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WQ0004797_Groundwater Monitoring Report November 2022_20221221
Anchor QEA of North Carolina, PLLC ANCHOR 23Haywood Street kz 0EAcw Asheville, North h Carolina 28801 828.281.3350 December 21, 2022 Blake Kehoe Director, Engineering Lassonde Pappas & Company, Inc. 125 Industrial Park Road Hendersonville, North Carolina 28792 Re: Fall 2022 Water Quality Sampling Event Non -Discharge Permit No. WQ0004797 Clement Pappas NC, LLC Dear Mr. Kehoe, Anchor QEA of North Carolina, PLLC, is pleased to present the results of the fall 2022 water quality sampling event at the Clement Pappas NC, LLC (Clement Pappas) facility (the Site), located at 485 Brookside Camp Road in Hendersonville, North Carolina. The company that operates the facility rebranded to Lassonde Pappas & Company in 2016; however, for permitting purposes, the Hendersonville facility retains the Clement Pappas NC, LLC name that is designated on the property deed. Clement Pappas is currently permitted under a Wastewater Irrigation System Permit by the North Carolina Department of Environmental Quality (DEQ) Environmental Management Commission for the operation of a 99,900-gallon-per-day wastewater treatment and irrigation facility. Groundwater Quality Anchor QEA performed the groundwater sampling event at the Site on November 8, 2022. A Site location map is included in Figure 1. The groundwater sampling event was performed in accordance with DEQ wastewater irrigation system permit No. WQ0004797 issued September 3, 2015, and renewed May 15, 2020 (referred to as "the permit" in this letter; effective September 1, 2020, and expiring July 31, 2026). Anchor QEA used low -flow methods to purge and collect groundwater samples from six monitoring wells: MW-4, MW-5, MW-6, MW-7R, MW-8, and MW-9. Monitoring well MW-9 was installed April 14, 2015, to replace the previously damaged monitoring well MW-2R. The locations of the monitoring wells are shown in Figure 2. Anchor QEA submitted the groundwater samples to Pace Analytical Services, Inc., a North Carolina -certified laboratory, for analysis of the parameters specified in the permit, as follows: • Total organic carbon • Chloride • Fecal coliform • Total ammonia • Total nitrate • Phosphorous • Total dissolved solids December 21, 2022 Page 2 Groundwater Elevation Table 1 summarizes current and historical groundwater elevations from November 2018 to November 2022. Except for monitoring well MW-9, all monitoring well concrete pads and top -of -well casing (TOC) elevations were surveyed by Wes Cole Land Surveying, PA, on November 21, 2012. Monitoring well MW-9 was surveyed by Wes Cole Land Surveying, PA, on May 29, 2015. The surveyed TOC elevations are shown in Table 1. Groundwater Analytical Results Table 2 summarizes the current and historical groundwater analytical results from November 2018 to November 2022. During the current sampling event, the parameters analyzed were below or within the groundwater standards provided in the permit,' except for nitrate, pH, and volatile organic compound (VOCs), which are described as follows: • The pH of the samples collected from MW-4 (5. 8 standard units [SU]), MW-5 (5.5 SU), MW-6 (5.4 SU), MW-7R (4.9 SU), and MW-9 (5.3 SU) were below the groundwater standard range of 6.5 to 8.5 SU. The sample collected from the background monitoring well, MW-5, has a pH (5.6) that is similar to the other groundwater monitoring wells. • The nitrate concentration exceeded the permit groundwater standard of 10 milligrams per liter (mg/L) in the sample collected from one monitoring well, MW-7R (24.2 mg/Q. • Four VOCs (tetrachloroethene, trichloroethene, cis-1,2-dichloroethene, and vinyl chloride) were detected in background monitoring well MW-5. The DEQ has acknowledged that the VOC detections in the background well, MW-5, are not related to facility operations; however, the DEQ has not yet determined the source. — Tetrachloroethene was detected at a concentration of 152.0 microgram per liter (Ng/L), which exceed the Title 15A, North Carolina Administrative Code [NCAC], Subchapter 2L.0202 standard (2L standard) of 0.70 pg/L. — Trichloroethene was detected at a concentration of 75.1 pg/L, which exceeds the 2L groundwater standard (3.0 pg/L). — Cis- 1,2-dichloroethene was detected at a concentration of 96.5 pg/L, which exceeds the 2L groundwater standard (70 pg/L). — Vinyl chloride was detected at a concentration of 1.1 pg/L, which exceeds the 2L groundwater standard (0.03 pg/L). The 2L standard for total coliform is 1 colony -forming unit per 100 milliliters (1 CFU/100 mQ. There is no specific permit limit or 2L standard for fecal coliform; however, total coliform includes fecal coliform. The following summarizes fecal coliform results from the groundwater monitoring wells: • Fecal coliform concentrations exceeded the 2L standard for total coliform in monitoring well MW-6 (164.0 CFU/100 mQ. Due to a suspected laboratory error, MW-6 was resampled on Most of the groundwater standards are represented by the 2L standards, with the exception of nitrate and total organic carbon, which are set in the Wastewater Irrigation System Permit Number WQ0004797. December 21, 2022 Page 3 December 5, 2022, and the fecal coliform concentration was significantly lower (12.0 CFU/100 mL) but still exceeded the 2L standard (1.0 CFU/100 mQ. Fecal coliform was not detected at or above laboratory detection limits in the samples collected from all other monitoring wells. Surface Water Quality Beginning in May 2017, Clement Pappas voluntarily collected surface water samples from Mud Creek, analyzing for the same constituents as those sampled in groundwater. The renewed permit issued in May 2020, and effective September 2020, requires semiannual sampling of the surface water locations. Sampling point SW-1 is located upstream of the Site, and sampling point SW-2 is located downstream of the Site. Sampling locations are shown in Figure 2. Surface Water Analytical Results Table 3 summarizes the historical and current surface water analytical results. For the November 2022 sampling event, no parameters were detected at concentrations above the associated Title 15A NCAC Subchapter 2B surface water standards (213 standards). Since collection of surface water samples for all permit constituents began in May 2017, nitrate concentrations have been similar in SW-1 (upstream) and SW-2 (downstream). The fall 2022 sampling showed a similar relationship: upstream sample SW-1 had a nitrate concentration of 0.65 mg/L, while downstream sample SW-2 had a concentration of 0.53 mg/L. The results for total organic carbon, chloride, total dissolved solids, ammonia, and total phosphorus were also similar for upstream and downstream samples, indicating the unlikelihood that the Site is impacting Mud Creek. Discussion and Recommendations Anchor QEA performed redevelopment of MW-7R in spring 2022 to remove organic debris, which have accumulated due to root penetration of the well screen and impacted water quality; however, the concentration of nitrate in the sample collected from MW-7R during the fall 2022 sampling event remained above the permit standard. No root mass was observed during sampling, but the root mass on the outside of the casing and within the sand pack may be continuing to leach nitrogen and lower the groundwater pH as organic matter decays. Nitrate concentrations were below the permit standard in samples collected from all other monitoring wells. The results for all analyzed constituents in surface water, including nitrate, were below applicable standards and similar for upstream and downstream samples. Per a discussion regarding the results with DEQ Hydrogeologist, Brett Laverty, Anchor QEA recommends that the facility consider installation of a replacement monitoring well for MW-7R. In accordance with the spray irrigation permit WQ0004797, Clement Pappas is required to submit the following to the DEQ by December 30, 2022 (on or before the last working day of the month following the sampling month): December 21, 2022 Page 4 • Laboratory analytical reports and chain -of -custody forms (Attachment 1) • Well sampling logs and the equipment documentation and instrument calibration data sheet (Attachment 2) • DEQ GW-59A — Compliance Report Form (Attachment 3) • DEQ GW-59 — Groundwater Quality Monitoring: Compliance Report Form, for each monitoring well (Attachment 4) Anchor QEA proposes to complete the next scheduled groundwater and surface water sampling event in May 2023. If you have any questions or would like additional information, please do not hesitate to contact me at (828) 281-3350 orjverde@anchorqea.com. Sincerely, / _/ /J V, �. Z_ Jennifer Verde, PE Managing Engineer James Robert Howell, PG Principal Scientist Attachments Table 1 Current and Historical Groundwater Elevation Measurements Table 2 Current and Historical Groundwater Analytical Results Table 3 Current and Historical Surface Water Analytical Results Figure 1 Site Location Map Figure 2 Site Map Attachment 1 Laboratory Analytical Reports and Chain -of -Custody Forms Attachment 2 Well Sampling Logs and Instrument Calibration Data Sheet Attachment 3 DEQ GW-59A — Compliance Report Form Attachment 4 DEQ GW-59 — Groundwater Quality Monitoring: Compliance Report Forms Tables Table 1 Current and Historical Groundwater Elevation Measurements Well Identification Screened Interval (ft bgs) Date Measured Depth to Groundwater (ft) Top -of -Casing Elevation (ft AMSL) Top -of -Casing Height Above Ground Surface (ft) Groundwater Elevation (ft AMSL) MW-4 5.0-15.0 05/02/2018 8.44 2063.77 2.43 2055.33 11/02/2018 8.00 2055.77 05/21/2019 8.49 2055.28 11/14/2019 8.82 2054.95 05/06/2020 7.98 2055.79 11/06/2020 8.02 2055.75 05/11/2021 8.52 2055.25 10/28/2021 9.15 2054.62 05/10/2022 9.14 2054.63 11/08/2022 9.35 2054.42 MW-5 9.0-19.0 05/02/2018 8.47 2085.60 3.00 2077.93 11/02/2018 8.23 2078.17 05/21/2019 8.57 2077.83 11/14/2019 8.90 2077.50 05/06/2020 8.28 2078.12 11/06/2020 8.90 2077.50 05/11/2021 8.77 2077.63 10/28/2021 9.44 2076.96 05/10/2022 9.15 2076.45 11 /08/2022 10.07 2075.53 MW-6 5.0-10.0 05/02/2018 5.36 2061.17 3.00 2056.54 11/02/2018 5.03 2056.87 05/21/2019 5.53 2056.37 11/14/2019 5.59 2056.31 05/06/2020 5.41 2056.49 11/06/2020 5.33 2056.57 05/11/2021 5.68 2056.22 10/28/2021 5.94 2055.96 05/10/2022 5.91 2055.26 11 /08/2022 6.40 2054.77 MW-7R 5.0-15.0 05/02/2018 10.99 2062.86 3.00 2051.87 11/02/2018 10.33 2052.53 05/21/2019 10.88 2051.98 11/14/2019 11.33 2051.53 05/06/2020 10.11 2052.75 11/06/2020 10.05 2052.81 05/11/2021 10.85 2052.01 10/27/2021 11.74 2051.12 05/10/2022 11.66 2051.20 11 /08/2022 11.80 2051.06 Fall 2022 Water Quality Sampling Event Page 1 of 2 Clement Pappas, Hendersonville, North Carolina December 2022 Table 1 Current and Historical Groundwater Elevation Measurements Well Identification Screened Interval (ft bgs) Date Measured Depth to Groundwater (ft) Top -of -Casing Elevation (ft AMSL) Top -of -Casing Height Above Ground Surface (ft) Groundwater Elevation (ft AMSL) MW-8 3.0-13.0 05/02/2018 9.39 2060.80 3.00 2051.41 11/02/2018 8.85 2051.95 05/21/2019 9.38 2051.42 11/14/2019 9.75 2051.05 05/06/2020 8.54 2052.26 11/06/2020 8.37 2052.43 05/11/2021 9.24 2051.56 10/27/2021 10.06 2050.74 05/10/2022 10.02 2050.78 11 /08/2022 10.31 2050.49 MW-9 6.0-16.0 05/02/2018 5.07 2060.23 1.44 2055.16 11/02/2018 4.55 2055.68 05/21/2019 4.89 2055.34 11/14/2019 5.15 2055.08 05/06/2020 4.30 2055.93 11/06/2020 4.10 2056.13 05/11/2021 4.75 2055.48 10/27/2021 5.57 2054.66 05/10/2022 5.70 2054.53 11 /08/2022 j 5.90 j 2054.33 Notes: Top -of -casing elevations: MW-5 through MW-8 top -of -casing elevations are based on a survey by Hill and Associates Surveyors, dated January 10, 2002, through May 2012. MW-2R and MW-4 top -of -casing elevations are based on differential level measurements made by Altamont Environmental, Inc., on June 26, 2006, through May 2012. The top -of -casing elevations for the monitoring wells were resurveyed on November 21, 2012, by Wes Cole Land Surveying. The top -of -casing elevations for MW-9 were surveyed on May 29, 2015, by Wes Cole Land Surveying. Monitoring is performed in accordance with Permit No. WQ0004797 issued to Clement Pappas on May 15, 2020 and effective on September 1, 2020. AMSL: above mean sea level bgs: below ground surface ft: feet Fall 2022 Water Quality Sampling Event Page 2 of 2 Clement Pappas, Hendersonville, North Carolina December 2022 Table 2 Current and Historical Groundwater Analytical Results pH Total Organic Carbon Chloride Fecal Coliform Nitrate Total Dissolved Solids Ammonia Total Phosphorus Tetrachloroethene Trichloroethene Cis-1.2- dichloroethene Trans-1.2- dichloroethene Vinyl Chloride 1.1-Dichloroethene Sample Name Sample Date (SU) (mg/L) (mg/L) (CFUs per 100 ml-) (mg/L) (mg/L) (mg/L) (mg/L) (pg/L) (pg/L) (pg/L) (pg/L) (pg/L) (pg/L) 2L Groundwater Standards 6.5 - 8.5 10 250 1 10 500 7.5 NL 0.7 3 70 700 0.03 7 Groundwater Standards Provided in Permit No. W00004797 6.5 - 8.5 10 250 NL 10 500 7.5 NL 0.7 3 70 700 0.03 7 05/02/2018 5.86 3.0 10.0 <1.0 2.1 167 <0.020 0.11 NR 11/02/2018 5.47 3.6 9.0 <10.0 0.48 137 <0.10 0.070 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 05/21/2019 5.81 3.0 11.3 <1.0 3.3 170 <0.050 0.044 J NR 11/14/2019 5.82 3.7 11 1 <1.0 0.42 190 <0.10 <0.050 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 05/06/2020 5.70 2.3 7.6 <1.0 3.7 172 <0.10 <0.050 NR MW-4 11/06/2020 5.30 2.8 6.9 <1.0 0.73 148 <0.10 <0.050 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 05/11/2021 5.8 2.8 6.9 <1.0 1.4 169 0.14 <0.050 NR 10/28/2021 5.7 3.1 6.7 <1.0 0.084 161 <0.10 <0.050 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 05/10/2022 5.8 2.9 6.8 <1.0 0.46 136 <0.10 0.063 NR 11/08/2022 5.8 3.2 10.3 <1.0 0.090 137 <0.10 <0.050 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 05/02/2018 5.69 5.7 16.1 2.0 0.0 90 <0.10 0.097 NR 11/02/2018 5.53 5.1 23.9 <10.0 <0.020 86 <0.10 0.085 39.1 6.0 6.7 <0.50 <1.0 <0.50 05/21/2019 5.68 9.4 26.8 7.0 0.1 91 <0.050 0.120 NR 11/14/2019 5.59 6.0 20.1 7.0 0.055 202 1 <0.10 0.081 22.4 4.4 5.0 <0.50 <1.0 <0.50 MW-5 05/06/2020 5.90 6.9 7.3 8.0 <0.040 116 <0.10 0.083 NR 11/06/2020 5.65 4.6 6.9 8.0 <0.040 61.0 <0.10 0.060 0.80 1.0 <0.50 <0.50 <1.0 <0.50 05/11/2021 5.5 5.5 11.8 <2.0 <0.040 110 <0.10 0.090 NR 10/28/2021 5.7 6.6 17.3 5.0 <0.040 76.0 <0.10 0.054 30.7 11.6 12.6 <0.50 <1.0 <0.50 05/10/2022 5.6 2.7 49.0 <1.0 0.10 158 <0.10 <0.050 NR 11/08/2022 5.5 2.3 51.4 <1.0 <0.040 132 <0.10 <0.050 152.0 75.1 96.5 <0.50 1.1 <0.50 05/02/2018 5.28 2.3 9.4 1.0 0.1 81 <0.10 0.097 NR 11/02/2018 5.02 2.5 10.1 69.0 0.6 88 <0.10 0.057 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 05/21/2019 5.46 3.3 11.3 23.0 0.4 78 <0.050 0.068 NR 11/14/2019 5.30 2.9 9.3 44.0 0.56 342 <0.10 0.052 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 05/06/2020 5.38 2.0 9.7 3.0 1.1 96.0 <0.10 <0.050 NR MW-6 11/06/2020 5.23 2.6 12.5 3.0 3.2 139 <0.10 <0.050 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 05/11/2021 5.5 2.2 10.9 5.0 1.4 99.0 <0.10 <0.050 NR 10/28/2021 5.4 2.3 8.7 <1.0 <0.040 85.0 <0.10 <0.050 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 05/10/2022 5.4 1.5 13.6 <1.0 <0.040 96.0 <0.10 <0.050 NR 11/08/2022 5.4 2.0 9.5 164.0/12.0* 0.40 85.0 <0.10 <0.050 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 05/02/2018 5.41 3.2 22.6 <2.0 15.5 207 <0.10 0.320 NR 11/02/2018 5.48 5.3 20.2 <10.0 15.7 243 <0.10 0.170 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 05/21/2019 5.58 3.0 29.0 <2.0 20.2 234 <0.050 0.130 NR 11/14/2019 6.42 3.0 22.7 1 <2.0 17.1 73 <0.10 0.084 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 MW-7R 05/06/2020 5.20 1.2 20.9 <1.0 21.5 219 <0.10 <0.050 NR 11/06/2020 5.54 1.7 17.8 <1.0 13.0 205 <0.10 <0.050 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 05/11/2021 5.2 1.7 34.2 <1.0 40.4 296 <0.10 0.051 NR 10/27/2021 5.3 1.1 24.9 <1.0 26.0 222 <0.10 <0.050 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 05/10/2022 5.1 <1.0 30.8 <1.0 31.0 279 <0.10 <0.050 NR 11/08/2022 4.9 1.0 31.4 <1.0 24.2 225 <0.10 <0.050 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 Fall 2022 Water Quality Sampling Event Page 1 of 2 Clement Pappas, Hendersonville, North Carolina December 2022 Table 2 Current and Historical Groundwater Analytical Results pH Total Organic Carbon Chloride Fecal Coliform Nitrate Total Dissolved Solids Ammonia Total Phosphorus Tetrachloroethene Trichloroethene Cis-1,2- dichloroethene Trans-1.2- dichloroethene Vinyl Chloride 1,1-Dichloroethene Sample Name Sample Date (SU) (mg/L) (mg/L) (CFUs per 100 ml-) (mg/L) (mg/L) (mg/L) (mg/L) (pg/L) (pg/L) (pg/L) (pg/L) (pg/L) (pg/L) 05/02/2018 6.74 10.8 12.9 <2.0 14.4 548 <0.10 0.190 NR 11/02/2018 6.52 9.5 8.0 19.0 6.8 351 <0.10 0.250 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 05/21/2019 6.89 7.9 7.3 <10.0 6.2 249 <0.050 0.290 NR 11/14/2019 6.71 7.7 7.2 2.0 1.2 51 <0.10 0.100 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 MW-8 05/06/2020 6.41 2.7 2.8 <1.0 3.6 139 <0.10 <0.050 NR 11/06/2020 6.34 2.8 2.3 1 14.0 2.4 127 <0.10 <0.050 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 05/11/2021 6.6 3.8 2.0 <1.0 1.7 114 <0.10 <0.050 NR 10/27/2021 6.6 4.7 3.5 1.0 0.86 189 < 0.10 < 0.050 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 05/10/2022 6.7 4.5 7.4 <1.0 3.2 240 <0.10 <0.050 NR 11/08/2022 6.6 6.2 12.2 <1.0 1.4 328 <0.10 <0.050 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 05/02/2018 5.52 4.6 4.9 <2.0 1 0.58 69 <0.10 0.370 NR 11/02/2018 5.11 8.4 5.8 <10.0 0.57 88 <0.10 0.470 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 05/21/2019 5.64 7.2 4.6 <10.0 0.20 80 <0.050 0.230 NR 11/14/2019 5.57 6.1 5.4 <1.0 0.89 56 <0.10 0.076 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 MW 9 05/06/2020 5.52 5.9 1.8 <1.0 <0.040 68.0 <0.10 0.099 NR 11/06/2020 4.93 4.5 1.4 16.0 0.043 88.0 <0.10 0.095 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 05/11/2021 1 5.4 3.6 9.8 <2.0 1.9 <25.0 <0.10 0.089 NR 10/27/2021 5.4 3.8 3.2 1.0 0.35 48.0 < 0.10 < 0.050 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 05/10/2022 5.4 3.6 6.3 <1.0 1.5 67.0 <0.10 0.086 NR 11/08/2022 5.3 2.8 8.7 <1.0 1.9 81.0 0.17 <0.050 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50 Notes: 2L standards are set in North Carolina Administrative Code, Title 15A Subchapter 2L - Groundwater Classifications and Standards, Department of Environmental Quality (Amended April 1, 2022). Total organic carbon and nitrate standards are set in Wastewater Irrigation System Permit Number WQ0004797. There is no defined 2L standard for fecal coliform; therefore, the standard listed is for "total coliform" *On December 5, 2022, Anchor QEA personnel resampled MW-6 for fecal coliform due to suspected laboratory error. Bolded values indicate a concentration equal to or above the respective groundwater standard or outside the groundwater standard range. PH is analyzed by Anchor QEA of North Carolina, PLLC; INC lab certification number 5445. Monitoring is performed in accordance with Permit No. WQ0004797 issued to Clement Pappas on May 15, 2020 and effective on September 1, 2020. < indicates that the constituent concentration was not detected above the method detection limit pg/L: micrograms per liter CFU: coliform-forming unit J: The concentration is above the adjusted method detection limit and below the adjusted reporting limit and is therefore considered an estimate. mg/L: milligrams per liter mL: milliliter NL: No 2L standard exists. NR: not reported SU: standard unit Fall 2022 Water Quality Sampling Event Page 2 of 2 Clement Pappas, Hendersonville, North Carolina December 2022 Table 3 Current and Historical Surface Water Analytical Results Sample Name Sample Date PH Total Organic Carbon Chloride Fecal Coliform Nitrate Total Dissolved Solids Ammonia Total Phosphorus (SU) (mg/L) (mg/L) (CFUs per 100 ml-) (mg/L) (mg/L) (mg/L) (mg/L) 28 Standard 6.0 - 9.0 NL 230 200 NL NL NL NL SW-1 (Upstream) 5/21/2019 7.02 1.6 5.0 98.0 0.75 42.0 <0.050 0.067 11/14/2019 6.76 1.9 5.3 118 0.83 57.0 <0.10 0.1 5/6/2020 7.20 1.6 4.6 290 0.76 49.0 <0.10 0.092 11/6/2020 5.83 1.6 4.4 145 0.71 56.0 <0.10 <0.050 5/11/2021 6.8 1.3 5.3 191 0.80 48.0 <0.10 0.068 10/27/2021 7.0 1.8 5.2 145 0.72 52.0 <0.10 0.061 5/10/2022 7.1 1.4 5.1 81.0 0.88 51.0 0.12 0.15 11/08/22 7.0 2.3 6.6 89.0 0.65 63.0 <0.10 0.13 SW-2 (Downstream) 5/21/2019 6.99 1.6 4.9 200 0.76 47.0 <0.050 0.068 11/14/2019 7.01 1.9 5.4 127 0.82 83.0 <0.10 0.089 5/6/2020 6.67 1.7 4.2 420 0.72 53.0 <0.10 <0.050 11/6/2020 6.19 1.6 4.4 97.0 0.70 59.0 <0.10 <0.050 5/11/2021 6.9 1.4 5.0 146 0.74 47.0 <0.10 0.061 10/27/2021 6.9 1.9 5.2 145 0.71 55.0 <0.10 0.063 5/10/2022 6.9 1.4 4.9 118 0.87 50.0 <0.10 0.16 11/08/22 7.0 2.3 5.9 164 0.53 54.0 <0.10 0.10 Notes: 2B standard: surface water standard per North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 2B - Surface Water and Wetland Standards (last amended in November 2022), or the standard obtained from the U.S. Environmental Protection Agency Nationally Recommended Water Quality Criteria for Aquatic Life and Human Health. Bolded values indicate a concentration equal to or above the respective 2B standard or a value outside the 2B standard range. < indicates that the constituent concentration was not detected above the laboratory reporting limit Monitoring is performed in accordance with Permit No. WQ0004797 issued to Clement Pappas on May 15, 2020 and effective on September 1, 2020. CFU: coliform-forming unit J: The concentration is above the adjusted method detection limit and below the adjusted reporting limit and is therefore considered an estimate. mg/L: milligrams per liter mL: milliliters NL: No NC 2B standard exists SU: standard unit Fall 2022 Water Quality Sampling Event Page 1 of 1 Clement Pappas, Hendersonville, North Carolina December 2022 Figures I;; W-wim , rA I\ �� \ (i i .\ -� �_� \ \ \ 1 ;1 / �i / II j 1 I •1 /^-\ 1 1 - _ f j / / /' . �� /�_ a� i j i'�- �\\ \ T \ \ ` __`� / 1 \I I/I I 'i/// / / / / / /'/' _-_-_' �- `_ -�` -/ // �^ \\`♦ :.\ - \\ k\\\\ ` ` \`�-�\`"\ \\\I 11 f/1 / I1 1 I\1 /// / /ice 1/ /�".`� \'`ice -� ( \� \�\" i I III 1�`\1111�11 III( \\��� \ \\\ \_ _� - \ \\`\ r- \\\ I / l I I /, f I / _ ----_` �`\ / / / �\' �� \� \ C'♦ �` \� . \ \\ III1 \��\\ \\\N (`\ \ �..` \ �/. \ \1\ II / I I 1 / I�l / /'r `�- l / \ \r\ 1' \ \\ \ I III \ 1 11111111 \\\\ `��\\\ \ \ \ \ \ \ ` \ \ ^♦\\ \\\ \\ \\\\ \\ \ \ \ \ / / r 1 1 - �- - {' I I I l / / // /'--_-_---�``� I I / /�` \\ > \` \ \ \ IN / I III II\I\\\\1\I\ \ 1 \�\\ ` \\\\� \\' \\\\\\\ \\\\\ \\\-, /. / \ \ �♦ F! 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Attachment 1 Laboratory Analytical Reports and Chain -of -Custody Forms leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 November 15, 2022 Ms. Jennifer Verde Anchor QEA of North Carolina 231 Haywood Street Asheville, INC 28801 RE: Project: Lassonde Pappas Pace Project No.: 92635495 Dear Ms. Verde: Enclosed are the analytical results for sample(s) received by the laboratory on November 08, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, (Z/� ` - Lord Patton lorri.patton@pacelabs.com 1(828)254-7176 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 48 lacmnalyfica(' www,pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Lassonde Pappas Pace Project No.: 92635495 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 CERTIFICATIONS South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 Virginia/VELAP Certification #: 460221 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 SAMPLE ANALYTE COUNT Project: Pace Project No.: Lassonde Pappas 92635495 Analytes Lab lD Sample ID Method Analysts Reported Laboratory 92635495001 MW-4-20221108 SM 6200B CL 63 PASI-C SM 2540C-2015 MAB2 1 PASI-A SM 9222D-2015 YEG 1 PASI-A EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A SM 4500-CI-E-2011 ANM 1 PASI-A SM 531OB-2014 MJP 1 PASI-A 92635495002 MW-5-20221108 SM 6200B CL 63 PASI-C SM 2540C-2015 MAB2 1 PASI-A SM 9222D-2015 YEG 1 PASI-A EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A SM 4500-CI-E-2011 ANM 1 PASI-A SM 531OB-2014 MJP 1 PASI-A 92635495003 MW-6-20221108 SM 6200B CL 63 PASI-C SM 2540C-2015 MAB2 1 PASI-A SM 9222D-2015 YEG 1 PASI-A EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A SM 4500-CI-E-2011 ANM 1 PASI-A SM 531OB-2014 MJP 1 PASI-A 92635495004 MW-7R-20221108 SM 6200B CL 63 PASI-C SM 2540C-2015 MAB2 1 PASI-A SM 9222D-2015 YEG 1 PASI-A EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A SM 4500-CI-E-2011 ANM 1 PASI-A SM 531OB-2014 MJP 1 PASI-A 92635495005 MW-8-20221108 SM 6200B CL 63 PASI-C SM 2540C-2015 MAB2 1 PASI-A SM 9222D-2015 YEG 1 PASI-A EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 SAMPLE ANALYTE COUNT Project: Lassonde Pappas Pace Project No.: 92635495 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A SM 4500-CI-E-2011 ANM 1 PASI-A SM 531OB-2014 MJP 1 PASI-A 92635495006 MW-9-20221108 SM 6200B CL 63 PASI-C SM 2540C-2015 JMH1 1 PASI-A SM 9222D-2015 YEG 1 PASI-A EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A SM 4500-CI-E-2011 ANM 1 PASI-A SM 531OB-2014 MJP 1 PASI-A 92635495007 SW-1-20221108 SM 2540C-2015 JMH1 1 PASI-A SM 9222D-2015 YEG 1 PASI-A EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A SM 4500-CI-E-2011 ANM 1 PASI-A SM 531OB-2014 MJP 1 PASI-A 92635495008 SW-2-20221108 SM 2540C-2015 JMH1 1 PASI-A SM 9222D-2015 YEG 1 PASI-A EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A SM 4500-CI-E-2011 ANM 1 PASI-A SM 531OB-2014 MJP 1 PASI-A 92635495009 TRIP BLANK 1 SM 6200B CL 63 PASI-C 92635495010 TRIP BLANK 2 SM 6200B CL 63 PASI-C PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas Pace Project No.: 92635495 Sample: MW-4-20221108 Lab ID: 92635495001 Collected: 11/08/22 14:09 Received: 11/08/22 16:22 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND ug/L 0.50 1 11/11/22 19:08 71-43-2 Bromobenzene ND ug/L 0.50 1 11/11/22 19:08 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/11/22 19:08 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/11/22 19:08 75-27-4 Bromoform ND ug/L 0.50 1 11/11/22 19:08 75-25-2 Bromomethane ND ug/L 5.0 1 11/11/22 19:08 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/11/22 19:08 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/11/22 19:08 135-98-8 tert-Butyl benzene ND ug/L 0.50 1 11/11/22 19:08 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/11/22 19:08 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/11/22 19:08 108-90-7 Chloroethane ND ug/L 1.0 1 11/11/22 19:08 75-00-3 Chloroform ND ug/L 0.50 1 11/11/22 19:08 67-66-3 Chloromethane ND ug/L 1.0 1 11/11/22 19:08 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/11/22 19:08 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/11/22 19:08 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/11/22 19:08 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/11/22 19:08 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/11/22 19:08 106-93-4 Dibromomethane ND ug/L 0.50 1 11/11/22 19:08 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/11/22 19:08 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/11/22 19:08 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/11/22 19:08 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/11/22 19:08 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/11/22 19:08 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/11/22 19:08 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/11/22 19:08 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 11/11/22 19:08 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 11/11/22 19:08 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/11/22 19:08 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/11/22 19:08 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/11/22 19:08 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/11/22 19:08 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/11/22 19:08 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 0.50 1 11/11/22 19:08 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/11/22 19:08 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/11/22 19:08 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/11/22 19:08 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/11/22 19:08 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/11/22 19:08 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/11/22 19:08 1634-04-4 Naphthalene ND ug/L 2.0 1 11/11/22 19:08 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/11/22 19:08 103-65-1 Styrene ND ug/L 0.50 1 11/11/22 19:08 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 11/11/22 19:08 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11/11/22 19:08 79-34-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /15/2022 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas Pace Project No.: 92635495 Sample: MW-4-20221108 Lab ID: 92635495001 Collected: 11/08/22 14:09 Received: 11/08/22 16:22 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Tetrachloroethene ND ug/L 0.50 1 11/11/22 19:08 127-18-4 Toluene ND ug/L 0.50 1 11/11/22 19:08 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 11/11/22 19:08 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 1 11/11/22 19:08 120-82-1 1,1,1-Trichloroethane ND ug/L 0.50 1 11/11/22 19:08 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 1 11/11/22 19:08 79-00-5 Trichloroethene ND ug/L 0.50 1 11/11/22 19:08 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 11/11/22 19:08 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 11/11/22 19:08 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 1 11/11/22 19:08 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 11/11/22 19:08 108-67-8 Vinyl chloride ND ug/L 1.0 1 11/11/22 19:08 75-01-4 m&p-Xylene ND ug/L 1.0 1 11/11/22 19:08 179601-23-1 o-Xylene ND ug/L 0.50 1 11/11/22 19:08 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 98 % 70-130 1 11/11/22 19:08 17060-07-0 4-Bromofluorobenzene (S) 98 % 70-130 1 11/11/22 19:08 460-00-4 Toluene-d8 (S) 98 % 70-130 1 11/11/22 19:08 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids 137 mg/L 25.0 1 11/11/22 12:03 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services -Asheville Fecal Coliforms ND CFU/100 mL 1.0 1 11/08/22 17:31 11/09/22 15:53 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 1 11/10/22 13:32 7664-41-7 353.2 Nitrogen, NO2/1403 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 0.090 mg/L 0.040 1 11/10/22 02:02 14797-55-8 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus ND mg/L 0.050 1 11/09/22 19:26 11/09/22 21:59 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 10.3 mg/L 1.0 1 11/10/2217:01 16887-00-6 Date: 11/15/2022 02:32 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas Pace Project No.: 92635495 Sample: MW-4-20221108 Lab ID: 92635495001 Collected: 11/08/22 14:09 Received: 11/08/22 16:22 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 5310B TOC Analytical Method: SM 531OB-2014 Pace Analytical Services -Asheville Total Organic Carbon 3.2 mg/L 1.0 1 11/14/22 13:43 7440-44-0 Date: 11/15/2022 02:32 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas Pace Project No.: 92635495 Sample: MW-5-20221108 Lab ID: 92635495002 Collected: 11/08/22 15:05 Received: 11/08/22 16:22 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND ug/L 0.50 1 11/11/22 19:26 71-43-2 Bromobenzene ND ug/L 0.50 1 11/11/22 19:26 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/11/22 19:26 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/11/22 19:26 75-27-4 Bromoform ND ug/L 0.50 1 11/11/22 19:26 75-25-2 Bromomethane ND ug/L 5.0 1 11/11/22 19:26 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/11/22 19:26 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/11/22 19:26 135-98-8 tert-Butyl benzene ND ug/L 0.50 1 11/11/22 19:26 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/11/22 19:26 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/11/22 19:26 108-90-7 Chloroethane ND ug/L 1.0 1 11/11/22 19:26 75-00-3 Chloroform ND ug/L 0.50 1 11/11/22 19:26 67-66-3 Chloromethane ND ug/L 1.0 1 11/11/22 19:26 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/11/22 19:26 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/11/22 19:26 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/11/22 19:26 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/11/22 19:26 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/11/22 19:26 106-93-4 Dibromomethane ND ug/L 0.50 1 11/11/22 19:26 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/11/22 19:26 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/11/22 19:26 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/11/22 19:26 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/11/22 19:26 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/11/22 19:26 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/11/22 19:26 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/11/22 19:26 75-35-4 cis-1,2-Dichloroethene 96.5 ug/L 0.50 1 11/11/22 19:26 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 11/11/22 19:26 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/11/22 19:26 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/11/22 19:26 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/11/22 19:26 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/11/22 19:26 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/11/22 19:26 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 0.50 1 11/11/22 19:26 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/11/22 19:26 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/11/22 19:26 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/11/22 19:26 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/11/22 19:26 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/11/22 19:26 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/11/22 19:26 1634-04-4 Naphthalene ND ug/L 2.0 1 11/11/22 19:26 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/11/22 19:26 103-65-1 Styrene ND ug/L 0.50 1 11/11/22 19:26 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 11/11/22 19:26 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11/11/22 19:26 79-34-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /15/2022 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas Pace Project No.: 92635495 Sample: MW-5-20221108 Lab ID: 92635495002 Collected: 11/08/22 15:05 Received: 11/08/22 16:22 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Tetrachloroethene 152 ug/L 0.50 1 11/11/22 19:26 127-18-4 Toluene ND ug/L 0.50 1 11/11/22 19:26 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 11/11/22 19:26 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 1 11/11/22 19:26 120-82-1 1,1,1-Trichloroethane ND ug/L 0.50 1 11/11/22 19:26 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 1 11/11/22 19:26 79-00-5 Trichloroethene 75.1 ug/L 0.50 1 11/11/22 19:26 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 11/11/22 19:26 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 11/11/22 19:26 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 1 11/11/22 19:26 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 11/11/22 19:26 108-67-8 Vinyl chloride 1.1 ug/L 1.0 1 11/11/22 19:26 75-01-4 m&p-Xylene ND ug/L 1.0 1 11/11/22 19:26 179601-23-1 o-Xylene ND ug/L 0.50 1 11/11/22 19:26 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 96 % 70-130 1 11/11/22 19:26 17060-07-0 4-Bromofluorobenzene (S) 99 % 70-130 1 11/11/22 19:26 460-00-4 Toluene-d8 (S) 98 % 70-130 1 11/11/22 19:26 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids 132 mg/L 25.0 1 11/11/22 12:03 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services -Asheville Fecal Coliforms ND CFU/100 mL 1.0 1 11/08/22 17:31 11/09/22 15:53 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 1 11/10/22 13:33 7664-41-7 353.2 Nitrogen, NO2/1403 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate ND mg/L 0.040 1 11/10/22 02:04 14797-55-8 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus ND mg/L 0.050 1 11/09/22 19:26 11/09/22 22:00 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 51.4 mg/L 2.0 2 11/10/2218:18 16887-00-6 Date: 11/15/2022 02:32 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas Pace Project No.: 92635495 Sample: MW-5-20221108 Lab ID: 92635495002 Collected: 11/08/22 15:05 Received: 11/08/22 16:22 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 5310B TOC Analytical Method: SM 531OB-2014 Pace Analytical Services -Asheville Total Organic Carbon 2.3 mg/L 1.0 1 11/14/22 14:35 7440-44-0 Date: 11/15/2022 02:32 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas Pace Project No.: 92635495 Sample: MW-6-20221108 Lab ID: 92635495003 Collected: 11/08/22 13:10 Received: 11/08/22 16:22 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND ug/L 0.50 1 11/11/22 19:44 71-43-2 Bromobenzene ND ug/L 0.50 1 11/11/22 19:44 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/11/22 19:44 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/11/22 19:44 75-27-4 Bromoform ND ug/L 0.50 1 11/11/22 19:44 75-25-2 Bromomethane ND ug/L 5.0 1 11/11/22 19:44 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/11/22 19:44 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/11/22 19:44 135-98-8 tert-Butyl benzene ND ug/L 0.50 1 11/11/22 19:44 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/11/22 19:44 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/11/22 19:44 108-90-7 Chloroethane ND ug/L 1.0 1 11/11/22 19:44 75-00-3 Chloroform ND ug/L 0.50 1 11/11/22 19:44 67-66-3 Chloromethane ND ug/L 1.0 1 11/11/22 19:44 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/11/22 19:44 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/11/22 19:44 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/11/22 19:44 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/11/22 19:44 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/11/22 19:44 106-93-4 Dibromomethane ND ug/L 0.50 1 11/11/22 19:44 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/11/22 19:44 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/11/22 19:44 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/11/22 19:44 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/11/22 19:44 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/11/22 19:44 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/11/22 19:44 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/11/22 19:44 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 11/11/22 19:44 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 11/11/22 19:44 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/11/22 19:44 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/11/22 19:44 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/11/22 19:44 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/11/22 19:44 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/11/22 19:44 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 0.50 1 11/11/22 19:44 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/11/22 19:44 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/11/22 19:44 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/11/22 19:44 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/11/22 19:44 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/11/22 19:44 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/11/22 19:44 1634-04-4 Naphthalene ND ug/L 2.0 1 11/11/22 19:44 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/11/22 19:44 103-65-1 Styrene ND ug/L 0.50 1 11/11/22 19:44 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 11/11/22 19:44 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11/11/22 19:44 79-34-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /15/2022 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas Pace Project No.: 92635495 Sample: MW-6-20221108 Lab ID: 92635495003 Collected: 11/08/22 13:10 Received: 11/08/22 16:22 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Tetrachloroethene ND ug/L 0.50 1 11/11/22 19:44 127-18-4 Toluene ND ug/L 0.50 1 11/11/22 19:44 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 11/11/22 19:44 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 1 11/11/22 19:44 120-82-1 1,1,1-Trichloroethane ND ug/L 0.50 1 11/11/22 19:44 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 1 11/11/22 19:44 79-00-5 Trichloroethene ND ug/L 0.50 1 11/11/22 19:44 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 11/11/22 19:44 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 11/11/22 19:44 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 1 11/11/22 19:44 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 11/11/22 19:44 108-67-8 Vinyl chloride ND ug/L 1.0 1 11/11/22 19:44 75-01-4 m&p-Xylene ND ug/L 1.0 1 11/11/22 19:44 179601-23-1 o-Xylene ND ug/L 0.50 1 11/11/22 19:44 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 98 % 70-130 1 11/11/22 19:44 17060-07-0 4-Bromofluorobenzene (S) 98 % 70-130 1 11/11/22 19:44 460-00-4 Toluene-d8 (S) 100 % 70-130 1 11/11/22 19:44 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids 85.0 mg/L 25.0 1 11/11/22 12:03 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services -Asheville Fecal Coliforms 164 CFU/100 mL 1.0 1 11/08/22 17:16 11/09/22 15:53 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 1 11/10/22 13:35 7664-41-7 353.2 Nitrogen, NO2/1403 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 0.40 mg/L 0.040 1 11/10/22 01:56 14797-55-8 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus ND mg/L 0.050 1 11/09/22 19:26 11/09/22 22:00 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 9.5 mg/L 1.0 1 11/10/2217:05 16887-00-6 Date: 11/15/2022 02:32 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas Pace Project No.: 92635495 Sample: MW-6-20221108 Lab ID: 92635495003 Collected: 11/08/22 13:10 Received: 11/08/22 16:22 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 5310B TOC Analytical Method: SM 531OB-2014 Pace Analytical Services -Asheville Total Organic Carbon 2.0 mg/L 1.0 1 11/14/22 14:53 7440-44-0 Date: 11/15/2022 02:32 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas Pace Project No.: 92635495 Sample: MW-7R-20221108 Lab ID: 92635495004 Collected: 11/08/22 11:02 Received: 11/08/22 16:22 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND ug/L 0.50 1 11/11/22 20:03 71-43-2 Bromobenzene ND ug/L 0.50 1 11/11/22 20:03 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/11/22 20:03 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/11/22 20:03 75-27-4 Bromoform ND ug/L 0.50 1 11/11/22 20:03 75-25-2 Bromomethane ND ug/L 5.0 1 11/11/22 20:03 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/11/22 20:03 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/11/22 20:03 135-98-8 tert-Butyl benzene ND ug/L 0.50 1 11/11/22 20:03 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/11/22 20:03 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/11/22 20:03 108-90-7 Chloroethane ND ug/L 1.0 1 11/11/22 20:03 75-00-3 Chloroform ND ug/L 0.50 1 11/11/22 20:03 67-66-3 Chloromethane ND ug/L 1.0 1 11/11/22 20:03 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/11/22 20:03 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/11/22 20:03 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/11/22 20:03 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/11/22 20:03 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/11/22 20:03 106-93-4 Dibromomethane ND ug/L 0.50 1 11/11/22 20:03 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/11/22 20:03 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/11/22 20:03 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/11/22 20:03 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/11/22 20:03 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/11/22 20:03 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/11/22 20:03 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/11/22 20:03 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 11/11/22 20:03 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 11/11/22 20:03 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/11/22 20:03 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/11/22 20:03 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/11/22 20:03 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/11/22 20:03 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/11/22 20:03 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 0.50 1 11/11/22 20:03 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/11/22 20:03 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/11/22 20:03 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/11/22 20:03 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/11/22 20:03 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/11/22 20:03 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/11/22 20:03 1634-04-4 Naphthalene ND ug/L 2.0 1 11/11/22 20:03 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/11/22 20:03 103-65-1 Styrene ND ug/L 0.50 1 11/11/22 20:03 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 11/11/22 20:03 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11/11/22 20:03 79-34-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /15/2022 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas Pace Project No.: 92635495 Sample: MW-7R-20221108 Lab ID: 92635495004 Collected: 11/08/22 11:02 Received: 11/08/22 16:22 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Tetrachloroethene ND ug/L 0.50 1 11/11/22 20:03 127-18-4 Toluene ND ug/L 0.50 1 11/11/22 20:03 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 11/11/22 20:03 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 1 11/11/22 20:03 120-82-1 1,1,1-Trichloroethane ND ug/L 0.50 1 11/11/22 20:03 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 1 11/11/22 20:03 79-00-5 Trichloroethene ND ug/L 0.50 1 11/11/22 20:03 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 11/11/22 20:03 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 11/11/22 20:03 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 1 11/11/22 20:03 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 11/11/22 20:03 108-67-8 Vinyl chloride ND ug/L 1.0 1 11/11/22 20:03 75-01-4 m&p-Xylene ND ug/L 1.0 1 11/11/22 20:03 179601-23-1 o-Xylene ND ug/L 0.50 1 11/11/22 20:03 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 96 % 70-130 1 11/11/22 20:03 17060-07-0 4-Bromofluorobenzene (S) 99 % 70-130 1 11/11/22 20:03 460-00-4 Toluene-d8 (S) 98 % 70-130 1 11/11/22 20:03 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids 225 mg/L 25.0 1 11/11/22 12:03 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services -Asheville Fecal Coliforms ND CFU/100 mL 1.0 1 11/08/22 17:16 11/09/22 15:53 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 1 11/10/22 13:36 7664-41-7 353.2 Nitrogen, NO2/1403 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 24.2 mg/L 0.40 10 11/10/22 02:22 14797-55-8 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus ND mg/L 0.050 1 11/09/22 19:26 11/09/22 22:01 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 31.4 mg/L 1.0 1 11/10/2217:06 16887-00-6 Date: 11/15/2022 02:32 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas Pace Project No.: 92635495 Sample: MW-7R-20221108 Lab ID: 92635495004 Collected: 11/08/22 11:02 Received: 11/08/22 16:22 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 5310B TOC Analytical Method: SM 531OB-2014 Pace Analytical Services -Asheville Total Organic Carbon 1.0 mg/L 1.0 1 11/14/22 15:13 7440-44-0 Date: 11/15/2022 02:32 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas Pace Project No.: 92635495 Sample: MW-8-20221108 Lab ID: 92635495005 Collected: 11/08/22 09:37 Received: 11/08/22 16:22 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND ug/L 0.50 1 11/11/22 20:21 71-43-2 Bromobenzene ND ug/L 0.50 1 11/11/22 20:21 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/11/22 20:21 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/11/22 20:21 75-27-4 Bromoform ND ug/L 0.50 1 11/11/22 20:21 75-25-2 Bromomethane ND ug/L 5.0 1 11/11/22 20:21 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/11/22 20:21 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/11/22 20:21 135-98-8 tert-Butyl benzene ND ug/L 0.50 1 11/11/22 20:21 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/11/22 20:21 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/11/22 20:21 108-90-7 Chloroethane ND ug/L 1.0 1 11/11/22 20:21 75-00-3 Chloroform ND ug/L 0.50 1 11/11/22 20:21 67-66-3 Chloromethane ND ug/L 1.0 1 11/11/22 20:21 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/11/22 20:21 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/11/22 20:21 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/11/22 20:21 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/11/22 20:21 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/11/22 20:21 106-93-4 Dibromomethane ND ug/L 0.50 1 11/11/22 20:21 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/11/22 20:21 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/11/22 20:21 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/11/22 20:21 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/11/22 20:21 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/11/22 20:21 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/11/22 20:21 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/11/22 20:21 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 11/11/22 20:21 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 11/11/22 20:21 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/11/22 20:21 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/11/22 20:21 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/11/22 20:21 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/11/22 20:21 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/11/22 20:21 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 0.50 1 11/11/22 20:21 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/11/22 20:21 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/11/22 20:21 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/11/22 20:21 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/11/22 20:21 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/11/22 20:21 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/11/22 20:21 1634-04-4 Naphthalene ND ug/L 2.0 1 11/11/22 20:21 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/11/22 20:21 103-65-1 Styrene ND ug/L 0.50 1 11/11/22 20:21 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 11/11/22 20:21 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11/11/22 20:21 79-34-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /15/2022 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas Pace Project No.: 92635495 Sample: MW-8-20221108 Lab ID: 92635495005 Collected: 11/08/22 09:37 Received: 11/08/22 16:22 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Tetrachloroethene ND ug/L 0.50 1 11/11/22 20:21 127-18-4 Toluene ND ug/L 0.50 1 11/11/22 20:21 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 11/11/22 20:21 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 1 11/11/22 20:21 120-82-1 1,1,1-Trichloroethane ND ug/L 0.50 1 11/11/22 20:21 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 1 11/11/22 20:21 79-00-5 Trichloroethene ND ug/L 0.50 1 11/11/22 20:21 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 11/11/22 20:21 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 11/11/22 20:21 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 1 11/11/22 20:21 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 11/11/22 20:21 108-67-8 Vinyl chloride ND ug/L 1.0 1 11/11/22 20:21 75-01-4 m&p-Xylene ND ug/L 1.0 1 11/11/22 20:21 179601-23-1 o-Xylene ND ug/L 0.50 1 11/11/22 20:21 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 97 % 70-130 1 11/11/22 20:21 17060-07-0 4-Bromofluorobenzene (S) 98 % 70-130 1 11/11/22 20:21 460-00-4 Toluene-d8 (S) 98 % 70-130 1 11/11/22 20:21 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids 328 mg/L 25.0 1 11/11/22 12:03 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services -Asheville Fecal Coliforms ND CFU/100 mL 1.0 1 11/08/22 17:16 11/09/22 15:53 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 1 11/10/22 13:38 7664-41-7 353.2 Nitrogen, NO2/1403 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 1.4 mg/L 0.040 1 11/10/22 01:47 14797-55-8 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus ND mg/L 0.050 1 11/09/22 19:26 11/09/22 22:02 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 12.2 mg/L 1.0 1 11/10/2217:06 16887-00-6 Date: 11/15/2022 02:32 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas Pace Project No.: 92635495 Sample: MW-8-20221108 Lab ID: 92635495005 Collected: 11/08/22 09:37 Received: 11/08/22 16:22 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 5310B TOC Analytical Method: SM 531OB-2014 Pace Analytical Services -Asheville Total Organic Carbon 6.2 mg/L 1.0 1 11/14/22 15:29 7440-44-0 Date: 11/15/2022 02:32 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas Pace Project No.: 92635495 Sample: MW-9-20221108 Lab ID: 92635495006 Collected: 11/08/22 12:20 Received: 11/08/22 16:22 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND ug/L 0.50 1 11/11/22 20:39 71-43-2 Bromobenzene ND ug/L 0.50 1 11/11/22 20:39 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/11/22 20:39 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/11/22 20:39 75-27-4 Bromoform ND ug/L 0.50 1 11/11/22 20:39 75-25-2 Bromomethane ND ug/L 5.0 1 11/11/22 20:39 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/11/22 20:39 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/11/22 20:39 135-98-8 tert-Butyl benzene ND ug/L 0.50 1 11/11/22 20:39 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/11/22 20:39 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/11/22 20:39 108-90-7 Chloroethane ND ug/L 1.0 1 11/11/22 20:39 75-00-3 Chloroform ND ug/L 0.50 1 11/11/22 20:39 67-66-3 Chloromethane ND ug/L 1.0 1 11/11/22 20:39 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/11/22 20:39 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/11/22 20:39 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/11/22 20:39 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/11/22 20:39 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/11/22 20:39 106-93-4 Dibromomethane ND ug/L 0.50 1 11/11/22 20:39 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/11/22 20:39 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/11/22 20:39 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/11/22 20:39 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/11/22 20:39 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/11/22 20:39 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/11/22 20:39 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/11/22 20:39 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 11/11/22 20:39 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 11/11/22 20:39 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/11/22 20:39 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/11/22 20:39 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/11/22 20:39 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/11/22 20:39 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/11/22 20:39 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 0.50 1 11/11/22 20:39 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/11/22 20:39 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/11/22 20:39 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/11/22 20:39 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/11/22 20:39 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/11/22 20:39 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/11/22 20:39 1634-04-4 Naphthalene ND ug/L 2.0 1 11/11/22 20:39 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/11/22 20:39 103-65-1 Styrene ND ug/L 0.50 1 11/11/22 20:39 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 11/11/22 20:39 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11/11/22 20:39 79-34-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /15/2022 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas Pace Project No.: 92635495 Sample: MW-9-20221108 Lab ID: 92635495006 Collected: 11/08/22 12:20 Received: 11/08/22 16:22 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Tetrachloroethene ND ug/L 0.50 1 11/11/22 20:39 127-18-4 Toluene ND ug/L 0.50 1 11/11/22 20:39 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 11/11/22 20:39 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 1 11/11/22 20:39 120-82-1 1,1,1-Trichloroethane ND ug/L 0.50 1 11/11/22 20:39 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 1 11/11/22 20:39 79-00-5 Trichloroethene ND ug/L 0.50 1 11/11/22 20:39 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 11/11/22 20:39 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 11/11/22 20:39 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 1 11/11/22 20:39 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 11/11/22 20:39 108-67-8 Vinyl chloride ND ug/L 1.0 1 11/11/22 20:39 75-01-4 m&p-Xylene ND ug/L 1.0 1 11/11/22 20:39 179601-23-1 o-Xylene ND ug/L 0.50 1 11/11/22 20:39 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 100 % 70-130 1 11/11/22 20:39 17060-07-0 4-Bromofluorobenzene (S) 98 % 70-130 1 11/11/22 20:39 460-00-4 Toluene-d8 (S) 98 % 70-130 1 11/11/22 20:39 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids 81.0 mg/L 25.0 1 11/11/22 19:37 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services -Asheville Fecal Coliforms ND CFU/100 mL 1.0 1 11/08/22 17:16 11/09/22 15:53 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia 0.17 mg/L 0.10 1 11/10/22 13:39 7664-41-7 353.2 Nitrogen, NO2/1403 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 1.9 mg/L 0.040 1 11/10/22 01:54 14797-55-8 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus ND mg/L 0.050 1 11/09/22 19:26 11/09/22 22:03 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 8.7 mg/L 1.0 1 11/10/2217:07 16887-00-6 Date: 11/15/2022 02:32 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas Pace Project No.: 92635495 Sample: MW-9-20221108 Lab ID: 92635495006 Collected: 11/08/22 12:20 Received: 11/08/22 16:22 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 5310B TOC Analytical Method: SM 531OB-2014 Pace Analytical Services -Asheville Total Organic Carbon 2.8 mg/L 1.0 1 11/14/22 15:48 7440-44-0 Date: 11/15/2022 02:32 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 22 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas Pace Project No.: 92635495 Sample: SW-1-20221108 Lab ID: 92635495007 Collected: 11/08/22 15:15 Received: 11/08/22 16:22 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Total Dissolved Solids MBIO 9222D Fecal Coliform AVL Fecal Coliforms 350.1 Ammonia Nitrogen, Ammonia 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate 365.1 Phosphorus, Total Phosphorus 4500 Chloride Chloride 531013 TOC Total Organic Carbon Date: 11/15/2022 02:32 PM Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville 63.0 mg/L 25.0 1 11/11/2219:37 Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services -Asheville 89.0 CFU/100 mL 1.0 1 11/08/22 17:31 11/09/22 15:53 Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville ND mg/L 0.10 1 11/10/2213:41 7664-41-7 Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville 0.65 mg/L 0.040 1 11/10/22 02:05 14797-55-8 Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville 0.13 mg/L 0.050 1 11/09/22 19:26 11/09/22 22:03 7723-14-0 Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville 6.6 mg/L 1.0 1 11/10/2217:08 16887-00-6 Analytical Method: SM 531OB-2014 Pace Analytical Services -Asheville 2.3 mg/L 1.0 1 11/14/2216:47 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas Pace Project No.: 92635495 Sample: SW-2-20221108 Lab ID: 92635495008 Collected: 11/08/22 10:00 Received: 11/08/22 16:22 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Total Dissolved Solids MBIO 9222D Fecal Coliform AVL Fecal Coliforms 350.1 Ammonia Nitrogen, Ammonia 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate 365.1 Phosphorus, Total Phosphorus 4500 Chloride Chloride 531013 TOC Total Organic Carbon Date: 11/15/2022 02:32 PM Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville 54.0 mg/L 25.0 1 11/11/2219:37 Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services -Asheville 164 CFU/100 mL 1.0 1 11/08/22 17:16 11/09/22 15:53 Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville ND mg/L 0.10 1 11/10/2213:48 7664-41-7 Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville 0.53 mg/L 0.040 1 11/10/22 01:49 14797-55-8 Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville 0.099 mg/L 0.050 1 11/09/22 19:26 11/09/22 22:06 7723-14-0 Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville 5.9 mg/L 1.0 1 11/10/2217:11 16887-00-6 Analytical Method: SM 531OB-2014 Pace Analytical Services -Asheville 2.3 mg/L 1.0 1 11/14/2217:02 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas Pace Project No.: 92635495 Sample: TRIP BLANK 1 Lab ID: 92635495009 Collected: 11/08/22 00:00 Received: 11/08/22 16:22 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND ug/L 0.50 1 11/11/22 18:32 71-43-2 Bromobenzene ND ug/L 0.50 1 11/11/22 18:32 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/11/22 18:32 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/11/22 18:32 75-27-4 Bromoform ND ug/L 0.50 1 11/11/22 18:32 75-25-2 Bromomethane ND ug/L 5.0 1 11/11/22 18:32 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/11/22 18:32 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/11/22 18:32 135-98-8 tert-Butyl benzene ND ug/L 0.50 1 11/11/22 18:32 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/11/22 18:32 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/11/22 18:32 108-90-7 Chloroethane ND ug/L 1.0 1 11/11/22 18:32 75-00-3 Chloroform ND ug/L 0.50 1 11/11/22 18:32 67-66-3 Chloromethane ND ug/L 1.0 1 11/11/22 18:32 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/11/22 18:32 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/11/22 18:32 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/11/22 18:32 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/11/22 18:32 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/11/22 18:32 106-93-4 Dibromomethane ND ug/L 0.50 1 11/11/22 18:32 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/11/22 18:32 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/11/22 18:32 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/11/22 18:32 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/11/22 18:32 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/11/22 18:32 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/11/22 18:32 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/11/22 18:32 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 11/11/22 18:32 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 11/11/22 18:32 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/11/22 18:32 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/11/22 18:32 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/11/22 18:32 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/11/22 18:32 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/11/22 18:32 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 0.50 1 11/11/22 18:32 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/11/22 18:32 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/11/22 18:32 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/11/22 18:32 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/11/22 18:32 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/11/22 18:32 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/11/22 18:32 1634-04-4 Naphthalene ND ug/L 2.0 1 11/11/22 18:32 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/11/22 18:32 103-65-1 Styrene ND ug/L 0.50 1 11/11/22 18:32 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 11/11/22 18:32 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11/11/22 18:32 79-34-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /15/2022 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas Pace Project No.: 92635495 Sample: TRIP BLANK 1 Lab ID: 92635495009 Collected: 11/08/22 00:00 Received: 11/08/22 16:22 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Tetrachloroethene ND ug/L 0.50 1 11/11/22 18:32 127-18-4 Toluene ND ug/L 0.50 1 11/11/22 18:32 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 11/11/22 18:32 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 1 11/11/22 18:32 120-82-1 1,1,1-Trichloroethane ND ug/L 0.50 1 11/11/22 18:32 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 1 11/11/22 18:32 79-00-5 Trichloroethene ND ug/L 0.50 1 11/11/22 18:32 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 11/11/22 18:32 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 11/11/22 18:32 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 1 11/11/22 18:32 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 11/11/22 18:32 108-67-8 Vinyl chloride ND ug/L 1.0 1 11/11/22 18:32 75-01-4 m&p-Xylene ND ug/L 1.0 1 11/11/22 18:32 179601-23-1 o-Xylene ND ug/L 0.50 1 11/11/22 18:32 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 98 % 70-130 1 11/11/22 18:32 17060-07-0 4-Bromofluorobenzene (S) 100 % 70-130 1 11/11/22 18:32 460-00-4 Toluene-d8 (S) 101 % 70-130 1 11/11/22 18:32 2037-26-5 Date: 11/15/2022 02:32 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 26 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas Pace Project No.: 92635495 Sample: TRIP BLANK 2 Lab ID: 92635495010 Collected: 11/08/22 00:00 Received: 11/08/22 16:22 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND ug/L 0.50 1 11/11/22 18:50 71-43-2 Bromobenzene ND ug/L 0.50 1 11/11/22 18:50 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/11/22 18:50 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/11/22 18:50 75-27-4 Bromoform ND ug/L 0.50 1 11/11/22 18:50 75-25-2 Bromomethane ND ug/L 5.0 1 11/11/22 18:50 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/11/22 18:50 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/11/22 18:50 135-98-8 tert-Butyl benzene ND ug/L 0.50 1 11/11/22 18:50 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/11/22 18:50 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/11/22 18:50 108-90-7 Chloroethane ND ug/L 1.0 1 11/11/22 18:50 75-00-3 Chloroform ND ug/L 0.50 1 11/11/22 18:50 67-66-3 Chloromethane ND ug/L 1.0 1 11/11/22 18:50 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/11/22 18:50 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/11/22 18:50 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/11/22 18:50 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/11/22 18:50 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/11/22 18:50 106-93-4 Dibromomethane ND ug/L 0.50 1 11/11/22 18:50 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/11/22 18:50 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/11/22 18:50 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/11/22 18:50 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/11/22 18:50 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/11/22 18:50 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/11/22 18:50 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/11/22 18:50 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 11/11/22 18:50 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 11/11/22 18:50 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/11/22 18:50 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/11/22 18:50 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/11/22 18:50 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/11/22 18:50 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/11/22 18:50 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 0.50 1 11/11/22 18:50 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/11/22 18:50 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/11/22 18:50 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/11/22 18:50 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/11/22 18:50 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/11/22 18:50 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/11/22 18:50 1634-04-4 Naphthalene ND ug/L 2.0 1 11/11/22 18:50 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/11/22 18:50 103-65-1 Styrene ND ug/L 0.50 1 11/11/22 18:50 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 11/11/22 18:50 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11/11/22 18:50 79-34-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /15/2022 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Lassonde Pappas Pace Project No.: 92635495 Sample: TRIP BLANK 2 Lab ID: 92635495010 Collected: 11/08/22 00:00 Received: 11/08/22 16:22 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Tetrachloroethene ND ug/L 0.50 1 11/11/22 18:50 127-18-4 Toluene ND ug/L 0.50 1 11/11/22 18:50 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 11/11/22 18:50 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 1 11/11/22 18:50 120-82-1 1,1,1-Trichloroethane ND ug/L 0.50 1 11/11/22 18:50 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 1 11/11/22 18:50 79-00-5 Trichloroethene ND ug/L 0.50 1 11/11/22 18:50 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 11/11/22 18:50 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 11/11/22 18:50 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 1 11/11/22 18:50 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 11/11/22 18:50 108-67-8 Vinyl chloride ND ug/L 1.0 1 11/11/22 18:50 75-01-4 m&p-Xylene ND ug/L 1.0 1 11/11/22 18:50 179601-23-1 o-Xylene ND ug/L 0.50 1 11/11/22 18:50 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 98 % 70-130 1 11/11/22 18:50 17060-07-0 4-Bromofluorobenzene (S) 98 % 70-130 1 11/11/22 18:50 460-00-4 Toluene-d8 (S) 99 % 70-130 1 11/11/22 18:50 2037-26-5 Date: 11/15/2022 02:32 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 28 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Lassonde Pappas Pace Project No.: 92635495 QC Batch: 736640 Analysis Method: SM 6200B QC Batch Method: SM 6200B Analysis Description: 6200E MSV Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92635495001, 92635495002, 92635495003, 92635495004, 92635495005, 92635495006, 92635495009, 92635495010 METHOD BLANK: 3834019 Matrix: Water Associated Lab Samples: 92635495001, 92635495002, 92635495003, 92635495004, 92635495005, 92635495006, 92635495009, 92635495010 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 0.50 11/11/22 14:01 1,1,1-Trichloroethane ug/L ND 0.50 11/11/22 14:01 1,1,2,2-Tetrachloroethane ug/L ND 0.50 11/11/22 14:01 1,1,2-Trichloroethane ug/L ND 0.50 11/11/22 14:01 1,1-Dichloroethane ug/L ND 0.50 11/11/22 14:01 1,1-Dichloroethene ug/L ND 0.50 11/11/22 14:01 1,1-Dichloropropene ug/L ND 0.50 11/11/22 14:01 1,2,3-Trichlorobenzene ug/L ND 2.0 11/11/22 14:01 1,2,3-Trichloropropane ug/L ND 0.50 11/11/22 14:01 1,2,4-Trichlorobenzene ug/L ND 2.0 11/11/22 14:01 1,2,4-Trimethylbenzene ug/L ND 0.50 11/11/22 14:01 1,2-Dibromo-3-chloropropane ug/L ND 1.0 11/11/22 14:01 1,2-Dibromoethane (EDB) ug/L ND 0.50 11/11/22 14:01 1,2-Dichlorobenzene ug/L ND 0.50 11/11/22 14:01 1,2-Dichloroethane ug/L ND 0.50 11/11/22 14:01 1,2-Dichloropropane ug/L ND 0.50 11/11/22 14:01 1,3,5-Trimethylbenzene ug/L ND 0.50 11/11/22 14:01 1,3-Dichlorobenzene ug/L ND 0.50 11/11/22 14:01 1,3-Dichloropropane ug/L ND 0.50 11/11/22 14:01 1,4-Dichlorobenzene ug/L ND 0.50 11/11/22 14:01 2,2-Dichloropropane ug/L ND 0.50 11/11/22 14:01 2-Chlorotoluene ug/L ND 0.50 11/11/22 14:01 4-Chlorotoluene ug/L ND 0.50 11/11/22 14:01 Benzene ug/L ND 0.50 11/11/22 14:01 Bromobenzene ug/L ND 0.50 11/11/22 14:01 Bromochloromethane ug/L ND 0.50 11/11/22 14:01 Bromodichloromethane ug/L ND 0.50 11/11/22 14:01 Bromoform ug/L ND 0.50 11/11/22 14:01 Bromomethane ug/L ND 5.0 11/11/22 14:01 Carbon tetrachloride ug/L ND 0.50 11/11/22 14:01 Chlorobenzene ug/L ND 0.50 11/11/22 14:01 Chloroethane ug/L ND 1.0 11/11/22 14:01 Chloroform ug/L ND 0.50 11/11/22 14:01 Chloromethane ug/L ND 1.0 11/11/22 14:01 cis-1,2-Dichloroethene ug/L ND 0.50 11/11/22 14:01 cis-1,3-Dichloropropene ug/L ND 0.50 11/11/22 14:01 Dibromochloromethane ug/L ND 0.50 11/11/22 14:01 Dibromomethane ug/L ND 0.50 11/11/22 14:01 Dichlorodifluoromethane ug/L ND 0.50 11/11/22 14:01 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /15/2022 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Lassonde Pappas Pace Project No.: 92635495 METHOD BLANK: 3834019 Matrix: Water Associated Lab Samples: 92635495001, 92635495002, 92635495003, 92635495004, 92635495005, 92635495006, 92635495009, 92635495010 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Diisopropyl ether ug/L ND 0.50 11/11/22 14:01 Ethylbenzene ug/L ND 0.50 11/11/22 14:01 Hexachloro-1,3-butadiene ug/L ND 2.0 11/11/22 14:01 Isopropylbenzene (Cumene) ug/L ND 0.50 11/11/22 14:01 m&p-Xylene ug/L ND 1.0 11/11/22 14:01 Methyl-tert-butyl ether ug/L ND 0.50 11/11/22 14:01 Methylene Chloride ug/L ND 2.0 11/11/22 14:01 n-Butylbenzene ug/L ND 0.50 11/11/22 14:01 n-Propylbenzene ug/L ND 0.50 11/11/22 14:01 Naphthalene ug/L ND 2.0 11/11/22 14:01 o-Xylene ug/L ND 0.50 11/11/22 14:01 sec-Butylbenzene ug/L ND 0.50 11/11/22 14:01 Styrene ug/L ND 0.50 11/11/22 14:01 tert-Butyl benzene ug/L ND 0.50 11/11/22 14:01 Tetrachloroethene ug/L ND 0.50 11/11/22 14:01 Toluene ug/L ND 0.50 11/11/22 14:01 trans-1,2-Dichloroethene ug/L ND 0.50 11/11/22 14:01 trans- 1,3-Dichloropropene ug/L ND 0.50 11/11/22 14:01 Trichloroethene ug/L ND 0.50 11/11/22 14:01 Trichlorofluoromethane ug/L ND 1.0 11/11/22 14:01 Vinyl chloride ug/L ND 1.0 11/11/22 14:01 1,2-Dichloroethane-d4 (S) % 100 70-130 11/11/22 14:01 4-Bromofluorobenzene (S) % 98 70-130 11/11/22 14:01 Toluene-d8 (S) % 99 70-130 11/11/22 14:01 LABORATORY CONTROL SAMPLE: Parameter 3834020 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 48.4 97 60-140 1,1,1-Trichloroethane ug/L 50 43.0 86 60-140 1,1,2,2-Tetrachloroethane ug/L 50 48.0 96 60-140 1,1,2-Trichloroethane ug/L 50 47.5 95 60-140 1,1-Dichloroethane ug/L 50 42.2 84 60-140 1,1-Dichloroethene ug/L 50 43.0 86 60-140 1,1-Dichloropropene ug/L 50 46.8 94 60-140 1,2,3-Trichlorobenzene ug/L 50 51.0 102 60-140 1,2,3-Trichloropropane ug/L 50 49.4 99 60-140 1,2,4-Trichlorobenzene ug/L 50 46.4 93 60-140 1,2,4-Trimethylbenzene ug/L 50 44.5 89 60-140 1,2-Dibromo-3-chloropropane ug/L 50 49.0 98 60-140 1,2-Dibromoethane (EDB) ug/L 50 49.1 98 60-140 1,2-Dichlorobenzene ug/L 50 47.1 94 60-140 1,2-Dichloroethane ug/L 50 43.7 87 60-140 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /15/2022 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Lassonde Pappas Pace Project No.: 92635495 LABORATORY CONTROL SAMPLE: Parameter 3834020 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,2-Dichloropropane ug/L 50 47.6 95 60-140 1,3,5-Trimethylbenzene ug/L 50 43.5 87 60-140 1,3-Dichlorobenzene ug/L 50 46.7 93 60-140 1,3-Dichloropropane ug/L 50 47.8 96 60-140 1,4-Dichlorobenzene ug/L 50 45.0 90 60-140 2,2-Dichloropropane ug/L 50 36.7 73 60-140 2-Chlorotoluene ug/L 50 43.2 86 60-140 4-Chlorotoluene ug/L 50 44.5 89 60-140 Benzene ug/L 50 43.5 87 60-140 Bromobenzene ug/L 50 46.1 92 60-140 Bromochloromethane ug/L 50 43.2 86 60-140 Bromodichloromethane ug/L 50 44.7 89 60-140 Bromoform ug/L 50 49.8 100 60-140 Bromomethane ug/L 50 45.7 91 60-140 Carbon tetrachloride ug/L 50 44.8 90 60-140 Chlorobenzene ug/L 50 46.0 92 60-140 Chloroethane ug/L 50 43.6 87 60-140 Chloroform ug/L 50 42.3 85 60-140 Chloromethane ug/L 50 45.3 91 60-140 cis-1,2-Dichloroethene ug/L 50 43.1 86 60-140 cis-1,3-Dichloropropene ug/L 50 45.4 91 60-140 Dibromochloromethane ug/L 50 48.1 96 60-140 Dibromomethane ug/L 50 48.3 97 60-140 Dichlorodifluoromethane ug/L 50 45.7 91 60-140 Diisopropyl ether ug/L 50 44.6 89 60-140 Ethylbenzene ug/L 50 44.6 89 60-140 Hexachloro-1,3-butadiene ug/L 50 43.3 87 60-140 Isopropylbenzene (Cumene) ug/L 50 43.8 88 60-140 m&p-Xylene ug/L 100 89.0 89 60-140 Methyl-tert-butyl ether ug/L 50 47.0 94 60-140 Methylene Chloride ug/L 50 44.7 89 60-140 n-Butylbenzene ug/L 50 41.9 84 60-140 n-Propylbenzene ug/L 50 42.5 85 60-140 Naphthalene ug/L 50 53.9 108 60-140 o-Xylene ug/L 50 44.8 90 60-140 sec-Butylbenzene ug/L 50 43.3 87 60-140 Styrene ug/L 50 45.9 92 60-140 tert-Butyl benzene ug/L 50 37.3 75 60-140 Tetrachloroethene ug/L 50 44.4 89 60-140 Toluene ug/L 50 43.7 87 60-140 trans-1,2-Dichloroethene ug/L 50 44.0 88 60-140 trans- 1,3-Dichloropropene ug/L 50 46.0 92 60-140 Trichloroethene ug/L 50 48.5 97 60-140 Trichlorofluoromethane ug/L 50 42.4 85 60-140 Vinyl chloride ug/L 50 47.4 95 60-140 1,2-Dichloroethane-d4 (S) % 99 70-130 4-Bromofluorobenzene (S) % 100 70-130 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /15/2022 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Lassonde Pappas Pace Project No.: 92635495 LABORATORY CONTROL SAMPLE: 3834020 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Toluene-d8 (S) % 98 70-130 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3834021 MS 92635809014 Spike Parameter Units Result Conc. MSD Spike Conc. 3834022 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 200 200 238 299 119 150 60-140 23 M1 1,1,1-Trichloroethane ug/L ND 200 200 232 284 116 142 60-140 20 M1 1,1,2,2-Tetrachloroethane ug/L ND 200 200 216 283 108 141 60-140 27 M1 1,1,2-Trichloroethane ug/L ND 200 200 226 285 113 142 60-140 23 M1 1,1-Dichloroethane ug/L ND 200 200 226 273 113 137 60-140 19 1,1-Dichloroethene ug/L ND 200 200 236 286 118 143 60-140 19 M1 1,1-Dichloropropene ug/L ND 200 200 256 313 128 157 60-140 20 M1 1,2,3-Trichlorobenzene ug/L ND 200 200 227 305 113 152 60-140 29 M1 1,2,3-Trichloropropane ug/L ND 200 200 207 270 103 135 60-140 26 1,2,4-Trichlorobenzene ug/L ND 200 200 227 289 113 145 60-140 24 M1 1,2,4-Trimethylbenzene ug/L 1250 200 200 1480 1500 118 124 60-140 1 1,2-Dibromo-3-chloropropane ug/L ND 200 200 202 274 101 137 60-140 30 1,2-Dibromoethane (EDB) ug/L ND 200 200 231 291 116 145 60-140 23 M1 1,2-Dichlorobenzene ug/L ND 200 200 228 286 114 143 60-140 23 M1 1,2-Dichloroethane ug/L ND 200 200 225 270 112 135 60-140 18 1,2-Dichloropropane ug/L ND 200 200 238 294 119 147 60-140 21 M1 1,3,5-Trimethylbenzene ug/L 338 200 200 557 598 109 130 60-140 7 1,3-Dichlorobenzene ug/L ND 200 200 227 284 114 142 60-140 22 M1 1,3-Dichloropropane ug/L ND 200 200 231 293 116 146 60-140 23 M1 1,4-Dichlorobenzene ug/L ND 200 200 224 279 112 139 60-140 22 2,2-Dichloropropane ug/L ND 200 200 223 273 111 137 60-140 20 2-Chlorotoluene ug/L ND 200 200 364 402 182 201 60-140 10 M1 4-Chlorotoluene ug/L ND 200 200 216 268 108 134 60-140 21 Benzene ug/L 7.8 200 200 232 285 112 138 60-140 20 Bromobenzene ug/L ND 200 200 224 275 112 138 60-140 21 Bromochloromethane ug/L ND 200 200 221 268 110 134 60-140 19 Bromodichloromethane ug/L ND 200 200 219 274 110 137 60-140 22 Bromoform ug/L ND 200 200 219 288 110 144 60-140 27 M1 Bromomethane ug/L ND 200 200 227 294 114 147 60-140 26 M1 Carbon tetrachloride ug/L ND 200 200 232 293 116 146 60-140 23 M1 Chlorobenzene ug/L ND 200 200 233 291 116 146 60-140 22 M1 Chloroethane ug/L ND 200 200 257 306 128 153 60-140 17 M1 Chloroform ug/L ND 200 200 206 250 103 125 60-140 19 Chloromethane ug/L ND 200 200 244 291 122 146 60-140 17 M1 cis-1,2-Dichloroethene ug/L ND 200 200 231 277 115 139 60-140 18 cis-1,3-Dichloropropene ug/L ND 200 200 223 284 111 142 60-140 24 M1 Dibromochloromethane ug/L ND 200 200 226 283 113 141 60-140 22 M1 Dibromomethane ug/L ND 200 200 230 290 115 145 60-140 23 M1 Dichlorodifluoromethane ug/L ND 200 200 272 322 136 161 60-140 17 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /15/2022 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Lassonde Pappas Pace Project No.: 92635495 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3834021 MS 92635809014 Spike Parameter Units Result Conc. MSD Spike Conc. 3834022 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Qual Diisopropyl ether ug/L ND 200 200 228 274 114 137 60-140 18 Ethylbenzene ug/L 240 200 200 478 530 119 145 60-140 10 M1 Hexachloro-1,3-butadiene ug/L ND 200 200 234 293 117 147 60-140 22 M1 Isopropylbenzene (Cumene) ug/L 58.4 200 200 284 342 113 142 60-140 19 M1 m&p-Xylene ug/L 656 400 400 1130 1240 118 146 60-140 10 M1 Methyl-tert-butyl ether ug/L ND 200 200 225 283 113 141 60-140 23 M1 Methylene Chloride ug/L ND 200 200 208 251 104 126 60-140 19 n-Butylbenzene ug/L 52.1 200 200 277 319 112 133 60-140 14 n-Propylbenzene ug/L 171 200 200 383 419 106 124 60-140 9 Naphthalene ug/L 56.4 200 200 290 371 117 157 60-140 25 M1 o-Xylene ug/L 175 200 200 410 463 118 144 60-140 12 M1 sec-Butylbenzene ug/L ND 200 200 226 288 113 144 60-140 24 M1 Styrene ug/L ND 200 200 229 288 114 144 60-140 23 M1 tert-Butyl benzene ug/L ND 200 200 192 235 96 118 60-140 20 Tetrachloroethene ug/L ND 200 200 233 297 117 148 60-140 24 M1 Toluene ug/L 25.3 200 200 243 303 109 139 60-140 22 trans-1,2-Dichloroethene ug/L ND 200 200 242 290 121 145 60-140 18 M1 trans- 1,3-Dichloropropene ug/L ND 200 200 221 279 111 140 60-140 23 Trichloroethene ug/L ND 200 200 246 309 123 154 60-140 23 M1 Trichlorofluoromethane ug/L ND 200 200 243 294 121 147 60-140 19 M1 Vinyl chloride ug/L ND 200 200 264 312 132 156 60-140 16 M1 1,2-Dichloroethane-d4 (S) % 98 98 70-130 4-Bromofluorobenzene (S) % 99 101 70-130 Toluene-d8(S) % 98 98 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /15/2022 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Lassonde Pappas Pace Project No.: 92635495 QC Batch: 736483 Analysis Method: SM 2540C-2015 QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92635495001, 92635495002, 92635495003, 92635495004, 92635495005 METHOD BLANK: 3832919 Matrix: Water Associated Lab Samples: 92635495001, 92635495002, 92635495003, 92635495004, 92635495005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Dissolved Solids mg/L ND 25.0 11/11/22 12:01 LABORATORY CONTROL SAMPLE: 3832920 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Dissolved Solids mg/L 250 248 99 90-110 SAMPLE DUPLICATE: 3832921 92635453003 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 3560 3580 0 SAMPLE DUPLICATE: 3832922 92636049005 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L ND ND Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /15/2022 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Lassonde Pappas Pace Project No.: 92635495 QC Batch: 736632 Analysis Method: SM 2540C-2015 QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92635495006, 92635495007, 92635495008 METHOD BLANK: 3833970 Matrix: Water Associated Lab Samples: 92635495006, 92635495007, 92635495008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Dissolved Solids mg/L ND 25.0 11/11/22 19:36 LABORATORY CONTROL SAMPLE: 3833971 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Dissolved Solids mg/L 250 256 102 90-110 SAMPLE DUPLICATE: 3833972 92635495006 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 81.0 76.0 6 SAMPLE DUPLICATE: 3833973 92635481001 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 664 690 4 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /15/2022 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Lassonde Pappas Pace Project No.: 92635495 QC Batch: 736023 Analysis Method: SM 9222D-2015 QC Batch Method: SM 9222D-2015 Analysis Description: 9222D Fecal Coliform(MF) -AVL Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92635495001, 92635495002, 92635495003, 92635495004, 92635495005, 92635495006, 92635495007, 92635495008 METHOD BLANK: 3830740 Matrix: Water Associated Lab Samples: 92635495001, 92635495002, 92635495003, 92635495004, 92635495005, 92635495006, 92635495007, 92635495008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Fecal Coliforms CFU/100 mL ND 1.0 11/09/22 15:53 SAMPLE DUPLICATE: 3830741 92635222002 Dup Parameter Units Result Result RPD Qualifiers Fecal Coliforms CFU/100 mL ND ND Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /15/2022 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Lassonde Pappas Pace Project No.: 92635495 QC Batch: 736107 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92635495001, 92635495002, 92635495003, 92635495004, 92635495005, 92635495006, 92635495007 METHOD BLANK: 3831029 Matrix: Water Associated Lab Samples: 92635495001, 92635495002, 92635495003, 92635495004, 92635495005, 92635495006, 92635495007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Ammonia mg/L ND 0.10 11/10/22 12:58 LABORATORY CONTROL SAMPLE: 3831030 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 5.1 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3831031 3831032 MS MSD 92634043004 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L 64.8 5 5 73.4 70.0 172 104 90-110 5 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3831033 3831034 MS MSD 92634820001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L 0.65 5 5 5.8 5.8 103 104 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /15/2022 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Lassonde Pappas Pace Project No.: 92635495 QC Batch: 736109 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92635495008 METHOD BLANK: 3831035 Associated Lab Samples: 92635495008 Parameter Units Nitrogen, Ammonia mg/L LABORATORY CONTROL SAMPLE: 3831036 Parameter Units Nitrogen, Ammonia mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.10 11 /10/22 13:42 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 5 5.2 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3831037 3831038 MS MSD 92635495008 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L ND 5 5 5.2 5.2 104 104 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3831039 3831040 MS MSD 92634939001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L 0.96 5 5 6.3 6.3 107 106 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /15/2022 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Lassonde Pappas Pace Project No.: 92635495 QC Batch: 736066 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92635495001, 92635495002, 92635495003, 92635495004, 92635495005, 92635495006, 92635495007, 92635495008 METHOD BLANK: 3830929 Matrix: Water Associated Lab Samples: 92635495001, 92635495002, 92635495003, 92635495004, 92635495005, 92635495006, 92635495007, 92635495008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L ND 0.040 11/10/22 01:38 LABORATORY CONTROL SAMPLE: 3830930 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 1.5 1.5 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3830931 3830932 MS MSD 92635543001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L 1.1 1.5 1.5 2.6 2.6 97 97 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3830933 3830934 MS MSD 92635495003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L 0.40 1.5 1.5 1.9 1.9 99 100 90-110 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /15/2022 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 39 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Lassonde Pappas Pace Project No.: 92635495 QC Batch: 736013 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92635495001, 92635495002, 92635495003, 92635495004, 92635495005, 92635495006, 92635495007, 92635495008 METHOD BLANK: 3830664 Matrix: Water Associated Lab Samples: 92635495001, 92635495002, 92635495003, 92635495004, 92635495005, 92635495006, 92635495007, 92635495008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Phosphorus mg/L ND 0.050 11/09/22 21:43 LABORATORY CONTROL SAMPLE: 3830665 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phosphorus mg/L 2.5 2.5 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3830666 3830667 MS MSD 92634536001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 1.7 2.5 2.5 4.1 4.1 97 96 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3830668 3830669 MS MSD 92634541002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 23.1 2.5 2.5 26.1 26.1 120 119 90-110 0 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /15/2022 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 40 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Lassonde Pappas Pace Project No.: 92635495 QC Batch: 736047 Analysis Method: SM 4500-CI-E-2011 QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92635495001, 92635495002, 92635495003, 92635495004, 92635495005, 92635495006, 92635495007, 92635495008 METHOD BLANK: 3830888 Matrix: Water Associated Lab Samples: 92635495001, 92635495002, 92635495003, 92635495004, 92635495005, 92635495006, 92635495007, 92635495008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 11/10/2216:52 LABORATORY CONTROL SAMPLE: 3830889 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 21.0 105 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3830890 3830891 MS MSD 92635249002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 105 10 10 113 113 78 81 90-110 0 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3830892 3830893 MS MSD 92635495001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 10.3 10 10 20.7 21.0 104 108 90-110 2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /15/2022 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 41 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Lassonde Pappas Pace Project No.: 92635495 QC Batch: 736855 Analysis Method: SM 531 OB-2014 QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92635495001, 92635495002, 92635495003, 92635495004, 92635495005, 92635495006, 92635495007, 92635495008 METHOD BLANK: 3834668 Matrix: Water Associated Lab Samples: 92635495001, 92635495002, 92635495003, 92635495004, 92635495005, 92635495006, 92635495007, 92635495008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Organic Carbon mg/L ND 1.0 11/14/22 13:09 LABORATORY CONTROL SAMPLE: 3834669 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Organic Carbon mg/L 25 24.4 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3834670 3834671 MS MSD 92635495001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Total Organic Carbon mg/L 3.2 25 25 29.4 29.5 105 105 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3834672 3834673 MS MSD 92634409008 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Total Organic Carbon mg/L ND 25 25 25.6 25.7 101 102 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /15/2022 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 42 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALIFIERS Project: Lassonde Pappas Pace Project No.: 92635495 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /15/2022 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 43 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Lassonde Pappas Pace Project No.: 92635495 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92635495001 MW-4-20221108 SM 6200B 736640 92635495002 MW-5-20221108 SM 6200B 736640 92635495003 MW-6-20221108 SM 6200B 736640 92635495004 MW-7R-20221108 SM 6200B 736640 92635495005 MW-8-20221108 SM 6200B 736640 92635495006 MW-9-20221108 SM 6200B 736640 92635495009 TRIP BLANK 1 SM 6200E 736640 92635495010 TRIP BLANK 2 SM 6200E 736640 92635495001 MW-4-20221108 SM 2540C-2015 736483 92635495002 MW-5-20221108 SM 2540C-2015 736483 92635495003 MW-6-20221108 SM 2540C-2015 736483 92635495004 MW-7R-20221108 SM 2540C-2015 736483 92635495005 MW-8-20221108 SM 2540C-2015 736483 92635495006 MW-9-20221108 SM 2540C-2015 736632 92635495007 SW-1-20221108 SM 2540C-2015 736632 92635495008 SW-2-20221108 SM 2540C-2015 736632 92635495001 MW-4-20221108 SM 9222D-2015 736023 SM 9222D-2015 736030 92635495002 MW-5-20221108 SM 9222D-2015 736023 SM 9222D-2015 736030 92635495003 MW-6-20221108 SM 9222D-2015 736023 SM 9222D-2015 736030 92635495004 MW-7R-20221108 SM 9222D-2015 736023 SM 9222D-2015 736030 92635495005 MW-8-20221108 SM 9222D-2015 736023 SM 9222D-2015 736030 92635495006 MW-9-20221108 SM 9222D-2015 736023 SM 9222D-2015 736030 92635495007 SW-1-20221108 SM 9222D-2015 736023 SM 9222D-2015 736030 92635495008 SW-2-20221108 SM 9222D-2015 736023 SM 9222D-2015 736030 92635495001 MW-4-20221108 EPA 350.1 Rev 2.0 1993 736107 92635495002 MW-5-20221108 EPA 350.1 Rev 2.0 1993 736107 92635495003 MW-6-20221108 EPA 350.1 Rev 2.0 1993 736107 92635495004 MW-7R-20221108 EPA 350.1 Rev 2.0 1993 736107 92635495005 MW-8-20221108 EPA 350.1 Rev 2.0 1993 736107 92635495006 MW-9-20221108 EPA 350.1 Rev 2.0 1993 736107 92635495007 SW-1-20221108 EPA 350.1 Rev 2.0 1993 736107 92635495008 SW-2-20221108 EPA 350.1 Rev 2.0 1993 736109 92635495001 MW-4-20221108 EPA 353.2 Rev 2.0 1993 736066 92635495002 MW-5-20221108 EPA 353.2 Rev 2.0 1993 736066 92635495003 MW-6-20221108 EPA 353.2 Rev 2.0 1993 736066 92635495004 MW-7R-20221108 EPA 353.2 Rev 2.0 1993 736066 92635495005 MW-8-20221108 EPA 353.2 Rev 2.0 1993 736066 92635495006 MW-9-20221108 EPA 353.2 Rev 2.0 1993 736066 92635495007 SW-1-20221108 EPA 353.2 Rev 2.0 1993 736066 92635495008 SW-2-20221108 EPA 353.2 Rev 2.0 1993 736066 92635495001 MW-4-20221108 EPA 365.1 Rev 2.0 1993 736013 EPA 365.1 Rev 2.0 1993 736054 92635495002 MW-5-20221108 EPA 365.1 Rev 2.0 1993 736013 EPA 365.1 Rev 2.0 1993 736054 92635495003 MW-6-20221108 EPA 365.1 Rev 2.0 1993 736013 EPA 365.1 Rev 2.0 1993 736054 92635495004 MW-7R-20221108 EPA 365.1 Rev 2.0 1993 736013 EPA 365.1 Rev 2.0 1993 736054 92635495005 MW-8-20221108 EPA 365.1 Rev 2.0 1993 736013 EPA 365.1 Rev 2.0 1993 736054 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /15/2022 02:32 PM without the written consent of Pace Analytical Services, LLC. Page 44 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Lassonde Pappas Pace Project No.: 92635495 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92635495006 MW-9-20221108 EPA 365.1 Rev 2.0 1993 736013 EPA 365.1 Rev 2.0 1993 92635495007 SW-1-20221108 EPA 365.1 Rev 2.0 1993 736013 EPA 365.1 Rev 2.0 1993 92635495008 SW-2-20221108 EPA 365.1 Rev 2.0 1993 736013 EPA 365.1 Rev 2.0 1993 92635495001 MW-4-20221108 SM 4500-CI-E-2011 736047 92635495002 MW-5-20221108 SM 4500-CI-E-2011 736047 92635495003 MW-6-20221108 SM 4500-CI-E-2011 736047 92635495004 MW-7R-20221108 SM 4500-CI-E-2011 736047 92635495005 MW-8-20221108 SM 4500-CI-E-2011 736047 92635495006 MW-9-20221108 SM 4500-CI-E-2011 736047 92635495007 SW-1-20221108 SM 4500-CI-E-2011 736047 92635495008 SW-2-20221108 SM 4500-CI-E-2011 736047 92635495001 MW-4-20221108 SM 5310B-2014 736855 92635495002 MW-5-20221108 SM 5310B-2014 736855 92635495003 MW-6-20221108 SM 5310B-2014 736855 92635495004 MW-7111-20221108 SM 5310B-2014 736855 92635495005 MW-8-20221108 SM 5310B-2014 736855 92635495006 MW-9-20221108 SM 5310B-2014 736855 92635495007 SW-1-20221108 SM 5310B-2014 736855 92635495008 SW-2-20221108 SM 5310B-2014 736855 Date: 11/15/2022 02:32 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Batch 736054 736054 736054 Page 45 of 48 ,4ace DC#_Title: ENV-FRM-HUN1-0083 v01_Sampie Condition Upon Receipt Effective Date: 05/12/2022 Laboratory receiving samples: Asheville Q Eden[] Greenwood ❑ Huntersville [] Raleigh❑ Mech: n KArnPrsvillen ConditionSample Client Name: F WO# : 926354951 „Upon Receipt Project #!; Courier: ❑Fed Ex [-]UPS [-]USPS Client ❑ Commercial []Pace ❑Other; 92535495 Custody Seal Present? ❑Yes Oct Seals Intact? ❑Yes *0 Packing Material: Bubble Wrap Bubble Bags ❑None ❑ Other Thermometer: J t,� ❑ IIIGun ID: ( (� 7/ Type of Ice:t�Jvvet Correction Factor: � Cooler Temp: / 7 Add/Subtract(°C) 0 Cooler Temp Corrected ('C): 6/- 5.7 USDA Regulated Soil ( N/A, water sample) Did samples origins m a quarantine zone within the United States: CA, NY, or SC Date/Initials Person Examining Contents; r r� 11 ❑Blue ❑None Biological Tissue Frozen? ❑Yes []No ❑N/A Temp should be above freezing to 6°C ❑Samples out of temp criteria. Samples on ice, cooling process has begun Did samples originate from a foreign source (internationally, (check maps)? (,-_)Yes UNo mJJUUJrrg nawaEi d,» rue,w niwJ! Uses Urvv Comments/Discrepancy: Chain of Custody Present? es ❑No ❑N/A 1. Sarnpfes Arrived within Hold Time? es ❑No ❑N/A Z. Short Hold Time Analysis (<72 hr.)? es ❑No ❑N/A 3. Rush Turn Around Time Requested? ❑Yes Pgpo ❑N/A 4. Sufficient Volume? es []No ❑NIA 5. Correct Containers Used? -Pace Containers Used? es es [:]No❑N/A []No ❑N/A 6. Containers Intact? es []No ❑NIA 7. Dissolved analysis; Samples Field Filtered? ❑Yes tAo ❑N/A B. Sample Labels Match CDC? -includes Date/Time/ID/Analysis Yes Matrix: [:]No []N/A 9. Headspace in VOA Vials (?S-6mrn)? ❑Yes tj�o []N/A 10. Trip Blank Present? Trip Blank Custody Seals Present? es es [:]No ❑No ❑N/A ❑N/A 11. COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Lot ID of split containers: Date/Time: Date: Date: r:eio uata nequ:reor Ures Uno Page 46 of 48 Qualtrax ID: 69614 Page 1 of 2 z z A M 3 M m m o n N O D N M v 67 A D A m n m y a TEMP in C Received on Ice (YIN) Custody Sealed Cooler (Y1Nj Samples Intacl (YIN) N � O to W r rn N1 p W N I I CM fif W i2 O 6, N N b N rJ c� d m— v a n w f on n ab N n ..--.-.■ Immmmmmma ®0,,,,,, —N ys4pgp�$a��n e � A o- �oa�oavg��o v MATM CODE (see vaW modes to loll) SAMPLE TYPE (G=GRAS C=COMP} J D � y n 4 — m z 0 SAMPLE TEMP AT COLLECTION 0 OF CONTAINERS Unpreserved ro Np (D H2SO4 HNO3 HCI NaOH Na2S203 Methanol Other Analyses Test Yi Fecal Caliform MF Chloride Ammonia, Total phosphorus Nitrate, Nitrite TDS TOC VOC by 62GO Trip Blank Residual Chlorine (YIN) -� Uj Q spy LTf 4i iD � P z n 0 D } N m m o n 0 0 a O 4 N d D � O m � a z 0 n lu N 3 a N C, N N n z rn 4 o n a � A ,n,• O # N p p CL m N 3 6 a o m m c n # 0 - 3 rp N ' 7 � o � � n m C a n w n rD O 1 N p a • J n n n a 3 m a n `C C o m p m -a-no.. o� ii m in CL C 3 a ti! a MQ 0 0 --1 n N � O � n m N m a r* o CL v C n `D Cr n N 3 p o0 y R x N (7 y C N N � n � Dl N `C A a N o to (D � w z o' n ° a eRi D e � O Page 47 of 48 DC#_Title: ENV-FRM-HUN1-0084 v01 Tech Spec Sample Condition �� , Upon Receipt Effective Date: 05/12/2022 *Check mark top half of box if PH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottles ***Check all unpreserved Nitrates for chlorine Project tt LJO# : 92535495 PM: Lip Due pate: 11/15 22 CLIENT: 93-ALTAMONT a Z a 2 a Z Z u N ry o z N N Q Cp T Z ry U Q 2 m m Z _ 4 70 Y v a L) a fi 7 a n a a c O ,n = O 2 H EL O Z a a C U v c 7 Y O iv VL N 2 ? 2 Z Z a a a 4 c Q v OO m a > Z Z D 2 ? c v a. u ° E u E a E a m : E u a E v E Cl L E w o E �_ -, E Q `m x E Q v a J E x E a a a J E a J E v o 5 E c 0 J E rn 0 7 E N 0 > E ++ `m G 7° a ° Vl E a d N E J E a J E io _ V1 E E Q E E .°. a a m m a m 7 N a m 7 .ti a m r4 c%i V a co o N Z rri a m ,� fNy ni t a. m M m a a m LL 3 • -� 7 •-� l7 a rl T .r l7 a N rn l7 a = vt H i7 a o J� m C7 a m C7 o a 7 2 m l7 ❑ a 1 m l7 a V 7 ai C7 a C M L7 o C7 a ut y � N y v, o m a M 0 G k7 a 0 i7 sn y 0 M o 1 , 13 J � i 3 � 3 4 1� 5 s I y I 7 I � 1 9 10 11 12 N\� pH Adjustment Log for Preserved Samples 5ample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot p Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i,e. Out of hold, incorrect preservative, out of temp, incorrect containers) Qualtrax Document ID: 70677 Page 2 of 2 Page 48 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 December 07, 2022 Jennifer Verde Anchor QEA 231 Haywood Street Asheville, NC 28801 RE: Project: C21482-01.01 TASK 7 Pace Project No.: 92639693 Dear Jennifer Verde: Enclosed are the analytical results for sample(s) received by the laboratory on December 05, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville If you have any questions concerning this report, please feel free to contact me. Sincerely, (4a-, +1 , `-NJIO , Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 10 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 CERTIFICATIONS Project: C21482-01.01 TASK 7 Pace Project No.: 92639693 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 South Carolina Laboratory ID: 99030 Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001 North Carolina Drinking Water Certification #: 37712 Virginia/VELAP Certification #: 460222 North Carolina Wastewater Certification #: 40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 10 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 SAMPLE ANALYTE COUNT Project: C21482-01.01 TASK 7 Pace Project No.: 92639693 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92639693001 MW-06-20221205 PASI-A = Pace Analytical Services - Asheville SM 9222D-2015 REPORT OF LABORATORY ANALYSIS YEG PAS I -A This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 10 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: C21482-01.01 TASK 7 Pace Project No.: 92639693 Sample: MW-06-20221205 Lab ID: 92639693001 Collected: 12/05/22 11:10 Received: 12/05/22 12:17 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services -Asheville Fecal Coliforms 12.0 CFU/100 mL 1.0 1 12/05/22 15:41 12/06/22 14:48 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/07/2022 08:26 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 10 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: C21482-01.01 TASK 7 Pace Project No.: 92639693 QC Batch: 741489 Analysis Method: SM 9222D-2015 QC Batch Method: SM 9222D-2015 Analysis Description: 9222D Fecal Coliform(MF) -AVL Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92639693001 METHOD BLANK: 3857406 Matrix: Water Associated Lab Samples: 92639693001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Fecal Coliforms CFU/100 mL ND 1.0 12/06/22 14:48 SAMPLE DUPLICATE: 3857407 Parameter Fecal Coliforms 92639618005 Dup Units Result Result RPD Qualifiers CFU/100 mL 69.0 67.0 3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/07/2022 08:26 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 10 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALIFIERS Project: C21482-01.01 TASK 7 Pace Project No.: 92639693 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/07/2022 08:26 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 10 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: C21482-01.01 TASK 7 Pace Project No.: 92639693 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92639693001 MW-06-20221205 SM 9222D-2015 741489 SM 9222D-2015 741491 Date: 12/07/2022 08:26 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 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Hrt dH m Nm 0 0 Er. rn 'y d h m M C ro ,'u ro n m m 0 a a W [+] n rJ r F• W rA {C x N 11- 0 U1 rr'G 10 � ro m a rob r w m ro p b YO R'dw 5w r-C G bO to Hn to En r f0 z W M •• .. f) 7 Y a. ro rt 0 a N. m ro C" r, m b S v w n rt rF [n r° W �k K ro m n r= rt -0m C rt W r• O N x m n oomwr.0 n nWw ro ,• ma m M N a n C W ro rt 3 rt n rt rt v P. a m m C N W G rd ro n n rt a r- m d It H n r p r- m ro t3 O y r C m m 'a 38 w N 'd Y n 7 f0 w f9 rt m ro iawm rca r. rar m rt n k r� - m w n ro W ro m W H n rrr 9 m R r m fi rt SD p n y Itrt r•C rC r{ K *C rC k K .a -r< .0 { .t z z z 5 z 2 2 2 2 2 2 2 2 b Oy Y'.o�95�q��bS 0 3 m n m QN I, 2 SS] ra W C m O z A a 0 ro 0 r- " w 7 tr z m C m m 'm = o n r m ; 0 0 A Page 9 of 10 DC#_Title: ENV-FRM-HUN1-0084 v01_Tech Spec Sample Condition -f ace Upon Receipt i Effective Date: 06/12/2022 *Check mark top half of box if pH and/or dechlorination Project # is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOE, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottles ***Check all unpreserved Nitrates for chlorine WO## : 92639693 PM: AMB Due Date: 12/12/22 CLIENT: 93-ALTAMONT a cEi u Z 41 L1 7 v J E a m Z G1 `1 7 J fNn a m Z 31 W D J E 0 a m Q Z -p N C d a m Y N Q 0 = o E ,,, N m an N 0 S n E o N a m ^ 0 m Z u Q N n E u� '"� a m V rq N 2 () N Z a E yr N ii m C 10 Ur o E a u z N d 0. 6 v *' 7 .i Q' Q d. _ Q v '= 2 w 0 Q z -0 O. C E J E o M (V Q N 0 '� N 61 -a Q +' vt N Q V o N I .A E Q E p 0 m Q �' Y 2 Z .n E 4J E o a O1 to O ¢ .'� * Q p > E 2 T 0 O z 0 N N Z a > E F G� 0 7 Z N Of c Q Q 3 E 'T 7 01 0 7 Z 0 rn Q Q 7 E 'f 7 m (D O IJ ¢ >} E v) G� V' a Z '.+ L7 d `m {S. m 'S x lJ 7 m I f0 N ,n E Ln in a yr m i N �0 61 ° vt E O k4 N a. o m N x V N `—° a E o N pC f/1 a. m — Z W N C a E a J of O > 4 0 Q @ C O C to E O > � in 7 z a Sl C 9 E Q E a m C7 d 1 { l 2 3 4 5 6 7 8 9 10 11 12 I 1_`\NNN I I 1\\\m I ri I I I.- I I pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot # Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Caraiina DEHNn Certnication Office ti.e. Out of hold, incorrect preservative, out of temp, incorrect containers) Qualtrax Document ID: 70677 Page 2 of 2 Page 10 of 10 Attachment 2 Well Sampling Logs and Instrument Calibration Data Sheet ANCHOR 1vcHO 0 Equipment Documentation and Instrument Calibration Data Sheet Project Name: L&S&M&x., p0.ippPys 2,012. E1nY• Com0i61vt"_ Analyst Conducting Calibration: Project Number: _C 2.t ci B 2 - Ot. O 1 Date of Calibration: 1, Project Location: Jr�v� bo mvi %%^r r [f �, Date of Field Measurements: I ( ( L Z Facility ID or Permit # (if applicable): EQUIPMENT DOCUMENTATION Rental sample analysis equipment or meters used to take measurements: E uipment Type Brand Serial Number Date of Use Rental Company 1 Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Select Turbidimeter. Hach 2100Q (s/n 151006045207) Rental Hach 2100Q (s/n Instrument Readings 10 NTU ALI 2 1 O Z (Hach 20 NTU 1111%ts -&5 Cal (NTU): 2100Q) 100 NTU ZI Z3 Of, t 2 Cal (NTU46., 800 NTU III Cal (NTU): 3 Cal Std Information Lot #- Expiration Date: *Pre -Analysis Time: r Result Li: 52 Time: r Time: 0 Time: Calibration Verification: Check (10 NTU): *Post -Analysis Check NTU): Result (NTU): Z Time: r C>-+• �! C Est (10 l . `$ YSI Professional Plus Multiparameter Meter (s/n 18BI01802) Cal Std Information Instrument Readings Date Lot # Opened Exp' Date Dissolved Oxygen Initial (%): Cal (%): �0 + .mHg: Temperature CQ: k Time: 0 • 5 Z- (% saturation) • 09 41 . -_ . tOO t • DO (Site #2, Initial (%): Cal (%): mmHg: Temperature CQ: Time: if applicable) * QC** Check DO Time: r I1L.(DO Result (%): Time: Result (%): Time: Result (%): PH 7 S.U. Initial: G 9 pHmV: — Cal (S.U.): pHmV:: f� -e-V Time: I S so report to 0.1 S.U. • o * 4 • . 10 ! PH 4 S.U. Initial: H.ciq pHmV: Cal (S.U.) pHmV: Time: I,G►:- 10122- report to 0.1 S.U. 14 I11. C,. rj5 Z pH 10 S.U. report to0.7S.U. Initial: lip -ID pHmV: Cal (S.U.): to—O pHmV: "200• Time: W%00 1 CX= 6I,(O 080-1 olt3 QC** pH 7 S.U. Time: 0�:0 Result (S.U.): Time: r C Result (S.U.): Time: Result (S.U.): 2.C7L� tot 2Z OI �2y report to0.1S.U. J Q �1p Spec. Cond. Initial: Cal (pmhos/cm): Time: tl.6cl - II ZZ �'8l2 3 I �� ,,000 pmhos/cm 01 l 3 0 0 l S- 3 % Recove = QC** Spec. Cond. Time: Result (Nmhos/cm): Time: Result (Nmhos/cm): Time: Result (Nmhos/cm): 2 6% ��22 23 1,000 mhos/cm 0 4 : (� 1 00 q [ o p $04 �W % Recovery=1 ORP 200 mV Initial: Cal: 2.00 Temperature CC): Time: Z�l �g�ZZ 03�Z3 Analyst Signature: 0& Analyst Name: Date: Notes: Revision 8, 1/11/22, CAP 1. Instruments shall be calibrated in accordance with the manufacturer's operation manual. 2. Specific Conductivity should be calibrated according to values representative of historic range. 3.Order of Calibration is as follows: Specific Conductivity, PH 7, PH 4, pH 10, DO, ORP, QC checks. 4. *When performing DO analyses at multiple sample sites (i.e. project/facility locations), the DO probe must be calibrated at each sample site prior to analysis. S. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the instrument needs to be recalibrated. 6. ** CC check must be performed prior to sampling and following completion of sampling, at a minimum. QC checks must be performed with calibration standard from a separate lot u as the initial QC. 7. % Recovery = (Value Obtained, pmhos/cm a True Value, pmhos/cm) x 100 8. NC Field Laboratory Certificate Number 5445 Q. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 10. Unless otherwise noted, all DO calibrations and measurements are performed at 0 ppt Salinity. 11. 1 pmho/cm = 1 pS/cm Abbreviations: Method Reference: pmhos/cm: micromhos per centimeter NTU: nephelometric turbidity units Temperature: SM 2550 B-2010 *C: degrees Celsius ORP: oxidation reduction potential Specific conductivity: EPA Method 120.1, Rev. 1982 DO: dissolved oxygen s/n: serial number DO: SM 4500 O G-2011 mg/L milligrams per liter S.U.: standard units pH: SM 4500-H' B-2011 mV: millivolt Spec. Cond.: Specific Conductivity Turbidity: SM 2130 B-2011 J �rl ( 4-1i Z- Page 1 of 1 lizANCHOR QEA Equipment Documentation and Instrument Calibration Data Sheet _ Project Name: — sJ—JftQ- 2tar4p Analyst Conducting Calibration: e, Pµ hle/YD/1 Project Number: `Q/r(Bj -Q/.O/ As�; Date of Calibration: IWS' zt122 Project Location: Aou,,,ta,14 IJUAe r Ale, Date of Field Measurements: Facility ID or Permit # (if applicable): wq ocj) I f 17 EQUIPMENT DOCUMENTATION Rental sample analysis equipment or meters used to take measurements: Equipment Type Brand Serial Number Date of Use Rental Company Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Select Turbidimeter. 10 NTU 2/22 *Pre -Analysis Check (10 NTU): *Post -Analysis Check (10 NTU): Hach 2100Q (s/n 151006045207) Rental Hach 2100Q (s/n ) Instrument Readings (Hach 2100Q) 20 NTU 100 NTU 5 2/23 13123 Cal (NTU): / q , q Cal (NTU). ,� Time: 0. *5 1 Time:0 70 Res uIt(NTU�j): Time: ,�1b -1 . B 2 0-7 41 Result (NTU): Time: 800 NTU A2// 3 Cal (NTU): O� Time: 0 748 7 Cal Std Information Lot#: Expiration Date Calibration Verification: YSI Professional Plus Multiparameter Meter (s/n 1181111011802) Instrument Readings Cal Std Information Lot # Date O ened Exp. ate Dissolved Oxygen (% saturation) Initial M: p R N-e 9 Cal (%): /GO, Q mmHg: GG- Temperature (°C): A 2. 0 Time:_, �� /V) DO (Site #2, if applicable)* Initia Cal % : mmHg: Temperature (°C): Time: CWP /eXa QC"* Check DO Time; 102-1 Result (%): /00.3 Time, r* Result (%): /0 IF,S Time: Result (%): �s PH 7 S.U. report toa1s.U. Initial: �/ T.0 pHmV: � ZS•% Cal (S.U.): �.V pHmV: ZS•Q Time: p 0-128 /isf00� (0////22 �/ C Z3 PH 4 S.U. report to a i s.U. Initial: 4,0 pHmV: /. Cal (S.U.): b � pHmV:: 140, If Time: 0 7 2 16J�04 f 10KNItt I /Z3 PH 10 S.U. report to a i s.U. Initial: 10• pHmV:- M 1 r 200• Cal (S.U.): I , 0 pHmV:�f - —Z00. S Time: 0 � s/ 8/�t'12 91 � 3 QC** pH 7 S.U. report to 0.1 S.U. Time: Result (S.U.): T, Time: 1353 Result (S.U.): �, Time: Result (S.U.): cA3/0 Aiuu�2 112, �,�P /u z Spec. Cond. 1,000 pmhos/cm Initjal�o / !!!! UU /00o ): Q v Tim0-7� 2 26H645 11/4/22 8/23 % Recove = QC** Spec. Cond. 1,000 mhos/cm Time: " o Result(pmhos/cm): t( -L 80 3 Time: {(� / •� I Resultt((�pmmhoos/cm): { 0o Time: Result (pmhos/cm): Z . Z ZGD�OrI �ifQ%M `��23 % Recovery= ORP zoo my®y: ial: 72-5 Cal: d0, (� Temperature (°C): �, Time: Q 4O ~2 1GFN/o 1 $/3p�z2 3�23 Analyst Signature: Analyst Name: C,4r,Sf kl j Pa i�� Date: I 5' 2QZZ Notes: Revision 8, 1/11/22, CAP 1. Instruments shall be calibrated in accordance with the manufacturer's operation manual. 2. Specific Conductivity should be calibrated according to values representative of historic range. 3. Order of Calibration is as follows: Specific Conductivity, PH 7, PH 4, pH 10, DO, ORP, QC checks. 4. *When performing DO analyses at multiple sample sites (i.e. project/facility, locations), the DO probe must be calibrated at each sample site prior to analysis. 5. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the instrument needs to be recalibrated. 6. ** QC check must be performed prior to sampling and following completion of sampling, at a minimum. QC checks must be performed with calibration standard from a separate lot # as the initial QC. 7. % Recovery = (Value Obtained, pmhos/cm a True Value, pmhos/cm) x 100 8. NC Field Laboratory Certificate Number 5445 9. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 10. Unless otherwise noted, all DO calibrations and measurements are performed at 0 ppt Salinity. 11. 1 pmho/cm =_1 pS/cm Abbreviations: Method Reference: pmhos/cm: micromhos per centimeter NTU: nephelometric turbidity units Temperature: SM 2550 B-2010 'C: degrees Celsius ORP: oxidation reduction potential Specific conductivity: EPA Method 120.1, Rev. 1982 DO: dissolved oxygen s/n: serial number DO: SM 4500 0 G-2011 mg/L: milligrams per liter S.U.: standard units PH: SM 4500-H' B-2011 mV: millivolt Spec. Cond.: Specific Conductivity Turbidity: SM 2130 B-2011 Page 1 of 1 Daily Safety Briefing Form Date: Project No: Project Name: t_A S C�) O V �&jQ V n n l[!n ANCHOR .�► QEA Person Conducting Health & Safety Project Meeting: V , V� Officer: '� j S111i j �� Manager: v Q d TOPICS COVERED: Highlighted topics ore required Emergency Procedures and Cl_�ines of Authority 'vacuation Route / ❑J L'J Directions to Hospital Review and Location /iCommunication Ste Security �ASP Q SSafety Equipment Location D Vessel Safety Protocols Safety Equipment Use Work Zones. VPoper mployee Right -to -Know/ Vehicle Safety and Driving/ ,,iDS Location Conditions LT Fire Extinguisher Location _,Road 1:1 EE uipment Safety and Operation C�7'�E e Wash Station Location f�J� Byddy System LT�Proper Use of PPE Procedures I�J' S�f and Coworker Monitoring �—d/decontamination L� Near Miss Reporting Procedures L Field Team Medical Conditions for Emergency Purposes (Confidential): ❑ Other: Weather Conditions: �;� I n t,/ Daily Work Scope: �I i�c Site -specific Hazards: Safety Comments: 1 of 1 1.7 Lifting Techniques 0-"Slips, Trips, and Falls C7�Hazard Exposure Routes ?eat and Cold Stress �verhead and Underfoot Hazards LJ Chemical Hazards ammable Hazards ��B iological Hazards Eating/Drinking/Smoking ❑ Reviewed Prior Lessons Learned Attendees 0 O PLAYING IT SAFE ANCHOR ..., QEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 ir-Flow Sampling Log Pell ip- t , ! f �1 1 t' Project Name: t �SQ YW(/t' a 13 U LkJQ Project Number: -4 2 — 0.01 Project Location: k L( —tic Sample Collector(s):'T04 I V= a Well Diameter: Screen Interval: Well Depth (as constructed): Depth to Water: 7 % Measuring Point: Depth of Pump Intake: 13, Pump Used (circle): aPeristalt' Bladder Comments: } lnAffintty n`VA0x Date: Weather: ►ins, Facility ID or Permit # (if applicable): �/\% y� O Sample ID (on COC): uJ ' _2 U7Z in Arrive at Well: ft bgs Start Time: '. 0 ft bgs Sample Time: 140 ft Leave Well: Well Type: dStick Up ❑flush Mount ft Tagged Bottom: r ' ft at (time): Other (describe): Purge Rate: � \3 Total Volume Purged: Pump Speed: o Time DTW (feet) Temperature (°C) Dissolved Oxygen (mg/L) Specific Conductivity (Nmhos/cm) pH (S.U.) report to 0.1 S.U. Oxidation Reduction Potential (mV) Turbidity (NTU) LA mused i�.2 2. Z(�2. S. g _S • �� r3aSi >sv ri - 202.5 4Z.1.L4 1•il 3 : S'T 205-I S. A1. I�Sy ` a 5 .. 912 6 C« 'ZG Uf L�ycc V. [� ZC -1 [c7 e 2-q . Q 1 3 La IS G 2112,S S. 2_1 I , S 1.11 v L"A- 2-0- Z (� (D - y O - Sample Analyst Signature: Sample Analyst _ ^/ Name: _ 1: i 1 Date: 11 �g f7�Z Notes: 1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity, +/- 3% Conductivity, +/- 0.7 pH unit,' +/- 10 mV for ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017) 2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 3. Samples are analyzed immediately upon collection. 4. NC Field Laboratory Certificate Number 5445 5. 1 pmho/cm = 1 pS/cm Abbreviations: °C: degrees Celsius S.U.: standard units pmhos/cm: micromhos per centimeter ft: feet mg/L: milligrams per liter in: inches mv: millivolt bgs: below ground surface NTU: nephelometric turbidity units TOC: top of casing Method Reference: Temperature: SM 2550 B-2010 Specific conductivity: EPA Method 120.1, Rev. 1982 DO: SM 4500 O G-2011 PH: SM 4500-H' B-2011 Turbidity: SM 2130 B-2011 . Page 1 of 1 ANCHOR +.�► QEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 14low.Sampling Log Well ID: 1 Project Name: Project Number: Project Location: Sample Collector(s): Well Diameter: Screen Interval: Well Depth (as constructed): Depth to Water: Measuring Point: Depth of Pump Intake: Pump Used (circle): Comments: Q / Date: �4 � a� C 2 , (, Weather: t 0h � I Facility ID or Permit # (if applicable): Vr Sample ID (on COC): MW - gi-c?©aD ( 1D in Arrive at Well: ft bgs Start Time: # iq ft bgs Sample Time: ( r �' ft Leave Well: Well Type: Stick Up ❑Flush Mount —� ft Tagged Bottom: , �jvi ft at (time): PeristaIti Bladder Other (describe): Purge Rate: (�� �� ��j� Total Volume Purged: i' t' Pump Speed: 35 435 L Time DTW (feet) Temperature ('Q Dissolved Oxygen (mg/L) Specific Conductivity (pmhos/cm) pH (S.U.) report to 0.1 S.U. Oxidation Reduction Potential (mV) Turbidity (NTU) L a, a3. o, u LP + ( 1 ` I 15 3 , t7l S�s �3a. 3 s , ��+ Sample Analyst Signature: Sample Analyst Name: n Date: ©g 2- Notes: 1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity,' +/- 3% Conductivity, +/- 0.7 pH unit; +/- 10 mV for ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017) 2. Documentation errors are to be crossed out with a single line, so the original tent is still legible, followed by the staff members initials and date 3. Samples are analyzed -immediately upon collection. 4. NC Field Laboratory Certificate Number 5445 5. 1 pmho/cm = 1 pS/cm Abbreviations: Method Reference: °C: degrees Celsius S.U.: standard units Temperature: SM 2550 B-2010 pmhos/cm: micromhos per centimeter ft: feet Specific conductivity: EPA Method 120.1, Rev. 1982 mg/L: milligrams per liter in: inches DO: SM 4500 O G-2011 mv: millivolt bgs: below ground surface pH: SM 4500-H' B-2011 NTU: nephelometric turbidity units TOO top of casing Turbidity: SM 2130 B-2011 Page 1 of 1 ANCHORQEA 2te ill-0 Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 N-Flow Sampling Log Well ID: Project Name: Project Number. Project Location: Sample Collector(s): Well Diameter: Screen Interval: Well Depth (as constructed): Depth to Water: Measuring Point: Depth of Pump Intake: Pump Used (circle): Comments: S, v (\ d C Q U C h 1t O \! 4 � [ C� — I U 0 (0 O C Peristaltic Bladder won r Date: Weather. Facility ID or Permit * (if applicable): Sample ID (on COC): in Arrive at Well: ft bgs Start Time: ft bgs Sample Time: ft Leave Well: Well Type: ft Tagged Bottom: Other (describe): ix, f? _ tn� O V r D 10 — Z Z j Stick Up ❑Flush Mount It at (time): Purge Rate: Total Volume Purged: Pump Speed: a "f \8Nn► 31, Time DTW (feet) Temperature (°C) Dissolved Oxygen (mg/L) Specific Conductivity (pmhos/cm) pH (S.U.) report to 0.1 S.U. Oxidation Reduction Potential (mV) Turbidity (NTU) - z aoGa �.5 s t ' 0 -� '� 13q,q 's 15f !� 1.0 i3 % " G' (11 d 1- r 16. C Sample Analyst Signatu Sample Analyst Name: biffmajDate: Notes: 1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity,- +/- 3% Conductivity, +/- 0.7 pH unit,, +/- 10 mV for ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017) 2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 3. Samples are analyzed immediately upon collection. 4. NC Field Laboratory Certificate Number 5445 5. 1 pmho/cm = 1 pS/cm Abbreviations: Method Reference: 'C: degrees Celsius S.U.: standard units Temperature: SM 2550 B-2010 pmhos/cm: micromhos per centimeter ft: feet Specific conductivity: EPA Method 120.1, Rev. 1982 mg/L: milligrams per liter in: inches DO: SM 4500 O G-2011 mv: millivolt bgs: below ground surface pH: SM 4500-H' B-2011 NTU: nephelometric turbidity units TOC: top of casing Turbidity: SM 2130 B-2011 Page 1 of 1 ANCHOR .ter QEA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 v-Flow Sampling Log Well ID, VNJ (, aa c� Project Name: 4�SDl'V In61 6 Project Number:yZ Project Location: ,I- `j��• �� VI'(, (� �� Sample Collector(s):j Well Diameter. f�_ Screen Interval: �y=� S _ Well Depth (as constructed): Depth to Water: t i, Measuring Point: Depth of Pump Intake: r�L Pump Used (circle): . eristaItic Bladder Comments: �6T �gti�ii�1 VVI Ole). Date: II Weather: W, S S lti�) Facility ID or Permit # (if applicable): _W Q00q 771-0- Sample ID (on COC): &&vj— 4 20 Z-2 11 D in Arrive at Well: _ip 4U ft bgs Start Time: S 3- ft bgs Sample Time: ft Leave Well: Well Type: oStick Up ❑Flush Mount ft Tagged Bottom: ft at (time): Other (describe): Purge Rate: - T� 1()gCl oW Total Volume Purged: Pump Speed: 3 Time DTW (feet) Temperature (°C) Dissolved Oxygen (mg/L) Specific Conductivity (pmhos/cm) pH (S.U.) report to 0.1 S.U. Oxidation Reduction Potential (mV) Turbidity (NTU) Z 1. r S �- q, 9 •Z, l Sample Analyst Signatur��1��1 p666666 e Sample Analyst Name: I"!l/V I Date: i a Notes: 1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity,' +/- 3% Conductivity,' +/- 0.7 pH unit +/- 10 mV for ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017) 2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 3. Samples are analyzed immediately upon collection. 4. NC Field Laboratory Certificate Number 5445 5. 1 pmho/cm = 1 pS/cm Abbreviations: Method Reference: 'C: degrees Celsius S.U.: standard units Temperature: SM 2550 B-2010 pmhos/cm: micromhos per centimeter ft: feet Specific conductivity: EPA Method 120.1, Rev. 1982 mg/L: milligrams per liter in: inches DO: SM 4500 O G-2011 mv: millivolt bgs: below ground surface PH: SM 4500-H' B-2011 NTU: nephelometric turbidity units TOC: top of casing Turbidity: SM 2130 B-2011 ,:�h ho Ioo- or) im • ' Page 1 of 1 �, ye ANCHOR QFA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 -Flow Sampling Log We11ID: '(YMW- 8 Project Name: Lassortcc Pctt?!xu 2o2-2- Env. GYv\3?voLvtcc Date: It 10,9/2-2 _ Project Number: G 21 t{ g 2. ► O 1. O 1 � Weather: 5° Project Location: t�d2 rSanvs 11•e r N G Facility ID or Permit # (if applicable): W 0 (D d)OL41 q"4 Sample Collector(s): ICg SyY•) Sample ID (on COC): of-v - 2 O 11O Well Diameter: Z in Arrive at Well: O8 = 30 Screen Interval: '� - t17� ft bgs Start Time: Well Depth (as constructed): r17� ft.bgs Sample Time: oct 3 Depth to Water. ► O . t ft Leave Well: Measuring Point: -I OC Well Type: Stick Up ❑Flush Mount Depth of Pump Intake: 12- ft Tagged Bottom: 1 5. 9 (0 ft at (time): Pump Used (circle): Peristaltic Bladder Other (describe): Purge Rate: O mL 1rvtiv\ Comments: tit-lytiQ 0S SS Total Volume Purged: Pump Speed: Specific Oxidation Dissolved Oxygen Conductivity pH (S.U.) Reduction Time DTW (feet) Temperature VQ (mg/L) (pmhos/cm) report to 0.1 S.U. Potential (mV) Turbidity (NTU) 6 :58 to. 4 IS-0 3•'04 4(05.} 42S.� o•s �.01 10. 3 15 • S 5- S �• 1 O• lo. 3y Is- 2- 31 •O 3 4 09:04 ko - Ig IS •_4 q 505• 4•3..' 2-z 6 . io 10.3y I 52-9•(P 144 -►3 to.-59 iS• 9 552 32l• (0 2 C9 •O .w3 5:V R 2. boo•(0 Z.o3 04 : t I S 1- L41 5L,09 2 G 2-+. m 1. 2. 5 0a12 10.3 t •o t•t :4- &S -�:- I .43 Oct, ZS X0. 34 1k.0 5 (0.(6 2-4 .5 . 05 Oct' Z5 10.'6 I •O 10 5 s-J - n l•of 61t-31 10. Zq 1(a. 0 n .qr 5'itu z0+• I 3 o =3 )n';4 Ho-0 •0 5 2vIf- 0 o•';v3 09= 0.3 A i1o. I 0 • 1q • 3 Sample Analyst Sample Analyst Signature: Name: (� $ Date: 11,1Qt,5 1Z•'L Notes: 1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity,' +/- 3% Conductivity, +/- 0A pH unit, +/- 10 mV for ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017) 2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 3. Samples are analyzed immediately upon collection. 4. NC Field Laboratory Certificate Number 5445 5. 1 pmho/cm = 1 PS/cm Abbreviations: °C: degrees Celsius S.U.: standard units pmhos/cm: micromhos per centimeter ft: feet mg/L: milligrams per liter in: inches mv: millivolt bgs: below ground surface NTU: nephelometric turbidity units TOC: top of casing Method Reference: Temperature: SM 2550 B-2010 Specific conductivity: EPA Method 120.1, Rev. 1982 DO: SM 4500 O G-2011 pH: SM 4500-H' B-2011 Turbidity: SM 2130 B-2011 Page 1 of 1 ANCHOR QEA. Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 i-Flow Sampling Log Well ID: mw- Project Name: Us6oyxcko Nov W Q YY%n0p" Date: ,t I o$ M7_ Project Number: C 21 4 18'2_ - 0 1 . 1 Weather: t7 S �h Project Location: k' to- 1'l C. Facility ID or Permit # (if applicable): Q 0 'i Sample Collector(s): K�j r �m Sample ID (on COQ: w- 0 01-12p2211 O 5 Well Diameter: 2• in Arrive at Well: Screen Interval: S - 13 ft bgs StartTime: I •, c.1-- Well Depth (as constructed): 13 ft.bgs Sample Time: 17 -.1 O Depth to Water: 5.90 ft Leave Well: Measuring Point: TDC Well Type: wick Up ❑Flush Mount Depth of Pump Intake: I Z ft Tagged Bottom: I 's • 0 9 ft at (time): 11. 3S Pump Used (circle): Peristalti Bladder Other (describe): Purge Rate: 1 bo A%Q y.,'{ Comments: Dtx�� ov" _z �l : 4 5 Total Volume Purged: Pump Speed: Specific Oxidation Dissolved Oxygen Conductivity pH (S.U.) Reduction Time DTW (feet) Temperature (°C) (mg/L) (Nmhos/cm) report to 0.1 S.U. Potential (mW Turbidity (NTU) III LA_+ .1 9 tQ•2 'Z.0 S 202. S. 2 L42.4.5 t2• 1'• 50 .2R t .3 I.So 2• S•2. 39 3 2 1$•2 t.`g 1q4.0 5.2 3T+. 8 Co .a� 1 • 5 3 Ltf�•2 2.3(0 15 .9 3�9.9- S•o 11 - S9 M1 .S9 1'12. S•3 353•-+ 3-3 12;0'3� 18.3 2.12 130.2 S-S 299.2 3•(03 12 :0 S 1 .3 1.25 10 . _+ S•`F 25-4.0 g. to t :0 3 t 0•8 d2- 13 5.2 240•S 8.35 2: 1 is. 3 0• tc�o 5.3 2--Y2 2:14 1 b.(03 CVB .4 S.S 2 2 .2 .S4 2 1-4 (0.3 L19.4o 0.(01 r't • 5.3 2.1(0• 0 S. 33 '• 2c� O.S15 q rg .2 3 211 `4 5• a 1 Sample Analyst Signature: Sample Analyst Name: �• MC+ Date: Notes: 1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity,' +/- 3% Conductivity' +/- 0.1 pH unit +/- 10 mV for ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017) 2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date 3. Samples are analyzed immediately upon collection. 4. NC Field Laboratory Certificate Number 5445 S. 1 pmho/cm = 1 pS/cm Abbreviations: Method Reference: 'C: degrees Celsius S.U: standard units Temperature: SM 2550 B-2010 pmhos/cm: micromhos per centimeter ft: feet Specific conductivity: EPA Method 120.1, Rev. 1982 mg/L: milligrams per liter in: inches DO: SM 4500 O G-2011 mv: millivolt bgs: below ground surface pH: SM 4500-H' B-2011 NTU: nephelometric turbidity units TOC: top of casing Turbidity: SM 2130 B-2011 Page 1 of 1 ANCHOR .�► Q EA Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Surface Water Sampling Log Location ID: SF ) " 1 Project Name: L.)dh� e N 0V WO MOh . Date: 1 Project Number: �� (l,F — Q j Weather: S Project Location: L�-f`� d_�� . VNii acility ID or Permit # (if applicable): �J 21.� Sample Collector(s): Sample ID (on COC): Comments: Sample Method (circle Grab Syringe Pump Bailer-Disp. Other: one): Specific Oxidation Temperature Dissolved Conductivity pH (S.U.) Reduction Turbidity Time VC) Oxygen (mg/L) (pmhos/cm) report to 0.1 S.U. Potential (mV) (NTU) Comments tw.$ -4.0 Sampling Container Number of Containers Requested Analysis 500 mL Plastic 2 17DS 250 mL Plastic L a -r-e 119 125 mL Plastic h I G 40 mL Glass Ty C I L Glass Other Vegetation: u2 mt acCe'S93W t Access: olu drl!4 t beae Sample Analyst Sample Analyst Signatur . Name: Y— f> Date: ZZ Notes: 1. Documentation errors are to be crossed out with a sinale line, so the oriainal text is still leaible, followed by the staff members initials and date 2. Samples are analyzed immediately upon collection. 3. NC Field Laboratory Certificate Number 5445 Abbreviations: °C: degrees Celsius pmhos/cm: micromhos per centimeter mg/L: milligrams per liter mv: millivolt NTU: nephelometric turbidity units S.U.: standard units Method Reference: Temperature: SM 2550 B-2010 Specific conductivity: EPA Method 120.1, Rev. 1982 DO: SM 4500 O G-2011 pH: SM 4500-H' B-2011 Turbiditv: SM 2130 B-2011 Page 1 of 1 ANCHOR QEA` 4—' Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 iurface Water Sampling Log Location ID: 2 Project Name: V AWDHU 6 , Date: 1 " 22 Project Number: C Z � -L—b' d ! Weather: of &vn n Project Location: [A V i G Facility ID or Permit # (if applicable): Sample Collector(s): Sample ID (on COC): SWI2 Comments: Sample Method (circle Grab Syringe Pump Bailer-Disp. Other: one): Specific Oxidation Temperature Dissolved Conductivity pH (S.U.) Reduction Turbidity Time (°C) Oxygen (mg/L) (pmhos/cm) report to 0.1 S.U. Potential (mV) (NTU) Comments icon Sampling Container Number of Containers Requested Analysis 500 mL Plastic s Z 250 mL Plastic 125 mL Plastic 2 i 40 mL Glass 1 L Glass Other Vegetation: Access:_p()-# [z,� Sample Analyst �* Sample Analyst Signature: %/� Name: Date: Notes: 1. Documentation errors are to be crossed out with a sinale line, so the oriainal text is still legible, followed by the staff members initials and date 2. Samples are analyzed immediately upon collection. 3. NC Field Laboratory Certificate Number 5445 Abbreviations: Method Reference: °C: degrees Celsius Temperature: SM 2550 B-2010 pmhos/cm: micromhos per centimeter Specific conductivity: EPA Method 1201, Rev. 1982 mg/L: milligrams per liter DO: SM 4500 O G-2011 mv: millivolt pH: SM 4500-H' B-2011 NTU: nephelometric turbidity units Turbiditv: SM 2130 B-2011 S.U.: standard units A Ask OW +ro Y t C OLVE S` 0U- e Page 1 of 1 Okz,ANCHOR QEA`'`.6.' 4r6rV Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Low -Flow Sampling Log Well ID: Project Name: Project Number: Project Location: Sample Collector(s): Well Diameter. Screen Interval: Well Depth (as constructed): Depth to Water: Measuring Point: Depth of Pump Intake: Pump Used (circle): Comments: Lases 1 %Apt CZl'�Z—"-0/H• d / %dwl1P/nA114�� P<! k"3V S _ to p .r.,-; FQC 9 Peristaltic _ �/C Bladder djo Date: S 22 Weather. gzJ 0 Facility ID or Permit # (if applicable): Sample ID (on COC): _ — d2Z 20 in Arrive at Well: / QQ oo ft bgs Start Time: / ft bgs Sample Time: 1 / ft Leave Well: 125 Well Type: wick Up ❑Flush Mount ft Tagged Bottom: ft at (time): Other (describe): Purge Rate: A/ Total Volume Purged: Pump Speed: ,4ec In t QQ '`rL Mil 4 000114L, 3. 2 Ha Time DTW (feet) Temperature CQ Dissolved oxygen (mg/L) Specific Conductivity (pmhos/cm) pH (S.U.) report to 0.1 S.U. Oxidation Reduction Potential (mV) Turbidity (NTU) 5,90 ! .3 1, 9 2. . 313. 3._5-3 0 *t S. R ✓/. / 71.3 Z 05. y- 2.. ✓ S. CY0 10.q Z.2 5.1 217. o 2 5.,76 r . /. 2 / 5• 0.6 /,L IQ 5 .90 11. /.2 3 /6 .35.3 z86. . /a . q0 I/.q 5.3 2$q;8 LIC / .s.Rd U.1 90.3 5.3 232 if f. . ✓ 5 W- 2 1,011 /5 , • 3 �Zll 2 /. #3 S.qa IL 2 /, . 1 f. 29 2 4155.0 5.3 235. R 1. Sample Analyst Signature: Sample Analyst Name: C'h,-, st a,1 pQ i-A Join Date: 19N40 ZZ Notes: 1: Stabilization (3 successive readings, 3 minutes apart): within ./ 10% DO and turbidity, +/- 3% Conductivity; +/- 0.1 pH unit; +/- 10 mV for ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017: 2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff member's initials and date 3. Samples are analyzed immediately upon collection. 4. NC Field Laboratory Certificate Number 5445 5.1 pmho/cm = 1 pS/cm Abbreviations: 'C: degrees Celsius S.U.: standard units pmhos/cm: micromhos per centimeter ft: feet mg/L: milligrams per liter in: inches mv: millivolt bgs: below ground surface NTU: nephelometric turbidity units TOO top of casing Method Reference: Temperature: SM 2550 B-2010 Specific conductivity: EPA Method 120.1, Rev. 1982 DO: SM 4500 O G-2016 PH: SM 4500-H' B-2011 Turbidity: SM 2130 B-2011 Page 1 of 1 CHAIN -OF -CUSTODY / Analytical Request Document Face, The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. I Submittino a sample via this chain of custodv constitutes acknowledoment and arreotance of the Pace Terms and Conditions found at hfos://info.Dacelabs.com/hubfs/oas-standard-terms.t)df. tion A Section B Section C r uired Client Information: Required Project Information: Invoice Information: Page - 1 Of 1 ipany: ANCHOR QEA OF NC, PLLC eportTo: ChuckYjPpiD_ " i Milf ttention: ress: 231 Haywood Street opy To: ompany Name: eville, NC 2BB01 ddress: [roject Regui twy Agency Iil: urchase Order #: ace Quote: [ace ne: (628)707-5827 Fax: roject Name: Lassonde Pappas ace Project Manager: lorri.patton@pacelabs.com, State LLoclwe t uested Due Date: #: Profile #: 8114 NC Requested An& sE-6J1ti6Ct(n' g O COLLECTED Preservatives MATRIX CODE Dtinking Water OW c V O Water Wi m U D Waste Water WW SAMPLE ID Froduat P SolllSolid - SL , a 0 OU �(A 8t., w L y t Z } on oL .-. O V START END F 0 2 a One Character per box. Wipe WP Air AR w w ¢ a w Z m. E m o m O `o (A-Z, 0-9 /, -) Other OT 0 a F m a O ~ S N Y U {t Sample Ida must be unique Tissue TS U W Z N O o O m c Z a cc ii j a a 0 m0 = m rn t m L' m `o E m O O m v V < ¢ DATE TIME DATE TIME ¢ m 0 ac c N = z 2 U 2 z m z m O <L s U¢ E -- 'z F F > It- D I MW-4 Zl `�V IAd X X X X X X X 2 MW-5 l Vl�'«Vd� 1j52 X X X X X X X b1, o$ 3 MW-6 - Zo W 1:11 X X X X X X X n U o� 4 MW-7R _ 10 W V X X X X X X X 5 MW-8 - 70V 11V6 VVI Oq.M X X Ix X X X X ®46, ttlgl2 6 MW-9 — µZ t Vill Z X X X X X IX X 11 T Sw-12U105 WT ISI x. x x x x x G ti�22� 1 1 bib 1 a SW-2 W i� X X X X X X �V a Trip Blank 1 . (.v2mZ VWT bDM X Zt/ 0 Trip Blank 2 v�' X 7 2 ADDITIONS{. C*M&WWS fiELINQUISHED BY I AFRUATION i wx TIME ACCEPTS BY AFFILIA'nON DATE TINE SAMPLE CONDtTiONS SAMPLEIR NA4E AND 91GNATURE U N U o a c , m PRINT Name of SAMPLER: a i ' z w} o 6.-. H o z E z N} SIGNATURE of SAMPLER: DATE Signed: ` \^ Fw UVY Chi CHAIN -OF -CUSTODY Analytical Request, DOCument PaceAnalytical Chain -of -Custody is a LEGAL DOCUMENT - Complete all relevent fields LAB USE ONLY- Affix Workorder/Login Label Here or List Pace Workorder Number or MTJL Log -in Number Here ALL SHADED AREAS are for LAB USE ONLY Company: Anc{I r !.: PLICr�E Billing Information: Address:.,,._ .".ail i1C 2i;0 Container Preservative Type ** Lab Project Manager: Report To: i . f 7 L/_aUl1 '' )all orfq , {^4 EmailTo: //4.. 4.., ** Preservative Types: (1) nitric acid, (2) sulfuric acid, (3) hydrochloric acid, (4) sodium hydroxide, (5) zinc acetate, (6) methanol, (7) sodium bisulfate, (8) sodium thiosulfate, (9) hexane, JAI ascorbic acid, (B) ammonium sulfate, (C) ammonium hydroxide, (D) TSP, (U) Unpreserved, (0) Other Copy To: Verde� Site Collection Info/Address: Analyses lab Profile/line: Customer Project Name/Number: � 2 ` CJ l . ! fS State, County/City: Time Zone Collected:. , /gie � �lc�l .;:an [ ] PT [ ]. MT [ ] CT [VIET Lab Sample Receipt Checklist: Custody Seals Present/Intact Y N NA Custody Signatures Present Y N NA Collector Signature Present Y N NA Bottles Intact Y N NA Correct Bottles Y N NA Phone: yl < `< t H 4{11i't Email: Site/Facility ID #: - - - Compliance Monitoring? ['vrYes [ ] No Collected By (print): Purchase Order #: DW PWS ID #: ^ I �lr _�., T.�^ ],� f ,`t ! L 1 Quote #: DW Location Code: - Sufficient Volume Y N NA Samples Received on Ice Y N NA VOA - Headspace Acceptable Y N NA USDA Regulated Soils Y N NA Samples in Holding Time Y N NA Residual Chlorine Present Y N NA Collected By (signature): Turnaround Date Required: e ,.J,. r "' Immediately Packed on Ice: [ V']_ Yes , [ . ] No Sample Disposal: Rush: Field Filtered (if applicable): [VI Dispose as appropriate [ ] Return [ ]Archive: [ ) Hold: [ ] Same bay [ ] Next Day ( ] 2 Day { }3 Day { ] 4 Day [ J S Day (Expedite Charges Aply) p [ ] Yes [v]'No Analysis: Cl Strips: Sample pH Acceptable Y N NA pH Strips: Sulfide Present Y N NA Lead Acetate Strips: _ *Matrix Codes (Insert in. Matrix box below): Drinking Water'(DW), Ground Water (GW), Wastewater (WW), Product (P), Soil/Solid (SL), Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Bioassay (B), Vapor (V), Other (OT) LAB USE ONLY: Lab Sample # / Comments: Customer Sample ID Matrix * Comp / Grab Collected (or Composite Start) Composite End Res Cl # of Ctns Date Time Date Time Customer Remarks / Special Conditions / Possible Hazards: Type of Ice Used: Wet ` Blue Dry None SHORT HOLDS PRESENT (<72 hours): Y N N/A Lab Sample Temperature Info: Packing Material Used: Lab Tracking #: '7 Temp Blank Received: Y N NA Therm ID#: 2 Cooler 1 Temp Upon Receipt: oC Samples received via Radchem sample(s) screened (<500 cpm): Y N NA FEDEX UPS Client Courier Pace Courier Cooler 1 Therm Corr. Factor: oc Cooler 1 Corrected Temp: oC Relinquished by/Company: (Signature) Date/Time: Received by/Company: (Signature) Date/Time: MTJL LAB USE ONLY Comments: % , J # 2 4 L _ Table M f /`� // r %1uc., IA1.6 17 Acctnum- Relinquished by/Company: (Signature) Date/Time: Received by/Company: (Signature) Date/Time: Template. Trip Blank Received- Y N NA Prelogin: HCL McOH TSP Other Relinquished by/Company: (Signature) Date/Time: Received by/Company: (Signature) Date/Time: PM: IPB: Non Conformance(s): Page: YES / NO of: Attachment 3 DEQ GW-59A — Compliance Report Form SUBMIT FORM ON YELLOW PAPER ONLY • • DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2026 Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC Permit Name (if different): NPDES Other Facility Address: 485 Brookside Camp Road TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville NC 28792 County Henderson ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑■ Spray Field ❑ Remediation: Contact Person: Blake Kehoe Telephone#: (828) 693-0711 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: (from Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW-4 Date sample collected: 11/8/2022 FIELD ANALYSES: WAS Well Depth: 18.22 ft. Well Diameter: 2 in. pH 00400: 5.8 units Temp. 000lo: 17.4 °C DRY at Depth to Water Level 82546: 9.35 ft. below measuring point Screened Interval: 5 ft. to 15 ft. Spec. Cond. 00094: 212.0 µMhos time of sampling, Measuring Point is 2.43 ft. above land surface Relative M.P. Elevation: 2063.77 ft. Odor 00085: none check Volume of water pumped/bailed before sampling: 0.97 gallons Appearance here:❑ Samples for metals were collected unfiltered: ❑■ YES ❑ NO and field acidified: ❑■ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 11/9/2022 Laboratory Name: Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NOz) as N 00615 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 <1.0 /100mL Nitrate (1103) as N 00620 0.090 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 <0.050 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 137 mg/L Al -Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC oo68o 3.2 mg/L Ca - Calcium oo916 mg/L Chloride 00940 10.3 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia oo6lo <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Blake Kehoe, Director Engineering Permittee (or Authorized Agent) Name and Title - Please print or type Signature of Permittee (or Authorized Agent) (Date) GW-59 Rev.06-07-2018 SUBMIT FORM ON YELLOW PAPER ONLY • • DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2026 Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC Permit Name (if different): NPDES Other Facility Address: 485 Brookside Camp Road TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville NC 28792 County Henderson ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑■ Spray Field ❑ Remediation: Contact Person: Blake Kehoe Telephone#: (828) 693-0711 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: (from Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW-5 Date sample collected: 11/8/2022 FIELD ANALYSES: WAS Well Depth: 18.59 ft. Well Diameter: 2 in. pH 00400: 5.5 units Temp. 000lo: 17.5 °C DRY at Depth to Water Level 82546: 10.07 ft. below measuring point Screened Interval: 9 ft. to 19 ft. Spec. Cond. 00094: 221.9 µMhos time of sampling, Measuring Point is 3.00 ft. above land surface Relative M.P. Elevation: 2085.60 ft. Odor 00085: none check Volume of water pumped/bailed before sampling: 0.83 gallons Appearance here:❑ Samples for metals were collected unfiltered: ❑■ YES ❑ NO and field acidified: ❑■ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 11/9/2022 Laboratory Name: Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NOz) as N 00615 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 <1.0 /100mL Nitrate (1103) as N 00620 <0.040 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 <0.050 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 132 mg/L Al -Aluminum 01105 mg/L Tetrachloroethene - 152.0 pg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L Trichloroethene - 75.1 pg/L TOC 00680 2.3 mg/L Ca - Calcium oo916 mg/L Cis-1,2-dichloroethene - 96.5 pg/L Chloride 00940 51.4 mg/L Cd - Cadmium 01027 ug/L Vinyl chloride - 1.1 pg/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L *Note MW-5 is background well so from unknown off -site source Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia oo6lo <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Blake Kehoe, Director Engineering Permittee (or Authorized Agent) Name and Title - Please print or type Signature of Permittee (or Authorized Agent) (Date) GW-59 Rev.06-07-2018 SUBMIT FORM ON YELLOW PAPER ONLY • • DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2026 Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC Permit Name (if different): NPDES Other Facility Address: 485 Brookside Camp Road TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville NC 28792 County Henderson ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑■ Spray Field ❑ Remediation: Contact Person: Blake Kehoe Telephone#: (828) 693-0711 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: (from Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW-6 Date sample collected: 11/9/2022 FIELD ANALYSES: WAS Well Depth: 11.59 ft. Well Diameter: 2 in. pH 00400: 5.4 units Temp. 000lo: 18.0 °C DRY at Depth to Water Level 82546: 6.40 ft. below measuring point Screened Interval: 5 ft. to 10 ft. Spec. Cond. 00094: 140.0 µMhos time of sampling, Measuring Point is 3.00 ft. above land surface Relative M.P. Elevation: 2061.17 ft. Odor 00085: none check Volume of water pumped/bailed before sampling: 0.73 gallons Appearance here:❑ Samples for metals were collected unfiltered: ❑■ YES ❑ NO and field acidified: ❑■ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 11/9/2022 Laboratory Name: Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NOz) as N 00615 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 164.0 /100mL Nitrate (1103) as N 00620 0.40 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 <0.050 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 85.0 mg/L Al -Aluminum 01105 mg/L Constituent resampled on 12/5 due to suspected lab error pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 2.0 mg/L Ca - Calcium oo916 mg/L Chloride 00940 9.5 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia oo6lo <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Blake Kehoe, Director Engineering Permittee (or Authorized Agent) Name and Title - Please print or type Signature of Permittee (or Authorized Agent) (Date) GW-59 Rev.06-07-2018 SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2026 Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC Permit Name (if different): NPDES Other Facility Address: 485 Brookside Camp Road TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville (Street) NC 28792 CountyHenderson El Lagoon ❑Remediation: Infiltration Gallery (City) (State) (zip) Spray Field ❑Remediation: Contact Person: Blake Kehoe Telephone#: (828) 693-0711 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 from Permit ❑ Water Source Heat Pump ❑ Other: SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW-6 Date sample collected: 12/5/2022 FIELD ANALYSES: WAS Well Depth: hVa ft. Well Diameter: 2 in. pH ooaoo: 5.3 units Temp. 000lo: 11.2 -C DRY at Depth to Water Level 82546: 5.78 ft. below measuring point Screened Interval: 5 ft. to 10 ft. Spec. Cond. 00094: 155.0 µMhos time ofsampling, Measuring Point is 3.00 ft. above land surface Relative M.P. Elevation: 2061.17 ft. Odor 00085: none check Volume of water pumped/bailed before sampling: 0.71 gallons Appearance here: Samples for metals were collected unfiltered: A YES ❑ NO and field acidified: R YES ❑ NO LABORATORY INFORMATION Date sample analyzed:121612022 Laboratory Name: Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 12.0 /100mL Nitrate (NO3) as N 00620 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 mg/L (Nate: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved SOlids:Total 70300 mg/L Al -Aluminum ollo5 mg/L Note: Resample/reanalysis on 12/5 performed due to previous pH (Lab) 00403 units Ba - Barium 01007 ug/L suspected lab error TOC 00680 mg/L Ca - Calcium oo916 mg/L Chloride 00940 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? M Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal Anthony Aponte, Plant Manager Permittee (or Authorized Agent) Name and Title - Please print or type Signature of Permittee (or Authorized Agent) (Date) GW-59 Rev.06-07-2018 SUBMIT FORM ON YELLOW PAPER ONLY • • DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2026 Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC Permit Name (if different): NPDES Other Facility Address: 485 Brookside Camp Road TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville NC 28792 County Henderson ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑■ Spray Field ❑ Remediation: Contact Person: Blake Kehoe Telephone#: (828) 693-0711 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation AreaO No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: (from Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW-7R Date sample collected: 11/8/2022 FIELD ANALYSES: WAS Well Depth: 17.44 ft. Well Diameter: 2 in. pH 00400: 4.9 units Temp. 000lo: 16.8 °C DRY at Depth to Water Level 82546: 11.80 ft. below measuring point Screened Interval: 5 ft. to 15 ft. Spec. Cond. 00094: 365.7 µMhos time of sampling, Measuring Point is 3.00 ft. above land surface Relative M.P. Elevation: 2062.86 ft. Odor 00085: none check Volume of water pumped/bailed before sampling: 0.36 gallons Appearance here:❑ Samples for metals were collected unfiltered: ❑■ YES ❑ NO and field acidified: ❑■ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 11/9/2022 Laboratory Name: Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NOz) as N 00615 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 <1.0 /100mL Nitrate (NO3) as N 00620 24.2 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 <0.050 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 225 mg/L Al -Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC o0680 1.0 mg/L Ca - Calcium o0916 mg/L Chloride 00940 31.4 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia o0610 <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Blake Kehoe, Director Engineering Permittee (or Authorized Agent) Name and Title - Please print or type Signature of Permittee (or Authorized Agent) (Date) GW-59 Rev.06-07-2018 SUBMIT FORM ON YELLOW PAPER ONLY • • DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2026 Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC Permit Name (if different): NPDES Other Facility Address: 485 Brookside Camp Road TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville NC 28792 County Henderson ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑■ Spray Field ❑ Remediation: Contact Person: Blake Kehoe Telephone#: (828) 693-0711 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: (from Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW-8 Date sample collected: 11/8/2022 FIELD ANALYSES: WAS Well Depth: 13.96 ft. Well Diameter: 2 in. pH 00400: 6.6 units Temp. 000lo: 16.1 °C DRY at Depth to Water Level 82546: 10.31 ft. below measuring point Screened Interval: 3 ft. to 13 ft. Spec. Cond. 00094: 577.7 µMhos time of sampling, Measuring Point is 3.00 ft. above land surface Relative M.P. Elevation: 2060.80 ft. Odor 00085: none check Volume of water pumped/bailed before sampling: 1.3 gallons Appearance here:❑ Samples for metals were collected unfiltered: ❑■ YES ❑ NO and field acidified: ❑■ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 11/9/2021 Laboratory Name: Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NOz) as N 00615 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 <1.0 /100mL Nitrate (1103) as N 00620 1.4 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 <0.050 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 703oo 328 mg/L Al -Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC oo68o 6.2 mg/L Ca - Calcium oo916 mg/L Chloride 00940 12.2 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia oo6lo <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Blake Kehoe, Director Engineering Permittee (or Authorized Agent) Name and Title - Please print or type Signature of Permittee (or Authorized Agent) (Date) GW-59 Rev.06-07-2018 SUBMIT FORM ON YELLOW PAPER ONLY • • DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2026 Facility Name: Clement Pappas Non -Discharge WQ0004797 UIC Permit Name (if different): NPDES Other Facility Address: 485 Brookside Camp Road TYPE OF PERMITTED OPERATION BEING MONITORED Hendersonville NC 28792 County Henderson ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑■ Spray Field ❑ Remediation: Contact Person: Blake Kehoe Telephone#: (828) 693-0711 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other: (from Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW-9 Date sample collected: 11/8/2022 FIELD ANALYSES: WAS Well Depth: 18.09 ft. Well Diameter: 2 in. pH 00400: 5.3 units Temp. 000lo: 18.2 °C DRY at Depth to Water Level 82546: 5.90 ft. below measuring point Screened Interval: 6 ft. to 16 ft. Spec. Cond. 00094: 98.2 µMhos time of sampling, Measuring Point is 1.44 ft. above land surface Relative M.P. Elevation: 2060.23 ft. Odor 00085: none check Volume of water pumped/bailed before sampling: 1.4 gallons Appearance here:❑ Samples for metals were collected unfiltered: ❑■ YES ❑ NO and field acidified: ❑■ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 11/9/2022 Laboratory Name: Pace Analytical Services Certification No. 37712 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NOz) as N 00615 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 <1.0 /100mL Nitrate (1103) as N 00620 1.9 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 <0.050 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 81.0 mg/L Al -Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 2.8 mg/L Ca - Calcium oo916 mg/L Chloride 0094o 8.7 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia oo6lo 0.17 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Blake Kehoe, Director Engineering Permittee (or Authorized Agent) Name and Title - Please print or type Signature of Permittee (or Authorized Agent) (Date) GW-59 Rev.06-07-2018 Attachment 4 DEQ GW-59 — Groundwater Quality Monitoring: Compliance Report Forms GW-59A COMPLIANCE REPORT FORM Permit # (Submit one each monitoring period with GI1'-59 fornis.) 1 Enter date monitoring results were due. ( ) Will this monitoring report (GW-59 and GW-59A) YES NO be submitted after the established due date? 2 Was any required information missing on the GW-59 report forms? YES NO IF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES NO identification plate, area overgrown, etc.)? If the ansiver is " 3 es ", contact the Regional Office for guidance. 4 Are any monitored constituents equal to or above the established standards? YES NO If the answer to question 4 is "NO", skip to section 8. If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s) exceeding standards in the space provided below: 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO same constituent(s) in the same well(s) in the last two years? If the answer to question 5 is "NO", skip to section 8. If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding standards, concentrations) reported, and sample collection date for each occurrence (for the last two years). 6 Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES NO If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly located; contact the Regional Office. 7 Is the permittee implementing previously approved actions required by the Division involving this YES NO groundwater quality problem? If the answer to question 7 is "YES", describe those actions in the space provided below. If the answer to question 7 is "NO", contact the Regional Office within 90 days; an evaluation may be required to determine the impact the waste disposal system is having at the review and compliance boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation, fines, and/or penalties. 8 The person completing this portion (GW-59A) of the monitoring report should sign below and submit this form with G W-59 forms for required wells to the address provided at the top of the current G W-59 form. I hereby acknowledge that the above information was evaluated and the information submitted in this report (Compliance Report GW-59A) is true and complete to the best of my knowledge. Signature of Permittee (or Authorized Agent) Date GR'-59A 12/8/2003