WQ0002708_Monitoring - 11-2023_20231220

Monitoring Report Submittal
Permit Number#*
Name of Facility:*
Month: * November
Report Information
Type *
GW-59
Confirmation Email Address:
Name of Submitter: *
Signature:
Date of submittal:
Initial Review
WQ0002708
Wrenn Road WTF
Year:* 2023
Upload Document*
November 2023 WQ0002708 GW59+VOC.pdf 5.98MB
PDF Only
Please upload one PDF containing all applicable monitoring reports
(i.e., NDMR, NDAR-1, NDAR-2, NDMLR, GW-59).
[e-mail]
Emily Fentress
Reviewer: Wanda.Gerald
12/20/2023
This will be filled in automatically

Is the project number correct?* W00002708
Is the monitoring report accepted?* Yes NO
Regional Office* Raleigh
Reviewer: _anonymous
Review Date: 1/3/2024

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
FACILITY INFORMATION
Facility Name: Wrenn Road Spray Irrigation Facility
Permit Name (if different):
Facility Address: 8828 Wrenn Road
Garner, NC 27529
Contact Person: Lisa Joseph
Well Location/Site Name: Wrenn Road
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
DIVISION OF WATER QUALITY -INFORMATION PROCESSING UN
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone].
PERMIT Number: Expiration Date: September 30, 2026_
Non -Discharge WO 0002708 UIC
NPDES Other
TYPE OF PERMITTED OPERATION BEING MONITOR
❑ Lagoon ❑ Remediation: Infiltration Gallery
❑x Spray Field ❑ Remediation:
❑ Rotary Distributor ❑ Land Application of Sludge
❑ Water Source Heat Pump ❑ Other:
SAMPLING INFORMATION
WELL ID NUMBER (from Permit): B3 Date sample collected: 11/14/2023 FIELD ANALYSES
Well Depth: 29.54 ft. Well Diameter: _ 2_ in. pH 5.17
ft Depth to Water Level: 24.33 . below measuring point Screened Interval: 15_ft. to 30 ft. Spec. Cond.
Measuring Point is 3 ft. above land surface Relative M.P. Elevation: ft. Odor
Volume of water pumped/bailed before sampling: 4.00 gallons Appearance
County: Wake
Telephone #: [phone]
No. of wells to be sampled: 3
units Temp
77
No
Clear
Samples for metals were collected unfiltered: ❑O Yes ❑ No and field acidified: px Yes ❑ No
LABORATORY INFORMATION
(Date sample analyzed: 11/14/2023 Laboratory Name: City of Raleigh Neuse River WW La_b________
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations,
COD mg/I Nitrite (NO2) as N mg/I
Coliform: MF Fecal
<1.0 /100m1
Nitrate (NO3) as N
1.11 mg/I
Coliform: MF Total
/100ml Phosphorous: Total as P
<0.02 mg/1
(Note: Use MPN method
for highly turbid samples)
Orthophosphate
mg/I
Dissolved Solids: Total
46 mg/1
Al -Aluminum
_ mg/I
pH (when analyzed)
__ units
Ba - Barium
mg/l
TOC
<1.000 mg/I
Ca - Calcium
mg/I
Chloride
4.23 mg/I
Cd - Cadmium
mg/I
Arsenic
<0.002 mg/I
Chromium - Total
mg/I
Grease and Oils
mg/I
Cu - Copper _
_ mg/1
Phenol
mg/I
Fe - Iron
<0.010 mg/I
Sulfate
1.04 mg/I
Hg - Mercury
mg/I
Specific Conductance
_ pMhos
K - Potassium
_ mg/I
Total Ammonia
mg/l
Mg - Magnesium
mg/I
(Ammonia Nitrogen;NH3
as N; Ammonia Nitrogen, Tota
Mn - Manganese
0.003 mg/I
TKN as N
_ mg/I
Ni - Nickel
mg/I
For Remediation Systems Only (Attach Lab Reports):
Influent Total VOC's
Lisa Joseph, Resource Recovery Manager
Permittee (or Authorized Agent) Name and Title - Please print or type
GW-59 Rev. 1 /2007
If WELL
WAS
15.90 oC DRY at
pMhos time of
.sampling,
check here:
Certification No. 51.00
Pb- Lead mg/I
Zn - Zinc mg/I
Other (Specify Compunds and Concentration Units):
Acrylamide ug/L _ <0.10
ORGANICS: (by GC, GClMS, HPLC)
(Specify test and method #. ATTACH LAB REPORT.)
Report Attached? O Yes ❑ No
VOC_ , method #_ __ _ 8260D
method #
method #
method #
•/I Effluent Total VOC's:• •
port is true, accurate, and complete,and that the laboratory analytical data was produced using approved methods
s for s ibmitting false information, includinq the possibility of fines and imprisonment for knowing violations.

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
Facility Name: Wrenn Road Spray Irrigation Facility
Permit Name (if different):
Facility Address: 8828 Wrenn Road
Garner, NC 27529
Contact Person: Lisa Joseph
Well Location/Site Name: Wrenn Road
!SAMPLING INFORMATION
SUBMIT FORM ON YELLOW PAPER ONLY
originalMall DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
and 1 .. DIVISION OF WATER QUALITY -INFORMATION PROCESSING UN
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone].
PERMIT Number: Expiration Date: December 31, 2016
- Non -Discharge WQ 0002708 UIC _
NPDES Other
]TYPE OF PERMITTED OPERATION BEING MONITOR
County: Wake ❑ Lagoon ❑ Remediation: Infiltration Gallery
Telephone #: [phone] Ox Spray Field ❑ Remediation:
No. of wells to be sampled: 3 ❑ Rotary Distributor ❑ Land Application of Sludge
❑ Water Source Heat Pump ❑ Other:
'WELL ID NUMBER (from Permit):__ B8
!Well Depth: 30.45 ft.
Depth to Water Level: 24.15 ft. below measuring point
Measuring Point is 3 ft. above land surface
Volume of water pumped/bailed before sampling: 4.50 gallons
jSamples for metals were collected unfiltered: O Yes
'LABORATORY INFORMATION
Date sample collected:
Well Diameter:
Screened Interval:
Relative M.P. Elevation:
11/14/2023 FIELD ANALYSES
2 in. pH 4,95 units
15 ft. to 30 ft. Spec. Cond. 64
ft. Odor No
Appearance Clear
and field -acidified: ❑x Yes _ -❑ No
Date sample analyzed: 11/14/2023 Laboratory Name: City of Raleigh N_euse River WW Lab
:PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD mg/I Nitrite (NO2) as N mg/I
Coliform: MF Fecal <1.0 /100ml Nitrate (NO3) as N <0.40 mg/I
Coliform: MF Total /100ml Phosphorous: Total as P <0.02 mg/I
Temp
If WELL
WAS
15.80 -C DRY at
pMhos :time of
sampling,
(check here:
Certification No. 51.00
Pb - Lead mg/I
Zn - Zinc _ mg/I
(Note: Use MPN method for highly turbid samples)
(Dissolved
Orthophosphate
mg/I
Other (Specify Compunds and Concentration Units):
Solids: Total
75 mg/I
Al -Aluminum
mg/I
_Acrylamide_ <0.10
pH (when analyzed) _
units
Ba - Barium
mg/I
-
TOC
<1.000 mg/I
Ca - Calcium
mg/I
Chloride
24.75 mg/l
Cd - Cadmium
mg/I
Arsenic
<0.002 mg/I
Chromium - Total
mg/I
Grease and Oils
mg/I
Cu - Copper
___ _ mg/I
ORGANICS: (by GC, GCIMS, HPLC)
Phenol
mg/I
Fe -Iron
____0_ .015 mg/I
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate
1.02 mg/I
Hg - Mercury
mg/I
Report Attached? O Yes EI No
SP ecific Conductance
pMhos
K - Potassium
m /I
VOC , method # 8260D
Total Ammonia mg/I Mg - Magnesium
(Ammonia Nitrogen;NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese
TKN as N mg/1 Ni - Nickel -
For Remediation Systems Only (Attach Lab Reports)
Influent Total VOC's:
mg/I
Lisa Joseph, Resource _R_ ecovery Manager �✓ �- —
Permittee (or Authorized Agent) Name and Title - Please print or type Signature
GW-59 Rev. 1 /2007
method
0•58 mg/I method #
method
TotalEffluent •VOC Removal
i complete,and that the laboratory analytical data was produced using approved methods
orrriation,includinp the gossmbilitof fines and im risonment for knowing violations.
iF-iry ♦ i / /

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
FACILITY INFORMATION
Facility Name: Wrenn Road Spray Irrigation Facility
Permit Name (if different):
Facility Address: 8828 Wrenn Road
Garner, NC 27529
Contact Person: Lisa Joseph
Well Location/Site Name: Wrenn Road
SAMPLING INFORMATION
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
DIVISION OF WATER QUALITY -INFORMATION PROCESSING UN
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone:
PERMIT Number: Expiration Date: September 30, 2026
,Non -Discharge WO 0002708 UIC
NPDES Other
- TYPE OF PERMITTED OPERATION BEING MONITOR
County: Wake ❑ Lagoon ❑ Remediation: Infiltration Gallery
Telephone #: [phone] ❑x Spray Field ❑ Remediation:
No. of wells to be sampled: 3 ❑ Rotary Distributor ❑ Land Application of Sludge
❑ Water Source Heat Pump Other:
WELL ID NUMBER (from Permit): B9
Well Depth: 29•9 ft.
Depth to Water Level: 21.60 ft. below measuring point
Measuring Point is 3 ft. above land surface
Volume of water pumped/bailed before sampling: 2.75 gallons
Samples for metals were collected unfiltered: px Yes
LABORATORY INFORMATION
Date sample collected:
Well Diameter:
Screened Interval:
Relative M.P. Elevation:
11 /14/2023
2 in.
4.5 ft. to 24 ft.
ft.
❑ No and field acidified:
FIELD ANALYSES
pH 5.12 units
Spec. Cond. 132
Odor No
Appearance Clear
xp Yes -- ❑ No
Date sample analyzed:
11/14/2023
Laboratory Name:
City of Raleigh Neuse River WW Lab
PARAMETERS
NOTE: Values should reflect dissolved
and colloidal concentrations.
COD
mg/I
Nitrite (NO2) as N
mg/I
Coliform: MF Fecal
`1.0 /100ml
Nitrate (NO3) as N
4.31 mg/I
Coliform: MF Total
/100ml
Phosphorous: Total as P
<0.02 mg/I
(Note: Use MPN method for highly turbid samples)
Orthophosphate
mg/I
Dissolved Solids: Total
122 mg/I
Al -Aluminum
mg/I
pH (when analyzed)
units
Ba - Barium
mg/I
TOC
- <1.000 mg/I
Ca - Calcium
mg/I
Chloride
33.34 mg/I
Cd - Cadmium
mg/I
Arsenic
<0.002 mg/I
Chromium - Total
_ mg/I
Grease and Oils
mg/I
Cu - Copper
mg/I
Phenol
_ mg/I
Fe - Iron
0.281 mg/I
Sulfate
_ — 5.41 mg/I
Hg - Mercury
_ _ mg/I
Specific Conductance
_ pMhos
K - Potassium
mg/I
Total Ammonia
mg/I
Mg - Magnesium_
_ _ _ _ -_ _ mg/I
mo (Ammonia Nitrogen;NH3 as N; Amnia Nitrogen, Total)
Mn - Manganese
0.091 mg/1
TKN as N
mg/I
Ni - Nickel
___ _ mg/I
For Remediation Systems Only (Attach Lab Reports): Influent Total VOC's:
mg/I Effluent Total VOC's:
Lisa Joseph, Resource Recovery Manager _
Permittee (or Authorized Agent) Name and Title - Please print or type
GW-59
Temp 17.20 °C
pMhos
Certification No. 51.00
Pb - Lead mg/I
Zn - Zinc mg/I
If WELL
WAS
DRY at
time of
sampling,
jcheck here:
El
Other (Specify Compunds and Concentration Units):
Acrylamide ug/L <0.10
ORGANICS: (by GC, GC/MS, HPLC)
(Specify test and method #. ATTACH LAB REPORT.)
Report Attached? ❑x Yes p No
- _ VOC . method # 8260D
method #
method #
method #
mg/I VOC Removal %
(or Authorized Agent)
)a11, ,
(Date)

GW-59A COMPLIANCE REPORT FORM Permit # WQ0002708
(Submit one each monitoring period with GW-59 forms.)
I
Enter date monitoring results were due. (12/31/2023) Will this monitoring report (GW-59 and GW-59A) be
YES
NO
submitted after the established due date?
2
Was any required information missing on the GW-59 report forms?
YES1
NO
1F the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
YES
NO
identification plate, area overgrown, etc.)? If the ansirer is "Yes", contact the Regional Office for guidance.
4
Are any monitored constituents equal to or above the established standards?
YES
NO
If the answer to question 4 is NO" skip to section 8.
If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s)
exceeding standards in the space provided below:
*See attached
5
For the constituents identified in question 4 above, have standards been exceeded previously for the
ES
NO
same constituent(s) in the same well(s) in the last two years?
If the answer to question 5 is "NO", skip to section 8.
If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding
standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years).
*See attached
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
YES
NO
If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly
located; contact the Regional Office.
7
Is the permittee implementing previously approved actions required by the Division involving this
YES
NO
groundwater quality problem?
If the answer to question 7 is "YES", describe those actions in the space provided below.
If the answer to question 7 is "NO", contact the Regional Office within 90 days; an evaluation may be
required to determine the impact the waste disposal system is having at the review and compliance
boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation
fines, and/or penalties.
A naturall-occuning manganese baseline study was conducted to establish new manganese permit limits.
8
The person completing this portion (GW-59A) of the monitoring report should sign below and submit this
form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form.
I hereby acknowledge that the above information was evaluated and the information submitted in this
Corna ort GW-59A) is true and complete to the best of my knowledge.
10 !'
7:n4aturre
mittee ( Authorized Agent) D e
GW-59A 12/8/2003

Wrenn Road GW November 2023
B8
B9
Mn
Mn
Nov-23
0.058
0.091
Jul-23
0.041
0.047
Mar-23
0.06
0.093
AVG
0.05
0.08
All results are reported in mg/L

WayPAoint .
NALYTICAL
11 /29/2023
City of Raleigh
Robin Scudelari
8500 Battle Bridge
Raleigh, NC, 27610
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Ref: Analytical Testing
Lab Report Number: 23-320-0075
Client Project Description: Raleigh Neuse River Resource Recovery Fa
Dear Robin Scudelari:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 11/16/2023 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136
Method Update Rule May 2021) unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Si`cencerelly,,k � j%'n
f�
Terri W Cole
Laboratory Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 18

Waypointo
ANALYTICAL
449 5pringbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State
Program
Lab ID
Expiration Date
North Carolina
State Program
37735
07/31/2024
North Carolina
State Program
402
12/31/2023
South Carolina
State Program
99012
07/31/2024
South Carolina
State Program
99012
12/31/2023
Page 1 of 1 00016/23-320-0075
Page 2 of 18

Waypoint.(D
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Sample Summary Table
Report Number: 23-320-0075
Client Project Description: Raleigh Neuse River Resource Recovery Fa
Lab No Client Sample ID Matrix Date Collected Date Received
89396
Wrenn
Road
B-3
Aqueous
11/14/2023
09:25
11/16/2023
14:15
89397
Wrenn
Road
B-8
Aqueous
11/14/2023
10:50
11/16/2023
14:15
89398
Wrenn
Road
B-9
Aqueous
11/14/2023
11:50
11/16/2023
14:15
Page 3 of 18

Waypoint
NALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Client: City of Raleigh CASE NARRATIVE
Project: Raleigh Neuse River Resource Recovery Fa
Lab Report Number: 23-320-0075
Date: 11 /22/2023
Volatile Organic Compounds - GC/MS Method 8260D
Analyte: 1,2,3-Trichlorobenzene
QC Batch No: V40459/V40458
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the
batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: 2-Hexanone
QC Batch No: V40459/V40458
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the
batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: Acetone
QC Batch No: V40459/V40458
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the
batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: 1,2-Dibromo-3-chloropropane
QC Batch No: V40459/V40458
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the
batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: Naphthalene
QC Batch No: V40459/V40458
LCSD fails high. All other QC in the batch passes including the LCS. Data not affected. No further action taken.
Page 4 of 18

0
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
00015
City of Raleigh Project Raleigh Neuse River Resource Recovery Fa
Robin Scudelari Report Date : 11/29/2023
8500 Battle Bridge Information : Received : 11/16/2023
Raleigh , NC 27610
Report Number : 23-320-0075 REPORT OFANAL YSIS
Lab No : 89396 Matrix: Aqueous
Sample ID : Wrenn Road B-3 Sampled: 11/14/2023 9:25
Analytical Method: 8260D Prep Batch(es): V40458 11/20/23 09:00
Prep Method: 5030E
Test Results Units MQL DF Date / Time By Analytical
Analyzed Batch
Acetone
<5.00
pg/L
5.00
1
11/20/23 22:22
MSA
V40459
Acrolein
<5.00
pg/L
5.00
1
11/20/23 22:22
MSA
V40459
Acrylonitrile
<5.00
pg/L
5.00
1
11/20/23 22:22
MSA
V40459
Benzene
<0.500
pg/L
0.500
1
11/20/23 22:22
MSA
V40459
Bromobenzene
<0.500
pg/L
0.500
1
11/20/23 22:22
MSA
V40459
Bromochloromethane
<1.00
pg/L
1.00
1
11/20/23 22:22
MSA
V40459
Bromodichloromethane
<0.500
pg/L
0.500
1
11/20/23 22:22
MSA
V40459
Bromoform
<5.00
pg/L
5.00
1
11/20/23 22:22
MSA
V40459
Bromomethane
<1.00
pg/L
1.00
1
11/20/23 22:22
MSA
V40459
n-Butylbenzene
<1.00
pg/L
1.00
1
11/20/23 22:22
MSA
V40459
sec -Butyl benzene
<0.500
pg/L
0.500
1
11/20/23 22:22
MSA
V40459
tert-Butyl benzene
<2.00
pg/L
2.00
1
11/20/23 22:22
MSA
V40459
Carbon Disulfide
<5.00
pg/L
5.00
1
11/20/23 22:22
MSA
V40459
Carbon Tetrachloride
<0.500
pg/L
0.500
1
11/20/23 22:22
MSA
V40459
Chlorobenzene
<0.500
pg/L
0.500
1
11/20/23 22:22
MSA
V40459
Chlorodibromomethane
<0.500
pg/L
0.500
1
11/20/23 22:22
MSA
V40459
Chloroethane
<1.00
pg/L
1.00
1
11/20/23 22:22
MSA
V40459
Chloroform
<0.500
pg/L
0.500
1
11/20/23 22:22
MSA
V404S9
Chloromethane
<0.500
pg/L
0.500
1
11/20/23 22:22
MSA
V40459
2-Chlorotoluene
<0.500
pg/L
0.500
1
11/20/23 22:22
MSA
V40459
4-Chlorotoluene
<0.500
pg/L
0.500
1
11/20/23 22:22
MSA
V40459
Di -Isopropyl Ether (DIPE)
<5.00
pg/L
5.00
1
11/20/23 22:22
MSA
V40459
Qualifiers/ DF
Dilution Factor
MQL
Method Quantitation Limit
Definitions
Page 5 of 18

•n
W�ypOI■ ■�.. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
00015
City of Raleigh Project Raleigh Neuse River Resource Recovery Fa
Robin Scudelari Report Date : 11/29/2023
8500 Battle Bridge Information : Received : 11/16/2023
Raleigh , NC 27610
Report Number : 23-320-0075 REPORTOFANALYSIS
Lab No : 89396 Matrix: Aqueous
Sample ID : Wrenn Road B-3 Sampled: 11/14/2023 9:25
Analytical Method: 8260D Prep Batch(es): V40458 11/20/23 09:00
Prep Method: 5030B
Test Results Units MQL DF Date / Time By Analytical
Analyzed Batch
1,2-Dibromo-3-Chloropropane
<2.00
pg/L
2.00
1
11/20/23 22:22
MSA
V40459
1,2-Dibromoethane
<0.500
pg/L
0.500
1
11/20/23 22:22
MSA
V40459
Dibromomethane
<0.500
pg/L
0.500
1
11/20/23 22:22
MSA
V40459
1,2-Dichlorobenzene
<0.500
pg/L
0.500
1
11/20/23 22:22
MSA
V40459
1,3-Dichlorobenzene
<0.500
pg/L
0.500
1
11/20/23 22:22
MSA
V40459
1,4-Dichlorobenzene
<0.500
p9/L
0.500
1
11/20/23 22:22
MSA
V40459
Dichlorodifluoromethane
<5.00
p9/L
5.00
1
11/20/23 22:22
MSA
V40459
1,1-Dichloroethane
<0.500
p9/L
0.500
1
11/20/23 22:22
MSA
V40459
1,2-Dichloroethane
<0.500
pg/L
0.500
1
11/20/23 22:22
MSA
V40459
1,1-Dichloroethene
<0.500
pg/L
0.500
1
11/20/23 22:22
MSA
V40459
cis-1,2-Dichloroethene
<0.500
pg/L
0.500
1
11/20/23 22:22
MSA
V40459
trans- 1,2-Dichloroethene
<0.500
pg/L
0.500
1
11/20/23 22:22
MSA
V40459
1,2-Dichloropropane
<0.500
pg/L
0.500
1
11/20/23 22:22
MSA
V40459
1,3-Dichloropropane
<0.500
pg/L
0.500
1
11/20/23 22:22
MSA
V40459
2,2-Dichloropropane
<2.00
pg/L
2.00
1
11/20/23 22:22
MSA
V40459
1,1-Dichloropropene
<0.500
pg/L
0.500
1
11/20/23 22:22
MSA
V40459
cis-1,3-Dichloropropene
<0.500
pg/L
0.500
1
11/20/23 22:22
MSA
V40459
trans-1,3-Dichloropropene
<0.500
pg/L
0.500
1
11/20/23 22:22
MSA
V40459
Ethylbenzene
<0.500
pg/L
0.500
1
11/20/23 22:22
MSA
V40459
Ethyl Tertiary Butyl Ether (ETBE)
<10.0
pg/L
10.0
1
11/20/23 22:22
MSA
V40459
Hexachlorobutadiene
<2.00
pg/L
2.00
1
11/20/23 22:22
MSA
V40459
n-Hexane
<10.0
pg/L
10.0
1
11/20/23 22:22
MSA
V40459
Qualifiers/ DF Dilution Factor
MQL
Method Quantitation Limit
Definitions
Page 6 of 18

Waypointo
ANALYTICAL
00015
City of Raleigh Project
Robin Scudelari
8500 Battle Bridge Information
Raleigh , NC 27610
Report Number : 23-320-0075
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Raleigh Neuse River Resource Recovery Fa
REPORT OFANALYSIS
Report Date : 11/29/2023
Received : 11/16/2023
Lab No : 89396 Matrix: Aqueous
Sample ID : Wrenn Road B-3 Sampled: 11/14/2023 9:25
Analytical Method: 8260D Prep Batch(es): V40458 11/20/23 09:00
Prep Method: 5030E
Test Results Units MQL DF Date / Time By Analytical
Analyzed Batch
2-Hexanone
<5.00
ug/L
5.00
1
11/20/23 22:22
MSA
V40459
Isopropyl benzene
<5.00
Ug/L
5.00
1
11/20/23 22:22
MSA
V40459
4-Isopropyl toluene
<0.500
ug/L
0.500
1
11/20/23 22:22
MSA
V40459
Methyl Ethyl Ketone (MEK)
<5.00
ug/L
5.00
1
11/20/23 22:22
MSA
V40459
Methyl tert-butyl ether (MTBE)
<0.500
Ng/L
0.500
1
11/20/23 22:22
MSA
V40459
4-Methyl-2-Pentanone
<5.00
ug/L
5.00
1
11/20/23 22:22
MSA
V40459
Methylene Chloride
<1.00
ug/L
1.00
1
11/20/23 22:22
MSA
V40459
Naphthalene
<1.00
ug/L
1.00
1
11/20/23 22:22
MSA
V40459
n-Propylbenzene
<0.500
ug/L
0.500
1
11/20/23 22:22
MSA
V40459
Styrene
<0.500
ug/L
0.500
1
11/20/23 22:22
MSA
V40459
1,1,1,2-Tetrachloroethane
<0.500
ug/L
0.500
1
11/20/23 22:22
MSA
V40459
1,1,2,2-Tetrachloroethane
<0.500
ug/L
0.500
1
11/20/23 22:22
MSA
V40459
Tetrachloroethene
<0.500
ug/L
0.500
1
11/20/23 22:22
MSA
V40459
Toluene
<0.500
ug/L
0.500
1
11/20/23 22:22
MSA
V40459
1,2,3-Trichlorobenzene
<2.00
Ng/L
2.00
1
11/20/23 22:22
MSA
V40459
1,2,4-Trichlorobenzene
<1.00
Ng/L
1.00
1
11/20/23 22:22
MSA
V40459
1, 1, 1 -Trich loroethane
<0.500
Ng/L
0.500
1
11/20/23 22:22
MSA
V40459
1, 1, 2-Trichloroethane
<0.500
Ng/L
0.500
1
11/20/23 22:22
MSA
V40459
Trichloroethene
<0.500
Ng/L
0.500
1
11/20/23 22:22
MSA
V40459
Trichlorolluoromethane
<0.500
ug/L
0.500
1
11/20/23 22:22
MSA
V40459
1,2,3-Trichloropropane
<1.00
pg/L
1.00
1
11/20/23 22:22
MSA
V40459
1,3,5-Trimethylbenzene
<0.500
Ng/L
0.500
1
11/20/23 22:22
MSA
V40459
Qualifiers/ DF Dilution Factor MQL Method Quantitation Limit
Definitions
Page 7 of 18

Waypointo.
ANALYTICAL
00015
City of Raleigh Project
Robin Scudelari
8500 Battle Bridge Information
Raleigh , NC 27610
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Raleigh Neuse River Resource Recovery Fa
Report Number : 23-320-0075 REPORTOFANALYSIS
Report Date : 11/29/2023
Received : 11/16/2023
Lab No : 89396 Matrix: Aqueous
Sample ID : Wrenn Road B-3 Sampled: 11/14/2023 9:25
Analytical Method: 8260D Prep Batch(es): V40458 11/20/23 09:00
Prep Method: 5030E
Test Results Units MQL DF Date / Time By Analytical
Analyzed Batch
Vinyl Acetate
<2.00
pg/L
2.00
1
11/20/23 22:22 MSA
V40459
Vinyl Chloride
<0.500
ug/L
0.500
1
11/20/23 22:22 MSA
V40459
o-Xylene
<0.500
leg/L
0.500
1
11/20/23 22:22 MSA
V40459
m,p-Xylene
<1.00
Ug/L
1.00
1
11/20/23 22:22 MSA
V40459
Xylene (Total)
<0.500
Ng/L
0.500
1
11/20/23 22:22
V40459
Surrogate: 4-Bromofluorobenzene
101
Limits: 80-124%
1 11/20/23 22:22 MSA
V40459
Surrogate: Dibromofluoromethane
102
Limits: 75-129%
1 11/20/23 22:22 MSA
V40459
Surrogate: 1,2-Dichloroethane - d4
105
Limits: 63-136%
1 11/20/23 22:22 MSA
V40459
Surrogate: Toluene-d8
101
Limits: 77-123%
1 11/20/23 22:22 MSA
V40459
Qualifiers/ DF Dilution Factor MQL Method Quantitation Limit
Definitions
Page 8 of 18

0
Waypoint 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
00015
City of Raleigh Project Raleigh Neuse River Resource Recovery Fa
Robin Scudelari Report Date : 11/29/2023
8500 Battle Bridge Information : Received : 11/16/2023
Raleigh , NC 27610
Report Number :23-320-0075 REPORT OFANAL YSIS
Lab No : 89397
Matrix: Aqueous
Sample ID: Wrenn Road B-8
Sampled:
11/14/2023 10:50
Analytical Method: 8260D
Prep Batch(es):
V40458
11/20/23 09:00
Prep Method: 5030B
Test
Results
Units
MOL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<5.00
pg/L
5.00
1
11/20/23 22:47
MSA
V40459
Acrolein
<5.00
pg/L
5.00
1
11/20/23 22:47
MSA
V40459
Acrylonitrile
<5.00
pg/L
5.00
1
11/20/23 22:47
MSA
V40459
Benzene
<0.500
pg/L
0.500
1
11/20/23 22:47
MSA
V40459
Bromobenzene
<0.500
pg/L
0.500
1
11/20/23 22:47
MSA
V40459
Bromochloromethane
<1.00
pg/L
1.00
1
11/20/23 22:47
MSA
V40459
Bromodichloromethane
<0.500
pg/L
0.500
1
11/20/23 22:47
MSA
V40459
Bromoform
<5.00
pg/L
5.00
1
11/20/23 22:47
MSA
V40459
Bromomethane
<1.00
pg/L
1.00
1
11/20/23 22:47
MSA
V40459
n-Butylbenzene
<1.00
p9/L
1.00
1
11/20/23 22:47
MSA
V40459
sec -Butyl benzene
<0.500
pg/L
0.500
1
11/20/23 22:47
MSA
V40459
tert-Butyl benzene
<2.00
pg/L
2.00
1
11/20/23 22:47
MSA
V40459
Carbon Disulfide
<5.00
pg/L
5.00
1
11/20/23 22:47
MSA
V40459
Carbon Tetrachloride
<0.500
pg/L
0.500
1
11/20/23 22:47
MSA
V40459
Chlorobenzene
<0.500
pg/L
0.500
1
11/20/23 22:47
MSA
V40459
Chlorodibromomethane
<0.500
pg/L
0.500
1
11/20/23 22:47
MSA
V40459
Chloroethane
<1.00
pg/L
1.00
1
11/20/23 22:47
MSA
V40459
Chloroform
<0.500
pg/L
0.500
1
11/20/23 22:47
MSA
V40459
Chloromethane
<0.500
pg/L
0.500
1
11/20/23 22:47
MSA
V40459
2-Chlorotoluene
<0.500
pg/L
0.500
1
11/20/23 22:47
MSA
V40459
4-Chlorotoluene
<0.500
pg/L
0.500
1
11/20/23 22:47
MSA
V40459
Di -Isopropyl Ether (DIPE)
<5.00
pg/L
5.00
1
11/20/23 22:47
MSA
V40459
Qualifiers/ DF Dilution Factor
MQL Method Quantitation Limit
Definitions
Page 9 of 18

0
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
00015
City of Raleigh Project Raleigh Neuse River Resource Recovery Fa
Robin Scudelari Report Date : 11/29/2023
8500 Battle Bridge Information : Received : 11/16/2023
Raleigh, NC 27610
Report Number : 23-320-0075 REPORT OFANAL YSIS
Lab No : 89397
Matrix: Aqueous
Sample ID : Wrenn Road B-8
Sampled:
11/14/2023 10:50
Analytical Method: 8260D
Prep Batch(es):
V40458
11/20/23 09:00
Prep Method: 5030E
Test
Results
Units
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,2-Dibromo-3-Chloropropane
<2.00
ug/L
2.00
1
11/20/23 22:47
MSA
V40459
1,2-Dibromoethane
<0.500
ug/L
0.500
1
11/20/23 22:47
MSA
V40459
Dibromomethane
<0.500
u9/L
0.500
1
11/20/23 22:47
MSA
V40459
1,2-Dichlorobenzene
<0.500
ug/L
0.500
1
11/20/23 22:47
MSA
V40459
1,3-Dichlorobenzene
<0.500
ug/L
0.500
1
11/20/23 22:47
MSA
V40459
1,4-Dichlorobenzene
<0.500
ug/L
0.500
1
11/20/23 22:47
MSA
V40459
Dichlorodifluoromethane
<5.00
pg/L
5.00
1
11/20/23 22:47
MSA
V40459
1,1-Dichloroethane
<0.500
Ng/L
0.500
1
11/20/23 22:47
MSA
V40459
1,2-Dichloroethane
<0.500
Ng/L
0.500
1
11/20/23 22:47
MSA
V40459
1,1-Dichloroethene
<0.500
ug/L
0.500
1
11/20/23 22:47
MSA
V40459
cis- 1, 2-Dich loroethene
<0.500
u9/L
0.500
1
11/20/23 22:47
MSA
V40459
trans- 1, 2-Dichloroethene
<0.500
u9/L
0.500
1
11/20/23 22:47
MSA
V40459
1,2-Dichloropropane
<0.500
ug/L
0.500
1
11/20/23 22:47
MSA
V40459
1,3-Dichloropropane
<0.500
ug/L
0.500
1
11/20/23 22:47
MSA
V40459
2,2-Dichloropropane
<2.00
u9/L
2.00
1
11/20/23 22:47
MSA
V40459
1,1-Dichloropropene
<0.500
ug/L
0.500
1
11/20/23 22:47
MSA
V40459
cis- 1,3-Dichloropropene
<0.500
Ng/L
0.500
1
11/20/23 22:47
MSA
V40459
trans- 1, 3-Dichloropropene
<0.500
Ng/L
0.500
1
11/20/23 22:47
MSA
V40459
Ethylbenzene
<0.500
Ng/L
0.500
1
11/20/23 22:47
MSA
V40459
Ethyl Tertiary Butyl Ether (ETBE)
<10.0
Ng/L
10.0
1
11/20/23 22:47
MSA
V40459
Hexachlorobutadiene
<2.00
ug/L
2.00
1
11/20/23 22:47
MSA
V40459
n-Hexane
<10.0
ug/L
10.0
1
11/20/23 22:47
MSA
V40459
Qualifiers/ DF Dilution Factor
MQL Method Quantitation Limit
Definitions
Page 10 of 18

Waypointo
ANALYTICAL
00015
City of Raleigh Project
Robin Scudelari
8500 Battle Bridge Information
Raleigh , NC 27610
Report Number : 23-320-0075
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Raleigh Neuse River Resource Recovery Fa
REPORT OF ANAL YSIS
Report Date : 11/29/2023
Received : 11/16/2023
Lab No : 89397 Matrix: Aqueous
Sample ID: Wrenn Road B-8 Sampled: 11/14/2023 10:50
Analytical Method: 8260D Prep Batch(es): V40458 11/20/23 09:00
Prep Method: 5030E
Test Results Units MQL DF Date / Time By Analytical
Analyzed Batch
2-Hexanone
<5.00
pg/L
5.00
1
11/20/23 22:47
MSA
V40459
Isopropylbenzene
<5.00
pg/L
5.00
1
11/20/23 22:47
MSA
V40459
4-Isopropyl toluene
<0.500
pg/L
0.500
1
11/20/23 22:47
MSA
V40459
Methyl Ethyl Ketone (MEK)
<5.00
pg/L
5.00
1
11/20/23 22:47
MSA
V40459
Methyl tert-butyl ether (MTBE)
<0.500
p9/L
0.500
1
11/20/23 22:47
MSA
V40459
4-Methyl-2-Pentanone
<5.00
pg/L
5.00
1
11/20/23 22:47
MSA
V40459
Methylene Chloride
<1.00
pg/L
1.00
1
11/20/23 22:47
MSA
V40459
Naphthalene
<1.00
pg/L
1.00
1
11/20/23 22:47
MSA
V40459
n-Propylbenzene
<0.500
pg/L
0.500
1
11/20/23 22:47
MSA
V40459
Styrene
<0.500
pg/L
0.500
1
11/20/23 22:47
MSA
V40459
1,1,1,2-Tetrachloroethane
<0.500
pg/L
0.500
1
11/20/23 22:47
MSA
V40459
1,1,2,2-Tetrachloroethane
<0.500
pg/L
0.500
1
11/20/23 22:47
MSA
V40459
Tetrachloroethene
<0.500
pg/L
0.500
1
11/20/23 22:47
MSA
V40459
Toluene
<0.500
pg/L
0.500
1
11/20/23 22:47
MSA
V40459
1,2,3-Trichlorobenzene
<2.00
pg/L
2.00
1
11/20/23 22:47
MSA
V40459
1,2,4-Trichlorobenzene
<1.00
pg/L
1.00
1
11/20/23 22:47
MSA
V40459
1, 1, 1-Trichloroethane
<0.500
pg/L
0.500
1
11/20/23 22:47
MSA
V40459
1, 1, 2-Trichloroethane
<0.500
pg/L
0.500
1
11/20/23 22:47
MSA
V40459
Trichloroethene
<0.500
pg/L
0.500
1
11/20/23 22:47
MSA
V40459
Trichlorofluoromethane
<0.500
pg/L
0.500
1
11/20/23 22:47
MSA
V40459
1,2,3-Trichloropropane
<1.00
pg/L
1.00
1
11/20/23 22:47
MSA
V40459
1,3,5-Trimethylbenzene
<0.500
pg/L
0.500
1
11/20/23 22:47
MSA
V40459
Qualifiers/ DF Dilution Factor
MQL
Method Quantitation Limit
Definitions
Page 11 of 18

Waypointo
ANALYTICAL
00015
City of Raleigh Project
Robin Scudelari
8500 Battle Bridge Information
Raleigh , NC 27610
Report Number : 23-320-0075
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Raleigh Neuse River Resource Recovery Fa
REPORT OFANAL YSIS
Report Date : 11/29/2023
Received : 11/16/2023
Lab No : 89397
Sample ID : Wrenn Road B-8
Matrix: Aqueous
Sampled: 11/14/2023 10:50
Analytical Method: 8260D
Prep Batch(es):
V40458 11/20/23 09:00
Prep Method: 5030E
Test
Results
Units
MQL
DF
Date / Time By
Analytical
Analyzed
Batch
Vinyl Acetate
<2.00
Ng/L
2.00
1
11/20/23 22:47 MSA
V40459
Vinyl Chloride
<0.500
Ng/L
0.500
1
11/20/23 22:47 MSA
V40459
o-Xylene
<0.500
N9/L
0.500
1
11/20/23 22:47 MSA
V40459
m,p-Xylene
<1.00
Ng/L
1.00
1
11/20/23 22:47 MSA
V40459
Xylene (Total)
<0.500
Ng/L
0.500
1
11/20/23 22:47
V40459
Surrogate: 4-Bromofluorobenzene
102
Limits: 80-124%
1 11/20/23 22:47 MSA
V40459
Surrogate: Dibromofluoromethane
103
Limits: 75-129%
1 11/20/23 22:47 MSA
V40459
Surrogate: 1,2-Dichloroethane - d4
103
Limits: 63-136%
1 11/20/23 22:47 MSA
V40459
Surrogate: Toluene-d8
102
Limits: 77-123%
1 11/20/23 22:47 MSA
V40459
Qualifiers/ DF Dilution Factor MQL Method Quantitation Limit
Definitions
Page 12 of 18

Waypointo
ANALYTICAL
00015
City of Raleigh Project
Robin Scudelari
8500 Battle Bridge Information
Raleigh , NC 27610
Report Number:23-320-0075
Lab No : 89398
Sample ID : Wrenn Road B-9
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca I.com
Raleigh Neuse River Resource Recovery Fa
REPORT OFANAL YSIS
Report Date : 11/29/2023
Received : 11/16/2023
Matrix: Aqueous
Sampled: 11 / 14/ 2023 11:50
Analytical Method: 8260D
Prep Method: 5030B
Test
Results
Prep Batch(es):
Units
V40458
MQL
11/20/23 09:00
DF
Date / Time
Analyzed
By
Analytical
Batch
Acetone
<5.00
pg/L
5.00
1
11/20/23 23:12
MSA
V40459
Acrolein
<5.00
pg/L
5.00
1
11/20/23 23:12
MSA
V40459
Acrylonitrile
<5.00
pg/L
5.00
1
11/20/23 23:12
MSA
V40459
Benzene
<0.500
pg/L
0.500
1
11/20/23 23:12
MSA
V40459
Bromobenzene
<0.500
pg/L
0.500
1
11/20/23 23:12
MSA
V40459
Bromochloromethane
<1.00
pg/L
1.00
1
11/20/23 23:12
MSA
V40459
Bromodichloromethane
<0.500
pg/L
0.500
1
11/20/23 23:12
MSA
V40459
Bromoform
<5.00
pg/L
5.00
1
11/20/23 23:12
MSA
V40459
Bromomethane
<1.00
pg/L
1.00
1
11/20/23 23:12
MSA
V40459
n-Butylbenzene
<1.00
pg/L
1.00
1
11/20/23 23:12
MSA
V40459
sec -Butyl benzene
<0.500
pg/L
0.500
1
11/20/23 23:12
MSA
V40459
tert-Butyl benzene
<2.00
pg/L
2.00
1
11/20/23 23:12
MSA
V40459
Carbon Disulfide
<5.00
pg/L
5.00
1
11/20/23 23:12
MSA
V40459
Carbon Tetrachloride
<0.500
pg/L
0.500
1
11/20/23 23:12
MSA
V40459
Chlorobenzene
<0.500
pg/L
0.500
1
11/20/23 23:12
MSA
V40459
Chlorodibromomethane
<0.500
pg/L
0.500
1
11/20/23 23:12
MSA
V40459
Chloroethane
<1.00
pg/L
1.00
1
11/20/23 23:12
MSA
V40459
Chloroform
1.80
pg/L
0.500
1
11/20/23 23:12
MSA
V40459
Chloromethane
<0.500
pg/L
0.500
1
11/20/23 23:12
MSA
V40459
2-Chlorotoluene
<0.500
pg/L
0.500
1
11/20/23 23:12
MSA
V40459
4-Chlorotoluene
<0.500
pg/L
0.500
1
11/20/23 23:12
MSA
V40459
Di -Isopropyl Ether (DIPE)
<5.00
pg/L
5.00
1
11/20/23 23:12
MSA
V40459
Qualifiers/ DF Dilution Factor MQL Method Quantitation Limit
Definitions
Page 13 of 18

Waypointo
ANALYTICAL
00015
City of Raleigh Project
Robin Scudelari
8500 Battle Bridge Information
Raleigh , NC 27610
Report Number:23-320-0075
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Raleigh Neuse River Resource Recovery Fa
REPORT OF ANALYSIS
Report Date : 11/29/2023
Received : 11/16/2023
Lab No : 89398 Matrix: Aqueous
Sample ID : Wrenn Road B-9 Sampled: 11/14/2023 11:50
Analytical Method: 8260D
Prep Method: 5030B
Test
Results
Prep Batch(es):
Units
V40458
MQL
11/20/23 09:00
DF
Date / Time
Analyzed
By
Analytical
Batch
1,2-Dibromo-3-Chloropropane
<2.00
pg/L
2.00
1
11/20/23 23:12
MSA
V40459
1,2-Dibromoethane
<0.500
pg/L
0.500
1
11/20/23 23:12
MSA
V40459
Dibromomethane
<0.500
pg/L
0.500
1
11/20/23 23:12
MSA
V40459
1,2-Dichlorobenzene
<0.500
pg/L
0.500
1
11/20/23 23:12
MSA
V40459
1,3-Dichlorobenzene
<0.500
pg/L
0.500
1
11/20/23 23:12
MSA
V40459
1,4-Dichlorobenzene
<0.500
pg/L
0.500
1
11/20/23 23:12
MSA
V40459
Dichlorodifluoromethane
<5.00
pg/L
5.00
1
11/20/23 23:12
MSA
V40459
1,1-Dichloroethane
<0.500
pg/L
0.500
1
11/20/23 23:12
MSA
V40459
1,2-Dichloroethane
<0.500
p9/L
0.500
1
11/20/23 23:12
MSA
V40459
1,1-Dichloroethene
<0.500
p9/L
0.500
1
11/20/23 23:12
MSA
V40459
cis-1,2-Dichloroethene
<0.500
p9/L
0.500
1
11/20/23 23:12
MSA
V40459
trans- 1,2-Dichloroethene
<0.500
p9/L
0.500
1
11/20/23 23:12
MSA
V40459
1,2-Dichloropropane
<0.500
p9/L
0.500
1
11/20/23 23:12
MSA
V40459
1,3-Dichloropropane
<0.500
pg/L
0.500
1
11/20/23 23:12
MSA
V40459
2,2-Dichloropropane
<2.00
pg/L
2.00
1
11/20/23 23:12
MSA
V40459
1,1-Dichloropropene
<0.500
pg/L
0.500
1
11/20/23 23:12
MSA
V40459
cis-1,3-Dichloropropene
<0.500
pg/L
0.500
1
11/20/23 23:12
MSA
V40459
trans- 1,3-Dichloropropene
<0.500
pg/L
0.500
1
11/20/23 23:12
MSA
V40459
Ethylbenzene
<0.500
pg/L
0.500
1
11/20/23 23:12
MSA
V40459
Ethyl Tertiary Butyl Ether (ETBE)
<10.0
pg/L
10.0
1
11/20/23 23:12
MSA
V40459
Hexachlorobutadiene
<2.00
pg/L
2.00
1
11/20/23 23:12
MSA
V40459
n-Hexane
<10.0
pg/L
10.0
1
11/20/23 23:12
MSA
V40459
Qualifiers/ DF Dilution Factor MQL Method Quantitation Limit
Definitions
Page 14 of 18

Waypointo
ANALYTICAL
00015
City of Raleigh Project
Robin Scudelari
8500 Battle Bridge Information
Raleigh , NC 27610
Report Number : 23-320-0075
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Raleigh Neuse River Resource Recovery Fa
REPORT OFANAL PSIS
Report Date : 11/29/2023
Received : 11/16/2023
Lab No : 89398 Matrix: Aqueous
Sample ID : Wrenn Road B-9 Sampled: 11/14/2023 11:50
Analytical Method: 8260D Prep Batch(es): V40458 11/20/23 09:00
Prep Method: 5030B
Test Results Units MQL DF Date / Time By Analytical
Analyzed Batch
2-Hexanone
<5.00
Ng/L
5.00
1
11/20/23 23:12
MSA
V40459
Isopropylbenzene
<5.00
ug/L
5.00
1
11/20/23 23:12
MSA
V40459
4-Isopropyl toluene
<0.500
N9/L
0.500
1
11/20/23 23:12
MSA
V40459
Methyl Ethyl Ketone (MEK)
<5.00
Ng/L
5.00
1
11/20/23 23:12
MSA
V40459
Methyl tert-butyl ether (MTBE)
<0.500
ug/L
0.500
1
11/20/23 23:12
MSA
V40459
4-Methyl-2-Pentanone
<5.00
ug/L
5.00
1
11/20/23 23:12
MSA
V40459
Methylene Chloride
<1.00
ug/L
1.00
1
11/20/23 23:12
MSA
V40459
Naphthalene
<1.00
ug/L
1.00
1
11/20/23 23:12
MSA
V40459
n-Propylbenzene
<0.500
ug/L
0.500
1
11/20/23 23:12
MSA
V40459
Styrene
<0.500
ug/L
0.500
1
11/20/23 23:12
MSA
V40459
1,1,1,2-Tetrachloroethane
<0.500
Ng/L
0.500
1
11/20/23 23:12
MSA
V40459
1,1,2,2-Tetrachloroethane
<0.500
ug/L
0.500
1
11/20/23 23:12
MSA
V40459
Tetrachloroethene
<0.500
ug/L
0.500
1
11/20/23 23:12
MSA
V40459
Toluene
<0.500
ug/L
0.500
1
11/20/23 23:12
MSA
V40459
1,2,3-Trichlorobenzene
<2.00
ug/L
2.00
1
11/20/23 23:12
MSA
V40459
1,2,4-Trichlorobenzene
<1.00
ug/L
1.00
1
11/20/23 23:12
MSA
V40459
1, 1, 1-Trichloroethane
<0.500
ug/L
0.500
1
11/20/23 23:12
MSA
V40459
1,1,2-Trichloroethane
<0.500
ug/L
0.500
1
11/20/23 23:12
MSA
V40459
Trichloroethene
<0.500
ug/L
0.500
1
11/20/23 23:12
MSA
V40459
Trichlorofluoromethane
<0.500
ug/L
0.500
1
11/20/23 23:12
MSA
V40459
1,2,3-Trichloropropane
<1.00
ug/L
1.00
1
11/20/23 23:12
MSA
V40459
1,3,5-Trimethylbenzene
<0.500
ug/L
0.500
1
11/20/23 23:12
MSA
V40459
Qualifiers/ DF Dilution Factor
MQL
Method Quantitation Limit
Definitions
Page 15 of 18

0
Waypoint, 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
00015
City of Raleigh Project Raleigh Neuse River Resource Recovery Fa
Robin Scudelari Report Date : 11/29/2023
8500 Battle Bridge Information : Received : 11/16/2023
Raleigh , NC 27610
Report Number :23-320-0075
Lab No : 89398
Sample ID : Wrenn Road B-9
REPORT OFANAL YSIS
Matrix: Aqueous
Sampled: 11/14/2023 11:50
Analytical Method: 8260D
Prep Batch(es):
V40458 11/20/23 09:00
Prep Method: 5030E
Test
Results Units
MQL
DF
Date I Time By Analytical
Analyzed
Batch
Vinyl Acetate
<2.00 ug/L
2.00
1
11/20/23 23:12 MSA
V40459
Vinyl Chloride
<0.500 ug/L
0.500
1
11/20/23 23:12 MSA
V40459
o-Xylene
<0.500 ug/L
0.500
1
11/20/23 23:12 MSA
V40459
m,p-Xylene
<1.00 ug/L
1.00
1
11/20/23 23:12 MSA
V40459
Xylene (Total)
<0.500 ug/L
0.500
1
11/20/23 23:12
V40459
Surrogate: 4-Bromofluorobenzene
104
Limits: 80-124%
1 11/20/23 23:12 MSA
V40459
Surrogate: Dibromofluoromethane
102
Limits: 75-129%
1 11/20/23 23:12 MSA
V40459
Surrogate: 1,2-Dichloroethane - d4
100
Limits: 63-136%
1 11/20/23 23:12 MSA
V40459
Surrogate: Toluene-d8
102
Limits: 77-123%
1 11/20/23 23:12 MSA
V40459
Qualifiers/ DF Dilution Factor
Definitions
MQL Method Quantitation Limit
Page 16 of 18

Waypointe)
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 00015
Customer Name: City of Raleigh
Report Number: 23-320-0075
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client C Courier
0 Other:
Thermometer ID:
�-
IRT15 0.8C
Shipping container/cooler uncompromised?
CO) Yes
0 No
Number of coolers/boxes received
F 1
Custody seals intact on shipping container/cooler?
0 Yes
0 No
# Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
Yes
0 No
COC agrees with sample label(s)?
Yes
0 No
COC properly completed
Yes
0 No
Samples in proper containers?
Yes
0 No
Sample containers intact?
0 Yes
0 No
Sufficient sample volume for indicated test(s)?
CO) Yes
0 No
All samples received within holding time?
Yes
0 No
Cooler temperature in compliance?
U Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes
O No
Water - Sample containers properly preserved
Yes
0 No
0 N/A
Water - VOA vials free of headspace
Yes
0 No
0 N/A
Trip Blanks received with VOAs
0 Yes
0 No
0 N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
N/A
High concentration container (48 hr) Low concentration EnCore samplers (48 hr)
High concentration pre -weighed (methanol -14 d) Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included?
0 Yes
No
Comments:
Signature: Terri W Cole _ Date & Time: r11� /16/2023 17:00:10
Page 17 of 18

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