HomeMy WebLinkAboutNC0000078_Groundwater Monitoring Report November 2022_20221231Mf(G (
GW-59A COMPLIANCE REPORT FORM Permit#NC 60wo 7k
(Subunit one cewh nrnnitas'h,,edad o ith G W-59 Jorrns.)
1
Enter date monitoring results were due. �) Will this monitoring report (GW.59 and GW-59A)
YES
NO
be submitted after the established due d ?
2
Was any required information missing on the GW-59 report forms?
YES
NO
IF the answer to question t or 2 is "YES", list in the space provided below the well identification number(c) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
YES
NO
identification plate, area overgrown, etc.)? [#'the answer is "Yes ", contact the ftegiorvol OJ}ice forguidance.
4
Are any monitored constituents equal to or above the established standards?
V,YS'
NO
If the answer to question 4 is "NOy skip to section 8.
If the answer to question 4 is "YES"list the affected wells individually with constituent(s) and concentration($)
exceeding standards in the space provided below.
,S/,--1- 4Tl��l���
5
For the constituents identified in question 4 above, have standards been exceeded previously for the
YES
NO
same tonstituent(s) in the same well(s) In the last two years?
/
If the answer to question 5 is "NO", skip to section 8.
If the answer to question 5 is "YES" list in the space provided below, each well with constituents) exceeding
standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years).
6
Are the monitoring wells listed in section 5located at or beyond the review boundary?
YES
NO
If the answer is "YES" a groundwater qualify problem maybe occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", moniforing wells may be improperly
located; contact the Regional Office.
7
is the partridge implementing previously approved actions required by the Division involving this
YES
NO
groundwater quality problem?
lithe answer to question 7 is "YES", describe those actions in the space provided below.
If the answer to question 7 is "NO", contact the Regional Office within 90 days: an evaluation may be
required to determine the t the t disposal t Is havingt the d compliatic
boundaries surrounding this facility. Failure to do a. may ubiect the 'tt to Notice f Violation,
fines, and/or penalties. RR�FIVFD
JAN 17 2023
aSBCTICd1
g
The person completing this portion (G W-59A) of the monitoring report shoo mft rs
form with G W-59 forms for required wells to the address provided at the top of the current G W-59 f0tho
s 7
1 hereby acknowledge that the above Information was evaluated and the Information submitted in Igis�
report (Compliance Report GW-59A) is true and complete to the best of my knowledge.
)a.
r�`,4'
ram/ /2�3//Zyo
Signature of Permlttea (or AutM1priutl Agent)00
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A
aceAnalytical
wxw.penlabe.mm
December 28, 2022
Mr. Bernie Kelly
Davidson River Village, LLC
P.O. Box 880
Pisgah Forest, NC 28768
RE: Project: MW NOVEMBER 2022
Pace Project No.: 92637869
Dear Mr. Kelly
Pace Analytical Services, LLC
2225 Riveraitle or.
Asheville, be 28804
(828)254-7176
Enclosed are the analytical results for sample(s) received by the laboratory on November 21, 2022. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services -Asheville
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Peachtree Corners, GA
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
��
Taylor Dyson for
Lorri Patton
lorri.patton@pacelabs.com
1(828)254-7176
Project Manager
Enclosures
Q Ae�a60i
r
REPORT OF LABORATORY ANALYSIS
not report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 28
t
�ceAnalytical ®
Pace Analytical Services, LLC
Dt
2iii RiversideC28
M
ASM1ev828)2C 20Bn4
wwx.patelaE9.ttAI
(028)254-]1I8
CERTIFICATIONS
Project: MW NOVEMBER 2022
Pace Project No.: 92637869
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99008
South Carolina Certification #: 99006001
9800 Kincey Ave. Ste 100, Huntersville, NO 28078
South Carolina Drinking Water Gen. #: 99006003
North Carolina Drinking Water CerlIDcatlon #: 37706
FloridalNELAP Certification #: E87627
North Carolina Field Services Certification #: 5342
Kentucky UST Certification #:84
North Carolina Wastewater Certification #:12
Louisiana DoH Drinking Water#: LA029
South Carolina Laboratory ID: 99006
VirginiaNELAP Certification #: 460221
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NO 28804
South Carolina Laboratory ID: 99030
FlondalNEIAP Certification #: E87648
South Carolina Certification #: 99030001
North Carolina Drinking Water Certification#: 37712
VinIniaNELAP Certification #: 460222
North Carolina Wastewater Certification #:40
Pace Analytical Services Peachtree Corners
If Technology Pkwy, Peachtree Corners, GA 30092 North Carolina Certification #: 381
Florida DOH Certification k E87315 South Carolina Certification #: 98011001
Georgia DW Inorganics Certification #: 812
REPORT OF LABORATORY ANALYSIS
This repel shell not be reproduced, except in full,
winsat the written consent of Pace Analytical Services, LLG.
Page 2 of 28
,clakeAnalytical
WWW.pdOeldE9.t0111
SAMPLE ANALYTE COUNT
Pace Analytical Services, LLO
2225 Riverside D,.
Asheville, Nc 25804
(628)254 7176
Project
Pace Project No.:
MW NOVEMBER 2022
92637869
Analylee
LibID
Sample ID
Method
Analysts
Reported
Laboratory
92637869001
Q88V2
EPA 6D20B
CW1
]
PASI-GA
EPA 7470A
VB
1
PASI-GA
SM 6200B
CIE
63
PASI-C
SM 254OC-2015
CS1
1
PASI-A
EPA 300.0 Rev 2.11993
CDC
1
PASI-A
EPA 350.1 Rev 2.01993
ARJ
1
PASI-A
SM 53108-2014
MJP
1
PASI-A
92637869002
ASB-01
EPA 6020E
CW1
➢
PASI-GA
EPA 7470A
VB
1
PASI-GA
SM 6200B
CL
63
PASI-C
SM 254OC-2015
CS1
1
PASI-A
EPA 300.0 Rev 2.11993
CDC
1
PASI-A
EPA 350.1 Rev 2.01993
ARJ
1
PASI-A
SM 531 OB-2014
MJP
1
PASI-A
92637869003
ASB-02
EPA 6020B
CW1
]
PASI-GA
EPA 7470A
VB
1
PASI-GA
SM 6200B
CIE
63
PASI-C
SM 254OC-2015
C51
1
PASI-A
EPA 300.0 Rev 2.11993
CDC
1
PASI-A
EPA 350.1 Rev 2.0 1993
ARJ
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
PASI-A= Pace Analytical Services -Asheville
PASI-C = Pace Analytical Services - Charlotte
PASI-GA= Pace Analytical Services - Peachtree Canners, GA
REPORT OF LABORATORY ANALYSIS
This round shall not be rc,,.dc d, except In full,
without the written consent of Pace Analytical Services, ac. Page 3 of 28
r
24
aceAnalytical
wuw.panlebassm
ANALYTICAL RESULTS
Project: MW NOVEMBER 2022
Pace Project No.: 92637669
Sample: 0881 Lab ID: 92637869001 Collected : 111211221145 Received: 11/21/22
Pace Analytical Services, LLC
2225 Riverside or.
Asheville, NC 28804
(621I254999
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Monitoring WeII Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Paco
1
1112312210:13
Collected By
Mark
1
11/23/22 10:13
Swann
Collected Data
11/21/22
1
1112312210:13
Collected Time
1146
1
11/23/2210:13
pH
5.21 Std. Units
1
11123/2210:13
Temperature
15.4 deg
1
11/2312210.13
Static Water Level
69.63 feet
1
1112312210:13
Specific Conductance
19.0 umhoslcm
1
1112312210:13
Oxygen, Dissolved
4.99 mg/L
1
11/23/22 10:13
778244-7
Total Well Depth
68.5 feet
1
11/23/2210:13
REDOX
35.7 all
1
11123/2210:13
Turbidity
2.85 NTU
1
11123/2210:13
Odor
None
1
11123/2210:13
Appearance
Clear
1
11/23/2210:13
6020 MET ICPMS NC
Analytical Method: EPA 6020B Preparation Method:
EPA3006A
Pace Analytical Services - Peachtree
Corners,
GA
Arsenic
NO ug/L
5.0
1
12/23/2209:16
12/2312216:31
7440-38-2
Chromium
NO ug/L
5.0
1
12123/2209:16
12123/221631
7440-47-3
Cobalt
NO ug/L
10
1
1212312209:16
12/23/221631
744048-4
Iron
69.7 ug/L
40.0
1
12/23/2209:16
12123/2216:31
7439-89-6
Lead
NO ug/L
1.0
1
12123/2209:16
12/23/2216:31
7439-92-1
Manganese
NO uglL
10.0
1
12/2312209:16
12/23/2216:31
7439-96-5
Sodium
1120 uglL
100
1
1212312209:16
12/2312216:31
7440-23-5
7470 Mercury
Analytical Method: EPA 7470A Preparation Method:
EPA 7470A
Pace Analytical Services - Peachtree
Corners,
CA
Mercury
NO ug/L
0.20
1
121091220990
1210912213:29
7439-97-6
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Benzene
ND ug/L
0.50
1
11128/2220:22
71-43-2
Bromobenzene
ND ug/L
0.50
1
11/28/2220:22
108-86-1
BromocN.Bmethane
NO ug/L
0.50
1
11/2B/2220:22
74-97-5
Bromadichloromethane
NO ug/L
0.50
1
1112812220:22
]5-2]-4
Bromofarm
NO ug/L
0.50
1
1112812220:22
75-25-2
Bromomethane
NO ug/L
5.0
1
1112812220:22
74-83-9
n-Butylbenzene
NO ug/L
0.50
1
11/2812220:22
104-51-8
sec-Butylbenzene
NO ug/L
0.50
1
1112812220:22
135-98-8
tart-Butylbenzene
NO ug/L
0.50
1
1112812220:22
98-06-6
Carbon tetrachloride
NO ug/L
0.50
1
1112812220:22
56-23-5
Chlorobenzene
NO ug/L
0.50
1
1112812220:22
108-90-7
Chl.... than.
NO u0/L
1L
1
11/2812220:22
75-00-3
CM1lorofx.
ND uglL
0.50
1
11128/2220:22
67-66-3
Chlormuethane
NO ug/L
1.0
1
11128/2220:22
74-87-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,
except
in full,
Date: 12128/202204:07 PM
whhoutthewrltten... at al Pace Analytmal
Sales, LLC.
Page 4 of 28
t Pace Analytical services, LLC
�ceMalytical o 225 R1ven128
Asheville NO 804
..ourselves (8262B)254-01 ]6
ANALYTICAL RESULTS
Project: MW NOVEMBER 2022
Pace Project No.: 92637869
Sample: O88V2 Lab ID: 92637869001 Collected: 1111/2211A5 Received 1112112217:10 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[
620DB MSV
Analytical Method:
SM 6200B
Pace Analytical Services - Charlotte
2-Chlorotoluene
NO
ug/L
0.50
1
11/28/22 20:22
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/28/22 20:22
106-434
1,2-Dibromo-3-chlmopropane
NO
ug/L
1.0
1
1112812220:22
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11128/2220:22
12448-1
1,2-Dlbmmoethane(EDB)
ND
ug/L
050
1
11/28122 20:22
106-93-4
Dibromomethane
ND
ug/L
0,50
1
11/28/22 20:22
74-95-3
1,2-Dichloabenudes
ND
ugd-
0.50
1
1112812220,22
95-50-1
1,3-Dichlorabenzene
ND
ug/L
0.50
1
1112812220:22
541-73-1
1,4-Dichlorabenzene
NO
ug/L
0.50
1
11/28/22 20:22
108-46-7
Dichlorodl0ueromethane
NO
ug/L
0.50
1
11/28/22 20:22
75-71-8
1,1-Dichloroethane
NO
ug/L
0.50
1
11/28/22 20:22
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/28/22 20:22
107-06-2
1,1-Dichlooethene
ND
ug/L
050
1
11/28122 20:22
75-35-4
cis-1,2-Dlchloroethene
ND
ug/L
0.50
1
11/28/22 20:22
156-59-2
trans-1,2-Dichloroethene
NO
ug/L
0.50
1
11128/22 20:22
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11128/22 20:22
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
1112812220:22
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/28/22 20:22
594-20-7
1,1-Dichlorapropene
ND
ugi
0.50
1
1112812220:22
563-58-6
cis-1,3-Dichloropropene
NO
ug/L
0.50
1
11/28/22 20:22
10061-01-5
trans-1,3-Dichloropropane
NO
ug/L
0.50
1
11/28/22 20:22
10001-02-6
Diisopropyl ether
NO
ug/L
0.50
1
11/28/22 20:22
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/2812220:22
10041-4
Nexachloro-1,3-butadien ,
ND
ug/L
2.0
1
11/28/22 20:22
87-68-3
Isopropylbenrane(Curl
ND
ugh-
0,50
1
11/28122 20,22
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/28/22 20:22
75-09-2
Methyl-tert-butyl ether
ND
u9/L
0.50
1
11/28/22 20:22
1634-04-4
Naphthalene
ND
uglL
2.0
1
1112812220:22
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
1112812220:22
103-65-1
Styrene
NO
ug/L
0.50
1
11/28/22 20:22
100-42-5
1,1, 1,2-Tetrachloroethane
NO
ug/L
0.50
1
11/28/22 20:22
630-20-6
1,1,2,2-Tetrachlaroethane
NO
ug/L
0.50
1
11/28/22 20:22
79-34-5
Tetrachlaroethene
ND
ug/L
0.50
1
11/28/22 20:22
127-18-4
Toluene
ND
ugh-
0.50
1
11/28122 20:22
108-88-3
1,2,3-Trichlorobenzene
ND
ug/L
2.0
1
11/28/22 20:22
87-61-6
1,2,4-Trichlombenzene
ND
ug/L
2.0
1
11/28/22 20:22
120-82-1
1,1,1-Trichloroethane
ND
ugA-
0.50
1
11/28/22 20:22
71-55-6
1,1,2-Trichloroethane
ND
ug/L
0.50
1
11/28/22 20:22
79-00-5
Trichloroethene
NO
ni
0.50
1
11128/2220:22
79-01-8
Trichloro9uommethane
NO
ug/L
1 0
1
11/28/22 20:22
75-694
1,2,3-Trichloropropane
NO
ug/L
0.50
1
11/28/22 20:22
96-18-4
1,2,4-Trimethylbenzene
NO
ug/L
0.50
1
11/28122 20:22
95-63-6
13,5-Trimethylbenzene
ND
ug/L
0.50
1
11/2812220:22
108-61-8
Vinyl chloride
NO
ug/L
1.0
1
11128/22 20 22
75-01-4
m&p-Xylene
ND
ugh-
1.0
1
11/28/22 20:22
179601-23-1
o-Xylene
ND
ug/L
0.50
1
11/2812220.22
95-47-6
REPORT OF LABORATORY ANALYSIS
This report shall nor be reproduced, except In full,
Date: 12/28/2022 04:07 Pro without the written co heart of Pace Aneiydcal 6ervicas,LLC. Page 5 of 28
a'OAnalytical a
www.penlaba.com
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2226 Riverside Dr.
Asheville, NC 28804
(626)2547176
Project: MW NOVEMBER 2022
Pace Project No.: 92637869
Sample: Q66V2 Lab ID: 92637969001 Collected: 1112112211:45 Received: 11/21/22 17 10 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
6200B MSV Analytical Method: SM 62008
PaceAnalytical Services - Charlotte
Surrogates
1,2-131chlomethane-d4(S)
90 %
70-130
1
11128/2220:22
17080-07-0
4-Bromofluombenzene(S)
W %
70-130
1
11128/2220:22
460-00-4
To1uene-08(S)
100 %
70-130
1
11128/2220:22
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
NO mg/L
25.0
1
11/23/2218:58
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.11993
Pace Analytical Services -Asheville
Sulfate
NO mg/L
1.0
1
11122/2219:26
14808-79-8
350.1 Ammonia
Analytical Method EPA 350.1 Rev 2.01993
Pace Analytical Services - Asheville
Nitrogen, Ammonia
ND mg/L
0.10
1
12/01f22 1322
766441-7
5310B TOC
Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
NO mg/L.
1.0
1
1112812220:30
744044-0
REPORT OF LABORATORY ANALYSIS
ThIs repot shall not be epmtluced except In full,
Date: 121281202204:07 PM without the written consent of Pace Analytical services, I.I.C.
Page 6 of 28
Pace Analytical Services, LLC
aceAnaly ical ® 2225 Rlv C 28 Dr.
Asheville, NC 2e509
W4Nv.penlaEi.[om
(636)350-]1I6
ANALYTICAL RESULTS
Project: MW NOVEMBER 2022
Pace Pni No.: 92637869
Sample: ASB-01 Lab ID: 92637869002 Collected: 11121/221646 Received: 11/21/221710 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzetl CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
11123/2210:15
Collected By
Mark
1
11/2312210:16
Swann
Collected Data
11121122
1
11123/2210:15
Collected Time
1546
1
11123/2210:15
PH
5.93 Sitl. Units
1
1112312210:15
Temperature
13.5 all C
1
11/2312210:15
Bill Water Level
8.25 feet
1
11123/2210:15
Specific Conductance
403.2 umhos/cm
1
1112312210:15
Oxygen, Dissolved
0.65 mg/L
1
11/2312210:15
778244-7
Total Well Depth
15.0 feet
1
11/2312210:15
REDOX
-164.6 mV
1
1112312210:15
Turbidity
3.44 NTU
1
1112312210:16
Odor
None
1
1112312210:16
Appearance
Clear
1
1112312210:15
6020 MET ICPMS NO
Analytical Method: EPA 6020B Preparation Method:
EPA 3005A
-
Pace Analytical Services - Peachtree
Corners,
GA
Arsenic
ND ugd-
5.0
1
12/23/2209,16
12/23/221837
7440-38-2
Chromium
ND ug/L
50
1
12/2312209:16
121231221637
744047-3
Cobalt
3.5 uglL
1.0
1
12123/2209:16
12/231221637
744048-4
Iron
779 u9IL
400
1
1212312209:16
12/23/2216:37
7439-89-6
Lead
ND u9IL
1.0
1
12/2312209:16
12/23/2216:37
7439-92-1
Manganese
1760 ug/L
100
10
12/2312209:16
1212712213:46
7439-96-5
Sodium
28300 ug/L
1000
10
1212312209:16
1212712213:46
7440-23-5
]4]0 Mercury
Analytical Method: EPA 7470A Preparation Method:
EPA 7470A
Pace Analytical Services - Peachtree
Corners,
GA
Mercury
NO ug/L
0.20
1
12109/2209:00
12/0912213:40
7439-97-6
6200B MSV
Analytical Method: SM 6200E
Pace Analytical Services - Charlotte
Benzene
NO ug/L
0.50
1
11128/2220:41
71-43-2
Bmmobanzene
NO ug/L
O50
1
1112812220:41
108-86-1
Bromochloromethaoe
ND ug/L
0.50
1
1112812220:41
74-97-5
Bromatlichloromethane
ND ug/L
0,50
1
11/2812220:41
76-27-4
Bronchi
NO ug/L
0,50
1
11/2812220:41
75-25-2
Bromomethane
ND ug/L
5.0
1
1112812220:41
74-83-9
n-Butylbenzene
ND ug/L
0.50
1
11128/2220:41
104-51-8
seto-Bulylb6nzene
ND ig/L
0.50
1
11/2812220:41
135-98-8
tert-Butylbenzene
ND ug/L
0.50
1
11/28/2220:41
98-06-6
Carbon tetrachloride
ND ug/L
0.50
1
11/2812220:41
56-23-5
Chlorobenzene
ND ug/L
0.50
1
11/2812220:41
108-904
Chlomethane
ND ug/L
10
1
1112812220:41
75-00-3
Chloroform
NO u9IL
0.50
1
11128/2220:41
67-66-3
Chloromethme
ND u9I1-
1.0
1
1112812220:41
74-87-3
REPORT OF LABORATORY ANALYSIS
This report shell not be reproduced,
except
in full,
Date: 12/28/202204:07PM
without the wntten consent of Pace Analytical
Services. LLC.
Page 7 of 28
aceAnalytical
ww.psnlaBLwm
ANALYTICAL RESULTS
Pace Anil I Services, LLC
2225 Riverside Dr.
Asheoille, NC 26804
(821
Project: MW NOVEMBER 2022
Pace Project No.: 92637869
Sample: ASB-01 Lab ID: 92637869002 Collected: 11/21/2215:45 Received: 11/21/22 17 10 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Dual
6200B MI
Analytical Method:
SM 6200B
Pace Analytical Services - Charade
2-Chlomtoluene
ND
u9I1-
0.50
1
11128/2220:41
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
1112&2220:41
10643-4
1,2-Dibromc-3-chlcropropane
NO
ug/L
1.0
1
1112812220,41
96-12-8
Dibromochloromethane
NO
ug/L
0.50
1
11/2812220:41
124-48-1
1,2-Dibramoethane(I
NO
ug/L
0.50
1
11/2812220:41
106-934
Dibromomethane
NO
up-
0.50
1
11/28/2220:41
74-95-3
1,2-Dichlorobenzene
NO
ug/L
0.50
1
11128/2220:41
95-50-1
1,3-Dichlorobenzene
NO
uga-
0.50
1
11128/2220:41
541-73-1
1ADichlorobenzene
ND
upl-
0.50
1
11128/2220:41
106-46-7
Dichitrodiharnomethanc
NO
ug/L
0.50
1
11128/2220:41
75-71-8
1,1-Dichloroethans
ND
u9IL
0.50
1
W28/2220:41
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
1112812220:41
107-06-2
1,1-Dichloroethene
NO
ug/L
U0
1
11/2812220:41
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
1112812220:41
156-59-2
trans-1,2-Dichloroethene
NO
all
0.50
1
11128/2220:41
156-60-5
1,2-Dichloropropane
NO
ugh-
0.50
1
11/2812220:41
78-57-5
1,3-Dichloropropane
NO
ug/L
0.50
1
11/2812220:41
142-28-9
2,2-Dichloropropane
NO
ug/L
0.50
1
11/2812220:41
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/28/2220:41
563-68-6
cis-1,3-Dichloropropene
ND
u9IL
0.50
1
11/2812220:41
10061-01-5
trans-1,3-Dichloropropene
ND
u9IL
0.50
1
11/28/2220:41
10061-02-6
Diisoprcpyl ether
NO
ug/L
0.50
1
11/28/2220:41
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/2812220:41
100-414
Hexachloro-1,3-butadiene
ND
up-
2.0
1
1112812220:41
87-68-3
Isopmpylbenzene(Cumene)
NO
up-
0.50
1
11128/2220:41
98-82-8
Methylene Chloride
NO
ug/L
2.0
1
11/2812220:41
75-09-2
Methyl-tert-butyl ether
ND
u9/L
0.50
1
11/2812220:41
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/2812220:41
91-20-3
n-Propylbenzene
ND
u9I1-
0.50
1
11128/2220:41
103-65-1
Styrene
NO
u9IL
0.50
1
11/28/2220:41
100-42-5
1,1,1,2-Tetrachlorcethane
NO
ug/L
0.50
1
1112812220:41
630-20-6
1,1,2,2-Tetrachloroethane
NO
1
0.50
1
1112812220:41
79-34-5
Tetrachloroethene
NO
u9IL
0.50
1
11/2812220:41
127-184
Toluene
NO
ug/L
U0
1
11128/2220:41
108-88-3
1,2,3-Trichlcrobenzene
NO
had-
2.0
1
11128/2220:41
87-61-6
1,2,4-Trichlombenzene
NO
ugh-
2.0
1
11/2812220:41
120-82-1
1,1,1-Trichlaroethane
NO
ugh-
0.50
1
11128/2220:41
71-55-6
1,1,2-Trichlaroethane
NO
ug/L
0.50
1
11128/2220:41
79-00-5
Tdchloroetman,
ND
u9IL
0.50
1
11/2812220:41
79-01-6
Trichlcrofluoromethane
ND
ug/L
1'0
1
1112812220:41
75-69-4
1,2,3-Tdchimepropane
ND
ug/L
0.50
1
11/2812220:41
96-15-4
1,2,4-Trimethylbenzene
NO
ug/L
0.50
1
1112812220A1
95-63-6
1,3,5-Trimethylbenzene
NO
ug/L
0.50
1
11/2812220:41
108-67-8
Vinyl chloride
NO
up-
1.0
1
1112812220:41
75-01-4
m&p-Xylene
NO
ug/L
1.0
1
1112812220:41
179601-23-1
o-Xylene
NO
u9/L
0.50
1
11128/2220:41
95-47-6
REPORT OF LABORATORY ANALYSIS
This repel shall not be reproduced except In WII,
Date: 12/28/202204:07 PM Mthoutlha wrihin consent of Pace AnalNicel Services,LLC.
Page 8 of 28
aceAnalyical
weepaselshrucas
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-9176
Project: MW NOVEMBER
2022
Pace Project Ne.: 92637869
Sample: ASB-01
Lab ID: 92637869002 Collected:
11/21/221545
Received: 111211221710 Matrix:Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Oual
6200B MSV
Analytical Method: SM 6200E
Para Analytical Services - Charlotte
Surrogates
1,2-Dichloreethani(S)
93 %
70-130
1
1112812220:41
17060-07-0
4-Bromofluerobenzene(S)
98 %
70-130
1
11128/2220:41
460-004
Toluene-d8(S)
99 %
70-130
1
11/28/2220:41
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
239 dri
25.0
1
11/23/2218 58
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.11993
Pace Analytical Services -Asheville
Sulfate
7.5 mg/L
1.0
1
11/22/22 19:41
14808-79-8
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.01993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
NO ri
0.10
1
12/012213:23
7664414
5310B TOC
Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
ND or lL
1.0
1
1112812220:48
7440-44-0
Date: 12/28/2022 04:07 PM
REPORT OF LABORATORY ANALYSIS
This .,sit shsll not be reprotlecetl, except In fell
without the written wnsent of Pace Analytical Services, LLC.
Page 9 of 28
Pace Antlytical Services, LLC
® 2225 Riverside Dr.
aceAnaljd al Asheville, NC 28804
...pacelabimm
(828)25L]1]6
ANALYTICAL RESULTS
Project'. MW NOVEMBER 2022
Pace Project No.: 92637869
Sample: ASB-02 Lab ID: 92837869003 Collected: 11/2112214:45 Received 11/2112217:10 Mark Water
Parameters Results Units Report Limit OF Prepared Analyzed GAS No. Qual
Monitoring Well Data
Analytical Method:
Paces Analytical Services - Charlotte
Performed by
Pace
1
11/2312210:17
Collected By
Mark
1
11/2312210:17
Swann
Collected Date
11/21122
1
11/23/22 10:17
Calleded Time
1445
1
1112312210:17
pH
5.90 Std. Units
1
11/23122 10:17
Temperature
15.5 deg 0
1
1V23I2210:17
Static Water Level
8.50 feet
1
1123/22 10:17
Specific Conductance
129.6 umhos/cm
1
11123/2210:17
Oxygen, Dissolved
3.31 mg/L
1
11/23/22 1017
7782-44-7
Total Well Depth
12.0 feet
1
11/23/22 10:17
REDOX
-63.0 mV
1
11/23/2210:17
Turbidity
8.24 NTU
1
11/23/22 10:17
Odor
None
1
11/2312210:17
Appearance
Clear
1
11/23/2210:17
6020 MET ICPMS NC
Analytical Method: EPA 6020B Preparation Method:
EPA 30D5A
Pace Analytical Services - Peachtree
Corners,
GA
Arsenic
ND ug/L
5.0
1
12/2312209:16
121231221701
7440-38-2
Chromium
NO uglL
50
1
12/2312209:16
12/23/221701
744047-3
Cobalt
NO ug/L
1.0
1
12/2312209:18
12/23/221701
744048-4
Iron
364 ug/L
40.0
1
12/2312209:10
12/23rz211:01
7439-89-6
Lead
NO ug/L
1.0
1
12123/2209:16
12/23/2217:01
7439-92-1
Manganese
ND ug/L
10.0
1
12123/2209:16
12/23/2217:01
7439-96-5
Sodium
11100 ug/L
500
5
12/23/22 09:16
12123/22 1]:0]
7440-23-5
]4]0 Mercury
Analytical Method: EPA 7470A Preparation Method.
EPA 7470A
Pace Analytical Services - Peachtree
Corners,
GA
Mercury
NO ug/L
0.20
1
1210912209:00
12/09/2213:42
]439-9]-6
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Benzene
ND uglL
0.50
1
11/28/2220:59
71-43-2
Bromobenzene
NO ug/L
0.50
1
11/28/22 20:59
1081
Bromochloromethane
NO ug/L
050
1
11128/2220:59
]4-9]-5
Bromodichloromethane
NO ug/L
0,50
1
11/28/22 20:59
]5-2]-4
Brom dorm
NO ug/L
0.50
1
11/28/22 20:69
75-25-2
Brom media ne
NO ug/L
5.0
1
11/28122 20:59
74-83-9
n-Butylbenzene
NO uglL
0.50
1
11/28/2220:59
104-51-8
sec-Butylbenzene
ND .,at
0.50
1
11/2812220:69
135-98-8
tert-Butylbenzene
NO ug/L
0.50
1
11/28/22 20:59
98-06-6
Carbon tatrm hloride
NO ug/L
0.50
1
11128/22 20:59
56-23-5
Chlorobenzene
NO upl-
0.50
1
11/28/22 20:59
108-90-7
Chlorcethane
NO ug/L
1.0
1
1112812220:69
75-00-3
Chloroform
NO all
0,60
1
11/28/22 20:59
67-06-3
Chlommethane
NO ug/L
1.0
1
11/28/22 20:59
74-87-3
REPORT OF LABORATORY ANALYSIS
Tabasco shall not be repratlncod,
except
In lull,
Date: 12/28/2022 04:07 PM
without the written consent of Paces Analytical
Services,LLC.
Page 10 of 28
aceAnalytical n
wuw.peuNaBe.00m
ANALYTICAL RESULTS
Project: MW NOVEMBER 2022
Pace Project No.: 92637869
Pace Analytical Services, LLC
2225 Riverside Or.
Asheville, NO 28804
(82e)254-7176
Sample: ASBA2 Lab ID: 92637869003 Collected 111211221445 Received: 11/21/2217:10 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Dual
6200B MSV
Analytical Method:
SM 6200B
Pace Analytical Services - Charlotte
2-Chlorotomene
NO
ug/L
0.50
1
11/28/22
20:59
9549-8
4-Chlomtoluene
NO
ug1L
0.50
1
11/28/22
20:59
106-434
1,2-Dib10mo-3-chlompmhane
ND
ug/L
1.0
1
11/28/22
20:59
96-12-8
Dibromochloromethane
NO
ug/L
0.50
1
11/28122
20:59
124-48-1
1,2-Dibromaethana(EDB)
NO
ug/L
0.50
1
11/28/22
20:59
106-93-4
Dibromomethane
NO
ug/L
0.50
1
11/28/22
20:59
74-95-3
1,2-0Ichlorobenzene
NO
ug/L
0,50
1
11/28/22
20:59
95-50-1
1,3-DIChlorobenzene
NO
ug/L
0.50
1
11/28/22
20:59
541-73-1
1,4-Dichlorobenzene
NO
ug/L
0.50
1
11/28/22
20:59
106-46-7
Dichlorodi8uoramethane
NO
u1
0.50
1
11/28/22
20:59
75-71-8
1,1-Dichloroethane
NO
ug/L
0.50
1
11/28/22
20:59
75-343
1,2-Dichloroethane
NO
ug1L
0.50
1
11/28122
20:59
107-06-2
1 1-Dichloroethane
NO
ug/L
0.50
1
11128/22
20:59
75-354
cis-1,2-Dichloroethene
NO
ug/L
0.50
1
11128/22
20:59
156-59-2
trans-1,2-Dichlaroethene
NO
ug/L
0.50
1
11128/22
20:59
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/2812220:59
78-87-5
1,3-0Ichloropropane
NO
ug/L
0.50
1
11/28/22
20:59
142-28-9
2,2-0Ichloropropane
ND
ug/L
0.50
1
11/28/22
20:59
594-204
1,1-Dichloropropane
NO
ug/L
0.50
1
11/28/22
20:59
563-58-6
cis-1,3-Dichlaropropene
NO
ug/L
0.50
1
11/28/22
20:59
10061-01-5
trans-1,3-Dichloropropene
NO
ug/L
0.50
1
11/28/2220:59
10061-02-6
Diisopmpyl ether
ND
ug/L
0.50
1
1112812220:59
108-20-3
Ethylbenzene
NO
ug/L
0.50
1
11128122
20:59
100-41-4
Hexachlaro-1,3-butadiene
NO
ug/L
2.0
1
11/28/22
20:59
87-68-3
Isopropytionzene(Cumene)
NO
ug/L
0.50
1
11128/22
20.59
98-82-8
Methylene Chloride
NO
ug/L
2.0
1
11/28/22
20:59
75-09-2
Methyl-tert-butyl ether
NO
ug/L
0.50
1
11/28/22
20:59
1634-044
Naphthalene
NO
ug/L
2.0
1
11/28/22
20:59
91-20-3
n-Propylbenzene
NO
ug/L
0.50
1
11/28/22
20:59
103-65-1
Styrene
ND
ug1L
0.50
1
11/28122
20:59
100-42-5
1,1,1,2-Te rachloamethane
NO
ug/L
0.50
1
11/28122
20:59
630-20-6
1 1,2,2-Tetrachloroethane
NO
ug/L
0.50
1
11128/22
20:59
79-34-5
Tetrachloroethene
ND
ug/L
0.50
1
11/28122
20 59
127-18-4
Toluene
NO
ug/L
0.50
1
11125122
20:59
108-88-3
1,2,3-Trichlombenzene
NO
ug/L
2.0
1
11128/22
20:59
87-61-6
1,2,4-Trichlombenzene
ND
ug/L
2.0
1
11128/22
20:59
120-62-1
1,10-Trichloroethane
NO
ug/L
050
1
11/28/22
20:59
71-55-6
1,1,2-Trichloroethane
NO
ug/L
0,50
1
11/28/22
20:59
79-00-5
Trichloraethene
NO
ug/L
0.50
1
11/28/22
20:59
79-01-6
Trichloro0uoromethane
NO
ug1L
1.0
1
11/28/22
20:59
75-69-4
1,2,3-Trichloropmpane
NO
ug/L
0.50
1
11/28/22
20:59
96-18-4
1 2,4-Trimethylbenzene
NO
uglL
0.50
1
111281222059
95-63-6
1,3,5-Tnanethylbenzene
NO
ugll-
0.50
1
11/28/22
20:59
108-67-8
Vinyl chloride
ND
uglL
1 0
1
11/28/22
20:59
75-01-4
m&p-Xylene
NO
uglL
1.0
1
11128/2220:59
179601-23-1
o-Xylene
NO
ug/L
0.50
1
11/28122
20:59
95-47-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12128/202204:07 PM without the written consent of Pace Analytical services, LLG Page 11 of 28
aceAnalytical s
wwmpa<slahf.4om
ANALYTICAL RESULTS
Project: MW NOVEMBER 2022
Pace Project No.: 92637869
Pace Analytical Servli LLC
2225 Riverside or.
Asheville, NC 28804
(828)254-7195
Sample: ASB.02
Lab ID: 92637869003 Collected:
11/211221445
Received: 11/21/2217:10 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Oual
6200E MSV
Analytical Method: SM 6200B
Pace Analytical Service. - Charlotte
Surrogates
1,2-Dichloroethane-d4(5)
92 %
70-130
1
11/28/22 20:59
17060-07-0
4-Bromofluorobenzene(5)
99 %
70-130
1
11/28/22 20:59
460-00-4
Toluene-dB(S)
100 %
70-130
1
11/28/22 20:59
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
62.0 mg/L
25.0
1
11/23/22 18:58
300.E IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.11993
Pace Analytical Services -Asheville
Sulfate
3.9 mg/L
1.0
1
11/22/22 20:25
14808-79-8
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.01993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
NO mg/L
0.10
1
12/01a213:25
7664-41-7
6310B TOC
Analytical Method: SM 531OB-2014
Pace Analytical Services - Asheville
Total Organic Carbon
ND mg/L
1.0
1
11/28/22 21:16
7440-44-0
Ild[s1igYD/Y1rYYlrLiai�g�Sl
REPORT OF LABORATORY ANALYSIS
This repoa shall not be reproduced, except lM1 full,
witM1outthe wriden consent of Pace Analyliral6ervices, LLC.
Page 12 of 28
aceAnalyticals
wtrw embracer,
QUALITY CONTROL DATA
Project: MW NOVEMBER 2022
Pace Project No.: 92637869
Pace Analytical Services, LLL
2226 Riverside Cr.
Asheville, NC 28804
(828)254-71I6
QC Batch: 745561 Analysis Method: EPA6020B
QC Batch Method: EPA3005A Analysis Description: 6020 MET, NC
Laboratory: Pace Analytical Services- Peachtree Corners, GA
Associated Lab Samples: 92637889001,92637869002, 92637869003
METHOD BLANK: 3878342 Matrix: Water
Associated Lab Samples: 92637869001,92637869002,92637869003
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Arsenic
ug/L
NO
5.0
12=12216:19
Chromium
ug/L
ND
5.0
12123/22 16:19
Cobalt
ug/L
ND
1.0
1212312216:19
Iron
u9/L
NO
40.0
12123/M2 16:19
Lead
uga-
NO
1.0
12123/221619
Manganese
ug/L
NO
10.0
12/23/221619
Sodium
ug/L
ND
100
12123/221619
LABORATORY CONTROL SAMPLE:
Parameter
3878343
Units
Spike
Can..
LCS
Result
LCS
% Rau
%Rec
Limits Qualifiers
Arsenic
ug/L
100
98.5
99
80-120
Chromium
ug/L
100
96.3
96
80-120
Cobalt
ug/L
100
95.1
96
80-120
Iron
ug/L
1000
991
97
80-120
Lead
ug/L
100
101
101
80-120
Manganese
ug/L
100
99.1
99
80-120
Sodium
ug/L
1000
997
100
80-120
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
3878417
3878418
MS
MSD
92637869002
Spike
Spike
MS
MSD
MS
VISO
%Rec
Parameter
Units
Result
Cone.
Come.
Result
Result
%Rec
%Rec
Limits
RED Quiet
Arsenic
ugA-
NO
100
100
97.9
98.2
98
98
75-125
0
Chromium
uglL
ND
100
100
94.2
93.7
94
93
75-125
1
Cobalt
uga-
3.5
100
100
96.3
95.5
93
92
75-125
1
Iron
uga-
779
1000
1000
1730
1740
96
96
75-125
0
Lead
ug/L
NO
100
100
94.4
93.2
94
93
75-125
1
Manganese
ug/L
1760
100
100
1850
1900
82
131
75-125
3
Sodium
ug/L
28300
1000
1000
29300
30600
107
236
75-125
4
Results Presmled on this page are In the units Indicated by Me"unne column exceptMem an alternate unit Is presenkE to the age m Aa result
REPORT OF LABORATORY ANALYSIS
TNarepali shall not be ca,mcmaid, except In full,
Date: 12/28/2022 04:07 PM wshom the written consent of Pace Analyl'mal Services, LLC, Page 13 of 28
aceAnalytical e
Wadvernalbr ORi
QUALITY CONTROL DATA
Pmjact: MWNOVEMBER2022
Pace Project Na.: 92637869
Pace Analytical services, LLC
2225 Riverside or.
Asbevirs, NC 28804
n2p25471T6
UG Balch: 742260 Analysis Method: EPA7470A
QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury
Laboratory: Pace Analytical Services- Peachtree Corners, GA
Associated Lab Samples: 92637869001, 92637869002, 92637869003
METHOD BLANK: 3861520 Matrix: Water
Associated Lab Samples: 92637869001, 9263]869002, 9263➢869003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury uglL NO 0.20 12109a213:19
LABORATORY CONTROL SAMPLE: 3861521
Spike LCS LCS %Roc
Parameter Units Cann Result %Red Limits Qualifiers
Mercury uglL 2.5 2.3 91 80-120
MATRIX SPIKE& MATRIX SPIKE DUPLICATE: 3861522 3861523
MS MSD
92637869001 Spike Spike MS MSD MS MSD %Red
Parameter Units Result Cone. Conc. Result Result %Red %Rec Limits RPD Qual
Mercury uglL NO 2.5 2.5 22 2.2 87 88 75-125 1
Results preanted on this page are In the units Indloated by Me "Un[is" column except Mere an alreform unit IS presumed to Me right or the result
REPORT OF LABORATORY ANALYSIS
This repot shall not be reproduced, except in lull,
Date: 12/28/202204:07PM without the written consent of Pace Analytlwl servicas, llc.
Page 14 of 28
aceAnalytical
wwu.pdceldEe.min
QUALITY CONTROL DATA
Project: MW NOVEMBER 2022
Pace Project No.: 92637869
DO Batch: 739372 Analysis Method: SM 6200B
QC Batch Method: SM 6200B Analysis Description: 62003 MSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92637869001,92637869002,926378690D3
METHOD BLANK: 3847386
Associated Lab Samples: 92637869001,92637869002,92637869003
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
Analyzed
1,1, 1,2-Tetrachloroethane
ug/L
NO
0.50
11/28/22 1645
1,1,1-Trichloraethane
ug/L
NO
0.50
11/28/22 10:45
1 1,2,2-Tetrachloroethane
mpL
ND
0.50
11/28/22 16:45
1,1,2-Trichloraethane
ug/L
ND
0.50
11/28/22 16:45
1,1-Dichloroethane
ug/L
NO
0.50
11/28/22 1645
IL1-Dichloroethene
ug/L
ND
0.50
11/28122 16:45
1,1-Dichloropropene
ug/L
ND
0,50
11/28122 16:45
L2,3-Trich1ombenzene
uglL
NO
2.0
11128/2216:45
1,2,3-Trichloropropane
ug/L
ND
0.50
11/28/22 16:45
1,2,4-Trichlorobenzene
ug/L
NO
2.0
11/28122 16:45
1,2,4-Trimethylbenzene
ug/L
NO
0.50
11/28/22 16:45
1,2-Dibnomo-3-chlonopropane
ug/L
NO
1.0
11/28/22 16:45
1,2-Dibromaethane(EDB)
ug/L
NO
0.50
11128/2216:45
1,2-Dichlorobenzene
uglL
NO
0.50
11/28/22 16:45
1,2-Dichloroethane
ug/L
NO
0.50
11/28/22 16:45
1,2-Dichlompropane
ug/L
NO
0.50
11/28/22 1645
1,3,5-Trlmethylbenzene
up/L
NO
0.60
11/28/22 1645
1,3-Dichlorobenzene
ug/L
NO
0.50
11/28/22 10:45
1,3 Dichloropropane
ug/L
NO
0.50
11/28/22 16:45
1A Dichlorobenzene
ug/L
ND
0.50
11/28/2216:45
2,2-Dlchloropropana
ug/L
ND
0.60
112812216:45
2-Chloraloluene
ug/L
NO
0.50
lV2812216:45
4-Chlorotoluene
uglL
NO
0.50
11128/22 16:45
Benzene
uglL
NO
0.50
1112812216A5
Bmambenzene
uOIL
NO
0.50
1112812216:45
BernMahloremethane
uglL
NO
0.50
11/28/2216 45
Bromodichloromethane
uglL
NO
0.50
11/28/22 16 45
Bromcfarm
ug/L
NO
0.50
11/28122 16:45
Bromomethane
uglL
NO
6.0
111281221645
Carbon tetrachlanide
ugll-
NO
0.50
11/281221645
Chlorobenzene
ug/L
NO
0.50
11/28/22 16:45
Chloroethane
ug/L
NO
1.0
11/28/22 1645
Chloroform
uglL
ND
0.50
11/28/22 1645
Chloromethane
uglL
NO
1.0
11/28/22 16:45
cis-1,2-Dichloroethene
ug/L
NO
0.50
11/28/22 16:45
cis-1,3-Dichloropropene
ug/L
ND
0.60
11/28/22 16:45
Dibromochleromethane
ug/L
ND
0.50
11/28/22 16:45
Dibromomethane
ug/L
NO
0.50
11/28122 16:45
Dichlaradifluoromethane
ug/L
NO
0.50
11/28/22 16:45
Diisopropyl ether
ug/L
ND
0.50
11/28/22 16:45
Qualifiers
Pace Analytical Services, LLC
2225 RiaMside or.
Asheville, NC 28804
(e2e)2544176
Reaulta preemtod on ih la page are In me units Indicated by Ne" Units " column except wM1ere an share ate on It Is presented to Me core of the result
REPORT OF LABORATORY ANALYSIS
Thiftench than not be reprotluc.d, except In full,
Date: 12/28/2022 04:07 PM wilhout the written consent of Pace Analytical Services,LLC.
Page 15 of 28
Pace Analytical Services, LLC
aceAnalytical ® R' NC O4
ASM1eville.NC 2s9a4
www.peuleEs.coRr
(628)254-71 ]6
QUALITY CONTROL DATA
Project: MW NOVEMBER 2022
Paw Project No.: 92637869
METHOD BLANK: 3847386
Matrix:
Water
As ... later] Lab Samples: 9263]869001,9263]869002,92637869003
Blank
Reaching
Parameter
Units
Result
Limit
Analyzed
Qualifiers
Ethylbenzene
ug/L
ND
0.50
11/28/2216:45
Hexachlom-1,3-butadiene
ug/L
ND
2.0
11/28122 16:45
Isopropylbenzene(Cumene)
ug/L
ND
0.50
lV2812216:45
m&p-Xylene
ug/L
ND
1.0
11128/22 16:45
Methyl-tert-butyl ether
ug/L
ND
0.50
11/28122 16:45
Methylene Chloride
ug/L
ND
2.0
11/28/22 16:45
n-Butylbenzene
ug1L
ND
0.50
11/28/22 1645
n-Propylbenzene
ug1L
ND
0.50
11/28/22 1645
Naphthalene
To&
ND
2.0
11/28/2216:45
0-Xylene
ug/L
ND
0.50
11/28/22 16A5
sec-Butylbenzene
ug/L
ND
0.50
11/28/2216:45
Styrene
ug/L
NO
0.50
11128122 16:45
terFButylbenzene
ugh-
NO
0.50
11/28/22 16:45
Tetrachlomethene
ug/L
ND
0.50
1112812216:45
Toluene
ug/L
ND
0.50
11128/2216:45
trans-1,2-Dichloroethene
ug1L
ND
0.50
1112812216:45
trans-1,3-Dichloropropene
ug1L
ND
0.50
11/28/22 16:45
Trichlomethene
ug/L
ND
0.50
11/28/22 16:45
TrichlorOfluoromethane
ug/L
ND
1.0
11/28122 16:45
Vinyl chloride
ug/L
ND
1.0
11128/22 16A5
1,2-Dichloroethane-cif(8)
%
91
70-130
11128122 16
45
4-BromoOuorobenzene(5)
%
99
70-130
1112812216:45
Toluene-08 (S)
%
101
70-130
11128/2216:45
IABORATORY CONTROL SAMPLE:
Parameter
3847387
Units
Spike
Cont.
LCS
Result
LCS
% Rec
%Rec
Limits Qualifiers
1,10,2-Tetrachloroethane
ug/L
50
49.0
98
60-140
1,1,1-Tdchloroethane
ug/L
50
47.4
95
60-140
1,1,2,2-Tetrachloroethane
ug/L
50
45.7
91
60-140
1,1,2-Trichloroethane
uglL
50
48.0
96
60-140
1,1-Dichloroethane
ug/L
50
43.8
88
60-140
1,1-Dichloraethene
ug/L
50
493
99
60-140
IJ-Dichlarapropene
ug/L
50
49.3
99
60-140
1 ,2,34rlchlorobenzene
uglL
50
52.3
105
60-140
1,2,3-Trichloropropane
ug/L
50
43.6
87
60-140
1,2,4-Trich1orobemzene
ug/L
50
51.7
103
60-140
1,2,4-Trimethylbenzene
ug/L
50
47.1
94
60-140
1,2-Dlbromo-3-chloropmpane
ug/L
50
48.5
97
60-140
1,2-Dibmmoethane(EDS)
ug/L
50
49.3
99
60-140
1,2-Dlchlombenzene
ug/L
50
48.5
97
60-140
1,2-Dichloroethane
ug/L
50
43.3
87
60-140
1,2-Dichlompropane
ug/L
50
47.4
95
60-140
1,3,5-Trimethylbenzene
uyl-
50
46.8
94
60-140
scoria pmamtetl an thIt pane an In the units Indicated by to Unlre column except xTere an alterna@unit is presented to Ne right of the result
REPORT OF LABORATORY ANALYSIS
This report seen not be reproduced, except In lull,
Date: 12/28/2022 0497 PM wiNOUt the written consent of Pace Analytical Services,LLC. Page 16 of 28
aceAnalytical®
Isee pecoubmtMe
QUALITY CONTROL DATA
Projed: MWNCVEMBER2022
Pace Project No.: 92637869
Pace Analytical Sam Ices, LLC
2225 amersiae or.
Asheville, NC 28804
(928)2547196
LABORATORY CONTROL SAMPLE:
Parameter
3847387
Units
Spike
Cane.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,3-Dichlorobenzene
ug/L
50
48.6
97
60-140
1,3-0ichloropropane
ug/L
50
46.8
94
60-140
1,4-Dichlorobenzene
ug/L
50
46.9
94
60-140
2,2-Dlchlompropane
ug/L
50
44.8
90
60-140
2-Chlorotoluene
ug/L
50
45.5
91
60-140
4-Chlorotoluene
ug/L
50
45.2
90
60-140
Benzene
uglL
50
45.6
91
60-140
Brorahenzene
ug1L
50
49.4
99
60-140
Bromochloromethane
ug/L
50
50.3
101
60-140
Bromodichloromethane
ug/L
50
46.4
93
60-140
Bromnic.
ug/L
50
49.4
99
60-140
Bromomelhane
ug/L
50
46.4
93
60-140
Carbon tetrachloride
ugh-
50
45.4
91
60-140
Chlarobenzene
ug/L
50
47.8
96
60-140
Chloroethane
ug/L
50
50.7
101
60-140
Chlaroform
ug/L
50
44.1
88
60-140
Chlaromethrne
ug/L
50
51.6
103
60-140
cis-1,2-Dlchloroethene
ug/L
50
43.5
87
60-140
cis-1,3-Dichloropropene
ug/L
50
46.9
94
60-140
Dibrcmochloromethane
ug/L
50
45.8
98
60-140
Dibromomethane
ug/L
50
53.7
107
60-140
Dichloradifluaromethanl
uglL
50
66 9
114
60-140
DllA.pinpyl ether
uglL
50
43.4
87
60-140
Etylbenzene
uglL
50
45.9
92
60-140
Hexachlom-1,3-butadlene
uglL
50
51.0
103
60-140
Isopropylbenzene(Cunt
ug/L
50
46.3
93
60-140
all Xylene
ug/L
100
91.7
92
60-140
Methyl-tert-butyl ether
ug/L
50
47.8
96
60-140
Methylene Chloride
ug/L
50
41.5
83
60-140
n-Butylbenzene
ug/L
50
46.3
93
60-140
n-Propylbenzene
ug/L
50
45.2
90
60-140
Naphthalene
ug/L
50
53.5
107
60-140
o-Xylene
ugh-
50
47.4
95
60-140
sec-Butylbenzene
ug/L
50
45.3
91
60-140
Styrene
ug/L
50
48.3
97
60-140
tert-Butylbenzene
uglL
50
40.1
80
60-140
Tetrachleethene
ugli-
50
50.7
101
60-140
Toluene
uglL
50
44.6
89
60-140
trans-1,2-Dichloroethene
ug/L
50
46.3
93
60-140
trans-1,3-0ichloropropane
ug/L
50
46.4
93
60-140
Trichloroethene
uglL
50
51.5
103
60-140
Trichlorotluoromethane
ug/L
50
42.7
85
60-140
Vinyl chloride
uglL
50
50.8
102
60-140
1,2-Dichloroelhane-d4(S)
%
92
70-130
4-Bramoflucrobenzene(S)
%
97
70-130
Toluene-de(S)
%
97
70-130
Results presented on this page an In the on Its Ind tested by Me"Wits" column exoeewhere on alternate unit is pros anted to Me right of the man It
REPORT OF LABORATORY ANALYSIS
This reach shall not be reproduced, except in full.
Date: 1212812022 04:07 PM without the wriaen wnsentof Pace Analytiai Services,LLC.
Page 17 of 28
aceAnalytical
Wessermishb9Fem
QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside or.
Asheville, NO 268N
(828)254-7176
Project: MWNCVEMBER2022
Pace Project No.: 92637869
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
3848920
3848921
MS
MSD
92638143002
Spike
Spike
MS
MSD
MS
MSD
%Rec
Parameter
Units
Result
Conc,
Conc.
Result
Result
%Rec
%Rec
Limits RED Dual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
24.6
25.2
123
126
60-140
2
1,1,1-1-achlorcethane
ug/L
ND
20
20
24.1
24.4
120
122
60-140
1
1, 1,2,2-Tetrachloroethane
ug/L
NO
20
20
23.3
23.8
117
119
80-140
2
1,1,2-Trichloroelhane
upi-
ND
20
20
24.2
24.9
121
125
60-140
3
1,1-Dichloroethane
ug/L
ND
20
20
22.4
22.9
112
115
60-140
2
1,1-Dichloroethene
m/L
NO
20
20
25.6
26.1
128
131
60-140
2
1,1-Dichloropropene
ug1L
NO
20
20
25.1
25.6
125
128
60-140
2
1,2,3-Trichlorobenzene
ug/L
NO
20
20
21.3
26.8
136
134
60-140
2
1,2,3-Trichloropropane
ug/L
ND
20
20
22.1
22.4
110
112
60-140
1
1,2,11-Trichlorobenzene
ug/L
ND
20
20
25.9
25.2
129
126
60-140
3
1,2,4-Trimethylbenzene
ug/L
ND
20
20
24.4
24.0
122
120
60-140
2
12-Dibromc-3-chloropropane
ug/L
ND
20
20
24.5
24.4
122
122
60-140
0
1,2-Dibromaethane (EDB)
ug/L
ND
20
20
25.2
25.2
126
126
60-140
0
1,2-Dlchlorohenzene
ug&
ND
20
20
25.0
25.0
125
125
60-140
0
IX-Dichloroethane,
ug/L
ND
20
20
22.2
22.7
111
114
60-140
2
1,2-Dichloropropane
ug/L
NO
20
20
24.4
24.7
122
124
60-140
1
1,3,5-Trimethylbenzene
uglL
NO
20
20
24.1
23.7
120
118
60-140
2
1,3-Dichlorobenzene
ug/L
NO
20
20
25.2
24.5
126
122
60-140
3
1,3-Dichloropropane
ug/L
ND
20
20
23.6
24.0
116
120
60-140
2
1,4-Dichlorobenzene
ug/L
ND
20
20
241
23.7
121
118
60-140
2
2,2-Dichloropropane
uglL
NO
20
20
22 9
23.3
114
117
60-140
2
2-Chloratoluene
ug/L
NO
20
20
23.6
23.3
118
116
60-140
1
4-Chloratoluene
ug/L
ND
20
20
23.3
23.1
117
116
60-140
1
Benzene
ug/L
ND
20
20
24.2
24.3
121
121
60-140
0
Bromobenzene
uglL
ND
20
20
25.9
25.5
129
128
60-140
1
Bromochlaromethane
ug/L
ND
20
20
25.8
26.2
129
131
60-140
1
Bromodlchimomethane
ug/L
ND
20
20
23.2
23.8
116
119
60-140
3
Bromoform
uglL
ND
20
20
23.7
24.3
119
121
60-140
2
Bromomethane
ug/L
NO
20
20
24.1
24.7
121
123
60-140
2
Carbon tetrachloride
ug/L
NO
20
20
23.3
23.0
117
118
60-140
1
Chlorobenzene
ug/L
ND
20
20
24.9
25.3
124
126
60-140
2
Chloroelhane
ug/L
ND
20
20
30.2
30.7
151
154
60-140
2 MI
Chloroform
ug/L
ND
20
20
21.8
22.4
109
112
60-140
3
Chlommethane
ug/L
NO
20
20
26.3
26.9
132
135
60-140
2
cis-1,2-Dionomethene
ug/L
NO
20
20
220
22.6
110
113
60-140
3
cis-1,3-Dichloropropene
ug/L
ND
20
20
23.5
23.8
117
119
60-140
1
Dibromochlaromelhane
ug/L
ND
20
20
24A
24.4
121
122
60-140
1
Dibromomethane
ug/L
ND
20
20
27.4
27.8
137
139
60-140
1
Dichlorodiflumomethane
u9/L
ND
20
20
30.0
30.4
150
152
80-140
1 M1
Diisopo pyl ether
ug/L
ND
20
20
21.7
22.2
109
Ill
60-140
2
Ethylbenzene
ug/L
NO
20
20
23.8
24.1
119
120
60-140
1
Hexachlorc-1,3-butadiens
ug/L
ND
20
20
28.1
24.7
131
124
60-140
6
Isopropylbenzene(Cummul
uglL
ND
20
20
24.0
24.0
120
120
60-140
0
all -Xylene
ug/L
NO
40
40
47.9
48.E
120
122
60-140
2
Methyl-lerl-butyl ether
uglL
ND
20
20
23.9
24.2
119
121
60-140
1
Methylene Chloride
ugh.
ND
20
20
18.7
19.2
93
96
60-140
3
Results pre6mted on
this page are In
the units Indicated
by del
colummi
except%vimm an alternate
unit Is presenbdta
Me m
u lbe result
REPORT OF
LABORATORY ANALYSIS
This
report shall not be, reproduced,
except In full.
Date: 12/281202204:07PM
without the
written consent of Pace Analytical services,LLC.
Page 18 of 28
aceAnalyticale
,mospsnnea.wm
QUALITY CONTROL DATA
Pace Analytical Services, LLL
2225 Rlversim, Dr.
Asheville, NC 26e04
(628)254-]1]6
Project: MW NOVEMBER 2022
Pace Project No.: 92637869
MATRIX SPIKE& MATRIX SPIKE
DUPLICATE:
3848920
3848921
MS
MSD
92636143002
Spike
Spike
MS
MSD
MS
MSD
%Rec
Parameter
Units
Result
Cone.
Can..
Result
Result
%Rec
%Rec
Limits
RPD Dual
n-Butylbenzene
ug/L
NO
20
20
23.1
22.2
116
111
60-140
4
n-Prapylbenzene
tai
ND
20
20
23 4
22.9
117
115
60-140
2
Naphthalene
ug/L
ND
20
20
27.7
27.4
139
137
60-140
1
a-Xylene
ug/L
NO
20
20
24.6
25.1
123
125
60-140
2
sec-Butylbenzene
ug/L
ND
20
20
23.4
22.9
117
115
60-140
2
Styrene
ug/L
NO
20
20
24.7
25.0
124
125
60-140
1
ted-Butylbenzene
ui
ND
20
20
20.9
20.6
105
103
60-140
1
Tehachlomethene
uglL
NO
20
20
26.3
26.2
131
131
60-140
0
Toluene
ug/L
ND
20
20
23.8
24.0
119
120
60-140
1
trans-1,2-Dichloroethene
uglL
ND
20
20
23.6
24.1
118
121
60-140
2
trans-1,3-Dichloropropene
ug/L
ND
20
20
23 2
23.6
116
118
60-140
2
Trichloroethene
ug/L
ND
20
20
26S
27.4
134
137
60-140
2
Trichloaftecromethan,
ug/L
ND
20
20
23.4
24.1
117
120
60-140
3
Vinyl chlo,id.
hall-
ND
20
20
26.2
27.0
131
135
60-140
3
1,2-Dichloroethanei(S)
%
87
86
70-130
4-BromoOuorobenzene(S)
%
95
97
70-130
Toluenei(S)
%
96
96
70-130
Results preauite4 on this page an In the units Ind icated by Me" ends column except where an alternate unit Is presented to the 09M of th a recall,
REPORT OF LABORATORY ANALYSIS
This start shall net be rap.dn,m , Mxcept in lNl,
Date: 12/28/2022 0407 PM without the written consent of Pace Analytical Services, L-C.
Page 19 of 28
A
aceAnalytical a
Moo'cral.bet.
QUALITY CONTROL DATA
Project: MW NOVEMBER 2022
Pace Project No.: 92637869
Pace Analytic at
Services, LLL
2325 Riverside Dr
Asheville, NC 28804
(828)254-71I6
OC Balch: 739252
Analysis Method:
SM 254OC-2015
OC Balch Method: SM 25400-2015
Analysis Description:
2540C Total Dissolved Solids
Laboratory:
Pace Analytical Sewage - Asheville
Associated Lab Samples: 92637869001,92637869002,92637869003
METHOD BLANK: 3847109
Matrix: Water
Associated Lab Samples: 92837869001,9263]869002,9263]869003
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Total Dissolved Solids
mg/L
NO 25.0
11/23/22 18:57
LABORATORY CONTROL SAMPLE: 3847110
Spike LCS
LCS %Rise
Parameter
Units
Cone. Result
%Rec Unable Callipers
Total Dissolved Solids
mg/L
250 250
100 90-110
SAMPLE DUPLICATE: 3847137
92637869001 Cup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L NO NO
SAMPLE DUPLICATE: 3847138
92637869002 DRIP
Parameter Units Result Result RED Qualifiers
Total Dissolved Solids mg/L 239 235 2
Results presmled on this page are In the units Indicated by to aults'column except Mere an alterna@unit Is presented to the Ham of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced except in run,
Date: 12/28/2022 04:07 PM without the values .,sent of Pace Analytical Services, L-C. Page 20 of 28
aceAnalytical
www.paeelabexem
QUALITY CONTROL DATA
Pace Analytical Servlces, LL6
2225 Rivarsitle 0r.
Asheville, NC 28804
(828)254-]1]6
Project: MW NOVEMBER 2022
Pace Project No.: 92637869
QC Batch: 738688 Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method'. EPA 300.E Rev 2.11993 Analysis 0.... jlion: 300.0 IC Anions
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92637869001, 9263]869002, 9263T869003
METHOD BLANK: 3844213 Matrix: Water
Associated Lab Samples: 92637669001, 9263T869002, 9263]869003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfate cri NO 1,0 11/22/22 15:44
LABORATORY CONTROL SAMPLE: 3844214
Spike LCS LCS %Rec
Parameter Units Con.. Result % Rao Limits Qualifiers
Sulfate mg/L 50 49.4 99 90-110
MATRIX SPIKE& MATRIX SPIKE DUPLICATE: 3844215 3844216
MS MSD
92637785001 Spike Spike MS MSD MS MSD A Rec
Parameter Units Result Conc. Cone. Result Result %Rao %Rec Limits RPD Dust
Sulfate mg/L 1.3 50 50 50.6 51.0 99 99 90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3844217 3844218
MS MSD
92637869002 Spike Spike MIS MSD MS MSD %Rec
Parameter Units Result Cann Conc. Result Result % Re. % Rao Limits RPD Qual
Sulfate mUIL TS 5D 50 57.3 69.8 100 104 90-110 4
Results preemted on th Is page are In the arts Indicated byte UnIts" column exceptxTere an alternate
REPORT OF LABORATORY ANALYSIS
This report shell not be repmdvc im, except In full,
Date: 12128/202204:07 PM without the written consent of Pace Analytical Services,I
Page 21 of 28
aceAnalytical a
wu^x.psni'marm
QUALITY CONTROL DATA
Pace Analytical generous, LLC
2225 Riverside or.
Ashoulle, NO 28804
Ri 7176
Project:
MW NOVEMBER 2022
Pace Project No.:
92637869
QC Batch:
740395
Analysis Method:
EPA 350.1 Rev 2.01993
OC Batch Method
EPA 35D.1, Rev 2.01993
Analysis Description:
350.1 Ammonia
Laboratory:
Pace Analytical Services - Asheville
Associated Lab Samples:
92637869001, 9263]869002, 92637869003
METHOD BLANK'. 3851988
Matrix:
Water
Associated Lab Samples: 92637869001, 92637869002, 92631869003
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Nitrogen, Ammonia
mg/L
ND
0.10
12/01=12:57
LABORATORY CONTROL SAMPLE:
3851989
Spike
LCS
LCS %Rec
Parameter
Units
Cant.
Result
%Rec Limits Qualifiers
Nitrogen, Ammonia
ni
5
5.0
100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3851990 3851991
MS MSD
92637782002 Spike Spike ME MSD MS MSD %Rec
Parameter Units Result Cant. Conc Result Result %Rec %Rec Limits RPD Qual
Nitrogen, Ammonia all 0.24 5 5 5.5 5.5 105 105 90-110 0
MATRIX SPIKE& MATRIX SPIKE DUPLICATE: 3851992
3851993
MS
MSD
92637786002 Spike
Spike
MS MSD MS
MSD
%Rec
Parameter Units Result Cont.
Cann
Result Result %Rec
%Rec
Limits RPD Qual
Nitrogen, Ammonia mg1L 3.3 5
5
8.6 8.5 106
106
90-110 0
Resul6 preamte6 on this page are In the on Its Ind lcaled by MeUrge mlumo exceptxLere an allernah unit Is presented to the Ham or the result
REPORT OF LABORATORY ANALYSIS
This revolt shall not be repmaucea, except In full,
Date: 121281202204:07 PM withom the wrote, co,ce,t of Pace Analytical Bevil LLC.
Page 22 of 28
aceAnalytical'
wuwparolabLpcm
QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)250.1176
Project'. MW NOVEMBER 2022
Pace Project No.: 92637869
QC Batch: 739521 Analysis Method: SM 531 OB-2014
QC Batch Method: SM 631 OB-2014 Analysis Description: 5310B TOC
Laboratory: Pace Analytical Services -Ashei
Associated Lab Samples: 92837869001, 92637869002,92637869003
METHOD BLANK: 3848016 Matrix: Water
Associated Lab Samples: 92637869001, 92639669002, 9263]869003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Organic Carbon ni NO 1.0 1112812214:18
LABORATORY CONTROL SAMPLE: 3848017
Spike LCS LCS %Rec
Parameter Units Can.. Result %Rec Limits Qualifiers
Total Organic Carbon all 25 24.7 99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3848018 3848019
MS MSD
92637828001 Spike Spike MS MSD MS VISO %Roo
Parameter Units Result Coal Conc. Result Result %Rec %Rec Until RPD Qual
Total Organic Carbon mg/L ND 25 25 25.2 25.7 100 102 90-110 2
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3848020 3848021
MS MSD
92637822004 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Dual
Total Organic Carbon mg/L 2.3 25 25 28.7 28.7 106 105 90-110 0
Reeulte preimted an MIS page are In the units Ind issued by Ne"Uses 'column except waste an alternate unit Is presen el to the tlpM of Me vault
REPORT OF LABORATORY ANALYSIS
The meet.ball not be reproduced, except In full,
Date: 12/281202204:07 PM without the written consent of Pace Analytical Services,LLC.
Page 23 of 28
aceAnalytical e
www.pereall
QUALIFIERS
Project: MW NOVEMBER 2022
Pace Project No.: 92637669
DEFINITIONS
Pace Analytical Services, LLC
2225 Riverside D,
Asheville, NC 28804
(B2b264-)17e
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTO -Too Numerous To Count
d - Estimated concentration above the adjusted method detection limit and below the adjusted repor ing limit.
Ml-Adjusted Method Detection Limit.
POL- Practical Ouantitation Limit.
RL- Repoding Limit -The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyle In a specific matrix.
S- Surrogate
1,2-Dlpheny1firydrezine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RAPID values.
-CS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP- Sample Duplicate
RPD - Relative Percent Difference
INC - Not Calculable.
SG - Silica Gel - CleanUp
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate fort Chlomethylvinyl ether.
A separate vial preserved! to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrelein and Acrylonitrile by EPA
Method 8260.
N-Nitmsodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total' may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TIN -The NELAC Institute.
ANALYTE QUALIFIERS
Mt Matrix spike recovery exceeded OC limits. Batch accepted based on laboratory control sample (LCS)recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reprotleceQ except in full.
Date: 12/28/202231 PM without the written consent of Pace Analytical Services,LLC.
Page 24 of 28
aceAnalyical
ses, cautbache
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Analytical Services, LLC
222E Riverside or.
Asheville, NC 28804
(828)2547176
Project:
Pace Project No.:
MW NOVEMBER 2022
92637869
Analytical
Lab ID
Sample ID
QC Batch Method
QC Balch
Analytical Method
Batch
92637869001
Q08V2
92637869002
ASBA1
92637869003
ASB-02
92637869001
Q88V2
EPA3005A
745581
EPA6020B
745722
92637869002
ASB-01
EPA3005A
745581
EPA6020B
745722
92637869003
ASB-02
EPA3005A
745561
EPA6020B
745722
92637869001
Q88V2
EPA7470A
742260
EPA7470A
742277
92637869002
ASB-01
EPA7470A
742260
EPA7470A
742277
92637869003
ASB-02
EPA 7470A
742260
EPA7470A
742277
92637869001
Q88V2
SM 6200B
739372
92637869002
ASB-01
SM 6200B
739372
92637869003
ASB-02
SM 6200B
739372
92637869001
Q88V2
SM 2540C-2015
739252
92637869002
ASB-01
SM 2540C-2015
739252
92637869003
ASB�02
SM 2540C-2015
739252
92637869001
QB8V2
EPA 300.0 Rev 2.11993
738688
92637869002
ASBl
EPA 300.0 Rev 2.11993
738688
92637869003
ASBA2
EPA 300.0 Rev 2.11993
73B68B
92637869001
Q88V2
EPA 350.1 Rev 2.01993
740395
92637869002
ASSA1
EPA 350.1 Rev 2.01993
740395
92637869003
ASS-02
EPA 350.1 Rev 2.01993
740395
92637869001
Q88V2
SM 531OB-2014
739521
92637869002
All
SM 5310B-2014
739521
92637869003
ASB-02
SM 5310B-2014
739521
REPORT OF LABORATORY ANALYSIS
This report shell not be mpm6uced, except In full,
Bate: 12/2812022 04:07 PM without the written consent of Pace Analytical Services, LLC,
Page 25 of 28
DC#_Titio: ENV-FRM-HUN1.0083 v01 _Sample Condition Upon Receipt'
ace'
a. roxu
Effective Date: B5/12/2022
Laboratory receiving samples,
Asheville Eden❑ Greenwood ❑ Huntersville ❑ Raleigh[) Mech= I«vtllen Atlanta❑ Kernersville❑
• • Client Name: ( WO# a673�
. 92 869
Project q:I
�c�u;d.S nElu
Courier; ❑red ex ❑urs ❑uses pcueer
El Commercial ace ❑Other._ 92637889
I
Custody Seal Present? Dyes O Seals Intact? ❑Yes (QNq 1 'G,_
,fit Dale/Initials Perzan Examinlitg Consents, I _1.1J
Packing Material: ❑Bubble Wrap Potable Bags ❑None ❑ Other Biological Tissue Frozen?
Thermometer: / '} TTT"' ❑Yes ON. ❑N/A
0IR.GunID: t�/I
TYpcaflce: Wet ❑clue []None'
Correction Factor:
CoolerTemp: "'" Add/Subtractl°CI TO Temp should be above freezing to WC
[]Samples out of temp a Bolo. Samples an Ice, <.mIng Presess.
Cooler Temp Correctdd(eC): 3 -Ci has begun.
USDA Regulated Soil (ILJ N/A, water,eample).
Did samples onglnate In a quarantine. Within the United States; CA, NY, RISC hid samples originate from a foreign source(internationally,
`
Comrnenss(DlscrvPanry:
Chain of Custody Present?
es
ONo
QN/A
1.
Samples Arrived within Hod Time?
es
No
- N A
2.
Short Held Time Aea1ysls(02 Iv.)?
be,
ON/A
3.
Rush Turn Around TIM a Requested?
vas
ONO
ON/A
A
Sufficient Volume?
ffYO,
Nn
ONJA
S.
Correct Contedl Used?
-Pace Containers Used?
es
ONo
EINO
ON/a
N/A
B.
Containers Intact?
QNa:
N/A'.
?.
Dissolved analysis:. Samples Field Filtered?
[]Yes
o
IN/A
gl
Sample Labels Match CCC?
dntludes.Date(Time(ID/Analysis .Maids
'(RYes
((°�
N,,
ON/A
B.
fleadspace In VDA Vials i>Rgmmlt
Y¢s
a
❑N/A
10.
Trip Blank Present?
Trip Blank Cu,omly Seals Present?
❑Yez
❑Yea
v
❑N[A
N/A
1L
COMMENTS/SAMPLE DISCREPANCY
I.Ot ID Of Spin containers:
CLIENT NOTIFICATION/RESOLUTION
Person con(actedf
Project Manager SCURF Review:
Project Manager SRFRevieW:
Qualtrax ID:. 69614
Daie/nme
Date:
Date:
Page 26 of 28
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Page 27 of 28
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"Check mark: top half of box IfrPH..and/or dechlorination Project:#
is verified and within the acceptance range for
preservation samples...
EA[epthms'VOA, colderm,T000f and Grease,DRO/Bo15(water) DOC, tLHg
**Bottom half of boa 1,to list number of bottles
*"Check all unpreserved.Nitrates for chlorine
PM: UP Our. Oat.: 12/07/22
CLIENT: 93-0avidsonit
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PH Adjustment Log for Preserved Samples
Sample lD
Type of Preservative
PH upon retelpt
Oate peeservaalodaJJmtad
Time preaerv.1.
adjosted
AmaGntof PaaerealIva
.added'
LORM:
Note: whenever mere s a murepa., wneco:a na: u: yu: mm., w^........ ,^•••v.•............. _......... __ __..... _._...
Onnorhold, lntortert preservallea,oul-1 W-11p,ln[orrect cont-nno-)
Quallrax Document ID: 70677
Page 2 of 2
Page 28 of 28
pxumentNumbu:P-CAI4PLD�aJ1+ev.et
Name and Affiliation(Sampler(s): k ;Date:
Data Shed
Nameand A(dliatian (Inspector): ~'�S4 ll d f tion
Weli N:__M l' Q d?✓7- Well LackedO)
Well Diametcx: �: '1. q Comtmctim: (if- feel/StamlessSteel) ._.
Total WellDeptlt. �d.W Jt MuitlPactor:-/6S PIRa&aa/t21%,atazv.dl
Static Wateitxvel .,Ei.@ Ca'singVolume: Jdf gall°ca .
Height of WaterColumn: CaL 3 Volumes: 3_ayZ'�! gaU°ds
. Pmn intakP(N;o� -
Y ge bdornrnl=on
I, ! }!-. Staet_ )U=J� Pinuh'.N�O PuxgxIUte'.---rhv v/-:...�
b,✓ Total VolumePucged. �7 .(`.O_, (Bail
Nuging Method l''i_f��—:--
5amnlu. teInfofmation
Date Collected, �/ JA/,M__ Time Collecti( 1p ) �,n,J e✓I ��b
SamplivgEquipmeatUsed: f9 a,.iJ a)..� -. hmteumentN:_ istt
qdred
�-
BoRleType li'esex'VatJnll
V;✓ Pn;
`�JJW
9JYl
Field bTeasmem- tdlOU e t'ons//4-.r
¢ Tur6¢ht
Sample Temp Tune _'-1�--- Y-
y'r Pe2+rag/L:_ _—Tune-_-
DissOxy(mg/L)._—Tune--
(� J / µh Res, C'J (mg/LW9/L):_-
SpecificCond(n5): Tan n C T>se�—
S , F Lu'Y Odox: V-0 L
Sample pft (s.a ): ) Time _
) tf'.i A eazance:�La.2 Tnne ._.._......
ReDox(mV): itf __Tune:._ Pp--Txme_.--
ReDox (FH value):YSI ProPIVs+200mV l=' -Othe':
General/WeathesObsexvatim+s_. —.- Temp — Al /s (°•� Wind a, (MP')
(suxmy/cloudy/eauty)
'4,Q-.. Date: /�.f/. ✓y_- -----�
Sampler Signature '�.------- —__�
LT�t`idity
�ft)
Spec. Re➢ax nmavedTime Temp DL9s Oxy CondP,(su.)Levpurged(m6/L) (u5) }' DI U ro sV) ) (ga5ans/) r
1I
Document Name: Document Issued July 28,2016
1 dArralyNcai" Field Data 9lzeet
Document Number; Issueing Authority::
F CARTEED-001,Mv.01 Pace Huntersville Quality'. Office
I it:}) -ram
s
Client: 0/ t
i Location;
Project:
Well ID:-G % C/
Stabilization Test
®®®®®®®®®®
• I VA 0 G 1 Y� u
pommentN Aieid daln5h¢et Pa a tai_
iw ro
h� �iYehe
D tN Ukv HCAh FY.O.uor iM er
I I Wagnuuwnryr
09t
Field Data 53ieet ,
iV t.f...
�(<alft- reolec(.N:
Client:.�li_-,- .----....-Lacnfionf
Nahteand Affiliation (Sa(nplel•(s) %t'i/;S
f�Js
Naxneand-Afladon
W'llI fo5utahon
WeIIIU. <F1 JR u L-- —
WeRlbelwd' /NO)
/
Construction. -(I Steel/Stniiiless.$ieeY) _
WEADiwnetor •%-
Total Well Depth: /`T'3 `Y0 ft
Mom Pactox'l_, t`2kadlaf/ll)lx314 141 '
State Water Level.•' 7"E 1t
Casing Volume. 6�diia
-
%lift
Qeight of Water Colurfsn',���
Cut d Volumes: �t 0 �� gallau
-
Pwnp Intake•_)_) -�Yt -� _.
Date Purged:_/-�' 7=Start,
ILI
)`� Fmish- l �aIurge ltnte;.�. �.
Puiging Method• tn,b
--7otalValuifte Paged:
Szmph�informatinn g-
Date Collected }I/_J
frrr
Tune Collrew (aixl/pm) 4_'
j
Sampling Egwpment[Jsrd:. �en ,�f �;__
lnatrumPinib NS,.:'—/("sFFnG%!GJ-Y'f'
pBsttle l}/pe
PFuaeC7ation alYels Required .
V_Af � �
L
.�_
I (tq"r,
N! .
Field M t¢ uienta/Observahons
3i Tnne�'i
Sant le'femp( J.'
p
_Turbidity(nta)
-
Dlss Ozy (mg/L) �L%+-�__ Tnne
S Y s pe 2+tii6/L _ Time
Specific Cond (us): j, �- Time..)•,"
T"j- lies. Cl (m6/L�(µg/L).__,__�Tmte
c:...;..i,, a_n�'„ ,. �. A 5 T7m2:
� s 4-¢=0dor:__.�✓Y^s c Time: _/ —�-
ReUox (mV): ✓/iw G.. .._.�Tistte:
ReDox (alvalhe):ySTproPlus+200mV—
General/VVeatlrer
.. _(surety/cldudy/rainy) TeirLP' •�.6m Wind � _(mph).
Samplor•Signatuee��--=—Da[e:.1_� _� .. � _...
Time Temp. Diss Ozy.
Purged CC) (mg/L)
fo
ReDaz Turbidity volwne WateYhntdved other ,
(rcv) I (nm) Peellnns/mis) level (ft)
DocumentNa..er
Document lu ed ry0vember 27,2018
of
Pieldnut.sheet
-
Page
-
Document Number.
luue AuLLiorh Y
P-CAR-FLD.001.rev.02
:i,
Pace Fluete.,rille Quality Office
Client:.
Location: V' +-t ° n ti p-. any
Project:
Well ID:
Reviewed Date and
Stabilization TeSt
1Nall Diameter
.l3vlttplieafian Faatar""
1.
0.0409
.2
0:0413
' i.625
0.Y080
0.1630
0.3670
4
0.6530
--
6
Y.+tfi ;0
8:
2.6100
Tinie
;Purged
Temp.
(IC)
Dies O%y.
(rng/L)
Spec.
Cond.
(US)l
pH (s.u)
ReOox (mV).
Turbidity
ntu )
Volume Removed
)g allons/oils)
circle one
Water level
((t)
Other
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Dot m IN .Tielddata 6lw t Po_
- n f /- .p.1°3A(IdlyNL81 Issuirtga zFo�lty PazeH.
/� Oesument Nu 1e'F-(.AR-FLD-001-Office
L
Field DataSheet
(M"t:_.1�� __Location:
•1G
Name and Affiliation (6ampler(s) �. NeldDawShwtRevI—
Nameand Affiliation (Inspect(r):_
--��`---- By:
Date:
Well information
,�...®—m
Wallfl) >� '0 d-
WellLoaked NO)
_
Well Diameter �' /
Constitution, (P C feel/Stainless Steel)
Totat Well Depth 0 J_ ,ft
Mliltt PaCfW` ("0.sad;ns/12)tr319xz99]
Static Water Level: T,o_� ft
CasingVVlumer-Q:u > gallons
Ca1.3Volumes:. "110
Height of WaterColumnr_"_t
.gallons
Pump Intake it
Pmxe lnPoEmakio,;l d hn/M{f
Date Purge1_/_/__1"'Snrt: ��'�"�� piitish: �`F `�PnrgeRateJ�
Purging Method'_ e L ;_U f _ TOtal Volume Purged , 0,9(BaRou'9/(�
9mm�b1l¢Infornlatlo - -
DateCollerted__}1/_.��- Time Collected:.
Sampling SgNpmeatUsmh 1_t'1241 d Instrument lD. �.L' ,
Bottle Type- Preservation Amdysra Regvi ed. . --
fF✓AFL-- !/Go (( -
- -- -7-0
Field Measure ts/Observahons tF I.Lir
Sample Temp (q 1 5 _, r _Time: J'F4"J ,'Lucuiclity (ntu) 2 k. Time; _._
Dus Oxy(mg/L)__�_,5- Time.
Six,cific Cond. uu: A4. (, lime:J`Y ' Res C.(mg/LU(Ng/L):`_T�ime'.
Sample phsu 5 .70 Time: /4T Odm. _✓Jdi _, Time:
ReDax (mV): G jr V Time: I DWI APAaeaeance: (,(?e, —:rime.
�
ReDox(RH vahte):YSI PraPhts+200mV.1y -Otherr':,.------Tape:. -
Geirmn/Weathec Obaervafions "l Vil -- ---
_-(sunny/cloudy/ramy)'r mPCrr_CF) Wind .✓_(mph)
Sampler
SPo° ReDOx Turbrdit Yore 'Water
"T:ep. Dins Oxy Cont. pH (s.uJ y xemaverl leel (t Otrter
)jmg/L)(aS) oDo (nor) 'orots)() .Ill h?� azl. '�S.l s/i%.. 2f5'
(te-ri