WQ0004797_Groundwater Moniotring Report November 2023_20231221

Monitoring Report Submittal
........ ......... ......... ......... .........
Permit Number#* WQ0004797
Name of Facility:*
Month: * November
Report Information
Type *
GW-59
Confirmation Email Address:
Name of Submitter: *
Signature:
Date of submittal:
Initial Review
Reviewer:
Clement Pappas NC LLC
Year:* 2023
Upload Document*
Signed GW 59's.pdf 994.46KB
PDF Only
Please upload one PDF containing all applicable monitoring reports
(i.e., NDMR, NDAR-1, NDAR-2, NDMLR, GW-59).
[e-mail]
Dale I Wolfe
Wanda.Gerald
12/21 /2023
This will be filled in automatically

Is the project number correct?* W00004797
Is the monitoring report accepted?* Yes NO
Regional Office* Asheville
Reviewer: _anonymous
Review Date: 1/9/2024

SUBMIT FORM ON YELLOW PAPER ONLY
ME=
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, INC 27899.1677
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date: 7/3112026
Facility Name: Clement Pappas
Non -Discharge W00004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp Road
TYPE OF PERMITTED OPERATION BEING MONITORED
"=fee1i
Hendersonville NC
28792 County Henderson
❑ La goon 0 Remediation: Infiltration Gallery
N Spray Field ❑ Remediation:
Contact Person: James Frazier
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled:
6
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-4
Date sample collected: 11/8/2023
FIELD ANALYSES:
WAS
Well Depth 18.23 ft_
Well Diameter: 2
in.
pH oo400: 5.7 units Temp. 000lo: 17.3 °C
DRY at
time ofsampling,
Depth to Water Level 82546: 9.88 ft. below measuring point Screened Interval: 5
ft. to 15
ft. Spec. Cond. 00094: 179.8 µMhos
Measuring Point is 2.43 ft. above land surface
Relative M.P. Elevation: 2063.77 ft.
Odor 00085: none
check
Volume of water pumped/bailed before sampling:
2.25
gallons
Appearance
here:❑
Samples for metals were collected unfiltered: A YES
❑ NO and field acidified: © YES
❑ NO
LABORATORY INFORMATION
Date sample analyzed: 11/8/2023
Laboratory Name: Pace Analytical Services
Certification No. 37712
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615
mg1L Pb - Lead oio51 ug/L
Coliform: MF Fecal 31616 <1.0
/100mL
Nitrate (NO3) as N 00620 <0.040
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665 <0.050
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L
Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 121
mg/L
Al -Aluminum o11o5
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC 0068o 2.9
mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 13.1
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L
ORGANICS: (by GC; GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? C1 Yes (1) ❑ No (0)
pecific Conductance 00095
µMhos
K - Potassium 00937
mg/L
VOC 7873 method #
Total Ammonia 00610 <0.10
mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
method #
TKN as N 00625
mg/L
Ni - Nickel o1o67
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOG Removal%
James Frazier, Plant Manager
Permittee (or Authorized Agent) Name and Title - Please print or type
Z3
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date: 7/31/2026
Facility Name: 'Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp Road
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
Hendersonville NC 28792 County Henderson
© Spray Field ❑ Remediation:
Contact Person: James Frazier
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
� fr�,m
Penn t
SAMPLING INFORMATION
if WELL
WELL ID NUMBER (from Permit): MW-5
Date sample collected: 11/9/2023
FIELD ANALYSES:
WAS
Well Depth: 18.56 ft.
Well Diameter: 2 in.
pH 00400: 5.5 units Temp. 000lo: 17.7 °C
DRY at
Depth to Water Level 82546:10.90 ft. below measuring point Screened Interval: 9 ft.
to 19
ft Spec. Cond. 00094: 208.6 µMhos
time of
sampling,
Measuring Point is 3.00 ft. above land surface
Relative M.P. Elevation: 2085.60
ft.
Odor 00085: none
check
Volume of water pumped/bailed before sampling:
2•31
gallons
Appearance
here- El
Samples for metals were collected unfiltered: C1 YES
❑ NO and field acidified * YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed. 111912023
Laboratory Name: Pace Analytical Services
Certification No. 37712
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N oo615
mg/L
Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 <1.0
/100mL
Nitrate (NO3) as N 00620 0.066
mg/L
Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665 <0.050
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L
Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 125.0
mg/L
Al - Aluminum 01105
mg/L
Tetrachloroethene -169.0 pg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
Trichloroethene - 155.0 lig/L
TOC 00680 1.8
mg/L
Ca - Calcium 00916
mg/L
Cis-1,2-dichloroethene - 111.0 pg/L
Chloride 0094o 47.2
mg/L
Cd - Cadmium 01027
ug/L
Vinyl chloride -1.3 µg/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
'Note MW-5 is background well so from unknown off -site source
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L
ORGANICS: (by GC, GCIMS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? Ol Yes (1) ❑ No (0)
pecific Conductance 00095
µMhos
K - Potassium 00937
mg/L
VOC 7873 method # SM 6200B
Total Ammonia o0610 <0.10
mg/L
Mg - Magnesium oo927
mg/L
method #
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
James Frazier, Plant Manager
Permittee (or Authorized Agent) Name and Title - Please print or type
ittee
5
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
• •
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
• •
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date: 7/31/2026
Facility Name: Clement Pappas
Nan -Discharge VV00004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC
28792 County Henderson
❑ Lagoon ❑ Remediation: Infiltration Gallery
� Spray Field El Remediation:
Contact Person: James Frazier
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
(from Pam-d)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-6
Date sample collected: 11/8/2023
FIELD ANALYSES:
WAS
Well Depth 11.56 ft.
Well Diameter: 2 in.
pH 0040o: 5.6 units Temp. 00010: 20.5 °C
DRY at
Depth to Water Level 82546: 8.05 ft. below measuring point Screened Interval: 5 ft.
to 10
ft. Spec. Cond. 00094: 261.3 µMhos
time of
sampling,
Measuring Point is 3.00 _ft. above land surface
Relative M.P. Elevation: 2061.17
ft.
Odor 00085: none
check
Volume of water pumped/bailed before sampling:
1.08
gallons
Appearance
here: El
Samples for metals were collected unfiltered: K YES
❑ NO and field acidified: X YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: 11/8/2023
Laboratory Name: Pace Analytical Services
Certification No. 37712
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615
mg/L
Pb - Lead o1o51 ug/L
Coliform: MF Fecal 31616 1.0
/100mL
Nitrate (NO3) as N 00620 7.5
mg/L
Zn -Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665 <0.050
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L
Other (Specify Compounds and Concentration Units):
dissolved Solids:Total 70300 168.0
mg/L
Al - Aluminum o11o5
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC 00680 1.6
mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 17.4
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L
ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? X Yes (1) ❑ No (0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L
VOC 7873 method #
Total Ammonia 00610 <0.10
mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen; NH3asN; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
method #
TKN as N 00625
mg/L
Ni - Nickel'o1067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
James Frazier, Plant Manager
Permittee (or Authorized Agent) Name and Title - Please print or type
Z[
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27ON-1617
FACILITY INFORMATION
Please Print Cleady or Type
PERMIT Number: Expiration Date: 7/31/2026
Facility Name: Clement Pappas
Non -Discharge W00004797 UIC
NPDES Other
Permit Name (if different):
Facility Address: 485 Brookside Camp Road
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
Hendersonville NC 28792 County Henderson
E01 Spray Field ❑ Remediation:
Contact Person: James Frazie
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
(from Parnvq
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-7R2
Date sample collected 1118/2023
FIELD ANALYSES:
WAS
Well Depth 1i 39 ft,
Well Diameter 2 in.
pH oonoo. 5.7 units Temp aowo 16.7 °C
DRY at
time
Depth to Water Level 82546 12-21 ft. below measuring point Screened Interval 5 ft. to
15
ft. Spec. Cond. 00094 370.7 µMhos
sam �n
P 9
Measuring Point Is N/A ft. above land surface
Relative M.P Elevation 2062.86' ft.
Odor 000m none
check
Volume of water pumped/bailed before sampling:
319
gallons
Appearance 'Elevation assumed based on MWJR
here❑
Samples for metals were collected unfiltered [K YES
❑ NO and field acidified 0 YES O NO
LABORATORY INFORMATION
Date sample analyzed: 11/312023
Laboratory Name: Pace Analytical Services
Certification No. 37712
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead o1o51 ug/L
Coliform: MF Fecal 31616 <1.0
/100mL
Nitrate (NO3) as N 00620 19.1
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665 <0.050
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L
Other (Specify Compounds and Concentration Units)
dissolved Solids:Total 70300 242
mg/L
Al -Aluminum 01105
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC 00680 <1.0
mg/L
Ca - Calcium 00916
mg/L
Chloride 0094o 24.5
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L
ORGANICS: (by GC, GUMS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? LEI Yes (1) ❑ No (0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L
VOC 7873 method #
Total Ammonia 00610 <0.10
mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mglL vUU Kernovat"/o
James Frazier, Plant Manager
Pernntiee f or ALrthorized Agent) Name and Title - Please print or type
ZI
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
•
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699.1617
FACILITY INFORMATION
Please Prinf Clearly or Type
PERMIT Number: Expiration Date: 7/31/2026
Facility Name: Clement Pappas
Non -Discharge WW00004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp Road
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
Hendersonville " `' NC 28792 County Henderson
IN Spray Field ❑ Remediation:
Contact Person: James Frazier
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
(from
Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-8
Date sample collected: 11/8/2023
FIELD ANALYSES:
WAS
Well Depth 13.95 ft,
Well Diameter 2 in
pH oo400 6.6 units Temp. 000lo 15A 'C
DRY at
Depth to Water Level 52546 11 10 ft. below measuring point Screened Interval- 3 ft.
to 13
ft. Spec. Cond. 00094 604 4 uMhos
time of
sampling.
Measuring Point is 3.00 ft above land surface
Relative M.P Elevation 2060.80
ft.
Odor 00085 none
check
Volume of water pumped/bailed before sampling:
3-09
gallons
Appearance
here❑
Samples for metals were collected unfiltered X YES
❑ NO and field acidified K YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed:1118/2023
Laboratory Name: Pace Analytical Services
Certification No. 37712
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead o1o51 ug/L
Coliform: MF Fecal 31616 <1.0
/100mL
Nitrate (NO3) as N 00620 0.18
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100ml-
Phosphorus: Total as P 00665 <0.050
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L
Other (Specify Compounds and Concentration Units):
)issolved Solids:Total 70300 334
mg/L
Al -Aluminum oil o5
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC 006so 7.5
mg/L
Ca - Calcium 00916
mg/L
Chloride oo94o 15.8
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L
ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? M Yes (1) ❑ No (0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L
VOC 7873 method #
Total Ammonia 00610 0.16
mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen; NH3asN; Ammonia Nitrogen, Total)
Mn - Manganese olo55
ug/L
method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOG Removal%
James Frazier, Plant Manager
Pernnittee (or Authorized Agent) Name and Title - Please print or type
(or Authorized Agent)
Z1ZI Z3
(Date)
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
• .
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699.1617
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date: 7/31/2026
Facility game: Clement Pappas
Non -Discharge W00004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC
28792 County Henderson
❑ Lagoon ❑ Remediation: Infiltration Gallery
N Spray Field ❑ Remediation:
Contact Person: James Frazier
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
(from Pemvt)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-9
Date sample collected: 11/9/2023
FIELD ANALYSES:
WAS
Well Depth: 18.08 ft.
Well Diameter: 2 in.
pH 00400: 5.2 units Temp. 00010: 17.3 °C
DRY at
time ofsampling,
Depth to Water Level 82546: 621 ft. below measuring point Screened Interval: 6 ft. to
16
ft. Spec. Cond. 00094: 111.1 µMhos
Measuring Point is 1.44 ft. above land surface
Relative M.P. Elevation: 2060.23 ft.
Odor 00085: none
check
Volume of water pumped/bailed before sampling:
3.43
gallons
Appearance
here:
Samples for metals were collected unfiltered: 0 YES
❑ NO and field acidified- ❑■ YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: 111912023
Laboratory Name: Pace Analytical Services
Certification No. 37712
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead o1o51 ug/L
Coliform: MF Fecal 31616 <1.0
/100mL
Nitrate (NO3) as N 00620 2.4
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665 <0.050
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 7030o 80.0
mg/L
Al -Aluminum 01105
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC 00680 2.3
mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 8.7
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? K Yes (1) ❑ No (0)
Specific Conductance 00095
µMhos
K -Potassium 00937
mg/L
VOC 7873 method #
Total Ammonia 00610 <0.10
mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen; NH3as N, Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOG Removan/o
James Frazier, Plant Manager
Permlttee (or Authorized Agent) Name and Title - Please pent or type
21z1
GW-59 Rev.06-07-2018

Permit# WQ0004797
1
Enter date monitoring results were due. ( 12/29/2023 ) Will this monitoring report (GW-59 and GW-59A)
YES
NO
be submitted after the established due date?
YES
X
2
Was any required information missing on the GW-59 report forms?
l
IF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
3
YES
NO
identification plate, area overgrown, etc.)? If the answer is "Yes", contacl the Regional Office for guidance.
Are any monitored constituents equal to or above the established standards?
If the answer to question 4 is NO", skip to section S.
X
4
T
NO
if the answer to question 4 is "YES" list the affected wells individually with constiluent(s) and concentration(s)
exceeding standards in the space provided below:
Nitrate (2L = 10m9/L): M11-7R2Ca 19.1 mg/L
Fecal coliform (2L - 1 CFU/100 ML)! MW-6O 1.0 CFU/100 mL
Tetrachloroethene (21, = 0.7 )ag/L): MW-5s 169.0 µg/L
Trichloroethene (2L = 3 µg/t): MW-5® 155.0 µg/L; Cis-1,2-dichloroethene (2L = 70 µ�/L): MW-5® 111.0 µg/L
vinyl Chloride (2L = 0.03 µg/L): MW'® 1.3 µg/L *Note: MW-5 is background well
5
For the constituents identified in question 4 above, have standards been exceeded previously for the
YES
NO
same constituent(s) in the same well(s) in the last two years?
If the answer to question 5 is "NO", skip to section 8.
X
If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding
standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years).
litrate Fecal Coliform Tetrachlerouthene Trichloroethene Cie-1,2-dichloroethene Vinyl Chloride
IW-7R2 (m9/L) MW-6 (CFU/100ML) MW-5 (ug/L) MW-5 (ug/L) MW-5 (ug/L) MW-5 (ug/
)
S/03/23: 18.4 11/08/22: -164.0 10/26/21: 30.7 10/26/21: 11.6 11/08/22: 96.5 11/08/22:
1.1
11/06/22: 12.0 11/08/22: 152.0 11/08/22: 75.1
05/03/23: 15.0
• POS$FBLE LAB ERROR SUBSEQUENTLY RESAMPLED
6
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
YES
NO
X
If the answer is "YES", a groundwater quality problem maybe occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO" monitoring wells maybe improperly
located; contact the Regional Office.
7
Is the permittee implementing previously approved actions required by the Division involving this
YES
NO
groundwater quality problem?
X
If the answer to question 7 is 'YES", describe those actions in the space provided below.
if the answer to question 7 is "NO", contact the Regional Office within 90 days; an evaluation may be
required to determine the impact the waste disposal system is having at the review and compliance
boundaries surrounding this facility. Failure to do so may subiect the permittee to a Notice of Violation,
fines, and/or penalties.
Monitoring well MW-711 was replaced by MW-7112 prior to the Spring 2023 monitoring event due to root penetration of the well screen and
concerns regarding impacts to water quality measurements.
g
The person completing this portion (GW-59A) of the monitoring report should sign below and submit this
form with G W-59 forms for required wells to the address provided at the top of the current G W-59 form.
I hereby acknowledge that the above information was evaluated and the information submitted in this
report LiZompliance Report GW-59A) is true and complete to the best of my knowledge.
r
APe rmltteee (or Authorized Agent) Date
GtY-59A 12/8/2003

Tables

Table 1
Current and Historical Groundwater Elevation Measurements
Well
Identification
Screened
Interval
(ft bgs)
Date
Measured
Depth to
Groundwater
(ft)
Top -of -Casing
Elevation
(ft AMSL)
Top -of -Casing
Height Above
Ground Surface
(ft)
Groundwater
Elevation
(ft AMSL)
MW-4
5.0 - 15.0
05/02/2018
8.44
2063.77
2.43
2055.33
11/02/2018
8.00
2055.77
05/21/2019
8.49
2055.28
11/14/2019
8.82
2054.95
05/06/2020
7.98
2055.79
11/06/2020
8.02
2055.75
05/11/2021
8.52
2055.25
10/28/2021
9.15
2054.62
05/10/2022
9.14
2054.63
11/08/2022
9.35
2054.42
05/03/2023
8.79
2054.98
11/08/2023
9.88
2053.89
MW-5
9.0 - 19.0
05/02/2018
8.47
2085.60
3.00
2077.93
11/02/2018
8.23
2078.17
05/21/2019
8.57
2077.83
11/14/2019
8.90
2077.50
05/06/2020
8.28
2078.12
11/06/2020
8.90
2077.50
05/11/2021
8.77
2077.63
10/28/2021
9.44
2076.96
05/10/2022
9.15
2076.45
11/08/2022
10.07
2075.53
05/03/2023
8.85
2076.75
11 /09/2023
10.90
2074.70
MW-6
5.0 - 10.0
05/02/2018
5.36
2061.17
3.00
2056.54
11/02/2018
5.03
2056.87
05/21/2019
5.53
2056.37
11/14/2019
5.59
2056.31
05/06/2020
5.41
2056.49
11/06/2020
5.33
2056.57
05/11/2021
5.68
2056.22
10/28/2021
5.94
2055.96
05/10/2022
5.91
2055.26
11/08/2022
6.40
2054.77
05/03/2023
5.74
2055.43
11/08/2023
8.05
2053.12
MW-7R
5.0 - 15.0
05/02/2018
10.99
2062.86
3.00
2051.87
11/02/2018
10.33
2052.53
05/21/2019
10.88
2051.98
11/14/2019
11.33
2051.53
05/06/2020
10.11
2052.75
11/06/2020
10.05
2052.81
05/11/2021
10.85
2052.01
10/27/2021
11.74
2051.12
05/10/2022
11.66
2051.20
11/08/2022
11.80
2051.06
MW-7R2
5.0 - 15.0
05/03/2023
10.57
--
3.00
--
11/08/2023
12.21
--
Fall 2023 Groundwater Sampling Event Page 1 of 6
Clement Pappas, Hendersonville, North Carolina December 2023

Table 1
Current and Historical Groundwater Elevation Measurements
Well
Identification
Screened
Interval
(ft bgs)
Date
Measured
Depth to
Groundwater
(ft)
Top -of -Casing
Elevation
(ft AMSL)
Top -of -Casing
Height Above
Ground Surface
(ft)
Groundwater
Elevation
(ft AMSL)
MW-8
3.0 - 13.0
05/15/2002
10.25
2061.40
3.00
2051.15
11/05/2002
10.35
2051.05
05/13/2003
8.16
2053.24
11 /04/2003
10.23
2051.17
05/05/2004
10.30
2051.10
11/09/2004
8.90
2052.50
05/17/2005
10.08
2051.32
11 /03/2005
10.61
2050.79
05/24/2006
10.60
2050.80
11/09/2006
9.40
2052.00
05/18/2007
10.31
2051.09
11 /13/2007
11.09
2050.31
05/27/2008
10.83
2050.57
11 /18/2008
11.11
2050.29
05/28/2009
8.25
2053.15
11/05/2009
9.22
2052.18
05/13/2010
9.88
2051.52
11 /08/2010
10.38
2051.02
05/17/2011
10.27
2051.13
11/15/2011
10.87
2050.53
05/17/2012
8.03
2053.37
11/07/2012
10.45
2060.80
3.00
2050.35
05/16/2013
8.58
2052.22
11 /20/2013
10.34
2050.46
05/22/2014
9.79
2051.01
11/18/2014
10.03
2050.77
05/13/2015
10.34
2050.46
11/04/2015
7.21
2053.59
05/04/2016
9.84
2050.96
11 /09/2016
11.16
2049.64
05/02/2017
8.48
2052.32
11/08/2017
8.73
2052.07
05/02/2018
9.39
2051.41
11/02/2018
8.85
2051.95
05/21/2019
9.38
2051.42
11/14/2019
9.75
2051.05
05/06/2020
8.54
2052.26
11/06/2020
8.37
2052.43
05/11 /2021
9.24
2051.56
10/27/2021
10.06
2050.74
05/10/2022
10.02
2050.78
11 /08/2022
10.31
2050.49
05/03/2023
9.41
2051.39
11 /08/2023
11.10
2049.70
Fall 2023 Groundwater Sampling Event Page 2 of 6
Clement Pappas, Hendersonville, North Carolina December 2023

Table 1
Current and Historical Groundwater Elevation Measurements
Well
Identification
Screened
Interval
(ft bgs)
Date
Measured
Depth to
Groundwater
(ft)
Top -of -Casing
Elevation
(ft AMSL)
Top -of -Casing
Height Above
Ground Surface
(ft)
Groundwater
Elevation
(ft AMSL)
MW-9
6.0-16.0
05/02/2018
5.07
2060.23
1.44
2055.16
11/02/2018
4.55
2055.68
05/21/2019
4.89
2055.34
11/14/2019
5.15
2055.08
05/06/2020
4.30
2055.93
11/06/2020
4.10
2056.13
05/11/2021
4.75
2055.48
10/27/2021
5.57
2054.66
05/10/2022
5.70
2054.53
11/08/2022
5.90
2054.33
05/03/2023
5.02
2055.21
11/09/2023
6.21
2054.02
Notes:
AMSL: above mean sea level
bgs: below ground surface
ft: feet
Top -of -casing elevations: MW-5 through MW-8 top -of -casing elevations are based on a survey by Hill and Associates Surveyors,
dated January 10, 2002, through May 2012. MW-2R and MW-4 top -of -casing elevations are based on differential level
measurements made by Altamont Environmental, Inc., on June 26, 2006, through May 2012. The top -of -casing elevations for the
monitoring wells were resurveyed on November 21, 2012, by Wes Cole Land Surveying. The top -of -casing elevations for MW-9
were surveyed on May 29, 2015, by Wes Cole Land Surveying.
Monitoring is performed in accordance with Permit No. WQ0004797 issued to Clement Pappas on May 15, 2020 and effective on
September 1, 2020.
Fall 2023 Groundwater Sampling Event Page 3 of 6
Clement Pappas, Hendersonville, North Carolina December 2023

Table 2
Current and Historical Groundwater Analytical Results
Sample Name
Sample Date
0 c
o
0
V
LL
a
a
Z
�
EA
G
H {/01
M
p
E
Q
VI
0
t
a.IV
a
H
=
t
s
H
C
s
d
0
H
d
d
�v
�n v
V '0
d
d
R v
H
0
U
=
>
c
V
0
(SU)
(mg/L)
(mg/L)
(CFUs
per 100 mL)
(mg/L)
(mg/L)
(mg/L)
(mg/L)
(Ng/L)
(Ng/L)
(Ng/L)
(Ng/L)
(Ng/L)
(Ng/L)
2L Groundwater Standards
6.5 - 8.5
10
250
1
10
500
7.5
NL
0.7
3
70
700
0.03
7
Groundwater Standards Provided in Permit No. WQ0004797
6.5 - 8.5
10
250
NL
10
500
7.5
NL
0.7
3
70
700
0.03
7
11/14/2019
5.8
3.7
11
<1.0
0.42
190
<0.10
<0.050
<0.50
<0.50
<0.50
<0.50
<1.0
<0.50
05/06/2020
5.7
2.3
7.6
<1.0
3.7
172
<0.10
<0.050
NR
11/06/2020
5.3
2.8
6.9
<1.0
0.73
148
<0.10
<0.050
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
05/11/2021
5.8
2.8
6.9
<1.0
1.4
169
0.14
<0.050
NR
MW-4
10/28/2021
5.7
3.1
6.7
<1.0
0.084
161
<0.10
<0.050
<0.50 <0.50 <0.50 <0.50 <1.0 <0.50
05/10/2022
5.8
2.9
6.8
<1.0
0.460
136
<0.10
0.063
NR
11/08/2022
5.8
3.2
10.3
<1.0
0.090
137
<0.10
<0.050
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
05/03/2023
5.6
3.3
10.3
<1.0
0.660
126
<0.10
<0.050
NR
11/08/2023
5.7
2.9
13.1
<1.0
<0.040
121
<0.10
<0.050
<0.50
<0.50
<0.50
<0.50
<1.0
<0.50
11/14/2019
5.6
6.0
20.1
7.0
0.055
202
<0.10
0.081
22.4
4.4
5.0
<0.50
<1.0
<0.50
05/06/2020
5.9
6.9
7.3
8.0
<0.040
116
<0.10
0.083
NR
11/06/2020
5.7
4.6
6.9
8.0
<0.040
61.0
<0.10
0.060
0.80 1.0 <0.50 1 <0.50 <1.0 <0.50
05/11/2021
5.5
5.5
11.8
<2.0
<0.040
110
<0.10
0.090
NR
MW-5
10/28/2021
5.7
6.6
17.3
5.0
<0.040
76.0
<0.10
0.054
30.7 11.6 12.6 <0.50 <1.0 <0.50
05/10/2022
5.6
2.7
49.0
<1.0
0.10
158
<0.10
1 <0.050
NR
11/08/2022
5.5
2.3
51.4
<1.0
<0.040
132
<0.10
<0.050
152.0 75.1 96.5 1 <0.50 1.1 <0.50
05/03/2023
5.3
6.3
4.2
<1.0
0.049
75.0
<0.10
0.075
NR
11/09/2023
5.5
1.8
47.2
<1.0
0.066
125
<0.10
<0.050
169
155
111
0.76
1.3
<0.50
11/14/2019
5.3
2.9
9.3
44.0
0.56
342
<0.10
0.052
<0.50
<0.50
<0.50
<0.50
<1.0
<0.50
05/06/2020
5.4
2.0
9.7
3.0
1.1
96.0
<0.10
<0.050
NR
11/06/2020
5.2
2.6
12.5
3.0
3.2
139
<0.10
<0.050
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
05/11/2021
5.5
2.2
10.9
5.0
1.4
99.0
<0.10
<0.050
NR
MW-6
10/28/2021
5.4
2.3
8.7
<1.0
<0.040
85.0
<0.10
<0.050
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
05/10/2022
5.4
1 1.5
13.6
<1.0
<0.040
96.0
<0.10
<0.050
NR
11/08/2022
5.4
2.0
9.5
1 164.0/12.0*
1 0.40
1 85.0
1 <0.10
1 <0.050
1 <0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
05/03/2023
5.2
1.5
8.8
15.0
0.15
86.0
<0.10
<0.050
1 NR
11/08/2023
5.6
1.6
17.4
1.0
7.5
168
<0.10
<0.050
1 <0.50
<0.50
<0.50
1 <0.50
<1.0
<0.50
Fall 2023 Groundwater Sampling Event Page 4 of 6
Clement Pappas, Hendersonville, North Carolina December 2023

Table 2
Current and Historical Groundwater Analytical Results
Sample Name
Sample Date
0 C
o
0
V
LL
a
a
Z
�
EA
G
H {/01
M
p
E
Q
,�
0
t
a.IV
a
H
a
C
t
s
H
C
s
d
0
H
d
d
�v
s
�n v
V '0
d
d
C t
R v
H
0
U
�,
C
>
C
V
0
(SU)
(mg/L)
(mg/L)
(CFUs
per 100 mL)
(mg/L)
(mg/L)
(mg/L)
(mg/L)
(pg/L)
(pg/L)
(pg/L)
(pg/L)
(pg/L)
(pg/L)
11/14/2019
6.42
3.0
22.7
<2.0
17.1
73
<0.10
0.084
<0.50
<0.50
<0.50
<0.50
<1.0
<0.50
05/06/2020
5.20
1.2
20.9
<1.0
21.5
219
<0.10
<0.050
NR
11/06/2020
5.54
1.7
17.8
<1.0
13.0
205
<0.10
<0.050
<0.50
<0.50
<0.50
1 <0.50
<1.0
<0.50
MW-7R
05/11/2021
5.2
1.7
34.2
<1.0
40.4
296
<0.10
0.051
NR
10/27/2021
5.3
1.1
24.9
<1.0
26.0
222
<0.10
<0.050
<0.50
<0.50
<0.50
1 <0.50
<1.0
<0.50
05/10/2022
5.1
<1.0
30.8
<1.0
31.0
279
<0.10
<0.050
NR
11/08/2022
4.9
1.0
31.4
<1.0
24.2
225
<0.10
<0.050
<0.50
<0.50
<0.50
1 <0.50
<1.0
<0.50
MW-7R2
05/03/2023
5.2
1.8
26.6
<1.0
18.4
232
<0.10
<0.050
NR
11/08/2023
5.7
<1.0
24.5
<1.0
19.1
242
<0.10
<0.050
<0.50
<0.50
<0.50
<0.50
<1.0
<0.50
11/14/2019
6.7
7.7
7.2
2.0
1.2
51.0
<0.10
0.100
<0.50
<0.50
<0.50
<0.50
<1.0
<0.50
05/06/2020
6.4
2.7
2.8
<1.0
3.6
139
<0.10
<0.050
NR
11/06/2020
6.3
2.8
2.3
14.0
2.4
127
<0.10
<0.050
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
05/11/2021
6.6
3.8
2.0
<1.0
1.7
114
<0.10
<0.050
NR
MW-8
10/27/2021
6.6
4.7
3.5
1.0
0.86
189
< 0.10
< 0.050
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
05/10/2022
6.7
4.5
7.4
<1.0
3.2
240
<0.10
<0.050
NR
11/08/2022
6.6
6.2
12.2
<1.0
1.4
328
<0.10
<0.050
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
05/03/2023
6.6
4.9
10.9
<1.0
2.2
242
<0.10
<0.050
NR
11/08/2023
6.6
7.5
15.8
<1.0
0.18
334
0.16
<0.050
<0.50
<0.50
<0.50
<0.50
<1.0
<0.50
11/14/2019
5.6
6.1
5.4
<1.0
0.89
56.0
<0.10
0.076
<0.50
<0.50
<0.50
<0.50
<1.0
<0.50
05/06/2020
5.5
5.9
1.8
<1.0
<0.040
68.0
<0.10
0.099
NR
11/06/2020
4.9
4.5
1.4
16.0
0.043
88.0
<0.10
0.095
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
05/11/2021
5.4
3.6
9.8
<2.0
1.9
<25.0
<0.10
0.089
NR
MW-9
10/27/2021
5.4
3.8
3.2
1.0
0.35
48.0
< 0.10
< 0.050
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
05/10/2022
5.4
3.6
6.3
<1.0
1.5
67.0
<0.10
0.086
NR
11/08/2022
5.3
2.8
8.7
<1.0
1.9
81.0
0.17
<0.050
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
05/03/2023
5.1
4.7
13.4
<1.0
3.8
83.0
<0.10
0.080
NR
11/09/2023
5.2
2.3
1 8.7
1 <1.3
1 2.4
80.0
<0.10
<0.050
1 <0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
Notes:
< indicates that the constituent concentration was not detected above the method detection limit
pg/L: micrograms per liter; mg/L: milligrams per liter; mL: milliliter
CFU: colony -forming unit
J: The concentration is above the adjusted method detection limit and below the adjusted reporting limit and is therefore considered an estimate.
NL : No 2L standard exists. NR: not reported. SU: standard unit.
2L standards are set in North Carolina Administrative Code, Title 15A Subchapter 2L - Groundwater Classifications and Standards, Department of Environmental Quality (Amended April 1, 2022). Total organic carbon and nitrate standards are set in Wastewater
Irrigation System Permit Number WQ0004797. There is no defined 2L standard for fecal coliform; therefore, the standard listed is for "total coliform."
Bolded values indicate a concentration equal to or above the respective groundwater standard or outside the groundwater standard range.
pH is analyzed by Anchor QEA of North Carolina, PLLC; INC lab certification number 5445.
Monitoring is performed in accordance with Permit No. WQ0004797 issued to Clement Pappas on May 15, 2020, and effective on September 1, 2020.
Monitoring well MW-7R2 was installed on May 1, 2023 to replace MW-7R.
Fall 2023 Groundwater Sampling Event Page 5 of 6
Clement Pappas, Hendersonville, North Carolina December 2023

Table 3
Current and Historical Surface Water Analytical Results
Sample Name
Sample Date
c.
O
ate+
0
L
� O u
y
L
O
U
O
f6
V '
LL u
i
Z
VI
at6+ '^
T
� 0 0
(d
a
3
L
O
tn
V O
H a
(SU)
(mg/L)
(mg/L)
(CFUs per 100 mL)
(mg/L)
(mg/L)
(mg/L)
(mg/L)
28 Standard
6.0 - 9.0
NL
230
200
NL
NL
NL
NL
11/14/2019
6.76
1.9
5.3
118
0.83
57.0
<0.10
0.1
5/6/2020
7.20
1.6
4.6
290
0.76
49.0
<0.10
0.092
11/6/2020
5.83
1.6
4.4
145
0.71
56.0
<0.10
<0.050
SW-1
5/11/2021
6.8
1.3
5.3
191
0.80
1 48.0
<0.10
0.068
10/27/2021
7.0
1.8
5.2
145
0.72
52.0
<0.10
0.061
(Upstream)
5/10/2022
7.1
1.4
5.1
81.0
0.88
51.0
0.12
0.15
11/08/22
7.0
2.3
6.6
89.0
0.65
63.0
<0.10
0.13
05/04/23
6.6
1.4
5.0
173
0.69
49.0
<0.10
0.061
11/08/23
6.7
1.6
7.1
86.0
0.98
65.0
<0.10
<0.050
11/14/2019
7.01
1.9
5.4
127
0.82
83.0
<0.10
0.089
5/6/2020
6.67
1.7
4.2
420
0.72
53.0
<0.10
<0.050
11/6/2020
6.19
1.6
4.4
97.0
0.70
59.0
<0.10
<0.050
SW-2
5/11/2021
6.9
1.4
5.0
146
0.74
47.0
<0.10
0.061
10/27/2021
6.9
1.9
5.2
145
0.71
55.0
<0.10
0.063
(Downstream)
5/10/2022
6.9
1.4
4.9
118
0.87
50.0
<0.10
0.16
11/08/22
7.0
2.3
5.9
164
0.53
54.0
<0.10
0.099
05/04/23
6.6
1.3
4.8
98.0
0.61
43.0
1 <0.10
0.055
11/08/23
6.6
1.8
7.9
136
1.3
63.0
1 <0.10
0.067
Notes:
< indicates that the constituent concentration was not detected above the laboratory reporting limit
2B standard: surface water standard per North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 2B - Surface Water
CFU: coliform-forming unit
J: The concentration is above the adjusted method detection limit and below the adjusted reporting limit and is therefore considered an estimate.
mg/L: milligrams per liter; mL: milliliters
NL: No NC 2B standard exists
SU: standard unit
Bolded values indicate a concentration equal to or above the respective 2B standard or a value outside the 2B standard range.
Monitoring is performed in accordance with Permit No. WQ0004797 issued to Clement Pappas on May 15, 2020 and effective on September 1, 2020.
Fall 2023 Groundwater Sampling Event Page 6 of 6
Clement Pappas, Hendersonville, North Carolina December 2023

Figures

I;; W-wim ,

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\\ - �
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/
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If
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11\\ ♦♦����// �- .•,\ `. j j 1 i 1 I 1 I l 1 �'\. I I t11. \♦-_ _/ // /�1 L
- ,dam \\\`\' \\ �,\ l'I \_-`♦ \ \ \ •_' / �% / _ II � \ \ � \ - `�`�__ / / \ \ \ \\\\\
NN
NN AND STORAGE AREA
LEGEND
71
MONITORING WELL ------
OLD OR FORMER MONITORING WELL* k
D SURFACE WATER SAMPLE LOCATION IN Y//
10,
• •CONTOUR• • 1� /-j,� \� �� \ \♦ `♦ `\ ;�Y j/// .\\ \\ \ \\ /�.' \ \\ f \ \ - lC•'ll'�'ril / I I l I hl I /'�_ \\\y.I -
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` -'�.. / \ \ \ \\� \ �\ \\� `♦_/ /// 1 \1' �. `�\ ♦\ ` /R-� / / /' \
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,�I /•�•- _ •I I -�`\ 1 `\\ \ �/. / �\ . 1\\✓/ II / / •. \\' / -uj, J I \\ I) I j I 1 \ \ �\
' ! I 1 \ \\ \ \ \ 1 \ 7�. / / \ \� �/ / /' it} - I ./.'�'� •� 1 I 1 1. ) J 1\
STREAM CENTERLINE
\a' W-A
Op

Attachment 1
Laboratory Analytical Reports and
Chain -of -Custody Forms

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
November 16, 2023
Christian Patterson
Anchor QEA
231 Haywood Street
Asheville, NC 28801
RE: Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
Dear Christian Patterson:
Enclosed are the analytical results for sample(s) received by the laboratory on November 08, 2023. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
612-473-6801
Project Manager
Enclosures
cc: Jessica Mayers, Anchor QEA
Jennifer Verde, Anchor QEA
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
CERTIFICATIONS
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
VirginiaNELAP Certification #: 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
VirginiaNELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Lassoride Pappas SemiAnnual
92697837
Analytes
Lab lD
Sample ID
Method
Analysts
Reported
Laboratory
92697837001
MW-6
SM 6200B
SAS
63
PASI-C
SM 2540C-2015
JMH1
1
PASI-A
SM 9222D-2015
YEG
1
PASI-A
EPA 350.1 Rev 2.0 1993
ARJ
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
3
PASI-A
EPA 365.1 Rev 2.0 1993
Zip
1
PASI-A
SM 4500-CI-E-2011
Zip
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92697837002
MW-7R2
SM 6200B
SAS
63
PASI-C
SM 2540C-2015
JMH1
1
PASI-A
SM 9222D-2015
YEG
1
PASI-A
EPA 350.1 Rev 2.0 1993
ARJ
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
3
PASI-A
EPA 365.1 Rev 2.0 1993
Zip
1
PASI-A
SM 4500-CI-E-2011
Zip
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92697837003
MW-8
SM 6200B
SAS
63
PASI-C
SM 2540C-2015
JMH1
1
PASI-A
SM 9222D-2015
YEG
1
PASI-A
EPA 350.1 Rev 2.0 1993
ARJ
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
3
PASI-A
EPA 365.1 Rev 2.0 1993
Zip
1
PASI-A
SM 4500-CI-E-2011
Zip
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92697837004
SW-1
SM 2540C-2015
JMH1
1
PASI-A
SM 9222D-2015
YEG
1
PASI-A
EPA 350.1 Rev 2.0 1993
ARJ
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
3
PASI-A
EPA 365.1 Rev 2.0 1993
Zip
1
PASI-A
SM 4500-CI-E-2011
Zip
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92697837005
SW-2
SM 2540C-2015
JMH1
1
PASI-A
SM 9222D-2015
YEG
1
PASI-A
EPA 350.1 Rev 2.0 1993
ARJ
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
3
PASI-A
EPA 365.1 Rev 2.0 1993
Zip
1
PASI-A
SM 4500-CI-E-2011
Zip
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
Lab ID Sample ID Method
Analysts
Analytes
Reported
Laboratory
SM 531OB-2014
MJP
1
PASI-A
92697837006 MW-4 SM 6200B
SAS
63
PASI-C
SM 2540C-2015
JMH1
1
PASI-A
SM 9222D-2015
YEG
1
PASI-A
EPA 350.1 Rev 2.0 1993
ARJ
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
3
PASI-A
EPA 365.1 Rev 2.0 1993
Zip
1
PASI-A
SM 4500-CI-E-2011
Zip
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92697837007 TB-20231108 SM 6200B
SAS
63
PASI-C
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
Sample: MW-6 Lab ID: 92697837001 Collected: 11/08/23 12:25 Received: 11/08/23 15:35 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical
Services - Charlotte
Benzene
ND
ug/L
0.50
1
11/15/23 00:59
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/15/23 00:59
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/15/23 00:59
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/15/23 00:59
75-27-4
Bromoform
ND
ug/L
0.50
1
11/15/23 00:59
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/15/23 00:59
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/15/23 00:59
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/15/23 00:59
135-98-8
tert-Butyl benzene
ND
ug/L
0.50
1
11/15/23 00:59
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/15/23 00:59
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/15/23 00:59
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/15/23 00:59
75-00-3
Chloroform
ND
ug/L
0.50
1
11/15/23 00:59
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/15/23 00:59
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/15/23 00:59
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/15/23 00:59
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/15/23 00:59
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/15/23 00:59
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/15/23 00:59
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/15/23 00:59
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/15/23 00:59
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/15/23 00:59
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/15/23 00:59
106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/15/23 00:59
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/15/23 00:59
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/15/23 00:59
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/15/23 00:59
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/15/23 00:59
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/15/23 00:59
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/15/23 00:59
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/15/23 00:59
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/15/23 00:59
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/15/23 00:59
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/15/23 00:59
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
0.50
1
11/15/23 00:59
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/15/23 00:59
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/15/23 00:59
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/15/23 00:59
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/15/23 00:59
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/15/23 00:59
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/15/23 00:59
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/15/23 00:59
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/15/23 00:59
103-65-1
Styrene
ND
ug/L
0.50
1
11/15/23 00:59
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/15/23 00:59
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
11/15/23 00:59
79-34-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:30 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
Sample: MW-6 Lab ID: 92697837001 Collected: 11/08/23 12:25 Received: 11/08/23 15:35 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Tetrachloroethene
ND ug/L
0.50
1
11/15/23 00:59
127-18-4
Toluene
ND ug/L
0.50
1
11/15/23 00:59
108-88-3
1,2,3-Trichlorobenzene
ND ug/L
2.0
1
11/15/23 00:59
87-61-6
1,2,4-Trichlorobenzene
ND ug/L
2.0
1
11/15/23 00:59
120-82-1
1,1,1-Trichloroethane
ND ug/L
0.50
1
11/15/23 00:59
71-55-6
1,1,2-Trichloroethane
ND ug/L
0.50
1
11/15/23 00:59
79-00-5
Trichloroethene
ND ug/L
0.50
1
11/15/23 00:59
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/15/23 00:59
75-69-4
1,2,3-Trichloropropane
ND ug/L
0.50
1
11/15/23 00:59
96-18-4
1,2,4-Trimethylbenzene
ND ug/L
0.50
1
11/15/23 00:59
95-63-6
1,3,5-Trimethylbenzene
ND ug/L
0.50
1
11/15/23 00:59
108-67-8
Vinyl chloride
ND ug/L
1.0
1
11/15/23 00:59
75-01-4
m&p-Xylene
ND ug/L
1.0
1
11/15/23 00:59
179601-23-1
o-Xylene
ND ug/L
0.50
1
11/15/23 00:59
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
93 %
70-130
1
11/15/23 00:59
17060-07-0
4-Bromofluorobenzene (S)
94 %
70-130
1
11/15/23 00:59
460-00-4
Toluene-d8 (S)
97 %
70-130
1
11/15/23 00:59
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
168 mg/L
25.0
1
11/14/23 15:19
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015
Pace Analytical Services -Asheville
Fecal Coliforms
1.0 CFU/100 mL
1.0
1
11/08/23 16:48 11/09/23 15:07
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L
0.10
1
11/11/23 12:05
7664-41-7
353.2 Nitrogen, NO2/1403 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, NO2 plus NO3
7.5 mg/L
0.20
5
11/10/23 01:35
Nitrogen, Nitrate
7.5 mg/L
0.20
5
11/10/23 01:35
14797-55-8
Nitrogen, Nitrite
ND mg/L
0.040
1
11/10/23 01:07
14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
ND mg/L
0.050
1
11/15/2315:32 11/16/2311:47
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
17.4 mg/L
1.0
1
11/15/2317:01
16887-00-6
Date: 11/16/2023 02:30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
Sample: MW-6 Lab ID: 92697837001 Collected: 11/08/23 12:25 Received: 11/08/23 15:35 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon 1.6 mg/L 1.0 1 11/14/23 16:10 7440-44-0
Date: 11/16/2023 02:30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
Sample: MW-7R2 Lab ID: 92697837002 Collected: 11/08/23 11:10 Received: 11/08/23 15:35 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical
Services - Charlotte
Benzene
ND
ug/L
0.50
1
11/15/23 01:17
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/15/23 01:17
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/15/23 01:17
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/15/23 01:17
75-27-4
Bromoform
ND
ug/L
0.50
1
11/15/23 01:17
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/15/23 01:17
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/15/23 01:17
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/15/23 01:17
135-98-8
tert-Butyl benzene
ND
ug/L
0.50
1
11/15/23 01:17
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/15/23 01:17
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/15/23 01:17
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/15/23 01:17
75-00-3
Chloroform
ND
ug/L
0.50
1
11/15/23 01:17
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/15/23 01:17
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/15/23 01:17
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/15/23 01:17
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/15/23 01:17
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/15/23 01:17
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/15/23 01:17
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/15/23 01:17
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/15/23 01:17
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/15/23 01:17
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/15/23 01:17
106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/15/23 01:17
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/15/23 01:17
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/15/23 01:17
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/15/23 01:17
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/15/23 01:17
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/15/23 01:17
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/15/23 01:17
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/15/23 01:17
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/15/23 01:17
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/15/23 01:17
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/15/23 01:17
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
0.50
1
11/15/23 01:17
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/15/23 01:17
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/15/23 01:17
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/15/23 01:17
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/15/23 01:17
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/15/23 01:17
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/15/23 01:17
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/15/23 01:17
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/15/23 01:17
103-65-1
Styrene
ND
ug/L
0.50
1
11/15/23 01:17
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/15/23 01:17
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
11/15/23 01:17
79-34-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:30 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
Sample: MW-7R2 Lab ID: 92697837002 Collected: 11/08/23 11:10 Received: 11/08/23 15:35 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Tetrachloroethene
ND ug/L
0.50
1
11/15/23 01:17
127-18-4
Toluene
ND ug/L
0.50
1
11/15/23 01:17
108-88-3
1,2,3-Trichlorobenzene
ND ug/L
2.0
1
11/15/23 01:17
87-61-6
1,2,4-Trichlorobenzene
ND ug/L
2.0
1
11/15/23 01:17
120-82-1
1,1,1-Trichloroethane
ND ug/L
0.50
1
11/15/23 01:17
71-55-6
1,1,2-Trichloroethane
ND ug/L
0.50
1
11/15/23 01:17
79-00-5
Trichloroethene
ND ug/L
0.50
1
11/15/23 01:17
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/15/23 01:17
75-69-4
1,2,3-Trichloropropane
ND ug/L
0.50
1
11/15/23 01:17
96-18-4
1,2,4-Trimethylbenzene
ND ug/L
0.50
1
11/15/23 01:17
95-63-6
1,3,5-Trimethylbenzene
ND ug/L
0.50
1
11/15/23 01:17
108-67-8
Vinyl chloride
ND ug/L
1.0
1
11/15/23 01:17
75-01-4
m&p-Xylene
ND ug/L
1.0
1
11/15/23 01:17
179601-23-1
o-Xylene
ND ug/L
0.50
1
11/15/23 01:17
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
95 %
70-130
1
11/15/23 01:17
17060-07-0
4-Bromofluorobenzene (S)
96 %
70-130
1
11/15/23 01:17
460-00-4
Toluene-d8 (S)
97 %
70-130
1
11/15/23 01:17
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
242 mg/L
25.0
1
11/14/23 15:21
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2015 Preparation
Method: SM 9222D-2015
Pace Analytical Services -Asheville
Fecal Coliforms
ND CFU/100 mL
1.0
1
11/08/23 16:26 11/09/23 15:07
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L
0.10
1
11/11/23 12:23
7664-41-7
353.2 Nitrogen, NO2/1403 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, NO2 plus NO3
19.1 mg/L
0.40
10
11/10/23 01:31
Nitrogen, Nitrate
19.1 mg/L
0.40
10
11/10/23 01:31
14797-55-8
Nitrogen, Nitrite
ND mg/L
0.040
1
11/10/23 01:02
14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation
Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
ND mg/L
0.050
1
11/15/2315:32 11/16/2311:47
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
24.5 mg/L
1.0
1
11/15/2317:04
16887-00-6
Date: 11/16/2023 02:30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 9 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
Sample: MW-7R2 Lab ID: 92697837002 Collected: 11/08/23 11:10 Received: 11/08/23 15:35 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon ND mg/L 1.0 1 11/14/23 16:26 7440-44-0
Date: 11/16/2023 02:30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 10 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
Sample: MW-8 Lab ID: 92697837003 Collected: 11/08/23 10:12 Received: 11/08/23 15:35 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical
Services - Charlotte
Benzene
ND
ug/L
0.50
1
11/15/23 01:35
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/15/23 01:35
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/15/23 01:35
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/15/23 01:35
75-27-4
Bromoform
ND
ug/L
0.50
1
11/15/23 01:35
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/15/23 01:35
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/15/23 01:35
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/15/23 01:35
135-98-8
tert-Butyl benzene
ND
ug/L
0.50
1
11/15/23 01:35
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/15/23 01:35
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/15/23 01:35
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/15/23 01:35
75-00-3
Chloroform
ND
ug/L
0.50
1
11/15/23 01:35
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/15/23 01:35
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/15/23 01:35
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/15/23 01:35
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/15/23 01:35
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/15/23 01:35
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/15/23 01:35
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/15/23 01:35
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/15/23 01:35
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/15/23 01:35
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/15/23 01:35
106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/15/23 01:35
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/15/23 01:35
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/15/23 01:35
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/15/23 01:35
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/15/23 01:35
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/15/23 01:35
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/15/23 01:35
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/15/23 01:35
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/15/23 01:35
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/15/23 01:35
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/15/23 01:35
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
0.50
1
11/15/23 01:35
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/15/23 01:35
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/15/23 01:35
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/15/23 01:35
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/15/23 01:35
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/15/23 01:35
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/15/23 01:35
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/15/23 01:35
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/15/23 01:35
103-65-1
Styrene
ND
ug/L
0.50
1
11/15/23 01:35
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/15/23 01:35
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
11/15/23 01:35
79-34-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:30 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
Sample: MW-8 Lab ID: 92697837003 Collected: 11/08/23 10:12 Received: 11/08/23 15:35 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Tetrachloroethene
ND ug/L
0.50
1
11/15/23 01:35
127-18-4
Toluene
ND ug/L
0.50
1
11/15/23 01:35
108-88-3
1,2,3-Trichlorobenzene
ND ug/L
2.0
1
11/15/23 01:35
87-61-6
1,2,4-Trichlorobenzene
ND ug/L
2.0
1
11/15/23 01:35
120-82-1
1,1,1-Trichloroethane
ND ug/L
0.50
1
11/15/23 01:35
71-55-6
1,1,2-Trichloroethane
ND ug/L
0.50
1
11/15/23 01:35
79-00-5
Trichloroethene
ND ug/L
0.50
1
11/15/23 01:35
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/15/23 01:35
75-69-4
1,2,3-Trichloropropane
ND ug/L
0.50
1
11/15/23 01:35
96-18-4
1,2,4-Trimethylbenzene
ND ug/L
0.50
1
11/15/23 01:35
95-63-6
1,3,5-Trimethylbenzene
ND ug/L
0.50
1
11/15/23 01:35
108-67-8
Vinyl chloride
ND ug/L
1.0
1
11/15/23 01:35
75-01-4
m&p-Xylene
ND ug/L
1.0
1
11/15/23 01:35
179601-23-1
o-Xylene
ND ug/L
0.50
1
11/15/23 01:35
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
95 %
70-130
1
11/15/23 01:35
17060-07-0
4-Bromofluorobenzene (S)
95 %
70-130
1
11/15/23 01:35
460-00-4
Toluene-d8 (S)
97 %
70-130
1
11/15/23 01:35
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
334 mg/L
25.0
1
11/14/23 15:21
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015
Pace Analytical Services -Asheville
Fecal Coliforms
ND CFU/100 mL
1.0
1
11/08/23 16:26 11/09/23 15:07
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
0.16 mg/L
0.10
1
11/11/23 12:27
7664-41-7
353.2 Nitrogen, NO2/1403 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, NO2 plus NO3
0.18 mg/L
0.040
1
11/10/23 01:00
Nitrogen, Nitrate
0.18 mg/L
0.040
1
11/10/23 01:00
14797-55-8
Nitrogen, Nitrite
ND mg/L
0.040
1
11/10/23 01:00
14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
ND mg/L
0.050
1
11/15/2315:32 11/16/2311:48
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
15.8 mg/L
1.0
1
11/15/2317:05
16887-00-6
Date: 11/16/2023 02:30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 12 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
Sample: MW-8 Lab ID: 92697837003 Collected: 11/08/23 10:12 Received: 11/08/23 15:35 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon 7.5 mg/L 1.0 1 11/14/23 17:29 7440-44-0
Date: 11/16/2023 02:30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 13 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
Sample: SW-1 Lab ID: 92697837004 Collected: 11/08/23 14:30 Received: 11/08/23 15:35 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Total Dissolved Solids
MBIO 9222D Fecal Coliform AVL
Fecal Coliforms
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, NO2 plus NO3
Nitrogen, Nitrate
Nitrogen, Nitrite
365.1 Phosphorus, Total
Phosphorus
4500 Chloride
Chloride
531013 TOC
Total Organic Carbon
Date: 11/16/2023 02:30 PM
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
65.0 mg/L 25.0
1
11/14/2315:21
Analytical Method: SM 9222D-2015 Preparation
Method: SM 9222D-2015
Pace Analytical Services -Asheville
86.0 CFU/100 mL 1.0
1
11/08/23 16:48 11/09/23 15:07
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
ND mg/L 0.10
1
11/11/2312:28
7664-41-7
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
0.98 mg/L 0.040
1
11/10/23 01:11
0.98 mg/L 0.040
1
11/10/23 01:11
14797-55-8
ND mg/L 0.040
1
11/10/23 01:11
14797-65-0
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
ND mg/L 0.050
1
11/15/2315:32 11/16/2311:50
7723-14-0
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
7.1 mg/L 1.0
1
11/15/2317:07
16887-00-6
Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
1.6 mg/L 1.0
1
11/14/2317:47
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 14 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
Sample: SW-2 Lab ID: 92697837005 Collected: 11/08/23 14:30 Received: 11/08/23 15:35 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Total Dissolved Solids
MBIO 9222D Fecal Coliform AVL
Fecal Coliforms
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, NO2 plus NO3
Nitrogen, Nitrate
Nitrogen, Nitrite
365.1 Phosphorus, Total
Phosphorus
4500 Chloride
Chloride
531013 TOC
Total Organic Carbon
Date: 11/16/2023 02:30 PM
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
63.0 mg/L 25.0
1
11/14/2315:21
Analytical Method: SM 9222D-2015 Preparation
Method: SM 9222D-2015
Pace Analytical Services -Asheville
136 CFU/100 mL 1.0
1
11/08/23 15:50 11/09/23 15:07
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
ND mg/L 0.10
1
11/11/2312:30
7664-41-7
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
1.3 mg/L 0.040
1
11/10/23 01:12
1.3 mg/L 0.040
1
11/10/23 01:12
14797-55-8
ND mg/L 0.040
1
11/10/23 01:12
14797-65-0
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
0.067 mg/L 0.050
1
11/15/2315:32 11/16/2311:51
7723-14-0
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
7.9 mg/L 1.0
1
11/15/2317:08
16887-00-6
Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
1.8 mg/L 1.0
1
11/14/2318:08
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 15 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
Sample: MW-4 Lab ID: 92697837006 Collected: 11/08/23 14:05 Received: 11/08/23 15:35 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical
Services - Charlotte
Benzene
ND
ug/L
0.50
1
11/15/23 01:53
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/15/23 01:53
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/15/23 01:53
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/15/23 01:53
75-27-4
Bromoform
ND
ug/L
0.50
1
11/15/23 01:53
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/15/23 01:53
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/15/23 01:53
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/15/23 01:53
135-98-8
tert-Butyl benzene
ND
ug/L
0.50
1
11/15/23 01:53
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/15/23 01:53
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/15/23 01:53
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/15/23 01:53
75-00-3
Chloroform
ND
ug/L
0.50
1
11/15/23 01:53
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/15/23 01:53
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/15/23 01:53
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/15/23 01:53
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/15/23 01:53
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/15/23 01:53
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/15/23 01:53
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/15/23 01:53
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/15/23 01:53
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/15/23 01:53
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/15/23 01:53
106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/15/23 01:53
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/15/23 01:53
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/15/23 01:53
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/15/23 01:53
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/15/23 01:53
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/15/23 01:53
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/15/23 01:53
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/15/23 01:53
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/15/23 01:53
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/15/23 01:53
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/15/23 01:53
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
0.50
1
11/15/23 01:53
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/15/23 01:53
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/15/23 01:53
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/15/23 01:53
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/15/23 01:53
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/15/23 01:53
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/15/23 01:53
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/15/23 01:53
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/15/23 01:53
103-65-1
Styrene
ND
ug/L
0.50
1
11/15/23 01:53
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/15/23 01:53
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
11/15/23 01:53
79-34-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:30 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
Sample: MW-4 Lab ID: 92697837006 Collected: 11/08/23 14:05 Received: 11/08/23 15:35 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Tetrachloroethene
ND ug/L
0.50
1
11/15/23 01:53
127-18-4
Toluene
ND ug/L
0.50
1
11/15/23 01:53
108-88-3
1,2,3-Trichlorobenzene
ND ug/L
2.0
1
11/15/23 01:53
87-61-6
1,2,4-Trichlorobenzene
ND ug/L
2.0
1
11/15/23 01:53
120-82-1
1,1,1-Trichloroethane
ND ug/L
0.50
1
11/15/23 01:53
71-55-6
1,1,2-Trichloroethane
ND ug/L
0.50
1
11/15/23 01:53
79-00-5
Trichloroethene
ND ug/L
0.50
1
11/15/23 01:53
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/15/23 01:53
75-69-4
1,2,3-Trichloropropane
ND ug/L
0.50
1
11/15/23 01:53
96-18-4
1,2,4-Trimethylbenzene
ND ug/L
0.50
1
11/15/23 01:53
95-63-6
1,3,5-Trimethylbenzene
ND ug/L
0.50
1
11/15/23 01:53
108-67-8
Vinyl chloride
ND ug/L
1.0
1
11/15/23 01:53
75-01-4
m&p-Xylene
ND ug/L
1.0
1
11/15/23 01:53
179601-23-1
o-Xylene
ND ug/L
0.50
1
11/15/23 01:53
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
95 %
70-130
1
11/15/23 01:53
17060-07-0
4-Bromofluorobenzene (S)
95 %
70-130
1
11/15/23 01:53
460-00-4
Toluene-d8 (S)
97 %
70-130
1
11/15/23 01:53
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
121 mg/L
25.0
1
11/14/23 15:21
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015
Pace Analytical Services -Asheville
Fecal Coliforms
ND CFU/100 mL
1.0
1
11/08/23 16:48 11/09/23 15:07
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L
0.10
1
11/11/23 12:31
7664-41-7
353.2 Nitrogen, NO2/1403 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, NO2 plus NO3
ND mg/L
0.040
1
11/10/23 01:08
Nitrogen, Nitrate
ND mg/L
0.040
1
11/10/23 01:08
14797-55-8
Nitrogen, Nitrite
ND mg/L
0.040
1
11/10/23 01:08
14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
ND mg/L
0.050
1
11/15/2315:32 11/16/2311:52
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
13.1 mg/L
1.0
1
11/15/2317:09
16887-00-6
Date: 11/16/2023 02:30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 17 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
Sample: MW-4 Lab ID: 92697837006 Collected: 11/08/23 14:05 Received: 11/08/23 15:35 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon 2.9 mg/L 1.0 1 11/14/23 18:23 7440-44-0
Date: 11/16/2023 02:30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 18 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
Sample: TB-20231108 Lab ID: 92697837007 Collected: 11/08/23 00:00 Received: 11/08/23 15:35 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical
Services - Charlotte
Benzene
ND
ug/L
0.50
1
11/15/23 00:22
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/15/23 00:22
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/15/23 00:22
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/15/23 00:22
75-27-4
Bromoform
ND
ug/L
0.50
1
11/15/23 00:22
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/15/23 00:22
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/15/23 00:22
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/15/23 00:22
135-98-8
tert-Butyl benzene
ND
ug/L
0.50
1
11/15/23 00:22
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/15/23 00:22
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/15/23 00:22
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/15/23 00:22
75-00-3
Chloroform
ND
ug/L
0.50
1
11/15/23 00:22
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/15/23 00:22
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/15/23 00:22
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/15/23 00:22
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/15/23 00:22
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/15/23 00:22
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/15/23 00:22
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/15/23 00:22
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/15/23 00:22
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/15/23 00:22
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/15/23 00:22
106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/15/23 00:22
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/15/23 00:22
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/15/23 00:22
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/15/23 00:22
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/15/23 00:22
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/15/23 00:22
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/15/23 00:22
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/15/23 00:22
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/15/23 00:22
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/15/23 00:22
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/15/23 00:22
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
0.50
1
11/15/23 00:22
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/15/23 00:22
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/15/23 00:22
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/15/23 00:22
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/15/23 00:22
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/15/23 00:22
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/15/23 00:22
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/15/23 00:22
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/15/23 00:22
103-65-1
Styrene
ND
ug/L
0.50
1
11/15/23 00:22
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/15/23 00:22
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
11/15/23 00:22
79-34-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:30 PM without the written consent of Pace Analytical Services, LLC.
Page 19 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
Sample: TB-20231108
Lab ID: 92697837007 Collected:
11/08/23 00:00
Received: 11/08/23 15:35 Matrix: Water
Parameters
Results
Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
6200B MSV
Analytical Method:
SM 6200B
Pace Analytical
Services - Charlotte
Tetrachloroethene
ND
ug/L
0.50
1
11/15/23 00:22
127-18-4
Toluene
ND
ug/L
0.50
1
11/15/23 00:22
108-88-3
1,2,3-Trichlorobenzene
ND
ug/L
2.0
1
11/15/23 00:22
87-61-6
1,2,4-Trichlorobenzene
ND
ug/L
2.0
1
11/15/23 00:22
120-82-1
1,1,1-Trichloroethane
ND
ug/L
0.50
1
11/15/23 00:22
71-55-6
1,1,2-Trichloroethane
ND
ug/L
0.50
1
11/15/23 00:22
79-00-5
Trichloroethene
ND
ug/L
0.50
1
11/15/23 00:22
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
11/15/23 00:22
75-69-4
1,2,3-Trichloropropane
ND
ug/L
0.50
1
11/15/23 00:22
96-18-4
1,2,4-Trimethylbenzene
ND
ug/L
0.50
1
11/15/23 00:22
95-63-6
1,3,5-Trimethylbenzene
ND
ug/L
0.50
1
11/15/23 00:22
108-67-8
Vinyl chloride
ND
ug/L
1.0
1
11/15/23 00:22
75-01-4
m&p-Xylene
ND
ug/L
1.0
1
11/15/23 00:22
179601-23-1
o-Xylene
ND
ug/L
0.50
1
11/15/23 00:22
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
94
%
70-130
1
11/15/23 00:22
17060-07-0
4-Bromofluorobenzene (S)
96
%
70-130
1
11/15/23 00:22
460-00-4
Toluene-d8 (S)
98
%
70-130
1
11/15/23 00:22
2037-26-5
Date: 11/16/2023 02:30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 20 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
QC Batch: 812813 Analysis Method: SM 6200B
QC Batch Method: SM 6200B Analysis Description: 6200E MSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92697837001, 92697837002, 92697837003, 92697837006, 92697837007
METHOD BLANK: 4208360 Matrix: Water
Associated Lab Samples: 92697837001, 92697837002, 92697837003, 92697837006, 92697837007
Blank Reporting
Parameter Units Result Limit Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
0.50
11/15/23 00:04
1,1,1-Trichloroethane
ug/L
ND
0.50
11/15/23 00:04
1,1,2,2-Tetrachloroethane
ug/L
ND
0.50
11/15/23 00:04
1,1,2-Trichloroethane
ug/L
ND
0.50
11/15/23 00:04
1,1-Dichloroethane
ug/L
ND
0.50
11/15/23 00:04
1,1-Dichloroethene
ug/L
ND
0.50
11/15/23 00:04
1,1-Dichloropropene
ug/L
ND
0.50
11/15/23 00:04
1,2,3-Trichlorobenzene
ug/L
ND
2.0
11/15/23 00:04
1,2,3-Trichloropropane
ug/L
ND
0.50
11/15/23 00:04
1,2,4-Trichlorobenzene
ug/L
ND
2.0
11/15/23 00:04
1,2,4-Trimethylbenzene
ug/L
ND
0.50
11/15/23 00:04
1,2-Dibromo-3-chloropropane
ug/L
ND
1.0
11/15/23 00:04
1,2-Dibromoethane (EDB)
ug/L
ND
0.50
11/15/23 00:04
1,2-Dichlorobenzene
ug/L
ND
0.50
11/15/23 00:04
1,2-Dichloroethane
ug/L
ND
0.50
11/15/23 00:04
1,2-Dichloropropane
ug/L
ND
0.50
11/15/23 00:04
1,3,5-Trimethylbenzene
ug/L
ND
0.50
11/15/23 00:04
1,3-Dichlorobenzene
ug/L
ND
0.50
11/15/23 00:04
1,3-Dichloropropane
ug/L
ND
0.50
11/15/23 00:04
1,4-Dichlorobenzene
ug/L
ND
0.50
11/15/23 00:04
2,2-Dichloropropane
ug/L
ND
0.50
11/15/23 00:04
2-Chlorotoluene
ug/L
ND
0.50
11/15/23 00:04
4-Chlorotoluene
ug/L
ND
0.50
11/15/23 00:04
Benzene
ug/L
ND
0.50
11/15/23 00:04
Bromobenzene
ug/L
ND
0.50
11/15/23 00:04
Bromochloromethane
ug/L
ND
0.50
11/15/23 00:04
Bromodichloromethane
ug/L
ND
0.50
11/15/23 00:04
Bromoform
ug/L
ND
0.50
11/15/23 00:04
Bromomethane
ug/L
ND
5.0
11/15/23 00:04
Carbon tetrachloride
ug/L
ND
0.50
11/15/23 00:04
Chlorobenzene
ug/L
ND
0.50
11/15/23 00:04
Chloroethane
ug/L
ND
1.0
11/15/23 00:04
Chloroform
ug/L
ND
0.50
11/15/23 00:04
Chloromethane
ug/L
ND
1.0
11/15/23 00:04
cis-1,2-Dichloroethene
ug/L
ND
0.50
11/15/23 00:04
cis-1,3-Dichloropropene
ug/L
ND
0.50
11/15/23 00:04
Dibromochloromethane
ug/L
ND
0.50
11/15/23 00:04
Dibromomethane
ug/L
ND
0.50
11/15/23 00:04
Dichlorodifluoromethane
ug/L
ND
0.50
11/15/23 00:04
Diisopropyl ether
ug/L
ND
0.50
11/15/23 00:04
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:30 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
METHOD BLANK: 4208360 Matrix: Water
Associated Lab Samples: 92697837001, 92697837002, 92697837003, 92697837006, 92697837007
Blank Reporting
Parameter Units Result Limit Analyzed
Ethylbenzene
ug/L
ND
0.50
11/15/23 00:04
Hexachloro-1,3-butadiene
ug/L
ND
2.0
11/15/23 00:04
Isopropylbenzene (Cumene)
ug/L
ND
0.50
11/15/23 00:04
m&p-Xylene
ug/L
ND
1.0
11/15/23 00:04
Methyl-tert-butyl ether
ug/L
ND
0.50
11/15/23 00:04
Methylene Chloride
ug/L
ND
2.0
11/15/23 00:04
n-Butylbenzene
ug/L
ND
0.50
11/15/23 00:04
n-Propylbenzene
ug/L
ND
0.50
11/15/23 00:04
Naphthalene
ug/L
ND
2.0
11/15/23 00:04
o-Xylene
ug/L
ND
0.50
11/15/23 00:04
sec-Butylbenzene
ug/L
ND
0.50
11/15/23 00:04
Styrene
ug/L
ND
0.50
11/15/23 00:04
tert-Butyl benzene
ug/L
ND
0.50
11/15/23 00:04
Tetrachloroethene
ug/L
ND
0.50
11/15/23 00:04
Toluene
ug/L
ND
0.50
11/15/23 00:04
trans-1,2-Dichloroethene
ug/L
ND
0.50
11/15/23 00:04
trans- 1,3-Dichloropropene
ug/L
ND
0.50
11/15/23 00:04
Trichloroethene
ug/L
ND
0.50
11/15/23 00:04
Trichlorofluoromethane
ug/L
ND
1.0
11/15/23 00:04
Vinyl chloride
ug/L
ND
1.0
11/15/23 00:04
1,2-Dichloroethane-d4 (S)
%
94
70-130
11/15/23 00:04
4-Bromofluorobenzene (S)
%
95
70-130
11/15/23 00:04
Toluene-d8 (S)
%
97
70-130
11/15/23 00:04
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
4208361
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1,1,2-Tetrachloroethane
ug/L
20
21.5
107
60-140
1,1,1-Trichloroethane
ug/L
20
19.3
96
60-140
1,1,2,2-Tetrachloroethane
ug/L
20
20.4
102
60-140
1,1,2-Trichloroethane
ug/L
20
20.8
104
60-140
1,1-Dichloroethane
ug/L
20
18.2
91
60-140
1,1-Dichloroethene
ug/L
20
19.8
99
60-140
1,1-Dichloropropene
ug/L
20
20.3
102
60-140
1,2,3-Trichlorobenzene
ug/L
20
21.9
109
60-140
1,2,3-Trichloropropane
ug/L
20
19.0
95
60-140
1,2,4-Trichlorobenzene
ug/L
20
20.6
103
60-140
1,2,4-Trimethylbenzene
ug/L
20
21.0
105
60-140
1,2-Dibromo-3-chloropropane
ug/L
20
20.9
105
60-140
1,2-Dibromoethane (EDB)
ug/L
20
21.3
107
60-140
1,2-Dichlorobenzene
ug/L
20
21.3
106
60-140
1,2-Dichloroethane
ug/L
20
18.1
91
60-140
1,2-Dichloropropane
ug/L
20
19.1
96
60-140
1,3,5-Trimethylbenzene
ug/L
20
20.8
104
60-140
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:30 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
LABORATORY CONTROL SAMPLE:
Parameter
4208361
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,3-Dichlorobenzene
ug/L
20
20.7
104
60-140
1,3-Dichloropropane
ug/L
20
19.7
98
60-140
1,4-Dichlorobenzene
ug/L
20
20.4
102
60-140
2,2-Dichloropropane
ug/L
20
15.8
79
60-140
2-Chlorotoluene
ug/L
20
19.8
99
60-140
4-Chlorotoluene
ug/L
20
20.3
101
60-140
Benzene
ug/L
20
19.0
95
60-140
Bromobenzene
ug/L
20
20.6
103
60-140
Bromochloromethane
ug/L
20
20.3
102
60-140
Bromodichloromethane
ug/L
20
19.1
95
60-140
Bromoform
ug/L
20
21.1
105
60-140
Bromomethane
ug/L
20
15.0
75
60-140
Carbon tetrachloride
ug/L
20
20.4
102
60-140
Chlorobenzene
ug/L
20
19.8
99
60-140
Chloroethane
ug/L
20
17.5
88
60-140
Chloroform
ug/L
20
18.3
92
60-140
Chloromethane
ug/L
20
15.3
77
60-140
cis-1,2-Dichloroethene
ug/L
20
18.1
91
60-140
cis-1,3-Dichloropropene
ug/L
20
19.0
95
60-140
Dibromochloromethane
ug/L
20
20.7
104
60-140
Dibromomethane
ug/L
20
20.9
104
60-140
Dichlorodifluoromethane
ug/L
20
19.4
97
60-140
Diisopropyl ether
ug/L
20
17.3
87
60-140
Ethylbenzene
ug/L
20
19.3
96
60-140
Hexachloro-1,3-butadiene
ug/L
20
21.2
106
60-140
Isopropylbenzene (Cumene)
ug/L
20
20.7
103
60-140
m&p-Xylene
ug/L
40
40.1
100
60-140
Methyl-tert-butyl ether
ug/L
20
18.1
90
60-140
Methylene Chloride
ug/L
20
17.0
85
60-140
n-Butylbenzene
ug/L
20
19.9
100
60-140
n-Propylbenzene
ug/L
20
19.6
98
60-140
Naphthalene
ug/L
20
23.1
115
60-140
o-Xylene
ug/L
20
20.9
104
60-140
sec-Butylbenzene
ug/L
20
20.3
101
60-140
Styrene
ug/L
20
21.4
107
60-140
tert-Butyl benzene
ug/L
20
17.0
85
60-140
Tetrachloroethene
ug/L
20
19.8
99
60-140
Toluene
ug/L
20
18.9
94
60-140
trans-1,2-Dichloroethene
ug/L
20
18.0
90
60-140
trans- 1,3-Dichloropropene
ug/L
20
19.0
95
60-140
Trichloroethene
ug/L
20
20.0
100
60-140
Trichlorofluoromethane
ug/L
20
19.6
98
60-140
Vinyl chloride
ug/L
20
15.5
78
60-140
1,2-Dichloroethane-d4 (S)
%
93
70-130
4-Bromofluorobenzene (S)
%
97
70-130
Toluene-d8 (S)
%
97
70-130
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:30 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4208362 4208363
MS MSD
92697837001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
21.9
21.2
109
106
60-140 3
1,1,1-Trichloroethane
ug/L
ND
20
20
20.1
19.6
101
98
60-140 3
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
20.3
19.8
102
99
60-140 2
1,1,2-Trichloroethane
ug/L
ND
20
20
20.5
19.7
103
99
60-140 4
1,1-Dichloroethane
ug/L
ND
20
20
19.9
19.6
99
98
60-140 1
1,1-Dichloroethene
ug/L
ND
20
20
20.7
20.4
103
102
60-140 1
1,1-Dichloropropene
ug/L
ND
20
20
21.6
21.3
108
107
60-140 1
1,2,3-Trichlorobenzene
ug/L
ND
20
20
21.0
20.7
105
103
60-140 2
1,2,3-Trichloropropane
ug/L
ND
20
20
19.9
18.8
99
94
60-140 6
1,2,4-Trichlorobenzene
ug/L
ND
20
20
20.9
21.1
104
105
60-140 1
1,2,4-Trimethylbenzene
ug/L
ND
20
20
21.5
21.6
107
108
60-140 1
1,2-Dibromo-3-chloropropane
ug/L
ND
20
20
19.8
19.9
99
100
60-140 1
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
21.2
20.3
106
102
60-140 4
1,2-Dichlorobenzene
ug/L
ND
20
20
21.2
20.9
106
105
60-140 1
1,2-Dichloroethane
ug/L
ND
20
20
18.9
17.9
95
90
60-140 5
1,2-Dichloropropane
ug/L
ND
20
20
20.5
19.7
103
98
60-140 4
1,3,5-Trimethylbenzene
ug/L
ND
20
20
21.6
21.3
108
106
60-140 2
1,3-Dichlorobenzene
ug/L
ND
20
20
21.0
21.2
105
106
60-140 1
1,3-Dichloropropane
ug/L
ND
20
20
20.1
19.4
101
97
60-140 3
1,4-Dichlorobenzene
ug/L
ND
20
20
20.1
20.0
101
100
60-140 1
2,2-Dichloropropane
ug/L
ND
20
20
21.1
20.5
105
103
60-140 3
2-Chlorotoluene
ug/L
ND
20
20
20.8
20.5
104
102
60-140 1
4-Chlorotoluene
ug/L
ND
20
20
20.5
21.1
102
105
60-140 3
Benzene
ug/L
ND
20
20
20.6
20.4
103
102
60-140 1
Bromobenzene
ug/L
ND
20
20
20.6
20.2
103
101
60-140 2
Bromochloromethane
ug/L
ND
20
20
20.8
19.8
104
99
60-140 5
Bromodichloromethane
ug/L
ND
20
20
19.3
19.0
96
95
60-140 2
Bromoform
ug/L
ND
20
20
19.8
19.3
99
97
60-140 2
Bromomethane
ug/L
ND
20
20
22.2
22.3
111
112
60-140 1
Carbon tetrachloride
ug/L
ND
20
20
20.8
20.7
104
104
60-140 0
Chlorobenzene
ug/L
ND
20
20
20.6
20.4
103
102
60-140 1
Chloroethane
ug/L
ND
20
20
21.1
20.9
105
105
60-140 1
Chloroform
ug/L
ND
20
20
19.2
19.0
96
95
60-140 1
Chloromethane
ug/L
ND
20
20
17.9
17.6
90
88
60-140 2
cis-1,2-Dichloroethene
ug/L
ND
20
20
19.7
19.3
98
97
60-140 2
cis-1,3-Dichloropropene
ug/L
ND
20
20
20.5
20.1
102
101
60-140 2
Dibromochloromethane
ug/L
ND
20
20
20.1
20.2
101
101
60-140 0
Dibromomethane
ug/L
ND
20
20
21.2
20.4
106
102
60-140 4
Dichlorodifluoromethane
ug/L
ND
20
20
17.9
17.2
89
86
60-140 4
Diisopropyl ether
ug/L
ND
20
20
18.6
18.1
93
90
60-140 3
Ethylbenzene
ug/L
ND
20
20
20.8
20.5
104
103
60-140 1
Hexachloro-1,3-butadiene
ug/L
ND
20
20
21.3
21.4
107
107
60-140 1
Isopropylbenzene (Cumene)
ug/L
ND
20
20
22.1
21.8
111
109
60-140 2
m&p-Xylene
ug/L
ND
40
40
41.3
41.4
103
104
60-140 0
Methyl-tert-butyl ether
ug/L
ND
20
20
18.5
17.5
92
87
60-140 5
Methylene Chloride
ug/L
ND
20
20
17.8
17.4
89
87
60-140 2
Results presented on this page are in the units indicated
by the "Units"
column
except where
an alternate unit
is presented to the right
of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:30 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
4208362
4208363
MS
MSD
92697837001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
n-Butylbenzene
ug/L
ND
20
20
21.3
21.1
107
106
60-140
1
n-Propylbenzene
ug/L
ND
20
20
20.5
20.4
103
102
60-140
1
Naphthalene
ug/L
ND
20
20
21.5
20.8
108
104
60-140
3
o-Xylene
ug/L
ND
20
20
21.0
21.0
105
105
60-140
0
sec-Butylbenzene
ug/L
ND
20
20
21.2
21.1
106
106
60-140
0
Styrene
ug/L
ND
20
20
21.9
21.3
110
106
60-140
3
tert-Butyl benzene
ug/L
ND
20
20
17.5
17.6
87
88
60-140
1
Tetrachloroethene
ug/L
ND
20
20
21.2
21.3
106
106
60-140
0
Toluene
ug/L
ND
20
20
20.1
19.8
100
99
60-140
1
trans-1,2-Dichloroethene
ug/L
ND
20
20
20.0
19.9
100
99
60-140
1
trans- 1,3-Dichloropropene
ug/L
ND
20
20
20.4
19.9
102
100
60-140
3
Trichloroethene
ug/L
ND
20
20
21.1
21.1
106
105
60-140
0
Trichlorofluoromethane
ug/L
ND
20
20
20.1
20.0
100
100
60-140
0
Vinyl chloride
ug/L
ND
20
20
18.9
18.3
94
92
60-140
3
1,2-Dichloroethane-d4 (S)
%
89
85
70-130
4-Bromofluorobenzene (S)
%
99
98
70-130
Toluene-d8(S)
%
98
98
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:30 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
QC Batch: 813022 Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697837001, 92697837002, 92697837003, 92697837004, 92697837005, 92697837006
METHOD BLANK: 4209564
Matrix:
Water
Associated Lab Samples: 92697837001, 92697837002, 92697837003, 92697837004, 92697837005, 92697837006
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Total Dissolved Solids
mg/L
ND
25.0
11/14/23 15:19
LABORATORY CONTROL SAMPLE:
4209565
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Total Dissolved Solids
mg/L
250
256
102 90-110
SAMPLE DUPLICATE: 4209566
92697693034 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 85.0 83.0 2
SAMPLE DUPLICATE: 4209567
92698167003 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 39.0 45.0 14
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:30 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
QC Batch: 812230 Analysis Method: SM 9222D-2015
QC Batch Method: SM 9222D-2015 Analysis Description: 9222D Fecal Coliform(MF) -AVL
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697837001, 92697837002, 92697837003, 92697837004, 92697837005, 92697837006
METHOD BLANK: 4205793 Matrix: Water
Associated Lab Samples: 92697837001, 92697837002, 92697837003, 92697837004, 92697837005, 92697837006
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Fecal Coliforms CFU/100 mL ND 1.0 11/09/23 15:07
SAMPLE DUPLICATE: 4205794
92697544001 Dup
Parameter Units Result Result RPD Qualifiers
Fecal Coliforms CFU/100 mL 109 136 22
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:30 PM without the written consent of Pace Analytical Services, LLC.
Page 27 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
QC Batch: 812610 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697837001, 92697837002, 92697837003, 92697837004, 92697837005, 92697837006
METHOD BLANK: 4207713
Matrix:
Water
Associated Lab Samples: 92697837001, 92697837002, 92697837003, 92697837004, 92697837005, 92697837006
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Nitrogen, Ammonia
mg/L
ND
0.10
11/11/23 12:02
LABORATORY CONTROL SAMPLE:
4207714
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Nitrogen, Ammonia
mg/L
5
4.9
99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4207715 4207716
MS MSD
92697837001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L ND 5 5 4.8 4.8 96 96 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4207717 4207718
MS MSD
92697837002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L ND 5 5 4.7 4.7 95 95 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:30 PM without the written consent of Pace Analytical Services, LLC.
Page 28 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
QC Batch: 812294 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697837001, 92697837002, 92697837003, 92697837004, 92697837005, 92697837006
METHOD BLANK: 4206176
Matrix:
Water
Associated Lab Samples:
92697837001, 92697837002, 92697837003, 92697837004, 92697837005,
92697837006
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Nitrogen, Nitrate
mg/L
ND
0.040
11/10/23 00:44
Nitrogen, Nitrite
mg/L
ND
0.040
11/10/23 00:44
Nitrogen, NO2 plus NO3
mg/L
ND
0.040
11/10/23 00:44
LABORATORY CONTROL SAMPLE: 4206177
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L 1.5 1.5 103 90-110
Nitrogen, Nitrite mg/L 1 1.0 104 90-110
Nitrogen, NO2 plus NO3 mg/L 2.5 2.6 103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
4206178
4206179
MS
MSD
92697930001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Nitrogen, Nitrate
mg/L
0.26
1.5
1.5
1.8
1.8
101
103
90-110
1
Nitrogen, Nitrite
mg/L
ND
1
1
1.1
1.1
107
109
90-110
2
Nitrogen, NO2 plus NO3
mg/L
0.26
2.5
2.5
2.9
2.9
104
106
90-110
1
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
4206180
4206181
MS
MSD
92697837002
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Nitrogen, Nitrate
mg/L
19.1
1.5
1.5
20.6
20.6
101
104
90-110
0
Nitrogen, Nitrite
mg/L
ND
1
1
1.1
1.0
107
104
90-110
3
Nitrogen, NO2 plus NO3
mg/L
19.1
2.5
2.5
21.6
21.7
103
104
90-110
0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:30 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
QC Batch: 813188 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697837001, 92697837002, 92697837003, 92697837004, 92697837005, 92697837006
METHOD BLANK: 4210464
Matrix:
Water
Associated Lab Samples: 92697837001, 92697837002, 92697837003, 92697837004, 92697837005, 92697837006
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Phosphorus
mg/L
ND
0.050
11/16/2311:37
LABORATORY CONTROL SAMPLE:
4210465
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Phosphorus
mg/L
2.5
2.6
102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4210468 4210469
MS MSD
92696580001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L 1.6 2.5 2.5 4.0 4.0 98 99 90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4210516 4210517
MS MSD
92697768009 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L 0.86 2.5 2.5 3.4 3.3 101 99 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:30 PM without the written consent of Pace Analytical Services, LLC.
Page 30 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
QC Batch: 813517 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697837001, 92697837002, 92697837003, 92697837004, 92697837005, 92697837006
METHOD BLANK: 4212045
Matrix:
Water
Associated Lab Samples: 92697837001, 92697837002, 92697837003, 92697837004, 92697837005, 92697837006
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Chloride
mg/L
ND
1.0
11/15/2316:58
LABORATORY CONTROL SAMPLE:
4212046
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Chloride
mg/L
20
20.9
104 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4212047 4212048
MS MSD
92697837001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 17.4 10 10 27.7 27.7 104 104 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:30 PM without the written consent of Pace Analytical Services, LLC.
Page 31 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
QC Batch: 813070 Analysis Method: SM 531 OB-2014
QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697837001, 92697837002, 92697837003, 92697837004, 92697837005, 92697837006
METHOD BLANK: 4209685
Matrix:
Water
Associated Lab Samples: 92697837001, 92697837002, 92697837003, 92697837004, 92697837005, 92697837006
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Total Organic Carbon
mg/L
ND
1.0
11/14/23 13:15
LABORATORY CONTROL SAMPLE:
4209686
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Total Organic Carbon
mg/L
25
23.9
96 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4209687 4209688
MS MSD
92697397007 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L ND 25 25 23.6 24.0 95 96 90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4209689 4209690
MS MSD
92697473001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L 3.7 25 25 28.5 28.4 99 99 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:30 PM without the written consent of Pace Analytical Services, LLC.
Page 32 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALIFIERS
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
REPORT OF LABORATORY ANALYSIS
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Date: 11 /16/2023 02:30 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Lassoride Pappas SemiAnnual
92697837
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92697837001
MW-6
SM 6200B
812813
92697837002
MW-7R2
SM 6200B
812813
92697837003
MW-8
SM 6200B
812813
92697837006
MW-4
SM 6200B
812813
92697837007
TB-20231108
SM 6200B
812813
92697837001
MW-6
SM 2540C-2015
813022
92697837002
MW-7R2
SM 2540C-2015
813022
92697837003
MW-8
SM 2540C-2015
813022
92697837004
SW-1
SM 2540C-2015
813022
92697837005
SW-2
SM 2540C-2015
813022
92697837006
MW-4
SM 2540C-2015
813022
92697837001
MW-6
SM 9222D-2015
812230
SM 9222D-2015
812231
92697837002
MW-7R2
SM 9222D-2015
812230
SM 9222D-2015
812231
92697837003
MW-8
SM 9222D-2015
812230
SM 9222D-2015
812231
92697837004
SW-1
SM 9222D-2015
812230
SM 9222D-2015
812231
92697837005
SW-2
SM 9222D-2015
812230
SM 9222D-2015
812231
92697837006
MW-4
SM 9222D-2015
812230
SM 9222D-2015
812231
92697837001
MW-6
EPA 350.1 Rev 2.0 1993
812610
92697837002
MW-7R2
EPA 350.1 Rev 2.0 1993
812610
92697837003
MW-8
EPA 350.1 Rev 2.0 1993
812610
92697837004
SW-1
EPA 350.1 Rev 2.0 1993
812610
92697837005
SW-2
EPA 350.1 Rev 2.0 1993
812610
92697837006
MW-4
EPA 350.1 Rev 2.0 1993
812610
92697837001
MW-6
EPA 353.2 Rev 2.0 1993
812294
92697837002
MW-7R2
EPA 353.2 Rev 2.0 1993
812294
92697837003
MW-8
EPA 353.2 Rev 2.0 1993
812294
92697837004
SW-1
EPA 353.2 Rev 2.0 1993
812294
92697837005
SW-2
EPA 353.2 Rev 2.0 1993
812294
92697837006
MW-4
EPA 353.2 Rev 2.0 1993
812294
92697837001
MW-6
EPA 365.1 Rev 2.0 1993
813188
EPA 365.1 Rev 2.0 1993
813694
92697837002
MW-7R2
EPA 365.1 Rev 2.0 1993
813188
EPA 365.1 Rev 2.0 1993
813694
92697837003
MW-8
EPA 365.1 Rev 2.0 1993
813188
EPA 365.1 Rev 2.0 1993
813694
92697837004
SW-1
EPA 365.1 Rev 2.0 1993
813188
EPA 365.1 Rev 2.0 1993
813694
92697837005
SW-2
EPA 365.1 Rev 2.0 1993
813188
EPA 365.1 Rev 2.0 1993
813694
92697837006
MW-4
EPA 365.1 Rev 2.0 1993
813188
EPA 365.1 Rev 2.0 1993
813694
92697837001
MW-6
SM 4500-CI-E-2011
813517
92697837002
MW-7R2
SM 4500-CI-E-2011
813517
92697837003
MW-8
SM 4500-CI-E-2011
813517
92697837004
SW-1
SM 4500-CI-E-2011
813517
92697837005
SW-2
SM 4500-CI-E-2011
813517
92697837006
MW-4
SM 4500-CI-E-2011
813517
92697837001
MW-6
SM 5310B-2014
813070
92697837002
MW-7R2
SM 5310B-2014
813070
92697837003
MW-8
SM 5310B-2014
813070
92697837004
SW-1
SM 5310E-2014
813070
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:30 PM without the written consent of Pace Analytical Services, LLC.
Page 34 of 38

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Lassoride Pappas SemiAnnual
Pace Project No.: 92697837
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
92697837005 SW-2 SM 5310E-2014 813070
92697837006 MW-4 SM 5310B-2014 813070
Date: 11/16/2023 02:30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Analytical
Batch
Page 35 of 38

aceDC# Title: ENV-FRM-HUN1-0083 v02 —
Sample Condition Upon Receipt
.
I Effective Date: 11/14/2022 8:18:30 AM
Laboratory rec iving samples:
Asheville Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville[] Atlanta❑ Kernersville❑
Sample Condition Client Name:Upon Receipt WO# : 92697837
Courler: fed Fx �� Project #: UPS usi35 Client 1111111111111111111111111
❑ Commercial ❑Pace ❑Other, 92697837
Custody Seal Present? El Yes -allo Seals Intact? ❑Yes 1�`No
Packing Material: ❑ Bubble Wrap '5�Bubbie Bags ❑ None ❑ Other
Thermometer:
❑ IR Gun ID: A )=i.f7 Type of ice: XWet ❑clue
�} C �i Correction Factor:
Cooler Temp: " Add/Subtract (T) C
Cooler Temp Corrected (°C):
USDA Regulated Soil (� N/A, water sample)
Did samples originate in a quarantine zone within the United States CA, NY, or SC
trhPrI, mantl?MYes F1Nn
Date/Initials Person Examining ContentsjC j � /�
Biological Tissue Frozen?
❑Yes ❑No �b/A
❑ None
Temp should be above freezing to 6°C
❑Samples out of temp criteria. Samples on ice, coolirig process
has begun
Did samples originate from a foreign source (internationally,
including Hawaii and Puerto Rico)? ❑Yes ❑No
Comments/Discrepancy:
Chain of Custody Present?
1KYes
❑ No
] N/A
1.
Samples Arrived within Hold Time?
NYes
❑ N.
(3 N/A
2.
Short Hold Time Analysis 1c72 hr.)?
Yes
❑ No
❑ N/A
3.
Rush Turn Around Time Requested?
❑ Yes
❑ NO
N/A
4.
Sufficient Volume?
)2es
El No
[I N/A
5.
Correct Containers Used?
-Pace Containers Used?
axes
Wyes
❑No
❑ No
[I N/A
❑ N/A
6.
Containers intact?
Yes
❑ No
❑ N/A
7.
Dissolved analysis: Samples Field Filtered?
[I Yes
No
'�i/A
B.
Sample Labels Match COC?
-includesDate/Time/ID/Analysis Matrix:___
M�Yes
No
ON/A
9.
Headspace in VOA Vials (>5-Gmm)?
❑ Yes
❑ No
❑ N/A
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
El Yes
❑Ycs
El No
❑No
El NIA
[I N/A
11.
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
Lot ID of split containers:
Date/Time:
Date:
Field Data Required? LJYes LJNa
Project Manager SRF Review:
Date:
Page 36 of 38
ni,aIfrav in- ACIR IA pane 1 of ?

�CC
DC#_Title: ENV-FRM-HUN1-0083 v02_Sample Condition Upon Receipt
Effective Date: 11/14/2022 8:18:30 AM
*Check mark top half of box if pH and/or dechlorination is verified and Project #
within the acceptance range for preservation samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
**Bottom half of box is to list number of bottles
***Check all unpreserved Nitrates for chlorine
wa#:92697837
PM: AM8 Due Date: 11/16/23
CLIENT: 93—ALTAMONT
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pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot #
Note: Whenever there is a discrepancy affecting North Carotna conipliancesamples, a copy of this form wN be 5ent to the Ncrth Carolina DENR Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers. Page 37 of 38
n—l+r.,., In- CZGr 3A Panda 7 of ')

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Page 38 Of 38
Preservation
nomcorformance
identified
for
sample.

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
November 16, 2023
Christian Patterson
Anchor QEA
231 Haywood Street
Asheville, NC 28801
RE: Project: Lassonde Pappas WQ
Pace Project No.: 92697939
Dear Christian Patterson:
Enclosed are the analytical results for sample(s) received by the laboratory on November 09, 2023. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
612-473-6801
Project Manager
Enclosures
cc: Jessica Mayers, Anchor QEA
Jennifer Verde, Anchor QEA
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 29

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Lassonde Pappas WQ
Pace Project No.: 92697939
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
CERTIFICATIONS
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
VirginiaNELAP Certification #: 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
VirginiaNELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 29

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Project: Lassonde Pappas WQ
Pace Project No.: 92697939
Analytes
Lab lD Sample ID
Method
Analysts
Reported
Laboratory
92697939001 MW-5
SM 6200B
SAS
63
PASI-C
SM 2540C-2015
JMH1
1
PASI-A
SM 9222D-2015
YEG
1
PASI-A
EPA 350.1 Rev 2.0 1993
NCF
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
3
PASI-A
EPA 365.1 Rev 2.0 1993
Zip
1
PASI-A
SM 4500-CI-E-2011
Zip
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92697939002 MW-9
SM 6200B
SAS
63
PASI-C
SM 2540C-2015
JMH1
1
PASI-A
SM 9222D-2015
YEG
1
PASI-A
EPA 350.1 Rev 2.0 1993
NCF
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
3
PASI-A
EPA 365.1 Rev 2.0 1993
Zip
1
PASI-A
SM 4500-CI-E-2011
Zip
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92697939003 TB- 20231109
SM 6200B
SAS
63
PASI-C
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 29

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas WQ
Pace Project No.: 92697939
Sample: MW-5 Lab ID: 92697939001 Collected: 11/09/23 11:00 Received: 11/09/23 12:14 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical
Services - Charlotte
Benzene
ND
ug/L
0.50
1
11/15/23 04:02
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/15/23 04:02
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/15/23 04:02
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/15/23 04:02
75-27-4
Bromoform
ND
ug/L
0.50
1
11/15/23 04:02
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/15/23 04:02
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/15/23 04:02
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/15/23 04:02
135-98-8
tert-Butyl benzene
ND
ug/L
0.50
1
11/15/23 04:02
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/15/23 04:02
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/15/23 04:02
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/15/23 04:02
75-00-3
Chloroform
ND
ug/L
0.50
1
11/15/23 04:02
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/15/23 04:02
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/15/23 04:02
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/15/23 04:02
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/15/23 04:02
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/15/23 04:02
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/15/23 04:02
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/15/23 04:02
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/15/23 04:02
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/15/23 04:02
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/15/23 04:02
106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/15/23 04:02
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/15/23 04:02
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/15/23 04:02
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/15/23 04:02
75-35-4
cis-1,2-Dichloroethene
111
ug/L
0.50
1
11/15/23 04:02
156-59-2
trans-1,2-Dichloroethene
0.76
ug/L
0.50
1
11/15/23 04:02
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/15/23 04:02
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/15/23 04:02
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/15/23 04:02
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/15/23 04:02
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/15/23 04:02
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
0.50
1
11/15/23 04:02
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/15/23 04:02
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/15/23 04:02
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/15/23 04:02
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/15/23 04:02
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/15/23 04:02
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/15/23 04:02
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/15/23 04:02
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/15/23 04:02
103-65-1
Styrene
ND
ug/L
0.50
1
11/15/23 04:02
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/15/23 04:02
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
11/15/23 04:02
79-34-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:31 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 29

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas WQ
Pace Project No.: 92697939
Sample: MW-5 Lab ID: 92697939001 Collected: 11/09/23 11:00 Received: 11/09/23 12:14 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Tetrachloroethene
169 ug/L
0.50
1
11/15/23 04:02
127-18-4
Toluene
ND ug/L
0.50
1
11/15/23 04:02
108-88-3
1,2,3-Trichlorobenzene
ND ug/L
2.0
1
11/15/23 04:02
87-61-6
1,2,4-Trichlorobenzene
ND ug/L
2.0
1
11/15/23 04:02
120-82-1
1,1,1-Trichloroethane
ND ug/L
0.50
1
11/15/23 04:02
71-55-6
1,1,2-Trichloroethane
ND ug/L
0.50
1
11/15/23 04:02
79-00-5
Trichloroethene
155 ug/L
0.50
1
11/15/23 04:02
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/15/23 04:02
75-69-4
1,2,3-Trichloropropane
ND ug/L
0.50
1
11/15/23 04:02
96-18-4
1,2,4-Trimethylbenzene
ND ug/L
0.50
1
11/15/23 04:02
95-63-6
1,3,5-Trimethylbenzene
ND ug/L
0.50
1
11/15/23 04:02
108-67-8
Vinyl chloride
1.3 ug/L
1.0
1
11/15/23 04:02
75-01-4
m&p-Xylene
ND ug/L
1.0
1
11/15/23 04:02
179601-23-1
o-Xylene
ND ug/L
0.50
1
11/15/23 04:02
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
90 %
70-130
1
11/15/23 04:02
17060-07-0
4-Bromofluorobenzene (S)
96 %
70-130
1
11/15/23 04:02
460-00-4
Toluene-d8 (S)
94 %
70-130
1
11/15/23 04:02
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
125 mg/L
25.0
1
11/14/23 15:26
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015
Pace Analytical Services -Asheville
Fecal Coliforms
ND CFU/100 mL
1.0
1
11/09/23 15:27 11/10/23 13:58
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L
0.10
1
11/15/23 03:52
7664-41-7
353.2 Nitrogen, NO2/1403 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, NO2 plus NO3
0.066 mg/L
0.040
1
11/10/23 01:22
Nitrogen, Nitrate
0.066 mg/L
0.040
1
11/10/23 01:22
14797-55-8
Nitrogen, Nitrite
ND mg/L
0.040
1
11/10/23 01:22
14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
ND mg/L
0.050
1
11/15/2315:32 11/16/2311:59
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
47.2 mg/L
2.0
2
11/15/2317:19
16887-00-6
Date: 11/16/2023 02:31 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 29

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas WQ
Pace Project No.: 92697939
Sample: MW-5 Lab ID: 92697939001 Collected: 11/09/23 11:00 Received: 11/09/23 12:14 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon 1.8 mg/L 1.0 1 11/14/23 18:46 7440-44-0
Date: 11/16/2023 02:31 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 29

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas WQ
Pace Project No.: 92697939
Sample: MW-9 Lab ID: 92697939002 Collected: 11/09/23 10:10 Received: 11/09/23 12:14 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical
Services - Charlotte
Benzene
ND
ug/L
0.50
1
11/15/23 02:12
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/15/23 02:12
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/15/23 02:12
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/15/23 02:12
75-27-4
Bromoform
ND
ug/L
0.50
1
11/15/23 02:12
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/15/23 02:12
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/15/23 02:12
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/15/23 02:12
135-98-8
tert-Butyl benzene
ND
ug/L
0.50
1
11/15/23 02:12
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/15/23 02:12
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/15/23 02:12
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/15/23 02:12
75-00-3
Chloroform
ND
ug/L
0.50
1
11/15/23 02:12
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/15/23 02:12
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/15/23 02:12
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/15/23 02:12
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/15/23 02:12
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/15/23 02:12
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/15/23 02:12
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/15/23 02:12
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/15/23 02:12
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/15/23 02:12
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/15/23 02:12
106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/15/23 02:12
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/15/23 02:12
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/15/23 02:12
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/15/23 02:12
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/15/23 02:12
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/15/23 02:12
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/15/23 02:12
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/15/23 02:12
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/15/23 02:12
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/15/23 02:12
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/15/23 02:12
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
0.50
1
11/15/23 02:12
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/15/23 02:12
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/15/23 02:12
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/15/23 02:12
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/15/23 02:12
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/15/23 02:12
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/15/23 02:12
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/15/23 02:12
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/15/23 02:12
103-65-1
Styrene
ND
ug/L
0.50
1
11/15/23 02:12
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/15/23 02:12
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
11/15/23 02:12
79-34-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:31 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 29

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas WQ
Pace Project No.: 92697939
Sample: MW-9 Lab ID: 92697939002 Collected: 11/09/23 10:10 Received: 11/09/23 12:14 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Tetrachloroethene
ND ug/L
0.50
1
11/15/23 02:12
127-18-4
Toluene
ND ug/L
0.50
1
11/15/23 02:12
108-88-3
1,2,3-Trichlorobenzene
ND ug/L
2.0
1
11/15/23 02:12
87-61-6
1,2,4-Trichlorobenzene
ND ug/L
2.0
1
11/15/23 02:12
120-82-1
1,1,1-Trichloroethane
ND ug/L
0.50
1
11/15/23 02:12
71-55-6
1,1,2-Trichloroethane
ND ug/L
0.50
1
11/15/23 02:12
79-00-5
Trichloroethene
ND ug/L
0.50
1
11/15/23 02:12
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/15/23 02:12
75-69-4
1,2,3-Trichloropropane
ND ug/L
0.50
1
11/15/23 02:12
96-18-4
1,2,4-Trimethylbenzene
ND ug/L
0.50
1
11/15/23 02:12
95-63-6
1,3,5-Trimethylbenzene
ND ug/L
0.50
1
11/15/23 02:12
108-67-8
Vinyl chloride
ND ug/L
1.0
1
11/15/23 02:12
75-01-4
m&p-Xylene
ND ug/L
1.0
1
11/15/23 02:12
179601-23-1
o-Xylene
ND ug/L
0.50
1
11/15/23 02:12
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
94 %
70-130
1
11/15/23 02:12
17060-07-0
4-Bromofluorobenzene (S)
96 %
70-130
1
11/15/23 02:12
460-00-4
Toluene-d8 (S)
98 %
70-130
1
11/15/23 02:12
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
80.0 mg/L
25.0
1
11/14/23 15:36
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2015 Preparation
Method:
SM 9222D-2015
Pace Analytical Services -Asheville
Fecal Coliforms
ND CFU/100 mL
1.3
1.3
11/09/23 15:27 11/10/23 13:58
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L
0.10
1
11/15/23 03:56
7664-41-7
353.2 Nitrogen, NO2/1403 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, NO2 plus NO3
2.4 mg/L
0.040
1
11/10/23 01:17
Nitrogen, Nitrate
2.4 mg/L
0.040
1
11/10/23 01:17
14797-55-8
Nitrogen, Nitrite
ND mg/L
0.040
1
11/10/23 01:17
14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation
Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
ND mg/L
0.050
1
11/15/2315:32 11/16/2312:00
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
8.7 mg/L
1.0
1
11/15/2317:13
16887-00-6
Date: 11/16/2023 02:31 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 8 of 29

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas WQ
Pace Project No.: 92697939
Sample: MW-9 Lab ID: 92697939002 Collected: 11/09/23 10:10 Received: 11/09/23 12:14 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon 2.3 mg/L 1.0 1 11/14/23 19:06 7440-44-0
Date: 11/16/2023 02:31 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 9 of 29

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas WQ
Pace Project No.: 92697939
Sample: TB- 20231109 Lab ID: 92697939003 Collected: 11/09/23 00:00 Received: 11/09/23 12:14 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical
Services - Charlotte
Benzene
ND
ug/L
0.50
1
11/15/23 00:40
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/15/23 00:40
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/15/23 00:40
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/15/23 00:40
75-27-4
Bromoform
ND
ug/L
0.50
1
11/15/23 00:40
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/15/23 00:40
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/15/23 00:40
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/15/23 00:40
135-98-8
tert-Butyl benzene
ND
ug/L
0.50
1
11/15/23 00:40
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/15/23 00:40
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/15/23 00:40
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/15/23 00:40
75-00-3
Chloroform
ND
ug/L
0.50
1
11/15/23 00:40
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/15/23 00:40
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/15/23 00:40
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/15/23 00:40
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/15/23 00:40
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/15/23 00:40
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/15/23 00:40
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/15/23 00:40
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/15/23 00:40
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/15/23 00:40
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/15/23 00:40
106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/15/23 00:40
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/15/23 00:40
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/15/23 00:40
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/15/23 00:40
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/15/23 00:40
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/15/23 00:40
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/15/23 00:40
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/15/23 00:40
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/15/23 00:40
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/15/23 00:40
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/15/23 00:40
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
0.50
1
11/15/23 00:40
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/15/23 00:40
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/15/23 00:40
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/15/23 00:40
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/15/23 00:40
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/15/23 00:40
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/15/23 00:40
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/15/23 00:40
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/15/23 00:40
103-65-1
Styrene
ND
ug/L
0.50
1
11/15/23 00:40
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/15/23 00:40
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
11/15/23 00:40
79-34-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:31 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 29

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas WQ
Pace Project No.: 92697939
Sample: TB- 20231109
Lab ID: 92697939003 Collected:
11/09/23 00:00
Received: 11/09/23 12:14 Matrix: Water
Parameters
Results
Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
6200B MSV
Analytical Method:
SM 6200B
Pace Analytical
Services - Charlotte
Tetrachloroethene
ND
ug/L
0.50
1
11/15/23 00:40
127-18-4
Toluene
ND
ug/L
0.50
1
11/15/23 00:40
108-88-3
1,2,3-Trichlorobenzene
ND
ug/L
2.0
1
11/15/23 00:40
87-61-6
1,2,4-Trichlorobenzene
ND
ug/L
2.0
1
11/15/23 00:40
120-82-1
1,1,1-Trichloroethane
ND
ug/L
0.50
1
11/15/23 00:40
71-55-6
1,1,2-Trichloroethane
ND
ug/L
0.50
1
11/15/23 00:40
79-00-5
Trichloroethene
ND
ug/L
0.50
1
11/15/23 00:40
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
11/15/23 00:40
75-69-4
1,2,3-Trichloropropane
ND
ug/L
0.50
1
11/15/23 00:40
96-18-4
1,2,4-Trimethylbenzene
ND
ug/L
0.50
1
11/15/23 00:40
95-63-6
1,3,5-Trimethylbenzene
ND
ug/L
0.50
1
11/15/23 00:40
108-67-8
Vinyl chloride
ND
ug/L
1.0
1
11/15/23 00:40
75-01-4
m&p-Xylene
ND
ug/L
1.0
1
11/15/23 00:40
179601-23-1
o-Xylene
ND
ug/L
0.50
1
11/15/23 00:40
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
95
%
70-130
1
11/15/23 00:40
17060-07-0
4-Bromofluorobenzene (S)
95
%
70-130
1
11/15/23 00:40
460-00-4
Toluene-d8 (S)
98
%
70-130
1
11/15/23 00:40
2037-26-5
Date: 11/16/2023 02:31 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 29

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ
Pace Project No.: 92697939
QC Batch: 812813 Analysis Method: SM 6200B
QC Batch Method: SM 6200B Analysis Description: 6200E MSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92697939001, 92697939002, 92697939003
METHOD BLANK: 4208360 Matrix:
Associated Lab Samples: 92697939001, 92697939002, 92697939003
Blank
Parameter Units Result
Water
Reporting
Limit
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
0.50
11/15/23 00:04
1,1,1-Trichloroethane
ug/L
ND
0.50
11/15/23 00:04
1,1,2,2-Tetrachloroethane
ug/L
ND
0.50
11/15/23 00:04
1,1,2-Trichloroethane
ug/L
ND
0.50
11/15/23 00:04
1,1-Dichloroethane
ug/L
ND
0.50
11/15/23 00:04
1,1-Dichloroethene
ug/L
ND
0.50
11/15/23 00:04
1,1-Dichloropropene
ug/L
ND
0.50
11/15/23 00:04
1,2,3-Trichlorobenzene
ug/L
ND
2.0
11/15/23 00:04
1,2,3-Trichloropropane
ug/L
ND
0.50
11/15/23 00:04
1,2,4-Trichlorobenzene
ug/L
ND
2.0
11/15/23 00:04
1,2,4-Trimethylbenzene
ug/L
ND
0.50
11/15/23 00:04
1,2-Dibromo-3-chloropropane
ug/L
ND
1.0
11/15/23 00:04
1,2-Dibromoethane (EDB)
ug/L
ND
0.50
11/15/23 00:04
1,2-Dichlorobenzene
ug/L
ND
0.50
11/15/23 00:04
1,2-Dichloroethane
ug/L
ND
0.50
11/15/23 00:04
1,2-Dichloropropane
ug/L
ND
0.50
11/15/23 00:04
1,3,5-Trimethylbenzene
ug/L
ND
0.50
11/15/23 00:04
1,3-Dichlorobenzene
ug/L
ND
0.50
11/15/23 00:04
1,3-Dichloropropane
ug/L
ND
0.50
11/15/23 00:04
1,4-Dichlorobenzene
ug/L
ND
0.50
11/15/23 00:04
2,2-Dichloropropane
ug/L
ND
0.50
11/15/23 00:04
2-Chlorotoluene
ug/L
ND
0.50
11/15/23 00:04
4-Chlorotoluene
ug/L
ND
0.50
11/15/23 00:04
Benzene
ug/L
ND
0.50
11/15/23 00:04
Bromobenzene
ug/L
ND
0.50
11/15/23 00:04
Bromochloromethane
ug/L
ND
0.50
11/15/23 00:04
Bromodichloromethane
ug/L
ND
0.50
11/15/23 00:04
Bromoform
ug/L
ND
0.50
11/15/23 00:04
Bromomethane
ug/L
ND
5.0
11/15/23 00:04
Carbon tetrachloride
ug/L
ND
0.50
11/15/23 00:04
Chlorobenzene
ug/L
ND
0.50
11/15/23 00:04
Chloroethane
ug/L
ND
1.0
11/15/23 00:04
Chloroform
ug/L
ND
0.50
11/15/23 00:04
Chloromethane
ug/L
ND
1.0
11/15/23 00:04
cis-1,2-Dichloroethene
ug/L
ND
0.50
11/15/23 00:04
cis-1,3-Dichloropropene
ug/L
ND
0.50
11/15/23 00:04
Dibromochloromethane
ug/L
ND
0.50
11/15/23 00:04
Dibromomethane
ug/L
ND
0.50
11/15/23 00:04
Dichlorodifluoromethane
ug/L
ND
0.50
11/15/23 00:04
Diisopropyl ether
ug/L
ND
0.50
11/15/23 00:04
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:31 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 29

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ
Pace Project No.: 92697939
METHOD BLANK: 4208360 Matrix:
Associated Lab Samples: 92697939001, 92697939002, 92697939003
Blank
Parameter Units Result
Water
Reporting
Limit
Analyzed
Ethylbenzene
ug/L
ND
0.50
11/15/23 00:04
Hexachloro-1,3-butadiene
ug/L
ND
2.0
11/15/23 00:04
Isopropylbenzene (Cumene)
ug/L
ND
0.50
11/15/23 00:04
m&p-Xylene
ug/L
ND
1.0
11/15/23 00:04
Methyl-tert-butyl ether
ug/L
ND
0.50
11/15/23 00:04
Methylene Chloride
ug/L
ND
2.0
11/15/23 00:04
n-Butylbenzene
ug/L
ND
0.50
11/15/23 00:04
n-Propylbenzene
ug/L
ND
0.50
11/15/23 00:04
Naphthalene
ug/L
ND
2.0
11/15/23 00:04
o-Xylene
ug/L
ND
0.50
11/15/23 00:04
sec-Butylbenzene
ug/L
ND
0.50
11/15/23 00:04
Styrene
ug/L
ND
0.50
11/15/23 00:04
tert-Butyl benzene
ug/L
ND
0.50
11/15/23 00:04
Tetrachloroethene
ug/L
ND
0.50
11/15/23 00:04
Toluene
ug/L
ND
0.50
11/15/23 00:04
trans-1,2-Dichloroethene
ug/L
ND
0.50
11/15/23 00:04
trans- 1,3-Dichloropropene
ug/L
ND
0.50
11/15/23 00:04
Trichloroethene
ug/L
ND
0.50
11/15/23 00:04
Trichlorofluoromethane
ug/L
ND
1.0
11/15/23 00:04
Vinyl chloride
ug/L
ND
1.0
11/15/23 00:04
1,2-Dichloroethane-d4 (S)
%
94
70-130
11/15/23 00:04
4-Bromofluorobenzene (S)
%
95
70-130
11/15/23 00:04
Toluene-d8 (S)
%
97
70-130
11/15/23 00:04
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
4208361
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1,1,2-Tetrachloroethane
ug/L
20
21.5
107
60-140
1,1,1-Trichloroethane
ug/L
20
19.3
96
60-140
1,1,2,2-Tetrachloroethane
ug/L
20
20.4
102
60-140
1,1,2-Trichloroethane
ug/L
20
20.8
104
60-140
1,1-Dichloroethane
ug/L
20
18.2
91
60-140
1,1-Dichloroethene
ug/L
20
19.8
99
60-140
1,1-Dichloropropene
ug/L
20
20.3
102
60-140
1,2,3-Trichlorobenzene
ug/L
20
21.9
109
60-140
1,2,3-Trichloropropane
ug/L
20
19.0
95
60-140
1,2,4-Trichlorobenzene
ug/L
20
20.6
103
60-140
1,2,4-Trimethylbenzene
ug/L
20
21.0
105
60-140
1,2-Dibromo-3-chloropropane
ug/L
20
20.9
105
60-140
1,2-Dibromoethane (EDB)
ug/L
20
21.3
107
60-140
1,2-Dichlorobenzene
ug/L
20
21.3
106
60-140
1,2-Dichloroethane
ug/L
20
18.1
91
60-140
1,2-Dichloropropane
ug/L
20
19.1
96
60-140
1,3,5-Trimethylbenzene
ug/L
20
20.8
104
60-140
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:31 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 29

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ
Pace Project No.: 92697939
LABORATORY CONTROL SAMPLE:
Parameter
4208361
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,3-Dichlorobenzene
ug/L
20
20.7
104
60-140
1,3-Dichloropropane
ug/L
20
19.7
98
60-140
1,4-Dichlorobenzene
ug/L
20
20.4
102
60-140
2,2-Dichloropropane
ug/L
20
15.8
79
60-140
2-Chlorotoluene
ug/L
20
19.8
99
60-140
4-Chlorotoluene
ug/L
20
20.3
101
60-140
Benzene
ug/L
20
19.0
95
60-140
Bromobenzene
ug/L
20
20.6
103
60-140
Bromochloromethane
ug/L
20
20.3
102
60-140
Bromodichloromethane
ug/L
20
19.1
95
60-140
Bromoform
ug/L
20
21.1
105
60-140
Bromomethane
ug/L
20
15.0
75
60-140
Carbon tetrachloride
ug/L
20
20.4
102
60-140
Chlorobenzene
ug/L
20
19.8
99
60-140
Chloroethane
ug/L
20
17.5
88
60-140
Chloroform
ug/L
20
18.3
92
60-140
Chloromethane
ug/L
20
15.3
77
60-140
cis-1,2-Dichloroethene
ug/L
20
18.1
91
60-140
cis-1,3-Dichloropropene
ug/L
20
19.0
95
60-140
Dibromochloromethane
ug/L
20
20.7
104
60-140
Dibromomethane
ug/L
20
20.9
104
60-140
Dichlorodifluoromethane
ug/L
20
19.4
97
60-140
Diisopropyl ether
ug/L
20
17.3
87
60-140
Ethylbenzene
ug/L
20
19.3
96
60-140
Hexachloro-1,3-butadiene
ug/L
20
21.2
106
60-140
Isopropylbenzene (Cumene)
ug/L
20
20.7
103
60-140
m&p-Xylene
ug/L
40
40.1
100
60-140
Methyl-tert-butyl ether
ug/L
20
18.1
90
60-140
Methylene Chloride
ug/L
20
17.0
85
60-140
n-Butylbenzene
ug/L
20
19.9
100
60-140
n-Propylbenzene
ug/L
20
19.6
98
60-140
Naphthalene
ug/L
20
23.1
115
60-140
o-Xylene
ug/L
20
20.9
104
60-140
sec-Butylbenzene
ug/L
20
20.3
101
60-140
Styrene
ug/L
20
21.4
107
60-140
tert-Butyl benzene
ug/L
20
17.0
85
60-140
Tetrachloroethene
ug/L
20
19.8
99
60-140
Toluene
ug/L
20
18.9
94
60-140
trans-1,2-Dichloroethene
ug/L
20
18.0
90
60-140
trans- 1,3-Dichloropropene
ug/L
20
19.0
95
60-140
Trichloroethene
ug/L
20
20.0
100
60-140
Trichlorofluoromethane
ug/L
20
19.6
98
60-140
Vinyl chloride
ug/L
20
15.5
78
60-140
1,2-Dichloroethane-d4 (S)
%
93
70-130
4-Bromofluorobenzene (S)
%
97
70-130
Toluene-d8 (S)
%
97
70-130
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:31 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 29

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ
Pace Project No.: 92697939
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4208362 4208363
MS MSD
92697837001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
21.9
21.2
109
106
60-140 3
1,1,1-Trichloroethane
ug/L
ND
20
20
20.1
19.6
101
98
60-140 3
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
20.3
19.8
102
99
60-140 2
1,1,2-Trichloroethane
ug/L
ND
20
20
20.5
19.7
103
99
60-140 4
1,1-Dichloroethane
ug/L
ND
20
20
19.9
19.6
99
98
60-140 1
1,1-Dichloroethene
ug/L
ND
20
20
20.7
20.4
103
102
60-140 1
1,1-Dichloropropene
ug/L
ND
20
20
21.6
21.3
108
107
60-140 1
1,2,3-Trichlorobenzene
ug/L
ND
20
20
21.0
20.7
105
103
60-140 2
1,2,3-Trichloropropane
ug/L
ND
20
20
19.9
18.8
99
94
60-140 6
1,2,4-Trichlorobenzene
ug/L
ND
20
20
20.9
21.1
104
105
60-140 1
1,2,4-Trimethylbenzene
ug/L
ND
20
20
21.5
21.6
107
108
60-140 1
1,2-Dibromo-3-chloropropane
ug/L
ND
20
20
19.8
19.9
99
100
60-140 1
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
21.2
20.3
106
102
60-140 4
1,2-Dichlorobenzene
ug/L
ND
20
20
21.2
20.9
106
105
60-140 1
1,2-Dichloroethane
ug/L
ND
20
20
18.9
17.9
95
90
60-140 5
1,2-Dichloropropane
ug/L
ND
20
20
20.5
19.7
103
98
60-140 4
1,3,5-Trimethylbenzene
ug/L
ND
20
20
21.6
21.3
108
106
60-140 2
1,3-Dichlorobenzene
ug/L
ND
20
20
21.0
21.2
105
106
60-140 1
1,3-Dichloropropane
ug/L
ND
20
20
20.1
19.4
101
97
60-140 3
1,4-Dichlorobenzene
ug/L
ND
20
20
20.1
20.0
101
100
60-140 1
2,2-Dichloropropane
ug/L
ND
20
20
21.1
20.5
105
103
60-140 3
2-Chlorotoluene
ug/L
ND
20
20
20.8
20.5
104
102
60-140 1
4-Chlorotoluene
ug/L
ND
20
20
20.5
21.1
102
105
60-140 3
Benzene
ug/L
ND
20
20
20.6
20.4
103
102
60-140 1
Bromobenzene
ug/L
ND
20
20
20.6
20.2
103
101
60-140 2
Bromochloromethane
ug/L
ND
20
20
20.8
19.8
104
99
60-140 5
Bromodichloromethane
ug/L
ND
20
20
19.3
19.0
96
95
60-140 2
Bromoform
ug/L
ND
20
20
19.8
19.3
99
97
60-140 2
Bromomethane
ug/L
ND
20
20
22.2
22.3
111
112
60-140 1
Carbon tetrachloride
ug/L
ND
20
20
20.8
20.7
104
104
60-140 0
Chlorobenzene
ug/L
ND
20
20
20.6
20.4
103
102
60-140 1
Chloroethane
ug/L
ND
20
20
21.1
20.9
105
105
60-140 1
Chloroform
ug/L
ND
20
20
19.2
19.0
96
95
60-140 1
Chloromethane
ug/L
ND
20
20
17.9
17.6
90
88
60-140 2
cis-1,2-Dichloroethene
ug/L
ND
20
20
19.7
19.3
98
97
60-140 2
cis-1,3-Dichloropropene
ug/L
ND
20
20
20.5
20.1
102
101
60-140 2
Dibromochloromethane
ug/L
ND
20
20
20.1
20.2
101
101
60-140 0
Dibromomethane
ug/L
ND
20
20
21.2
20.4
106
102
60-140 4
Dichlorodifluoromethane
ug/L
ND
20
20
17.9
17.2
89
86
60-140 4
Diisopropyl ether
ug/L
ND
20
20
18.6
18.1
93
90
60-140 3
Ethylbenzene
ug/L
ND
20
20
20.8
20.5
104
103
60-140 1
Hexachloro-1,3-butadiene
ug/L
ND
20
20
21.3
21.4
107
107
60-140 1
Isopropylbenzene (Cumene)
ug/L
ND
20
20
22.1
21.8
111
109
60-140 2
m&p-Xylene
ug/L
ND
40
40
41.3
41.4
103
104
60-140 0
Methyl-tert-butyl ether
ug/L
ND
20
20
18.5
17.5
92
87
60-140 5
Methylene Chloride
ug/L
ND
20
20
17.8
17.4
89
87
60-140 2
Results presented on this page are in the units indicated
by the "Units"
column
except where
an alternate unit
is presented to the right
of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:31 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 29

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ
Pace Project No.: 92697939
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
4208362
4208363
MS
MSD
92697837001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
n-Butylbenzene
ug/L
ND
20
20
21.3
21.1
107
106
60-140
1
n-Propylbenzene
ug/L
ND
20
20
20.5
20.4
103
102
60-140
1
Naphthalene
ug/L
ND
20
20
21.5
20.8
108
104
60-140
3
o-Xylene
ug/L
ND
20
20
21.0
21.0
105
105
60-140
0
sec-Butylbenzene
ug/L
ND
20
20
21.2
21.1
106
106
60-140
0
Styrene
ug/L
ND
20
20
21.9
21.3
110
106
60-140
3
tert-Butyl benzene
ug/L
ND
20
20
17.5
17.6
87
88
60-140
1
Tetrachloroethene
ug/L
ND
20
20
21.2
21.3
106
106
60-140
0
Toluene
ug/L
ND
20
20
20.1
19.8
100
99
60-140
1
trans-1,2-Dichloroethene
ug/L
ND
20
20
20.0
19.9
100
99
60-140
1
trans- 1,3-Dichloropropene
ug/L
ND
20
20
20.4
19.9
102
100
60-140
3
Trichloroethene
ug/L
ND
20
20
21.1
21.1
106
105
60-140
0
Trichlorofluoromethane
ug/L
ND
20
20
20.1
20.0
100
100
60-140
0
Vinyl chloride
ug/L
ND
20
20
18.9
18.3
94
92
60-140
3
1,2-Dichloroethane-d4 (S)
%
89
85
70-130
4-Bromofluorobenzene (S)
%
99
98
70-130
Toluene-d8(S)
%
98
98
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:31 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 29

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ
Pace Project No.: 92697939
QC Batch: 813022 Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697939001, 92697939002
METHOD BLANK: 4209564 Matrix: Water
Associated Lab Samples: 92697939001, 92697939002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 11/14/23 15:19
LABORATORY CONTROL SAMPLE: 4209565
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Dissolved Solids mg/L 250 256 102 90-110
SAMPLE DUPLICATE: 4209566
92697693034 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 85.0 83.0 2
SAMPLE DUPLICATE: 4209567
92698167003 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 39.0 45.0 14
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:31 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 29

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ
Pace Project No.: 92697939
QC Batch: 812505 Analysis Method: SM 9222D-2015
QC Batch Method: SM 9222D-2015 Analysis Description: 9222D Fecal Coliform(MF) -AVL
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697939001, 92697939002
METHOD BLANK: 4207011 Matrix: Water
Associated Lab Samples: 92697939001, 92697939002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Fecal Coliforms CFU/100 mL ND 1.0 11/10/23 13:58
SAMPLE DUPLICATE: 4207012
Parameter
Fecal Coliforms
92697939002 Dup
Units Result Result RPD Qualifiers
CFU/100 mL ND ND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:31 PM without the written consent of Pace Analytical Services, LLC.
Page 18 of 29

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ
Pace Project No.: 92697939
QC Batch: 813274 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697939001, 92697939002
METHOD BLANK: 4210891
Matrix:
Water
Associated Lab Samples: 92697939001, 92697939002
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Nitrogen, Ammonia
mg/L
ND
0.10
11/15/23 03:30
LABORATORY CONTROL SAMPLE:
4210892
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Nitrogen, Ammonia
mg/L
5
4.9
98 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4210893 4210894
MS MSD
92697823002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 36.0 5 5 40.9 41.0 98 99 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4210895 4210896
MS MSD
92697933001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L ND 5 5 4.8 4.8 97 96 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:31 PM without the written consent of Pace Analytical Services, LLC.
Page 19 of 29

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ
Pace Project No.: 92697939
QC Batch: 812294 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697939002
METHOD BLANK: 4206176
Matrix:
Water
Associated Lab Samples: 92697939002
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Nitrogen, Nitrate
mg/L
ND
0.040
11/10/23 00:44
Nitrogen, Nitrite
mg/L
ND
0.040
11/10/23 00:44
Nitrogen, NO2 plus NO3
mg/L
ND
0.040
11/10/23 00:44
LABORATORY CONTROL SAMPLE: 4206177
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L 1.5 1.5 103 90-110
Nitrogen, Nitrite mg/L 1 1.0 104 90-110
Nitrogen, NO2 plus NO3 mg/L 2.5 2.6 103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
4206178
4206179
MS
MSD
92697930001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Nitrogen, Nitrate
mg/L
0.26
1.5
1.5
1.8
1.8
101
103
90-110
1
Nitrogen, Nitrite
mg/L
ND
1
1
1.1
1.1
107
109
90-110
2
Nitrogen, NO2 plus NO3
mg/L
0.26
2.5
2.5
2.9
2.9
104
106
90-110
1
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
4206180
4206181
MS
MSD
92697837002
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Nitrogen, Nitrate
mg/L
19.1
1.5
1.5
20.6
20.6
101
104
90-110
0
Nitrogen, Nitrite
mg/L
ND
1
1
1.1
1.0
107
104
90-110
3
Nitrogen, NO2 plus NO3
mg/L
19.1
2.5
2.5
21.6
21.7
103
104
90-110
0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:31 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 29

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ
Pace Project No.: 92697939
QC Batch: 812295 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697939001
METHOD BLANK: 4206182
Matrix:
Water
Associated Lab Samples: 92697939001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Nitrogen, Nitrate
mg/L
ND
0.040
11/10/23 01:18
Nitrogen, Nitrite
mg/L
ND
0.040
11/10/23 01:18
Nitrogen, NO2 plus NO3
mg/L
ND
0.040
11/10/23 01:18
LABORATORY CONTROL SAMPLE: 4206183
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L 1.5 1.5 103 90-110
Nitrogen, Nitrite mg/L 1 1.1 106 90-110
Nitrogen, NO2 plus NO3 mg/L 2.5 2.6 104 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
4206184
4206185
MS
MSD
92697939001 Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result Conc.
Conc.
Result
Result
% Rec
% Rec
Limits RPD Qual
Nitrogen, Nitrate
mg/L
0.066 1.5
1.5
1.6
1.6
102
100
90-110 2
Nitrogen, Nitrite
mg/L
ND 1
1
1.1
1.1
107
108
90-110 1
Nitrogen, NO2 plus NO3
mg/L
0.066 2.5
2.5
2.7
2.7
104
103
90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:31 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 29

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ
Pace Project No.: 92697939
QC Batch: 813188 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697939001, 92697939002
METHOD BLANK: 4210464
Matrix:
Water
Associated Lab Samples: 92697939001, 92697939002
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Phosphorus
mg/L
ND
0.050
11/16/2311:37
LABORATORY CONTROL SAMPLE:
4210465
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Phosphorus
mg/L
2.5
2.6
102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4210468 4210469
MS MSD
92696580001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L 1.6 2.5 2.5 4.0 4.0 98 99 90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4210516 4210517
MS MSD
92697768009 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L 0.86 2.5 2.5 3.4 3.3 101 99 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:31 PM without the written consent of Pace Analytical Services, LLC.
Page 22 of 29

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ
Pace Project No.: 92697939
QC Batch: 813517 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697939001, 92697939002
METHOD BLANK: 4212045
Matrix:
Water
Associated Lab Samples: 92697939001, 92697939002
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Chloride
mg/L
ND
1.0
11/15/2316:58
LABORATORY CONTROL SAMPLE:
4212046
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Chloride
mg/L
20
20.9
104 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4212047 4212048
MS MSD
92697837001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 17.4 10 10 27.7 27.7 104 104 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:31 PM without the written consent of Pace Analytical Services, LLC.
Page 23 of 29

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ
Pace Project No.: 92697939
QC Batch: 813070 Analysis Method: SM 531 OB-2014
QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92697939001, 92697939002
METHOD BLANK: 4209685
Matrix:
Water
Associated Lab Samples: 92697939001, 92697939002
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Total Organic Carbon
mg/L
ND
1.0
11/14/23 13:15
LABORATORY CONTROL SAMPLE:
4209686
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Total Organic Carbon
mg/L
25
23.9
96 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4209687 4209688
MS MSD
92697397007 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L ND 25 25 23.6 24.0 95 96 90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4209689 4209690
MS MSD
92697473001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L 3.7 25 25 28.5 28.4 99 99 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:31 PM without the written consent of Pace Analytical Services, LLC.
Page 24 of 29

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALIFIERS
Project: Lassonde Pappas WQ
Pace Project No.: 92697939
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:31 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 29

ceo
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Lassonde Pappas WQ
92697939
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92697939001
MW-5
SM 6200B
812813
92697939002
MW-9
SM 6200B
812813
92697939003
TB-20231109
SM 6200B
812813
92697939001
MW-5
SM 2540C-2015
813022
92697939002
MW-9
SM 2540C-2015
813022
92697939001
MW-5
SM 9222D-2015
812505
SM 9222D-2015
812507
92697939002
MW-9
SM 9222D-2015
812505
SM 9222D-2015
812507
92697939001
MW-5
EPA 350.1 Rev 2.0 1993
813274
92697939002
MW-9
EPA 350.1 Rev 2.0 1993
813274
92697939001
MW-5
EPA 353.2 Rev 2.0 1993
812295
92697939002
MW-9
EPA 353.2 Rev 2.0 1993
812294
92697939001
MW-5
EPA 365.1 Rev 2.0 1993
813188
EPA 365.1 Rev 2.0 1993
813694
92697939002
MW-9
EPA 365.1 Rev 2.0 1993
813188
EPA 365.1 Rev 2.0 1993
813694
92697939001
MW-5
SM 4500-CI-E-2011
813517
92697939002
MW-9
SM 4500-CI-E-2011
813517
92697939001
MW-5
SM 5310B-2014
813070
92697939002
MW-9
SM 5310B-2014
813070
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2023 02:31 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 29

�ce' DC#_Title: ENV-FRM-HUN1.0083 v02 Sample Condition Upon Receipt
' 141J1EL 5?i/�:S
Effective Date: 11/W2022 8:18:30 AM
Laboratory receiving samples:
Asheville Eden[] Greenwood ❑ Huntersville ❑ Raleigh❑ MechanMechanicsville[:]Atlanta❑ Kernersville❑
Sample • •, • Client Name: Project #: [WO#:92697939
y
Courier: Fed Ex UPS LISPS Client 11111111111111111111111
❑ Commercial ❑ Pace ❑ Other: 92697939
Custody Seal Present? ❑Yes P5N0 Seals Intact? ❑Yes �No �
Date/Initials Person Facamining Contents.—kawau
Parking Material: El Bubble Wrapubble Bags ❑None ❑ Other Biological Tissue Fir Zen?
Thermometer: ❑ Yes El No J!9 N/A
❑ IR Gun ID: (l TosZ Type of Ice: %et ❑ Blue
7 7 _ Correction Factor:
Cooler Temp: Add/Subtract (°C)
Cooler Temp Corrected (Q: (�
USDA Regulated Soil ( N/A, water sample)
[)id samples originate in a quarantine zone within the United States: CA, NY, or SC
n mn
❑ None
Temp should be above freezing to WC
❑Samplesout of temp criteria. Samples on ice,cooling process
has begun
Did samples originate from a foreign source (internationally,
includine Hawaii and Puerto Rico)? El Yes ❑No
Comments/Discre panty:
Chain of Custody Present?
Yes
❑ No
] N/A
1.
Samples Arrived within Hold Time?
es
❑ No
❑ N/A
2.
Short Hold Time Analysis (<72 hr.)?
es
❑ No
❑ N/A
3.
Rush Turn Around Time Requested?
[I Yes
[I No
>rVIA
4.
5ufficientVolume?
Ayes
❑No
❑N/A
S.
Correct Containers Used?
Pace Containers Used?
Yes
Wes
❑ No
❑ No
❑ N/A
❑ N/A
6.
Containers Intact?
ky—es
❑ No
❑ N/A
7.
Dissolved analysis: Samples Field Filtered?
El Yes
El No
*LSJN/A
8.
Sample Labels Match COC?
-IncIudesDate/Ti me/ID/Analysis Matrix:___
Yes
T
1
❑ No
❑ N/A
9.
Headspace in VOA Vials (>5-Gmm)?
'Wes
❑ No
❑ WA
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
P� m
V[ Cs
❑No
❑ No
❑N/A
❑ N/A
11.
COMMENTS/SAMPLE DISCREPANCY
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
Date/Time:
Date:
Field Data Required f LJ Yes LJ No
Project Manager SRF Review:
Date:
Page 27 of 29
()llnitrov in. RQR1d Dona i of 7

-face
Mtst[tS44.KEll
DC#_Title: ENV-FRM-HUN1-0083 v02_Sample Condition Upon Receipt
I Effective Date: 11/14/2022 8.18:30 AM
*Check mark top half of box if pH and/or dechlorination is verified and Project #
within the acceptance range for preservation samples.
Fxceptions: VOA, CDliform, TOC, oil and Grease, DRO/8015 (water) DOC, LLHg
**Bottom half of box is to list number of bottles
***Check all unpreserved Nitrates for chlorine
wp#:92697939
PM: AMB Due Date: 11/16/23
CLIENT: 93—ALTAMONT
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pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservatlon
adjusted
Amount of Preservative
added
Lot #
Note: Wheneverthereisa discrepancy affecting North Carolina compliance samples, a copy of this formwill be sent to the North Carolina DENR Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers. Page 28 of 29
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Page 29 of 29

Attachment 2
Well Sampling Logs and Instrument
Calibration Data Sheet

IiIizANCHOR
QE w
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Low -Flow Sampling Log
well lm. MW-4
Project Name: Lassonde Pappas WQ Monitoring Date: 1 UL.3
Project Number: C31482-01.01 Task 5 Weather. -�dp
Project Location: Hendersonville, NC Facility ID or Permit # (f applicable): Permit No. WQ0004797
Sample Collector(s): C, ?R i T. �rrrwto(/. Sample ID (on COC): MW-4- '^'k /!cm
Well Diameter: 2 in Arrive at Well: j-1-3-0
Screen Interval: 5-15 ft bgs Start Time: 133 7
Well Depth (as constructed): 15 ft bgs Sample Time: /*0
Depth to Water. C{• $$ ft Leave Well: 1 f
Measuring Point: TOC_E Well Type: ya5tick Up ❑Flush Mount
Depth of Pump Intake: 14 �� ft Tagged Bottom: 1Z. 03 ft4iiYJ'_' at (time): C�
Pump Used (circle): Peristaltic Bladder Other (describe): Purge Rate: �j�4y�
Comments: rT(� A d✓( % 3 �' �/{„! (!y IvyG } ;NlR tC�/gpely , >�/�1,,r /r�C 2,�� ry l Volume Purged: 3
Hi _ .5�7 ��/� Pump Speed: o, 9
Time
DTW (feet)
Temperature VQ
Dissolved Oxygen
(mg/L)
Specific
Conductivity
(pmhos/cm)
PH (S.U.)
report to 0.1 S.U.
Oxidation
Reduction
Potential (m%q
Turbidity (NTU)
!
1 •03
d. a�
S,1
U. l
/. 13
. Oq
I •Z
1+2
/ .3
5.2
V. 3
i1 _Y?
/34-4
/040
2
0-s3
I
--JI
SE. 3
4
0
0. s
5
:-1
1353
to.//
/
0-59
511
.13
135C
lo.11
0. EO
/
0,83
/ 02
I -3
0.
/
'f�
Sample Analyst Signature: �y
Sample Analyst
Name:
a,'t �(� pc �i(
Date:
Notes:
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity +/- 3% Conductivity, +/- 0.7 pH unit,' +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff member's initials and date.
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445
5. 1 pmho/cm = 1 pS/cm
Abbreviations:
Method Reference:
"C: degrees Celsius S.U.: standard units
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter ft: feet
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter in: inches
DO: SM 4500 O G-2016
mV: millivolt bgs: below ground surface
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units TOO top of casing
Turbidity: SM 2130 B-2011
Page 2 of 7

A-14 ANCHOR
Q�4..c.c�
e.+c-Alf
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Low -Flow Sampling Log
well ID: MW-5
Project Name: Lassonde Pappas WQ Monitoring
Project Number: C31482-01.01 Task 5
Project Location: Hendersonville, NC
Sample Collector(s): C- AA tallm T Arm'a?!
Well Diameter. 2
Screen Interval: 9-19
Well Depth (as constructed): 19
Depth to Water. /a,O o
Measuring Point TOC 1
Depth of Pump Intake:
Pump Used (circle): Peristaltic Bladder
Comments: Jj� nQA /6��, 6W R/�
�Ip • sr 0 P
Date: � fa lzay"33
Weather. 00 C/fir
Facility ID or Permit # (if applicable): Permit No. W00004797
Sample ID (on COC): MW-5- UZ,51 Opt
in Arrive at Well: / Oa %
ft bgs Start Time: ) d311-f
ft bgs Sample Time: 0
ft Leave Well: I2
Well Type: 14Stick Up h,.kFlush Mount
ft Tagged Bottom: I ft at (time):
Other (describe): —ems Purge Rate:
3sTl. ow /w'G ,' 95'0 hL�„�t,!a Total Volume Purged:
/LV_q—• — Pump Speed:
2JUML�^v�!
Time
DTw (feet)
Temperature (°C)
Dissolved Oxygen
(mg/L)
Specific
Conductivity
(Nmhos/cm)
pH (S.U.)
report to 0.1 S.U.
Oxidation
Reduction
Potential (mV)
Turbidity (NTU)
10
I 6
Vd-Z
//1.6
1_1
1040
Il•z
.1
2iJ•
9
/0
Q,
21L- Z
S. if
/
If 1. SIT
S.
S . 0
✓.
lI.
2
'LIZ.G
.S
I.22
6
0. 4
JO-E.
It
Z2 . !
q
I - SAt
ri.so
201-'1
5
/ . 9
.2Y,
In
II.gI
0
/.2_0
Sample Analyst Signature:
Sample Analyst
Name:
C/�`y�f>� ��,c�
Date:I//QQ�3
Notes:
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity; +/- 3%Conductivity; +/- 0.7 pH unite +/- 10mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff member's initials and date.
3. Samples are analyzed immediately upon collection. L,
4. NC Field Laboratory Certificate Number 5445
5. 1 pmho/cm = 1 pS/cm
Abbreviations:
Method Reference:
°C: degrees Celsius S.U.: standard units
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter ft: feet
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter in: inches
DO: SM 4500 O G-2016
mv: millivolt bgs: below ground surface
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units TOC: top of casing
Turbidity: SM 2130 B-2011
1
Page 3 of 7

ANCHOR
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Low -Flow Sampling Log
well ID: MW-6
Project Name: Lassonde Pappas WQ Monitoring
Date: fI 9/Zd
Project Number: C31482-01.01 Task 5
Weather. . 'ff-01ir-,/ta2-
Project Location: Hendersonville, NC
Facility ID or Permit # (if applicable): Permit No. W00004797
Sample Collector(s): C.SPA T • q��cwoo
Sample ID (on COC): MW-6- 20L31/0a
Well Diameter. 2
in
Arrive at Well: 1/30
Screen Interval: 5-10
ftbgs
Start Time: 1138
Well Depth (as constructed): 10
ft bgs
Sample Time: 12 ZS
Depth to Water.. .Q�
ft
Leave Well: 1313
Measuring Point TOC
Depth of Pump Intake: ' ��, S rV W&AI
ft
Well Type: gStick U
Tagged Bottom: �■ rft
❑Flush Mount
at (time):
Pump Used (circle): Peristaltic Bladder
Other (describe):
Purge Rate:
Comments: R/s �� //� S F/afr p� f /�rl���fak/y , cL,., /apt 30p1,,,(�Total Volume Purged:
�(�(r
tee � wJ ,R ,vA 10 31•'111ro HIS (50,4-&A) . ! � 48.3 Na ;t,`r;,//
Pump Speed:
Specific
Oxidation
Dissolved Oxygen
Conductivity
pH (S.U.)
Reduction
Time
DTw (feet)
Temperature ("C)
(mg/L)
(pmhos/cm)
report to 0.1 S.U.
Potential (m1)
Turbidity (NTU)
.C3
.3
2.S1
2.3
5.q
// -2
T- U
1at
- 073
3.3
/0 8.
q7-.1
.�
1 sl
10. 5
I -3
13. It5
S.
q&. /
-7. zS
/a.
1. 7
0. 4
S._1
. a
. 8 /
2.11
q/•-7
3_S
/zoo
1 /. Sz
__SAII
a.
..5
►1� �. 8
/
//. Z
12.1
G. 3I
_3
(
//.SI
.3
Iz/. a
22.2
a
11. S/
/0/.
/9C, 3.9
/
/I.5J
2 2.
5. 1l
. d
11
//.
ZO I
C
257.
/ 3#A
/Zls1
5
0.
S
Z -5
C
./3.5- S
S_
l22I
ll_
SC1.
�j
Sample Analyst Signature.
--(!�/`� �
Sample Analyst
Name:
/�
01kH�1� �lyd - 10,0
Date: IfIdloc"t,T�
Notes:
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity, +/- 3% Conductivity; +/- 0.1 pH unit, +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff member's initials and date.
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445
S. 1 pmho/cm = 1 pS/cm
Abbreviations:
Method Reference:
"C: degrees Celsius S.U.: standard units
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter ft: feet
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter in: inches
DO: SM 4500 O G-2016
mv: millivolt bgs: below ground surface
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units TOC: top of casing
Turbidity: SM 2130 8-2011
N�
(/S2 D"it -��'`"� 9i, L q •1 Igo
tV0 FIOW rot 00 M 111n
Page 4 of 7

ANCHOR
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Low -Flow Sampling Log
well ID: MW-7112
Project Name: Lassonde Pappas WQ Monitoring Date: l/ B 2-OZ
Project Number: C31482-01.01 Task 5 Weather: Cj• Cl
Project Location: Hendersonville, NC Facility ID or Permit # (f applicable): Permit No. WQ0004797
Sample Collector(s): �_ ��] �� T, Aa~vvi Sample ID (on COC): MW-7R2- 2,02,3110E
Well Diameter. 2 in Arrive at Well: /Q3
Screen Interval: 5-15 ft bgs Start Time:
Well Depth (as constructed): 15 ft bgs Sample Time:
Depth to Water:_2 'L ft Leave Well:
Measuring Point TOC Well Type: xStick Up I - o�lush Mount
Depth of Pump Intake: 12 ft Tagged Bottom: / 7- a A ft at (time): j 2
Pump Used (circle): Peristaltic Bladder Other (describe): 1 _ Purge Rate:
t
Comments: �� 4� liC1 q't_ Flow orQstj��/ 10 #T' chow /AJ}C, 7 -9fs ��y Total Volume Purged: r �M
PtNtc` &Ae ll a Pump Speed:
Time
DTW (feet)
Temperature (*Q
Dissolved Oxygen
(mg/L)
Specific
Conductivity
(pmhos/cm)
pH (S.U.)
report to 0.1 S.U.
Oxidation
Reduction
Potential (mV)
Turbidity (NTU)
/Z. Z 3
2 - 6
.2
4S.
/
.23
16.E
. -40
Z.2
1 S.S
0.98
.116
0
1 6
1
d.
/Z_J - I
0-sc'
1051
1Z. 2 3
36-G S
, 6
l /8.
0—co
//UZI
12.
2•R3
c"G
6
//6.3
0.47
1Zo Jr,
Z• qv
J.
/✓/.0
v. JCB
!
IZ.
2-90
CT.fy
Sample Analyst Signature:
Sample Analyst
Name:
C rff1,AR J?(GI^ivj&4
Date:
Notes:
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity, +/- 3% Conductivity, +/- 0.1 pH unit,, +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date.
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445
5.1 pmho/cm = 1 pS/cm
Abbreviations:
Method Reference:
°C: degrees Celsius S.U.: standard units
Temperature: SM 2550 B-2010
Nmhos/cm: micromhos per centimeter ft: feet
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter in: inches
DO: SM 4500 O G-2016
mv: millivolt bgs: below ground surface
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units TOC: top of casing
Turbidity: SM 2130 B-2011
Page 5 of 7

ANCHOR
!1F A�+l'� 4 .4..�i
�aLb..c..L�
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Low -Flow Sampling Log
1well ID: MW-8
Project Name: Lassonde Pappas WQ Monitoring Date: /I
ZS& 023
Project Number: C31482-01.01 Task 5 Weather: SJ `rr C leA✓-
Project Location: Hendersonville, NC Facility ID or Permit # (if applicable): Permit No. WQD004797
Sample Collector(s): a f1Cej % Rr v/ Sample ID (on COC): MW-8- 20Z3 / f(y
Well Diameter. 2 in Arrive at Well: 0,121
Screen Interval: 3-13 ft bgs Start Time: Q-141/
Well Depth (as constructed): 13 ft bgs Sample Time: 1017—
Depth to Water. !l. ► o ft Leave Well: I0.32
Measuring Point TOC Well Type: 1aStick Up f❑Flush Mount
Depth of Pump Intake: / 2 ft Tagged Bottom: 3 . Cis 'Of{ r at (time):
Pump Used (circle): Peristaltic Bladder Other (describe): _ ` I Purge Rate:
Comments: FKmA oA lly F/6w id,, w-J (71IS. 2 C® -mcIA m T/y� � Total Volume Purged:
-300 -Z'I-A4 , Pump Speed:
�vZ�
30rJ
gGd, L
�Z
Time
DTw (feet)
Temperature (*Q
Dissolved Oxygen
(mg/L)
Specific
Conductivity
(pmhos/cm)
pH (S.U.)
report to 0.1 S.0
Oxidation
Reduction
Potential (mV)
Turbidity (NTU)
�t
q
1. a
6
U
d.
QSO
/2
,l
0,cif
SU
f,5
J'tS.
q
O q 5
/• 1 Z
. 2
0. q 2
3.9
G. P
31,_1
O. ,t`!
S
2
15.
0117C
I
a.5
Y.3
Q. U
! Z
/J,
CG7
RZO
C, 6
SZ- 2
0-col
U OZ
! .
IS.
a._5*9
J
6.6,
0 -3$
009
.
t-,
6! .
1008I.
s.
Sample Analyst Signature: G//,C�`
Sample Analyst
Name:/�,ff�
fg{f fps
Date: 111.8/26"7
Notes:
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity,, +/- 3% Conductivity,* +/ 0.7 pH unit; +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff member's initials and date.
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445
5. 1 pmho/cm = 1 pS/cm
Abbreviations:
°C: degrees Celsius
S.U.: standard units
pmhos/cm: micromhos percentimeter
ft: feet
mg/L: milligrams per liter
in: inches
mv: millivolt
bgs: below ground surface
NTU: nephelometric turbidity units
TOC: top of casing
Method Reference:
Temperature: SM 2550 B-2010
Specific conductivity: EPA Method 120.1, Rev. 1982
DO: SM 4500 O G-2016
pH: SM 4500-H' B-2011
Turbidity: SM 2130 B-2011
Page 6 of 7

ANCHOR
�cLEAn�.�..�.�
f..6.i.�
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Low -Flow Sampling Log
iWell ID: MW-9
Project Name: Lassonde Pappas WQ Monitoring
Date:
Project Number: C31482-01.01 Task 5
Weather. Qf C/,
Project Location: Hendersonville, NC
Facility ID or Permit # (if applicable): Permit No. W00004797
Sample Collector(s): C- PA 9-krJon
J
7, Arawoo!/
Sample ID (on COC): MW-9- 4V //(Jq
Well Diameter. 2
F
in
Arrive at Well: 040C)
Screen Interval: -1�
ft bgs
Start Time: 0 926
Well Depth (as constructed): 1
ftbgs
Sample Time: f o! 6
Depth to Water. �,2
ft
Leave Well: /Q %-
Measuring Point TOC
Well Type: mStick Up
"Uysh Mount
Depth of Pump Intake: / 1
it
Tagged Bottom: 1 03
at (time):
Pump Used (circle): Peristaltic Bladder
Other (diescrbe):
Purge Rate:
Zj p y
Comments: 06%%0 d n
/
PW ps13W4-,1
p44,4tembl,
FJW /y/ Total Volume Purged:
, ?j 00
6 361D7w VIP
%fw�uA OAP J�/d.
@6►35.Q Hz Pump speed:
3S.Ol�
Specific
Oxidation
Dissolved Oxygen
Conductivity
pH (S.U.)
Reduction
Time
DTW (feet)
Temperature (°C)
(mg/L)
(pmhos/cm)
report to 0.1 S.U.
Potential (mV)
Turbidity (NTU)
OIZZ tnAP
1 ,9
/ 1.
/3.4I
a ,7r, 6#z
11C. 17
a2$
, Z
- 0
Ids-s
19.
9
To. 0
.0
l
qJ-4
7.P-0
. Z
8.0
1
n
�S
• g
r/1..
S,
i_ /
5.5
5.2
z
1. /0
/36 I
•Z
't5.
1
d
0.8
] I. 5
S. 2
31J
/
09S2,!,
J
Z
09s
! r
//S.9
S. z3�-
I
01s
G. Ss
!
a.ss
_­1
5.2
.o
Id
s
s
Sample Analyst Signature:
Sample Analyst
Name:
C�rlS�i K0 %w TPi}Jy/!
Date:
Notes;
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity, +/- 3% Conductivity; +/- 0.1 pH unit +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff member's initials and date.
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445
S. 1 pmho/cm = 1 pS/cm
Abbreviations:
Method Reference:
°C: degrees Celsius S.U.: standard units
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter ft: feet
Specific conductivity. EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter in: inches
DO: SM 45000 G-2016
mV: millivolt bgs: below ground surface
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units TOC: top of casing
Turbidity: SM 2130 B-2011
Page 7 of 7

ANCHOR
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Surface Water Sampling Log
Location ID:
SW-1
Project Name: Lassonde Pappas WQ Monitoring
Date:
%I ,8%Z3
Project Number. C31482-01.01 Task 5
Weathers
Project Location: Hendersonville, NC
Facility ID or Permit # (if applicable):
Permit No. W00004797
Sample Collector(s): �, PA�1&I 4MI a4l
Sample ID (on COQ
SW-1- Z.01,3/108
Comments:
Sample Method (circle
one): Grab Syringe
Pump
Bailer Disp.
Other.
Specific
Oxidation
Temperature
Dissolved
Conductivity
pH (S.U.)
Reduction
Turbidity
Time
VC)
Oxygen (mg/L)
(pmhos/cm)
report to 0.1 S.U.
Potential (mV)
(NTU)
Comments
1�30
Iz.z
9,q 3
1 '-7
6'-7
3,03
Sampling Container Number of Containers
Requested Analysis
500 mL Plastic
250 mL Plastic
125 mL Plastic
40 mL Glass
1 L Glass
Other
Vegetation: hrA✓y Access: PC10 r
Sample Analyst /�
Sample Analyst Signature: Name: �n/'s9Y% / JI.y Date:
Notes:
1. Documentation errors are to be crossed out with a sinale line. so the oriainal text is still leoible. followed by the staff members initials and date
2. Samples are analyzed immediately upon collection.
3. NC Field Laboratory Certificate Number 5445
Abbreviations:
Method Reference:
°C: degrees Celsius
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter
DO: SM 4500 O G-2011
mv: millivolt
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units
Turbiditv: SM 2130 B-2011
S.U.: standard units
Page 2 of 3

� 'y� AANCHOR,(,z QEA c..�.v
L.�.v
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Surface Water Sampling Log
Location ID:
SW-2
Project Name: Lassonde Pappas WQ Monitoring Date: '''S 1z023
Project Number. C31482-01.01 Task 5 Weather: JC� oF' Clete
Project Location: Hendersonville, NC Facility ID or Permit # (if applicable): Permit No. WQ0004797
Sample Collector(s): C At,"&,jmt T - r4I _Sample ID (on COQ SW-2- 2,07,3/10
Comments:
Sample Method (circle
Grab Syringe
one):
Pump
Bailer Disp.
Other.
Time
Temperature
VC)
Dissolved
Oxygen (mg/L)
Specific
Conductivity
(Nmhos/cm)
pH (S.U.)
report to 0.1 S.U.
Oxidation
Reduction
Potential (mV)
Turbidity
(NTU)
Comments
oqos
�o.s
'3 Go
130-.3
Sampling Container
Number of Containers
Requested Analysis
500 mL Plastic
250 mL Plastic
125 mL Plastic
40 mL Glass
1 L Glass
Other
Vegetation: See S-4 /L40to-dt, Access: FA,'I-
j — Sample Analyst — ^4
Sample Analyst Signature: ` Name: C�1/'.�}/�Y/ !'�YfEP-A0a Date: ll/ 0Z 3
Notes:
1. Documentation errors are to be crossed out with a single line. so the oriainal text is still legible, followed by the staff members initials and date
2. Samples are analyzed immediately upon collection.
3. NC Field Laboratory Certificate Number 5445
Abbreviations:
Method Reference:
°C: degrees Celsius
Temperature: SM 2550 B-2010
Nmhos/cm: micromhos per centimeter
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter
DO: SM 4500 0 G-2011
mV: millivolt
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units
Turbiditv: SM 2130 B-2011
S.U.: standard units
Page 3 of 3

Pace* Location Requested (City/State):
aCell,Pace AnaIyt1mICh.rktte CHAIN -OF -CUSTODY Analytical Request Document
LAB USE ONLY- Affix Workorder/Login Label Here
9800 Kincey Ave. Suite 100, Huntersvllle, NC 28078
Chain -of -Custody is a LEGAL DOCUMENT- Complete all relevant fields
❑e�
Company Name: ANCHOR QEA of NORTH CAROLINA
Contact/Report To: Christian Patterson
Street Address 231 Haywood Street, Asheville, NC 28801
Phone #: [phone]
___. ......_.._. .................. ..... ....__. ..._._...._
..._........
E-Mail: [e-mail]
..... _.....
Scan
QR Code for instructions
Invoke To: AccountsPay4ble
Project Name: Lassoltfde Pappas SemiAnnual
Invoice E-Mail: [e-mail]
Specify Container Size'
•
-Container 1 1 z SOOmL, 3 250m a
114 (1 1 1 41 1
12SmL, (5) 100mL, (6) 40ml. vial, 17) Encore, (a)
...... .._......._.. _
_....... _.. ............ ............... ...
.._.....
TerroCare, 9) Other
Site Collection Info/Facility ID (as applicable):
Purchase Order # (if
Identify
Container Preservative
Type***
••• Preservative Types: (1) None, (2) HNO3, (3)
applicable):
1-12504, (4) HCI, (5) NaOH, (6) 7n Acetate, (7)
--
Quote #:
._ ......._...........
Na1-1504, (8) Sod. Thiosulfate, (9) Ascorbic Acid, (10)
McOH, (11) Other
Analysis Requested
Time Zone Collected:. ( ] AK [ ] PT [ ] MT [ ) CT
[VTET
County / State origin of sampie(s): North Carolina
n
m
-
Proj. Mgr.
Angela Below0
w
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Data Deliverables:
Regulatory Program (DW, RCRA, etc.) as applicable:
AcctNum/Client ID:
c
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<
( ] Level II [ ] Level III [ ] Level IV
rn
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a
E
Rush (Pre -approval required):
DW PW51D # or WW Permit # as applicable:
o
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EL_�
c0
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Tatite #:
[ ] EQUIS
[ ] 2 Day [ ] 3 d a
....., Y ( 15 day [ ]Other
o
( ]Other
Date Results
wA� l
q
m
0
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Field Filtered (if applicable): [ ]Yes [ No
Profile/Template:
Requested: ...�44J. ®
Analysis:
0
m
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0
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2632
$
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• Matrix Codes (Insert in Matrix box below): Drinking Water [DW), Ground Water (GW), Waste Water (W W), Product (P), Soil/Solid (5S), Oil (OL), Wipe (WP), Tissue ITS), Bioassay (3), Vapor (V),
Prolog /Bottle Ord. ID:
Other (OT), Surface Water (SW),Sediment (SED), Sludge (SL), Caulk
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Matrix
Comp/
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Number
Containers
& Type of
Grab
CL2
Plastic
Glass
N
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Sample Comment
Dateq
Time
Date
Time
MW-15
WT
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X
X
X
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X
X
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MW-71R2
WT
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X
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MW-8
WT
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Customer Remarks /Special Conditions/ Possible Hazards: ,p Collected
1a,Oft Fe� CQJv TO.M') Printed
By: /- �
Name: Chrixtbl^ PR'•r`r' fwr
Additional Instructions from Pace*:
Signature:
-
#'roolers. Thermometer ID:
Corte Factor ('C): bs. Temp. ('C)mp. ('C)
Relinquished by/Company: (Signature)
Da¢e/Tim� �� Re
ived /C any: [51 a
at'Mie/Time-
q �
J
Tracking Number.
_ ��
Relinquished by/Company: (Signature)
Del[e JTime: Received
by/Company Si atur
Date/Time:
-
Deliveredby: [ ].in -Person [. ]Courier
Reiinquished by/Company: (Signature)
Date/Tme: Resolved
by/Company: (Signature)
Date/Time:
[ )FedEX j ]UP 5 ,[ )Other
Relinquished by/Company: (Signature)
Date/Time: Received
by/Company: (Signature)
Date/TIm :
Page: i of 1
aa.,mrrunga wa tors uram vi cuswuy cunsutuses acxnowieogment ano accepTance oT one race- l erms ana conaitions found at https://www.pacelabs.com/resource-library/resource/pace-terms-and-conditions/ ENV-FRM-00RQ-0019 v01 082123

,�"Analjftal'
Required Client Information: Section A
Company: ANCHOR OEA of NORTH CAF
Address: 231 Haywood Street
Asheville, NC 28801
Phone: Fax:
[phone]
W
Z
)d Client Information: Section B
To: Jennifer Verde
): iverdeC&-anchoroea.com &
Invoice To: Robert Cork
P.O. C31482-01.01
Project Name: Lassonde Pappas
Project Number:
i Client Information: Section D Valid MatrbrOdd.
Matra Gads
water wT
S.a sL
Oil oL
wia. wi=
Air AR
Tissue Ts
Other OT
SAMPLE ID (One charater per box.)
SAMPLE CONDITION: SAMPLE NOTES:
Temp in C
-I-
Received an Ice
N
Sealed Cooler
Y /(g)
Sample Intact
/ N
Additional Comments:
W
O
U
CHAIN -OF -CUSTODY J Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately
Page: 1 of 1
Client Information (Check quotelcontract): To Be Completed by Pace Analytical Client: Section C
Requested Due Date: Quote Reference:
'TAT: Standard Project Manager.
angela. [e-mail]
rum around Ilmas toss than 14 days subject Project
Prole #:
a Rush Turnaround Surcharge.
im Around Time (TAT) In calendar days.
Presorvaeves
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Name of SAMPLER
TURE of SAMPLER
III

ANCHOR
CI:li 4-4.09—i
E ui ment Documentation and Instrument Calibration Data Sheet
Project Name: to S2 n Jp rAQ*If3 JAI& /f to t/¢Ohild Analyst Conducting Calibration:
Project Number: 71talf .5 Date of Calibration: /,/ $ C/L
Project Location:, Date of Field Measurements:13
Facility ID or Permit # (if applicable): LA/Q 000 � }
EQUIPMENT DOCUMENTATION
Rental sample analysis equipment or meters used to take measurements:
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
EquiementType
Brand
Serial Number Date of Use
Rental Company
Select Turbidimeter.
Hach 21000 (s/n 151006045207)
Rental Hach 2100Q (s/n _.
Instrument Readings
(Hach 2100Q)
Cal Std Information
10 NTU
20 NTU
100 NTU
800 NTU
tot #:
A3 t 2'i
R Z/i
Expiration Date:
/ #
// y
Cal (NTU)-
Cal (NTU 0.I
Cal (NTU) il"o
Time: 0G58
Time: ow
3
Time: 0701,
Calibration
Verification:
*Pre -Analysis
Check (10NTU):
Result(N1TOU)::
/0, ,/
Time:
0703
.Post -Analysis
Check (10 NTU):
Result (NTU :
. rp
Time:
1 9 1S
YSI Professional Plus Multiparameter Meter (s/n 186101802)
Instrument Readings
Cal Std Information
Lot #
Date
Opened
Exxp. Date
Dissolved Oxygen
(% saturation)
Initial):.
1Vy
Cal (%):
I^T]
mmHg: ��
Temperature
erature CC):
, 0
Time:
o 8 s�
DO (Site#2,
ifa licable)*
Initial (%):
Cal (%):
mmHg:
Tem
ime:
01 ///1/2J
QC** Check: DO
Timed $5 r
A
Result�(9,��:0 •
Time: ���
Result (%),
Time: n
Result (%):
PH 7 S.U.
report to 0.7 S.U.
Initiate,
�rpp
pHm/V: r
W
Cal (S.U..):
pHmV: 7
Tim-b_,,,
U
PH 4 S.U..
report to 0.7 S.U.
Initial,
pHmV:
'
Cal (S.U.):
40
pHmV: 2 p
-1 T.O
Time:
/
PH 10 S.U.
report to0.7S.U.
Initial:p/
pHmV:
Cal (S.U.):
/0•i%/
pHmV:
— I/Y. S
Time:
-fZZ
-16elw
W40,17
q
1/
QC** PH 7 S.U.
report to0.1S.U.
Time:
Result (S.U.):
Time:
IC14
Result (S.U.):
Time:
GOU)}
g y
8/3/Z3
Z�
W.C. Cond.
1,000 mhos/cm
Initial:
fool
Cal (Nmhos/cm):
Jp�
Time:
% Recovery=
QC** Spec Cond.
1,000 mhos/cm
Time:
d 33
Result (pmhos/cm):
0.0
Time:
��IQ
Result (umhos/cm):
�4d
Time:
Result (Nmhos/cm):
3:5;aon
./i/8/z3
31t5o'
% Recovery=
ORP 200 mV
Initi
%i 5
Cal:
'200 D
'
Tem erpture CC):
�j / 3
! I
Time:
Q17'3 1
Analyst Signature: Analyst Name:�r/s ff� Q �jL Date: /,�`y1,7 0 -,7-3
Notes:
Revision 8, 1111/22, CAP
1. Instruments shall be calibrated in accordance with the manufacturer's operation manual.
2. Specific Conductivity should be calibrated according to values representative of historic range.
3. Order of Calibration is as follows: Specific Conductivity, pH 7, pH 4, pH 10, DO, DRIP, QC checks.
4. *When performing DO analyses at multiple sample sites (i.e. project/facility locations), the DO probe must be calibrated at each sample site prior to analysis.
S. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the instrument needs to be recalibrated.
6. "QC check must be performed prior to sampling and following completion of sampling, at a minimum. QC checks must be performed with calibration standard from a separate lot # as the initial QC.
7. % Recovery = (Value Obtained, pmhos/cm + True Value, pmhos/cm) x 100
8, NC Field Laboratory Certificate Number 5445
9. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
10. Unless otherwise noted, all DO calibrations and measurements are performed at 0 ppt Salinity.
11. 1 pmho/cm = 1 VS/cm
Abbreviations:
pmhos/cm: micromhos per centimeter
°C: degrees Celsius
DO: dissolved oxygen
mg/L: milligrams per liter
mV: millivolt
NTU: nephelometric turbidity units
ORP: oxidation reduction potential
s/n: serial number
S.U.: standard units
Spec. Cond.: Specific Conductivity
Method Reference:
Temperature: SM 2550 B-2010
Specific conductivity. EPA Method 120.1, Rev. 1982
DO: SM 4500 O G-2016
PH: SM 4500-H' B-2011
Turbidity: SM 2130 B-2011
Page 1 of 1

Attachment 3
DEQ GW-59A Compliance Report Form

GW-59A COMPLIANCE REPORT FORM Permit # WQ0004797
(Stthntit one each monitoring period with GIh59 forms.)
1
Enter date monitoring results were due. ( 12/29/2023 ) Will this monitoring report (GW-59 and GW-59A)
YES
NO
be submitted after the established due date?
X
2
Was any required information missing on the GW-59 report forms?
YES
X
IF the answer to question 1 or 2 is "YES, list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
YES
NO
identification plate, area overgrown, etc.)? If the ansiver is "Yes ", contact the Regional Office for guidance.
X
4
Are any monitored constituents equal to or above the established standards?
YES
1S
NO
If the answer to question 4 is "NO", skip to section 8.
If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s)
exceeding standards in the space provided below. -
Nitrate (2L = 10mg/L): MW-7R2@ 19.1 mg/L
Fecal coliform (2L = 1 CFU/100 ML): MW-6@ 1.0 CFU/100 mL
Tetrachloroethene (2L = 0.7 pg/L): MW-5@ 169.0 pg/L
Trichloroethene (2L = 3 pg/L): MW-5@ 155.0 pg/L; Cis-1,2-dichloroethene (2L = 70 pg/L): MW-5@ 111.0 pg/L
Vinyl Chloride (2L = 0.03 pg/L): MW-@ 1.3 pg/L *Note: MW-5 is background well
5
For the constituents identified in question 4 above, have standards been exceeded previously for the
YES
NO
same constituent(s) in the same well(s) in the last two years?
X
If the answer to question 5 is "NO'; skip to section 8.
If the answer to question 5 is "YES'; list in the space provided below, each well with constituent(s) exceeding
standards, concentrations) reported, and sample collection date for each occurrence (for the last two years).
itrate Fecal Coliform Tetrachloroethene Trichloroethene Cis-1,2-dichloroethene Vinyl Chloride
VfW-7R2 (mg/L) MW-6 (CFU/100mL) MW-5 (ug/L) MW-5 (ug/L) MW-5 (ug/L) MW-5 (ug/
)
5/03/23: 18.4 11/08/22: *164.0 10/28/21: 30.7 10/28/21: 11.6 11/08/22: 96.5 11/08/22:
1.1
11/08/22: 12.0 11/08/22: 152.0 11/08/22: 75.1
05/03/23: 15.0
* POSSIBLE LAB ERROR SUBSEQUENTLY RESAMPLED
6
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
YES
NO
X
If the answer is "YES'; a groundwater quality problem may be occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly
located; contact the Regional Office.
7
Is the permittee implementing previously approved actions required by the Division involving this
IT,
NO
groundwater quality problem?
X
If the answer to question 7 is "YES'; describe those actions in the space provided below.
If the answer to question 7 is "NO'; contact the Regional Office within 90 days; an evaluation may be
required to determine the impact the waste disposal system is having at the review and compliance
boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation,
fines, and/or penalties.
Monitoring well MW-7R was replaced by MW-7R2 prior to the Spring 2023 monitoring event due to root penetration of the well screen and
concerns regarding impacts to water quality measurements.
g
The person completing this portion (GW-59A) of the monitoring report should sign below and submit this
form with G W-59 forms for required wells to the address provided at the top of the current G W-59 form.
I hereby acknowledge that the above information was evaluated and the information submitted in this
report (Compliance Report GW-59A) is true and complete to the best of my knowledge.
Signature of Permittee (or Authorized Agent) Date
G1V-59A 12/8/2003

Attachment 4
DEQ GW-59 Groundwater Quality
Monitoring: Compliance Report Forms

SUBMIT FORM ON YELLOW PAPER ONLY
• •
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
• •
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date: 7/31/2026
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville !Street' NC
28792 CountyHenderson
El Lagoon ❑Remediation: Infiltration Gallery
(city) (State)
(Zip!
❑■ Spray Field ❑Remediation:
Contact Person: James Frazier
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
(from Permit
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-4
Date sample collected: 11/8/2023
FIELD ANALYSES:
WAS
Well Depth: 18.23 ft.
Well Diameter: 2 in.
pH 00400: 5.7 units Temp. 000lo: 17.3 oC
DRY at
Depth to Water Level 82546: 9.88 ft. below measuring point Screened Interval: 5 ft. to
15
—
ft. Spec. Cond. 00094: 179.8 µMhos
time of
sampling,
Measuring Point is 2.43 ft. above land surface
Relative M.P. Elevation: 2063.77 ft.
Odor 00085: none
check
Volume of water pumped/bailed before sampling:
2.25
gallons
Appearance
here:❑
Samples for metals were collected unfiltered: ❑■ YES
❑ NO and field acidified: ❑■ YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: 11/8/2023
Laboratory Name: Pace Analytical Services
Certification No. 37712
PARAMETERS NOTE: Values should reflect
dissolved
and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 <1.0
/100mL
Nitrate (NO3) as N 00620 <0.040
ni Zn - Zinc 01092 ni
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665 <0.050
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
ni Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 121
mg/L
Al - Aluminum 01105
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC 00680 2.9
mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 13.1
ni
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
ni
Cu - Copper 01042
ni ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
ni
Hg - Mercury 71900
ug/L
Lab Report Attached? ❑■ Yes (1) ❑ No (0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L VOC 7873 method #
Total Ammonia oo610 <0.10
ni
Mg - Magnesium 00927
ni method #
(Ammonia Nitrogen; NH3asN; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
, method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
James Frazier, Plant Manager
Permittee (or Authorized Aqent) Name and Title - Please print or type
Siqnature of Permittee (or Authorized Aqent) (Date)
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
• •
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
• •
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date: 7/31/2026
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville !Street' NC
28792 CountyHenderson
El Lagoon ❑Remediation: Infiltration Gallery
(city) (State)
(Zip!
❑■ Spray Field ❑Remediation:
Contact Person: James Frazier
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
(from Permit
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-5
Date sample collected: 11/9/2023
FIELD ANALYSES:
WAS
Well Depth: 18.56 ft.
Well Diameter: 2 in.
pH 00400: 5.5 units Temp. 000lo: 17.7 oC
DRY at
Depth to Water Level 82546: 10.90 ft. below measuring point Screened Interval: 9 ft. to
19
—
ft. Spec. Cond. 00094: 208.6 µMhos
time of
sampling,
Measuring Point is 3.00 ft. above land surface
Relative M.P. Elevation: 2085.60 ft.
Odor 00085: none
check
Volume of water pumped/bailed before sampling:
2.31
gallons
Appearance
here:❑
Samples for metals were collected unfiltered: ❑■ YES
❑ NO and field acidified: ❑■ YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: 11/9/2023
Laboratory Name: Pace Analytical Services
Certification No. 37712
PARAMETERS NOTE: Values should reflect
dissolved
and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 <1.0
/100mL
Nitrate (NO3) as N 00620 0.066
ni Zn - Zinc 01092 ni
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665 <0.050
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
ni Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 125.0
mg/L
Al - Aluminum 01105
mg/L Tetrachloroethene - 169.0 pg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
Trichloroethene - 155.0 pg/L
TOC 00680 1.8
mg/L
Ca - Calcium 00916
mg/L Cis- 1,2-dichloroethene - 111.0 pg/L
Chloride 00940 47.2
ni
Cd - Cadmium 01027
ug/L
Vinyl chloride - 1.3 pg/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
'Note MW-5 is background well so from unknown off -site source
Grease and Oils 00552
ni
Cu - Copper 01042
ni ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
ni
Hg - Mercury 71900
ug/L
Lab Report Attached? ❑■ Yes (1) ❑ No (0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L VOC 7873 method # SM 6200B
Total Ammonia oo610 <0.10
ni
Mg - Magnesium 00927
ni method #
(Ammonia Nitrogen; NH3asN; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
, method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
James Frazier, Plant Manager
Permittee (or Authorized Aqent) Name and Title - Please print or type
Siqnature of Permittee (or Authorized Aqent) (Date)
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
• •
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
• •
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date: 7/31/2026
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville !Street' NC
28792 CountyHenderson
El Lagoon ❑Remediation: Infiltration Gallery
(city) (State)
(Zip!
❑■ Spray Field ❑Remediation:
Contact Person: James Frazier
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
(from Permit
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-6
Date sample collected: 11/8/2023
FIELD ANALYSES:
WAS
Well Depth: 11.56 ft.
Well Diameter: 2 in.
pH 00400: 5.6 units Temp. 000lo: 20.5 oC
DRY at
Depth to Water Level 82546: 8.05 ft. below measuring point Screened Interval: 5 ft. to
10
—
ft. Spec. Cond. 00094: 261.3 µMhos
time of
sampling,
Measuring Point is 3.00 ft. above land surface
Relative M.P. Elevation: 2061.17 ft.
Odor 00085: none
check
Volume of water pumped/bailed before sampling:
1.08
gallons
Appearance
here:❑
Samples for metals were collected unfiltered: ❑■ YES
❑ NO and field acidified: ❑■ YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: 11/8/2023
Laboratory Name: Pace Analytical Services
Certification No. 37712
PARAMETERS NOTE: Values should reflect
dissolved
and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 1.0
/100mL
Nitrate (NO3) as N 00620 7.5
ni Zn - Zinc 01092 ni
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665 <0.050
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
ni Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 168.0
mg/L
Al - Aluminum 01105
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC 00680 1.6
mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 17.4
ni
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
ni
Cu - Copper 01042
ni ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
ni
Hg - Mercury 71900
ug/L
Lab Report Attached? ❑■ Yes (1) ❑ No (0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L VOC 7873 method #
Total Ammonia oo610 <0.10
ni
Mg - Magnesium 00927
ni method #
(Ammonia Nitrogen; NH3asN; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
, method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
James Frazier, Plant Manager
Permittee (or Authorized Aqent) Name and Title - Please print or type
Siqnature of Permittee (or Authorized Aqent) (Date)
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
• •
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
• •
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date: 7/31/2026
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville !Street' NC
28792 CountyHenderson
El Lagoon ❑Remediation: Infiltration Gallery
(city) (State)
(Zip!
❑■ Spray Field ❑Remediation:
Contact Person: James Frazie
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
(from Permit
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-7R2
Date sample collected: 11/8/2023
FIELD ANALYSES:
WAS
Well Depth: 17.39 ft.
Well Diameter: 2 in.
pH 00400: 5.7 units Temp. 000lo: 16.7 oC
DRY at
Depth to Water Level 82546: 12.21 ft. below measuring point Screened Interval: 5 ft. to
15
—
ft. Spec. Cond. 00094: 370.7 µMhos
time of
sampling,
Measuring Point is N/A ft. above land surface
Relative M.P. Elevation: 2062.86* ft.
Odor 00085: none
check
Volume of water pumped/bailed before sampling:
3.19
gallons
Appearance `Elevation assumed based on MW-7R
here:❑
Samples for metals were collected unfiltered: ❑■ YES
❑ NO and field acidified: ❑■ YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: 11/8/2023
Laboratory Name: Pace Analytical Services
Certification No. 37712
PARAMETERS NOTE: Values should reflect
dissolved
and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 <1.0
/100mL
Nitrate (NO3) as N 00620 19.1
ni Zn - Zinc 01092 ni
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665 <0.050
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
ni Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 242
mg/L
Al - Aluminum 01105
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC 00680 <1.0
mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 24.5
ni
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
ni
Cu - Copper 01042
ni ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
ni
Hg - Mercury 71900
ug/L
Lab Report Attached? ❑■ Yes (1) ❑ No (0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L VOC 7873 method #
Total Ammonia oo610 <0.10
ni
Mg - Magnesium 00927
ni method #
(Ammonia Nitrogen; NH3asN; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
, method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
James Frazier, Plant Manager
Permittee (or Authorized Aqent) Name and Title - Please print or type
Siqnature of Permittee (or Authorized Aqent) (Date)
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
• •
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date: 7/31/2026
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville !Street' NC
28792 CountyHenderson
El Lagoon ❑Remediation: Infiltration Gallery
(city) (State)
(Zip!
❑■ Spray Field ❑Remediation:
Contact Person: James Frazier
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
(from Permit
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-8
Date sample collected: 11/8/2023
FIELD ANALYSES:
WAS
Well Depth: 13.95 ft.
Well Diameter: 2 in.
pH 00400: 6.6 units Temp. 000lo: 15.4 oC
DRY at
Depth to Water Level 82546: 11.10 ft. below measuring point Screened Interval: 3 ft. to
13
—
ft. Spec. Cond. 00094: 604.4 µMhos
time of
sampling,
Measuring Point is 3.00 ft. above land surface
Relative M.P. Elevation: 2060.80 ft.
Odor 00085: none
check
Volume of water pumped/bailed before sampling:
3.09
gallons
Appearance
here:❑
Samples for metals were collected unfiltered: ❑■ YES
❑ NO and field acidified: ❑■ YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: 11/8/2023
Laboratory Name: Pace Analytical Services
Certification No. 37712
PARAMETERS NOTE: Values should reflect
dissolved
and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 <1.0
/100mL
Nitrate (NO3) as N 00620 0.18
ni Zn - Zinc 01092 ni
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665 <0.050
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
ni Other (Specify Compounds and Concentration Units):
issolved Solids:Total 703oo 334
mg/L
Al - Aluminum 01105
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC 00680 7.5
mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 15.8
ni
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
ni
Cu - Copper 01042
ni ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
ni
Hg - Mercury 71900
ug/L
Lab Report Attached? ❑■ Yes (1) ❑ No (0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L VOC 7873 method #
Total Ammonia oo610 0.16
ni
Mg - Magnesium 00927
ni method #
(Ammonia Nitrogen; NH3asN; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
, method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
James Frazier, Plant Manager
Permittee (or Authorized Aqent) Name and Title - Please print or type
Siqnature of Permittee (or Authorized Aqent) (Date)
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
• •
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
• •
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date: 7/31/2026
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville !Street' NC
28792 CountyHenderson
El Lagoon ❑Remediation: Infiltration Gallery
(city) (State)
(Zip!
❑■ Spray Field ❑Remediation:
Contact Person: James Frazier
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
(from Permit
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-9
Date sample collected: 11/9/2023
FIELD ANALYSES:
WAS
Well Depth: 18.08 ft.
Well Diameter: 2 in.
pH 00400: 5.2 units Temp. 000lo: 17.3 oC
DRY at
Depth to Water Level 82546: 6.21 ft. below measuring point Screened Interval: 6 ft. to
16
—
ft. Spec. Cond. 00094: 111.1 µMhos
time of
sampling,
Measuring Point is 1.44 ft. above land surface
Relative M.P. Elevation: 2060.23 ft.
Odor 00085: none
check
Volume of water pumped/bailed before sampling:
3.43
gallons
Appearance
here:❑
Samples for metals were collected unfiltered: ❑■ YES
❑ NO and field acidified: ❑■ YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: 11/9/2023
Laboratory Name: Pace Analytical Services
Certification No. 37712
PARAMETERS NOTE: Values should reflect
dissolved
and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 <1.0
/100mL
Nitrate (NO3) as N 00620 2.4
ni Zn - Zinc 01092 ni
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665 <0.050
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
ni Other (Specify Compounds and Concentration Units):
issolved Solids:Total 703oo 80.0
mg/L
Al - Aluminum 01105
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC 00680 2.3
mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 8.7
ni
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
ni
Cu - Copper 01042
ni ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
ni
Hg - Mercury 71900
ug/L
Lab Report Attached? ❑■ Yes (1) ❑ No (0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L VOC 7873 method #
Total Ammonia oo610 <0.10
ni
Mg - Magnesium 00927
ni method #
(Ammonia Nitrogen; NH3asN; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
, method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
James Frazier, Plant Manager
Permittee (or Authorized Aqent) Name and Title - Please print or type
Siqnature of Permittee (or Authorized Aqent) (Date)
GW-59 Rev.06-07-2018