HomeMy WebLinkAboutNC0000078_Groundwater Moniotring Report November 2023_20231215GW-59A COMPLIANCE REPORT FORM Permit#
(,5rib it ane each nio nitorint; period with Gff-59fiaavns,)
j
Enter date monitoring results were due. ( 112 KWill this monitoring report (GW-59 and GW-59A)
YES
NO
be submitted after the established due date?
2
Was any required information missing on the GW-59 report forms`'
YES
NO
IF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
YES
NO
identification plate, area overgrown, etc.)? If the answer is "Yes ", contact the Regional Office for guidance.
f
4
Are any monitored constituents equal to or above the established standards?
YF5,,
NO
If the answer to question 4 is "NO", skip to section 8.
If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s)
exceeding standards in the space provided below:
5
For the constituents identified in question 4 above, have standards been exceeded previously for the
YES
NO
same constituent(s) in the same well(s) in the last two years?
If the answer to question 5 is "NO", skip to section 8.
If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding
standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years).
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
YES
NO,
If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly
located; contact the Regional Office.
7
Is the permittee implementing previously approved actions required by the Division involving this
YES
NOf
groundwater quality problem?
If the answer to question 7 is "YES", describe those actions in the space provided below.
If the answer to question 7 is "NO", contact the Regional Office within 90 days; an evaluation may be
required to determine the impact the waste disposal system is having at the review and compliance
boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation,
fines, and/or penalties.
g
The person completing this portion (GW-59A) of the monitoring report should sign below and submit this
form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form.
I hereby acknowledge that the above information was evaluated and the information submitted in this
report (Compliance Report GW-59A) is true and complete to the best of my knowledge.
<
4
Signature of Permittee (or, Authorised Agent) / Date/
-�9A 12/8/2003
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
December 14, 2023
Mr. Bernie Kelly
Davidson River Village, LLC
P.O. Box 880
Pisgah Forest, NC 28768
RE: Project: November 23' Sampling
Pace Project No.: 92700675
Dear Mr. Kelly:
Enclosed are the analytical results for sample(s) received by the laboratory on November 28, 2023. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services -Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Sara Poulson
sara.poulson@pacelabs.com
704-977-0964
Project Manager
Enclosures
`geQitA"tt?Q%,
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 28
Project: November 23' Sampling
Pace Project No.: 92700675
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
CERTIFICATIONS
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Page 2 of 28
aee
SAMPLE ANALYTE COUNT
Project: November 23' Sampling
Pace Project No.: 92700675
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92700675001
Q88V2
EPA 601OD
DBB1
6
PASI-A
EPA 6020E
KRL
1
PASI-A
EPA 7470A
BM
1
PASI-A
SM 6200B
SAS
63
PASI-C
SM 2540C-2015
RVS
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
EPA 350.1 Rev 2.0 1993
EGC
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92700675002
ASB-01
EPA 601OD
DBB1
6
PASI-A
EPA6020B
KRL
1
PASI-A
EPA 7470A
BM
1
PASI-A
SM 6200B
SAS
63
PASI-C
SM 2540C-2015
RVS
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
EPA 350.1 Rev 2.0 1993
EGC
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92700675003
ASB-02
EPA 601 OD
D1361
6
PASI-A
EPA 60206 - _ ..
KRL _
1
PASI-A
EPA 7470A
BM
1
PASI-A
SM 6200E
SAS
63
PASI-C
SM 2540C-2015
RVS
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
EPA 350.1 Rev 2.0 1993
EGC
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 28
Pace Analytical Services, LLC
2225 Riverside Dr,
Asheville, NC 28804
(828)254-7176
ANALYTICAL RESULTS
Project: November 23' Sampling
Pace Project No.: 92700675
Sample: Q88V2 Lab ID: 92700676001 Collected: 11/28/23 11:35 Received: 11/28/23 17:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
12/14/23 09:37
Collected By
MPS
1
12/14/23 09:37
Collected Date
11/28/23
1
12/14/23 09:37
Collected Time
11:35
1
12/14/23 09:37
pH
4.97 Std. Units
1
12/14/23 09:37
Temperature
12.3 deg C
1
12/14/23 09:37
Static Water Level
65.46 feet
1
12/14/23 09:37
Specific Conductance
19.4 umhos/cm
1
12/14/23 09:37
Oxygen, Dissolved
5.18 mg/L
1
12/14/23 09:37
7782-44-7
Total Well Depth
68.5 feet
1
12/14/23 09:37
REDOX
182.3 my
1
12/14/23 09:37
Turbidity
3.19 NTU
1
12/14/23 09:37
Iron, Ferrous
NA mg/L
1
12/14/23 09:37
Odor
None
1
12/14/23 09:37
Appearance
Clear
1
12/14/23 09:37
6010 MET ICP
Analytical Method: EPA 601 OD Preparation
Method:
EPA 3010A
Pace Analytical Services -Asheville
Arsenic
ND ug/L
10.0
1 11/30/23 12:45
12/05/23 21:33
7440-38-2
Chromium
39.2 ug/L
5.0
1 11/30/23 12:45
12/05/23 21:33
7440-47-3
Iron
273 ug/L
50.0
1 11/30/23 12:45
12/06/2316:05
7439-89-6
Lead
ND ug/L
5.0
1 11/30/23 12:45
12/05/23 21:33
7439-92-1
Manganese
13.7 ug/L
5.0
1 11/30/23 12:45
12/05/23 21:33
7439-96-5
Sodium
ND ug/L
5000
1 11/30/23 12:45
12/05/23 21:33
7440-23-5
6020 MET ICPMS
Analytical Method: EPA 6020B Preparation Method:
EPA 3010A
Pace Analytical Services -Asheville
Cobalt
ND ug/L
1.0
1 11/29/23 01:49
11/30/23 14:49
7440-48-4
7470 Mercury
Analytical Method: EPA 7470A Preparation
Method:
EPA 7470A
Pace Analytical Services -Asheville
Mercury
ND ug/L
0.20
1 11/29/23 11:35
11/30/23 09:39
7439-97-6
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Benzene
ND ug/L
0.50
1
12/04/23 20:21
71-43-2
Bromobenzene
ND ug/L
0.50
1
12/04/23 20:21
108-86-1
Bromochloromethane
ND ug/L
0.50
1
12/04/23 20:21
74-97-5
Bromodichloromethane
ND ug/L
0.50
1
12/04/23 20:21
75-27-4
Bromoform
ND ug/L
0.50
1
12/04/23 20:21
75-25-2
Bromomethane
ND ug/L
5.0
1
12/04/23 20:21
74-83-9
n-Butylbenzene
ND ug/L
0.50
1
12/04/23 20:21
104-51-8
sec-Butylbenzene
ND ug/L
0.50
1
12/04/23 20:21
135-98-8
tert-Butylbenzene
ND ug/L
0.50
1
12/04/23 20:21
98-06-6
Carbon tetrachloride
ND ug/L
0.50
1
12/04/23 20:21
56-23-5
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/14/2023 10:53 AM
without the written consent of Pace Analytical Services, LLC.
Page 4 of 28
lace",
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Project: November 23' Sampling
Pace Project No.: 92700675
Sample: Q88V2 Lab ID: 92700675001 Collected: 11/28/23 11:35 Received: 11/28/23 17:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua]
6200B MSV
Analytical Method: SM 6200B
Pace Analytical
Services - Charlotte
Chlorobenzene
ND
ug/L
0.50
1
Chloroethane
ND
ug/L
1.0
1
Chloroform
ND
ug/L
0,50
1
Chloromethane
ND
ug/L
1.0
1
2-Chlorotoluene
ND
ug/L
0.50
1
4-Chlorotoluene
ND
ug/L
0.50
1
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
Dibromochloromethane
ND
ug/L
0.50
1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
Dibromomethane
ND
ug/L
0.50
1
1,2-Dichlorobenzene
ND
ug/L
0.50
1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
Dichlorodifluoromethane
ND
ug/L
0.50
1
1,1-Dichloroethane
ND
ug/L
0.50
1
1,2-Dichloroethane
ND
ug/L
0.50
1
1,1-Dichloroethene
ND
ug/L
0.50'
1
cis- 1,2-Dichloroethene
ND
ug/L
0.50
1
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
1,2-Dichloropropane
ND
ug/L
0.50
1
1,3-Dichloropropane
ND
ug/L
0.50
1
2,2-Dichloropropane
ND
ug/L
0.50
1
1,1-Dichloropropene
ND
ug/L
0.50
1
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
trans-1,3-Dichloropropene
ND
ug/L
0.50
1
Diisopropyl ether
ND
ug/L
0.50
1
Ethylbenzene
ND
ug/L
0.50
1
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
Methylene Chloride
ND
ug/L
2.0
1
Methyl -tent -butyl ether
ND
ug/L
0.50
1
Naphthalene
ND
ug/L
2.0
1
n-Propylbenzene
ND
ug/L
0.50
1
Styrene
ND
ug/L
0.50
1
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
Tetrachloroethene
ND
ug/L
0.50
1
Toluene
ND
ug/L
0.50
1
1,2,3-Trichlorobenzene
ND
ug/L
2.0
1
1,2,4-Trichlorobenzene
ND
ug/L
2.0
1
1,1,1-Trichloroethane
ND
ug/L
0.50
1
1,1,2-Trichloroethane
ND
ug/L
0.50
1
Trichloroethene
ND
ug/L
0.50
1
Trichlorofluoromethane
ND
ug/L
1.0
1
1,2,3-Trichloropropane
ND
ug/L
0.50
1
1,2,4-Trimethylbenzene
ND
ug/L
0.50
1
Date: 12/14/2023 10:53 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
12/04/23 20:21
108-90-7
12/04/23 20:21
75-00-3
12/04/23 20:21
67-66-3
12/04/23 20:21
74-87-3
12/04/23 20:21
95-49-8
12/04/23 20:21
106-43-4
12/04/23 20:21
96-12-8
12/04/23 20:21
124-48-1
12/04/23 20:21
106-93-4
12/04/23 20:21
74-95-3
12/04/23 20:21
95-50-1
12/04/23 20:21
541-73-1
12/04/23 20:21
106-46-7
12/04/23 20:21
75-71-8
12/04/23 20:21
75-34-3
12/04/23 20:21
107-06-2
12/04/23 20:21
75-35-4
12/04/23 20:21
156-59-2
12/04/23 20:21
156-60-5
12/04/23 20:21
78-87-5
12/04/23 20:21
142-28-9
12/04/23 20:21
594-20-7
12/04/23 20:21
563-58-6
12/04/23 20:21
10061-01-5
12/04/23 20:21
10061-02-6
12/04/23 20:21
108-20-3
12/04/23 20:21
100-41-4
12/04/23 20:21
87-68-3
12/04/23 20:21
98-82-8
12/04/23 20:21
75-09-2
12/04/23 20:21
1634-04-4
12/04/23 20:21
91-20-3
12/04/23 20:21
103-65-1
12/04/23 20:21
100-42-5
12/04/23 20:21
630-20-6
12/04/23 20:21
79-34-5
12/04/23 20:21
127-18-4
12/04/23 20:21
108-88-3
12/04/23 20:21
87-61-6
12/04/23 20:21
120-82-1
12/04/23 20:21
71-55-6
12/04/23 20:21
79-00-5
12/104/23 20:21
79-01-6
12/04/23 20:21
75-69-4
12/04/23 20:21
96-18-4
12/04/23 20:21
95-63-6
Page 5 of 28
2 le
ace�'
I
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr,
Asheville, NC 28804
(828)254-7176
Project: November 23' Sampling
Pace Project No.: 92700675
Sample: Q88V2
Lab lD: 92700675001 Collected:
11/28/23 11:35
Received: 11/28/23 17:00 Matrix:
Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
6200E MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
1,3,5-Trimethylbenzene
ND ug/L
0.50
1
12/04/23 20:21
108-67-8
Vinyl chloride
ND ug/L
1.0
1
12/04/23 20:21
75-01-4
m&p-Xylene
ND ug/L
1.0
1
12/04/23 20:21
179601-23-1
o-Xylene
ND ug/L
0.50
1
12/04/23 20:21
95-47-6
Surrogates
1,2-Dichloroethane-d4(S)
98 %
70-130
1
12/04/23 20:21
17060-07-0
4-Bromofluorobenzene (S)
95 %
70-130
1
12/04/23 20:21
460-00-4
Toluene-d8 (S)
98 %
70-130
1
12/04/23 20:21
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services - Asheville
Total Dissolved Solids
ND mg/L
25.0
1
11/29/23 19:20
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1
1993
Pace Analytical Services - Asheville
Sulfate
ND mg/L
1.0
1
11/29/2316:36
14808-79-8
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L
0.10
1
12/09/23 11:56
7664-41-7
5310B TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
ND mg/L
1.0
1
12/05/23 04:30
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/14/2023 10:53 AM without the written consent of Pace Analytical Services, LLC.
Page 6 of 28
aee
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Project: November 23' Sampling
Pace Project No.: 92700675
Sample: ASB-01 Lab ID: 92700675002 Collected: 11/28/23 14:05 Received: 11/28/23 17:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
12/14/23 09:39
Collected By
MPS
1
12/14/23 09:39
Collected Date
11/28/23
1
12/14/23 09:39
Collected Time
14:05
1
12/14/23 09:39
pH
5.92 Std. Units
1
12/14/23 09:39
Temperature
11.4 deg C
1
12/14/23 09:39
Static Water Level
9.09 feet
1
12/14/23 09:39
Specific Conductance
400.8 umhos/cm
1
12/14/23 09:39
Oxygen, Dissolved
0.28 mg/L
1
12/14/23 09:39
7782-44-7
Total Well Depth
15.00 feet
1
12/14/23 09:39
REDOX
182.7 my
1
12/14/23 09:39
Turbidity
7.47 NTU
1
12/14/23 09:39
Odor
None
1
12/14/23 09:39
Appearance
Clear
1
12/14/23 09:39
6010 MET ICP
Analytical Method: EPA 601 OD Preparation
Method: EPA 3010A
Pace Analytical Services -Asheville
Arsenic
ND ug/L
10.0
1 11/30/23 12:45
12/05/23 21:36
7440-38-2
Chromium
ND ug/L
5.0
1 11/30/23 12:45
12/05/23 21:36
7440-47-3
Iron
1860 ug/L
50.0
1 11/30/23 12:45
12/06/2316:08
7439-89-6
Lead
ND ug/L
5.0
1 11/30/23 12:45
12/05/23 21:36
7439-92-1
Manganese
1950 ug/L
5.0
1 11/30/23 12:45
12/05/23 21:36
7439-96-5
Sodium
30900 ug/L
5000
1 11/30/23 12:45
12/05/23 21:36
7440-23-5
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation
Method: EPA 3010A
Pace Analytical Services - Asheville
Cobalt
4.1 ug/L
1.0
1 11/29/23 01:49
11/30/23 15:13
7440-48-4
7470 Mercury
Analytical Method: EPA 7470A Preparation
Method:
EPA 7470A
Pace Analytical Services -Asheville
Mercury
ND ug/L
0.20
1 11/29/23 11:35
11/30/23 09:42
7439-97-6
6200E MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Benzene _
-ND ug/L
0.50
1
12/04/23 20:40
71-43-2
Bromobenzene
ND ug/L
0.50
1
12/04/23 20:40
108-86-1
Bromochloromethane
ND ug/L
0.50
1
12/04/23 20:40
74-97-5
Bromodichloromethane
ND ug/L
0.50
1
12/04/23 20:40
75-27-4
Bromoform
ND ug/L
0.50
1
12/04/23 20:40
75-25-2
Bromomethane
ND ug/L
5.0
1
12/04/23 20:40
74-83-9
n-Butylbenzene
ND ug/L
0.50
1
12/04/23 20:40
104-51-8
sec-Butylbenzene
ND ug/L
0.50
1
12/04/23 20:40
135-98-8
tert-Butylbenzene
ND ug/L'
0.50
1
12/04/23 20:40
98-06-6
Carbon tetrachloride
ND ug/L
0.50
1
12/04/23 20:40
56-23-5
Chlorobenzene
ND ug/L
0.50
1
12/04/23 20:40
108-90-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/14/2023 10:53 AM
without the written consent of Pace Analytical Services, LLC.
Page 7 of 28
ANALYTICAL RESULTS
Project: November 23' Sampling
Pace Project No.: 92700675
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Sample: ASB-01 Lab ID: 92700675002 Collected: 11/28/23 14:05 Received: 11/28/23 17:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Date: 12/14/2023 10:53 AM
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
ND ug/L
1.0
1
ND ug/L
0.50
1
ND ug/L
1.0
1
ND ug/L
0.50
1
ND ug/L
0.50
1
ND ug/L
1.0
1
ND ug/L
0.50
1
ND ug/L
0.50
1
ND ug/L
0.50
1
ND ug/L
0.50
1
ND ug/L
0.50
1
ND ug/L
0.50
1
ND ug/L
0.50
1
ND ug/L
0.50
1
ND ug/L
0.50
1
ND ug/L
0.50
1
ND ug/L
0.50
1
ND ug/L
0.50
1
ND ug/L
0.50
1
ND ug/L
0.50
1
ND ug/L
0.50.
1._.
ND ug/L
0.50
1
ND ug/L
0.50
1
ND ug/L
0.50
1
ND ug/L .
0.50
1
ND ug/L
0.50
1
ND ug/L
2.0
1
ND ug/L
0.50
1
ND ug/L
2.0
1
ND ug/L
0.50
1
ND ug/L
2.0
1
ND ug/L
0.50
1
ND ug/L
0.50
1
ND ug/L
0.50
1
ND ug/L
0.50
1
ND ug/L
0.50
1
ND ug/L
0.50
1
ND ug/L
2.0
1
ND ug/L
2.0
1
ND ug/L
0.50
1
ND ug/L
0.50
1
ND ug/L
0.50
1
ND ug/L
1.0
1
ND ug/L
0.50
1
ND ug/L
0.50
1
ND ug/L
0.50
1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
12/04/23 20:40 75-00-3
12/04/23 20:40 67-66-3
12/04/23 20:40 74-87-3
12/04/23 20:40 95-49-8
12/04/23 20:40 106-43-4
12/04/23 20:40 96-12-8
12/04/23 20:40 124-48-1
12/04/23 20:40 106-93-4
12/04/23 20:40 74-95-3
12/04/23 20:40 95-50-1
12/04/23 20:40 541-73-1
12/04/23 20:40 106-46-7
12/04/23 20:40 75-71-8
12/04/23 20:40 75-34-3
12/04/23 20:40 107-06-2
12/04/23 20:40 75-35-4
12/04/23 20:40 156-59-2
12/04/23 20:40 156-60-5
12/04/23 20:40 78-87-5
12/04/23 20:40 142-28-9
12/04/23 20`40 594-20-7
12/04/23 20:40 563-58-6
12/04/23 20:40 10061-01-5
12/04/23 20:40 10061-02-6
12/04/23 20:40 108-20-3
12/04/23 20:40 100-41-4
12/04/23 20:40 87-68-3
12/04/23 20:40 98-82-8
12/04/23 20:40 75-09-2
12/04/23 20:40 1634-04-4
12/04/23 20:40 91-20-3
12/04/23 20:40 103-65-1
12/04/23 20:40 100-42-5
12/104/23 20:40 630-20-6
12/04/23 20:40 79-34-5
12/04/23 20:40 127-18-4
12/04/23 20:40 108-88-3
12/04/23 20:40 87-61-6
12/04/23 20:40 120-82-1
12/04/23 20:40 71-55-6
12/04/23 20:40 79-00-5
12/104/23 20:40 79-01-6
12/04/23 20:40 75-69-4
12/04/23 20:40 96-18-4
12/04/23 20:40 95-63-6
12/104/23 20:40 108-67-8
Page 8 of 28
ANALYTICAL RESULTS
Project: November 23' Sampling
Pace Project No.: 92700675
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Sample: ASB-01
Lab ID: 92700675002 Collected:
11/28/23 14:05
Received: 11/28/23 17:00 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qua]
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Vinyl chloride
ND ug/L
1.0
1
12/04/23 20:40
75-01-4
m&p-Xylene
ND ug/L
1.0
1
12/04/23 20:40
179601-23-1
o-Xylene
ND ug/L
0.50
1
12/04/23 20:40
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
97 %
70-130
1
12/04/23 20:40
17060-07-0
4-Bromof]uorobenzene (S)
95 %
70-130
1
12/04/23 20:40
460-00-4
Toluene-d8 (S)
98 %
70-130
1
12/04/23 20:40
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
268 mg/L
25.0
1
11/29/23 19:20
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1
1993
Pace Analytical Services - Asheville
Sulfate
8.4 mg/L
1.0
1
11/29/2317:20
14808-79-8
350.1 Ammonia
Analytical Method: EPA350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, Ammonia
ND mg/L
0.10
1
12/09/23 11:57
7664-41-7
5310B TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services - Asheville
Total Organic Carbon
ND mg/L
1.0
1
12/05/23 04:48
7440-44-0
Date: 12/14/2023 10:53 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 9 of 28
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
ANALYTICAL RESULTS
Project: November 23' Sampling
Pace Project No.: 92700675
Sample: ASB-02 Lab ID: 92700675003 Collected: 11/28/23 13:10 Received: 11/28/23 17:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No, Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
12/14/23 09:41
Collected By
MPS
1
12/14/23 09:41
Collected Date
11/28/23
1
12/14/23 09:41
Collected Time
13:10
1
12/14/23 09:41
pH
5.73 Std. Units
1
12/14/23 09:41
Temperature
14.3 deg C
1
12/14/23 09:41
Static Water Level
9.39 feet
1
12/14/23 09:41
Specific Conductance
160.6 umhos/cm
1
12/14/23 09:41
Oxygen, Dissolved
3.41 mg/L
1
12/14/23 09:41
7782-44-7
Total Well Depth
12.00 feet
1
12/14/23 09:41
REDOX
179.8 mV
1
12/14/23 09:41
Turbidity
1.21 NTU
1
12/14/23 09:41
Odor
None
1
12/14/23 09:41
Appearance
Clear
1
12/14/23 09:41
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method:
EPA 3010A
Pace Analytical Services - Asheville
-
Arsenic
ND ug/L
10.0
1 11/30/23 12:45
12/05/23 21:39
7440-38-2
Chromium
ND ug/L
5.0
1 11/30/23 12:45
12/05/23 21:39
7440-47-3
Iron
186 ug/L
50.0
1 11/30/23 12:45
12/06/2316:11
7439-89-6
Lead
ND ug/L
5.0
1 11/30/23 12:45
12/05/23 21:39
7439-92-1
Manganese
86.4 ug/L
5.0
1 11/30/23 12:45
12/05/23 21:39
7439-96-5
Sodium
17500 ug/L
5000
1 11/30/23 12:45
12/05/23 21:39
7440-23-5
6020 MET ICPMS
Analytical Method: EPA 6020B Preparation Method:
EPA 3010A
Pace Analytical Services - Asheville
Cobalt
ND ug/L
1.0
1 11/29/23 01:49
11/30/23 15:18
7440-48-4
7470 Mercury
Analytical Method: EPA 7470A Preparation
Method:
EPA 7470A
Pace Analytical Services - Asheville
Mercury
ND ug/L
0.20
1 11/29/23 11:35
11/30/23 09:44
7439-97-6
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Benzene
ND ug/L
0.50
1
12/04/23 20:58
71-43-2
Bromobenzene
ND ug/L
0.50
1
12/04/23 20:58
108-86-1
Bromochloromethane
ND ug/L
0.50
1
12/04/23 20:58
74-97-5
Bromodichloromethane
ND ug/L
0.50
1
12/04/23 20:58
75-27-4
Bromoform
ND ug/L
0.50
1
12/04/23 20:58
75-25-2
Bromomethane
ND ug/L
5.0
1
12/04/23 20:58
74-83-9
n-Butylbenzene
ND ug/L
0.50
1
12/04/23 20:58
104-51-8
sec -Butyl benzene
ND ug/L
0.50
1
12/04/23 20:58
135-98-8
tert-Butylbenzene
ND ug/L
0.50
1
12/04/23 20:58
98-06-6
Carbon tetrachloride
ND ug/L
0.50
1
12/04/23 20:58
56-23-5
Chlorobenzene
ND ug/L
0.50
1
12/04/23 20:58
108-90-7
'REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/14/2023 10:53 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 28
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804 -Va c e
f (828)254-7176
i
ANALYTICAL RESULTS
Project: November 23' Sampling
Pace Project No.: 92700675
Sample: ASB-02 Lab ID: 92700675003 Collected: 11/28/23 13:10 Received: 11/28/23 17:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared
6200B MSV
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Date: 12/14/2023 10:53 AM
Analytical Method: SM 6200B
Pace Analytical
Services - Charlotte
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug%L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug%L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug7L
1.0 1
0.50 1
1.0 1
0.50 1
0.50 1
1.0 1
0.50 1
0.50 1
0.50 1
0.50 1
0.50 1
0.50 1
0.50 1
0.50 1
0.50 1
0.50 1
0.50 1
0.50 1
0.50 1
0.50 1
0.50 1
0.50 1
0.50 1
0.50 1
0.50 1
0.50 1
2.0 1
0.50 1
2.0 1
0.50 1
2.0 1
0.50 1
0.50 1
0.50 1
0.50 1
0.50 1
0.50 1
2.0 1
2.0 1
0.50 1
0.50 1
0.50 1
1.0 1
0.50 1
0.50 1
0.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC
Analyzed CAS No. Qual
12/04/23 20:58 75-00-3
12/04/23 20:58 67-66-3
12/04/23 20:58 74-87-3
12/04/23 20:58 95-49-8
12/04/23 20:58 106-43-4
12/04/23 20:58 96-12-8
12/04/23 20:58 124-48-1
12/04/23 20:58 106-93-4
12/04/23 20:58 74-95-3
12/04/23 20:58 95-50-1
12/04/23 20:58 541-73-1
12/04/23 20:58 106-46-7
12/04/23 20:58 75-71-8
12/04/23 20:58 75-34-3
12/04/23 20:58 107-06-2
12/04/23 20:58 75-35-4
12/04/23 20:58 156-59-2
12/04/23 20:58 156-60-5
12/04/23 20:58 78-87-5
12/04/23 20:58 142-28-9
"12/04/23 20.'58 594-20-7
12/04/23 20:58 563-58-6
12/04/23 20:58 10061-01-5
12/04/23 20:58 10061-02-6
12/04/23 20:58 108-20-3
12/04/23 20:58 100-41-4
12/04/23 20:58 87-68-3
12/04/23 20:58 98-82-8
12/04/23 20:58 75-09-2
12/04/23 20:58 1634-04-4
12/04/23 20:58 91-20-3
12/104/23 20:58 103-65-1
12/04/23 20:58 100-42-5
12/04/23 20:58 630-20-6
12/04/23 20:58 79-34-5
12/04/23 20:58 127-18-4
12/04/23 20:58 108-88-3
12/04/23 20:58 87-61-6
12/04/23 20:58 120-82-1
12/104/23 20:58 71-55-6
12/04/23 20:58 79-00-5
12/o4/23 20:58 79-01-6
12/04/23 20:58 75-69-4
12/04/23 20:58 96-18-4
12/04/23 20:58 95-63-6
12/04/23 20:58 108-67-8
Page 11 of 28
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
ANALYTICAL RESULTS
Project: November 23' Sampling
Pace Project No.: 92700675
Sample: ASB-02
Lab ID: 92700675003 Collected:
11/28/23 13:10
Received: 11/28/23 17:00 Matrix:
Water
Parameters
Results Units Report
Limit
DF
Prepared Analyzed
CAS No. Qual
6200E MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Vinyl chloride
ND ug/L
1.0
1
12/04/23 20:58
75-01-4
m&p-Xylene
ND ug/L
1.0
1
12/04/23 20:58
179601-23-1
o-Xylene
ND ug/L
0.50
1
12/04/23 20:58
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
97 %
70-130
1
12/04/23 20:58
17060-07-0
4-Bromofluorobenzene (S)
96 %
70-130
1
12/04/23 20:58
460-00-4
Toluene-d8 (S)
99 %
70-130
1
12/04/23 20:58
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services - Asheville
Total Dissolved Solids
95.0 mg/L
25.0
1
11/29/23 19:20
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1
1993
Pace Analytical Services -Asheville
Sulfate
2.6 mg/L
1.0
1
11/29/2317:35
14808-79-8
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, Ammonia
ND mg/L
0.10
1
12/09/23 11:59
7664-41-7
5310BTOC
Analytical Method: SM 5310E-2014
Pace Analytical Services - Asheville
Total Organic Carbon
ND mg/L
1.0
1
12/05/23 05:07
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/14/2023 10:53 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 28
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
QUALITY CONTROL DATA
Project: November,23' Sampling
Pace Project No.: 92700675
QC Batch: 816038 Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92700675001, 92700675002, 92700675003
METHOD BLANK: 4223715 Matrix: Water
Associated Lab Samples: 92700675001, 92700675002, 92700675003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ug/L ND 0.20 11/30/23 09:02
LABORATORY CONTROL SAMPLE:
4223716
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Mercury
ug/L
2.5
2.6
103
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4223717
4223718
MS
MSD
92700370002
Spike
Spike MS
MSD
MS MSD % Rec
Parameter
Units Result
Conc.
Conc. Result
Result
% Rec % Rec Limits RPD Qua]
Mercury
ug/L ND
2.5
2.5 2.5
2.5
99 100 75-125 2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/14/2023 10:53 AM without the written consent of Pace Analytical Services, LLC, Page 13 of 28
(. �9(3ce�,
QUALITY CONTROL DATA
Project: November 23' Sampling
Pace Project No.: 92700675
QC Batch: 816317 Analysis Method: EPA 601 OD
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92700675001, 92700675002, 92700675003
METHOD BLANK: 4225280
Matrix: Water
Associated Lab Samples:
92700675001, 92700675002, 92700675003
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Arsenic
ug/L
ND
10.0
12/05/23 20:28
Chromium
ug/L
ND
5.0
12/05/23 20:28
Iron
ug/L
ND
50.0
12/05/23 20:28
Lead
ug/L
ND
5.0
12/05/23 20:28
Manganese
ug/L
ND
5.0
12/05/23 20:28
Sodium
ug/L
ND
5000
12/05/23 20:28
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
LABORATORY CONTROL SAMPLE:
4225281
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Arsenic
ug/L
- 500
486
97
80-120
Chromium
ug/L
500
504
101
80-120
Iron
ug/L
5000
5150
103
80-120
Lead
ug/L
500
492
98
80-120
Manganese
ug/L
500
510
102
80-120
Sodium
ug/L
5000
5140
103
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4225282
4225283
MS
MSD
92700682042
Spike
Spike
MS
MSD
MS MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD Qual
Arsenic
ug/L
ND
500
500
487
476
97
95
75-125
2
Chromium
ug/L
126
.500
500
612
640
97
103
75-125
5
Iron
ug/L
56100
5000
5000
65100
79300
179
462
75-125
20 M1
Lead
ug/L
10.0
500
500
506
498
99
98
75-125
2
Manganese
ug/L
1070
500
500
1640
1740
115
135
75-125
6 M1
Sodium
ug/L
6150
5000
5000
11800
11600
112
110
75-125
1
Results presented on this page are in the units indicated by the "Units" columnexcept where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/14/2023 10:53 AM without the written consent of Pace Analytical Services, LLC.
Page 14 of 28
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
QUALITY CONTROL DATA
Project: November 23' Sampling
Pace Project No.: 92700675
QC Batch: 815917 Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92700675001, 92700675002, 92700675003
METHOD BLANK: 4223268 Matrix: Water
Associated Lab Samples: 92700675001, 92700675002, 92700675003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Cobalt ug/L ND 1.0 11/30/2314:39
LABORATORY CONTROL SAMPLE: 4223269
Spike
LCS
LCS
% Rec
Parameter Units
Conc.
Result
% Rec
Limits Qualifiers
Cobalt ug/L
50
51.8
104
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4223270
4223271
MS
MSD
92700675001
Spike
Spike MS
MSD
MS MSD % Rec
Parameter Units Result
Conc.
Conc. Result
Result
% Rec % Rec Limits RPD Qual
Cobalt ug/L ND
50
50 51.3
50.1
102 100 75-125 2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/14/2023 10:53 AM without the written consent of Pace Analytical Services, LLC. Page 15 of 28
Pace Analytical Services, LLC
2225 Riverside Dr,
Asheville, NC 28804
(828)254-7176
QUALITY CONTROL DATA
Project: November 23' Sampling
Pace Project No.: 92700675
QC Batch: 817079 Analysis Method: SM 6200B
QC Batch Method: SM 6200B Analysis Description: 6200B MSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92700675001, 92700675002, 92700675003
METHOD BLANK: 4228984
Matrix: Water
Associated Lab Samples: 92700675001, 92700675002, 92700675003
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
0.50
12/04/23 18:14
1,1,1-Trichloroethane
ug/L
ND
0.50
12/04/23 18:14
1,1,2,2-Tetrachloroethane
ug/L
ND
0.50
12/04/23 18:14
1,1,2-Trichloroethane
ug/L
ND
0.50
12/04/23 18:14
1,1-Dichloroethane
ug/L
ND
0.50
12/04/23 18:14
1,1-Dichloroethene
ug/L
ND
0.50
12/04/23 18:14
1,1-Dichloropropene
ug/L
ND
0.50
12/04/23 18:14
1,2,3-Trichlorobenzene
ug/L
ND
2.0
12/04/23 18:14
1,2,3-Trichloropropane
ug/L
ND
0.50
12/04/23 18:14
1,2,4-Trichlorobenzene
ug/L
ND
2.0
12/04/23 18:14
1,2,4-Trimethylbenzene
ug/L
ND
0.50
12/04/23 18:14
1,2-Dibromo-3-chloropropane
ug/L
ND
1.0
12/04/23 18:14
1,2-Dibromoethane (EDB)
ug/L
ND
0.50
12/04/23 18:14
1,2-Dichlorobenzene
ug/L
ND
0.50
12/04/23 18:14
1,2-Dichloroethane
ug/L
ND
0.50
12/04/23 18:14
1,2-Dichloropropane
ug/L
ND
0.50
12/04/23 18:14
1,3,5-Trimethylbenzene
ug/L
ND
0.50
12/04/23 18:14
1,3-Dichlorobenzene
ug/L
ND
0.50
12/04/23 18:14
1,3-Dichloropropane
ug/L
ND
0.50
12/04/23 18:14
1,4-Dichlorobenzene
ug/L
ND
0.50
12/04/23 18:14
2,2-Dichloropropane
ug/L
ND
0.50
12/04/23 18:14
2-Chlorotoluene
ug/L
ND
0.50
12/04/23 18:14
4-Chlorotoluene
ug/L
ND
0.50
12/04/23 18:14
Benzene
ug/L
ND
0.50
12/04/23 18:14
Bromobenzene
ug/L
ND
0.50
12/04/23 18:14
Bromochloromethane
ug/L
ND
0.50
12/04/23 18:14
Bromodichloromethane
ug/L
ND
0.50
12/04/23 18:14
Bromoform
ug/L
ND
0.50
12/04/23 18:14
Bromomethane
ug/L
ND
5.0
12/04/23 18:14
Carbon tetrachloride
ug/L
ND
0.50
12/04/23 18:14
Chlorobenzene
ug/L
ND
0.50
12/04/23 18:14
Chloroethane
ug/L
ND
1.0
12/04/23 18:14
Chloroform
ug/L
ND
0.50
12/04/23 18:14
Chloromethane
ug/L
ND
1.0
12/04/23 18:14
cis-1,2-Dichloroethene
ug/L
ND
0.50
12/04/23 18:14
cis-1,3-Dichloropropene
ug/L
ND
0.50
12/04/23 18:14
Dibromochloromethane
ug/L
ND
0.50
12/04/23 18:14
Dibromomethane
ug/L
ND
0.50
12/04/23 18:14
Dichlorodifluoromethane
ug/L
ND
0.50
12/104/2318:14
Diisopropyl ether
ug/L
ND
0.50
12/104/23 18:14
Results presorted on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced•, except in full.
Date: 12/14/2023 10:53 AM without the written consent of Pace Analytical Services, LLC.
Page 16 of 28
QUALITY CONTROL DATA
Project: November 23' Sampling
Pace Project No.: 92700675
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
METHOD BLANK: 4228984 Matrix: Water
Associated Lab Samples: 92700675001, 92700675002, 92700675003
Blank Reporting
Parameter Units Result Limit
Analyzed Qualifiers
Ethylbenzene
ug/L
ND
0.50
12/04/23 18:14
Hexachloro-1,3-butadiene
ug/L
ND
2.0
12/04/23 18:14
Isopropylbenzene (Cumene)
ug/L
ND
0.50
12/04/23 18:14
m&p-Xylene
ug/L
ND
1.0
12/04/23 18:14
Methyl-tert-butyl ether
ug/L
ND
0.50
12/04/23 18:14
Methylene Chloride
ug/L
ND
2.0
12/04/23 18:14
n-Butylbenzene
ug/L
ND
0.50
12/04/23 18:14
n-Propylbenzene
ug/L
ND
0.50
12/04/23 18:14
Naphthalene
ug/L
ND
2.0
12/04/23 18:14
o-Xylene
ug/L
ND
0.50
12/04/23 18:14
sec-Butylbenzene
ug/L
ND
0.50
12/04/23 18:14
Styrene
ug/L
ND
0.50
12/04/23 18:14
tert-Butylbenzene
ug/L
ND
0.50
12/04/23 18:14
Tetra chloroethene
ug/L
ND
0.50
12/04/23 18:14
Toluene
ug/L
ND
0.50
12/04/23 18:14
trans-1,2-Dichloroethene
ug/L
ND
0.50
12/04/23 18:14
trans-1,3-Dichloropropene
ug/L
ND
0.50
12/04/23 18:14
Trichloroethene
ug/L
ND
'0.50
12/04/23 18:14
Trichlorofluoromethane
ug/L
ND
1.0
12/04/23 18:14
Vinyl chloride
ug/L
ND
1.0
12/04/23 18:14
1,2-Dichloroethane-d4 (S)
%
97
70-130
12/04/23 18:14
4-Bromofluorobenzene (S)
%
97
70-130
12/04/2318;14 - -
Toluene-d8 (S)
%
99
70-130
12/04/23 18:14
LABORATORY CONTROL SAMPLE:
4228985
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
20
18.9
94
60-140
1,1,1-Trichloroethane
ug/L
20
19.4
97
60-140
1,1,2,2-Tetrachloroethane
ug/L
20
19.7
99
60-140
1,1,2-Trichloroethane
ug/L
20
19.8
99
60-140
1,1-Dichloroethane
ug/L
20
19.3
97
60-140
1,1-Dichloroethene
ug/L
20
19.6
98
60-140
1,1-Dichloropropene
ug/L
20
21.1
105
60-140
1,2,3-Trichlorobenzene
ug/L
20
18.9
94
60-140
1,2,3-Trichloropropane
ug/L
20
18.5
92
60-140
1,2,4-Trichlorobenzene
ug/L
20
19.2
96
60-140
1,2,4-Trimethylbenzene
ug/L
20
20.2
101
60-140
1,2-Dibromo-3-chloropropane
ug/L
20
17.9
90
60-140
1,2-Dibromoethane (EDB)
ug/L
20
19.9
99
60-140
1,2-Dichlorobenzene
ug/L
20
19.9
99
60-140
1,2-Dichloroethane
ug/L
20
19.4
97
60-140
1,2-Dichloropropane
ug/L
20
19.6
98
60-140
1,3,5-Trimethylbenzene
ug/L
20
20.1
100
60-140
Results presented on this page are in the
units indicated by the "Units"
column except
where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not
be reproduced,
except in full,
Date: 12/14/2023 10:53 AM
without the written consent
of Pace Analytical Services, LLC.
Page 17 of 28
(-Faca,.
QUALITY CONTROL DATA
Project: November 23' Sampling
Pace Project No.: 92700675
LABORATORY CONTROL SAMPLE: 4228985
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,3-Dichlorobenzene
ug/L
20
19.8
99
60-140
1,3-Dichloropropane
ug/L
20
18.8
94
60-140
1,4-Dichlorobenzene
ug/L
20
19.6
98
60-140
2,2-Dichloropropane
ug/L
20
18.7
93
60-140
2-Chlorotoluene
ug/L
20
19.4
97
60-140
4-Chlorotoluene
ug/L
20
19.8
99
60-140
Benzene
ug/L
20
19.3
96
60-140
Bromobenzene
ug/L
20
19.5
97
60-140
Bromochloromethane
ug/L
20
20.3
102
60-140
Bromodichloromethane
ug/L
20
18.3
92
60-140
Bromoform
ug/L
20
17.6
88
60-140
Bromomethane
ug/L
20
18.1
90
60-140
Carbon tetrachloride
ug/L
20
18.8
94
60-140
Chlorobenzene
ug/L
20
19.1
95
60-140
Chloroethane
ug/L
20
21.4
107
60-140
Chloroform
ug/L
20
18.8
94
60-140
Chloromethane
ug/L
20
17.8
89
60-140
cis-1,2-Dichloroethene
ug/L
20
18.9
95
60-140
cis-1,3-Dichloropropene
ug/L
20
18.5
93
60-140
Dibromochloromethane
ug/L
20
18.8
94
60-140
Dibromomethane
ug/L
20
19.2
96
60-140
Dichlorodifluoromethane
ug/L
20
16.7
84
60-140
Diisopropyl ether
ug/L
20
18.2
91
60-140
Ethylbenzene
ug/L
20
19.0
95
60-140
Hexachloro-1,3-butadiene
ug/L
20
20.0
100
60-140
Isopropylbenzene (Cumene)
ug/L
20
19.3
96
60-140
m&p-Xylene
ug/L
40
38.2
95
60-140
Methyl-tert-butyl ether
ug/L
20
18.1
91
60-140
Methylene Chloride
ug/L
20
19.6
98
60-140
n-Butylbenzene
ug/L
20
21.2
106
60-140
n-Propylbenzene
ug/L
20
19.5
97
60-140
Naphthalene
ug/L
20
19.0
95
60-140
o-Xylene
ug/L
20
19.1
96
60-140
sec-Butylbenzene
ug/L
20
20.1
100
60-140
Styrene
ug/L
20
19.6
98
60-140
tent-Butylbenzene
ug/L
20
16.2
81
60-140
tetra chi oroethene
ug/L
20
18.5
92
60-140
Toluene
ug/L
20
18.9
94
60-140
trans-1,2-Dichloroethene
ug/L
20
19.8
99
60-140
trans-1,3-Dichloropropene
ug/L
20
18.4
92
60-140
Trichloroethene
ug/L
20
19.8
99
60-140
Trichlorofluoromethane
ug/L
20
19.4
97
60-140
Vinyl chloride
ug/L
20
16.6
83
60-140
1,2-Dichloroethane-d4 (S)
%
_
100
70-130
4-Bromofluorobenzene (S)
%
98
70-130,
Toluene-d8 (S)
%
100
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS -
This report shall not be reproduced, except in full,
Date: 12/14/2023 10:53 AM without the written consent of Pace Analytical Services, LLC.
Page 18 of 28
ace
QUALITY CONTROL DATA
Project: November 23' Sampling
Pace Project No.: 92700675
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
4228986
4228987
MS
MSD
92700404001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
23.2
22.6
116
113
60-140
3
1,1,1-Trichloroethane
ug/L
ND
20
20
25.0
24.2
125
121
60-140
3
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
23.9
22.8
120
114
60-140
5
1,1,2-Trichloroethane
ug/L
ND
20
20
24.1
23.0
120
115
60-140
4
1,1-Dichloroethane
ug/L
ND
20
20
24.3
23.6
122
118
60-140
3
1,1-Dichloroethene
ug/L
ND
20
20
25.8
25.2
129
126
60-140
2
1,1-Dichloropropene
ug/L
ND
20
20
26.9
26.3
134
132
60-140
2
1,2,3-Trichlorobenzene
ug/L
ND
20
20
21.0
20.2
105
101
60-140
4
1,2,3-Trichloropropane
ug/L
ND
20
20
22.6
21.3
113
107
60-140
6
1,2,4-Trichlorobenzene
ug/L
ND
20
20
20.7
20.5
104
103
60-140
1
1,2,4-Trimethylbenzene
ug/L
ND
20
20
23.2
23.0
116
115
60-140
1
1,2-Dibromo-3-chloropropane
ug/L
ND
20
20
21.2
19.6
106
98
60-140
8
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
23.9
23.2
119
116
60-140
3
1,2-Dichlorobenzene
ug/L
ND
20
20
22.8
22.0
114
110
60-140
4
1,2-Dichloroethane
ug/L
ND
20
20
24.4
23.4
122
117
60-140
4
1,2-Dichloropropane
ug/L
ND
20
20
24.5
23.6
122
118
60-140
4
1,3,5-Trimethylbenzene
ug/L
ND
20
20
23.1
22.7
115
113
60-140
2
1,3-Dichlorobenzene
ug/L
ND
- 20
120
22:3
21.9
112
109
60-140
2
1,3-Dichloropropane
ug/L
ND
20
20
22.9
22.3
115
111
60-140
3
1,4-Dichlorobenzene
ug/L
ND
20
20
22.2
21.9
111
109
60-140
2
2,2-Dichloropropane
ug/L
ND
20
20
23.8
23.2
119
116
60-140
3
2-Chlorotoluene
ug/L
ND
20
20
22.6
22.0
113
_ _110
60-140
2
4-Chlorotoluene
ug/L
ND
20
20
22.6
22.5
113
113
60-140
0
Benzene
ug/L
ND
20
20
23.9
23.2
119
116
60-140
3
Bromobenzene
ug/L
ND
20
20
22.7
21.9
114
; ; 110
60-140
4
Bromochloromethane
ug/L
ND
20
20
25.1
24.3
125
121
60-140
3
Bromodichloromethane
ug/L
ND
20
20
22.9
22.4
114
1t2
60-140
2
Bromoform
ug/L
ND
20
20
21.2
20.3
106
101
60-140
5
Bromomethane
ug/L
ND
20
20
20.8
22.5
104
113
60-140
8
Carbon tetrachloride
ug/L
ND
20
20
23.8
23.3
119
117
60-140
2
Chlorobenzene
ug/L
ND
20
20
23.4
22.6
117
113
60-140
3
Chloroetha`ne
ug/L
ND
20
20
27.0
26.3
135
132
60-140
3
Chloroform
ug/L
ND
20
20
23.4
22.8
117
114
60-140
3
Chloromethane
ug/L
ND
20
20
21.8
21.3
109
107
60-140
2
cis-1,2-Dichloroethene
ug/L
ND
20
20
23.9
23.4
119
117
60-140
2
cis-1,3-Dichloropropene
ug/L
ND
20
20
22.1
21.9
111
110
60-140
1
Dibromochloromethane
ug/L
ND
20
20
22.5
22.0
112
110
60-140
2
Dibromomethane
ug/L
ND
20
20
23.0
22.1
115
110
60-140
4
Dichlorodifluoromethane
ug/L
ND
20
20
22.4
21.9
112
109
60-140
2
Diisopropyl ether
ug/L
ND
20
20
22.9
21.9
114
110
60-140
4
Ethylbenzene
ug/L
ND
20
20
23.0
22.6
115
113
60-140
2
Hexachloro-1,3-butadiene
ug/L
ND
20
20
21.8
22.1
109
110
60-140
1
Isopropylbenzene (Cumene)
ug/L
ND
20
20
23.5
23.1
118
116
60-140
2
m&p-Xylend
ug/L
ND
40
40
46.4
45.9
116
115
60-140
1
Methyl-tert-butyl ether
ug/L
ND
20
20
22.8
21.7
114
108
60-140
5
Methylene Chloride
ug/L
ND
20
20
22.9
22.2
114
111
60-140
3
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result
Date: 12/14/2023 10:53 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 19 of 28
aye
QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Project: November 23' Sampling
Pace Project No.: 92700675
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
4228986
4228987
MS
MSD
92700404001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
n-Butylbenzene
ug/L
ND
20
20
23.3
23.5
117
118
60-140
1
n-Propylbenzene
ug/L
ND
20
20
22.5
22.2
112
111
60-140
1
Naphthalene
ug/L
ND
20
20
22.2
21.0
111
105
60-140
6
o-Xylene
ug/L
ND
20
20
22.5
22.0
112
110
60-140
2
sec-Butylbenzene
ug/L
ND
20
20
23.0
22.9
115
114
60-140
1
Styrene
ug/L
ND
20
20
23.8
22.9
119
114
60-140
4
tert- Butyl benzene
ug/L
ND
20
20
18.5
18.4
92
92
60-140
0
Tetrachloroethene
ug/L
ND
20
20
22.3
21.9
112
109
60-140
2
Toluene
ug/L
ND
20
20
23.2
22.5
116
112
60-140
3
trans-1,2-Dichloroethene
ug/L
ND
20
20
25.4
24.9
127
124
60-140
2
trans-1,3-Dichloropropene
ug/L
ND
20
20
22.6
22.0
113
110
60-140
3
Trichloroethene
ug/L
ND
20
20
24.1
23.5
121
118
60-140
2
Trichlorofluoromethane
ug/L
ND
20
20
25.9
24.8
129
124
60-140
4
Vinyl chloride
ug/L
ND
20
20
21.4
21.0
107
105
60-140
2
1,2-Dichloroethane-d4 (S)
%
102
102
70-130
4-Bromofluorobenzene (S)
%
100
101
70-130
Toluene-d8 (S)
%
99
100
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/14/2023 10:53 AM without the written consent of Pace Analytical Services, LLC. Page 20 of 28
( VIWO—
a c e
QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Project: November 23' Sampling
Pace Project No.: 92700675
QC Batch: 816201
Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015
Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92700675001, 92700675002,
92700675003
METHOD BLANK: 4224632
Matrix: Water
Associated Lab Samples: 92700675001, 92700675002,
92700675003
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Total Dissolved Solids mg/L
ND 25.0 11/29/23 19:16
LABORATORY CONTROL SAMPLE: 4224633
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Total Dissolved Solids mg/L
250 236 94 90-110
SAMPLE DUPLICATE: 4224634
92700675001 Dup
Parameter Units
Result Result RPD Qualifiers
Total Dissolved Solids mg/L
ND ND
Results presented on this page are in the
units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/14/2023 10:53 AM
without the written consent of Pace Analytical Services, LLC. Page 21 of 28
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804 ,Face"
(828)254-7176
QUALITY CONTROL DATA
Project: November 23' Sampling
Pace Project No.: 92700675
QC Batch: 816035 Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92700675001, 92700675002, 92700675003
METHOD BLANK: 4223672 Matrix: Water
Associated Lab Samples: 92700675001, 92700675002, 92700675003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfate mg/L ND 1.0 11/29/2312:39
LABORATORY CONTROL SAMPLE: 4223673
Spike
LCS
LCS
% Rec
Parameter Units
Conc.
Result
% Rec
Limits
Qualifiers
Sulfate mg/L
50
51.0
102
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4223674
4223675
MS
MSD
92700658001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits RPD Qual
Sulfate mg/L 227
50
50
257
267
61
81
90-110 4 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4223676
4223677
MS
MSD
92700675001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits RPD Qual
Sulfate mg/L ND
50
50
51.7
52.4
103
104
90-110 1
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/14/2023 10:53 AM without the written consent of Pace Analytical Services, LLC. Page 22 of 28
ace
QUALITY CONTROL DATA
Project: November 23' Sampling
Pace Project No.: 92700675
QC Batch: 818305 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92700675001, 92700675002, 92700675003
METHOD BLANK: 4235915 Matrix: Water
Associated Lab Samples: 92700675001, 92700675002, 92700675003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Ammonia mg/L ND 0.10 12/09/23 11:17
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
LABORATORY CONTROL SAMPLE: 4235916
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Ammonia mg/L 5 4.9 98 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
4235917
4235918
MS
MSD
92701169004
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits RPD Qua]
Nitrogen, Ammonia mg/L
ND
5
5
4.9
4.9
99
98
90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
4235919
4235920
MS
MSD
92701169005
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits RPD Qual
Nitrogen, Ammonia mg/L
ND
5
5
4.9
4.9
99
99
90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/14/2023 10:53 AM without the written consent of Pace -Analytical Services, LLC. Page 23 of 28
(-`1 Pace�,
QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr,
Asheville, NC 28804
(828)254-7176
Project: November 23' Sampling
Pace Project No.: 92700675
QC Batch: 817029
Analysis Method: SM 531OB-2014
QC Batch Method: SM 531 OB-2014
Analysis Description: 5310B TOC
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92700675001, 92700675002,
92700675003
METHOD BLANK: 4228713
Matrix: Water
Associated Lab Samples: 92700675001, 92700675002,
92700675003
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Total Organic Carbon mg/L
ND 1.0
12/04/23 23:08
LABORATORY CONTROL SAMPLE: 4228714
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Total Organic Carbon mg/L
25 23.9
95 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4228715 4228716
MS MSD
92701157003
Spike Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec
Limits RPD Qual
Total Organic Carbon mg/L ND
25 25 23.3
23.4 93 94
90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4228717 4228718
MS MSD
92700635001
Spike Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec
Limits RPD Qual
Total Organic Carbon mg/L 291
25 25 305
310 54 77
90-110 2 M1
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/14/2023 10:53 AM without the written consent of Pace Analytical Services, LLC. Page 24 of 28
(Vace,
QUALIFIERS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-7176
Project: November 23' Sampling
Pace Project No.: 92700675
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270 The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/14/2023 10:53 AM without the written consent of Pace Analytical Services, LLC.
Page 25 of 28
ace
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: November 23' Sampling
Pace Project No.: 92700675
Lab ID Sample ID
92700675001
Q88V2
92700675002
ASB-01
92700675003
ASB-02
92700675001
Q88V2
92700675002
ASB-01
92700675003
ASB-02
92700675001
Q88V2
92700675002
ASB-01
92700676003
ASB-02
92700675001
Q88V2
92700675002
ASB-01
92700675003
ASB-02
92700675001
Q88V2
92700675002
ASB-01
92700675003
ASB-02
92700675001
Q88V2
92700675002
ASB-01
92700675003
ASB-02
92700675001
Q88V2
92700675002
ASB-01
92700675003
ASB-02
92700675001
Q88V2
92700675QQ2
ASB-01
92700675003
ASB702
92700675001
Q88V2
92700676002
ASB-01
92700675003
ASB-02
Date: 12/14/2023 10:53 AM
Pace Analytical Services, LLC
2225 Riverside Dr,
Asheville, NC 28804
(828)254-7176
QC Batch Method QC Batch Analytical Method
EPA 3010A
816317
EPA 3010A
816317
EPA 3010A
816317
EPA 3010A
815917
EPA 3010A
815917
EPA 3010A
815917
EPA 7470A
816038
EPA 7470A
816038
EPA 7470A
816038
SM 6200B
817079
SM 6200B
817079
SM 6200B
817079
SM 2540C-2015
816201
SM 2540C-2015
816201
SM 2540C-2015
816201
EPA 300.0 Rev 2.1 1993
816035
EPA 300.0 Rev 2.1 1993
816035
EPA 300.0 Rev 2.1 1993
816035
EPA 350.1 Rev 2.0 1993
818305
EPA 350.1 Rev 2.0 1993
08305
EPA 350.1 Rev 2.0 1993
818305
SM 531OB-2014
817029
SM 531OB-2014
817029
SM 531OB-2014
817029
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
EPA 601 OD
EPA 601 OD
EPA 601 OD
EPA 6020E
EPA 6020B
EPA 6020B
EPA 7470A
EPA 7470A
EPA 7470A
Analytical
Batch
816486
816486
816486
815929
815929
815929
816130
816130
816130
Page 26 of 28
If
CHAIN -OF -CUSTODY Analytical Request Document
Face Analytical"
Chair,uf CustodyisaLfGAI.IJOCLIMLNT- Completcall relevcn(fields
LAB USE ONLY. Affix Workor, WO# , 9270d675
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Product (P), Soil/Solid (SILL oil (OL), Wipe (WP), Au (AR), Tasue ITS), Bioassay (B), Vapor IV), Other (OT)
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SHORT HOLDS PRESENT (02 hours): N N/A
Lab Sample Temperature Info:
Temp Blank 11,5e,rvgsl. Y (� NA
Therm 100: 10 / 0 q
Cooler 1 Temp Upon Receipt: 3�✓ oC
Cooler I Theron Corr. Factor 0 oc
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CHAIN -OF -CUSTODY Analytical Request Document
Face Analytical "
Chain-ofCustodv is a LEGAL DOCUMENT- Complete All releven(fields
LAB USE ONLY -Affix Worker, W® : g2700675
ALL SHADES 111II I1 11I I 1 III III III
82700675
Address: r -
/
Report To: Email To: •- Preservative Types: (1) nitric acid, (2) sulfuric acid, (3) hydrochloric add, (4) sodium hydroxide, (5) lint ocelate,
¢ a�•� / t;.. // (f) methanol, Q) smflurn bisulfate, (8) sodium thiosulfam, (9) hexane, (A) ascorbic acid, (R) ammonium sulfate,
Copy To: .Site Collection Info/Address: (C) amino nium hydroxide: (0) 75P, (U) Unpreserved, (0) Other _
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Customer Project Name/Number: State: �ougtvIcity: Time Zone Collected: i.::n Snmplo Rrcaipt Checklist:
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