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HomeMy WebLinkAboutNC0000078_Groundwater Moniotring Report November 2023_20231215GW-59A COMPLIANCE REPORT FORM Permit# (,5rib it ane each nio nitorint; period with Gff-59fiaavns,) j Enter date monitoring results were due. ( 112 KWill this monitoring report (GW-59 and GW-59A) YES NO be submitted after the established due date? 2 Was any required information missing on the GW-59 report forms`' YES NO IF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES NO identification plate, area overgrown, etc.)? If the answer is "Yes ", contact the Regional Office for guidance. f 4 Are any monitored constituents equal to or above the established standards? YF5,, NO If the answer to question 4 is "NO", skip to section 8. If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s) exceeding standards in the space provided below: 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO same constituent(s) in the same well(s) in the last two years? If the answer to question 5 is "NO", skip to section 8. If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years). Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES NO, If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly located; contact the Regional Office. 7 Is the permittee implementing previously approved actions required by the Division involving this YES NOf groundwater quality problem? If the answer to question 7 is "YES", describe those actions in the space provided below. If the answer to question 7 is "NO", contact the Regional Office within 90 days; an evaluation may be required to determine the impact the waste disposal system is having at the review and compliance boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation, fines, and/or penalties. g The person completing this portion (GW-59A) of the monitoring report should sign below and submit this form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form. I hereby acknowledge that the above information was evaluated and the information submitted in this report (Compliance Report GW-59A) is true and complete to the best of my knowledge. < 4 Signature of Permittee (or, Authorised Agent) / Date/ -�9A 12/8/2003 D D D D D p p LA Ln LA (n V) pp pp W W W W W pp pp O O O O O < < N N N -0 n i�: = -a n -a = O O = =r _ v a a o r+ 3 Ln Ln 3 m a l0 N Ln rQ N W O 0 N O O . Ul . . N Ul V 0 0 0 w O W Ln N N N N (LD Ln Ln Ln C� z C 3 a" rD n O a c m a w m 3 5 ,_+' a- z o a a 3 r. z < n =_ O o O � O O r 00 O r J n O -n 0 m m c. rt O N (D N O r c m V 0 m c m O m <O n O n (D B 0 z N 0 N 3 0 0 n 0 Y m 1 O < rn D0 �^ W CL o " Al o D m Z 3 c cn v D 3 = (n -n -n (D1 co = ' Q 0 d y(D o m -1 '� v -I -nID n O. n N 0 o O Q. O o O m z 0 W 0 ; O z N ._. m m m w 0' CD C� 3 m 0 CDCL ! Z O 2 0 O O O O W N O O O O O O O O O V O Er w O w O �{ O D) m O O (D (n (D .P (n V W O Ln Ln N O O N (D .P O O 00 O A O W W O O? d N O D) D) W r('' W ' N< z ? w 3 X O m N N �. zM d 0 0 N 3 m a o G (o (0c (O c (O (O c 2. (Q (D C) (a N . r= 0 r i= r' r= 3 3 r r r m 0 0 u, C� O 0 o 0 (o 0 n D a. 2 n 3 Q W o (n (o m (D c� 3 fl w m voi m m 3 3� 5 m v 3 3 3 3 m m 0 0 m 0 0 00 (D N 00 ro W � o 0 0 O A 0 0 A 0 0 W 0 0 N 00 D 0 o O 0 O 0 v O 0 rn m V M N V V O N N .P V 01 V m V N C, Et U- c c 3 3 c c 3 c c 3 c 3 3 3 (n m (n (o cc (c (o (a cc (n m - co co r- r � r= r- r= r= r- r' r r i- � F� < r N O O a D $ z N 0 n o M O a m J n o c�i a m m m m❑�t U) � � =r -nI = a aaCL kk *kk n (7 ❑ W Z � o m 0 0 z C: q 0 0 0 a' a m c' n o 3 0 O O N ID O10 �. (a c m O O, `G n O 3 7 a u, 0 a 0 0 0 m m o' C a 0 3 a z _z c O m(D r L O p 0 m m cn CD Z z "s N o o ,�, 3 m O N N m 0 (D D1 r= r cn < 0 3 c 0 m = r m 3 S v r 0 O a v O m v, < 3 (D o O p rn O �. (D a n -Oi m 3 = O w ::h o 6J (�D (D 00 00 CD c -°. M ti C C 3 c m -< cn m C cn m c A M. = 0 ❑. Z O v O m o 0 a m Q m n a C CD a M C v (D 0 d 3 0 c (D 0 m rn o- 0 0 m 3 U (D 0' Z m ol4 (n � co Q m o 0 -n Q 2 m 0 � o O r 0 w 0 a v o 0 o D N Q ` Z O 0 .Op C m C1 -i o z � � o o 0 1 0 CD 0 c n =T-C7 o = p *- m 0 o N m o 0 w CD 0 �; m z W N N 3 O a 2 C CD m Z ((DD O "0 0 s O c (D m o O N co (D O o ? 3 (n A (D O_ W W 0 0 m z Q � � (D cn ti a m � m < c = a (n N m 0 N a m 0 c Ow EO Dv 0 D m -•� m� i OC q r O -< g �O z --1 O X v CD n m 0 ❑ ❑ ❑ ❑ " m u m 0 x 9 O ;acn 0 m -O r- to 0 -n cn _p v n -1 Z m cn sv �! o c T v c o v' n Z m rr 6 o 00 (D ' O v O o m OVo 3 [W ❑ ❑ ❑ Z X Q o N (CD ((DD fWn O C -g m C D n (D Z (D n D-a CO v 3 v v m 3 Z 0 o cn ' s' x m v N C O C. 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(a o o (fl 0m o d rCD (Q N a o w T. j O a El N m .o Z o Z (o a n _- - Z O Oo o T= p �d ww D°o D o p Z o 0- 3m(�am r vw� (° 3 ' sv Z p m p Zo a am a a 0Z m m En o 3 0 -I am 0 � ° c= In' C: c --0 In o c' c' c' c R W `" m m w m 3 `z = = CD m 3 3 `, °1 3 3 3 3 m m z Z M Z �(D CD 2 O O 00 00 O O O O 00 o O O 0 0 0 N �' m C" p n m N 0 o 0 m w 0 0 0 0 0 0 m m m m= (U CD' (p N O O o� m cn N W O A A w N O O 0 m N O d. < _ _ V 41 J V O m N A V m V Ul J Ul 0 C" 3 `NG N -u z m CL CD 3 cn -< (n N -p N W I O I O `\CD Q V o a ❑ ' " 3 w m O o. (Q CC (p (0 (Q (D (p (Q (Q (O (O (Q (a (fl (Q I o rrrrrrrrrrrrrrrr < -0 o m cn °: °m ❑❑❑❑M v � m < r O o 55 O N° D O cn -0 m cn r- m cn p� a z -4 O Q' 'a Q N Q a 3 6 a p (�D o m ° (o O ? Z N' O m' C� m G� Q o v c m r m o o r m °' ° -0 m c m n z m CDZ < (n =(D n� o 0 o K D p T= :U m a< a ow°O w m o o 0 ,(mn, D CVi. a zmm Zv (No coo on D. m oCD 0r- N a m o Z CJ O O _ 1 c m CD O v o m r Z ?° O o t/ 3 A 3. N' O o m 3 C) w C oC) 0 � U) p CO Z ° n o a (i 3 � m O go Z x z '=c a CL 1 (' a � rn��co vZ ra an 0 C ' n z CD Z S C == v m m n p m mviwD o o3 nOn ��o Ca c ❑ o• r r m 000 z m~ Z m' o o Cl) m _( -t c v CD to (O C) 0 N =' N - w 3 N 0'3a m < m CD G) ; (n o c (D < a N D N O _o CD O Z m d CL 73 (D W CD 0 m -n X CD CD Q 0 _ cn N CD y O 0 'G W n s W C CD a O y 7 c (D 0 m O n cn (O r m c 0 0 v O 0 vi 3 r CO a o Cl) G Z o cn 0 co -n -n -n -n n O o (D° a 3 0 3 i7 ° Doj 0' o o° " m 3 y m m 0 N o O m cl Z Z O N 0' o Q Q N 3 Z D p -� R a m = c m i W �' C- o N _ N o 3 o Z z z W cn -0 a D 3 m -n m 0 W cn O n D mm �� o o= Q 0 0 Z0 0 0ZN-nN m;u Z co ,� o Z W m m (n ° o n v 3. v �' W p a � 3 3 '� D W m 3 m (D °� < D 'v �1 m O o m Z O x o m o 0 o o o (D W N -,Im O o O0 O o 0 (D c 0 m N O 0 A J 0 W 0 i a (J m o o W f?1 3 (p N a m N U A O _1 3 (D 0- C) U N O O fJ O N M N Z O (D (lt A N W O m N O N A o o O W O O O A D) W (n e o W i m Q z O � n c Z C ;aD 3 s SU c O m CD cn l cQ - °m CD Z n 0 3 a m a -no -I O< m G '3-"' cr 0 � D =r O G 3 < -I �. =3 N A Cri z O v 3 3 3= 3= 3 3c: 3 3 y �f` < a ma:) r (a r o (0 r r, (O_ r r (0 r (A r _. m (° r CD o O o (o cn r 0 m CO O m = m m r r =. Q a CO ❑ O. N O (n Z CL n Z O Z O (a ff1 m CL D O o c (� cD m 0 W (Q 3 - v W y -I Z m Z- � a CD v z m j (o = o m T o C� 3 d n c 0? 0 m 0 0 0 ° o w < m o _I OD a = n Z v � °a a W W °'. �' m v ° o ° m con c c c "O 0 c c c c W W m m(n m CD `z W m 3 CD 3 3 42 o �' 3 3 3 3 m -o z Z z �' _(D cDCD = .(T. O O 0 0 .J.. O O O O 02 O JO 0 0 o cu 3 Q m 0- 0 n cn w Q fco --i 0 m J 0 (D (f N V) J (D W J D O O o A M 0 A N 0 W A 0 N J D m o O J O U) m m O m J N m N O m • 0 0 N 0 (D Q ( < w > 0 3 O O W w N !A - = Z (D W o ° Q W En W co`< z J� 4 1 M _ = m m W cn co Q ,� W ❑ �� 3 W FP ° V t0 (Q (3 (3 (O (Q (0 (= (= (3 (3 (n (B (3 (0 I 17 za o, -< 0 m ❑ ❑ ❑ ❑ cn G r p -i q c� cn p N -o D O cn -o -n �� cn -9 r- 0 O � >, z '�' O Ci a a :(1 N 0 N a ? N 6 a OQ N O= m a)) O� (Q 00 ? Z rh, 0 m Z O_ O m C N r- CD v (� .OP (D 4 M W = 9 m -Zi: < D c.o W a `c' — �' a o O (n 'O = n W a w O o m (7 0 y cn O O -. ?I (D M m U o n. A -n N 0 0 0 o 0 N u, C, D O z " m. m. v O � S m z'._ W °° m O o• c n ° o 0 c ' m o 0 D o o D m r z m a O n o n 30 ?. v cn a O 'o o � c �m FJL m �' o O 4` '+... f o c n (D (O. c 3 m °' z zr ❑■ Q (n n (D a Z 3 D c ❑� ❑❑❑ z X z c CL 3 °o_ a n D 2 T n a o Cl, o' Z o 9 m m rn C v m y n 0 ° o m Q m m Z o C) 0' m -' 0 x z c c 0 c 0 m o q ya $ a v Q ,o � Mtn me ❑r D' r r cn -. W o o p v o � v, �' W o, ° cn 0 0 Z o v Z m 0 M o 0' � -1 OW o C (n o -p � �. ri o W � m W z , o - Q o 0 o N `D � O v W. CD m W :3D CD R m0 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 December 14, 2023 Mr. Bernie Kelly Davidson River Village, LLC P.O. Box 880 Pisgah Forest, NC 28768 RE: Project: November 23' Sampling Pace Project No.: 92700675 Dear Mr. Kelly: Enclosed are the analytical results for sample(s) received by the laboratory on November 28, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services -Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Sara Poulson sara.poulson@pacelabs.com 704-977-0964 Project Manager Enclosures `geQitA"tt?Q%, REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 28 Project: November 23' Sampling Pace Project No.: 92700675 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 CERTIFICATIONS South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 Virginia/VELAP Certification #: 460221 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 2 of 28 aee SAMPLE ANALYTE COUNT Project: November 23' Sampling Pace Project No.: 92700675 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92700675001 Q88V2 EPA 601OD DBB1 6 PASI-A EPA 6020E KRL 1 PASI-A EPA 7470A BM 1 PASI-A SM 6200B SAS 63 PASI-C SM 2540C-2015 RVS 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 350.1 Rev 2.0 1993 EGC 1 PASI-A SM 531OB-2014 MJP 1 PASI-A 92700675002 ASB-01 EPA 601OD DBB1 6 PASI-A EPA6020B KRL 1 PASI-A EPA 7470A BM 1 PASI-A SM 6200B SAS 63 PASI-C SM 2540C-2015 RVS 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 350.1 Rev 2.0 1993 EGC 1 PASI-A SM 531OB-2014 MJP 1 PASI-A 92700675003 ASB-02 EPA 601 OD D1361 6 PASI-A EPA 60206 - _ .. KRL _ 1 PASI-A EPA 7470A BM 1 PASI-A SM 6200E SAS 63 PASI-C SM 2540C-2015 RVS 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 350.1 Rev 2.0 1993 EGC 1 PASI-A SM 531OB-2014 MJP 1 PASI-A PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 28 Pace Analytical Services, LLC 2225 Riverside Dr, Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: November 23' Sampling Pace Project No.: 92700675 Sample: Q88V2 Lab ID: 92700676001 Collected: 11/28/23 11:35 Received: 11/28/23 17:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 12/14/23 09:37 Collected By MPS 1 12/14/23 09:37 Collected Date 11/28/23 1 12/14/23 09:37 Collected Time 11:35 1 12/14/23 09:37 pH 4.97 Std. Units 1 12/14/23 09:37 Temperature 12.3 deg C 1 12/14/23 09:37 Static Water Level 65.46 feet 1 12/14/23 09:37 Specific Conductance 19.4 umhos/cm 1 12/14/23 09:37 Oxygen, Dissolved 5.18 mg/L 1 12/14/23 09:37 7782-44-7 Total Well Depth 68.5 feet 1 12/14/23 09:37 REDOX 182.3 my 1 12/14/23 09:37 Turbidity 3.19 NTU 1 12/14/23 09:37 Iron, Ferrous NA mg/L 1 12/14/23 09:37 Odor None 1 12/14/23 09:37 Appearance Clear 1 12/14/23 09:37 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic ND ug/L 10.0 1 11/30/23 12:45 12/05/23 21:33 7440-38-2 Chromium 39.2 ug/L 5.0 1 11/30/23 12:45 12/05/23 21:33 7440-47-3 Iron 273 ug/L 50.0 1 11/30/23 12:45 12/06/2316:05 7439-89-6 Lead ND ug/L 5.0 1 11/30/23 12:45 12/05/23 21:33 7439-92-1 Manganese 13.7 ug/L 5.0 1 11/30/23 12:45 12/05/23 21:33 7439-96-5 Sodium ND ug/L 5000 1 11/30/23 12:45 12/05/23 21:33 7440-23-5 6020 MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3010A Pace Analytical Services -Asheville Cobalt ND ug/L 1.0 1 11/29/23 01:49 11/30/23 14:49 7440-48-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury ND ug/L 0.20 1 11/29/23 11:35 11/30/23 09:39 7439-97-6 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND ug/L 0.50 1 12/04/23 20:21 71-43-2 Bromobenzene ND ug/L 0.50 1 12/04/23 20:21 108-86-1 Bromochloromethane ND ug/L 0.50 1 12/04/23 20:21 74-97-5 Bromodichloromethane ND ug/L 0.50 1 12/04/23 20:21 75-27-4 Bromoform ND ug/L 0.50 1 12/04/23 20:21 75-25-2 Bromomethane ND ug/L 5.0 1 12/04/23 20:21 74-83-9 n-Butylbenzene ND ug/L 0.50 1 12/04/23 20:21 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 12/04/23 20:21 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 12/04/23 20:21 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 12/04/23 20:21 56-23-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/14/2023 10:53 AM without the written consent of Pace Analytical Services, LLC. Page 4 of 28 lace", ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: November 23' Sampling Pace Project No.: 92700675 Sample: Q88V2 Lab ID: 92700675001 Collected: 11/28/23 11:35 Received: 11/28/23 17:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua] 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Chlorobenzene ND ug/L 0.50 1 Chloroethane ND ug/L 1.0 1 Chloroform ND ug/L 0,50 1 Chloromethane ND ug/L 1.0 1 2-Chlorotoluene ND ug/L 0.50 1 4-Chlorotoluene ND ug/L 0.50 1 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 Dibromochloromethane ND ug/L 0.50 1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 Dibromomethane ND ug/L 0.50 1 1,2-Dichlorobenzene ND ug/L 0.50 1 1,3-Dichlorobenzene ND ug/L 0.50 1 1,4-Dichlorobenzene ND ug/L 0.50 1 Dichlorodifluoromethane ND ug/L 0.50 1 1,1-Dichloroethane ND ug/L 0.50 1 1,2-Dichloroethane ND ug/L 0.50 1 1,1-Dichloroethene ND ug/L 0.50' 1 cis- 1,2-Dichloroethene ND ug/L 0.50 1 trans-1,2-Dichloroethene ND ug/L 0.50 1 1,2-Dichloropropane ND ug/L 0.50 1 1,3-Dichloropropane ND ug/L 0.50 1 2,2-Dichloropropane ND ug/L 0.50 1 1,1-Dichloropropene ND ug/L 0.50 1 cis-1,3-Dichloropropene ND ug/L 0.50 1 trans-1,3-Dichloropropene ND ug/L 0.50 1 Diisopropyl ether ND ug/L 0.50 1 Ethylbenzene ND ug/L 0.50 1 Hexachloro-1,3-butadiene ND ug/L 2.0 1 Isopropylbenzene (Cumene) ND ug/L 0.50 1 Methylene Chloride ND ug/L 2.0 1 Methyl -tent -butyl ether ND ug/L 0.50 1 Naphthalene ND ug/L 2.0 1 n-Propylbenzene ND ug/L 0.50 1 Styrene ND ug/L 0.50 1 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 Tetrachloroethene ND ug/L 0.50 1 Toluene ND ug/L 0.50 1 1,2,3-Trichlorobenzene ND ug/L 2.0 1 1,2,4-Trichlorobenzene ND ug/L 2.0 1 1,1,1-Trichloroethane ND ug/L 0.50 1 1,1,2-Trichloroethane ND ug/L 0.50 1 Trichloroethene ND ug/L 0.50 1 Trichlorofluoromethane ND ug/L 1.0 1 1,2,3-Trichloropropane ND ug/L 0.50 1 1,2,4-Trimethylbenzene ND ug/L 0.50 1 Date: 12/14/2023 10:53 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/04/23 20:21 108-90-7 12/04/23 20:21 75-00-3 12/04/23 20:21 67-66-3 12/04/23 20:21 74-87-3 12/04/23 20:21 95-49-8 12/04/23 20:21 106-43-4 12/04/23 20:21 96-12-8 12/04/23 20:21 124-48-1 12/04/23 20:21 106-93-4 12/04/23 20:21 74-95-3 12/04/23 20:21 95-50-1 12/04/23 20:21 541-73-1 12/04/23 20:21 106-46-7 12/04/23 20:21 75-71-8 12/04/23 20:21 75-34-3 12/04/23 20:21 107-06-2 12/04/23 20:21 75-35-4 12/04/23 20:21 156-59-2 12/04/23 20:21 156-60-5 12/04/23 20:21 78-87-5 12/04/23 20:21 142-28-9 12/04/23 20:21 594-20-7 12/04/23 20:21 563-58-6 12/04/23 20:21 10061-01-5 12/04/23 20:21 10061-02-6 12/04/23 20:21 108-20-3 12/04/23 20:21 100-41-4 12/04/23 20:21 87-68-3 12/04/23 20:21 98-82-8 12/04/23 20:21 75-09-2 12/04/23 20:21 1634-04-4 12/04/23 20:21 91-20-3 12/04/23 20:21 103-65-1 12/04/23 20:21 100-42-5 12/04/23 20:21 630-20-6 12/04/23 20:21 79-34-5 12/04/23 20:21 127-18-4 12/04/23 20:21 108-88-3 12/04/23 20:21 87-61-6 12/04/23 20:21 120-82-1 12/04/23 20:21 71-55-6 12/04/23 20:21 79-00-5 12/104/23 20:21 79-01-6 12/04/23 20:21 75-69-4 12/04/23 20:21 96-18-4 12/04/23 20:21 95-63-6 Page 5 of 28 2 le ace�' I ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr, Asheville, NC 28804 (828)254-7176 Project: November 23' Sampling Pace Project No.: 92700675 Sample: Q88V2 Lab lD: 92700675001 Collected: 11/28/23 11:35 Received: 11/28/23 17:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200E MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte 1,3,5-Trimethylbenzene ND ug/L 0.50 1 12/04/23 20:21 108-67-8 Vinyl chloride ND ug/L 1.0 1 12/04/23 20:21 75-01-4 m&p-Xylene ND ug/L 1.0 1 12/04/23 20:21 179601-23-1 o-Xylene ND ug/L 0.50 1 12/04/23 20:21 95-47-6 Surrogates 1,2-Dichloroethane-d4(S) 98 % 70-130 1 12/04/23 20:21 17060-07-0 4-Bromofluorobenzene (S) 95 % 70-130 1 12/04/23 20:21 460-00-4 Toluene-d8 (S) 98 % 70-130 1 12/04/23 20:21 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services - Asheville Total Dissolved Solids ND mg/L 25.0 1 11/29/23 19:20 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services - Asheville Sulfate ND mg/L 1.0 1 11/29/2316:36 14808-79-8 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 1 12/09/23 11:56 7664-41-7 5310B TOC Analytical Method: SM 531 OB-2014 Pace Analytical Services -Asheville Total Organic Carbon ND mg/L 1.0 1 12/05/23 04:30 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/14/2023 10:53 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 28 aee ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: November 23' Sampling Pace Project No.: 92700675 Sample: ASB-01 Lab ID: 92700675002 Collected: 11/28/23 14:05 Received: 11/28/23 17:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 12/14/23 09:39 Collected By MPS 1 12/14/23 09:39 Collected Date 11/28/23 1 12/14/23 09:39 Collected Time 14:05 1 12/14/23 09:39 pH 5.92 Std. Units 1 12/14/23 09:39 Temperature 11.4 deg C 1 12/14/23 09:39 Static Water Level 9.09 feet 1 12/14/23 09:39 Specific Conductance 400.8 umhos/cm 1 12/14/23 09:39 Oxygen, Dissolved 0.28 mg/L 1 12/14/23 09:39 7782-44-7 Total Well Depth 15.00 feet 1 12/14/23 09:39 REDOX 182.7 my 1 12/14/23 09:39 Turbidity 7.47 NTU 1 12/14/23 09:39 Odor None 1 12/14/23 09:39 Appearance Clear 1 12/14/23 09:39 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic ND ug/L 10.0 1 11/30/23 12:45 12/05/23 21:36 7440-38-2 Chromium ND ug/L 5.0 1 11/30/23 12:45 12/05/23 21:36 7440-47-3 Iron 1860 ug/L 50.0 1 11/30/23 12:45 12/06/2316:08 7439-89-6 Lead ND ug/L 5.0 1 11/30/23 12:45 12/05/23 21:36 7439-92-1 Manganese 1950 ug/L 5.0 1 11/30/23 12:45 12/05/23 21:36 7439-96-5 Sodium 30900 ug/L 5000 1 11/30/23 12:45 12/05/23 21:36 7440-23-5 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services - Asheville Cobalt 4.1 ug/L 1.0 1 11/29/23 01:49 11/30/23 15:13 7440-48-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury ND ug/L 0.20 1 11/29/23 11:35 11/30/23 09:42 7439-97-6 6200E MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene _ -ND ug/L 0.50 1 12/04/23 20:40 71-43-2 Bromobenzene ND ug/L 0.50 1 12/04/23 20:40 108-86-1 Bromochloromethane ND ug/L 0.50 1 12/04/23 20:40 74-97-5 Bromodichloromethane ND ug/L 0.50 1 12/04/23 20:40 75-27-4 Bromoform ND ug/L 0.50 1 12/04/23 20:40 75-25-2 Bromomethane ND ug/L 5.0 1 12/04/23 20:40 74-83-9 n-Butylbenzene ND ug/L 0.50 1 12/04/23 20:40 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 12/04/23 20:40 135-98-8 tert-Butylbenzene ND ug/L' 0.50 1 12/04/23 20:40 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 12/04/23 20:40 56-23-5 Chlorobenzene ND ug/L 0.50 1 12/04/23 20:40 108-90-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/14/2023 10:53 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 28 ANALYTICAL RESULTS Project: November 23' Sampling Pace Project No.: 92700675 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: ASB-01 Lab ID: 92700675002 Collected: 11/28/23 14:05 Received: 11/28/23 17:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene Isopropylbenzene (Cumene) Methylene Chloride Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Date: 12/14/2023 10:53 AM Analytical Method: SM 6200B Pace Analytical Services - Charlotte ND ug/L 1.0 1 ND ug/L 0.50 1 ND ug/L 1.0 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 1.0 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50. 1._. ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L . 0.50 1 ND ug/L 0.50 1 ND ug/L 2.0 1 ND ug/L 0.50 1 ND ug/L 2.0 1 ND ug/L 0.50 1 ND ug/L 2.0 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 2.0 1 ND ug/L 2.0 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 1.0 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 0.50 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/04/23 20:40 75-00-3 12/04/23 20:40 67-66-3 12/04/23 20:40 74-87-3 12/04/23 20:40 95-49-8 12/04/23 20:40 106-43-4 12/04/23 20:40 96-12-8 12/04/23 20:40 124-48-1 12/04/23 20:40 106-93-4 12/04/23 20:40 74-95-3 12/04/23 20:40 95-50-1 12/04/23 20:40 541-73-1 12/04/23 20:40 106-46-7 12/04/23 20:40 75-71-8 12/04/23 20:40 75-34-3 12/04/23 20:40 107-06-2 12/04/23 20:40 75-35-4 12/04/23 20:40 156-59-2 12/04/23 20:40 156-60-5 12/04/23 20:40 78-87-5 12/04/23 20:40 142-28-9 12/04/23 20`40 594-20-7 12/04/23 20:40 563-58-6 12/04/23 20:40 10061-01-5 12/04/23 20:40 10061-02-6 12/04/23 20:40 108-20-3 12/04/23 20:40 100-41-4 12/04/23 20:40 87-68-3 12/04/23 20:40 98-82-8 12/04/23 20:40 75-09-2 12/04/23 20:40 1634-04-4 12/04/23 20:40 91-20-3 12/04/23 20:40 103-65-1 12/04/23 20:40 100-42-5 12/104/23 20:40 630-20-6 12/04/23 20:40 79-34-5 12/04/23 20:40 127-18-4 12/04/23 20:40 108-88-3 12/04/23 20:40 87-61-6 12/04/23 20:40 120-82-1 12/04/23 20:40 71-55-6 12/04/23 20:40 79-00-5 12/104/23 20:40 79-01-6 12/04/23 20:40 75-69-4 12/04/23 20:40 96-18-4 12/04/23 20:40 95-63-6 12/104/23 20:40 108-67-8 Page 8 of 28 ANALYTICAL RESULTS Project: November 23' Sampling Pace Project No.: 92700675 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: ASB-01 Lab ID: 92700675002 Collected: 11/28/23 14:05 Received: 11/28/23 17:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua] 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Vinyl chloride ND ug/L 1.0 1 12/04/23 20:40 75-01-4 m&p-Xylene ND ug/L 1.0 1 12/04/23 20:40 179601-23-1 o-Xylene ND ug/L 0.50 1 12/04/23 20:40 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 97 % 70-130 1 12/04/23 20:40 17060-07-0 4-Bromof]uorobenzene (S) 95 % 70-130 1 12/04/23 20:40 460-00-4 Toluene-d8 (S) 98 % 70-130 1 12/04/23 20:40 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids 268 mg/L 25.0 1 11/29/23 19:20 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services - Asheville Sulfate 8.4 mg/L 1.0 1 11/29/2317:20 14808-79-8 350.1 Ammonia Analytical Method: EPA350.1 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Ammonia ND mg/L 0.10 1 12/09/23 11:57 7664-41-7 5310B TOC Analytical Method: SM 531 OB-2014 Pace Analytical Services - Asheville Total Organic Carbon ND mg/L 1.0 1 12/05/23 04:48 7440-44-0 Date: 12/14/2023 10:53 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 28 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: November 23' Sampling Pace Project No.: 92700675 Sample: ASB-02 Lab ID: 92700675003 Collected: 11/28/23 13:10 Received: 11/28/23 17:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No, Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 12/14/23 09:41 Collected By MPS 1 12/14/23 09:41 Collected Date 11/28/23 1 12/14/23 09:41 Collected Time 13:10 1 12/14/23 09:41 pH 5.73 Std. Units 1 12/14/23 09:41 Temperature 14.3 deg C 1 12/14/23 09:41 Static Water Level 9.39 feet 1 12/14/23 09:41 Specific Conductance 160.6 umhos/cm 1 12/14/23 09:41 Oxygen, Dissolved 3.41 mg/L 1 12/14/23 09:41 7782-44-7 Total Well Depth 12.00 feet 1 12/14/23 09:41 REDOX 179.8 mV 1 12/14/23 09:41 Turbidity 1.21 NTU 1 12/14/23 09:41 Odor None 1 12/14/23 09:41 Appearance Clear 1 12/14/23 09:41 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services - Asheville - Arsenic ND ug/L 10.0 1 11/30/23 12:45 12/05/23 21:39 7440-38-2 Chromium ND ug/L 5.0 1 11/30/23 12:45 12/05/23 21:39 7440-47-3 Iron 186 ug/L 50.0 1 11/30/23 12:45 12/06/2316:11 7439-89-6 Lead ND ug/L 5.0 1 11/30/23 12:45 12/05/23 21:39 7439-92-1 Manganese 86.4 ug/L 5.0 1 11/30/23 12:45 12/05/23 21:39 7439-96-5 Sodium 17500 ug/L 5000 1 11/30/23 12:45 12/05/23 21:39 7440-23-5 6020 MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3010A Pace Analytical Services - Asheville Cobalt ND ug/L 1.0 1 11/29/23 01:49 11/30/23 15:18 7440-48-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services - Asheville Mercury ND ug/L 0.20 1 11/29/23 11:35 11/30/23 09:44 7439-97-6 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND ug/L 0.50 1 12/04/23 20:58 71-43-2 Bromobenzene ND ug/L 0.50 1 12/04/23 20:58 108-86-1 Bromochloromethane ND ug/L 0.50 1 12/04/23 20:58 74-97-5 Bromodichloromethane ND ug/L 0.50 1 12/04/23 20:58 75-27-4 Bromoform ND ug/L 0.50 1 12/04/23 20:58 75-25-2 Bromomethane ND ug/L 5.0 1 12/04/23 20:58 74-83-9 n-Butylbenzene ND ug/L 0.50 1 12/04/23 20:58 104-51-8 sec -Butyl benzene ND ug/L 0.50 1 12/04/23 20:58 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 12/04/23 20:58 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 12/04/23 20:58 56-23-5 Chlorobenzene ND ug/L 0.50 1 12/04/23 20:58 108-90-7 'REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/14/2023 10:53 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 28 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 -Va c e f (828)254-7176 i ANALYTICAL RESULTS Project: November 23' Sampling Pace Project No.: 92700675 Sample: ASB-02 Lab ID: 92700675003 Collected: 11/28/23 13:10 Received: 11/28/23 17:00 Matrix: Water Parameters Results Units Report Limit DF Prepared 6200B MSV Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene Isopropylbenzene (Cumene) Methylene Chloride Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Date: 12/14/2023 10:53 AM Analytical Method: SM 6200B Pace Analytical Services - Charlotte ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug%L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug%L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug7L 1.0 1 0.50 1 1.0 1 0.50 1 0.50 1 1.0 1 0.50 1 0.50 1 0.50 1 0.50 1 0.50 1 0.50 1 0.50 1 0.50 1 0.50 1 0.50 1 0.50 1 0.50 1 0.50 1 0.50 1 0.50 1 0.50 1 0.50 1 0.50 1 0.50 1 0.50 1 2.0 1 0.50 1 2.0 1 0.50 1 2.0 1 0.50 1 0.50 1 0.50 1 0.50 1 0.50 1 0.50 1 2.0 1 2.0 1 0.50 1 0.50 1 0.50 1 1.0 1 0.50 1 0.50 1 0.50 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC Analyzed CAS No. Qual 12/04/23 20:58 75-00-3 12/04/23 20:58 67-66-3 12/04/23 20:58 74-87-3 12/04/23 20:58 95-49-8 12/04/23 20:58 106-43-4 12/04/23 20:58 96-12-8 12/04/23 20:58 124-48-1 12/04/23 20:58 106-93-4 12/04/23 20:58 74-95-3 12/04/23 20:58 95-50-1 12/04/23 20:58 541-73-1 12/04/23 20:58 106-46-7 12/04/23 20:58 75-71-8 12/04/23 20:58 75-34-3 12/04/23 20:58 107-06-2 12/04/23 20:58 75-35-4 12/04/23 20:58 156-59-2 12/04/23 20:58 156-60-5 12/04/23 20:58 78-87-5 12/04/23 20:58 142-28-9 "12/04/23 20.'58 594-20-7 12/04/23 20:58 563-58-6 12/04/23 20:58 10061-01-5 12/04/23 20:58 10061-02-6 12/04/23 20:58 108-20-3 12/04/23 20:58 100-41-4 12/04/23 20:58 87-68-3 12/04/23 20:58 98-82-8 12/04/23 20:58 75-09-2 12/04/23 20:58 1634-04-4 12/04/23 20:58 91-20-3 12/104/23 20:58 103-65-1 12/04/23 20:58 100-42-5 12/04/23 20:58 630-20-6 12/04/23 20:58 79-34-5 12/04/23 20:58 127-18-4 12/04/23 20:58 108-88-3 12/04/23 20:58 87-61-6 12/04/23 20:58 120-82-1 12/104/23 20:58 71-55-6 12/04/23 20:58 79-00-5 12/o4/23 20:58 79-01-6 12/04/23 20:58 75-69-4 12/04/23 20:58 96-18-4 12/04/23 20:58 95-63-6 12/04/23 20:58 108-67-8 Page 11 of 28 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: November 23' Sampling Pace Project No.: 92700675 Sample: ASB-02 Lab ID: 92700675003 Collected: 11/28/23 13:10 Received: 11/28/23 17:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200E MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Vinyl chloride ND ug/L 1.0 1 12/04/23 20:58 75-01-4 m&p-Xylene ND ug/L 1.0 1 12/04/23 20:58 179601-23-1 o-Xylene ND ug/L 0.50 1 12/04/23 20:58 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 97 % 70-130 1 12/04/23 20:58 17060-07-0 4-Bromofluorobenzene (S) 96 % 70-130 1 12/04/23 20:58 460-00-4 Toluene-d8 (S) 99 % 70-130 1 12/04/23 20:58 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services - Asheville Total Dissolved Solids 95.0 mg/L 25.0 1 11/29/23 19:20 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Sulfate 2.6 mg/L 1.0 1 11/29/2317:35 14808-79-8 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Ammonia ND mg/L 0.10 1 12/09/23 11:59 7664-41-7 5310BTOC Analytical Method: SM 5310E-2014 Pace Analytical Services - Asheville Total Organic Carbon ND mg/L 1.0 1 12/05/23 05:07 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/14/2023 10:53 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 28 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: November,23' Sampling Pace Project No.: 92700675 QC Batch: 816038 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92700675001, 92700675002, 92700675003 METHOD BLANK: 4223715 Matrix: Water Associated Lab Samples: 92700675001, 92700675002, 92700675003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 11/30/23 09:02 LABORATORY CONTROL SAMPLE: 4223716 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.6 103 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4223717 4223718 MS MSD 92700370002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua] Mercury ug/L ND 2.5 2.5 2.5 2.5 99 100 75-125 2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/14/2023 10:53 AM without the written consent of Pace Analytical Services, LLC, Page 13 of 28 (. �9(3ce�, QUALITY CONTROL DATA Project: November 23' Sampling Pace Project No.: 92700675 QC Batch: 816317 Analysis Method: EPA 601 OD QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92700675001, 92700675002, 92700675003 METHOD BLANK: 4225280 Matrix: Water Associated Lab Samples: 92700675001, 92700675002, 92700675003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Arsenic ug/L ND 10.0 12/05/23 20:28 Chromium ug/L ND 5.0 12/05/23 20:28 Iron ug/L ND 50.0 12/05/23 20:28 Lead ug/L ND 5.0 12/05/23 20:28 Manganese ug/L ND 5.0 12/05/23 20:28 Sodium ug/L ND 5000 12/05/23 20:28 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 LABORATORY CONTROL SAMPLE: 4225281 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic ug/L - 500 486 97 80-120 Chromium ug/L 500 504 101 80-120 Iron ug/L 5000 5150 103 80-120 Lead ug/L 500 492 98 80-120 Manganese ug/L 500 510 102 80-120 Sodium ug/L 5000 5140 103 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4225282 4225283 MS MSD 92700682042 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Arsenic ug/L ND 500 500 487 476 97 95 75-125 2 Chromium ug/L 126 .500 500 612 640 97 103 75-125 5 Iron ug/L 56100 5000 5000 65100 79300 179 462 75-125 20 M1 Lead ug/L 10.0 500 500 506 498 99 98 75-125 2 Manganese ug/L 1070 500 500 1640 1740 115 135 75-125 6 M1 Sodium ug/L 6150 5000 5000 11800 11600 112 110 75-125 1 Results presented on this page are in the units indicated by the "Units" columnexcept where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/14/2023 10:53 AM without the written consent of Pace Analytical Services, LLC. Page 14 of 28 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: November 23' Sampling Pace Project No.: 92700675 QC Batch: 815917 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92700675001, 92700675002, 92700675003 METHOD BLANK: 4223268 Matrix: Water Associated Lab Samples: 92700675001, 92700675002, 92700675003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Cobalt ug/L ND 1.0 11/30/2314:39 LABORATORY CONTROL SAMPLE: 4223269 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Cobalt ug/L 50 51.8 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4223270 4223271 MS MSD 92700675001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Cobalt ug/L ND 50 50 51.3 50.1 102 100 75-125 2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/14/2023 10:53 AM without the written consent of Pace Analytical Services, LLC. Page 15 of 28 Pace Analytical Services, LLC 2225 Riverside Dr, Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: November 23' Sampling Pace Project No.: 92700675 QC Batch: 817079 Analysis Method: SM 6200B QC Batch Method: SM 6200B Analysis Description: 6200B MSV Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92700675001, 92700675002, 92700675003 METHOD BLANK: 4228984 Matrix: Water Associated Lab Samples: 92700675001, 92700675002, 92700675003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 0.50 12/04/23 18:14 1,1,1-Trichloroethane ug/L ND 0.50 12/04/23 18:14 1,1,2,2-Tetrachloroethane ug/L ND 0.50 12/04/23 18:14 1,1,2-Trichloroethane ug/L ND 0.50 12/04/23 18:14 1,1-Dichloroethane ug/L ND 0.50 12/04/23 18:14 1,1-Dichloroethene ug/L ND 0.50 12/04/23 18:14 1,1-Dichloropropene ug/L ND 0.50 12/04/23 18:14 1,2,3-Trichlorobenzene ug/L ND 2.0 12/04/23 18:14 1,2,3-Trichloropropane ug/L ND 0.50 12/04/23 18:14 1,2,4-Trichlorobenzene ug/L ND 2.0 12/04/23 18:14 1,2,4-Trimethylbenzene ug/L ND 0.50 12/04/23 18:14 1,2-Dibromo-3-chloropropane ug/L ND 1.0 12/04/23 18:14 1,2-Dibromoethane (EDB) ug/L ND 0.50 12/04/23 18:14 1,2-Dichlorobenzene ug/L ND 0.50 12/04/23 18:14 1,2-Dichloroethane ug/L ND 0.50 12/04/23 18:14 1,2-Dichloropropane ug/L ND 0.50 12/04/23 18:14 1,3,5-Trimethylbenzene ug/L ND 0.50 12/04/23 18:14 1,3-Dichlorobenzene ug/L ND 0.50 12/04/23 18:14 1,3-Dichloropropane ug/L ND 0.50 12/04/23 18:14 1,4-Dichlorobenzene ug/L ND 0.50 12/04/23 18:14 2,2-Dichloropropane ug/L ND 0.50 12/04/23 18:14 2-Chlorotoluene ug/L ND 0.50 12/04/23 18:14 4-Chlorotoluene ug/L ND 0.50 12/04/23 18:14 Benzene ug/L ND 0.50 12/04/23 18:14 Bromobenzene ug/L ND 0.50 12/04/23 18:14 Bromochloromethane ug/L ND 0.50 12/04/23 18:14 Bromodichloromethane ug/L ND 0.50 12/04/23 18:14 Bromoform ug/L ND 0.50 12/04/23 18:14 Bromomethane ug/L ND 5.0 12/04/23 18:14 Carbon tetrachloride ug/L ND 0.50 12/04/23 18:14 Chlorobenzene ug/L ND 0.50 12/04/23 18:14 Chloroethane ug/L ND 1.0 12/04/23 18:14 Chloroform ug/L ND 0.50 12/04/23 18:14 Chloromethane ug/L ND 1.0 12/04/23 18:14 cis-1,2-Dichloroethene ug/L ND 0.50 12/04/23 18:14 cis-1,3-Dichloropropene ug/L ND 0.50 12/04/23 18:14 Dibromochloromethane ug/L ND 0.50 12/04/23 18:14 Dibromomethane ug/L ND 0.50 12/04/23 18:14 Dichlorodifluoromethane ug/L ND 0.50 12/104/2318:14 Diisopropyl ether ug/L ND 0.50 12/104/23 18:14 Results presorted on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced•, except in full. Date: 12/14/2023 10:53 AM without the written consent of Pace Analytical Services, LLC. Page 16 of 28 QUALITY CONTROL DATA Project: November 23' Sampling Pace Project No.: 92700675 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 METHOD BLANK: 4228984 Matrix: Water Associated Lab Samples: 92700675001, 92700675002, 92700675003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Ethylbenzene ug/L ND 0.50 12/04/23 18:14 Hexachloro-1,3-butadiene ug/L ND 2.0 12/04/23 18:14 Isopropylbenzene (Cumene) ug/L ND 0.50 12/04/23 18:14 m&p-Xylene ug/L ND 1.0 12/04/23 18:14 Methyl-tert-butyl ether ug/L ND 0.50 12/04/23 18:14 Methylene Chloride ug/L ND 2.0 12/04/23 18:14 n-Butylbenzene ug/L ND 0.50 12/04/23 18:14 n-Propylbenzene ug/L ND 0.50 12/04/23 18:14 Naphthalene ug/L ND 2.0 12/04/23 18:14 o-Xylene ug/L ND 0.50 12/04/23 18:14 sec-Butylbenzene ug/L ND 0.50 12/04/23 18:14 Styrene ug/L ND 0.50 12/04/23 18:14 tert-Butylbenzene ug/L ND 0.50 12/04/23 18:14 Tetra chloroethene ug/L ND 0.50 12/04/23 18:14 Toluene ug/L ND 0.50 12/04/23 18:14 trans-1,2-Dichloroethene ug/L ND 0.50 12/04/23 18:14 trans-1,3-Dichloropropene ug/L ND 0.50 12/04/23 18:14 Trichloroethene ug/L ND '0.50 12/04/23 18:14 Trichlorofluoromethane ug/L ND 1.0 12/04/23 18:14 Vinyl chloride ug/L ND 1.0 12/04/23 18:14 1,2-Dichloroethane-d4 (S) % 97 70-130 12/04/23 18:14 4-Bromofluorobenzene (S) % 97 70-130 12/04/2318;14 - - Toluene-d8 (S) % 99 70-130 12/04/23 18:14 LABORATORY CONTROL SAMPLE: 4228985 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 20 18.9 94 60-140 1,1,1-Trichloroethane ug/L 20 19.4 97 60-140 1,1,2,2-Tetrachloroethane ug/L 20 19.7 99 60-140 1,1,2-Trichloroethane ug/L 20 19.8 99 60-140 1,1-Dichloroethane ug/L 20 19.3 97 60-140 1,1-Dichloroethene ug/L 20 19.6 98 60-140 1,1-Dichloropropene ug/L 20 21.1 105 60-140 1,2,3-Trichlorobenzene ug/L 20 18.9 94 60-140 1,2,3-Trichloropropane ug/L 20 18.5 92 60-140 1,2,4-Trichlorobenzene ug/L 20 19.2 96 60-140 1,2,4-Trimethylbenzene ug/L 20 20.2 101 60-140 1,2-Dibromo-3-chloropropane ug/L 20 17.9 90 60-140 1,2-Dibromoethane (EDB) ug/L 20 19.9 99 60-140 1,2-Dichlorobenzene ug/L 20 19.9 99 60-140 1,2-Dichloroethane ug/L 20 19.4 97 60-140 1,2-Dichloropropane ug/L 20 19.6 98 60-140 1,3,5-Trimethylbenzene ug/L 20 20.1 100 60-140 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/14/2023 10:53 AM without the written consent of Pace Analytical Services, LLC. Page 17 of 28 (-Faca,. QUALITY CONTROL DATA Project: November 23' Sampling Pace Project No.: 92700675 LABORATORY CONTROL SAMPLE: 4228985 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,3-Dichlorobenzene ug/L 20 19.8 99 60-140 1,3-Dichloropropane ug/L 20 18.8 94 60-140 1,4-Dichlorobenzene ug/L 20 19.6 98 60-140 2,2-Dichloropropane ug/L 20 18.7 93 60-140 2-Chlorotoluene ug/L 20 19.4 97 60-140 4-Chlorotoluene ug/L 20 19.8 99 60-140 Benzene ug/L 20 19.3 96 60-140 Bromobenzene ug/L 20 19.5 97 60-140 Bromochloromethane ug/L 20 20.3 102 60-140 Bromodichloromethane ug/L 20 18.3 92 60-140 Bromoform ug/L 20 17.6 88 60-140 Bromomethane ug/L 20 18.1 90 60-140 Carbon tetrachloride ug/L 20 18.8 94 60-140 Chlorobenzene ug/L 20 19.1 95 60-140 Chloroethane ug/L 20 21.4 107 60-140 Chloroform ug/L 20 18.8 94 60-140 Chloromethane ug/L 20 17.8 89 60-140 cis-1,2-Dichloroethene ug/L 20 18.9 95 60-140 cis-1,3-Dichloropropene ug/L 20 18.5 93 60-140 Dibromochloromethane ug/L 20 18.8 94 60-140 Dibromomethane ug/L 20 19.2 96 60-140 Dichlorodifluoromethane ug/L 20 16.7 84 60-140 Diisopropyl ether ug/L 20 18.2 91 60-140 Ethylbenzene ug/L 20 19.0 95 60-140 Hexachloro-1,3-butadiene ug/L 20 20.0 100 60-140 Isopropylbenzene (Cumene) ug/L 20 19.3 96 60-140 m&p-Xylene ug/L 40 38.2 95 60-140 Methyl-tert-butyl ether ug/L 20 18.1 91 60-140 Methylene Chloride ug/L 20 19.6 98 60-140 n-Butylbenzene ug/L 20 21.2 106 60-140 n-Propylbenzene ug/L 20 19.5 97 60-140 Naphthalene ug/L 20 19.0 95 60-140 o-Xylene ug/L 20 19.1 96 60-140 sec-Butylbenzene ug/L 20 20.1 100 60-140 Styrene ug/L 20 19.6 98 60-140 tent-Butylbenzene ug/L 20 16.2 81 60-140 tetra chi oroethene ug/L 20 18.5 92 60-140 Toluene ug/L 20 18.9 94 60-140 trans-1,2-Dichloroethene ug/L 20 19.8 99 60-140 trans-1,3-Dichloropropene ug/L 20 18.4 92 60-140 Trichloroethene ug/L 20 19.8 99 60-140 Trichlorofluoromethane ug/L 20 19.4 97 60-140 Vinyl chloride ug/L 20 16.6 83 60-140 1,2-Dichloroethane-d4 (S) % _ 100 70-130 4-Bromofluorobenzene (S) % 98 70-130, Toluene-d8 (S) % 100 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS - This report shall not be reproduced, except in full, Date: 12/14/2023 10:53 AM without the written consent of Pace Analytical Services, LLC. Page 18 of 28 ace QUALITY CONTROL DATA Project: November 23' Sampling Pace Project No.: 92700675 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4228986 4228987 MS MSD 92700404001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 23.2 22.6 116 113 60-140 3 1,1,1-Trichloroethane ug/L ND 20 20 25.0 24.2 125 121 60-140 3 1,1,2,2-Tetrachloroethane ug/L ND 20 20 23.9 22.8 120 114 60-140 5 1,1,2-Trichloroethane ug/L ND 20 20 24.1 23.0 120 115 60-140 4 1,1-Dichloroethane ug/L ND 20 20 24.3 23.6 122 118 60-140 3 1,1-Dichloroethene ug/L ND 20 20 25.8 25.2 129 126 60-140 2 1,1-Dichloropropene ug/L ND 20 20 26.9 26.3 134 132 60-140 2 1,2,3-Trichlorobenzene ug/L ND 20 20 21.0 20.2 105 101 60-140 4 1,2,3-Trichloropropane ug/L ND 20 20 22.6 21.3 113 107 60-140 6 1,2,4-Trichlorobenzene ug/L ND 20 20 20.7 20.5 104 103 60-140 1 1,2,4-Trimethylbenzene ug/L ND 20 20 23.2 23.0 116 115 60-140 1 1,2-Dibromo-3-chloropropane ug/L ND 20 20 21.2 19.6 106 98 60-140 8 1,2-Dibromoethane (EDB) ug/L ND 20 20 23.9 23.2 119 116 60-140 3 1,2-Dichlorobenzene ug/L ND 20 20 22.8 22.0 114 110 60-140 4 1,2-Dichloroethane ug/L ND 20 20 24.4 23.4 122 117 60-140 4 1,2-Dichloropropane ug/L ND 20 20 24.5 23.6 122 118 60-140 4 1,3,5-Trimethylbenzene ug/L ND 20 20 23.1 22.7 115 113 60-140 2 1,3-Dichlorobenzene ug/L ND - 20 120 22:3 21.9 112 109 60-140 2 1,3-Dichloropropane ug/L ND 20 20 22.9 22.3 115 111 60-140 3 1,4-Dichlorobenzene ug/L ND 20 20 22.2 21.9 111 109 60-140 2 2,2-Dichloropropane ug/L ND 20 20 23.8 23.2 119 116 60-140 3 2-Chlorotoluene ug/L ND 20 20 22.6 22.0 113 _ _110 60-140 2 4-Chlorotoluene ug/L ND 20 20 22.6 22.5 113 113 60-140 0 Benzene ug/L ND 20 20 23.9 23.2 119 116 60-140 3 Bromobenzene ug/L ND 20 20 22.7 21.9 114 ; ; 110 60-140 4 Bromochloromethane ug/L ND 20 20 25.1 24.3 125 121 60-140 3 Bromodichloromethane ug/L ND 20 20 22.9 22.4 114 1t2 60-140 2 Bromoform ug/L ND 20 20 21.2 20.3 106 101 60-140 5 Bromomethane ug/L ND 20 20 20.8 22.5 104 113 60-140 8 Carbon tetrachloride ug/L ND 20 20 23.8 23.3 119 117 60-140 2 Chlorobenzene ug/L ND 20 20 23.4 22.6 117 113 60-140 3 Chloroetha`ne ug/L ND 20 20 27.0 26.3 135 132 60-140 3 Chloroform ug/L ND 20 20 23.4 22.8 117 114 60-140 3 Chloromethane ug/L ND 20 20 21.8 21.3 109 107 60-140 2 cis-1,2-Dichloroethene ug/L ND 20 20 23.9 23.4 119 117 60-140 2 cis-1,3-Dichloropropene ug/L ND 20 20 22.1 21.9 111 110 60-140 1 Dibromochloromethane ug/L ND 20 20 22.5 22.0 112 110 60-140 2 Dibromomethane ug/L ND 20 20 23.0 22.1 115 110 60-140 4 Dichlorodifluoromethane ug/L ND 20 20 22.4 21.9 112 109 60-140 2 Diisopropyl ether ug/L ND 20 20 22.9 21.9 114 110 60-140 4 Ethylbenzene ug/L ND 20 20 23.0 22.6 115 113 60-140 2 Hexachloro-1,3-butadiene ug/L ND 20 20 21.8 22.1 109 110 60-140 1 Isopropylbenzene (Cumene) ug/L ND 20 20 23.5 23.1 118 116 60-140 2 m&p-Xylend ug/L ND 40 40 46.4 45.9 116 115 60-140 1 Methyl-tert-butyl ether ug/L ND 20 20 22.8 21.7 114 108 60-140 5 Methylene Chloride ug/L ND 20 20 22.9 22.2 114 111 60-140 3 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result Date: 12/14/2023 10:53 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 28 aye QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: November 23' Sampling Pace Project No.: 92700675 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4228986 4228987 MS MSD 92700404001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual n-Butylbenzene ug/L ND 20 20 23.3 23.5 117 118 60-140 1 n-Propylbenzene ug/L ND 20 20 22.5 22.2 112 111 60-140 1 Naphthalene ug/L ND 20 20 22.2 21.0 111 105 60-140 6 o-Xylene ug/L ND 20 20 22.5 22.0 112 110 60-140 2 sec-Butylbenzene ug/L ND 20 20 23.0 22.9 115 114 60-140 1 Styrene ug/L ND 20 20 23.8 22.9 119 114 60-140 4 tert- Butyl benzene ug/L ND 20 20 18.5 18.4 92 92 60-140 0 Tetrachloroethene ug/L ND 20 20 22.3 21.9 112 109 60-140 2 Toluene ug/L ND 20 20 23.2 22.5 116 112 60-140 3 trans-1,2-Dichloroethene ug/L ND 20 20 25.4 24.9 127 124 60-140 2 trans-1,3-Dichloropropene ug/L ND 20 20 22.6 22.0 113 110 60-140 3 Trichloroethene ug/L ND 20 20 24.1 23.5 121 118 60-140 2 Trichlorofluoromethane ug/L ND 20 20 25.9 24.8 129 124 60-140 4 Vinyl chloride ug/L ND 20 20 21.4 21.0 107 105 60-140 2 1,2-Dichloroethane-d4 (S) % 102 102 70-130 4-Bromofluorobenzene (S) % 100 101 70-130 Toluene-d8 (S) % 99 100 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/14/2023 10:53 AM without the written consent of Pace Analytical Services, LLC. Page 20 of 28 ( VIWO— a c e QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: November 23' Sampling Pace Project No.: 92700675 QC Batch: 816201 Analysis Method: SM 2540C-2015 QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92700675001, 92700675002, 92700675003 METHOD BLANK: 4224632 Matrix: Water Associated Lab Samples: 92700675001, 92700675002, 92700675003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Dissolved Solids mg/L ND 25.0 11/29/23 19:16 LABORATORY CONTROL SAMPLE: 4224633 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Dissolved Solids mg/L 250 236 94 90-110 SAMPLE DUPLICATE: 4224634 92700675001 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L ND ND Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/14/2023 10:53 AM without the written consent of Pace Analytical Services, LLC. Page 21 of 28 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 ,Face" (828)254-7176 QUALITY CONTROL DATA Project: November 23' Sampling Pace Project No.: 92700675 QC Batch: 816035 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92700675001, 92700675002, 92700675003 METHOD BLANK: 4223672 Matrix: Water Associated Lab Samples: 92700675001, 92700675002, 92700675003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L ND 1.0 11/29/2312:39 LABORATORY CONTROL SAMPLE: 4223673 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 50 51.0 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4223674 4223675 MS MSD 92700658001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Sulfate mg/L 227 50 50 257 267 61 81 90-110 4 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4223676 4223677 MS MSD 92700675001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Sulfate mg/L ND 50 50 51.7 52.4 103 104 90-110 1 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/14/2023 10:53 AM without the written consent of Pace Analytical Services, LLC. Page 22 of 28 ace QUALITY CONTROL DATA Project: November 23' Sampling Pace Project No.: 92700675 QC Batch: 818305 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92700675001, 92700675002, 92700675003 METHOD BLANK: 4235915 Matrix: Water Associated Lab Samples: 92700675001, 92700675002, 92700675003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Ammonia mg/L ND 0.10 12/09/23 11:17 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 LABORATORY CONTROL SAMPLE: 4235916 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 4.9 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4235917 4235918 MS MSD 92701169004 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua] Nitrogen, Ammonia mg/L ND 5 5 4.9 4.9 99 98 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4235919 4235920 MS MSD 92701169005 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L ND 5 5 4.9 4.9 99 99 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/14/2023 10:53 AM without the written consent of Pace -Analytical Services, LLC. Page 23 of 28 (-`1 Pace�, QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr, Asheville, NC 28804 (828)254-7176 Project: November 23' Sampling Pace Project No.: 92700675 QC Batch: 817029 Analysis Method: SM 531OB-2014 QC Batch Method: SM 531 OB-2014 Analysis Description: 5310B TOC Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92700675001, 92700675002, 92700675003 METHOD BLANK: 4228713 Matrix: Water Associated Lab Samples: 92700675001, 92700675002, 92700675003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Organic Carbon mg/L ND 1.0 12/04/23 23:08 LABORATORY CONTROL SAMPLE: 4228714 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Organic Carbon mg/L 25 23.9 95 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4228715 4228716 MS MSD 92701157003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Total Organic Carbon mg/L ND 25 25 23.3 23.4 93 94 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4228717 4228718 MS MSD 92700635001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Total Organic Carbon mg/L 291 25 25 305 310 54 77 90-110 2 M1 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/14/2023 10:53 AM without the written consent of Pace Analytical Services, LLC. Page 24 of 28 (Vace, QUALIFIERS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: November 23' Sampling Pace Project No.: 92700675 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270 The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/14/2023 10:53 AM without the written consent of Pace Analytical Services, LLC. Page 25 of 28 ace QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: November 23' Sampling Pace Project No.: 92700675 Lab ID Sample ID 92700675001 Q88V2 92700675002 ASB-01 92700675003 ASB-02 92700675001 Q88V2 92700675002 ASB-01 92700675003 ASB-02 92700675001 Q88V2 92700675002 ASB-01 92700676003 ASB-02 92700675001 Q88V2 92700675002 ASB-01 92700675003 ASB-02 92700675001 Q88V2 92700675002 ASB-01 92700675003 ASB-02 92700675001 Q88V2 92700675002 ASB-01 92700675003 ASB-02 92700675001 Q88V2 92700675002 ASB-01 92700675003 ASB-02 92700675001 Q88V2 92700675QQ2 ASB-01 92700675003 ASB702 92700675001 Q88V2 92700676002 ASB-01 92700675003 ASB-02 Date: 12/14/2023 10:53 AM Pace Analytical Services, LLC 2225 Riverside Dr, Asheville, NC 28804 (828)254-7176 QC Batch Method QC Batch Analytical Method EPA 3010A 816317 EPA 3010A 816317 EPA 3010A 816317 EPA 3010A 815917 EPA 3010A 815917 EPA 3010A 815917 EPA 7470A 816038 EPA 7470A 816038 EPA 7470A 816038 SM 6200B 817079 SM 6200B 817079 SM 6200B 817079 SM 2540C-2015 816201 SM 2540C-2015 816201 SM 2540C-2015 816201 EPA 300.0 Rev 2.1 1993 816035 EPA 300.0 Rev 2.1 1993 816035 EPA 300.0 Rev 2.1 1993 816035 EPA 350.1 Rev 2.0 1993 818305 EPA 350.1 Rev 2.0 1993 08305 EPA 350.1 Rev 2.0 1993 818305 SM 531OB-2014 817029 SM 531OB-2014 817029 SM 531OB-2014 817029 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. EPA 601 OD EPA 601 OD EPA 601 OD EPA 6020E EPA 6020B EPA 6020B EPA 7470A EPA 7470A EPA 7470A Analytical Batch 816486 816486 816486 815929 815929 815929 816130 816130 816130 Page 26 of 28 If CHAIN -OF -CUSTODY Analytical Request Document Face Analytical" Chair,uf CustodyisaLfGAI.IJOCLIMLNT- Completcall relevcn(fields LAB USE ONLY. Affix Workor, WO# , 9270d675 6� IIIII II III I III II I III ALL SHADEL 92700675 — Container Preservative 7Ve- Company: Billing Information: Addrms: •/ Report To: /� Email To: `•P,e (G) methanol, ICI ammonium r,,,u,eTypes:(t),I:,cadd,(2)sulfo,ic Q) z hydroxide, Jivar bisuifa te, (D) TSP, (8) sodium (U) On, c—ed, acid,(3)hydrochlor1,add, thiosu)rat%(9) (0) Other hexane, ___ 14) mdium lrrdo,ride,(ST rin:-0te, (A) ascorbic acid, Bi ammonium sulfate, Copy To: .Site C011eclion Info/Address: ' Analyses Lab Profile/L'ine: Customer Project Name/Number: !� ✓ .n,!!R ) 3 Jn.//,, t Stale our,LY/City. Time Zone Collected: �.:' J/c / r rn✓oyr✓a,V. 111'T( MIT IcT LJ�T ( �� �-� Ct T '��' '.a '� -") �.J . J t-i> , pl. lr c pt ct •kiea: C-tody SC%J.R tr 1C Intact Y IS Imo+ Custad1 „ipnntur _n taeee t r;)tt [l Coll t ,ill r r_ Gaon. r Ei w t, Aottkent:act Nil Cor c t F3 ittlea t nt 5utfi a nt vole.. Y Samploa P<caivcd t !ce tt ,IA VOA. 11-d;pace Arr.ptatil. T 14A USD Yea fated als 1 It Sampl h Sn i;ol tin3 lma Nll,l Ren 1 7 Ctrioy).ntsss.el pe w 1v. aA e1 str T t aa:plc p8 ll�a i! 17A cceo(w Js� pit t Pe ...... ./�.� (. ..ry.. I,�___ Su iflr' kY ent V 1) AD Lead Acetate ship .// W a USE ONLY: Lob suvpic. 3./ C :mnenta:' � � ^ O� Y Phone: Email: Site/facility IDg Compliance Monitoring? I'y'e ( )No -r Collerted By 1prir Q. 1 '1�1 /J2 L �e !✓�'::., Purchase Order If: Quote it: DW PWS ID 0: OW Location Code; Collcc[yclfBy (signature.); /'7iy- roman .unit Date Required: S {n Immediately Pace on ice: JNo Sample Disposal ( I Dap i e a Tpr.pnale I I Return I I Arch — _ Rusty ( ) Same Day ( I Next Day I J 2 Day ( 13 Day ( 1 A DaY I ) 5 Day (txped to ar;ChAPpl ies y) Field Filtered fit applicable): ( j Yes [ I Ncr Analysis: 'Matrix Codes (Insert in Matrix box below): Drinking Water(DW), Ground Water(GW), Wastewatar(WW), Product (P), Soil/Solid (SILL oil (OL), Wipe (WP), Au (AR), Tasue ITS), Bioassay (B), Vapor IV), Other (OT) Customer Sampie ID Matrix' Cornp/ Grab Collected (or Conipos le, Start) Composite End Res Cl It .f Clns Date Time Date Time ............ . .. .... ................ . . s Customer Remarks / Special Conditions / Possibl,: )laaards: Type of Ice Used: We Blue Dry None SHORT HOLDS PRESENT (02 hours): N N/A Lab Sample Temperature Info: Temp Blank 11,5e,rvgsl. Y (� NA Therm 100: 10 / 0 q Cooler 1 Temp Upon Receipt: 3�✓ oC Cooler I Theron Corr. Factor 0 oc Cooler t C."e't,id Temp: __;=, oc ommcntz. Packing Material Use Labtracking h: - r• / Badchem iaaple(s).screened (1500 rpm): Y N 179.FEDFX Samples received via. - .UPS Client Cc ,ia, Paco our rr RehngmsI em by/Company (Signature) 12,.t Dale/Lme, Received by/Company: (Signature) Date/TIrne / M lA8 USE C313LY Tabl, it: cctmm�. Re hnqu Shad by/Company (S:f n pure) - ... .._...... Date/Time (lit.! J :� `,Ia Received by/Company: (Signature) .E', pp/rG,ic 1{bJ._,. Date/Tune: ``�rri i. i /rrrD Template: Prelog n. Trip Blank Received: Y 6 NA HCL McOH TSF Other Helinyunhed by/Company: (Signature) Date/Time: Received by/Company: (Signature) Date/ ime: PM; Non Conform' ,ce(s): I Page"'- e - 2� CHAIN -OF -CUSTODY Analytical Request Document Face Analytical " Chain-ofCustodv is a LEGAL DOCUMENT- Complete All releven(fields LAB USE ONLY -Affix Worker, W® : g2700675 ALL SHADES 111II I1 11I I 1 III III III 82700675 Address: r - / Report To: Email To: •- Preservative Types: (1) nitric acid, (2) sulfuric acid, (3) hydrochloric add, (4) sodium hydroxide, (5) lint ocelate, ¢ a�•� / t;.. // (f) methanol, Q) smflurn bisulfate, (8) sodium thiosulfam, (9) hexane, (A) ascorbic acid, (R) ammonium sulfate, Copy To: .Site Collection Info/Address: (C) amino nium hydroxide: (0) 75P, (U) Unpreserved, (0) Other _ Analyses lLab Profile/Line: Customer Project Name/Number: State: �ougtvIcity: Time Zone Collected: i.::n Snmplo Rrcaipt Checklist: �i Sra..r:,,✓, < e ✓ I I PT ( ) MT l I CT [,_-ET -• a/�i.�� '1 ✓,,..i Cuscady Scala Preaeneltntoct Y tt l Phone: Site/Facility ID It: Compliance Monitoring? custody signnturea vrnaooc }-,tl v email: I-{-h'es l I No Collector Stgnatnre Itrcaent F,xJh ZIA no". nail: n i;A Collccled By (Print) Purchose Order if: DW PWS ID It: Core t ""tL,s 11 nA 1 Quote It DW Location Code: .Su ificient Volume Y ,i ItA Sanplor Pnc.ivo 1 on lco N tAr Coll Lied,Ry (;I);nattue). 'rmo and Date R squired: Immediately Pac'P. on tce: Vor, lined Cpaco Acc ptabi Y NA /'��_ S ri (-jYes No usp"I Ro Sarspgulacua sails a l,s in Sample Disposal; Rush: Field Filtered (if applicable): !7 Rena I 1 c11 � r y�L VA 1 I L,sm.,v ,sappromiin, I J Return ( ) Same Day ( ) Next Day I ) Yes ( ) No ( Cl Sir p y C I I A ch've. ( ) z Da ( 13 Day [ I n Day I 1 s Day J !,pit pti A cecpt,,j'I / ZIA (Expeditu Chutes A"YI Solf dr, Analysis: St uy,.> e q l I �_\ •—' krene t 1'�N QiI+\ Matrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (WW), ` �` J Lend Acetate strip _„_ t"„•/ Product (P), Sod/Solid (SQ, Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Bioassay (b), Vapor (V), Other (OT) f` - A Comp / Collected (or End Res It of t � l Lab S rpld..d / Covenants: ConNositc „? - Custon,erSamplr.IO Matd,, Grab Composite Start) Cl Clns C� ''� �. ^ OC Dale Time Date Time I 7 v ! ! ? 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