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WQ0032016_Groundwater Monitoring Report July 2023_20230826
M--59A COMPLIANCE REPORT FORM Permit:1#_WQ0032016 f5'ubmit ane eaeh inemiroring pe•iod iarith GAL 9 Jon e .) X Enter date monitoring results were Clue_ (7/31/2023 ) Will this monitoring report (GVV-59 and GW-59A) YES NO be submitted after the established due date? X Z Was any required information missing on the GW-59 report forms? YES NO X IF the answer to question 1 or 2 is "YES", fist in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need orrepair or maintenance (damaged casing, unlocked or missing cap, missing I YES NO identffication plate, area overgrown, etc.)" if rJre a+rairer is "Yrs"> contact Ilse Itegior+ai Ojjice fo+ n +icicurce. 4 Are any monitored constituents equal to or above the established standards? YES NO If the answer to question 4 is "NO", skip to section B. If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s) exceeding standards in the space provided below: 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO same constituent(s) in the same well(s) in the fast two years? if the answer to question 5 is "NO", skip to section B. If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years). MW-1: pH 6.14; Fe 0.654 MW-2: pH 5,07 MW-3: Fe 16.7 Mn 0.155 G Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES NO If the answer is "YES" a groundwater quality problem maybe occurring, CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. if the answer is "NO" monitoring wells may be improperly located; contact the Regional Office. f 7 Is the permittee implementing previously approved actions required by the Division involving this YES NO groundwater quality problem? If the answer to question 7 is "YES", describe those actions in the space provided below. If the answer to question 7 is "NO" contact the Regional Office within 90 days: an evaluation may 6e required to determine the im,cact the waste disposal system is having at the review and corn fiance boundaries surrounding this facility. Failure to do so may subject the permitte_e_to a Notice of Violation, fines, and/or penalties. S The person completing this portion (GW-59A) of the monitoring report should sign below and submit this form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form. I hereby acknowledge that the above information was evaluated and the information submitted in this report (Compliance Report GIB-59A) is true and complete to the best of my knowledge. /&LVJI-- 2(.-2-3 Signature n ermittee (or Authorized Agent) hate CW-g3.A ]V i2003 SUBMIT FORM ON YELLOW PAPFR ONI Y GROUNDWATER QUALITY MONITORING: DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES COMPLIANCE REPORT FORM INFORMATION PROCESSING UNIT 1617 MAIL SERVICE CENTER, RALEIGH, NC 27599-1617 FACILITY INFORMATION Please Print Cfearly or Type PERMIT Number: Expiration Date: sl3012028 Facility Name: Rose Hill Plantation Development, LLC Non -Discharge UIC NPDES Other WQD032016 Permit Name (if different): Facility Address: 3041 New Leicester Highway TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery Leicester NC 28748 County Buncombe ❑ Spray Field ❑ Remediation: Contact Person: Bob Barr Telephone#: (828) 251-1900 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Well # 1(MW A on GW-1 b) No. of wells to be sampled: 3 ❑ Water Source Heat Pump ❑■ Other: Surface Irrigation (from Permit( SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): Well # 1 Upgradient Date sample collected: 711B/2023 FIELD ANALYSES: WAS Well Depth: 69 ft. Well Diameter: 2 in. pH 00400: 6.14 units Temp. 00010; 24.2 °C DRY at Depth to Water Level 62546: 38.8 p ft. below measuring point Screened Interval: 49 ft. to 69 ft. Spec. Cond. 000s4: 49.8 N Mhos time of Measuring Point is 2.5 ft. above land surface Relative M.P. Elevation: ft. Odor aa0a5: None sampling,check Volume of water pumped/bailed before sampling: gallons Appearance Clear here:❑ Samples for metals were collected unfiltered: ■❑ YES ❑ NO and field acidified: ❑■ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 81212023 Laboratory Name: Pace Analytical Certification No. 40 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N o0615 <0.040 mg1L Pb -Lead o1051 <5.0 ug/L Coliform: MF Fecal 31616 <1 /100mL Nitrate (NO3) aS N 00620 <0.040 mg/L Zn - Zinc 01092 <10,0 mg/L Coliform: MF Total 31504 1104mL Phosphorus: Total as P 00665 n.066 mg/L (Note: use MPN method for highly turbid Samples( Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 703oo 49.0 mg/L Al - Aluminum olto5 mg/L pH (Lab) 00403 units Ba - Barium 01007 23.2 ug/L TOC oc6so <1.0 mg/L Ca - Calcium ooa16 mg/L Chloride 00940 1.0 mg/L Cd - Cadmium 01027 ug/L Arsenic 01CO2 <10.0 ug1L Chromium: Total 01034 <5.0 ug/L Grease and OiIS 00552 mg/L Cu - Copper 01042 <5.0 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 uglL Fe - Iron 01045 654 ug1L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mglL Hg - Mercury 719oo ug1L Lab Report Attached? ❑ Yes (1) © No (0) Specific Conductance 000ss tcMhos K - Potassium 00937 mglL VOC 7873 method # SM 6200E Total Ammonia o0s1a <0.10 mg/L Mg - Magnesium 00927 mg1L method # (Ammonia Nitrogen; NH, as N; Ammonia Nilrooen,Total) Mn - Manganese 01055 14.5 g uglL ,method # TKN as N 00625 mglL Ni - Nickel 01067 uglL method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs� mg/L Eff lue nt Total VOCs: mg/L VOC Removal% I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a OWR-certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. Robert P. Barr 1 Authorized Agent Permittee (or Authorized Agent) Name and Title - Please print or type Signature of GW-59 Rev.06-07-2018 (or Authorized Agent) (Date) SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM Facility Name: Rose Hill Plantation Development, LLC Permit Name (if different): Facility Address: 3041 New Leicester Highway Leicester" NC 28748 ontact Person: Bob Barr tell Location/Site Name: Weil # 2(MW B on GW-1h) Clearfy or Type County Buncombe Telephone#: (828) 251-1900 No. of wells to be sampled: 3 DEPARTMENT OF ENVIRONMENTAL QUALITY - DIY. OF WATER RESOURCI INFORMATION PROCESSING UNIT 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699.1617 3ERMIT Number: Expiration Date: 613012028 Von -Discharge UIC VPDES Other 1N00032016 TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑ Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑■ Other: Surface Irrigation uninr ui�� umr-wnii I wry If WELL WELL 10 NUMBER (from Permit): Well # 2 downgradient Date sample collected: 7/18/2023 FIELD ANALYSES: WAS Well Depth: 30 ft. Well Diameter: 2 in. H ooaoo: 5.07 19.4 p units Temp. a0o10 °C DRY at Depth to Water Level 82546: 13.56 ft. below measuring point Screened Interval: 10 ft. to 30 ft. Spec. Cond. 00094: 23.7 µMhos time of Measuring Point is 2.5 ft. above land surface Relative M.P. Elevation: ft. � Odor 00085: None sampling,check Volume of water pumped/bailed before sampling: gallons Appearance Clear here: for metals were collected unfiltered: © YES ❑ NO and field acidified:❑!. YES ❑ NO ❑Samples ate sample analyzed: 812/2023 Laboratory Name: Pace Analytical Certification Ne. 40 IRAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N oo615 e0.040 mg/L Pb -Lead 01c51 1.1 ugi Coliform: MF Fecal 31615 <1.0 /100mL Nitrate (NO3) as N 00620 0.48 mg/L Zn -Zinc o1e92 10.0 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P oo665 <0.050 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): solved Salids:Total 7030a <25-0 mg/L Al - Aluminum o11o5 mglL PH (Lab) 00403 units Ba - Barium 01007 28.1 ug1L TOC 00680 <1.0 mg1L Ca - Calcium 00916 mg/L Chloride o094a 2.5 mg1L Cd - Cadmium 01027 uglL Arsenic 01002 <10.0 uglL Chromium: Total 01034 <5.0 ugi Grease and Oils 00552 mg/L Cu - Copper 01042 <5.0 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ugi Fe - Iron 01045 239 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug1L Lab Report Attached? ❑ Yes (1) ❑■ No (0) ecific Conductance 00095 µMhos K -Potassium 00937 mg/L VOC 7873 method # SM 6200E Total Ammonia 00610 <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Arnmonia Nitrogen, NH3 as N', Ammonia !Nitrogen, Total) Mn - Manganese o1055 <10.0 uglL ,method # TKN as N 00525 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mglL Fffluent Total VOCs: mg/L VOC Removal% GW-59 Rev.06-07-2018 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM FACILITY INFORMATION Please Pnnt Facility Name: Rose Hill Plantation Development, LLC Permit Name (if different): Facility Address: 3041 New Leicester Highway Leicester """ NC 28748 ontact Person: Bob Barr fell Location/Site Name: Well # 3 cr Type County Buncombe Telephone#: (828) 251-1900 No. of wells to be sampled: 3 DEPARTMENT OF ENVIRONMENTAL. QUALITY . DIV. OF WATER RESOURC INFORMATION PROCESSING UNIT 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 PERMIT Number: Expiration Date: 6130/2028 Non -Discharge UIC NPDES Other lNQ10032016 TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑ Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge WELL ID NUMBER (from Permit): Well # 3 Date sample collected: 7/18/2023 Well Depth: 14 €t. Well Diameter: 2 in, Depth to Water Level 82546: 5.45 ft. below measuring point Screened Interval: 4 ft. to 14 ft. Measuring Point is 0 ft. above land surface Relative M.P. Elevation: ft. Volume of water pumped/bailed before sampling: gallons Samples for metals were collected unfiltered: *YES ❑ NO and field acidified 0 YES ❑ NO I AQn0A-rr1OV IAICf1OKIIA-rinKi Date sample analyzed: 812/2023 Laboratory Name: Pace Analytical PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg1L Nitrite (NO2) as N 00615 <0.040 Coliform: MF Fecal 31616 <1.D /100mL Nitrate (NO.) as N 00520 <0.040 Coliform: MF Total 31504 1100mL Phosphorus: Total as P omss 0.86 (Note, Use MPN method for highly turbid samples) Orthophosphate 70507 )issolved Solids:Total 70300 91.0 mg/L Al - Aluminum o11a5 PH (Lab) 00403 units Ba - Barium o1007 19.9 TOC oo680 <1 A mg/L Ca - Calcium oo91s Chloride 00940 3.5 mg/L Cd - Cadmium 01027 Arsenic 01002 <10.0 ug1L Chromium: Total 01034 <5.0 Grease and Oils 00552 mg/L Cu - Copper 01042 <5.0 Phenol 32730 uglL Fe - Iron 01045 16700 Sulfate 00945 mg/L Hg - Mercury 71900 Specific Conductance ooe95 µMhos K - Potassium 0D937 Total Ammonia 00610 <0.10 mg/L Mg - Magnesium 00927 (Ammonia Nitrogen; NH, as N: Ammonia Nitrogen, Total) Mn -Manganese o1as5 551 TKN as N 00625 mg/L Ni - Nickel 01067 mglL ri mg1L mg/L mg/L ug/L mg/L ug1L uglL mglL uglL ug/L mg/L mg/L ug/L ug/L ❑ Water Source Heat Pump ❑■ Other: Surface Irrigation FIELD ANALYSES: PH 00400_ 6.54 units Temp. 00010: 24.9 Spec. Cond. 00004: 108,16 µMhos Odor 00085: None Appearance Clear Pb - Lead o1os1 <5.0 Zn - Zinc 01092 <10.0 Certification No. 40 ug1L mg/L If WELL WAS oC DRY at time of sampling, check here:❑ Other (Specify Compounds and Concentration Units): ORGANICS: (by GC, GC/MS, HPLC) (Specify test and method #. ATTACH LAB REPORT.) Lab Report Attached? ❑ Yes (1) 0 No (0) VOC 7873 method # SM 6200E method # method # method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Robert P. Barr 1 Authorized Agent Permlftee (or Authorized Agent) Name and Title - Please print or GW 59 Rev. D6-07-2018 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: ROSE HILL MW 7/18/23 Pace Project No.: 92677958 Sample: MWA Lab ID: 92677958001 Collected: 07/18/23 13:25 Received: 07/18/23 15:50 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 07/18/23 13:25 Collected By M.Swann 1 07/18/23 13:25 Collected Date 7/18/23 1 07/18/23 13:25 Collected Time 13:25 1 07/18/23 13:25 pH 6.14 Std. Units 1 07/18/23 13:25 Temperature 24.2 deg C 1 07/18/23 13:25 Static Water Level 38.80 feet 1 07/18/23 13:25 Specific Conductance 49.8 umhos/cm 1 07/18/23 13:25 Oxygen, Dissolved 3.90 mg/L 1 07/18/23 13:25 7782-44-7 Total Well Depth 69.0 feet 1 07/18/23 13:25 REDOX 129.9 my 1 07/18/23 13:25 Turbidity 9.45 NTU 1 07/18/23 13:25 Odor None 1 07/18/23 13:25 Appearance Clear 1 07/18/23 13:25 200.8 ATL ICPMS, NC Analytical Method: EPA 200.8 Preparation Method: EPA 200.8 Pace Analytical Services - Peachtree Corners, GA Arsenic ND ug/L 5.0 1 07/29/2310:22 07/31/2317:16 7440-38-2 Barium 23.2 ug/L 5.0 1 07/29/2310:22 07/31/2317:16 7440-39-3 Chromium ND ug/L 5.0 1 07/29/2310:22 07/31/2317:16 7440-47-3 Copper ND ug/L 5.0 1 07/29/2310:22 07/31/2317:16 7440-50-8 Iron 654 ug/L 40.0 1 07/29/2310:22 07/31/2317:16 7439-89-6 Lead ND ug/L 1.0 1 07/29/2310:22 07/31/2317:16 7439-92-1 Manganese 14.5 ug/L 10.0 1 07/29/2310:22 07/31/2317:16 7439-96-5 Zinc ND ug/L 10.0 1 07/29/2310:22 07/31/2317:16 7440-66-6 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids 49.0 mg/L 25.0 1 07/20/23 10:27 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services -Asheville Fecal Coliforms ND CFU/100 mL 1.0 1 07/18/23 16:35 07/19/23 15:04 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 1 07/29/23 12:50 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate ND mg/L 0.040 1 07/19/23 00:11 14797-55-8 Nitrogen, Nitrite ND mg/L 0.040 1 07/19/23 00:11 14797-65-0 Date: 08/02/2023 11:46 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 29 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: ROSE HILL MW 7/18/23 Pace Project No.: 92677958 Sample: MW-1 Lab ID: 92677958001 Collected: 07/18/23 13:25 Received: 07/18/23 15:50 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus 0.066 mg/L 0.050 1 07/28/2315:45 07/31/2312:01 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 1.0 mg/L 1.0 1 07/25/23 22:00 16887-00-6 531013 TOC Analytical Method: SM 531 OB-2014 Pace Analytical Services -Asheville Total Organic Carbon ND mg/L 1.0 1 07/20/23 23:28 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/02/2023 11:46 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 29 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: ROSE HILL MW 7/18/23 Pace Project No.: 92677958 Sample: MW-2 Lab ID: 92677958002 Collected: 07/18/23 10:15 Received: 07/18/23 15:50 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 07/18/23 10:20 Collected By M.Swann 1 07/18/23 10:20 Collected Date 7/18/23 1 07/18/23 10:20 Collected Time 10:20 1 07/18/23 10:20 pH 5.07 Std. Units 1 07/18/23 10:20 Temperature 19.4 deg C 1 07/18/23 10:20 Static Water Level 13.56 feet 1 07/18/23 10:20 Specific Conductance 23.7 umhos/cm 1 07/18/23 10:20 Oxygen, Dissolved 4.58 mg/L 1 07/18/23 10:20 7782-44-7 Total Well Depth 30 feet 1 07/18/23 10:20 REDOX 139.6 my 1 07/18/23 10:20 Turbidity 6.27 NTU 1 07/18/23 10:20 Odor None 1 07/18/23 10:20 Appearance Clear 1 07/18/23 10:20 200.8 ATL ICPMS, NC Analytical Method: EPA 200.8 Preparation Method: EPA 200.8 Pace Analytical Services - Peachtree Corners, GA Arsenic ND ug/L 5.0 1 07/29/2310:22 07/31/2317:37 7440-38-2 Barium 28.1 ug/L 5.0 1 07/29/2310:22 07/31/2317:37 7440-39-3 Chromium ND ug/L 5.0 1 07/29/2310:22 07/31/2317:37 7440-47-3 Copper ND ug/L 5.0 1 07/29/2310:22 07/31/2317:37 7440-50-8 Iron 239 ug/L 40.0 1 07/29/2310:22 07/31/2317:37 7439-89-6 Lead 1.1 ug/L 1.0 1 07/29/2310:22 07/31/2317:37 7439-92-1 Manganese ND ug/L 10.0 1 07/29/2310:22 07/31/2317:37 7439-96-5 Zinc 10.0 ug/L 10.0 1 07/29/2310:22 07/31/2317:37 7440-66-6 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids ND mg/L 25.0 1 07/20/23 10:27 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services -Asheville Fecal Coliforms ND CFU/100 mL 1.0 1 07/18/23 16:35 07/19/23 15:04 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 1 07/29/23 12:52 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 0.48 mg/L 0.040 1 07/19/23 00:10 14797-55-8 Nitrogen, Nitrite ND mg/L 0.040 1 07/19/23 00:10 14797-65-0 Date: 08/02/2023 11:46 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 29 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: ROSE HILL MW 7/18/23 Pace Project No.: 92677958 Sample: MW-2 Lab ID: 92677958002 Collected: 07/18/23 10:15 Received: 07/18/23 15:50 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus ND mg/L 0.050 1 07/28/2315:45 07/31/2312:02 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 2.5 mg/L 1.0 1 07/25/23 22:01 16887-00-6 531013 TOC Analytical Method: SM 531 OB-2014 Pace Analytical Services -Asheville Total Organic Carbon ND mg/L 1.0 1 07/20/23 23:48 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/02/2023 11:46 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 29 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: ROSE HILL MW 7/18/23 Pace Project No.: 92677958 Sample: MW-313 Lab ID: 92677958003 Collected: 07/18/23 14:55 Received: 07/18/23 15:50 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 07/18/23 14:55 Collected By M.Swann 1 07/18/23 14:55 Collected Date 7/18/23 1 07/18/23 14:55 Collected Time 14:55 1 07/18/23 14:55 pH 6.54 Std. Units 1 07/18/23 14:55 Temperature 24.9 deg C 1 07/18/23 14:55 Static Water Level 5.45 feet 1 07/18/23 14:55 Specific Conductance 108.6 umhos/cm 1 07/18/23 14:55 Oxygen, Dissolved 0.23 mg/L 1 07/18/23 14:55 7782-44-7 Total Well Depth 14.00 feet 1 07/18/23 14:55 REDOX 17.3 my 1 07/18/23 14:55 Turbidity 9.19 NTU 1 07/18/23 14:55 Odor None 1 07/18/23 14:55 Appearance Clear 1 07/18/23 14:55 200.8 ATL ICPMS, NC Analytical Method: EPA 200.8 Preparation Method: EPA 200.8 Pace Analytical Services - Peachtree Corners, GA Arsenic ND ug/L 5.0 1 07/29/2310:22 07/31/2317:41 7440-38-2 Barium 19.9 ug/L 5.0 1 07/29/2310:22 07/31/2317:41 7440-39-3 Chromium ND ug/L 5.0 1 07/29/2310:22 07/31/2317:41 7440-47-3 Copper ND ug/L 5.0 1 07/29/2310:22 07/31/2317:41 7440-50-8 Iron 16700 ug/L 400 10 07/29/2310:22 08/01/2314:31 7439-89-6 Lead ND ug/L 1.0 1 07/29/2310:22 07/31/2317:41 7439-92-1 Manganese 551 ug/L 10.0 1 07/29/2310:22 07/31/2317:41 7439-96-5 Zinc ND ug/L 10.0 1 07/29/2310:22 07/31/2317:41 7440-66-6 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids 91.0 mg/L 25.0 1 07/20/23 10:27 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services -Asheville Fecal Coliforms ND CFU/100 mL 1.0 1 07/18/23 16:35 07/19/23 15:04 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 1 07/29/23 12:53 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate ND mg/L 0.040 1 07/19/23 00:12 14797-55-8 Nitrogen, Nitrite ND mg/L 0.040 1 07/19/23 00:12 14797-65-0 Date: 08/02/2023 11:46 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 29 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: ROSE HILL MW 7/18/23 Pace Project No.: 92677958 Sample: MW-313 Lab ID: 92677958003 Collected: 07/18/23 14:55 Received: 07/18/23 15:50 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus 0.86 mg/L 0.050 1 07/28/2315:45 07/31/2312:03 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 3.5 mg/L 1.0 1 07/25/23 22:01 16887-00-6 531013 TOC Analytical Method: SM 531 OB-2014 Pace Analytical Services -Asheville Total Organic Carbon ND mg/L 1.0 1 07/21/23 00:06 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/02/2023 11:46 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 29 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALIFIERS Project: ROSE HILL MW 7/18/23 Pace Project No.: 92677958 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/02/2023 11:46 AM without the written consent of Pace Analytical Services, LLC. Page 19 of 29 N G 10 cc V M VI A W A7 ITEM # a m c D 0 n W N @ G N �-0 s om 3 N N w A r a x@ n Cr 4 Y w 7�7 N 3 r� 3 0 w o nwi O A O N 3 n w 'w : r 3 c'i Cr Q rn 2 a x e O GI � N m N � a N aapgowygsoM g� a g �. C w' u�_ o$ A N � 3 6 4 V U 'a C] .Zl 00 Vl � n N Q. z1 MATRIX CCOE (see valid modes W lefl) # Q o ! C @ 7 SAMPLE TYPE (G-GRAB C=COMP) o 2 s m C N O O D = y a m _ F 1 m ti Z r i M as m Y C t=i cv � -� m m ❑ y r 0 m °"� A 1 %V OCP n to ,v r� ~ m L� ' M 0 O A Lr n m y o 0 SAMPLE TEMP AT COLLECTION c` s.� C. #OF CONTAINERS n n n a 11 y fTl '-� •> r• Q as m n 0 w Unpreserved m@@ 3 v p 1 1 f m 2 — a m m o R1 O H2SO4 > HNO3 HCI rsay NaOH o C 7 Na2S2O3 CD m a °? 6'Z,�_ Methanol M y —i Others n YIN Analyses Test (3 m t9 x x x TOC a g x x I x Chloride m m = � m fD x x x Fecal Cali Q c n p y rt a nx x x Ammonia 1 Total Phosphoru °» 3 n 0 x x x Nitrate or Nitrite D v n J o n - 3 O x x x TD$ 6y 254QC m c �} iD x x x 2GO.7 iCP Metals a r m a TEMP in C to rn Residual Chlorine (YJN) m e e �" n Recelved on y Ice y (Y!N) d unto y a Cooler 2 Samples 1In (Y/N( awl Page 23 of 29 Date Issued November 27, 2018 ➢omment Name: Field data Sheet page: 1 of 22, B y Issuing Authority Paa kinntersaille Quality Docment Number: F-CAR-FLD-001-rev.02 - Office Field Data Sheet ` Client. Q ® Location: Rog. c r Project #: Name and Affiliation (Sampler(s):J Field Data Sheet Review: Name and Affiliation (Inspector): 1)�0 ! f 1 D BY Date: r j d� .� Well Information Well ID: /-vl W/ Well Locked: NO) Well Diameter: Construction: teel/Stainless Steel) Total Well Depth: �� `� ft MultiFactor*: 1� [(Radius/12)2 x 3 I4 x 7.48] Static Wafer Level: r v' ft. Casing Volume: t 9 0 G gallons Height of Water Column 3 `� ft Cal. 3 Volumes: I� gallons Pump Intake: L' g a Information 7 Date Puro / d:� / Start: ,P Finish: f � 1 E a Purge Rate: / a a ,A, r- M ! Purging Method: P4 ° •- so / Total Volume Purged: 7 gallonsl-") ` Sant Iin lnfclr�lation Date Collected: /-__ Time Collected: 3 A (arn/ Sampling Equipment Used: �`'' ✓ i : , Lstrument 1D:� L Bottle Type Preservation Analysis Required P J a-i r E U:/r'2, ' �J I. Lf — A-,,), 1 ptr�1-fr 1 Field measure m arts Observations r Sample Temp (°C):_ ` . a� .--_Time: ) � }.� Turbidity (ntu): Tune: Dins DxY (mS/L)- v Time Specific Cand. (u5): 1,' Time: h- Ras. Cl (mg/Ly(µg/L): Time: Sample pH (s.u.)_ r / Time: ) �� .r Odor: A1: .1 J �— Time: ReDox (mV): �' S' Time: k� Appearance: t ReDox'(EH value):YSIProPlus+200rnV `3.c4'S Other: tee: Genexal/�Veather Observations: � �`'�'' '4 � cloudy/rainy) Temp {°F) Windy (mph) Sampler Signature: --�Date:. '? 1160.�/!.A.[l (16A VAA A4u� Time Temp. Diss Oxy. Spec. Cond. pH (s.u.) ReDox Turbidity tY Volume removed Water Other Purged o C) { (mgJLj (U) ) (ntu} (gfallonsr� level (ft) ( / {(>nV/ 1.7uft l tr/ i ti.a rii��i•.S CJ i�t� 5�.�►J L' -2`I So.� b / � j�3.7 iu�7.�' e7?;} fCr.Cy h��� O�14 �Q _�:� i• �3 Page 24 of 29 client: Location; Project: Well I D: Reviewed Date and'!By: Stabilization Test J Document Name: Document Issued: November 27,2018 Field ield Data Sheet Page �of Document Number: fssueing Authority; F-CAR—FLD-001.rev-02 pace HurLtersvifle Quality Office 2 4 L46801 -lot Time Purged T6..1-hp, (00 DNS GXY, (mg/L) Spec, Cond. (us) PH ReDox (mV) Turbidity (n'tu) VOIUMeRem ved' . I IS) (gallons ern circle one water level other OV L�r 15 A(-6 q 0 J— '44 )k)� x1a 03 0,4, r 4; 1'00 fl;— N -o 91 Page 25 of 29 J� Datelssued Noveaiber 27,2018 Document Name: Field data Sheet page. 1 of:+ �'�.• Issuiatg ,Authacitq: Pace Fluntersviile Quality Document Nnmbes: F-CAR-FLD-001-rev.02 pffiCe Name and Affiliation (Sampler(s): M?4.e Name and Affiliation (inspector): Well Infomatian Well ID: M r✓ Well Diameter: r Total Well Depth_ :3 01 tx', °r• ft Static Water Level: 3 . ft. Height of Water Column: A.ft Well Locked: Construction: dd Data Sheet Review: Date:-11 NO) el/Stairdess Steel) Multi Factor*: d- ["(Radius/12)2.3.14 z T181 Casing Volume: gallons Cal, 3 Volumes: I " `ti ! gallons Pump Intake: I— ft Purse Lnfornla.tion Date Purged: 1 1 �_ Start :1�---- Finish: tl f Purge Rate: 1 is d Purging Method: c• i Totai Volume Purged: 100I2 (gallons/ Sam Lin infomation 7 j / 'Time Collected: 10 `L" Cam)Pm) Date Collected: / Sampling Equipment Used: L '+ / E le lnstrument Pottle Type Preservation Analysis Required dt 4z =P 1. any .fV1� r 170 _ Observations _ LL JJ '6 ►� A-i7 , f 1 o L Field Meastuene ?Li �, v �' • Time: Sample Temp (q: r `F' Time: (0 Turbidity (ntu): � J' � Dins Oxy {mg/ 4Time: J Fe 2y& m -�— E Specific Cbnd. (6): ._7 Time: Z 12 Res. Q (rng/L)/(µg/L):_ Time Sample pH (s,u.): _.— ��. D � —Time: } d_. Odor: Al I' e- Time: ReDox (mV): h `l, (, Time: �- Appearance: b(�..✓._.Time: r +� ReDox(EH value):YSI ProPlus+200mV_�, - �� Other: General/weather Observations: 1 i�✓tat ! ~ �9 `� / .�c%n%�S _ �,Aq�4_1 urtnY/cl ud airty) Tempt (°F) Wind D' 1 (mph) Sampler Signatur_: _Date: $talt4117ACt" Tact Time Te1i1 . p Diss Ox . Y Spec. Cond, T , i s u p _ ( ) ReDox Turbidity Volume removed Water Ocher Purged ( q (mg/L) ( ) (MV`) (ntu) (gallons level (ft) � � 1 67 �J� j '� ii `� c.�Y ��y���qT �,!`` �//y' �7 ��] ��/• `i 5I 7 j Page 26 of 29 `7 - i ?,- )- 3 Document Name: Field Data Sheet Document Number: F-CAR—KD-001,rev.D2 Client: Location:— -4 V, c Project: Well I D: A RevieWed Date and By: stabilization Test M - R 'JO Document pw-f Issueijlg katbority; Pace -Huntosvi4! Quality office 4 Time purged Td.6p. ("C) Diss Dxy, (mg/L) Spec. Cond. (us) pH (s.u.) Volume Rernoved' Turbidity Water level Other ReDox (mV) (ntu) circle one e 7 19, Mc, 0 iD I J— i's, IQ Page 27 of 29 ova' Document blame: Field data Sheet I —Da telssued Novembev27,2M$ pa : 1 of 2- x7Wc-o w)*eiy - Document ]Number: F-CAR-FLD-001-rev.02 Issuing Anf}torlty Pace Huntersvit[e Quality office 6 Field Data Sheet E4Z # ff Pro'1ect #: Name and Affiliation (Sampler(s):_ /WA P'�C'�—' Name and Affiliation (Inspector): Inf Well ormation WellID: Well Diameter: ' Total Well Depth: �� ' `� ft Static Water Level: ' Lf-'—.ft Height of Wat.-r Column • s ` 1 ft Well Locked: Constructions Field Data Sheet Review: bate: / NO) (rQteel/Stainless Steel) Multi Factor*: r ( Ii l (rtadius/12)2,t3.14x7.481 Casing Volume: �i3 6s gallons Cal. 3 Volumes: r ' gallons Pump Intake: Pnrae Information Date Purb d: / 1 7 / Start: f � Firdsh: r �" Purge Rate:' n,/p ,1 -7" / r Purging Method _ .S.f� I f i- Total Volume Purged: (gaL1a Imis) Salktpl7llg_IRfE34'rl�atiOR � Date Collected: Time Collected: 1 ' (am6?6 f J- yF Sampling Equipment Used: / s �• T-istrument ID: y S Bottle Type Preservation Analysis Requited t �c7 - lU„ 11"4 ��cw Field Measurerner!ts Observations `f' • Time: Jr ty ( ) �~ Sample Temp. (°C): �}� Turbidity ntu : 9 Time: Diss 0xy (mg/L): Or L 3 Time: Vf�_Fe 2+ mg/L: Specific Cond. (uS): (0 � _ _. Time: �Res. Cl (mg/Ly(µg/L): — Time:- Sample pH (s.u.): 6 �'` Time: ` �~ Odor: N� Time: r' ReDox (mV): 1 '� Time: �Y`s��" A earance: ��1 Time: ReDox - (EH value):YSI ProPlus +200mV--- General/Weather Observations, S 2 /cloudy/rainy) Temp.f CF) Wind0- J'~ (mph) Sampler Signattu Date: Stabilization Test Time Purged Temp. (C) Diss Oxy. (mg/I) Spec, { d 19 pH (s.u.) ReDox (mV) Turbidity (rota) Volume (o-remov ,,��,V. vlevel (ft) Other l L• •t „� J(� �� ^ V �J `�riir /�• 71 Page 28 of 29 !' .1 L` C Jx2- /?/ c- t -7 - IG -- K Document Name: Document Issued: November 27, 2018 Field Data Sheet Psgd of _2- Dacummt Number; Issueing Authority: F-CAR-FLD-001.rev.02 face ?iuntetsvoe Quality Office Client: Location: J� t Project: /1-7 Weil ID: Reviewed Date and By:+ Stabilization Test { i+l'�iEflZ ^:1a 1-2 1.423 161,70 Time Purged TEvr p. (°C) Diss Oxy, (mg/L) Spec. Cond. (US) pH (s.u.) ReDox (mV) Turbidity (n'tu] Volume Rernoved (gallonslmis) circle one Water level ( � Other Boa;, Page 29 of 29 ceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 August 02, 2023 Kimber Reese RPB Systems Inc. P.O. Box 1325 Asheville, NC 28802 RE: Project: ROSE HILL MW 7/18/23 Pace Project No.: 92677958 Dear Kimber Reese: Enclosed are the analytical results for sample(s) received by the laboratory on July 18, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte • Pace Analytical Services - Peachtree Corners, GA If you have any questions concerning this report, please feel free to contact me. Sincerely, Lord Patton lorri.patton@pacelabs.com 1(828)254-7176 Project Manager Enclosures cc: Mr. Robert Barr, RPB Systems Inc. Ms. Liz Barr, RPB Systems Inc. Lord Patton REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 29