WQ0004797_Groundwater Monitoring Report May 2023_20230620

Anchor QEA of North Carolina, PLLC ANCHOR
231 Haywood Street
Asheville, North Carolina 28801 kz QEA c
828.281.3350
June 20, 2023
Blake Kehoe
Director, Engineering
Lassonde Pappas & Company, Inc.
125 Industrial Park Road
Hendersonville, North Carolina 28792
Re: Spring 2023 Water Quality Sampling Event
Non -Discharge Permit No. WQ0004797
Clement Pappas NC, LLC
Dear Mr. Kehoe,
Anchor QEA of North Carolina, PLLC, is pleased to present the results of the Spring 2023 water
quality sampling event at the Clement Pappas NC, LLC (Clement Pappas), facility (the Site), located at
485 Brookside Camp Road in Hendersonville, North Carolina. The company that operates the facility
rebranded to Lassonde Pappas & Company in 2016; however, for permitting purposes, the
Hendersonville facility retains the Clement Pappas NC, LLC, name that is designated on the property
deed. Clement Pappas is currently permitted under a Wastewater Irrigation System Permit by the
North Carolina Department of Environmental Quality (DEQ) Environmental Management Commission
for the operation of a 99,900-gallon-per-day wastewater treatment and irrigation facility.
Groundwater Well Replacement
The DEQ recommended replacement of monitoring well MW-7R due to well integrity issues.
Anchor QEA oversaw the installation of replacement monitoring well MW-7R2 by licensed well driller
SAEDACCO on May 1, 2023. Subsequently, SAEDACCO decommissioned monitoring well MW-7R by
removing the casing and tremie grouting in place with neat cement and bentonite grout mix. The
well construction record for MW-7R2 and the well abandonment record for MW-71R are included in
Attachment 1.
Groundwater Quality
Anchor QEA performed the groundwater sampling event at the Site on May 3 and 4, 2023. A Site
location map is included in Figure 1. The groundwater sampling event was performed in accordance
with DEQ wastewater irrigation system permit No. WQ0004797 issued September 3, 2015, and
renewed May 15, 2020 (referred to as "the permit" in this letter; effective September 1, 2020, and
expiring July 31, 2026). Anchor QEA used low -flow methods to purge and collect groundwater
samples from six monitoring wells: MW-4, MW-5, MW-6, MW-7R2, MW-8, and MW-9. Monitoring
well MW-9 was installed April 14, 2015, to replace the previously damaged monitoring well MW-2R,
and monitoring well MW-7R2 was installed on May 1, 2023, to replace MW-7R. The locations of the

Page 2
monitoring wells are shown in Figure 2. Anchor QEA submitted the groundwater samples to Pace
Analytical Services, Inc., a North Carolina -certified laboratory, for analysis of the parameters specified
in the permit, as follows:
• Total organic carbon
• Chloride
• Fecal coliform
• Ammonia
• Nitrate
• Total phosphorous
• Total dissolved solids
Groundwater Elevation
Table 1 summarizes current and historical groundwater elevations from May 2018 to May 2023. Except
for monitoring wells MW-7R2 and MW-9, all monitoring well concrete pads and top -of -well casing (TOC)
elevations were surveyed by Wes Cole Land Surveying, PA, on November 21, 2012. Monitoring well
MW-9 was surveyed by Wes Cole Land Surveying, PA, on May 29, 2015. The surveyed TOC elevations are
shown in Table 1.
Groundwater Analytical Results
Table 2 summarizes the current and historical groundwater analytical results from May 2019 to May 2023.
During the current sampling event, the parameters analyzed were below or within the groundwater
standards provided in the permit,' except for nitrate and pH, which are described as follows:
• The pH of the samples collected from MW-4 (5.6 standard units [SU]), MW-5 (5.3 SU),
MW-6 (5.2 SU), MW-7R2 (5.2 SU), and MW-9 (5.1 SU) were below the groundwater standard
range of 6.5 to 8.5 SU. The sample collected from the background monitoring well, MW-5, has
a pH (5.3) that is similar to the other groundwater monitoring wells.
• The nitrate concentration exceeded the permit groundwater standard of 10 milligrams per
liter (mg/L) in the sample collected from one monitoring well, MW-7R2 (18.4 mg/L).
The 2L standard for total coliform is 1 colony -forming unit per 100 milliliters (1 CFU/100 mQ. There is
no specific permit limit or 2L standard for fecal coliform; however, total coliform includes fecal
coliform. The following summarizes fecal coliform results from the groundwater monitoring wells:
• Fecal coliform concentrations exceeded the 2L standard for total coliform in monitoring well
MW-6 (15.0 CFU/100 mL). Fecal coliform was not detected at or above laboratory detection
limits in the samples collected from all other monitoring wells.
Most of the groundwater standards are represented by the 2L standards, with the exception of nitrate and total organic carbon,
which are set in the Wastewater Irrigation System Permit Number WQ0004797.

Page 3
Surface Water Quality
Beginning in May 2017, Clement Pappas voluntarily collected surface water samples from Mud Creek,
analyzing for the same constituents as those sampled in groundwater. The renewed permit issued in
May 2020, and effective September 2020, requires semiannual sampling of the surface water
locations. Sampling point SW-1 is located upstream of the Site, and sampling point SW-2 is located
downstream of the Site. Sampling locations are shown in Figure 2.
Surface Water Analytical Results
Table 3 summarizes the historical and current surface water analytical results. For the May 2023
sampling event, no parameters were detected at concentrations above the associated Title
15A NCAC Subchapter 2B surface water standards (213 standards).
Since collection of surface water samples for all permit constituents began in May 2017, nitrate
concentrations have been similar in SW-1 (upstream) and SW-2 (downstream). The Spring 2023
sampling showed a similar relationship: upstream sample SW-1 had a nitrate concentration of
0.69 mg/L, while downstream sample SW-2 had a concentration of 0.61 mg/L. The results for total
organic carbon, chloride, total dissolved solids, ammonia, and total phosphorus were also similar for
upstream and downstream samples, indicating the unlikelihood that the Site is impacting Mud Creek.
Discussion and Recommendations
Monitoring well MW-7R was replaced by MW-7R2 prior to the Spring 2023 monitoring event due to
root penetration of the well screen and concerns regarding impacts to water quality measurements.
All constituent concentrations in the sample collected from the replacement well MW-7R2 during the
Spring 2023 event were below the permit standard with the exception of nitrate, which was above
the permit standard, but at the lowest concentration since 2020. If nitrate concentrations in MW-7R2
do not decrease below the permit standard during subsequent monitoring events, the facility may
need to consider mitigation measures such as reduction of wastewater application rates to the fields
upgradient of MW-7R2 (Field 513, Field 8, and Field 9).
Fecal coliform concentrations measured in samples collected from MW-6 exceeded the permit
standard in both Spring 2022 and Fall 2023. Since only the wastewater generated by juice production
(and not domestic wastewater) is discharged to the facility wastewater treatment and irrigation
system, the likely source of fecal coliform detected in MW-6 is wildlife in the vicinity of the
wastewater treatment lagoon and irrigation fields.
Nitrate and fecal coliform concentrations were below the permit standard in samples collected from
all other monitoring wells during the Spring 2023 event. The results for all analyzed constituents in
surface water, including nitrate and fecal coliform, were below applicable standards and similar for
upstream and downstream samples. In accordance with the spray irrigation permit WQ0004797,

Page 4
Clement Pappas is required to submit the following to the DEQ by June 30, 2023 (on or before the
last working day of the month following the sampling month):
• Laboratory analytical reports and chain -of -custody forms (Attachment 2)
• Well sampling logs and the equipment documentation and instrument calibration data sheet
(Attachment 3)
• DEQ GW-59A — Compliance Report Form (Attachment 4)
• DEQ GW-59 — Groundwater Quality Monitoring: Compliance Report Form, for each
monitoring well (Attachment 5)
Anchor QEA proposes to complete the next scheduled groundwater and surface water sampling
event in November 2023. Anchor QEA will notify the DEQ of the proposed November sampling
event dates per the request by the DEQ to split samples during the next sampling event.
If you have any questions or would like additional information, please do not hesitate to contact me
at [phone] [e-mail].
Sincerely,
1
Jennife(Verde, PE
Managing Engineer
6 9ames Robert Howell, PG
Principal Scientist
Attachments
Table 1 Current and Historical Groundwater Elevation Measurements
Table 2 Current and Historical Groundwater Analytical Results
Table 3 Current and Historical Surface Water Analytical Results
Figure 1 Site Location Map
Figure 2 Site Map
Attachment 1 MW-7R2 Well Construction Record and MW-7R Well Abandonment Record
Attachment 2 Laboratory Analytical Reports and Chain -of -Custody Forms
Attachment 3 Well Sampling Logs and Instrument Calibration Data Sheet
Attachment 4 DEQ GW-59A—Compliance Report Form
Attachment 5 DEQ GW-59—Groundwater Quality Monitoring: Compliance Report Forms

Tables

Table 1
Current and Historical Groundwater Elevation Measurements
Well
Identification
Screened
Interval
(ft bgs)
Date
Measured
Depth to
Groundwater
(ft)
Top -of -Casing
Elevation
(ft AMSL)
Top -of -Casing
Height Above
Ground Surface
(ft)
Groundwater
Elevation
(ft AMSL)
MW-4
5.0 - 15.0
05/02/2018
8.44
2063.77
2.43
2055.33
11/02/2018
8.00
2055.77
05/21/2019
8.49
2055.28
11/14/2019
8.82
2054.95
05/06/2020
7.98
2055.79
11/06/2020
8.02
2055.75
05/11 /2021
8.52
2055.25
10/28/2021
9.15
2054.62
05/10/2022
9.14
2054.63
11/08/2022
9.35
2054.42
05/03/2023
8.79
2054.98
MW-5
9.0 - 19.0
05/02/2018
8.47
2085.60
3.00
2077.93
11/02/2018
8.23
2078.17
05/21/2019
8.57
2077.83
11/14/2019
8.90
2077.50
05/06/2020
8.28
2078.12
11/06/2020
8.90
2077.50
05/11 /2021
8.77
2077.63
10/28/2021
9.44
2076.96
05/10/2022
9.15
2076.45
11/08/2022
10.07
2075.53
05/03/2023
8.85
2076.75
MW-6
5.0 - 10.0
05/02/2018
5.36
2061.17
3.00
2056.54
11/02/2018
5.03
2056.87
05/21/2019
5.53
2056.37
11/14/2019
5.59
2056.31
05/06/2020
5.41
2056.49
11/06/2020
5.33
2056.57
05/11 /2021
5.68
2056.22
10/28/2021
5.94
2055.96
05/10/2022
5.91
2055.26
11/08/2022
6.40
2054.77
05/03/2023
5.74
2055.43
MW-7R
5.0 - 15.0
05/02/2018
10.99
2062.86
3.00
2051.87
11/02/2018
10.33
2052.53
05/21/2019
10.88
2051.98
11/14/2019
11.33
2051.53
05/06/2020
10.11
2052.75
11/06/2020
10.05
2052.81
05/11 /2021
10.85
2052.01
10/27/2021
11.74
2051.12
05/10/2022
11.66
2051.20
11/08/2022
1 11.80
1 2051.06
MW-7R2
5.0 - 15.0
05/03/2023
1 10.57
--
3.00
1--
Fall 2022 Groundwater Sampling Event Page 1 of 3
Clement Pappas, Hendersonville, North Carolina June 2023

Table 1
Current and Historical Groundwater Elevation Measurements
Well
Identification
Screened
Interval
(ft bgs)
Date
Measured
Depth to
Groundwater
(ft)
Top -of -Casing
Elevation
(ft AMSL)
Top -of -Casing
Height Above
Ground Surface
(ft)
Groundwater
Elevation
(ft AMSL)
MW-8
3.0 - 13.0
05/15/2002
10.25
2061.40
3.00
2051.15
11 /05/2002
10.35
2051.05
05/13/2003
8.16
2053.24
11 /04/2003
10.23
2051.17
05/05/2004
10.30
2051.10
11/09/2004
8.90
2052.50
05/17/2005
10.08
2051.32
11 /03/2005
10.61
2050.79
05/24/2006
10.60
2050.80
11/09/2006
9.40
2052.00
05/18/2007
10.31
2051.09
11 /13/2007
11.09
2050.31
05/27/2008
10.83
2050.57
11 /18/2008
11.11
2050.29
05/28/2009
8.25
2053.15
11/05/2009
9.22
2052.18
05/13/2010
9.88
2051.52
11 /08/2010
10.38
2051.02
05/17/2011
10.27
2051.13
11/15/2011
10.87
2050.53
05/17/2012
8.03
2053.37
11/07/2012
10.45
2060.80
3.00
2050.35
05/16/2013
8.58
2052.22
11 /20/2013
10.34
2050.46
05/22/2014
9.79
2051.01
11/18/2014
10.03
2050.77
05/13/2015
10.34
2050.46
11/04/2015
7.21
2053.59
05/04/2016
9.84
2050.96
11 /09/2016
11.16
2049.64
05/02/2017
8.48
2052.32
11/08/2017
8.73
2052.07
05/02/2018
9.39
2051.41
11/02/2018
8.85
2051.95
05/21 /2019
9.38
2051.42
11/14/2019
9.75
2051.05
05/06/2020
8.54
2052.26
11/06/2020
8.37
2052.43
05/11 /2021
9.24
2051.56
10/27/2021
10.06
2050.74
05/10/2022
10.02
2050.78
11 /08/2022
10.31
2050.49
05/03/2023
9.41
2051.39
Fall 2022 Groundwater Sampling Event Page 2 of 3
Clement Pappas, Hendersonville, North Carolina June 2023

Table 1
Current and Historical Groundwater Elevation Measurements
Well
Identification
Screened
Interval
(ft bgs)
Date
Measured
Depth to
Groundwater
(ft)
Top -of -Casing
Elevation
(ft AMSL)
Top -of -Casing
Height Above
Ground Surface
(ft)
Groundwater
Elevation
(ft AMSL)
MW-9
6.0-16.0
05/02/2018
5.07
2060.23
1.44
2055.16
11/02/2018
4.55
2055.68
05/21/2019
4.89
2055.34
11/14/2019
5.15
2055.08
05/06/2020
4.30
2055.93
11/06/2020
4.10
2056.13
05/11 /2021
4.75
2055.48
10/27/2021
5.57
2054.66
05/10/2022
5.70
2054.53
11/08/2022
5.90
2054.33
05/03/2023
5.02
2055.21
Notes:
AMSL: above mean sea level
bgs: below ground surface
ft: feet
I op-ot-casing elevations: MW-5 through MW_6 top-ot-casing elevations are based on a survey by Hill and Associates Surveyors,
dated January 10, 2002, through May 2012. MW-2R and MW-4 top -of -casing elevations are based on differential level
measurements made by Altamont Environmental, Inc., on June 26, 2006, through May 2012. The top -of -casing elevations for the
monitoring wells were resurveyed on November 21, 2012, by Wes Cole Land Surveying. The top -of -casing elevations for MW-9
were surveved on Mav 29. 2015. by Wes Cole Land Survevina.
Monitoring is performed in accordance with Permit No. WQ0004797 issued to Clement Pappas on May 15, 2020 and effective on
September 1, 2020.
Fall 2022 Groundwater Sampling Event Page 3 of 3
Clement Pappas, Hendersonville, North Carolina June 2023

Table 2
Current and Historical Groundwater Analytical Results
Sample Name
Sample Date
V
.a
O=
Y
O
E
L
O
v°
iG
V
d
i
++
G1
�
C
C
=
E
i
C
i
�'
0
a
i
a
41
++
N
O L.r
0
s
V
4/
y
t
d41
o
=
d
IV
C4
s
=
d
41
IV
47
'i
O
ij
d
t
y
C
L
O
L'
(SU)
(mg/L)
(mg/L)
(CFUs
per 100 mL)
(mg/L)
(mg/L)
(mg/L)
(mg/L)
(Ng/L)
(Ng/L)
(Ng/L)
(Ng/L)
(Ng/L)
(Ng/L)
2L Groundwater Standards
6.5 - 8.5
10
250
1
10
500
7.5
NL
0.7
3
70
700
0.03
7
Groundwater Standards Provided in Permit No. WQ0004797
6.5 - 8.5
10
250
NL
10
500
7.5
NL
0.7
1 3
1 70
1 100
1 0.03
7
05/21/2019
5.8
3.0
11.3
<1.0
3.3
170
<0.050
0.044 J
NR
11/14/2019
5.8
3.7
11
<1.0
0.42
190
<0.10
<0.050
<0.50 <0.50 <0.50
1 <0.50 <1.0 <0.50
05/06/2020
5.7
2.3
7.6
<1.0
3.7
172
<0.10
<0.050
NR
11/06/2020
5.3
1 2.8
6.9
<1.0
0.73
148
<0.10
<0.050
<0.50 <0.50 <0.50
1 <0.50 <1.0 <0.50
MW-4
05/11/2021
5.8
2.8
6.9
<1.0
1.4
169
0.14
<0.050
NR
10/28/2021
5.7
3.1
6.7
<1.0
0.084
161
<0.10
<0.050
<0.50 <0.50 <0.50
1 <0.50 <1.0 <0.50
05/10/2022
5.8
2.9
6.8
<1.0
0.460
136
<0.10
0.063
NR
11/08/2022
5.8
3.2
10.3
<1.0
0.090
137
<0.10
<0.050
<0.50 <0.50 <0.50
1 <0.50 <1.0 <0.50
05/03/2023
5.6
3.3
10.3
<1.0
0.660
126
<0.10
<0.050
NR
05/21/2019
5.7
9.4
26.8
7.0
0.057
91.0
<0.050
0.120
NR
11/14/2019
5.6
6.0
20.1
7.0
0.055
202
<0.10
0.081
22.4 4.4 5.0 1 <0.50 <1.0 <0.50
05/06/2020
5.9
6.9
7.3
8.0
<0.040
116
<0.10
0.083
NR
11/06/2020
5.7
4.6
6.9
8.0
<0.040
61.0
<0.10
0.060
0.80 1.0 <0.50 1 <0.50 <1.0 <0.50
MW-5
05/11/2021
5.5
5.5
11.8
<2.0
<0.040
110
<0.10
0.090
NR
10/28/2021
5.7
6.6
17.3
5.0
<0.040
76.0
<0.10
0.054
30.7 11.6 12.6 1 <0.50 <1.0 <0.50
05/10/2022
5.6
2.7
49.0
<1.0
0.10
158
<0.10
<0.050
NR
11/08/2022
5.5
2.3
51.4
<1.0
<0.040
132
<0.10
<0.050
152.0 75.1 T 96.5 1 <0.50 1.1 <0.50
05/03/2023
5.3
6.3
4.2
<1.0
0.049
75.0
<0.10
0.075
NR
05/21/2019
5.5
3.3
11.3
23.0
0.4
78.0
<0.050
0.068
NR
11/14/2019
5.3
2.9
9.3
44.0
0.56
342
<0.10
0.052
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
05/06/2020
5.4
2.0
9.7
3.0
1.1
96.0
<0.10
<0.050
NR
11/06/2020
5.2
2.6
12.5
3.0
3.2
139
<0.10
<0.050
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
MW-6
05/11/2021
5.5
2.2
10.9
5.0
1.4
99.0
<0.10
<0.050
NR
10/28/2021
5.4
2.3
8.7
<1.0
<0.040
85.0
<0.10
<0.050
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
05/10/2022
5.4
1.5
13.6
<1.0
<0.040
96.0
<0.10
<0.050
NR
11/08/2022
5.4
2.0
9.5
164.0/12.0*
0.40
85.0
<0.10
<0.050
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
05/03/2023
5.2
1.5
8.8
15.0
0.15
86.0
<0.10
<0.050
NR
Spring 2023 Groundwater Sampling Event Page 1 of 2
Clement Pappas, Hendersonville, North Carolina June 2023

Table 2
Current and Historical Groundwater Analytical Results
Sample Name
Sample Date
V
.a
O=
Y
O
E
L
O
v°
iG
d
i
G1
>
C
C
=
E
i
C
�'
0
a
ate+
ar
41
++
O L.r
0
s
V
4/
y
d41
o
=
IV
C4
s
=
41
IV
C
47
'L
O
d
_
t
y
L
O
(SU)
(mg/L)
(mg/L)
(CFUs
per 100 mL)
(mg/L)
(mg/L)
(mg/L)
(mg/L)
(Ng/L)
(Ng/L)
(Ng/L)
(N9/L)
(Ng/L)
(Ng/L)
05/21/2019
5.58
3.0
29.0
<2.0
20.2
234
<0.050
0.130
NR
11/14/2019
6.42
3.0
22.7
<2.0
17.1
73
<0.10
0.084
<0.50 <0.50 <0.50
1 <0.50 <1.0 <0.50
05/06/2020
5.20
1.2
20.9
<1.0
21.5
219
<0.10
<0.050
NR
MW-7R
11/06/2020
5.54
1.7
17.8
<1.0
13.0
205
<0.10
<0.050
<0.50 <0.50 <0.50
1 <0.50 <1.0 <0.50
05/11/2021
5.2
1.7
34.2
<1.0
40.4
296
<0.10
0.051
NR
10/27/2021
5.3
1.1
24.9
<1.0
26.0
222
<0.10
<0.050
<0.50 <0.50 <0.50
1 <0.50 <1.0 <0.50
05/10/2022
5.1
<1.0
30.8
<1.0
31.0
279
<0.10
<0.050
NR
11/08/2022
4.9
1.0
31.4
<1.0
24.2
225
<0.10
<0.050
<0.50 <0.50 <0.50
1 <0.50 <1.0 <0.50
MW-7R2
05/03/2023
5.2
1.8
26.6
<1.0
18.4
232
<0.10
<0.050
NR
05/21/2019
6.9
7.9
7.3
<10.0
6.2
249
<0.050
0.290
NR
11/14/2019
6.7
7.7
7.2
2.0
1.2
51.0
<0.10
0.100
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
05/06/2020
6.4
2.7
2.8
<1.0
3.6
139
<0.10
<0.050
NR
11/06/2020
6.3
2.8
2.3
14.0
2.4
127
<0.10
<0.050
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
MW-8
05/11/2021
6.6
3.8
2.0
<1.0
1.7
114
<0.10
<0.050
NR
10/27/2021
6.6
4.7
3.5
1.0
0.86
189
< 0.10
< 0.050
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
05/10/2022
6.7
4.5
7.4
<1.0
3.2
240
<0.10
<0.050
NR
11/08/2022
6.6
6.2
12.2
<1.0
1.4
328
<0.10
<0.050
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
05/03/2023
6.6
4.9
10.9
<1.0
2.2
242
<0.10
<0.050
NR
05/21/2019
5.6
7.2
4.6
<10.0
0.20
80.0
<0.050
0.230
NR
11/14/2019
5.6
6.1
5.4
<1.0
0.89
56.0
<0.10
0.076
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
05/06/2020
5.5
5.9
1.8
<1.0
<0.040
68.0
<0.10
0.099
NR
11/06/2020
4.9
4.5
1.4
16.0
0.043
88.0
<0.10
0.095
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
MW-9
05/11/2021
5.4
3.6
9.8
<2.0
1.9
<25.0
<0.10
0.089
NR
10/27/2021
5.4
3.8
3.2
1.0
0.35
48.0
< 0.10
< 0.050
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
05/10/2022
5.4
1 3.6
6.3
<1.0
1.5
67.0
<0.10
0.086
NR
11/08/2022
5.3
2.8
8.7
<1.0
1.9
81.0
0.17
<0.050
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
05/03/2023
5.1
4.7
13.4
<1.0
3.8
83.0
<0.10
0.080
NR
Notes:
< indicates that the constituent concentration was not detected above the method detection limit
pg/L: micrograms per liter; mg/L: milligrams per liter; mL: milliliter
CFU: colony -forming unit
J: The concentration is above the adjusted method detection limit and below the adjusted reporting limit and is therefore considered an estimate.
NL : No 2L standard exists. NR: not reported. SU: standard unit.
2L standards are set in North Carolina Administrative Code, Title 15A Subchapter 2L - Groundwater Classifications and Standards, Department of Environmental Quality (Amended April 1, 2022). Total organic carbon and nitrate standards are set in Wastewater
Irrigation System Permit Number WQ0004797. There is no defined 2L standard for fecal coliform; therefore, the standard listed is for "total coliform."
Bolded values indicate a concentration equal to or above the respective groundwater standard or outside the groundwater standard range.
pH is analyzed by Anchor QEA of North Carolina, PLLC; INC lab certification number 5445.
Monitoring is performed in accordance with Permit No. WQ0004797 issued to Clement Pappas on May 15, 2020, and effective on September 1, 2020.
Monitoring well MW-7R2 was installed on May 1, 2023 to replace MW-7R.
Spring 2023 Groundwater Sampling Event Page 2 of 2
Clement Pappas, Hendersonville, North Carolina June 2023

Table 3
Current and Historical Surface Water Analytical Results
Sample Name
Sample Date
Q.
V
C
O
r °1
L
H O V
L �
O
i;
E
L
O
�0 =
LL v
i
Z
>
ate+ N
H C �n
m
O
O
EIA
Q
L
0
Q
fa
�. O
° a
(SU)
(mg/L)
(mg/L)
(CFUs per 100 ml-)
(mg/L)
(mg/L)
(mg/L)
1 (mg/L)
28 Standard
6.0 - 9.0
NL
230
200
NL
NL
NL
NL
SW-1
(Upstream)
5/21/2019
7.02
1.6
5.0
98.0
0.75
42.0
<0.050
0.067
11/14/2019
6.76
1.9
5.3
118
0.83
57.0
<0.10
0.1
5/6/2020
7.20
1.6
4.6
290
0.76
49.0
<0.10
0.092
11/6/2020
5.83
1.6
4.4
145
0.71
56.0
<0.10
<0.050
5/11/2021
6.8
1.3
5.3
191
0.80
48.0
<0.10
0.068
10/27/2021
7.0
1.8
5.2
145
0.72
52.0
<0.10
0.061
5/10/2022
7.1
1.4
5.1
81.0
0.88
51.0
0.12
0.15
11/08/22
7.0
2.3
6.6
89.0
0.65
63.0
<0.10
0.13
05/04/23
6.6
1.4
5.0
173
0.69
49.0
<0.10
0.061
SW-2
(Downstream)
5/21/2019
6.99
1.6
4.9
200
0.76
47.0
<0.050
0.068
11/14/2019
7.01
1.9
5.4
127
0.82
83.0
<0.10
0.089
5/6/2020
6.67
1.7
4.2
420
0.72
53.0
<0.10
<0.050
11/6/2020
6.19
1.6
4.4
97.0
0.70
59.0
<0.10
<0.050
5/11/2021
6.9
1.4
5.0
146
0.74
47.0
<0.10
0.061
10/27/2021
6.9
1.9
5.2
145
0.71
55.0
<0.10
0.063
5/10/2022
6.9
1.4
4.9
118
0.87
50.0
<0.10
0.16
11/08/22
7.0
2.3
5.9
164
0.53
54.0
<0.10
0.099
05/04/23
6.6
1.3
4.8
98.0
0.61
43.0
<0.10
0.055
Notes:
< indicates that the constituent concentration was not detected above the laboratory reporting limit
2B standard: surface water standard per North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 2B - Surface Water
CFU: coliform-forming unit
J: The concentration is above the adjusted method detection limit and below the adjusted reporting limit and is therefore considered an estimate.
mg/L: milligrams per liter
mL: milliliters
NL: No NC 2B standard exists
SU: standard unit
Bolded values indicate a concentration equal to or above the respective 2B standard or a value outside the 2B standard range.
Monitoring is performed in accordance with Permit No. WQ0004797 issued to Clement Pappas on May 15, 2020 and effective on September 1, 2020.
Fall 2022 Groundwater Sampling Event Page 1 of 1
Clement Pappas, Hendersonville, North Carolina June 2023

Figures

I;; W-wim ,

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NN
NN AND STORAGE AREA
LEGEND
71
MONITORING WELL ------
OLD OR FORMER MONITORING WELL* k
D SURFACE WATER SAMPLE LOCATION IN Y//
10,
• •CONTOUR• • 1� /-j,� \� �� \ \♦ `♦ `\ ;�Y j/// .\\ \\ \ \\ /�.' \ \\ f \ \ - lC•'ll'�'ril / I I l I hl I /'�_ \\\y.I -
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STREAM CENTERLINE
\a' W-A
Op

Attachment 1
MW-7R2 Well Construction Record and
MW-7R Well Abandonment Record

WELL CONSTRUCTION RECORD
Thh Farn S-0n ba usnd FK 5i ngk 9r m0l iuk wells
1. Wei I Contractor Informallon:
For Frworikil 4rw ON LY:
Stefan Smith
Weft Coililrdclm taarm
3576A
NC Well Cnnlf dor Cal ifraeLion Niollber
SAEDACCO Inc
UOriPui} r+fanlC
#, Wjil fg115trWti0H PcrMiit ff
List LrUd7ppei aWr well glair lfi fEr.. Cfmilh'. Rdw, Yariurtne, ffwGq rjr.0
MAlg,Timulturml DMIMicipaVFttblic
DGeaihemtal tHealiltKoclirlg Apply) DResidenfial WaluSupph' (single)
011{dylstria1fC0rnmerc1ial DResidential Walu Supph' (shared)
❑Irri tion
Nom-watff SUMP y Well:
phlpnilor4Lz ❑RCc€r3 Cr}'
QAgltifcF Rcchmp
❑GFuundyr'LfcF RCn"iafigar
13AglfikF Slorage Trod Reca%v7
❑Salinity Harriu
❑AglrifQF T45t
❑510rrm;'ater E"inagC
❑ExivEin ffiml TrxhnOLpg}'
115ds5;dkrrcc -COM trl
❑GeoilremLal IC'losed Limp)
❑TrauT
❑GmdYennal McAn eCboli ne Rrwnsl
❑Oilier textllain udder #21 1
4. D4te We11(s) Conlplelt',I; 5/1/2023 Well 1Dff MW7R2
50_ k`te11lArratilrn:
Lassonde Pappas Company
Fnciliw TVA! i7F8pplwmblel
485 Brookside Camp Rd., Hendersonville, NC, 28792
Phrsicel Address_ City- and Zip
11 fs. 15 A. sand
ft. fI,
MOLTER CASMG For ouM rasnl ncRs OR Ll ER{iF Ncahk
non TO Rf#bMR Tn�€'rn FSS HhTFRT#I•
0 fL. 5 rL 2" in- SCH-40 PVC
Ub MFR LASI NG OR 71'RING { jln lk-FAMAl clu�-d4miM
PROkI TO � DEiti1ETF.H ­ 7iif€ kK 4. R ERIAL
7'i.SCFiiyN
FROM TO RrammT'FR SLOTSii:R THK-Ki SS MATRR1M.
5 fL 15 f1• 2" iR .010 SCH-40 PVC
F ft ia.
10 fL 13 FL Portland I Pour I
VR1711 113 m4-rEkUl. EMMACTME:ti1-MYTurrn
4 ft. 15 fi, Sand #2
tt, ft.
3n, D1g1I L1MG LOG faattaeli addilionHI stl , if ncecssl ml
0 fL 15 rL fine -medium sand
fL fL
fe, fL
fL fL
fi. ft,
Ff:+ FG
1 1 foot bentonite seal from 3 to 4 feet.
01MM4' PLARCI IdCvlff" ivri Na fP1^t}
ib.14 ituds Awl 1.nngitaliv in tlegr•eeclmirmU*1xconjIF. nr ckcimnl degrmc:
22, CErtifleatiana
{dKL:11SIJ nik:Ll69ui3SINMilk k:31rl
35.378088 N 82.489455 W
5/9/2023
SI�g*rw or W'c11 CallMKtar Dak
6. is I are) Ihrt welUsk 5UPennanent u r 111'emporary
LLf' signMg lfrir harm. f hrrnbr reFji&' roar Me we 4mo tear f werej c�rnm'rca in �xvrdm cn
1rarh U4 NCAC OX .0ifk? or f SA MCAC UC ,0 Weff CbrrafrrKr mr Swndafda ay0 Awi a
7. is thin a repair fe an exist n%wrell. --J'Ycx Irr ®Nrr
r{ x4 r�Fi rryya rr{ 7s' dx ew pfm'udrd r+rib� �l F�f �nr'iFeF
1f Mfs Jx rr fgmir, f U vor 4r?v' w i-di oxt+ fnn f chu rnlor7,wWai 4mrf exgifabi rAe rwnwre of Me
repair urrd ew AIL FinaF�w.YeeJrdm m em the r5cu � of rfibef nun.
y y 1 y i �y 1
23, She d iaWhom or addllltmal well drf8r11:
You Army ,Ise t3fe back Of this Page to provide addifional wdl site de#ails Or well
S.1l umhcr of wa`Ils touslttirctrtd: 1
WnSJ311rdUrl delails. You rria_+' also auach addilicmat pages if uecessan .
for lrtkke(Je jrtfeertwi of nrxi-warer srVph- wefts ONLY mrll My srtanraarrso%w. iw. }%,4 cw)
salbrirme form.
SUBMITTAL INSTUCI70NS
9. Toted wtll depth be&m Wid surfiam 15 ((f.)
24a. Ftc All Wrilx: Subaru{ lies farm williin D days of compkiioo of wet I
FoFrrrllfrrpie wefts Ifsr vli A-f.0f rjdi femrle.Y(wfe- Tti:ZM' awd 2@Jffr}
Con5lniCt1pn to fhc folLouing-
1U. Stair weer levri below hrp. of casing, 11 ffl.1
Division aFVI'ater krNources, Informatiou Vruccsuiog Unit,
If wlelrrfi fir, d es 441O a inaffrg. uu' "4 "
1617 Mail :SCrt'irC Center, I airigh, XC 27699-1617
11. Bmrhole dismrrcr: 8.25" (ice)
tab. For Inimflos Weill ONLY: In addifion Lo sending Me form to e1w address in
24a abm'e. also submit a cop of this form within zp days of cDnipleiiofl of t++ell
l2,'► CII toufilrnetion rnbtho'd, HSA
conSlfuuLiurl 11) lire f01705vi1tg:
{i.e. retar}', cable- dirai pYrshcfa.L
Dh-Ilion tr WAler RemmrceN.lreldergmund Injeciiou Control Program,
FOR WATERSGPPLY WELLS ONLY.
1636 Mail Srrvirx'Center. RLaltith, NC 23699-1636
13at, Vidd (aint) ?Nahrul of Icst'
24r- For Wj4W Ste * In"gtturn V4'ft
Also submit One cop} of this foilll %tiithin 30 days ofconrplelion of
13b. bisini'm6m hper Amount:
wdl cnosinirtian to the ¢rnmr; health depu air= of the roomy whom
-
Corr5truCt4d
Farin GW-L Nonh Carat Ira D,�pnnrcilE DIEM ilolUMILI aid NICILF21 %.WLliroti - DLL:n YDii or W21or Ravin Rt, IStd ALIgust 2413

WELL ABANDONMENT RECORD
This faun can be used for siggie or mullipte wells
1, Wen Cpatrggwr lnfriinngtion_
170T Irkirrul Use ONLY:
W E [.L A BAN DQN M ENT DETAM
Stefan Smith 7:L Numlrrr kriwdis beio%alrandoued. 1
V A-Commelm hfanle (or sled onirT persmwtl, abandmluig, A an hK lrr prapcny) F,-y nridupre OiNiVicur uP NUN HYAW etrppA-
c+ousrrxcriori rxar.vb mt cwe j;jrai.
3576A
NC Wcll CuFfl Dior Carl ifrrllian hltunber
SAEDACCO Inc
C0111Pan,. Mania
2. Wa1 Canstrmction Per m t 4 ,.--,____-- .
1.,Kr <Nr .qp i'ka Je w 11 prrmiex r,.r- Cr ram . S&w. J ur,.om w- I"Y,ui; rim. ij kkr,rre
& Wd t use (chrrk well uae):
Winer Supply Well;
❑Agrir.altkttlrl
❑Gee t4mwt ftalin000Ling Supplyi
❑ indingirial(Comrmrcial
❑irripliois
Non -Water SaI" Well -
❑Aquifer RecharDV
[:]Aquifer Stonkgr and 1kC0 M
❑Aquifer Teal
❑ExprAincnl9l Trclrrirpbe-w
DGwihenikal (ClasixdLoopk
LIC,eo(hemal (Heatingr'C'ooliug
i. DaM wgIL(F) ab;mdnnM- 5/l/2023
Am. T''rii iteration
Lassonde Pappas Company
FacileH."vrcrName
11hlrtnir-#M11l'tiblic
❑Rrsidknrial Water Supply f-,ingle)
❑Rcsidlenriat warn ��uppl' tshared i
00irumiduarer Rentedialiour
❑Salinii; Hamer
❑Stornm,dicr Dminagr
❑Subsidnxe C'orrml
l7Tracer
LICglkefinplain under 7g)
Irtrilils MM ff upplt, Nei
485 Brookside Camp Rd. Hendersonville, NC 28792
PhL-sisal Ad&as. Cti4, and Zip
Henderson
Cawai.s
Parcel1&0:1k 6411.NO. (PIN)
I;k 1�wfiojde And lonF,iM& in du1uvcsAM rutmiwmndsardccimal dcl cm
{ifvV.11 I'KA0, itiw UVWLS i. Vifii4rCip
35.378088
N
82.489455
arlh MLY wig Oke save
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FOR WATER SUPPLY WEL[ 5 ONIA;
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7C, SCAlingr mgtcrials used (Cheek ik111hat mpply)-
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amid did a copy ofAriN record h N beeir pro ded fa fhe wef! owner.
9. Site diagram or addlt[oilalvvell details:
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W abartdonutertl detail,. You ma}• a1w 1112CIL additional pages if rkeC M(V-
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Attachment 2
Laboratory Analytical Reports and
Chain -of -Custody Forms

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
May 11, 2023
Jennifer Verde
Anchor QEA
231 Haywood Street
Asheville, NC 28801
RE: Project: LASSONDE PAPPAS SPRING WQ
Pace Project No.: 92665684
Dear Jennifer Verde:
Enclosed are the analytical results for sample(s) received by the laboratory on May 03, 2023. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
%5x_s1—
Erick Hanna
[e-mail]
[phone]
Project Manager
Enclosures
cc: Jessica Mayers, Anchor QEA
Christian Patterson, Anchor QEA
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
CERTIFICATIONS
Project: LASSONDE PAPPAS SPRING WQ
Pace Project No.: 92665684
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, INC 28804 South Carolina Laboratory ID: 99030
Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001
North Carolina Drinking Water Certification #: 37712 Virginia/VELAP Certification #: 460222
North Carolina Wastewater Certification #: 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
LASSONDE PAPPAS SPRING WQ
92665684
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92665684001
MW-8-20230503
SM 2540C-2015
JMH1
1
PASI-A
SM 9222D-2015
SMS
1
PASI-A
EPA 350.1 Rev 2.0 1993
ARJ
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
Zip
1
PASI-A
SM 4500-CI-E-2011
KDF1
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92665684002
MW-7R2-20230503
SM 2540C-2015
JMH1
1
PASI-A
SM 9222D-2015
SMS
1
PASI-A
EPA 350.1 Rev 2.0 1993
ARJ
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
Zip
1
PASI-A
SM 4500-CI-E-2011
KDF1
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92665684003
MW-6-20230503
SM 2540C-2015
JMH1
1
PASI-A
SM 9222D-2015
SMS
1
PASI-A
EPA 350.1 Rev 2.0 1993
ARJ
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
Zip
1
PASI-A
SM 4500-CI-E-2011
KDF1
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92665684004
MW-5-20230503
SM 2540C-2015
JMH1
1
PASI-A
SM 9222D-2015
SMS
1
PASI-A
EPA 350.1 Rev 2.0 1993
ARJ
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
Zip
1
PASI-A
SM 4500-CI-E-2011
KDF1
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92665684005
MW-4-20230503
SM 2540C-2015
JMH1
1
PASI-A
SM 9222D-2015
SMS
1
PASI-A
EPA 350.1 Rev 2.0 1993
ARJ
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
Zip
1
PASI-A
SM 4500-CI-E-2011
KDF1
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92665684006
MW-9-20230503
SM 2540C-2015
MAB2
1
PASI-A
SM 9222D-2015
SMS
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Project: LASSONDE PAPPAS SPRING WQ
Pace Project No.: 92665684
Analytes
Lab ID Sample ID
Method
Analysts
Reported
Laboratory
EPA 350.1 Rev 2.0 1993
ARJ
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
Zip
1
PASI-A
SM 4500-CI-E-2011
KDF1
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: LASSONDE PAPPAS SPRING WQ
Pace Project No.: 92665684
Sample: MW-8-20230503 Lab ID: 92665684001 Collected: 05/03/23 09:17 Received: 05/03/23 16:46 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
242 mg/L 25.0
1
05/05/23 13:35
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2015 Preparation
Method: SM 9222D-2015
Pace Analytical Services -Asheville
Fecal Coliforms
ND CFU/100 mL 1.0
1
05/03/23 17:12 05/04/23 15:26
1g
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L 0.10
1
05/09/23 13:33
7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
2.2 mg/L 0.040
1
05/04/23 03:42
14797-55-8
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
ND mg/L 0.050
1
05/09/2311:29 05/09/2315:05
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
10.9 mg/L 1.0
1
05/09/23 08:08
16887-00-6
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
4.9 mg/L 1.0
1
05/09/23 15:05
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11 /2023 03:19 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: LASSONDE PAPPAS SPRING WQ
Pace Project No.: 92665684
Sample: MW-7R2-20230503 Lab ID: 92665684002 Collected: 05/03/23 14:22 Received: 05/03/23 16:46 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Total Dissolved Solids
MBIO 9222D Fecal Coliform AVL
Fecal Coliforms
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
365.1 Phosphorus, Total
Phosphorus
4500 Chloride
Chloride
531013 TOC
Total Organic Carbon
Date: 05/11/2023 03:19 PM
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
232 mg/L 25.0
1
05/05/2313:35
Analytical Method: SM 9222D-2015 Preparation
Method: SM 9222D-2015
Pace Analytical Services -Asheville
ND CFU/100 mL 1.0
1
05/03/23 17:45 05/04/23 15:26
2g
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
ND mg/L 0.10
1
05/09/2313:34
7664-41-7
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
18.4 mg/L 0.40
10
05/04/23 04:02
14797-55-8
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation
Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
ND mg/L 0.050
1
05/09/2311:29 05/09/2315:06
7723-14-0
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
26.6 mg/L 1.0
1
05/09/23 08:09
16887-00-6
Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
1.8 mg/L 1.0
1
05/09/2315:26
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: LASSONDE PAPPAS SPRING WQ
Pace Project No.: 92665684
Sample: MW-6-20230503 Lab ID: 92665684003 Collected: 05/03/23 13:20 Received: 05/03/23 16:46 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Total Dissolved Solids
MBIO 9222D Fecal Coliform AVL
Fecal Coliforms
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
365.1 Phosphorus, Total
Phosphorus
4500 Chloride
Chloride
531013 TOC
Total Organic Carbon
Date: 05/11/2023 03:19 PM
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
86.0 mg/L 25.0
1
05/05/2313:35
Analytical Method: SM 9222D-2015 Preparation
Method: SM 9222D-2015
Pace Analytical Services -Asheville
15.0 CFU/100 mL 1.0
1
05/03/23 17:45 05/04/23 15:26
2g
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
ND mg/L 0.10
1
05/09/2313:36
7664-41-7
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
0.15 mg/L 0.040
1
05/04/23 03:52
14797-55-8
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
ND mg/L 0.050
1
05/09/2311:29 05/09/2315:08
7723-14-0
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
8.8 mg/L 1.0
1
05/09/23 08:10
16887-00-6
Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
1.5 mg/L 1.0
1
05/09/2315:53
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: LASSONDE PAPPAS SPRING WQ
Pace Project No.: 92665684
Sample: MW-5-20230503 Lab ID: 92665684004 Collected: 05/03/23 15:35 Received: 05/03/23 16:46 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Total Dissolved Solids
MBIO 9222D Fecal Coliform AVL
Fecal Coliforms
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
365.1 Phosphorus, Total
Phosphorus
4500 Chloride
Chloride
531013 TOC
Total Organic Carbon
Date: 05/11/2023 03:19 PM
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
75.0 mg/L 25.0
1
05/05/2313:35
Analytical Method: SM 9222D-2015 Preparation
Method: SM 9222D-2015
Pace Analytical Services -Asheville
ND CFU/100 mL 1.0
1
05/03/23 17:45 05/04/23 15:26
2g
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
ND mg/L 0.10
1
05/09/2313:37
7664-41-7
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
0.049 mg/L 0.040
1
05/04/23 04:05
14797-55-8
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
0.075 mg/L 0.050
1
05/09/2311:29 05/09/2315:09
7723-14-0
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
4.2 mg/L 1.0
1
05/09/23 08:14
16887-00-6
Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
6.3 mg/L 1.0
1
05/09/2316:09
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 8 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: LASSONDE PAPPAS SPRING WQ
Pace Project No.: 92665684
Sample: MW-4-20230503 Lab ID: 92665684005 Collected: 05/03/23 10:44 Received: 05/03/23 16:46 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
126 mg/L 25.0
1
05/05/23 13:35
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2015 Preparation
Method: SM 9222D-2015
Pace Analytical Services -Asheville
Fecal Coliforms
ND CFU/100 mL 1.0
1
05/03/23 17:12 05/04/23 15:26
1g
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L 0.10
1
05/09/23 13:39
7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
0.66 mg/L 0.040
1
05/04/23 03:46
14797-55-8
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
ND mg/L 0.050
1
05/09/2311:29 05/09/2315:10
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
10.3 mg/L 1.0
1
05/09/23 08:15
16887-00-6
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
3.3 mg/L 1.0
1
05/09/23 16:29
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11 /2023 03:19 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: LASSONDE PAPPAS SPRING WQ
Pace Project No.: 92665684
Sample: MW-9-20230503 Lab ID: 92665684006 Collected: 05/03/23 12:01 Received: 05/03/23 16:46 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Total Dissolved Solids
MBIO 9222D Fecal Coliform AVL
Fecal Coliforms
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
365.1 Phosphorus, Total
Phosphorus
4500 Chloride
Chloride
531013 TOC
Total Organic Carbon
Date: 05/11/2023 03:19 PM
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
83.0 mg/L 25.0
1
05/07/2315:04
Analytical Method: SM 9222D-2015 Preparation
Method: SM 9222D-2015
Pace Analytical Services -Asheville
ND CFU/100 mL 1.0
1
05/03/23 17:45 05/04/23 15:26
2g
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
ND mg/L 0.10
1
05/09/2313:40
7664-41-7
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
3.8 mg/L 0.040
1
05/04/23 03:48
14797-55-8
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
0.080 mg/L 0.050
1
05/09/2311:29 05/09/2315:10
7723-14-0
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
13.4 mg/L 1.0
1
05/09/23 08:16
16887-00-6
Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
4.7 mg/L 1.0
1
05/09/2316:47
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 10 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: LASSONDE PAPPAS SPRING WQ
Pace Project No.: 92665684
QC Batch: 772653 Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92665684001, 92665684002, 92665684003, 92665684004, 92665684005
METHOD BLANK: 4010883
Matrix:
Water
Associated Lab Samples: 92665684001, 92665684002, 92665684003, 92665684004, 92665684005
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Total Dissolved Solids
mg/L
ND
25.0
05/05/23 13:31
LABORATORY CONTROL SAMPLE:
4010884
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Total Dissolved Solids
mg/L
251
246
98 90-110
SAMPLE DUPLICATE: 4010885
92665461001 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 162 165 2
SAMPLE DUPLICATE: 4010886
92665594001 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 740 450 49 D6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2023 03:19 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 23

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: LASSONDE PAPPAS SPRING WQ
Pace Project No.: 92665684
QC Batch: 772873 Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92665684006
METHOD BLANK: 4012129
Associated Lab Samples: 92665684006
Parameter
Units
Total Dissolved Solids
mg/L
LABORATORY CONTROL SAMPLE:
4012130
Parameter
Units
Total Dissolved Solids
mg/L
SAMPLE DUPLICATE: 4012131
Parameter
Units
Total Dissolved Solids
mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
N D 25.0 05/07/23 15:04
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
251 250 100 90-110
92665979001 Dup
Result Result RPD Qualifiers
91.0 89.0 2
SAMPLE DUPLICATE: 4012132
92665764002 Dup
Parameter Units Result Result
Total Dissolved Solids mg/L 751 736
RPD Qualifiers
2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/11/2023 03:19 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 23

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: LASSONDE PAPPAS SPRING WQ
Pace Project No.: 92665684
QC Batch: 772628 Analysis Method: SM 9222D-2015
QC Batch Method: SM 9222D-2015 Analysis Description: 9222D Fecal Coliform(MF) -AVL
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92665684001, 92665684002, 92665684003, 92665684004, 92665684005, 92665684006
METHOD BLANK: 4010801 Matrix: Water
Associated Lab Samples: 92665684001, 92665684002, 92665684003, 92665684004, 92665684005, 92665684006
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Fecal Coliforms CFU/100 mL ND 1.0 05/04/23 15:11
SAMPLE DUPLICATE: 4010802
92665621001 Dup
Parameter Units Result Result RPD Qualifiers
Fecal Coliforms CFU/100 mL ND ND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11 /2023 03:19 PM without the written consent of Pace Analytical Services, LLC.
Page 13 of 23

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: LASSONDE PAPPAS SPRING WQ
Pace Project No.: 92665684
QC Batch: 772834 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92665684001, 92665684002, 92665684003, 92665684004, 92665684005, 92665684006
METHOD BLANK: 4011964
Matrix:
Water
Associated Lab Samples: 92665684001, 92665684002, 92665684003, 92665684004, 92665684005, 92665684006
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Nitrogen, Ammonia
mg/L
ND
0.10
05/09/23 13:14
LABORATORY CONTROL SAMPLE:
4011965
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Nitrogen, Ammonia
mg/L
5
5.1
101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4011966 4011967
MS MSD
92665529001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 2.0 5 5 7.0 6.9 100 100 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4011968 4011969
MS MSD
92665531001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 0.33 5 5 5.3 5.3 100 100 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/11 /2023 03:19 PM without the written consent of Pace Analytical Services, LLC.
Page 14 of 23

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: LASSONDE PAPPAS SPRING WQ
Pace Project No.: 92665684
QC Batch: 772226 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92665684001, 92665684002, 92665684003, 92665684004, 92665684005, 92665684006
METHOD BLANK: 4008951
Matrix:
Water
Associated Lab Samples: 92665684001, 92665684002, 92665684003, 92665684004, 92665684005, 92665684006
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Nitrogen, Nitrate
mg/L
ND
0.040
05/04/23 03:25
LABORATORY CONTROL SAMPLE:
4008952
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Nitrogen, Nitrate
mg/L
1.5
1.4
92 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4008953 4008954
MS MSD
92665508001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrate mg/L ND 1.5 1.5 1.3 1.3 89 88 90-110 2
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4008955 4008956
MS MSD
92665547002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrate mg/L 0.25 1.5 1.5 1.7 1.7 96 94 90-110 2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/11 /2023 03:19 PM without the written consent of Pace Analytical Services, LLC.
Page 15 of 23

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: LASSONDE PAPPAS SPRING WQ
Pace Project No.: 92665684
QC Batch: 773093 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92665684001, 92665684002, 92665684003, 92665684004, 92665684005, 92665684006
METHOD BLANK: 4012823
Matrix:
Water
Associated Lab Samples: 92665684001, 92665684002, 92665684003, 92665684004, 92665684005, 92665684006
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Phosphorus
mg/L
ND
0.050
05/09/2314:55
LABORATORY CONTROL SAMPLE:
4012824
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Phosphorus
mg/L
2.5
2.5
102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4012825 4012826
MS MSD
92665531003 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L ND 2.5 2.5 2.7 2.6 107 104 90-110 3
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4012827 4012828
MS MSD
92665531004 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L 0.083 2.5 2.5 2.7 2.8 106 107 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/11 /2023 03:19 PM without the written consent of Pace Analytical Services, LLC.
Page 16 of 23

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: LASSONDE PAPPAS SPRING WQ
Pace Project No.: 92665684
QC Batch: 772962 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92665684001, 92665684002, 92665684003, 92665684004, 92665684005, 92665684006
METHOD BLANK: 4012254
Matrix:
Water
Associated Lab Samples: 92665684001, 92665684002, 92665684003, 92665684004, 92665684005, 92665684006
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Chloride
mg/L
ND
1.0
05/09/23 07:19
LABORATORY CONTROL SAMPLE:
4012255
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Chloride
mg/L
20
21.2
106 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4012256 4012257
MS MSD
92664065001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 35.1 10 10 47.1 46.8 120 117 90-110 1 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4012258 4012259
MS MSD
92664155001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 9.6 10 10 19.3 19.6 97 100 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11 /2023 03:19 PM without the written consent of Pace Analytical Services, LLC.
Page 17 of 23

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: LASSONDE PAPPAS SPRING WQ
Pace Project No.: 92665684
QC Batch: 773276 Analysis Method: SM 531 OB-2014
QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92665684001, 92665684002, 92665684003, 92665684004, 92665684005, 92665684006
METHOD BLANK: 4013703
Matrix:
Water
Associated Lab Samples: 92665684001, 92665684002, 92665684003, 92665684004, 92665684005, 92665684006
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Total Organic Carbon
mg/L
ND
1.0
05/09/23 13:53
LABORATORY CONTROL SAMPLE:
4013704
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Total Organic Carbon
mg/L
25
24.3
97 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4013705 4013706
MS MSD
92665614001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L 2.0 25 25 25.5 25.5 94 94 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/11 /2023 03:19 PM without the written consent of Pace Analytical Services, LLC.
Page 18 of 23

Pace Analytical Services, LLC
leac,yficalAnal2225 Riverside Dr.
Asheville, NC 28804
www.pacelabs.com [phone]
QUALIFIERS
Project: LASSONDE PAPPAS SPRING WQ
Pace Project No.: 92665684
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
1g Negative control associated with sample indicates possible contamination
2g Readout not completed within method requirements, 24+/-2 hours.
D6 The precision between the sample and sample duplicate exceeded laboratory control limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
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Date: 05/11/2023 03:19 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 23

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
LASSONDE PAPPAS SPRING WQ
92665684
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method Batch
92665684001
MW-8-20230503
SM 2540C-2015
772653
92665684002
MW-7R2-20230503
SM 2540C-2015
772653
92665684003
MW-6-20230503
SM 2540C-2015
772653
92665684004
MW-5-20230503
SM 2540C-2015
772653
92665684005
MW-4-20230503
SM 2540C-2015
772653
92665684006
MW-9-20230503
SM 254OC-2015
772873
92665684001
MW-8-20230503
SM 9222D-2015
772628
SM 9222D-2015 772642
92665684002
MW-7R2-20230503
SM 9222D-2015
772628
SM 9222D-2015 772642
92665684003
MW-6-20230503
SM 9222D-2015
772628
SM 9222D-2015 772642
92665684004
MW-5-20230503
SM 9222D-2015
772628
SM 9222D-2015 772642
92665684005
MW-4-20230503
SM 9222D-2015
772628
SM 9222D-2015 772642
92665684006
MW-9-20230503
SM 9222D-2015
772628
SM 9222D-2015 772642
92665684001
MW-8-20230503
EPA 350.1 Rev 2.0 1993
772834
92665684002
MW-7112-20230503
EPA 350.1 Rev 2.0 1993
772834
92665684003
MW-6-20230503
EPA 350.1 Rev 2.0 1993
772834
92665684004
MW-5-20230503
EPA 350.1 Rev 2.0 1993
772834
92665684005
MW-4-20230503
EPA 350.1 Rev 2.0 1993
772834
92665684006
MW-9-20230503
EPA 350.1 Rev 2.0 1993
772834
92665684001
MW-8-20230503
EPA 353.2 Rev 2.0 1993
772226
92665684002
MW-7R2-20230503
EPA 353.2 Rev 2.0 1993
772226
92665684003
MW-6-20230503
EPA 353.2 Rev 2.0 1993
772226
92665684004
MW-5-20230503
EPA 353.2 Rev 2.0 1993
772226
92665684005
MW-4-20230503
EPA 353.2 Rev 2.0 1993
772226
92665684006
MW-9-20230503
EPA 353.2 Rev 2.0 1993
772226
92665684001
MW-8-20230503
EPA 365.1 Rev 2.0 1993
773093
EPA 365.1 Rev 2.0 1993 773298
92665684002
MW-7R2-20230503
EPA 365.1 Rev 2.0 1993
773093
EPA 365.1 Rev 2.0 1993 773298
92665684003
MW-6-20230503
EPA 365.1 Rev 2.0 1993
773093
EPA 365.1 Rev 2.0 1993 773298
92665684004
MW-5-20230503
EPA 365.1 Rev 2.0 1993
773093
EPA 365.1 Rev 2.0 1993 773298
92665684005
MW-4-20230503
EPA 365.1 Rev 2.0 1993
773093
EPA 365.1 Rev 2.0 1993 773298
92665684006
MW-9-20230503
EPA 365.1 Rev 2.0 1993
773093
EPA 365.1 Rev 2.0 1993 773298
92665684001
MW-8-20230503
SM 4500-CI-E-2011
772962
92665684002
MW-7R2-20230503
SM 4500-CI-E-2011
772962
92665684003
MW-6-20230503
SM 4500-CI-E-2011
772962
92665684004
MW-5-20230503
SM 4500-CI-E-2011
772962
92665684005
MW-4-20230503
SM 4500-CI-E-2011
772962
92665684006
MW-9-20230503
SM 4500-CI-E-2011
772962
92665684001
MW-8-20230503
SM 531OB-2014
773276
92665684002
MW-7R2-20230503
SM 531OB-2014
773276
92665684003
MW-6-20230503
SM 531OB-2014
773276
92665684004
MW-5-20230503
SM 531OB-2014
773276
92665684005
MW-4-20230503
SM 531OB-2014
773276
92665684006
MW-9-20230503
SM 531OB-2014
773276
REPORT OF LABORATORY ANALYSIS
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Date: 05/11/2023 03:19 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 23

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Page 23 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
May 11, 2023
Jennifer Verde
Anchor QEA
231 Haywood Street
Asheville, NC 28801
RE: Project: LASSONDE PAPPAS SPRING 2023 WQ
Pace Project No.: 92665946
Dear Jennifer Verde:
Enclosed are the analytical results for sample(s) received by the laboratory on May 04, 2023. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
%5x_s1—
Erick Hanna
[e-mail]
[phone]
Project Manager
Enclosures
cc: Jessica Mayers, Anchor QEA
Christian Patterson, Anchor QEA
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 18

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
CERTIFICATIONS
Project: LASSONDE PAPPAS SPRING 2023 WQ
Pace Project No.: 92665946
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, INC 28804 South Carolina Laboratory ID: 99030
Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001
North Carolina Drinking Water Certification #: 37712 Virginia/VELAP Certification #: 460222
North Carolina Wastewater Certification #: 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 18

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
LASSONDE PAPPAS SPRING 2023 WQ
92665946
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92665946001
SW-1
SM 2540C-2015
JMH1
1
PASI-A
SM 9222D-2015
YEG
1
PASI-A
EPA 350.1 Rev 2.0 1993
ARJ
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
Zip
1
PASI-A
SM 4500-CI-E-2011
KDF1
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92665946002
SW-2
SM 2540C-2015
JMH1
1
PASI-A
SM 9222D-2015
YEG
1
PASI-A
EPA 350.1 Rev 2.0 1993
ARJ
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
Zip
1
PASI-A
SM 4500-CI-E-2011
KDF1
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 18

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: LASSONDE PAPPAS SPRING 2023 WQ
Pace Project No.: 92665946
Sample: SW-1 Lab ID: 92665946001 Collected: 05/04/23 12:17 Received: 05/04/23 13:33 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
49.0 mg/L 25.0
1
05/09/23 10:22
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2015 Preparation
Method: SM 9222D-2015
Pace Analytical Services -Asheville
Fecal Coliforms
173 CFU/100 mL 1.0
1
05/04/23 16:19 05/05/23 14:46
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L 0.10
1
05/09/23 13:45
7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
0.69 mg/L 0.040
1
05/05/23 00:24
14797-55-8
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
0.061 mg/L 0.050
1
05/09/2311:29 05/09/2315:17
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
5.0 mg/L 1.0
1
05/09/23 08:17
16887-00-6
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
1.4 mg/L 1.0
1
05/09/23 17:07
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11 /2023 06:46 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 18

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: LASSONDE PAPPAS SPRING 2023 WQ
Pace Project No.: 92665946
Sample: SW-2 Lab ID: 92665946002 Collected: 05/04/23 11:32 Received: 05/04/23 13:33 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
43.0 mg/L 25.0
1
05/09/23 10:22
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2015 Preparation
Method: SM 9222D-2015
Pace Analytical Services -Asheville
Fecal Coliforms
98.0 CFU/100 mL 1.0
1
05/04/23 16:19 05/05/23 14:46
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L 0.10
1
05/09/23 13:49
7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
0.61 mg/L 0.040
1
05/05/23 00:23
14797-55-8
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
0.055 mg/L 0.050
1
05/10/2311:40 05/10/2314:59
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
4.8 mg/L 1.0
1
05/09/23 08:18
16887-00-6
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
1.3 mg/L 1.0
1
05/09/23 17:25
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11 /2023 06:46 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 18

Pace Analytical Services, LLC
leac,yficalAnal2225 Riverside Dr.
Asheville, NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: LASSONDE PAPPAS SPRING 2023 WQ
Pace Project No.: 92665946
QC Batch: 773137 Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92665946001, 92665946002
METHOD BLANK: 4013069
Associated Lab Samples: 92665946001, 92665946002
Parameter
Units
Total Dissolved Solids
mg/L
LABORATORY CONTROL SAMPLE:
4013070
Parameter
Units
Total Dissolved Solids
mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
N D 25.0 05/09/23 10:20
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
250 246 98 90-110
SAMPLE DUPLICATE: 4013071
92665967001 Dup
Parameter Units Result Result
Total Dissolved Solids mg/L 121 122
SAMPLE DUPLICATE: 4013072
92665946002 Dup
Parameter Units Result Result
Total Dissolved Solids mg/L 43.0 46.0
RPD Qualifiers
1
RPD Qualifiers
7
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11 /2023 06:46 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 18

Pace Analytical Services, LLC
leac,yficalAnal2225 Riverside Dr.
Asheville, NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: LASSONDE PAPPAS SPRING 2023 WQ
Pace Project No.: 92665946
QC Batch: 772748 Analysis Method: SM 9222D-2015
QC Batch Method: SM 9222D-2015 Analysis Description: 9222D Fecal Coliform(MF) -AVL
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92665946001, 92665946002
METHOD BLANK: 4011544
Matrix:
Water
Associated Lab Samples: 92665946001, 92665946002
Blank
Reporting
Parameter
Units
Result
Limit Analyzed Qualifiers
Fecal Coliforms
CFU/100 mL
ND
1.0 05/05/23 14:46
SAMPLE DUPLICATE: 4011546
92665856001
Dup
Parameter
Units
Result
Result RPD Qualifiers
Fecal Coliforms
CFU/100 mL
20.0
15.0 29 D6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11 /2023 06:46 PM without the written consent of Pace Analytical Services, LLC.
Page 7 of 18

Pace Analytical Services, LLC
leac,yficalAnal2225 Riverside Dr.
Asheville, NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: LASSONDE PAPPAS SPRING 2023 WQ
Pace Project No.: 92665946
QC Batch: 772834 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92665946001, 92665946002
METHOD BLANK: 4011964
Matrix:
Water
Associated Lab Samples: 92665946001, 92665946002
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Nitrogen, Ammonia
mg/L
ND
0.10
05/09/23 13:14
LABORATORY CONTROL SAMPLE:
4011965
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Nitrogen, Ammonia
mg/L
5
5.1
101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4011966 4011967
MS MSD
92665529001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 2.0 5 5 7.0 6.9 100 100 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4011968 4011969
MS MSD
92665531001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 0.33 5 5 5.3 5.3 100 100 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11 /2023 06:46 PM without the written consent of Pace Analytical Services, LLC.
Page 8 of 18

Pace Analytical Services, LLC
leac,yficalAnal2225 Riverside Dr.
Asheville, NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: LASSONDE PAPPAS SPRING 2023 WQ
Pace Project No.: 92665946
QC Batch: 772512 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92665946001, 92665946002
METHOD BLANK: 4010410
Matrix:
Water
Associated Lab Samples: 92665946001, 92665946002
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Nitrogen, Nitrate
mg/L
ND
0.040
05/04/23 23:57
LABORATORY CONTROL SAMPLE:
4010411
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Nitrogen, Nitrate
mg/L
1.5
1.5
102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4010412 4010413
MS MSD
92665767001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrate mg/L 0.63 1.5 1.5 2.4 2.4 116 118 90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4010414 4010415
MS MSD
92665827010 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrate mg/L 0.085 1.5 1.5 1.7 1.7 111 108 90-110 2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11 /2023 06:46 PM without the written consent of Pace Analytical Services, LLC.
Page 9 of 18

Pace Analytical Services, LLC
leac,yficalAnal2225 Riverside Dr.
Asheville, NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: LASSONDE PAPPAS SPRING 2023 WQ
Pace Project No.: 92665946
QC Batch: 773093 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92665946001
METHOD BLANK: 4012823
Associated Lab Samples: 92665946001
Parameter Units
Phosphorus mg/L
LABORATORY CONTROL SAMPLE: 4012824
Parameter Units
Phosphorus mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
N D 0.050 05/09/23 14:55
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
2.5 2.5 102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4012825 4012826
MS MSD
92665531003 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L ND 2.5 2.5 2.7 2.6 107 104 90-110 3
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4012827 4012828
MS MSD
92665531004 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L 0.083 2.5 2.5 2.7 2.8 106 107 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11 /2023 06:46 PM without the written consent of Pace Analytical Services, LLC.
Page 10 of 18

Pace Analytical Services, LLC
leac,yficalAnal2225 Riverside Dr.
Asheville, NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: LASSONDE PAPPAS SPRING 2023 WQ
Pace Project No.: 92665946
QC Batch: 773401 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92665946002
METHOD BLANK: 4014350
Associated Lab Samples: 92665946002
Parameter Units
Phosphorus mg/L
LABORATORY CONTROL SAMPLE: 4014351
Parameter Units
Phosphorus mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.050 05/10/2314:38
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
2.5 2.5 102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4014352 4014353
MS MSD
92664829001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L 4.7 2.5 2.5 7.4 7.3 108 105 90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4014354 4014355
MS MSD
92665176001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L 0.094 2.5 2.5 2.7 2.7 105 106 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11 /2023 06:46 PM without the written consent of Pace Analytical Services, LLC.
Page 11 of 18

Pace Analytical Services, LLC
leac,yficalAnal2225 Riverside Dr.
Asheville, NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: LASSONDE PAPPAS SPRING 2023 WQ
Pace Project No.: 92665946
QC Batch: 772962 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92665946001, 92665946002
METHOD BLANK: 4012254
Matrix:
Water
Associated Lab Samples: 92665946001, 92665946002
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Chloride
mg/L
ND
1.0
05/09/23 07:19
LABORATORY CONTROL SAMPLE:
4012255
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Chloride
mg/L
20
21.2
106 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4012256 4012257
MS MSD
92664065001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 35.1 10 10 47.1 46.8 120 117 90-110 1 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4012258 4012259
MS MSD
92664155001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 9.6 10 10 19.3 19.6 97 100 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11 /2023 06:46 PM without the written consent of Pace Analytical Services, LLC.
Page 12 of 18

Pace Analytical Services, LLC
leac,yficalAnal2225 Riverside Dr.
Asheville, NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: LASSONDE PAPPAS SPRING 2023 WQ
Pace Project No.: 92665946
QC Batch: 773276 Analysis Method: SM 531 OB-2014
QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92665946001, 92665946002
METHOD BLANK: 4013703
Matrix:
Water
Associated Lab Samples: 92665946001, 92665946002
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Total Organic Carbon
mg/L
ND
1.0
05/09/23 13:53
LABORATORY CONTROL SAMPLE:
4013704
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Total Organic Carbon
mg/L
25
24.3
97 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4013705 4013706
MS MSD
92665614001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L 2.0 25 25 25.5 25.5 94 94 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11 /2023 06:46 PM without the written consent of Pace Analytical Services, LLC.
Page 13 of 18

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALIFIERS
Project: LASSONDE PAPPAS SPRING 2023 WQ
Pace Project No.: 92665946
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
D6 The precision between the sample and sample duplicate exceeded laboratory control limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
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[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
LASSONDE PAPPAS SPRING 2023 WQ
92665946
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92665946001
SW-1
SM 2540C-2015
773137
92665946002
SW-2
SM 2540C-2015
773137
92665946001
SW-1
SM 9222D-2015
772748
SM 9222D-2015
772751
92665946002
SW-2
SM 9222D-2015
772748
SM 9222D-2015
772751
92665946001
SW-1
EPA 350.1 Rev 2.0 1993
772834
92665946002
SW-2
EPA 350.1 Rev 2.0 1993
772834
92665946001
SW-1
EPA 353.2 Rev 2.0 1993
772512
92665946002
SW-2
EPA 353.2 Rev 2.0 1993
772512
92665946001
SW-1
EPA 365.1 Rev 2.0 1993
773093
EPA 365.1 Rev 2.0 1993
773298
92665946002
SW-2
EPA 365.1 Rev 2.0 1993
773401
EPA 365.1 Rev 2.0 1993
773579
92665946001
SW-1
SM 4500-CI-E-2011
772962
92665946002
SW-2
SM 4500-CI-E-2011
772962
92665946001
SW-1
SM 5310E-2014
773276
92665946002
SW-2
SM 5310E-2014
773276
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/11/2023 06:46 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 18

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Page 17 of 18

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Page 18 of 18

Attachment 3
Well Sampling Logs and Instrument
Calibration Data Sheet

#szANCHOR
(�F w 16.0&.v
�jj� e.w
5vD3[ti3
uipment Documentation and Instrument Calibration Data Sheet
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Name:Ld5S&yyU YGQQ�y� j Monii•af- reI t Analyst Conducting Calibration:
s2�(h0.
Project Number: �1 y'81-01- 0I Date of Calibration: ( L 2-02
Project Location: t 1%�d 4J«nV1«2t NK' Date of Field Measurements: 0$(03
Facility ID or Permit # (if applicable): _ W-MM" 47;Ir a::I_
tQU1rMlN I OUCUMtN 1A11UN
Rental sample analysis equipment or meters used to take measurements:
EcluipmentType
Brand Serial Number Date of Use
Hach 2100Q (s/n 151006045207)
Rental Hach 2100Q (s/n i
Instrument Readings
(Hach 21000)
10 NTU 20 NTU 100 NTU
Z Z A7AIS RIIS3
053 Q
Cal (NTU): Cal (fyTU) 3
Time: ' j _tf/ Time: `1
*Pre -Analysis Result t((NTU : l� Time 31
Check (10 NTU): " 1 `$
*Post.Analysis Result W lt` e(•N�TU): Time:
of
Check (10 NTU): - I - sot
Rental Company
800 NTU
2 m
Cal (NTU):
Time:
OS/a3123
Select Turbidimeter.
Cal Std_ Information
Lot #
iration Date.
Calibration
Verification:
YSI Professional Plus Muldparameter Meter
4Ab418111481802). [ 6
Instrument Readings
Cal Std Information
Lot #
Date
0 ened
Exp. Date
Dissolved Oxygen
(% saturation)
Initial (%):
—1
Cal (%):
0 '/'
mmHg: i
� S s , I
Temperature (°C):
1 C
Time:
)l SCI
DO (Site #2,
if a llwble)"
Initial (%):
Cal (%):
mmHg:
Temperature CQ:
Time:
QC** Check: DO
Time:
Result (%):
Time:
Result (%):
Time:
Result (%):
PH 7 S.U.
report to0.1S.U.
Initi I:
pHmV:
Z%e
Cal S.U.):
0�
pHmV:
Time:
-t
I &V
(b l-
(cS�ZZ
PH4S.U.
report to 0.1 S.U.
Initial:
3 .�
pHmV:
l �
Cal (S.U.):
pHmV:
Time:
� S1094=
[GK�D[�
oGi7,
IQ"
1 Z
PH 10 S.U.
report to 0.1 S.U.
Initial:
Of -Q
pHmV: r �y C
, 1 tp-1 • J
Cal (S.U.):
•t�
pHmV:
—
Tim
t&T
QC** pH 7 S.U.
report to 0.1 S.U.
Time:
i
CK0 Lf 7
Result (S.U.):
Result
r - �
Time:
�
Result (S.U.):
• 0}
Time:
I, Q S
Result (S.U.):
�
� &rA
- has
e1
Ca LZ
Spec Cond.
1,000 Nmhos/cm
Initial:
I OV—z'
Cal (Nmhos/cm):
L M
Time:
(pZ f5
2 6% `-t.
Co Li s
05/2,3
% Recovery=
QC** Spec. Cond.
1,000 pmhos/cm
Time:
(Qb
0 1
Result(pmhos� J s//cm):
b
Time: 1
a" 1
Result (Nmhos/cm):
- t
Time:
Result (pmhos/cm):
ZG,S
% Recovery=
06 [yA
ORP 200 mV
Initial:
J a
Cal:
200
Temperature CC):
l `i. (o
Time:
LAI--
(,[ l
Analyst Signature:
Analyst Name: eSSI co-
Date: QSi10��Z
Notes: Q 1
Revision 8, 1/11/22, CAP
1. Instruments shall be calibrated in accordance with the manufacturer's operation manual.
2. Specific Conductivity should be calibrated according to values representative of historic range.
3. Order of Calibration is as follows: Specific Conductivity, pH 7, pH 4, pH 10, DO, ORP, QC checks.
4. `When performing DO analyses at multiple sample sites (.e. project/facility locations), the DO probe must be calibrated at each sample site prior to analysis.
S. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the instrument needs to be recalibrated.
6. •' QC check must be performed prior to sampling and following completion of sampling, at a minimum. QC checks must be performed with calibration standard from a separate lot # as the initial QC.
7. % Recovery = (Value Obtained, pmhos/cm + True Value, pmhos/cm) x 100
8. NC Field Laboratory Certificate Number 5445
9. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
10. Unless otherwise noted, all DO calibrations and measurements are performed at 0 ppt Salinity.
11. 1 pm ho/cm = 1 pS/cm
Abbreviations: Method Reference:
pmhos/cm: micromhos per centimeter NTU: nephelometric turbidity units Temperature: SM 2550 B-2010
°C: degrees Celsius ORP: oxidation reduction potential Speck conductivity, EPA Method 120.1, Rev. 1982
DO: dissolved oxygen s/n: serial number DO: SM 4500 O G-2011
mg/L: milligrams per liter S.U.: standard units pH: SM 4500-H• B-2011
mV: millivolt Spec. Cond.: Specific Conductivity Turbidity: SM 2130 B-2011
Page 1 of 1

ANCHOR
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Equipment Documentation and Instrument Calibration Data Sheet
Project Name: LiASSot� �o_- PQopo,5 Analyst Conducting Calibration: ',S xv"16�
Project Number: 924&00 03.Q1+ C 314 57. .. 61 . 01 . Date of Calibration: 0 5(c>LA i; 23
Project Location: I AIE— ocki rLV41-Q 1 6M �7r� Date of Field Measurements: Os I ott 1�
Facility ID or Permit # (if applicable): r8-97* W W 00 1�y 7tq_f
EQUIPMENT DOCUMENTATION
Rental sample analysis equipment or meters used to take measurements:
EquipmentType Brand Serial Number Date of Use Rental Com a
Select Turbidimeter.®
Hach 2100Q (s/n 151006045207)
Rental Hach 21000 (s/n
Instrument Readings
(Hach 2100Q)
Cal Std Information
10 NTU
20 NTU
100 NTU
800 NTU
Lot#:
IATI'A%
IA2-115
Ili
Altl(D
Expiration Date:
'3,5
015111-6ot
(Z.
Cal (NTU): LCIII, Q
Cal (NTU): f OO
Cal (NTU): aQ Z
Time: tOw
Time: 1004
Time: to
Calibration *Pre
Verification- Check
-Analysis
(10 NTU):
Result (NTU):
LO I
Time: �UO
*Post
Check
-Analysis
(10 NTU):
Result Q(NTU):
1 . S
Time:
1 2;
YSI Professional Plus Multiparameter Meter (s/n 1094040M
Instrument Readings
Cal Std Information
Lot #
Date
Opened
Ex _ Date
P
Dissolved Oxygen Initial
(% saturation)
(%):
"I'll •
Cal (%):
(t) 0
mmHg:
1
1 (D Z• . 5j
Temperature CQ:
L'J.
Time:
to 1 Z
DO (Site #2, Initial
if applicable)*
(%):
Cal (%): o
0
mmH
.2'G
Temperature (°C):
Z-H • .L
Time: _
27}
QC** Check: DO Time:
G'
D��Q
Result t� 0
Time:
Result (%):
Time:
Result (%):
PH 7 S.U. Initial:
report to 0.1 S.U.
• -I ►
pHmV:
� •�
Cal (S.U.): t
�'D {
pHmV: r
� - (o
Time:: F, Q
v 1 �
IMP
10112.
^1
C*1 ,3
pH 4 S.U. Initial:
reportt. a i s.U.
.C3YC
pHmV:
as
Cal (S.U.):
-06
pHmV:
"aQt
Time: �j
OR49
( at K.
05123
III LI
PH 10 S.U. Initial:
reportto0.1S.U.
pHmV:
-IS1-.S
Cal (S.U.):
Ci�OI
pHmV: Q
��5-1•
Time: Q
0 `5J
( (hZ
co23
QC** pH 7 S.U. Time:
report to a i S.U.
LQ
Result (S.U.):
Time:
�O
Result (S.U.):
Time:
RGq
D
Spec. Cord. Initial:
1,000 mhos/cm
Q`S
Cal (pmhos/cm):
11,0 00
Time:
octq3
?-Cft4
r?
23
% Recove =
QC** Spec. Cond. Time:
1,000 mhos/cm
r _
O q 5(0
Result (pmhos/cm):
lI-CQ
Time:
H 25
Result (Nmhos/cm):
cc 004
Time:
Result (pmhos/cm):
nQ
G of J
1190
05123
10(23
Recovery=
Initial:
ORP 200 mV
2c�2 2
Cal:
2rV0
Temp rature (°C):
�
Time::. a
U L 5
'1
u7123
09123
[Analyst Signature:
Analyst Name: 7ebs; c
Date: S��`� 123
Notes: �} V f 1
Revision 8, 1/11/22, CAP Y
1. Instruments shall be calibrated in accordance with the manufacturer's operation manual.
2. Specific Conductivity should be calibrated according to values representative of historic range.
3. Order of Calibration is as follows: Specific Conductivity, pH 7, PH 4, pH 10, DO, ORP, QC checks.
4. *When performing DO analyses at multiple sample sites (.e. projecVfacility locations), the DO probe must be calibrated at each sample site prior to analysis-
5 - CC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the instrument needs to be recalibrated.
6. " QC check must be performed prior to sampling and following completion of sampling, at a minimum. QC checks must be performed with calibration standard from a separate lot # as the initial QC.
7. % Recovery = (Value Obtained, pmhos/cm + True Value, pmhos/cm) x 100
8. NC Field Laboratory Certificate Number 5445
9. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
10. Unless otherwise noted, all DO calibrations and measurements are performed at 0 ppt Salinity.
11. 1 Pm ho/cm = 1 PS/cm
Abbreviations: Method Reference:
pmhos/cm: micromhos per centimeter NTU: nephelometric turbidity units Temperature: SM 2550 B-2010
IC: degrees Celsius ORP: oxidation reduction potential Specific conductivity. EPA Method 120.1, Rev. 1982
DO: dissolved oxygen s/n: serial number DO: SM 4500 O G-2011
mg/L• milligrams per liter S.U.: standard units pH: SM 4500-H' B-2011
mV: millivolt Spec. Cond.: Specific Conductivity Turbidity. SM 2130 B-2011
Page 1 of 1

ANCHOR
Daily Safety Briefing Form .�► QEA ` '
Date: 015/a5i �Z3
Project No: C314'en cat . of
Project Name:
Person Conducting Health & Safety Project
Meeting: T. (Y'1tx.c,�e.� S- Officer: -T- S a yu,,,r Manager
,-
g
TOPICS COVERED:
K Emergency Procedures and
64 Lines of Authority
Evacuation Route
l!R Directions to Hospital
E� Communication
(E� HASP Review and Location
K Site Security
L Safety Equipment Location
EL Vessel Safety Protocols
Proper Safety Equipment Use
K Work Zones
Employee Right -to -Know/
ER Vehicle Safety and Driving/
SDS Location
Road Conditions
Fire Extinguisher Location
5� Equipment Safety and Operation
Eye Wash Station Location
IJ Proper Use of PPE
iq Buddy System
14 Decontamination Procedures
Self and Coworker Monitoring
10 Near Miss Reporting Procedures
11 Field Team Medical Conditions for Emergency Purposes (Confidential):
❑ Other:
Weather Conditions: L Q -- 56 S y� aAt ,
Daily Work Scope:
` sL. vflk-e-� at,�
Site -specific Hazards: Si,t. �l,IIS
dyAm'A' 1-); oiog; (al 4S
Safety Comments:
1 of 1
d Lifting Techniques
IR Slips, Trips, and Falls
M Hazard Exposure Routes
54 Heat and Cold Stress
IQ Overhead and Underfoot Hazards
K Chemical Hazards
K Flammable Hazards
�1 Biological Hazards
Eating/Drinking/Smoking
RZ Reviewed Prior Lessons Learned
Printed Name
Attendees
O Q O
PLAYING IT SAFE

ANCHOR
QEA 4-4-AL-0
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Low -Flow Sampling Log
Well ID: 'n\W
ProjectName:��n&g Pcw�k&S WQ Date: 0 3�23
Project Number. Weather. '2" urn
Project Location: Cam. n �� Facility ID or Permit # (if applicable): C1.
Sample Collector(s): y 1 Sample ID (on COQ:
Well Diameter. °Z in Arrive at Well: 0 = Q
Screen Interval: >l S ft bgs Start Time: C) 2
Well Depth (as constructed): ft bgs Sample Time:
Depth to Water. e } ft Leave Well:
Measuring Point: TO c Well Type: Stick Up ❑Flush Mount
Depth of Pump Intake: V_Z1 ft Tagged Bottom: Zy ft at (time): (Q
Pump Used (circle): eristaltic Bladder Other (describe): Purge Rate: SO.n L i v1\iv\
Comments: �r� y� �A a� l {0 10 ; DV 1 Q (� ` Total Volume Purged:
i 0 Ll- Pump Speed: 3 3. 5 f m
Time
DTW (feet)
Temperature VQ
Dissolved Oxygen
(mg/L)
Specific
Conductivity
(pmhos/cm)
pH (S.U.)
report to 0.1 S.U.
Oxidation
Reduction
Potential (mV)
Turbidity (NTU)
0 23
2
1. '9
2CO• 9
S • :+ t
2 ; ...}
Z 5
i 0 2
I
'1 15
ici
216 ,
t
t32.�
v
.1 t.4
5.G5
2101.
ii.p
icy' 2.
.9
l
I`f
3
2Zc�.
SFJ
j3 .qq
13 19
1, O f
lqq.1
15.60
2t f
l 0
3.q
H-0
O 0
ZO1
5,5
ZZ
1'} •2Z
Zc2.2
C5.t00
2f9 'Z
�.
Sample Analyst Signature:
Sample Analyst
Name: Q�Si C -
Date: Z.
43i a
Notes:
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity,, +/- 3% Conductivity,' +/- 0.1 pH unit +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017'
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff member's initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445
.
5.1 pmho/cm = 1 pS/cm
Abbreviations:
Method Reference:
°C: degrees Celsius S.U.: standard units
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter ft: feet
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter in: inches
DO: SM 4500 O G-2016
mv: millivolt bgs: below ground surface
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units TOC: top of casing
Turbidity: SM 2130 B-2011
Page 1 of 1

ANCHOR
�A QEA t
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 281101
Low -Flow Sampling Log
well ID: 5
Project Name: S o (� � �
¢S Uhl
r(�(ipylt pn/L9L Date: rj 1034 -_ 3
Project Number..L_aA4 _ C:r(_1 A
�T Weather. I
Project Location: f�L'hC4Q+-�nnv i t.Lp
(Mc
, VtYI i.E:
Facility ID or Permit # (if applicable): 4-
Sample Collector(s)i7TJhM
_ _ Sample ID (on COC): — -27Z O C)
Well Diameter. °Z
in Arrive at Well: �4
Screen Interval: C —
ft bgs Start Time: -S
Well Depth (as constructed): I q
ft bgs Sample Time: 153S
Depth to Water._ S
ft Leave Well:
Measuring Point: 'nx
Well Type: kttick Up ❑Flush Mount
Depth of Pump Intake: j S
ft Tagged Bottom: IU , S 9 ft at (time): I
Pump Used (circle): Peristalti
Bladder
Other (describe):_ Purge Rate:T
Comments:u.�
f�3 `Z
�Lf� Total Volume Purged:l
I _S1>
Pump Speed: l'
Dissolved Oxygen
Conductivity
pH (S.U.)
Reduction
Time DTW (feet)
Temperature (°C)
(mg/L)
(Nmhos/cm) report to 0.1 S.U.
Potential (m1)
)S 3
S
0.SC-�
9 P,.-4
S.`3
3.o
L4
5 _"3 3
22�1. w
s 3
is
9AD
y
0 . -Q
S• 3 �
-zs-
2'2c�-
S
13.2
O.y
2 ,
Sample Analyst
Sample Analyst Signature:
- -
Name:
--r-
�1eSS1 co,' {YkL;. ,yam
Date:
Notes:
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity,- +/- 3% Conductivity,- +/-
0.7 pH unit• +/- 70 mV (or ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017;
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff member's initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445
5.1 pmho/cm = 1 pS/cm
Abbreviations:
Method Reference:
°C: degrees Celsius S.U.: standard units
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter ft: feet
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L milligrams per liter in: inches
DO: SM 4500 O G-2016
mv: millivolt bgs: below ground surface
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units TOO top of casing
Turbidity: SM 2130 B-2011
(NTU)
Page 1 of 1

ANCHOR
QEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Low -Flow Sampling Log
well ID:
"
Project Name: 11A SOY1[Q� 1(� LS �C� (� [YIr�C�� Dt12gL Date: C) 51,3 j
Project Number. Weather. i
Project Location: 1 y�� 1� ,�G Facility ID or Permit # (if applicable): W Q
Sample Collector(s): Sample ID (on COC): ^ Z G 50
Well Diameter. 2 in Arrive at Well: Z1-4
Screen Interval: 10 ft bgs Start Time: 12-15—el
Well Depth (as constructed): 0 ft bgs Sample Time: + p
Depth to Water: ft Leave Well: 1 3
Measuring Point: MceWell Type: 'bStick Up oFlush Mount
Depth of Pump Intake: ft Tagged Bottom: 11,44ft at (time):
Pump Used (circle): Peristaltic Bladder Other (describe): Purge Rate:
Comments: u� t �j j� �L (� e z� Total Volume Purged:
Pump Speed:'j—>�
L
i 5 °n,L yyl
Time
DTW (feet)
Temperature (°C)
Dissolved Oxygen
(mg/L)
Specific
Conductivity
(pmhos/cm)
pH (S.U.)
report to 0.1 S.U.
Oxidation
Reduction
Potential (m%o
Turbidity (NTU)
3U2.
0,0G
14
L :.T5
OLE
t2 O5
(016
Jq
G
� .Z
�-Z0
2` i.'�
Z
a
(o-O
i .
Z2
25Z>
4>
09
i
55•22-
2_42,2
�o
�3
4 S
O.GZ
i �i
5.Z3
Z3 n9
0.81
Sample Analyst Signature:
Sample Analyst
Name:
SS t� [
Date:
Notes: I
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity, +/- 3% Conductivity, +/- 0.7 pH unit +/- 10 mV_ for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017:
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff member's initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445
5.1 pmho/cm = 1 pS/cm
Abbreviations:
Method Reference:
°C: degrees Celsius S.U.: standard units
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter ft: feet
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter in: inches
DO: SM 4500 O G-2016
mV: millivolt bgs: below ground surface
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units TOC: top of casing
Turbidity. SM 2130 B-2011
Page 1 of 1

A-4ANCHOR
i+t"tl Q
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Low -Flow Sampling Log
Well ID,
1
Project Name: l a�SGrYl2_ ^,% � f% (Ylnr�
Project Number. , -
Project Location: p, ) `.e r 'KL.
Sample Collector(s):
Well Diameter.
Screen Interval:
Well Depth (as constructed):
2-Depth to Water. , s •
Measuring Point: 3
Depth of Pump Intake: 5
Pump Used (circle): eristalti > Bladder
Comments:_ p Dri )4 D L
Ci�v tl�. Date: 0 103 1­2_3
—F Weather. I ° v n
Facility ID or Permit # (if applicable):
Sample ID (on CCIQ (mow — 2 — ZZ 65 03
in Arrive at Well: 1'
ft bgs Start Time: N 0 4
ft bgs Sample Time: 2-
ft Leave Well: k^I.4
Well Type: gtick Up ❑Flush Mount
ft Tagged Bottom: �., ft at (time): 3 S (y
?ther (describe): Purge Rate: 115m Ll rvt'ol
Vff-1 7>'J Total Volume Purged:
Pump Speed:
Time.
DTW (feet)
Temperature(*Q
Dissolved Oxygen
(mg/L)
Specific
Conductivity
(Nmhos/cm)
pH (S.U.)
report to 0.1 S.U.
Oxidation
Reduction
Potential (mV)
Turbidity (NTU)
b .5
20
2:
5
2
2-5---
Li�.
io s-Ir
►
z-3S
12-2-
ySO I
I
iZ
Z
.3
u
J Ll,
5.0
5:i
�Ceo
b2-0
-+
3
ZO
Z'S 9
_
Sample Analyst Signature:
Sample Analyst
Name:
SSA Cc,
Date-
•�SlcS3['l3
Notes:
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity; +/- 3% Conductivity, +/- 0.1 pH unit,, +/- 70 ml/for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017:
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff member's initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445
5.1 pmho/cm = 1 p5/cm
Abbreviations:
°C: degrees Celsius S.U.: standard units
pmhos/cm:micromhos per centimeter ft: feet
mg/L: milligrams per liter in: inches
mv: millivolt bgs: below ground surface
NTU: nephelometric turbidity units TOC: top of casing
Method Reference:
Temperature: SM 2550 B-2010
Specific conductivity: EPA Method 120.1, Rev. 1982
DO: SM 4500 O G-2016
PH: SM 4500-H` B-2011
Turbidity: SM 2130 B-2011
Page 1 of 1

ANCHOR
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Low -Flow Sampling Log
Well ID:
Project Name:1ASSOYXC.Q_, �acti?6?tS WCi'?
Project Number: '
C3t�it�2- c� i- of
�eM ibWnL4:,nY,
—�-
>a-" Date: �JiO f` -
weather. 9 .9
Project Location:��
�, �c�
Facility ID or Permit # (if applicable): K =}q,
Sample Collector(s):
jrYl
Sample ID (on COC): b
Well Diameter.
in
Arrive at Well: O
Screen Interval:
— �'�
ft bgs
Start Time:
Well Depth (as constructed):
ft bgs
Sample Time:;
Depth to Water.
ft
Leave Well:
Measuring Point:
Depth of Pump Intake:
I'Z
ft
Well Type;c,4Stick Up ❑Flush Mount
Tagged Bottom: i � 9 9 ftat (time): (j y
Pump Used (circle): eristaltic Bladder
Comments: k '• 07
Other (describe):
/offTotal
Purge Rate: I Jr© mL li in %
Volume Purged:
Pump Speed: _64
Specific
Oxidation
Dissolved Oxygen
Conductivity
pH (S.U.)
Reduction
Time
(*feeet)
Temperature (°C)
(mg/L)
(Nmhos/cm)
report to 0.1 S.U.
Potential (mV)
Turbidity (NTU)
09
/ �DTW
"T Gr
yS
9�'
f-..©
p.q
k
Z- i
3-
Sir
S1
2 0
2 `I `t
5
Li 9
O CI IJ
4q
I� . o
a.
4
s
2
4-10,
CA•49
i ,3
Li3.
Sample Analyst
Sample Analyst Signature:
Name: �e � Cc�_ Date: CS I03l l
Notes: W
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity +/- 3% Conductivity, +/- 0.1 pH uni; +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017;
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff member's initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445
5. 1 pmho/cm = 1 pS/cm
Abbreviations:
Method Reference:
°C: degrees Celsius S.U.: standard units
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter ft: feet
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter in: inches
DO: SM 4500 O G-2016
mv: millivolt bgs: below ground surface
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units TOC: top of casing
Turbidity: SM 2130 B-2011
Page 1 of 1

ANCHOR
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Low -Flow Sampling Log
lWell ID: (Y)
— q
Project Name: �S �,p p �`rC�� � 0 Date: s%b 02
Project Number. Weather. rJ " wl f 2� e
Project Location: � �� ; ��r �� Facility ID or Permit # (if applicable): ]I�1 IS (Tjm Cn
Sample Collector(s)r-fTlf� M Sample ID (on COC): 9-T
Well Diameter. in Arrive at Well:
Screen Interval: ft bgs Start Time:
Well Depth (as constructed): ft bgs Sample Time: Z -
Depth to Water. S Q2 ft Leave Well: 4 Z 3
Measuring Point: T[]G Well Type: ,Stick Up ❑Flush Mount
Depth of Pump Intake: 1'L ft Tagged Bottom: DCZ at (time): t
Pump Used (circle): Peristaltic Bladder Other (describe): Purge Rate:
Comments: MOP E> .•' Total Volume Purged:
PumpSpeed:
Time
DTW (feet)
Temperature (°C)
Dissolved Oxygen
(mg/L)
Specific
Conductivity
(pmhos/cm)
pH (S.U.)
report to 0.1 S.U.
Oxidation
Reduction
Potential (mV)
Turbidity (NTU)
'A
3 S
'-t 1
L i s -1
5.2
23T 5
`; . 2
it 2
,(-h5
1` -1
0=�0
145 3
5
2-4[.
1 �
55
4
14•0
0 -5
5 i
I Ii
� �.3
S®
5.SI
l
0
H4
S Ge)
3
3S Z-
� 01
52
D-
1
5 it
3 .3
51r
Sample Analyst Signature:
_ _
Sample Analyst
Name: e�`7iCr�
Date: t—cZ 1
Notes:
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity,' +/- 3%Conductivity, +/- 0.1 pH unit,' +/- 70 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017;
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff member's initials and date
3. Samples are analyzed immediately upon collection.
4._NC Field Laboratory Certificate Number 5445
S. 1 pmho/cm = 1 pS/cm
Abbreviations:
Method Reference:
'C: degrees Celsius S.U.: standard units
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter ft: feet
Specific conductivity: EPA Method 120.1, Rev.1982
mg/L: milligrams per liter in: inches
DO: SM 4500 O G-2016
mV: millivolt bgs: below ground surface
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units TOC: top of casing
Turbidity: SM 2130 B-2011
Page 1 of 1

ANCHOR
QEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Surface Water Sampling Log
Location ID:
Project Name:
Lay5o�-BLS
�Q
monk;
Date:
5 Jp� Z
Project Number:
(► _fit
Weather:
Project Location:
i ii� ��
Facility ID or Permit # (if applicable):.
Sample Collector(s):
Sample ID (on COC):
S i - 2c�23oS
Comments:
Sample Method (circle
one)
Grab
Syringe
Pump
Bailer-Disp.
Other:
Specific
Oxidation
Temperature
Dissolved
Conductivity
pH (S.U.)
Reduction
Turbidity
Time
VC)
Oxygen (mg/L)
(Nmhos/cm)
report to 0.1 S.U.
Potential (mV)
(NTU)
Comments
12►-
�� 3
�D
3
�r5
S2
Sampling Container
Number of Containers
Requested Analysis
500 mL Plastic
250 mL Plastic
125 mL Plastic
40 mL Glass
1 L Glass
Other
Vegetation: C.� � yQ Access: k20-L71'
Sample Analyst
Sample Analyst Signature: Name: Date: D5(Ly4I�ZA)
Notes:
1. Documentation errors are to be crossed out with a sinale line, so the oriainal text is still leaible, followed by the staff members initials and date
2. Sample's are analyzed immediately upon collection.
3. NC Field Laboratory Certificate Number 5445
Abbreviations:
Method Reference:
°C: degrees Celsius
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter
DO: SM 4500 O G-2011
mv: millivolt
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units
Turbidity: SM 2130 B-2011
S.U.: standard units
Page 1 of 1

ANCHOR
QEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Surface Water Sampling Log
location ID: 5 w — 2
Project Name:
ll �
S Uri@ iYidn��Onna
Date: bj/bq
Project Number:
dl
3
Weather: S 5P w
Project Location:
YIdlPX56r<yil(e
Facility ID or Permit
# (if applicable): ( (�0
Sample Collector(s):
ti-�
Sample ID (on COC):
Comments:
Sample Method (circle
one):
Grab
Syringe
Pump
Bailer Disp. Other:
Specific
Oxidation
Temperature
Dissolved
Conductivity
pH (S.U.)
Reduction
Turbidity
Time
VQ
Oxygen (mg/L)
(Nmhos/cm)
report to 0.1 S.U.
Potential (mV)
(NTU)
Comments
.2 .1
(,( 5.q
Co ,lL>3
° 1
g,L+;
Sampling Container
Number of Containers
Requested Analysis
500 mL Plastic
250 mL Plastic
125 mL Plastic
40 mL Glass
1 L Glass
Other
Vegetation: Wfj Access: ir'�'�
Sample Analyst
Sample Analyst Signature: Name: e &,z>( [-- Date:
Notes:
1. Documentation errors are to be crossed out with a sinole line, so the original text is still legible. followed by the staff members initials and date
2. Samples are analyzed immediately upon collection.
3. NC Field Laboratory Certificate Number 5445
Abbreviations:
Method Reference:
°C: degrees Celsius
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter
DO: SM 4500 O G-2011
mV: millivolt
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units
Turbidity: SM 2130 B-2011
S.U.: standard units
Page 1 of 1

Attachment 4
DEQ GW-59A Compliance Report Form

;�,�'-.'it);� i';'r:'�i9'%•i. iF.. f??',� ? i(;' !'�:`iilll! WQ0004797
',`;�il�ririr :ut�'rtr��lt ra��i!ilu• i;i,1 f�:,•ir,;i is•.rrh G)1-:�9-lur'i1t1.1
1
Enter date monitoring results were due. ( 06/30/2023 ) Will this monitoring report (GW-59 and GW-59A)
YES
NO
be submitted after the established due date?
YES
X
NO
2
Nas any required information missing on the GW-59 report forms?
x
IF the answer to question 9 or 2 is "YES", list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
YES
NO
identification plate, area overgrown, etc.)? If the answer is 'Yes'•. cowoci the Regional Officefor guidcnrce.
X
4
Are any monitored constituents equal to or above the established standards?
T
1i
NO
If the answer to question 4 is "NO'; skip to section 8.
If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentrations)
exceeding standards in the space provided below:
Nitrate (2L = 10mg/L): MW-7R2O 18.4 mg/L
Fecal coliform (2L = 1 CFU/100 mL): MW-69 15.0 CFU/100 mL
For the constituents identified in question 4 above, have standards been exceeded previously for the
YES
NO
same constituent(s) in the same well(s) in the last two years?
X
If the answer to question 5 is "NO", skip to section 8.
if the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding
standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years).
Fecal Coliform Nitrate
MW-6 (CFU/100mL) MW-7R (mg/L)
05/11/21: 5.0 05/11/21: 40.4
10/28/21: ND 10/27/21: 26.0
05/10/22: ND 05/10/22: 31.0
11/08/22: -164.0 RESAMPLE 12/05/22: 12.0 11/08/22: 24.2
• ossible lab error
6
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
YES
_
NO
X
If the answer is "YES", a groundwater quality problem maybe occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells maybe improperly
located; contact the Regional Office.
7
Is the permittee implementing previously approved actions required by the Division involving this
YES
NO
groundwater quality problem?
X
if the answer to question 7 is "YES" describe those actions in the space provided below.
if the answer to question 7 is "NO", contact fhe Regional Office within 90 days, an evaluaffon ►na .lie
required to determine the impact the waste_ disposal system is having at the review and compfiarrce
boundaries surrounq ng this facllity. Failure to do so may sub►ect the nen"itMe to a Notice of Vioration,
fines, andlor penalties.
Monitoring well MW-7R was replaced by MW-7R2 prior to the Spring 2023 monitoring event due to root penetration of the well screen and
concerns regarding impacts to water quality measurements
g
The person completing this portion (G W-59A) of the monitoring report should sign below and submit this
form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form.
I hereby a n❑ iledge that the above information was evaluated and the information submitted in this
report ( m I tic . port GW-59A) is true and complete to the best of my knowledge,
u I ZZ 23
Signature rPe ittee (or Authorized Agent) Date
�
._1
G \ -59 1 1 _1,18111103

Attachment 5
DEQ GW-59 Groundwater Quality
Monitoring: Compliance Report Forms

SUBMIT FORM ON YELLOW PAPER ONLY
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617
FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2026
Facility Name: Clement Pappas Non -Discharge W00004797 UIC
Permit Name (if different): NPDES Other
Facility Address: 485 Brookside Camp Road TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC 28792 County Henderson ❑ Lagoon ❑ Remediation: Infiltration Gallery
N Spray Field ❑ Remediation
Contact Person: James Frazier Telephone#: [phone] ❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area No. of wells to be sampled' 6 ❑ Water Source Heat Pump ❑ Other:
{tram Permit}
_ ..__...._ ..._�...._, .. If WELL
WELL ID NUMBER (from Permit): MW-4
Well Depth: 18.24 ft.
Depth to Water Level 82546: 8.79 ft below measuring point
Measuring Point is 2.43 ft. above land surface
Volume of water pumped/bailed before sampling: 0.83
Samples for metals were collected unfiltered: X YES ❑
Date sample collected: 5/3/2023
Well Diameter: 2 in.
Screened Interval: 5 ft. to 15 ft.
Relative M P. Elevation: 2063.77 ft.
gallons
NO and field acidified: .0 YES
late sample analyzed: 5/3/2023 Laboratory Name: Pace Analytical Services
ARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L Nitrite (NO,) as N 00615 mg/L
Coliform: MF Fecal 31616 <1.0 /100mL Nitrate (NO3) as N 00620 0.660 mg/L
Coliform: MF Total 31504
(Note Use MPN method for highly turbid samples)
_/100mL
ved Solids:Total 70300.126
mg/L
pH (Lab) 00403
units
TOC 0068o 33
mg/L
Chloride 00940 103
mg/L
Arsenic 01002
ug/L
Grease and Oils 00552
mg/L
Phenol 32730
ug/L
Sulfate 00945
mg/L
fic Conductance 00095
µMhos
Total Ammonia 00610 <0 10
mg/L
(Ammonia Nitrogen. NH, as N, Ammonia Nitrogen, Total)
TKN as N 00625
mg/L
Phosphorus: Total as P 00665 <0.050
mg/L
Orthophosphate 70507
mg/L
Al - Aluminum 01105
mg/L
Ba - Barium 01007
ug/L
Ca - Calcium 00916
mg/L
Cd - Cadmium 01027
ug/L
Chromium: Total 01034
ug/L
Cu - Copper 01042
mg/L
Fe - Iron 01045
ug/L
Hg - Mercury 71900
ug/L
K - Potassium 00937
mg/L
Mg - Magnesium 00927
mg/L
Mn - Manganese 01055
ug/L
Ni - Nickel 01067
ug/L
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs:
James Frazier. Plant Manager
Permittee (or AU60rtZ6d Agent) Name and Tdle - Please print ortype
GW-59 Rev 06-07-2018
FIELD ANALYSES:
pH 00400: 5.6 units
Spec. Cond. 00094: 202.
Odor 000a5: none
AnnParance
Temp 00010: 14.0 aC
2 )tMhos
Certification No. 37712
Pb - Lead o1o51 ug/L
Zn - Zinc 01092 mg/L
Other (Specify Compounds and Concentration Units):
ORGANICS: (by GC, GC/MS, HPLC)
(Specify test and method #. ATTACH LAB REPORT.)
Lab Report Attached? 0 Yes (1) ❑ No (0)
method #
method #
method #
mg/L Effluent Total VOCs:
(or Authorized Agenll
, method #
mg/L VOC Removal%
L3
DRY at
time of
sampling,
check
here: El

JUblvlll rVKIVI VIV 7tLLV VV r'HF'CK VIVLY
DEPARTMENT OF ENV IRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617
FACILITY INFORMATION
Plea soPrfptCTear7yorType
PERMIT Number: Expiration Date: 7/31/2026
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC
28792
County Henderson
❑ Lagoon ❑ Remediation: Infiltration Gallery
A Spray Field ❑ Remediation:
Contact Person: James Frazier
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
[fmm Aarmip
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-5
Date sample collected: 5/3/2023
FIELD ANALYSES:
WAS
Well Depth: 18 59 ft
Well Diameter: 2 in
pH 0040o: 5.3 units Temp. 000lo: 13.2 °C
DRY at
Depth to Water Level 82546: 8.85 ft. below measuring point Screened Interval: 9 ft
to 19 ft.
Spec. Cond 00094: 49.3 tlMhos
time of
sampling,
Measuring Point is 3.00 ft. above land surface
Relative M P. Elevation: 2085 60
ft,
Odor 00065 none
check
Volume of water pumped/bailed before sampling:
0.89
gallons
Appearance
here
Samples for metals were collected unfiltered: OYES
❑ NO and field acidified: 0 YES
❑ NO
LABORATORY INFORMATION
Date sample analyzed: 5/3/2023
Laboratory Name: Pace Analytical Services
Certification No 37712
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO,) as N 00615
mg/L
Pb - Lead olo51 ug/L
Coliform: MF Fecal 31616 <1,0
/100mL
Nitrate (NO3) as N 00620 0,049
mg/L
Zn -Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665 0.075
mg/L
(Note Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L
Other (Specify Compounds and Concentration Units):
1ssolved Solids:Total 7030o 750
mg/L
AI - Aluminum oilos
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC 00680 6.3
mg/L
Ca - Calcium oo916
mg/L
Chloride 0094o 4.2
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L
ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? ® Yes (1) ❑ No (0)
pecific Conductance 00095
µMhos
K - Potassium 00937
mg/L
method #
Total Ammonia 00610 <0.10
mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen, NH, as N, Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
, method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L vuL; Her l /o
James Frazier, Plant Manager
Permittee (or Authorized Agent) Name and Title - Please print or type
GW-59 Rev 06-07-2018
of
(or.AuthQrized Agent)
N

SUBMIT FORM ON YELLOW PAPER ONLY
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
+
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date: 7/31/2026
Facility Name: Clement Pappas
Non -Discharge VVQ0004797 UIC
NPDES Other
Permit Name (if different):
Facility Address: 485 Brookside Camp Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC
28792 County Henderson
❑ Lagoon ❑ Remediation: Infiltration Gallery
N Spray Field ❑ Remediation:
Contact Person: James Frazier
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
fRc_n Pzmin
SAMPLING INFORMATION
It WELL
WELL ID NUMBER (from Permit): MW-6
Date sample collected: 5/3/2023
FIELD ANALYSES:
WAS
Well Depth: 11.59 ft.
Well Diameter: 2 in.
pH 00400: 5.2 units Temp. 000lo: 14.5 °C
DRY at
time of
Depth to Water Level 82546: 5.74 ft. below measuring point Screened Interval: 5 ft.
to 10
ft. Spec. Cond. 00094: 138.1 µMhos
sampling.
Measuring Point is 3.00 ft. above land surface
Relative M.P. Elevation: 2061.17
ft
Odor 00085: none
check
Volume of water pumped/bailed before sampling:
1.19
gallons
Appearance
here:
Samples for metals were collected unfiltered: 0 YES
❑ NO and field acidified: © YES
❑ NO
LABORATORY INFORMATION
Date sample analyzed 5/3/2023
Laboratory Name: Pace Analytical Services
Certification No 37712
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead o1o51 ug/L
Coliform: MF Fecal 31616 15_0
/100mL
Nitrate (NO3) as N 00620 0 15
mg/L
Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665 <0 050
mg/L
(Note: Use MPN method for highly turbid sunplesi
Orthophosphate 70507.
mg/L
Other (Specify Compounds and Concentration Units):
Dissolved Solids:Total 70300 86.0
mg/L
Al - Aluminum 01105
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC 00680 1.5
mg/L
Ca - Calcium 00916
mg/L
Chloride 0094o 8.8
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002_
ug1L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L
ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? '141 Yes (1) ❑ No (0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L method #
Total Ammonia 00610 <0.10
mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen. NH3 as N: AMrnDnte Nitrogen Total)
Mn - Manganese 01055
ug/L , method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
James Frazier. Plant Manager
Permittee (or Authorized Agent) Name and Title - Please print or type
(or Authorized Agent)
717
GW-59 Rev 06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617
FACILITY INFORMATION
Please Pnor C1Harfy or Type
PERMIT Number: Expiration Date: 7/31/2026
Facility Name: Clement Pappas
Non -Discharge W00004797 UIC
NPDES Other
Penmi" Name (if different):
Facility Address: 485 Brookside Camp Road
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
Hendersonville NC 28792 County Henderson
© Spray Field ❑ Remediation:
Contact Person: James Frazier
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
ixd Ferr iU
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-7R2
Date sample collected: 5/3/2023
FIELD ANALYSES:
WAS
Well Depth: 17 39 ft.
Well Diameter: 2 in.
pH 00400: 5.2 units Temp. 000lo: 14.8 °C
DRY at
Depth to Water Level e2546: 10-57 ft. below measuring point Screened Interval: 5 ft.
to 15
ft. Spec_ Cond. 00094: 337.1 (Mhos
time ofsampling,
Measuring Point is N/A ft. above land surface
Relative M.P. Elevation: 2062 86'
ft,
Odor 00085: none
check
Volume of water pumped/bailed before sampling:
0.83
gallons
Appearance 'Elevation assumed based on MW-7R
here:❑
Samples for metals were collected unfiltered: ❑■ YES
❑ NO and field acidified: ❑■ YES
❑ NO
LABORATORY INFORMATION
Date sample analyzed: 5/3/2023
Laboratory Name: Pace Analytical Services
Certification No- 37712
PARAMETERS NOTE. Values should reflect
dissolved and colloidal concentrations -
COD 00335
mg/L
Nitrite (NO,) as N o0615
mg/L Pb - Lead o1051 ug/L
Coliform: MF Fecal 31616 <1 0
/100mL
Nitrate (NO3) as N 00620 18.4
mg/L
Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665 <0.050
mg/L
(Note Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 703oo 232
mg/L
Al - Aluminum o11o5
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC 00680 1.8
mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 266
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug1L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? W Yes (1) ❑ No (0)
Specific Conductance 00095
ttMhos
K - Potassium 00937
mg/L
method #
Total Ammonia 00610 <0 10
mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen, NH, as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs. mg/L VOC Removal%
James Frazier, Plant Manager
Permittee (or Authorized Agent) Name and Title - Please print or type
(orAulhwned Agent)
GW-59 Rev 06-07-2018

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
C. ".1 1 ry 1McnnILA A Ttruu Ptease Print Clearly or
3cility Name: Clement Pappas
srmit Name (if different)
3cility Address: 485 Brookside Camp Road
endersonville NC
act Person: James Frazier
Location/Site Name: Irrigation Area
28792
WELL ID NUMBER (from Permit). MW-8
Well Depth: 13 99 ft.
Depth to Water Level 82546: 9 41 ft. below measuring point
Measuring Point is 300 ft. above land surface
Volume of water pumped/bailed before sampling: 0.48
Samples for metals were collected unfiltered: 10 YES ❑
SUBMIT FORM ON YELLOW PAPER ONLY
County Henderson
Telephone#: [phone]
No. of wells to be sampled: 6
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
INFORMATION PROCESSING UNIT
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617
PERMIT Number: Expiration Date: 7/31/2026
Non -Discharge W00004797 UIC
NPDES Other
TYPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
❑■ Spray Field ❑ Remediation
❑ Rotary Distributor ❑ Land Application of Sludge
❑ Water Source Heat Pump ❑ Other:
Date sample collected: 5/3/2023
Well Diameter: 2 in
Screened Interval: 3 ft to 13 ft,
Relative M P. Elevation: 2060.80 ft.
gallons
NO and field acidified: 0 YES ❑ NO
Date sample analyzed 5/3/2023 Laboratory Name: Pace Analytical Services
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO,) as N 00615
mg/L
Coliform: MF Fecal 31616 <1_0
/100mL
Nitrate (NO3) as N 00620 22
mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665 <0 050
mg/L
(Note Use MPN method for highly turbid
Orthophosphate 70507
mg/L
)Issolved Solids:Total 703oo 242
mg/L
Al -Aluminum 01105
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC 00680 4.9
mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 10.9
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L
Phenol 32730
ug/L
Fe - Iron 01045
ug/L
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L
Total Ammonia 00610 <0.10
mg/L
Mg - Magnesium 00927
mg/L
(Ammonia Nitrogen, NH, as R Ammonia r4itrugen Total)
Mn - Manganese 01055
ug/L
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L
For Remediation Systems Only (Attach Lab Reports)
Influent Total VOCs: mg/L
FIELD ANALYSES: WAJ
pH 00400: 6.6 units Temp. oo01o: 13.1 DRY at
tMhos time of
Spec. Cond. 00094: 410.3 } sampling,
Odor 00085: none check
Appearance here El
Certification No 37712
Pb - Lead o1o51 ug/L
Zn -Zinc 01092 mg/L
Other (Specify Compounds and Concentration Units):
ORGANICS: (by GC, GC/MS, HPLC)
(Specify test and method #. ATTACH LAB REPORT.)
Lab Report Attached? 0 Yes (1) ❑ No (0)
Effluent Total VOCs:
method #
method #
method #
method #
mq/L VOC Removal%
G W-59 Rev 06-07-2018

Sl IRMIT FORM ON YELLOW PAPER ONLY
0
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date: 7/31/2026
Facility Name: Clement Pappas
Nan -discharge W00004797 UIC
NPDES Other
Permit Name (if different):
Facility Address: 485 Brookside Camp Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC
28792 County Henderson
❑ Lagoon ❑ Remediation: Infiltration Gallery
0 Spray Field ❑ Remediation:
Contact Person: James Frazier
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No of wells to be sampled 6
❑ Water Source Heat Pump ❑ Other:
dram Permit]
SAMPLING INFORMATION
1` WELL
WELL ID NUMBER (from Permit): MW-9
Date sample collected: 5/3/2023
FIELD ANALYSES:
WAS
Well Depth: 18 06 ft,
Well Diameter: 2 in
pH 00400: 5.1 units Temp 000lo: 13.9 oC
DRY at
time of
Depth to Water Level 82546: 5_02 ft below measuring point Screened Interval: 6 ft
to 16
ft. Spec. Cond. 00094: 144.4 µMhos
sampling.
Measuring Point is 1.44 -ft. above land surface
Relative M P Elevation: 2060.23
ft
Odor 00085: none
check
Volume of water pumped/bailed before sampling:
0.55
gallons
Appearance
here:❑
Samples for metals were collected unfiltered: A YES
❑ NO and field acidified 0 YES
❑ NO
LABORATORY INFORMATION
Date sample analyzed: 5/3/2023
Laboratory Name: Pace Analytical Services
Certification No. 37712
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO,) as N 00615
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 <1.0
/100ml-
Nitrate (NO3) as N 00620 3.8
mg/L
Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100ml-
Phosphorus: Total as P 00665. 0.080
mg/L
(Note Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L
Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 830
mg/L
Al - Aluminum 01105
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC 0068o 4.7
mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 134
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
uglL
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? 411T. Yes (1) ❑ No (0)
pecffic Conductance 00095
µMhos
K - Potassium 00937
mg/L VOC 7873 method #
Total Ammonia 00610 <0.10
mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen, NH;as WAM MAONW606n.. Total)
Mn - Manganese 01055
ug/L , method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs
James Frazier, Plant Manager
Aermiltae (or Authorized Agent) Name and Title - Please print or type
mg/L Effluent Total VOCs:
(or
mg/L VOG Removal%
GW-59 Rev 06-07-2018