WQ0003698_Groundwater Monitoring Report July 2023_20230727

#=CL#
July 27, 2023
LIMS USE: FR - TIM HORTON
LIMS OBJECT ID: 92677108
92677108
Project:
Pace Project No.:
RE:
Mr. Tim Horton
City of Marion
3982 NC Hwy 226 South
Marion, NC 28752
MONITORING WELLS
Dear Mr. Horton:
Enclosed are the analytical results for sample(s) received by the laboratory on July 12, 2023. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Jonathan W Biddix
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 1 of 26
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92677108
MONITORING WELLS
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 2 of 26
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92677108
MONITORING WELLS
Lab ID Sample ID Matrix Date Collected Date Received
92677108001 MW-3 Water 07/12/23 11:20 07/12/23 17:40
92677108002 MW-2 Water 07/12/23 12:10 07/12/23 17:40
92677108003 MW-4 Water 07/12/23 13:10 07/12/23 17:40
92677108004 MW-1R Water 07/12/23 15:20 07/12/23 17:40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 3 of 26
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92677108
MONITORING WELLS
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92677108001 MW-3 EPA 200.8 Rev 5.4 1994 6 PASI-AKRL
SM 4500-H+B-2011 1 PASI-ASMS
EPA 300.0 Rev 2.1 1993 4 PASI-ACDC
EPA 350.1 Rev 2.0 1993 1 PASI-AEGC
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 2 PASI-AMFO
SM 4500-P E-2011 1 PASI-AJP1
92677108002 MW-2 EPA 200.8 Rev 5.4 1994 6 PASI-AKRL
SM 4500-H+B-2011 1 PASI-ASMS
EPA 300.0 Rev 2.1 1993 4 PASI-ACDC
EPA 350.1 Rev 2.0 1993 1 PASI-AEGC
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 2 PASI-AMFO
SM 4500-P E-2011 1 PASI-AJP1
92677108003 MW-4 EPA 200.8 Rev 5.4 1994 6 PASI-AKRL
SM 4500-H+B-2011 1 PASI-ASMS
EPA 300.0 Rev 2.1 1993 4 PASI-ACDC
EPA 350.1 Rev 2.0 1993 1 PASI-AEGC
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 2 PASI-AMFO
SM 4500-P E-2011 1 PASI-AJP1
92677108004 MW-1R EPA 200.8 Rev 5.4 1994 6 PASI-AKRL
SM 4500-H+B-2011 1 PASI-ASMS
EPA 300.0 Rev 2.1 1993 4 PASI-ACDC
EPA 350.1 Rev 2.0 1993 1 PASI-AEGC
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 2 PASI-AMFO
SM 4500-P E-2011 1 PASI-AJP1
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 4 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677108
MONITORING WELLS
Sample:MW-3 Lab ID:92677108001 Collected:07/12/23 11:20 Received:07/12/23 17:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method:
Pace Analytical Services - Charlotte
Monitoring Well Data
Performed by Pace 07/27/23 15:181
Collected By Ryan
Byas
07/27/23 15:181
Collected Date 7/12/23 07/27/23 15:181
Collected Time 11:20 07/27/23 15:181
pH 5.1 Std. Units 07/27/23 15:181
Temperature 26.5 deg C 07/27/23 15:181
Static Water Level 34.06 feet 07/27/23 15:181
Specific Conductance 114.2 umhos/cm 07/27/23 15:181
Oxygen, Dissolved 3.3 mg/L 07/27/23 15:18 7782-44-71
Total Well Depth 50.02 feet 07/27/23 15:181
Turbidity 9.6 NTU 07/27/23 15:181
Odor None 07/27/23 15:181
Appearance Clear 07/27/23 15:181
Analytical Method: EPA 200.8 Rev 5.4 1994 Preparation Method: EPA 200.8 Rev 5.4 1994
Pace Analytical Services - Asheville
200.8 MET ICPMS
Barium 323 ug/L 07/25/23 23:47 7440-39-307/22/23 11:383.0 0.64 3
Boron ND ug/L 07/25/23 04:59 7440-42-807/22/23 11:3850.0 8.5 1
Cadmium 0.52 ug/L 07/25/23 04:59 7440-43-907/22/23 11:380.20 0.060 1
Cobalt 2.8 ug/L 07/25/23 04:59 7440-48-407/22/23 11:381.0 0.050 1
Iron 478 ug/L 07/25/23 04:59 7439-89-607/22/23 11:3850.0 20.9 1
Manganese 85.8 ug/L 07/25/23 04:59 7439-96-507/22/23 11:382.0 1.0 1
Analytical Method: SM 4500-H+B-2011
Pace Analytical Services - Asheville
4500H+ pH, Electrometric
pH at 25 Degrees C 5.3 Std. Units 07/20/23 13:55 H30.10 0.10 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Bromide 0.11 mg/L 07/14/23 23:19 24959-67-90.10 0.060 1
Chloride 7.9 mg/L 07/14/23 23:19 16887-00-61.0 0.60 1
Fluoride ND mg/L 07/14/23 23:19 16984-48-80.10 0.050 1
Sulfate ND mg/L 07/14/23 23:19 14808-79-81.0 0.50 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia ND mg/L 07/26/23 09:19 7664-41-70.10 0.031 1
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total ND mg/L 07/26/23 03:18 7727-37-907/25/23 17:220.50 0.25 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/27/2023 03:56 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 5 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677108
MONITORING WELLS
Sample:MW-3 Lab ID:92677108001 Collected:07/12/23 11:20 Received:07/12/23 17:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 7.3 mg/L 07/14/23 01:14 14797-55-80.20 0.050 5
Nitrogen, Nitrite ND mg/L 07/14/23 00:58 14797-65-00.040 0.031 1
Analytical Method: SM 4500-P E-2011
Pace Analytical Services - Asheville
SM4500P-E, Phosphate, Ortho
Orthophosphate as P ND mg/L 07/14/23 04:120.050 0.012 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/27/2023 03:56 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 6 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677108
MONITORING WELLS
Sample:MW-2 Lab ID:92677108002 Collected:07/12/23 12:10 Received:07/12/23 17:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method:
Pace Analytical Services - Charlotte
Monitoring Well Data
Performed by Pace 07/27/23 15:311
Collected By Ryan
Byas
07/27/23 15:311
Collected Date 7/12/23 07/27/23 15:311
Collected Time 12:10 07/27/23 15:311
pH 6.4 Std. Units 07/27/23 15:311
Temperature 20.6 deg C 07/27/23 15:311
Static Water Level 18.96 feet 07/27/23 15:311
Specific Conductance 330.2 umhos/cm 07/27/23 15:311
Oxygen, Dissolved .80 mg/L 07/27/23 15:31 7782-44-71
Total Well Depth 38.02 feet 07/27/23 15:311
Turbidity 2.4 NTU 07/27/23 15:311
Odor Sulfur 07/27/23 15:311
Appearance Clear 07/27/23 15:311
Analytical Method: EPA 200.8 Rev 5.4 1994 Preparation Method: EPA 200.8 Rev 5.4 1994
Pace Analytical Services - Asheville
200.8 MET ICPMS
Barium 55.4 ug/L 07/25/23 05:04 7440-39-307/22/23 11:381.0 0.21 1
Boron 40.1J ug/L 07/25/23 05:04 7440-42-807/22/23 11:3850.0 8.5 1
Cadmium ND ug/L 07/25/23 05:04 7440-43-907/22/23 11:380.20 0.060 1
Cobalt 0.96J ug/L 07/25/23 05:04 7440-48-407/22/23 11:381.0 0.050 1
Iron 42200 ug/L 07/25/23 23:52 7439-89-607/22/23 11:3850020910
Manganese 1530 ug/L 07/25/23 23:52 7439-96-507/22/23 11:3820.0 10.2 10
Analytical Method: SM 4500-H+B-2011
Pace Analytical Services - Asheville
4500H+ pH, Electrometric
pH at 25 Degrees C 6.3 Std. Units 07/20/23 13:59 H30.10 0.10 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Bromide 0.071J mg/L 07/14/23 23:34 24959-67-90.10 0.060 1
Chloride 1.2 mg/L 07/14/23 23:34 16887-00-61.0 0.60 1
Fluoride ND mg/L 07/14/23 23:34 16984-48-80.10 0.050 1
Sulfate 0.71J mg/L 07/14/23 23:34 14808-79-81.0 0.50 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia 5.6 mg/L 07/26/23 11:54 7664-41-70.10 0.031 1
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total 5.8 mg/L 07/26/23 03:19 7727-37-907/25/23 17:220.50 0.25 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/27/2023 03:56 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 7 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677108
MONITORING WELLS
Sample:MW-2 Lab ID:92677108002 Collected:07/12/23 12:10 Received:07/12/23 17:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 0.027J mg/L 07/14/23 01:00 14797-55-80.040 0.010 1
Nitrogen, Nitrite ND mg/L 07/14/23 01:00 14797-65-0 M10.040 0.031 1
Analytical Method: SM 4500-P E-2011
Pace Analytical Services - Asheville
SM4500P-E, Phosphate, Ortho
Orthophosphate as P ND mg/L 07/14/23 04:150.050 0.012 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/27/2023 03:56 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 8 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677108
MONITORING WELLS
Sample:MW-4 Lab ID:92677108003 Collected:07/12/23 13:10 Received:07/12/23 17:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method:
Pace Analytical Services - Charlotte
Monitoring Well Data
Performed by Pace 07/27/23 15:401
Collected By Ryan
Byas
07/27/23 15:401
Collected Date 7/12/23 07/27/23 15:401
Collected Time 13:10 07/27/23 15:401
pH 5.0 Std. Units 07/27/23 15:401
Temperature 23.6 deg C 07/27/23 15:401
Static Water Level 20.55 feet 07/27/23 15:401
Specific Conductance 63.7 umhos/cm 07/27/23 15:401
Oxygen, Dissolved .5 mg/L 07/27/23 15:40 7782-44-71
Total Well Depth 35.37 feet 07/27/23 15:401
Turbidity .1 NTU 07/27/23 15:401
Odor None 07/27/23 15:401
Appearance Clear 07/27/23 15:401
Analytical Method: EPA 200.8 Rev 5.4 1994 Preparation Method: EPA 200.8 Rev 5.4 1994
Pace Analytical Services - Asheville
200.8 MET ICPMS
Barium 115 ug/L 07/25/23 05:09 7440-39-307/22/23 11:381.0 0.21 1
Boron ND ug/L 07/25/23 05:09 7440-42-807/22/23 11:3850.0 8.5 1
Cadmium 0.18J ug/L 07/25/23 05:09 7440-43-907/22/23 11:380.20 0.060 1
Cobalt 3.0 ug/L 07/25/23 05:09 7440-48-407/22/23 11:381.0 0.050 1
Iron 31.3J ug/L 07/25/23 05:09 7439-89-607/22/23 11:3850.0 20.9 1
Manganese 124 ug/L 07/25/23 05:09 7439-96-507/22/23 11:382.0 1.0 1
Analytical Method: SM 4500-H+B-2011
Pace Analytical Services - Asheville
4500H+ pH, Electrometric
pH at 25 Degrees C 5.4 Std. Units 07/20/23 14:03 H30.10 0.10 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Bromide 0.20 mg/L 07/15/23 00:36 24959-67-90.10 0.060 1
Chloride 2.2 mg/L 07/15/23 00:36 16887-00-61.0 0.60 1
Fluoride ND mg/L 07/15/23 00:36 16984-48-80.10 0.050 1
Sulfate ND mg/L 07/15/23 00:36 14808-79-81.0 0.50 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia ND mg/L 07/26/23 11:58 7664-41-70.10 0.031 1
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total ND mg/L 07/26/23 03:23 7727-37-907/25/23 17:220.50 0.25 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/27/2023 03:56 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 9 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677108
MONITORING WELLS
Sample:MW-4 Lab ID:92677108003 Collected:07/12/23 13:10 Received:07/12/23 17:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 3.3 mg/L 07/14/23 01:05 14797-55-80.040 0.010 1
Nitrogen, Nitrite ND mg/L 07/14/23 01:05 14797-65-00.040 0.031 1
Analytical Method: SM 4500-P E-2011
Pace Analytical Services - Asheville
SM4500P-E, Phosphate, Ortho
Orthophosphate as P ND mg/L 07/14/23 04:150.050 0.012 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/27/2023 03:56 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 10 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677108
MONITORING WELLS
Sample:MW-1R Lab ID:92677108004 Collected:07/12/23 15:20 Received:07/12/23 17:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method:
Pace Analytical Services - Charlotte
Monitoring Well Data
Performed by Pace 07/27/23 15:511
Collected By Ryan
Byas
07/27/23 15:511
Collected Date 7/12/23 07/27/23 15:511
Collected Time 15:20 07/27/23 15:511
pH 5.9 Std. Units 07/27/23 15:511
Temperature 31.4 deg C 07/27/23 15:511
Static Water Level 26.94 feet 07/27/23 15:511
Specific Conductance 62.62 umhos/cm 07/27/23 15:511
Oxygen, Dissolved 5.3 mg/L 07/27/23 15:51 7782-44-71
Total Well Depth 62.62 feet 07/27/23 15:511
Turbidity 8.9 NTU 07/27/23 15:511
Odor None 07/27/23 15:511
Appearance Clear 07/27/23 15:511
Analytical Method: EPA 200.8 Rev 5.4 1994 Preparation Method: EPA 200.8 Rev 5.4 1994
Pace Analytical Services - Asheville
200.8 MET ICPMS
Barium 33.4 ug/L 07/25/23 05:14 7440-39-307/22/23 11:381.0 0.21 1
Boron ND ug/L 07/25/23 05:14 7440-42-807/22/23 11:3850.0 8.5 1
Cadmium ND ug/L 07/25/23 05:14 7440-43-907/22/23 11:380.20 0.060 1
Cobalt 0.14J ug/L 07/25/23 05:14 7440-48-407/22/23 11:381.0 0.050 1
Iron 288 ug/L 07/25/23 05:14 7439-89-607/22/23 11:3850.0 20.9 1
Manganese 18.5 ug/L 07/25/23 05:14 7439-96-507/22/23 11:382.0 1.0 1
Analytical Method: SM 4500-H+B-2011
Pace Analytical Services - Asheville
4500H+ pH, Electrometric
pH at 25 Degrees C 6.2 Std. Units 07/20/23 14:07 H30.10 0.10 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Bromide ND mg/L 07/15/23 00:52 24959-67-90.10 0.060 1
Chloride ND mg/L 07/15/23 00:52 16887-00-61.0 0.60 1
Fluoride ND mg/L 07/15/23 00:52 16984-48-80.10 0.050 1
Sulfate ND mg/L 07/15/23 00:52 14808-79-81.0 0.50 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia ND mg/L 07/26/23 12:03 7664-41-70.10 0.031 1
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total ND mg/L 07/26/23 03:26 7727-37-907/25/23 17:220.50 0.25 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/27/2023 03:56 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 11 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92677108
MONITORING WELLS
Sample:MW-1R Lab ID:92677108004 Collected:07/12/23 15:20 Received:07/12/23 17:40 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLPQL
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 0.062 mg/L 07/14/23 01:08 14797-55-80.040 0.010 1
Nitrogen, Nitrite ND mg/L 07/14/23 01:08 14797-65-00.040 0.031 1
Analytical Method: SM 4500-P E-2011
Pace Analytical Services - Asheville
SM4500P-E, Phosphate, Ortho
Orthophosphate as P 0.018J mg/L 07/14/23 04:170.050 0.012 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/27/2023 03:56 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 12 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92677108
MONITORING WELLS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
788276
EPA 200.8 Rev 5.4 1994
EPA 200.8 Rev 5.4 1994
200.8 MET
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92677108001, 92677108002, 92677108003, 92677108004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4086502
Associated Lab Samples:92677108001, 92677108002, 92677108003, 92677108004
Matrix:Water
AnalyzedMDL
Barium ug/L ND 1.0 07/25/23 03:540.21
Boron ug/L ND 50.0 07/25/23 03:548.5
Cadmium ug/L ND 0.20 07/25/23 03:540.060
Cobalt ug/L ND 1.0 07/25/23 03:540.050
Iron ug/L ND 50.0 07/25/23 03:5420.9
Manganese ug/L ND 2.0 07/25/23 03:541.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4086503LABORATORY CONTROL SAMPLE:
LCSSpike
Barium ug/L 51.850 104 85-115
Boron ug/L 50.650 101 85-115
Cadmium ug/L 52.350 105 85-115
Cobalt ug/L 53.550 107 85-115
Iron ug/L 13501250 108 85-115
Manganese ug/L 53.350 107 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4086504MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92676993002
4086505
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Barium ug/L 50 103 70-130105 2 205010.5 62.0 63.0
Boron ug/L 50 97 70-13092 3 205066.8 116 113
Cadmium ug/L 50 101 70-130102 1 2050ND50.7 51.2
Cobalt ug/L 50 104 70-130104 0 2050ND52.5 52.7
Iron ug/L 1250 99 70-130100 0 201250270039403950
Manganese ug/L 50 105 70-130105 0 2050197249249
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4086506MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92677318002
4086507
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Barium ug/L 50 103 70-130102 1 20501.4 53.1 52.7
Boron ug/L 50 100 70-13099 1 2050ND53.7 53.2
Cadmium ug/L 50 101 70-130102 0 2050ND50.7 50.8
Cobalt ug/L 50 106 70-130105 1 2050ND52.9 52.6
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/27/2023 03:56 PM
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Page 13 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92677108
MONITORING WELLS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4086506MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92677318002
4086507
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Iron ug/L 1250 108 70-130107 1 201250ND14001390
Manganese ug/L 50 106 70-130105 1 20505.4 58.4 57.7
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/27/2023 03:56 PM
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Page 14 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92677108
MONITORING WELLS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
788076
SM 4500-H+B-2011
SM 4500-H+B-2011
4500H+B pH
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92677108001, 92677108002, 92677108003, 92677108004
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92678150001
4085470SAMPLE DUPLICATE:
pH at 25 Degrees C Std. Units 6.7 H31106.7
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92678212001
4085471SAMPLE DUPLICATE:
pH at 25 Degrees C Std. Units 12.6 E,H301012.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/27/2023 03:56 PM
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2225 Riverside Dr.
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Page 15 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92677108
MONITORING WELLS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
786751
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
300.0 IC Anions
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92677108001, 92677108002, 92677108003, 92677108004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4079032
Associated Lab Samples:92677108001, 92677108002, 92677108003, 92677108004
Matrix:Water
AnalyzedMDL
Bromide mg/L ND 0.10 07/14/23 16:370.060
Chloride mg/L ND 1.0 07/14/23 16:370.60
Fluoride mg/L ND 0.10 07/14/23 16:370.050
Sulfate mg/L ND 1.0 07/14/23 16:370.50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4079033LABORATORY CONTROL SAMPLE:
LCSSpike
Bromide mg/L 2.52.5 100 90-110
Chloride mg/L 50.750 101 90-110
Fluoride mg/L 2.52.5 100 90-110
Sulfate mg/L 49.950 100 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4079034MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92677218001
4079035
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Bromide mg/L 2.5 102 90-110103 1 102.5ND 2.5 2.6
Chloride mg/L 50 103 90-110104 1 10505.0 56.3 56.9
Fluoride mg/L 2.5 98 90-110100 2 102.50.11 2.6 2.6
Sulfate mg/L 50 100 90-110102 1 1050ND51.0 51.7
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4079036MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92676944002
4079037
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Bromide mg/L 2.5 108 90-110106 2 102.50.53 3.2 3.2
Chloride mg/L 50 108 90-110106 0 1050162216215
Fluoride mg/L M12.5 0 90-1100 102.5ND ND ND
Sulfate mg/L M1508990-11089 0 105035.1 79.7 79.6
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/27/2023 03:56 PM
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2225 Riverside Dr.
Asheville, NC 28804
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Page 16 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92677108
MONITORING WELLS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
788937
EPA 350.1 Rev 2.0 1993
EPA 350.1 Rev 2.0 1993
350.1 Ammonia
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92677108001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4089440
Associated Lab Samples:92677108001
Matrix:Water
AnalyzedMDL
Nitrogen, Ammonia mg/L ND 0.10 07/26/23 08:360.031
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4089441LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Ammonia mg/L 5.25 104 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4089442MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92677977001
4089443
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Ammonia mg/L 5 102 90-110102 0 1051.2 6.3 6.3
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4089444MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92677978001
4089445
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Ammonia mg/L 5 101 90-110105 1 10514.9 19.9 20.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/27/2023 03:56 PM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 17 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92677108
MONITORING WELLS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
789259
EPA 350.1 Rev 2.0 1993
EPA 350.1 Rev 2.0 1993
350.1 Ammonia
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92677108002, 92677108003, 92677108004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4090787
Associated Lab Samples:92677108002, 92677108003, 92677108004
Matrix:Water
AnalyzedMDL
Nitrogen, Ammonia mg/L ND 0.10 07/26/23 11:510.031
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4090788LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Ammonia mg/L 5.15 102 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4090789MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92677108002
4090790
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Ammonia mg/L 5 96 90-11096 0 1055.6 10.4 10.4
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4090791MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92677108003
4090792
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Ammonia mg/L 5 103 90-110102 1 105ND5.2 5.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/27/2023 03:56 PM
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Asheville, NC 28804
[phone]
Page 18 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92677108
MONITORING WELLS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
789051
EPA 351.2 Rev 2.0 1993
EPA 351.2 Rev 2.0 1993
351.2 TKN
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92677108001, 92677108002, 92677108003, 92677108004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4089877
Associated Lab Samples:92677108001, 92677108002, 92677108003, 92677108004
Matrix:Water
AnalyzedMDL
Nitrogen, Kjeldahl, Total mg/L ND 0.50 07/26/23 03:160.25
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4089878LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Kjeldahl, Total mg/L 9.910 99 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4089879MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92677108003
4089880
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Kjeldahl, Total mg/L 10 100 90-11098 3 1010ND10.2 10
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4089881MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92677108004
4089882
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Kjeldahl, Total mg/L 10 98 90-110100 2 1010ND9.8 10.0
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/27/2023 03:56 PM
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2225 Riverside Dr.
Asheville, NC 28804
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Page 19 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92677108
MONITORING WELLS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
786706
EPA 353.2 Rev 2.0 1993
EPA 353.2 Rev 2.0 1993
353.2 Nitrate + Nitrite, Unpres.
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92677108001, 92677108002, 92677108003, 92677108004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4078943
Associated Lab Samples:92677108001, 92677108002, 92677108003, 92677108004
Matrix:Water
AnalyzedMDL
Nitrogen, Nitrate mg/L ND 0.040 07/14/23 00:420.010
Nitrogen, Nitrite mg/L ND 0.040 07/14/23 00:420.031
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4078944LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Nitrate mg/L 1.51.5 99 90-110
Nitrogen, Nitrite mg/L 0.971 97 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4078945MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92677079001
4078946
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Nitrate mg/L 1.5 94 90-11098 3 101.50.064 1.5 1.5
Nitrogen, Nitrite mg/L 1 97 90-11099 2 1010.055 1.0 1.0
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4078947MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92677108002
4078948
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Nitrate mg/L 1.5 78 90-11080 2 101.50.027J 1.2 1.2
Nitrogen, Nitrite mg/L M118490-11086 2 101ND0.87 0.89
REPORT OF LABORATORY ANALYSIS
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Page 20 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92677108
MONITORING WELLS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
786714
SM 4500-P E-2011
SM 4500-P E-2011
SM4500P-E Phosphorus, Ortho
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92677108001, 92677108002, 92677108003, 92677108004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4078963
Associated Lab Samples:92677108001, 92677108002, 92677108003, 92677108004
Matrix:Water
AnalyzedMDL
Orthophosphate as P mg/L ND 0.050 07/14/23 04:100.012
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4078964LABORATORY CONTROL SAMPLE:
LCSSpike
Orthophosphate as P mg/L 0.250.25 99 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4078965MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92677148001
4078966
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Orthophosphate as P mg/L 0.25 98 90-110102 4 100.25ND 0.27 0.29
REPORT OF LABORATORY ANALYSIS
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Page 21 of 26
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92677108
MONITORING WELLS
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Analyte concentration exceeded the calibration range. The reported result is estimated.E
Sample was received or analysis requested beyond the recognized method holding time.H3
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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Page 22 of 26
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92677108
MONITORING WELLS
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92677108001 MW-3
92677108002 MW-2
92677108003 MW-4
92677108004 MW-1R
92677108001 788276 788606MW-3 EPA 200.8 Rev 5.4 1994 EPA 200.8 Rev 5.4 1994
92677108002 788276 788606MW-2 EPA 200.8 Rev 5.4 1994 EPA 200.8 Rev 5.4 1994
92677108003 788276 788606MW-4 EPA 200.8 Rev 5.4 1994 EPA 200.8 Rev 5.4 1994
92677108004 788276 788606MW-1R EPA 200.8 Rev 5.4 1994 EPA 200.8 Rev 5.4 1994
92677108001 788076MW-3 SM 4500-H+B-2011
92677108002 788076MW-2 SM 4500-H+B-2011
92677108003 788076MW-4 SM 4500-H+B-2011
92677108004 788076MW-1R SM 4500-H+B-2011
92677108001 786751MW-3 EPA 300.0 Rev 2.1 1993
92677108002 786751MW-2 EPA 300.0 Rev 2.1 1993
92677108003 786751MW-4 EPA 300.0 Rev 2.1 1993
92677108004 786751MW-1R EPA 300.0 Rev 2.1 1993
92677108001 788937MW-3 EPA 350.1 Rev 2.0 1993
92677108002 789259MW-2 EPA 350.1 Rev 2.0 1993
92677108003 789259MW-4 EPA 350.1 Rev 2.0 1993
92677108004 789259MW-1R EPA 350.1 Rev 2.0 1993
92677108001 789051 789226MW-3 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92677108002 789051 789226MW-2 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92677108003 789051 789226MW-4 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92677108004 789051 789226MW-1R EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92677108001 786706MW-3 EPA 353.2 Rev 2.0 1993
92677108002 786706MW-2 EPA 353.2 Rev 2.0 1993
92677108003 786706MW-4 EPA 353.2 Rev 2.0 1993
92677108004 786706MW-1R EPA 353.2 Rev 2.0 1993
92677108001 786714MW-3 SM 4500-P E-2011
92677108002 786714MW-2 SM 4500-P E-2011
92677108003 786714MW-4 SM 4500-P E-2011
92677108004 786714MW-1R SM 4500-P E-2011
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/27/2023 03:56 PM
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[phone]
Page 23 of 26
Page 24 of 26
Page 25 of 26
Page 26 of 26