NC0006254_Groundwater Monitoring Report November 2023_20231214

PO Box 604 ▪ Fletcher, NC 28732 ▪ Cell: 828-508-4510

November 16, 2023
Mr. Brett Laverty
NCDEQ Division of Water Resources
Asheville Regional Office
2090 US Highway 70
Swannanoa, NC 28778

RE: Groundwater Analytical Results – November 7, 2023
Blue Ridge Tissue Corporation
1427 Yadkin River Road
Patterson, North Carolina

Mr. Laverty:

On November 7, 2023, Singleton Environmental, Inc. (SEI) visited the Blue Ridge Tissue site
located at 1427 Yadkin River Road in Patterson, North Carolina, to collect groundwater samples
from monitoring wells MW-1, MW-3, MW-4, MW-6, MW-7, and MW-8. Monitoring wells
MW-2 and MW-6 were dry, therefore, not sampled. The depth to groundwater in the remaining
monitoring wells ranged from 6.19 feet in MW-4 to 20.85 feet in MW-3. Refer to Table 1 for all
monitoring well groundwater depths and Figure 1 for all monitoring well locations.

All groundwater samples, except for MW-2 and MW-6, were collected using a peristaltic pump
connected to a Horiba U52-2 water quality meter with a flow-through-cell to collect groundwater
parameters (temperature, pH, specific conductivity, dissolved oxygen, ORP, and turbidity).

The groundwater samples were submitted on ice to Pace Analytical for the analysis of EPA
Method 6200B, 8-RCRA Metals (Method 200.7), pH, ammonia, TKN, sulfate, nitrogen, nitrite,
and nitrate.

The laboratory analysis of groundwater sample MW-1 detected concentrations of total iron and
total manganese above the NCAC 2L groundwater standards. Both concentrations were higher
than the July 2023 event.

The laboratory analysis of groundwater sample MW-3 detected concentrations of ammonia, total
barium, total iron, and total manganese above the NCAC 2L groundwater standards. The metals
concentrations were lower than the July 2023 event. Tetrachloroethene was detected for the first
time in MW-3, however, the concentration was just below the NCAC 2L groundwater standards.

The laboratory analysis of groundwater sample MW-4 detected concentrations of total iron and
total manganese above the NCAC 2L groundwater standards. The concentration of total iron was
lower and total manganese was higher than the July 2023 event.

The laboratory analysis of gr oundwater sample MW-7 did not detect any concentrations exceeding
the NCAC 2L groundwater standards.
Singleton Environmental, Inc.

Singleton Environmental, Inc.

The laboratory analysis of groundwater sample MW-8 did not detect any concentrations exceeding
the NCAC 2L groundwater standards.

The analytical results are shown in Table 2 and Table 3. The laboratory data sheets are also
attached.

During the April 2017 groundwater sampling event, AECOM reported a possible sheen on the
groundwater in monitoring well MW-4. During the November 2023 event a sheen was not
observed; however, VOC samples were collected at all monitoring wells that were sampled. With
the exception of MW-3, all of the sampled monitoring well samples at the site were non-detect for
VOCs during the November 2023 event. A concentration of tetrachloroethene detected in MW-3
was below the NCAC 2L groundwater standards.

Singleton Environmental, Inc. recommends sampling the monitoring wells again in March 2024
for the same compounds to continue tracking the groundwater concentrations and groundwater
levels at the site. It is also recommended that MW-3 is also sampled using EPA Method 6200B to
track the tetrachloroethene concentration.

If you have any questions, you can reach me at [phone].

Sincerely,

Chris Singleton, P.G.
Singleton Environmental, Inc.

cc: Dave Hallock, Blue Ridge Tissue Corporation
Lyndon Sutliff, Blue Ridge Tissue Corporation

Attachments
@A
@A @A
@A
@A
@A
@A
@A
MW-2
MW-3
MW-4
MW-1
@A
MW-5
MW-7
MW-6
MW-8
1
2
8
0
12
6
0
1
3
2
0
1340
1360
1380
1
2
4
0
142
0
1240
1420
Source: Esri, DigitalGlobe, GeoEye, Earthstar Geographics, CNES/AirbusDS, USDA, USGS, AEX, Getmapping, Aerogrid, IGN, IGP, swisstopo, and theGIS User Community
Figure
60540673
1
May 2017
§
0 200 400Feet
1 inch = 200 feet
Y
a
d
k
i
n

R
i
v
e
r

R
d
Whisn
a
n
t

R
d
Yad
k
i
n

R
i
v
e
r
Y
a
d
k
i
n

R
i
v
e
r
Roby M
a
r
t
i
n

R
d
#0
Site Layout MapBlue Ridge Tissue CorporationPatterson, North Carolina
Legend
Property Boundary
Yadkin River Flow Direction#
Land Surface Elevation Contour (ft above mean sea level)
Monitoring Well Location
Abandoned Water Well#0@A
Well ID Date Installed Total Depth (feet
bls)
Screened Interval
(feet bls)
Top of Casing
Elevation (feet msl)
Date Water Level
Measured
Depth to Water (feet
BTOC)
Groundwater Elevation
(feet msl)
MW-1 02/08/11 11 6-11 1253.71 11/07/23 13.75 1,239.96
MW-2 08/12/09 50 40-50 1323.03 11/07/23 N/A N/A
MW-3 08/13/09 20 10-20 1299.02 11/07/23 20.85 1,278.17
MW-4 08/13/09 15 5-15 1247.23 11/07/23 6.19 1,241.04
MW-5 08/16/11 21 11-21 1285.46 N/A N/A N/A
MW-6 08/06/14 29 19-29 1341.55 11/07/23 N/A N/A
MW-7 08/06/14 24 14-24 1274.41 11/07/23 20.20 1,254.21
MW-8 08/06/14 20 10-20 1253.14 11/07/23 15.15 1,237.99
Notes:
bls - feet below land surface BTOC - below top of casing msl - above mean sea level NG - not gauged
AECOM
Table 1
Monitoring Well Construction and Groundwater Elevations
Blue Ridge Tissue Corporation
1427 Yadkin River Road
Patterson, North Carolina
Sample ID MW-1 MW-2*MW-3 MW-4 MW-6 MW-7 MW-8
Sample Date 11/07/23 11/07/23 11/07/23 11/07/23 11/07/23 11/07/23 11/07/23
Temperature (°C)NS 19.4 N/A 23.50 23.90 N/A 22.60 23.30
pH (standard units)NS 6.80 N/A 6.30 6.40 N/A 6.00 5.80
Specific Conductivity (mS/cm)NS 0.601 N/A 0.57 0.292 N/A 0.102 0.074
Dissolved Oxygen (mg/L)NS 3.00 N/A 3.22 1.20 N/A 4.35 6.45
ORP (mV)NS 45.0 N/A 61.00 -17.0 N/A 207.0 210.0
Turbidity (NTU)NS 10 N/A 44.00 23 N/A 3.8 7.5
Gallons Pumped NS 1 N/A <1.0 2 N/A 2.5 2
Cloudy/Odor No/No No/Odor N/A Cloudy/Odor No/Slight Odor N/A No/No No/No
Total Barium (ug/L)700 215 N/A 322 91.7 N/A 62.9 12.6
Total Iron (ug/L)300 33300 N/A 27300 13300 N/A 51.5 ND
Total Manganese (ug/L)50 3420 N/A 2910 2120 N/A ND ND
Arsenic (ug/L)10 ND N/A ND ND N/A ND ND
Chromium (ug/L)10 ND N/A ND ND N/A ND ND
Lead (ug/L)15 ND N/A ND ND N/A ND ND
Sulfate (mg/L)N/A ND N/A 12.3 4.9 N/A 1.7 16.5
Ammonia (mg/L)1.5 0.71 N/A 15.3 0.56 N/A ND ND
TKN (mg/L)N/A 1.1 N/A 17.8 0.76 N/A ND ND
Nitrogen NO2 plus NO3 (mg/L)N/A ND N/A ND ND N/A ND 1.7
Nitrate (mg/L)10 ND N/A ND ND N/A 1 1.7
Nitrite (mg/L)1 0.051 N/A 0.051 ND N/A 1 ND
pH (standard units)N/A 6.4 N/A 6.4 6.4 N/A 6.4 5.9
Total Disolved Solids (mg/L)N/A N/A N/A N/A N/A N/A N/A N/A
Notes:
Samples analyzed for total and dissolved iron, barium and manganese by EPA Method 200.7
2L Standard - North Carolina groundwater quality standards established in Title 15A of the North Carolina Administrative Code, Subchapter 2L, Section 0.20
°C - degrees Celsius
µS/cm - microsiemens per centimeter
EPA - United States Environmental Protection Agency mg/L - milligrams per liter
mV - millivolt
NA - Not analyzed NS - No standard
NTU - Nephelometric Turbidity Unit
RCRA - Resource Conservation Recovery Act
Bold samples indicate concentrations above the 2L Standard
*MW-2 purged with disposable bailer, water quality parameters collected from same bail as sample.
2L
Standard
Field Parameters
Analytical Parameters
Table 2
Blue Ridge Tissue Corporation
1427 Yadkin River Road
Patterson, North Carolina
Benzen
e
Ethylbe
nzene
Naphth
alene
Tetrachl
oroethe
ne
Toluene Trichlor
oethene
m&p-
Xylene
Date
Collected
(mm/dd/yy)
Sample
Depth
(ft. BGS)
ug/L ug/L ug/L ug/L ug/L ug/L ug/L
MW-1 11/07/2023 ND ND ND ND ND ND ND
MW-3 11/07/2023 ND ND ND 0.64 ND ND ND
MW-4 11/07/2023 ND ND ND ND ND ND ND
MW-7 11/07/2023 ND ND ND ND ND ND ND
MW-8 11/07/2023 ND ND ND ND ND ND ND
1 600 6 0.7 600 3 N/A
5000 84500 6000 700 260000 3000 N/A
mg/L = milligrams per liter
ug/L = micrograms per liter
Bold data above the MSCC (Soil to Groundwater)
NOTES:
ND = Not Detected
ft. BGS = feet below ground surface
Sample ID
Constituent of Concern
2L Class GA Standards
2L Class GCL Standards
Analytical Method EPA Method 6200B
Table # 3
Summary of Analytical Results - Water Samples
Blue Ridge Tissue 11/07
11/16/2023 11:25
Facility ID# or NCDENR's Incident #
#=CL#
November 16, 2023
LIMS USE: FR - CHRIS SINGLETON
LIMS OBJECT ID: 92697285
92697285
Project:
Pace Project No.:
RE:
Chris Singleton
Singleton Environmental
105 Charlotte Highway
Asheville, NC 28803
Blue Ridge Tissue 11/07
Dear Chris Singleton:
Enclosed are the analytical results for sample(s) received by the laboratory on November 07, 2023. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Matthew Brainard
[e-mail]
Project Manager
704-977-0942
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 1 of 37
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 2 of 37
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92697285001 MW-1 EPA 200.7 Rev 4.4 1994 6 PASI-ASBW
EPA 200.8 Rev 5.4 1994 6 PASI-AKRL
SM 6200B 63 PASI-CLMB
SM 4500-H+B-2011 1 PASI-ASMS
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
EPA 350.1 Rev 2.0 1993 1 PASI-ANCF
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 3 PASI-AMFO
92697285002 MW-3 EPA 200.7 Rev 4.4 1994 6 PASI-ASBW
EPA 200.8 Rev 5.4 1994 6 PASI-AKRL
SM 6200B 63 PASI-CLMB
SM 4500-H+B-2011 1 PASI-ASMS
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
EPA 350.1 Rev 2.0 1993 1 PASI-ANCF
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 3 PASI-AMFO
92697285003 MW-4 EPA 200.7 Rev 4.4 1994 6 PASI-ASBW
EPA 200.8 Rev 5.4 1994 6 PASI-AKRL
SM 6200B 63 PASI-CLMB
SM 4500-H+B-2011 1 PASI-ASMS
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
EPA 350.1 Rev 2.0 1993 1 PASI-ANCF
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 3 PASI-AMFO
92697285004 MW-7 EPA 200.7 Rev 4.4 1994 6 PASI-ASBW
EPA 200.8 Rev 5.4 1994 6 PASI-AKRL
SM 6200B 63 PASI-CLMB
SM 4500-H+B-2011 1 PASI-ASMS
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
EPA 350.1 Rev 2.0 1993 1 PASI-ANCF
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 3 PASI-AMFO
92697285005 MW-8 EPA 200.7 Rev 4.4 1994 6 PASI-ASBW
EPA 200.8 Rev 5.4 1994 6 PASI-AKRL
SM 6200B 63 PASI-CLMB
SM 4500-H+B-2011 1 PASI-ASMS
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 3 of 37
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
EPA 350.1 Rev 2.0 1993 1 PASI-ANCF
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 3 PASI-AMFO
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 4 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Sample:MW-1 Lab ID:92697285001 Collected:11/07/23 09:45 Received:11/07/23 15:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Arsenic ND ug/L 11/09/23 17:00 7440-38-211/08/23 13:3510.0 1
Barium 215 ug/L 11/09/23 17:00 7440-39-311/08/23 13:355.0 1
Chromium ND ug/L 11/09/23 17:00 7440-47-311/08/23 13:355.0 1
Iron 33300 ug/L 11/09/23 17:00 7439-89-611/08/23 13:3550.0 1
Lead ND ug/L 11/09/23 17:00 7439-92-111/08/23 13:355.0 1
Manganese 3420 ug/L 11/09/23 17:00 7439-96-511/08/23 13:355.0 1
Analytical Method: EPA 200.8 Rev 5.4 1994 Preparation Method: EPA 200.8 Rev 5.4 1994
Pace Analytical Services - Asheville
200.8 MET ICPMS
Arsenic 1.1 ug/L 11/08/23 22:08 7440-38-211/08/23 12:301.0 1
Barium 180 ug/L 11/08/23 22:08 7440-39-311/08/23 12:301.0 1
Chromium 1.5 ug/L 11/08/23 22:08 7440-47-311/08/23 12:301.0 1
Iron 30700 ug/L 11/09/23 13:45 7439-89-611/08/23 12:3050010
Lead 3.0 ug/L 11/08/23 22:08 7439-92-111/08/23 12:301.0 1
Manganese 3280 ug/L 11/09/23 13:50 7439-96-511/08/23 12:3040.0 20
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 11/10/23 04:53 71-43-20.50 1
Bromobenzene ND ug/L 11/10/23 04:53 108-86-10.50 1
Bromochloromethane ND ug/L 11/10/23 04:53 74-97-50.50 1
Bromodichloromethane ND ug/L 11/10/23 04:53 75-27-40.50 1
Bromoform ND ug/L 11/10/23 04:53 75-25-20.50 1
Bromomethane ND ug/L 11/10/23 04:53 74-83-95.0 1
n-Butylbenzene ND ug/L 11/10/23 04:53 104-51-80.50 1
sec-Butylbenzene ND ug/L 11/10/23 04:53 135-98-80.50 1
tert-Butylbenzene ND ug/L 11/10/23 04:53 98-06-60.50 1
Carbon tetrachloride ND ug/L 11/10/23 04:53 56-23-50.50 1
Chlorobenzene ND ug/L 11/10/23 04:53 108-90-70.50 1
Chloroethane ND ug/L 11/10/23 04:53 75-00-31.0 1
Chloroform ND ug/L 11/10/23 04:53 67-66-30.50 1
Chloromethane ND ug/L 11/10/23 04:53 74-87-3 M11.0 1
2-Chlorotoluene ND ug/L 11/10/23 04:53 95-49-80.50 1
4-Chlorotoluene ND ug/L 11/10/23 04:53 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 11/10/23 04:53 96-12-81.0 1
Dibromochloromethane ND ug/L 11/10/23 04:53 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 11/10/23 04:53 106-93-40.50 1
Dibromomethane ND ug/L 11/10/23 04:53 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 11/10/23 04:53 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 11/10/23 04:53 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 11/10/23 04:53 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 11/10/23 04:53 75-71-8 M10.50 1
1,1-Dichloroethane ND ug/L 11/10/23 04:53 75-34-30.50 1
1,2-Dichloroethane ND ug/L 11/10/23 04:53 107-06-20.50 1
1,1-Dichloroethene ND ug/L 11/10/23 04:53 75-35-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 5 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Sample:MW-1 Lab ID:92697285001 Collected:11/07/23 09:45 Received:11/07/23 15:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
cis-1,2-Dichloroethene ND ug/L 11/10/23 04:53 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 11/10/23 04:53 156-60-50.50 1
1,2-Dichloropropane ND ug/L 11/10/23 04:53 78-87-50.50 1
1,3-Dichloropropane ND ug/L 11/10/23 04:53 142-28-90.50 1
2,2-Dichloropropane ND ug/L 11/10/23 04:53 594-20-70.50 1
1,1-Dichloropropene ND ug/L 11/10/23 04:53 563-58-6 M10.50 1
cis-1,3-Dichloropropene ND ug/L 11/10/23 04:53 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 11/10/23 04:53 10061-02-60.50 1
Diisopropyl ether ND ug/L 11/10/23 04:53 108-20-30.50 1
Ethylbenzene ND ug/L 11/10/23 04:53 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 11/10/23 04:53 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 11/10/23 04:53 98-82-80.50 1
Methylene Chloride ND ug/L 11/10/23 04:53 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 11/10/23 04:53 1634-04-40.50 1
Naphthalene ND ug/L 11/10/23 04:53 91-20-32.0 1
n-Propylbenzene ND ug/L 11/10/23 04:53 103-65-10.50 1
Styrene ND ug/L 11/10/23 04:53 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 11/10/23 04:53 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 11/10/23 04:53 79-34-50.50 1
Tetrachloroethene ND ug/L 11/10/23 04:53 127-18-40.50 1
Toluene ND ug/L 11/10/23 04:53 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 11/10/23 04:53 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 11/10/23 04:53 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 11/10/23 04:53 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 11/10/23 04:53 79-00-50.50 1
Trichloroethene ND ug/L 11/10/23 04:53 79-01-60.50 1
Trichlorofluoromethane ND ug/L 11/10/23 04:53 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 11/10/23 04:53 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 11/10/23 04:53 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 11/10/23 04:53 108-67-80.50 1
Vinyl chloride ND ug/L 11/10/23 04:53 75-01-41.0 1
m&p-Xylene ND ug/L 11/10/23 04:53 179601-23-11.0 1
o-Xylene ND ug/L 11/10/23 04:53 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)90 %11/10/23 04:53 17060-07-070-130 1
4-Bromofluorobenzene (S)98 %11/10/23 04:53 460-00-470-130 1
Toluene-d8 (S)104 %11/10/23 04:53 2037-26-570-130 1
Analytical Method: SM 4500-H+B-2011
Pace Analytical Services - Asheville
4500H+ pH, Electrometric
pH at 25 Degrees C 6.4 Std. Units 11/09/23 12:39 H30.10 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate ND mg/L 11/07/23 20:51 14808-79-81.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 6 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Sample:MW-1 Lab ID:92697285001 Collected:11/07/23 09:45 Received:11/07/23 15:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia 0.71 mg/L 11/15/23 04:48 7664-41-70.10 1
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total 1.1 mg/L 11/16/23 07:02 7727-37-911/15/23 23:490.50 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, NO2 plus NO3 ND mg/L 11/08/23 02:120.040 1
Nitrogen, Nitrate ND mg/L 11/08/23 02:12 14797-55-80.040 1
Nitrogen, Nitrite 0.051 mg/L 11/08/23 02:12 14797-65-00.040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 7 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Sample:MW-3 Lab ID:92697285002 Collected:11/07/23 11:40 Received:11/07/23 15:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Arsenic ND ug/L 11/09/23 17:03 7440-38-211/08/23 13:3510.0 1
Barium 322 ug/L 11/09/23 17:03 7440-39-311/08/23 13:355.0 1
Chromium ND ug/L 11/09/23 17:03 7440-47-311/08/23 13:355.0 1
Iron 27300 ug/L 11/09/23 17:03 7439-89-611/08/23 13:3550.0 1
Lead ND ug/L 11/09/23 17:03 7439-92-111/08/23 13:355.0 1
Manganese 2910 ug/L 11/09/23 17:03 7439-96-511/08/23 13:355.0 1
Analytical Method: EPA 200.8 Rev 5.4 1994 Preparation Method: EPA 200.8 Rev 5.4 1994
Pace Analytical Services - Asheville
200.8 MET ICPMS
Arsenic 2.2 ug/L 11/08/23 22:13 7440-38-211/08/23 12:301.0 1
Barium 285 ug/L 11/09/23 13:55 7440-39-311/08/23 12:302.0 2
Chromium ND ug/L 11/08/23 22:13 7440-47-311/08/23 12:301.0 1
Iron 25800 ug/L 11/09/23 14:00 7439-89-611/08/23 12:3050010
Lead ND ug/L 11/08/23 22:13 7439-92-111/08/23 12:301.0 1
Manganese 2750 ug/L 11/09/23 14:05 7439-96-511/08/23 12:3040.0 20
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 11/10/23 05:11 71-43-20.50 1
Bromobenzene ND ug/L 11/10/23 05:11 108-86-10.50 1
Bromochloromethane ND ug/L 11/10/23 05:11 74-97-50.50 1
Bromodichloromethane ND ug/L 11/10/23 05:11 75-27-40.50 1
Bromoform ND ug/L 11/10/23 05:11 75-25-20.50 1
Bromomethane ND ug/L 11/10/23 05:11 74-83-95.0 1
n-Butylbenzene ND ug/L 11/10/23 05:11 104-51-80.50 1
sec-Butylbenzene ND ug/L 11/10/23 05:11 135-98-80.50 1
tert-Butylbenzene ND ug/L 11/10/23 05:11 98-06-60.50 1
Carbon tetrachloride ND ug/L 11/10/23 05:11 56-23-50.50 1
Chlorobenzene ND ug/L 11/10/23 05:11 108-90-70.50 1
Chloroethane ND ug/L 11/10/23 05:11 75-00-31.0 1
Chloroform ND ug/L 11/10/23 05:11 67-66-30.50 1
Chloromethane ND ug/L 11/10/23 05:11 74-87-31.0 1
2-Chlorotoluene ND ug/L 11/10/23 05:11 95-49-80.50 1
4-Chlorotoluene ND ug/L 11/10/23 05:11 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 11/10/23 05:11 96-12-81.0 1
Dibromochloromethane ND ug/L 11/10/23 05:11 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 11/10/23 05:11 106-93-40.50 1
Dibromomethane ND ug/L 11/10/23 05:11 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 11/10/23 05:11 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 11/10/23 05:11 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 11/10/23 05:11 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 11/10/23 05:11 75-71-80.50 1
1,1-Dichloroethane ND ug/L 11/10/23 05:11 75-34-30.50 1
1,2-Dichloroethane ND ug/L 11/10/23 05:11 107-06-20.50 1
1,1-Dichloroethene ND ug/L 11/10/23 05:11 75-35-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 8 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Sample:MW-3 Lab ID:92697285002 Collected:11/07/23 11:40 Received:11/07/23 15:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
cis-1,2-Dichloroethene ND ug/L 11/10/23 05:11 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 11/10/23 05:11 156-60-50.50 1
1,2-Dichloropropane ND ug/L 11/10/23 05:11 78-87-50.50 1
1,3-Dichloropropane ND ug/L 11/10/23 05:11 142-28-90.50 1
2,2-Dichloropropane ND ug/L 11/10/23 05:11 594-20-70.50 1
1,1-Dichloropropene ND ug/L 11/10/23 05:11 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 11/10/23 05:11 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 11/10/23 05:11 10061-02-60.50 1
Diisopropyl ether ND ug/L 11/10/23 05:11 108-20-30.50 1
Ethylbenzene ND ug/L 11/10/23 05:11 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 11/10/23 05:11 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 11/10/23 05:11 98-82-80.50 1
Methylene Chloride ND ug/L 11/10/23 05:11 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 11/10/23 05:11 1634-04-40.50 1
Naphthalene ND ug/L 11/10/23 05:11 91-20-32.0 1
n-Propylbenzene ND ug/L 11/10/23 05:11 103-65-10.50 1
Styrene ND ug/L 11/10/23 05:11 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 11/10/23 05:11 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 11/10/23 05:11 79-34-50.50 1
Tetrachloroethene 0.64 ug/L 11/10/23 05:11 127-18-40.50 1
Toluene ND ug/L 11/10/23 05:11 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 11/10/23 05:11 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 11/10/23 05:11 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 11/10/23 05:11 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 11/10/23 05:11 79-00-50.50 1
Trichloroethene ND ug/L 11/10/23 05:11 79-01-60.50 1
Trichlorofluoromethane ND ug/L 11/10/23 05:11 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 11/10/23 05:11 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 11/10/23 05:11 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 11/10/23 05:11 108-67-80.50 1
Vinyl chloride ND ug/L 11/10/23 05:11 75-01-41.0 1
m&p-Xylene ND ug/L 11/10/23 05:11 179601-23-11.0 1
o-Xylene ND ug/L 11/10/23 05:11 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)90 %11/10/23 05:11 17060-07-070-130 1
4-Bromofluorobenzene (S)98 %11/10/23 05:11 460-00-470-130 1
Toluene-d8 (S)105 %11/10/23 05:11 2037-26-570-130 1
Analytical Method: SM 4500-H+B-2011
Pace Analytical Services - Asheville
4500H+ pH, Electrometric
pH at 25 Degrees C 6.4 Std. Units 11/09/23 12:51 H30.10 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate 12.3 mg/L 11/07/23 21:06 14808-79-81.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 9 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Sample:MW-3 Lab ID:92697285002 Collected:11/07/23 11:40 Received:11/07/23 15:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia 15.3 mg/L 11/15/23 04:49 7664-41-70.30 3
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total 17.8 mg/L 11/16/23 07:03 7727-37-911/15/23 23:490.50 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, NO2 plus NO3 ND mg/L 11/08/23 02:210.040 1
Nitrogen, Nitrate ND mg/L 11/08/23 02:21 14797-55-80.040 1
Nitrogen, Nitrite 0.051 mg/L 11/08/23 02:21 14797-65-00.040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 10 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Sample:MW-4 Lab ID:92697285003 Collected:11/07/23 12:05 Received:11/07/23 15:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Arsenic ND ug/L 11/09/23 17:05 7440-38-211/08/23 13:3510.0 1
Barium 91.7 ug/L 11/09/23 17:05 7440-39-311/08/23 13:355.0 1
Chromium ND ug/L 11/09/23 17:05 7440-47-311/08/23 13:355.0 1
Iron 13300 ug/L 11/09/23 17:05 7439-89-611/08/23 13:3550.0 1
Lead ND ug/L 11/09/23 17:05 7439-92-111/08/23 13:355.0 1
Manganese 2120 ug/L 11/09/23 17:05 7439-96-511/08/23 13:355.0 1
Analytical Method: EPA 200.8 Rev 5.4 1994 Preparation Method: EPA 200.8 Rev 5.4 1994
Pace Analytical Services - Asheville
200.8 MET ICPMS
Arsenic 2.0 ug/L 11/08/23 22:18 7440-38-211/08/23 12:301.0 1
Barium 76.9 ug/L 11/08/23 22:18 7440-39-311/08/23 12:301.0 1
Chromium ND ug/L 11/08/23 22:18 7440-47-311/08/23 12:301.0 1
Iron 12300 ug/L 11/09/23 14:10 7439-89-611/08/23 12:302505
Lead ND ug/L 11/08/23 22:18 7439-92-111/08/23 12:301.0 1
Manganese 2010 ug/L 11/09/23 14:15 7439-96-511/08/23 12:3040.0 20
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 11/10/23 05:29 71-43-20.50 1
Bromobenzene ND ug/L 11/10/23 05:29 108-86-10.50 1
Bromochloromethane ND ug/L 11/10/23 05:29 74-97-50.50 1
Bromodichloromethane ND ug/L 11/10/23 05:29 75-27-40.50 1
Bromoform ND ug/L 11/10/23 05:29 75-25-20.50 1
Bromomethane ND ug/L 11/10/23 05:29 74-83-95.0 1
n-Butylbenzene ND ug/L 11/10/23 05:29 104-51-80.50 1
sec-Butylbenzene ND ug/L 11/10/23 05:29 135-98-80.50 1
tert-Butylbenzene ND ug/L 11/10/23 05:29 98-06-60.50 1
Carbon tetrachloride ND ug/L 11/10/23 05:29 56-23-50.50 1
Chlorobenzene ND ug/L 11/10/23 05:29 108-90-70.50 1
Chloroethane ND ug/L 11/10/23 05:29 75-00-31.0 1
Chloroform ND ug/L 11/10/23 05:29 67-66-30.50 1
Chloromethane ND ug/L 11/10/23 05:29 74-87-31.0 1
2-Chlorotoluene ND ug/L 11/10/23 05:29 95-49-80.50 1
4-Chlorotoluene ND ug/L 11/10/23 05:29 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 11/10/23 05:29 96-12-81.0 1
Dibromochloromethane ND ug/L 11/10/23 05:29 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 11/10/23 05:29 106-93-40.50 1
Dibromomethane ND ug/L 11/10/23 05:29 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 11/10/23 05:29 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 11/10/23 05:29 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 11/10/23 05:29 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 11/10/23 05:29 75-71-80.50 1
1,1-Dichloroethane ND ug/L 11/10/23 05:29 75-34-30.50 1
1,2-Dichloroethane ND ug/L 11/10/23 05:29 107-06-20.50 1
1,1-Dichloroethene ND ug/L 11/10/23 05:29 75-35-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 11 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Sample:MW-4 Lab ID:92697285003 Collected:11/07/23 12:05 Received:11/07/23 15:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
cis-1,2-Dichloroethene ND ug/L 11/10/23 05:29 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 11/10/23 05:29 156-60-50.50 1
1,2-Dichloropropane ND ug/L 11/10/23 05:29 78-87-50.50 1
1,3-Dichloropropane ND ug/L 11/10/23 05:29 142-28-90.50 1
2,2-Dichloropropane ND ug/L 11/10/23 05:29 594-20-70.50 1
1,1-Dichloropropene ND ug/L 11/10/23 05:29 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 11/10/23 05:29 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 11/10/23 05:29 10061-02-60.50 1
Diisopropyl ether ND ug/L 11/10/23 05:29 108-20-30.50 1
Ethylbenzene ND ug/L 11/10/23 05:29 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 11/10/23 05:29 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 11/10/23 05:29 98-82-80.50 1
Methylene Chloride ND ug/L 11/10/23 05:29 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 11/10/23 05:29 1634-04-40.50 1
Naphthalene ND ug/L 11/10/23 05:29 91-20-32.0 1
n-Propylbenzene ND ug/L 11/10/23 05:29 103-65-10.50 1
Styrene ND ug/L 11/10/23 05:29 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 11/10/23 05:29 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 11/10/23 05:29 79-34-50.50 1
Tetrachloroethene ND ug/L 11/10/23 05:29 127-18-40.50 1
Toluene ND ug/L 11/10/23 05:29 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 11/10/23 05:29 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 11/10/23 05:29 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 11/10/23 05:29 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 11/10/23 05:29 79-00-50.50 1
Trichloroethene ND ug/L 11/10/23 05:29 79-01-60.50 1
Trichlorofluoromethane ND ug/L 11/10/23 05:29 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 11/10/23 05:29 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 11/10/23 05:29 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 11/10/23 05:29 108-67-80.50 1
Vinyl chloride ND ug/L 11/10/23 05:29 75-01-41.0 1
m&p-Xylene ND ug/L 11/10/23 05:29 179601-23-11.0 1
o-Xylene ND ug/L 11/10/23 05:29 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)92 %11/10/23 05:29 17060-07-070-130 1
4-Bromofluorobenzene (S)99 %11/10/23 05:29 460-00-470-130 1
Toluene-d8 (S)104 %11/10/23 05:29 2037-26-570-130 1
Analytical Method: SM 4500-H+B-2011
Pace Analytical Services - Asheville
4500H+ pH, Electrometric
pH at 25 Degrees C 6.4 Std. Units 11/09/23 12:57 H30.10 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate 4.9 mg/L 11/07/23 21:20 14808-79-81.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 12 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Sample:MW-4 Lab ID:92697285003 Collected:11/07/23 12:05 Received:11/07/23 15:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia 0.56 mg/L 11/15/23 04:52 7664-41-70.10 1
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total 0.76 mg/L 11/16/23 07:06 7727-37-911/15/23 23:490.50 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, NO2 plus NO3 ND mg/L 11/08/23 02:230.040 1
Nitrogen, Nitrate ND mg/L 11/08/23 02:23 14797-55-80.040 1
Nitrogen, Nitrite ND mg/L 11/08/23 02:23 14797-65-00.040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 13 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Sample:MW-7 Lab ID:92697285004 Collected:11/07/23 11:23 Received:11/07/23 15:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Arsenic ND ug/L 11/09/23 17:07 7440-38-211/08/23 13:3510.0 1
Barium 62.9 ug/L 11/09/23 17:07 7440-39-311/08/23 13:355.0 1
Chromium ND ug/L 11/09/23 17:07 7440-47-311/08/23 13:355.0 1
Iron 51.5 ug/L 11/09/23 17:07 7439-89-611/08/23 13:3550.0 1
Lead ND ug/L 11/09/23 17:07 7439-92-111/08/23 13:355.0 1
Manganese ND ug/L 11/09/23 17:07 7439-96-511/08/23 13:355.0 1
Analytical Method: EPA 200.8 Rev 5.4 1994 Preparation Method: EPA 200.8 Rev 5.4 1994
Pace Analytical Services - Asheville
200.8 MET ICPMS
Arsenic ND ug/L 11/08/23 22:23 7440-38-211/08/23 12:301.0 1
Barium 50.5 ug/L 11/08/23 22:23 7440-39-311/08/23 12:301.0 1
Chromium ND ug/L 11/08/23 22:23 7440-47-311/08/23 12:301.0 1
Iron ND ug/L 11/08/23 22:23 7439-89-611/08/23 12:3050.0 1
Lead ND ug/L 11/08/23 22:23 7439-92-111/08/23 12:301.0 1
Manganese ND ug/L 11/08/23 22:23 7439-96-511/08/23 12:302.0 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 11/10/23 05:47 71-43-20.50 1
Bromobenzene ND ug/L 11/10/23 05:47 108-86-10.50 1
Bromochloromethane ND ug/L 11/10/23 05:47 74-97-50.50 1
Bromodichloromethane ND ug/L 11/10/23 05:47 75-27-40.50 1
Bromoform ND ug/L 11/10/23 05:47 75-25-20.50 1
Bromomethane ND ug/L 11/10/23 05:47 74-83-95.0 1
n-Butylbenzene ND ug/L 11/10/23 05:47 104-51-80.50 1
sec-Butylbenzene ND ug/L 11/10/23 05:47 135-98-80.50 1
tert-Butylbenzene ND ug/L 11/10/23 05:47 98-06-60.50 1
Carbon tetrachloride ND ug/L 11/10/23 05:47 56-23-50.50 1
Chlorobenzene ND ug/L 11/10/23 05:47 108-90-70.50 1
Chloroethane ND ug/L 11/10/23 05:47 75-00-31.0 1
Chloroform ND ug/L 11/10/23 05:47 67-66-30.50 1
Chloromethane ND ug/L 11/10/23 05:47 74-87-31.0 1
2-Chlorotoluene ND ug/L 11/10/23 05:47 95-49-80.50 1
4-Chlorotoluene ND ug/L 11/10/23 05:47 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 11/10/23 05:47 96-12-81.0 1
Dibromochloromethane ND ug/L 11/10/23 05:47 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 11/10/23 05:47 106-93-40.50 1
Dibromomethane ND ug/L 11/10/23 05:47 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 11/10/23 05:47 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 11/10/23 05:47 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 11/10/23 05:47 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 11/10/23 05:47 75-71-80.50 1
1,1-Dichloroethane ND ug/L 11/10/23 05:47 75-34-30.50 1
1,2-Dichloroethane ND ug/L 11/10/23 05:47 107-06-20.50 1
1,1-Dichloroethene ND ug/L 11/10/23 05:47 75-35-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 14 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Sample:MW-7 Lab ID:92697285004 Collected:11/07/23 11:23 Received:11/07/23 15:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
cis-1,2-Dichloroethene ND ug/L 11/10/23 05:47 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 11/10/23 05:47 156-60-50.50 1
1,2-Dichloropropane ND ug/L 11/10/23 05:47 78-87-50.50 1
1,3-Dichloropropane ND ug/L 11/10/23 05:47 142-28-90.50 1
2,2-Dichloropropane ND ug/L 11/10/23 05:47 594-20-70.50 1
1,1-Dichloropropene ND ug/L 11/10/23 05:47 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 11/10/23 05:47 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 11/10/23 05:47 10061-02-60.50 1
Diisopropyl ether ND ug/L 11/10/23 05:47 108-20-30.50 1
Ethylbenzene ND ug/L 11/10/23 05:47 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 11/10/23 05:47 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 11/10/23 05:47 98-82-80.50 1
Methylene Chloride ND ug/L 11/10/23 05:47 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 11/10/23 05:47 1634-04-40.50 1
Naphthalene ND ug/L 11/10/23 05:47 91-20-32.0 1
n-Propylbenzene ND ug/L 11/10/23 05:47 103-65-10.50 1
Styrene ND ug/L 11/10/23 05:47 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 11/10/23 05:47 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 11/10/23 05:47 79-34-50.50 1
Tetrachloroethene ND ug/L 11/10/23 05:47 127-18-40.50 1
Toluene ND ug/L 11/10/23 05:47 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 11/10/23 05:47 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 11/10/23 05:47 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 11/10/23 05:47 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 11/10/23 05:47 79-00-50.50 1
Trichloroethene ND ug/L 11/10/23 05:47 79-01-60.50 1
Trichlorofluoromethane ND ug/L 11/10/23 05:47 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 11/10/23 05:47 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 11/10/23 05:47 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 11/10/23 05:47 108-67-80.50 1
Vinyl chloride ND ug/L 11/10/23 05:47 75-01-41.0 1
m&p-Xylene ND ug/L 11/10/23 05:47 179601-23-11.0 1
o-Xylene ND ug/L 11/10/23 05:47 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)89 %11/10/23 05:47 17060-07-070-130 1
4-Bromofluorobenzene (S)99 %11/10/23 05:47 460-00-470-130 1
Toluene-d8 (S)106 %11/10/23 05:47 2037-26-570-130 1
Analytical Method: SM 4500-H+B-2011
Pace Analytical Services - Asheville
4500H+ pH, Electrometric
pH at 25 Degrees C 6.4 Std. Units 11/09/23 12:45 H30.10 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate 1.7 mg/L 11/07/23 21:35 14808-79-81.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 15 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Sample:MW-7 Lab ID:92697285004 Collected:11/07/23 11:23 Received:11/07/23 15:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia ND mg/L 11/15/23 04:54 7664-41-70.10 1
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total ND mg/L 11/16/23 07:07 7727-37-911/15/23 23:490.50 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, NO2 plus NO3 1.0 mg/L 11/08/23 02:200.040 1
Nitrogen, Nitrate 1.0 mg/L 11/08/23 02:20 14797-55-80.040 1
Nitrogen, Nitrite ND mg/L 11/08/23 02:20 14797-65-00.040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 16 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Sample:MW-8 Lab ID:92697285005 Collected:11/07/23 10:48 Received:11/07/23 15:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Arsenic ND ug/L 11/09/23 17:09 7440-38-211/08/23 13:3510.0 1
Barium 12.6 ug/L 11/09/23 17:09 7440-39-311/08/23 13:355.0 1
Chromium ND ug/L 11/09/23 17:09 7440-47-311/08/23 13:355.0 1
Iron ND ug/L 11/09/23 17:09 7439-89-611/08/23 13:3550.0 1
Lead ND ug/L 11/09/23 17:09 7439-92-111/08/23 13:355.0 1
Manganese ND ug/L 11/09/23 17:09 7439-96-511/08/23 13:355.0 1
Analytical Method: EPA 200.8 Rev 5.4 1994 Preparation Method: EPA 200.8 Rev 5.4 1994
Pace Analytical Services - Asheville
200.8 MET ICPMS
Arsenic ND ug/L 11/08/23 22:28 7440-38-211/08/23 12:301.0 1
Barium 10.1 ug/L 11/08/23 22:28 7440-39-311/08/23 12:301.0 1
Chromium ND ug/L 11/08/23 22:28 7440-47-311/08/23 12:301.0 1
Iron ND ug/L 11/08/23 22:28 7439-89-611/08/23 12:3050.0 1
Lead ND ug/L 11/08/23 22:28 7439-92-111/08/23 12:301.0 1
Manganese ND ug/L 11/08/23 22:28 7439-96-511/08/23 12:302.0 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 11/10/23 06:06 71-43-20.50 1
Bromobenzene ND ug/L 11/10/23 06:06 108-86-10.50 1
Bromochloromethane ND ug/L 11/10/23 06:06 74-97-50.50 1
Bromodichloromethane ND ug/L 11/10/23 06:06 75-27-40.50 1
Bromoform ND ug/L 11/10/23 06:06 75-25-20.50 1
Bromomethane ND ug/L 11/10/23 06:06 74-83-95.0 1
n-Butylbenzene ND ug/L 11/10/23 06:06 104-51-80.50 1
sec-Butylbenzene ND ug/L 11/10/23 06:06 135-98-80.50 1
tert-Butylbenzene ND ug/L 11/10/23 06:06 98-06-60.50 1
Carbon tetrachloride ND ug/L 11/10/23 06:06 56-23-50.50 1
Chlorobenzene ND ug/L 11/10/23 06:06 108-90-70.50 1
Chloroethane ND ug/L 11/10/23 06:06 75-00-31.0 1
Chloroform ND ug/L 11/10/23 06:06 67-66-30.50 1
Chloromethane ND ug/L 11/10/23 06:06 74-87-31.0 1
2-Chlorotoluene ND ug/L 11/10/23 06:06 95-49-80.50 1
4-Chlorotoluene ND ug/L 11/10/23 06:06 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 11/10/23 06:06 96-12-81.0 1
Dibromochloromethane ND ug/L 11/10/23 06:06 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 11/10/23 06:06 106-93-40.50 1
Dibromomethane ND ug/L 11/10/23 06:06 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 11/10/23 06:06 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 11/10/23 06:06 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 11/10/23 06:06 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 11/10/23 06:06 75-71-80.50 1
1,1-Dichloroethane ND ug/L 11/10/23 06:06 75-34-30.50 1
1,2-Dichloroethane ND ug/L 11/10/23 06:06 107-06-20.50 1
1,1-Dichloroethene ND ug/L 11/10/23 06:06 75-35-40.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 17 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Sample:MW-8 Lab ID:92697285005 Collected:11/07/23 10:48 Received:11/07/23 15:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
cis-1,2-Dichloroethene ND ug/L 11/10/23 06:06 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 11/10/23 06:06 156-60-50.50 1
1,2-Dichloropropane ND ug/L 11/10/23 06:06 78-87-50.50 1
1,3-Dichloropropane ND ug/L 11/10/23 06:06 142-28-90.50 1
2,2-Dichloropropane ND ug/L 11/10/23 06:06 594-20-70.50 1
1,1-Dichloropropene ND ug/L 11/10/23 06:06 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 11/10/23 06:06 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 11/10/23 06:06 10061-02-60.50 1
Diisopropyl ether ND ug/L 11/10/23 06:06 108-20-30.50 1
Ethylbenzene ND ug/L 11/10/23 06:06 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 11/10/23 06:06 87-68-32.0 1
Isopropylbenzene (Cumene)ND ug/L 11/10/23 06:06 98-82-80.50 1
Methylene Chloride ND ug/L 11/10/23 06:06 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 11/10/23 06:06 1634-04-40.50 1
Naphthalene ND ug/L 11/10/23 06:06 91-20-32.0 1
n-Propylbenzene ND ug/L 11/10/23 06:06 103-65-10.50 1
Styrene ND ug/L 11/10/23 06:06 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 11/10/23 06:06 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 11/10/23 06:06 79-34-50.50 1
Tetrachloroethene ND ug/L 11/10/23 06:06 127-18-40.50 1
Toluene ND ug/L 11/10/23 06:06 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 11/10/23 06:06 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 11/10/23 06:06 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 11/10/23 06:06 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 11/10/23 06:06 79-00-50.50 1
Trichloroethene ND ug/L 11/10/23 06:06 79-01-60.50 1
Trichlorofluoromethane ND ug/L 11/10/23 06:06 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 11/10/23 06:06 96-18-40.50 1
1,2,4-Trimethylbenzene ND ug/L 11/10/23 06:06 95-63-60.50 1
1,3,5-Trimethylbenzene ND ug/L 11/10/23 06:06 108-67-80.50 1
Vinyl chloride ND ug/L 11/10/23 06:06 75-01-41.0 1
m&p-Xylene ND ug/L 11/10/23 06:06 179601-23-11.0 1
o-Xylene ND ug/L 11/10/23 06:06 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)89 %11/10/23 06:06 17060-07-070-130 1
4-Bromofluorobenzene (S)97 %11/10/23 06:06 460-00-470-130 1
Toluene-d8 (S)104 %11/10/23 06:06 2037-26-570-130 1
Analytical Method: SM 4500-H+B-2011
Pace Analytical Services - Asheville
4500H+ pH, Electrometric
pH at 25 Degrees C 5.9 Std. Units 11/09/23 12:42 H30.10 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Sulfate 16.5 mg/L 11/07/23 21:50 14808-79-81.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 18 of 37
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Sample:MW-8 Lab ID:92697285005 Collected:11/07/23 10:48 Received:11/07/23 15:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia ND mg/L 11/15/23 04:55 7664-41-70.10 1
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total ND mg/L 11/16/23 07:12 7727-37-911/15/23 23:490.50 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, NO2 plus NO3 1.7 mg/L 11/08/23 02:180.040 1
Nitrogen, Nitrate 1.7 mg/L 11/08/23 02:18 14797-55-80.040 1
Nitrogen, Nitrite ND mg/L 11/08/23 02:18 14797-65-00.040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 19 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
811746
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
200.7 MET
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92697285001, 92697285002, 92697285003, 92697285004, 92697285005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4202749
Associated Lab Samples:92697285001, 92697285002, 92697285003, 92697285004, 92697285005
Matrix:Water
Analyzed
Arsenic ug/L ND 10.0 11/09/23 16:40
Barium ug/L ND 5.0 11/09/23 16:40
Chromium ug/L ND 5.0 11/09/23 16:40
Iron ug/L ND 50.0 11/09/23 16:40
Lead ug/L ND 5.0 11/09/23 16:40
Manganese ug/L ND 5.0 11/09/23 16:40
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4202750LABORATORY CONTROL SAMPLE:
LCSSpike
Arsenic ug/L 460500 92 85-115
Barium ug/L 477500 95 85-115
Chromium ug/L 470500 94 85-115
Iron ug/L 47705000 95 85-115
Lead ug/L 460500 92 85-115
Manganese ug/L 473500 95 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4202751MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92696335001
4202752
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Arsenic ug/L 500 99 70-130100 1500ND499505
Barium ug/L 500 102 70-130103 150013.2 523 527
Chromium ug/L 500 98 70-13099 1500ND491498
Iron ug/L 5000 104 70-130104 0500030254905510
Lead ug/L 500 95 70-13097 2500ND477484
Manganese ug/L 500 101 70-130101 050024.5 528 530
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4202753MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92696553001
4202754
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Arsenic ug/L 500 109 70-130113 4500ND546566
Barium ug/L 500 118 70-130127 850013.9 602 651
Chromium ug/L 500 113 70-130117 4500ND566590
Iron ug/L M1500013970-130151 75000155085009100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 20 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4202753MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92696553001
4202754
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Lead ug/L 500 107 70-130111 4500ND536557
Manganese ug/L M150013470-130145 850017.8 686 743
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 21 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
811744
EPA 200.8 Rev 5.4 1994
EPA 200.8 Rev 5.4 1994
200.8 MET
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92697285001, 92697285002, 92697285003, 92697285004, 92697285005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4202719
Associated Lab Samples:92697285001, 92697285002, 92697285003, 92697285004, 92697285005
Matrix:Water
Analyzed
Arsenic ug/L ND 1.0 11/08/23 21:14
Barium ug/L ND 1.0 11/08/23 21:14
Chromium ug/L ND 1.0 11/08/23 21:14
Iron ug/L ND 50.0 11/08/23 21:14
Lead ug/L ND 1.0 11/08/23 21:14
Manganese ug/L ND 2.0 11/08/23 21:14
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4202720LABORATORY CONTROL SAMPLE:
LCSSpike
Arsenic ug/L 47.150 94 85-115
Barium ug/L 47.850 96 85-115
Chromium ug/L 52.150 104 85-115
Iron ug/L 13601250 109 85-115
Lead ug/L 51.650 103 85-115
Manganese ug/L 52.250 104 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4202721MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92696337001
4202722
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Arsenic ug/L 50 97 70-13097 0504.6 52.9 53.0
Barium ug/L 50 98 70-13098 0501.8 50.8 50.6
Chromium ug/L 50 100 70-130103 3501.1 51.0 52.7
Iron ug/L 1250 94 70-130104 51250111022902400
Lead ug/L 50 106 70-130106 150ND53.1 53.4
Manganese ug/L 50 100 70-130103 350ND51.3 52.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 22 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
811909
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92697285001, 92697285002, 92697285003, 92697285004, 92697285005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4203833
Associated Lab Samples:92697285001, 92697285002, 92697285003, 92697285004, 92697285005
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 11/10/23 04:35
1,1,1-Trichloroethane ug/L ND 0.50 11/10/23 04:35
1,1,2,2-Tetrachloroethane ug/L ND 0.50 11/10/23 04:35
1,1,2-Trichloroethane ug/L ND 0.50 11/10/23 04:35
1,1-Dichloroethane ug/L ND 0.50 11/10/23 04:35
1,1-Dichloroethene ug/L ND 0.50 11/10/23 04:35
1,1-Dichloropropene ug/L ND 0.50 11/10/23 04:35
1,2,3-Trichlorobenzene ug/L ND 2.0 11/10/23 04:35
1,2,3-Trichloropropane ug/L ND 0.50 11/10/23 04:35
1,2,4-Trichlorobenzene ug/L ND 2.0 11/10/23 04:35
1,2,4-Trimethylbenzene ug/L ND 0.50 11/10/23 04:35
1,2-Dibromo-3-chloropropane ug/L ND 1.0 11/10/23 04:35
1,2-Dibromoethane (EDB)ug/L ND 0.50 11/10/23 04:35
1,2-Dichlorobenzene ug/L ND 0.50 11/10/23 04:35
1,2-Dichloroethane ug/L ND 0.50 11/10/23 04:35
1,2-Dichloropropane ug/L ND 0.50 11/10/23 04:35
1,3,5-Trimethylbenzene ug/L ND 0.50 11/10/23 04:35
1,3-Dichlorobenzene ug/L ND 0.50 11/10/23 04:35
1,3-Dichloropropane ug/L ND 0.50 11/10/23 04:35
1,4-Dichlorobenzene ug/L ND 0.50 11/10/23 04:35
2,2-Dichloropropane ug/L ND 0.50 11/10/23 04:35
2-Chlorotoluene ug/L ND 0.50 11/10/23 04:35
4-Chlorotoluene ug/L ND 0.50 11/10/23 04:35
Benzene ug/L ND 0.50 11/10/23 04:35
Bromobenzene ug/L ND 0.50 11/10/23 04:35
Bromochloromethane ug/L ND 0.50 11/10/23 04:35
Bromodichloromethane ug/L ND 0.50 11/10/23 04:35
Bromoform ug/L ND 0.50 11/10/23 04:35
Bromomethane ug/L ND 5.0 11/10/23 04:35
Carbon tetrachloride ug/L ND 0.50 11/10/23 04:35
Chlorobenzene ug/L ND 0.50 11/10/23 04:35
Chloroethane ug/L ND 1.0 11/10/23 04:35
Chloroform ug/L ND 0.50 11/10/23 04:35
Chloromethane ug/L ND 1.0 11/10/23 04:35
cis-1,2-Dichloroethene ug/L ND 0.50 11/10/23 04:35
cis-1,3-Dichloropropene ug/L ND 0.50 11/10/23 04:35
Dibromochloromethane ug/L ND 0.50 11/10/23 04:35
Dibromomethane ug/L ND 0.50 11/10/23 04:35
Dichlorodifluoromethane ug/L ND 0.50 11/10/23 04:35
Diisopropyl ether ug/L ND 0.50 11/10/23 04:35
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 23 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4203833
Associated Lab Samples:92697285001, 92697285002, 92697285003, 92697285004, 92697285005
Matrix:Water
Analyzed
Ethylbenzene ug/L ND 0.50 11/10/23 04:35
Hexachloro-1,3-butadiene ug/L ND 2.0 11/10/23 04:35
Isopropylbenzene (Cumene)ug/L ND 0.50 11/10/23 04:35
m&p-Xylene ug/L ND 1.0 11/10/23 04:35
Methyl-tert-butyl ether ug/L ND 0.50 11/10/23 04:35
Methylene Chloride ug/L ND 2.0 11/10/23 04:35
n-Butylbenzene ug/L ND 0.50 11/10/23 04:35
n-Propylbenzene ug/L ND 0.50 11/10/23 04:35
Naphthalene ug/L ND 2.0 11/10/23 04:35
o-Xylene ug/L ND 0.50 11/10/23 04:35
sec-Butylbenzene ug/L ND 0.50 11/10/23 04:35
Styrene ug/L ND 0.50 11/10/23 04:35
tert-Butylbenzene ug/L ND 0.50 11/10/23 04:35
Tetrachloroethene ug/L ND 0.50 11/10/23 04:35
Toluene ug/L ND 0.50 11/10/23 04:35
trans-1,2-Dichloroethene ug/L ND 0.50 11/10/23 04:35
trans-1,3-Dichloropropene ug/L ND 0.50 11/10/23 04:35
Trichloroethene ug/L ND 0.50 11/10/23 04:35
Trichlorofluoromethane ug/L ND 1.0 11/10/23 04:35
Vinyl chloride ug/L ND 1.0 11/10/23 04:35
1,2-Dichloroethane-d4 (S)%90 70-130 11/10/23 04:35
4-Bromofluorobenzene (S)%96 70-130 11/10/23 04:35
Toluene-d8 (S)%106 70-130 11/10/23 04:35
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4203834LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 21.520 108 60-140
1,1,1-Trichloroethane ug/L 21.420 107 60-140
1,1,2,2-Tetrachloroethane ug/L 22.320 112 60-140
1,1,2-Trichloroethane ug/L 23.420 117 60-140
1,1-Dichloroethane ug/L 21.920 110 60-140
1,1-Dichloroethene ug/L 20.520 103 60-140
1,1-Dichloropropene ug/L 25.320 127 60-140
1,2,3-Trichlorobenzene ug/L 21.520 107 60-140
1,2,3-Trichloropropane ug/L 20.820 104 60-140
1,2,4-Trichlorobenzene ug/L 21.420 107 60-140
1,2,4-Trimethylbenzene ug/L 22.220 111 60-140
1,2-Dibromo-3-chloropropane ug/L 22.720 113 60-140
1,2-Dibromoethane (EDB)ug/L 23.420 117 60-140
1,2-Dichlorobenzene ug/L 22.020 110 60-140
1,2-Dichloroethane ug/L 20.720 104 60-140
1,2-Dichloropropane ug/L 24.320 121 60-140
1,3,5-Trimethylbenzene ug/L 21.920 110 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 24 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4203834LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 22.320 112 60-140
1,3-Dichloropropane ug/L 22.420 112 60-140
1,4-Dichlorobenzene ug/L 20.720 104 60-140
2,2-Dichloropropane ug/L 20.320 101 60-140
2-Chlorotoluene ug/L 21.620 108 60-140
4-Chlorotoluene ug/L 22.120 110 60-140
Benzene ug/L 22.120 110 60-140
Bromobenzene ug/L 21.920 110 60-140
Bromochloromethane ug/L 23.520 117 60-140
Bromodichloromethane ug/L 21.420 107 60-140
Bromoform ug/L 21.220 106 60-140
Bromomethane ug/L 16.520 82 60-140
Carbon tetrachloride ug/L 20.820 104 60-140
Chlorobenzene ug/L 20.820 104 60-140
Chloroethane ug/L 19.320 96 60-140
Chloroform ug/L 20.920 104 60-140
Chloromethane ug/L 24.920 125 60-140
cis-1,2-Dichloroethene ug/L 21.520 108 60-140
cis-1,3-Dichloropropene ug/L 22.920 114 60-140
Dibromochloromethane ug/L 22.520 112 60-140
Dibromomethane ug/L 21.020 105 60-140
Dichlorodifluoromethane ug/L 25.120 125 60-140
Diisopropyl ether ug/L 24.220 121 60-140
Ethylbenzene ug/L 20.820 104 60-140
Hexachloro-1,3-butadiene ug/L 20.320 102 60-140
Isopropylbenzene (Cumene)ug/L 21.020 105 60-140
m&p-Xylene ug/L 40.940 102 60-140
Methyl-tert-butyl ether ug/L 19.620 98 60-140
Methylene Chloride ug/L 20.920 105 60-140
n-Butylbenzene ug/L 20.820 104 60-140
n-Propylbenzene ug/L 21.020 105 60-140
Naphthalene ug/L 23.720 119 60-140
o-Xylene ug/L 21.520 108 60-140
sec-Butylbenzene ug/L 21.020 105 60-140
Styrene ug/L 22.120 110 60-140
tert-Butylbenzene ug/L 21.620 108 60-140
Tetrachloroethene ug/L 21.220 106 60-140
Toluene ug/L 20.220 101 60-140
trans-1,2-Dichloroethene ug/L 22.120 111 60-140
trans-1,3-Dichloropropene ug/L 22.020 110 60-140
Trichloroethene ug/L 21.520 107 60-140
Trichlorofluoromethane ug/L 18.720 94 60-140
Vinyl chloride ug/L 21.920 109 60-140
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%99 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 25 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4203835MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92697285001
4203836
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 117 60-140121 320ND23.4 24.2
1,1,1-Trichloroethane ug/L 20 118 60-140124 520ND23.5 24.7
1,1,2,2-Tetrachloroethane ug/L 20 118 60-140119 120ND23.7 23.8
1,1,2-Trichloroethane ug/L 20 120 60-140124 320ND24.0 24.8
1,1-Dichloroethane ug/L 20 120 60-140128 620ND23.9 25.5
1,1-Dichloroethene ug/L 20 120 60-140126 520ND24.0 25.1
1,1-Dichloropropene ug/L M12014660-140150 320ND29.1 29.9
1,2,3-Trichlorobenzene ug/L 20 117 60-140120 220ND23.4 24.0
1,2,3-Trichloropropane ug/L 20 111 60-140110 120ND22.2 22.0
1,2,4-Trichlorobenzene ug/L 20 118 60-140121 220ND23.7 24.1
1,2,4-Trimethylbenzene ug/L 20 123 60-140129 520ND24.7 25.8
1,2-Dibromo-3-chloropropane ug/L 20 119 60-140119 020ND23.8 23.9
1,2-Dibromoethane (EDB)ug/L 20 125 60-140126 020ND25.0 25.1
1,2-Dichlorobenzene ug/L 20 119 60-140120 020ND23.9 24.0
1,2-Dichloroethane ug/L 20 108 60-140110 220ND21.6 22.1
1,2-Dichloropropane ug/L 20 135 60-140139 320ND27.0 27.8
1,3,5-Trimethylbenzene ug/L 20 122 60-140125 320ND24.4 25.1
1,3-Dichlorobenzene ug/L 20 122 60-140123 120ND24.3 24.7
1,3-Dichloropropane ug/L 20 120 60-140121 120ND23.9 24.2
1,4-Dichlorobenzene ug/L 20 115 60-140119 320ND23.1 23.7
2,2-Dichloropropane ug/L 20 121 60-140128 520ND24.2 25.5
2-Chlorotoluene ug/L 20 123 60-140124 120ND24.5 24.8
4-Chlorotoluene ug/L 20 123 60-140125 220ND24.5 24.9
Benzene ug/L 20 124 60-140129 320ND24.9 25.7
Bromobenzene ug/L 20 118 60-140123 420ND23.6 24.5
Bromochloromethane ug/L 20 128 60-140132 420ND25.5 26.4
Bromodichloromethane ug/L 20 114 60-140119 420ND22.8 23.7
Bromoform ug/L 20 112 60-140114 120ND22.5 22.8
Bromomethane ug/L 20 72 60-14085 1720ND14.4 17.1
Carbon tetrachloride ug/L 20 124 60-140126 220ND24.7 25.2
Chlorobenzene ug/L 20 116 60-140119 320ND23.1 23.7
Chloroethane ug/L 20 108 60-140116 720ND21.6 23.3
Chloroform ug/L 20 113 60-140119 520ND22.6 23.8
Chloromethane ug/L M12013860-140147 720ND27.5 29.4
cis-1,2-Dichloroethene ug/L 20 119 60-140123 420ND23.7 24.7
cis-1,3-Dichloropropene ug/L 20 124 60-140125 120ND24.8 25.1
Dibromochloromethane ug/L 20 121 60-140119 120ND24.1 23.8
Dibromomethane ug/L 20 112 60-140115 320ND22.4 23.1
Dichlorodifluoromethane ug/L M12017860-140188 620ND35.5 37.7
Diisopropyl ether ug/L 20 125 60-140125 020ND25.0 25.0
Ethylbenzene ug/L 20 115 60-140121 520ND22.9 24.1
Hexachloro-1,3-butadiene ug/L 20 124 60-140129 420ND24.7 25.7
Isopropylbenzene (Cumene)ug/L 20 119 60-140123 320ND23.8 24.5
m&p-Xylene ug/L 40 116 60-140120 340ND46.6 48.0
Methyl-tert-butyl ether ug/L 20 101 60-14099 220ND20.3 19.9
Methylene Chloride ug/L 20 109 60-140117 620ND21.9 23.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 26 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4203835MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92697285001
4203836
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
n-Butylbenzene ug/L 20 123 60-140127 320ND24.7 25.4
n-Propylbenzene ug/L 20 120 60-140123 220ND24.0 24.6
Naphthalene ug/L 20 127 60-140125 120ND25.3 25.1
o-Xylene ug/L 20 118 60-140122 320ND23.5 24.4
sec-Butylbenzene ug/L 20 122 60-140126 320ND24.5 25.2
Styrene ug/L 20 121 60-140124 320ND24.2 24.9
tert-Butylbenzene ug/L 20 104 60-140108 420ND20.7 21.6
Tetrachloroethene ug/L 20 117 60-140121 420ND23.3 24.2
Toluene ug/L 20 114 60-140119 420ND22.8 23.9
trans-1,2-Dichloroethene ug/L 20 123 60-140132 720ND24.6 26.3
trans-1,3-Dichloropropene ug/L 20 118 60-140119 120ND23.5 23.8
Trichloroethene ug/L 20 122 60-140125 320ND24.3 25.1
Trichlorofluoromethane ug/L 20 119 60-140126 620ND23.8 25.2
Vinyl chloride ug/L 20 130 60-140138 520ND26.1 27.5
1,2-Dichloroethane-d4 (S)%90 70-13086
4-Bromofluorobenzene (S)%98 70-13098
Toluene-d8 (S)%99 70-130100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 27 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
812019
SM 4500-H+B-2011
SM 4500-H+B-2011
4500H+B pH
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92697285001, 92697285002, 92697285003, 92697285004, 92697285005
Parameter Units
Dup
Result QualifiersRPDResult
92697285002
4204488SAMPLE DUPLICATE:
pH at 25 Degrees C Std. Units 6.5 H316.4
Parameter Units
Dup
Result QualifiersRPDResult
92697285003
4204489SAMPLE DUPLICATE:
pH at 25 Degrees C Std. Units 6.4 H316.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 28 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
811602
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
300.0 IC Anions
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92697285001, 92697285002, 92697285003, 92697285004, 92697285005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4202137
Associated Lab Samples:92697285001, 92697285002, 92697285003, 92697285004, 92697285005
Matrix:Water
Analyzed
Sulfate mg/L ND 1.0 11/07/23 20:21
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4202138LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate mg/L 51.050 102 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4202139MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92697037011
4202140
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Sulfate mg/L 50 100 90-110103 3502.7 52.8 54.4
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4202293MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92697285005
4202294
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Sulfate mg/L 50 101 90-11099 25016.5 67.1 65.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 29 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
813275
EPA 350.1 Rev 2.0 1993
EPA 350.1 Rev 2.0 1993
350.1 Ammonia
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92697285001, 92697285002, 92697285003, 92697285004, 92697285005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4210897
Associated Lab Samples:92697285001, 92697285002, 92697285003, 92697285004, 92697285005
Matrix:Water
Analyzed
Nitrogen, Ammonia mg/L ND 0.10 11/15/23 04:16
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4210898LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Ammonia mg/L 4.95 98 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4210899MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92696618001
4210900
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Ammonia mg/L 5 96 90-11096 050.035J 4.8 4.8
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4210901MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92696640002
4210902
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Ammonia mg/L 5 96 90-11096 0525.4 30.2 30.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 30 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
813545
EPA 351.2 Rev 2.0 1993
EPA 351.2 Rev 2.0 1993
351.2 TKN
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92697285001, 92697285002, 92697285003, 92697285004, 92697285005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4212213
Associated Lab Samples:92697285001, 92697285002, 92697285003, 92697285004, 92697285005
Matrix:Water
Analyzed
Nitrogen, Kjeldahl, Total mg/L ND 0.50 11/16/23 06:50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4212214LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Kjeldahl, Total mg/L 10.310 103 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4212215MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92697285004
4212216
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Kjeldahl, Total mg/L 10 110 90-110108 210ND11.0 10.8
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4212217MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92697285005
4212218
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Kjeldahl, Total mg/L 10 108 90-110105 210ND10.8 10.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 31 of 37
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
811654
EPA 353.2 Rev 2.0 1993
EPA 353.2 Rev 2.0 1993
353.2 Nitrate + Nitrite, Unpres.
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92697285001, 92697285002, 92697285003, 92697285004, 92697285005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4202417
Associated Lab Samples:92697285001, 92697285002, 92697285003, 92697285004, 92697285005
Matrix:Water
Analyzed
Nitrogen, Nitrate mg/L ND 0.040 11/08/23 01:51
Nitrogen, Nitrite mg/L ND 0.040 11/08/23 01:51
Nitrogen, NO2 plus NO3 mg/L ND 0.040 11/08/23 01:51
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4202418LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Nitrate mg/L 1.51.5 100 90-110
Nitrogen, Nitrite mg/L 0.991 99 90-110
Nitrogen, NO2 plus NO3 mg/L 2.52.5 100 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4202419MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92697326007
4202420
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Nitrate mg/L 1.5 105 90-110105 01.50.058 1.6 1.6
Nitrogen, Nitrite mg/L 1 107 90-110104 21ND1.1 1.1
Nitrogen, NO2 plus NO3 mg/L 2.5 106 90-110105 12.50.058 2.7 2.7
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4202421MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92697207003
4202422
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Nitrate mg/L 1.5 110 90-110110 01.50.59 2.2 2.2
Nitrogen, Nitrite mg/L 1 105 90-110105 01ND1.1 1.1
Nitrogen, NO2 plus NO3 mg/L 2.5 108 90-110108 02.50.59 3.3 3.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 32 of 37
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Sample was received or analysis requested beyond the recognized method holding time.H3
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 33 of 37
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92697285
Blue Ridge Tissue 11/07
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92697285001 811746 811921MW-1 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92697285002 811746 811921MW-3 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92697285003 811746 811921MW-4 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92697285004 811746 811921MW-7 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92697285005 811746 811921MW-8 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92697285001 811744 811917MW-1 EPA 200.8 Rev 5.4 1994 EPA 200.8 Rev 5.4 1994
92697285002 811744 811917MW-3 EPA 200.8 Rev 5.4 1994 EPA 200.8 Rev 5.4 1994
92697285003 811744 811917MW-4 EPA 200.8 Rev 5.4 1994 EPA 200.8 Rev 5.4 1994
92697285004 811744 811917MW-7 EPA 200.8 Rev 5.4 1994 EPA 200.8 Rev 5.4 1994
92697285005 811744 811917MW-8 EPA 200.8 Rev 5.4 1994 EPA 200.8 Rev 5.4 1994
92697285001 811909MW-1 SM 6200B
92697285002 811909MW-3 SM 6200B
92697285003 811909MW-4 SM 6200B
92697285004 811909MW-7 SM 6200B
92697285005 811909MW-8 SM 6200B
92697285001 812019MW-1 SM 4500-H+B-2011
92697285002 812019MW-3 SM 4500-H+B-2011
92697285003 812019MW-4 SM 4500-H+B-2011
92697285004 812019MW-7 SM 4500-H+B-2011
92697285005 812019MW-8 SM 4500-H+B-2011
92697285001 811602MW-1 EPA 300.0 Rev 2.1 1993
92697285002 811602MW-3 EPA 300.0 Rev 2.1 1993
92697285003 811602MW-4 EPA 300.0 Rev 2.1 1993
92697285004 811602MW-7 EPA 300.0 Rev 2.1 1993
92697285005 811602MW-8 EPA 300.0 Rev 2.1 1993
92697285001 813275MW-1 EPA 350.1 Rev 2.0 1993
92697285002 813275MW-3 EPA 350.1 Rev 2.0 1993
92697285003 813275MW-4 EPA 350.1 Rev 2.0 1993
92697285004 813275MW-7 EPA 350.1 Rev 2.0 1993
92697285005 813275MW-8 EPA 350.1 Rev 2.0 1993
92697285001 813545 813639MW-1 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92697285002 813545 813639MW-3 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92697285003 813545 813639MW-4 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92697285004 813545 813639MW-7 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92697285005 813545 813639MW-8 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92697285001 811654MW-1 EPA 353.2 Rev 2.0 1993
92697285002 811654MW-3 EPA 353.2 Rev 2.0 1993
92697285003 811654MW-4 EPA 353.2 Rev 2.0 1993
92697285004 811654MW-7 EPA 353.2 Rev 2.0 1993
92697285005 811654MW-8 EPA 353.2 Rev 2.0 1993
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/16/2023 11:25 AM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 34 of 37
Page 35 of 37
Page 36 of 37
Page 37 of 37