NC0024911_Groundwater Monitoring Report January 2024_20240126

GW-59A COMPLIANCE REPORT FORM Permit # NCO024911
(Submit one each monitoring period with GIV--59 forms)
I
Enter date monitoring results were due. (_02/28/2024_) Will this monitoring report (GW-59 and GW-59A)
YES NQ
be submitted after the established due date?
2
Was any required information missing on the GW-59 report forms?
YES N
IF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
YES NO
identification plate, area overgrown, etc.)? If the answer is "Yes ", contact the Regional Office for guidance.
4
Are any monitored constituents equal to or above the established standards?
YE NO
If the answer to question 4 is "NO", skip to section 8.
If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s)
exceeding standards in the space provided below:
MW-05 MW-06R MW-07 MW-08R
pH 5.53
Mn 50.3 ug/L
5
For the constituents identified in question 4 above, have standards been exceeded previously for the
YES NO
same constituent(s) in the same well(s) in the last two years?
If the answer to question 5 is "NO", skip to section 8.
If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding standards,
concentration(s) reported, and sample collection date for each occurrence (for the last two years).
MW-05 pH Mn Fe MW-06R pH Mn Fe MW-07 pH Mn Fe MW-08R pH Mn Fe
1/24/22 5.7 1/24/22 5.17 12,300 ug/L 9,200 ug/L 1124/22 6.1 1/24/22 9.780 ug/L 32,300 ug/L
6/27122 5.52 76.2 ug/L 382 ug/L 6/27/22 5.67 14,100 ug/L 16,900 ug/L 6/27/22 5.89 191 ug/L 6/27122 17,000 ug/L 49,900 ug/L
10113/22 5.75 13.9 ug/L 66.5 ug/L 10113122 6.13 11,200 ug/L 34,800 ug/L 10/13/22 6.02 444 ug/L 10113122 8,850 ug/L 18,400 ug/L
1105/23 5.59 1105/23 5.55 9,970 ug/L 5,660 ug/L 1105123 6.41 1/05/23 14,900 ug/L 53,000 ug/L
6/12/23 5.28 529 ug/L 882 ug/L 6/12/23 5.21 8,710 ug/L 4,390 ug/L 6/12/23 5.65 6112123 17,700 ug/L 39,000 ug/L
10110/23 5.19 10/10123 5.62 10,800 ug/L 13,500 ug/L 10/10/23 5.62 1,870 ug/L 336 ug/L 10/10/23 10,000 ug/L 26,800 ug/L
6
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
YES NO
If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells maybe improperly
located; contact the Regional Office.
7
Is the permittee implementing previously approved actions required by the Division involving this
YES NO
groundwater quality problem?
If the answer to question 7 is "YES", describe those actions in the space provided below.
If the answer to question 7 is "NO", contact the Regional Office within 90 days: an evaluation may be
reauired to determine the impart the waste disposal system is having at the review and compliance
boundaries surroundina this facility Failure to do so may ubiect the permittee to a Notice of Violation.
fines. and/or penalties.
g
The person completing this portion (G W-59A) of the monitoring report should sign below and submit this
form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form.
I hereby acknowledge that the above information was evaluated and the information submitted in this
report (Compliance Report GW-59A) is true and complete to the best of my knowledge.
v 2-/
A2 V
Signature o er ee (or Authorized Agent) ate
GW-59A 12/8/2003

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
Clearly or
Facility Name: Metropolitan Sewerage District
Permit Name (if different):
Facility Address: 2225 Riverside Drive, Asheville, NC 28804
County Buncombe
act Person: Bart Farmer Telephone#: [phone]
Location/Site Name: Upgradient of Ash Lagoon No. of wells to be sampled: 4
IEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
DNISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
PERMIT Number: Expiration Date: 12/31/22
Non -Discharge UIC
NPDES NCO024911 Other
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
❑ Spray Field 0 Remediation:
❑ Rotary Distributor ❑ Land Application of Sludge
❑ Water Source Heat Pump ❑ Other:
WELL ID NUMBER (from Permit): MW-05 Date sample collected: 01/04/24
(Nell Depth: 24 ft. Well Diameter: 2 in.
Depth to Water Level 82546: 20.76 ft. below measuring point Screened Interval: 0 ft. to 24 ft.
Measuring Point is 0.0 ft. above land surface Relative M.P. Elevation: ft.
Volume of water pumped/bailed before sampling: .330 gallons
Samples for metals were collected unfiltered: YES ❑ NO and field acidified: 0 YES ❑ NO
LABORATORY INFORMATION
04/24 0119/24 Laboratory Name: Pace Analytical Services, LLC
Date sample analyzed. 0/ -
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615
Coliform: MF Fecal 31616
/100mL
Nitrate (NO3) as N 00620 <0.040
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
Dissolved Solids:Total 70300 35.0
mg/L
AI -Aluminum 01105
pH (Lab) 00403
units
Ba - Barium 01007 14.3
TOC 00680 <1.0
mg/L
Ca - Calcium 00916
Chloride oo94o 1.3
mg/L
Cd - Cadmium 01027 <1.0
Arsenic 01002 <10.0
ug/L
Chromium: Total 01034 <5.0
Grease and Oils 00552
mg/L
Cu - Copper 01042
Phenol 32730
ug/L
Fe - Iron 01045 210
Sulfate 00945 3.5
mg/L
Hg - Mercury 71900 <0.20
Specific Conductance 00095
µMhos
K - Potassium 00937
Total Ammonia 00610 <0.10
mg/L
Mg - Magnesium 00927
(Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055 50.3
TKN as N 00625
mg/L
Ni - Nickel 01067
For Remediation Systems Only (Attach Lab Reports):
Permittee (or Authorized Agent) Name and Title - Please print or type
Influent Total VOCs
mq/L
mg/L
mg/L
mg/L
mg/L
mg/L
ug/L
mg/L
ug/L
ug/L
mg/L
ug/L
ug/L
mg/L
mg/L
ug/L
ug/L
FIELD ANALYSES:
pH 00400: 5.53 units
Spec. Cond. 00094:35.0
Odor 00085: None Detected
Appearance Clear
Temp. 00010: 6.7 °C
µMhos
Certification No. 40,12
Pb -Lead olo51 <5.0 ug/L
Zn - Zinc 01092 mg/L
Other (Specify Compounds and Concentration Units):
Ag-Silver <5.0 ug/L
Se -Selenium <10.0 ug/L
Na-Sodium <5000 ug/L
ORGANICS: (by GC, GC/MS, HPLC)
(Specify test and method #. ATTACH LAB REPORT.)
Lab Report Attached? ❑ Yes (1) El No (0)
VOC 78732 method #
method #
method #
method #
Effluent Total VOCs:
VOC Removal%
WAS DRY
at time of
here:
GW-59 Rev.8/2013

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
Clearly or
Facility Name: Metropolitan Sewerage District
Permit Name (if different):
Facility Address: 2225 Riverside Drive, Asheville, NC 28804
County Buncombe
Contact Person: Bart Farmer Telephone#: [phone]
Well Location/Site Name: Downgradient of Ash Lagoon No. of wells to be sampled: 4
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
PERMIT Number: Expiration Date: 12/31/22
Non -Discharge UIC
NPDES NCO024911 Other
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
❑ Spray Field ❑ Remediation:
❑ Rotary Distributor ❑ Land Application of Sludge
❑ Water Source Heat Pump 0 Other:
If WELL
SAMPLING INFORMATION
WELL ID NUMBER (from Permit): MW-06R
Date sample collected: 01/04/24
FIELD ANALYSES:
WAS DRY
at time of
Well Depth: 18 ft.
2
Well Diameter: in.
H 00400: units Tem 000lo: oC
p P�
sampling,
Depth to Water Level 82546: 17.74 ft. below measuring point
Screened Interval: 8 ft. to
18 ft.
µMhos
Spec. Cond. 00094:
check
here:
Measuring Point is 0.0 ft. above land
surface
Relative M.P. Elevation: ft.
Odor 00085: None Detected
Volume of water pumped/bailed before sampling:
gallons
Appearance Clear
Samples for metals were collected unfiltered:
El YES ❑
NO and field acidified: El YES ❑ NO
LABORATORY INFORMATION
LaboratoryName: Pace Analytical Services, LLC
Certification No.
Date sample analyzed:
PARAMETERS NOTE: Values should reflect dissolved and colloidal
concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615
mg/L
Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616
/100mL
Nitrate (NO3) as N 00620
mg/L
Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L
Other (Specify Compounds and Concentration Units):
Dissolved Solids:Total 70300
mg/L
Al -Aluminum 01105
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC 00680
mg/L
Ca - Calcium 00916
mg/L
Chloride 00940
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L
ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? ❑ Yes (1) ❑ No (0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L
VOC 78732 method #
Total Ammonia 00610
mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen; NH3asN: Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
, method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports):
Influent Total VOCs: mg/L
Effluent Total VOCs: mg/L VOC Removal%
Permittee (or Authorized Agent) Name and Title - Please print or type
GW-59 Rev.8/2013

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
Please Print Clearly or
Facility Name: Metropolitan Sewerage District
Permit Name (if different):
Facility Address: 2225 Riverside Drive, Asheville, NC 28804
County Buncombe
Contact Person: Bart Farmer
Well Location/Site Name: Downgradient of Ash Lagoon
SAMPLING INFORMATION
WELL ID NUMBER (from Permit): MW-07
Well Depth: 14 ft.
Depth to Water Level 82546: 17.74 ft. below measuring point
Measuring Point is 0.0 ft. above land surface
Telephone#: [phone]
No. of wells to be sampled: 4
Date sample collected: 01/04/24
Well Diameter: 2 in.
Screened Interval: 4 ft.
Relative M.P. Elevation:
Volume of water pumped/bailed before sampling: gallons
Samples for metals were collected unfiltered: m YES El NO and field acidified: ❑YES
Date sample analyzed: Laboratory Name:
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615
Coliform: MF Fecal 31616
/100mL
Nitrate (NO3) as N 00620
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
Dissolved Solids:Total 70300
mg/L
Al -Aluminum ol105
pH (Lab) 00403
units
Ba - Barium 01007
TOC 00680
mg/L
Ca - Calcium 00916
Chloride 00940
mg/L
Cd - Cadmium 01027
Arsenic 01002
ug/L
Chromium: Total 01034
Grease and Oils 00552
mg/L
Cu - Copper 01042
Phenol 32730
ug/L
Fe - Iron 01045
Sulfate 00945
mg/L
Hg - Mercury 71900
Specific Conductance 00095
µMhos
K - Potassium 00937
Total Ammonia 00610
mg/L
Mg - Magnesium 00927
(Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
TKN as N 00625
mg/L
Ni - Nickel 01067
For Remediation Systems Only (Attach Lab Reports)
Influent Total VOCs:
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
PERMIT Number: Expiration Date: 12/31/22
Non -Discharge UIC
NPDES NCO024911 Other
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
❑ Spray Field ❑ Remediation:
❑ Rotary Distributor ❑ Land Application of Sludge
❑ Water Source Heat Pump 0 Other:
to 14 ft.
ft.
Pace Analytical Services, LLC
mq/L
FIELD ANALYSES: WAS DRY
at time of
pH 00400: units Temp. 00010: °C sampling,
Spec. Cond. 00094: µMhos check
Odor 00085: None detected here:
Appearance Clear
Certification No.
mg/L Pb - Lead o1o51 ug/L
mg/L Zn - Zinc 01092 mg/L
mg/L
mg/L Other (Specify Compounds and Concentration Units):
mg/L
ug/L
mg/L
ug/L
ug/L
mg/L ORGANICS: (by GC, GC/MS, HPLC)
ug/L (Specify test and method #. ATTACH LAB REPORT.)
ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0)
mg/L VOC 78732 method #
mg/L method #
ug/L method #
ug/L method #
Effluent Total VOCs: mg/L VOC Removal%
GW-59 Rev.8/2013

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
Print Clearly or
Facility Name: Metropolitan Sewerage District
Permit Name (if different):
Facility Address: 2225 Riverside Drive, Asheville, NC 28804
County Buncombe
act Person: Bart Farmer Telephone#: [phone]
Location/Site Name: Downgradient of Ash Lagoon No. of wells to be sampled: 4
WELL ID NUMBER (from Permit): MW-OSR
Well Depth: 18 ft.
Depth to Water Level 82546: 16.2 ft. below measuring point
Measuring Point is 0.0 ft. above land surface
Volume of water pumped/bailed before sampling: 0 gallons
Samoles for metals were collected unfiltered: YES ❑ NO
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
PERMIT Number: Expiration Date: 12/31/22
Non -Discharge UIC
NPDES NCO024911 Other
TYPE OF PERMITTED OPERATION BEING MONITORED
0 Lagoon ❑ Remediation: Infiltration Gallery
❑ Spray Field ❑ Remediation:
❑ Rotary Distributor ❑ Land Application of Sludge
❑ Water Source Heat Pump ❑ Other:
Date sample collected: 01/4/24
Well Diameter: 2 in.
Screened Interval: 8 ft. to 18 ft.
Relative M.P. Elevation: ft.
field acidified
YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: Laboratory Name: Pace Analytical Services, LLC
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615
mg/L
Coliform: MF Fecal 31616
/100mL
Nitrate (NO3) as N 00620
mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L
Dissolved Solids:Total 70300
mg/L
Al -Aluminum 01105
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC co68o
mg/L
Ca - Calcium 00916
mg/L
Chloride 00940
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total o1034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L
Phenol 32730
ug/L
Fe - Iron 01045
ug/L
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L
Specific Conductance oo095
µMhos
K - Potassium 00937
mg/L
Total Ammonia 00610
mg/L
Mg - Magnesium 00927
mg/L
(Ammonia Nitrogen: NH, as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCS:
r3.�•� T, 1'.aK1J1e9
Permittee (or Authorized Agent) Name and Title - Please print or type
FIELD ANALYSES:
pH 00400: units
Spec. Cond. 00094:
Odor 000m:
Appearance
WAS DRY
at time of
Temp.00010: °C sampling,
µMhos check
Certification No.
Pb - Lead o1o51 ug/L
Zn - Zinc 01092 mg/L
Other (Specify Compounds and Concentration Units)
ORGANICS: (by GC, GC/MS, HPLC)
(Specify test and method #. ATTACH LAB REPORT.)
Lab Report Attached? ❑ Yes (1) ❑ No (0)
VOC 78732 method #
method #
method #
method #
mg/L Effluent Total VOCs:
mg/L VOC Removal%
�2G
here:
21
GW-59 Rev.8/2013

ace � �,
January 19, 2024
Bart Farmer
MSD of Buncombe County
RE: Project: Monitoring Wells Jan 2024
Pace Project No.: 92706796
Dear Bart Farmer:
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on January 04, 2024. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Katharine E Burnham
[e-mail]
828-417-6061
Project Manager
Enclosures
cc: Ms. Shannon Bergeron, Metropolitan Sewerage District
Mr. John Gosnell, Metropolitan Sewerage District
Ms. Sheila Kilby, MSD of Buncombe County
Mr. Chad Ledford, Metropolitan Sewerage District
Ms. Angel McCrain, MSD of Buncombe County
Patrick Smith, MSD of Buncombe County, NC
Mr. Alan Taylor, Metropolitan Sewerage District
Mr. Schuyler Taylor, Metropolitan Sewerage District
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 26

(A"?acia,
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
CERTIFICATIONS
Project: Monitoring Wells Jan 2024
Pace Project No.: 92706796
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
South Carolina Drinking Water Cert. #: 99006003
North Carolina Drinking Water Certification #: 37706
Florida/NELAP Certification #: E87627
North Carolina Field Services Certification #: 5342
Kentucky UST Certification #: 84
North Carolina Wastewater Certification #: 12
Louisiana DoH Drinking Water #: LA029
South Carolina Laboratory ID: 99006
VirginiaNELAP Certification #: 460221
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804 South Carolina Laboratory ID: 99030
Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001
North Carolina Drinking Water Certification #: 37712 VirginiaNELAP Certification #: 460222
North Carolina Wastewater Certification #: 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 26

(A-'gaca
SAMPLE ANALYTE COUNT
Project: Monitoring Wells Jan 2024
Pace Project No.: 92706796
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Lab ID Sample ID Method
Analysts
Analytes
Reported
Laboratory
92706796001 MW-5 EPA 200.7 Rev 4.4 1994
DBB1
10
PASI-A
EPA 245.1 Rev 3.0 1994
BM
1
PASI-A
SM 2540C-2015
RVS
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
EPA 350.1 Rev 2.0 1993
NCF
1
PASI-A
EPA 353.2 Rev 2.0 1993
NCF
1
PASI-A
SM 4500-CI-E-2011
Zip
1
PASI-A
SM 5310B-2014
MDW
1
PASI-A
PASI-A = Pace Analytical Services -Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 26

(-- ace�'
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Monitoring Wells Jan 2024
Pace Project No.: 92706796
Sample: MW-5
Lab ID: 92706796001 Collected: 01/04/24 09:50
Received: 01/04/24 12:05 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared
Analyzed
CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
01/05/24 15:14
Collected By
Mark
1
01/05/24 15:14
Swann
Collected Date
1/4/24
1
01/05/24 15:14
Collected Time
09:50
1
01/05/24 15:14
pH
5.53 Std. Units
1
01/05/24 15:14
Temperature
6.7 deg C
1
01/05/24 15:14
Static Water Level
20.76 ft feet
1
01/05/24 15:14
Specific Conductance
35.0 umhos/cm
1
01/05/24 15:14
Odor
None
1
01/05/24 15:14
Appearance
Clear
1
01/05/24 15:14
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
Arsenic
ND ug/L 10.0
1
01/05/24 16:05
01/07/24 20:07
7440-38-2
Barium
14.3 ug/L 5.0
1
01/05/24 16:05
01/07/24 20:07
7440-39-3
Cadmium
ND ug/L 1.0
1
01/05/24 16:05
01/07/24 20:07
7440-43-9
Chromium
ND ug/L 5.0
1
01/05/24 16:05
01/07/24 20:07
7440-47-3
Iron
210 ug/L 50.0
1
01/05/24 16:05
01/07/24 20:07
7439-89-6
Lead
ND ug/L 5.0
1
01/05/24 16:05
01/07/24 20:07
7439-92-1
Manganese
50.3 ug/L 5.0
1
01/05/24 16:05
01/07/24 20:07
7439-96-5
Selenium
ND ug/L 10.0
1
01/05/24 16:05
01/07/24 20:07
7782-49-2
Silver
ND ug/L 5.0
1
01/05/24 16:05
01/07/24 20:07
7440-22-4
Sodium
ND ug/L 5000
1
01/05/24 16:05
01/07/24 20:07
7440-23-5
245.1 Mercury
Analytical Method: EPA 245.1 Rev 3.0 1994 Preparation Method: EPA 245.1 Rev 3.0 1994
Pace Analytical Services - Asheville
Mercury
ND ug/L 0.20
1
01/06/2410:33
01/06/2413:04
7439-97-6
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
35.0 mg/L 25.0
1
01/04/24 20:20
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
Sulfate
3.5 mg/L 1.0
1
01/06/24 03:06
14808-79-8
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L 0.10
1
01/16/24 04:11
7664-41-7
353.2 Nitrogen, NO2/1\103 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
ND mg/L 0.040
1
01/05/24 00:45
14797-55-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/19/2024 03:39 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 26

ANALYTICAL RESULTS
Project: Monitoring Wells Jan 2024
Pace Project No.: 92706796
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-5
Lab ID: 92706796001 Collected: 01/04/24 09:50
Received: 01/04/24 12:05 Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed CAS No. Qual
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
1.3 mg/L 1.0 1
01111/2416:08 16887-00-6
5310B TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services - Asheville
Total Organic Carbon
ND mg/L 1.0 1
01/10/24 00:25 7440-44-0
Date: 01/19/2024 03:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 26

(-�Face-
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Monitoring Wells Jan 2024
Pace Project No.: 92706796
Sample: MW-6R
Lab ID: 92706796002 Collected: 01/04/24 11:05
Received: 01/04/24 12:05 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed CAS No. Qua]
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
01/05/24 15:19
Collected By
Mark
1
01/05/24 15:19
Swann
Collected Date
1/4/24
1
01/05/24 15:19
Collected Time
11:05
1
01/05/24 15:19
Static Water Level
17.74 ft feet
1
01/05/24 15:19
Date: 01/19/2024 03:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 26

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Monitoring Wells Jan 2024
Pace Project No.: 92706796
Sample: MW-7 Lab ID: 92706796003 Collected: 01/04/24 11:00 Received: 01/04/24 12:05 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
Collected By
Mark
Swann
Collected Date
1/4/24
Collected Time
11:00
Static Water Level
17.74 ft feet
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/19/2024 03:39 PM without the written consent of Pace Analytical Services, LLC.
01 /05/24 15:23
01 /05/24 15:23
01 /05/24 15:23
01 /05/24 15:23
01 /05/24 15:23
Page 7 of 26

(�Vace�'
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Monitoring Wells Jan 2024
Pace Project No.: 92706796
Sample: MW-08R Lab ID: 92706796004 Collected: 01/04/24 11:40 Received: 01/04/24 12:05 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace 1
01/05/24 15:28
Collected By
Mark 1
01/05/24 15:28
Swann
Collected Date
1/4/24 1
01/05/24 15:28
Collected Time
11:40 1
01/05/24 15:28
Static Water Level
16.20 ft feet 1
01/05/24 15:28
Date: 01/19/2024 03:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 8 of 26

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Monitoring Wells Jan 2024
Pace Project No.: 92706796
QC Batch: 823778
Analysis Method: EPA 245.1 Rev 3.0 1994
QC Batch Method: EPA 245.1 Rev 3.0 1994
Analysis Description: 245.1 Mercury
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92706796001
METHOD BLANK: 4261412
Matrix: Water
Associated Lab Samples: 92706796001
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Mercury ug/L
ND 0.20 01/06/2412:59
LABORATORY CONTROL SAMPLE: 4261413
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Mercury ug/L
2.5 2.5 101 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4261414 4261415
MS MSD
92706796001
Spike Spike MS MSD MS MSD % Rec
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD Qua[
Mercury ug/L ND
2.5 2.5 2.5 2.6 102 104 70-130 2
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/19/2024 03:39 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 26

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Monitoring Wells Jan 2024
Pace Project No.: 92706796
QC Batch: 823754
Analysis Method:
EPA 200.7 Rev 4.4 1994
QC Batch Method: EPA 200.7 Rev
4.4 1994
Analysis Description: 200.7 MET
Laboratory:
Pace Analytical Services - Asheville
Associated Lab Samples: 92706796001
METHOD BLANK: 4261305
Matrix: Water
Associated Lab Samples: 92706796001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Qualifiers
Arsenic
ug/L
ND
10.0
01/0712418:37
Barium
ug/L
ND
5.0
01/07/2418:37
Cadmium
ug/L
ND
1.0
01/07/2418:37
Chromium
ug/L
ND
5.0
01/07/2418:37
Iron
ug/L
ND
50.0
01/07/2418:37
Lead
ug/L
ND
5.0
01/07/2418:37
Manganese
ug/L
ND
5.0
01/07/2418:37
Selenium
ug/L
ND
10.0
01/07/2418:37
Silver
ug/L
ND
5.0
01/08/2412:12
Sodium
ug/L
ND
5000
01/07/2418:37
LABORATORY CONTROL SAMPLE:
4261306
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Arsenic
ug/L
500
481
96
85-115
Barium
ug/L
500
504
101
85-115
Cadmium
ug/L
500
475
95
85-115
Chromium
ug/L
500
475
95
85-115
Iron
ug/L
5000
5050
101
85-115
Lead
ug/L
500
468
94
85-115
Manganese
ug/L
500
500
100
85-115
Selenium
ug/L
500
472
94
85-115
Silver
ug/L
250
277
111
85-115
Sodium
ug/L
5000
5130
103
85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
4261307
4261308
MS
MSD
92706850002
Spike
Spike
MS
MSD MS MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result % Rec
% Rec
Limits
RPD Qual
Arsenic
ug/L
ND
500
500
537
538
107 107
70-130
0
Barium
ug/L
97.9
500
500
645
658
109 112
70-130
2
Cadmium
ug/L
ND
500
500
505
506
101 101
70-130
0
Chromium
ug/L
ND
500
500
523
525
104 105
70-130
0
Iron
ug/L
667
5000
5000
6270
6390
112 114
70-130
2
Lead
ug/L
ND
500
500
504
504
101 101
70-130
0
Manganese
ug/L
93.7
500
500
637
648
109 111
70-130
2
Selenium
ug/L
ND
500
500
536
540
107 108
70-130
1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/19/2024 03:39 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 26

QUALITY CONTROL DATA
Project: Monitoring Wells Jan 2024
Pace Project No.: 92706796
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4261307
MS
92706850002 Spike
Parameter Units Result Conc.
Silver ug/L ND 250
Sodium ug/L 72000 5000
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
4261309
MS
92706613001
Spike
Parameter
Units
Result
Conc.
Arsenic
ug/L
ND
500
Barium
ug/L
ND
500
Cadmium
ug/L
ND
500
Chromium
ug/L
50.4
500
Iron
ug/L
2550
5000
Lead
ug/L
ND
500
Manganese
ug/L
537
500
Selenium
ug/L
ND
500
Silver
ug/L
ND
250
Sodium
ug/L
73900
5000
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
4261308
MSD
Spike
MS
MSD
MS MSD % Rec
Conc.
Result
Result
% Rec % Rec Limits RPD Qua]
250
282
279
113 111 70-130 1
5000
79100
80200
143 164 70-130 1 M1
4261310
MSD
Spike
MS
MSD
MS
MSD
% Rec
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
500
530
519
106
104
70-130
2
500
551
550
110
110
70-130
0
500
510
499
102
100
70-130
2
500
579
564
106
103
70-130
3
5000
8470
8270
118
114
70-130
2
500
509
498
102
100
70-130
2
500
1110
1110
115
114
70-130
1
500
531
524
106
105
70-130
1
250
280
273
112
109
70-130
3
5000
82100
80700
164
135
70-130
2 M1
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/19/2024 03:39 PM without the written consent of Pace Analytical Services, LLC.
Page 11 of 26

(�Vace�,
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Monitoring Wells Jan 2024
Pace Project No.: 92706796
QC Batch: 823582 Analysis Method: SM 2540C-2015
QC Batch Method: SM 254OC-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92706796001
METHOD BLANK: 4260599
Associated Lab Samples: 92706796001
Parameter Units
Total Dissolved Solids mg/L
LABORATORY CONTROL SAMPLE: 4260600
Parameter Units
Total Dissolved Solids mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 25.0 01/04/24 20:17
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
250 264 106 90-110
SAMPLE DUPLICATE: 4260601
92706701001 Dup
Parameter Units Result Result
Total Dissolved Solids mg/L 269 273
RPD Qualifiers
1
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/19/2024 03:39 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 26

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Monitoring Wells Jan 2024
Pace Project No.: 92706796
QC Batch: 823647
Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993
Analysis Description: 300.0
IC Anions
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92706796001
METHOD BLANK: 4260757
Matrix: Water
Associated Lab Samples: 92706796001
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Sulfate mg/L
ND 1.0
01/05/24 23:45
LABORATORY CONTROL SAMPLE: 4260758
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Sulfate mg/L
50 50.8
102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4260759 4260760
MS MSD
92706860007
Spike Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec
Limits RPD Qual
Sulfate mg/L 7.0
50 50 57.7
57.4 101 101
90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4260761 4260762
MS MSD
92706820007
Spike Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec
Limits RPD Qual
Sulfate mg/L 302
50 50 347
345 91 87
90-110 1 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /19/2024 03:39 PM without the written consent of Pace Analytical Services, LLC.
Page 13 of 26

Project: Monitoring Wells Jan 2024
Pace Project No.: 92706796
QC Batch: 825632
QC Batch Method: EPA 350.1 Rev 2.0 1993
Associated Lab Samples: 92706796001
METHOD BLANK: 4270062
Associated Lab Samples: 92706796001
Parameter Units
Nitrogen, Ammonia mg/L
QUALITY CONTROL DATA
Analysis Method:
Analysis Description:
Laboratory:
Matrix: Water
EPA 350.1 Rev 2.0 1993
350.1 Ammonia
Pace Analytical Services - Asheville
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.10 01/16/24 03:54
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE: 4270063
Spike LCS LCS %Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Ammonia mg/L 5 5.0 99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4270064 4270065
MS MSD
92706737001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 5.3 5 5 10.2 10.2 97 97 90 110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4270066 4270067
MS MSD
92706770001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L ND 5 5 5.1 5.0 100 100 90-110 0
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/19/2024 03:39 PM without the written consent of Pace Analytical Services, LLC.
Page 14 of 26

(A`gaca,
QUALITY CONTROL DATA
Project: Monitoring Wells Jan 2024
Pace Project No.: 92706796
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QC Batch: 823596
Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92706796001
METHOD BLANK: 4260633
Matrix: Water
Associated Lab Samples: 92706796001
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L
ND 0.040 01/05/24 00:28
LABORATORY CONTROL SAMPLE: 4260634
Spike LCS LCS %Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L
1.5 1.5 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4260635 4260636
MS MSD
92706647001
Spike Spike MS MSD MS MSD
% Rec
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec
Limits RPD Qual
Nitrogen, Nitrate mg/L 0.23
1.5 1.5 1.8 1.9 107 108
90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4260637 4260638
MS MSD
92706567001
Spike Spike MS MSD MS MSD
% Rec
Parameter Units Result
Conc. Conc, Result Result % Rec % Rec
Limits RPD Qual
Nitrogen, Nitrate mg/L 27.6
1.5 1.5 28.9 29.4 91 125
90-110 2
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/19/2024 03:39 PM without the written consent of Pace Analytical Services, LLC.
Page 15 of 26

ace
QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Monitoring Wells Jan 2024
Pace Project No.: 92706796
QC Batch: 824649
Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011
Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92706796001
METHOD BLANK: 4265675
Matrix: Water
Associated Lab Samples: 92706796001
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Chloride mg/L
ND 1.0 01/11/2415:35
LABORATORY CONTROL SAMPLE: 4265676
Spike LCS LCS %Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Chloride mg/L
20 21.1 105 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4265677 4265678
MS MSD
92706669001
Spike Spike MS MSD MS MSD
% Rec
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec
Limits RPD Qua[
Chloride mg/L 2240
10 10 2220 2200 -177 -375
90-110 1 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4265679 4265680
MS MSD
92706179001
Spike Spike MS MSD MS MSD
% Rec
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec
Limits RPD Qual
Chloride mg/L 104000
10 10 111 110 72 61
90-110 1 M1
ug/L
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /19/2024 03:39 PM without the written consent of Pace Analytical Services, LLC.
Page 16 of 26

(�Vace�,
QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Monitoring Wells Jan 2024
Pace Project No.: 92706796
QC Batch: 824046
Analysis Method: SM 531OB-2014
QC Batch Method: SM 531 OB-2014
Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92706796001
METHOD BLANK: 4262598
Matrix: Water
Associated Lab Samples: 92706796001
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Total Organic Carbon mg/L
ND 1.0 01/09/24 16:47
LABORATORY CONTROL SAMPLE: 4262599
Spike LCS LCS %Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Total Organic Carbon mg/L
25 23.6 95 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4262600 4262601
MS MSD
92706860001
Spike Spike MS MSD MS MSD
% Rec
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec
Limits RPD Qual
Total Organic Carbon mg/L ND
25 25 24.0 24.2 96 97
90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4262602 4262603
MS MSD
92706860002
Spike Spike MS MSD MS MSD
% Rec
Parameter Units Result
Conc. Conc, Result Result % Rec % Rec
Limits RPD Qua[
Total Organic Carbon mg/L 4.9
25 25 28.9 28.6 96 95
90-110 1
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /19/2024 03:39 PM without the written consent of Pace Analytical Services, LLC.
Page 17 of 26

a
QUALIFIERS
Project: Monitoring Wells Jan 2024
Pace Project No.: 92706796
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /19/2024 03:39 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 26

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Monitoring Wells Jan 2024
Pace Project No.: 92706796
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92706796001
MW-5
92706796002
MW-6R
92706796003
MW-7
92706796004
MW-08R
92706796001
MW-5
EPA 200.7 Rev 4.4 1994
823754
92706796001
MW-5
EPA245.1 Rev 3.01994
823778
92706796001
MW-5
SM 2540C-2015
823582
92706796001
MW-5
EPA 300.0 Rev 2.1 1993
823647
92706796001
MW-5
EPA 350.1 Rev 2.0 1993
825632
92706796001
MW-5
EPA 353.2 Rev 2.0 1993
823596
92706796001
MW-5
SM 4500-CI-E-2011
824649
92706796001
MW-5
SM 531OB-2014
824046
Date: 01/19/2024 03:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
EPA 200.7 Rev 4.4 1994 823859
EPA 245.1 Rev 3.0 1994 823889
Page 19 of 26

DC#_Title: ENV-FRM-HUN1-0083 v02_Sample Condition Upon Receipt
I -lace
Effective Date: 11/14/2022 8:18:30 AM
Laboratory receiving samples:
Asheville Eden[] Greenwood ❑ HLtntersville ❑ Raleigh[] Mechanicsville[] Atlanta[]Kernersville❑
Sample condition Client Name: WOE : 92706796
Project il:
i �t i Courier, 0 Fed Ex El UP5 USPS Client
(.] Commercial �Pace U other: 92706796
Custody Seal Present? ❑Yes No Seals Intact? ❑Yes ONO
Date/Initials Person Examining contents;___�_`�_ _! _
Packing Material: ❑ BUbble Wrap ©,nubble Bags ❑ None ❑ Other Biological Tissue Frozen?
❑ Yes ❑ No ❑ N/A
Thermometer:
❑ I R Gun ID: Type of Ice: Q wet ❑Blur. ❑None
Correction Factor:
Cooler Temp: Acid/Subtract ('C) Temp should be above freezing to 6°C
❑ Samples out of temp criteria. Samples on ice, cooling process
4 7
Cooler Temp Corrected (°C): has begun
USDA Regulated Soil (❑ N/A, water sample)
Dirt samples originate in a quarantine zone within the United States: CA, NY, or SC Did samples originaUs from a foreign
�sofurce (internationally,
and Pnrrtn Him)? 1 IYes ❑No
'CheCk ril ips)f I_jYeS Lr No
Comments/Discrepancy:
Chain of Custody Present?
Yes
El No
]N/A
],
Samples Arrived within Hold Time?
l vs
El No
❑N/A
J.
Short Hold Time Analysis (02 hr.)?
yes
El No
❑N/A
3.
Rush Turn Around Time Requested?
❑Yes
No
L7N/A
A.
Sufficient volume?
Yes
El No
❑N/A
51
Correct Containers Used?
-pace Containers Used?
PYes
P Yes
❑No
❑No
❑N/A
❑N/A
G.
Containers Intact?
P Yes
❑No
❑N/A
7.
Dissolved analysis: Samples Field Filtered?
[I Yes
/bNo
❑N/A
8.
Sample Labels MatchCOC?
-Itic IUdesDate/Time/ID/Analysis Matrix:_
Yes
_ _(____ ___
❑No
❑N/A
9.
HeadspaceinVOA Vials (>S•6mm)?
Trip Blank Present?
Trip Blank Custody Seals Present?
❑Yes
❑Yes
❑Ycs
L)No
I�INc
trtiv'o
❑N/A
[I N/A
❑N/A
10.
11.
r
COMMENTS/SAMPLE DISCREPANCY
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
Project Manager SRF Review:
Date/Time:
Date:
Date:
Pond 'I rnf 7
Page 20 of 26

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Page 21 of 26
Preservation
non confmroance
San
ple.
identified
for

,1�pca' ce
DC# Title: ENV-FRM-HUN1.0083 02_Sample Condition Upon Receipt
Effective Date: 11/14/2022 8:18:30 AM
*Check mark top half of box if pH and/or dechlorination Is verified and Project #
within the acceptance range for preservation samples,
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
**Bottom half of box is to list number of bottles
***Check all unpreserved Nitrates for chlorine
Wp#92706796
PM: KEB Due Date: 01/18/24
CLIENT: 93-MSO
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pH Adjustment
Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot It
Note: Whenever there is a uiscrepancy arlecUng N01I11 Larmna cornpnarce sample, a curry UI
Out of hold, incorrect preservative, out of temp, incorrect containers. Page 22 of 26
nilaltrov Irl' fgr:'Id Pan. 9 of 7

Date Issued: March 81 2019.'
Document Hanle: Field data Sheet Page: 1 of
aCeNlals frc it Issubig Authority: Pace fittntersvi+le Quality
Document Numbei: F-CAR fLD 001-rev.03 Office
i
Client: !11
Me1u Ma[a artt-ci
M �'� �✓' I
—Location,
Name and Affiliation (Sampler(s):
--Project
M N A-j r 1 Field Data Sheet Review,
Name and Affiliation (Inspector):,
fir Date: 'A L' By:
Well Information
I �
Well ID: _/l7 w S�
Well Locked: Y / NO / Plushmount )
Well Diameter:
Construction: ( /Steel/Sta(nless Steel)
Total Well Depth: �Lq
ft Multi Factor*; f /'3 ('(Radius/12)20.14 x 7.481
Static Water Level: 2-G,'7 t
ft Casing Volume: O.$).3/), gallons
Height of Water Column: 3 ,J y .
ft Cal. 3 Volumes: �•"' ?,tU gallons
Pump Intake: ?_ { ft
Purge Information
l7 �.. 1-`l Start: ��. �,U Finish: `%�{"'— Purge Rate:_
Date Purged:_/—i / —_� —
c 2„ /„ /f. t Total Volume Purged: /� '�� ' (gallons/Inl/L)
Purging Methods � l.r'
Samylins Information
Date Collected: 1 /L `" / `� Time Collected: �� �n�%' in)
SamplinR Equipment Used: 8 x, t14 Instrument ID: y . e ' /
Bottle Type
Pi�'?t r,t-
Preservation
Lis oy-
Analysis Requited
A/
�`u V
Field Measurements/Observations
'
1
%"r
Sample Temp Cq:. G 7 Time:
s
Turbidity (ntu): � Tune:
Diss Ox m L ' 'line•
�� `'
Pe 2-+- mg/L• 1V"
Specific Cond. (us): 3 ' • Time:
Res. Cl (mg/L)/(ttg/L)' �Q rinse,
Saiiiple pff (sm.): c;' r S Time:
`mod
Odor: nl �,✓c, ' Tinte:..._
U� 1f o
12e�Dox (mV): � --
S 1, ' Time:
�s-'
Appearance- l u ,. - Tune:
Pp
+~
Rel7ox (CI -I value):YS1. ProPlus.4.200ntV
1.
Ok}ter: - iir'1� Time:
General/Weather Observations•
(sunny/cloudy/rainy) Temp. = (-6 Wind `a. sJ (inph)
Sampler Signature: �%r ►'�= r--'
_Date:
`Jtil[)ttlZanon
les[
o time
Time
Temp.
a
Diss Oxy.
Spec.
Cond.
pH (s.u.)
ReDox
mV
{ )
Turbidity
YOther
ntuons
{ )
nlovecJ
tls
:(ga:lelL /�
Water
{ )
level ftPurged
(C)
(ntg/L)
{uS)
s.yr.
t1� `7svo
Ttr-
9',Y'3
35,E
`i,a
IS 1. ?
3>
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Page 23 of 26

r?CB/hL7!} 1iL71
Document Name: Field date Sheet
Date Issued: March'8 2019'
rAge, 1 of 1
Document Number: F-CAR-FLD-001-rev.03
lssulug Authority: Pace Hturiersville Quality
Office
Clien
aj
Nameand Affiliation (Sampler(s): .4
Name and Affiliation (Inspector): 9�
Well Information
Well ID: ,— i>7 b-l"-
Well Diameter,
Total Well Depth: /,?• J./fE
Static Water Level: / 7-) 7 ,t ft
Height of Water Column:%, r- _ft
Field Data Sheet Review:
Date: 1 IA JAA By:
Well Locked: ( YES / NO /(Fluslmiount)%'
Construction: PV .Steel/Stainless Steel)
Multi Factor*: • /-13 (1(Radius/12)2 x 3A4 x 7.481
Casing Volume: 19, 0 7 6 0 gallons
Cal. 3 Volumes: _ 0 -19�j gallons
PUMP Intake: le, ft
Pure Information _
Date Purged' ( / 4 �� /�_ Start : / v Finish: l/v� Purge Rake: te
Purging Method: P'= 't +1 / /• _ Total Volume Purged: 3 Pd (gallons/ it /Is)
SaingIing Information
Date Collected: 1 / d�/ .� _ Time Collected:
Sampling Equipment Used:_ 1� ��' /L Instrument ID:`f14'�
Bottle Type Preservation Analysis Required
Field Measurements/Observations /
Sanaple Temp (aC): - Time:__. -_Turbidity (ntu): N �i� Time: All)
Diss Oxy (mg/la): Time: -_ Fe 2+ mg/L: /i1/x Time:
Specific Cond. (uS): Time: Res. Cl (nig/L)/(itg/L):1 ilne:
Sample pH (s.u.): Time: —Odor: i% =i Time:
ReDox (mV). Time: I Appearance: Time:
ReDox (EH value):YSI ProPlus -+-200rilV_ Other: wc Time: //
General/Weather Observations S ✓•� 'y �' ��l
nny'/cloudy/rainy) Tempff) W1nd3%+1v (mph)
Sampler Signature: `j� �- ( -Date:" --
e a_t..l:.,...►ir... Toe►
flap Vaal.auuva�
Time
Purged
a
Temp.
(°C)
Diss C)xy.
(mg/
Spec,
tu5) •
PH (Sal.)
ReDox
(mV)
Turbidity
(ntu)
Volume
removed
(gallotIs/mis/
Water
level (ft)
Other
Page 24 of 26

Document Name: Field data Sheet
Dale issued: IVI Page: 1 of of ( 2019"
,. BCeAnalytical
Issulag Authority: face I•Ihmlersville Quality
Document Number: F-CAR.1113-001-rev.03
Office
Field Data Sheet
/.t /C. 11://e Proiect 41: !✓ 1
Name and Affiliation (Sampler(s): ZLI f Field Data Sheet Review:
Name and Affiliation (Inspector): ���
Date:
Well Information
Well ID 62 IZ Well Locked: ( YES / NO ius unount )
Well Diameter: Construction: �/Steet/Staulless Steel)
Total Well Depth: 72 i` ft Multi Factor•'k: i 1 is ('(Radius/12)2x3A4 x 7A81
Static Water Level: / 7, 7L ft Casing Volume. , D3 �'z 3 gallons
Height of Water Column: �, � / ft Cal, 3 Volumes: (9,02.6; gallons
Pump Intake: �II Y__ft
Purge information
Date Purged: I 10 Y / Start : / ! Finish: _//, i� Purge Rater
Purging Method: b,42 Total Volume Purged: A/ 4 (gallons/11115/1,)
Sampling Information
Date Collected- —/ / Tinie Collected:
Sampling Equipment U e Instrument ID: ( T
Bottle Type Preservation Analysis Required
Field Measurements/Observations
Sample Temp (°C):. A111 Time: __`_Turbidity (ntu): Tune:J�' �r
Diss Oxy (mg/L): Tune: Fe 2+ mg/L: Tune:
Specific Cond, (uS): Time: Ines. Cl (mg/L)/(irg/L): Time:
Sample pl-l. (s.u.): Tiine: Odor:_. Time: _
ReDox (inV): Time: Appearance: 'time:
ReDox (EH value).YS1 ProPlus +2t)On1 V Other: c✓� i 1) �� �—
General/Weather Observations: S v,✓" ti Cr
_ (sunny/cloudy/rainy) Tentp 3-1 ff) Wind,61 / 0 (nigh)
Sampler Signature:1f���__— _Date:_
Ct.hili6atinn Tout
Time
Purged
Temp.
(°C)
Disc oxy,
(Ing/L)
Spec
Cond.
(u5)
pH (s,u.)
ReDox
(mV)
Turbidity
(ntu)
Volume
removed
(gallons/nils/
L,
Water
level (ft)
Other
r
Page 25 of 26

;. ,7CoAl1a1yMc,l/
i
Document Name: Field data Sheet
Date Issued, March 8, 2019.
Page: 1 of i
bocument. Plumber: F-CAR-FI.D•001-rev.03
issuing Authority: race!-Ituitersville Quality
office
Client: M S �,) Location: (/,t
Name and Affiliation (Sampler(s):
Name and Affiliation (Inspector): _
Well Information
Well ID:. A i✓
Well Diameter: ;�
Total Well Depth: 1 `7, y ft
/r
Static Water Level: t' . J ft
I-feight of Water Column: 0 - g Lt ft
!ld Data Sheet Review:
�I�ID�N Y-
ate: By:
Well Locked: ( YES / NO -Fltlsimio it )
Construction: & Steel/Stainless Steel)
Multi Factor*: ' ,/ 61$ ['(Radius/12)2x 3.14 x 7.481
Casing Volume: D' /S ,; X.IN gallons
Cal.3 Volumes: ���J "lGG gallons
Dump Intake: ' ft
Purge Information j
Date Purged;—L/ v `f"' %_� Start :1J!=)_ Finish:_ I lq- J Purge Rate:
Purging Method.— 4 t �_t �* � t Total Voluule Purged: ' J (gallons/nits/L)
Sampling_ Information ��"
Date Collected: / / �/ Time Collected:—_�_— (m//ppin)
Sampling Equipment Used: I✓ t M l/e Instrument ID: �/ G '
Bottle Type
Preservation
Analysis Required
Field Measurements/Obse>.vatiotts
Sample Temp CC): , Time: _ _Turbidity (ntu): Tn1e: Al
Diss Oxy (mg/L): Time: Fe 2+ mg/L:_ Time:
Specific Cond. (uS): Time: Res. CL (nag/L)/(µg/L): Time:
Sample pH (s.u.): _ . Tune: Odor:, Time: --
ReDox (mV): Time: Appearance; 'Tune:_
ReDox (EH value):YSI ProPlus -1-200mV Other; %�� Time:
General/Weather Observations` <r/,✓ i �° &
SamplerSignature; "7 2�. 2 C ` _Da
camel. i'I:....►i n.. Tnn4
cloudy/rainy) Temp-3 > (*F) Wind-S-rJ (mpb)
/
a'7iq truunua�a
Time
Purged
acoa
Temp.
(C)
Diss Otiy.
(tng/i..)
Spec.
Cond.
(us)
pH (s.u.)
ReDox
(Inv)
Turbidity
(ntu)
Volume,
removed
(gnllol�s/mJs/
Water
level (ft)
Other
44
Page 26 of 26