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HomeMy WebLinkAboutNC0000078_Groundwater Monitoring Report November 2022_20221231Mf(G ( GW-59A COMPLIANCE REPORT FORM Permit#NC 60wo 7k (Subunit one cewh nrnnitas'h,,edad o ith G W-59 Jorrns.) 1 Enter date monitoring results were due. �) Will this monitoring report (GW.59 and GW-59A) YES NO be submitted after the established due d ? 2 Was any required information missing on the GW-59 report forms? YES NO IF the answer to question t or 2 is "YES", list in the space provided below the well identification number(c) and explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES NO identification plate, area overgrown, etc.)? [#'the answer is "Yes ", contact the ftegiorvol OJ}ice forguidance. 4 Are any monitored constituents equal to or above the established standards? V,YS' NO If the answer to question 4 is "NOy skip to section 8. If the answer to question 4 is "YES"list the affected wells individually with constituent(s) and concentration($) exceeding standards in the space provided below. ,S/,--1- 4Tl��l��� 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO same tonstituent(s) in the same well(s) In the last two years? / If the answer to question 5 is "NO", skip to section 8. If the answer to question 5 is "YES" list in the space provided below, each well with constituents) exceeding standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years). 6 Are the monitoring wells listed in section 5located at or beyond the review boundary? YES NO If the answer is "YES" a groundwater qualify problem maybe occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", moniforing wells may be improperly located; contact the Regional Office. 7 is the partridge implementing previously approved actions required by the Division involving this YES NO groundwater quality problem? lithe answer to question 7 is "YES", describe those actions in the space provided below. If the answer to question 7 is "NO", contact the Regional Office within 90 days: an evaluation may be required to determine the t the t disposal t Is havingt the d compliatic boundaries surrounding this facility. Failure to do a. may ubiect the 'tt to Notice f Violation, fines, and/or penalties. RR�FIVFD JAN 17 2023 aSBCTICd1 g The person completing this portion (G W-59A) of the monitoring report shoo mft rs form with G W-59 forms for required wells to the address provided at the top of the current G W-59 f0tho s 7 1 hereby acknowledge that the above Information was evaluated and the Information submitted in Igis� report (Compliance Report GW-59A) is true and complete to the best of my knowledge. )a. r�`,4' ram/ /2�3//Zyo Signature of Permlttea (or AutM1priutl Agent)00 J m m I GW-59A 12/12003 0re >>� W W m W W W 0 0 0 0 0 0� N N L+ F+ F+ I+ N 'o x o s� m m A O N v A 0 F+ O W J UI N O 0 0 l0 � t0 p0O pp M O \ � 6 a r r r C c c R 0 m 3 a O O _o o O a. — Dm Rr N o N m 3 3 -mla y n o 3 A m Z ry 53 m m' 0 1 P ti ay m n y O - O E o m z% $ E —— m v- p n S y H 'n\ Ra _ 3 3 F 3' 3 c 3 3 3 3 y 30 r r m n v � Z O o m F n D c m d ry '� fo °� 3 w o '" _ z _o m n o d Z � � w y a y z z N 3 3 3 3 E a z z 3 z a 8i m N 8i .emu ii �i g g u -0^. N o N o N m o� I c c 3 3 c c 3 c c 3 c 3 3 3 3 3 ^ < r m O u � o B m O y ^ O O 3 3 3 3 n 0 a y eti a r v = O ❑m0 o m am 5 A z i a ° 20 - ;z m m Fa 3 AA 3 m F "aw 3; 3 d 3 m 0 Z o 3 a E In o w n � a < III^ w H a1 Q o_, O 01 n A p y a a o m n m N N o a n c ° n 3 - a_ N< No to , � Flo 0 o n 11111111 m dN m E N m x � O o » a 3 z q m p o 01 O o m a y 0000OZ g n n O W ^ > > i a ~o o ^ m N a O m N � < m 9 'C m o Ina Tom. _.D N o q n 0 v Gi d H z= Q rs O O n e � $ 3 3� 2 3 3 3 3 'o 'o �' N . _ m a v u - a ? n z mK o s m O c g 4 3 0 D zO ZO Z y y o 0Er Z_ o T 0. 0 3 3 3 m z zz 8 0 j o 0 0 2 0 o = a 3 .0 9 n % 3 4 m c 3 3 c 3 c c 3 3 3 3 3 3 ti m < y O O n N Q ? Q N a FF x H D sr n m A n O 0 n n �l933°ttN D n n n n � T N ❑ r2 ➢� o m o 0 A a 3 9 z 0 4 I a i ❑DDOmm n N r p N 0 9 � 0 m 0 o q a - a 3 z 0 � o O T v m a r A a a m w o o - .. a ., 3' $,,O0 3d N 3MB o ° n or S z m a 0° i v m c n41 j 2vni MT3 ° $z 0 Z z 01 f/Id'{N _. d a. O 90 m o = ZO N z u� O ,°�� o O m 3 = pmw z m F S R 8 o 'o y 3 a az 0 ; ^ n 9 N O z� l n llw a¢ m n N m n £ n 3 3 c 3 m 3 3 ? 3 0 3 m �m�° r'°�Gr r --w L1 OR a u ❑ o' p p d s s D O o q a n o m o N A m z m o p D s O z n o o '^ T m 0 3 m p m 3 _o. _ m a z m N N 3_ v 3 n x a o x j d 3 n ud, m ,2 3 g '^ m 3 3 3 3 3 3 a z z G v m a m d n a w _ ° N x° O 3 3 c c 3 3 S 3 3 3 3 s ❑ ° ° ❑ m O Q �R w R ao ° °=-tw . 9 cAi _a N m grm-a 3 y 3 O a Z y T m A LI D 3 5 n z p N m d 6 0 0 GI /� 3 n :. w .. v N m °' \ a a 3 3 m 3 m 3 m O z D C n O- Ta°°° m m pl O u a tt t D <j o o A 3 3 m m c 3 , o m N L ' c 1 O 0 0 = n R z m o O m d _ °dym 11 Z Q A aceAnalytical wxw.penlabe.mm December 28, 2022 Mr. Bernie Kelly Davidson River Village, LLC P.O. Box 880 Pisgah Forest, NC 28768 RE: Project: MW NOVEMBER 2022 Pace Project No.: 92637869 Dear Mr. Kelly Pace Analytical Services, LLC 2225 Riveraitle or. Asheville, be 28804 (828)254-7176 Enclosed are the analytical results for sample(s) received by the laboratory on November 21, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services -Asheville • Pace Analytical Services - Charlotte • Pace Analytical Services - Peachtree Corners, GA If you have any questions concerning this report, please feel free to contact me. Sincerely, �� Taylor Dyson for Lorri Patton lorri.patton@pacelabs.com 1(828)254-7176 Project Manager Enclosures Q Ae�a60i r REPORT OF LABORATORY ANALYSIS not report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 28 t �ceAnalytical ® Pace Analytical Services, LLC Dt 2iii RiversideC28 M ASM1ev828)2C 20Bn4 wwx.patelaE9.ttAI (028)254-]1I8 CERTIFICATIONS Project: MW NOVEMBER 2022 Pace Project No.: 92637869 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99008 South Carolina Certification #: 99006001 9800 Kincey Ave. Ste 100, Huntersville, NO 28078 South Carolina Drinking Water Gen. #: 99006003 North Carolina Drinking Water CerlIDcatlon #: 37706 FloridalNELAP Certification #: E87627 North Carolina Field Services Certification #: 5342 Kentucky UST Certification #:84 North Carolina Wastewater Certification #:12 Louisiana DoH Drinking Water#: LA029 South Carolina Laboratory ID: 99006 VirginiaNELAP Certification #: 460221 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NO 28804 South Carolina Laboratory ID: 99030 FlondalNEIAP Certification #: E87648 South Carolina Certification #: 99030001 North Carolina Drinking Water Certification#: 37712 VinIniaNELAP Certification #: 460222 North Carolina Wastewater Certification #:40 Pace Analytical Services Peachtree Corners If Technology Pkwy, Peachtree Corners, GA 30092 North Carolina Certification #: 381 Florida DOH Certification k E87315 South Carolina Certification #: 98011001 Georgia DW Inorganics Certification #: 812 REPORT OF LABORATORY ANALYSIS This repel shell not be reproduced, except in full, winsat the written consent of Pace Analytical Services, LLG. Page 2 of 28 ,clakeAnalytical WWW.pdOeldE9.t0111 SAMPLE ANALYTE COUNT Pace Analytical Services, LLO 2225 Riverside D,. Asheville, Nc 25804 (628)254 7176 Project Pace Project No.: MW NOVEMBER 2022 92637869 Analylee LibID Sample ID Method Analysts Reported Laboratory 92637869001 Q88V2 EPA 6D20B CW1 ] PASI-GA EPA 7470A VB 1 PASI-GA SM 6200B CIE 63 PASI-C SM 254OC-2015 CS1 1 PASI-A EPA 300.0 Rev 2.11993 CDC 1 PASI-A EPA 350.1 Rev 2.01993 ARJ 1 PASI-A SM 53108-2014 MJP 1 PASI-A 92637869002 ASB-01 EPA 6020E CW1 ➢ PASI-GA EPA 7470A VB 1 PASI-GA SM 6200B CL 63 PASI-C SM 254OC-2015 CS1 1 PASI-A EPA 300.0 Rev 2.11993 CDC 1 PASI-A EPA 350.1 Rev 2.01993 ARJ 1 PASI-A SM 531 OB-2014 MJP 1 PASI-A 92637869003 ASB-02 EPA 6020B CW1 ] PASI-GA EPA 7470A VB 1 PASI-GA SM 6200B CIE 63 PASI-C SM 254OC-2015 C51 1 PASI-A EPA 300.0 Rev 2.11993 CDC 1 PASI-A EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A SM 531OB-2014 MJP 1 PASI-A PASI-A= Pace Analytical Services -Asheville PASI-C = Pace Analytical Services - Charlotte PASI-GA= Pace Analytical Services - Peachtree Canners, GA REPORT OF LABORATORY ANALYSIS This round shall not be rc,,.dc d, except In full, without the written consent of Pace Analytical Services, ac. Page 3 of 28 r 24 aceAnalytical wuw.panlebassm ANALYTICAL RESULTS Project: MW NOVEMBER 2022 Pace Project No.: 92637669 Sample: 0881 Lab ID: 92637869001 Collected : 111211221145 Received: 11/21/22 Pace Analytical Services, LLC 2225 Riverside or. Asheville, NC 28804 (621I254999 Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring WeII Data Analytical Method: Pace Analytical Services - Charlotte Performed by Paco 1 1112312210:13 Collected By Mark 1 11/23/22 10:13 Swann Collected Data 11/21/22 1 1112312210:13 Collected Time 1146 1 11/23/2210:13 pH 5.21 Std. Units 1 11123/2210:13 Temperature 15.4 deg 1 11/2312210.13 Static Water Level 69.63 feet 1 1112312210:13 Specific Conductance 19.0 umhoslcm 1 1112312210:13 Oxygen, Dissolved 4.99 mg/L 1 11/23/22 10:13 778244-7 Total Well Depth 68.5 feet 1 11/23/2210:13 REDOX 35.7 all 1 11123/2210:13 Turbidity 2.85 NTU 1 11123/2210:13 Odor None 1 11123/2210:13 Appearance Clear 1 11/23/2210:13 6020 MET ICPMS NC Analytical Method: EPA 6020B Preparation Method: EPA3006A Pace Analytical Services - Peachtree Corners, GA Arsenic NO ug/L 5.0 1 12/23/2209:16 12/2312216:31 7440-38-2 Chromium NO ug/L 5.0 1 12123/2209:16 12123/221631 7440-47-3 Cobalt NO ug/L 10 1 1212312209:16 12/23/221631 744048-4 Iron 69.7 ug/L 40.0 1 12/23/2209:16 12123/2216:31 7439-89-6 Lead NO ug/L 1.0 1 12123/2209:16 12/23/2216:31 7439-92-1 Manganese NO uglL 10.0 1 12/2312209:16 12/23/2216:31 7439-96-5 Sodium 1120 uglL 100 1 1212312209:16 12/2312216:31 7440-23-5 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services - Peachtree Corners, CA Mercury NO ug/L 0.20 1 121091220990 1210912213:29 7439-97-6 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND ug/L 0.50 1 11128/2220:22 71-43-2 Bromobenzene ND ug/L 0.50 1 11/28/2220:22 108-86-1 BromocN.Bmethane NO ug/L 0.50 1 11/2B/2220:22 74-97-5 Bromadichloromethane NO ug/L 0.50 1 1112812220:22 ]5-2]-4 Bromofarm NO ug/L 0.50 1 1112812220:22 75-25-2 Bromomethane NO ug/L 5.0 1 1112812220:22 74-83-9 n-Butylbenzene NO ug/L 0.50 1 11/2812220:22 104-51-8 sec-Butylbenzene NO ug/L 0.50 1 1112812220:22 135-98-8 tart-Butylbenzene NO ug/L 0.50 1 1112812220:22 98-06-6 Carbon tetrachloride NO ug/L 0.50 1 1112812220:22 56-23-5 Chlorobenzene NO ug/L 0.50 1 1112812220:22 108-90-7 Chl.... than. NO u0/L 1L 1 11/2812220:22 75-00-3 CM1lorofx. ND uglL 0.50 1 11128/2220:22 67-66-3 Chlormuethane NO ug/L 1.0 1 11128/2220:22 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12128/202204:07 PM whhoutthewrltten... at al Pace Analytmal Sales, LLC. Page 4 of 28 t Pace Analytical services, LLC �ceMalytical o 225 R1ven128 Asheville NO 804 ..ourselves (8262B)254-01 ]6 ANALYTICAL RESULTS Project: MW NOVEMBER 2022 Pace Project No.: 92637869 Sample: O88V2 Lab ID: 92637869001 Collected: 1111/2211A5 Received 1112112217:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[ 620DB MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte 2-Chlorotoluene NO ug/L 0.50 1 11/28/22 20:22 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/28/22 20:22 106-434 1,2-Dibromo-3-chlmopropane NO ug/L 1.0 1 1112812220:22 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11128/2220:22 12448-1 1,2-Dlbmmoethane(EDB) ND ug/L 050 1 11/28122 20:22 106-93-4 Dibromomethane ND ug/L 0,50 1 11/28/22 20:22 74-95-3 1,2-Dichloabenudes ND ugd- 0.50 1 1112812220,22 95-50-1 1,3-Dichlorabenzene ND ug/L 0.50 1 1112812220:22 541-73-1 1,4-Dichlorabenzene NO ug/L 0.50 1 11/28/22 20:22 108-46-7 Dichlorodl0ueromethane NO ug/L 0.50 1 11/28/22 20:22 75-71-8 1,1-Dichloroethane NO ug/L 0.50 1 11/28/22 20:22 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/28/22 20:22 107-06-2 1,1-Dichlooethene ND ug/L 050 1 11/28122 20:22 75-35-4 cis-1,2-Dlchloroethene ND ug/L 0.50 1 11/28/22 20:22 156-59-2 trans-1,2-Dichloroethene NO ug/L 0.50 1 11128/22 20:22 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11128/22 20:22 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 1112812220:22 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/28/22 20:22 594-20-7 1,1-Dichlorapropene ND ugi 0.50 1 1112812220:22 563-58-6 cis-1,3-Dichloropropene NO ug/L 0.50 1 11/28/22 20:22 10061-01-5 trans-1,3-Dichloropropane NO ug/L 0.50 1 11/28/22 20:22 10001-02-6 Diisopropyl ether NO ug/L 0.50 1 11/28/22 20:22 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/2812220:22 10041-4 Nexachloro-1,3-butadien , ND ug/L 2.0 1 11/28/22 20:22 87-68-3 Isopropylbenrane(Curl ND ugh- 0,50 1 11/28122 20,22 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/28/22 20:22 75-09-2 Methyl-tert-butyl ether ND u9/L 0.50 1 11/28/22 20:22 1634-04-4 Naphthalene ND uglL 2.0 1 1112812220:22 91-20-3 n-Propylbenzene ND ug/L 0.50 1 1112812220:22 103-65-1 Styrene NO ug/L 0.50 1 11/28/22 20:22 100-42-5 1,1, 1,2-Tetrachloroethane NO ug/L 0.50 1 11/28/22 20:22 630-20-6 1,1,2,2-Tetrachlaroethane NO ug/L 0.50 1 11/28/22 20:22 79-34-5 Tetrachlaroethene ND ug/L 0.50 1 11/28/22 20:22 127-18-4 Toluene ND ugh- 0.50 1 11/28122 20:22 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 11/28/22 20:22 87-61-6 1,2,4-Trichlombenzene ND ug/L 2.0 1 11/28/22 20:22 120-82-1 1,1,1-Trichloroethane ND ugA- 0.50 1 11/28/22 20:22 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 1 11/28/22 20:22 79-00-5 Trichloroethene NO ni 0.50 1 11128/2220:22 79-01-8 Trichloro9uommethane NO ug/L 1 0 1 11/28/22 20:22 75-694 1,2,3-Trichloropropane NO ug/L 0.50 1 11/28/22 20:22 96-18-4 1,2,4-Trimethylbenzene NO ug/L 0.50 1 11/28122 20:22 95-63-6 13,5-Trimethylbenzene ND ug/L 0.50 1 11/2812220:22 108-61-8 Vinyl chloride NO ug/L 1.0 1 11128/22 20 22 75-01-4 m&p-Xylene ND ugh- 1.0 1 11/28/22 20:22 179601-23-1 o-Xylene ND ug/L 0.50 1 11/2812220.22 95-47-6 REPORT OF LABORATORY ANALYSIS This report shall nor be reproduced, except In full, Date: 12/28/2022 04:07 Pro without the written co heart of Pace Aneiydcal 6ervicas,LLC. Page 5 of 28 a'OAnalytical a www.penlaba.com ANALYTICAL RESULTS Pace Analytical Services, LLC 2226 Riverside Dr. Asheville, NC 28804 (626)2547176 Project: MW NOVEMBER 2022 Pace Project No.: 92637869 Sample: Q66V2 Lab ID: 92637969001 Collected: 1112112211:45 Received: 11/21/22 17 10 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 62008 PaceAnalytical Services - Charlotte Surrogates 1,2-131chlomethane-d4(S) 90 % 70-130 1 11128/2220:22 17080-07-0 4-Bromofluombenzene(S) W % 70-130 1 11128/2220:22 460-00-4 To1uene-08(S) 100 % 70-130 1 11128/2220:22 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 254OC-2015 Pace Analytical Services -Asheville Total Dissolved Solids NO mg/L 25.0 1 11/23/2218:58 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.11993 Pace Analytical Services -Asheville Sulfate NO mg/L 1.0 1 11122/2219:26 14808-79-8 350.1 Ammonia Analytical Method EPA 350.1 Rev 2.01993 Pace Analytical Services - Asheville Nitrogen, Ammonia ND mg/L 0.10 1 12/01f22 1322 766441-7 5310B TOC Analytical Method: SM 531OB-2014 Pace Analytical Services -Asheville Total Organic Carbon NO mg/L. 1.0 1 1112812220:30 744044-0 REPORT OF LABORATORY ANALYSIS ThIs repot shall not be epmtluced except In full, Date: 121281202204:07 PM without the written consent of Pace Analytical services, I.I.C. Page 6 of 28 Pace Analytical Services, LLC aceAnaly ical ® 2225 Rlv C 28 Dr. Asheville, NC 2e509 W4Nv.penlaEi.[om (636)350-]1I6 ANALYTICAL RESULTS Project: MW NOVEMBER 2022 Pace Pni No.: 92637869 Sample: ASB-01 Lab ID: 92637869002 Collected: 11121/221646 Received: 11/21/221710 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzetl CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 11123/2210:15 Collected By Mark 1 11/2312210:16 Swann Collected Data 11121122 1 11123/2210:15 Collected Time 1546 1 11123/2210:15 PH 5.93 Sitl. Units 1 1112312210:15 Temperature 13.5 all C 1 11/2312210:15 Bill Water Level 8.25 feet 1 11123/2210:15 Specific Conductance 403.2 umhos/cm 1 1112312210:15 Oxygen, Dissolved 0.65 mg/L 1 11/2312210:15 778244-7 Total Well Depth 15.0 feet 1 11/2312210:15 REDOX -164.6 mV 1 1112312210:15 Turbidity 3.44 NTU 1 1112312210:16 Odor None 1 1112312210:16 Appearance Clear 1 1112312210:15 6020 MET ICPMS NO Analytical Method: EPA 6020B Preparation Method: EPA 3005A - Pace Analytical Services - Peachtree Corners, GA Arsenic ND ugd- 5.0 1 12/23/2209,16 12/23/221837 7440-38-2 Chromium ND ug/L 50 1 12/2312209:16 121231221637 744047-3 Cobalt 3.5 uglL 1.0 1 12123/2209:16 12/231221637 744048-4 Iron 779 u9IL 400 1 1212312209:16 12/23/2216:37 7439-89-6 Lead ND u9IL 1.0 1 12/2312209:16 12/23/2216:37 7439-92-1 Manganese 1760 ug/L 100 10 12/2312209:16 1212712213:46 7439-96-5 Sodium 28300 ug/L 1000 10 1212312209:16 1212712213:46 7440-23-5 ]4]0 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services - Peachtree Corners, GA Mercury NO ug/L 0.20 1 12109/2209:00 12/0912213:40 7439-97-6 6200B MSV Analytical Method: SM 6200E Pace Analytical Services - Charlotte Benzene NO ug/L 0.50 1 11128/2220:41 71-43-2 Bmmobanzene NO ug/L O50 1 1112812220:41 108-86-1 Bromochloromethaoe ND ug/L 0.50 1 1112812220:41 74-97-5 Bromatlichloromethane ND ug/L 0,50 1 11/2812220:41 76-27-4 Bronchi NO ug/L 0,50 1 11/2812220:41 75-25-2 Bromomethane ND ug/L 5.0 1 1112812220:41 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11128/2220:41 104-51-8 seto-Bulylb6nzene ND ig/L 0.50 1 11/2812220:41 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 11/28/2220:41 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/2812220:41 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/2812220:41 108-904 Chlomethane ND ug/L 10 1 1112812220:41 75-00-3 Chloroform NO u9IL 0.50 1 11128/2220:41 67-66-3 Chloromethme ND u9I1- 1.0 1 1112812220:41 74-87-3 REPORT OF LABORATORY ANALYSIS This report shell not be reproduced, except in full, Date: 12/28/202204:07PM without the wntten consent of Pace Analytical Services. LLC. Page 7 of 28 aceAnalytical ww.psnlaBLwm ANALYTICAL RESULTS Pace Anil I Services, LLC 2225 Riverside Dr. Asheoille, NC 26804 (821 Project: MW NOVEMBER 2022 Pace Project No.: 92637869 Sample: ASB-01 Lab ID: 92637869002 Collected: 11/21/2215:45 Received: 11/21/22 17 10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Dual 6200B MI Analytical Method: SM 6200B Pace Analytical Services - Charade 2-Chlomtoluene ND u9I1- 0.50 1 11128/2220:41 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 1112&2220:41 10643-4 1,2-Dibromc-3-chlcropropane NO ug/L 1.0 1 1112812220,41 96-12-8 Dibromochloromethane NO ug/L 0.50 1 11/2812220:41 124-48-1 1,2-Dibramoethane(I NO ug/L 0.50 1 11/2812220:41 106-934 Dibromomethane NO up- 0.50 1 11/28/2220:41 74-95-3 1,2-Dichlorobenzene NO ug/L 0.50 1 11128/2220:41 95-50-1 1,3-Dichlorobenzene NO uga- 0.50 1 11128/2220:41 541-73-1 1ADichlorobenzene ND upl- 0.50 1 11128/2220:41 106-46-7 Dichitrodiharnomethanc NO ug/L 0.50 1 11128/2220:41 75-71-8 1,1-Dichloroethans ND u9IL 0.50 1 W28/2220:41 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 1112812220:41 107-06-2 1,1-Dichloroethene NO ug/L U0 1 11/2812220:41 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 1112812220:41 156-59-2 trans-1,2-Dichloroethene NO all 0.50 1 11128/2220:41 156-60-5 1,2-Dichloropropane NO ugh- 0.50 1 11/2812220:41 78-57-5 1,3-Dichloropropane NO ug/L 0.50 1 11/2812220:41 142-28-9 2,2-Dichloropropane NO ug/L 0.50 1 11/2812220:41 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/28/2220:41 563-68-6 cis-1,3-Dichloropropene ND u9IL 0.50 1 11/2812220:41 10061-01-5 trans-1,3-Dichloropropene ND u9IL 0.50 1 11/28/2220:41 10061-02-6 Diisoprcpyl ether NO ug/L 0.50 1 11/28/2220:41 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/2812220:41 100-414 Hexachloro-1,3-butadiene ND up- 2.0 1 1112812220:41 87-68-3 Isopmpylbenzene(Cumene) NO up- 0.50 1 11128/2220:41 98-82-8 Methylene Chloride NO ug/L 2.0 1 11/2812220:41 75-09-2 Methyl-tert-butyl ether ND u9/L 0.50 1 11/2812220:41 1634-04-4 Naphthalene ND ug/L 2.0 1 11/2812220:41 91-20-3 n-Propylbenzene ND u9I1- 0.50 1 11128/2220:41 103-65-1 Styrene NO u9IL 0.50 1 11/28/2220:41 100-42-5 1,1,1,2-Tetrachlorcethane NO ug/L 0.50 1 1112812220:41 630-20-6 1,1,2,2-Tetrachloroethane NO 1 0.50 1 1112812220:41 79-34-5 Tetrachloroethene NO u9IL 0.50 1 11/2812220:41 127-184 Toluene NO ug/L U0 1 11128/2220:41 108-88-3 1,2,3-Trichlcrobenzene NO had- 2.0 1 11128/2220:41 87-61-6 1,2,4-Trichlombenzene NO ugh- 2.0 1 11/2812220:41 120-82-1 1,1,1-Trichlaroethane NO ugh- 0.50 1 11128/2220:41 71-55-6 1,1,2-Trichlaroethane NO ug/L 0.50 1 11128/2220:41 79-00-5 Tdchloroetman, ND u9IL 0.50 1 11/2812220:41 79-01-6 Trichlcrofluoromethane ND ug/L 1'0 1 1112812220:41 75-69-4 1,2,3-Tdchimepropane ND ug/L 0.50 1 11/2812220:41 96-15-4 1,2,4-Trimethylbenzene NO ug/L 0.50 1 1112812220A1 95-63-6 1,3,5-Trimethylbenzene NO ug/L 0.50 1 11/2812220:41 108-67-8 Vinyl chloride NO up- 1.0 1 1112812220:41 75-01-4 m&p-Xylene NO ug/L 1.0 1 1112812220:41 179601-23-1 o-Xylene NO u9/L 0.50 1 11128/2220:41 95-47-6 REPORT OF LABORATORY ANALYSIS This repel shall not be reproduced except In WII, Date: 12/28/202204:07 PM Mthoutlha wrihin consent of Pace AnalNicel Services,LLC. Page 8 of 28 aceAnalyical weepaselshrucas ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-9176 Project: MW NOVEMBER 2022 Pace Project Ne.: 92637869 Sample: ASB-01 Lab ID: 92637869002 Collected: 11/21/221545 Received: 111211221710 Matrix:Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Oual 6200B MSV Analytical Method: SM 6200E Para Analytical Services - Charlotte Surrogates 1,2-Dichloreethani(S) 93 % 70-130 1 1112812220:41 17060-07-0 4-Bromofluerobenzene(S) 98 % 70-130 1 11128/2220:41 460-004 Toluene-d8(S) 99 % 70-130 1 11/28/2220:41 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 254OC-2015 Pace Analytical Services -Asheville Total Dissolved Solids 239 dri 25.0 1 11/23/2218 58 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.11993 Pace Analytical Services -Asheville Sulfate 7.5 mg/L 1.0 1 11/22/22 19:41 14808-79-8 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.01993 Pace Analytical Services -Asheville Nitrogen, Ammonia NO ri 0.10 1 12/012213:23 7664414 5310B TOC Analytical Method: SM 531OB-2014 Pace Analytical Services -Asheville Total Organic Carbon ND or lL 1.0 1 1112812220:48 7440-44-0 Date: 12/28/2022 04:07 PM REPORT OF LABORATORY ANALYSIS This .,sit shsll not be reprotlecetl, except In fell without the written wnsent of Pace Analytical Services, LLC. Page 9 of 28 Pace Antlytical Services, LLC ® 2225 Riverside Dr. aceAnaljd al Asheville, NC 28804 ...pacelabimm (828)25L]1]6 ANALYTICAL RESULTS Project'. MW NOVEMBER 2022 Pace Project No.: 92637869 Sample: ASB-02 Lab ID: 92837869003 Collected: 11/2112214:45 Received 11/2112217:10 Mark Water Parameters Results Units Report Limit OF Prepared Analyzed GAS No. Qual Monitoring Well Data Analytical Method: Paces Analytical Services - Charlotte Performed by Pace 1 11/2312210:17 Collected By Mark 1 11/2312210:17 Swann Collected Date 11/21122 1 11/23/22 10:17 Calleded Time 1445 1 1112312210:17 pH 5.90 Std. Units 1 11/23122 10:17 Temperature 15.5 deg 0 1 1V23I2210:17 Static Water Level 8.50 feet 1 1123/22 10:17 Specific Conductance 129.6 umhos/cm 1 11123/2210:17 Oxygen, Dissolved 3.31 mg/L 1 11/23/22 1017 7782-44-7 Total Well Depth 12.0 feet 1 11/23/22 10:17 REDOX -63.0 mV 1 11/23/2210:17 Turbidity 8.24 NTU 1 11/23/22 10:17 Odor None 1 11/2312210:17 Appearance Clear 1 11/23/2210:17 6020 MET ICPMS NC Analytical Method: EPA 6020B Preparation Method: EPA 30D5A Pace Analytical Services - Peachtree Corners, GA Arsenic ND ug/L 5.0 1 12/2312209:16 121231221701 7440-38-2 Chromium NO uglL 50 1 12/2312209:16 12/23/221701 744047-3 Cobalt NO ug/L 1.0 1 12/2312209:18 12/23/221701 744048-4 Iron 364 ug/L 40.0 1 12/2312209:10 12/23rz211:01 7439-89-6 Lead NO ug/L 1.0 1 12123/2209:16 12/23/2217:01 7439-92-1 Manganese ND ug/L 10.0 1 12123/2209:16 12/23/2217:01 7439-96-5 Sodium 11100 ug/L 500 5 12/23/22 09:16 12123/22 1]:0] 7440-23-5 ]4]0 Mercury Analytical Method: EPA 7470A Preparation Method. EPA 7470A Pace Analytical Services - Peachtree Corners, GA Mercury NO ug/L 0.20 1 1210912209:00 12/09/2213:42 ]439-9]-6 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND uglL 0.50 1 11/28/2220:59 71-43-2 Bromobenzene NO ug/L 0.50 1 11/28/22 20:59 1081 Bromochloromethane NO ug/L 050 1 11128/2220:59 ]4-9]-5 Bromodichloromethane NO ug/L 0,50 1 11/28/22 20:59 ]5-2]-4 Brom dorm NO ug/L 0.50 1 11/28/22 20:69 75-25-2 Brom media ne NO ug/L 5.0 1 11/28122 20:59 74-83-9 n-Butylbenzene NO uglL 0.50 1 11/28/2220:59 104-51-8 sec-Butylbenzene ND .,at 0.50 1 11/2812220:69 135-98-8 tert-Butylbenzene NO ug/L 0.50 1 11/28/22 20:59 98-06-6 Carbon tatrm hloride NO ug/L 0.50 1 11128/22 20:59 56-23-5 Chlorobenzene NO upl- 0.50 1 11/28/22 20:59 108-90-7 Chlorcethane NO ug/L 1.0 1 1112812220:69 75-00-3 Chloroform NO all 0,60 1 11/28/22 20:59 67-06-3 Chlommethane NO ug/L 1.0 1 11/28/22 20:59 74-87-3 REPORT OF LABORATORY ANALYSIS Tabasco shall not be repratlncod, except In lull, Date: 12/28/2022 04:07 PM without the written consent of Paces Analytical Services,LLC. Page 10 of 28 aceAnalytical n wuw.peuNaBe.00m ANALYTICAL RESULTS Project: MW NOVEMBER 2022 Pace Project No.: 92637869 Pace Analytical Services, LLC 2225 Riverside Or. Asheville, NO 28804 (82e)254-7176 Sample: ASBA2 Lab ID: 92637869003 Collected 111211221445 Received: 11/21/2217:10 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Dual 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte 2-Chlorotomene NO ug/L 0.50 1 11/28/22 20:59 9549-8 4-Chlomtoluene NO ug1L 0.50 1 11/28/22 20:59 106-434 1,2-Dib10mo-3-chlompmhane ND ug/L 1.0 1 11/28/22 20:59 96-12-8 Dibromochloromethane NO ug/L 0.50 1 11/28122 20:59 124-48-1 1,2-Dibromaethana(EDB) NO ug/L 0.50 1 11/28/22 20:59 106-93-4 Dibromomethane NO ug/L 0.50 1 11/28/22 20:59 74-95-3 1,2-0Ichlorobenzene NO ug/L 0,50 1 11/28/22 20:59 95-50-1 1,3-DIChlorobenzene NO ug/L 0.50 1 11/28/22 20:59 541-73-1 1,4-Dichlorobenzene NO ug/L 0.50 1 11/28/22 20:59 106-46-7 Dichlorodi8uoramethane NO u1 0.50 1 11/28/22 20:59 75-71-8 1,1-Dichloroethane NO ug/L 0.50 1 11/28/22 20:59 75-343 1,2-Dichloroethane NO ug1L 0.50 1 11/28122 20:59 107-06-2 1 1-Dichloroethane NO ug/L 0.50 1 11128/22 20:59 75-354 cis-1,2-Dichloroethene NO ug/L 0.50 1 11128/22 20:59 156-59-2 trans-1,2-Dichlaroethene NO ug/L 0.50 1 11128/22 20:59 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/2812220:59 78-87-5 1,3-0Ichloropropane NO ug/L 0.50 1 11/28/22 20:59 142-28-9 2,2-0Ichloropropane ND ug/L 0.50 1 11/28/22 20:59 594-204 1,1-Dichloropropane NO ug/L 0.50 1 11/28/22 20:59 563-58-6 cis-1,3-Dichlaropropene NO ug/L 0.50 1 11/28/22 20:59 10061-01-5 trans-1,3-Dichloropropene NO ug/L 0.50 1 11/28/2220:59 10061-02-6 Diisopmpyl ether ND ug/L 0.50 1 1112812220:59 108-20-3 Ethylbenzene NO ug/L 0.50 1 11128122 20:59 100-41-4 Hexachlaro-1,3-butadiene NO ug/L 2.0 1 11/28/22 20:59 87-68-3 Isopropytionzene(Cumene) NO ug/L 0.50 1 11128/22 20.59 98-82-8 Methylene Chloride NO ug/L 2.0 1 11/28/22 20:59 75-09-2 Methyl-tert-butyl ether NO ug/L 0.50 1 11/28/22 20:59 1634-044 Naphthalene NO ug/L 2.0 1 11/28/22 20:59 91-20-3 n-Propylbenzene NO ug/L 0.50 1 11/28/22 20:59 103-65-1 Styrene ND ug1L 0.50 1 11/28122 20:59 100-42-5 1,1,1,2-Te rachloamethane NO ug/L 0.50 1 11/28122 20:59 630-20-6 1 1,2,2-Tetrachloroethane NO ug/L 0.50 1 11128/22 20:59 79-34-5 Tetrachloroethene ND ug/L 0.50 1 11/28122 20 59 127-18-4 Toluene NO ug/L 0.50 1 11125122 20:59 108-88-3 1,2,3-Trichlombenzene NO ug/L 2.0 1 11128/22 20:59 87-61-6 1,2,4-Trichlombenzene ND ug/L 2.0 1 11128/22 20:59 120-62-1 1,10-Trichloroethane NO ug/L 050 1 11/28/22 20:59 71-55-6 1,1,2-Trichloroethane NO ug/L 0,50 1 11/28/22 20:59 79-00-5 Trichloraethene NO ug/L 0.50 1 11/28/22 20:59 79-01-6 Trichloro0uoromethane NO ug1L 1.0 1 11/28/22 20:59 75-69-4 1,2,3-Trichloropmpane NO ug/L 0.50 1 11/28/22 20:59 96-18-4 1 2,4-Trimethylbenzene NO uglL 0.50 1 111281222059 95-63-6 1,3,5-Tnanethylbenzene NO ugll- 0.50 1 11/28/22 20:59 108-67-8 Vinyl chloride ND uglL 1 0 1 11/28/22 20:59 75-01-4 m&p-Xylene NO uglL 1.0 1 11128/2220:59 179601-23-1 o-Xylene NO ug/L 0.50 1 11/28122 20:59 95-47-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12128/202204:07 PM without the written consent of Pace Analytical services, LLG Page 11 of 28 aceAnalytical s wwmpa<slahf.4om ANALYTICAL RESULTS Project: MW NOVEMBER 2022 Pace Project No.: 92637869 Pace Analytical Servli LLC 2225 Riverside or. Asheville, NC 28804 (828)254-7195 Sample: ASB.02 Lab ID: 92637869003 Collected: 11/211221445 Received: 11/21/2217:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Oual 6200E MSV Analytical Method: SM 6200B Pace Analytical Service. - Charlotte Surrogates 1,2-Dichloroethane-d4(5) 92 % 70-130 1 11/28/22 20:59 17060-07-0 4-Bromofluorobenzene(5) 99 % 70-130 1 11/28/22 20:59 460-00-4 Toluene-dB(S) 100 % 70-130 1 11/28/22 20:59 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids 62.0 mg/L 25.0 1 11/23/22 18:58 300.E IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.11993 Pace Analytical Services -Asheville Sulfate 3.9 mg/L 1.0 1 11/22/22 20:25 14808-79-8 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.01993 Pace Analytical Services -Asheville Nitrogen, Ammonia NO mg/L 0.10 1 12/01a213:25 7664-41-7 6310B TOC Analytical Method: SM 531OB-2014 Pace Analytical Services - Asheville Total Organic Carbon ND mg/L 1.0 1 11/28/22 21:16 7440-44-0 Ild[s1igYD/Y1rYYlrLiai�g�Sl REPORT OF LABORATORY ANALYSIS This repoa shall not be reproduced, except lM1 full, witM1outthe wriden consent of Pace Analyliral6ervices, LLC. Page 12 of 28 aceAnalyticals wtrw embracer, QUALITY CONTROL DATA Project: MW NOVEMBER 2022 Pace Project No.: 92637869 Pace Analytical Services, LLL 2226 Riverside Cr. Asheville, NC 28804 (828)254-71I6 QC Batch: 745561 Analysis Method: EPA6020B QC Batch Method: EPA3005A Analysis Description: 6020 MET, NC Laboratory: Pace Analytical Services- Peachtree Corners, GA Associated Lab Samples: 92637889001,92637869002, 92637869003 METHOD BLANK: 3878342 Matrix: Water Associated Lab Samples: 92637869001,92637869002,92637869003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Arsenic ug/L NO 5.0 12=12216:19 Chromium ug/L ND 5.0 12123/22 16:19 Cobalt ug/L ND 1.0 1212312216:19 Iron u9/L NO 40.0 12123/M2 16:19 Lead uga- NO 1.0 12123/221619 Manganese ug/L NO 10.0 12/23/221619 Sodium ug/L ND 100 12123/221619 LABORATORY CONTROL SAMPLE: Parameter 3878343 Units Spike Can.. LCS Result LCS % Rau %Rec Limits Qualifiers Arsenic ug/L 100 98.5 99 80-120 Chromium ug/L 100 96.3 96 80-120 Cobalt ug/L 100 95.1 96 80-120 Iron ug/L 1000 991 97 80-120 Lead ug/L 100 101 101 80-120 Manganese ug/L 100 99.1 99 80-120 Sodium ug/L 1000 997 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3878417 3878418 MS MSD 92637869002 Spike Spike MS MSD MS VISO %Rec Parameter Units Result Cone. Come. Result Result %Rec %Rec Limits RED Quiet Arsenic ugA- NO 100 100 97.9 98.2 98 98 75-125 0 Chromium uglL ND 100 100 94.2 93.7 94 93 75-125 1 Cobalt uga- 3.5 100 100 96.3 95.5 93 92 75-125 1 Iron uga- 779 1000 1000 1730 1740 96 96 75-125 0 Lead ug/L NO 100 100 94.4 93.2 94 93 75-125 1 Manganese ug/L 1760 100 100 1850 1900 82 131 75-125 3 Sodium ug/L 28300 1000 1000 29300 30600 107 236 75-125 4 Results Presmled on this page are In the units Indicated by Me"unne column exceptMem an alternate unit Is presenkE to the age m Aa result REPORT OF LABORATORY ANALYSIS TNarepali shall not be ca,mcmaid, except In full, Date: 12/28/2022 04:07 PM wshom the written consent of Pace Analyl'mal Services, LLC, Page 13 of 28 aceAnalytical e Wadvernalbr ORi QUALITY CONTROL DATA Pmjact: MWNOVEMBER2022 Pace Project Na.: 92637869 Pace Analytical services, LLC 2225 Riverside or. Asbevirs, NC 28804 n2p25471T6 UG Balch: 742260 Analysis Method: EPA7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Laboratory: Pace Analytical Services- Peachtree Corners, GA Associated Lab Samples: 92637869001, 92637869002, 92637869003 METHOD BLANK: 3861520 Matrix: Water Associated Lab Samples: 92637869001, 9263]869002, 9263➢869003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury uglL NO 0.20 12109a213:19 LABORATORY CONTROL SAMPLE: 3861521 Spike LCS LCS %Roc Parameter Units Cann Result %Red Limits Qualifiers Mercury uglL 2.5 2.3 91 80-120 MATRIX SPIKE& MATRIX SPIKE DUPLICATE: 3861522 3861523 MS MSD 92637869001 Spike Spike MS MSD MS MSD %Red Parameter Units Result Cone. Conc. Result Result %Red %Rec Limits RPD Qual Mercury uglL NO 2.5 2.5 22 2.2 87 88 75-125 1 Results preanted on this page are In the units Indloated by Me "Un[is" column except Mere an alreform unit IS presumed to Me right or the result REPORT OF LABORATORY ANALYSIS This repot shall not be reproduced, except in lull, Date: 12/28/202204:07PM without the written consent of Pace Analytlwl servicas, llc. Page 14 of 28 aceAnalytical wwu.pdceldEe.min QUALITY CONTROL DATA Project: MW NOVEMBER 2022 Pace Project No.: 92637869 DO Batch: 739372 Analysis Method: SM 6200B QC Batch Method: SM 6200B Analysis Description: 62003 MSV Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92637869001,92637869002,926378690D3 METHOD BLANK: 3847386 Associated Lab Samples: 92637869001,92637869002,92637869003 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed 1,1, 1,2-Tetrachloroethane ug/L NO 0.50 11/28/22 1645 1,1,1-Trichloraethane ug/L NO 0.50 11/28/22 10:45 1 1,2,2-Tetrachloroethane mpL ND 0.50 11/28/22 16:45 1,1,2-Trichloraethane ug/L ND 0.50 11/28/22 16:45 1,1-Dichloroethane ug/L NO 0.50 11/28/22 1645 IL1-Dichloroethene ug/L ND 0.50 11/28122 16:45 1,1-Dichloropropene ug/L ND 0,50 11/28122 16:45 L2,3-Trich1ombenzene uglL NO 2.0 11128/2216:45 1,2,3-Trichloropropane ug/L ND 0.50 11/28/22 16:45 1,2,4-Trichlorobenzene ug/L NO 2.0 11/28122 16:45 1,2,4-Trimethylbenzene ug/L NO 0.50 11/28/22 16:45 1,2-Dibnomo-3-chlonopropane ug/L NO 1.0 11/28/22 16:45 1,2-Dibromaethane(EDB) ug/L NO 0.50 11128/2216:45 1,2-Dichlorobenzene uglL NO 0.50 11/28/22 16:45 1,2-Dichloroethane ug/L NO 0.50 11/28/22 16:45 1,2-Dichlompropane ug/L NO 0.50 11/28/22 1645 1,3,5-Trlmethylbenzene up/L NO 0.60 11/28/22 1645 1,3-Dichlorobenzene ug/L NO 0.50 11/28/22 10:45 1,3 Dichloropropane ug/L NO 0.50 11/28/22 16:45 1A Dichlorobenzene ug/L ND 0.50 11/28/2216:45 2,2-Dlchloropropana ug/L ND 0.60 112812216:45 2-Chloraloluene ug/L NO 0.50 lV2812216:45 4-Chlorotoluene uglL NO 0.50 11128/22 16:45 Benzene uglL NO 0.50 1112812216A5 Bmambenzene uOIL NO 0.50 1112812216:45 BernMahloremethane uglL NO 0.50 11/28/2216 45 Bromodichloromethane uglL NO 0.50 11/28/22 16 45 Bromcfarm ug/L NO 0.50 11/28122 16:45 Bromomethane uglL NO 6.0 111281221645 Carbon tetrachlanide ugll- NO 0.50 11/281221645 Chlorobenzene ug/L NO 0.50 11/28/22 16:45 Chloroethane ug/L NO 1.0 11/28/22 1645 Chloroform uglL ND 0.50 11/28/22 1645 Chloromethane uglL NO 1.0 11/28/22 16:45 cis-1,2-Dichloroethene ug/L NO 0.50 11/28/22 16:45 cis-1,3-Dichloropropene ug/L ND 0.60 11/28/22 16:45 Dibromochleromethane ug/L ND 0.50 11/28/22 16:45 Dibromomethane ug/L NO 0.50 11/28122 16:45 Dichlaradifluoromethane ug/L NO 0.50 11/28/22 16:45 Diisopropyl ether ug/L ND 0.50 11/28/22 16:45 Qualifiers Pace Analytical Services, LLC 2225 RiaMside or. Asheville, NC 28804 (e2e)2544176 Reaulta preemtod on ih la page are In me units Indicated by Ne" Units " column except wM1ere an share ate on It Is presented to Me core of the result REPORT OF LABORATORY ANALYSIS Thiftench than not be reprotluc.d, except In full, Date: 12/28/2022 04:07 PM wilhout the written consent of Pace Analytical Services,LLC. Page 15 of 28 Pace Analytical Services, LLC aceAnalytical ® R' NC O4 ASM1eville.NC 2s9a4 www.peuleEs.coRr (628)254-71 ]6 QUALITY CONTROL DATA Project: MW NOVEMBER 2022 Paw Project No.: 92637869 METHOD BLANK: 3847386 Matrix: Water As ... later] Lab Samples: 9263]869001,9263]869002,92637869003 Blank Reaching Parameter Units Result Limit Analyzed Qualifiers Ethylbenzene ug/L ND 0.50 11/28/2216:45 Hexachlom-1,3-butadiene ug/L ND 2.0 11/28122 16:45 Isopropylbenzene(Cumene) ug/L ND 0.50 lV2812216:45 m&p-Xylene ug/L ND 1.0 11128/22 16:45 Methyl-tert-butyl ether ug/L ND 0.50 11/28122 16:45 Methylene Chloride ug/L ND 2.0 11/28/22 16:45 n-Butylbenzene ug1L ND 0.50 11/28/22 1645 n-Propylbenzene ug1L ND 0.50 11/28/22 1645 Naphthalene To& ND 2.0 11/28/2216:45 0-Xylene ug/L ND 0.50 11/28/22 16A5 sec-Butylbenzene ug/L ND 0.50 11/28/2216:45 Styrene ug/L NO 0.50 11128122 16:45 terFButylbenzene ugh- NO 0.50 11/28/22 16:45 Tetrachlomethene ug/L ND 0.50 1112812216:45 Toluene ug/L ND 0.50 11128/2216:45 trans-1,2-Dichloroethene ug1L ND 0.50 1112812216:45 trans-1,3-Dichloropropene ug1L ND 0.50 11/28/22 16:45 Trichlomethene ug/L ND 0.50 11/28/22 16:45 TrichlorOfluoromethane ug/L ND 1.0 11/28122 16:45 Vinyl chloride ug/L ND 1.0 11128/22 16A5 1,2-Dichloroethane-cif(8) % 91 70-130 11128122 16 45 4-BromoOuorobenzene(5) % 99 70-130 1112812216:45 Toluene-08 (S) % 101 70-130 11128/2216:45 IABORATORY CONTROL SAMPLE: Parameter 3847387 Units Spike Cont. LCS Result LCS % Rec %Rec Limits Qualifiers 1,10,2-Tetrachloroethane ug/L 50 49.0 98 60-140 1,1,1-Tdchloroethane ug/L 50 47.4 95 60-140 1,1,2,2-Tetrachloroethane ug/L 50 45.7 91 60-140 1,1,2-Trichloroethane uglL 50 48.0 96 60-140 1,1-Dichloroethane ug/L 50 43.8 88 60-140 1,1-Dichloraethene ug/L 50 493 99 60-140 IJ-Dichlarapropene ug/L 50 49.3 99 60-140 1 ,2,34rlchlorobenzene uglL 50 52.3 105 60-140 1,2,3-Trichloropropane ug/L 50 43.6 87 60-140 1,2,4-Trich1orobemzene ug/L 50 51.7 103 60-140 1,2,4-Trimethylbenzene ug/L 50 47.1 94 60-140 1,2-Dlbromo-3-chloropmpane ug/L 50 48.5 97 60-140 1,2-Dibmmoethane(EDS) ug/L 50 49.3 99 60-140 1,2-Dlchlombenzene ug/L 50 48.5 97 60-140 1,2-Dichloroethane ug/L 50 43.3 87 60-140 1,2-Dichlompropane ug/L 50 47.4 95 60-140 1,3,5-Trimethylbenzene uyl- 50 46.8 94 60-140 scoria pmamtetl an thIt pane an In the units Indicated by to Unlre column except xTere an alterna@unit is presented to Ne right of the result REPORT OF LABORATORY ANALYSIS This report seen not be reproduced, except In lull, Date: 12/28/2022 0497 PM wiNOUt the written consent of Pace Analytical Services,LLC. Page 16 of 28 aceAnalytical® Isee pecoubmtMe QUALITY CONTROL DATA Projed: MWNCVEMBER2022 Pace Project No.: 92637869 Pace Analytical Sam Ices, LLC 2225 amersiae or. Asheville, NC 28804 (928)2547196 LABORATORY CONTROL SAMPLE: Parameter 3847387 Units Spike Cane. LCS Result LCS % Rec % Rec Limits Qualifiers 1,3-Dichlorobenzene ug/L 50 48.6 97 60-140 1,3-0ichloropropane ug/L 50 46.8 94 60-140 1,4-Dichlorobenzene ug/L 50 46.9 94 60-140 2,2-Dlchlompropane ug/L 50 44.8 90 60-140 2-Chlorotoluene ug/L 50 45.5 91 60-140 4-Chlorotoluene ug/L 50 45.2 90 60-140 Benzene uglL 50 45.6 91 60-140 Brorahenzene ug1L 50 49.4 99 60-140 Bromochloromethane ug/L 50 50.3 101 60-140 Bromodichloromethane ug/L 50 46.4 93 60-140 Bromnic. ug/L 50 49.4 99 60-140 Bromomelhane ug/L 50 46.4 93 60-140 Carbon tetrachloride ugh- 50 45.4 91 60-140 Chlarobenzene ug/L 50 47.8 96 60-140 Chloroethane ug/L 50 50.7 101 60-140 Chlaroform ug/L 50 44.1 88 60-140 Chlaromethrne ug/L 50 51.6 103 60-140 cis-1,2-Dlchloroethene ug/L 50 43.5 87 60-140 cis-1,3-Dichloropropene ug/L 50 46.9 94 60-140 Dibrcmochloromethane ug/L 50 45.8 98 60-140 Dibromomethane ug/L 50 53.7 107 60-140 Dichloradifluaromethanl uglL 50 66 9 114 60-140 DllA.pinpyl ether uglL 50 43.4 87 60-140 Etylbenzene uglL 50 45.9 92 60-140 Hexachlom-1,3-butadlene uglL 50 51.0 103 60-140 Isopropylbenzene(Cunt ug/L 50 46.3 93 60-140 all Xylene ug/L 100 91.7 92 60-140 Methyl-tert-butyl ether ug/L 50 47.8 96 60-140 Methylene Chloride ug/L 50 41.5 83 60-140 n-Butylbenzene ug/L 50 46.3 93 60-140 n-Propylbenzene ug/L 50 45.2 90 60-140 Naphthalene ug/L 50 53.5 107 60-140 o-Xylene ugh- 50 47.4 95 60-140 sec-Butylbenzene ug/L 50 45.3 91 60-140 Styrene ug/L 50 48.3 97 60-140 tert-Butylbenzene uglL 50 40.1 80 60-140 Tetrachleethene ugli- 50 50.7 101 60-140 Toluene uglL 50 44.6 89 60-140 trans-1,2-Dichloroethene ug/L 50 46.3 93 60-140 trans-1,3-0ichloropropane ug/L 50 46.4 93 60-140 Trichloroethene uglL 50 51.5 103 60-140 Trichlorotluoromethane ug/L 50 42.7 85 60-140 Vinyl chloride uglL 50 50.8 102 60-140 1,2-Dichloroelhane-d4(S) % 92 70-130 4-Bramoflucrobenzene(S) % 97 70-130 Toluene-de(S) % 97 70-130 Results presented on this page an In the on Its Ind tested by Me"Wits" column exoeewhere on alternate unit is pros anted to Me right of the man It REPORT OF LABORATORY ANALYSIS This reach shall not be reproduced, except in full. Date: 1212812022 04:07 PM without the wriaen wnsentof Pace Analytiai Services,LLC. Page 17 of 28 aceAnalytical Wessermishb9Fem QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside or. Asheville, NO 268N (828)254-7176 Project: MWNCVEMBER2022 Pace Project No.: 92637869 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3848920 3848921 MS MSD 92638143002 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc, Conc. Result Result %Rec %Rec Limits RED Dual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 24.6 25.2 123 126 60-140 2 1,1,1-1-achlorcethane ug/L ND 20 20 24.1 24.4 120 122 60-140 1 1, 1,2,2-Tetrachloroethane ug/L NO 20 20 23.3 23.8 117 119 80-140 2 1,1,2-Trichloroelhane upi- ND 20 20 24.2 24.9 121 125 60-140 3 1,1-Dichloroethane ug/L ND 20 20 22.4 22.9 112 115 60-140 2 1,1-Dichloroethene m/L NO 20 20 25.6 26.1 128 131 60-140 2 1,1-Dichloropropene ug1L NO 20 20 25.1 25.6 125 128 60-140 2 1,2,3-Trichlorobenzene ug/L NO 20 20 21.3 26.8 136 134 60-140 2 1,2,3-Trichloropropane ug/L ND 20 20 22.1 22.4 110 112 60-140 1 1,2,11-Trichlorobenzene ug/L ND 20 20 25.9 25.2 129 126 60-140 3 1,2,4-Trimethylbenzene ug/L ND 20 20 24.4 24.0 122 120 60-140 2 12-Dibromc-3-chloropropane ug/L ND 20 20 24.5 24.4 122 122 60-140 0 1,2-Dibromaethane (EDB) ug/L ND 20 20 25.2 25.2 126 126 60-140 0 1,2-Dlchlorohenzene ug& ND 20 20 25.0 25.0 125 125 60-140 0 IX-Dichloroethane, ug/L ND 20 20 22.2 22.7 111 114 60-140 2 1,2-Dichloropropane ug/L NO 20 20 24.4 24.7 122 124 60-140 1 1,3,5-Trimethylbenzene uglL NO 20 20 24.1 23.7 120 118 60-140 2 1,3-Dichlorobenzene ug/L NO 20 20 25.2 24.5 126 122 60-140 3 1,3-Dichloropropane ug/L ND 20 20 23.6 24.0 116 120 60-140 2 1,4-Dichlorobenzene ug/L ND 20 20 241 23.7 121 118 60-140 2 2,2-Dichloropropane uglL NO 20 20 22 9 23.3 114 117 60-140 2 2-Chloratoluene ug/L NO 20 20 23.6 23.3 118 116 60-140 1 4-Chloratoluene ug/L ND 20 20 23.3 23.1 117 116 60-140 1 Benzene ug/L ND 20 20 24.2 24.3 121 121 60-140 0 Bromobenzene uglL ND 20 20 25.9 25.5 129 128 60-140 1 Bromochlaromethane ug/L ND 20 20 25.8 26.2 129 131 60-140 1 Bromodlchimomethane ug/L ND 20 20 23.2 23.8 116 119 60-140 3 Bromoform uglL ND 20 20 23.7 24.3 119 121 60-140 2 Bromomethane ug/L NO 20 20 24.1 24.7 121 123 60-140 2 Carbon tetrachloride ug/L NO 20 20 23.3 23.0 117 118 60-140 1 Chlorobenzene ug/L ND 20 20 24.9 25.3 124 126 60-140 2 Chloroelhane ug/L ND 20 20 30.2 30.7 151 154 60-140 2 MI Chloroform ug/L ND 20 20 21.8 22.4 109 112 60-140 3 Chlommethane ug/L NO 20 20 26.3 26.9 132 135 60-140 2 cis-1,2-Dionomethene ug/L NO 20 20 220 22.6 110 113 60-140 3 cis-1,3-Dichloropropene ug/L ND 20 20 23.5 23.8 117 119 60-140 1 Dibromochlaromelhane ug/L ND 20 20 24A 24.4 121 122 60-140 1 Dibromomethane ug/L ND 20 20 27.4 27.8 137 139 60-140 1 Dichlorodiflumomethane u9/L ND 20 20 30.0 30.4 150 152 80-140 1 M1 Diisopo pyl ether ug/L ND 20 20 21.7 22.2 109 Ill 60-140 2 Ethylbenzene ug/L NO 20 20 23.8 24.1 119 120 60-140 1 Hexachlorc-1,3-butadiens ug/L ND 20 20 28.1 24.7 131 124 60-140 6 Isopropylbenzene(Cummul uglL ND 20 20 24.0 24.0 120 120 60-140 0 all -Xylene ug/L NO 40 40 47.9 48.E 120 122 60-140 2 Methyl-lerl-butyl ether uglL ND 20 20 23.9 24.2 119 121 60-140 1 Methylene Chloride ugh. ND 20 20 18.7 19.2 93 96 60-140 3 Results pre6mted on this page are In the units Indicated by del colummi except%vimm an alternate unit Is presenbdta Me m u lbe result REPORT OF LABORATORY ANALYSIS This report shall not be, reproduced, except In full. Date: 12/281202204:07PM without the written consent of Pace Analytical services,LLC. Page 18 of 28 aceAnalyticale ,mospsnnea.wm QUALITY CONTROL DATA Pace Analytical Services, LLL 2225 Rlversim, Dr. Asheville, NC 26e04 (628)254-]1]6 Project: MW NOVEMBER 2022 Pace Project No.: 92637869 MATRIX SPIKE& MATRIX SPIKE DUPLICATE: 3848920 3848921 MS MSD 92636143002 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cone. Can.. Result Result %Rec %Rec Limits RPD Dual n-Butylbenzene ug/L NO 20 20 23.1 22.2 116 111 60-140 4 n-Prapylbenzene tai ND 20 20 23 4 22.9 117 115 60-140 2 Naphthalene ug/L ND 20 20 27.7 27.4 139 137 60-140 1 a-Xylene ug/L NO 20 20 24.6 25.1 123 125 60-140 2 sec-Butylbenzene ug/L ND 20 20 23.4 22.9 117 115 60-140 2 Styrene ug/L NO 20 20 24.7 25.0 124 125 60-140 1 ted-Butylbenzene ui ND 20 20 20.9 20.6 105 103 60-140 1 Tehachlomethene uglL NO 20 20 26.3 26.2 131 131 60-140 0 Toluene ug/L ND 20 20 23.8 24.0 119 120 60-140 1 trans-1,2-Dichloroethene uglL ND 20 20 23.6 24.1 118 121 60-140 2 trans-1,3-Dichloropropene ug/L ND 20 20 23 2 23.6 116 118 60-140 2 Trichloroethene ug/L ND 20 20 26S 27.4 134 137 60-140 2 Trichloaftecromethan, ug/L ND 20 20 23.4 24.1 117 120 60-140 3 Vinyl chlo,id. hall- ND 20 20 26.2 27.0 131 135 60-140 3 1,2-Dichloroethanei(S) % 87 86 70-130 4-BromoOuorobenzene(S) % 95 97 70-130 Toluenei(S) % 96 96 70-130 Results preauite4 on this page an In the units Ind icated by Me" ends column except where an alternate unit Is presented to the 09M of th a recall, REPORT OF LABORATORY ANALYSIS This start shall net be rap.dn,m , Mxcept in lNl, Date: 12/28/2022 0407 PM without the written consent of Pace Analytical Services, L-C. Page 19 of 28 A aceAnalytical a Moo'cral.bet. QUALITY CONTROL DATA Project: MW NOVEMBER 2022 Pace Project No.: 92637869 Pace Analytic at Services, LLL 2325 Riverside Dr Asheville, NC 28804 (828)254-71I6 OC Balch: 739252 Analysis Method: SM 254OC-2015 OC Balch Method: SM 25400-2015 Analysis Description: 2540C Total Dissolved Solids Laboratory: Pace Analytical Sewage - Asheville Associated Lab Samples: 92637869001,92637869002,92637869003 METHOD BLANK: 3847109 Matrix: Water Associated Lab Samples: 92837869001,9263]869002,9263]869003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Dissolved Solids mg/L NO 25.0 11/23/22 18:57 LABORATORY CONTROL SAMPLE: 3847110 Spike LCS LCS %Rise Parameter Units Cone. Result %Rec Unable Callipers Total Dissolved Solids mg/L 250 250 100 90-110 SAMPLE DUPLICATE: 3847137 92637869001 Cup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L NO NO SAMPLE DUPLICATE: 3847138 92637869002 DRIP Parameter Units Result Result RED Qualifiers Total Dissolved Solids mg/L 239 235 2 Results presmled on this page are In the units Indicated by to aults'column except Mere an alterna@unit Is presented to the Ham of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced except in run, Date: 12/28/2022 04:07 PM without the values .,sent of Pace Analytical Services, L-C. Page 20 of 28 aceAnalytical www.paeelabexem QUALITY CONTROL DATA Pace Analytical Servlces, LL6 2225 Rivarsitle 0r. Asheville, NC 28804 (828)254-]1]6 Project: MW NOVEMBER 2022 Pace Project No.: 92637869 QC Batch: 738688 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method'. EPA 300.E Rev 2.11993 Analysis 0.... jlion: 300.0 IC Anions Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92637869001, 9263]869002, 9263T869003 METHOD BLANK: 3844213 Matrix: Water Associated Lab Samples: 92637669001, 9263T869002, 9263]869003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate cri NO 1,0 11/22/22 15:44 LABORATORY CONTROL SAMPLE: 3844214 Spike LCS LCS %Rec Parameter Units Con.. Result % Rao Limits Qualifiers Sulfate mg/L 50 49.4 99 90-110 MATRIX SPIKE& MATRIX SPIKE DUPLICATE: 3844215 3844216 MS MSD 92637785001 Spike Spike MS MSD MS MSD A Rec Parameter Units Result Conc. Cone. Result Result %Rao %Rec Limits RPD Dust Sulfate mg/L 1.3 50 50 50.6 51.0 99 99 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3844217 3844218 MS MSD 92637869002 Spike Spike MIS MSD MS MSD %Rec Parameter Units Result Cann Conc. Result Result % Re. % Rao Limits RPD Qual Sulfate mUIL TS 5D 50 57.3 69.8 100 104 90-110 4 Results preemted on th Is page are In the arts Indicated byte UnIts" column exceptxTere an alternate REPORT OF LABORATORY ANALYSIS This report shell not be repmdvc im, except In full, Date: 12128/202204:07 PM without the written consent of Pace Analytical Services,I Page 21 of 28 aceAnalytical a wu^x.psni'marm QUALITY CONTROL DATA Pace Analytical generous, LLC 2225 Riverside or. Ashoulle, NO 28804 Ri 7176 Project: MW NOVEMBER 2022 Pace Project No.: 92637869 QC Batch: 740395 Analysis Method: EPA 350.1 Rev 2.01993 OC Batch Method EPA 35D.1, Rev 2.01993 Analysis Description: 350.1 Ammonia Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92637869001, 9263]869002, 92637869003 METHOD BLANK'. 3851988 Matrix: Water Associated Lab Samples: 92637869001, 92637869002, 92631869003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Ammonia mg/L ND 0.10 12/01=12:57 LABORATORY CONTROL SAMPLE: 3851989 Spike LCS LCS %Rec Parameter Units Cant. Result %Rec Limits Qualifiers Nitrogen, Ammonia ni 5 5.0 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3851990 3851991 MS MSD 92637782002 Spike Spike ME MSD MS MSD %Rec Parameter Units Result Cant. Conc Result Result %Rec %Rec Limits RPD Qual Nitrogen, Ammonia all 0.24 5 5 5.5 5.5 105 105 90-110 0 MATRIX SPIKE& MATRIX SPIKE DUPLICATE: 3851992 3851993 MS MSD 92637786002 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cont. Cann Result Result %Rec %Rec Limits RPD Qual Nitrogen, Ammonia mg1L 3.3 5 5 8.6 8.5 106 106 90-110 0 Resul6 preamte6 on this page are In the on Its Ind lcaled by MeUrge mlumo exceptxLere an allernah unit Is presented to the Ham or the result REPORT OF LABORATORY ANALYSIS This revolt shall not be repmaucea, except In full, Date: 121281202204:07 PM withom the wrote, co,ce,t of Pace Analytical Bevil LLC. Page 22 of 28 aceAnalytical' wuwparolabLpcm QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)250.1176 Project'. MW NOVEMBER 2022 Pace Project No.: 92637869 QC Batch: 739521 Analysis Method: SM 531 OB-2014 QC Batch Method: SM 631 OB-2014 Analysis Description: 5310B TOC Laboratory: Pace Analytical Services -Ashei Associated Lab Samples: 92837869001, 92637869002,92637869003 METHOD BLANK: 3848016 Matrix: Water Associated Lab Samples: 92637869001, 92639669002, 9263]869003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Organic Carbon ni NO 1.0 1112812214:18 LABORATORY CONTROL SAMPLE: 3848017 Spike LCS LCS %Rec Parameter Units Can.. Result %Rec Limits Qualifiers Total Organic Carbon all 25 24.7 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3848018 3848019 MS MSD 92637828001 Spike Spike MS MSD MS VISO %Roo Parameter Units Result Coal Conc. Result Result %Rec %Rec Until RPD Qual Total Organic Carbon mg/L ND 25 25 25.2 25.7 100 102 90-110 2 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3848020 3848021 MS MSD 92637822004 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Dual Total Organic Carbon mg/L 2.3 25 25 28.7 28.7 106 105 90-110 0 Reeulte preimted an MIS page are In the units Ind issued by Ne"Uses 'column except waste an alternate unit Is presen el to the tlpM of Me vault REPORT OF LABORATORY ANALYSIS The meet.ball not be reproduced, except In full, Date: 12/281202204:07 PM without the written consent of Pace Analytical Services,LLC. Page 23 of 28 aceAnalytical e www.pereall QUALIFIERS Project: MW NOVEMBER 2022 Pace Project No.: 92637669 DEFINITIONS Pace Analytical Services, LLC 2225 Riverside D, Asheville, NC 28804 (B2b264-)17e DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTO -Too Numerous To Count d - Estimated concentration above the adjusted method detection limit and below the adjusted repor ing limit. Ml-Adjusted Method Detection Limit. POL- Practical Ouantitation Limit. RL- Repoding Limit -The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyle In a specific matrix. S- Surrogate 1,2-Dlpheny1firydrezine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RAPID values. -CS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP- Sample Duplicate RPD - Relative Percent Difference INC - Not Calculable. SG - Silica Gel - CleanUp U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate fort Chlomethylvinyl ether. A separate vial preserved! to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrelein and Acrylonitrile by EPA Method 8260. N-Nitmsodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total' may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TIN -The NELAC Institute. ANALYTE QUALIFIERS Mt Matrix spike recovery exceeded OC limits. Batch accepted based on laboratory control sample (LCS)recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reprotleceQ except in full. Date: 12/28/202231 PM without the written consent of Pace Analytical Services,LLC. Page 24 of 28 aceAnalyical ses, cautbache QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, LLC 222E Riverside or. Asheville, NC 28804 (828)2547176 Project: Pace Project No.: MW NOVEMBER 2022 92637869 Analytical Lab ID Sample ID QC Batch Method QC Balch Analytical Method Batch 92637869001 Q08V2 92637869002 ASBA1 92637869003 ASB-02 92637869001 Q88V2 EPA3005A 745581 EPA6020B 745722 92637869002 ASB-01 EPA3005A 745581 EPA6020B 745722 92637869003 ASB-02 EPA3005A 745561 EPA6020B 745722 92637869001 Q88V2 EPA7470A 742260 EPA7470A 742277 92637869002 ASB-01 EPA7470A 742260 EPA7470A 742277 92637869003 ASB-02 EPA 7470A 742260 EPA7470A 742277 92637869001 Q88V2 SM 6200B 739372 92637869002 ASB-01 SM 6200B 739372 92637869003 ASB-02 SM 6200B 739372 92637869001 Q88V2 SM 2540C-2015 739252 92637869002 ASB-01 SM 2540C-2015 739252 92637869003 ASB�02 SM 2540C-2015 739252 92637869001 QB8V2 EPA 300.0 Rev 2.11993 738688 92637869002 ASBl EPA 300.0 Rev 2.11993 738688 92637869003 ASBA2 EPA 300.0 Rev 2.11993 73B68B 92637869001 Q88V2 EPA 350.1 Rev 2.01993 740395 92637869002 ASSA1 EPA 350.1 Rev 2.01993 740395 92637869003 ASS-02 EPA 350.1 Rev 2.01993 740395 92637869001 Q88V2 SM 531OB-2014 739521 92637869002 All SM 5310B-2014 739521 92637869003 ASB-02 SM 5310B-2014 739521 REPORT OF LABORATORY ANALYSIS This report shell not be mpm6uced, except In full, Bate: 12/2812022 04:07 PM without the written consent of Pace Analytical Services, LLC, Page 25 of 28 DC#_Titio: ENV-FRM-HUN1.0083 v01 _Sample Condition Upon Receipt' ace' a. roxu Effective Date: B5/12/2022 Laboratory receiving samples, Asheville Eden❑ Greenwood ❑ Huntersville ❑ Raleigh[) Mech= I«vtllen Atlanta❑ Kernersville❑ • • Client Name: ( WO# a673� . 92 869 Project q:I �c�u;d.S nElu Courier; ❑red ex ❑urs ❑uses pcueer El Commercial ace ❑Other._ 92637889 I Custody Seal Present? Dyes O Seals Intact? ❑Yes (QNq 1 'G,_ ,fit Dale/Initials Perzan Examinlitg Consents, I _1.1J Packing Material: ❑Bubble Wrap Potable Bags ❑None ❑ Other Biological Tissue Frozen? Thermometer: / '} TTT"' ❑Yes ON. ❑N/A 0IR.GunID: t�/I TYpcaflce: Wet ❑clue []None' Correction Factor: CoolerTemp: "'" Add/Subtractl°CI TO Temp should be above freezing to WC []Samples out of temp a Bolo. Samples an Ice, <.mIng Presess. Cooler Temp Correctdd(eC): 3 -Ci has begun. USDA Regulated Soil (ILJ N/A, water,eample). Did samples onglnate In a quarantine. Within the United States; CA, NY, RISC hid samples originate from a foreign source(internationally, ` Comrnenss(DlscrvPanry: Chain of Custody Present? es ONo QN/A 1. Samples Arrived within Hod Time? es No - N A 2. Short Held Time Aea1ysls(02 Iv.)? be, ON/A 3. Rush Turn Around TIM a Requested? vas ONO ON/A A Sufficient Volume? ffYO, Nn ONJA S. Correct Contedl Used? -Pace Containers Used? es ONo EINO ON/a N/A B. Containers Intact? QNa: N/A'. ?. Dissolved analysis:. Samples Field Filtered? []Yes o IN/A gl Sample Labels Match CCC? dntludes.Date(Time(ID/Analysis .Maids '(RYes ((°� N,, ON/A B. fleadspace In VDA Vials i>Rgmmlt Y¢s a ❑N/A 10. Trip Blank Present? Trip Blank Cu,omly Seals Present? ❑Yez ❑Yea v ❑N[A N/A 1L COMMENTS/SAMPLE DISCREPANCY I.Ot ID Of Spin containers: CLIENT NOTIFICATION/RESOLUTION Person con(actedf Project Manager SCURF Review: Project Manager SRFRevieW: Qualtrax ID:. 69614 Daie/nme Date: Date: Page 26 of 28 Page 1. of:2r w w r �,,. 4g d .. � n b 3 q OY q o co 3 F� aa`g�Yy�A�n Y $ °a aP Bl�MPLE tYI!F (M'OMO UCOM}� If 5 4 g 3 � 9 FIPLETEM1IPRiCOLLECi ON' ' '1, � oFEpNT�lN6N6 B NCI y S W. NNSEOa * w q L— M.M., 8 g YINX % 8 % x m y x x rt='.06010 Z74'7/ a . x x X .1 �y 9 {, YJ iEM1IPinC ftov tluel Cldal (YIN) N NaJ mt lw N IVM �. R 9 II(TfioakO lmaCl (Yol P Page 27 of 28 zpa7ce, "Check mark: top half of box IfrPH..and/or dechlorination Project:# is verified and within the acceptance range for preservation samples... EA[epthms'VOA, colderm,T000f and Grease,DRO/Bo15(water) DOC, tLHg **Bottom half of boa 1,to list number of bottles *"Check all unpreserved.Nitrates for chlorine PM: UP Our. Oat.: 12/07/22 CLIENT: 93-0avidsonit E E G E q E It 9 E E a E E In a E a K E E E E `0 E 4 E 0 E E n •01. •°1• E P a E E a e E s I_ 1 I l J 3 4 5 6 0 9 tD u PH Adjustment Log for Preserved Samples Sample lD Type of Preservative PH upon retelpt Oate peeservaalodaJJmtad Time preaerv.1. adjosted AmaGntof PaaerealIva .added' LORM: Note: whenever mere s a murepa., wneco:a na: u: yu: mm., w^........ ,^•••v.•............. _......... __ __..... _._... Onnorhold, lntortert preservallea,oul-1 W-11p,ln[orrect cont-nno-) Quallrax Document ID: 70677 Page 2 of 2 Page 28 of 28 pxumentNumbu:P-CAI4PLD�aJ1+ev.et Name and Affiliation(Sampler(s): k ;Date: Data Shed Nameand A(dliatian (Inspector): ~'�S4 ll d f tion Weli N:__M l' Q d?✓7- Well LackedO) Well Diametcx: �: '1. q Comtmctim: (if- feel/StamlessSteel) ._. Total WellDeptlt. �d.W Jt MuitlPactor:-/6S PIRa&aa/t21%,atazv.dl Static Wateitxvel .,Ei.@ Ca'singVolume: Jdf gall°ca . Height of WaterColumn: CaL 3 Volumes: 3_ayZ'�! gaU°ds . Pmn intakP(N;o� - Y ge bdornrnl=on I, ! }!-. Staet_ )U=J� Pinuh'.N�O PuxgxIUte'.---rhv v/-:...� b,✓ Total VolumePucged. �7 .(`.O_, (Bail Nuging Method l''i_f��—:-- 5amnlu. teInfofmation Date Collected, �/ JA/,M__ Time Collecti( 1p ) �,n,J e✓I ��b SamplivgEquipmeatUsed: f9 a,.iJ a)..� -. hmteumentN:_ istt qdred �- BoRleType li'esex'VatJnll V;✓ Pn; `�JJW 9JYl Field bTeasmem- tdlOU e t'ons//4-.r ¢ Tur6¢ht Sample Temp Tune _'-1�--- Y- y'r Pe2+rag/L:_ _—Tune-_- DissOxy(mg/L)._—Tune-- (� J / µh Res, C'J (mg/LW9/L):_- SpecificCond(n5): Tan n C T>se�— S , F Lu'Y Odox: V-0 L Sample pft (s.a ): ) Time _ ) tf'.i A eazance:�La.2 Tnne ._.._...... ReDox(mV): itf __Tune:._ Pp--Txme_.-- ReDox (FH value):YSI ProPIVs+200mV l=' -Othe': General/WeathesObsexvatim+s_. —.- Temp — Al /s (°•� Wind a, (MP') (suxmy/cloudy/eauty) '4,Q-.. Date: /�.f/. ✓y_- -----� Sampler Signature '�.------- —__� LT�t`idity �ft) Spec. Re➢ax nmavedTime Temp DL9s Oxy CondP,(su.)Levpurged(m6/L) (u5) }' DI U ro sV) ) (ga5ans/) r 1I Document Name: Document Issued July 28,2016 1 dArralyNcai" Field Data 9lzeet Document Number; Issueing Authority:: F CARTEED-001,Mv.01 Pace Huntersville Quality'. Office I it:}) -ram s Client: 0/ t i Location; Project: Well ID:-G % C/ Stabilization Test ®®®®®®®®®® • I VA 0 G 1 Y� u pommentN Aieid daln5h¢et Pa a tai_ iw ro h� �iYehe D tN Ukv HCAh FY.O.uor iM er I I Wagnuuwnryr 09t Field Data 53ieet , iV t.f... �(<alft- reolec(.N: Client:.�li_-,- .----....-Lacnfionf Nahteand Affiliation (Sa(nplel•(s) %t'i/;S f�Js Naxneand-Afladon W'llI fo5utahon WeIIIU. <F1 JR u L-- — WeRlbelwd' /NO) / Construction. -(I Steel/Stniiiless.$ieeY) _ WEADiwnetor •%- Total Well Depth: /`T'3 `Y0 ft Mom Pactox'l_, t`2kadlaf/ll)lx314 141 ' State Water Level.•' 7"E 1t Casing Volume. 6�diia - %lift Qeight of Water Colurfsn',��� Cut d Volumes: �t 0 �� gallau - Pwnp Intake•_)_) -�Yt -� _. Date Purged:_/-�' 7=Start, ILI )`� Fmish- l �aIurge ltnte;.�. �. Puiging Method• tn,b --7otalValuifte Paged: Szmph�informatinn g- Date Collected }I/_J frrr Tune Collrew (aixl/pm) 4_' j Sampling Egwpment[Jsrd:. �en ,�f �;__ lnatrumPinib NS,.:'—/("sFFnG%!GJ-Y'f' pBsttle l}/pe PFuaeC7ation alYels Required . V_Af � � L .�_ I (tq"r, N! . Field M t¢ uienta/Observahons 3i Tnne�'i Sant le'femp( J.' p _Turbidity(nta) - Dlss Ozy (mg/L) �L%+-�__ Tnne S Y s pe 2+tii6/L _ Time Specific Cond (us): j, �- Time..)•," T"j- lies. Cl (m6/L�(µg/L).__,__�Tmte c:...;..i,, a_n�'„ ,. �. A 5 T7m2: � s 4-¢=0dor:__.�✓Y^s c Time: _/ —�- ReUox (mV): ✓/iw G.. .._.�Tistte: ReDox (alvalhe):ySTproPlus+200mV— General/VVeatlrer .. _(surety/cldudy/rainy) TeirLP' •�.6m Wind � _(mph). Samplor•Signatuee��--=—Da[e:.1_� _� .. � _... Time Temp. Diss Ozy. Purged CC) (mg/L) fo ReDaz Turbidity volwne WateYhntdved other , (rcv) I (nm) Peellnns/mis) level (ft) DocumentNa..er Document lu ed ry0vember 27,2018 of Pieldnut.sheet - Page - Document Number. luue AuLLiorh Y P-CAR-FLD.001.rev.02 :i, Pace Fluete.,rille Quality Office Client:. Location: V' +-t ° n ti p-. any Project: Well ID: Reviewed Date and Stabilization TeSt 1Nall Diameter .l3vlttplieafian Faatar"" 1. 0.0409 .2 0:0413 ' i.625 0.Y080 0.1630 0.3670 4 0.6530 -- 6 Y.+tfi ;0 8: 2.6100 Tinie ;Purged Temp. (IC) Dies O%y. (rng/L) Spec. Cond. (US)l pH (s.u) ReOox (mV). Turbidity ntu ) Volume Removed )g allons/oils) circle one Water level ((t) Other ,�— L.7 I�r0 tic. a- 0,2.: 0 ?'7 4;t1,6 J 5a - 549 J.. 7. I Qv� ,'.�L 5?,� rye 15.E -h L10 �0ew au).w 55. - 'l>,'0 l7 s.J Ih.? 1 1100 Pry Iw.J � > D. >,DS,a x G s, .>. ��,Sv e _/2&,> 5 !'7 I.e, 4-9 da J'.f 1114- 15.I t ?,f- k D,3 S.Z> x, j �-7 S'? Jo` �, r ytiJ �, I.dJ 359. J•9:i -C- 4. 9 �Lw-,o _ 395, y Sr41c IJ't;S3 '%: a.� '>, ri: o.J0 .�6Ssl, il, Dot m IN .Tielddata 6lw t Po_ - n f /- .p.1°3A(IdlyNL81 Issuirtga zFo�lty PazeH. /� Oesument Nu 1e'F-(.AR-FLD-001-Office L Field DataSheet (M"t:_.1�� __Location: •1G Name and Affiliation (6ampler(s) �. NeldDawShwtRevI— Nameand Affiliation (Inspect(r):_ --��`---- By: Date: Well information ,�...®—m Wallfl) >� '0 d- WellLoaked NO) _ Well Diameter �' / Constitution, (P C feel/Stainless Steel) Totat Well Depth 0 J_ ,ft Mliltt PaCfW` ("0.sad;ns/12)tr319xz99] Static Water Level: T,o_� ft CasingVVlumer-Q:u > gallons Ca1.3Volumes:. "110 Height of WaterColumnr_"_t .gallons Pump Intake it Pmxe lnPoEmakio,;l d hn/M{f Date Purge1_/_/__1"'Snrt: ��'�"�� piitish: �`F `�PnrgeRateJ� Purging Method'_ e L ;_U f _ TOtal Volume Purged , 0,9(BaRou'9/(� 9mm�b1l¢Infornlatlo - - DateCollerted__}1/_.��- Time Collected:. Sampling SgNpmeatUsmh 1_t'1241 d Instrument lD. �.L' , Bottle Type- Preservation Amdysra Regvi ed. . -- fF✓AFL-- !/Go (( - - -- -7-0 Field Measure ts/Observahons tF I.Lir Sample Temp (q 1 5 _, r _Time: J'F4"J ,'Lucuiclity (ntu) 2 k. Time; _._ Dus Oxy(mg/L)__�_,5- Time. Six,cific Cond. uu: A4. (, lime:J`Y ' Res C.(mg/LU(Ng/L):`_T�ime'. Sample phsu 5 .70 Time: /4T Odm. _✓Jdi _, Time: ReDax (mV): G jr V Time: I DWI APAaeaeance: (,(?e, —:rime. � ReDox(RH vahte):YSI PraPhts+200mV.1y -Otherr':,.------Tape:. - Geirmn/Weathec Obaervafions "l Vil -- --- _-(sunny/cloudy/ramy)'r mPCrr_CF) Wind .✓_(mph) Sampler SPo° ReDOx Turbrdit Yore 'Water "T:ep. Dins Oxy Cont. pH (s.uJ y xemaverl leel (t Otrter )jmg/L)(aS) oDo (nor) 'orots)() .Ill h?� azl. '�S.l s/i%.. 2f5' (te-ri