WQ0005910_Monitoring - 11-2023_20231212

Monitoring Report Submittal
Permit Number#* WQ0005910
Name of Facility:* Avoca LLC
Month: * November
Report Information
Type *
NDMR, NDAR-1, NDAR-2, NDMLR
Year:* 2023
Upload Document*
Avoca LLC Nov 2023 NDAR & NDMR.pdf 1.78MB
PDF Only
Please upload one PDF containing all applicable monitoring reports
(i.e., NDMR, NDAR-1, NDAR-2, NDMLR, GW-59).
Confirmation Email Address: * [e-mail]
Name of Submitter: * Brian M. Conner
Signature:
fftt;ew 6W C Cart
Date of submittal: 12/12/2023
This will be filled in automatically
Initial Review
Reviewer: Wanda.Gerald

Is the project number correct?* WQ0005910
Is the monitoring report accepted?* Yes No
Regional Office* Washington
Reviewer: _anonymous
Review Date: 12/19/2023

FORM NDMR 03-12 NON -DISCHARGE MONITORING REPORT (NDMR) Page k of I
Permit No.: W00005910
Facility Name Avoca - Merry Full WWTP
County Bertle
Month: November
Year: 2023
PPI• 001
Flow Measuring Point. ❑ Influent 2] Effluent ❑ No flow generated
Parameter Monitoring Point: ❑Influent El Effluent El Groundwater Lawenng ❑surface water
Parameter Code -►
50050
00310
00916
00940
00927
00610
00625
00620
00600
00400
00665
00931
00929
70300
00530
ar
o
O F
O
y
E �'
r
=
0 0
u-
LID
p
co
iG
U
oa�
z
U
E
?
a
aCi
=
Y z
a?
Z
m
FQ- :-z!
z
Q
c
i°
a
E° O
Q N W
E
O
N
iv �
'ram y to
C w
m c
F' vQi tlOj
24-hr
hrs
GPD
mg/L
mg/L
mg/L
mg/L
mg/L
mg1L
mg/L
mg/L
su
mg/L
Ratio
mg1L
mg1L
mg/L
1
10 00
8
20,116
812
2
0930
8
19,827
809
3
0730
8
14,289
846
4
0700
2
13,890
5
0715
2
12,731
6
0715
8
11,173
804
7
0715
8
9,962
836
8
0700
8
10,774
831
9
0730
8
7,676
824
10
0700
8
14,544
819
11
0630
2
16,272
12
0630
2
18,262
131
0745
8
4,470
807
14
0700
8
11,934
812
15
0730
8
15,092
357
8 855
64
2 347
<0 04
22A
<0 04
22.51
76
2.7
147
189.96
1600
107
16
0700
8
15,589
769
17
0745
8
14,535
1
1 752
18
0630
2
11,102
191
0700
2
10,243
20
0745
8
3,108
782
21
0745
8
6,927
756
22
0800
8
9,671
782
23
0900
2
15,585
1
776
24
0845
2
1 16,295
774
251
1000
2
15,798
26
05 30
2
3,773
27
0715
8
9,771
769
28
1300
8
6,965
762
29
0815
8
6,953
1
1
826
30
0715
8
4,964
817
31
Average,
11,743
35700
8.86
6400
2.35
000
22.40
000
2251
2.70
1470
189.96
1,600 00
10700
Daily Maximum-
20,116
35700
886
6400
2.35
004
22.40
004
22.51
#REFI
270
1470
189.96
1,600 00
10700
Daily Minimum
3,108
35700
886
6400
2.35
004
22.40
004
22,51
#REFI
2.70
1470
189.96
1,60000
10700
Sampling Type
Recorder
Grab
Grab
I Grab
Grab
Grab
I Grab
Grab
Grab
Grab
Grab
Calculated
I Grab
Grab
Grab
Monthly Avg. Limit:
50,000
Daily Limit,
Sample Frequency,
Continuous
Monthly
3 X Year
3 X Year
3 X Year
Monthly
Monthly
Monthly
Monthly
5 X Week
Monthly
3 X Year
I 3 X Year
3 X Year
Monthly

FORM: NDMR 03-12 NON -DISCHARGE MONITORING REPORT (NDMR) Page Z of 2-
Sampling Person(s) Certified Laboratories
Name: Brian Conner Name: Waypoint Analytical
Name: Name:
Does all monitoring data and sampling frequencies meet the requirements in Attachment A of your permit? 21 Compliant ❑ Non -Compliant
If the facility is non -compliant, please explain in the space below the reason(s) the facility was not in compliance. Provide in your explanation the date(s) of the non-compliance and describe the corrective
action(s) taken. Attach additional sheets if necessary.
Operator in Responsible Charge (ORC) Certification
Permittee Certification
ORC: Brian M. Conner
Permittee: Avoca, LLC
Certification No.: 993283
Signing Official: Sam Tynch
Grade: WW2 Phone Number: 252-482-2133
Signing Officials Title: Plant Manager
Has the ORC changed since the previous NDMR? ❑ Yes 0 No
Phone Number: 252-482-2133 Permit Expiration: 10/31/2024
Signature Date
Signature Date
By this signature, I certify that this report is accurrate and complete to the best of my knowledge.
I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in
accordance with a system designed to assure that all qualified personnel properly gathered and evaluated the information
submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for
gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am
aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for
knowing violations.
Mail Original and Two Copies to:
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, North Carolina 27699-1617

FORM NDAR-1 05-16 NON -DISCHARGE APPLICATION REPORT (NDAR-1) Page k of
Permit No WQ000591 1
• _ -
.nth: NovemberDid
irrigation occur
at this facility'?
121 YES ONO
Area (acres):
Area (acres).
._
. •.:
011110-101e,rMuCla
Grass
Hourly Rate (in):
R-M RA M RIM,
Annual Rate (in),
W RWM
-��
�
©�
r
w
•
w
r
IMMMM
Monthly ' J' '
12 Month ._.-
...
iiii®iiiii%�iiiii�iiiii
iiiiii�iiiiiiii'',

FORM NDAR-1 05-16 NON -DISCHARGE APPLICATION REPORT (NDAR-1) Page of
11111 • 1
Avoca -
Be - Month: November1
Did irrigation occur
at this facility?
ED YES El NO
�Field Name:
I�
�C�_��■
• •
����■
Hourly Rate (in):
Hourly Rate (inr�-
IRON
Im
MINE
M1111MM
11.N111
©■■■■■■■■
�■■■■■■■
■■■■�■■■■■
�■■■��
����
MMMMM
MMMMM
MMMMM
Monthly ._..%/////�/���///.o//////%
, ,.
�������,■■������
,
///////.sue'//////
..
,,

FORM: NDAR-1 05-16
NON -DISCHARGE APPLICATION REPORT (NDAR-1)
Page 3 of 3
Did the application rates exceed the limits in Attachment B of your permit?
Were adequate measures taken to prevent effluent ponding in or runoff from the sites?
Was a suitable vegetative cover maintained on all sites as specified in your permit?
Were all setbacks listed in your permit maintained for every application to each permitted site?
Were all freeboards maintained in accordance with the specified freeboard heights in your permit?
[21 Compliant
❑ Non -Compliant
0 Compliant
❑ Non -Compliant
I] Compliant
❑ Non -Compliant
0 Compliant
❑ Non -Compliant
El Compliant
❑ Non -Compliant
If the facility is non -compliant, please explain in the space below the reason(s) the facility was not in compliance. Provide in your explanation the date(s) of the non-compliance and describe the corrective
action(s) taken. Attach additional sheets if necessary.
Operator in Responsible Charge (ORC) Certification
Permittee Certification
ORC: Brian M. Conner
Permittee:
Avoca, LLC
Certification No.: 991857, 993283
Signing Official: Sam Tynch
Grade: SI / WW2 Phone Number: 252-482-2133
Signing Officials Title: Plant Manager
Has the ORC changed since the previous NDAR-1? ❑ Yes O No
Phone Number: 252-482-2133 Permit Exp.: 10/31/24
' X-.-la-�3
5 n -2
Signature Date
Y Signature Date
By this signature, I certify that this report is accurrate and complete to the best of my knowledge.
I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance
with a system designed to assure that all qualified personnel properly gathered and evaluated the information submitted. Based on my
inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the
information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations.
Mail Original and Two Copies to:
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, North Carolina 27699-1617

0
Waypoelnt .
ANALYTICAL
114 OAKMONT DRIVE
GREENVILLE, NC 27858
AVOCA, LLC (WASTEWATER)
MR. BRIAN CONNER
P.O. BOX 129
MERRY HILL, NC 27957
Drinking Water ID% 37715
Wastewater IDs 30
PHONE [phone]
FAX [phone]
ID#: 132
DATE COLLECTED: 11/15/23
DATE REPORTED : 12/06/23
REVIEWED BY:
Effluent
Well #5
Well #7
Well #8
Well #9
Analysis
Method
PARAMETERS
Date Analyst
Code
BOD, 1ng/I
r 357
11/15/23
HMV
5210B-16
Total Suspended Residue, n:g/l
107
11/16/23
BNC
2540D-15
Ammonia Nitrogen as N, mg/l
<0.04
11/19/23
TRJ
350.1 112-93
Ammonia Nitrogen as N, n:g/l
0.11
<0.04
1.17
<0.04
11/21/23
TRJ
350.1 112-93
Total Kjeldahl Nitrogen as N,n:g/l
22.40
12/05/23
TRJ
351.2 112-93
Nitrate+Nitrite as N, mg/1 (cnlc)
0.11
353.2 112-93
Nitrate Nitrogen as N, mg/l
<0.04
<0.04
1.73
0.44
3.69
11/16/23
AMC
353.2 112-93
Nitrite Nitrogen as N, mg/l
0.11
11/15/23
AMC
353.2 112-93
Total Phosphorus as P, mg/I
2.70
0.08
<0.04
2.21
0.10
11/20/23
AMC
365.4-74
Total Organic Carbon, mg/l
2.68
3.53
16.07
< 1.00
11/21/23
BLV
531OC-14
Chloride, n1g/l
64
11/22/23
BNC
4500CIAW I
Chloride, n1g/I
31
33
25
22
11/19/23
ADR
4500CLB-11
Total Dissolved Residue, mg/I
1600
580
170
780
190
11/20/23
BNC
D5907-13
Calcium, ug/l
8855
32024
7574
40064
40474
11/16/23
MTNI
EPA200.7
Magnesi:::n, ug/l
2347
11/16/23
MTM
EPA200.7
Sodium, ug/l
189960
11/16/23
MTM
EPA200.7
Sodium Adsorption Ratio (calc)
14.7
Total Nitrogen, n1g/I (calc)
22.51
All QC requirements were not met: r Replicate varied by more than 30%.

Waypointo
ANALYTICAL
114 OAKMONT DRIVE
GREENVILLE, NC 27858
AVOCA, LLC (WASTEWATER)
MR. BRIAN CONNER
P.O. BOX 129
MERRY HILL, NC 27957
Well #10 Well #11
PARAMETERS
Drinking Water ID, 37715
Wastewater IDS 10
PHONE [phone]
FAX [phone]
ID#: 132
DATE COLLECTED: 11/15/23
DATE REPORTED : 12/06/23
REVIEWED BY:
Analysis Method
Date Analyst Code
Annnonia Nitrogen as N, nlg/I
<0.04
12.28
11/21/23
TRJ
350.1 R2-93
Nitrate Nitrogen as N, nlg/l
6.80
<0.04
11/16/23
AMC
353.2 R2-93
Total Phosphorus as P, nlg/I
<0.04
0.16
11/20/23
AMC
365.4-74
Total Organic Carbon, mg/I
1.57
11.60
11/21/23
BLV
531OC-14
Chloride, mg/1
71
27
11/19/23
ADR
4500CLB-11
Total Dissolved Residue, mg/I
280
660
11/20/23
BNC
D5907-13
Calcium, ug/l
21596
20141
11/16/23
MTM
EPA200.7
All OC requirements were not mett r Replicate varied by more than 30%.

i
Waypointo
ANALYTICAL
114 OAKMONT DRIVE
GREENVILLE, NC 27858
CLIENT: AVOCA, LLC (WASTEWATER)
MR. BRIAN CONNER
P.O. BOX 129
MERRY HILL, NC 27957
REVIEWED BY: 4
444C
VOLATILE ORGANICS
STD. METHODS 8260D
Drinking Weter ID: 37715
Waetewa ter ID i 10
PHONE [phone]
FAX [phone]
CLIENT ID: 132
ANALYST: JAP
DATE COLLECTED: 11/15/23 Page: 1
DATE ANALYZED: 11/17/23
DATE REPORTED: 12/06/23
PARAMETERS, ug/I
Well #5
Well N7
Well #8
Well N9
Well #10
1. Benzene
<0.50
<0.50
<0.50
<0.50
<0.50
2. Bromobenzene
<0.50
<0.50
<0.50
<0.50
<0.50
3. Bromochloromelhanc
<0.50
<0.50
<0.50
<0.50
<0.50
4. Brontodichloromelhane
<0.50
<0.50
<0.50
<0.50
<0.50
5. Bromoform
<0.50
<0.50
<0.50
<0.50
<0.50
6. Bromome0nine
<0.50
<0,50
<0.50
<0.50
<0.50
7. N-Butylbenzene
<0.50
<0.50
<0.50
<0.50
<0.50
8. Sec-Butylbenzene
<0.50
<0.50
<0.50
<0.50
<0.50
9. Tert-Butylbenzene
<0.50
<0.50
<0.50
<0.50
<0.50
10. Carbon Tetrachloride
<0.50
<0.50
<0.50
<0.50
<0.50
11. ChlorobenZell e
<0.50
<0.50
<0.50
<0.50
<0.50
12. Chloroedume
<0.50
<0.50
<0.50
<0.50
<0.50
13. Chloroform
<0.50
<0.50
<0.50
<0.50
<0.50
14. Chloromethaue
<0.50
<0.50
<0.50
<0.50
<0.50
15. 2-Chlorololuenc
<0.50
<0.50
<0.50
<0.50
<0.50
16. 4-Chlorotoluene
<0.50
<0.50
<0.50
<0.50
<0.50
17. Dibronlochlorometh:utc
<0.50
<0.50
<0.50
<0.50
<0.50
18. 1,2-Dibronto-3-Chloropropane
<0.50
<0.50
<0.50
<0.50
<0.50
19. 1,2-Dibronloedume
<0.50
<0.50
<0.50
<0.50
<0.50
20. Dibromonlethane
<0.50
<0.50
<0.50
<0.50
<0.50
21. 1,2-Dichlorobenzene
<0.50
<0.50
<0.50
<0.50
<0.50
22. 1,34Dichlorobenzene
<0.50
<0.50
<0.50
<0.50
<0.50
23. 1,4-Dichlorobenzene
<0.50
<0.50
<0.50
<0.50
<0.50
24. Diclllol•odiilt101.Otttethane
<0.50
<0.50
<0.50
<0.50
<0.50
25. 1,1-Dichloroethane
<0.50
<0.50
<0.50
<0.50
<0.50
26. 1,2-Dichloroetltane
<0.50
<0.50
<0.50
<0.50
<0.50
27. 1,1-Dichloroethene
<0.50
<0.50
<0.50
<0.50
<0.50
28. Cis-1,2-Dicltloroelhene
<0.50
<0.50
<0.50
<0.50
<0.50
29. trims-1,2-Dichloroethene
<0.50
<0.50
<0.50
<0.50
<0.50
30. 1,2-Dichloropropane
<0.50
<0.50
<0.50
<0.50
<0.50
31. 1,3-Dichloropropane
<0.50
<0.50
<0.50
<0.50
<0.50
32. 2,2-Dichloropropane
<0.50
<0.50
<0.50
<0.50
<0.50
33. 1,I-Dichloropropene
<0.50
<0.50
<0.50
<0.50
<0.50
34. Cis-1,3-Dichloropropene
<0.50
<0.50
<0.50
<0.50
<0.50
35. trans-1,3-Dichloropropene
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
36. Ethylbenzene
<0.50
<0.50
<0.50
<0.50
<0.50
37. Hexachlorobuladicne
<0.50
<0,50
<0.50
<0.50
<0.50
38. Isopropylbenzene
<0.50
<0.50
<0.50
<0.50
<0.50
39. 4-Isopropylloluene
<0.50
<0.50
<0.50
<0.50
<0.50
40. Methylene Chloride
<0.50
<0.50
<0.50
<0.50
<0.50
41. Naphthalene
<0.50
<0.50
<0.50
<0.50
<0.50
42. Propylbenzene
<0.50
<0.50
<0.50
<0.50
<0.50
43. Styrene
<0.50
<0.50
<0.50
<0.50
<0.50
44. 1,1,1,2=retrachloroethane
<0.50
<0.50
<0.50
<0.50
<0.50
45. 1,1,2,2-Teh•achloroethanc
<0.50
<0.50
<0.50
<0.50
<0.50
46. Tetrachloroethene
<0.50
<0.50
<0.50
<0.50
<0.50
47. roluene
<0.50
<0.50
<0.50
<0.50
<0.50
48. 1,2,3-Trichlorobenzene
<0.50
<0.50
<0.50
<0.50
<0.50

Waypointo
ANALYTICAL
114 OAKMONT DRIVE
GREENVILLE, NG 27858
CLIENT: AVOCA, LLC (WASTEWATER)
MR. BRIAN CONNER
P.O. BOX 129
MERRY HILL, NC 27957
REVIEWED BY:
VOLATILE ORGANICS
STD. METHODS 8260D
Drinking Water ID: 37715
Wastewater ID10
PHONE [phone]
FAX [phone]
CLIENT ID: 132
ANALYST: JAP
DATE COLLECTED: 11/15/23 Page: 2
DATE ANALYZED: 11/17/23
DATE REPORTED: 12/06/23
PARAMETERS, ug/I
Well #5
Well Ill
Nvell #8
Well #9
Well #10
49, 1,2,4-Trichlorobenzene
<0.50
<0.50
<0.50
<0.50
<0.50
50. 1,1,1-Trichloroethane
<0.50
<0.50
<0.50
<0.50
<0.50
51. 1,1,2-Trichloroethane
<0.50
<0.50
<0.50
<0.50
<0.50
52. Trichloroelhene
<0.50
<0.50
<0.50
<0.50
<0.50
53. Trichlo•othio•onethntic
<0.50
<0.50
<0.50
<0.50
<0.50
54. 1,2,3-Trichloropropaue
<0.50
<0.50
<0.50
<0.50
<0.50
55. 1,2,4-Trimelhylbenzeue
<0.50
<0.50
<0.50
<0.50
<0.50
56. 1,3,5-Trimelhylbenzene
<0.50
<0.50
<0.50
<0.50
<0.50
57. Vinyl Chloride
<0.50
<0.50
<0.50
<0.50
<0.50
58. Total Kylenes
< 1.00
< 1.00
< 1.00
< 1.00
< 1.00
59. Nlethyl Tert BnOl Ether
< 1.00
< 1.00
< 1.00
< 1.00
< 1.00

Waypointo
ANALYTICAL
114 OAKMONT DRIVE
GREENVILLE, NC 27858
CLIENT: AVOCA, LLC (WASTEWATER)
MR. BRIAN CONNER
P.O. BOX 129
MERRY HILL, NC 27957
REVIEWED BY: Q
VOLATILE ORGANICS
STD. METHODS 8260D
Drinking Hater ID: 37715
Was teaeter IDS 10
PHONE [phone]
FAX [phone]
CLIENT ID: 132
ANALYST: JAP
DATE COLLECTED: 11/15/23
DATE ANALYZED: 11/17/23
DATE REPORTED: 12/06/23
PARAMC'rCRS, ug/1
Well #11
1.
Benzene
< 0.50
2.
Bromobenzene
<0.50
3.
Bromochloromethone
<0.50
4.
Bromodichloromelhane
<0.50
5.
Bromoform
<0.50
6.
Bromomelhnne
<0.50
7.
N-Butylbenzene
<0.50
8.
Sec-Butylbenzene
<0.50
9.
Tert-Butylbenzene
<0.50
10.
Carbon Tetrachloride
<0.50
11,
Chlorobenzene
< 0.50
12.
Chloroelhmle
<0.50
13.
Chloroform
< 0.50
14.
Chloronielhnne
<0.50
15.
2-Chlorotoluene
<0.50
16.
4-Chlorotoluene
<0.50
17.
Dibromochloromethm:e
<0.50
18.
1,2-Dibronio-3-Chloropropnne
< 0.50
19.
1,2-Dibromoethane
<0.50
20.
Dibromomelhane
<0.50
21.
1,2-Dichlorobenzene
< 0.50
22.
1,3-Dichlorobenzene
<0.50
23.
1,4-Dichlorobenzene
<0.50
24.
Dichlorodilluoroniethane
<0.50
25.
1,1-Dichloroetllnne
<0.50
26.
1,2-Dichloroelhene
< 0.50
27.
1,1-Dichloroethene
< 0.50
28.
Cis-1,2-Dichloroethene
<0.50
29.
trans-1,2-Dichloroethene
< 0.50
30.
1,2-Dichloropropene
< 0.50
31.
1,3-Dichloropropene
<0.50
32.
2,2-Dichloropropene
<0.50
33.
1,1-Dichloropropene
< 0.50
34.
Cis-1,3-Dichloropropene
<0.50
35.
trans-1,3-Dichloropropene
<0.50
36.
Cthylbenzene
<0.50
37.
Hexachlorobuladiene
<0.50
38.
Isopropylbenzene
< 0.50
39.
4-Isopropylloluene
<0.50
40.
Methylene Chloride
<0.50
41.
Nnphlhnlene
< 0.50
42.
Propylbenzene
< 0.50
43.
Styrene
< 0.50
44.
1,1,1,2-Tet•achloroethmte
<0.50
45.
1,1,2,24'etrachloroethane
<0.50
46.
Tetrnchloroethene
<0.50
47.
Toluene
<0.50
48.
1,2,3-Trichlorobenzenc
<0.50
Page: 3

Waypoint-0
ANALYTICAL
114 OAKMONT DRIVE
GREENVILLE, NC 27858
CLIENT: AVOCA, LLC (WASTEWATER)
MR. BRIAN CONNER
P.O. BOX 129
MERRY HILL, NC 27957
REVIEWED BY: /
VOLATILE ORGANICS
STD. METHODS 8260D
Drinking Water IDi 37715
Wastewater ID: 10
PHONE [phone]
FAX [phone]
CLIENT ID: 132
ANALYST: JAP
DATE COLLECTED: 11/15/23 Page: 4
DATE ANALYZED: 11/17/23
DATE REPORTED: 12/06/23
PARAMETERS, ug/I
Well #11
49.
1,2,4=rrichloroben7.cne
<0.50
50.
1,1,1-Trichloroethane
<0.50
51.
1,1,2-Trichloroethmic
<0.50
52.
Trichloroethene
<0.50
53,
'1'richlorolluorometh:ine
<0.50
54.
1,2,3-Trichloroprolmne
<0.50
55.
1,2,4-Trimethylbenzene
<0.50
56.
1,3,5-Trimethylbenr.ene
<0.50
57.
Vinyl Chloride
<0.50
58.
Total Xylenes
< 1.00
59.
Nlethyl Terl Butyl Ether
< 1.00

��ra�rpoint
CHAIN OF CUSTODY RECORD
Waypoint Analytical - Greenville
Page 1 of 2
Grccnvflle, NC 27858
INSINFECTION
\I
CHLORINE CHECK (LAB)
www.WaypointAnalytical.com
Phone [phone] • Fax [phone]
Ij CHLORINE
<0 5 mg/L -Yes (l� or No (N)
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CHEMICALPRESERVATION
'.O- BOX 129
MERRY HILL NC 27957
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SAMPLES COLLECTED BY
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PLEASE READ Instructions for completing this form on the reverse side. Sampler must place a "C" for composite sample or a"T for
FORM xs Grab sample in the blocks above for each parameter requested

Waypornt
Waypoint Analytical - GreenviIle
114 Qakmont Dr
CHAIN OF CUSTODY RECORD
Pa- e 2 of 2
Greenville. NC 27858 -
DISINFECTION
CHLORINE CHECK B
www.WaypointAnalytical corn
D 5mg/Yes ('0 or No (N))
Phone [phone] • Fax [phone]
CHLORINE
CLIENT: 132 Week: 51
pH CHECK (S U) (LAB)
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SAMPLES RECEIVED ON ICE. - NO
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RELINQUISHED BY (SIG)
DATEMME
RECEIVED BY (SIG)
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PLEASE READ I nstructlons for completing this form on the reverse Ssde. Sampler must place a "C' for composite sample or a "G" for
FORM rs Grab sample in the blocks above for each parameter requested

Waypiint.(2)
AiVALYTICAL
11/22/2023
Waypoint Analytical - Greenville
Ann Baynor
114 Oakmont Dr
Greenville, NC, 27858
Ref. Analytical Testing
Lab Report Number, 23-321-0064
Client Project Description. Avoca, LLC
(Wastewater)
Dear Ann Baynor
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Waypoint Analytical, LLC (Charlotte) received sample(s) on 11/17/2023 for the analyses presented in the
following report
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136
Method Update Rule May 2021) unless otherwise indicated
Certain parameters (chlorine, pH, dissolved oxygen, sulfite ,) are required to be analyzed within 15 minutes of
sampling Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s) Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
4��% �r
Jamie Corporaal
Laboratory Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

Waypoint,(2)
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529,6364
www.waypointanalyti ca I .com
Certification Summary
Laboratory Id: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State
Program
Lab ID
EX irk anon mate
North Carolina
State Program
37735
07/31/2024
North Carolina
State Program
402
12131/2023
South Carolina
State Program
99012
07/31/2024
South Carolina
State Program
99012
12/31/2023

a
Waypoint,
ANALYTICAL
Report Number: 23-321-0064
Client Project Description: Avoca, LLC
(Wastewater)
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.way po intana lyti ca l.com
Sample Summary Table
Lab No
Client Sample ID
Matrix
Date Collected
Date Received
89663
Effluent
Aqueous
11/15/2023
11/17/2023
89665
Well #S
Aqueous
11/15/2023
11/17/2023
69666
Well #i
Aqueous
11/15/2023
10:35
11/17/2023
89667
Well #8
Aqueous
11/15/2023
11:15
11/17/2023
89668
Well #9
Aqueous
11/15/2023
10:55
11/17/2023
89669
Well #10
Aqueous
11/15/2023
11:55
11/17/2023
89670
Well #11
Aqueous
11/15/2023
09:50
11/17/2023

9
int
Wayp.
ANALYTICAL
Client: Waypoint Analytical - Greenville
Project- Avoca, LLC
Lab Report Number: 23-321-0064
Date: 11/22/2023
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www,waypofntanafytical.com
Report Comments
No Well #4 sample from chain of custody sent per 11120 client email.
CASE NARRATIVE

(2)
Waypoint.
NC 28217
A49 SpringbrooE< Rd, Charlotte,
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
00435
Waypoint Analytical - Greenville Project Avoca, LLC
Ann Baynor Report Date : 11/22/2023
114 Oakmont Dr Information : (Wastewater) Received : 11/17/2023
Greenville , NC 27858
Report Number : 23-321-0064 REP0R7'0fANALY5XS
Lab No : 89663 Matrix: Aqueous
Sample ID: Effluent Sampled: 11/15/2023 0:00
Test Results Units MQL DF DatefTime By Analytical
Analyzed Method
Bromide (Br) 5.61 mg/L 500 10 11/21/23 12:45 KNC 300.0
Qualifiers/ DF Dilution Factor MQL Method Quantitation Limit
Definitions

(2)
Charlotte, NC 28217
Waypoint,
449 Sprtngbrook Rd,
Main 704.529.6364
ANALYTICAL www.waypolntanalytical.com
00435
Waypoint Analytical - Greenville Project Avoca, LLC
Ann Baynor Report Date : 11/22/2023
114 Oakmont Dr Information : (Wastewater) Received : 11/17/2023
Greenville , NC 27858
Report Number : 23-321-0064
Lab No : 89665
Sample ID : Well #5
Test
REPORT OPANALYSI'S
Matrix: Aqueous
Sampled: 11/15/2023 0:00
Results Units MQL DF Date / Time By Analytical
Analyzed Method
Bromide (Br) 5.03 mg/L 0.500 1 11/21/23 12.57 KNC 300.0
Qualifiers/ DF Dilution Factor MQL Method Quantitation Limit
Definitions

0
449 Springbroolc Rd, Charlotte, NC 28217
Waypoint.Main 704,529.6364
ANALYTICAL www.waypointanalytical.com
00435
Waypoint Analytical - Greenville Project Avoca, LLC
Ann Baynor Report Date : 11/22/2023
114 Oakmont Or Information: (Wastewater) Received: 11/17/2023
Greenville , NC 27858
Report Number : 23-321-0064 REPORTOFANALYSIS
Lab No: 89666 Matrix: Aqueous
Sample ID : Well #7 Sampled: 11/ 15/2023 10:35
Test Results Units MOL DF Date I Time By Analytical
Analyzed Method
Bromide (Br) 19.7 mg/L 0.500 1 11/21/23 13:34 KNC 300.0
Qualifiers/ DF Dilution Factor MQL Method Quantitation Limit
Definitions

(D
449 5pringbrook Rd, Charlotte, NC 28217
Waypoint.Main 704.529.6364
ANALYTICAL www.waypointanafyt(cal.com
00435
Waypoint Analytical - Greenville Project Avoca, LLC
Ann Baynor Report Date : 11/22%2023
114 Oakmont Dr Information : (Wastewater) Received : 11/17/2023
Greenville , NC 27858
Report Number: 23-321-0064 REPORT OFANAL YSIS
I
Lab No : 89667 Matrix: Aqueous
Sample ID: Well #8 Sampled: 11/15/2023 11:15
Test Results Units MOL DF Date / Time By Analytical
Analyzed Method
Bromide (8r) 3.95 mg/L 0.500 1 11/21/23 14:11 KNC 300.0
Qualifiers/ DF Dilution Factor MQL Method Quantitation Limit
Definitions

r
Waypoint,449 5pringbrdok Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointenalytical.com
00435
Waypomt Analytical - Greenville Pro)ect Avoca, LLC
Ann Bayr}or Report Date : 11/22/2023
114 Oakmont Dr Information : (Wastewater) Received : 11/17/2023
Greenville , NC 27858
Report Number: 23-321-0064 REPORT OFANAL YSIS
Lab No : 89668 Matrix: Aqueous
Sample Ib : Well #9 Sampled: 11/15/2023 10:55
Test Hesufts Units MQL OF Date f Time By Analytical
Analyzed Method
Bromide (Br) <0 500 mg/L 0.500 1 11/21/23 14:24 KNC 300.0
Qualifiers/ OF Dilution Factor MQL Method Quantitation Limit
Definitions

r •
Waypoint,
449 Springbroolc Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
00435
Waypoint Analytical - Greenville Project Avoca, LLC
Ann Baynor Report Date ; 11/22/2023
114 Oakmont Dr Information: (Wastewater) Received : 11/17/2023
Greenville , NC 27858
Report Number: 23-321-0064 REPORT OFANALYSIS
i
Lab No : 89669 Matrix: Aqueous
Sample ID : Well #10 Sampled: 11/15/2023 11:55
Test Results Units MOL DF Date / Time By Analytical
Analyzed Method
Bromide (8r) <0.500 mg/L. 0.500 1 11/21/23 14.36 KNC 300.0
Qualifiers/ DF Dilution Factor MQL Method Quantitat€on Limit
Definitions

a
r
Waypoint449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
00435
Waypoint Analytical - Greenville Project Avoca, LLC
Ann Baynor Report Date : 11/22/2023
114 Oakmont Or Information : (Wastewater) Received : 1111712023
Greenville , NC 27858
Report Number : 23-321-0064 REPORT OFANALY515
Lab No ; 89670 Matrix: Aqueous
Sample ID : Well #11 Sampled: 11/15/2023 9.50
Test Results Units MQL OF Date I Time By Analytical
Analyzed Method
a
Bromide (Br) 11.2 mg/L 0.500 1 11/21/23 14.48 KNC 300.0
Qualifiers/ DF Dilution Factor MQL Method Quantitation Limit
Definitions

s
Waypoint,
ANALYTICAL
449 Springbrook kd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 00435
Customer Name: Waypoint Analytical - Greenville
Report Number: 23-321-0064
Shipping Method
0 Fed Ex 0 US Postal DO Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IRT151AC
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolerslboxes received
r 1
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
Yes
0 No
COC agrees with sample label(s)?
Yes
0 No
COG properly completed
Yes
0 No
Samples in proper containers?
Yes
0 No
Sample containers intact?
Yes
0 No
Sufficient sample volume for indicated test(s)?
Yes
0 No
All samples received within holding time?
Yes
0 No
Cooler temperature in compliance?
Yes
0 No
Cooler/Samples arrived at the laboratory on ice
Samples were considered acceptable as cooling
process had begun.
Yes
0 No
Water - Sample containers properly preserved
Yes
0 No
0 NIA
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
DO N/A
(— High concentration container (48 hr) F_ Low concentration EnCore samplers (48 hr)
F High concentration pre -weighed (methanol -14 d) F Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: amie Corporaal Date &Time: i1/17/2023 17:37:54

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