848
Surrogate: Toluene-d8
96.6
Limits: 77-123%
10 01/26/24 18:27 MSA V42848
Analytical Method: 8270C
Prep Batch(es):
L730209 01/31/24 10:20
Prep Method: 3510C
Test
Results
Units
MQL
DF
Date / Time
By Analytical
Analyzed
Batch
TCLP 2-Methylphenol
<0.0250
mg/L
0.0250
5
01/31/24 19:06
SMB L730453
TCLP 3&4 Methylphenol
<0.0250
mg/L
0.0250
5
01/31/24 19:06
SMB L730453
TCLP 2,4-Dinitrotoluene
<0.0250
mg/L
0.0250
5
01/31/24 19:06
SMB L730453
TCLP Hexachlorobenzene
<0.0250
mg/L
0.0250
5
01/31/24 19:06
SMB L730453
Qualifiers/ * Outside QC Limit
DF
Dilution Factor
Definitions H Beyond holding
time
M
Minimum
value
MQL Method Quantitation Limit
Q
RPD
>40% dual column
results
Page 9 of 23

• nt�/aJ/pOI ■ ■ •r , 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01050
City of Statesville, NC Project 3rd Creek/4th Creek/Stalime
Ken Galloway Report Date : 02/06/2024
693 Bell Farm Road Information : Received : 01/22/2024
Statesville , NC 28625 JM
W��
Terri W Cole
Report Number : 24-022-0014 REPOR T OF A NA L YSIS Laboratory Project Manager
Lab No : 94822
Sample ID: Stalime
Matrix: TCLP
Sampled: 1/22/2024 10:05
Analytical Method: 8270C
Prep Batch(es):
L730209 01/31/24 10:20
Prep Method: 3510C
Test
Results
Units
MQL
DF
Date / Time By
Analytical
Analyzed
Batch
TCLP Hexachlorobutadiene
<0.0250
mg/L
0.0250
5
01/31/24 19:06 SMB
L730453
TCLP Hexachloroethane
<0.0250
mg/L
0.0250
5
01/31/24 19:06 SMB
L730453
TCLP Nitrobenzene
<0.0250
mg/L
0.0250
5
01/31/24 19:06 SMB
L730453
TCLP Pentachlorophenol
<0.0500
mg/L
0.0500
5
01/31/24 19:06 SMB
L730453
TCLP Pyridine
<0.0500
mg/L
0.0500
5
01/31/24 19:06 SMB
L730453
TCLP 2,4,5-Trichlorophenol
<0.0250
mg/L
0.0250
5
01/31/24 19:06 SMB
L730453
TCLP 2,4,6-Trichlorophenol
<0.0250
mg/L
0.0250
5
01/31/24 19:06 SMB
L730453
Surrogate: TCLP 2,4,6-Tribromophenol
108 *
Limits: 42-102%
5 01/31/24 19:06 SMB
L730453
Surrogate: TCLP 2-Fluorobiphenyl
64.5
Limits: 24-86%
5 01/31/24 19:06 SMB
L730453
Surrogate: TCLP 2-Fluorophenol
27.5
Limits: 13-37%
5 01/31/24 19:06 SMB
L730453
Surrogate: TCLP 4-Terphenyl-d14
79.0
Limits: 30-122%
5 01/31/24 19:06 SMB
L730453
Surrogate: TCLP Nitrobenzene-d5
55.3
Limits: 25-78%
5 01/31/24 19:06 SMB
L730453
Surrogate: TCLP Phenol-d6
19.8
Limits: 9-27%
5 01/31/24 19:06 SMB
L730453
Qualifiers/ * Outside QC Limit DF Dilution Factor
Definitions H Beyond holding time M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 10 of 23

Waypointo
ANALYTICAL
01050
City of Statesville, NC
Ken Galloway
693 Bell Farm Road
Statesville , NC 28625
Report Number : 24-022-0014
Lab No : 94823
Sample ID: Stalime
Project
Information
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypoi nta na lytica Isom
3rd Creek/4th Creek/Stalime
REPORT OF ANAL YSIS
Report Date : 02/06/2024
Received I: j01�/22/2024 �
Terri W Cole
Laboratory Project Manager
Matrix: Solids
Sampled: 1/ 22/ 2024 10:05
Test
Results
Units
MQL DF
Date / Time
Analyzed
By
Analytical
Method
Sulfide (Reactivity)
<25.0
mg/Kg
25.0 1
01/29/24 17:02
CNB
SW-7.3.4
Moisture
8.93
%
1
01/25/2415:51
PEB
SW-DRYWT
Cyanide, Reactive
<0.126
mg/Kg
0.126 1
01/30/24 17:15
CNB
SW-7.3.3
Ignitability
0.000
mm/sec
1
01/30/2416:12
RLW
SW-1030
pH
12.7 H
S.U.
1
01/22/24 12:00
JMD
9045D
Qualifiers/ * Outside QC Limit DF Dilution Factor
Definitions H Beyond holding time M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 11 of 23

Waypointo
ANALYTICAL
01050
City of Statesville, NC
Ken Galloway
693 Bell Farm Road
Statesville , NC 28625
Report Number : 24-022-0014
Lab No : 94824
Sample ID : 3rd Creek
Project
Information
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypoi nta na lytica Isom
3rd Creek/4th Creek/Stalime
REPORT OF ANAL YSIS
Report Date : 02/06/2024
Received I: j01�/22/2024 �
Terri W Cole
Laboratory Project Manager
Matrix: TCLP
Sampled: 1/ 22/ 2024 10:10
Test Results Units MQL DF Date / Time By Analytical
Analyzed Method
TCLP Herbicide Extraction
Leachate
1
01/29/24 15:00
TIT
SW-1311
TCLP Metals Extraction
Leachate
1
01/29/24 15:00
TJT
SW-1311
TCLP Pesticide Extraction
Leachate
1
01/29/24 15:00
TJT
SW-1311
TCLP SVOC Extraction
Leachate
1
01/29/24 15:00
TJT
SW-1311
TCLP VOC ZHE Extraction
Leachate
1
01/24/24 19:30
TBL
SW-1311 (ZHE)
Analytical Method: 6010D
Prep Batch(es):
L729970
01/30/24 11:46
Prep Method: 3015A
Test
Results
Units
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
TCLP Arsenic
<0.250
mg/L
0.250
1
01/30/24 15:32
BKN
L730052
TCLP Barium
<0.250
mg/L
0.250
1
01/30/24 15:32
BKN
L730052
TCLP Cadmium
<0.0500
mg/L
0.0500
1
01/30/24 15:32
BKN
L730052
TCLP Chromium
<0.100
mg/L
0.100
1
01/30/24 15:32
BKN
L730052
TCLP Lead
<0.100
mg/L
0.100
1
01/30/24 15:32
BKN
L730052
TCLP Selenium
<0.500
mg/L
0.500
1
01/30/24 15:32
BKN
L730052
TCLP Silver
<0.0500
mg/L
0.0500
1
01/30/24 15:32
BKN
L730052
Qualifiers/ * Outside QC Limit DF Dilution Factor
Definitions H Beyond holding time M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 12 of 23

0
• nt�/aJ/pOI
449 Springbrook
Rd, Charlotte, NC 28217
■ ■ •r ,
Main 704.529.6364
ANALYTICAL
www.waypointanalytical.com
01050
City of Statesville, NC Project 3rd Creek/4th Creek/Stalime
Ken Galloway
Report Date : 02/06/2024
693 Bell Farm Road Information :
Received : 01/22/2024
Statesville , NC 28625
JM W��
Terri W Cole
Report Number : 24-022-0014
REPOR T OF A NA L YSIS
Laboratory Project Manager
Lab No : 94824
Matrix: TCLP
Sample ID : 3rd Creek
Sampled: 1/22/2024 10:10
Analytical Method: 7470A
Prep Batch(es):
L729992
01/30/24 11:40
Prep Method: 7470A
Test Results
Units
MQL
DF Date / Time By Analytical
Analyzed Batch
TCLP Mercury <0.0200
mg/L
0.0200
1 01/30/24 15:10 FDS L730093
Analytical Method: 8081E
Prep Batch(es):
L730527
02/01/24 13:30
Prep Method: 3510C
Test Results
Units
MQL
DF Date / Time By Analytical
Analyzed Batch
TCLP Endrin <0.001600
mg/L
0.001600
10 02/01/24 20:05 VIC L730745
TCLP gamma-BHC <0.001600
mg/L
0.001600
10 02/01/24 20:05 VIC L730745
TCLP Methoxychlor <0.001600
mg/L
0.001600
10 02/01/24 20:05 VIC L730745
TCLP Toxaphene <0.01200
mg/L
0.01200
10 02/01/24 20:05 VIC L730745
TCLP Chlordane <0.008000
mg/L
0.008000
10 02/01/24 20:05 VIC L730745
TCLP Heptachlor Epoxide <0.001600
mg/L
0.001600
10 02/01/24 20:05 VIC L730745
TCLP Heptachlor <0.001600
mg/L
0.001600
10 02/01/24 20:05 VIC L730745
Surrogate: Decachlorobiphenyl
86.50
Limits: 36-116% 10 02/01/24 20:05 L730745
Surrogate: Tetrachloro-m-xylene
59.17
Limits: 25-123% 10 02/01/24 20:05 L730745
Analytical Method: 8151A
Prep Batch(es):
L730318
01/31/24 16:00
Prep Method: 8151A
Test Results
Units
MQL
DF Date / Time By Analytical
Analyzed Batch
TCLP 2,4-D <0.0200
mg/L
0.0200
1 02/02/24 01:33 VIC L730742
TCLP 2,4,5-TP (Silvex) <0.0020
mg/L
0.0020
1 02/02/24 01:33 VIC L730742
Surrogate: DCAA
82.20
Limits: 20-120% 1 02/02/24 01:33 L730742
Qualifiers/ * Outside QC Limit
DF Dilution Factor
Definitions H Beyond holding time
M Minimum value
MQL Method Quantitation Limit
Q RPD >40% dual column results
Page 13 of 23

�n
W�ypOI ■ ■� . 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01050
City of Statesville, NC Project 3rd Creek/4th Creek/Stalime
Ken Galloway
Report Date : 02/06/2024
693 Bell Farm Road
Information :
Received : 01/22/2024
Statesville , NC 28625
I I ,
W
V0
Terri W Cole
Report Number : 24-022-0014
REPOR T OF A
NA L YSIS
Laboratory Project Manager
Lab No : 94824
Matrix:
TCLP
Sample ID : 3rd Creek
Sampled:
1/22/2024 10:10
Analytical Method: 8260D
Prep Batch(es):
V42847 01/26/24 09:00
Prep Method: 5030E
Test
Results
Units
MQL
DF
Date / Time
By Analytical
Analyzed
Batch
TCLP Benzene
<0.0050
mg/L
0.0050
10
01/26/24 18:52
MSA V42848
TCLP Carbon Tetrachloride
<0.0200 M
mg/L
0.0200
10
01/26/24 18:52
MSA V42848
TCLP Chlorobenzene
<0.0050
mg/L
0.0050
10
01/26/24 18:52
MSA V42848
TCLP Chloroform
<0.0050
mg/L
0.0050
10
01/26/24 18:52
MSA V42848
TCLP 1,4-Dichlorobenzene
<0.0050
mg/L
0.0050
10
01/26/24 18:52
MSA V42848
TCLP 1,2-Dichloroethane
<0.0050
mg/L
0.0050
10
01/26/24 18:52
MSA V42848
TCLP 1,1-Dichloroethene
<0.0050
mg/L
0.0050
10
01/26/24 18:52
MSA V42848
TCLP Methyl Ethyl Ketone (MEK)
0.101
mg/L
0.0500
10
01/26/24 18:52
MSA V42848
TCLP Tetrachloroethene
<0.0050
mg/L
0.0050
10
01/26/24 18:52
MSA V42848
TCLP Trichloroethene
<0.0050
mg/L
0.0050
10
01/26/24 18:52
MSA V42848
TCLP Vinyl Chloride
<0.0050
mg/L
0.0050
10
01/26/24 18:52
MSA V42848
Surrogate:4-Bromofluorobenzene
102
Limits: 80-124%
10 01/26/24 18:52 MSA V42848
Surrogate: Dibromofluoromethane
87.0
Limits: 75-129%
10 01/26/24 18:52 MSA V42848
Surrogate: Toluene-d8
98.6
Limits: 77-123%
10 01/26/24 18:52 MSA V42848
Analytical Method: 8270C
Prep Batch(es):
L730209 01/31/24 10:20
Prep Method: 3510C
Test
Results
Units
MQL
DF
Date / Time
By Analytical
Analyzed
Batch
TCLP 2-Methylphenol
<0.0120
mg/L
0.0120
1
01/31/24 19:28
SMB L730453
TCLP 3&4 Methylphenol
<0.0120
mg/L
0.0120
1
01/31/24 19:28
SMB L730453
TCLP 2,4-Dinitrotoluene
<0.0120
mg/L
0.0120
1
01/31/24 19:28
SMB L730453
TCLP Hexachlorobenzene
<0.0120
mg/L
0.0120
1
01/31/24 19:28
SMB L730453
Qualifiers/ * Outside QC Limit
DF
Dilution Factor
Definitions H Beyond holding
time
M
Minimum
value
MQL Method Quantitation Limit
Q
RPD
>40% dual column
results
Page 14 of 23

• nt�/aJ/pOI ■ ■ •r , 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01050
City of Statesville, NC Project 3rd Creek/4th Creek/Stalime
Ken Galloway Report Date : 02/06/2024
693 Bell Farm Road Information : Received : 01/22/2024
Statesville , NC 28625 JM
W��
Terri W Cole
Report Number : 24-022-0014 REPOR T OF A NA L YSIS Laboratory Project Manager
Lab No : 94824
Sample ID : 3rd Creek
Matrix: TCLP
Sampled: 1/22/2024 10:10
Analytical Method: 8270C
Prep Batch(es):
L730209 01/31/24 10:20
Prep Method: 3510C
Test
Results
Units
MQL
DF
Date / Time By
Analytical
Analyzed
Batch
TCLP Hexachlorobutadiene
<0.0120
mg/L
0.0120
1
01/31/24 19:28 SMB
L730453
TCLP Hexachloroethane
<0.0120
mg/L
0.0120
1
01/31/24 19:28 SMB
L730453
TCLP Nitrobenzene
<0.0120
mg/L
0.0120
1
01/31/24 19:28 SMB
L730453
TCLP Pentachlorophenol
<0.0250
mg/L
0.0250
1
01/31/24 19:28 SMB
L730453
TCLP Pyridine
<0.0250
mg/L
0.0250
1
01/31/24 19:28 SMB
L730453
TCLP 2,4,5-Trichlorophenol
<0.0120
mg/L
0.0120
1
01/31/24 19:28 SMB
L730453
TCLP 2,4,6-Trichlorophenol
<0.0120
mg/L
0.0120
1
01/31/24 19:28 SMB
L730453
Surrogate: TCLP 2,4,6-Tribromophenol
76.3
Limits: 42-102%
1 01/31/24 19:28 SMB
L730453
Surrogate: TCLP 2-Fluorobiphenyl
59.8
Limits: 24-86%
1 01/31/24 19:28 SMB
L730453
Surrogate: TCLP 2-Fluorophenol
24.3
Limits: 13-37%
1 01/31/24 19:28 SMB
L730453
Surrogate: TCLP 4-Terphenyl-d14
68.8
Limits: 30-122%
1 01/31/24 19:28 SMB
L730453
Surrogate: TCLP Nitrobenzene-d5
50.5
Limits: 25-78%
1 01/31/24 19:28 SMB
L730453
Surrogate: TCLP Phenol-d6
17.2
Limits: 9-27%
1 01/31/24 19:28 SMB
L730453
Qualifiers/ * Outside QC Limit DF Dilution Factor
Definitions H Beyond holding time M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 15 of 23

Waypointo
ANALYTICAL
01050
City of Statesville, NC
Ken Galloway
693 Bell Farm Road
Statesville , NC 28625
Report Number : 24-022-0014
Lab No : 94825
Sample ID : 3rd Creek
Project
Information
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypoi nta na lytica Isom
3rd Creek/4th Creek/Stalime
REPORT OF ANAL YSIS
Report Date : 02/06/2024
Received I: j01�/22/2024 �
Terri W Cole
Laboratory Project Manager
Matrix: Solids
Sampled: 1/ 22/ 2024 10:10
Test
Results
Units
MQL DF
Date / Time
Analyzed
By
Analytical
Method
Sulfide (Reactivity)
<25.1
mg/Kg
25.1 1
01/29/24 17:02
CNB
SW-7.3.4
Moisture
86.4
%
1
01/25/2415:51
PEB
SW-DRYWT
Cyanide, Reactive
<0.125
mg/Kg
0.125 1
01/30/24 17:15
CNB
SW-7.3.3
Ignitability
0.000
mm/sec
1
01/30/2416:12
RLW
SW-1030
pH
5.95 H
S.U.
1
01/22/24 12:00
JMD
9045D
Qualifiers/ * Outside QC Limit DF Dilution Factor
Definitions H Beyond holding time M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 16 of 23

Waypointo
ANALYTICAL
01050
City of Statesville, NC
Ken Galloway
693 Bell Farm Road
Statesville , NC 28625
Report Number : 24-022-0014
Lab No : 94826
Sample ID : 4th Creek
Project
Information
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypoi nta na lytica Isom
3rd Creek/4th Creek/Stalime
REPORT OF ANAL YSIS
Report Date : 02/06/2024
Received I: j01�/22/2024 �
Terri W Cole
Laboratory Project Manager
Matrix: TCLP
Sampled: 1/ 22/ 2024 10:15
Test Results Units MQL DF Date / Time By Analytical
Analyzed Method
TCLP Herbicide Extraction
Leachate
1
01/29/24 15:00
TIT
SW-1311
TCLP Metals Extraction
Leachate
1
01/29/24 15:00
TJT
SW-1311
TCLP Pesticide Extraction
Leachate
1
01/29/24 15:00
TJT
SW-1311
TCLP SVOC Extraction
Leachate
1
01/29/24 15:00
TJT
SW-1311
TCLP VOC ZHE Extraction
Leachate
1
01/24/24 19:30
TBL
SW-1311 (ZHE)
Analytical Method: 6010D
Prep Batch(es):
L729970
01/30/24 11:46
Prep Method: 3015A
Test
Results
Units
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
TCLP Arsenic
<0.250
mg/L
0.250
1
01/30/24 15:48
BKN
L730052
TCLP Barium
<0.250
mg/L
0.250
1
01/30/24 15:48
BKN
L730052
TCLP Cadmium
<0.0500
mg/L
0.0500
1
01/30/24 15:48
BKN
L730052
TCLP Chromium
<0.100
mg/L
0.100
1
01/30/24 15:48
BKN
L730052
TCLP Lead
<0.100
mg/L
0.100
1
01/30/24 15:48
BKN
L730052
TCLP Selenium
<0.500
mg/L
0.500
1
01/30/24 15:48
BKN
L730052
TCLP Silver
<0.0500
mg/L
0.0500
1
01/30/24 15:48
BKN
L730052
Qualifiers/ * Outside QC Limit DF Dilution Factor
Definitions H Beyond holding time M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 17 of 23

0
• nt�/aJ/pOI
449 Springbrook
Rd, Charlotte, NC 28217
■ ■ •r ,
Main 704.529.6364
ANALYTICAL
www.waypointanalytical.com
01050
City of Statesville, NC Project 3rd Creek/4th Creek/Stalime
Ken Galloway
Report Date : 02/06/2024
693 Bell Farm Road Information :
Received : 01/22/2024
Statesville , NC 28625
JM W��
Terri W Cole
Report Number : 24-022-0014
REPOR T OF A NA L YSIS
Laboratory Project Manager
Lab No : 94826
Matrix: TCLP
Sample ID : 4th Creek
Sampled: 1/22/2024 10:15
Analytical Method: 7470A
Prep Batch(es):
L729992
01/30/24 11:40
Prep Method: 7470A
Test Results
Units
MQL
DF Date / Time By Analytical
Analyzed Batch
TCLP Mercury <0.0200
mg/L
0.0200
1 01/30/24 15:19 FDS L730093
Analytical Method: 8081E
Prep Batch(es):
L730527
02/01/24 13:30
Prep Method: 3510C
Test Results
Units
MQL
DF Date / Time By Analytical
Analyzed Batch
TCLP Endrin <0.001600
mg/L
0.001600
10 02/01/24 20:32 VIC L730745
TCLP gamma-BHC <0.001600
mg/L
0.001600
10 02/01/24 20:32 VIC L730745
TCLP Methoxychlor <0.001600
mg/L
0.001600
10 02/01/24 20:32 VIC L730745
TCLP Toxaphene <0.01200
mg/L
0.01200
10 02/01/24 20:32 VIC L730745
TCLP Chlordane <0.008000
mg/L
0.008000
10 02/01/24 20:32 VIC L730745
TCLP Heptachlor Epoxide <0.001600
mg/L
0.001600
10 02/01/24 20:32 VIC L730745
TCLP Heptachlor <0.001600
mg/L
0.001600
10 02/01/24 20:32 VIC L730745
Surrogate: Decachlorobiphenyl
47.46
Limits: 36-116% 10 02/01/24 20:32 L730745
Surrogate: Tetrachloro-m-xylene
42.00
Limits: 25-123% 10 02/01/24 20:32 L730745
Analytical Method: 8151A
Prep Batch(es):
L730318
01/31/24 16:00
Prep Method: 8151A
Test Results
Units
MQL
DF Date / Time By Analytical
Analyzed Batch
TCLP 2,4-D <0.0200
mg/L
0.0200
1 02/02/24 01:57 VIC L730742
TCLP 2,4,5-TP (Silvex) <0.0020
mg/L
0.0020
1 02/02/24 01:57 VIC L730742
Surrogate: DCAA
77.40
Limits: 20-120% 1 02/02/24 01:57 L730742
Qualifiers/ * Outside QC Limit
DF Dilution Factor
Definitions H Beyond holding time
M Minimum value
MQL Method Quantitation Limit
Q RPD >40% dual column results
Page 18 of 23

�n
W�ypOI ■ ■� . 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01050
City of Statesville, NC Project 3rd Creek/4th Creek/Stalime
Ken Galloway
Report Date : 02/06/2024
693 Bell Farm Road
Information :
Received : 01/22/2024
Statesville , NC 28625
I I ,
W
V0
Terri W Cole
Report Number : 24-022-0014
REPOR T OF A
NA L YSIS
Laboratory Project Manager
Lab No : 94826
Matrix:
TCLP
Sample ID : 4th Creek
Sampled:
1/22/2024 10:15
Analytical Method: 8260D
Prep Batch(es):
V42847 01/26/24 09:00
Prep Method: 5030E
Test
Results
Units
MQL
DF
Date / Time
By Analytical
Analyzed
Batch
TCLP Benzene
<0.0050
mg/L
0.0050
10
01/26/24 19:18
MSA V42848
TCLP Carbon Tetrachloride
<0.0200 M
mg/L
0.0200
10
01/26/24 19:18
MSA V42848
TCLP Chlorobenzene
<0.0050
mg/L
0.0050
10
01/26/24 19:18
MSA V42848
TCLP Chloroform
<0.0050
mg/L
0.0050
10
01/26/24 19:18
MSA V42848
TCLP 1,4-Dichlorobenzene
<0.0050
mg/L
0.0050
10
01/26/24 19:18
MSA V42848
TCLP 1,2-Dichloroethane
<0.0050
mg/L
0.0050
10
01/26/24 19:18
MSA V42848
TCLP 1,1-Dichloroethene
<0.0050
mg/L
0.0050
10
01/26/24 19:18
MSA V42848
TCLP Methyl Ethyl Ketone (MEK)
0.168
mg/L
0.0500
10
01/26/24 19:18
MSA V42848
TCLP Tetrachloroethene
<0.0050
mg/L
0.0050
10
01/26/24 19:18
MSA V42848
TCLP Trichloroethene
<0.0050
mg/L
0.0050
10
01/26/24 19:18
MSA V42848
TCLP Vinyl Chloride
<0.0050
mg/L
0.0050
10
01/26/24 19:18
MSA V42848
Surrogate:4-Bromofluorobenzene
98.6
Limits: 80-124%
10 01/26/24 19:18
MSA V42848
Surrogate: Dibromofluoromethane
87.4
Limits: 75-129%
10 01/26/24 19:18
MSA V42848
Surrogate: Toluene-d8
97.6
Limits: 77-123%
10 01/26/24 19:18
MSA V42848
Analytical Method: 8270C
Prep Batch(es):
L730209 01/31/24 10:20
Prep Method: 3510C
Test
Results
Units
MQL
DF
Date / Time
By Analytical
Analyzed
Batch
TCLP 2-Methylphenol
<0.0620
mg/L
0.0620
5
01/31/24 19:50
SMB L730453
TCLP 3&4 Methylphenol
<0.0620
mg/L
0.0620
5
01/31/24 19:50
SMB L730453
TCLP 2,4-Dinitrotoluene
<0.0620
mg/L
0.0620
5
01/31/24 19:50
SMB L730453
TCLP Hexachlorobenzene
<0.0620
mg/L
0.0620
5
01/31/24 19:50
SMB L730453
Qualifiers/ * Outside QC Limit
DF
Dilution Factor
Definitions H Beyond holding
time
M
Minimum
value
MQL Method Quantitation Limit
Q
RPD
>40% dual column
results
Page 19 of 23

• nt�/aJ/pOI ■ ■ •r , 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01050
City of Statesville, NC Project 3rd Creek/4th Creek/Stalime
Ken Galloway Report Date : 02/06/2024
693 Bell Farm Road Information : Received : 01/22/2024
Statesville , NC 28625 JM
W��
Terri W Cole
Report Number : 24-022-0014 REPOR T OF A NA L YSIS Laboratory Project Manager
Lab No : 94826
Sample ID : 4th Creek
Matrix: TCLP
Sampled: 1/22/2024 10:15
Analytical Method: 8270C
Prep Batch(es):
L730209 01/31/24 10:20
Prep Method: 3510C
Test
Results
Units
MQL
DF
Date / Time By
Analytical
Analyzed
Batch
TCLP Hexachlorobutadiene
<0.0620
mg/L
0.0620
5
01/31/24 19:50 SMB
L730453
TCLP Hexachloroethane
<0.0620
mg/L
0.0620
5
01/31/24 19:50 SMB
L730453
TCLP Nitrobenzene
<0.0620
mg/L
0.0620
5
01/31/24 19:50 SMB
L730453
TCLP Pentachlorophenol
<0.125
mg/L
0.125
5
01/31/24 19:50 SMB
L730453
TCLP Pyridine
<0.125
mg/L
0.125
5
01/31/24 19:50 SMB
L730453
TCLP 2,4,5-Trichlorophenol
<0.0620
mg/L
0.0620
5
01/31/24 19:50 SMB
L730453
TCLP 2,4,6-Trichlorophenol
<0.0620
mg/L
0.0620
5
01/31/24 19:50 SMB
L730453
Surrogate: TCLP 2,4,6-Tribromophenol
66.5
Limits: 42-102%
5 01/31/24 19:50 SMB
L730453
Surrogate: TCLP 2-Fluorobiphenyl
52.9
Limits: 24-86%
5 01/31/24 19:50 SMB
L730453
Surrogate: TCLP 2-Fluorophenol
18.9
Limits: 13-37%
5 01/31/24 19:50 SMB
L730453
Surrogate: TCLP 4-Terphenyl-d14
76.5
Limits: 30-122%
5 01/31/24 19:50 SMB
L730453
Surrogate: TCLP Nitrobenzene-d5
45.2
Limits: 25-78%
5 01/31/24 19:50 SMB
L730453
Surrogate: TCLP Phenol-d6
13.6
Limits: 9-27%
5 01/31/24 19:50 SMB
L730453
Qualifiers/ * Outside QC Limit DF Dilution Factor
Definitions H Beyond holding time M Minimum value
MQL Method Quantitation Limit Q RPD >40% dual column results
Page 20 of 23

Waypointo.
ANALYTICAL
01050
City of Statesville, NC
Ken Galloway
693 Bell Farm Road
Statesville , NC 28625
Report Number : 24-022-0014
Lab No : 94827
Sample ID : 4th Creek
Project
Information
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypoi nta na lytica Isom
3rd Creek/4th Creek/Stalime
REPORT OF ANAL YSIS
Report Date : 02/06/2024
Received I: j01�/22/2024 �
Terri W Cole
Laboratory Project Manager
Matrix: Solids
Sampled: 1/22/2024 10:15
Test
Results
Units
MQL DF
Date / Time
Analyzed
By
Analytical
Method
Sulfide (Reactivity)
<25.0
mg/Kg
25.0 1
01/29/24 17:02
CNB
SW-7.3.4
Moisture
82.7
%
1
01/25/2415:51
PEB
SW-DRYWT
Cyanide, Reactive
<0.125
mg/Kg
0.125 1
01/30/24 17:15
CNB
SW-7.3.3
Ignitability
0.000
mm/sec
1
01/30/2416:12
RLW
SW-1030
pH
6.94 H
S.U.
1
01/22/24 12:00
JMD
9045D
Qualifiers/ * Outside QC Limit
Definitions
DF Dilution Factor
Page 21 of 23

(2)
WayPAo0nt..
NALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 01050
Customer Name: City of Statesville, NC
Report Number: 24-022-0014
Shipping Method
0 Fed Ex 0 US Postal U Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IRT15 3.9C
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
F
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
Yes
0 No
COC agrees with sample Iabel(s)?
U Yes
0 No
COC properly completed
U Yes
0 No
Samples in proper containers?
U Yes
0 No
Sample containers intact?
Yes
0 No
Sufficient sample volume for indicated test(s)?
Yes
0 No
All samples received within holding time?
Yes
0 No
Cooler temperature in compliance?
Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
0 N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr) F Low concentration EnCore samplers (48 hr)
F_ High concentration pre -weighed (methanol -14 d) Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included?
0 Yes
0 No
Comments:
Signature: Angelo Norvell Date & Time: 01/22/2024 13:33:56
Page 22 of 23

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