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HomeMy WebLinkAboutWQ0003698_Groundwater Monitoring Report November 2023_20231127GW-59A COMPLIANCE REPORT FORM Permit # &)Q DDU 3 b4 (Submit one each monitoring period with GW-59 forms.) 1 Enter date monitoring results were due. V 7.UZ3 Will this monitoring report (GW-59 and GW-59A) YES NO be submitted after the established due date? 2 Was any required information missing on the GW-59 report forms? YES NO 54 IF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES NO identification plate, area overgrown, etc.)? If the answer is "Yes ", contact the Regional Office for guidance. 4 Are any monitored constituents equal to or above the established standards? YE NO If the answer to question 4 is "NO", skip to section 8. If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s) exceeding standards in the space provided below. 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO same constituent(s) in the same well(s) in the last two years? X If the answer to question 5 is "NO", skip to section 8. If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years). See, Aic,hA Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES NO X If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells maybe improperly located; contact the Regional Office. e., Co n 7 Is the permittee implementing previously approved actions required by the Division involving this YES NO groundwater quality problem? If the answer to question 7 is "YES", describe those actions in the space provided below. If the answer to question 7 is "NO" contact the Regional Office within 90 days; an evaluation may be required to determine the impact the waste disposal system is having at the review and compliance boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation, fines, and/or penalties. g The person completing this portion (G W-59A) of the monitoring report should sign below and submit this form with G W-59 forms for required wells to the address provided at the top of the current GW-59 form. I hereby acknowledge that the above information was evaluated and the information ubmitted in this report (Compliance ReportGW-59A) is true ancJ'complete to the best of my knowledge. 2 Signat of Permittee (or Aut on ed Agent) Date GW-59A 12/8/2003 Question #4 LAB DATA WHICH EXCEEDS PERMIT DATE MONITORING WELL # PARAMETER REPORTED DATA 11/2/2023 1 pH 5.6 Iron 464 ug/L 2 pH 6.4 Ammonia 4.2 mg/L Iron 23, 900 ug/L Manganese 1,490 ug/L 3 pH 5.2 Cobalt 2.4 ug/L Manganese 85.2 ug/L 4 pH 4.8 Cobalt 2.4 ug/L Manganese 123 ug/L QUESTION #5 LAB DATA WHICH EXCEEDS PERMIT FOR LAST 2 PREVIOUS YEARS 1 pH 5.7 2 Ammonia 6.4 mg/L Iron 43.9 mg/L Manganese 1,200 ug/L pH 6.3 3 Manganese 107 ug/L 4 pH 5.0 Manganese 172 ug/L pH 5.0 113 1 pH 5.9 2 Ammonia 5.4 mg/L Iron 27,100ug/L Manganese 1,250 ug/L pH 6.4 3 Cobalt 2.5 ug/L Manganese 98.5 ug/L pH 5.1 4 Manganese 86 ug/L pH 4.9 �3 y 1 pH 5.9 2 Ammonia 5.9 mg/L Cobalt 1.1 ug/L Iron 50,400 ug/L Manganese 1,310 ug/L 3 pH 5.2 Cobalt 2.2 ug/L Manganese 70.6 ug/L 4 pH 5 Cobalt 3.3 ug/L Manganese 126 ug/L 1 pH 5.9 2 pH 6.4 Ammonia 5.6 mg/L Iron 42,200 ug/L Manganese 1,530 ug/L 3 pH 5.1 Cobalt 2.8 ug/L Iron 478 ug/L Manganese 1 85.8 ug/L Page 1 4 pH 5 Cobalt 3.0 ug/L Manganese 124 ug/L 11%2%2023 r 1 pH 5.6 Iron 464 ug/L 2 pH 6.4 Ammonia 4.2 mg/L Iron 23, 900 ug/L Manganese 1,490 ug/L 3 pH 5.2 Cobalt 2.4 ug/L Manganese 85.2 ug/L 4 pH 4.8 Cobalt 2.4 ug/L Manganese 123 ug/L Page 2 to :. eon M &`W+ a) J —1 is 'c w9 NE N N 7 Qa E (4 L N ^ w o o U o a o CD }, S o C M Z N O Z O o O U LO '� ui L v J —1 o (p Q❑ M Q p p is a� r E = a W��# c O U z O aN Q NU o a) ik °' 0o 04' ZC) O �� c4) ZO Q E cW P El ❑ El El c umi g E E E E QQ E Z a� U VU' w U o N (�• 'a cM d O 0- m (o 42 c O_CD EOCl U O J v w CO o 0 0 ZT W Q 0 N 7 Z Ln C C O O Q D Ln V U +O+ 0 E w C LL 0 U) Q O U O M C Z CL O M W b. 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LY U N N 0 O N � W � o 2 > � o U `� n C9 U LQL Li CL LL 0 vai � cn n� J E E 1= r �Yaceo Project: MONITORING WELLS Pace Project No.: 92696570 Pace Analytical Services Ormond Beach 8 East Tower Circle, Ormond Beach, FL 32174 Alaska DEC- CS/UST/LUST Alabama Certification #: 41320 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity DoD-ANAB #:ADE-3199 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maine Certification M FLO1264 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification M 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 CERTIFICATIONS Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Ohio DEP 87780 Oklahoma Certification M D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 VirginiaNELAP Certification #: 460221 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 VirginiaNELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 37 ,41ace,o November 16, 2023 Mr. Tim Horton City of Marion 3982 NC Hwy 226 South Marion, NC 28752 RE: Project: MONITORING WELLS Pace Project No.: 92696570 Dear Mr. Horton: Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Enclosed are the analytical results for sample(s) received by the laboratory on November 02, 2023. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services -Asheville • Pace Analytical Services - Charlotte • Pace Analytical Services - Ormond Beach If you have any questions concerning this report, please feel free to contact me. Sincerely, Jonathan W Biddix jonathan.biddix@pacelabs.com 704-977-0978 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 37 �Yaceo SAMPLE ANALYTE COUNT Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MONITORING WELLS Pace Project No.: 92696570 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92696570001 MW-1R 92696570002 MW-2 92696570003 MW-3 92696570004 MW-4 EPA 200.7 EPA 200.8 EPA 8260D SM 4500-H+B_2011 EPA 300.0 Rev 2.1 1993 EPA 350.1 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 SM 4500-P E-2011 EPA 200.7 EPA 200.8 EPA 8260D SM 4500-H+B-2011 EPA 300.0 Rev 2.1 1993 EPA 350.1 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 SM 4500-P E-2011 EPA 200.7 EPA 200.8 EPA 8260D SM 4500-H+B-2011 EPA 300.0 Rev 2.1 1993 EPA 350.1 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 SM 4500-P E-2011 EPA 200.7 EPA 200.8 EPA 8260D SM 4500-H+B-2011 EPA 300.0 Rev 2.1 1993 EPA 350.1 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 SM 4500-P E-2011 REPORT OF LABORATORY ANALYSIS KC2 2 PASI-O EAP 4 PASI-O JJK 71 PASI-C SMS 1 PASI-A CDC 4 PASI-A NCF 1 PASI-A MFO 1 PASI-A MFO 2 PASI-A JP1 , 1 PASI-A TMA 2 PASI-O EAP 4 PASI-O JJK 71 PASI-C SMS 1 PASI-A CDC 4 PASI-A NCF 1 PASI-A MFO 1 PASI-A MFO 2 PASI-A JP1 1 PASI-A KC2 2 PASI-O EAP 4 PASI-O JJK 71 PASI-C SMS 1 PASI-A CDC 4 PASI-A NCF 1 PASI-A MFO 1 PASI-A MFO 2 PASI-A JP1 1 PASI-A KC2 2 PASI-O EAP 4 PASI-O JJK 71 PASI-C SMS 1 PASI-A CDC 4 PASI-A NCF 1 PASI-A MFO 1 PASI-A MFO 2 PASI-A JP1 1 PASI-A This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 37 Pace Analytical Services, LLC 2225 Riverside Dr. aceo Asheville, NC 28804 (828)254-7176 SAMPLE SUMMARY Project: Pace Project No.: MONITORING WELLS 92696570 Lab ID Sample ID Matrix Date Collected Date Received 92696570001 MW-1R Water 11/02/2312:55 11/02/2315:50 92696570002 MW-2 Water 11/02/2313:20 11/02/2315:50 92696570003 MW-3 Water 11/02/2311:50 11/02/2315:50 92696570004 MW-4 Water 11/02/2313:43 11/02/2315:50 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 37 �Yace- ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MONITORING WELLS Pace Project No.: 92696570 Sample: MW-1R Lab ID: 92696570001 Collected: 11/02/23 12:55 Received: 11/02/23 15:50 Matrix: Water Parameters Monitoring Well Data Performed by Collected By Collected Date Collected Time pH Temperature Static Water Level Specific Conductance Oxygen, Dissolved Total Well Depth Turbidity Odor Appearance 200.7 MET ICP Boron Iron 200.8 MET ICPMS Barium Cadmium Cobalt Manganese 8260D MSV Acetone Benzene Bromobenzene Bromochloromethane Bromodich loromethane Bromoform Bromomethane 2-Butanone (MEK) tert-Butyl Alcohol n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Date: 11/16/2023 11:22 AM Results Units PQL MDL DF Prepared Analyzed CAS No. Qual Analytical Method: Pace Analytical Services - Charlotte Pace 1 Matt 1 Reusch 11/2/23 1 12:55 1 5.6 Std. Units 1 14.5 deg C 1 29.05 feet 1 19.5 umhos/cm 1 10.2 mg/L 1 62.62 feet 1 13.6 NTU 1 No 1 clear w/ 1 fines Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 Pace Analytical Services - Ormond Beach 11/09/23 17:31 11/09/23 17:31 11/09/23 17:31 11/09/23 17:31 11/09/23 17:31 11/09/23 17:31 11/09/23 17:31 11/09/23 17:31 11/09/23 17:31 7782-44-7 11/09/23 17:31 11/09/23 17:31 11/09/23 17:31 11/09/23 17:31 ND ug/L 50.0 12.4 1 11/08/23 08:30 11/11/23 01:47 7440-42-8 464 ug/L 40.0 25.0 1 11/08/23 08:30 11/11/23 01:47 7439-89-6 Analytical Method: EPA 200.8 Preparation Method: EPA 200.8 Pace Analytical Services - Ormond Beach 38.5 ug/L 1.0 0.50 1 11/08/23 08:30 11/09/23 00:19 7440-39-3 ND ug/L 0.10 0.067 1 11/08/23 08:30 11/09/23 00:19 7440-43-9 ND ug/L 1.0 0.24 1 11/08/23 08:30 11/09/23 00:19 7440-48-4 9.0 ug/L 1.0 0.29 1 11/08/23 08:30 11/09/23 00:19 7439-96-5 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 3.0 1 11/07/23 05:59 67-64-1 ND ug/L 5.0 1.7 1 11/07/23 05:59 71-43-2 ND ug/L 5.0 1.9 1 11/07/23 05:59 108-86-1 ND ug/L 5.0 2.1 1 11/07/23 05:59 74-97-5 ND ug/L 5.0 1.1 1 11/07/23 05:59 75-27-4 ND ug/L 5.0 1.0 1 11/07/23 05:59 75-25-2 ND ug/L 10.0 6.0 1 11/07/23 05:59 74-83-9 ND ug/L 10.0 2.6 1 11/07/23 05:59 78-93-3 ND ug/L 100 11.6 1 11/07/23 05:59 75-65-0 ND ug/L 5.0 2.3 1 11/07/23 05:59 104-51-8 ND ug/L 5.0 2.2 1 11/07/23 05:59 135-98-8 ND ug/L 5.0 0.98 1 11/07/23 05:59 98-06-6 ND ug/L 5.0 2.2 1 11/07/23 05:59 56-23-5 ND ug/L 5.0 1.8 1 11/07/23 05:59 108-90-7 ND ug/L 10.0 4.1 1 11/07/23 05:59 75-00-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 6 of 37 SAMPLE ANALYTE COUNT Project: MONITORING WELLS Pace Project No.: 92696570 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Analytes Lab ID Sample ID Method Analysts Reported Laboratory PAST -A = Pace Analytical Services - Asheville PAST-C = Pace Analytical Services - Charlotte PASI-O = Pace Analytical Services - Ormond Beach REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 37 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: MONITORING WELLS Pace Project No.: 92696570 Sample: MW-1R Lab ID: 92696570001 Collected: 11/02/23 12:55 Received: 11/02/23 15:50 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Trichloroethene ND ug/L 5.0 1.8 1 11/07/23 05:59 79-01-6 Trichlorofluoromethane ND ug/L 10.0 1.5 1 11/07/23 05:59 75-69-4 1,2,3-Trichloropropane ND ug/L 5.0 1.1 1 11/07/23 05:59 96-18-4 1,2,4-Trimethylbenzene ND ug/L 5.0 2.0 1 11/07/23 05:59 95-63-6 1,3,5-Trimethylbenzene ND ug/L 5.0 2.1 1 11/07/23 05:59 108-67-8 Vinyl acetate ND ug/L 10.0 5.6 1 11/07/23 05:59 108-05-4 Vinyl chloride ND ug/L 5.0 1.8 1 11/07/23 05:59 75-01-4 m&p-Xylene ND ug/L 10.0 4.1 1 11/07/23 05:59 179601-23-1 o-Xylene ND ug/L 5.0 2.0 1 11/07/23 05:59 95-47-6 Surrogates 4-Bromofluorobenzene (S) 96 % 70-130 1 11/07/23 05:59 460-00-4 1,2-Dichloroethane-d4 (S) 94 % 70-130 1 11/07/23 05:59 17060-07-0 Toluene-d8(S) 106 % 70-130 1 11/07/23 05:59 2037-26-5 4500H+ pH, Electrometric Analytical Method: SM 4500-H+B-2011 Pace Analytical Services -Asheville pH at 25 Degrees C 6.0 Std. Units 0.10 0.10 1 11/09/23 12:24 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Bromide ND mg/L 0.10 0.060 1 11/03/23 22:27 24959-67-9 Chloride ND mg/L 1.0 0.60 1 11/03/23 22:27 16887-00-6 Fluoride ND mg/L 0.10 0.050 1 11/03/23 22:27 16984-48-8 Sulfate ND mg/L 1.0 0.50 1 11/03/23 22:27 14808-79-8 350.1 Ammonia Nitrogen, Ammonia 351.2 Total Kjeldahl Nitrogen Nitrogen, Kjeldahl, Total 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate Nitrogen, Nitrite SM4500P-E, Phosphate, Ortho Orthophosphate as P Date: 11/16/2023 11:22 AM Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Asheville ND mg/L 0.10 0.031 1 11/15/23 04:03 7664-41-7 Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Pace Analytical Services -Asheville ND mg/L 0.50 0.25 1 11/15/23 20:20 11/16/23 05:59 7727-37-9 Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville 0.052 mg/L 0.040 0.010 1 ND mg/L 0.040 0.031 1 Analytical Method: SM 4500-P E-2011 Pace Analytical Services -Asheville 0.014J mg/L 0.050 0.012 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 11/03/23 00:05 14797-55-8 11/03/23 00:05 14797-65-0 11/03/23 02:37 H3 Page 8 of 37 laceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: MONITORING WELLS Pace Project No.: 92696570 Sample: MW-lR Lab ID: 92696570001 Collected: 11/02/23 12:55 Received: 11/02/23 15:50 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Chloroform ND ug/L 5.0 1.3 1 11/07/23 05:59 67-66-3 Chloromethane ND ug/L 5.0 2.8 1 11/07/23 05:59 74-87-3 2-Chlorotoluene ND ug/L 5.0 1.8 1 11/07/23 05:59 95-49-8 4-Chlorotoluene ND ug/L 5.0 2.0 1 11/07/23 05:59 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 5.0 1.0 1 11/07/23 05:59 96-12-8 Dibromochloromethane ND ug/L 5.0 2.3 1 11/07/23 05:59 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 5.0 1.9 1 11/07/23 05:59 106-93-4 Dibromomethane ND ug/L 5.0 1.0 1 11/07/23 05:59 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 1.9 1 11/07/23 05:59 95-50-1 1,3-Dichlorobenzene ND ug/L 5.0 1.7 1 11/07/23 05:59 541-73-1 1,4-Dichlorobenzene ND ug/L 5.0 1.9 1 11/07/23 05:59 106-46-7 Dichlorodifluoromethane ND ug/L 5.0 1.8 1 11/07/23 05:59 75-71-8 1,1-Dichloroethane ND ug/L 5.0 2.3 1 11/07/23 05:59 75-34-3 1,2-Dichloroethane ND ug/L 5.0 2.1 1 11/07/23 05:59 107-06-2 1,2-Dichloroethene (Total) ND ug/L 5.0 5.0 1 11/07/23 05:59 540-59-0 1,1-Dichloroethene ND ug/L 5.0 2.2 1 11/07/23 05:59 75-35-4 cis-1,2-Dichloroethene ND ug/L 5.0 2.2 1 11/07/23 05:59 156-59-2 trans- l,2-Dichloroethene ND ug/L 5.0 2.2 1 11/07/23 05:59 156-60-5 1,2-Dichloropropane ND ug/L 5.0 2.1 1 11/07/23 05:59 78-87-5 1,3-Dichloropropane ND ug/L 5.0 1.9 1 11/07/23 05:59 142-28-9 2,2-Dichloropropane ND ug/L 5.0 2.4 1 11/07/23 05:59 594-20-7 1,1-Dichloropropene ND ug/L 5.0 2.8 1 11/07/23 05:59 563-58-6 cis- 1,3-Dichloropropene ND ug/L 5.0 2.0 1 11/07/23 05:59 10061-01-5 trans-1,3-Dichloropropene ND ug/L 5.0 2.2 1 11/07/23 05:59 10061-02-6 Diisopropyl ether ND ug/L 5.0 1.4 1 11/07/23 05:59 108-20-3 Ethylbenzene ND ug/L 5.0 1.8 1 11/07/23 05:59 100-41-4 Hexachloro-1,3-butadiene ND ug/L 5.0 4.8 1 11/07/23 05:59 87-68-3 2-Hexanone ND ug/L 10.0 4.2 1 11/07/23 05:59 591-78-6 Isopropylbenzene (Cumene) ND ug/L 5.0 2.1 1 11/07/23 05:59 98-82-8 p-Isopropyltoluene ND ug/L 5.0 1.0 1 11/07/23 05:59 99-87-6 Methylene Chloride ND ug/L 5.0 3.3 1 11/07/23 05:59 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 10.0 4.7 1 11/07/23 05:59 108-10-1 Methyl-tert-butyl ether ND ug/L 5.0 3.1 1 11/07/23 05:59 1634-04-4 Naphthalene ND ug/L 5.0 2.1 1 11/07/23 05:59 91-20-3 n-Propylbenzene ND ug/L 5.0 2.0 1 11/07/23 05:59 103-65-1 Styrene ND ug/L 5.0 1.9 1 11/07/23 05:59 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 5.0 1.1 1 11/07/23 05:59 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 5.0 2.0 1 11/07/23 05:59 79-34-5 Tetrachloroethene ND ug/L 5.0 1.8 1 11/07/23 05:59 127-18-4 Toluene ND ug/L 5.0 2.0 1 11/07/23 05:59 108-88-3 1,2,3-Trichlorobenzene ND ug/L 5.0 2.2 1 11/07/23 05:59 87-61-6 1,2,4-Trichlorobenzene ND ug/L 5.0 2.3 1 11/07/23 05:59 120-82-1 1,1,1-Trichloroethane ND ug/L 5.0 2.1 1 11/07/23 05:59 71-55-6 1,1,2-Trichloroethane ND ug/L 5.0 2.0 1 11/07/23 05:59 79-00-5 REPORT OF LABORATORY ANALYSIS IH,L1, V1 V1 V1 This report shall not be reproduced, except in full, Date: 11/16/2023 11:22 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 37 �Yaceo ANALYTICAL RESULTS Project: MONITORING WELLS Pace Project No.: 92696570 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: MW-2 Lab ID: 92696570002 Collected: 11/02/23 13:20 Received: 11/02/23 15:50 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Chloromethane ND ug/L 5.0 2.8 1 11/07/23 06:17 74-87-3 2-Chlorotoluene ND ug/L 5.0 1.8 1 11/07/23 06:17 95-49-8 4-Chlorotoluene ND ug/L 5.0 2.0 1 11/07/23 06:17 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 5.0 1.0 1 11/07/23 06:17 96-12-8 Dibromochloromethane ND ug/L 6.0 2.3 1 11/07/23 06:17 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 5.0 1.9 1 11/07/23 06:17 106-93-4 Dibromomethane ND ug/L 5.0 1.0 1 11/07/23 06:17 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 1.9 1 11/07/23 06:17 95-50-1 1,3-Dichlorobenzene ND ug/L 5.0 1.7 1 11/07/23 06:17 541-73-1 1,4-Dichlorobenzene ND ug/L 5.0 1.9 1 11/07/23 06:17 106-46-7 Dichlorodifluoromethane ND ug/L 5.0 1.8 1 11/07/23 06:17 75-71-8 1,1-Dichloroethane ND ug/L 5.0 2.3 1 11/07/23 06:17 75-34-3 1,2-Dichloroethane ND ug/L 5.0 2.1 1 11/07/23 06:17 107-06-2 1,2-Dichloroethene (Total) ND ug/L 5.0 5.0 1 11/07/23 06:17 540-59-0 1,1-Dichloroethene ND ug/L 5.0 2.2 1 11/07/23 06:17 75-35-4 cis-1,2-Dichloroethene ND ug/L 5.0 2.2 1 11/07/23 06:17 156-59-2 trans-1,2-Dichloroethene ND ug/L 5.0 2.2 1 11/07/23 06:17 156-60-5 1,2-Dichloropropane ND ug/L 5.0 2.1 1 11/07/23 06:17 78-87-5 1,3-Dichloropropane ND ug/L 5.0 1.9 1 11/07/23 06:17 142-28-9 2,2-Dichloropropane ND ug/L 5.0 2.4 1 11/07/23 06:17 594-20-7 1,1-Dichloropropene ND ug/L 5.0 2.8 1 11/07/23 06:17 563-58-6 cis-1,3-Dichloropropene ND ug/L 5.0 2.0 1 11/07/23 06:17 10061-01-5 trans-1,3-Dichloropropene ND ug/L 5.0 2.2 1 11/07/23 06:17 10061-02-6 Diisopropyl ether ND ug/L 5.0 1.4 1 11/07/23 06:17 108-20-3 Ethylbenzene ND ug/L 5.0 1.8 1 11/07/23 06:17 100-41-4 Hexachloro-1,3-butadiene ND ug/L 5.0 4.8 1 11/07/23 06:17 87-68-3 2-Hexanone ND ug/L 10.0 4.2 1 11/07/23 06:17 591-78-6 Isopropylbenzene (Cumene) ND ug/L 5.0 2.1 1 11/07/23 06:17 98-82-8 p-Isopropyltoluene ND ug/L 5.0 1.0 1 11/07/23 06:17 99-87-6 Methylene Chloride ND ug/L 5.0 3.3 1 11/07/23 06:17 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 10.0 4.7 1 11/07/23 06:17 108-10-1 Methyl-tert-butyl ether ND ug/L 5.0 3.1 1 11/07/23 06:17 1634-04-4 Naphthalene ND ug/L 5.0 2.1 1 11/07/23 06:17 91-20-3 n-Propylbenzene ND ug/L 5.0 2.0 1 11/07/23 06:17 103-65-1 Styrene ND ug/L 5.0 1.9 1 11/07/23 06:17 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 5.0 1.1 1 11/07/23 06:17 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 5.0 2.0 1 11/07/23 06:17 79-34-5 Tetrachloroethene ND ug/L 5.0 1.8 1 11/07/23 06:17 127-18-4 Toluene ND ug/L 5.0 2.0 1 11/07/23 06:17 108-88-3 1,2,3-Trichlorobenzene ND ug/L 5.0 2.2 1 11/07/23 06:17 87-61-6 1,2,4-Trichlorobenzene ND ug/L 5.0 2.3 1 11/07/23 06:17 120-82-1 1,1,1-Trichloroethane ND ug/L 5.0 2.1 1 11/07/23 06:17 71-55-6 1,1,2-Trichloroethane ND ug/L 5.0 2.0 1 11/07/23 06:17 79-00-5 Trichloroethene ND ug/L 5.0 1.8 1 11/07/23 06:17 79-01-6 REPORT OF LABORATORY ANALYSIS IH,L1, v1 v1 v1 This report shall not be reproduced, except in full, Date: 11/16/2023 11:22 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 37 �Yace"' ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MONITORING WELLS Pace Project No.: 92696570 Sample: MW-2 Lab ID: 92696570002 Collected: 11/02/23 13:20 Received: 11/02/23 15:50 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 11/09/23 17:34 Collected By Matt 1 11/09/23 17:34 Reucsh Collected Date 11/2123 1 11/09/23 17:34 Collected Time 13:20 1 11/09/23 17:34 pH 6.4 Std. Units 1 11/09/23 17:34 Temperature 15.1 deg C 1 11/09/23 17:34 Static Water Level 21.15 feet 1 11/09/23 17:34 Specific Conductance 267.6 umhos/cm 1 11/09/23 17:34 Oxygen, Dissolved .6 mg/L 1 11/09/23 17:34 7782-44-7 Total Well Depth 38.02 feet 1 11/09/23 17:34 Turbidity 2.2 NTU 1 11/09/23 17:34 Odor ND 1 11/09/23 17:34 Appearance Clear 1 11/09/23 17:34 200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 Pace Analytical Services - Ormond Beach Boron 34.1J ug/L 50.0 12.4 1 11/08/23 08:30 11/12/23 16:41 7440-42-8 Iron 23900 ug/L 40.0 25.0 1 11/08/23 08:30 11/12/23 16:41 7439-89-6 200.8 MET ICPMS Analytical Method: EPA 200.8 Preparation Method: EPA 200.8 Pace Analytical Services - Ormond Beach Barium 46.2 ug/L 1.0 0.50 1 11/08/23 08:30 11/09/23 00:24 7440-39-3 Cadmium ND ug/L 0.10 0.067 1 11/08/23 08:30 11/09/23 00:24 7440-43-9 Cobalt 0.74J ug/L 1.0 0.24 1 11/08/23 08:30 11/09/23 00:24 7440-48-4 Manganese 1490 ug/L 5.0 1.5 5 11/08/23 08:30 11/09/23 17:44 7439-96-5 8260D MSV Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 3.0 1 11/07/23 06:17 67-64-1 Benzene ND ug/L 5.0 1.7 1 11/07/23 06:17 71-43-2 Bromobenzene ND ug/L 5.0 1.9 1 11/07/23 06:17 108-86-1 Bromochloromethane ND ug/L 5.0 2.1 1 11/07/23 06:17 74-97-5 Bromodichloromethane ND ug/L 5.0 1.1 1 11/07/23 06:17 75-27-4 Bromoform ND ug/L 5.0 1.0 1 11/07/23 06:17 75-25-2 Bromomethane ND ug/L 10.0 6.0 1 11/07/23 06:17 74-83-9 v2 2-Butanone (MEK) ND ug/L 10.0 2.6 1 11/07/23 06:17 78-93-3 tert-Butyl Alcohol ND ug/L 100 11.6 1 11/07/23 06:17 75-65-0 n-Butylbenzene ND ug/L 5.0 2.3 1 11/07/23 06:17 104-51-8 sec-Butylbenzene ND ug/L 5.0 2.2 1 11/07/23 06:17 135-98-8 tert-Butylbenzene ND ug/L 5.0 0.98 1 11/07/23 06:17 98-06-6 Carbon tetrachloride ND ug/L 5.0 2.2 1 11/07/23 06:17 56-23-5 Chlorobenzene ND ug/L 5.0 1.8 1 11/07/23 06:17 108-90-7 Chloroethane ND ug/L 10.0 4.1 1 11/07/23 06:17 75-00-3 Chloroform ND ug/L 5.0 1.3 1 11/07/23 06:17 67-66-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/16/2023 11:22 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 37 �Yaceo Project: MONITORING WELLS Pace Project No.: 92696570 Sample: MW-3 Parameters Monitoring Well Data Performed by Collected By Collected Date Collected Time pH Temperature Static Water Level Specific Conductance Oxygen, Dissolved Total Well Depth Turbidity Odor Appearance 200.7 MET ICP Boron Iron 200.8 MET ICPMS Barium Cadmium Cobalt Manganese 8260D MSV Acetone Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) tert-Butyl Alcohol n-Butylbenzene sec-Butylbenzene tert-Butyl benzene Carbon tetrachloride Chlorobenzene Chloroethane Date: 11/16/2023 11:22 AM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Lab ID: 92696570003 Collected: 11/02/23 11:50 Received: 11/02/23 15:50 Matrix: Water Results Units PQL MDL DF Prepared Analyzed CAS No. Qual Analytical Method: Pace Analytical Services - Charlotte Pace 1 11/09/23 17:40 Matt 1 11/09/23 17:40 Reusch 11 /2/23 1 11/09/23 17:40 11:50 1 11/09/23 17:40 5.2 Std. Units 1 11/09/23 17:40 13.5 deg C 1 11/09/23 17:40 35.40 feet 1 11/09/23 17:40 115.3 umhos/cm 1 11/09/23 17:40 4.0 mg/L 1 11/09/23 17:40 7782-44-7 50.02 feet 1 11/09/23 17:40 9.7 NTU 1 11/09/23 17:40 ND 1 11/09/23 17:40 Clear w/ 1 11/09/23 17:40 Fines Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 Pace Analytical Services - Ormond Beach ND ug/L 50.0 12.4 1 11/08/23 08:30 11/11/23 02:00 7440-42-8 273 ug/L 40.0 25.0 1 11/08/23 08:30 11/11/23 02:00 7439-89-6 Analytical Method: EPA 200.8 Preparation Method: EPA 200.8 Pace Analytical Services - Ormond Beach 365 ug/L 1.0 0.50 1 11/08/23 08:30 11/09/23 00:28 7440-39-3 0.60 ug/L 0.10 0.067 1 11/08/23 08:30 11/09/23 00:28 7440-43-9 2.4 ug/L 1.0 0.24 1 11/08/23 08:30 11/09/23 00:28 7440-48-4 85.2 ug/L 1.0 0.29 1 11/08/23 08:30 11/09/23 00:28 7439-96-5 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 3.0 1 11/07/23 06:35 67-64-1 NO ug/L 5.0 1.7 1 11/07/23 06:35 71-43-2 ND ug/L 5.0 1.9 1 11/07/23 06:35 108-86-1 ND ug/L 5.0 2.1 1 11/07/23 06:35 74-97-5 ND ug/L 5.0 1.1 1 11/07/23 06:35 75-27-4 NO ug/L 5.0 1.0 1 11/07/23 06:35 75-25-2 ND ug/L 10.0 6.0 1 11/07/23 06:35 74-83-9 ND ug/L 10.0 2.6 1 11/07/23 06:35 78-93-3 NO ug/L 100 11.6 1 11/07/23 06:35 75-65-0 ND ug/L 5.0 2.3 1 11/07/23 06:35 104-51-8 ND ug/L 5.0 2.2 1 11/07/23 06:35 135-98-8 ND ug/L 5.0 0.98 1 11/07/23 06:35 98-06-6 ND ug/L 5.0 2.2 1 11/07/23 06:35 56-23-5 ND ug/L 5.0 1.8 1 11/07/23 06:35 108-90-7 ND ug/L 10.0 4.1 1 11/07/23 06:35 75-00-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 12 of 37 �aceo ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MONITORING WELLS Pace Project No.: 92696570 Sample: MW-3 Lab ID: 92696570003 Collected: 11/02/23 11:50 Received: 11/02/23 15:50 Matrix: Water Parameters Results Units PQL MDL OF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Chloroform NO ug/L 5.0 1.3 1 11/07/23 06:35 67-66-3 Chloromethane NO ug/L 5.0 2.8 1 11/07/23 06:35 74-87-3 2-Chlorotoluene NO ug/L 5.0 1.8 1 11/07/23 06:35 95-49-8 4-Chlorotoluene NO ug/L 5.0 2.0 1 11/07/23 06:35 106-43-4 1,2-Dibromo-3-chloropropane NO ug/L 5.0 1.0 1 11/07/23 06:35 96-12-8 Dibromochloromethane NO ug/L 5.0 2.3 1 11/07/23 06:35 124-48-1 1,2-Dibromoethane (ED13) NO ug/L 5.0 1.9 1 11/07/23 06:35 106-93-4 Dibromomethane NO ug/L 5.0 1.0 1 11/07/23 06:35 74-95-3 1,2-Dichlorobenzene NO ug/L 5.0 1.9 1 11/07/23 06:35 95-50-1 1,3-Dichlorobenzene NO ug/L 5.0 1.7 1 11/07/23 06:35 541-73-1 1,4-Dichlorobenzene NO ug/L 5.0 1.9 1 11/07/23 06:35 106-46-7 Dichlorodifluoromethane NO ug/L 5.0 1.8 1 11/07/23 06:35 75-71-8 1,1-Dichloroethane NO ug/L 5.0 2.3 1 11/07/23 06:35 75-34-3 1,2-Dichloroethane NO ug/L 5.0 2.1 1 11/07/23 06:35 107-06-2 1,2-Dichloroethene (Total) NO ug/L 5.0 5.0 1 11/07/23 06:35 540-59-0 1,1-Dichloroethene NO ug/L 5.0 2.2 1 11/07/23 06:35 75-35-4 cis-1,2-Dichloroethene NO ug/L 5.0 2.2 1 11/07/23 06:35 156-59-2 trans-1,2-Dichloroethene NO ug/L 5.0 2.2 1 11/07/23 06:35 156-60-5 1,2-Dichloropropane NO ug/L 5.0 2.1 1 11/07/23 06:35 78-87-5 1,3-Dichloropropane NO ug/L 5.0 1.9 1 11/07/23 06:35 142-28-9 2,2-Dichloropropane NO ug/L 5.0 2.4 1 11/07/23 06:35 594-20-7 1,1-Dichloropropene NO ug/L 5.0 2.8 1 11/07/23 06:35 563-58-6 cis-1,3-Dichloropropene NO ug/L 5.0 2.0 1 11/07/23 06:35 10061-01-5 trans- 1,3-Dichloropropene NO ug/L 5.0 2.2 1 11/07/23 06:35 10061-02-6 Diisopropyl ether NO ug/L 5.0 1.4 1 11/07/23 06:35 108-20-3 Ethylbenzene NO ug/L 5.0 1.8 1 11/07/23 06:35 100-41-4 Hexachloro-1,3-butadiene NO ug/L 5.0 4.8 1 11/07/23 06:35 87-68-3 2-Hexanone ND ug/L 10.0 4.2 1 11/07/23 06:35 591-78-6 Isopropylbenzene (Cumene) NO ug/L 5.0 2.1 1 11/07/23 06:35 98-82-8 p-Isopropyltoluene NO ug/L 5.0 1.0 1 11/07/23 06:35 99-87-6 Methylene Chloride NO ug/L 5.0 3.3 1 11/07/23 06:35 75-09-2 4-Methyl-2-pentanone (MIBK) NO ug/L 10.0 4.7 1 11/07/23 06:35 108-10-1 Methyl-tert-butyl ether NO ug/L 5.0 3.1 1 11/07/23 06:35 1634-04-4 Naphthalene NO ug/L 5.0 2.1 1 11/07/23 06:35 91-20-3 n-Propylbenzene NO ug/L 5.0 2.0 1 11/07/23 06:35 103-65-1 Styrene NO ug/L 5.0 1.9 1 11/07/23 06:35 100-42-5 1,1,1,2-Tetrachloroethane NO ug/L 5.0 1.1 1 11/07/23 06:35 630-20-6 1,1,2,2-Tetrachloroethane NO ug/L 5.0 2.0 1 11/07/23 06:35 79-34-5 Tetrachloroethene NO ug/L 5.0 1.8 1 11/07/23 06:35 127-18-4 Toluene NO ug/L 5.0 2.0 1 11/07/23 06:35 108-88-3 1,2,3-Trichlorobenzene NO ug/L 5.0 2.2 1 11/07/23 06:35 87-61-6 1,2,4-Trichlorobenzene NO ug/L 5.0 2.3 1 11/07/23 06:35 120-82-1 1,1,1-Trichloroethane ND ug/L 5.0 2.1 1 11/07/23 06:35 71-55-6 1,1,2-Trichloroethane NO ug/L 5.0 2.0 1 11/07/23 06:35 79-00-5 REPORT OF LABORATORY ANALYSIS IH,L1, v1 v1 v1 This report shall not be reproduced, except in full, Date: 11/16/2023 11:22 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 37 �Yacee ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MONITORING WELLS Pace Project No.: 92696570 Sample: MW-3 Lab ID: 92696570003 Collected: 11/02/23 11:50 Received: 11/02/23 15:50 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 11/09/23 17:40 Collected By Matt 1 11/09/23 17:40 Reusch Collected Date 11/2123 1 11/09/23 17:40 Collected Time 11:50 1 11/09/23 17:40 pH 5.2 Std. Units 1 11/09/23 17:40 Temperature 13.5 deg C 1 11/09/23 17:40 Static Water Level 35.40 feet 1 11/09/23 17:40 Specific Conductance 115.3 umhos/cm 1 11/09/23 17:40 Oxygen, Dissolved 4.0 mg/L 1 11/09/23 17:40 7782-44-7 Total Well Depth 50.02 feet 1 11/09/23 17:40 Turbidity 9.7 NTU 1 11/09/23 17:40 Odor ND 1 11/09/23 17:40 Appearance Clear w/ 1 11/09/23 17:40 Fines 200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 Pace Analytical Services - Ormond Beach Boron ND ug/L 50.0 12.4 1 11/08/23 08:30 11/11/23 02:00 7440-42-8 Iron 273 ug/L 40.0 25.0 1 11/08/23 08:30 11/11/23 02:00 7439-89-6 200.8 MET ICPMS Analytical Method: EPA 200.8 Preparation Method: EPA 200.8 Pace Analytical Services - Ormond Beach Barium 365 ug/L 1.0 0.50 1 11/08/23 08:30 11/09/23 00:28 7440-39-3 Cadmium 0.60 ug/L 0.10 0.067 1 11/08/23 08:30 11/09/23 00:28 7440-43-9 Cobalt 2.4 ug/L 1.0 0.24 1 11/08/23 08:30 11/09/23 00:28 7440-48-4 Manganese 85.2 ug/L 1.0 0.29 1 11/08/23 08:30 11/09/23 00:28 7439-96-5 8260D MSV Analytical Method: EPA8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 3.0 1 11/07/23 06:35 67-64-1 Benzene ND ug/L 5.0 1.7 1 11/07/23 06:35 71-43-2 Bromobenzene ND ug/L 5.0 1.9 1 11/07/23 06:35 108-86-1 Bromochloromethane ND ug/L 5.0 2.1 1 11/07/23 06:35 74-97-5 Bromodichloromethane ND ug/L 5.0 1.1 1 11/07/23 06:35 75-27-4 Bromoform ND ug/L 5.0 1.0 1 11/07/23 06:35 75-25-2 Bromomethane ND ug/L 10.0 6.0 1 11/07/23 06:35 74-83-9 2-Butanone (MEK) ND ug/L 10.0 2.6 1 11/07/23 06:35 78-93-3 tert-Butyl Alcohol ND ug/L 100 11.6 1 11/07/23 06:35 75-65-0 n-Butylbenzene ND ug/L 5.0 2.3 1 11/07/23 06:35 104-51-8 sec -Butyl benzene ND ug/L 5.0 2.2 1 11/07/23 06:35 135-98-8 tert-Butylbenzene ND ug/L 5.0 0.98 1 11/07/23 06:35 98-06-6 Carbon tetrachloride ND ug/L 5.0 2.2 1 11/07/23 06:35 56-23-5 Chlorobenzene ND ug/L 5.0 1.8 1 11/07/23 06:35 108-90-7 Chloroethane ND ug/L 10.0 4.1 1 11/07/23 06:35 75-00-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/16/2023 11:22 AM without the written consent of Pace Analytical Services, LLC. v2 Page 12 of 37 �Yaceo ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MONITORING WELLS Pace Project No.: 92696570 Sample: MW-2 Lab ID: 92696570002 Collected: 11/02/23 13:20 Received: 11/02/23 15:50 Matrix: Water Parameters 8260D MSV Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl acetate Vinyl chloride m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 4500H+ pH, Electrometric pH at 25 Degrees C 300.0 IC Anions 28 Days Bromide Chloride Fluoride Sulfate 350.1 Ammonia Nitrogen, Ammonia 351.2 Total Kjeldahl Nitrogen Nitrogen, Kjeldahl, Total 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate Nitrogen, Nitrite SM4500P-E, Phosphate, Ortho Orthophosphate as P Date: 11/16/2023 11:22 AM Results Units PQL MDL DF Prepared Analyzed CAS No. Qual Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 10.0 1.5 1 11/07/23 06:17 75-69-4 ND ug/L 5.0 1.1 1 11/07/23 06:17 96-18-4 ND ug/L 5.0 2.0 1 11/07/23 06:17 95-63-6 ND ug/L 5.0 2.1 1 11/07/23 06:17 108-67-8 ND ug/L 10.0 5.6 1 11/07/23 06:17 108-05-4 ND ug/L 5.0 1.8 1 11/07/23 06:17 75-01-4 ND ug/L 10.0 4.1 1 11/07/23 06:17 179601-23-1 ND ug/L 5.0 2.0 1 11/07/23 06:17 95-47-6 98 % 70-130 1 11/07/23 06:17 460-00-4 95 % 70-130 1 11/07/23 06:17 17060-07-0 104 % 70-130 1 11/07/23 06:17 2037-26-5 Analytical Method: SM 4500-H+B-2011 Pace Analytical Services -Asheville 6.4 Std. Units 0.10 0.10 1 11/09/23 12:27 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville ND mg/L 0.10 0.060 1 11/03/23 23:11 24959-67-9 1.5 mg/L 1.0 0.60 1 11/03/23 23:11 16887-00-6 0.086J mg/L 0.10 0.050 1 11/03/23 23:11 16984-48-8 1.6 mg/L 1.0 0.50 1 11/03/23 23:11 14808-79-8 Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville 4.2 mg/L 0.10 0.031 1 11/15/23 04:05 7664-41-7 Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Pace Analytical Services - Asheville 4.6 mg/L 0.50 0.25 1 11/15/23 20:20 11/16/23 06:02 7727-37-9 Analytical Method: EPA 353.2 Rev 2.01993 Pace Analytical Services -Asheville 0.082 mg/L 0,040 0.010 1 ND mg/L 0.040 0.031 1 Analytical Method: SM 4500-P E-2011 Pace Analytical Services -Asheville 0.0112,11 mg/L 0.050 0.012 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 11/03/23 00:06 14797-55-8 11/03/23 00:06 14797-65-0 11/03/23 02:37 H3 Page 11 of 37 �Yaceo ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MONITORING WELLS Pace Project No.: 92696570 Sample: MW-3 Lab ID: 92696570003 Collected: 11/02/23 11:50 Received: 11/02/23 15:50 Matrix: Water Parameters 8260D MSV Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl acetate Vinyl chloride m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 4500H+ pH, Electrometric pH at 25 Degrees C 300.0 IC Anions 28 Days Bromide Chloride Fluoride Sulfate 350.1 Ammonia Nitrogen, Ammonia 351.2 Total Kjeldahl Nitrogen Nitrogen, Kjeldahl, Total 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate Nitrogen, Nitrite SM4500P-E, Phosphate, Ortho Orthophosphate as P Date: 11/16/2023 11:22 AM Results Units PQL MDL DF Prepared Analyzed CAS No. Qual Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 5.0 1.8 1 11/07/23 06:35 79-01-6 ND ug/L 10.0 1.5 1 11/07/23 06:35 75-694 ND ug/L 5.0 1.1 1 11/07/23 06:35 96-184 ND ug/L 5.0 2.0 1 11/07/23 06:35 95-63-6 ND ug/L 5.0 2.1 1 11/07/23 06:35 108-67-8 ND ug/L 10.0 5.6 1 11/07/23 06:35 108-054 ND ug/L 5.0 1.8 1 11/07/23 06:35 75-01-4 ND ug/L 10.0 4.1 1 11/07/23 06:35 179601-23-1 ND ug/L 5.0 2.0 1 11/07/23 06:35 95-47-6 99 % 70-130 1 11/07/23 06:35 460-00-4 94 % 70-130 1 11/07/23 06:35 17060-07-0 104 % 70-130 1 11/07/23 06:35 2037-26-5 Analytical Method: SM 4500-H+B-2011 Pace Analytical Services -Asheville 5.4 Std. Units 0.10 0.10 1 11/09/23 12:18 H3 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville 0.12 mg/L 0.10 0.060 1 11/03/23 23:26 24959-67-9 8.3 mg/L 1.0 0.60 1 11/03/23 23:26 16887-00-6 ND mg/L 0.10 0.050 1 11/03/23 23:26 16984-48-8 ND mg/L 1.0 0.50 1 11/03/23 23:26 14808-79-8 Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville ND mg/L 0.10 0.031 1 11/15/23 04:06 7664-41-7 Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Pace Analytical Services -Asheville ND mg/L 0.50 0.25 1 11/15/23 20:20 11/16/23 06:03 7727-37-9 Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville 8.7 mg/L 0.20 0.050 5 11/03/23 00:17 14797-55-8 ND mg/L 0.040 0.031 1 11/03/23 00:03 14797-65-0 Analytical Method: SM 4500-P E-2011 Pace Analytical Services -Asheville ND mg/L 0.050 0.012 1 11/03/23 02:36 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 37 �laceo ANALYTICAL RESULTS race Analyacai seances, Lu: 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MONITORING WELLS Pace Project No.: 92696570 Sample: MW-4 Lab ID: 92696570004 Collected: 11/02/23 13:43 Received: 11/02/23 15:50 Matrix: Water Parameters Monitoring Well Data Performed by Collected By Collected Date Collected Time pH Temperature Static Water Level Specific Conductance Oxygen, Dissolved Total Well Depth Turbidity Odor Appearance 200.7 MET ICP Boron Iron 200.8 MET ICPMS Barium Cadmium Cobalt Manganese 8260D MSV Acetone Benzene Bromobenzene Bromochloromethane Bromodich loromethane Bromoform Bromomethane 2-Butanone (MEK) tert-Butyl Alcohol n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Date: 11/16/2023 11:22 AM Results Units PQL Analytical Method: Pace Analytical Services - Charlotte Pace Matt Reusch 11/2123 13:38 4.8 Std. Units 12.40 deg C 21.63 feet 68.8 umhos/cm 1.2 mg/L 35.37 feet .5 NTU ND Clear MDL DF Prepared Analyzed CAS No. Qual 1 11/09/23 17:43 1 11/09/23 17:43 1 11/09/23 17:43 1 11/09/23 17:43 1 11/09/23 17:43 1 11/09/23 17:43 1 11/09/23 17:43 1 11/09/23 17:43 1 11/09/23 17:43 7782-44-7 1 11/09/23 17:43 1 11/09/23 17:43 1 11/09/23 17:43 1 11/09/23 17:43 Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 Pace Analytical Services - Ormond Beach ND ug/L 50.0 12.4 1 11/08/23 08:30 11/11/23 02:04 744042-8 84.5 ug/L 40.0 25.0 1 11/08/23 08:30 11/11/23 02:04 7439-89-6 Analytical Method: EPA 200.8 Preparation Method: EPA 200.8 Pace Analytical Services - Ormond Beach 159 ug/L 1.0 0.50 1 11/08/23 08:30 11/09/23 00:33 7440-39-3 0.072.11 ug/L 0.10 0.067 1 11/08/23 08:30 11/09/23 00:33 7440-43-9 2.4 ug/L 1.0 0.24 1 11/08/23 08:30 11/09/23 00:33 744048-4 123 ug/L 1.0 0.29 1 11/08/23 08:30 11/09/23 00:33 7439-96-5 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 3.0 1 11/07/23 06:53 67-64-1 ND ug/L 5.0 1.7 1 11/07/23 06:53 71-43-2 ND ug/L 5.0 1.9 1 11/07/23 06:53 108-86-1 ND ug/L 5.0 2.1 1 11/07/23 06:53 74-97-5 ND ug/L 5.0 1.1 1 11/07/23 06:53 75-27-4 ND ug/L 5.0 1.0 1 11/07/23 06:53 75-25-2 ND ug/L 10.0 6.0 1 11/07/23 06:53 74-83-9 ND ug/L 10.0 2.6 1 11/07/23 06:53 78-93-3 ND ug/L 100 11.6 1 11/07/23 06:53 75-65-0 ND ug/L 5.0 2.3 1 11/07/23 06:53 104-51-8 ND ug/L 5.0 2.2 1 11/07/23 06:53 135-98-8 ND ug/L 5.0 0.98 1 11/07/23 06:53 98-06-6 ND ug/L 5.0 2.2 1 11/07/23 06:53 56-23-5 ND ug/L 5.0 1.8 1 11/07/23 06:53 108-90-7 ND ug/L 10.0 4.1 1 11/07/23 06:53 75-00-3 ND ug/L 5.0 1.3 1 11/07/23 06:53 67-66-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 15 of 37 �Yace" ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MONITORING WELLS Pace Project No.: 92696570 Sample: MW-4 Lab ID: 92696570004 Collected: 11/02/23 13:43 Received: 11/02/23 15:50 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Chloromethane ND ug/L 5.0 2.8 1 11/07/23 06:53 74-87-3 2-Chlorotoluene ND ug/L 5.0 1.8 1 11/07/23 06:53 95-49-8 4-Chlorotoluene ND ug/L 5.0 2.0 1 11/07/23 06:53 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 5.0 1.0 1 11/07/23 06:53 96-12-8 Dibromochloromethane ND ug/L 5.0 2.3 1 11/07/23 06:53 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 5.0 1.9 1 11/07/23 06:53 106-93-4 Dibromomethane ND ug/L 5.0 1.0 1 11/07/23 06:53 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 1.9 1 11/07/23 06:53 95-50-1 1,3-Dichlorobenzene ND ug/L 5.0 1.7 1 11/07/23 06:53 541-73-1 1,4-Dichlorobenzene ND ug/L 5.0 1.9 1 11/07/23 06:53 106-46-7 Dichlorodifluoromethane ND ug/L 5.0 1.8 1 11/07/23 06:53 75-71-8 1,1-Dichloroethane ND ug/L 5.0 2.3 1 11/07/23 06:53 75-34-3 1,2-Dichloroethane ND ug/L 5.0 2.1 1 11/07/23 06:53 107-06-2 1,2-Dichloroethene (Total) ND ug/L 5.0 5.0 1 11/07/23 06:53 540-59-0 1,1-Dichloroethene ND ug/L 5.0 2.2 1 11/07/23 06:53 75-35-4 cis-1,2-Dichloroethene ND ug/L 5.0 2.2 1 11/07/23 06:53 156-59-2 trans- 1,2-Dichloroethene ND ug/L 5.0 2.2 1 11/07/23 06:53 156-60-5 1,2-Dichloropropane ND ug/L 5.0 2.1 1 11/07/23 06:53 78-87-5 1,3-Dichloropropane ND ug/L 5.0 1.9 1 11/07/23 06:53 142-28-9 2,2-Dichloropropane ND ug/L 5.0 2.4 1 11/07/23 06:53 594-20-7 1,1-Dichloropropene ND ug/L 5.0 2.8 1 11/07/23 06:53 563-58-6 cis- 1,3-Dichloropropene ND ug/L 5.0 2.0 1 11/07/23 06:53 10061-01-5 trans-1,3-Dichloropropene ND ug/L 5.0 2.2 1 11/07/23 06:53 10061-02-6 Diisopropyl ether ND ug/L 5.0 1.4 1 11/07/23 06:53 108-20-3 Ethylbenzene ND ug/L 5.0 1.8 1 11/07/23 06:53 100-41-4 Hexachloro-1,3-butadiene ND ug/L 5.0 4.8 1 11/07/23 06:53 87-68-3 2-Hexanone ND ug/L 10.0 4.2 1 11/07/23 06:53 591-78-6 Isopropyl benzene (Cumene) ND ug/L 5.0 2.1 1 11/07/23 06:53 98-82-8 p-Isopropyltoluene ND ug/L 5.0 1.0 1 11/07/23 06:53 99-87-6 Methylene Chloride ND ug/L 5.0 3.3 1 11/07/23 06:53 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 10.0 4.7 1 11/07/23 06:53 108-10-1 Methyl-tert-butyl ether ND ug/L 5.0 3.1 1 11/07/23 06:53 1634-04-4 Naphthalene ND ug/L 5.0 2.1 1 11/07/23 06:53 91-20-3 n-Propylbenzene ND ug/L 5.0 2.0 1 11/07/23 06:53 103-65-1 Styrene ND ug/L 5.0 1.9 1 11/07/23 06:53 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 5.0 1.1 1 11/07/23 06:53 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 5.0 2.0 1 11/07/23 06:53 79-34-5 Tetrachloroethene ND ug/L 5.0 1.8 1 11/07/23 06:53 127-18-4 Toluene ND ug/L 5.0 2.0 1 11/07/23 06:53 108-88-3 1,2,3-Trichlorobenzene ND ug/L 5.0 2.2 1 11/07/23 06:53 87-61-6 1,2,4-Trichlorobenzene ND ug/L 5.0 2.3 1 11/07/23 06:53 120-82-1 1,1,1-Trichloroethane ND ug/L 5.0 2.1 1 11/07/23 06:53 71-55-6 1,1,2-Trichloroethane ND ug/L 5.0 2.0 1 11/07/23 06:53 79-00-5 Trichloroethene ND ug/L 5.0 1.8 1 11/07/23 06:53 79-01-6 REPORT OF LABORATORY ANALYSIS IH,L1, v1 v1 v1 This report shall not be reproduced, except in full, Date: 11/16/2023 11:22 AM without the written consent of Pace Analytical Services, LLC. Page 16 of 37 Project: MONITORING WELLS Pace Project No.: 92696570 Sample: MW-4 Parameters 8260D MSV Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl acetate Vinyl chloride m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 4500H+ pH, Electrometric pH at 25 Degrees C 300.0 IC Anions 28 Days Bromide Chloride Fluoride Sulfate 350.1 Ammonia Nitrogen, Ammonia 351.2 Total Kjeldahl Nitrogen Nitrogen, Kjeldahl, Total 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate Nitrogen, Nitrite SM4500P-E, Phosphate, Ortho Orthophosphate as P Date: 11/16/2023 11:22 AM Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Lab ID: 92696570004 Collected: 11/02/23 13:43 Received: 11/02/23 15:50 Matrix: Water Results Units PQL MDL DF Prepared Analyzed CAS No. Qual Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 10.0 1.5 1 11/07/23 06:53 75-69-4 ND ug/L 5.0 1.1 1 11/07/23 06:53 96-18-4 ND ug/L 5.0 2.0 1 11/07/23 06:53 95-63-6 ND ug/L 5.0 2.1 1 11/07/23 06:53 108-67-8 ND ug/L 10.0 5.6 1 11/07/23 06:53 108-05-4 ND ug/L 5.0 1.8 1 11/07/23 06:53 75-01-4 ND ug/L 10.0 4.1 1 11/07/23 06:53 179601-23-1 ND ug/L 5.0 2.0 1 11/07/23 06:53 95-47-6 96 % 70-130 1 11/07/23 06:53 460-00-4 94 % 70-130 1 11/07/23 06:53 17060-07-0 105 % 70-130 1 11/07/23 06:53 2037-26-5 Analytical Method: SM 4500-H+B-2011 Pace Analytical Services -Asheville 5.2 Std. Units 0.10 0.10 1 11/09/23 12:32 H3 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services - Asheville 0.20 mg/L 0.10 0.060 1 11/03/23 23:40 24959-67-9 2A mg/L 1.0 0.60 1 11/03/23 23:40 16887-00-6 ND mg/L 0.10 0.050 1 11/03/23 23:40 16984-48-8 ND mg/L 1.0 0.50 1 11/03/23 23:40 14808-79-8 Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Asheville ND mg/L 0.10 0.031 1 11/15/23 04:07 7664-41-7 Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Pace Analytical Services - Asheville ND mg/L 0.50 0.25 1 11/15/23 20:20 11/16/23 06:07 7727-37-9 Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville 4.2 mg/L 0.040 0.010 1 11/03/23 00:07 14797-55-8 ND mg/L 0.040 0.031 1 11/03/23 00:07 14797-65-0 Analytical Method: SM 4500-P E-2011 Pace Analytical Services -Asheville ND mg/L 0.050 0.012 1 11/03/23 02:38 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 37 �Yaces QUALITY CONTROL DATA Project: MONITORING WELLS Pace Project No.: 92696570 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QC Batch: 964625 Analysis Method: EPA 200.7 QC Batch Method: EPA 200.7 Analysis Description: 200.7 MET Laboratory: Pace Analytical Services - Ormond Beach Associated Lab Samples: 92696570001, 92696570002, 92696570003, 92696570004 METHOD BLANK: 5305592 Matrix: Water Associated Lab Samples: 92696570001, 92696570002, 92696570003, 92696570004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Boron ug/L ND 50.0 12.4 11/11/23 00:26 Iron ug/L ND 40.0 25.0 11/11/23 00:26 LABORATORY CONTROL SAMPLE: 5305593 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Boron ug/L 1250 1290 103 85-115 Iron ug/L 2500 2490 100 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 5305594 5305595 MS MSD 35838061002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conic. Result Result % Rec % Rec Limits RPD RPD Qual Boron ug/L 1460 4170 4170 5520 5410 97 95 70-130 2 20 Iron ug/L 143000 8330 8330 130000 123000 -154 -243 70-130 6 20 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 5305596 5305597 MS MSD 92696570004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Boron ug/L ND 1250 1250 1260 1290 100 103 70-130 2 20 Iron ug/L 84.5 2500 2500 2560 2590 99 100 70-130 1 20 Results presented on this page are In the units Indicated by the -Units" column except where an alternate unit Is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/16/2023 11:22 AM without the written consent of Pace Analytical Services, LLC. Page 18 of 37 lace" Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: MONITORING WELLS Pace Project No.: 92696570 QC Batch: 964623 Analysis Method: EPA 200.8 QC Batch Method: EPA 200.8 Analysis Description: 200.8 MET Laboratory: Pace Analytical Services - Ormond Beach Associated Lab Samples: 92696570001, 92696570002, 92696570003, 92696570004 METHOD BLANK: 5305586 Matrix: Water Associated Lab Samples: 92696570001, 92696570002, 92696570003, 92696570004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Barium ug/L ND 1.0 0.50 11/09/23 00:06 Cadmium ug/L ND 0.10 0.067 11/09/23 00:06 Cobalt ug/L ND 1.0 0.24 11/09/23 00:06 Manganese ug/L ND 1.0 0.29 11/09/23 00:06 LABORATORY CONTROL SAMPLE: 5305587 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Barium ug/L 50 51.0 102 85-115 Cadmium ug/L 5 5.1 102 85-115 Cobalt ug/L 50 52.5 105 85-115 Manganese ug/L 50 51.1 102 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 5305588 5305589 MS MSD 35838061001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Barium ug/L 42.5 50 50 94.5 96.1 104 107 70-130 2 20 Cadmium ug/L 0.14J 5 5 5.1 5.3 100 103 70-130 3 20 Cobalt ug/L 0.88J 50 50 51.4 53.5 101 105 70-130 4 20 Manganese ug/L 61.7 50 50 112 116 101 109 70-130 4 20 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 5305590 5305591 MS MSD 35838912002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Barium ug/L 16.0 50 50 66.1 67.0 100 102 70-130 1 20 Cadmium ug/L 0.067U 5 5 4.3 4.4 86 87 70-130 1 20 Cobalt ug/L 0.24U 50 50 48.4 49.3 97 98 70-130 2 20 Manganese ug/L 0.39J 50 50 39.5 39.4 78 78 70-130 0 20 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/16/2023 11:22 AM without the written consent of Pace Analytical Services, LLC. Page 19 of 37 �Yaceo QUALITY CONTROL DATA Project: MONITORING WELLS Pace Project No.: 92696570 QC Batch: 811225 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92696570001, 92696570002, 92696570003, 92696570004 METHOD BLANK: 4200042 Matrix: Water Associated Lab Samples: 92696570001, 92696570002, 92696570003, 92696570004 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 1.1 11/07/23 00:49 1,1,1-Trichloroethane ug/L ND 5.0 2.1 11/07/23 00:49 1,1,2,2-Tetrachloroethane ug/L ND 5.0 2.0 11/07/23 00:49 1,1,2-Trichloroethane ug/L ND 5.0 2.0 11/07/23 00:49 1,1-Dichloroethane ug/L ND 5.0 2.3 11/07/23 00:49 1,1-Dichloroethene ug/L ND 5.0 2.2 11/07/23 00:49 1,1-Dichloropropene ug/L ND 5.0 2.8 11/07/23 00:49 1,2,3-Trichlorobenzene ug/L ND 5.0 2.2 11/07/23 00:49 1,2,3-Trichloropropane ug/L ND 5.0 1.1 11/07/23 00:49 1,2,4-Trichlorobenzene ug/L ND 5.0 2.3 11/07/23 00:49 1,2,4-Trimethylbenzene ug/L ND 5.0 2.0 11/07/23 00:49 1,2-Dibromo-3-chloropropane ug/L ND 5.0 1.0 11/07/23 00:49 1,2-Dibromoethane (EDB) ug/L ND 5.0 1.9 11/07/23 00:49 1,2-Dichlorobenzene ug/L ND 5.0 1.9 11/07/23 00:49 1,2-Dichloroethane ug/L ND 5.0 2.1 11/07/23 00:49 1,2-Dichloroethene (Total) ug/L ND 5.0 5.0 11/07/23 00:49 1,2-Dichloropropane ug/L ND 5.0 2.1 11/07/23 00:49 1,3,5-Trimethylbenzene ug/L ND 5.0 2.1 11/07/23 00:49 1,3-Dichlorobenzene ug/L ND 5.0 1.7 11/07/23 00:49 1,3-Dichloropropane ug/L ND 5.0 1.9 11/07/23 00:49 1,4-Dichlorobenzene ug/L ND 5.0 1.9 11/07/23 00:49 2,2-Dichloropropane ug/L ND 5.0 2.4 11/07/23 00:49 2-Butanone (MEK) ug/L ND 10.0 2.6 11/07/23 00:49 2-Chlorotoluene ug/L ND 5.0 1.8 11/07/23 00:49 2-Hexanone ug/L ND 10.0 4.2 11/07/23 00:49 4-Chlorotoluene ug/L ND 5.0 2.0 11/07/23 00:49 4-Methyl-2-pentanone (MIBK) ug/L ND 10.0 4.7 11/07/23 00:49 Acetone ug/L ND 25.0 3.0 11/07/23 00:49 Benzene ug/L ND 5.0 1.7 11/07/23 00:49 Bromobenzene ug/L ND 5.0 1.9 11/07/23 00:49 Bromochloromethane ug/L ND 5.0 2.1 11/07/23 00:49 Bromodichloromethane ug/L ND 5.0 1.1 11/07/23 00:49 Bromoform ug/L ND 5.0 1.0 11/07/23 00:49 Bromomethane ug/L ND 10.0 6.0 11/07/23 00:49 Carbon tetrachloride ug/L ND 5.0 2.2 11/07/23 00:49 Chlorobenzene ug/L ND 5.0 1.8 11/07/23 00:49 Chloroethane ug/L ND 10.0 4.1 11/07/23 00:49 Chloroform ug/L ND 5.0 1.3 11/07/23 00:49 Chloromethane ug/L ND 5.0 2.8 11/07/23 00:49 cis-1,2-Dichloroethene ug/L ND 5.0 2.2 11/07/23 00:49 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 v1 v1 v2 Qualifiers Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/16/2023 11:22 AM without the written consent of Pace Analytical Services, LLC. Page 20 of 37 QUALITY CONTROL DATA Project: MONITORING WELLS Pace Project No.: 92696570 METHOD BLANK: 4200042 Matrix: Water Associated Lab Samples: 92696570001, 92696570002, 92696570003, 92696570004 Blank Reporting Parameter Units Result Limit MDL Analyzed cis-1,3-Dichloropropene ug/L ND 5.0 2.0 11/07/23 00:49 Dibromochloromethane ug/L ND 5.0 2.3 11/07/23 00:49 Dibromomethane ug/L ND 5.0 1.0 11/07/23 00:49 Dichlorodifluoromethane ug/L ND 5.0 1.8 11/07/23 00:49 Diisopropyl ether ug/L ND 5.0 1.4 11/07/23 00:49 Ethylbenzene ug/L ND 5.0 1.8 11/07/23 00:49 Hexachloro-1,3-butadiene ug/L ND 5.0 4.8 11/07/23 00:49 Isopropylbenzene (Cumene) ug/L ND 5.0 2.1 11/07/23 00:49 m&p-Xylene ug/L ND 10.0 4.1 11/07/23 00:49 Methyl-tert-butyl ether ug/L ND 5.0 3.1 11/07/23 00:49 Methylene Chloride ug/L ND 5.0 3.3 11/07/23 00:49 n-Butylbenzene ug/L ND 5.0 2.3 11/07/23 00:49 n-Propylbenzene ug/L ND 5.0 2.0 11/07/23 00:49 Naphthalene ug/L ND 5.0 2.1 11/07/23 00:49 o-Xylene ug/L ND 5.0 2.0 11/07/23 00:49 p-Isopropyltoluene ug/L ND 5.0 1.0 11/07/23 00:49 sec-Butylbenzene ug/L ND 5.0 2.2 11/07/23 00:49 Styrene ug/L ND 5.0 1.9 11/07/23 00:49 tert-Butyl Alcohol ug/L ND 100 11.6 11/07/23 00:49 tert-Butylbenzene ug/L ND 5.0 0.98 11/07/23 00:49 Tetrachloroethene ug/L ND 5.0 1.8 11/07/23 00:49 Toluene ug/L ND 5.0 2.0 11/07/23 00:49 trans-1,2-Dichloroethene ug/L ND 5.0 2.2 11/07/23 00:49 trans-1,3-Dichloropropene ug/L ND 5.0 2.2 11/07/23 00:49 Trichloroethene ug/L ND 5.0 1.8 11/07/23 00:49 Trichlorofluoromethane ug/L ND 10.0 1.5 11/07/23 00:49 Vinyl acetate ug/L ND 10.0 5.6 11/07/23 00:49 Vinyl chloride ug/L ND 5.0 1.8 11/07/23 00:49 1,2-Dichloroethane-d4 (S) % 95 70-130 11/07/23 00:49 4-Bromofluorobenzene (S) % 97 70-130 11/07/23 00:49 Toluene-d8 (S) % 104 70-130 11/07/23 00:49 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Qualifiers IH,v1 LABORATORY CONTROL SAMPLE: Parameter 4200043 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 20 20.8 104 70-130 1,1,1-Trichloroethane ug/L 20 21.6 108 70-130 1,1,2,2-Tetrachloroethane ug/L 20 22.0 110 70-130 1,1,2-Trichloroethane ug/L 20 22.0 110 70-130 1,1-Dichloroethane ug/L 20 21.5 108 70-130 1,1-Dichloroethene ug/L 20 21.6 108 69-131 1,1-Dichloropropene ug/L 20 23.5 118 70-132 v1 1,2,3-Trichlorobenzene ug/L 20 22.3 111 70-132 1,2,3-Trichloropropane ug/L 20 20.7 104 70-130 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /16/2023 11:22 AM without the written consent of Pace Analytical Services, LLC. Page 21 of 37 �Yaceo QUALITY CONTROL DATA Project: MONITORING WELLS Pace Project No.: 92696570 LABORATORY CONTROL SAMPLE: Parameter 4200043 Units Spike Conc. 1,2,4-Trichoorobenzene ug/L 20 1,2,4-Trimethylbenzene ug/L 20 1,2-Dibromo-3-chloropropane ug/L 20 1,2-Dibromoethane (EDB) ug/L 20 1,2-Dichlorobenzene ug/L 20 1,2-Dichloroethane ug/L 20 1,2-Dichloroethene (Total) ug/L 1,2-Dichloropropane ug/L 20 1,3,5-Trimethylbenzene ug/L 20 1,3-Dichlorobenzene ug/L 20 1,3-Dichloropropane ug/L 20 1,4-Dichlorobenzene ug/L 20 2,2-Dichloropropane ug/L 20 2-Butanone (MEK) ug/L 40 2-Chlorotoluene ug/L 20 2-Hexanone ug/L 40 4-Chlorotoluene ug/L 20 4-Methyl-2-pentanone (MIBK) ug/L 40 Acetone ug/L 40 Benzene ug/L 20 Bromobenzene ug/L 20 Bromochloromethane ug/L 20 Bromodichloromethane ug/L 20 Bromoform ug/L 20 Bromomethane ug/L 20 Carbon tetrachloride ug/L 20 Chlorobenzene ug/L 20 Chloroethane ug/L 20 Chloroform ug/L 20 Chloromethane ug/L 20 cis-1,2-Dichloroethene ug/L 20 cis-1,3-Dichloropropene ug/L 20 Dibromochloromethane ug/L 20 Dibromomethane ug/L 20 Dichlorodifluoromethane ug/L 20 Diisopropyl ether ug/L 20 Ethylbenzene ug/L 20 Hexachloro-1,3-butadiene ug/L 20 Isopropyl benzene (Cumene) ug/L 20 m&p-Xylene ug/L 40 Methyl-tert-butyl ether ug/L 20 Methylene Chloride ug/L 20 n-Butylbenzene ug/L 20 n-Propylbenzene ug/L 20 Naphthalene ug/L 20 o-Xylene ug/L 20 p-Isopropyltoluene ug/L 20 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 LCS Result LCS % Rec % Rec Limits Qualifiers 21.8 109 70-130 21.8 109 70-130 21.6 108 70-130 21.6 108 70-130 21.9 110 70-130 20.2 101 70-130 43.4 22.9 114 70-130 21.5 107 70-130 22.0 110 70-130 21.4 107 70-130 21.1 105 70-130 20.8 104 69-130 38.7 97 67-133 21.8 109 70-130 46.0 115 70-133 v1 21.8 109 70-130 43.6 109 70-130 42.5 106 67-130 22.2 111 70-130 21.3 106 70-130 21.8 109 70-130 21.0 105 70-130 20.3 102 70-133 16.2 81 41-148 v3 21.0 105 70-130 21.2 106 70-130 20.7 103 41-157 20.9 105 70-130 24.2 121 59-141 21.2 106 70-130 21.8 109 70-130 21.2 106 70-130 20.9 104 70-130 30.0 150 54-147 IH,L1,v1 21.7 108 70-130 20.9 105 70-130 20.9 105 70-134 21.1 106 70-130 41.9 105 70-130 21.5 107 70-130 22.9 115 62-130 21.2 106 70-130 21.1 105 70-130 23.5 118 70-135 21.2 106 70-130 21.7 108 70-130 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/16/2023 11:22 AM without the written consent of Pace Analytical Services, LLC. Page 22 of 37 lace - Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: MONITORING WELLS Pace Project No.: 92696570 LABORATORY CONTROL SAMPLE: 4200043 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers sec-Butylbenzene ug/L 20 21.3 107 70-130 Styrene ug/L 20 21.4 107 70-130 tert-Butyl Alcohol ug/L 200 211 105 66-132 tert-Butyl benzene ug/L 20 21.9 110 64-130 Tetrachloroethene ug/L 20 21.8 109 70-130 Toluene ug/L 20 21.0 105 70-130 trans-1,2-Dichloroethene ug/L 20 22.3 111 70-130 trans-1,3-Dichloropropene ug/L 20 21.1 105 70-130 Trichloroethene ug/L 20 21.5 108 70-130 Trichlorofluoromethane ug/L 20 20.3 102 57-130 Vinyl acetate ug/L 40 37.9 95 70-141 Vinyl chloride ug/L 20 22.0 110 66-140 1,2-Dichloroethane-d4 (S) % 96 70-130 4-Bromofluorobenzene (S) % 98 70-130 Toluene-d8 (S) % 100 70-130 MATRIX SPIKE SAMPLE: 4200044 92696570001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 16.7 83 70-146 1,1,1-Trichloroethane ug/L ND 20 17.0 85 70-150 1,1,2,2-Tetrachloroethane ug/L ND 20 16.1 81 66-144 1,1,2-Trichloroethane ug/L ND 20 16.3 82 70-142 1,1-Dichloroethane ug/L ND 20 17.3 87 68-150 1,1-Dichloroethene ug/L ND 20 19.1 96 64-162 1,1-Dichloropropene ug/L ND 20 18.8 94 70-160 1,2,3-Trichlorobenzene ug/L ND 20 16.3 82 66-151 1,2,3-Trichloropropane ug/L ND 20 15.5 78 66-144 1,2,4-Trichlorobenzene ug/L ND 20 16.0 80 69-147 1,2,4-Trimethylbenzene ug/L ND 20 16.8 84 67-149 1,2-Dibromo-3-chloropropane ug/L ND 20 14.6 73 62-146 1,2-Dibromoethane (EDB) ug/L ND 20 16.0 80 70-143 1,2-Dichlorobenzene ug/L ND 20 16.6 83 70-142 1,2-Dichloroethane ug/L ND 20 16.2 81 68-145 1,2-Dichloroethene (Total) ug/L ND 35.8 1,2-Dichloropropane ug/L ND 20 16.6 83 70-144 1,3,5-Trimethylbenzene ug/L ND 20 17.0 85 70-147 1,3-Dichlorobenzene ug/L ND 20 17.3 86 70-142 1,3-Dichloropropane ug/L ND 20 15.8 79 70-141 1,4-Dichlorobenzene ug/L ND 20 17.2 86 70-140 2,2-Dichloropropane ug/L ND 20 18.1 90 58-160 2-Butanone (MEK) ug/L ND 40 30.7 77 57-156 2-Chlorotoluene ug/L ND 20 17.0 85 70-148 2-Hexanone ug/L ND 40 30.5 76 62-153 4-Chlorotoluene ug/L ND 20 17.1 85 70-144 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/16/2023 11:22 AM without the written consent of Pace Analytical Services, LLC. Page 23 of 37 �Yace- QUALITY CONTROL DATA Project: MONITORING WELLS Pace Project No.: 92696570 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 MATRIX SPIKE SAMPLE: Parameter 4200044 Units 92696570001 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 4-Methyl-2-pentanone (MIBK) ug/L ND 40 30.8 77 65-144 Acetone ug/L ND 40 30.6 76 49-162 Benzene ug/L ND 20 17.5 87 68-144 Bromobenzene ug/L ND 20 16.7 83 70-144 Bromochloromethane ug/L ND 20 16.8 84 70-148 Bromodichloromethane ug/L ND 20 15.6 78 70-141 Bromoform ug/L ND 20 14.4 72 59-144 Bromomethane ug/L ND 20 15.8 79 23-190 v3 Carbon tetrachloride ug/L ND 20 17.2 86 70-147 Chlorobenzene ug/L ND 20 17.3 86 70-143 Chloroethane ug/L ND 20 17.8 89 55-190 Chloroform ug/L ND 20 16.6 83 67-148 Chloromethane ug/L ND 20 17.8 89 38-180 cis- 1,2-Dichloroethene ug/L ND 20 17.4 87 67-151 cis- 1,3-Dichloropropene ug/L ND 20 15.7 79 70-142 Dibromochloromethane ug/L ND 20 15.6 78 68-140 Dibromomethane ug/L ND 20 15.9 79 70-142 Dichlorodifluoromethane ug/L ND 20 18.5 93 15-200 Diisopropyl ether ug/L ND 20 15.8 79 62-149 Ethylbenzene ug/L ND 20 17.1 86 70-145 Hexachloro-1,3-butadiene ug/L ND 20 18.9 94 64-164 Isopropyl benzene (Cumene) ug/L ND 20 17.7 89 70-144 m&p-Xylene ug/L ND 40 34.1 85 70-148 Methyl-tert-butyl ether ug/L ND 20 14.4 72 64-146 Methylene Chloride ug/L ND 20 17.3 87 54-149 n-Butylbenzene ug/L ND 20 18.3 91 70-154 n-Propylbenzene ug/L ND 20 17.1 86 70-140 Naphthalene ug/L ND 20 15.6 78 62-154 o-Xylene ug/L ND 20 17.1 85 70-145 p-Isopropyltoluene ug/L ND 20 17.8 89 70-153 sec-Butylbenzene ug/L ND 20 17.5 88 70-145 Styrene ug/L ND 20 16.6 83 70-147 tert-Butyl Alcohol ug/L ND 200 149 75 49-190 tert-Butylbenzene ug/L ND 20 14.3 71 66-130 v3 Tetrachloroethene ug/L ND 20 17.6 88 70-145 Toluene ug/L ND 20 16.9 84 65-146 trans- 1,2-Dichloroethene ug/L ND 20 18.5 92 69-155 trans-1,3-Dichloropropene ug/L ND 20 15.2 76 70-142 Trichloroethene ug/L ND 20 17.5 87 70-152 Trichlorofluoromethane ug/L ND 20 17.4 87 60-158 Vinyl acetate ug/L ND 40 30.2 75 56-157 Vinyl chloride ug/L ND 20 17.5 87 51-178 1,2-Dichloroethane-d4 (S) % 95 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 99 70-130 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/16/2023 11:22 AM without the written consent of Pace Analytical Services, LLC. Page 24 of 37 Pace Analytical Services, LLC 2225 Riverside Dr. ,41ace" Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: MONITORING WELLS Pace Project No.: 92696570 SAMPLE DUPLICATE: 4200045 Parameter Units 92696570002 Result Dup Result RPD Max RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,1-Dichloropropene ug/L ND ND 30 1,2,3-Trichlorobenzene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2,4-Trichlorobenzene ug/L ND ND 30 1,2,4-Trimethylbenzene ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloroethene (Total) ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,3,5-Trimethylbenzene ug/L ND ND 30 1,3-Dichlorobenzene ug/L ND ND 30 1,3-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 2,2-Dichloropropane ug/L ND ND 30 2-Butanone (MEK) ug/L ND ND 30 2-Chlorotoluene ug/L ND ND 30 2-Hexanone ug/L ND ND 30 4-Chlorotoluene ug/L ND ND 30 4-Methyl-2-pentanone (MIBK) ug/L ND ND 30 Acetone ug/L ND ND 30 Benzene ug/L ND ND 30 Bromobenzene ug/L ND ND 30 Bromochloromethane ug/L ND ND 30 Bromodichloromethane ug/L ND ND 30 Bromoform ug/L ND ND 30 Bromomethane ug/L ND ND 30 v2 Carbon tetrachloride ug/L ND ND 30 Chlorobenzene ug/L ND ND 30 Chloroethane ug/L ND ND 30 Chloroform ug/L ND ND 30 Chloromethane ug/L ND ND 30 cis-1,2-Dichloroethene ug/L ND ND 30 cis-1,3-Dichloropropene ug/L ND ND 30 Dibromochloromethane ug/L ND ND 30 Dibromomethane ug/L ND ND 30 Dichlorodifluoromethane ug/L ND ND 30 Diisopropyl ether ug/L ND ND 30 Ethylbenzene ug/L ND ND 30 Hexachloro-1,3-butadiene ug/L ND ND 30 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/16/2023 11:22 AM without the written consent of Pace Analytical Services, LLC. Page 25 of 37 Yaceo Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MONITORING WELLS Pace Project No.: 92696570 SAMPLE DUPLICATE: 4200045 Parameter Isopropylbenzene (Cumene) m&p-Xylene Methyl-tert-butyl ether Methylene Chloride n-Butylbenzene n-Propylbenzene Naphthalene o-Xylene p-Isopropyltoluene sec-Butylbenzene Styrene tert-Butyl Alcohol tert-Butylbenzene Tetrachloroethene Toluene trans- 1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) QUALITY CONTROL DATA Units 92696570002 Result Dup Result RPD Max RPD Qualifiers ug/L ND ND 30 ug/L ND ND 30 ug/L ND ND 30 ug/L ND ND 30 ug/L ND ND 30 ug/L ND ND 30 ug/L ND ND 30 ug/L ND ND 30 ug/L ND ND 30 ug/L ND ND 30 ug/L ND ND 30 ug/L ND ND 30 ug/L ND ND 30 v2 ug/L ND ND 30 ug/L ND ND 30 ug/L ND ND 30 ug/L ND ND 30 ug/L ND ND 30 ug/L ND ND 30 ug/L ND ND 30 ug/L ND ND 30 % 95 96 % 98 96 e/ 104 99 Results presented on this page are in the units indicated by the -Units- column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/16/2023 11:22 AM without the written consent of Pace Analytical Services, LLC. Page 26 of 37 � laceo QUALITY CONTROL DATA Project: MONITORING WELLS Pace Project No.: 92696570 QC Batch: 812019 Analysis Method: SM 4500-H+B-2011 QC Batch Method: SM 4500-H+B-2011 Analysis Description: 4500H+B pH Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92696570001, 92696570002, 92696570003, 92696570004 Pace Analytical Services, LLG 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 SAMPLE DUPLICATE: 4204488 92697285002 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.4 6.5 1 10 H3 SAMPLE DUPLICATE: 4204489 92697285003 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.4 6.4 1 10 H3 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/16/2023 11:22 AM without the written consent of Pace Analytical Services, LLC. Page 27 of 37 �Yaceo QUALITY CONTROL DATA Project: MONITORING WELLS Pace Project No.: 92696570 QC Batch: 810775 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92696570001, 92696570002, 92696570003, 92696570004 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 METHOD BLANK: 4197596 Matrix: Water Associated Lab Samples: 92696570001, 92696570002, 92696570003, 92696570004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Bromide mg/L ND 0.10 0.060 11/03/2318:21 Chloride mg/L ND 1.0 0.60 11/03/2318:21 Fluoride mg/L ND 0.10 0.050 11/03/2318:21 Sulfate mg/L ND 1.0 0.50 11/03/2318:21 LABORATORY CONTROL SAMPLE: 4197597 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Bromide mg/L 2.5 2.5 100 90-110 Chloride mg/L 50 52.7 105 90-110 Fluoride mg/L 2.5 2.7 108 90-110 Sulfate mg/L 50 53.7 107 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4197598 4197599 MS MSD 92696521002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua[ Bromide mg/L 0.15 2.5 2.5 2.6 2.6 98 97 90-110 1 10 Chloride mg/L 7.6 50 50 58.6 58.8 102 102 90-110 0 10 Fluoride mg/L 0.13 2.5 2.5 3.0 3.0 115 113 90-110 1 10 M1 Sulfate mg/L 202 50 50 250 250 96 96 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4197600 4197601 MS MSD 92696570001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua[ Bromide mg/L ND 2.5 2.5 2.6 2.5 103 101 90-110 2 10 Chloride mg/L ND 50 50 54.1 53.5 107 106 90-110 1 10 Fluoride mg/L ND 2.5 2.5 2.8 2.7 109 107 90-110 2 10 Sulfate mg/L ND 50 50 54.6 53.5 108 106 90-110 2 10 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/16/2023 11:22 AM without the written consent of Pace Analytical Services, LLC. Page 28 of 37 �41aceo QUALITY CONTROL DATA Project: MONITORING WELLS Pace Project No.: 92696570 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QC Batch: 813274 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92696570001, 92696570002, 92696570003, 92696570004 METHOD BLANK: 4210891 Matrix: Water Associated Lab Samples: 92696570001, 92696570002, 92696570003, 92696570004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Ammonia mg/L ND 0.10 0.031 11/15/23 03:30 LABORATORY CONTROL SAMPLE: 4210892 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 4.9 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4210893 4210894 MS MSD 92697823002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Ammonia mg/L 36.0 5 5 40.9 41.0 98 99 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4210895 4210896 MS MSD 92697933001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Ammonia mg/L ND 5 5 4.8 4.8 97 96 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/16/2023 11:22 AM without the written consent of Pace Analytical Services, LLC. Page 29 of 37 ace" Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: MONITORING WELLS Pace Project No.: 92696670 QC Batch: 813543 Analysis Method: EPA 351.2 Rev 2.0 1993 QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92696570001, 92696570002, 92696570003, 92696570004 METHOD BLANK: 4212198 Matrix: Water Associated Lab Samples: 92696570001, 92696570002, 92696570003, 92696570004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Kjeldahl, Total mg/L ND 0.50 0.25 11/16/23 05:55 LABORATORY CONTROL SAMPLE: 4212199 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Kjeldahl, Total mg/L 10 10.2 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4212200 MS MSD 92696570003 Spike Spike Parameter Units Result Conc. Conc. Nitrogen, Kjeldahl, Total mg/L ND 10 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4212202 MS 92696570004 Spike Parameter Units Result Conc. Nitrogen, Kjeldahl, Total mg/L ND MSD Spike Conc. 10 10 4212201 MS MSD MS MSD % Rec Max Result Result % Rec % Rec Limits RPD RPD Qual 10.1 10.3 101 103 90-110 1 10 4212203 MS MSD MS MSD % Rec Max Result Result % Rec % Rec Limits RPD RPD Qual 10.6 10.9 105 108 90-110 3 10 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/16/2023 11:22 AM without the written consent of Pace Analytical Services, LLC. Page 30 of 37 QUALITY CONTROL DATA Project: MONITORING WELLS Pace Project No.: 92696570 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QC Batch: 810736 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92696570001, 92696570002, 92696570003, 92696570004 METHOD BLANK: 4197503 Matrix: Water Associated Lab Samples: 92696570001, 92696570002, 92696570003, 92696570004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Nitrate mg/L ND 0.040 0.010 11/02/23 23:43 Nitrogen, Nitrite mg/L ND 0.040 0.031 11/02/23 23:43 LABORATORY CONTROL SAMPLE: 4197504 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 1.5 1.4 95 90-110 Nitrogen, Nitrite mg/L 1 0.98 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4197505 4197506 MS MSD 92696493006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L ND 1.5 1.5 1.5 1.5 99 97 90-110 2 10 Nitrogen, Nitrite mg/L 0.94 1 1 1.5 1.6 59 63 90-110 3 10 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4197507 4197508 MS MSD 92696552001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 8.6 1.5 1.5 10.3 10.4 112 115 90-110 0 10 Nitrogen, Nitrite mg/L ND 1 1 1.1 1.1 106 106 90-110 0 10 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/16/2023 11:22 AM without the written consent of Pace Analytical Services, LLC. Page 31 of 37 �Yaceo QUALITY CONTROL DATA Project: MONITORING WELLS Pace Project No.: 92696570 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QC Batch: 810749 Analysis Method: SM 4500-P E-2011 QC Batch Method: SM 4500-P E-2011 Analysis Description: SM450OP-E Phosphorus, Ortho Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92696570001, 92696570002, 92696570003, 92696570004 METHOD BLANK: 4197531 Matrix: Water Associated Lab Samples: 92696570001, 92696570002, 92696570003, 92696570004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Orthophosphate as P mg/L ND 0.050 0.012 11/03/23 02:33 LABORATORY CONTROL SAMPLE: 4197532 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Orthophosphate as P mg/L 0.25 0.25 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4197533 4197534 MS MSD 92696374001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Orthophosphate as P mg/L ND 0.25 0.25 0.26 0.27 97 104 90-110 7 10 Results presented on this page are in the units indicated by the -Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/16/2023 11:22 AM without the written consent of Pace Analytical Services, LLC. Page 32 of 37 �41aceo QUALIFIERS Project: MONITORING WELLS Pace Project No.: 92696570 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as 'Total' may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS H3 Sample was received or analysis requested beyond the recognized method holding time. IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be considered an estimated value. L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11/16/2023 11:22 AM without the written consent of Pace Analytical Services, LLC. Page 33 of 37 �Yaceo QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: MONITORING WELLS Pace Project No.: 92696570 Lab ID Sample ID 92696570001 MW-1R 92696570002 MW-2 92696570003 MW-3 92696570004 MW-4 92696570001 MW-1R 92696570002 MW-2 92696570003 MW-3 92696570004 MW-4 92696570001 MW-111 92696570002 MW-2 92696570003 MW-3 92696570004 MW-4 92696570001 MW-1R 92696570002 MW-2 92696570003 MW-3 92696570004 MW-4 92696570001 MW-111 92696570002 MW-2 92696570003 MW-3 92696570004 MW-4 92696570001 MW-1R 92696570002 MW-2 92696570003 MW-3 92696570004 MW-4 92696570001 MW-1R 92696570002 MW-2 92696570003 MW-3 92696570004 MW-4 92696570001 MW-111 92696570002 MW-2 92696570003 MW-3 92696570004 MW-4 92696570001 MW-1R 92696570002 MW-2 92696570003 MW-3 92696570004 MW-4 92696570001 MW-111 92696570002 MW-2 92696570003 MW-3 92696570004 MW-4 Date: 11/16/2023 11:22 AM QC Batch Method EPA 200.7 EPA 200.7 EPA 200.7 EPA 200.7 EPA 200.8 EPA 200.8 EPA 200.8 EPA 200.8 EPA 8260D EPA 8260D EPA 8260D EPA 8260D SM 4500-H+B-2011 SM 4500-H+B-2011 SM 4500-H+B-2011 SM 4500-H+B-2011 EPA 300.0 Rev 2.1 1993 EPA 300.0 Rev 2.1 1993 EPA 300.0 Rev 2.1 1993 EPA 300.0 Rev 2.1 1993 EPA 350.1 Rev 2.0 1993 EPA 350.1 Rev 2.0 1993 EPA 350.1 Rev 2.0 1993 EPA 350.1 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 SM 4500-P E-2011 SM 4500-P E-2011 SM 4500-P E-2011 SM 4500-P E-2011 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Analytical QC Batch Analytical Method Batch 964625 964625 964625 964625 964623 964623 964623 964623 811225 811225 811225 811225 812019 812019 812019 812019 810775 810775 810775 810775 813274 813274 813274 813274 813543 813543 813543 813543 810736 810736 810736 810736 810749 810749 810749 810749 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. EPA 200.7 EPA 200.7 EPA 200.7 EPA 200.7 EPA 200.8 EPA 200.8 EPA 200.8 EPA 200.8 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993 964812 964812 964812 964812 964813 964813 964813 964813 813631 813631 813631 813631 Page 34 of 37 �F�ace 11.. 7 tE3(:N uuiF I IUe: t:NV-t-KM-HUN1-UUS3 vuZ_5ample Condition Upon Receipt Effective Date: 11/14/2022 Laboratory receiving samples: J Asheville ❑ Eden❑ Greenwood ❑ Huntersville F-� Raleigh❑ Mechanicsville❑ Atlanta[:] Kernersville❑ SampleClient Name:® Upon Receipt I 7 Project 926965�0 0: Courier: ed Ex ❑UPS ❑USPS ❑Client Il�ll' II� III �' III�I'II El Commercial [Pace ❑Other: 926915570 Custody Seal Present? ❑.Yes 16No Seals Intact? ❑Yes ❑No Date/Initials Person Examining Contents: Packing Material: ❑Bubble Wrap []Bubble Bags ❑None[,] Other Biological Tissue Frozen? Thermometer: _ ❑ IRGun Jp ' % ❑Yes []No ©�N/A I0: ��0 I `� Type of Ice: [Wet QBlue ❑None Correction Factor: Cooler Temp: f Add/Subtract ('C) r J Temp should be above freezing to 6°C n QSamples out of temp criteria. Samples on ice, cooling process Cooler Temp Corrected ( C): _ ? : i has begun USDA Regulated Soil ( ED N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC Did samples originate from a foreign source (internationally, (check mans17 nYpt nNn ;.A u. —il —4 o..,,..., t—I� _ M.._ Comments/Discrepancy: Chain of Custody Present? dyes QNo QN/A 1. Samples Arrived within Hold Time? [Yes QNo QN/A 2. Short Hold Time Analysis (02 hr.)? QYes []No QN/A 3. Rush Turn Around Time Requested? QYes dNo QN/A 4. Sufficient Volume? )Yes QNo QN/A 5. Correct Containers Used? Pace Containers Used? Oyes dyes QNo No QN/A QN/A 6. Containers Intact? Yes QNo []N/A 7. Dissolved analysis: Samples Field Filtered? QYes 6No QN/A 8. -Includes Date/Time/ID/Analysis Matrix: Headspace in VOA Vials (>5.6mm)? ❑Yes d No QN/A 10. Trip Blank Present? Trip Blank Custody Seals Present? []Yes [--]Yes : No [:]No QN/A 1)N/A 11. COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Date/Time: Project Manager SCURF Review: Date: Project Manager SRF Review: Date: Field Data Required? ❑Yes ❑No Page 35 of 37 Qual(rax IQ: 69614 Page 1 of 2 /l!�aceUU;; I itle: ENV-FRM-HUN1-0083 v02_sample Condition Upon Receipt t........:...: Effective Date: 11/14/2022 *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coiiform. TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg "Bottom half of box is to list number of bottles "'Check all unpreserved Nitrates for chlorine Project PM: JW8 Due Date: 11/17/23 CLIENT: 83—MARION 2 W v Z N m ? N v .Z N _ N _ a Q O Z Mn U ti A h a C '�°- .2,� CI itv N ` Z 'D a N V n N S , Q z Q Z ? d Q Z 9 Z ? Y a IQ z s A ' Z of M 0 4 ? Gi 0)? \ 2 fp 13 Z c u N c u N c u N i; Q "� = y •� ffl Z u N N a Z N u O ° Z u N w L Q c M S n v z N `7 7 t. y .0 0 y O� N z v z 2 U O N r-4 d a c v c. m N v Q c C7 Z n ? u n cam. w a N N S ? $ c s c � N v a j Q. J E in ti Q. J E o N O. J E S to 10 d o`, -- M a J E ,� a -J E o N ro `a J E N .Ni n . J E o .N-t 0 E 3 ", 0 E a a`, _ r•1 E Q ;, = .-/ Q J E o N .a 5 E Q °: e 1 E a J E O N E -� E q O > J E V Q 0 > J E Q a 0 > J E 7 a O > J E K 'H _m a E yOj m o. = e •a`, N J E N H .M N J E N N . o n. J E to N E a '' E 5 G E O N d .0 E E O V v _ O a m > Q. m > G. m > a m N v a m Z M a m eJ v a M in a I m W Vr 3 O rl t7 a = N l9 a M t7 Q t0 a N M t7 a V ai C7 c 2 01, o>> O~1 l7 O' t7 Q1 a A dCh x> w m a t9 o 1 -L 1 J 3 -7- 4 � S \ 6 7 8 9 10 11 12 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added lot ft .ute-—1leeac e, untie Ia a u.xrepans.y aecimg Norm Caronna comp Rance samples, a copy of this form will be sent to the North Carolina DENR Certification Office( i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Qualtrax ID: 69614 Page 2 of 2 Page 36 of 37 75 CO 3 3 3 a d f x LA e A ec L e o. z oa N a o S y C SE O r p q � n O C N N d • }`.•iCii v � I v W YS' � a 3 W W W WtA T a v o N M C W v 3 V = 4 io = o .l VN1x VI m O O m S 9 n O 2 !L 2-6 °� Z C g _L- E a n z g 5 X )< x X 200.8 MET ICPMS i X x J !) 300.0 IC Anions 28 Days — a_ / .✓ `J 350.1 Ammonia T o 351.2 Total KJeldahi Nitrogen "• R ' x y, 'X 353.2 Nitrogen, NO2IN03 unpres = y , N y v �/ y 4500H+ pH, Electrometric, rt m c 3 /� n 2 m 1S q p z A z )r v 8260D MSV ` �• 'y SM450OP•E, Phosphate, Ortho a S o 3 3 Lab Use Only rr e No •^ �.�. � _ N m W q3 d 0• � � 3 7 S a —_ a r Page 37 of 3 I I I I I I Identlrled for Preservation non-conformance�tl �.. sample. #sys_loc_0 measurement_ date M W-3 11/2/2023 11:50 M W-4 11/2/2023 1:43 MW-1R 11/2/202312:55 M W-2 11/2/2023 1:20 equipment historical_r water leve water_leve depth_unit reportable_yn 50.02 14.62 35.4 ft y 35.37 13.74 21.63 ft y 62.62 33.57 29.05 ft y 38.02 16.87 21.15 ft y E 'GttGGGGG GGGGGtGGGGGGGGGtGtG r 8 m E of E m E "Ix x x x x x x x x x x x x x x x x x x x x x x x x x x x =ddaaaaaaa�ad�da�daaaaadada�a = I I I I I I I I wl w'wi wl w'w'wl wl wl I I I I I I 'wl w'wl E u u ti a ti u u u u u u u u u u u u u u u ti u .1 u u u E a a a a a a a n i i a n i a a a a a a u a a a n a a a a t c E I EU' l7 l7 l7 l7 l7 U' (7 l7 U' U' l7 l7 (7 l7 U' l7 l7 l7 l7 (7 l7 l7 l7 l7 (7 U' l7 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 8 3 E E E E m w o u c E vz E �a zin c E azE vz y° u p w 0 u p u z u z u z u z M o ry o 0 0 0 0 0 0 0 o m �Mif ief i1°ll ul M N N N N in vl of vl of vOi i�f C O C O O O C E � e4 .i N .Ni .N-� .� �-1 .i .. .. .Mi N N •i .-I .. .-1 '. .i .� H .m-I w '1 .-, .. ti «I �I C N a w w a C >o N clu u O u O U N V Y E w ° E a w E A Q O O Qu QU uQQ QV C C K C uEnl z o o Z f, 1 o <0008sa s 00 p w u r. < O O o u m O�o 00 o0 a m a u I= I- I I I I I I I I I I I I I I I I 0 0 0 0 0 0 0 0 0 I I I I I I I I o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 N N N T M T m m m m m m m m m m m m m m _ N N N N N N E N NI NI NI N NI OI N N N N N N N N N N N N N N N N N N N N N w6 Ki ti ff I I I NI NI NI I I I I I I I I I I I I I 9 V 5 v Y Y Y „13 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 i 0 o x N x x x ml ¢l al a¢l wl w'al al w l u u d u u u a a u u u u a a u u u u u u d a a u u u u u 131C )�F3311C' 31 : F ppc6nitasu�1; �iQlircll.tf...lg- ' MgmF? 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IL;xmr,_.,nw 'ik3r,.;i=' :. �':1� 1J��1 w P ruervetlannon-conklFr rivince Fdand d'for' YR61hl ai!�r ri rl.l':.._41��niii e 11/30/23, 2:12 PM Submission Completed DWR - NonDischarge Monitoring Report Submittal Permit #: * Name of Facility:* Month: * November Report Information Type * GW-59 W00003698 Corpening Creek WWTP Confirmation Email Address:* Name of Submitter: Signature: * Submittal Date: Year:* 2023 Upload Document* MW Package--11.30.23.pdf PDF Only Please upload one PDF containing all applicable monitoring reports (i.e., NDMR, NDAR-1, NDAR-2, NDMLR, GW-59). thorton@marionnc.org Tim Horton 11 /30/2023 Will be filled out automatically. 3.26 M B dti d NORTH CAROLINA EnYiYOhmPnfQ� Quality https://edocs.deq.nc.gov/Forms/Form/Submit 1 /1