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HomeMy WebLinkAboutWQ0032016_Groundwater Monitoring Report November 2023_20231229GNN-59A C:'OXI PLIANCE REPORT FORM �'t s a��It � WCZaa32016 tSubmii five each pe€•ioel rviti€ [ill=iJ,iirrnrs.i __.,..,..,..._ j Enter date monitoring results were due, (7 31/2023 ) Wiil this monitoring report (GVV-59 and GW-59A) be submitted after the established due date? YES NO 2 Was any required information missing on the GW-59 report forms? IF the answer to question 1 or 2 is "YES'; list in the- space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. X T�S NO X j 3 Are auy of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing identification plate, area overgrown, etc.)? ifthe answer is "Yes", contucr the iiegior€cd Office for yrricic€»ca YES NO 4 Are any monitored constituents equal to or above the established standards? 11 the answer to question 4 is "1VU'; skip to section 8. If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentrations) exceeding standards in the space provided below,- YES NO 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO same constituent(s) in the same wells) in the last two years? If the answer to question 5 is "Np'; skip to section 8. If the answer to question 5 is "YES'; list in the space provided below, each well with constituent(s) exceeding standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years). MW-1: pH 6.14 MW-2: pH 5.24; Fe 0.303 MW-3: Fe 16.5 Mn 0,588 fitOFFICE the monitoring well listed in section 5 located at or beyond the review boundary? YE5 1140 he answer is "YES", a groundwater quality problem maybe occurring. CONTACT THE REGIONAL i'MMEDIATELY FOR GUIDANCE If the answer is "NO', monitoring wells may be improperlyated; contact the Regional Office. ! 7 I Js the permittee implementing previously approved actions required by the Division involving this YES No groundwater quality problem? if the answer to question 7 rs ''YES", describe Lhasa actions in the space If the answer to question T is "NO", contact the Regional OfFirp re m g The person completing this portion (GW-59A) of the monitoring report should sign below and submit this form with GW 59 forms for required wells to the address provided at the top of the current GW--59 form, l hereby acknowledge that the above information was evaluated and the information submitted in this report (Compliance Report GW-59Aj is. true and complete to the best of my knowledge. Signature €; W -59A 124i2003 (or Date SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM " " ' 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 FACILITY INFORMATION Please Print Cteariy or Type PERMIT Number: Expiration Date: 6130/2028 Facillty Name: Rase Hill Plantation Devefopment, LLC Non -Discharge UIC Permit Name (if different): NPDES Other W00032016 Facility Address: 3041 New Leicester Highway TYPE OF PERMITTED OPERATION BEING MONITORED Leicester NC 28748 County Buncombe ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑ Spray Field ❑ Remediation: Contact Person: Bob Barr Telephone#: (828) 251-1900 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Well # 1(MW A on GW-1 b) No. of wells to be sampled: 3 ❑ Water Source Heat Pump ❑1■ Other: Surface Irrigation tram a��ma} SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): Well # 1 Upyradient Date sample collected: 11/27/2023 FIELD ANALYSES: WAS Well Depth: 69 ft. Well Diameter: 2 in. pH 00400 6.14 units Temp. 00010: 11.9 °C DRY at Depth to Water Level 82546: 40.81 ft. below measuring p g paint Screened Interval: 49 ft. to 69 ft. Spec. Cond. o0o94: 43.8 µ Mhos time of sampling, Measuring Point is 2.5 ft. above land surface Relative M.P. Elevation: ft. Odor 00065: None check Volume of water pumped/bailed before sampling: gallons Appearance Clear here:❑ Samples for metals were collected unfiltered: EYES ❑ NO and field acidified: ❑■ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 1211212023 Laboratory Name: Pace Analytical Certification No. 40 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg[L Nitrite (NO2) as N OD615 <0.040 ni Pb -Lead o1o51 <5.0 ug/L Colifori MF Fecal 31s1s <1 /100mL Nitrate (NO3) as N 00620 <0.040 mg/L Zn - Zinc 01092 <10.0 ni Coliform: MF Total 31504 1100mL Phosphorus: Total as P 00665 0.072 ni (Note. Use MPN method for higNy turbid samples( Orthophosphate 70507 mgi Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 54.0 mglL Al -Aluminum at1c5 mg/L PH (Lab) 00403 units Ba - Barium 01007 21.5 ugi TOC 00680 <1.0 mg/L Ca - Calcium oos16 mg/L Chloride 00940 <1.0 mg/L Cd - Cadmium 01027 ug1L Arsenic oloo2 <10.0 ug/L Chromium: Total 01034 <5.0 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 <5.0 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 530 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate G0945 mg1L Hg - Mercury 71900 ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0) Specific Conductance oao85 FLmhos K - Potassium o0937 mg/L VOC 7873 method # SM 6200B Total Ammonia 00610 <0.10 mg/L Mg - Magnesium C0927 mg/L method # (Ammonia Nitrogen: NH,asW. Ammonia Nirrogen, Total) Mn - Manganese 01055 13.0 ug1L method # TKN as N 00625 mg/L Ni - Nickel 01057 ug1L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/1- Effluent Total VOCs: mg/L VOC Removal% Robert P. Barr / Authorized Agent Permitlee (or Authorized Agent) Name and Title - Please print or type GW-59 Rev.06-07-2018 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: DEPARTMENT OF ENVIRONMENTAL QUALITY- DIV. OF WATER RESOURCES INFORMA11OW PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 FACILITY INFORMATION Please Pnnt dearly or Type PERMIT Number: Expiration Date: 613612025 Facility Name: Rose Hill Plantation Development, LLC Non -Discharge UIC NPDES Other W00032o113 Permit Name (if different): Facility Address: 3041 New Leicester Highway TYPE OF PERMITTED OPERATION BEING MONITORED Leicester NC 28748 County Buncombe ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑ Spray Field ❑ Remediation: Contact Person: Bob Barr Telephone#: (828) 251-1900 ❑ Rotary Distributor ❑ Land Application of Sludge Well LocationlSite Name: Well # 2(MW B on GW-1b) No. of wells to be sampled: 3 ❑ Water Source Heat Pump ❑■ Other: Surface Irrigation ffrom Permit) SAMPLING INFORMATION If WELL WELL. ID NUMBER (from Permit): Well # 2 downgradient Date sample collected: 11/27/2023 FIELD ANALYSES: WAS Well Depth: 30 ft. Well Diameter: 2 in. pH 00400 5.24 units Temp. 000lo: 17.6 °C DRY at Depth to Water Level a2546: 15.5 p ft. below measuring point 1 Screened Interval: 0 ft. to 30 ft. Spec. Cond. 00asa: 19.9 µ Mhos time of sampling, Measuring Point is 2.5 ft. above land surface Relative M.P. Elevation: ft. Odor 00085: None check Volume of water pumped/bailed before sampling: gallons Appearance Clear here:❑ Samples for metals were collected unfiltered: ❑■- YES ❑ NO and field acidified: 0 YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 12/12/2023 Laboratory Name: Pace Analytical Certification No. 40 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 9o335 mg1L Nitrite (NO2) as N o0615 <0.040 mglL Pb -Lead a1 c51 <5.0 uglL Coliform: MF Fecal 31616 <1.0 1100ml- Nitrate (NO,) as N OD620 0,40 mglL Zn -Zinc 010g2 <19.0 mg1L Coliform: MF Total 31504 11OOmL Phosphorus: Total as P ooe65 <0,050 rng1L (Note: use MPN method for highly turbid samples) Orthophosphate 70507 mglL Other (Specify Compounds and Concentration Units): Dissolved Solids:Total m3oo <25.0 mglL Al - Aluminum o11a5 mglL pH (Lab) 00403 units Ba - Barium 01007 31.6 uglL TOC oosaa <1-0 mglL Ca - Calcium o0916 mglL Chloride 00940 1.0 mglL Cd - Cadmium 01027 uglL Arsenic 01002 <10.0 ug1L Chromium: Total 01034 <5.0 uglL Grease and Oils 00552 mglL Cu - Copper D1042 <5.0 mglL ORGANICS: (by GC, GC/MS, HPLC) Phenol 02730 uglL Fe - Iron 01045 303 uglL (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mglL Fig - Mercury 71900 uglL Lab Report Attached? ❑■ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00237 mglL VOC 7873 method # SM 6200E Total Ammonia oa610 <0.10 mglL Mg - Magnesium 00927 mglL method # (Ammonia Nitrogen. NH, as N; Ammonia Nitrogen, Total) Mn - Manganese o1o55 6.9 g ug1L ,method # TKN as N 00625 mglL Ni - Nickel 01067 uglL method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs mglL Effluent Total VOCs: mglL VOC Removal% Robert P. Barr 1 Authorized Agent Permittee (or Authorized Agent) Name and Title - Please print cr type GW-59 Rev.06-07-2018 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617MAIL SERVICE CENTER, RALEIGH,NG27699.1617 FACILITY INFORMATION Please Print Cleady or Type PERMIT Number: Expiration Date: 613012028 Facility Name: Rose Hill Plantation Development, LLC Non -Discharge UIC Permit Name (if different): NPDES Other W000320113 Facility Address: 3041 New Leicester Highway TYPE OF PERMITTED OPERATION BEING MONITORED Leicester NC 28748 County Buncombe ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑ Spray Field ❑ Remediation: Contact Person: Bob Barr Telephone# (828) 251-1900 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Well # 3 No. of wells to be sampled: 3 ❑ Water Source Heat Pump ❑■ Other: Surface Irrigation (tram Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): Well # 3 Date sample collected: 11/27/2023 FIELD ANALYSES: WAS Well Depth: 14 ft. Well Diameter: 2 in. pH 004Uo: 6.7 units Temp. 00010: 7.0 °C DRY at Depth to Water Level 82546: 5.16 p ff. below measuring 4 point Screened Interval: ft. to 14 #t. Spec. Cond. 000s4: 108.E �` Mhos time of sampling, Measuring Point is 0 ft, above land surface Relative M.P, Flevation: ft, Odor coon None check Volume of water pumped/bailed before sampling: gallons Appearance Clear here:❑ Samples for metals were collected unfiltered: *YES ❑ NO and field acidified: ❑■ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 1211212023 Laboratory Name: Pace Analytical Certification No. 40 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mglL Nitrite (NO2) as N oo615 <0.040 mglL Pb -Lead 01051 <5.0 uglL Coliform: MF Fecal 31616 <1.0 1100mL Nitrate (NO.) as N OD620 <0.040 mglL Zn - Zinc o1092 <10.0 mglL Coliform: MF Total 31504 1100mL Phosphorus: Total as P 66665 0.68 mg1L (Note, Use MPN method ror highly tumid samples) Orthophosphate 70507 mglL Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 79.0 mglL Al - Aluminum o1105 mglL PH (Lab) 00403 units Ba - Barium 01007 17.7 uglL TOC omsa <1.0 mglL Ca - Calcium 00916 mglL Chloride 00940 4.7 mglL Cd - Cadmium 01027 uglL Arsenic 01002 <10.0 ug1L Chromium: Total 01034 <5-0 uglL Grease and Oils 00552 mglL Cu - Copper 01042 <5.0 mglL ORGANICS: (by GC, GCIMS, HPLC) Phenol 32730 ug1L Fe - Iron 01D45 16500 uglL (Specify test and method #. ATTACH LAB REPORT.) Sulfate D0945 mglL Hg - Mercury 71900 uglL Lab Report Attached? ❑■ Yes (1) ❑ No (0) Specific Conductance coo95 �tMhos K - Potassium 00937 mglL VOC 7973 method # SM 6200E Total Ammonia coslo <0.10 mglL Mg - Magnesium 00927 mglL method # (Ammonia Nitrogen,, NH, as N, Ammania Nitrogen, Total) Mn -Manganese 0105s 588 uglL ,method # TKN as N 00625 mglL Ni - Nickel U1067 uglL method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mglL Effluent Total VOCs: mglL VOC Removal% Robert P. Barr/ Authorized Agent Permittee (or Authorized Agentj Name and Title - Mease print or type Signature of Permittee (or Authorized Agent) (Date) GVV-59 Rev.06-07-2018 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 December 12, 2023 Kimber Reese RPB Systems Inc. P.O. Box 1325 Asheville, NC 28802 RE: Project: Rose Hill MW 11/27 Pace Project No.: 92700404 Dear Kimber Reese: Enclosed are the analytical results for sample(s) received by the laboratory on November 27, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, (Z/� ` - Lord Patton lorri.patton@pacelabs.com 828-417-6055 Project Manager Enclosures cc: Mr. Robert Barr, RPB Systems Inc. Ms. Liz Barr, RPB Systems Inc. Lorri Patton REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 37 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Rose Hill MW 11/27 Pace Project No.: 92700404 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 CERTIFICATIONS South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 VirginiaNELAP Certification #: 460221 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 VirginiaNELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 37 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 SAMPLE ANALYTE COUNT Project: Pace Project No.: Rose Hill MW 11/27 92700404 Analytes Lab lD Sample ID Method Analysts Reported Laboratory 92700404001 MW-1 EPA 200.7 Rev 4.4 1994 DBB1 8 PASI-A SM 6200B SAS 63 PASI-C SM 2540C-2015 RVS 1 PASI-A SM 9222D-2015 YEG 1 PASI-A EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 353.2 Rev 2.0 1993 NCF 2 PASI-A EPA 365.1 Rev 2.0 1993 Zip 1 PASI-A SM 4500-CI-E-2011 Zip 1 PASI-A SM 531OB-2014 MJP 1 PASI-A 92700404002 MW-2 EPA 200.7 Rev 4.4 1994 D13131 8 PASI-A SM 6200B SAS 63 PASI-C SM 2540C-2015 RVS 1 PASI-A SM 9222D-2015 YEG 1 PASI-A EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 353.2 Rev 2.0 1993 NCF 2 PASI-A EPA 365.1 Rev 2.0 1993 Zip 1 PASI-A SM 4500-CI-E-2011 Zip 1 PASI-A SM 531OB-2014 MJP 1 PASI-A 92700404003 MW-31B EPA 200.7 Rev 4.4 1994 DB61 8 PASI-A SM 6200B SAS 63 PASI-C SM 2540C-2015 RVS 1 PASI-A SM 9222D-2015 YEG 1 PASI-A EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 353.2 Rev 2.0 1993 NCF 2 PASI-A EPA 365.1 Rev 2.0 1993 Zip 1 PASI-A SM 4500-CI-E-2011 Zip 1 PASI-A SM 531OB-2014 MJP 1 PASI-A PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 37 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Rose Hill MW 11/27 Pace Project No.: 92700404 Sample: MWA Lab ID: 92700404001 Collected: 11/27/23 15:00 Received: 11/27/23 16:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 11/29/23 12:01 Collected By Mark 1 11/29/23 12:01 Swann Collected Date 11/27/23 1 11/29/23 12:01 Collected Time 15:00 1 11/29/23 12:01 pH 6.14 Std. Units 1 11/29/23 12:01 Temperature 11.9 deg C 1 11/29/23 12:01 Static Water Level 40.81 feet 1 11/29/23 12:01 Specific Conductance 43.8 umhos/cm 1 11/29/23 12:01 Oxygen, Dissolved 4.65 mg/L 1 11/29/23 12:01 7782-44-7 REDOX 169.0 my 1 11/29/23 12:01 Turbidity 9.80 NTU 1 11/29/23 12:01 Odor No odor 1 11/29/23 12:01 Appearance Clear 1 11/29/23 12:01 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services -Asheville Arsenic ND ug/L 10.0 1 11/28/2312:30 12/06/2318:01 7440-38-2 Barium 21.5 ug/L 5.0 1 11/28/2312:30 12/06/2318:01 7440-39-3 Chromium ND ug/L 5.0 1 11/28/2312:30 12/06/2318:01 7440-47-3 Copper ND ug/L 5.0 1 11/28/2312:30 12/06/2318:01 7440-50-8 Iron 530 ug/L 50.0 1 11/28/2312:30 12/06/2318:01 7439-89-6 Lead ND ug/L 5.0 1 11/28/2312:30 12/06/2318:01 7439-92-1 Manganese 13.0 ug/L 5.0 1 11/28/2312:30 12/06/2318:01 7439-96-5 Zinc ND ug/L 10.0 1 11/28/2312:30 12/06/2318:01 7440-66-6 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND ug/L 0.50 1 12/04/2319:27 71-43-2 Bromobenzene ND ug/L 0.50 1 12/04/2319:27 108-86-1 Bromochloromethane ND ug/L 0.50 1 12/04/2319:27 74-97-5 Bromodichloromethane ND ug/L 0.50 1 12/04/2319:27 75-27-4 Bromoform ND ug/L 0.50 1 12/04/2319:27 75-25-2 Bromomethane ND ug/L 5.0 1 12/04/2319:27 74-83-9 n-Butylbenzene ND ug/L 0.50 1 12/04/2319:27 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 12/04/2319:27 135-98-8 tert-Butyl benzene ND ug/L 0.50 1 12/04/2319:27 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 12/04/23 19:27 56-23-5 Chlorobenzene ND ug/L 0.50 1 12/04/2319:27 108-90-7 Chloroethane ND ug/L 1.0 1 12/04/2319:27 75-00-3 Chloroform ND ug/L 0.50 1 12/04/2319:27 67-66-3 Chloromethane ND ug/L 1.0 1 12/04/2319:27 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 12/04/2319:27 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 12/04/2319:27 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 12/04/2319:27 96-12-8 Dibromochloromethane ND ug/L 0.50 1 12/04/2319:27 124-48-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 01:22 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 37 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Rose Hill MW 11/27 Pace Project No.: 92700404 Sample: MW-1 Parameters 6200B MSV 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene Isopropylbenzene (Cumene) Methylene Chloride Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) ANALYTICAL RESULTS Lab ID: 92700404001 Collected: 11/27/23 15:00 Received: 11/27/23 16:00 Matrix: Water Results Units Report Limit DF Prepared Analyzed CAS No. Qual Analytical Method: SM 6200B Pace Analytical Services - Charlotte ND ug/L 0.50 1 12/04/2319:27 106-93-4 ND ug/L 0.50 1 12/04/2319:27 74-95-3 ND ug/L 0.50 1 12/04/2319:27 95-50-1 ND ug/L 0.50 1 12/04/2319:27 541-73-1 ND ug/L 0.50 1 12/04/2319:27 106-46-7 ND ug/L 0.50 1 12/04/2319:27 75-71-8 ND ug/L 0.50 1 12/04/2319:27 75-34-3 ND ug/L 0.50 1 12/04/2319:27 107-06-2 ND ug/L 0.50 1 12/04/2319:27 75-35-4 ND ug/L 0.50 1 12/04/2319:27 156-59-2 ND ug/L 0.50 1 12/04/2319:27 156-60-5 ND ug/L 0.50 1 12/04/2319:27 78-87-5 ND ug/L 0.50 1 12/04/2319:27 142-28-9 ND ug/L 0.50 1 12/04/2319:27 594-20-7 ND ug/L 0.50 1 12/04/2319:27 563-58-6 ND ug/L 0.50 1 12/04/2319:27 10061-01-5 ND ug/L 0.50 1 12/04/2319:27 10061-02-6 ND ug/L 0.50 1 12/04/2319:27 108-20-3 ND ug/L 0.50 1 12/04/2319:27 100-41-4 ND ug/L 2.0 1 12/04/2319:27 87-68-3 ND ug/L 0.50 1 12/04/2319:27 98-82-8 ND ug/L 2.0 1 12/04/2319:27 75-09-2 ND ug/L 0.50 1 12/04/2319:27 1634-04-4 ND ug/L 2.0 1 12/04/2319:27 91-20-3 ND ug/L 0.50 1 12/04/2319:27 103-65-1 ND ug/L 0.50 1 12/04/2319:27 100-42-5 ND ug/L 0.50 1 12/04/2319:27 630-20-6 ND ug/L 0.50 1 12/04/2319:27 79-34-5 ND ug/L 0.50 1 12/04/2319:27 127-18-4 ND ug/L 0.50 1 12/04/2319:27 108-88-3 ND ug/L 2.0 1 12/04/2319:27 87-61-6 ND ug/L 2.0 1 12/04/2319:27 120-82-1 ND ug/L 0.50 1 12/04/2319:27 71-55-6 ND ug/L 0.50 1 12/04/2319:27 79-00-5 ND ug/L 0.50 1 12/04/2319:27 79-01-6 ND ug/L 1.0 1 12/04/2319:27 75-69-4 ND ug/L 0.50 1 12/04/2319:27 96-18-4 ND ug/L 0.50 1 12/04/2319:27 95-63-6 ND ug/L 0.50 1 12/04/2319:27 108-67-8 ND ug/L 1.0 1 12/04/2319:27 75-01-4 ND ug/L 1.0 1 12/04/2319:27 179601-23-1 ND ug/L 0.50 1 12/04/2319:27 95-47-6 96 % 70-130 1 12/04/2319:27 17060-07-0 97 % 70-130 1 12/04/2319:27 460-00-4 99 % 70-130 1 12/04/2319:27 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 01:22 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 37 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Rose Hill MW 11/27 Pace Project No.: 92700404 Sample: MWA Lab ID: 92700404001 Collected: 11/27/23 15:00 Received: 11/27/23 16:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids 54.0 mg/L 25.0 1 11/29/23 19:16 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services -Asheville Fecal Coliforms ND CFU/100 mL 1.0 1 11/27/23 16:31 11/28/23 15:16 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 1 12/08/23 11:29 7664-41-7 351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Kjeldahl, Total ND mg/L 0.50 1 12/07/23 18:10 12/08/23 05:09 7727-37-9 M1 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate ND mg/L 0.040 1 11/28/23 03:46 14797-55-8 Nitrogen, Nitrite ND mg/L 0.040 1 11/28/23 03:46 14797-65-0 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus 0.072 mg/L 0.050 1 12/08/2317:26 12/11/2312:23 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride ND mg/L 1.0 1 12/12/2311:49 16887-00-6 531013 TOC Analytical Method: SM 531 OB-2014 Pace Analytical Services -Asheville Total Organic Carbon ND mg/L 1.0 1 12/05/23 03:34 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 01:22 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 37 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Rose Hill MW 11/27 Pace Project No.: 92700404 Sample: MW-2 Lab ID: 92700404002 Collected: 11/27/23 12:00 Received: 11/27/23 16:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 11/29/23 12:04 Collected By Mark 1 11/29/23 12:04 Swann Collected Date 11/27/23 1 11/29/23 12:04 Collected Time 12:00 1 11/29/23 12:04 pH 5.24 Std. Units 1 11/29/23 12:04 Temperature 7.6 deg C 1 11/29/23 12:04 Static Water Level 15.50 feet 1 11/29/23 12:04 Specific Conductance 19.9 umhos/cm 1 11/29/23 12:04 Oxygen, Dissolved 4.91 mg/L 1 11/29/23 12:04 7782-44-7 REDOX 149.0 my 1 11/29/23 12:04 Turbidity 7.87 NTU 1 11/29/23 12:04 Odor No odor 1 11/29/23 12:04 Appearance /clear 1 11/29/23 12:04 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services -Asheville Arsenic ND ug/L 10.0 1 11/28/2312:30 12/06/2318:04 7440-38-2 Barium 31.6 ug/L 5.0 1 11/28/2312:30 12/06/2318:04 7440-39-3 Chromium ND ug/L 5.0 1 11/28/2312:30 12/06/2318:04 7440-47-3 Copper ND ug/L 5.0 1 11/28/2312:30 12/06/2318:04 7440-50-8 Iron 303 ug/L 50.0 1 11/28/2312:30 12/06/2318:04 7439-89-6 Lead ND ug/L 5.0 1 11/28/2312:30 12/06/2318:04 7439-92-1 Manganese 6.9 ug/L 5.0 1 11/28/2312:30 12/06/2318:04 7439-96-5 Zinc ND ug/L 10.0 1 11/28/2312:30 12/06/2318:04 7440-66-6 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND ug/L 0.50 1 12/04/2319:45 71-43-2 Bromobenzene ND ug/L 0.50 1 12/04/2319:45 108-86-1 Bromochloromethane ND ug/L 0.50 1 12/04/2319:45 74-97-5 Bromodichloromethane ND ug/L 0.50 1 12/04/2319:45 75-27-4 Bromoform ND ug/L 0.50 1 12/04/2319:45 75-25-2 Bromomethane ND ug/L 5.0 1 12/04/2319:45 74-83-9 n-Butylbenzene ND ug/L 0.50 1 12/04/2319:45 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 12/04/2319:45 135-98-8 tert-Butyl benzene ND ug/L 0.50 1 12/04/2319:45 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 12/04/23 19:45 56-23-5 Chlorobenzene ND ug/L 0.50 1 12/04/2319:45 108-90-7 Chloroethane ND ug/L 1.0 1 12/04/2319:45 75-00-3 Chloroform ND ug/L 0.50 1 12/04/2319:45 67-66-3 Chloromethane ND ug/L 1.0 1 12/04/2319:45 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 12/04/2319:45 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 12/04/2319:45 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 12/04/2319:45 96-12-8 Dibromochloromethane ND ug/L 0.50 1 12/04/2319:45 124-48-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 01:22 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 37 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Rose Hill MW 11/27 Pace Project No.: 92700404 Sample: MW-2 Parameters 6200B MSV 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene Isopropylbenzene (Cumene) Methylene Chloride Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) ANALYTICAL RESULTS Lab ID: 92700404002 Collected: 11/27/23 12:00 Received: 11/27/23 16:00 Matrix: Water Results Units Report Limit DF Prepared Analyzed CAS No. Qual Analytical Method: SM 6200B Pace Analytical Services - Charlotte ND ug/L 0.50 1 12/04/2319:45 106-93-4 ND ug/L 0.50 1 12/04/2319:45 74-95-3 ND ug/L 0.50 1 12/04/2319:45 95-50-1 ND ug/L 0.50 1 12/04/2319:45 541-73-1 ND ug/L 0.50 1 12/04/2319:45 106-46-7 ND ug/L 0.50 1 12/04/2319:45 75-71-8 ND ug/L 0.50 1 12/04/2319:45 75-34-3 ND ug/L 0.50 1 12/04/2319:45 107-06-2 ND ug/L 0.50 1 12/04/2319:45 75-35-4 ND ug/L 0.50 1 12/04/2319:45 156-59-2 ND ug/L 0.50 1 12/04/2319:45 156-60-5 ND ug/L 0.50 1 12/04/2319:45 78-87-5 ND ug/L 0.50 1 12/04/2319:45 142-28-9 ND ug/L 0.50 1 12/04/2319:45 594-20-7 ND ug/L 0.50 1 12/04/2319:45 563-58-6 ND ug/L 0.50 1 12/04/2319:45 10061-01-5 ND ug/L 0.50 1 12/04/2319:45 10061-02-6 ND ug/L 0.50 1 12/04/2319:45 108-20-3 ND ug/L 0.50 1 12/04/2319:45 100-41-4 ND ug/L 2.0 1 12/04/2319:45 87-68-3 ND ug/L 0.50 1 12/04/2319:45 98-82-8 ND ug/L 2.0 1 12/04/2319:45 75-09-2 ND ug/L 0.50 1 12/04/2319:45 1634-04-4 ND ug/L 2.0 1 12/04/2319:45 91-20-3 ND ug/L 0.50 1 12/04/2319:45 103-65-1 ND ug/L 0.50 1 12/04/2319:45 100-42-5 ND ug/L 0.50 1 12/04/2319:45 630-20-6 ND ug/L 0.50 1 12/04/2319:45 79-34-5 ND ug/L 0.50 1 12/04/2319:45 127-18-4 ND ug/L 0.50 1 12/04/2319:45 108-88-3 ND ug/L 2.0 1 12/04/2319:45 87-61-6 ND ug/L 2.0 1 12/04/2319:45 120-82-1 ND ug/L 0.50 1 12/04/2319:45 71-55-6 ND ug/L 0.50 1 12/04/2319:45 79-00-5 ND ug/L 0.50 1 12/04/2319:45 79-01-6 ND ug/L 1.0 1 12/04/2319:45 75-69-4 ND ug/L 0.50 1 12/04/2319:45 96-18-4 ND ug/L 0.50 1 12/04/2319:45 95-63-6 ND ug/L 0.50 1 12/04/2319:45 108-67-8 ND ug/L 1.0 1 12/04/2319:45 75-01-4 ND ug/L 1.0 1 12/04/2319:45 179601-23-1 ND ug/L 0.50 1 12/04/2319:45 95-47-6 96 % 70-130 1 12/04/2319:45 17060-07-0 96 % 70-130 1 12/04/2319:45 460-00-4 98 % 70-130 1 12/04/2319:45 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 01:22 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 37 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Rose Hill MW 11/27 Pace Project No.: 92700404 Sample: MW-2 Lab ID: 92700404002 Collected: 11/27/23 12:00 Received: 11/27/23 16:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids ND mg/L 25.0 1 11/29/23 19:16 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services -Asheville Fecal Coliforms ND CFU/100 mL 1.0 1 11/27/23 16:31 11/28/23 15:16 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 1 12/08/23 11:31 7664-41-7 351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Kjeldahl, Total ND mg/L 0.50 1 12/07/23 18:10 12/08/23 05:16 7727-37-9 M1 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 0.40 mg/L 0.040 1 11/28/23 03:45 14797-55-8 Nitrogen, Nitrite ND mg/L 0.040 1 11/28/23 03:45 14797-65-0 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus ND mg/L 0.050 1 12/08/2317:26 12/11/2312:28 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 1.9 mg/L 1.0 1 12/12/2311:50 16887-00-6 531013 TOC Analytical Method: SM 531 OB-2014 Pace Analytical Services -Asheville Total Organic Carbon ND mg/L 1.0 1 12/05/23 03:52 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 01:22 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 37 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Rose Hill MW 11/27 Pace Project No.: 92700404 Sample: MW-313 Lab ID: 92700404003 Collected: 11/27/23 10:30 Received: 11/27/23 16:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 11/29/23 12:06 Collected By Mark 1 11/29/23 12:06 Swann Collected Date 11/27/23 1 11/29/23 12:06 Collected Time 10:30 1 11/29/23 12:06 pH 6.70 Std. Units 1 11/29/23 12:06 Temperature 7.0 deg C 1 11/29/23 12:06 Static Water Level 5.16 feet 1 11/29/23 12:06 Specific Conductance 105.3 umhos/cm 1 11/29/23 12:06 Oxygen, Dissolved 0.30 mg/L 1 11/29/23 12:06 7782-44-7 REDOX 77.9 my 1 11/29/23 12:06 Turbidity 1.31 NTU 1 11/29/23 12:06 Odor No odor 1 11/29/23 12:06 Appearance Clear 1 11/29/23 12:06 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services -Asheville Arsenic ND ug/L 10.0 1 11/28/2312:30 12/06/2318:07 7440-38-2 Barium 17.7 ug/L 5.0 1 11/28/2312:30 12/06/2318:07 7440-39-3 Chromium ND ug/L 5.0 1 11/28/2312:30 12/06/2318:07 7440-47-3 Copper ND ug/L 5.0 1 11/28/2312:30 12/06/2318:07 7440-50-8 Iron 16500 ug/L 50.0 1 11/28/2312:30 12/06/2318:07 7439-89-6 Lead ND ug/L 5.0 1 11/28/2312:30 12/06/2318:07 7439-92-1 Manganese 588 ug/L 5.0 1 11/28/23 12:30 12/06/23 18:07 7439-96-5 Zinc ND ug/L 10.0 1 11/28/2312:30 12/06/2318:07 7440-66-6 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND ug/L 0.50 1 12/04/23 20:03 71-43-2 Bromobenzene ND ug/L 0.50 1 12/04/23 20:03 108-86-1 Bromochloromethane ND ug/L 0.50 1 12/04/23 20:03 74-97-5 Bromodichloromethane ND ug/L 0.50 1 12/04/23 20:03 75-27-4 Bromoform ND ug/L 0.50 1 12/04/23 20:03 75-25-2 Bromomethane ND ug/L 5.0 1 12/04/23 20:03 74-83-9 n-Butylbenzene ND ug/L 0.50 1 12/04/23 20:03 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 12/04/23 20:03 135-98-8 tert-Butyl benzene ND ug/L 0.50 1 12/04/23 20:03 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 12/04/23 20:03 56-23-5 Chlorobenzene ND ug/L 0.50 1 12/04/23 20:03 108-90-7 Chloroethane ND ug/L 1.0 1 12/04/23 20:03 75-00-3 Chloroform ND ug/L 0.50 1 12/04/23 20:03 67-66-3 Chloromethane ND ug/L 1.0 1 12/04/23 20:03 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 12/04/23 20:03 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 12/04/23 20:03 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 12/04/23 20:03 96-12-8 Dibromochloromethane ND ug/L 0.50 1 12/04/23 20:03 124-48-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 01:22 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 37 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Rose Hill MW 11/27 Pace Project No.: 92700404 Sample: MW-313 Parameters 6200B MSV 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene Isopropylbenzene (Cumene) Methylene Chloride Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) ANALYTICAL RESULTS Lab ID: 92700404003 Collected: 11/27/23 10:30 Received: 11/27/23 16:00 Matrix: Water Results Units Report Limit DF Prepared Analyzed CAS No. Qual Analytical Method: SM 6200B Pace Analytical Services - Charlotte ND ug/L 0.50 1 12/04/23 20:03 106-93-4 ND ug/L 0.50 1 12/04/23 20:03 74-95-3 ND ug/L 0.50 1 12/04/23 20:03 95-50-1 ND ug/L 0.50 1 12/04/23 20:03 541-73-1 ND ug/L 0.50 1 12/04/23 20:03 106-46-7 ND ug/L 0.50 1 12/04/23 20:03 75-71-8 ND ug/L 0.50 1 12/04/23 20:03 75-34-3 ND ug/L 0.50 1 12/04/23 20:03 107-06-2 ND ug/L 0.50 1 12/04/23 20:03 75-35-4 ND ug/L 0.50 1 12/04/23 20:03 156-59-2 ND ug/L 0.50 1 12/04/23 20:03 156-60-5 ND ug/L 0.50 1 12/04/23 20:03 78-87-5 ND ug/L 0.50 1 12/04/23 20:03 142-28-9 ND ug/L 0.50 1 12/04/23 20:03 594-20-7 ND ug/L 0.50 1 12/04/23 20:03 563-58-6 ND ug/L 0.50 1 12/04/23 20:03 10061-01-5 ND ug/L 0.50 1 12/04/23 20:03 10061-02-6 ND ug/L 0.50 1 12/04/23 20:03 108-20-3 ND ug/L 0.50 1 12/04/23 20:03 100-41-4 ND ug/L 2.0 1 12/04/23 20:03 87-68-3 ND ug/L 0.50 1 12/04/23 20:03 98-82-8 ND ug/L 2.0 1 12/04/23 20:03 75-09-2 ND ug/L 0.50 1 12/04/23 20:03 1634-04-4 ND ug/L 2.0 1 12/04/23 20:03 91-20-3 ND ug/L 0.50 1 12/04/23 20:03 103-65-1 ND ug/L 0.50 1 12/04/23 20:03 100-42-5 ND ug/L 0.50 1 12/04/23 20:03 630-20-6 ND ug/L 0.50 1 12/04/23 20:03 79-34-5 ND ug/L 0.50 1 12/04/23 20:03 127-18-4 ND ug/L 0.50 1 12/04/23 20:03 108-88-3 ND ug/L 2.0 1 12/04/23 20:03 87-61-6 ND ug/L 2.0 1 12/04/23 20:03 120-82-1 ND ug/L 0.50 1 12/04/23 20:03 71-55-6 ND ug/L 0.50 1 12/04/23 20:03 79-00-5 ND ug/L 0.50 1 12/04/23 20:03 79-01-6 ND ug/L 1.0 1 12/04/23 20:03 75-69-4 ND ug/L 0.50 1 12/04/23 20:03 96-18-4 ND ug/L 0.50 1 12/04/23 20:03 95-63-6 ND ug/L 0.50 1 12/04/23 20:03 108-67-8 ND ug/L 1.0 1 12/04/23 20:03 75-01-4 ND ug/L 1.0 1 12/04/23 20:03 179601-23-1 ND ug/L 0.50 1 12/04/23 20:03 95-47-6 96 % 70-130 1 12/04/23 20:03 17060-07-0 95 % 70-130 1 12/04/23 20:03 460-00-4 99 % 70-130 1 12/04/23 20:03 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 01:22 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 37 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Rose Hill MW 11/27 Pace Project No.: 92700404 Sample: MW-313 Lab ID: 92700404003 Collected: 11/27/23 10:30 Received: 11/27/23 16:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Total Dissolved Solids MBIO 9222D Fecal Coliform AVL Fecal Coliforms 350.1 Ammonia Nitrogen, Ammonia 351.2 Total Kjeldahl Nitrogen Nitrogen, Kjeldahl, Total 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate Nitrogen, Nitrite 365.1 Phosphorus, Total Phosphorus 4500 Chloride Chloride 531013 TOC Total Organic Carbon Date: 12/12/2023 01:22 PM Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville 79.0 mg/L 25.0 1 11/29/2319:16 Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services -Asheville ND CFU/100 mL 1.0 1 11/27/23 16:31 11/28/23 15:16 Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville ND mg/L 0.10 1 12/08/2311:32 7664-41-7 Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Pace Analytical Services -Asheville ND mg/L 0.50 1 12/07/23 18:10 12/08/23 05:19 7727-37-9 Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville ND mg/L 0.040 1 11/28/23 03:42 14797-55-8 ND mg/L 0.040 1 11/28/23 03:42 14797-65-0 Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville 0.68 mg/L 0.050 1 12/08/2317:26 12/11/2312:32 7723-14-0 Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville 4.7 mg/L 1.0 1 12/12/2311:52 16887-00-6 Analytical Method: SM 531OB-2014 Pace Analytical Services -Asheville ND mg/L 1.0 1 12/05/23 04:11 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 37 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Rose Hill MW 11/27 Pace Project No.: 92700404 QC Batch: 815696 Analysis Method: EPA 200.7 Rev 4.4 1994 QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92700404001, 92700404002, 92700404003 METHOD BLANK: 4222018 Matrix: Water Associated Lab Samples: 92700404001, 92700404002, 92700404003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Arsenic ug/L ND 10.0 12/06/2317:30 Barium ug/L ND 5.0 12/06/2317:30 Chromium ug/L ND 5.0 12/06/2317:30 Copper ug/L ND 5.0 12/06/2317:30 Iron ug/L ND 50.0 12/06/2317:30 Lead ug/L ND 5.0 12/06/2317:30 Manganese ug/L ND 5.0 12/06/2317:30 Zinc ug/L ND 10.0 12/06/2317:30 LABORATORY CONTROL SAMPLE: 4222019 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic ug/L 500 496 99 85-115 Barium ug/L 500 505 101 85-115 Chromium ug/L 500 501 100 85-115 Copper ug/L 500 499 100 85-115 Iron ug/L 5000 5100 102 85-115 Lead ug/L 500 497 99 85-115 Manganese ug/L 500 510 102 85-115 Zinc ug/L 500 503 101 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4222020 4222021 MS MSD 92700206001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Arsenic ug/L ND 500 500 532 531 106 106 70-130 0 Barium ug/L 86.6 500 500 605 607 104 104 70-130 0 Chromium ug/L 1.91 500 500 513 513 102 102 70-130 0 Copper ug/L 2.6J 500 500 540 540 108 108 70-130 0 Iron ug/L 2980 5000 5000 8090 8090 102 102 70-130 0 Lead ug/L 2.2J 500 500 509 507 101 101 70-130 0 Manganese ug/L 539 500 500 1050 1050 103 102 70-130 1 Zinc ug/L 16.9 500 500 517 517 100 100 70-130 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 01:22 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 37 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Rose Hill MW 11/27 Pace Project No.: 92700404 QC Batch: 817079 Analysis Method: SM 6200B QC Batch Method: SM 6200B Analysis Description: 6200E MSV Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92700404001, 92700404002, 92700404003 METHOD BLANK: 4228984 Matrix: Associated Lab Samples: 92700404001, 92700404002, 92700404003 Blank Parameter Units Result Water Reporting Limit Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 0.50 12/04/23 18:14 1,1,1-Trichloroethane ug/L ND 0.50 12/04/23 18:14 1,1,2,2-Tetrachloroethane ug/L ND 0.50 12/04/23 18:14 1,1,2-Trichloroethane ug/L ND 0.50 12/04/23 18:14 1,1-Dichloroethane ug/L ND 0.50 12/04/23 18:14 1,1-Dichloroethene ug/L ND 0.50 12/04/23 18:14 1,1-Dichloropropene ug/L ND 0.50 12/04/23 18:14 1,2,3-Trichlorobenzene ug/L ND 2.0 12/04/23 18:14 1,2,3-Trichloropropane ug/L ND 0.50 12/04/23 18:14 1,2,4-Trichlorobenzene ug/L ND 2.0 12/04/23 18:14 1,2,4-Trimethylbenzene ug/L ND 0.50 12/04/23 18:14 1,2-Dibromo-3-chloropropane ug/L ND 1.0 12/04/23 18:14 1,2-Dibromoethane (EDB) ug/L ND 0.50 12/04/23 18:14 1,2-Dichlorobenzene ug/L ND 0.50 12/04/23 18:14 1,2-Dichloroethane ug/L ND 0.50 12/04/23 18:14 1,2-Dichloropropane ug/L ND 0.50 12/04/23 18:14 1,3,5-Trimethylbenzene ug/L ND 0.50 12/04/23 18:14 1,3-Dichlorobenzene ug/L ND 0.50 12/04/23 18:14 1,3-Dichloropropane ug/L ND 0.50 12/04/23 18:14 1,4-Dichlorobenzene ug/L ND 0.50 12/04/23 18:14 2,2-Dichloropropane ug/L ND 0.50 12/04/23 18:14 2-Chlorotoluene ug/L ND 0.50 12/04/23 18:14 4-Chlorotoluene ug/L ND 0.50 12/04/23 18:14 Benzene ug/L ND 0.50 12/04/23 18:14 Bromobenzene ug/L ND 0.50 12/04/23 18:14 Bromochloromethane ug/L ND 0.50 12/04/23 18:14 Bromodichloromethane ug/L ND 0.50 12/04/23 18:14 Bromoform ug/L ND 0.50 12/04/23 18:14 Bromomethane ug/L ND 5.0 12/04/23 18:14 Carbon tetrachloride ug/L ND 0.50 12/04/23 18:14 Chlorobenzene ug/L ND 0.50 12/04/23 18:14 Chloroethane ug/L ND 1.0 12/04/23 18:14 Chloroform ug/L ND 0.50 12/04/23 18:14 Chloromethane ug/L ND 1.0 12/04/23 18:14 cis-1,2-Dichloroethene ug/L ND 0.50 12/04/23 18:14 cis-1,3-Dichloropropene ug/L ND 0.50 12/04/23 18:14 Dibromochloromethane ug/L ND 0.50 12/04/23 18:14 Dibromomethane ug/L ND 0.50 12/04/23 18:14 Dichlorodifluoromethane ug/L ND 0.50 12/04/23 18:14 Diisopropyl ether ug/L ND 0.50 12/04/23 18:14 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 01:22 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 37 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Rose Hill MW 11/27 Pace Project No.: 92700404 METHOD BLANK: 4228984 Matrix: Associated Lab Samples: 92700404001, 92700404002, 92700404003 Blank Parameter Units Result Water Reporting Limit Analyzed Ethylbenzene ug/L ND 0.50 12/04/23 18:14 Hexachloro-1,3-butadiene ug/L ND 2.0 12/04/23 18:14 Isopropylbenzene (Cumene) ug/L ND 0.50 12/04/23 18:14 m&p-Xylene ug/L ND 1.0 12/04/23 18:14 Methyl-tert-butyl ether ug/L ND 0.50 12/04/23 18:14 Methylene Chloride ug/L ND 2.0 12/04/23 18:14 n-Butylbenzene ug/L ND 0.50 12/04/23 18:14 n-Propylbenzene ug/L ND 0.50 12/04/23 18:14 Naphthalene ug/L ND 2.0 12/04/23 18:14 o-Xylene ug/L ND 0.50 12/04/23 18:14 sec-Butylbenzene ug/L ND 0.50 12/04/23 18:14 Styrene ug/L ND 0.50 12/04/23 18:14 tert-Butyl benzene ug/L ND 0.50 12/04/23 18:14 Tetrachloroethene ug/L ND 0.50 12/04/23 18:14 Toluene ug/L ND 0.50 12/04/23 18:14 trans-1,2-Dichloroethene ug/L ND 0.50 12/04/23 18:14 trans- 1,3-Dichloropropene ug/L ND 0.50 12/04/23 18:14 Trichloroethene ug/L ND 0.50 12/04/23 18:14 Trichlorofluoromethane ug/L ND 1.0 12/04/23 18:14 Vinyl chloride ug/L ND 1.0 12/04/23 18:14 1,2-Dichloroethane-d4 (S) % 97 70-130 12/04/23 18:14 4-Bromofluorobenzene (S) % 97 70-130 12/04/23 18:14 Toluene-d8 (S) % 99 70-130 12/04/23 18:14 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 4228985 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 20 18.9 94 60-140 1,1,1-Trichloroethane ug/L 20 19.4 97 60-140 1,1,2,2-Tetrachloroethane ug/L 20 19.7 99 60-140 1,1,2-Trichloroethane ug/L 20 19.8 99 60-140 1,1-Dichloroethane ug/L 20 19.3 97 60-140 1,1-Dichloroethene ug/L 20 19.6 98 60-140 1,1-Dichloropropene ug/L 20 21.1 105 60-140 1,2,3-Trichlorobenzene ug/L 20 18.9 94 60-140 1,2,3-Trichloropropane ug/L 20 18.5 92 60-140 1,2,4-Trichlorobenzene ug/L 20 19.2 96 60-140 1,2,4-Trimethylbenzene ug/L 20 20.2 101 60-140 1,2-Dibromo-3-chloropropane ug/L 20 17.9 90 60-140 1,2-Dibromoethane (EDB) ug/L 20 19.9 99 60-140 1,2-Dichlorobenzene ug/L 20 19.9 99 60-140 1,2-Dichloroethane ug/L 20 19.4 97 60-140 1,2-Dichloropropane ug/L 20 19.6 98 60-140 1,3,5-Trimethylbenzene ug/L 20 20.1 100 60-140 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 01:22 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 37 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Rose Hill MW 11/27 Pace Project No.: 92700404 LABORATORY CONTROL SAMPLE: Parameter 4228985 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,3-Dichlorobenzene ug/L 20 19.8 99 60-140 1,3-Dichloropropane ug/L 20 18.8 94 60-140 1,4-Dichlorobenzene ug/L 20 19.6 98 60-140 2,2-Dichloropropane ug/L 20 18.7 93 60-140 2-Chlorotoluene ug/L 20 19.4 97 60-140 4-Chlorotoluene ug/L 20 19.8 99 60-140 Benzene ug/L 20 19.3 96 60-140 Bromobenzene ug/L 20 19.5 97 60-140 Bromochloromethane ug/L 20 20.3 102 60-140 Bromodichloromethane ug/L 20 18.3 92 60-140 Bromoform ug/L 20 17.6 88 60-140 Bromomethane ug/L 20 18.1 90 60-140 Carbon tetrachloride ug/L 20 18.8 94 60-140 Chlorobenzene ug/L 20 19.1 95 60-140 Chloroethane ug/L 20 21.4 107 60-140 Chloroform ug/L 20 18.8 94 60-140 Chloromethane ug/L 20 17.8 89 60-140 cis-1,2-Dichloroethene ug/L 20 18.9 95 60-140 cis-1,3-Dichloropropene ug/L 20 18.5 93 60-140 Dibromochloromethane ug/L 20 18.8 94 60-140 Dibromomethane ug/L 20 19.2 96 60-140 Dichlorodifluoromethane ug/L 20 16.7 84 60-140 Diisopropyl ether ug/L 20 18.2 91 60-140 Ethylbenzene ug/L 20 19.0 95 60-140 Hexachloro-1,3-butadiene ug/L 20 20.0 100 60-140 Isopropylbenzene (Cumene) ug/L 20 19.3 96 60-140 m&p-Xylene ug/L 40 38.2 95 60-140 Methyl-tert-butyl ether ug/L 20 18.1 91 60-140 Methylene Chloride ug/L 20 19.6 98 60-140 n-Butylbenzene ug/L 20 21.2 106 60-140 n-Propylbenzene ug/L 20 19.5 97 60-140 Naphthalene ug/L 20 19.0 95 60-140 o-Xylene ug/L 20 19.1 96 60-140 sec-Butylbenzene ug/L 20 20.1 100 60-140 Styrene ug/L 20 19.6 98 60-140 tert-Butyl benzene ug/L 20 16.2 81 60-140 Tetrachloroethene ug/L 20 18.5 92 60-140 Toluene ug/L 20 18.9 94 60-140 trans-1,2-Dichloroethene ug/L 20 19.8 99 60-140 trans- 1,3-Dichloropropene ug/L 20 18.4 92 60-140 Trichloroethene ug/L 20 19.8 99 60-140 Trichlorofluoromethane ug/L 20 19.4 97 60-140 Vinyl chloride ug/L 20 16.6 83 60-140 1,2-Dichloroethane-d4 (S) % 100 70-130 4-Bromofluorobenzene (S) % 98 70-130 Toluene-d8 (S) % 100 70-130 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 01:22 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 37 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Rose Hill MW 11/27 Pace Project No.: 92700404 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4228986 4228987 MS MSD 92700404001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 23.2 22.6 116 113 60-140 3 1,1,1-Trichloroethane ug/L ND 20 20 25.0 24.2 125 121 60-140 3 1,1,2,2-Tetrachloroethane ug/L ND 20 20 23.9 22.8 120 114 60-140 5 1,1,2-Trichloroethane ug/L ND 20 20 24.1 23.0 120 115 60-140 4 1,1-Dichloroethane ug/L ND 20 20 24.3 23.6 122 118 60-140 3 1,1-Dichloroethene ug/L ND 20 20 25.8 25.2 129 126 60-140 2 1,1-Dichloropropene ug/L ND 20 20 26.9 26.3 134 132 60-140 2 1,2,3-Trichlorobenzene ug/L ND 20 20 21.0 20.2 105 101 60-140 4 1,2,3-Trichloropropane ug/L ND 20 20 22.6 21.3 113 107 60-140 6 1,2,4-Trichlorobenzene ug/L ND 20 20 20.7 20.5 104 103 60-140 1 1,2,4-Trimethylbenzene ug/L ND 20 20 23.2 23.0 116 115 60-140 1 1,2-Dibromo-3-chloropropane ug/L ND 20 20 21.2 19.6 106 98 60-140 8 1,2-Dibromoethane (EDB) ug/L ND 20 20 23.9 23.2 119 116 60-140 3 1,2-Dichlorobenzene ug/L ND 20 20 22.8 22.0 114 110 60-140 4 1,2-Dichloroethane ug/L ND 20 20 24.4 23.4 122 117 60-140 4 1,2-Dichloropropane ug/L ND 20 20 24.5 23.6 122 118 60-140 4 1,3,5-Trimethylbenzene ug/L ND 20 20 23.1 22.7 115 113 60-140 2 1,3-Dichlorobenzene ug/L ND 20 20 22.3 21.9 112 109 60-140 2 1,3-Dichloropropane ug/L ND 20 20 22.9 22.3 115 111 60-140 3 1,4-Dichlorobenzene ug/L ND 20 20 22.2 21.9 111 109 60-140 2 2,2-Dichloropropane ug/L ND 20 20 23.8 23.2 119 116 60-140 3 2-Chlorotoluene ug/L ND 20 20 22.6 22.0 113 110 60-140 2 4-Chlorotoluene ug/L ND 20 20 22.6 22.5 113 113 60-140 0 Benzene ug/L ND 20 20 23.9 23.2 119 116 60-140 3 Bromobenzene ug/L ND 20 20 22.7 21.9 114 110 60-140 4 Bromochloromethane ug/L ND 20 20 25.1 24.3 125 121 60-140 3 Bromodichloromethane ug/L ND 20 20 22.9 22.4 114 112 60-140 2 Bromoform ug/L ND 20 20 21.2 20.3 106 101 60-140 5 Bromomethane ug/L ND 20 20 20.8 22.5 104 113 60-140 8 Carbon tetrachloride ug/L ND 20 20 23.8 23.3 119 117 60-140 2 Chlorobenzene ug/L ND 20 20 23.4 22.6 117 113 60-140 3 Chloroethane ug/L ND 20 20 27.0 26.3 135 132 60-140 3 Chloroform ug/L ND 20 20 23.4 22.8 117 114 60-140 3 Chloromethane ug/L ND 20 20 21.8 21.3 109 107 60-140 2 cis-1,2-Dichloroethene ug/L ND 20 20 23.9 23.4 119 117 60-140 2 cis-1,3-Dichloropropene ug/L ND 20 20 22.1 21.9 111 110 60-140 1 Dibromochloromethane ug/L ND 20 20 22.5 22.0 112 110 60-140 2 Dibromomethane ug/L ND 20 20 23.0 22.1 115 110 60-140 4 Dichlorodifluoromethane ug/L ND 20 20 22.4 21.9 112 109 60-140 2 Diisopropyl ether ug/L ND 20 20 22.9 21.9 114 110 60-140 4 Ethylbenzene ug/L ND 20 20 23.0 22.6 115 113 60-140 2 Hexachloro-1,3-butadiene ug/L ND 20 20 21.8 22.1 109 110 60-140 1 Isopropylbenzene (Cumene) ug/L ND 20 20 23.5 23.1 118 116 60-140 2 m&p-Xylene ug/L ND 40 40 46.4 45.9 116 115 60-140 1 Methyl-tert-butyl ether ug/L ND 20 20 22.8 21.7 114 108 60-140 5 Methylene Chloride ug/L ND 20 20 22.9 22.2 114 111 60-140 3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 01:22 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 37 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Rose Hill MW 11/27 Pace Project No.: 92700404 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4228986 4228987 MS MSD 92700404001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual n-Butylbenzene ug/L ND 20 20 23.3 23.5 117 118 60-140 1 n-Propylbenzene ug/L ND 20 20 22.5 22.2 112 111 60-140 1 Naphthalene ug/L ND 20 20 22.2 21.0 111 105 60-140 6 o-Xylene ug/L ND 20 20 22.5 22.0 112 110 60-140 2 sec-Butylbenzene ug/L ND 20 20 23.0 22.9 115 114 60-140 1 Styrene ug/L ND 20 20 23.8 22.9 119 114 60-140 4 tert-Butyl benzene ug/L ND 20 20 18.5 18.4 92 92 60-140 0 Tetrachloroethene ug/L ND 20 20 22.3 21.9 112 109 60-140 2 Toluene ug/L ND 20 20 23.2 22.5 116 112 60-140 3 trans-1,2-Dichloroethene ug/L ND 20 20 25.4 24.9 127 124 60-140 2 trans- 1,3-Dichloropropene ug/L ND 20 20 22.6 22.0 113 110 60-140 3 Trichloroethene ug/L ND 20 20 24.1 23.5 121 118 60-140 2 Trichlorofluoromethane ug/L ND 20 20 25.9 24.8 129 124 60-140 4 Vinyl chloride ug/L ND 20 20 21.4 21.0 107 105 60-140 2 1,2-Dichloroethane-d4 (S) % 102 102 70-130 4-Bromofluorobenzene (S) % 100 101 70-130 Toluene-d8(S) % 99 100 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 01:22 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 37 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Rose Hill MW 11/27 Pace Project No.: 92700404 QC Batch: 816201 Analysis Method: SM 2540C-2015 QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92700404001, 92700404002, 92700404003 METHOD BLANK: 4224632 Matrix: Water Associated Lab Samples: 92700404001, 92700404002, 92700404003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Dissolved Solids mg/L ND 25.0 11/29/23 19:16 LABORATORY CONTROL SAMPLE: 4224633 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Dissolved Solids mg/L 250 236 94 90-110 SAMPLE DUPLICATE: 4224634 92700675001 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L ND ND Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 01:22 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 37 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Rose Hill MW 11/27 Pace Project No.: 92700404 QC Batch: 815883 Analysis Method: SM 9222D-2015 QC Batch Method: SM 9222D-2015 Analysis Description: 9222D Fecal Coliform(MF) -AVL Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92700404001, 92700404002, 92700404003 METHOD BLANK: 4223105 Matrix: Water Associated Lab Samples: 92700404001, 92700404002, 92700404003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Fecal Coliforms CFU/100 mL ND 1.0 11/28/23 15:16 SAMPLE DUPLICATE: 4223106 Parameter Fecal Coliforms 92700344001 Dup Units Result Result RPD Qualifiers CFU/100 mL ND ND Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 01:22 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 37 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Rose Hill MW 11/27 Pace Project No.: 92700404 QC Batch: 817976 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92700404001, 92700404002, 92700404003 METHOD BLANK: 4234025 Matrix: Water Associated Lab Samples: 92700404001, 92700404002, 92700404003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Ammonia mg/L ND 0.10 12/08/23 10:48 LABORATORY CONTROL SAMPLE: 4234026 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 5.1 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4234027 4234028 MS MSD 92701462002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L ND 5 5 5.3 5.3 104 104 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4234029 4234030 MS MSD 92701513001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L ND 5 5 4.0 3.9 80 78 90-110 2 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 01:22 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 37 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Rose Hill MW 11/27 Pace Project No.: 92700404 QC Batch: 817929 Analysis Method: EPA 351.2 Rev 2.0 1993 QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92700404001, 92700404002, 92700404003 METHOD BLANK: 4233593 Matrix: Water Associated Lab Samples: 92700404001, 92700404002, 92700404003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Kjeldahl, Total mg/L ND 0.50 12/08/23 05:07 LABORATORY CONTROL SAMPLE: 4233594 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Kjeldahl, Total mg/L 10 11.0 110 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4233595 4233596 MS MSD 92700404001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Kjeldahl, Total mg/L ND 10 10 11.5 11.2 115 112 90-110 3 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4233597 4233598 MS MSD 92700404002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Kjeldahl, Total mg/L ND 10 10 11.3 11.2 113 112 90-110 1 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 01:22 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 37 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Rose Hill MW 11/27 Pace Project No.: 92700404 QC Batch: 815591 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92700404001, 92700404002, 92700404003 METHOD BLANK: 4221749 Matrix: Water Associated Lab Samples: 92700404001, 92700404002, 92700404003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L ND 0.040 11/28/23 03:38 Nitrogen, Nitrite mg/L ND 0.040 11/28/23 03:38 LABORATORY CONTROL SAMPLE: 4221750 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 1.5 1.5 102 90-110 Nitrogen, Nitrite mg/L 1 1.0 104 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4221805 4221806 MS MSD 92700404003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L ND 1.5 1.5 1.1 1.1 76 76 90-110 1 Nitrogen, Nitrite mg/L ND 1 1 0.91 0.91 90 90 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 01:22 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 37 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Rose Hill MW 11/27 Pace Project No.: 92700404 QC Batch: 818194 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92700404001, 92700404002, 92700404003 METHOD BLANK: 4235180 Matrix: Water Associated Lab Samples: 92700404001, 92700404002, 92700404003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Phosphorus mg/L ND 0.050 12/11/2312:19 LABORATORY CONTROL SAMPLE: 4235181 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phosphorus mg/L 2.5 2.6 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4235182 4235183 MS MSD 92700404001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 0.072 2.5 2.5 2.7 2.7 104 104 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4235184 4235185 MS MSD 92700404002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L ND 2.5 2.5 2.6 2.6 103 104 90-110 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 01:22 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 37 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Rose Hill MW 11/27 Pace Project No.: 92700404 QC Batch: 818724 Analysis Method: SM 4500-CI-E-2011 QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92700404001, 92700404002, 92700404003 METHOD BLANK: 4238012 Matrix: Water Associated Lab Samples: 92700404001, 92700404002, 92700404003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 12/12/2311:47 LABORATORY CONTROL SAMPLE: 4238013 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 20.8 104 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4238014 4238015 MS MSD 92700804001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 2.2 10 10 12.6 12.6 104 104 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4238016 4238017 MS MSD 92700804002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 22.8 10 10 32.8 32.8 100 101 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 01:22 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 37 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Rose Hill MW 11/27 Pace Project No.: 92700404 QC Batch: 817029 Analysis Method: SM 531 OB-2014 QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92700404001, 92700404002, 92700404003 METHOD BLANK: 4228713 Matrix: Water Associated Lab Samples: 92700404001, 92700404002, 92700404003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Organic Carbon mg/L ND 1.0 12/04/23 23:08 LABORATORY CONTROL SAMPLE: 4228714 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Organic Carbon mg/L 25 23.9 95 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4228715 4228716 MS MSD 92701157003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Total Organic Carbon mg/L ND 25 25 23.3 23.4 93 94 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4228717 4228718 MS MSD 92700635001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Total Organic Carbon mg/L 291 25 25 305 310 54 77 90-110 2 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 01:22 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 37 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALIFIERS Project: Rose Hill MW 11/27 Pace Project No.: 92700404 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/12/2023 01:22 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 37 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Rose Hill MW 11/27 92700404 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92700404001 MW-1 92700404002 MW-2 92700404003 MW-3B 92700404001 MW-1 EPA 200.7 Rev 4.4 1994 815696 EPA 200.7 Rev 4.4 1994 815830 92700404002 MW-2 EPA 200.7 Rev 4.4 1994 815696 EPA 200.7 Rev 4.4 1994 815830 92700404003 MW-3B EPA 200.7 Rev 4.4 1994 815696 EPA 200.7 Rev 4.4 1994 815830 92700404001 MW-1 SM 6200B 817079 92700404002 MW-2 SM 6200B 817079 92700404003 MW-3B SM 6200B 817079 92700404001 MW-1 SM 2540C-2015 816201 92700404002 MW-2 SM 2540C-2015 816201 92700404003 MW-3B SM 2540C-2015 816201 92700404001 MW-1 SM 9222D-2015 815883 SM 9222D-2015 815887 92700404002 MW-2 SM 9222D-2015 815883 SM 9222D-2015 815887 92700404003 MW-3B SM 9222D-2015 815883 SM 9222D-2015 815887 92700404001 MW-1 EPA 350.1 Rev 2.0 1993 817976 92700404002 MW-2 EPA 350.1 Rev 2.0 1993 817976 92700404003 MW-3B EPA 350.1 Rev 2.0 1993 817976 92700404001 MW-1 EPA 351.2 Rev 2.0 1993 817929 EPA 351.2 Rev 2.0 1993 818118 92700404002 MW-2 EPA 351.2 Rev 2.0 1993 817929 EPA 351.2 Rev 2.0 1993 818118 92700404003 MW-3B EPA 351.2 Rev 2.0 1993 817929 EPA 351.2 Rev 2.0 1993 818118 92700404001 MW-1 EPA 353.2 Rev 2.0 1993 815591 92700404002 MW-2 EPA 353.2 Rev 2.0 1993 815591 92700404003 MW-3B EPA 353.2 Rev 2.0 1993 815591 92700404001 MW-1 EPA 365.1 Rev 2.0 1993 818194 EPA 365.1 Rev 2.0 1993 818654 92700404002 MW-2 EPA 365.1 Rev 2.0 1993 818194 EPA 365.1 Rev 2.0 1993 818654 92700404003 MW-3B EPA 365.1 Rev 2.0 1993 818194 EPA 365.1 Rev 2.0 1993 818654 92700404001 MW-1 SM 4500-CI-E-2011 818724 92700404002 MW-2 SM 4500-CI-E-2011 818724 92700404003 MW-3B SM 4500-CI-E-2011 818724 92700404001 MW-1 SM 5310B-2014 817029 92700404002 MW-2 SM 5310B-2014 817029 92700404003 MW-3B SM 5310B-2014 817029 Date: 12/12/2023 01:22 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 28 of 37 DCi# Title: ENV-FRM-HUN1-0083 02_Sample Condition Upon Receipt �Ce F11a7G15Ft:i�`-i Effective Date: 11/14/2022 8.18:30 AM Laboratory receiving samples, Asheville-W Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville❑ Atlant-17 Sample Condition Client fume: �#.92 Upon Receipt 1915 Project it: Courier: ElFed Ex UP5 Other: USPS Client l lJ ��l w 11 m 1l 1� 1 ❑ Commercial -Pace ❑ 4 82100404 Custody Seal Present? ❑Yes 4a11° Seals Intact? El Yes Id No L Packing Material: ❑ Bubble Wrap ❑ Bubble Bags None ❑ Other Thermometer: ❑ IR Gun ID: �o Type of Ice: `KWet ❑ Blue —� Correction Factor: Cooler Temp: Add/Subtract(°C) Cooler Temp Corrected (°C): Ua USDA Regulated Soil (1�0 N/A, water sample} Did samples originate in a quarantine zone within the United States: CA, NY, or SC LUMPAGV 1:i/7ArvtrLC OF?4n[rHlm�l Date/lnitlals Person Examining Contents;— Biological Tissue Frozen? ❑Yes ❑No -EF-N/A ❑ None Temp should be above freezing to 6°C ❑ Samples aot of temp criteria. Samples on ice, cooling process has begun Did samples originate from a foreign source (inter —nationally, y Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: Date/Time: Date: Project Manager SRF Review: Date: Page 29 of 37 .. .—. rnC 4 6 Mono 1 of i m 0 0 A 0 I� c v I� O ' „ � N T• v � n j N a -V 3 n a e r a n d n c = w W a ae �_ 0 ♦ K n C 4n n � ^ � .� � .� N � � 2 O N n ^n o2 N a OF IE c 0 (7 O i = a ro n = m rC C 3 Z N z n � i d a n o o 8 S — I c � it ti c A w a'- n n 3 o oEL D rt v �—i 2 c Ln U q5 L1 m m � N a ;, fl a v � o. n a p A n c 1L Q P x 6 T n 3 3 _ v o 3 3 3 3 y _ _ c Suv n _ - y fV3 m 'a v _ `c th $ o a = C N o C r A 9 c m 3 _ rD z i X X X Ammonia / Total Phosphorus X X X Chloride Fecal Coll o a a X x X n * { o S S F X X X Metals 200.7 3 3 3 A x ^_ Nitrate or Nitrite L h X X or izo w 3 _ co X X 7C TDS by 2540C 3 1 d m d y o z X X X TOC s 0 o m w -71 VOC 6200 o k w 2 oa lab Use Only 3 0 3 c r o ~ A t. c&$ 9 -�^ a M e = c OEn3'-mx . d -_V� 'a uN`na CD 3 n m zi r - � ti xx w V n 3 n — m s Page 30 of 37 Preservation non nce idemilied for sample. } � Q W, d O irk c, ro� lye � �z�m Q 91 O :. o N O °Y9 @ h TT n' J J 3 � sNa CID�i fi v- Q i> 6 C tj, o CV �. 6 V c 4 c n � ro m c• age 31 of 37 . �ce.4tk7lytiCdl Document IVanie: Field data Sheet Document Number_ F-CAR-FLD-001-rev.03 Date Issued March 8; 2019- Page: 1 of a' issuing Authority: PaceHuntersvill! office Field Data Sheet Client: r Location: 2 /� Name and Affiliation (Sampler(s): M I'-' p>? e Name and Affiliation (Inspector): +---- Well Information Well ID: �✓ Well Diameter: z•i Total Well Depth: Static Water Level: 1-0 . V I ft Haight of Water Column: 2�1' 1 1 ft Well Locked: Id Data Sheet Review: Date: l \ I' C� 1(;� By NQ / Flushmount ) Construction: V Steel/Stainless Steel) Multi Factor*: �_ $ r(Radius/12)2 x3.14 x 7.481 Casing Volume:l" 7 gallons Cal. 3 Volumes: 3� gallons Pump Intake: 11 ft Pur a Ifl€ormati©n 1 Date Purged:_/ 7 / 3 Start. s G` Parish: + - Purge Rate: Purging Method: A Total Volume Purged: (1-1' ' `' (gallons/ Is L) 5arnnpli;< Information Date Collected:_J1_/ �� / �- `i Time Collected: s ' J (am/ m Sampling Equipment Used, 1t/1 c .✓s,, ,. _ Instrument ID: Battle Type Preservation Analysis Required --- i Y, y r , L- IA.ijr i } L Field Measurernents/Dbservations Sample Temp (°C): r� '{7 Time: f `3 Turbidity (ntu): q e6y Time: ( S 0 � Diss Oxy (mg/L): Time.• j Fe 2+ mg/L-. �, Tirane Specific Cond. (uS): Time: 3�0 d Res. Cl (mg/L)/(Ag;/L): Tine: Sample pH. (s.u.); ! / Time: S`v v Odor: Time: ! s^o ReDox (MV). 169 Time: 1 spa i Appearance: �/� Tin1e: a ReDox (EH value):YSI ProPlus +200mV d 6 I other: Ajlq Tune: General/Weather Observations: 5 (sunny/cloudy/rainy) Temp. � ff) Wind Q0 (mph) Sampler Signature,,• - 7. L-` Date: Stabilization F est Diss Oxy. Spec. Cond. pH (s.u.) ReDox Turbidity ty ntu ( ) Vol -Lime remov (g allons cols Water level ft ( ) Other i1ne Temp. [Purged a { C) (mg/i) (u� mV ( ) L y�� S f 6,1 /o.a.� G7 l�.1 .7� 4L.7 rh tx.t Y-OOJ 7). i 11 •�>.Aj Page 32 of 37 Document Nance: Document Issued: March 8, 2019 Field Data Shcet Page�,,of j— 11!;aceArtalytrcal Dpcnlnv nt Number: Issueing Authority: F-CAR-FLD-001.rev.03 Pace HuntersvilteQuality Office 1 /-)-7--3 Client: !� Location: k // Project /V1 1,✓ -� Well ID: N W • J Reviewed Date and By: `jZ" 1 Stabilization Test Well Diameter Multiplication Factor' 1 0.0403 1.2 0.0913 1.625 0.1050 2 0.1630 3 0.3670 4 0.6530 1.46S0 6 S 2.6100 Time Purged Temp. (°C) Diss Dxy. (mg/L) Spec. Cond. (US) T pH (s.u.) ReDox (mV) Turbidity (ntu) Volume RemovedWater (gallons/&L) circle one level (ft) Other t.1 5 0-00 6 .I b . is 6�- s fir, l 0 1 a '70 `+, —) / `�- 16 G a , � �) —7 4-iF,9f- 6.1 U i�; • 4' lid,s� �� J� �fl. ?7 0� * d3 It�F.y G.� >~ >'67,? �4' 16Z. 11, a l -.,ra lr a�,� 1f1. did ? Ir7. 00 Page 33 of 37 b✓e4L -- aceFvta(i�Prc�t� i i Document Flame: Field data Sheet Document Munsber: F-CAR-FM-041-rev.03 Meld Data Sheet Name -and Affiliatiori (Sampler(s): Al t 1 84 C Name and Affiliation (Inspector): lf,4 Well Information Well ID: Well Diameter: I Welt Locked: Construction: Date Issued: March 802819' Page: 1 of i Issuuig Authority: Pace I-iuntersville Quality Office #: 4-1/, ! Field Data Sheet Review: Date: ` l aC� �, BY y 3'/ NO / Flushmount ) Steel/Stainless Steel) Total Well Depth: _ �� `Ft Multi Factor' , ! L 2 ["(Radius/ 12)2 x 3.14 x 70] Static Water Level: �� s" ft Casing Volume: 6 l gallons Height of Water Column:l' �- ft Cal. 3 Volumes: �• a7 04"' gallons Pump Intake: 1 ft �I.0_JV3 Puma Information Date Purged:�_L/ start: r �t U Fftiish; Ll � Purge Rate: Purging Method: -1 1 0. t Total Volume Purged: (gallons SaYn lie Information Date Collected: � � / I�/ ) 3 Time Collected: i ) {anz/ m Sampling Equipment Used: / A � - Instrument ID: y � f Bottle Type Preservation Analysis Required ;r l.Al-/ r 4�Nldv� ik4 f1 Field Measurements/Observations 3 ✓I ,)a S r I� I c y J e t 3 i/>!j4 %- j/ s I O � Sample Temp (°C): 7 Time: I ° Turbidity (ntu): �• Tinge: Diss Oxy (mg/L): ; Time: 1 1 v J Fe 2+ mg/L- AIA Time: 14/4 Specific Cond. (uS): �� c1 Time: l � � Res. Cl (mg/L)/(ug/L): i1,3 Mile: Sample pH (s,u.): 3 Time: ° 0 Odor: N° Time; ( )_ J 3 ReDox (mV): . J Time. ° ' Appearance: 'Time: 1 O ReDax (EH value):YSI ProPlus +200mV 3 4�" 5 Other: Time: General/Weather Observations: } ✓VI"J !d ( ..nri�i/cloudy/rainy) Temp. � J_ CF) Wind E ' h- (mph) Sampler Signature, )1 / t' =-- Date: =1 FpYi u.0 M•� Volume Time Temp. Diss Oxy. Spec. Cond pH (s.u.) I2eDax Turbidity (ntu) removedWater s t (gallons/ level (ft) Other Purged Cq (tng/ L) (us)/ mV (} t > 1ST �r L --P /J 4/ P 4- i U Page 34 of 37 Document Name: Fleid data Sheet Date issued: Marrh.8 ?Q19 Page: 1 of k Issuing Authority: Pace Hmitersville Quality .- l7ceAna4iticai Document t�lumber: F=CAR-CAR-0pl-rev,63 Office �Affi to n Field Data Sheet A it 1-4 11 Praiect#: Li r✓ Nance and Affiliation (Sampler(s): M ! -1 b, � Name and Affiliation (Inspector): /V4 Well Information Well ID: M I,; • 3 9 ri Well Diameter. Total Well Depth: Ft Static Water Level: S-' I d ft Height of Water Column: Y.- ft Field Data Sheet Review: I Date: � 1 j q0) j +� �� By: � C A — II Well Locked: ( YES /(NO / Flushmount) Construction. (P1" /Steel/Stainless Steel) Multi Factor*. - f 6 S [+(Radius/12)2 x 3.14 x 7.481 Casing Volume: J `f` �" gallons Cal. 3 Volumes. 3 '` Z L gallons Pump Intake: �•�� ft Purge Information. Date Purged:/ / Start: G A Finish: / ,-Purge Rate: 0d 1'- A1— Purging Method: ft., a 4, I __Total Volume Purged: 4- r ° ' (gallons/ YL) Sampling Inforn_ �ati_on Date Collected: I I / } �/ 1 Time Collected: (4n }'pm ) 1 Sampling. Equipment Used: f �' a / i Instrument ID:_ �i S 4-4- et Bottle Type Preservation Analysis Required 3 rt',-,?1- ✓N'P.2 c i ,• so ". 110)a 5 PJi A/ d3 P ,Mc TO L- d„3, I f1 4L ✓� � Field Measuremernts/Observations r P: ,v Fi 44 "V, J" Sample Temp (°C): or 0 Time: 1,; 3 o Turbidity (ntu). 0 I Time: 10 J J Diss Oxy (mg/L): ' Time: 1 j Fe 2+ mg/L: Time: Z ,, Specific Cond. (uS): / �' Time: 10 3 a Res. CI {ing/L)/(µglL): ' 7 Time: /Vo? Sample pH (s.u.): ' 7 `� Time: / `'' 3 Odor: I✓ J ,vTime: 1 3 J ReDox (mV): 7•`7 Time: / ' 30 � Ap earance: ` Time: / J 3 IieDnx (EH value):YSI ProPlus +200znV -ter116ther:er: Tune:`" _ General/Weather Observations: (sunny/cloudy/rainy) Temp. `F (OF) Wind-4-•,,- (mph) Sampler Signature: Date: ll ' Stabilization Test Volume Time Temp. Diss Oxy. Spec. • pH (s.u.) ReDox Turbidity removed Water level Other Purged (IC) (mg/L) o nd (MV) (ntu) (gallons/i�/ (ft) L 7�.� pvr L- «, + Page 35 of 37 //-,.---;,., 3 aceAfalytical i Client: Location: A Project; /tit fv Well ID: Document Name: .Field Data Sheet Document Number: F-CAR-FLD-001.rev.03 Reviewed Date and By: 'C Stabilization Test Document Issued: March 8, 2019 PagAof _+. Issu :ing Authority: Pace 1-tuntersville Quality Office Well Diameter .Multiplication Factor" 1 0.0408 1.2 0.0913 1.625 0.1030 2 0.1630 3 0.36: 0 4 0.6530 6 IA6S0 3 2.6100 Time Purged Temp. (00 Diss Ox y (mg/L) At Spec. Cond. (u5) pH (s.u.) ReDox (mV) � �' Turbidity ntu ) ! i J� r,3V Volume Removed (gallons/rids/L) circle one T u �4 Water level (ft) r. 1� Other Page 36 of 37 DC#_Title: ENV-FRM-HUN1-0083 v02_Sample Condition Upon Receipt Effective Date: 11/14/2022 8:18:30 AM *Check mark top half of box if pH and/or dechlorination is verified and Project # within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg *Bottom half of box is to list number of bottles * * *Check all unpreserved [citrates for chlorine W4## : 9270Q444 PM: UP Due Date: 12/12/23 CLIENT: 93-RPB E m a z } a a v w n. J E rry ri 9 tl a. m a Z -p a a >jc u a J E v�i N 7 M a Co a Z `a u m a J E o In D N a W a D v d = rl �-/ a CD U N x� OonO xx u m a J E N ry vi [r n co N x a u m Q J E N Z T a co o ro z a ¢ M u m a J E ry ,..� N V a co U a O z a J E ry r-I Co V a u v v am CA G LL �v a a 7 a E Q m` — r-I 7 ri t7 a N v " x a E Q a` ri T rl U a ¢ ?o > E ¢ ..� o u1 N m t7 a v T a D = .n E a ✓ - r-1 �S ri l7 a = a u i E a J E ,0 N 11 M l7 a a r Z n E Q o Q V' m l7 C z Q 0 > E �0y i I m l7 C a z O Ln N Q D > 0 H a` l7 > m c a O > �0} i C� l7 > aCL m a O > moo{ 7 3 Q� l7 C ¢ C 0. 0 N j N a x m 'c d ra. > .M.. dC U > a z ro a Cu � « Vl E Ln N FL Ln a 0 a z a cit ul E 0 N N rs LA n o v, z m a E rY p[ M a m c D Jo E Q J 0 0 ~ l7 a ro m C u Vl E 0 N 7 l7 0 > Z 7 i E Q E may T C7 o 1Nd J N \\NJ � t I _� 4 I \N 7 -\Nfi 8 9 1D 11 12 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot N Note: Wheneverthere is a discrepancy affecting North Carolina compliance samples, a copy of this tormwill be sent to the North Carolina DENR Certititation Office (i.e. out of hold, incorrect preservative, out of temp, incorrect containers. Page 37 of 37 r)iiaFfrw Irl- F4F1A P3 nn '7 of ')