WQ0005910_Monitoring - 11-2023_20231212 (3)

Monitoring Report Submittal
Permit Number#*
Name of Facility:*
Month: * November
Report Information
Type *
GW-59
Confirmation Email Address:
Name of Submitter: *
Signature:
Date of submittal:
Initial Review
WQ0005910
Avoca LLC
Year:* 2023
Upload Document*
Avoca LLC Nov 2023 GW-59 Forms.pdf 3.66MB
PDF Only
Please upload one PDF containing all applicable monitoring reports
(i.e., NDMR, NDAR-1, NDAR-2, NDMLR, GW-59).
[e-mail]
Brian M. Conner
fftt;ew 6W C Cart
Reviewer: Wanda.Gerald
12/12/2023
This will be filled in automatically

Is the project number correct?* WQ0005910
Is the monitoring report accepted?* Yes No
Regional Office* Washington
Reviewer: _anonymous
Review Date: 12/19/2023

GW-59A COMPLIANCE REPORT FORM Permit # Q OooGc\ 1 C)
(Subunit nine each ►►iouiloriug period milli GIV-59 forms.)
I
Enter date monitoring results were due. (ta-3\ -.Z Will this monitoring report (GW-59 and GW-59A)
YES
NO
be submitted after the established due date?
2
Was any required information missing on the GNV-59 report forms?
YES
NO
IF the answer to question 1 or 2 is 'YES", list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
/
V
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
YES
NO
identification plate, area overgrown, etc.)? If the answer is "}es", contact the Regional Dfceforguidance.
4
Are any monitored constituents equal to or above the established standards?
YES
NO
If the answer to question 4 is "NO", skip to section 8.
If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s)
exceeding standards in the space provided below:
tot- mvoS - Ukoo
MW (b - -1,50
5
For the constituents identified in question 4 above, have standards been exceeded previously for the
YES
NO
same constituent(s) in the same well(s) in the last two years?
If the answer to question 5 is "NO'; skip to section 8.
if the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding
standards, concentration(s) reported, and sample collection date for each oc urrence (for the last two years).
1h�1�3-�0•�$ z►anln-\�.qt. 't1„►-)a-la%o -1I1o11z-1>o -�tk,la3-sso 'tti]A1ri-sqo
31ab1z'i-1-14 3)aol�a-�1.5 3bV11-kolo 31aol2z-ulo 31�g1�,Z-s�o 3130117�-S�10
•�t+ Ut1�1�Z-�3o \�I1'bl>'2-St.O �\1►1.111-SRO
6
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
YES
NO
If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly
located; contact the Regional Office.
V
7
Is the permittee implementing previously approved actions required by the Division involving this
YES
NO
groundwater quality problem?
If the answer to question 7 is "YES", describe those actions in the space provided below.
If the answer to question 7 is "NO", contact the Regional Office within 90 days; an evaluation may be
required to determine the impact the waste disposal system is having at the review and compliance
boundaries surrounding this facility. Failure to do so ►may subject the permittee to a Notice of Violation,
fines, and/or penalties.
g
The person completing this portion (GW-59A) of the monitoring report should sign below and submit this
form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form.
I hereby acknowledge that the above information was evaluated and the information submitted in this
report (Compliance Report GW-59A) is true and complete to the best of my knowledge.
j
O —\-;w—
Signature of Perntittee Or uthorized Agent) Date
G\V-59A 12/8/2003

SUBMIT FORM ON YELLOW PAPER ONLY
• .
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone:9IM07-6306
FACILITY INFORMATION Please Print Clearly or Type
PERMIT Number: Expiration Date: 10'3�-ZO Z
Facility Name: Avoca LLC
Non -Discharge W00005910 UIC
Permit Name (if different):
NPDES Other
Facility Address: (;\A\ A.":pc' �Gl,r rvi
TYPE OF PERMITTED OPERATION BEING MONITORED
❑Lagoon ❑Remediation: Infiltration Gallery
str
(eeU Z7Q(S--1 Count Bertie L y
�
(Cil) Sate! Zp1
X Spray Field ❑Remediation:
Contact Person: Brian Conner
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:Avoca LLC
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
;from Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): - S
Date sample collected: L\"�S -Z3
FIELD ANALYSES:
WAS
Well Depth: 21-'I ft.
Well Diameter: 2. in.
pH 00400:LJ43units Temp. 00010: Vii •`L0 eC
DRY at
Depth to Water Level 82546: 10. 3 ft. below measuring point Screened Interval: ft. to 7.2.
ft. Spec. Cond. 000sa: µMhos
time of
sampling,
Measuring Point is Z. ft. above land surface
Relative M.P. Elevation: ft.
Odor 00085: e-.
check
Volume of water pumped/bailed before sampling: gallons �/
Appearance Ck"l
here:❑
Samples for metals were collected unfiltered: YES
❑ NO and field acidified: DYES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: 11-kS-a 3 -� \1-S { 23
, ^
Laboratory Name: tatty po�.��
tuna\y Certification No. lO
PARAMETERS NOTE: Values should reflect dissolved
and colloidal concentrations.
COD 00335 mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 /100mL
Nitrate (NO3) as N 00620 L Q , Q 1.}
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL
Phosphorus: Total as P 00665 Q . 8
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 5C60 mg/L
Al - Aluminum 01105
mg/L
pH (Lab) 00403 units
Ba - Barium 01007
ug/L
TOC 00680 2.(08 mg/L
Ca - Calcium 00916 32. C)
mg/L
Chloride oos4o mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002 ug/L
Chromium: Total o1034
ug/L
Grease and Oils 00552 mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
Fe - Iron 01045
ug/L
TACH LAB REPORT.)
(Specify test and methoVes
Sulfate 00945 mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? (1) ❑ No (0)
pecific Conductance 00095 µMhos
K - Potassium 00937
mg/L VOC 7873 method #
Total Ammonia 0o6lo mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
, method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs:
Samye.\ L. 1�:,Y ,n ply+ Mir.
Permittee (or Authorized Agent) Name and Title - Please print or type
Totalmg/L Effluent •
iplete. and that the laboratory analytical data
t possibility of fines and imprisonment for knt
r'W._
mg/L VOC Removal%
� 2-12-23
(Date)
GW-59 Rev.3-1-2016

SUBMIT FORM ON YELLOW PAPER ONLY
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
-
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone:[phone]
FACILITY INFORMATION Please Print Clearly or Type
PERMIT Number: Expiration Date:
Facility Name: Avoca LLC
Non -Discharge W00005910 UIC
Permit Name (if different):
NPDES Other
Facility Address: ' jA\ A"'J'�C.ck emu.. Qd -
TYPE OF PERMITTED OPERATION BEING MONITORED
❑Lagoon ❑Remediation: Infiltration Gallery
, 2.19 S� County Bertie
�f 2
(City)(Stater ("Lip)
A Spray Field ❑ Remediation:
Contact Person: Brian Conner
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:Avoca LLC
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
WELL ID NUMBER (from Permit): M� -�
Date sample collected: k k- l5'23
FIELD ANALYSES:
If WELL
WAS
Well Depth: vooft.
Well Diameter: 2 in.
pH 00400:"1Hlunits Temp. o0oio: too-Z °C
DRY at
Depth to Water Level 82546: C( .2.. ft. below measuring point
Screened Interval: :s::ft. to
Q
I Uft. Spec. Cond. 00094: uMhos
time ofsampling,
Measuring Point is �. ft. above land surface
Relative M.P. Elevation: ft.
Odor o0085: ^jp,nt
check
Volume of water pumped/bailed before sampling: S
gallons
Appearance
here:❑
Samples for metals were collected unfiltered: ErYES ❑
NO and field acidified: BYES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: ��' 15-�3 'J1 k-L-15
LaboratoryName: �a� �a.r��'
y�c.1.s�;�1 Certification No. �Q
PARAMETERS NOTE: Values should reflect dissolved and
colloidal concentrations.
COD 00335 mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 /100mL
Nitrate (NO3) as N 00620 "�'J
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL Phosphorus: Total as P o0665 L , p1-{
mg/L
(Note: use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 k-1 0 mg/L
AI - Aluminum 011o5
mg/L
pH (Lab) 00403 units
Ba - Barium 01007
ug/L
TOC oofiso 3 , s mg/L
Ca - Calcium 00916 -j , Sj LA
mg/L
Chloride 00940 33 mg/L
Cd - Cadmium 01027
ug/L
Arsenic olon ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552 mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
Fe - Iron 01045
ug/L
(Specify test and method #./kTTACH LAB REPORT.)
Sulfate 00945 mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? Yes (1) ❑ No (0)
pecific Conductance 00095 uMhos
K - Potassium 00937
mg/L VOC 7873 method #
Total Ammonia o0610 G Q . a LA mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
Permittee (or Authorized Aqent) Name and Title - Please print or type
GW-59 Rev.3-1-2016
(Date)

SUBMIT FORM ON YELLOW PAPER ONLY
• •
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION Please Print Clearly or Type
PERMIT Number: Expiration Date: 1 Q X —202.
Facility Name: Avoca LLC
Non -Discharge WQ0005910 UIC
Permit Name (if different):
NPDES Other
Facility Address: %%A% pjtz cc, (711,'- n
TYPE OF PERMITTED OPERATION BEING MONITORED
(streeq
I,i C.r 2�I q
1 County Bertie
El Lagoon ❑Remediation: Infiltration Gallery
( iiy) (state) (zip)
❑■ Spray Field ❑ Remediation:
Contact Person: Brian Conner
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:AVoca LLC
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
WA3 -
FIELD ANALYSES:
If WELL
WAS
WELL ID NUMBER (from Permit):
Date sample collected:
Well Depth: 100 ft.
Well Diameter: 2- in.
pH 00400;(p.lounits Temp. 00010: 2°C
DRY at
Depth to Water Level 62546:S.$ ft. below measuring point
Screened Interval: a�ft. to ft.
Spec. Cond. 000sa: µMhos
time ofsampling,
Measuring Point is �-- ft. above land surface
Relative M.P. Elevation: ft.
Odor o0085: NQ,%R-
check
Volume of water pumped/bailed before sampling:
gallons
Appearance L\cAy
here:❑
Samples for metals were collected unfiltered: YES ❑
NO and field acidified: 2// YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: %%-k`S-Z3
Laboratory Name: S ,�C1 O01„�
i",/�
SM\'I�;
C 11 Certification No.�
PARAMETERS NOTE: Values should reflect dissolved and
colloidal concentrations.~�'
COD 00335 mg/L
Nitrite (NO2) as N 00615
mg/L
Pb - Lead o1o51 ug/L
Coliform: MF Fecal 31616 /100mL
Nitrate (NO3) as N 00620 0 . LALk
mg/L
Zn - Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 2..2.1
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L
Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 C) mg/L
Al -Aluminum olim
mg/L
pH (Lab) 00403 units
Ba - Barium 01007
ug/L
TOC oo66o fo .O—I mg/L
Ca - Calcium oos16 4 D . O Ls'1
mg/L
Chloride oo94o ZS mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002 ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552 mg/L
Cu - Copper 01042
mg/L
ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
Fe - Iron 01045
ug/L
TACH LAB REPORT.)
(Specify test and methoVes
Sulfate 00945 mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? (1) ❑ No (0)
pecific Conductance 00095 µMhos
K - Potassium 00937
mg/L
VOC 7873 method #
Total Ammonia ooseo mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen. Total)
Mn - Manganese 01055
ug/L
method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
GW-59 Rev.3-1-2016

SUBMIT FORM ON YELLOW PAPER ONLY
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC27699-1617 Phone:[phone]
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date: - O
Facility Name: Avoca LLC
Non -Discharge WQ0005910 UIC
Permit Name (if different):
NPDES Other
Facility Address: 00L\l Pt%J0 (cx
TYPE OF PERMITTED OPERATION BEING MONITORED
�. ` (Street) N C.
� �
2-j
-7 Coun
County Bettie
El Lagoon ❑Remediation: Infiltration Gallery
( ly) (state)
(zip)
X■ Spray Field ❑ Remediation:
Contact Person: Brian Conner
Telephone* 252-482-2133
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:Avoca LLC
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION n�eA
WELL ID NUMBER (from Permit): Mw— 9
Date sample collected: 11 ^1'�' 2?j
FIELD ANALYSES:
If WELL
WAS
Well Depth: 2.2.00 ft.
Well Diameter: 2 in.
pH oo400:S.5qunits Temp. 0oolo: \i °C
DRY at
Depth to Water Level 82546: tL{ ft. below measuring point Screened Interval: 10 ft. to a 3 ft. Spec. Cond. 00094: µMhos
time ofsampling,
Measuring Point is 2. ft. above land surface
Relative M.P. Elevation: ft.
Odor 00085: w o^f_
check
Volume of water pumped/bailed before sampling:
S
gallons
Appearance Lk k.r
here:❑
Samples for metals were collected unfiltered: YES ❑ NO and field acidified: R// ES ❑ NO
LABORATORY INFORMATION
Date sample analyzed:
LaboratoryName:
Certification No.�
PARAMETERS NOTE: Values should reflect
dissolved
and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead olo51 ug/L
Coliform: MF Fecal 31616
/100mL
Nitrate (NO3) as N 00620 3 6Q
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300
mg/L
Al - Aluminum oilo5
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC 00680 4 , .O 0
mg/L
Ca - Calcium 00916 yQ ����
mg/L
Chloride oo94o 2.2-
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total olo34
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron o1045
ug/L
(Specify test and method #. TTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? 9 Yes (1) ❑ No (0)
pecific Conductance 00095
µMhos
K - Potassium 00937
mg/L VOC 7873 method #
Total Ammonia oo6lo L O . d
mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen: NH,, as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
JGtmvGk I- - 1•tv t,. Nilx^!� q tr-
Permittee (or Authorized AqentT Name and Title - Please print or
GW-59 Rev.3-1-2016

SUBMIT FORM ON YELLOW PAPER ONLY
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone:9IM07-6306
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date: kV '31^ 10�
Facility Name: Avoca LLC
Non -Discharge WQ0005910 UIC
NPDES Other
Permit Name (if different):
Facility Address: 93L{\ IrVOca ;z Y-M
1��f�
•
TYPE OF PERMITTED OPERATION BEING MONITORED
El Lagoon ❑Remediation: Infiltration Gallery
1--a-1
County Y� ty Bertie
X Spray Field ❑ Remediation:
Contact Person: Brian Conner
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:Avoca LLC
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): M W _
1 c)
Date sample collected: 1 X -I G' ;L
3
FIELD ANALYSES:
WAS
Well Depth: 2 oft.
Well Diameter: 2. in.
pH ooaco 3.4to units Temp. 00010: WaA eC
DRY at
Depth to Water Level s25a6: \ ft. below measuring
p
g point Screened Interval: 3 ft. to
Z.O
ft. Spec. Cond. 0009<: uMhos
time of
sampling,
Measuring Point is 2. ft. above land surface
Relative M.P. Elevation: ft.
Odor 00085:
check
Volume of water pumped/bailed before sampling:
S'
gallons
Appearance C \e_af
here:❑
Samples for metals were collected unfiltered: [YES
^�
El NO and field acidified: L9 �'ES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: 1\���-�3 ��-� �3
Laboratory Name: `A C4�:A po ^^ -
y \
�,nQ\�►Tic�� Certification No. 1
PARAMETERS NOTE: Values should reflect dissolved
and colloidal concentrations.
COD o0335
mg/L
Nitrite (NO2) as N oos15
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616
/100mL
Nitrate (NO3) as N 00620 .4b d
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/10OmL
Phosphorus: Total as P 00665 L O • O LA
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 2�
mg/L
Al -Aluminum o1105
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOO oosso
mg/L
Ca - Calcium 00916 2.1 . S �i Lv
mg/L
Chloride 00940 '1
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01o34
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L
(Specify test and method#/ATTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? Lid" Yes (1) ❑ No (0)
pecific Conductance 000m
uMhos
K - Potassium 00937
mg/L VOC 7873 method #
Total Ammonia oc6lo <. Q , LA
mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH3as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
GW-59 Rev.3-1-2016

SUBMIT FORM ON YELLOW PAPER ONLY
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
111617
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone:[phone]
FACILITY INFORMATION Please Print Clearly or Type
PERMIT Number: Expiration Date:
Facility Name: Avoca LLC
Non -Discharge W00005910 UIC
Permit Name (if different):
NPDES Other
r� c�
Facility Address: 'i7y � AV O ALL
TYPE OF PERMITTED OPERATION BEING MONITORED
f*A '�v ; %, (Street) t'J` Z�C
County Bertie
❑ Lagoon ❑ Remediation: Infiltration Gallery
( ity) (St-te) (zip)
❑■ Spray Field ❑Remediation:
Contact Person: Brian Conner
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:Avoca LLC
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit):
Date sample collected:
FIELD ANALYSES:
WAS
Well Depth: Z 0 ft.
Well Diameter: Z in.
pH ooaoo:114.43 units Temp. 000lo: 1l0 °C
DRY at
Depth to Water Level 825a6: �3,?j ft. below measuring
p g point
Screened Interval: 3 ft.
to20
ft. Spec. Cond. 000sa: µ Mhos
time of
sampling,
Measuring Point is 2- ft. above land surface
Relative M.P. Elevation:
ft.
Odor 00085: O vnQ
check
Volume of water pumped/bailed before sampling: 5
gallons
Appearance Clear
here:❑
Samples for metals were collected unfiltered: ES ❑
NO and field acidified: 5?�ES
❑ NO
LABORATORY INFORMATION
Date sample analyzed: \\-�S-Z3 � \rl-s"a3
Laboratory Name: \.0ay �a.,n�
N1a�yr;
11 .nn
C. Certification No. 1V
PARAMETERS NOTE: Values should reflect dissolved and
colloidal concentrations.
COD 00335 mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead o1o51 ug/L
Coliform: MF Fecal 31616 /100mL
Nitrate (NO3) as N 00620 4 0 , 0�"E mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 , \ L0
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 kp(o mg/L
Al -Aluminum olim
mg/L
pH (Lab) 00403 units
Ba - Barium 01007
ug/L
TOC 00680 \ \ • LOCI mg/L
Ca - Calcium 00916 mg/L
Chloride oosao 2.1 mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002 ug/L
Chromium: Total wou
ug/L
Grease and Oils 00552 mg/L
Cu - Copper 01042
mg/L
ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
Fe - Iron 01045
ug/L
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate oo945 mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? ,&—y Yes (1) ❑ No (0)
pecific Conductance 00095 µMhos
K - Potassium 00937
mg/L
VOC 7873 method #
Total Ammonia 00610 \Z--Zoo mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
method #
TKN as N 00625 mg/L
Ni - Nickel mo67
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete. and that the laboratory analytical data was produced using approved methods of analysis by a
DWR-certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations.
I c.k L- 7 1? I&,"t- y
ittee (or Authorized Agent) ame and Title - Please print or
GW-59 Rev.3-1-2016
(Date)

Waypoint.0
ANALYTICAL
114 OAKMONT DRIVE
GREENVILLE, NC 27858
AVOCA, LLC (WASTEWATER)
MR. BRIAN CONNER
P.O. BOX 129
MERRY HILL, NC 27957
Drinking Water ID: 37715
Waatew tar ID i 10
PHONE [phone]
FAX [phone]
ID# : 132
DATE COLLECTED: 11/15/23
DATE REPORTED : 12/06/23
REVIEWED BY:
Effluent
Well N5
Well H7
Well N8
Well N9
Analysis
Method
PARAMETERS
Date
Analyst
Code
BOD, rng/I
r 357
11/15/23
HMV
5210I3-16
Total Suspended Residue, mg/I
107
11/16/23
BNC
2540D-15
Anunonia Nitrogen as N, mg/I
<0.04
11/19/23
TRJ
350.1 112-93
Ammonia Nitrogen as N, mg/I
0.11
<0.04
1.17
<0.04
11/21/23
TRJ
350.1 112-93
Total Kjeldald Nitrogen as N,mg/I
22.40
12/05/23
TRJ
351.2 112-93
Nitrate+Nitrite as N, mg/I (calc)
0.11
353.2 112-93
Nitrate Nitrogen as N, mg/I
<0.04
<0.04
1.73
0.44
3.69
11/16/23
AMC
353.2 112-93
Nitrite Nitrogen as N, mg/I
0.11
11/15/23
AMC
353.2 112-93
Total Phosphorus as P, mg/I
2.70
0.08
<0.04
2.21
0.10
11/20/23
AMC
365.4-74
Total Organic Carbon, mg/I
2.68
3.53
16.07
<1.00
11/21/23
BLV
531OC-14
Chloride, mg/I
64
11/22/23
BNC
4500CLB-11
Chloride, mg/I
31
33
25
22
11/19/23
ADR
4500CLB-11
Total Dissolved Residue, mg/I
1600
580
170
780
190
11/20/23
BNC
D5907-13
C8lcium, ug/l
8855
32024
7574
40064
40474
11/16/23
MTNI
EPA200.7
Magnesium, ug/I
2347
11/16/23
MTM
EPA200.7
Sodium, ug/I
189960
11/16/23
MTM
EPA200.7
Sodium Adsorption Ratio (calc)
14.7
Total Nitrogen, mg/I (calc)
22.51
All QC requirements Were not meta r Replicate varied by more than 30%.

Wayposinto
ANALYTICAL
114 OAKMONT DRIVE
GREENVILLE, NC 27858
AVOCA, LLC (WASTEWATER)
MR. BRIAN CONNER
P.O. BOX 129
MERRY HILL, NC 27957
Well #10 Well #11
PARAMETERS
Drinking Water IDS 37715
Wastewater ID: 10
PHONE [phone]
FAX [phone]
ID##: 132
DATE COLLECTED: 11/15/23
DATE REPORTED : 12/06/23
REVIEWED BY:
Analysis Method
Date Analyst Code
Anunonin Nitrogen as N, ing/1
<0.04
12.28
11/21/23
TRJ
350.1 112-93
Nitrate Nitrogen as N, mg/I
6.80
<0.04
11/16/23
AMC
353.2 112-93
Total Phosphorus as P, mg/I
<0.04
0.16
11/20/23
AMC
365.4-74
Total Organic Carbon, mg/l
1.57
11.60
11/21/23
BLV
531OC-14
Chloride, mg/I
71
27
11/19/23
ADR
4500CLB-11
Total Dissolved Residue, mg/l
280
660
11/20/23
BNC
D5907-13
Calcium, ug/I
21596
20141
11/16/23
MTM
EPA200.7
All QC requirements were not met: r Replicate varied by more than 30%.

i
Waypoint,,.
ANALYTICAL
114 OAKMONT DRIVE
GREENVILLE, NC 27858
CLIENT: AVOCA, LLC (WASTEWATER)
MR. BRIAN CONNER
P.O. BOX 129
MERRY HILL, NC 27957
REVIEWED BY:
VOLATILE ORGANICS
STD. METHODS 8260D
Drinking Water ID: 37715
Want ewater ID: 10
PHONE [phone]
FAX [phone]
CLIENT ID: 132
ANALYST: JAP
DATE COLLECTED: 11/15/23 Page: 1
DATE ANALYZED: 11/17/23
DATE REPORTED: 12/06/23
PARAMETERS, ug/I
Well N5
Well #7
Nell #8
Well #9
Well #10
1. Benzene
<0.50
<0.50
<0.50
<0.50
<0.50
2. Bromobenzene
<0.50
<0.50
<0.50
<0.50
<0.50
3. Bromochloromethane
<0.50
<0.50
<0.50
<0.50
<0.50
4. Bronlodichloronnelhanc
<0.50
<0.50
<0.50
<0.50
<0.50
5. Bromoform
<0.50
<0.50
<0.50
<0.50
<0.50
6. Bromonlelhane
<0.50
<0.50
<0.50
<0.50
<0.50
7. N-Butylhenzeue
<0.50
<0.50
<0.50
<0.50
<0.50
8. Sec-Bulylbenzene
<0.50
<0.50
<0.50
<0.50
<0.50
9. Tert-Butylbenzene
<0.50
<0.50
<0.50
<0,50
<0.50
10. Carbon Tetrachloride
<0.50
<0.50
<0.50
<0.50
<0.50
It. Chlorobenzene
<0.50
<0.50
<0.50
<0.50
<0.50
12. Chloroelhane
<0.50
<0.50
<0.50
<0.50
<0.50
13. Chloroform
<0.50
<0.50
<0.50
<0.50
<0.50
14. Chloromethane
<0.50
<0.50
<0.50
<0.50
<0.50
15. 2-Chlorotoluene
<0.50
<0.50
<0.50
<0.50
<0.50
16. 4-Chlorofohnene
<0.50
<0.50
<0.50
<0.50
<0.50
17. Dibromochloromethane
<0,50
<0.50
<0.50
<0.50
<0.50
18. 1,2-Dibronio-3-Chloropropane
<0.50
<0.50
<0.50
<0.50
<0.50
19. 1,2-11)ibromoethanc
<0.50
<0.50
<0.50
<0.50
<0.50
20. Dibromomethane
<0.50
<0.50
<0.50
<0.50
<0.50
21. 1,2-Dichloroberrrene
<0.50
<0.50
<0.50
<0.50
<0.50
22. 1,3-Dichlorobenzene
<0.50
<0.50
<0.50
<0.50
<0.50
23. 1,4-Dichlorobenzene
<0.50
<0.50
<0.50
<0.50
<0.50
24. Dichlorodifluoi-omelhane
<0.50
<0.50
<0.50
<0.50
<0.50
25. 1,1-Dichloroethane
<0.50
<0.50
<0.50
<0.50
<0.50
26. 1,2-Dichloroethane
<0.50
<0.50
<0.50
<0.50
<0.50
27. 1,1-Dichloroethene
<0.50
<0.50
<0.50
<0.50
<0.50
28. Cis-1,2-Dichloroethene
<0.50
<0.50
<0.50
<0.50
<0.50
29. trans-1,2-Dichloroethene
<0.50
<0.50
<0.50
<0.50
<0.50
30. 1,2-Dichloroprop:me
<0.50
<0.50
<0.50
<0.50
<0.50
31. 1,3-Dichloropropene
<0.50
<0.50
<0.50
<0.50
<0.50
32. 2,2-Dichloropropme
<0.50
<0.50
<0.50
<0.50
<0.50
33. 1,l-Dichloropropene
<0.50
<0.50
<0.50
<0.50
<0.50
34. Cis-1,3-Dichloropropene
<0.50
<0.50
<0.50
<0.50
<0.50
35. trans-1,3-Dichloropropene
<0.50
<0.50
<0.50
<0.50
<0.50
36. E(hylbenzene
<0.50
<0.50
<0.50
<0.50
<0.50
37. Hexachlorobutadiene
<0.50
<0.50
<0.50
<0.50
<0.50
38. Isopropylbenzene
<0.50
<0.50
<0.50
<0.50
<0.50
39. 4-Isopropyltoluenc
<0.50
<0.50
<0.50
<0.50
<0.50
40. Methylene Chloride
<0.50
<0.50
<0.50
<0.50
<0.50
41, Naphthalene
<0.50
<0.50
<0.50
<0.50
<0.50
42. Propylbenzene
<0.50
<0.50
<0.50
<0.50
<0.50
43. Styrene
<0.50
<0.50
<0.50
<0.50
<0.50
44. 1,1,1,2-Teirnehloroelhane
<0.50
<0.50
<0.50
<0.50
<0.50
45. 1,1,2,2=letrachloroeflume
<0.50
<0.50
<0.50
<0.50
<0.50
46. retrachloroethene
<0.50
<0.50
<0.50
<0.50
<0.50
47. 'Toluene
<0.50
<0.50
<0.50
<0.50
<0.50
48. 1,2,3-Trichlorobenzenc
<0,50
<0.50
<0,50
<0.50
<0.50

Waypointo
ANALYTICAL
114 OAKMONT DRIVE
GREENVILLE, NC 27858
CLIENT: AVOCA, LLC (WASTEWATER)
MR. BRIAN CONNER
P.O. BOX 129
MERRY HILL, NC 27957
REVIEWED BY:
VOLATILE ORGANICS
STD. METHODS 8260D
Drinking Water IDi 17715
Mlaotawater ID: 10
PHONE [phone]
FAX [phone]
CLIENT ID: 132
ANALYST: JAP
DATE COLLECTED: 11/15/23 Page: 2
DATE ANALYZED: 11/17/23
DATE REPORTED: 12/06/23
PARAMETERS, ug/I
Well N5
Well #7
Well N8
Well N9
Nvell #10
49. 1,2,4-Trichlorobenzene
<0.50
<0.50
<0.50
<0.50
<0.50
50. 1,1,1-Trichloroethanc
<0.50
<0.50
<0.50
<0.50
<0.50
51. 1,1,2-Trichloroethane
<0.50
<0.50
<0.50
<0.50
<0.50
52. Trichloroelhene
<0.50
<0.50
<0.50
<0.50
<0.50
53. 'I'richlol•olluol•omethane
<0.50
<0.50
<0.50
<0.50
<0.50
54. 1,2,3-Trichloropropaoc
<0.50
<0.50
<0.50
<0.50
<0.50
55. 1,2,4=I'rimetiq,11)en•rene
<0.50
<0.50
<0.50
<0.50
<0.50
56. 1,3,5-Trimethylbenzene
<0.50
<0.50
<0.50
<0.50
<0.50
57. Vinyl Chloride
<0.50
<0.50
<0.50
<0.50
<0.50
58. Totol Xylenes
< 1.00
< 1.00
< 1.00
< 1.00
< 1.00
59. rvleliryl 'Cent Butyl Ether
< 1.00
< 1.00
< 1.00
< 1.00
< 1.00

Waypointo
ANALYTICAL
114 OAKMONT DRIVE
GREENVILLE, NC 27858
CLIENT: AVOCA, LLC (WASTEWATER)
MR. BRIAN CONNER
P.O. BOX 129
MERRY HILL, NC 27957
REVIEWED BY:
VOLATILE ORGANICS
STD. METHODS 8260D
Drinking Water IDs 37715
We tewater IDt 10
PHONE [phone]
FAX [phone]
CLIENT ID: 132
ANALYST: JAP
DATE COLLECTED: 11/15/23
DATE ANALYZED: 11/17/23
DATE REPORTED: 12/06/23
PARAMETERS, ug/I
Well all
1.
Benzene
<0.50
2.
Bromobenzene
<0.50
3.
Bromochloromefhnne
<0.50
4.
Bronlodielulo-onetluane
<0.50
5.
Bromoform
<0.50
6.
Bromomethane
<0.50
7.
N-Bulylbenzene
<0.50
8.
Sec-Bulylbenzene
<0.50
9.
Tert-Bulylbenzene
<0.50
10.
Carbon Teh-achloride
<0.50
11.
Chlorobenzene
<0.50
12.
Chloroethnue
<0.50
13.
Chloroform
<0.50
14.
Chloromefhane
<0.50
15.
2-Chlorotoluene
<0.50
16.
4-Chlorotolnene
<0.50
17.
Dibromochloromethnne
<0.50
18.
1,2-Dibromo-3-Cllo-opropane
<0.50
19.
1,2-Dibromoethaue
<0.50
20.
Dibromomethnne
<0.50
21.
1,2-Dichlorobenzene
<0.50
22.
1,3-Dichlorobenzene
<0.50
23.
1,4-Dichlorobenzene
<0.50
24.
Dichlorodifluoromeflnne
<0.50
25.
1,1-Dichloroethane
<0.50
26.
1,2-Dichloroethane
<0.50
27.
1,1-Dichloroeihene
<0.50
28.
Cis- 1,2-Dichlo oethene
<0.50
29.
lraus-1,2-Dichloroethene
< 0.50
30.
1,2-Dichloropropanc
< 0.50
31.
1,3-Dichloropropanc
<0.50
32.
2,2-Dichloropropanc
<0.50
33.
1,1-Dichloropropene
<0.50
34.
Cis-1,3-Dichloropropene
< 0.50
35.
frans-1,3-Dichloropropene
<0.50
36.
Ethylbenzene
<0.50
37.
Herachlorobulldiene
<0.50
38.
lsopropylbenzene
<0.50
39.
4-Isopropylloluene
<0.50
40.
Methylene Chloride
<0.50
41.
Naphthalene
<0.50
42.
Propylbenzene
< 0.50
43.
Styrene
<0.50
44.
1,1,1,2-Tefrachloroethane
<0.50
45.
1,1,2,2-Telrachloroethane
< 0.50
46.
Tetrachloroeihene
<0.50
47.
Toluene
<0.50
48.
1,2,3-Trichlorobenzene
<0.50
Page: 3

Waypoint.
ANALYTICAL
114 OAKMONT DRIVE
GREENVILLE, NC 27858
CLIENT: AVOCA, LLC (WASTEWATER)
MR. BRIAN CONNER
P.O. BOX 129
MERRY HILL, NC 27957
REVIEWED BY: /
VOLATILE ORGANICS
STD. METHODS 8260D
Drinking Slater ID t 37715
Waetowater IDS 10
PHONE [phone]
FAX [phone]
CLIENT ID: 132
ANALYST: JAP
DATE COLLECTED: 11/15/23 Page: 4
DATE ANALYZED: 11/17/23
DATE REPORTED: 12/06/23
PARAMETERS, ug/I
Well #11
49.
1,2,4-Trichlorobcnzene
<0.50
50,
1,1,1-Trichloroclhane
<0.50
51.
1,1,24'richloroelhanc
<0.50
52.
Trichloroethcnc
< 0.50
53.
7'richloroFluoroinethaue
<0.50
54.
1,2,3-Trichloropropanc
<0.50
55.
1,2,4-Trimethylbenzene
<0.50
56.
1,3,5-Trimelhylbenzene
<0.50
57.
Vinyl Chloride
<0.50
58,
'Total Xylenes
< 1.00
59.
N4ethyl Tert 11nlyl Ether
< 1.00

r AJs3y�11ii
Waypoint Analytical - Greenville
lien v .n.
CHAIN OF CUSTODY RECORD
Page 1 of 2
Greenville. NC 27858
DISINFECTION
\(
CHLORINE CHECK (
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Phone [phone] • Fax [phone]
CHLORINE
:0 5 mglL -Yes (Y) or Noo (N)
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pH CHECK (S.U.) (LAB)
CLIENT: 132 Week: 51
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P
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CONTAINER TYPE, PIG
,VOCA, LLC (WASTEWATER)
❑ NONE
4R- BRIAN CONNER
'.O. BOX 129
I
CHEMICALPRESERVATION
4ERRY HILT. NC 27957
A
A
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C
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SAMPLES COLLECTED BY
(Please Pnnt)
SAMPLES RECEIVED IN LAB AT �%.r% °C
RELINQUISHED BY (SIG) (SAMPLER)
DATEMME
RECEIVED BY (SIG)
DATEMME
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SAMPLES RECEIVED ON ICE. E - NO
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DAT15TIME
PLEASE READ Instructions for completing this form on the reverse side. Sampler must place a "C for composite sample or a "T for
FORM z5 Grab sample in the blocks above for each parameter requested

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_LY71U
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Waypoint Analytical - GreenvilIe
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❑ NONE
I R. BR1AN CONNER
1-0. BOX 129
CHEMICALPRESERVAT10N
MERRY HILL NC 27957
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Effluent
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CLASSIFICATION•
❑ WASTEWATER (NPDES)
WeR #4
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Well #5
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Well #11
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SAMPLES COLLECTED BY:
(Please Pnnt)
IL
SAMPLES RECEIVED IN LAB AT °C
RELINQUISHED BY (SIG.) (SAMPLER)
DATEMME
RECEIVED BY (SIG)
DATEMME
COMMENTS
SAMPLES RECEIVED ON ICE NO
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PLEASE REAP) Instructions for completing this form on the reverse side.
FORM n5
Sampler must place a "C" for composite sample or a "G" for
Grab sample In the blocks above for each parameter requested

Waypiint.(D
ANALYTICAL
11/22/2023
Waypoint Analytical - Greenville
Ann Baynor
114 Oakmont Dr
Greenville, NC, 27858
Ref, Analytical Testing
Lab Report Number: 23-321-0064
Client Project Description: Avoca, LLC
(Wastewater)
Dear Ann Baynor.
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.064
www.waypointanalytical.com
Waypoint Analytical, LLC (Charlotte) received sample(s) on 11 /17/2023 for the analyses presented in the
following report
The above referenced project has been analyzed per your instructions The analyses were performed in
accordance with the applicable analytical method
The analytical data has been validated using standard quality control measures performed as required by the
analytical method Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136
Method Update Rule May 2021) unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite.. ) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated This report shalt not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information
Sincerely,
6 % �
Jamie Corporaal
Laboratory Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

Waypoint,(2)
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Maln 704,529.6364
www,waypointanalytical.com
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State
Program
Lab ID
Expiration Date
North Carolina
State Program
37735
07/31/2024
North Carolina
State Program
402
12/31/2023
South Carolina
State Program
99012
07/31/2024
South Carolina
State Program
99012
12/31/2023
o.,,,,, 1 M i nnni R/71_']7i.MRA

•
•
ANALYTICAL
Waypoint,
449 Springbrook Rd, Charlotte, NC 28717
Main 704.529.6364
www.waypoiritanalytical.com
Sample Summary Table
Report Number: 23-321-0064
Client project Description: Avoca, LLC
(Wastewater)
Lab No Client Sample ID Matrix Date Collected Date Received
89663
I
Effluent
Aqueous
11/15/2023
11/17/2023
89665
Well #5
Aqueous
11/15/2023
11/17/2023
89666
Well #7
Aqueous
11/15/2023
10:35
11/17/2023
89667
Well #8
Aqueous
11/15/2023
11:15
11/17/2023
89668
Well #9
Aqueous
11/15/2023
10:55
11/17/2023
89669
Well #10
Aqueous
11/15/2023
11:55
11/17/2023
89670
Well #11
Aqueous
11/15/2023
09:50
11/17/2023

Waypoint,(2)
ANALYTICAL
Client: Waypoint Analytical - Greenvil€e
Project, Avoca, LLC
Lab Report Number: 23-321-0064
Date: 11 /2212023
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www,waypointanalytical.com
Report Comments
No Well #4 sample from chain of custody sent per 11/20 client email.
CASE NARRATIVE

0
i
' 449 Springbrook Rd, Charlotte, NC 28717
ay Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
00435
Waypoint Analytical - Greenville Project Avoca, LLC
Ann Baynor Report Date : 11/22/2023
114 Oakmont Dr Information: (Wastewater) Received ; 11/17/2023
Greenville, NC 27858
Report Number: 23-321-0064 REPORT OFANALYSIS
Lab No : 89663 Matrix: Aqueous
Sample ID : Effluent Sampled: 11/15/2023 0:00
Test Results Units MQL DF Date 1 Time By Analytical
Analyzed Method
Bromide (Br) 5.61 mg/L 500 10 11/21/23 12:45 KNC 300.0
Qualifiers/ DF Dilution Factor MQL Method Quantitation Limit
Definitions

(2)
Waypoint,
449 Springbroolc Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalyticol.com
00435
Waypoint Analytical - Greenville Project Avoca, LLC
Ann Baynor Report Date : 11/22/2023
114 Oakmont Dr Information : (Wastewater) Received : 11/17/2023
Greenville, NC 27858
Report Number : 23-321-0064
Lab No : 89665
Sample ID : Well #5
Test
Bromide (Br)
REPORTOFANALYSIS
Results Units
5.03 mg/L
Matrix: Aqueous
Sampled: 11/15/2023 0:00
MQL DF Date I Time By Analytical
Analyzed Method
0 500 1 11/21/23 12:57 KNC 300.0
Qualifiers/ DF Dilution Factor MQL Method Quantrtation Limit
Definitions

e
N
Waypoint,
449 5pringbrook Rd, Charlotte, NC 28217
Maln 704.529.6364
ANALYTICAL www.waypointanalytical.com
00435
Waypoint Analytical - Greenville Project Avoca, LLC
Ann Gaynor Report Date ; 11/22/2023
114 Oakmont Dr Information: (Wastewater) Received ; 11/17/2023
Greenville , NC 27858
Report Number : 23-321-0064 REPORTOFANALYSIS
Lab No : 89666 Matrix: Aqueous
Sample ID: Well #7 Sampled: 11/15/2023 10:35
Test Results Units MQL DF Date i Time By Analytical
Analyzed Method
Bromide (Br) 19.7 rng/L 0.500 1 11/21/23 13:34 KNC 300.0
Qualifiers/ DF Dilution Factor MQL Method Quantitation Limit
Definitions

A
449 5pringbroolc Rd, Charlotte, NC 28217
Waypoint,Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
00435
Waypomt Analytical - Greenville Project Avoca, LLC
Ann 8aynor Report Date ; 1112212023
114 Oakmont Dr Information : (Wastewater) Received : 11/17/2023
Greenville , NC 27858
Report Number: 23-321-0064
REPORT OFANALYSIS
Lab No: 89667 Matrix: Aqueous
Sample ID - Well #8 Sampled: 11/15/2023 11:15
Test Results Units MQL DF Date / Time By Analytical
Analyzed Method
Bromide (8r) 3.95 mg/L 0.500 1 11/21/23 14:11 KNC 300.0
Qualifiers/ DF Dilution Factor MQL Method Quantitation Limit
Definitions

0
Waypoint,® 449 5pringbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
00435
Waypoint Analytical - Greenville Project Avoca, LLC
Ann Baynor Report Date : 11/22/2023
114 Oakmont Dr Information : (Wastewater) Received : IV17/2023
Greenville , NC 27858
Report Number: 23-321-0064
Lab No : 89668
Sample ID : Well #9
Test
1?EP0R7'0FANALYSI5
Matrix: Aqueous
Sampled: 11/ 15/ 2023 10:55
Results Units MQL OF Date / Time By Analytical
Analyzed Method
Bromide (Br) <0.500 mg/L 0.500 1 11/21/23 14:24 KNC 300.0
Qualifiers/ DF Dilution Factor MQL Method Quantitatlon Limit
Definitions

Waypomt
449 5pringbrook Rd, Charlotte, NC 28217
Main 704.529,6364
ANALYTICAL
www.waypointanalytical.com
00435
Waypolnt Analytical - Greenville
Project
Avoca, LLC
Ann Baynor
Report Date : 11/22/2023
114 Oakmont Dr
Information : (Wastewater)
Received : 11/17/2023
Greenville , NC 27858
Report Number : 23-321-0064
REPORT OFANALYSIS
Lab No: 89669
Matrix: Aqueous
Sample ID :Well #10
Sampled: 11/15/2023 11:55
Test
Results
Units MOL
DF Date / Time By Analytical
Analyzed Method
Bromide (Br)
<0.500
mg/L 0.500
1 11/21/23 14:36 KNC 300.0
Qualifiers/ DF Dilution Factor MQL Method Quantitatlon Limit
Definitions

a
Q
Waypoint,449 Springbrooh Rd, Charlotte, NC 28217
Maln 704.529.6364
ANALYTICAL www.waypointanalytical.com
00435
Waypo?nt Analytical - Greenville Project Avoca, LLC
Ann Gaynor Report Date : 11/22/2023
114 Oakmont ter Information : (Wastewater) Received ; 11/17/2023
Greenville , NC 27858
Report Number: 23-321-0064 REPOR T OF ANALYSIS
Lab No ; 89670 Matrix: Aqueous
Sample ID, Well #11 Sampled: 11115/2023 9.50
Test Results Units MQL DF Date / Time By Analytical
Analyzed Method
Bromide (Br) 11,2 mg/L 0.500 1 11/21/23 14:48 KNC 300.0
Qualifiers/ DF Dilution Factor MQL Method Quantitation Limit
Definitions

0
Waypoint.
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 00435
Customer Name: Waypoint Analytical - Greenville
Report Number: 23-321-0064
Shipping Method
0 Fed Ex 0 US Postal © Lab 0 Other:
0 UPS 0 Client 0 Courier Thermometer ID: JIRT15 1 AC
Shipping container/cooler uncompromised?
© Yes
0 No
Number of coolers/boxes received
F 1
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
Yes
0 No
COC agrees with sample labei(s)?
Yes
0 No
COG properly completed
Yes
0 No
Samples in proper containers?
Yes
0 No
Sample containers intact?
Yes
0 No
Sufficient sample volume for indicated test(s)?
0 Yes
0 No
All samples received within holding time?
Q Yes
0 No
Cooler temperature in compliance?
Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Water - Sample containers properly preserved
Yes
Yes
0 No
0 No
0 NIA
Water - VOA vials free of headspace
0 Yes
0 No
* N/A
Trip Blanks received with VOAs
0 Yes
0 No
* N/A
Soil VOA method 5035 — compliance criteria met
d Yes
0 No
Q N/A
(— High concentration container (48 hr) 7 Low concentration EnCore samplers (48 hr)
F High concentration pre -weighed (methanol -14 d) ; Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included?
Comments: f
0Yes *No
Signature: Pamie Corporaal _ Date & Time: 11/17/2023 17:37:54

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