NC0024911_Groundwater Monitoring Report January 2023_20230206

PN SEW ?40
o�
Metropolitan ewers e District
= OF BUNCOMBE COUNTY, NORTH CAROLINA
F 'NUNTYFFP
February 6, 2023
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Information Processing Unit;
Please find attached Groundwater Quality monitoring reports for January 2023 from Metropolitan
Sewerage District of Buncombe County (MSD). These monitoring report forms have additional
identification on the well ID line; MW-05, MW-06R, MW-07 and MW-08R, for ease and reference.
Monitoring Well-05 exceeded allowable limits for pH. Monitoring Well-0611 exceeded allowable limits
for pH, manganese, and iron. Monitoring Well-07 exceeded allowable limits for pH. Monitoring Well-0811
exceeded allowable limits for manganese and iron.
Please do hesitate to contact me at 828-225-8224 with questions regarding the attached reports.
Sincerely,
Bart Farmer
Director of Operations & Pretreatment
MSD of Buncombe County
Protecting Our Natural Resources-
2028 RIVERSIDE DRIVE, ASHEVILLE, NORTH CAROLINA28804 TELEPHONE: [phone] FAX: [phone] WEBSITE: www.msdbc.org

2
GW-59A COMPLIANCE REPORT FORM Permit # NCO024911
(Submit one each monitoring period with GIV--59 forms.)
Enter date monitoring results were due. (_02/28/2023_) Will this monitoring report (GW-59 and GW-59A)T7�/�
be submitted after the established due date?
Was any required information missing on the GW-59 report forms?
IF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
YES
3 1 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing I YES I NO
lfthe answer is ")'es", contact the Regional Office for guidance.
identification plate, area overgrown, etc.)?
4
5
6
8
Are any monitored constituents equal. to or above the established standards
If the answer to question 4 is "NO", skip to section 8.
If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s)
exceeding standards in the space provided below:
MW-05 MW-06R MW-07 MW-08R
pH 5.59 pH 5.55 pH 6.41
Mn 9,970 ug/L Mn 14,900 ug/L
Fe 5,660 ug/L Fe 53,000 ug/L
For the constituents identified in question 4 above, have standards been exceeded previously for the
same constituent(s) in the same well(s) in the last two years?
If the answer to question 5 is "NO", skip to section 8.
If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s)
exceeding standards,
concentration(s) reported, and sample collection date for each occurrence (for the last two years).
MW-05 pH Mn Fe MW-06R pH Mn Fe MW-07 pH Mn Fe MW-08R
6.0 334 ug/L 1/15121
pH Mn
20,100 ug/L
Fe
69,000 ug/L
1115121 5.6 1115/21 5.3 8,510 ug/L 1,250 ug/L 1/15/21
6/24121 5.4 9,980 ug/L 5,360 ug/1 6/24/21 5.9 176 ug/L 6/24/21
15,000 ug/L
50,700 ug/L
6/24121 5.4
10/1121 5.5 10/1/21 5.2 6,690 ug/L 1,080 ug/L 1011/21 5.8 740 ug/L 1011/21
1/24/22
11,000 uglL
9,780 ug/L
37,600 ug/L
32,300 ug/L
1/24122 5.7 1/24/22 5.17 12,300 ug/L 9,200 ug/L 1124122 6.1
6/27122 5.52 76.2 ug/L 382 ug/L 6127/22 5.67 14,100 ug/L 16,900 ug/L 6/27122 5.89 191 ug/L 6127122
17,000 ug/L
8,850 ug/L
49,900 ug/L
18,400 ug/L
10/13122 5.75 13.9 ug/L 66.5 ug/L 10/13/22 6.13 11,200 ug/L 34,800 ug/L 10/13122 6.02 444 ug/L 10113/22
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly
located; contact the Regional Office.
Is the permittee implementing previously approved actions required by the Division involving this
groundwater quality problem?
If the answer to question 7 is "YES", describe those actions in the space provided below.
If the answer to question 7 is "NO", contact the Regional Office within 90 days: an evaluation may be
reg►red to determine the impact the waste disposal system is having at the review and compl►ance
boundaries d hrrounding this facility, Failure to do so may sukiect the permittee to a Notice of Violation.
fines. and/or oenalties.
The person completing this portion (G W-59A) of the monitoring report should sign below and submit this
form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form.
I hereby acknowledge that the above information was evaluated and the information submitted in this
report (Compliange Report GW-59A) is true and complete to the best of my knowledge.
re of Permittee (or, uthorized Agent)
Y�W I NO
YES I NO
YES
YES I NW
GW-59A 12/8/2003

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM Please PrntCleadyor
FACILITY INFORMATION
Facility Name: Metropolitan Sewerage District
Permit Name (if different):
Facility Address: 2225 Riverside Drive, Asheville, NC 28804
act Person: Bart Farmer
Location/Site Name: Upgradient of Ash Lagoon
SUBMIT FORM ON YELLOW PAPER ONLY
County Buncombe
Telephone#: [phone]
No. of wells to be sampled: 4
)EPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
)IVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
PERMIT Number:
Expiration Date: i213t/22
Non -Discharge
UIC
NPDES NCO024911
Other
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon
❑ Remediation: Infiltration Gallery
❑ Spray Field
❑ Remediation:
❑ Rotary Distributor
❑ Land Application of Sludge
❑ Water Source Heat Pump
❑ Other:
SAMPLING INFORMATION 01/05/23 FIELD ANALYSES:
MW-05 Date sample collected: 00010: 9.7 °C
NELL ID NUMBER (from Permit): Well Diameter: 2 in. pH ooaoo: 5.59 units Temp.
24 ft. 35.4 µMhos
Nell Depth: Screened Interval: 0 ft. to 24 ft. Spec. Cond. 00094:
18.95 ft. below measuring point Odor 00085. None
Depth to Water Level azsas: Relative M.P. Elevation: ft.
Measuring Point is
0.0 ft. above land surface Appearance Clear
Volume of water pumped/bailed before sampling: ' 0'7� NO gallons and field acidified: 0 YES ❑ NO
Sam les for metals were collected unfiltered: (� YES ❑ Certification No. 4040, 53
42,12
LABORATORY INFORMATION Laboratory Name: Pace Analytical Services, LLC
Date sample analyzed: 01/06l23-011119123
NOTE : Values should reflect dissolved and colloidal concentrations.
PARAMETERS
mg/L
Nitrite (NO2) as N 00615
COD oo
/100mL
Nitrate (NO3) as N 00620 0.042
Coliform: MF Fecal 31616
/100mL
Phosphorus: Total as P oosss
Coliform: MF Total 31504
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
Dissolved Solids:Total 70300 35.0
mglL
Al -Aluminum o11os
Barium 0100716.4
PH (Lab) 00403
units
mg/L
Ba _
Ca - Calcium 00916
TOC 00680 <1.0
m /L
g
<1.0
Cd -Cadmium 01027_
Chloride 00940 1.5
<5.0
Chromium: Total 01034_
Arsenic 01002 <10.0
ug/L
mg/L
Cu - Copper oloaz_
Grease and Oils 00552
Fe Iron oloas 143
Phenol 3273o
ug/L
mg/L
—
Hg - Mercury 71900 <0.2
Sulfate o0945 4.1
µMhos
K - Potassium 00937_
Specific Conductance 00095
mg/L
Mg -Magnesium 00927_
Total Ammonia 0o6lo <0.10
Nitrogen, Total)
Mn - Manganese 0105543.8
(Ammonia Nitrogen; NH, as N; Ammonia
Ni - Nickel 01067_
TKN as N ooszs
mg/L
For Remediation Systems Only (Attach Lab Reports):
A I"
Permittee (or Authorized Agent) Name and Title - Please print or type
Influent Total VOCs:
INAS DRY
at time of
sampling,
check
mg/L
Pb -Lead 01051 15.0 ug/L
mg/L
Zn - Zinc 01092 mg/L
mg/L
Compounds and Concentration Units):
mg/L
Other (Specify
mg/L
Ag-Silver <5.0 ug/L
ug/L
Se -Selenium 1-10.0 ug/L
mg/L
Na-Sodium <5000 ug/L
_ ug/L
ug/L
ORGANICS: (by GC, GC/MS, HPLC)
mg/L
(Specify test and method #. ATTACH LAB REPORT.)
ug/L
ug/L
Lab Report Attached? ❑ Yes (1) 0 No (0)
_
mg/L
VOC 78732 method #
#
mg/L
,method
#
ug/L
,method
method #
ug/L
Effluent Total VOCs:
VOC Removal%
LOW
GW-59 Rev.8/2013

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM please Print Clearly orType
FACILITY INFORMATION
Facility Name: Metropolitan Sewerage District
Permit Name (if different):
Facility Address: 2225 Riverside Drive, Asheville, NC 28804
Contact Person: Bart Farmer
Well Location/Site Name: Downgradient of Ash Lagoon
SUBMIT FORM ON YELLOW PAPER ONLY
County Buncombe
Telephone#: [phone]
No. of wells to be sampled: 4
)EPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
)MSION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
PERMIT Number: Expiration Date: t2/31/22
Non -Discharge UIC
NPDES NCO024911 Other
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑Remediation: Infiltration Gallery
❑ Spray Field ❑ Remediation:
❑ Rotary Distributor ❑ Land Application of Sludge
❑ Water Source Heat Pump ❑ Other:
SAMPLING INFORMATION MW-06R Date sample collected: 01/05/23 FIELD ANALYSES:
HELL ID NUMBER (from Permit): H 00400: 5.55 units Temp. 00010: 18.0 °C
17 ft. Well Diameter: 2 in. p 297.3 µMhos
Nell Depth: 18 ft. Spec. Cond. 000sa:
10.05 ft. below measuring point Screened Interval: 8 ft. to None
depth to Water Level 825a6: ft. Odor 00085:
0.0 ft. above land surface Relative M.P. Elevation: Clear
vleasuring Point is Appearance
Volume of water pumped/bailed before sampling: 1.45 gallons
Sam les for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: '❑ YES ❑ NO
Certification No. 40, 5342,12
BORATORY INFORMATION ta N me: Pace Analytical Services, LLC
LA
Date sample analyzed: 01/06i23-ovl9rzs Laboraory
NOTE: Values should reflect dissolved and colloidal concentrations.
PARAMETERS
mg/L
Nitrite (NOZ) as N 00615
COD oo33s
/100mL
Nitrate (NO3) as N 00620 0.16
Coliform: MF Fecal 31616
/100mL
Phosphorus: Total as P 00665
Coliform: MF Total 31504
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
Dissolved Solids:Total 70300 186
mg/L
Al- Aluminum oil 0s
01007 70.8
pH (Lab) 00403
units
ga -Barium
TOC oo680 1.3
mg/L
Ca - Calcium 00916
Chloride oosao 13.0
mg/L
Cd - Cadmium 01027 <1.0
`10
ug/L
Chromium: Total 01034 <5.0
Arsenic 01002
mg/L
Cu - Copper 01042
Grease and Oils oossz
Fe -Iron 01045 5,660
Phenol 32730
9
uglL
H g Mercury 71soo <0.2
Sulfate oosas 86
µ Mhos
K -Potassium oos37
Specific Conductance 00095
mg/L
Mg -Magnesium 00927
Total Ammonia 00610 0.4
Nitrogen; NH,as N; Ammonia Nitrogen, Total)
Mn - Manganese o1 oss 9,970
(Ammonia
mg/L
Ni - Nickel 01067
TKN as N 00625
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs:
T ,grl�f 1 C%L'
Permittee (or Authorized Agent) Name and Title - Please print or type
INAS DRY
at time of
sampling,
check
here:
l—'
mg/L
Pb - Lead o1o51 `5•0 ug/L
mg/L
Zn - Zinc 01092 mg/L
mg/L
mg/L
Other (Specify Compounds and Concentration Units):
mg/L
Ag Silver <5.0 ug/L
ug/L
Se -Selenium <10.0 ug/L
mg/L
Na-Sodium 17,400 ug/L
ug/L
ug/L
mg/L
ORGANICS: (by GC, GC/MS, HPLC)
ug/L
(Specify test and method #. ATTACH LAB REPORT.)
ug/L
Lab Report Attached? ❑ Yes (1) 0 No (0)
mg/L
VOC 78732 method #
mg/L
method #
ug/L
method #
ug/L
method #
/L VOC Removal%
mg/L Effluent Total VOCs: mg —
Of
GW-59 Rev.8/2013

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM please Print Clearly or
FACILITY INFORMATION
Facility Name: Metropolitan Sewerage District
Permit Name (if different):
(erside Drive, Asheville, NC 28804
Facility Address: 2225 Riv
act Person: Bart Farmer
Location/Site Name: Downgradient of Ash Lagoon
L ID NUMBER (from Permit):
MW-07
Depth: 14 ft.
h to Water Level 82546' 10.31 ft. below measuring point
wring Point is 0.0 ft. above land surface
Tie of water pumped/bailed before sampling: 0.92 gallons
nles for metals were collected unfiltered: '❑ YES ❑ NO
SUBMIT FORM ON YELLOW PAPER ONLY
County Buncombe
Telephone#: [phone]
No. of wells to be sampled: 4
)EPARTMENT OF ENVIRONMENT 8 NATURAL RESOURCES
)(VISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
PERMIT Number:
Expiration Date: tu3v1-5
Non -Discharge
UIC
NPDES NCO024911
Other
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon
m Remediation: Infiltration Gallery
❑ Spray Field
❑ Remediation:
❑ Rotary Distributor
❑ Land Application of Sludge
❑ Water Source Heat Pump
❑ Other:
Date sample collected:
01/05/23 FIELD ANALYSES:
Well Diameter: 2 in. pH ooaoo: 6.41 units Temp. 00010: 172 C
°
µMhos
Screened Interval: 4 ft. to 14 ft. Spec. Cond. 00094:
None
ft. Odor 000ss:
414.1
Relative M.P. Elevation: Clear
Appearance
-Dv INFORMAI IL)N N me' Pace Analytical Services, LLC
LABORA Laboratory a
Date sample analyzed: 01/06123-01/19123
Values should reflect dissolved and colloidal concentrations.
PARAMETERS NOTE:
mg/L
Nitrite (NO2) as N 00615
COD 00335
/100mL
Nitrate (NO,) as N ooszo 14.5
Coliform: MF Fecal 3161s
/100mL
Phosphorus: Total as P 00665
ColiformMF Total 3150a
:
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
Solids:Total 70300 254
mg/L
AI -Aluminum 01105
Dissolved
units
ga _ Barium 01007 36.7
pH (Lab) 00403
mg/L
Ca - Calcium 00916
TOC o068o 2.2
mg/L
Cd -Cadmium o1027 `1.0
Chloride 00940 11.4
ug/L
Chromium: Total 01027 `5.0
Arsenic 01002 <10.0
mg/L
Cu - Copper 01042
Grease and Oils oo55z
Fe -Iron oloas `50.0
Phenol 32730
ug/L
H Mercury 71900 `0.2
g
Sulfate oo9a5 51.8
µMhos
K - Potassium 00937
Specific Conductance 000ss
mg/L
M Magnesium 00927
9 -
Total Ammonia 00610 <0.10
Nitrogen, Total)
Mn - Manganese 01055 8.3
(Ammonia Nitrogen: NH3as N; Ammonia
mg/L
Ni - Nickel 01067_
TKN as N 00625
For Remediation Systems Only (Attach Lab Reports):
Influent Total VOCs:
Permittee (or Authorized Agent) Name and Title - Please print or type
mg/L
mg/L
mg/L
mg/L
mg/L
ug/L
mg/L
ug/L
ug/L
mg/L
_ ug/L
ug/L
mg/L
_ mg/L
_ ug/L
ug/L
Certification No. 40, 5342,12
Pb - Lead o1051 `5 0 ug/L
Zn - Zinc 01092 mg/L
Other (Specify Compounds and Concentration Units):
Ag-Silver <5.0 ug/L
Se -Selenium <10.0 ug/L
Na-Sodium 7,220 ug/L
ORGANICS: (by GC, GC/MS, HPLC)
(Specify test and method #. ATTACH LAB REPORT.)
Lab Report Attached? ❑ Yes (1) 0 No (0)
VOC 78732 method #
method #
method #
method #
mg/L Effluent Total VOCs:
of
WAS DRY
at time of
sampling,
mg/L VOC Removal%
3/� 3
1-0
GW-59 Rev.8/2013

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
FACILITY INFORMATION Please Print Clearly or Type
Facility Name: Metropolitan Sewerage District
Permit Name (if different):
Facility Address: 2225 Riverside Drive, Asheville, NC 28804
County Buncombe
act Person: Bart Farmer Telephone#: [phone]
Location/Site Name: Downgradient of Ash Lagoon No. of wells to be sampled: 4
L ID NUMBER (from Permit): MW-08R
Depth: 17 ft.
h to Water Level 82546: 9.99 ft. below measuring point
wring Point is 0.0 ft. above land surface
Tle of water pumped/bailed before sampling: 1.19
oles for metals were collected unfiltered: m YES
gallons
NO
Date sample collected: 01/05/23
Well Diameter: 2 in
Screened Interval: 8 ft.
Relative M.P. Elevation:
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 91M07-6306
PERMIT Number: Expiration Date: 12/31/22
Non -Discharge UIC
NPDES NCO024911 Other
TYPE OF PERMITTED OPERATION BEING MONITORED
0 Lagoon ❑ Remediation: Infiltration Gallery
❑ Spray Field ❑ Remediation:
❑ Rotary Distributor ❑ Land Application of Sludge
❑ Water Source Heat Pump ❑ Other:
to 18 ft.
ft.
❑ NO
FIELD ANALYSES:
pH 00400: 6.67 units
Spec. Cond. 00094: 612
Odor 00085: None
Appearance Clear
Temp. 000lo: 17.2 °C
µMhos
ate sample analyzed` 01106/23-01/19/23
Laboratory Name: Pace Analytical Services, LLC
Certification No. 40, 5342,12
%RAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615
mg/L
Pb -Lead olo51 <5.0 ug/L
Coliform: MF Fecal 31616
/100mL
Nitrate (NO3) as N 00620 <0.040
mg/L
Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L
Other (Specify Compounds and Concentration Units):
Dissolved Solids:Total 70300 265
mg/L
Al -Aluminum 01105
mg/L
Ag-Silver <5.0 ug/L
pH (Lab) 00403
units
Ba - Barium 01007 49•8
ug/L
Se -Selenium <10.0 ug/L
TOC 00680 2-8
mg/L
Ca - Calcium 00916
mg/L
Na-Sodium 32,800 ug/L
Chloride 00940 15.3
mg/L
Cd -Cadmium 01027 <1.0
ug/L
Arsenic 01002 <10.0
ug/L
Chromium: Total 01034 <5.0
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L
ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045 53,000
ug/L
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 120
mg/L
Hg - Mercury 71900 <0.20
ug/L
Lab Report Attached? ❑ Yes (1) El No (0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L
VOC 78732 method #
Total Ammonia owo 0.40
mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen; NH.as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055 14,900
ug/L
, method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOUs: mg/L vuk, Kemovat 7o
WAS DRY
at time of
sampling,
check
here:
GW-59 Rev.8/2013

2eAnalytical
www.pacelabs.com
(-
January 23, 2023
Bart Farmer
MSD of Buncombe County
RE: Project: JANUARY 2023 MW'S
Pace Project No.: 92645304
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Dear Bart Farmer: anuary 05, 2023. The results
Enclosed are the the labraory on J
dd inithisr apotrt f Res ltslereported the e nyconformot tthe applicable TNI/NELAC Standards andrelatthenly to
the samples Include de
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor Dyson
[e-mail]
[phone]
Project Manager
Enclosures
cc: Ms. Shannon Bergeron, Metropolitan Sewerage District
Mr. John Gosnell, Metropolitan Sewerage District
Ms. Sheila Kilby, MSD of Buncombe County
Mr. Chad Ledford, Metropolitan Sewerage District
Ms. Angel McCrain, MSD of Buncombe County
Patrick Smith, MSD of Buncombe County, NC
Mr. Alan Taylor, Metropolitan Sewerage District
Mr. Schuyler Taylor, Metropolitan Sewerage District
Q pceI
REPORT OF LABORATORY ANALYSIS
TNI This report shall not be reproduced, except in full,
\ i j without the written consent of Pace Analytical Services, LLC.
eq,RA'C�'

aceAnalytical
www.pacelabs.com
Project: JANUARY 2023 MW'S
Pace Project No.: 92645304
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 KinceyAve. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification M E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
CERTIFICATIONS
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
VirginiaNELAP Certification M 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
VirginiaNELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]

�?ceAnalytical'
www.pacelab5.com
Project: JANUARY 2023 MW'S
Pace Project No.: 92645304
Lab ID Sample ID
92645304001 MW-05
92645304002 MW-06R
92645304003 MW-07
92646304004 MW-08R
PASI-A = Pace Analytical Services -Asheville
PASI-C = Pace Analytical Services - Charlotte
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Method
Analysts
Analytes
Reported
Laboratory
EPA 200.7 Rev 4.4 1994
SBW
10
PASI-A
EPA 245.1 Rev 3.0 1994
NMP
1
PASI-A
SM 2540C-2015
MA132
1
PASI-A
EPA 300.0 Rev 2.1 1993
JCM
1
PASI-A
EPA 350.1 Rev 2.0 1993
ARJ
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
SM 4500-CI-E-2011
MDW
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
EPA 200.7 Rev 4.4 1994
SBW
10
PASI-A
EPA 245.1 Rev 3.0 1994
NMP
1
PASI-A
SM 254OC-2015
MAB2
1
PASI-A
EPA 300.0 Rev 2.1 1993
JCM
1
PASI-A
EPA 350.1 Rev 2.0 1993
ARJ
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
SM 4500-CI-E-2011
MDW
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
EPA 200.7 Rev 4.4 1994
SBW
10
PASI-A
EPA 245.1 Rev 3.0 1994
NMP
1
PASI-A
SM 2540C-2015
MA62
1
PASI-A
EPA 300.0 Rev 2.1 1993
JCM
1
PASI-A
EPA 350.1 Rev 2.0 1993
ARJ
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
SM 4500-CI-E-2011
MDW
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
EPA 200.7 Rev 4.4 1994
DEC, SBW
10
PASI-A
EPA 245.1 Rev 3.0 1994
NMP
1
PASI-A
SM 2540C-2015
MA132
1
PASI-A
EPA 300.0 Rev 2.1 1993
JCM
1
PASI-A
EPA 350.1 Rev 2.0 1993
ARJ
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
SM 4500-CI-E-2011
MDW
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

aceAnalytical `y
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ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: JANUARY 2023 MW'S
Pace Project No.: 92645304
Lab ID: 92645304001 Collected: 01/05/23 10:05
Received: 01/05/23 15:05 Matrix: Water
Sample: MW-05
Units Report Limit DF
Prepared Analyzed CAS No. Qual
Parameters
Results
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
1
01/18/23 11:42
Performed by
Pace
1
01/18/23 11:42
Collected By
Mark
Swann 1
01/18/23 11:42
Collected Date
1 /5/23
1
01/18/23 11:42
Collected Time
1010
1
01/18/23 11:42
pH
5.59 Std. Units
1
01/18/23 11:42
Temperature
9.7 deg C
1
01/18/23 11:42
Static Water Level
18.95 feet
1
01/18/23 11:42
Specific Conductance
35.4 umhos/cm
1
01/18/23 11:42
Odor
None
1
01/18/23 11:42
Appearance
Clear
4.4 1994 Preparation
Method: EPA 200.7 Rev 4.4 1994
Analytical Method: EPA 200.7 Rev
200.7 MET ICP
Pace Analytical Services - Asheville
ND ug/L 10.0 1
01/18/23 01:53 01/19/23 13:01 7440 38-2
Arsenic
5.0 1
01/18/23 01:53 01/19/23 13:01 7440-39-3
Barium
16.4 ug/L
1.0 1
01/18/23 01:53 01/19/23 13:01 7440-43-9
Cadmium
ND ug/L
5.0 1
01/18/23 01:53 01/19/23 13:01 7440-47-3
Chromium
ND ug/L
ug/L 50.0 1
01/18/23 01:53 01/19/23 13:01 7439-89-6
Iron
143
5.0 1
01/18/23 01:53 01/19/23 13:01 7439-92-1
Lead
ND ug/L
5.0 1
01/18/23 01:53 01/19/23 13:01 7439-96-5
Manganese
43.8 ug/L
ND ug/L 10.0 1
01/18/23 01:53 01/19/23 13:01 7782-49-2
Selenium
5.0 1
01/18/23 01:53 01/19/23 13:01 7440-22-4
Silver
ND ug/L
ug/L 5000 1
01/18/23 01:53 01/19/23 13:01 7440-23-5
Sodium
ND
Analytical Method: EPA 245.1 Rev 3.0 1994 Preparation Method: EPA 245.1 Rev 3.0 1994
245.1 Mercury
Pace Analytical Services -Asheville
0.20 1
01/19/23 07:33 01/19/23 10:57 7439-97-6
Mercury
ND ug/L
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
35.0 mg/L 25.0 1
01 /09/23 15:00
Total Dissolved Solids
Analytical Method: EPA 300.0 Rev 2.1 1993
300.0 IC Anions 28 Days
Pace Analytical Services -Asheville
1.0 1
01/06/23 22:37 14808-79-8
Sulfate
4.1 mg/L
Analytical Method: EPA 350.1 Rev 2.0 1993
350.1 Ammonia
Pace Analytical Services - Asheville
0.10 1
01/14/2312:55 7664-41-7
Nitrogen, Ammonia
ND mg/L
Analytical Method: EPA 353.2 Rev 2.0 1993
353.2 Nitrogen, NO2/NO3 unpres
Pace Analytical Services - Asheville
0.040 1
01 /06/23 00:55 14797-55-8
Nitrogen, Nitrate
0.042 mg/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /23/2023 12:31 PM
without the written consent of Pace Analytical Services, LLC.

aceAnalytical ,y
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ANALYTICAL RESULTS
Project: JANUARY 2023 MW'S
Pace Project No.: 92645304
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-05 Lab ID: 92646304001 Collected: 01/05/23 10:05 Received: 01/05/23 15:05 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
4500 Chloride Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services - Asheville
Chloride 1.5 mg/L 1.0 1 01/06/2318:49 16887-00-6
5310B TOC Analytical Method: SM 5310E-2014
Pace Analytical Services - Asheville
Total Organic Carbon ND mg/L 1.0 1 01/10/23 06:41 7440-44-0
Date: 01/23/2023 12:31 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

aceAnalytical o
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i
Project:
Pace Project No.:
Sample: MW-06R
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
JANUARY 2023 MW'S
92645304
Lab ID: 92645304002 Collected: 01/05/23 11:45 Received: 01/05/23 15:05 Matrix: Water
Parameters
Monitoring Well Data
Performed by
Collected By
Collected Date
Collected Time
pH
Temperature
Static Water Level
Specific Conductance
Odor
Appearance
200.7 MET ICP
Arsenic
Barium
Cadmium
Chromium
Iron
Lead
Manganese
Selenium
Silver
Sodium
245.1 Mercury
Mercury
2540C Total Dissolved Solids
Total Dissolved Solids
300.0 IC Anions 28 Days
S u Ifate
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
Date: 01/23/2023 12:31 PM
Results Units Report Limit
DF
Prepared Analyzed CAS No. Qua[
Analytical Method:
Pace Analytical Services - Charlotte
1
01/18/23 11:47
Pace
1
01/18/23 11:47
Mark
Swann
1
01/18/23 11:47
1/5/23
1
01/18/23 11:47
1145
1
01/18/23 11:47
5.55 Std. Units
1
01/18/23 11:47
18.0 deg C
1
01/18/23 11:47
10.05 feet
1
01/18/23 11:47
297.3 umhos/cm
1
01/18/23 11:47
None
1
01/18/23 11:47
Clear
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services -Asheville
ND ug/L
10.0
1
01/18/23 01:53 01/19/23 13:18 7440-38-2
70.8 ug/L
5.0
1
01/18/23 01:53 01/19/23 13:18 7440-39-3
ND ug/L
1.0
1
01/18/23 01:53 01/19/23 13:18 7440-43-9
ND ug/L
5.0
1
01/18/23 01:53 01/19/23 13:18 7440-47-3
5660 ug/L
50.0
1
01/18/23 01:53 01/19/23 13:18 7439-89-6
ND ug/L
5.0
1
01/18/23 01:53 01/19/23 13:18 7439-92-1
9970 ug/L
5.0
1
01/18/23 01:53 01/19/23 13:18 7439-96-5
ND ug/L
10.0
1
01/18/23 01:53 01/19/23 13:18 7782-49-2
ND ug/L
5.0
1
01/18/23 01:53 01/19/23 13:18 7440-22-4
17400 ug/L
5000
1
01/18/23 01:53 01/19/23 13:18 7440-23-5
Analytical Method: EPA 245.1 Rev 3.0
1994 Preparation Method: EPA 245.1 Rev 3.0 1994
Pace Analytical Services -Asheville
ND ug/L
0.20
1
01/19/23 07:33 01/19/23 11:04 7439-97-6
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
186 mg/L
25.0
1
01 /09/23 15:00
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
86.9 mg/L
1.0
1
01 /06/23 23:26 14808-79-8
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
0.40 mg/L
0.10
1
01/14/2313:18 7664-41-7
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services - Asheville
0.16 mg/L
0.040
1
01/06/23 00:58 14797-55-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

aceAnalytical s9
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I
ANALYTICAL RESULTS
Project: JANUARY 2023 MW'S
Pace Project No.: 92645304
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-06R Lab ID: 92645304002 Collected: 01/05/23 11:45 Received: 01/05/23 15:05 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[
4500 Chloride Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services - Asheville
Chloride 13.0 mg/L 1.0 1 01/06/2318:50 16887-00-6
5310B TOC Analytical Method: SM 531 OB-2014
Pace Analytical Services - Asheville
Total Organic Carbon 1.3 mg/L 1.0 1 01/10/23 06:56 7440-44-0
Date: 01/23/202312:31 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

aceAnalytical
1 www.pacelab$.cam
I
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: JANUARY 2023 MW'S
Pace Project No.: 92645304
Lab ID: 92645304003 Collected: 01/05/23 12:50
Received: 01/05/23 15:05 Matrix: Water
Sample: MW-07
Results Units Report Limit DF
Prepared Analyzed CAS No. Qual
Parameters
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
1
01/18/23 11:51
Performed by
Pace
1
01/18/23 11:51
Collected By
Mark
Swann
01/18/23 11:51
Collected Date
1 1 /5/23
1
01/18/23 11:51
Collected Time
1250
1
01/18/23 11:51
pH
641 Std. Units
.
1
01/18/23 11:51
Temperature
deg C
1
01/18/23 11:51
Static Water Level
0.31 feet 1
10.31
01/18/23 11:51
Specific Conductance
414.1 umhoslcm
1
01/18/23 11:51
Odor
None
1
01/18/23 11:51
Appearance
Clear
4.4 1994 Preparation
Method: EPA 200.7 Rev 4.4 1994
200.7 MET ICP
Analytical Method: EPA 200.7 Rev
Pace Analytical Services - Asheville
10.0 1
01/18/23 01:53 01/19/23 13:22 7440 38 2
Arsenic
ND ug/L
5.0 1
01/18/23 01:53 01/19/23 13:22 7440-39-3
Barium
36.7 ug/L
1.0 1
01/18/23 01:53 01/19/23 13:22 7440-43-9
Cadmium
ND ug/L
5.0 1
01/18/23 01:53 01/19/23 13:22 7440-47-3
Chromium
ND ug/L
50.0 1
01/18/23 01:53 01/19/23 13:22 7439-89-6
Iron
ND ug/L
5.0 1
01/18/23 01:53 01/19/23 13:22 7439-92-1
Lead
ND ug/L
5.0 1
01/18/23 01:53 01/19/23 13:22 7439-96-5
Manganese
8.3 ug/L
ND ug/L 10.0 1
01/18/23 01:53 01/19/23 13:22 7782-49-2
Selenium
5.0 1
01/18/23 01:53 01/19/23 13:22 7440-22-4
Silver
ND ug/L
5000 1
01/18/23 01:53 01/19/23 13:22 7440-23-5
Sodium
7220 ug/L
Analytical Method: EPA 245.1 Rev 3.0 1994 Preparation Method: EPA 245.1 Rev 3.0 1994
246.1 Mercury
Pace Analytical Services - Asheville
0.20 1
01/19/23 07:33 01/19/23 11:06 7439-97-6
Mercury
ND ug/L
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services - Asheville
254 mg/L 25.0 1
01/09/2315:00
Total Dissolved Solids
Analytical Method: EPA 300.0 Rev 2.1 1993
300.0 IC Anions 28 Days
Pace Analytical Services -Asheville
1.0 1
01 /06/23 23:43 14808-79-8
Sulfate
51.8 mg/L
Analytical Method: EPA 350.1 Rev 2.0 1993
350.1 Ammonia
Pace Analytical Services - Asheville
ND mg/L 0.10 1
01/14/2313:26 7664-41-7
Nitrogen, Ammonia
Analytical Method: EPA 353.2 Rev 2.0 1993
353.2 Nitrogen, NO2/NO3 unpres
Pace Analytical Services -Asheville
0.20 5
01/06/23 01:24 14797-55-8
Nitrogen, Nitrate
14.5 mg/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /23/2023 12:31 PM without the written consent of Pace Analytical Services, LLC.

aceAnalytical
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ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: JANUARY 2023 MW'S
Pace Project No.: 92645304
Sample: MW-07 Lab lD: 92645304003 Collected: 01/05/23 12:50 Received: 01/05/23 15:05 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
4500 Chloride Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride 11.4 mg/L 1.0 1 01/06/2318:50 16887-00-6 M1
5310B TOC Analytical Method: SM 531 OB-2014
Pace Analytical Services - Asheville
Total Organic Carbon 2.2 mg/L 1.0 1 01/10/23 07:14 7440-44-0
Date: 01/23/202312:31 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

aceAnalytical Q'
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ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: JANUARY 2023 MW'S
Pace Project No.: 92645304
Sample: MW-08R
Lab ID: 92645304004 Collected: 01/05/23 14:25
Received: 01/05/23 15:05 Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace 1
1
01/18/23 11:54
01/18/23 11:54
Collected By
Mark
Swann
1
01/18/23 11:54
Collected Date
1/5/23
1
01/18/23 11:54
Collected Time
1425
1
01/18/23 11:54
pH
6.67 Std. Units
1
01/18/23 11:54
Temperature
17.2 deg C
1
01/18/23 11:54
Static Water Level
9.99 feet
1
01/18/23 11:54
Specific Conductance
612 umhos/cm
1
01/18/23 11:54
Odor
None
1
01/18/23 11:54
Appearance
Clear
Method: EPA 200.7 Rev 4.4 1994 Preparation
Method: EPA 200.7 Rev 4.4 1994
200.7 MET ICP
Analytical
Pace Analytical Services -Asheville
ND ug/L 10.0 1
01/18/23 01:53 01/19/23 13:25 7440-38-2
Arsenic
49.8 ug/L 5.0 1
01/18/23 01:53 01/19/23 13:25 7440-39-3
Barium
ND ug/L 1.0 1
01/18/23 01:53 01/19/23 13:25 7440-43-9
Cadmium
ND ug/L 5.0 1
01/18/23 01:53 01/19/23 13:25 7440 47 3
Chromium
53000 ug/L 50.0 1
01/18/23 01:53 01/19/23 13:25 7439-89-6
Iron
ND ug/L 5.0 1
01/18/23 01:53 01/19/23 13:25 7439-92-1
Lead
14900 ug/L 25.0 5
01/18/23 01:53 01/19/23 20:46 7439-96-5
Manganese
ND ug/L 10.0 1
01/18/23 01:53 01/19/23 13:25 7782-49-2
Selenium
ND ug/L 5.0 1
01/18/23 01:53 01/19/23 13:25 7440-22-4
Silver
32800 ug/L 5000 1
01/18/23 01:53 01/19/23 13:25 7440-23-5
Sodium
Analytical Method: EPA 245.1 Rev 3.0 1994 Preparation
Method: EPA 245.1 Rev 3.0 1994
245.1 Mercury
Pace Analytical Services - Asheville
ND ug/L 0.20 1
01/19/23 07:33 01/19/23 11:09 7439-97-6
Mercury
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
265 mg/L 25.0 1
01/09/23 15:00
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
120 mg/L 3.0 3
01/07/2312:45 14808-79-8
Sulfate
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
0.40 mg/L 0.10 1
01/14/2313:27 7664-41-7
Nitrogen, Ammonia
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
ND mg/L 0.040 1
01/06/23 01:13 14797-55-8
Nitrogen, Nitrate
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /23/2023 12:31 PM
without the written consent of Pace Analytical Services, LLC.

aceAnalytical w
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ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: JANUARY 2023 MW'S
Pace o.: N Project 92645304
Sample: M No.: Lab ID: 92645304004 Collected: 01/05/23 14:25 Received: 01/05/23 15:05 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
4500 Chloride Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services - Asheville
Chloride 15.3 mg/L 1.0 1 01/06/2318:52 16887-00-6 M1
5310B TOC Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon 2.8 mg/L 1.0 1 01/10/23 07:33 7440-44-0
Date: 01/23/202312:31 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

lace Analytical
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QUALITY CONTROL DATA
Project: JANUARY 2023 MW'S
Pace Project No.: 92645304
QC Batch: 750315 Analysis Method: EPA 245.1 Rev 3.0 1994
QC Batch Method: EPA 245.1 Rev 3.0 1994 Analysis Description: 245.1 Mercury
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92645304001, 92645304002, 92645304003, 92645304004
METHOD BLANK: 3899909 Matrix: Water
Associated Lab Samples: 92645304001, 92645304002, 92645304003, 92645304004
Blank Reporting
Parameter Units Result Limit Analyzed_ Qualifiers
Mercury ug/L ND 0.20 01/19/2310:50
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE:
Parameter
3899910
Units
Spike
Cone.
LCS
Result
LCS
% Rec
%Rec
Limits Qualifiers
Mercury
ug/L
2.5
2.5
98
85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3899911
3899912
MS
MSD
Parameter
92645304001
Units Result
Spike
Cone.
Spike MS
Cone. Result
MSD
Result
MS MSD % Rec
% Rec % Rec Limits RPD
Mercury
ug/L ND
2.5
2.5 2.7
2.7
107 108 70-130 2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /23/2023 12:31 PM without the written consent of Pace Analytical Services, LLC.
Qual

laceAnalyfical
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: JANUARY 2023 MW'S
Pace Project No.: 92645304
Analysis Method: EPA 200.7 Rev 4.4 1994
749968
QC Batch:
QC Batch Method: EPA 200.7 Rev 4.4 1994
Analysis Description: 200.7 MET
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92645304001,
92645304002, 92645304003, 92645304004
METHOD BLANK: 3898403
Matrix: Water
Associated Lab Samples: 92645304001,
92645304002, 92645304003, 92645304004
Blank Reporting
Parameter
Units
Result Limit
Analyzed
Qualifiers
ug/L
ND 10.0
01/19/2312:54
Arsenic
ug/L
ND 5.0
01/19/2312:54
Barium
ug/L
ND 1.0
01/19/2312:54
Cadmium
ug/L
ND 5.0
01/19/2312:54
Chromium
ug/L
ND 50.0
01/19/2312:54
Iron
ug/L
ND 5.0
01/19/2312:54
Lead
ug/L
ND 5.0
01/19/2312:54
Manganese
ug/L
ND 10.0
01/19/2312:54
Selenium
ug/L
ND 5.0
01/19/2312:54
Silver
ug/L
ND 5000
01/19/2312:54
Sodium
LCS %Rec
LABORATORY CONTROL SAMPLE: 3898404
Spike LCS
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
ug/L
500 461
92
85-115
Arsenic
ug/L
500 470
94
85-115
Barium
ug/L
500 478
96
85-115
Cadmium
ug/L
500 485
97
85-115
Chromium
ug/L
5000 4680
94
85-115
Iron
ug/L
500 481
96
85-115
Lead
ug/L
500 482
96
85-115
Manganese
ug/L
500 463
93
85-115
Selenium
ug/L
250 238
95
85-115
Silver
ug/L
5000 4430J
89
85-115
Sodium
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3898405 MS
92645304001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3898406
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
%Rec
Limits
RPD Qual
ug/L
ND
500
500
497
488
99
97
70130
2
Arsenic
ug/L
16.4
500
500
512
501
99
97
70-130
2
Barium
ug/L
ND
500
500
513
503
103
101
70-130
2
Cadmium
ug/L
ND
500
500
516
506
103
101
70-130
2
Chromium
ug/L
143
5000
5000
5140
5040
100
98
70-130
2
Iron
ug/L
ND
500
500
509
497
102
99
70-130
2
Lead
ug/L
43.8
500
500
560
547
103
101
70-130
2
Manganese
ND
500
500
511
500
102
100
70-130
2
Selenium
ug/L
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /23/2023 12:31 PM without the written consent of Pace Analytical Services, LLC.

aceAnalytical'
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QUALITY CONTROL DATA
Project: JANUARY 2023 MW'S
Pace Project No.: 92645304
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3898405
MS
92645304001 Spike
Parameter Units Result Conc.
Silver ug/L ND 250
Sodium ug/L ND 5000
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
3898406
MSD
Spike
MS
MSD
MS MSD % Rec
Conc.
Result
Result
% Rec % Rec Limits RPD Qual
250
253
248
101 99 70-130 2
5000
6760
6580
98 94 70-130 3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /23/2023 12:31 PM without the written consent of Pace Analytical Services, LLC.

aceAnalytical
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i
QUALITY CONTROL DATA
Project: JANUARY 2023 MW'S
Pace Project No.: 92645304
y
QC Batch: 748051
Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92645304001, 92645304002, 92645304003, 92645304004
METHOD BLANK: 3888897 Matrix: Water
Associated Lab Samples: 92645304001, 92645304002, 92645304003, 92645304004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 01/09/23 14:56
LABORATORY CONTROL SAMPLE: 3888898
Parameter
Total Dissolved Solids
SAMPLE DUPLICATE: 3888899
Parameter
Total Dissolved Solids
SAMPLE DUPLICATE: 3888900
Parameter
Total Dissolved Solids
Units
mg/L
Units
mg/L
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
250 258 103 90-110
92645366005 Dup
Result Result RPD Qualifiers
193 180 7
92645366015 Dup
Units Result Result RPD Qualifiers
mg/L 77.0 80.0 4
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /23/2023 12:31 PM without the written consent of Pace Analytical Services, LLC.

aceAnalytical "
www.pacelabs.com
QUALITY CONTROL DATA
Project: JANUARY 2023 MW'S
Pace Project No.: 92645304
QC Batch: 747749 Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92645304001, 92645304002, 92645304003, 92645304004
METHOD BLANK: 3887559 Matrix: Water
Associated Lab Samples: 92645304001, 92645304002, 92645304003, 92645304004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfate mg/L ND 1.0 01/06/2316:55
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE: 3887560
Spike LCS LCS %Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfate mg/L 50 53.8 108 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3887561 3887562
MS MSD
92644916001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua[
Sulfate mg/L 37.1 50 50 85.1 85.8 96 97 90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3887563 3887564
MS MSD
92645251002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Sulfate mg/L 11.0 50 50 60.5 60.9 99 100 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /23/2023 12:31 PM without the written consent of Pace Analytical Services, LLC.

aceAnalytical
www.pacelabs.com
Project: JANUARY 2023 MW'S
Pace Project No.: 92645304
QC Batch: 748894
QC Batch Method: EPA 350.1 Rev 2.0 1993
Associated Lab Samples: 92645304001
METHOD BLANK: 3893205
Associated Lab Samples: 92645304001
Parameter Units
Nitrogen, Ammonia mg/L
LABORATORY CONTROL SAMPLE: 3893206
Parameter Units
Nitrogen, Ammonia mg/L
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA 350.1 Rev 2.0 1993
Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services - Asheville
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.10 01/14/2312:14
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
5 5.3 105 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3893207 3893208
MS MSD
92645937001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 0.37 5 5 5.5 5.5 102 102 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3893209 3893210
MS MSD
92645996001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 2.0 5 5 7.1 7.1 102 102 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /23/2023 12:31 PM without the written consent or Pace Analytical Services, LLC.

aceAnalytical "
www.pacelabs.com
QUALITY CONTROL DATA
Project: JANUARY 2023 MW'S
Pace Project No.: 92645304
QC Batch: 749081 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92645304002, 92645304003, 92645304004
METHOD BLANK: 3894242 Matrix: Water
Associated Lab Samples: 92645304002, 92645304003, 92645304004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Ammonia mg/L ND 0.10 01/14/2313:11
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE: 3894243
Spike LCS LCS %Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Ammonia mg/L 5 5.2 104 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3894244 3894245
MS MSD
92645216001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 14.8 5 5 20.6 20.7 117 119 90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3894246 3894247
MS MSD
92645304002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 0.40 5 5 5.5 5.5 102 102 90 110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /23/2023 12:31 PM without the written consent of Pace Analytical Services, LLC.

aceAnalytical -
www.pacelabs.com
Project: JANUARY 2023 MW'S
Pace Project No.: 92645304
QC Batch: 747700
QC Batch Method: EPA 353.2 Rev 2.0 1993
Associated Lab Samples: 92645304001, 92645304002
METHOD BLANK: 3887439
Associated Lab Samples: 92645304001, 92645304002
Parameter Units
Nitrogen, Nitrate mg/L
QUALITY CONTROL DATA
Analysis Method: EPA 353.2 Rev 2.0 1993
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Laboratory: Pace Analytical Services - Asheville
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.040 01/06/23 00:27
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE: 3887440
Spike LCS LCS %Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L 1.5 1.5 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3887441 3887442
MS MSD
92645169001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrate mg/L 0.94 1.5 1.5 2.5 2.6 104 109 90-110 3
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3887443 3887444
MS MSD
92645373006 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua[
Nitrogen, Nitrate mg/L 2.3 1.5 1.5 3.9 3.9 102 103 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /23/2023 12:31 PM without the written consent of Pace Analytical Services, LLC.

aceAnalytical
t ,ww.pacelabs.c0m
Project: JANUARY 2023 MW'S
Pace Project No.: 92645304
QC Batch: 747701
QC Batch Method: EPA 353.2 Rev 2.0 1993
Associated Lab Samples: 92645304003, 92645304004
METHOD BLANK: 3887445
Associated Lab Samples: 92645304003, 92645304004
Parameter
Nitrogen, Nitrate
Units
mg/L
QUALITY CONTROL DATA
Analysis Method: EPA 353.2 Rev 2.0 1993
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Laboratory: Pace Analytical Services -Asheville
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.040 01/06/23 01:00
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE: 3887446
Spike LCS LCS %Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L 1.5 1.4 94 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3887447 3887448
MS MSD
92645373010 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua]
Nitrogen, Nitrate mg/L 1.8 1.5 1.5 3.5 3.5 113 112 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /23/2023 12:31 PM without the written consent of Pace Analytical Services, LLC.

aceAnalytical
}/ www.pacelabs.com
I
QUALITY CONTROL DATA
Project: JANUARY 2023 MW'S
Pace Project No.: 92645304
QC Batch: 747953 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92645304001, 92645304002, 92645304003, 92645304004
METHOD BLANK: 3888587 Matrix: Water
Associated Lab Samples: 92645304001, 92645304002, 92645304003, 92645304004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chloride mg/L ND 1.0 01/06/2318:41
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE: 3888588
Spike LCS LCS %Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chloride mg/L 20 20.3 102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3888589 3888590
MS MSD
92645304003 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 11.4 10 10 22.5 22.3 111 109 90-110 1 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3888591 3888592
MS MSD
92645304004 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua]
Chloride mg/L 15.3 10 10 26.6 26.5 113 112 90-110 0 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /23/2023 12:31 PM without the written consent of Pace Analytical Services, LLC.

aceAnalytical "
www.pacelabs.com
j
QUALITY CONTROL DATA
Project: JANUARY 2023 MW'S
Pace Project No.: 92645304
QC Batch: 748188 Analysis Method: SM 531 OB-2014
QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92645304001, 92645304002, 92645304003, 92645304004
METHOD BLANK: 3889474 Matrix: Water
Associated Lab Samples: 92645304001, 92645304002, 92645304003, 92645304004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Organic Carbon mg/L ND 1.0 01/10/23 01:46
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE: 3889475
Spike LCS LCS %Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Organic Carbon mg/L 25 24.7 99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3889476 3889477
MS MSD
92645600002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L ND 25 25 24.8 25.0 98 99 90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3889478 3889479
MS MSD
92645600003 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L ND 25 25 26.0 26.0 104 104 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /23/2023 12:31 PM without the written consent of Pace Analytical Services, LLC.

aceAnalytical ,y
www.pacclabs.com
QUALIFIERS
Project: JANUARY 2023 MW'S
Pace Project No.: 92645304
DEFINITIONS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /23/2023 12:31 PM without the written consent of Pace Analytical Services, LLC.

�FJceAnalytical
www.pacelabs.com
i
i
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project:
Pace Project No.:
Lab ID
JANUARY 2023 MW'S
92645304
Sample ID
QC Batch Method
QC Batch
Analytical
Analytical Method Batch
92645304001
MW-05
92645304002
MW-06R
92645304003
MW-07
92645304004
MW-08R
92645304001
MW-05
EPA 200.7 Rev 4.4 1994
749968
EPA 200.7 Rev 4.4 1994 749977
92645304002
MW-06R
EPA 200.7 Rev 4.4 1994
749968
EPA 200.7 Rev 4.4 1994 749977
92645304003
MW-07
EPA 200.7 Rev 4.4 1994
749968
EPA 200.7 Rev 4.4 1994 749977
92645304004
MW-08R
EPA 200.7 Rev 4.4 1994
749968
EPA 200.7 Rev 4.4 1994 749977
92645304001
MW-05
EPA 245.1 Rev 3.0 1994
750315
EPA 245.1 Rev 3.0 1994 750375
92645304002
MW-06R
EPA 245.1 Rev 3.0 1994
750315
EPA 245.1 Rev 3.0 1994 750375
92645304003
MW-07
EPA 245.1 Rev 3.0 1994
750315
EPA 245.1 Rev 3.0 1994 750375
92645304004
MW-08R
EPA 245.1 Rev 3.0 1994
750315
EPA 245.1 Rev 3.0 1994 750375
92645304001
MW-05
SM 2540C-2015
748051
92645304002
MW-06R
SM 2540C-2015
748051
92645304003
MW-07
SM 2540C-2015
748051
92645304004
MW-08R
SM 2540C-2015
748051
92645304001
MW-05
EPA 300.0 Rev 2.1 1993
747749
92645304002
MW-06R
EPA 300.0 Rev 2.1 1993
747749
92645304003
MW-07
EPA 300.0 Rev 2.1 1993
747749
92645304004
MW-08R
EPA 300.0 Rev 2.1 1993
747749
92645304001
MW-05
EPA 350.1 Rev 2.0 1993
748894
92645304002
MW-06R
EPA 350.1 Rev 2.0 1993
749081
92645304003
MW-07
EPA 350.1 Rev 2.0 1993
749081
92645304004
MW-08R
EPA 350.1 Rev 2.0 1993
749081
92645304001
MW-05
EPA 353.2 Rev 2.0 1993
747700
92645304002
MW-06R
EPA 353.2 Rev 2.0 1993
747700
92645304003
MW-07
EPA 353.2 Rev 2.0 1993
747701
92645304004
MW-08R
EPA 353.2 Rev 2.0 1993
747701
92645304001
MW-05
SM 4500-CI-E-2011
747953
92645304002
MW-06R
SM 4500-CI-E-2011
747953
92645304003
MW-07
SM 4500-CI-E-2011
747953
92645304004
MW-08R
SM 4500-CI-E-2011
747953
92645304001
MW-05
SM 5310B-2014
748188
92645304002
MW-06R
SM 5310B-2014
748188
92645304003
MW-07
SM 5310B-2014
748188
92645304004
MW-08R
SM 5310B-2014
748188
Date: 01/23/202312:31 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.

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Document Name: Field data Sheet - Page: 10
lssuing Authority: PaceH
Document Number: F-CAR-FLD-001-rev.02 Office
i
Field Data Sheet _ f
Client. .n'1 Sj Location: A J ale a / 4- Project #:
Name and Affiliation (Sampler(s): /11 iA Ags Z Field Data Sheet Review:
Name and Affiliation (inspector): Date: By.
Well Information
Well ID: M-y- fg 5
Well Diameter: a
Total Well Depth: Z� ft
Static Water Level: i' . ft
Height of Water Column: F , ft
Well Locked: f(YEW NO)
Construction: (Steel/StainlessSteel)
MultiFactor*: -16 3 ( (Radius/12)2x3.14x7.481
Casing Volume: 9, ? o l i gallons
Cal. 3 Volumes: 'A, N" 6 5 �1'r gallons
Pump Intake:
ft
Purge Infonnation
Date Purged: L _/ _/
Start:
JS Finish: d (`PurgeRate:_—
Purging Method: r� .t , s
i
Total Volume Purged:—
(gallons/ 11
Sampling Information
Date Collected: / �%
3
Time Collected: ' �'
(am/Pm)
Sampling Equipment Used: �
� n I � �,
r
' Instrument ID:
Sqw- ?6
.Bott1E•Type-: _- . ,..
.
Preservation - _ ...
Analysis Required
&;,X
VeleM ,
--J c�� sd N ,✓
` V
Via' fit
` a �
Field Measurements/Observations
f J
o Time:
Sample Temp. ( C):
C 0! `�
Turbidity (ntu):�% Time:
I f i 'Time:
.Diss Oxy (mg/L):
10 1 `3
Fe 2+ mg/L. —Tif
_ _.�...
Specific Cond. (uS). 3_T Time:.
10 1 J
Res. Cl (mg/L)/(µg/4 —=I " e:�—
Sample pH (s:u.): s1. ��3 Time:
f 0 i �
Odor: NJ �J e. Time:
—
ReDox (mV): �i I Time:
10 1 b'
AA C I--, — Time:
PPearance:
10/0 —
ReDox (EH value):YSI ProPluS +200mV
I *
Othe :
1
General/Weather Observations—:p
-
,,
(sunny/cloudy/rainy) Temp%'. �F) Wind (mph)
�7
Date:
Sampler Signature
—..
Stabilization Test
`14-)
Spec
Time
Temp,
Diss Oxy.
Con(
Purged
CC)
(mg/L)
(uS
�j sr.
17
s
13 0

Document Name: Field data Sheet
Document Number: F-CAR FLD-0014-.02
Field Data Sheet
A . . I I
Name and Affiliation (Sampler(s): /1� f
Name and Affiliation (lnspector):
Well Information
Well ID: �W_ 0C Well Locked:
Well Diameter: Construction:
Multi Factor*: v 12)2x319x7,.98]
Casing Volume: gallons
Cal. 3 Volumes: J, 3 9 e; ,-_ gallons
Page: 1 of 2
Issu ng Authority: Pace Huntersville Quality
office
niect #: M W -------
Ad Data SheetRe"":
Date: By:
Total Well Depth: ft
Static Water Level: D i G !_--ft
Height of Water Column:__ '_') ° ft
/ NO)
+oof /gtainlessSteel)
Pump Intake:
purge Information q J Finish: 1 � +F�- PurgeRate:_&'� A
Date Purged: / /— ��-- Start . /
�� o v (gallons/MIS)
Purging Method: L Total Volume Purged: _�—
Sampling LctF� ormation
Time Collected: � � � - (am/ pm) '
Date Collected: / /� J 0.4-? b
Sampling Equipment Used: GLz, Instrument ID: %
Preservation Analysis Required
Bottle:Type_.._,..` L l�
�l rt1� 3 ,o 1
Y JA
3 P �. 9 Y, ► �3 t,
Field Measurements/Observations
�Turbidityntu_�T—�-T�e' If —
Sample Temp M: j 3 Time: ( )
Diss Oxy (mg/L): �' I Time: -
It'� Res. Cl m L L ime:�--
� of 7 3 Time:. IF ( g/ )/(µg/ )� I �..
Specific Cond. (uS): _�_` — --- Time: �—
..f � Time: (1_ `F° —Odor: Sample pH pH (s.u.): ( Time: 1
11 �-4' Appearance:
R:eDox (mV)-C'! ��—Time:---
� ReDox (EH value):YSI PrOPluS +200mV� Other:
General/Weather Observations: W +7 f'(°F Wind 0 /J (mph)
(sunny/cloudy/rainy) Temp. )
Date , 5
Sampler Signatur ,
Stabilization Test Volume
Spec. Water ether
p ReDox Turbidity rexnaved level (ft)
Time • Temp. Diss Oxy. Cond, pH (s.u.) (mV) (ntu) (gallons/ d
Purged Cc) (mg/L) (US)
--'
r--
04- i S1 ,1-
J,jA.L

} V. Document Name:
Field Data Sheet
Document Number:
F-C _ _001.rev.02
Client:
Location:
Project: /,LJ ' J
Well ID:
Reviewed Date and By:
Stabilization Test
Document Issued: November 27, 2018
Pagkf _
Issueing Authority:
Pace Huntersville Quality Office
2.
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Document Name: Field data Sheet Page: 1 of 2
All?eefiFlalyticHf b Issuing Authority: Pace Hur
Document Number: F-CAR FLD 001-rev.02 Office
Field Data Sheet
Client� S � Location: & 11, v //e Project #:Ll /!✓ �
Name and Affiliation (Sampler(s): ffDate:
SheetReyiew:
Name and Affiliation (Inspector): z-By:
Well Information
Well ID: h/ ' FJ 7 Well Locked: ONO)
Well Diameter:
Total Well Depth: ft
Static Water Level: r_3—ft.
.
Height of Water Column: 3, 6
Construction:
Steel)
Multi Factor` J ['(Radius/12)2,3 .14 x 7.48j
Casing Volume: 0, K 011 - gallons
Cal. 3 Volumes: /• 0 L) Y-*/ gallons
Pump Intake: Z. x i ft
Pure Information ,
r �. )). Y-r Pux eRate: f D�?!='
Date Purged:�_/ S / Ali Start: [ 1 Finish B
pp -)
Purging Method: U� .z S 01 `- Total Volume Purged:— (gallons s
Sampling Iztfor'matioii
Date Collected: 't '3 Time Collected: r< ��� a (am/Pm}
Sampling Equipment Used: Instrument ID: / S
Preservation Analysis Requited
i P t,4 ST, L Nl���✓
1 Pz.gs N� Jam
3 PL,c t- p c
VIL9',
Field Measurements/Observations S 0
f
0 7, l,. Time: /? Turbidity (ntu): O_� Time: �-
sample Temp (C): —
Time: _----
Diss O m L : 3 Time: r ' _ Fe 2+ mg/L:
xy ( g/) Specific Cond. (uS):414- �---Te: C �r -Res. Cl (mg/L)/(µg/L) :Time:—_—
Sample pH (s.u.}:
Time: ►- - Odor: N0.N e Time: 1 5�
5`i' Time: )-'a' Apipearance: e—A Time: —
ReDox (mV): Time:
Repo (EH value):YSI Pro Plus +200mV /6�—Other:
General/Weather Observations: f" °F Wind!
• �� (mph)
(sunny/cloudy/rainy) Temp- ( )
Sampler Signature: n D Date:
Stabilization Test
v
Time Temp. T)iss Oxy
Purged M (mg/L)
q--. I 5-
Spec.
ReDox
`turbidity
Volume
Water
Other
Cond.
pH (s.u:)
(mV
iernoved
(8allons
level (ft)
(S)
/(ntu)
1 00
(92
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Document Name: Document Issued: November 27, 2018
f #= Field Data Sheet Page�-of _z
,sci1
Document Number: Issueing Authority:
F-CAR-FLD-001.rev.02 Pace Huntexsville Quality Office
Client: -. M S
Location: h Ayt v, lie
Project:
Well ID:
Reviewed Date and By:
Stabilization Test
F-kJ
0,. 4 - .
x_
1.2
t ?
0- 630
L46N
i
Time
Purged
Temp.
(°C)
Diss Oxy.
(mg/L)
Spec.
Cond.
(US)
pH (s.u.)
ReDox (mV)
Turbidity
(ntu)
Volume Removed
(gallons/mis) circle
cane
Water level
(�).
Other

150
Document Name: Field data Sheet Page: 1 of 2
�_ �L•'eAd1*AYoN3 - lssujg Authority: Pace Huntersville Quality
Document Number: F-CAR-FLD-001-rev.02 Office
Name and AffiliatioA f ampler(s): /Ll
Name and Affiliation (Inspector):
Well Information
Well ID:. . M (4/ o8r�
Well Diameter:
Total Well Depth: j ft
Static Water Level:. ft
Height of Water Column: ! 0 / ft
r
Well Locked:
Construction:
// "'4 Project #: /Ll
Field Data Sheet Review:
Date: By:
�54 NO)
Steel)
Multi Factor*: ! r(Radius/12)2 x 3.14 x 7.481
Casing Volume: ��t L� �" gallons
Cal. 3 Volumes: 3 *'-) 3q gallons
Pump Intake: I .L ' ft
Purge Information I r 3
Date -Purged: L / S / Start: 63 Finish: A4 0 Purge Rate: /Oa �`✓� �L'r^'
PUT d: nL 2, jr ` Total Volume Purged:' _' "' _ (gallons)'
ging Methoi s
Sampling Information
Date Collected: .j / t-/_ Time Collected: (am m),
Sampling Equipment Used: ,tir J Instrument
:Bottle Type Preservation Analysis Required
A- K, L(�!✓�� i1�
L N J +i d✓�s ``�
Ili '9U 3
VAIP/tz J
6 kv
Field Measurements/Observatlons
6
% VY
Sample Temp ( q:
Time: I �� Turbidity (ntu): r 0
Time:
Diss Oxy (mg/L): 0, 1.�
Time: ` i Fe 2+ mg/L: Yore: `
Specific Cond. (uS):
Time:. ��dr, Res. Cl (mg/L)/(µg/L):
ime:
Sample pH (s.u.):
Time: Odor: A/o ..�
Time:
ReDox (mV):
Time: /' pearance: C Ld-,,
Ap
Time: / x'
ReDox (EH value):YSI ProPlus +200mY 91 3 Other:
I Me:
General/Weather-Observations:
S v.- ✓x
(sunny/cloudy/rainy) Temp:
(°F) Wind ° (mph)
Sampler Signat
0 -LS7'_- r' ___ —
JLiLUll1ZriLAU1L
1CSL
Diss Oxy.
(mg/L)
°
6S e".
Cond.
(IS)
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pH (s.u.)
ReDox
(mV)
Turbidity
(ntu)
C a
Volume
nnoved
(a�ans )
Water
level (ft)
Other
Time
Purged
Temp.
(°C)
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Document Name: Document Issued: November 27, 2018
AO
x Field Data Sheet Page .�f
Document Number: Issueing Authority:
F-CAR-FLD-001.rev.02 Pace Huntersville Quality Office
�,3
Client: wi S 0
Location: /� d A11 v, «e
Project: M H'
Well ID: 1-
Reviewed Date and By:_
Stabilization Test
+� 1Y33 7.2I�r
.'I it �7e;3 M F•i3 =,
12
TOM
' 4
0:080
M
Time
Purged
Temp.
o
�, �)
Diss Oxy,
(mg/L)
Spec.
Cond.
(US)
pH (s.u.)
ReDox (mV)
Turbidity
(ntu)
Volume Removed
(gallons/mis)
A
circle one
Water level
(ft)
Other
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