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HomeMy WebLinkAboutNC0020559_Fact Sheet_20231130Fact Sheet NPDES Permit No. NCO020559 Permit Writer/Email Contact: Gary Perlmutter, gary.perlmutter@deq.nc.gov Date: November 17, 2023 Division/Branch: NC Division of Water Resources/NPDES Municipal Permitting Fact Sheet Template: Version 09Jan2017 Permitting Action: 0 Renewal ❑ Renewal with Expansion ❑ New Discharge ❑ Modification (Fact Sheet should be tailored to mod request) Note: A complete application should include the following: • For New Dischargers, EPA Form 2A or 2D requirements, Engineering Alternatives Analysis, Fee • For Existing Dischargers (POTW), EPA Form 2A, 3 effluent pollutant scans, 4 2nd species WET tests. • For Existing Dischargers (Non-POTW), EPA Form 2C with correct analytical requirements based on industry category. Complete applicable sections below. If not applicable, enter NA. 1. Basic Facility Information Facility Information Applicant/Facility Name: City of Henderson/ Henderson Water Reclamation Facility (WRF) Applicant Address: PO Box 1434, Henderson, NC 27536 Facility Address: 1646 West Andrews Avenue, Henderson, NC 27536 Permitted Flow: 4.14 MGD / 6.0 MGD Facility Type/Waste: MAJOR Municipal: 98.2% domestic, 1.8% industrial' Facility Class: Grade IV Treatment Units: Bar screen, grit chamber, Parshall flume, biological nutrient removal system (BNR: oxidation ditch with anaerobic and anoxic basins), clarifiers, tertiary sand filters, post aeration, UV disinfection; sludge digestor, thickener Pretreatment Program (Y/N) Yes; active with LTMP County: Vance Region Raleigh Footnote. 1. Based on total permitted industrial flow of 0.075 MGD. Briefly describe the proposed permitting action and facility background: The City of Henderson has applied for an NPDES permit renewal for its WRF in November 2022. Review of the application found it incomplete with only the EPA Form 2A and a topographic map submitted; the following attachments were found lacking: • Three Effluent Pollutant Scans Page 1 of 19 • Four 2nd species (Fathead Minnow) whole effluent toxicity reports • Process narrative • Facility diagram with water balances • Sludge management plan • Mercury Minimization Plan action summary • Chemical Addendum These elements were requested on 9/11/2023 and all but the Chemical Addendum and diagram were received on 9/19/2023; the remaining were received on 9/25 and 9/26/2023. This facility serves a population of-16,400 residents in the City of Henderson (-15,000) and parts of Vance County (-1400). The facility has an active pretreatment program with one SIU, Mars Pet Care (pet food manufacturer). Inflow and Infiltration (I&I): The City reported an average daily flow of 0.195 MGD I&I. From the application, the City states: "The City of Henderson has secured funding from state funding in order to address I&I issues within the Sandy Creek Basin which contributes a major portion of I&I flow. " Sludge Management: From the submitted Sludge Management Plan: "We have two aerobic digesters, a drum thickener, we use polymer to dewater sludge. We also process 35-45 thousand gallons of mixed liquor per day. Digested sludge is hauled from the facility by Granville Farms who holds a land application permit. (Permit number WQ0000838) The onsite Lab forms testing to facilitate wasting rates. " 2. Receiving Waterbody Information Receiving Waterbody Information Outfalls/Receiving Stream(s): Outfall 001 — Nutbush Creek Stream Segment: 23-8-(1)b Stream Classification: C Drainage Area (mi2): 3.8 Summer 7Q10 (cfs) 0.2 Winter 7Q10 (cfs): 0.4 30Q2 (cfs): 0.5 Average Flow (cfs): 3.5 IWC (% effluent): 97% at 4.14 MGD / 98% at 6.0 MGD 2022 303(d) listed/parameter: Fish Community (Nar, AL, FW) Subject to TMDL/parameter: Statewide Mercury TMDL River Basin/HUC: Roanoke / 03010102 USGS Topo Quad: Henderson, NC The 2022 Integrated Report cites the receiving stream segment as meeting criteria for all parameters assessed except for Fish Community, which is impaired, and Fecal Coliform, for which data are inconclusive. Nutbush Creek was assessed for Fish Community on 5/28/2019, resulting in a bioclassification of Fair. Page 2 of 19 3. Effluent Data Summary Effluent data for Outfall 001 are summarized from February 2019 through August 2023 (Table 1). Table 1. Effluent Data Summary Outfall 001. Parameter Units Average Max Min Permit Limit 1 Flow MGD 2.23 11.50 0.70 MA = 4.14 BOD5 summer mg/L 3.3 21.4 1.5 WA = 9.0 MA = 6.0 BOD5 winter mg/L 3.8 89.8 < 2 WA = 18.0 MA = 12.0 BOD Removal % 97.9 99.7 70.5 > 85 TSS mg/L 3.7 309 < 2.5 WA = 45.0 MA = 30.0 TSS Removal % 98.4 99.9 34.6 > 85 mg/L 9 NH3N summer 0.54 17.6 < 0.1 MA = 3.0 NH3N winter mg/L 0.57 14.9 < 0.1 MA = 6.0 TN mg/L 5.6 12.7 u.6 Monitor & Report TP summer mg/L 0.147 0.833 0.022 QA = 1.0 TP winter mg/L 0.087 0.363 0.028 QA = 1.5 TRC µg/L 17.0 19.8 < 16.0 DM = 17.0 2 Fecal coliform #/100 mL 12.3 > 18,900 < 1 WA = 400 (geometric mean) MA = 200 pH SU 6.8 7.5 6.1 6.0 - 9.0 DO mg/L 8.2 12.6 6.0 DA > 6.0 Temperature ° C 19.2 28.3 Monitor & Report Conductivity µmhos/cm 405 1453 IJV Monitor & Report Total Cadmium µg/L All non -detects at < 0.15 Monitor & Report Total Copper µg/L 2.2 4 < 2 MA = 26.7 DM = 39.9 Total Selenium µg/L All non -detects at < 1 Monitor & Report Total Silver µg/L All non -detects at < 0.5 with one at < 5 Monitor & Report Total Hardness mg/L 51 64 40 Monitor & Report Footnotes on the next page. Page 3 of 19 Footnotes. 1. MA = Monthly Average; WA = Weekly Average, QA = Quarterly Average; DM = Daily Maximum; DA = Daily Average. 2. Results < 50 µg/L considered compliant. The highest annual average flow was 2.468 MGD, 59.6% of the permitted 4.14 MGD flow, in 2021. 4. Instream Data Summary Instream monitoring may be required in certain situations, for example: 1) to verify model predictions when model results for instream DO are within 1 mg/1 of instream standard at full permitted flow; 2) to verify model predictions for outfall diffuser; 3) to provide data for future TMDL; 4) based on other instream concerns. Instream monitoring may be conducted by the Permittee, and there are also Monitoring Coalitions established in several basins that conduct instream sampling for the Permittee (in which case instream monitoring is waived in the permit as long as coalition membership is maintained). If applicable, summarize any instream data and what instream monitoring will be proposed for this permit action: The current permit requires instream monitoring for a variety of parameters at various frequencies at one upstream (U) and two downstream (D1, D2) locations: • DO, Temperature, Conductivity — weekly at all locations • DO, Temperature, Secchi Depth, NO2+NO3, Ammonia, TKN, TP, Chlorophyll -a — monthly in summer at D 1 and D2 o DO, Temperature at depth profiles of 1 m intervals o NO2+NO3, Ammonia, TKN, TP, Chl-a as spatial composites throughout the photic zone • Total Hardness — quarterly at U. The locations are: • U at NC Hwy 39, —0.27 miles above the outfall; • D1 at powerline crossing, —0.43 miles below the outfall; and • D2 at immediately above the confluence of Indian Creek and Crooked Creek in Kerr Lake, —3.8 miles below the outfall. This extensive instream monitoring regime was first placed into the permit in 1990 following recommendations of an instream assessment conducted in 1988, citing lake concerns of hyper- and mesotrophic conditions and that the Nutbush Creek arm of the lake is dominated by WWTP effluent. Instream data were acquired from submitted DMRs from August 2018 through February 2023 for review. The data were checked against applicable stream standards as well as for effluent impacts, the latter via statistical testing of downstream averages against the upstream average of each parameter using t-test with the level of significance (p-value) set at 0.05. Hardness data are required for calculating total metals from dissolved metals that are hardness -dependent and are discussed in Section 6.4 Reasonable Potential Analysis below. The data are summarized in Tables 2 — 4 and discussed here. ble 2. Instream Data Summary: averages of year-round data with ranges in parentheses. *Statistically significantly different from Upstream. arameter, units U (Outfall 001) D1 (Outfall 001) D2 (Outfall 001A) Standard DO, mg/L Avg = 10.6 (5.4-18.3) Avg = 10.6 (5.9-16.2) Avg = 10.7 (6.1-16.8) 5.0 Temperature, °C Avg = 15.2 (3.1-27.7) Avg = 18.9* (4.6-33.4) Avg = 19.4* (4.3-32.9) 32.0 Conductivity, mhos/cm Avg = 215 (7-587) Avg = 130* (70-238) Avg = 102* (71-148) NA Page 4 of 19 Dissolved Oxygen (DO) — DO is in the permit as a parameter of concern for aquatic life. Summer minima at all stations were all above the stream standard of 5.0 mg/L (15A NCAC 02B .0211). No statistically significant differences were found between the upstream and downstream stations. Concurrent effluent average DO is similar with similar summer minima. Temperature Temperature is in the permit as a parameter of concern for aquatic life. The summer maximum at the upstream station was below the 32°C standard for lower piedmont and coastal plain waters (15A NCAC 02B .0211), but the maxima downstream exceeded the standard with the maximum at D2 highest. Statistically significant differences were found between U and D 1 and between U and D2 with the downstream temperatures at both stations higher. Average increase from up- to downstream temperature increase at both stations was higher than the standard of 2.8°C (15A NCAC 02B .0211) with the average increase to DI being 3.78 and the average increase to D2 being 3.71 °C. Temperature at DI increased > 2.8°C from upstream 143 times and at D2 it increased > 2.8°C from upstream 108 times. Concurrent effluent temperatures are similar to those downstream, and on average higher than upstream. Statistical t-testing found the effluent temperature to be significantly higher than that at U but not at than D 1. Conductivity — Conductivity is in the permit as an indicator of industrial sources. The Town has an active pretreatment program with one SIU, a pet food manufacturer. Downstream Conductivity at both stations tested significantly lower than the upstream conductivity, suggesting no impact from the effluent. However, concurrent effluent Conductivity is twice as high as that upstream, suggesting the potential to impact. It is also possible that additional sources upstream are contributing to the conductivity of the stream. Fecal Coliform — Instream monitoring for Fecal Coliform is not in the current permit; it was removed from the permit in 1997. According to Division guidance, instream fecal coliform monitoring may be removed from a permit unless the receiving stream is either Class B or impaired for the parameter. The receiving stream Nutbush Creek currently meets the criteria as it is not impaired and is a Class C waterbody. Nutbush Creek is also a headwater of Kerr Lake, which is Class B at —3.6 miles downstream of the outfall. Instream fecal coliform data are available via the Division's Ambient Monitoring System at Station N5000000, located at NCSR 1317 (Spring Valley Rd), —1.3 miles downstream of the outfall. Reviewed data from January 2019 through December 2022 (n = 26 samples) ranged from 13 — 2500 cfu/ 100 mL with a geometric mean of 225 cfu/100 mL. The Division's 2012 Roanoke Basin Plan reported that for the period of 2004 — 2008 the geomean was 116 cfu/100 mL, noting that when the geometric mean exceeds 200 cfu/100 mL, there is a strong likelihood a 5-in-30 study would result in impairment. To address this concern, instream monitoring for Fecal Coliform at all stations will be added to the permit at the same frequencies as for DO, Temperature and Conductivity. Depth profile data show that D1 at the powerline is a shallower waterbody than D2, which is deeper into Kerr Lake. DO decreased with depth at both stations, but temperatures show a consistent decrease only at D2 (Table 3). Page 5 of 19 Table 3. Instream Data Summary: averages of summer depth profile data with ranges in parentheses. Parameter, units Depth DI (Out001) 2 (Outfa11OO1A) Standard Surface Avg = 10.6 Avg = 9.3 5.0 (5.9 - 16.2) (6.1 - 13.7) 1 in Avg = 9.5 Avg = 9.4 NA (4.8 - 17.0) (5.8 - 14.0) 2 m 6.0 Avg = 9.0 NA DO m /L g (N = 1 sample) (4.4 -12.3) 3 m NA Avg = 7.8 NA (4.1 - 11.0) 4 m NA Avg = 7.3 NA (3.9 - 11.4) Surface Avg = 24.8 Avg = 25.0 32.0 (15.6 - 33.4) (15.2 - 32.9) 1 in Avg = 24.6 Avg = 24.4 NA (16.7 - 30.8) (15.1 - 30.7) 2 in 7 NA Temperature, °C (N = 1 sample) 4.7 - 29.7) (1 3 m NA Avg = 23.2 NA (13.3 - 29.1) 4 m NA Avg = 22.9 NA (14.3 - 28.9) Summer monitoring for nutrient and related data were reviewed and compared between the two downstream stations by statistical t-tests. All but Ammonia tested significantly lower at D2 than at D 1; Ammonia tested no difference (Table 4). Effluent nutrient parameters TN & TP plus Ammonia were all much higher than instream concentrations on average, suggesting effluent impact. To better understand the potential instream impact by the effluent, upstream monitoring for Ammonia, NO2+NO3, TKN, and TP will be added to the permit. Table 4. Instream Data Summary: summer downstream nutrient and related parameters (averages with ranges in parentheses). *Statistically significantly different from D1. Parameter, units D1 AMS Station D2 Standard (Outfall001) N5000000 (Outfall001A) Ammonia (NH3-N), mg/L Avg = 0.100 Avg = 0.11 Avg = 0.097 NA (0.061-0.200) (0.02-1.70) (0.071-0.100) NOz+NO3, mg/L Avg = 0.19 Avg = 2.93 Avg = 0.11 NA (0.10-0.72) (0.48-6.8) (0.10-0.43) TKN, mg/L Avg = 0.98 Avg = 0.68 Avg = 0.63* NA (0.24-3.07) (0.33-2.2) (0.24-1.17) Total Phosphorus (TP), mg/L Avg = 0.090 Avg = 0.07 Avg = 0.049* NA (0.026-0.151) (0.02-0.32) (0.020-0.480) Chlorophyll -a, mg/L Avg = 39.6 NA Avg = 28.4* 40 (17.3-125) (11.9-54.3) Page 6 of 19 Situated between D 1 and D2 lies the station N500000, operated by the Division's Ambient Monitoring System (AMS). Samples collected at this station were grabbed at the surface, no spatial composites throughout the photic zone as are D1 and D2, therefore comparisons could not be made. However, AMS monitoring is year-round, not seasonal as at D 1 and D2. Review of the AMS data found no discernable seasonal variation among nutrient parameters (Fig. 1). To better understand instream nutrient concentrations and their impact on Chlorophyll -a concentrations both instream and in Kerr Lake, and in consultation with the Division's River Basin Planning Branch, monitoring for these parameters was increased to year-round. AMS Station 5000000 — TP NO2+NO3 TKN 8.0 0.35 7.0 0.30 J 6.0 ■ 0.25 50 J 0 4.0 % 0 20 E z 0.15 N 3.0 r z 2.0 A00666*0 % _ 0.10 1.0� 0.05 o.o 0.00 �y� 'y�,��•Lo 'L'�,~a•Ly y h y (S ,��,�O�y 1� ti�$,�o�� ''11,�ay'Y Figure 1. Nutrient concentrations in the Nutbush Creek arm of Kerr Lake, 2019-2022. In August 2009, the benthic macroinvertebrate community in the receiving stream was evaluated at station NB49 (approximately 1 mile downstream from WWTP). With respect to the benthic community, the stream received a bioclassification of Fair, and a generally tolerant benthic community was found at this sampling site. In June 2014, the fish community in the receiving stream was evaluated at station NF28 (1.3 miles downstream from WWTP). The stream was rated Good -Fair, and the analysis noted that "there has been no consistent long-term change in the water quality or fish community since 1994." Is this facility a member of a Monitoring Coalition with waived instream monitoring (YIN): NO Name of Monitoring Coalition: NA 5. Compliance Summary Summarize the compliance record with permit effluent limits (past 5 years): From August 2018 through July 2023 the facility had reported exceedences in BOD, Ammonia and TSS, resulting in various enforcement actions (see Table 5). These violations are also listed in the EPA ECHO (Enforcement and Compliance History Online) Detailed Facility Report. Page 7 of 19 Table 5. Effluent monitoring violations summary, August 2018 — July 2023. Weekly Monthly Daily Notices of Notices of Enforcement Parameter Average Average Maximum Deficiency Violations Cases Exceedences Exceedences Exceedences BOD 2 2 NA 1 0 3 Ammonia NA 0 0 2 TSS 1 0 NA 0 0 1 Summarize the compliance record with aquatic toxicity test limits and any second species test results (past S years): The facility passed 17 of 20 quarterly chronic toxicity tests with two test failures and passed the post -fail subsequent tests. The four second species chronic toxicity tests, collected in October 2019, April 20020, July 2021, and January 2022, all passed. Summarize the results from the most recent compliance inspection: The most recent facility inspection conducted in June 2023 reported that the facility was largely well maintained and operated with the following deficiencies: 1) flowmeters were not calibrated within the past year, and 2) ORC visits were not documented. The most recent pretreatment inspection was conducted in August 2021 with no details of the inspection results reported. 6. Water Quality -Based Effluent Limitations (WQBELs) 6.1 Dilution and Mixing Zones In accordance with 15ANCAC 2B.0206, the following streamflows are used for dilution considerations for development of WQBELs: 1 Q 10 streamflow (acute Aquatic Life); 7Q 10 streamflow (chronic Aquatic Life; non -carcinogen HH); 30Q2 streamflow (aesthetics); annual average flow (carcinogen, HH). If applicable, describe any other dilution factors considered (e.g., based on CORMIX model results): NA If applicable, describe any mixing zones established in accordance with 1 SA NCAC 2B.0204(b): NA 6.2 Oxygen -Consuming Waste Limitations Limitations for oxygen -consuming waste (e.g., BOD) are generally based on water quality modeling to ensure protection of the instream dissolved oxygen (DO) water quality standard. Secondary TBEL limits (e.g., BOD= 30 mg/1 for Municipals) may be appropriate if deemed more stringent based on dilution and model results. If permit limits are more stringent than TBELs, describe how limits were developed: Limits for BOD5 at 4.14 MGD flow were determined in a 1988 waste load allocation on the basis of water quality protection and the previous permit limits. Limits for BOD5 at 6.0 MGD flow are based on 1990 speculative limits using previously permitted equivalent loading criteria and the previous QUAL2E model run in 1987 along with best professional judgment. The following excerpt is from the July 31, 1990 Speculative Limits letter, modified for clarity: Page 8 of 19 The following set of limits was derived for BOD5, Ammonia (NH3-N), and Dissolved Oxygen (DO): Parameter Summer Winter BOD5 (mg/L) 5.0 10.0 NH3-N (mg/L) 1.0 1.9 DO (mg/L) 7.0 7.0 These limits were derived based on a combination of water quality modeling and best professional judgment. The previous model indicated that the minimum predicted DO occurred at the end of the model at the stream -lake interface, with most of the oxygen demand remaining. Since the critical lake portion cannot reliably be modeled with the available data, a water quality model was not run to evaluate the 6.0 MGD waste flow. Instead, equivalent loading criteria were used to develop allocation limits. At 6.0 MGD, the BOD5 limit would be 4.1 mg/L and the NH3-N limit would be 2.1 mg1L. Since the Division (then known as Department of Environment, Health, and Natural Resources: Division of Environmental Management) does not usually assign BOD5 limits below 5 mg/L, limits of 5 mg/L BOD5 and 1 mg1L NH3-N were assigned. These limits result in near identical ultimate BOD loading (1502 lb/d in previous allocation and 1476 lb/d for expansion). While technology has advanced since 1990 and the Division has assigned BOD5 limits < 5 mg/L in other permitting scenarios, it remains true that the BOD5 limit of 5.0 mg/L and ammonia limit of 1.0 mg/L at the 6.0 MGD flow tier result in a protective ultimate BOD5 loading. As such, no changes were made for BOD5 limits. See Ammonia and Total Residual Chlorine Limitations below for additional information regarding ammonia limits. 6.3 Ammonia and Total Residual Chlorine Limitations Limitations for Ammonia are based on protection of aquatic life utilizing an ammonia chronic criterion of 1.0 mg/L (summer) and 1.8 mg/L (winter). Acute ammonia limits are derived from chronic criteria, utilizing a multiplication factor of 3 for Municipals and a multiplication factor of 5 for Non -Municipals. Limitations for Total Residual Chlorine (TRC) are based on the NC water quality standard for protection of aquatic life (17 µg/L) and capped at 28 µg/L (acute impacts). Due to analytical issues, all TRC values reported below 50 µg/L are considered compliant with their permit limit. Describe any proposed changes to ammonia and/or TRC limits for this permit renewal: Current permit Ammonia limits of 3.0/6.0 mg/L monthly/weekly average in summer and 6.0/18.0 mg/L monthly/weekly average in winter at 4.14 MGD are based on a 1985 waste load allocation (WLA) using QUAL2 model results for protection of the DO stream standard. Current Ammonia limits of 1.0/3.0 mg/L monthly/weekly average and 2.0/6.0 mg/L monthly/weekly average at 6.0 MGD are based on a WLA calculation for protection against ammonia toxicity. The WLA was used to evaluate ammonia limits using the permitted flows, the low stream flows of 7Q 10 = 0.2 cfs (summer) and 0.4 cfs (winter), and the NC criteria of 1.0 and 1.8 mg/L, with resulting allowable concentrations of 1.0/3.0 mg/L monthly/weekly average in summer and 1.9/3.8 mg/L monthly/weekly average at both flow tiers. However, since there is no discernible differences between up- and downstream DO and increased instream monitoring for ammonia is proposed, no changes were made. Current permit TRC limits of 17.0 µg/L daily maximum at both flow tiers were added in 1990 (July 31, 1990 letter) based on standard operating procedure/action level for TRC. The WLA form was also used to calculate TRC allowable concentrations at both flow tiers, finding them to be as protective as the current limits. No changes were made. 6.4 Reasonable Potential Analysis (RPA) for Toxicants If applicable, conduct RPA analysis and complete information below. Page 9 of 19 The need for toxicant limits is based upon a demonstration of reasonable potential to exceed water quality standards, a statistical evaluation that is conducted during every permit renewal utilizing the most recent effluent data for each outfall. The RPA is conducted in accordance with 40 CFR 122.44 (d) (i). The NC RPA procedure utilizes the following: 1) 95% Confidence Level/95% Probability; 2) assumption of zero background; 3) use of '/2 detection limit for "less than" values; and 4) streamflows used for dilution consideration based on 15A NCAC 2B.0206. Effective April 6, 2016, NC began implementation of dissolved metals criteria in the RPA process in accordance with guidance titled NPDES Implementation of Instream Dissolved Metals Standards, dated June 10, 2016. Effluent and upstream hardness monitoring are required in the current permit for calculating total metals for those dissolved metals that are hardness dependent. Permittee-submitted data averaged 51.0 mg/L effluent and 67.2 mg/L upstream, both higher than the default value of 25 mg/L. These data were used in the RPA. A reasonable potential analysis was conducted on effluent toxicant data collected between August 2018 — July 2023. Pollutants of concern included toxicants with positive detections and associated water quality standards/criteria. Based on this analysis, the following permitting actions are proposed for this permit: • Effluent Limit with Monitoring. The following parameters will receive a water quality -based effluent limit (WQBEL) since they demonstrated a reasonable potential to exceed applicable water quality standards/criteria: o Total Zinc: ■ MA, DM = 238 µg/L at 4.14 MGD; ■ MA, DM = 235 µg/L at 6.0 MGD. • Monitoring Only. The following parameters will receive a monitor -only requirement since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria, but the maximum predicted concentration was >50% of the allowable concentration: None. • No Limit or Monitoring: The following parameters will not receive a limit or monitoring, since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria and the maximum predicted concentration was <50% of the allowable concentration: Arsenic, Beryllium, Cadmium, Total Phenols, Total Chromium, Total Copper, Cyanide, Total Lead, Total Molybdenum, Total Nickel, Total Selenium, Total Silver at both flow tiers. • POTW Effluent Pollutant Scan Review: Three effluent pollutant scans were evaluated for additional pollutants of concern. o The following parameter(s) will receive a water quality -based effluent limit (WQBEL) with monitoring, since as part of a limited data set, two samples exceeded the allowable discharge concentration: None at both flow tiers o The following parameter(s) will receive a monitor -only requirement, since as part of a limited data set, one sample exceeded the allowable discharge concentration: None at both flow tiers. Aside from the parameters above, no detections were reported in the Effluent Pollutant Scans. If applicable, attach a spreadsheet of the RPA results as well as a copy of the Dissolved Metals Implementation Fact Sheet for freshwater/saltwater to this Fact Sheet. Include a printout of the RPA Dissolved to Total Metal Calculator sheet if this is a Municipality with a Pretreatment Program. 6.5 Toxicity Testing Limitations Permit limits and monitoring requirements for Whole Effluent Toxicity (WET) have been established in accordance with Division guidance (per WET Memo, 8/2/1999). Per WET guidance, all NPDES permits issued to Major facilities or any facility discharging "complex" wastewater (contains anything other than domestic waste) will contain appropriate WET limits and monitoring requirements, with several exceptions. The State has received prior EPA approval to use an Alternative WET Test Procedure in NPDES permits, using single concentration screening tests, with multiple dilution follow-up upon a test failure. Page 10 of 19 Describe proposed toxicity test requirement: This is a Major POTW, and a chronic WET limit at 90% at effluent at 4.14 and 6.0 MGD flow tiers will continue on a quarterly frequency. 6.6 Mercury Statewide TMDL Evaluation There is a statewide TMDL for mercury approved by EPA in 2012. The TMDL target was to comply with EPA's mercury fish tissue criteria (0.3 mg/kg) for human health protection. The TMDL established a wasteload allocation for point sources of 37 kg/year (81 lb/year), and is applicable to municipals and industrial facilities with known mercury discharges. Given the small contribution of mercury from point sources (-2% of total load), the TMDL emphasizes mercury minimization plans (MMPs) for point source control. Municipal facilities > 2 MGD and discharging quantifiable levels of mercury (>1 ng/L) will receive an MMP requirement. Industrials are evaluated on a case -by -case basis, depending if mercury is a pollutant of concern. Effluent limits may also be added if annual average effluent concentrations exceed the WQBEL value (based on the NC WQS of 12 ng/L) and/or if any individual value exceeds a TBEL value of 47 ng/L. The current permit has a MMP special condition, and an MMP summary was provided by the Permittee upon request. Describe proposed permit actions based on mercury evaluation: Since no annual average mercury concentration exceeded the WQBEL, and no individual mercury sample exceeded the TBEL (Table 6), no mercury limit is required. However, since the facility is > 2 MGD and has reported quantifiable levels of mercury (> 1 ng/L), a mercury minimization plan (MMP) is required and the condition has been revised toward maintaining the MMP. Table 6. Mercury Effluent Data Summary. 2020 2021 2022 2023 # of Samples 1 12 3 1 Annual Average Conc. ng/L 1.1 1.8 0.5 0.5 Maximum Conc., ng/L 1.14 6.44 0.50 0.50 TBEL, ng/L 47 WQBEL, ng/L at 4.14 MGD 12.4 WQBEL, ng/L at 6.0 MGD 12.3 6.7 Other TMDL/Nutrient Management Strategy Considerations If applicable, describe any other TMDLsMutrient Management Strategies and their implementation within this permit: Currently the receiving stream has no TMDL or Nutrient Management Strategy. The current permit has monthly monitoring for Total Nitrogen and weekly monitoring with seasonal limits for Total Phosphorus. To better understand the effluent nitrogen, Nitrite+Nitrate (NO2+NO3) and Total Kjeldahl Nitrogen (TKN) monitoring will be added to the permit at the same frequency as Total Nitrogen monitoring. Seasonal TP limits for 4.14 MGD flow were originally based on a 1988 WLA (summer: 0.5 mg/L, winter: 2.0 mg/L) and modified in 1989 to current limits (summer: 1.0 mg/L, winter: 1.5 mg/L) based on a request from the City of Henderson (see request letter April 12, 1989; approval letter May 8, 1989). For 6.0 MGD flow, the TP limit of 0.5 mg/L was based on 1990 Speculative Limits for this flow. A mass balance showed that an effluent TP concentration of 0.2 mg/L was needed to meet an instream target concentration of 150 µg/L during average stream flow; however, the limit of 0.5 mg/L was assigned during speculative limits developed. Instream water quality downstream of the outfall is concerning as Chlorophyll -a data collected by DWR AMS average just below the stream standard of 40 µg/L. To address this concern, expanded instream monitoring is proposed (see Section 4 above). Page 11 of 19 6.8 Other WQBEL Considerations If applicable, describe any other parameters of concern evaluated for WQBELs: Emerging contaminants PFAS and 1,4-Dioxane were considered when the facility submitted its Chemical Addendum on 9/25/2023. The City responded: "The City Of Henderson Water Reclamation doesn't anticipate any emerging contaminants (1.4-D or PFAS) to be present in the wastewater. " The receiving water does not enter any water supply waters before crossing the Virginia state line —14.3 miles downstream of the discharge. The facility's permitted SIU is a pet food manufacturer that is not a potential 1,4-Dioxane source; no requirements for 1,4-Dioxane were added to the permit. However, based on the pervasive nature of these chemicals and following EPA guidance on PFAS monitoring (memo, 12/5/2022), quarterly monitoring for PFAS was added to the permit to generate data for fixture evaluation. If applicable, describe any special actions (HQW or ORW) this receiving stream and classification shall comply with in order to protect the designated waterbody: NA. If applicable, describe any compliance schedules proposed for this permit renewal in accordance with 15A NCAC 2H.0107(c)(2)(B), 40CFR 122.47, and EPA May 2007 Memo: NA If applicable, describe any water quality standards variances proposed in accordance with NCGS 143- 215.3(e) and 15A NCAC 2B.0226 for this permit renewal: NA 7. Technology -Based Effluent Limitations (TBELs) Municipals. Are concentration limits in the permit at least as stringent as secondary treatment requirements (30 mg/L BOD51TSS for Monthly Average, and 45 mg/L for BODS/TSS for Weekly Average). YES If NO, provide a justification for alternative limitations (e.g., waste stabilization pond). NA Are 85% removal requirements for BOD51TSS included in the permit? YES. Review of the data for both parameters found overall average of removal to be > 85%, but with 4 and 6 occurrences of BOD and TSS removal < 85%, respectively. If NO, provide a justification (e.g., waste stabilization pond). NA Industrials. NA 8. Antidegradation Review (New/Expanding Discharge): The objective of an antidegradation review is to ensure that a new or increased pollutant loading will not degrade water quality. Permitting actions for new or expanding discharges require an antidegradation review in accordance with 15A NCAC 213.0201. Each applicant for a new/expanding NPDES permit must document an effort to consider non -discharge alternatives per 15A NCAC 2H.0105(c)(2). In all cases, existing instream water uses and the level of water quality necessary to protect the existing use is maintained and protected. If applicable, describe the results of the antidegradation review, including the Engineering Alternatives Analysis (EAA) and any water quality modeling results: NA Page 12 of 19 9. Antibacksliding Review: Sections 402(o)(2) and 303(d)(4) of the CWA and federal regulations at 40 CFR 122.44(1) prohibit backsliding of effluent limitations in NPDES permits. These provisions require effluent limitations in a reissued permit to be as stringent as those in the previous permit, with some exceptions where limitations may be relaxed (e.g., based on new information, increases in production may warrant less stringent TBEL limits, or WQBELs may be less stringent based on updated RPA or dilution). Are any effluent limitations less stringent than previous permit (YES/NO): Yes: Cadmium, Copper, Selenium and Silver. If YES, confirm that antibacksliding provisions are not violated: Based on RPA results of recent effluent data with recent effluent and upstream hardness concentrations showing no reasonable potential to exceed stream water quality standards (hereafter "RP"), limits and monitoring requirements for Total Copper have been removed from the permit. Similarly, quarterly monitoring requirements for Total Cadmium, Total Selenium and Total Silver have been removed from the permit. 10. Monitoring Requirements Monitoring frequencies for NPDES permitting are established in accordance with the following regulations and guidance: 1) State Regulation for Surface Water Monitoring, 15A NCAC 213.0500; 2) NPDES Guidance, Monitoring Frequency for Toxic Substances (7/15/2010 Memo); 3) NPDES Guidance, Reduced Monitoring Frequencies for Facilities with Superior Compliance (10/22/2012 Memo); 4) Best Professional Judgement (BPJ). Per US EPA (Interim Guidance, 1996), monitoring requirements are not considered effluent limitations under Section 402(o) of the Clean Water Act, and therefore anti -backsliding prohibitions would not be triggered by reductions in monitoring frequencies. All effluent parameters are monitored under 15A NCAC 02B .0500. For instream monitoring, refer to Section 4. 11. Electronic Reporting Requirements The US EPA NPDES Electronic Reporting Rule was finalized on December 21, 2015. Effective December 21, 2016, NPDES regulated facilities are required to submit Discharge Monitoring Reports (DMRs) electronically. While NPDES regulated facilities would initially be required to submit additional NPDES reports electronically effective December 21, 2020, EPA extended this deadline from December 21, 2020, to December 21, 2025. The current compliance date, effective January 4, 2021, was extended as a final regulation change published in the November 2, 2020 Federal Register. This permit contains the requirements for electronic reporting, consistent with Federal requirements. 12. Summary of Proposed Permitting Actions: Tables 7 and 8 summarize the permit conditions and proposed changes at the 4.14 and 6.0 MGD flow tiers, respectively. Page 13 of 19 Table 7. Current Permit Conditions and Proposed Changes at 4.14 MGD. Parameter Current Permit Proposed Change Basis for Condition/Change Flow MA = 4.14 MGD Monitor continuously No change 15A NCAC 02B .0505 Summer: MA = 6.0 mg/L WA = 9.0 mg/L WQBEL. Based on protection of BOD5 Winter: No change DO standard. 15A NCAC 02B MA = 12.0 mg/L .0200, .0508. WA = 18.0 mg/L Monitor daily MA = 30 mg/L TBEL. Secondary treatment TSS WA = 45 mg/L No change standards, 40 CFR 133, 15A NCAC Monitor daily 02B .0406, .0508. Summer: MA = 3.0 mg/L WA = 9.0 mg/L No change in effluent WQBEL. Based on protection of Winter: limits or monitoring. State DO WQ standard, 15A NCAC = = MA 6.0 mg/L 02B .0200. NH3-N WA 18.0 mg/L Increase instream Monitor effluent daily sampling to year- Increased instream monitoring Monitor instream round; add monthly added to better understand effluent monthly at D1, D2 in upstream monitoring. impact. summer MA = 200 /100 mL Add instream (U, D1, WQBEL. State WQ standard, 15A Fecal coliform WA = 400 /100 mL D2) monthly NCAC 02B .0200 Monitor daily monitoring year-round Downstream AMS data show likelihood of impairment. TRC DM = 17 µg/L No change WQBEL. State WQ standard, 15A Monitor daily NCAC 02B .0200 pH 6 — 9 SU No change WQBEL. State WQ standard, 15A Monitor daily NCAC 02B .0200 DA > 6 mg/L WQBEL. State WQ standard, 15A Monitor effluent daily NCAC 02B .0200, .0500. Instream DO Monitor instream No change monitoring based on 1990 monthly, including recommendations from 1988 summer depth profiles at Instream Assessment regarding Kerr DI and D2 Lake trophic concerns. Monitor effluent daily State monitoring requirements, 15A Monitor instream NCAC 02B .0508. Instream Temperature monthly, including No change monitoring based on 1990 summer depth profiles at recommendations from 1988 D1 and D2 Instream Assessment regarding Kerr Lake trophic concerns. Monitor effluent daily State monitoring requirements, 15A Conductivity Monitor instream No change B NCAC 02 monthly .0508. Page 14 of 19 Parameter Current Permit' Proposed Change Basis for Condition/Change Total Nitrogen Monitor effluent No change State monitoring requirements, 15A monthly NCAC 213.0500. Add monthly effluent Monitor instream monitoring.Increase instream To better understand effluent TN TKN monthly at D1, D2 in sampling year- concentrations and effluent impact summer round; add monthly on instream concentrations. upstream monitoring. Add monthly effluent Monitor instream monitoring.Increase instream To better understand effluent TN NO2+NO3 monthly at D1, D2 in sampling year- concentrations and effluent impact summer round; add monthly on instream concentrations. upstream monitoring. Summer: QA = 1.0 mg/L Winter: Increase instream WQBEL. Originally based on 1988 QA — 15 mg/L . sampling to year- W LA, modified per City request in Total Phosphorus Monitor weekly round; add monthly 1989. Upstream monitoring to better Monitor instream upstream monitoring. understand effluent impact on monthly at D1, D2 in instream concentrations. summer No reasonable potential (RP) to Total Cadmium Monitor quarterly Remove from permit exceed stream WQ standard found in RPA. MA = 26.7 µg/L No reasonable potential (RP) to Total Copper DM = 39.9 µg/L Remove from permit exceed stream WQ standard found Monitor monthly in RPA. Total Silver Monitor quarterly Remove from permit No RP found; all data were nondetects. No RP found; maximum predicted value > 50% allowable Total Selenium Monitor quarterly Remove from permit concentration due to one high nondetect; defer monitoring to LTMP. Total Zinc No requirement MA, DM = 238 µg/L Monitor monthly WQBEL. RP found Monitor quarterly at Hardness -dependent dissolved Total Hardness effluent and instream at No change metals water quality standards U approved in 2016. Add quarterly PFAS No requirement monitoring with EPA recommendations (guidance delayed memo, 12/5/2022). implementation Chronic limit at 90% WQBEL. No toxics in toxic Toxicity Test effluent No change amounts. 15A NCAC 28.0200 and 15A NCAC 028.0500 Page 15 of 19 Parameter Current Permit' Proposed Change Basis for Condition/Change Effluent Pollutant Three times per permit Update sample years 40 CFR 122 Scan cycle to 2025, 2026, 2027 Mercury Modify condition WQBEL. Consistent with 2012 Minimization Plan Special Condition toward MMP Statewide Mercury TMDL (MMP) maintenance Implementation. Electronic Special Condition Update Special In accordance with EPA Electronic Reporting Condition Reporting Rule 2015. Footnote. 1. MGD = Million Gallons per Day; MA = Monthly Average; WA = Weekly Average; DA = Daily Average; DM = Daily Maximum; QA = Quarterly Average. Table 8. Current Permit Conditions and Proposed Changes 6.0 MGD. Parameter Current Permit Proposed Change Basis for Condition/Change Flow MA 6.0 MGD Monitor continuously No change 15A NCAC 02B .0505 Summer: MA = 5.0 mg/L WA = 7.5 mg/L WQBEL. Based on protection of BODS Winter: No change DO standard. 15A NCAC 02B. 0200 MA = 10.0 mg/L WA = 15.0 mg/L Monitor daily MA = 30.0 mg/L TBEL. Secondary treatment TSS WA = 45.0 mg/L No change standards, 40 CFR 133, 15A NCAC Monitor daily 02B .0406 Summer: MA = 1.0 mg/L WA = 3.0 mg/L WQBEL. Based on protection of NH3-N Winter: No change State WQ criteria. 15A NCAC 02B. MA = 2.0 mg/L 0200, .0508 WA = 6.0 mg/L Monitor daily MA = 200 /100 mL WQBEL. State WQ standard, 15A Fecal Coliform WA = 400 /100 mL No change NCAC 2B .0200, .0508 Monitor daily TRC DM = 17 µg/L No change WQBEL. State WQ standard, 15A Monitor daily NCAC 2B .0200, .0508 DA > 6 mg/L WQBEL. State WQ standard, 15A Monitor effluent daily NCAC 02B .0200, .0500. Instream DO Monitor instream No change monitoring based on 1990 monthly, including recommendations from 1988 summer depth profiles at Instream Assessment regarding Kerr D 1 and D2 Lake trophic concerns. Page 16 of 19 Parameter Current Permit' Proposed Change Basis for Condition/Change Monitor effluent daily State monitoring requirements, 15A Monitor instream NCAC 02B .0508. Instream Temperature monthly, including No change monitoring based on 1990 summer depth profiles at recommendations from 1988 D1 and D2 Instream Assessment regarding Kerr Lake trophic concerns. Monitor effluent daily State monitoring requirements, 15A Conductivity Monitor instream No change B NCAC 02 monthly .0508. PH 6.0 — 9.0 SU No change WQBEL. State WQ standard, 15A Monitor daily NCAC 2B .0200, .0508 Total Nitrogen Monitor effluent No change State monitoring requirements, 15A monthly NCAC 213.0500. Add monthly effluent Monitor instream monitoring.Increase instream To better understand effluent TN TKN monthly at D1, D2 in sampling year- concentrations and effluent impact summer round; add monthly on instream concentrations. upstream monitoring. Add monthly effluent Monitor instream monitoring.Increase instream To better understand effluent TN NO2+NO3 monthly at D1, D2 in sampling to year- concentrations and effluent impact m sumer round; add monthly on instream concentrations. upstream monitoring. Summer: QA = 1.0 mg/L Winter: Increase instream WQBEL. Originally based on 1988 QA = 1.5 mg/L sampling to year- WLA, modified per City request in Total Phosphorus Monitor weekly round; add monthly 1989. Upstream monitoring to better Monitor instream upstream monitoring. understand effluent impact on monthly at D1, D2 in instream concentrations. summer MA = 26.7 µg/L No reasonable potential (RP) to Total Copper DM = 39.9 µg/L Remove from permit exceed stream WQ standard found Monitor monthly in RPA. Total Silver Monitor quarterly Remove from permit No RP found; all data were nondetects. No RP found; maximum predicted value > 50% allowable Total Selenium Monitor quarterly Remove from permit concentration due to one high nondetect; defer monitoring to LTMP. Total Zinc No requirement MA, DM = 235 µg/L Monitor monthly WQBEL. RP found Page 17 of 19 Parameter Current Permit' Proposed Change Basis for Condition/Change Monitor quarterly at Hardness -dependent dissolved Total Hardness effluent and instream at No change metals water quality standards U approved in 2016. Add quarterly PFAS No requirement monitoring with EPA recommendations (guidance delayed memo, 12/5/2022). implementation Chronic limit 90% WQBEL. No toxics in toxic Toxicity Test effluent No change amounts. 15A NCAC 0213.0200, .0508 Reduce to three times Effluent Pollutant per permit cycle; add Scan Annual to 1st 3 yrs after 6.0 40 CFR 122 MGD expansion complete. Mercury Modify condition WQBEL. Consistent with 2012 Minimization Plan Special Condition toward MMP Statewide Mercury TMDL (MMP) maintenance Implementation. Electronic No requirement Add Electronic Reporting Special In accordance with EPA Electronic Reporting Condition Reporting Rule 2015. Footnote. 1. MGD = Million Gallons per Day; MA = Monthly Average; WA = Weekly Average; DA = Daily Average; DM = Daily Maximum; QA = Quarterly Average. 13. Public Notice Schedule: Permit to Public Notice: 10/14/2023 Per 15A NCAC 2H .0109 & .0111, The Division will receive comments for a period of 30 days following the publication date of the public notice. Any request for a public hearing shall be submitted to the Director within the 30 days comment period indicating the interest of the party filing such request and the reasons why a hearing is warranted. 14. NPDES Division Contact If you have any questions regarding any of the above information or on the attached permit, please contact Gary Perlmutter at (919) 707-3611 or via email at gary.perlmutterkdeq.nc.gov. 15. Fact Sheet Addendum (if applicable): Were there any changes made since the Draft Permit was public noticed (Yes/No): The draft permit was distributed to the applicant, EPA and various Division personnel. No comments were received from any party. If Yes, list changes and their basis below: NA Page 18 of 19 16. Fact Sheet Attachments (if applicable): • Effluent Pollutant Scans, 2020, 2021, 2022 • 2nd species WET test reports, 2019, 2020, 2021, 2022 • MMP summary • Process Narrative • Sludge Management Plan • Chemical Addendum note • NPDES Pretreatment POC form • 2022 NC 303(d) list of impaired waters, p. 103 • 2022 Integrated Report, p. 848 • Fish Community Sample report, NF28 • Correspondence with DWR Basin Planning Branch • Monitoring Violations Report • EPA ECHO detailed facility report • WET test summary sheet, p. 49 • Compliance Inspection report, 6/7/2023 • Pretreatment Inspection report, 8/24/2021 • NH3/TRC WLA Calculations for 4.14 and 6.0 MGD • RPA Spreadsheet Summary for 4.14 and 6.0 MGD • NPDES Dissolved Metals Fact Sheet memo • Mercury TMDL Evaluation for 4.14 and 6.0 MGD Page 19 of 19 Annual Monitoring and Pollutant Scan Permit No. NCO020559 Month April Outfall 001 Year 2021 Facility Name City of Henderson WRF ORC Clarissa Lipscomb Date of sampling 4/8/2021 Phone 252-431-6080 Analytical Laboratory HWRF Lab, Meritech Parameter Parameter Code Sample Type Analytical Method Quantitation Level Sample Result Units of Measurement Ammonia (as N) C0610 Composite SM 4500 NH3 D-2011 0.1 ND mg/L µg/L Chlorine (total residual, TRC) 50060 Grab SM 4500 Cl G-2011 16 ND Dissolved Oxygen 00300 Grab SM 4500 0 G-2011 1.0 9.0 mg/L Nitrite plus Nitrate Total (as N) 00630 Composite EPA 353.2 0.1 4.71 mg/L Total Kjeldahl Nitrogen 00625 Composite EPA 351.1 0.2 0.93 mg/L Oil and Grease 00556 Grab EPA 1664B 5 ND mg/L Total Phosphorus C0665 Composite EPA 200.7 0.02 1 0.08 mg/L Total Dissolved Solids Hardness 70295 Composite SM 2540 C 10 368 mg/L 00900 Composite SM 2340 B 1 64 mg/L Metals (total recoverable), cyanide and total phenols Antimony Arsenic Beryllium 01097 Composite EPA 200.8 0.5 0.6 µg/L 01002 Composite EPA 200.8 2 ND µg/L 01012 Composite EPA 200.8 0.5 ND µg/L Cadmium 01027 Composite EPA 200.8 0.15 ND µg/L Chromium 01034 Composite EPA 200.8 2 ND µg/L Copper 01042 Composite EPA 200.8 2 ND µg/L Lead 01051 Composite EPA 200.8 0.5 ND µg/L Mercury (Method 1631E) COMER Grab 1631E 0.0010 0.00173 µg/L Nickel 01067 Composite EPA 200.8 0.5 8.5 µg/L Selenium 01147 Composite EPA 200.8 1 ND µg/L Silver 01077 Composite EPA 200.8 0.5 ND µg/L Thallium 01059 Composite EPA 200.8 0.5 ND µg/L Zinc 01092 Composite EPA 200.8 15 145 µg/L Cyanide 00720 Grab EPA 335.4 0.005 ND mg/L Total phenolic compounds 32730 Grab EPA 420.1 0.010 ND mg/L Volatile organic compounds Acrolein 34210 Acrylonitrile 34215 Grab EPA 624.1 50 ND µg/L Grab EPA 624.1 10 ND µg/L Benzene 34030 Grab EPA 624.1 1.00 ND µg/L Bromoform 32104 Grab EPA 624.1 1.00 ND µg/L Carbon Tetrachloride 32102 Grab EPA 624.1 1.00 ND µg/L Chlorobenzene 34301 Grab EPA 624.1 1.00 ND µg/L Chlorodibromomethane 34306 Grab EPA 624.1 1.00 ND µg/L Chloroethane 85811 Grab EPA 624.1 5.00 ND µg/L 2-chloroethyl vinyl ether 34576 Grab EPA 624.1 5.00 ND µg/L Chloroform 32106 Grab EPA 624.1 1.00 ND µg/L Dichlorobromomethane 32101 Grab EPA 624.1 1.00 ND µg/L 1, 1 -dichloroethane 34496 Grab EPA 624.1 1.00 ND µg/L 1,2-dichloroethane 32103 Grab EPA 624.1 1.00 ND µg/L Trans-1,2-dichloroethylene 34546 Grab EPA 624.1 1.00 ND µg/L 1, 1 -dichloroethylene 34501 Grab EPA 624.1 1.00 ND µg/L 1,2-dichloropropane 34541 Grab EPA 624.1 1.00 ND µg/L 1,3-dichloropropylene 77163 Grab EPA 624.1 1.00 ND µg/L Ethylbenzene 34371 Grab EPA 624.1 1 1.00 ND µg/L Methyl Bromide 34413 Grab EPA 624.1 1 5.00 ND µg/L Form - DMR- PPA-1 Page 1 Annual Monitoring and Pollutant Scan Permit No. NCO020559 Month April Outfall 001 Year 2021 Parameter am Parameter Code Sample Type Grab Analytical Method Quantitation Level 5.00 Sample Result Units of Measurement Methyl Chloride 34418 EPA 624.1 ND µg/L Methylene Chloride 34423 Grab EPA 624.1 1.00 ND µg/L 1,1,2,2-tetrachloroethane 81549 Grab EPA 624.1 1.00 ND µg/L Tetrachloroethylene 34475 Grab EPA 624.1 1.00 ND µg/L Toluene 34010 Grab EPA 624.1 1.00 ND µg/L 1, 1, 1 -trichloroethane 34506 Grab EPA 624.1 1.00 ND µg/L 1,1,2-trichloroethane 34511 Grab EPA 624.1 1.00 ND µg/L Trichloroethylene 39180 Grab EPA 624.1 1.00 ND µg/L Vinyl Chloride 39175 Grab EPA 624.1 5.00 ND µg/L P-chloro-m-creso 34452 Grab EPA 625.1 10 ND µg/L 2-chlorophenol 34586 Grab EPA 625.1 10 ND µg/L 2,4-dichlorophenol 34601 Grab EPA 625.1 10 ND µg/L 2,4-dimethylphenol 34606 Grab EPA 625.1 10 ND µg/L 4,6-dinitro-o-cresol 34657 Grab EPA 625.1 50 ND µg/L 2,4-dinitrophenol 34616 Grab EPA 625.1 50 ND µg/L 2-nitrophenol 34591 Grab EPA 625.1 10 ND µg/L 4-nitrophenol 34646 Grab EPA 625.1 50 ND µg/L Pentachlorophenol 39032 Grab EPA 625.1 50 ND µg/L Phenol 34694 Grab EPA 625.1 10 ND µg/L 2,4,6-trichlorophenol 34621 Grab EPA 625.1 10 ND µg/L Base -neutral compounds Acenaphthene 34205 Grab EPA 625.1 10 ND µg/L Acenaphthylene 34200 Grab EPA 625.1 10 ND µg/L Anthracene CO220 Grab EPA 625.1 10 ND µg/L Benzidine 39120 Grab EPA 625.1 50 ND µg/L Benzo(a)anthracene 34526 Grab EPA 625.1 10 ND µg/L Benzo(a)pyrene 34247 Grab EPA 625.1 10 ND µg/L 3,4 benzofluoranthene 34230 Grab EPA 625.1 10 ND µg/L Benzo(ghi)perylene 34521 Grab EPA 625.1 10 ND µg/L Benzo(k)fluoranthene 34242 Grab EPA 625.1 10 ND µg/L Bis (2-chloroethoxy) methane 34278 Grab EPA 625.1 10 ND µg/L Bis (2-chloroethyl) ether 34273 Grab EPA 625.1 10 ND µg/L Bis (2-chloroisopropyl) ether 34283 Grab EPA 625.1 10 ND µg/L Bis (2-ethylhexyl) phthalate 39100 Grab EPA 625.1 10 ND µg/L 4-bromophenyl phenyl ether 34636 Grab EPA 625.1 10 ND µg/L Butyl benzyl phthalate 34292 Grab EPA 625.1 10 ND µg/L 2-chloronaphthalene 34581 Grab EPA 625.1 10 ND µg/L 4-chlorophenyl phenyl ether 34641 Grab EPA 625.1 10 ND µg/L Chrysene 34320 Grab EPA 625.1 10 ND µg/L Di-n-butyl phthalate 39110 Grab EPA 625.1 10 ND µg/L Di-n-octyl phthalate 34596 Grab EPA 625.1 10 ND µg/L Dibenzo(a,h)anthracene 34556 Grab EPA 625.1 10 ND µg/L 1,2-dichlorobenzene 34536 Grab EPA 625.1 10 ND µg/L 1,3-dichlorobenzene 34566 Grab EPA 625.1 10 ND µg/L 1,4-dichlorobenzene 34571 Grab EPA 625.1 10 ND µg/L 3,3-dichlorobenzidine 34631 Grab EPA 625.1 50 ND µg/L Diethyl phthalate 34336 Grab EPA 625.1 10 ND µg/L Dimethyl phthalate 34341 Grab EPA 625.1 10 ND µg/L 2,4-dinitrotoluene 34611 Grab EPA 625.1 10 ND µg/L Form - DMR- PPA-1 Page 2 Annual Monitoring and Pollutant Scan Permit No. NCO020559 Month April Outfall 001 Year 2021 Parameter Parameter Code Sample Type Grab Analytical Method Quantitation Level 10 Sample Result Units of Measurement 2,6-dinitrotoluene C0626 EPA 625.1 ND µg/L 1,2-dipheny1hydrazine 34346 Grab EPA 625.1 10 ND µg/L Fluoranthene C0376 Grab EPA 625.1 10 ND µg/L Fluorene 34381 Grab EPA 625.1 10 ND µg/L Hexachlorobenzene C0700 Grab EPA 625.1 10 ND µg/L Hexachlorobutadiene 39702 Grab EPA 625.1 10 ND µg/L Hexachlorocyclo-pentadiene 34386 Grab EPA 625.1 50 ND µg/L Hexachloroethane 34396 Grab EPA 625.1 10 ND µg/L Indeno(1,2,3-cd)pyrene 34403 Grab EPA 625.1 10 ND µg/L Isophorone 34408 Grab EPA 625.1 10 ND µg/L Naphthalene 34696 Grab EPA 625.1 10 ND µg/L Nitrobenzene 34447 Grab EPA 625.1 10 ND µg/L N-nitrosodi-n-propylamine 34428 Grab EPA 625.1 10 ND µg/L N-nitrosodimethylamine 34438 Grab EPA 625.1 10 ND µg/L N-nitrosodiphenylamine 34433 Grab EPA 625.1 10 ND µg/L Phenanthrene 34461 Grab EPA 625.1 10 ND µg/L Pyrene 34469 Grab EPA 625.1 10 ND µg/L 1,2,4,-trichlorobenzene 34551 Grab EPA 625.1 10 ND µg/L "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Authorized Representative name Signature Date Form - DMR- PPA-1 Page 3 Annual Monitoring and Pollutant Scan Permit No. NCO020559 Month January Outfall 001 Year 2020 Facility Name City of Henderson WRF ORC H Lamont Allen Date of sampling 1/9/20 Phone 252-431-6080 Analytical Laboratory HWRF Lab, Meritech Parameter 0 Parameter Code Sample Type Analytical Method Quantitation Level Sample Result Units of Measurement Ammonia (as N) C0610 Composite SM 4500 NH3 D-2011 0.1 0.2 mg/L µg/L Chlorine (total residual, TRC) 50060 Grab SM 4500 Cl G-2011 16 ND Dissolved Oxygen 00300 Grab SM 4500 0 G-2011 1.0 9.2 mg/L Nitrite plus Nitrate Total (as N) 00630 Composite EPA 353.2 0.1 7.17 mg/L Total Kjeldahl Nitrogen 00625 Composite EPA 351.1 0.2 ND mg/L Oil and Grease 00556 Grab EPA 1664B 5 ND mg/L Total Phosphorus C0665 Composite EPA 200.7 10.02 10.06 1mg/L Total Dissolved Solids Hardness 70295 Composite SM 2540 C 10 174 mg/L 00900 Composite SM 2340 B 1 56 mg/L Metals (total recoverable), cyanide and total phenols Antimony Arsenic Beryllium 01097 Composite EPA 200.8 0.5 ND µg/L 01002 Composite EPA 200.8 2 ND µg/L 01012 Composite EPA 200.8 0.5 ND µg/L Cadmium 01027 Composite EPA 200.8 0.15 ND µg/L Chromium 01034 Composite EPA 200.8 2 ND µg/L Copper 01042 Composite EPA 200.8 2 ND µg/L Lead 01051 Composite EPA 200.8 0.5 ND µg/L Mercury (Method 1631E) COMER Grab 1631E 0.0010 ND µg/L Nickel 01067 Composite EPA 200.8 0.5 2.0 µg/L Selenium 01147 Composite EPA 200.8 1 ND µg/L Silver 01077 Composite EPA 200.8 0.5 ND µg/L Thallium 01059 Composite EPA 200.8 0.5 ND µg/L Zinc 01092 Composite EPA 200.8 5 18 µg/L Cyanide 00720 Grab EPA 335.4 0.005 0.007 mg/L Total phenolic compounds 32730 Grab EPA 420.1 0.010 0.011 mg/L Volatile organic compounds Acrolein 34210 Acrylonitrile 34215 Grab EPA 624.1 50 ND µg/L Grab EPA 624.1 10 ND µg/L Benzene 34030 Grab EPA 624.1 1.00 ND µg/L Bromoform 32104 Grab EPA 624.1 1.00 ND µg/L Carbon Tetrachloride 32102 Grab EPA 624.1 1.00 ND µg/L Chlorobenzene 34301 Grab EPA 624.1 1.00 ND µg/L Chlorodibromomethane 34306 Grab EPA 624.1 1.00 ND µg/L Chloroethane 85811 Grab EPA 624.1 5.00 ND µg/L 2-chloroethyl vinyl ether 34576 Grab EPA 624.1 5.00 ND µg/L Chloroform 32106 Grab EPA 624.1 1.00 ND µg/L Dichlorobromomethane 32101 Grab EPA 624.1 1.00 ND µg/L 1, 1 -dichloroethane 34496 Grab EPA 624.1 1.00 ND µg/L 1,2-dichloroethane 32103 Grab EPA 624.1 1.00 ND µg/L Trans-1,2-dichloroethylene 34546 Grab EPA 624.1 1.00 ND µg/L 1, 1 -dichloroethylene 34501 Grab EPA 624.1 1.00 ND µg/L 1,2-dichloropropane 34541 Grab EPA 624.1 1.00 ND µg/L 1,3-dichloropropylene 77163 Grab EPA 624.1 1.00 ND µg/L Ethylbenzene 34371 Grab EPA 624.1 1.00 ND µg/L Methyl Bromide 34413 Grab EPA 624.1 5.00 ND µg/L Form - DMR- PPA-1 Page 1 Annual Monitoring and Pollutant Scan Permit No. NCO020559 Month January Outfall _001 Year 2020 Parameter am Parameter Code Sample Type Grab Analytical Method Quantitation Level 5.00 Sample Result ND Units of Measurement Methyl Chloride 34418 EPA 624.1 µg/L Methylene Chloride 34423 Grab EPA 624.1 1.00 ND µg/L 1,1,2,2-tetrachloroethane 81549 Grab EPA 624.1 1.00 ND µg/L Tetrachloroethylene 34475 Grab EPA 624.1 1.00 ND µg/L Toluene 34010 Grab EPA 624.1 1.00 ND µg/L 1, 1, 1 -trichloroethane 34506 Grab EPA 624.1 1.00 ND µg/L 1,1,2-trichloroethane 34511 Grab EPA 624.1 1.00 ND µg/L Trichloroethylene 39180 Grab EPA 624.1 1.00 ND µg/L Vinyl Chloride 39175 Acid -extractable compounds P-chloro-m-creso 34452 2-chlorophenol 34586 Grab Grab EPA 624.1 EPA 625.1 1.00 10 ND ND µg/L µg/L Grab EPA 625.1 10 ND µg/L 2,4-dichlorophenol 34601 Grab EPA 625.1 10 ND µg/L 2,4-dimethylphenol 34606 Grab EPA 625.1 10 ND µg/L 4,6-dinitro-o-cresol 34657 Grab EPA 625.1 50 ND µg/L 2,4-dinitrophenol 34616 Grab EPA 625.1 50 ND µg/L 2-nitrophenol 34591 Grab EPA 625.1 10 ND µg/L 4-nitrophenol 34646 Grab EPA 625.1 50 ND µg/L Pentachlorophenol 39032 Grab EPA 625.1 50 ND µg/L Phenol 34694 Grab EPA 625.1 10 ND µg/L 2,4,6-trichlorophenol 34621 Grab EPA 625.1 10 ND µg/L Base -neutral compounds Acenaphthene 34205 34200 Grab EPA 625.1 10 ND µg/L Acenaphthylene Grab EPA 625.1 10 ND µg/L Anthracene CO220 Grab EPA 625.1 10 ND µg/L Benzidine 39120 Grab EPA 625.1 50 ND µg/L Benzo(a)anthracene 34526 Grab EPA 625.1 10 ND µg/L Benzo(a)pyrene 34247 Grab EPA 625.1 10 ND µg/L 3,4 benzofluoranthene 34230 Grab EPA 625.1 10 ND µg/L Benzo(ghi)perylene 34521 Grab EPA 625.1 10 ND µg/L Benzo(k)fluoranthene 34242 Grab EPA 625.1 10 ND µg/L Bis (2-chloroethoxy) methane 34278 Grab EPA 625.1 10 ND µg/L Bis (2-chloroethyl) ether 34273 Grab EPA 625.1 10 ND µg/L Bis (2-chloroisopropyl) ether 34283 Grab EPA 625.1 10 ND µg/L Bis (2-ethylhexyl) phthalate 39100 Grab EPA 625.1 10 ND µg/L 4-bromophenyl phenyl ether 34636 Grab EPA 625.1 10 ND µg/L Butyl benzyl phthalate 34292 Grab EPA 625.1 10 ND µg/L 2-chloronaphthalene 34581 Grab EPA 625.1 10 ND µg/L 4-chlorophenyl phenyl ether 34641 Grab EPA 625.1 10 ND µg/L Chrysene 34320 Grab EPA 625.1 10 ND µg/L Di-n-butyl phthalate 39110 Grab EPA 625.1 10 ND µg/L Di-n-octyl phthalate 34596 Grab EPA 625.1 10 ND µg/L Dibenzo(a,h)anthracene 34556 Grab EPA 625.1 10 ND µg/L 1,2-dichlorobenzene 34536 Grab EPA 625.1 10 ND µg/L 1,3-dichlorobenzene 34566 Grab EPA 625.1 10 ND µg/L 1,4-dichlorobenzene 34571 Grab EPA 625.1 10 ND µg/L 3,3-dichlorobenzidine 34631 Grab EPA 625.1 50 ND µg/L Diethyl phthalate 34336 Grab EPA 625.1 10 ND µg/L Dimethyl phthalate 34341 Grab EPA 625.1 10 ND µg/L 2,4-dinitrotoluene 34611 Grab EPA 625.1 10 ND µg/L Form - DMR- PPA-1 Page 2 Annual Monitoring and Pollutant Scan Permit No. NCO020559 Month January Outfall _001 Year 2020 Parameter Parameter Code Sample Type Grab Analytical Method Quantitation Level 10 Sample Result Units of Measurement 2,6-dinitrotoluene C0626 EPA 625.1 ND µg/L 1,2-dipheny1hydrazine 34346 Grab EPA 625.1 10 ND µg/L Fluoranthene C0376 Grab EPA 625.1 10 ND µg/L Fluorene 34381 Grab EPA 625.1 10 ND µg/L Hexachlorobenzene C0700 Grab EPA 625.1 10 ND µg/L Hexachlorobutadiene 39702 Grab EPA 625.1 10 ND µg/L Hexachlorocyclo-pentadiene 34386 Grab EPA 625.1 50 ND µg/L Hexachloroethane 34396 Grab EPA 625.1 10 ND µg/L Indeno(1,2,3-cd)pyrene 34403 Grab EPA 625.1 10 ND µg/L Isophorone 34408 Grab EPA 625.1 10 ND µg/L Naphthalene 34696 Grab EPA 625.1 10 ND µg/L Nitrobenzene 34447 Grab EPA 625.1 10 ND µg/L N-nitrosodi-n-propylamine 34428 Grab EPA 625.1 10 ND µg/L N-nitrosodimethylamine 34438 Grab EPA 625.1 10 ND µg/L N-nitrosodiphenylamine 34433 Grab EPA 625.1 10 ND µg/L Phenanthrene 34461 Grab EPA 625.1 10 ND µg/L Pyrene 34469 Grab EPA 625.1 10 ND µg/L 1,2,4,-trichlorobenzene 34551 Grab EPA 625.1 10 ND µg/L "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Authorized Representative name Signature Date Form - DMR- PPA-1 Page 3 Annual Monitoring and Pollutant Scan Permit No. Month Outfall Year Facility Name City of Henderson WRF ORC Clarissa Lipscomb Date of sampling 7/21/2022 Phone 252-431-6080 Analytical Laboratory HWRF Lab, Meritech Parameter Parameter Code Sample Type Analytical Method Quantitation Level Sample Result Units of Measurement Ammonia (as N) C0610 Composite SM 4500 NH3 D-2011 0.1 0.2 mg/L µg/L Chlorine (total residual, TRC) 50060 Grab SM 4500 Cl G-2011 16 Dissolved Oxygen 00300 Grab SM 4500 O G-2011 1.0 6.6 mg/L Nitrite plus Nitrate Total (as N) 00630 Composite EPA 353.2 0.1 1.6 mg/L Total Kjeldahl Nitrogen 00625 Composite EPA 351.1 0.2 0.7 mg/L Oil and Grease 00556 Grab EPA 1664B 5 ND mg/L Total Phosphorus C0665 Composite I EPA 200.7 0.02 1 0.121 1 mg/L Total Dissolved Solids Hardness Metals (total recoverable), cyanide Antimony Arsenic Beryllium Cadmium 70295 Composite SM 2540 C 10 179 mg/L 00900 and total phenols 01097 Composite Composite SM 2340 B EPA 200.8 1 0.5 40 ND mg/L µg/L 01002 Composite EPA 200.8 2 ND µg/L 01012 Composite EPA 200.8 0.5 ND µg/L 01027 Composite EPA 200.8 0.15 ND µg/L Chromium 01034 Composite EPA 200.8 2 ND µg/L Copper 01042 Composite EPA 200.8 2 ND µg/L Lead 01051 Composite EPA 200.8 0.5 ND µg/L Mercury (Method 1631E) COMER Grab 1631E 0.0010 ND µg/L Nickel 01067 Composite EPA 200.8 0.5 3.0 µg/L Selenium 01147 Composite EPA 200.8 1 ND µg/L Silver 01077 Composite EPA 200.8 0.5 ND µg/L Thallium 01059 Composite EPA 200.8 0.5 ND µg/L Zinc 01092 Composite EPA 200.8 5 29 µg/L Cyanide 00720 Grab EPA 335.4 0.005 ND mg/L Total phenolic compounds 32730 Volatile organic compounds Acrolein 34210 Acrylonitrile 34215 Benzene 34030 Grab Grab EPA 420.1 EPA 624.1 0.010 50 0.019 ND mg/L µg/L Grab EPA 624.1 10 ND µg/L Grab EPA 624.1 1.00 ND µg/L Bromoform 32104 Grab EPA 624.1 1.00 ND µg/L Carbon Tetrachloride 32102 Grab EPA 624.1 1.00 ND µg/L Chlorobenzene 34301 Grab EPA 624.1 1.00 ND µg/L Chlorodibromomethane 34306 Grab EPA 624.1 1.00 ND µg/L Chloroethane 85811 Grab EPA 624.1 5.00 ND µg/L 2-chloroethyl vinyl ether 34576 Grab EPA 624.1 5.00 ND µg/L Chloroform 32106 Grab EPA 624.1 1.00 ND µg/L Dichlorobromomethane 32101 Grab EPA 624.1 1.00 ND µg/L 1, 1 -dichloroethane 34496 Grab EPA 624.1 1.00 ND µg/L 1,2-dichloroethane 32103 Grab EPA 624.1 1.00 ND µg/L Trans-1,2-dichloroethylene 34546 Grab EPA 624.1 1.00 ND µg/L 1, 1 -dichloroethylene 34501 Grab EPA 624.1 1.00 ND µg/L 1,2-dichloropropane 34541 Grab EPA 624.1 1.00 ND µg/L 1,3-dichloropropylene 77163 Grab EPA 624.1 1.00 ND µg/L Ethylbenzene 34371 Grab EPA 624.1 1.00 ND µg/L Methyl Bromide 34413 Grab EPA 624.1 5.00 ND µg/L Form - DMR- PPA-1 Page 1 Annual Monitoring and Pollutant Scan Permit No. Month Outfall Year Parameter Parameter Code Sample Type Grab Analytical Method EPA 624.1 Quantitation Level Sample Result ND Units of Measurement µg/L Methyl Chloride 34418 5.00 Methylene Chloride 34423 Grab EPA 624.1 1.00 ND µg/L 1,1,2,2-tetrachloroethane 81549 Grab EPA 624.1 1.00 ND µg/L Tetrachloroethylene 34475 Grab EPA 624.1 1.00 ND µg/L Toluene 34010 Grab EPA 624.1 1.00 ND µg/L 1, 1, 1 -trichloroethane 34506 Grab EPA 624.1 1.00 ND µg/L 1,1,2-trichloroethane 34511 Grab EPA 624.1 1.00 ND µg/L Trichloroethylene Vinyl Chloride Acid -extractable compounds P-chloro-m-creso 2-chlorophenol 39180 Grab EPA 624.1 1.00 ND µg/L 39175 34452 Grab Grab EPA 624.1 EPA 625.1 5.00 10 ND ND µg/L µg/L 34586 Grab EPA 625.1 10 ND µg/L 2,4-dichlorophenol 34601 Grab EPA 625.1 10 ND µg/L 2,4-dimethylphenol 34606 Grab EPA 625.1 10 ND µg/L 4,6-dinitro-o-cresol 34657 Grab EPA 625.1 50 ND µg/L 2,4-dinitrophenol 34616 Grab EPA 625.1 50 ND µg/L 2-nitrophenol 34591 Grab EPA 625.1 10 ND µg/L 4-nitrophenol 34646 Grab EPA 625.1 50 ND µg/L Pentachlorophenol 39032 Grab EPA 625.1 50 ND µg/L Phenol 34694 Grab EPA 625.1 10 ND µg/L 2,4,6-trichlorophenol Base -neutral compounds Acenaphthene 34621 34205 Grab Grab EPA 625.1 EPA 625.1 10 10 ND ND µg/L µg/L Acenaphthylene 34200 Grab EPA 625.1 10 ND µg/L Anthracene CO220 Grab EPA 625.1 10 ND µg/L Benzidine 39120 Grab EPA 625.1 50 ND µg/L Benzo(a)anthracene 34526 Grab EPA 625.1 10 ND µg/L Benzo(a)pyrene 34247 Grab EPA 625.1 10 ND µg/L 3,4 benzofluoranthene 34230 Grab EPA 625.1 10 ND µg/L Benzo(ghi)perylene 34521 Grab EPA 625.1 10 ND µg/L Benzo(k)fluoranthene 34242 Grab EPA 625.1 10 ND µg/L Bis (2-chloroethoxy) methane 34278 Grab EPA 625.1 10 ND µg/L Bis (2-chloroethyl) ether 34273 Grab EPA 625.1 10 ND µg/L Bis (2-chloroisopropyl) ether 34283 Grab EPA 625.1 10 ND µg/L Bis (2-ethylhexyl) phthalate 39100 Grab EPA 625.1 10 ND µg/L 4-bromophenyl phenyl ether 34636 Grab EPA 625.1 10 ND µg/L Butyl benzyl phthalate 34292 Grab EPA 625.1 10 ND µg/L 2-chloronaphthalene 34581 Grab EPA 625.1 10 ND µg/L 4-chlorophenyl phenyl ether 34641 Grab EPA 625.1 10 ND µg/L Chrysene 34320 Grab EPA 625.1 10 ND µg/L Di-n-butyl phthalate 39110 Grab EPA 625.1 10 ND µg/L Di-n-octyl phthalate 34596 Grab EPA 625.1 10 ND µg/L Dibenzo(a,h)anthracene 34556 Grab EPA 625.1 10 ND µg/L 1,2-dichlorobenzene 34536 Grab EPA 625.1 10 ND µg/L 1,3-dichlorobenzene 34566 Grab EPA 625.1 10 ND µg/L 1,4-dichlorobenzene 34571 Grab EPA 625.1 10 ND µg/L 3,3-dichlorobenzidine 34631 Grab EPA 625.1 50 ND µg/L Diethyl phthalate 34336 Grab EPA 625.1 10 ND µg/L Dimethyl phthalate 34341 Grab EPA 625.1 10 ND µg/L 2,4-dinitrotoluene 34611 Grab EPA 625.1 10 ND µg/L Form - DMR- PPA-1 Page 2 Annual Monitoring and Pollutant Scan Permit No. Month Outfall Year Parameter Parameter Code Sample Type Grab Analytical Method EPA 625.1 Quantitation Level Sample Result ND Units of Measurement µg/L 2,6-dinitrotoluene C0626 10 1,2-diphenylhydrazine 34346 Grab EPA 625.1 10 ND µg/L Fluoranthene C0376 Grab EPA 625.1 10 ND µg/L Fluorene 34381 Grab EPA 625.1 10 ND µg/L Hexachlorobenzene C0700 Grab EPA 625.1 10 ND µg/L Hexachlorobutadiene 39702 Grab EPA 625.1 10 ND µg/L Hexachlorocyclo-pentadiene 34386 Grab EPA 625.1 50 ND µg/L Hexachloroethane 34396 Grab EPA 625.1 10 ND µg/L Indeno(1,2,3-cd)pyrene 34403 Grab EPA 625.1 10 ND µg/L Isophorone 34408 Grab EPA 625.1 10 ND µg/L Naphthalene 34696 Grab EPA 625.1 10 ND µg/L Nitrobenzene 34447 Grab EPA 625.1 10 ND µg/L N-nitrosodi-n-propylamine 34428 Grab EPA 625.1 10 ND µg/L N-nitrosodimethylamine 34438 Grab EPA 625.1 10 ND µg/L N-nitrosodiphenylamine 34433 Grab EPA 625.1 10 ND µg/L Phenanthrene 34461 Grab EPA 625.1 10 ND µg/L Pyrene 34469 Grab EPA 625.1 10 ND µg/L 1,2,4,-trichlorobenzene 34551 Grab EPA 625.1 10 ND µg/L Sampling should be conducted as specified in 40 CFR Part 136. " I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Authorized Representative name Signature Date Form - DMR- PPA-1 Page 3 Eif'luent Toxicity Report Form -Chronic Fathead Minnow Multi -Concentration Test Dat9:10/18/2019 Facility: Henderson NPDES # NC00 20559 Pipe #: 001 County: Vance L o tory: Witech, Inc. (Lab #NCO27) Comments Signature of Operator in Responsible Charge x d , / Signature of Laboratory Supervisor MAIL ORIGINAL TO: Water Sciences Section Aquatic Toxicology Branch Division of Water Resources 1621 Mail Service Center Raleigh, N.C. 27699-1621 Test Initiation Date/Time 10/8/2019 4:40 PM Avg Wt/Surv. Control 0.506 % Eff. Repl. 1 2 3 4 Control Surviving # Original # Wt/original (mg) 22.5 Surviving # Original # Wt/original (mg) 10 10 10 Q10 10 10 10 4 0.523 0.489 0.486 10 10 10 10 10 10 10 10 0.526 0.581 0.473 0.504 Survival 100.0 Avg Wt (mg) 0.506 Test Organisms 1R Cultured in -House FW Outside Supplier Hatch Date: 10/7/19 Survival 100.0 Hatch Time: 3:00 pm CT Avg Wt (mg) 0.521 45 Surviving # % Survival 100.0 10 10 10 10 Original # 10 10 10 10 0.581 0.521 0.650 0.518 90 Surviving # % Survival 97.5 Original # Wt/original (mg) Avg Wt (mg)�.546 95 Surviving # % Survival 100.0 Original # Wt/original (mg) Avg Wt (mg) 0.550 100 Surviving # % Survival 97.5 Original # Wt/original (mg) Avg Wt (mg) 0.566 Nater Quality Data Day Control 0 1 2 3 4 5 6 pH (SU) Init/Fin DO (mg/L) [nit/Fin Temp (C) Init/Fin High Concentration pH (SU) Init/Fin DO (mg/L) Init/Fin Temp (C) Init/Fin Sample Collection Start Date Grab Composite (Duration) Hardness (mg/L) Alkalinity (mg/L) Conductivity (umhos/cm) Chlorine(mg/L) Temp. at Receipt (°C) 10 10 10 10 10 10 0.571 0.541 0.569 9 10 10 10 10 10 10 10 0.464 0.650 0.518 0.631 7.92 / 7.70 7.86 / 7.64 7.74 / 7.84 7.89 / 7.83 7.98 / 7.81 7.91 / 7.68 7.95 / 7.48 7.68 / 7.23 7.74 / 7.20 7.93 / 7.59 7.86 / 7.69 7.83 / 7.91 8.04 / 7.54 7.97 / 7.06 24.3 / 25.2 24.6 / 25.3 24.3 / 24.7 24.7 124.9 24.1 125.5 24.2 ! 24.7 24.1 ! 24.8 0 1 2 3 4 5 6 7.36 17.48 7.37 / 7.47 7.23 17.58 7.53 / 7.73 7.71 / 7.72 7.76 / 7.59 7.42 / 7.45 7.95 / 7.33 8.11 / 7.10 8.39 17.75 8.10 / 7.62 7.95 / 7.97 7.87 / 7.51 8.21 1 2 3 10/7l2019 10/9/2019 10l10/2019 24.0 24.1 24.8 52 52 52 30 30 28 471 475 480 <0.1 <0.1 <0.1 2.6 2.7 0.8 Dilution H2O Batch # 1441 1442 1443 1444 Hardness (mg/L) 48 46 46 42 Alkalinity (mg/L) 29 31 30 30 Conductivity (umhos/cm) 166 178 173 167 Survival Growth Normal 171 F j Hom. Var. 171 :j NOEC 100 100 LOEC >100 >100 ChV >100 >100 Method Steel's Dunnett's Overall Result ChV >100 Slats Survival Growth Conc. Critical Calculated Critical Calculated 22.5 10 18 2.41-0.3500 45 10 18 2.41-1.3999 90 10 16 2.41-0.9031 95 10 18 2.41-0.9991 100 10 16 2.41-1.3604 10 10 9 10 10 10 10 10 0.658 0.582 0.455 0.487 nia/n c..- AT C /A//lAl ' 'Effluent Toxicity Report Form -Chronic Fathead Minnow Multi -Concentration Test Qa, .4/30/2020 Facility: Henderson NPDES # NCOO 20559 Pipe#: 001 County: Vance 2-L-6 4) — - J Signature of Laboratory Supervisor MAIL ORIGINAL TO: Water Sciences Section Aquatic Toxicology Branch Division ^/ Water Resources /oo/Mail Service Center Raleigh, N.c.o,6Yo-mzz Test |nitieUonDntelTkna 4/21/2020 4:15RN �vgVVU�um�Con�n % Eff. Repl. 1 u 3 4 Gumiving# Original # Wt/original (mg) Gurviving# Original # Wt/original (mg) Test Organisms r' Cultured In -House FW Outside Supplier Avg N8(mg)���� �0� ^----' ---- %Guwiva| Hatch Time 3:00 mCT Guwiving# Y6Survival OnQmm|# VVVungina|(ng) Avg w«(mg) Gu=wno# mSumwo Original # � ~— vvuvngine|(ng) Avg wm(ng ourvwnQ#Wt/original (mg) [ 96Gum*a 10 OhQ��|# Gummm # %Gmv*al ongmu|# Wt/origina/(mg) Avg mm(mg) Water Quality Data Day Control n 1 u n 4 o s pH(GU)|nit/Fin DO(mg/L) |nit/Fin Temp (C)|nit/Fin High Concentration o 1 x x 4 a e pM(GU)!nit/Fio '/ 8O(m0/L)/niUFin [2 Temp (C)|nit/F)n . 7 25.5 24.6 / 25.4 1 2. Sample 1 2 3 Survival Growth Collection Start Date Grab Composite (Duration) *ardnaue(mg/L) A|ko|inity<mg/L> Conductivity (umhox/cm) ChlohmKmg/L) Temp, at Receipt (T) Dunnett'stats Survival s /L42 ) I m/utionH20Batch # Hardneso(mO Alka|inKy(mQ/L) Conduct|vity(umhus/cm) IRE] I [___ Normal /L42 ) I m/utionH20Batch # Hardneso(mO Alka|inKy(mQ/L) Conduct|vity(umhus/cm) IRE] I [___ Normal m/utionH20Batch # Hardneso(mO Alka|inKy(mQ/L) Conduct|vity(umhus/cm) IRE] I [___ Normal F1 �� Hom.Vor. 171 �l NDEC 100 100 LOEC —7�0-- -->100—' ChV -->100—' -->100�_ Method —Steel's-- — Effluent Toxicity Report Form -Chronic Fathead Minnow Multi -Concentration Test Date:7/23/2021 Facility: Henderson _- NPIDES # NCOO 20559 Pipe #: 001 County: Vance Labor Meritech, 1pe._(Lab #NP,027) Comments X Signatur f or i es=pe Ch_a-rgetErpail/Phone number X Signature of Laboratory Supervisor MAIL ORIGINAL TO: Water Sciences Section Aquatic Toxicology Branch Division of Water Resources 1621 Mail Service Center Raleigh, N.C. 27699-1621 Test Initiation Date/Time 7/13/2021 4:53 PM Avg Wt/Surv. Control F-7-553­1 % Eff. Repl. 1 2 3 4 Control Surviving # Original # Wt/original (mg) 22.5 Surviving# Original # WUoriginal (mg) % SurvivalF-977-5­1 Test Organisms Cultured In -House Outside Supplier Avg Wt (mg) I 0.538 1 Hatch Date: 7/12/21 % SurvivaIF97.5 Hatch Time: 4:00-5:00 pm Avg Wt (mg)F--0.477 r --- 4-5-1 Surviving # % Survival F90_0__� 10 9 9 8 Original # 10 10 10 1 10 Wt/original (mg) 0.542J 0.439 0,476 0.508 Avg Wt (mg)F0_4_9_1___j 97_Surviving # % Survival F92 _5___j Original # I Wt/original (mg) Avg Wt (mg)F- _04_51 79_5Surviving # � % Survival 82.5 F Original # Wt/original (mg) Avg Wt (mg) F --- 0-4-4-7-1 100 Surviving # % Survival F8_50___j Original # Wt/original (mg) Avg Wt (mg) 0.447 Water Quality Data Day Control 0 1 2 3 4 5 6 pH (SU) Init/Fin 7.73 / 7.88 7.98 / 7.81 7.68 / 7.72 7.84 / 7.97 7.98 / 7.85 7.96 / 7.58 7,67 17.60 DO (mg/L) Init/Fin 7.79 / 7.80 8.00 / 7.06 7.71 / 7,55 8.06 / 7.62 7.92 / 7.95 8.06 / 7,33 8.07 / 7.05 Temp (C) Init/Fin 24.3 / 24.8 24.2 / 25.2 25.2 / 25.0124.2 / 24.5 24.9 / 24.9 24.8 / 25.0 24.0 / 24.7 High Concentration pH (SU) Init/Fin DO (mg/L) Init/Fin Temp (C) Init/Fin Sample Collection Start Date Grab Composite (Duration) Hardness (mg/L) Alkalinity (mg/L) Conductivity (umhos/cm) Chlorine(mg/L) Temp. at Receipt (,q D 1 9 .1 A A A 7.28 / 7.72 7.55 7.68 7.19 / 7.73 7.38 7.77 7.69 / 7.81 7.72 / .75 7.44 / 7.53 8,10 / 7.66 8.20 / 7.32 8.17 / 7.65 8.38 7.55 7.98 / 7.96 8.14 / 7.30 8.36 / 6,96 24.5 / 24,6 1 24 24.5 / 24.6 24.6 / 24.9 1 2 3 7/12/2021 7/1-4/2021 7/15/2021 23.9 24.8 42 46 46 32 30 31 303 361 380 <0. I <0.1 <0. 1 1.4 1,5 1.5 Dilution Batch # Hardness (mg/L) Alkalinity (mg/L) Conductivity (umhos/cm) .9 / 25.0 24.8 / 24.7 24.0 243 24.8 / 25.1 Survival Growth Normal FO I Hom. Var. F1_1 I 100 100 LOEC >100 >100 ChV >100 Dunnett's ett's MENUM-7 24.1 Stats Survival Growth Conc. Critical Calculated Critical Calculated 22.5 2.41 0 2.41 1,4778 45 - 24_1 lA387 41 90 2.41 0.6396 2,41 2.1198 95 2,41 1.9188 241 2.3682 H2.* _4 ' 1 1,599 F2_41 2107 H2O NOEL >100 Method 0.9594 100 2. 7.28 / 7.72 7.55 7.68 7.19 / 7.73 7.38 7.77 7.69 / 7.81 7.72 / .75 7.44 / 7.53 8,10 / 7.66 8.20 / 7.32 8.17 / 7.65 8.38 7.55 7.98 / 7.96 8.14 / 7.30 8.36 / 6,96 24.5 / 24,6 1 24 24.5 / 24.6 24.6 / 24.9 1 2 3 7/12/2021 7/1-4/2021 7/15/2021 23.9 24.8 42 46 46 32 30 31 303 361 380 <0. I <0.1 <0. 1 1.4 1,5 1.5 Dilution Batch # Hardness (mg/L) Alkalinity (mg/L) Conductivity (umhos/cm) .9 / 25.0 24.8 / 24.7 24.0 243 24.8 / 25.1 Survival Growth Normal FO I Hom. Var. F1_1 I 100 100 LOEC >100 >100 ChV >100 Dunnett's ett's MENUM-7 24.1 Stats Survival Growth Conc. Critical Calculated Critical Calculated 22.5 2.41 0 2.41 1,4778 45 - 24_1 lA387 41 90 2.41 0.6396 2,41 2.1198 95 2,41 1.9188 241 2.3682 H2.* _4 ' 1 1,599 F2_41 2107 H2O NOEL >100 Method 0.9594 100 2. 1 2 3 7/12/2021 7/1-4/2021 7/15/2021 23.9 24.8 42 46 46 32 30 31 303 361 380 <0. I <0.1 <0. 1 1.4 1,5 1.5 Dilution Batch # Hardness (mg/L) Alkalinity (mg/L) Conductivity (umhos/cm) .9 / 25.0 24.8 / 24.7 24.0 243 24.8 / 25.1 Survival Growth Normal FO I Hom. Var. F1_1 I 100 100 LOEC >100 >100 ChV >100 Dunnett's ett's MENUM-7 24.1 Stats Survival Growth Conc. Critical Calculated Critical Calculated 22.5 2.41 0 2.41 1,4778 45 - 24_1 lA387 41 90 2.41 0.6396 2,41 2.1198 95 2,41 1.9188 241 2.3682 H2.* _4 ' 1 1,599 F2_41 2107 H2O NOEL >100 Method 0.9594 100 2. 7/12/2021 7/1-4/2021 7/15/2021 23.9 24.8 42 46 46 32 30 31 303 361 380 <0. I <0.1 <0. 1 1.4 1,5 1.5 Dilution Batch # Hardness (mg/L) Alkalinity (mg/L) Conductivity (umhos/cm) .9 / 25.0 24.8 / 24.7 24.0 243 24.8 / 25.1 Survival Growth Normal FO I Hom. Var. F1_1 I 100 100 LOEC >100 >100 ChV >100 Dunnett's ett's MENUM-7 24.1 Stats Survival Growth Conc. Critical Calculated Critical Calculated 22.5 2.41 0 2.41 1,4778 45 - 24_1 lA387 41 90 2.41 0.6396 2,41 2.1198 95 2,41 1.9188 241 2.3682 H2.* _4 ' 1 1,599 F2_41 2107 H2O NOEL >100 Method 0.9594 100 2. Dilution Batch # Hardness (mg/L) Alkalinity (mg/L) Conductivity (umhos/cm) .9 / 25.0 24.8 / 24.7 24.0 243 24.8 / 25.1 Survival Growth Normal FO I Hom. Var. F1_1 I 100 100 LOEC >100 >100 ChV >100 Dunnett's ett's MENUM-7 24.1 Stats Survival Growth Conc. Critical Calculated Critical Calculated 22.5 2.41 0 2.41 1,4778 45 - 24_1 lA387 41 90 2.41 0.6396 2,41 2.1198 95 2,41 1.9188 241 2.3682 H2.* _4 ' 1 1,599 F2_41 2107 H2O NOEL >100 Method 0.9594 100 2. MENUM-7 24.1 Stats Survival Growth Conc. Critical Calculated Critical Calculated 22.5 2.41 0 2.41 1,4778 45 - 24_1 lA387 41 90 2.41 0.6396 2,41 2.1198 95 2,41 1.9188 241 2.3682 H2.* _4 ' 1 1,599 F2_41 2107 H2O NOEL >100 Method 0.9594 100 2. H2O NOEL >100 Method 0.9594 100 2. 0.9594 100 2. Effluent Toxicity Report Form -Chronic Fathead Minnow Multi -Concentration Test Date:1/24/2022 Facility: Henderson X I - Signature of era r in ngib)16e-'C-h-arq-e/-E-m-ai'I/Phone number x Signature of Laboratory Supervisor MAIL ORIGINAL TO: Water Sciences Section Aquatic Toxicology Branch Division of Water Resources 1621 Mail Service Center Raleigh, N.C. 27699-1621 Test Initiation DatefTime 1111/2022 4:50 PM Avg Wt/Surv. Control 0.587 22.5 Surviving# Original # Wt/original (mg) E �51 Surviving # Original # WVoriginal (mg) F 9-0 Surviving# Original # Wt/original (mg) 95 Surviving# Original # Wt/original (mg) 100 1 Surviving 10 10 9 10 10 Original 10 10 10 10 Wt/original (mg) 0.551 0.449 1 0.575 I0.551 Water Quality Data Day Control 0 1 2 3 pH (SU) Init/Fin 7.97 / 7.78 7.88 / 8.04 7.42 / 7.55 .88 / 7.79 DO (mg/L) Init/Fin Temp (C) [nit/Fin 24�5 / 24.7124.0 / 24.5 24.9 / 24.5 24.7 / 24.9 % Survival F-7 _00_0____1 Avg Wt (mg)F-70-358-77--� % Survival F-7 _00_0__� Avg Wt (mg) F --- 0-5-35--7 % SurvjvaIF1_00_0__� Avg Wt (mg) F-7354-7--1 % Survival 100.0 Avg Wt (mg) _0 % Survival E-10-0-0-D Avg Wt (mg)F0_5_1_0 7___j % Survival F97.5 Avg Wt (mg) F--5-32­1 4 5 6 Test Organisms i® Cultured In -House Fv Outside Supplier Hatch Date: 1110/22 Hatch Time: 4:00-5:00 pm 8,10 / 7.42 7.84 7.71 8.17 / 7.60 8.06 / 8.30 8.49 17.78 High Concentration 0 1 2 3 pH (SU) Init/Fin DO (mlg/L) Init/Fin Temp (C) Init/Fin Sample Collection Start Date Grab Composite (Duration) Hardness (mg/L) Alkalinity (mg1L) Conductivity (umhos/cm) Chlorine(mg/L) Temp. at Receipt ('C) 4 5 6 1 2 3 man mm Survival Growth Overall Result Normal rl 171 1 ChV >100 Hom. Var. p JP1 NOEL 100 100 LOEC >100 >100 ChV >100 >100 Method Steel's Dunnett's Conc. 22.5 Survival i Critical Calculated 10 18 18 1 10 18 1 10 �10 16 _� Growth i Critical Calculated 2.41 1,1826 2.41 0.9070 2.41 1.2514 2.41 1 7624 2.41 1.2629 45 90 95 100 r)Wrl C-- AT JZ 14111A) MMP Action Summary Plan competed 11/15/2019 We completed Industrial Facility Mercury Survey for Mars Pert Care on 11/1/2021. Recycle Used Fluorescent light tubes through City of Henderson Operation Center Program. Eliminated Mercury containing Thermometers. Eliminated all Mercury containing chemicals in Lab. City of Henderson WRF Data for Influent and Effluent Mercury Results Date Influent Mercury (µ/L) EPA Method 245.1 Effluent (µ/L) EPA Method 1631 1/9/2020 <0.2 <0.001 4/22/2020 .0013 4/23/2020 0.8 7/15/2020 0.00597 7/16/2020 <0.2 10/7/2020 0.00114 10/8/2020 <0.2 1/14/2021 0.3 0.00146 2/18/2021 <0.2 2/17/2021 <0.001 3/11/2021 <0.2 <0.001 4/8/2021 <0.2 0.00173 5/5/2021 <0.2 <0.001 6/9/2021 <0.2 0.00327 7/15/2021 <0.2 0.00644 8/4/2021 <0.2 <0.001 9/8/2021 <0.2 <0.001 10/7/2021 <0.2 0.0501 11/3/2021 <0.2 <0.001 12/1/2021 <0.2 <0.001 1/13/2022 <0.2 <0.001 4/7/2022 <0.2 <0.001 7/14/2022 <0.2 7/21/2022 <0.001 10/5/2022 <0.2 <0.001 1/10/2023 <0.2 0.0018 4/5/2023 <0.2 4/26/2023 0.001 Process Narrative Waste water enters the plant and goes through automatic bar screens. Influent continues through the grit camber then passes through Parshall Flume into the Influent pump station. Influent is then pumped to Anaerobic basin in Oxidation ditch then goes to the anoxic basin in the Oxidation ditch continues to BNR part of the Oxidation ditch. The waste water then goes over the Weir into the final Clarifier box. Mixed liquor is then returned to Anaerobic basin or to the Sludge thickener. Clarifier water flows to the four Tertiary sand filter then goes to the Post Air where is it Aerated then it flows to the UV Disinfection then is discharged in the creek. Thicken Sludge goes to the Aerobic digestor and then hauled off by Granville Farms. Sludge Management Plan We have two aerobic digesters, a drum thickener, we use polymer to dewater sludge. We also process 35-45 thousand gallons of mixed liquor per day. Digested sludge is hauled from the facility by Granville Farms who holds a land application permit. (Permit number WQ0000838) The onsite Lab forms testing to facilitate wasting rates. Chemical Addendum The City Of Henderson Water Reclamation doesn't anticipate any emerging contaminants (1.4-D or PFAS) to be present in the wastewater. A 13 C D E F I G I H I J K L M N O 1 P NPDES/PT POC Review Form Version: 2022.06.22 2 1. Facility's General Information 3 Data of (draft) Review 9/12/2023 c. POC review due to: e. Contact Information 4 Data of (final) Review Municipal NPDES renewal ❑ Regional Office (RO) Raleigh 5 NPDES Permit Writer (pw) Gary Perlmutter HWA-AT/LTMP Review ElRO PT Staff Chang Zhang RO NPDES Staff Vanessa Manuel 6 Permitlee-Facility Name Town of Henderson - Henderson WRF New Industries ❑ Facility PT Staff, email Darrel Johnson, di ohnson(dci.henderson.nc.us 7 NPDES Permit Numher NC0020559 WWTP-ansion ❑ f. Receiving Stream 8 NPDES Permit Effecfwe Date Stream reclasedadjustment ❑ Qutfall 9 Chemical Addendum Submittal Data Omfell relmationladjustmeat ❑ Receiving Stream: Nutbush Cr CA, cfs: 3.5 10 NPDES Permit Public Notice Dete 7Q10 update ❑ Stream Class C 7Q10 (a), cfs: 0.2 11 eDMR data evaluated from: 10 Other POC review trigger, explain: Oufall Lat. 36.21.01 Oui Long. -78.24.40 12 3 a. W WTP Capacity Summary 0utfall 11 Current Permitted Flow, mgd 4.1 Dee '' signed Fes4.1 Receiving Stream: OA, cfs: 14 Permitted SIU Flaw, mgd 0.08 d. IU Summary Stream Class 7Q10. cfs: RP 15 b. PT Docs. Summary # IUs 1 Oufall Let. Ouffall Leng. 16 IWS approval date 6/1412017 #SIUs 1 Is there a PWS downstream of the Facility's Outfalls? ❑ YES ❑ NO 17 .0 USTMP approval date: 2/14/2020 #CIUs 0 Comments: 18 19 .E d HWA approval data m 0 6/15/2017 If NSCIUs 0 If w/Local Permits or Other Tyfies 0 20 Z 2. Industrial Users' Information. 21 # Industrial User (IU) Name IU Activity IU Non Conventional Pollutans & Toxic Pollutant IUP Effective Date 22 1 Mars Pet Care oet food BOD, TSS Temperature, pH COD, Cu, 0&G, Total Phosphorus, TKN, Zn 4/3/2022 23 2 24 s 25 4 26 s 31 comment: 32 3. Status of Pretreatment Program (check all that apply) 33 Status of Pretreatment Pro ram check all that appl 34 ❑ 1) facility has no SIUs, does have Division approved Pretreatment Program that is INACTIVE 35 ❑ 2) facility has no SIUs, does not have Division approved Pretreatment Program 36 ❑ 3) facility has SIUs and DWQ approved Pretreatment Program 37 ❑ 3a) Full Program with LTMP 3g ❑ 31b) Modified Program with STMP 39 ❑ 4) additional conditions regarding Pretreatment attached or listed below 40 2 5) facility's sludge is being land applied or composted 41 ❑ 6) facility's sludge is incinerated (add Beryllium and Mercury sampling according to § 503,43) 42 43 ❑ ❑ 7) facility's sludge is taken to a landfill, if yes wlandfill: hich 8) other 44 45 46 Sludge DisposalAN.- 47 Sludge Permit Page 1 20559 POC Review Form A 6 I C D I E F G H I J K I L I M N O P 48 4. LTMP/STMP and HWA Review 49 PW: Find L/STMP document, HWA spreadsheet, DMR, previous and new NPDES permit for next section. 50 5, a �Comment N� U n Parameter of Concern POC Check List New NPDES POC Previous NPDES POC Required by EPA PT 1 POC due to Sludge 2 POC due to SIU 3 POTW POC 4 L/STMP Effluent Freq NPDES Effluent Freq PQLs review % Removal Rate PQL from L/STMP, ug/I Required PQL per NPDES permit Recomm. PQL, ug/I 52 ❑' Flow ❑' ❑' ❑' ❑ I Quarterly 53 ❑ BOD Li ❑ ❑+ ❑ Quarterly 2 mg/L 54 ❑' TSS Quarterly 2.5 mg/L 55 ❑ NH3 0 ❑ ❑ ❑ Quarterly 0.1 mg/I 56 ❑' Arsenic ❑ ❑ 0 ❑' ❑ Quarterly 10.0 2.0 Reduce to recommended PQL 57 ❑ Barium ❑ ❑ ❑ ❑ ❑ 58 ❑ Beryllium(5) ❑ ❑ ❑ ❑ ❑ 59 0 Cadmiumi ❑ ❑ 0 ❑' ❑ ❑ Quarterly 2.0 0.5 Reduce torecommended PQL 60 ❑ Chromium(1) ❑ ❑ 0 ❑ ❑ ❑ I Quarterly 5 o 10.0 61 0 copper(1) ❑ ❑ El p ❑ ❑ Quarterly 2.0 2.0 62 ❑ Cyanide ❑ ❑ ❑ ❑ ❑ 63 ❑' Lead(1) ❑ ❑ ❑ 0 ❑ ❑ Quarterly 10.0 2.0 Reduce torecommended PQL 64 ❑' Mercury(5) ❑ ❑ ❑' ❑ ❑ Quarterly o.00l 0.001 65 0 Molybdenum ❑ ❑ ❑+ ❑i ❑ Quarterly 100.0 10.0 Reduce torecommended PQL 66 ❑ Nickel(l) ❑ ❑ 0 ❑+ ❑ ❑ Quarterly 10.0 So Reduce to recommended PQL 67 ❑ Selenium ❑ ❑ ❑' ❑ ❑ Quarterly 10.0 68 ❑' Silver ❑ ❑ ❑' ❑ ❑ Quarterly 5.0 1.0 Reduce to recommended PQL 69 0 Ziri ❑ ❑ ❑ 0 ❑+ ❑ Quarterly 10.0 10.0 70 ❑ Sludge Flow to Disposal E ❑ ❑ Quarterly 71 0 % Solids to Disposal ❑ ❑ ❑ Quarterly 72 ❑' Oil S Grease 0 ❑ Quarterly 5 ni 73 ❑ TKN ❑ 0 ❑ Quarterly 1 mg/L 74 ❑ TP ❑ Q ❑ Quarterly 0.2 mg/L 75 ❑ ❑ ❑ ❑ ❑ 76 ❑ ❑ ❑ ❑ ❑ 77 ❑ ❑ ❑ ❑ ❑ 78 79 80 81 12 Footnotes: 83 (1) Always in the LTMP/STMP due to EPA -PT requirement 84 (2) Only in LTMP/STMP if listed in sludge permit 85 (3) Only in LTMP/STMP while SIU still discharges to POTW 86 (4) Only in LTMP/STMP when pollutant is still of concern to POTW 87 (5) In LTMP/STMP, R sewage sludge is incinerated 88 Please use blue foal, for the info updated by pw 89 Please use red font for POC that need to be addedlmodi ied In L/STMP sampling plan 90 Please use orange font and air Isethrough for POC that may be 11samp! ing plan giI Blue shaded cell (D60:1182): Parameters usually included under that POC list 92 93 Facility Summary/background information/NPDES-PT regulatory action: POC to be added/modified In USTMP: 94 95 gg 97 ORC's comments on IU/POC: POC submitted through Chemical Addendum or Supplemental Chemical Datashest: Additional pollutants added to USTMP due to POTWs concerns: NPDES pw's comments on IU/POC. g8 6. Pretreatment updates in response to NPDES permit renewal gg 1 NPDES Permit Effective Data 180 days after effective (date): I Permit writer, please add list of required/recommended PT updates in NPDES permit cover letter. Page 2 20559 POC Review Form NORTH CAROLINA 2022 303(D) LIST Middle Roanoke Roanoke River Basin AU Name AU ID Description Roanoke River Basin AU Number Classification 03010102 AU_LengthArea AU —Units Middle Roanoke Island Creek (Island Creek Reservoir) 23-4 C 6.4 FW Miles 6945 From source to North Carolina -Virginia State Line, including that portion of Island Creek Reservoir in North Carolina below normal operating elevation PARAMETER IR CATEGORY CRITERIA STATUS REASON FOR RATING 303D YEAR Benthos (Nar, AL, FW) 5 Exceeding Criteria Fair, Poor or Severe Bioclassification 2022 Nutbush Creek (Including Nutbush Creek Arm of John 23-8-(1)a H. Kerr Reservoir below normal pool elevation) 7006 From source to NC 39 PARAMETER IR CATEGORY CRITERIA STATUS Benthos (Nar, AL, FW) 5 Exceeding Criteria C 1.7 FW Miles REASON FOR RATING 303D YEAR Fair, Poor or Severe Bioclassification 1998 Nutbush Creek (Including Nutbush Creek Arm of John 23-8-(1)b C 1.6 FW Miles H. Kerr Reservoir below normal pool elevation) 7007 From NC 39 to SR 1317 PARAMETER IR CATEGORY CRITERIA STATUS REASON FOR RATING 303D YEAR Fish Community (Nar, AL, FW) 5 Exceeding Criteria Fair, Poor or Severe Bioclassification 1998 Roanoke River Basin 03010103 Upper Dan DAN RIVER (North Carolina portion) 22-(1)b C;Tr 11.6 FW Miles 6481 From Little Dan River to Peters Creek PARAMETER IR CATEGORY CRITERIA STATUS REASON FOR RATING 303D YEAR Turbidity (10 NTU, AL, Tr) 5 Exceeding Criteria 2018 Belews Creek (including Belews Lake below elevation 22-27-(7) C 789.7 FW Acres 725) (1) 6627 From Southern Railroad Bridge to to a point 1.8 mile downstream of Forsyth -Stokes County Line PARAMETER IR CATEGORY CRITERIA STATUS REASON FOR RATING 303D YEAR Water Temperature (322C, AL, LP&CP) 5 Exceeding Criteria 2014 Smith River 22-40-(1) WS-IV 2.8 FW Miles 6693 From North Carolina -Virginia State Line to a point 0.8 mile downstream of Rockingham County SR 1714 (Aiken Road) PARAMETER IR CATEGORY CRITERIA STATUS Benthos (Nar, AL, FW) 5 Exceeding Criteria REASON FOR RATING 303D YEAR Fair, Poor or Severe Bioclassification 2008 6/7/2022 NC 2022 303d List- Approved by EPA 4/30/2022 Page 103 of 192 NORTH CAROLINA 2022 INTEGRATED REPORT Middle Roanoke Roanoke River Basin AU Name AU Number AU ID Description Nutbush Creek (Including Nutbush Creek Arm of John 23-8-(1)b C H. Kerr Reservoir below normal pool elevation) 7007 From NC 39 to SR 1317 2022 Water Quality Assessments PARAMETER Water Temperature (322C, AL, LP&CP) Dissolved Oxygen (4 mg/I, AL, FW) pH (6 su, AL, FW) pH (9.0, AL, FW) Chloride (230 mg/I, AL, FW) Flouride (1.8 mg/I, AL, FW) Turbidity (50 NTU, AL, FW miles) Fish Community (Nar, AL, FW) Benthos (Nar, AL, FW) Fecal Coliform (GM 200/400, REC, FW) Nutbush Creek (Including Nutbush Creek Arm of John 23-8-(1)c H. Kerr Reservoir below normal pool elevation) 7008 From SR 1317 to Nutbush Creek Arm of Kerr Reservoir 2022 Water Quality Assessments PARAMETER Fish Community (Nar, AL, FW) Classification AU LengthArea AU Units 1.6 FW Miles IR CATEGORY CRITERIA STATUS 1 Meeting Criteria 1 Meeting Criteria 1 Meeting Criteria 1 Meeting Criteria 1 Meeting Criteria 1 Meeting Criteria 1 Meeting Criteria 5 Exceeding Criteria 1 Meeting Criteria 3a Data Inconclusive 104.4 FW Acres IR CATEGORY CRITERIA STATUS 1 Meeting Criteria 6/7/2022 NC 2022 INTEGRATED REPORT -Category 5 Approved by EPA 4/30/2022 Page 848 of 1346 FISH COMMUNITY SAMPLE Waterbody Location Station ID Date Bioclassification NUTBUSH CR SR 1317 NF28 05/28/19 Fair County 8 digit HUC Latitude Longitude Elevation (ft) Reference Site VANCE 03010102 36.369048 -78.408169 320 No Level IV Ecoregion Drainage Area (mi2) Stream Width (m) Stream Depth (m) Northern Outer Piedmont 6.1 7 0.3 Upstream NPDES Dischargers (>_ 1 MGD or < 1 MGD and within 1 mile) NPDES Number Volume (MGD) Henderson WRF (Water Reclamation Facility) NCO020559 4.1 Landuse (%) Forest Developed Impervious Cultivation Grass/Herb/Shrub Wetland Water Barren 1992 45.2 45.1 no data 7.0 no data 1.2 0.1 1.4 2001 33.8 53.9 15.1 5.7 4.6 1.1 0.1 0.0 2006 33.7 54.2 15.2 5.7 5.2 1.1 0.1 0.0 2011 34.6 52.9 15.8 5.9 5.4 1.1 0.1 0.0 Water Quality Parameters 2004 2014 2019 Temperature (°C) 14.6 21.8 22.7 Dissolved Oxygen (mg/L) 10.6 7.1 7.7 Specific Conductance (pS/cm) 467 511 294 pH (s.u.) 7.4 7.4 7.5 Habitat Assessment Scores (max score) 2019 Channel Modification (5) 5 Instream Habitat (20) 12 Bottom Substrate (15) 3 Pool Variety (10) 4 Riffle Habitat (16) 7 Bank Erosion (7) 6 Bank Vegetation (7) 7 Light Penetration (10) 6 Left Riparian Score (5) 5 Right Riparian Score (5) 5 Total Habitat Score (100) 60 Water Clarity IClear. Substrates Isand, gravel, bedrock, and silt. Sample Date Sample ID Species Total NCIBI Score NCIBI Rating 05/28/19 2019-36 12 38 Fair 06/11 /14 2014-43 12 42 Good -Fair 04/29/04 2004-28 13 38 Fair 10/04/94 94-42 12 44 Good -Fair Data Watershed - a northern flowing tributary to Kerr Reservoir, draining central Vance County. This site is about 1.3 miles downstream from the Henderson WRF, and 1.4 miles upstream from the creek's confluence with the lake. Habitats - wide forested riparian zones here are providing moderate canopy shading. Instream habitats are primarily shallow, embedded, sandy/silty runs with overhanging shrubs along the edges. Abundant bedrock veins are present in the downstream part of the reach near the road crossing. There have been no obvious habitat changes at this site since the 2014 survey. 2019 Fish Community - the creek became very turbid with silts during sampling. Lower fish diversity here as seen in past assessments, with the same number of species present as in 2014. A slight trophic shift between insectivores and omnivores+herbivores (including dominance of the omnivorous Spottail Shiner) is the reason for the 4 point decline in NCIBI score and rating. However, these slight declines do not reflect any big changes to the fish community. Two species of fish were observed with young -of -year cohorts in 2019 - Bluegill (n=1), and Bluehead Chub (schools observed but not collected). 1994-2019 - consistently high conductivities have been measured at this site due to the Henderson WRP, and also from Henderson's non -point runoff. Although still quite elevated, 2019 marked the lowest conductivity measured here to date. Nutbush Creek continues to support lower fish species richness, with a total of 16 known species collected from this site including no suckers, 4 sunfish and bass (3 collected in 2019), 8 minnows (6 collected in 2019), 2 catfish (both collected in 2019), and 2 darters (1 collected in 2019). Although the rating here dropped back down to Fair in 2019, the fish assemblage does not appear to have changed much in this urban watershed since the 2014 survey. Most Abundant Sp. ISpottail Shiner (n=73, 28%). Non -Native Sp. I Green Sunfish (n=19), Bluegill (n=39). Species Change Since Last Cycle Species gained since 2014 - Creek Chub (n=1, last collected here in 2004), and Yellow Bullhead (n=1, new record). Species lost since 2014 - Rosyside Dace (1 collected in 2014), and Comely Shiner (7 collected in 2014). Henderson WRF - Permit NCO020559 Shepherd, Forest T Mon 9/18/2023 5:16 PM To:Perlmutter, Gary <gary.perlmutter@deq.nc.gov> Cc:Deamer, Nora <nora.deamer@deq.nc.gov> 9 attachments 0 MB) NCO020559_32230 - Chlorophyll A_Downstream_001.png; NCO020559_32230 - Chlorophyll A_ Downstream_001A.png; NCO020559_CO610 - Nitrogen, Ammonia Total (as N) - Concentration_Effluent_001.png; NCO020559_34611 - 2,4-dinitrotoluene_Effluent_001.png; NC0020559_01092 - Zinc, Total (as Zn)_Influent_001.png; NCO020559_01092 - Zinc, Total (as Zn)_Effluent_001.png; NCO020559_00630 - Nitrite plus Nitrate Total (as N)_Downstream_001.png; NCO020559_00630 - Nitrite plus Nitrate Total (as N)_Downstream_001A.png; NCO020559_00630 - Nitrite plus Nitrate Total (as N)_Effluent_001.png; Basin planning pulled the influent, effluent, and instream monitoring data provided by the Henderson WRF (NC0020559). Based on the 2015 — 2023 data, the chlorophyll a numbers recorded at both the downstream monitoring stations are concerning (see attached). In reviewing the nutrients (nitrate+nitrite, total nitrogen, total Kjeldahl nitrogen, and total phosphorus) they appear to be following their current limits (only ammonia attached). Two other notable parameters were 2,4-dinitrotoluene and zinc (see attached). Notably, this facility is discharging into a stream with low streamflow volumes (winter 7Q10 0.4 cfs; summer 7Q10 0.2 cfs; average 3.5 cfs) and their IWC (%) is 97% at 4.14 MGD and 98% at 6 MGD. While reviewing their nitrate+nitrite data we are concerned about the concentrations the facility is reporting. The Division has an ambient monitoring system (AMS) station (N5000000) located between the D1 and D2 monitoring stations established by the facility. There is considerable difference in the nitrate+nitrite concentrations recorded at the D1 station compared to our AMS station N5000000. The stations are approximately 0.87 miles apart and there are no significant sources of nutrients in the drainage area between D1 and N5000000. We suggest adding a split sampling effort because the nitrate+nitrite concentrations recorded at their downstream station D1 are very low compared to the AMS station (N5000000) between the facilities stations D1 and D2. We defer to your judgement call on how many split samples to collect. The chlorophyll a numbers recorded at the downstream monitoring stations (D1 and D2) and the ambient lakes monitoring program station ROA037A (see below) run by DWR's Intensive Survey Branch (which is co -located with the permittee's most downstream monitoring stations) suggest that the available nutrients in Nutbush Creek and draining to John H. Kerr Reservoir are having an impact on water quality. Values can be above the chlorophyll a water quality standard and can be the highest recorded lake station across John H. Kerr Reservoir. The chlorophyll a concentrations in Nutbush Creek (station D1) are extremely concerning with a large number of records above 40 µg/L. This is a small stream where a large percentage of the flow is likely wastewater discharge during low flow periods. The chlorophyll a levels indicate that it is a highly productive stream. It is not surprising that there are impacted biology communities. I would also assume that there is a lot of periphytic growth that likely occurs in this stream. The creek likely backs up or there is a slow flow allowing for the algae to grow in this system. Nutrient levels in the effluent of the Henderson WRF (NC0020559) are contributing to the cumulative impact to Nutbush Creek and John H. Kerr Reservoir. There is a concern for the levels of chlorophyll a recorded in Nutbush Creek and a concern that if nutrients increase to this arm of John H. Kerr Reservoir, we could have an impaired waterway in the future. We request year-round monthly monitoring for upstream nutrients (NO2+NO3, NH3-N, TKN, and Total Phosphorus) using a grab sample and downstream nutrients (NO2+NO3, NH3-N, TKN, and Total Phosphorus), secchi, and chlorophyll a using a composite sample in the lake and a grab sample in the creek. The reason for this additional monitoring is the concerning chlorophyll a levels and the need to begin capturing an entire year -long understanding of the nutrients in Nutbush Creek to monitor the nutrient levels responsible for the elevated chlorophyll a from the areas draining to the Henderson WRF outfall and downstream from their return flows. The last two comments we would like to share are that the composite sample the facility is collecting for nutrients, secchi, and chlorophyll a at station D1 should be a grab sample since the stream in that section of the Nutbush Creek is most likely shallow given the volume and the width of the stream channel. It seems quite difficult to sample at twice the secchi depth. Also, as we discussed previously, the AMS station N5000000 should have chlorophyll a added as a water quality parameter that is sampled monthly. Basin planners discussed possibly a year-round special study in 2024. Would you be willing to request this parameter be added to the water quality parameters sampled at AMS station N5000000 to align with what the permittee has to sample and to help determine Nutbush Creek's compliance with the water quality standards? Roanoke River Basin Data, DWR Intensive Survey Branch: https!Lwww.deq.nc.gov/water- g_a ritybims reports/roanoke19finaI/download SURFACE PHYSICAL DATA PHOTIC ZONE DATA Total Ternp Dep[h Percent Total Suspendad Total Lake Date Sampling DO Water pH Cond. Secchi DO TP TKN NH3 NO. TN TON TIN Chia Solids Solids Turbidity He'dnes Station IL C s.u. mh-lom meters SAT m !L m 1L !L m !L m IL m !L m 1L IL m iL m IL NT IJ rrgL HUC 03010102 J HN H. KERR September 18, 2019 RCA037A 7.6 27.8 7.2 92 1 .0 97.3% 0.03 0.45 10.02 10.02 0.46 0.44 0.02 19.0 73 112.0 5.4 RESERVOIR September 18, 2019 RCA037D 7.8 27.4 7.2 86 2CI 983% 002 0.32 <0.02 <0.02 0.33 0.31 0.02 11.0 59 <6.2 2.8 25.0 September 18. 2019 ROA037E 7.3 27.4 7.2 90 2.0 93.0% 0.02 0.31 0.02 r0.02 032 0.30 0.02 10.0 74 <6.2 3.3 September 18, 2019 ROA0371 66 26.6 7.2 96 28 82 9% 002 027 003 <0 02 028 024 004 58 60 <fi 2 18 Se tember 18. 2019 ROA0371J 6.0 26.8 7.6 101 2.5 75.3% 0.02 0.28 0.03 <0.02 0.29 0.25 0.04 4.6 80 <6.2 1.5 Augusl28, 2019 RCAU37A 79 2111 7.5 93 1 5 1030% 0 02 0 33 <0.02 <0 02 0.34 0.32 0 02 7 T 84 <6 2 3.1 Augusl28, 2019 RCA037B 7.5 28.6 7.6 88 1.5 982% 0.02 0.31 <0.02 10.02 0.32 0.30 0.02 11.0 100 112.0 2.3 27.0 Augusl28, 2019 RCA037E 7.4 27.8 7.4 93 2CI 95.5% <0.02 0.3C <0.02 <O.C2 031 0.29 0.02 10.0 74 :6.2 2.1 Augusl28, 2019 ROA0371 6.9 27.8 7.2 95 2.5 80-3% <0.02 0.30 al <0.02 031 0.28 0.63 5.3 84 �62 1.8 Au us128, 2019 ROA037IJ 6.8 27.7 7.4 102 2.5 87.4% <0.02 0.33 0.02 <0.02 0.34 0.32 0.02 6.3 68 �6.2 1.6 July 18, 2019 RCA037A 7.4 30.8 7.6 102 1 .3 99.6% 19.❑ H1.0 :6.2 4.1 July 18, 2019 RCA037B 7.8 31.5 7.3 91 2CI 107.29E 100 66 �6.2 2.9 28.0 Juy 10, 2019 RCA037E 6.8 30.1 7.2 97 20 91.0% 120 73 �12 3.8 July 18. 2019 ROA0371 7.3 30.7 7.4 96 2.5 99.0% 8.1 74 <120 2.3 July18. 2019 ROA0371J 7.fi 30.9 7.7 76 2.5 102.8% 8.2 65 �6.2 2.0 June 2fi. 2019 ROA037A 9.2 27.9 8.3 92 0.9 117.1% 0.02 <0.02 <0.02 0.02 170 t6.2 3.7 June 26, 2019 ROA0376 8.B 27.5 7.7 93 1 .4 1092% <0.02 <0.02 <0.02 0.02 3.6 69 •�6.2 2.7 30.0 June 26, 2019 RCA037E 8.7 27.5 7.9 96 1 .6 110.0% <0.02 <0.02 110 8C •=6.2 2.1 June 26, 2019 ROA0371 8.4 26.5 8.0 96 1.6 109.0% 10.02 <0.02 <0.02 0.02 7.5 72 12.0 1.8 June 26. 2019 ROA0371J May 21, 2019 RCA037A 9.2 24.1 8.3 9B 12 110.7 % 002 0.41 <0.02 007 0.48 0.40 0.08 13.0 75 1120 33 May 21, 2019 RCA037B 94 24 7 8 5 92 2.1 1 142 % 002 039 c0.02 0 OS 0 47 ❑ 38 0013 11 0 74 a62 2 8 300 May 21, 2019 RCA037E 8.9 23.1 8.0 92 1.5 104.9% <0.02 0.27 <0.02 0.10 037 0.26 0.11 8.9 65 <B2 32 May 21, 2019 ROA0371 9.0 243 8.2 92 1.8 109.3% <0.02 0.28 <002 0.08 036 0.27 0.09 a.7 8o <B2 2.7 Ma 21, 2019 ROA0371J 9.1 25.4 8.4 94 2.0 111.2% <0.02 0.32 <002 0.07, 039 0.31 0.08 9.4 72 <62 2.9 Thank you for giving us an opportunity to review the data associated with the Henderson WRF - Permit NCO020559 Until Next Time, Forest Shepherd (he/him) Environmental Program Consultant Division of Water Resources North Carolina Department of Environmental Quality Office: (919) 707-9042 Forest.Shepherd deq.nc.gov <- (Please note new email address) Email correspondence to and from this address may be subject to the North Carolina Public Records Law and may be disclosed to third parties by an authorized state official. MONITORING REPORT(MR) VIOLATIONS for: Permit: NCO020559 MRS Betweel 8 - 2018 and 9 - 2023 Region: % Facility Name: % Param Nam(% County: % Major Minor: % Report Date: 09/18/22 Page 1 of 1 Violation Category:Limit Violation Program Category: NPDES WW Subbasin: % Violation Action: PERMIT: NCO020559 FACILITY: City of Henderson - Henderson Water Reclamation COUNTY: Vance REGION: Raleigh Facility Limit Violation MONITORING VIOLATION UNIT OF CALCULATED % REPORT OUTFALL LOCATION PARAMETER DATE FREQUENCY MEASURE LIMIT VALUE Over VIOLATION TYPE VIOLATION ACTION 03 - 2019 001 Effluent BOD, 5-Day (20 Deg. C) - 03/23/19 5 X week mg/I 18 18.58 3.2 Weekly Average Concentration Exceeded 05 - 2021 001 Effluent BOD, 5-Day (20 Deg. C) - 05/31/21 5 X week mg/I 6 6.23 3.8 Monthly Average Concentration Exceeded 06 - 2021 001 Effluent BOD, 5-Day (20 Deg. C) - 06/12/21 5 X week mg/I 9 9.66 7.3 Weekly Average Concentration Exceeded 06 - 2021 001 Effluent BOD, 5-Day (20 Deg. C) - 06/30/21 5 X week mg/I 6 7.2 20.1 Monthly Average Concentration Exceeded 09-2020 001 Effluent Chlorine, Total Residual 09/29/20 5 X week ug/I 17 19.8 16.5 Daily Maximum Exceeded 05 - 2022 001 Effluent Nitrogen, Ammonia Total (as 05/28/22 5 X week mg/I 9 15.32 70.2 Weekly Average N) - Concentration Exceeded 05 - 2022 001 Effluent Nitrogen, Ammonia Total (as 05/31 /22 5 X week mg/I 3 4.68 56.0 Monthly Average N) - Concentration Exceeded 01 -2019 001 Effluent pH 01/28/19 5 X week su 6 5.3 11.7 Daily Minimum Not Reached 03 - 2019 001 Effluent Solids, Total Suspended - 03/23/19 5 X week mg/I 45 56.2 24.9 Weekly Average Concentration Exceeded Proceed to Enforcement Case Proceed to NOD Proceed to Enforcement Case Proceed to Enforcement Case No Action, BPJ Proceed to Enforcement Case Proceed to Enforcement Case No Action, BPJ Proceed to Enforcement Case 10/2/23, 9:41 AM Detailed Facility Report I ECHO I US EPA Detailed Facility Report ECHQ,ll,,, Detailed Facility Report Facility Summary HENDERSON NUTBUSH CREEK WWTP 1646 WEST ANDREWS AVENUE, HENDERSON, NC 27536 FRS„(Faci,litg,Regis[„ry„Service) ID: 110002357930 EPA Region: 04 Latitude: 36.349349 Longitude:-78.411438 Locational Data Source: FRS Industries: -- Indian Country: N Enforcement and Compliance Summary Statute Compliance Monitoring Activities (5 years) Date of — Compliance Monitoring Activity Compliance status Otn in Noncompliance 1& 12) Otn with Sign'dicant vi.Wion Informal Enforcement Acions IS years) Formal Enforcement ANons (5 years) Penalties from Formal Er fon, m . Actions (5 years) EPA Us (5 years) Penalties from EPA Cases is years) Regulatory Information Clean Air Act( CAA): No Information Clean Water Act (CWA): Non -Major, Permit Effective (NCL020559), Major, Permit Expired (NCO020559), Non -Major, Permit Effective (NCG110075) Resource Conservation and Recovery Act (RCRA): No Information Safe Drinking Water Act(SDWA): No Information Go To Enforcement/Co F'Iiance Details Known Data Problems Facility/System Characteristics Facility/System Characteristics 7 06/07/2023 Violation Identified 12 0 4 $5,971 Other Regulatory Reports Air Emissions Inventory (EIS): No Information Greenhouse Gas Emissions (eGGRT): No Information Toxic Releases (TRU: No Information Compliance and Emissions Data Reporting Interface (CEDRI): No Information sysmm Nrtun Idemiaer J —�Areu Permit Expiration Date _ Indian Country Latitude Longitude FRS 110002357930 N 36,349349-78,411438 IOS-NPDES CWA NCL020559 Non -Major: Associated Permit Record ERettive Biosolids 12/31/2025 N 36.349349-78,411438 ICIS-NPDES CWA NCO020559 Major: NPDES ndlvidual Permit Expired Biosolids, POTW Pretreatment 03/31/2023 N 36.348645-78.412073 IOS-NPDES CWA NCG110075 N.nM jor: General Permit Covered Facility ERettive OS/31/2028 N 36.3497-78.7119 Facility Address System statue¢ Facility Name i FacilityAddress , Facility County FRS 110002357930 HENDERSONNUTBUSH CREEK 1 1646 WEST ANDREWS AVENUE, HENDERSON, NC 27536 Vance County ICIS-NPDES CWA NCL020559 CITY OF'ENDERSON PO BOX 1434, HENDERSON, NO 27536-1434 Vance Counry ICIS-NPDES CWA NCO020559 HENDERSON WATER RECLAMATION FACTITV 1646 WANDREWS AVE, HENDERSON, NC275362555 Vance County ICIS-NPDES CWA NC3110075 NUTBUSH CREEKWWTP 1646 WANDREWS AVE, HENDERSON, NO 27536 Vance Count' Facility SIC_(Standard Industrial Classification) Codes Facility NAICS (North,Amencan Industry Classification System) Codes system Identifier SIC Code SIC Description . Idemifier NAICS Code NAICS Description ICIS NPDES NCO020559 4952 Sewerage Syttems No data records returned Facility Industrial Effluent Guidelines Facility Tribe Information Identifier UN— Guideline(40 CFR Part) ■ Effluent Guideline Description Reservation Name Tribe Name Dirtanceto Tdbe(miles) NCO020559 401 General provisions NCG 110075 401 General prow:ions No data records returned Enforcement and Compliance Compliance Monitoring HistoryLast 5ye Statute Source ID sy— Activity Type Compliance Monitoring Type Lead Agenry Data nnding(if applicable) CWA NCO020559 ICIS-NPDES Inspection/Evaluation Base Program -Evaluation State 06/07/2023 CWA NCO020559 US-NPDES Inspection/Evaluation Base Program- Evaluation State 08/24/2021 CWA NCO020559 ICIS-NPDES Inspecion/Evaluation Base Program -Evaluation State 07/22/2021 CWA NCO020559 ICIS-NPDES Inspettion/Evaluation Base Program- Biomonimring State 07/14/2020 CWA NCO020559 ICIS-NPDES Inspecion/Evaluation Base Program -Evaluation State 07/17/2019 CWA NCO020559 ICIS-NPDES Inspettion/Evaluation Base Program -Evaluation State 01/31/2019 CWA NCL020559 ICIS-NPDES OReite Record Review Biosolids-Desk Audit EPA 12/31/2022 Entries in italics are not counted as EPA official inspections. Compliance Summary Data Statute source ID C $N415fgRifi N mglie )/H,PV(Hgh_R!onty Yolat on) Current A9 OF Qlrs with NC(N comp) ance)(of 12) Data La#Refreshed CWA NCL020559 No 06/30/2023 0 09/29/2023 CWA NCO020559 No 06/30/2023 112 09/29/2023 https://echo.epa.gov/detailed-facility-report?fid=l 10002357930&ej_type=sup&ej_compare=US 1 /3 10/2/23, 9:41 AM Detailed Facility Report I ECHO I US EPA Statute 5— ID C rent SNC(Sgnifi t Noncomplencel/HPV (High P riy Violation) Current Asof Qtrs w th NC(Noncomphance) RA 12) Data Last Refreshed CWA NCG 110075 No 06/30/2023 0 09/29/2023 Three Year Compliance History by Quarter Statute Pmgram/PollutanuYolation Type QTR 1 QTR 2 QTR 3 QTR 4 QTR S QTR 6 QTR J QTR 8 QTR 9 QTR 10 QTR 11 QTR 12 QTR 13+ EWA(S--ID: NCL020559) 07/01 09/30/20 10/01-12/31/20 01/01-03/31/21 04/01-06/30121 07/01-09/30/21 10/01-12/31/21 01/01-03/31/22 04/01-06/30/22 07101-09/30/22 10/01-12/31/22 01101-03/31/23 04/01-06/30/23 0]/01 09/29/23 Facility -Level Status NO Violation NO Vlolation NO Violation NO Violallon NO Violation NO Vlolation NO Violation NO Violation NO Viola<ion NO Vlolation NO Uolation NO Violation Undetermined Ider�---- QuarteHy Noncompliance Report Hiztory CWA ($oumelD: N00020559) 07/01-01/30/20 10/01-12/31/20 01/01-03/31/21 04/01-06/30121 07/01-09/30/21 10/01-12131121 01101-03/31/22 04/01-06/30/22 07/01-09130/22 10/01-12/31/22 01/01-03/31/23 04/01-06/30/23 0]/O1- 09/29/23 Facility -Level Status Violation Identified Volition Identified Violationldentified Violationldentified Violation Identified Volation Identified Violationldentified Violationldentified Violationldentified Volition Identified Viol— ldendfed Violationldentified Undetermined Report History Reportable Reportable Reportable Reportable Reportable Reportable Reportable Reportable Reportable Reportable Reportable Reportable 4-,I*I,N0ncompliance Noncompliance Noncompliance Noncompliance Noncompliance Noncompliance Noncompliance Noncompliance Noncompliance Noncompliance Noncompliance Noncompliance Noncompliance Po11— Disch Mon Loc Freq Point BOD. S-dav 20 a CWA deg.0 001- Effluenx Mthly 4% M Gross 001- Effluent NMth M Gross ]% .CWA BOO. S-day.20 deg C .CWA Nit-- 001- EfFl t Mthly M Gross 56% fi lm E CWA ias NJ 001- I Eff—rt NMth 70% M Gross Late or Missing Discharge Monitoring Report (DMR) Measurements Counts of tale DMR Measurements 1 Counts of Missing DMR Measumments 3 11 3 3 3 3 3 3 3 3 3 3 CWA (S.—ID: NCG110075) 07/01-09/30/20 10/01.12/31/20 01/01.03/31/21 04/01.06/30/21 09/01-09/30/21 10101.12/31121 01/01.03/31/22 04/01.06/30/22 07/01-09/30/22 10/01-12/31/22 01/01.03/31/23 04/01-06/30/23 07/01. 09/29/23 Facility -Level Status ---------- No Vola0on Undetermined bfied Identified Qoartedy Noncompliance Report History Informal Enforcement Actions Last5Years St— System Lead Aq—n CWA ICIS-NPDES NC0020559 Base Program- Noticeof Yolati— State 05/12/2023 CWA ICIS-NPDES NC0020559 Base Program -Notice of ViolMion State 01/06/2023 CWA ICIS-NPDES NC0020559 Base Program- Noticeof Uolation State 071110. CWA ICIS-NPDES NC0020559 Base Program -Notice of Violrtion State 08/23/2021 CWA ICIS-NPDES NC0020559 Base Program- Noticeof Yolati— State O111312011 CWA ICIS-NPDES NC0020559 Base Program -Notice of Volition State 03/22/2021 CWA ICIS-NPDES NC0020559 Base Program- Noticeof Yolation State 05/27/2019 Entries in italics are not counted as informal enforcement actions" in EPA policies pertaining to enforcement response tools. Formal Enforcement Actions Last5Years Statute system UWS.di— source ID `Typeof Action Case N. lead Agenry Case Name Issued/�ate Set1.—WARions Settlement/Action Date Federal Penally Assessed State/Local PenaltyAssessed Penalty Amount Collected SEPV.1- Comp ARi—Cost CWA ICIS-NPDE5 OTHER NPDES/NC0020559 Administrative-FormaIl NC-LV-2022-0303 State C'ly of Henderson 11/212022 1 11/21/2022 $0 $2,055 - $0 $0 CWA ICIS-NPDE5 OTHER NPDE5/NC0020559 Administrative -Formal NC-LV-2021-0311 State Clty of Henderson 11/092021 1 11/09/2021 $0 $1,555 - $0 $0 CWA ICIS-NPDE5 OTHER NPDE5/NC0020559 Administrative -Formal NCTX-2021-000S State City of Henderson 06/072021 1 06/07/2021 $0 E2,0]4 - $0 $0 CWA IICIS-NPDE5 OTHER (NPDES/NC0020559 Administative-Formal)NC-LV-2019-Ot]BI State CiI of Henderson 0]/302019 1 0]/30/2019 $0 $28] - $0 $0 Environmental Conditions Watersheds 12 Dgt WBD.IW h dB ,..,n„dary,DatasetI HUC LRAD WBD (Wet ,hedB .dory EL &gUSubwatershed Name(RAD S— Water Body Name((41j(I .grated Beach Closures Within Beach Closures Wthn Lazt Pollutarrts Potentally Related to Watershed with ESA(E dang,ered5pegesAgR- .tReafh4PEEeas.D.aAa4ase)) (.Ria$I1.9d?rzaa Data base)) ,Cpmplian£a#xh;KMF9P5yA9.T..R Lart Vear T Years Impairment listed Aquatic Species? 030101021002 Headwaters Wtbush Creek NUTBUSH CREEK (I NCLUDING N UTBUSH CREEK No No - Ves ARM OF TO 030201010103 Shelton Creek - No No Assessed Waters From Latest State Submission (ATTAINS) State Report eyde Assessment Unit ID Ave rtUnit Name Water Condition Cauze Groups Impaired i Drinking Water Use Ecological Use Fish Consumption Uze Recreation Uze Other Use No data records returned Air Quality Nonattainment Areas Pollutant Within Nonattainment 5tatu—al Nonattainment StMus Applicablestandard(s) —1 Within Maintenance 5-uz Area? Maintenancest—a Applicable standard(s) No data records returned Pollutants Toxics Release Inventory History of Reported Chemicals Released in Pounds per Year at Site TRI Facility ID Year Total Air Emissions Surface Wafer Discharges off -site Tranderste Po — No data records returned Toxics Release Inventory Total Releases and Transfers in Pounds by Chemical and Year Chemical Name No data records returned .GWA.(.C....lea.. n..Wa...ter,Act) Discharge Monitoring Report (DMR) Pollutant Loadings No data records returned Community Underground Injections Releases to Land Total Chsite Releases Total Off -Sint Tranders DMR and TRI Multi -Year Loading Report https://echo.epa.gov/detailed-facility-report?fid=110002357930&ej_type=sup&ej_compare=US 2/3 10/2/23, 9:41 AM Environmental Justice Detailed Facility Report I ECHO I US EPA This section shows indexes from EJScreen, EPA's screening tool for environmental justice (EJ) concerns. EPA uses these indexes to identify geographic areas that may warrant further consideration or analysis for potential EJ concerns. Use of these indexes does not designate an area as an "EJ community" or "EJ facility." EJScreen provides screening level indicators, not a determination of the existence or absence of EJ concerns. For more information, see the EJScreen home R1,dgg. EJScreen Indexes Shown Related Reports EJScreen Community Report Compare to Q US Q State Index Type O Environmental Justice O Supplemental Download Data census Block Group ID: 371819603002 Us (Percentile) Supplemental Indexes FacilityCeneus131-k—up 1-mile Max Count of Indexes At or Above 80th Percentile 1 1 Particulate Matter 2.5 68 68 Ozone 60 60 Diesel Particulate Matter 37 54 Air Toxics Cancer Rsk 0 85 0 85 Air Toxics Respiratory Hazard Index 68 68 Toxic Releases to Air 70 70 Taf,Proximity 68 75 Lead Paint 49 55 Risk Management Plan(RMP) Facility Proximity 64 64 Hazardous Waste Proximity so 50 Superf,nd Proximity 74 74 Underground Storage TenkS(USr) 75 0 82 Wastewater Discharge 24 24 Demographic Profile of Surrounding Area (1 mile) O Facility 1-mile Radius ❑ Facility Census Block Group This section provides demographic information regarding the community surrounding the facility. ECHO compliance data alone are not sufficient to determine whether violations at a particular facility had negative impacts on public health or the environment. Statistics are based upon the 2010 U.S. Census and 2017 - 2021 American Community Survey (ACS) 5-year Summary and are accurate to the extent that the facility latitude and longitude listed below are correct. EPNS spatial processing methodology considers the overlap between the selected radii and the census blocks (for U.S. Census demographics) and census block groups (for ACS demographics) in determining the demographics surrounding the facility. For more detail about this methodology, see the DFR Data Dictionary.. General Statinicz (us. Census) Total Persons Population Denziry =483/,­L Housing Units in Area General Statistic(AC$(Mler19@i Commyniry.5untey)) Total Persons 1,264 Percent People of Color 68% Households in Area 613 Households on Public Assistance 8 Persons With Low Income 542 Percent With Low Income 43% Gaoglaphy Radius of Selected Area Center Latitude 36.349349 Center fnngitude -78.411438 Land Area 100% Water Area 0% InBreakdown(AC,S,(AmeriS.i!a.4gmtBg.Blb..;<.P.rygy))-Households(%) Less than $15,DDD 108 (1759%) $15,000-$25,000 72(11.73%) $25,000-$50,000 256(41.69%) $50,000 - $75,000 105 (17.1%) Greater than $75,000 73 (11.89%) LAST UPDATED ON SEPTEMBER 21, 2022 DATA REFRESH INFORMATION Age Breakdown(U.S. Census) -Persons(%) , Children 5 years and younger 130 (9%) Minors 17 years and younger 407 (27%) Adults 18 years and older 1,083 (73%) Seniors 65 years and older 287 (19%) Race Breakdown (U.S. Census) -Persons (%) White 260(17%) African -American 1, 184(79%) Hispanic -Origin 26(2%) Asian/Pacific Islander 12 (1%) American Indian 1 (0%) Other/Muhiracial 33 (2%) Eduoatlon Ie.I(Peraons 25&oI&r)(ACS(A can Communty Survey))-Penons(%) Less than 9th Grade 20 (2.23%) 9th through 12th Grade 51 (5,61%) High School Diploma 307 (34,26%) Some College/2-year 261 (29.13%) „B,.S;/,B.,A,J13—„h„e„(o„r,ofSc„ie„n„W,Ba„chelo-,r„o Arfs)or More 164 (18.3%) https://echo.epa.gov/detailed-facility-report?fid=110002357930&ej_type=sup&ej_compare=US 3/3 Whole Effluent Toxicity Testing and Self Monitoring Summary Havelock WWTP NCO021253/001 County: Craven Mysd7dPF Begin: 6/1/2014 Mysid or Cerio Lim@ NonComp: Single J F M A M 2019 Fail Pass >60 - - 2020 Pass - - Pass - 2021 Pass - - Pass - 2022 Pass - - Pass - 2023 Pass - - Pass - Henderson Nutbush Cr WWTP NCO020559/001 County: Vance Ceri7dPF Begin: 8/1/2019 chr lim: 90% NonComp: Single J F M A M 2019 Pass - - Pass - 2020 Pass - - Pass>100(P) - 2021 Fail >100 63.6 Pass - 2022 Pass >100(P) - - Pass - 2023 Pass - - Pass - Hendersonville WTP NCO042277/001 County: Henderson Ceri7dPF Begin: 6/1/2021 Chr Monit: 90% NonComp: J F M A M 2019 - Fail - - Fail 2020 - Pass - - Pass 2021 - Pass - - Pass 2022 - Fail - - Pass 2023 - Pass - - Pass Hendersonville WWTP NCO025534/001 County: Henderson Ceri7dPF Begin: 1/1/2018 chr lim 18% @ 4.8M NonComp: Single J F M A M 2019 - Pass - - Pass 2020 - Pass - - Pass 2021 - Pass - - Pass 2022 - Pass - - Pass 2023 - Pass - - Pass Hickory WTP (NCG590036) NCO044121/001 County: Catawba Ceri7dPF Begin: 8/1/2021 ANNUAL (NCG59003 NonComp: J F M A M 2019 Pass - - Pass - 2020 Pass - - Pass - 2021 Pass - - Pass - 2022 Pass - - - - 2023 Pass - - - - Region: WARO Basin: NEU10 Jan Apr Jul Oct SOC JOC: 7Q10: 0 PF: 2.25 IWC: 100 Freq: Q l J A S O N - Pass - - Pass - Pass - - Pass Pass - - Pass - Pass - - Pass Pass Region: RRO Basin: ROA06 Jan AprJulOct SOC JOC: 7Q10: 0.20 PF: 4.14 IWC: 97 Freq: Q J J A S O N - Pass - - Pass >100(P) - Pass - - Pass - Pass >100(P) - - Pass - Pass - - Fail >100 Pass - Region: ARO 7Q10: I Region: ARO 7Q10: 17 J Region: MRO 70,10: J Basin: FRB03 Feb May Aug Nov PF: IWC: Freq: Q J A S O Pass - Pass Pass Pass Basin: FRB02 Feb May Aug Nov PF: 4.8 IWC: 22 Freq: Q J A S O Pass - Pass Pass Pass Pass Basin: CTB32 Mar Jun Sep Dec PF: IWC: Freq: A J A S O Pass - - Pass Pass - - Pass Pass SOC JOC: N Pass Pass Pass Fail SOC JOC: N Pass Pass Pass Pass SOC JOC: N C C >100 G C C Leeend: P= Fathead minnow (Pimohales oromelas). H=No Flow (facility is active). s = Solit test between Certified Labs Page 49 of 115 United States Environmental Protection Agency Form Approved. EPA Washington, D.C. 20460 OMB No. 2040-0057 Water Compliance Inspection Report Approval expires 8-31-98 Section A: National Data System Coding (i.e., PCS) Transaction Code NPDES yr/mo/day Inspection Type Inspector Fac Type 1 IN 1 2 u 3 I NCO020559 I11 121 23/06/07 I17 18I � I 19 I s I 201 I 211IIIII 111111III II III III1 I I IIIII IIIIIIIII II r6 Inspection Work Days Facility Self -Monitoring Evaluation Rating B1 QA ---------------------- Reserved ------------------- 67 I 72 I n, I 71 I 74 79 I I I I I I I80 701 I 71 I LL -1 I I LJ Section B: Facility Data Name and Location of Facility Inspected (For Industrial Users discharging to POTW, also include Entry Time/Date Permit Effective Date POTW name and NPDES permit Number) 09:30AM 23/06/07 19/08/01 Henderson Water Reclamation Facility 1646 W Andrews Ave Exit Time/Date Permit Expiration Date Henderson NC 275362555 12:30PM 23/06/07 23/03/31 Name(s) of Onsite Representative(s)/Titles(s)/Phone and Fax Number(s) Other Facility Data Clarissa LipscombH CPO KLRWS ORC/252-438-2141 /2524387866 Clarissa M Lipscomb/ORC/252-438-2142/ Name, Address of Responsible Official/Title/Phone and Fax Number Contacted Terrell Blackmon,PO Box 1434 Henderson NC 275361434/City Manager/252-430-5701 / No Section C: Areas Evaluated During Inspection (Check only those areas evaluated) Permit 0 Flow Measurement Operations & Maintenar Records/Reports Self -Monitoring Progran 0 Sludge Handling Dispo: Facility Site Review Effluent/Receiving Wate Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) (See attachment summary) Name(s) and Signature(s) of Inspector(s) Agency/Office/Phone and Fax Numbers Date Cheng Zhang DWR/RRO WQ/919-791-4200/ Kevin Fowler DWR/RRO WQ/919-791-4200/ Signature of Management Q A Reviewer Agency/Office/Phone and Fax Numbers Date EPA Form 3560-3 (Rev 9-94) Previous editions are obsolete. Page# NPDES yr/mo/day Inspection Type NCO020559 I11 12I 23/06/07 117 18 i c i (Cont.) Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) The current permit expired on March 31, 2023. Renewal application was received by the Division on November 28, 2022. The 4.14 MGD facility consists of the following units: influent pump station; dual bar screens; grit removal system; biological nutrient removal system — 4 anaerobic basins, 2 anoxic zones, 2 oxidation ditches with 4 aerators ( 100 HP); two secondary clarifiers; UV disinfection with sodium hypochlorite backup; four (4) tertiary sand filters; post aeration; aerobic digester; sludge holding tank; waste activated sludge pumps, screw thickener; and screw thickener discharge pump. At the time of inspection, the following treatment units were not in used due to low flow: one of two BNR ditches, and two of four tertiary filters. Color of the influent in the oxidation ditch appeared chocolate brown. Foam covered about 50% of the basin. Effluent flowing at the weirs of the secondary clarifier and clear well of the tertiary sand filters appeared clear. Sludge blankets in the secondary clarifiers were less than a foot. feet. The screw thickener was in operation at the time of inspection. The aerobic digester was about 3/4 full. Discharge Monitoring Report records for for July 2022 and January 2023 were reviewed with lab bench sheets and no transcription errors were noted. Chain of Custody forms are completed and kept on site. A daily operation log book is maintained and kept on site. Records are maintained for at least three years. The laboratory was checked in a cursory manner. All calibrations of instruments and temperatures of refrigerators and other equipment are recorded daily in a log book. The following deficiencies were noted during the inspection: 1. Influent and effluent flow meters were last calibrated on February 2, 2022, permit requires flow meters to be calibrated at least annually; 2. ORC visitation has not been documented. Page# Permit: NCO020559 Inspection Date: 06/07/2023 Owner -Facility: Henderson Water Reclamation Facility Inspection Type: Compliance Evaluation Operations & Maintenance Yes No NA NE Is the plant generally clean with acceptable housekeeping? 0 ❑ ❑ ❑ Does the facility analyze process control parameters, for ex: MLSS, MCRT, Settleable ❑ ❑ ❑ Solids, pH, DO, Sludge Judge, and other that are applicable? Comment: Facility analyze MLSS, DO, temperature, PH, settleable solids, sludge blanket for process control Permit Yes No NA NE (If the present permit expires in 6 months or less). Has the permittee submitted a new ❑ ❑ ■ ❑ application? Is the facility as described in the permit? ❑ ■ ❑ ❑ # Are there any special conditions for the permit? 0 ❑ ❑ ❑ Is access to the plant site restricted to the general public? 0 ❑ ❑ ❑ Is the inspector granted access to all areas for inspection? ■ ❑ ❑ ❑ Comment: Influent pump station needs to be added to the treatment components list Pump Station - Influent Yes No NA NE Is the pump wet well free of bypass lines or structures? 0 ❑ ❑ ❑ Is the wet well free of excessive grease? ■ ❑ ❑ ❑ Are all pumps present? 0 ❑ ❑ ❑ Are all pumps operable? 0 ❑ ❑ ❑ Are float controls operable? 0 ❑ ❑ ❑ Is SCADA telemetry available and operational? 0 ❑ ❑ ❑ Is audible and visual alarm available and operational? ❑ ❑ 0 ❑ Comment: Four pumps Bar Screens Yes No NA NE Type of bar screen a.Manual ❑ b.Mechanical Are the bars adequately screening debris? ■ ❑ ❑ ❑ Is the screen free of excessive debris? 0 ❑ ❑ ❑ Is disposal of screening in compliance? 0 ❑ ❑ ❑ Is the unit in good condition? 0 ❑ ❑ ❑ Comment: Two bar screens Page# 3 Permit: NCO020559 Inspection Date: 06/07/2023 Bar Screens Owner -Facility: Henderson Water Reclamation Facility Inspection Type: Compliance Evaluation Grit Removal Type of grit removal a.Manual b.Mechanical Is the grit free of excessive organic matter? Is the grit free of excessive odor? # Is disposal of grit in compliance? Comment: One channel with grit pump in use, a spare channel for future expansion Oxidation Ditches Are the aerators operational? Are the aerators free of excessive solids build up? # Is the foam the proper color for the treatment process? Does the foam cover less than 25% of the basin's surface? Is the DO level acceptable? Are settleometer results acceptable (> 30 minutes)? Is the DO level acceptable?(1.0 to 3.0 mg/1) Are settelometer results acceptable?(400 to 800 ml/I in 30 minutes) Yes No NA NE Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ ❑ ■ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ Comment: One of the two oxidation ditches were online at the time of inspection. Anaerobic zone (influent goes into) and anoxic zone (influent and returned mixed liquor go into) at the head of each oxidation ditch, for biological nutrient removal. Foam covered more than 50% of the basin's surface. Operator explained that it was common in late spring/early summer, and was trying to reduce the amount of foam by wasting more. MLSS was about 2500 mg/L. Secondary Clarifier Yes No NA NE Is the clarifier free of black and odorous wastewater? ■ ❑ ❑ ❑ Is the site free of excessive buildup of solids in center well of circular clarifier? 0 ❑ ❑ ❑ Are weirs level? 0 ❑ ❑ ❑ Is the site free of weir blockage? ■ ❑ ❑ ❑ Is the site free of evidence of short-circuiting? ■ ❑ ❑ ❑ Is scum removal adequate? 0 ❑ ❑ ❑ Is the site free of excessive floating sludge? 0 ❑ ❑ ❑ Is the drive unit operational? 0 ❑ ❑ ❑ Page# 4 Permit: NCO020559 Inspection Date: 06/07/2023 Owner -Facility: Henderson Water Reclamation Facility Inspection Type: Compliance Evaluation Secondary Clarifier Is the return rate acceptable (low turbulence)? Is the overflow clear of excessive solids/pin floc? Is the sludge blanket level acceptable? (Approximately'/4 of the sidewall depth) Comment: Sludge blankets were 0.25 and 0.75 foot on the day of inspection. Filtration (High Rate Tertiary) Type of operation: Is the filter media present? Is the filter surface free of clogging? Is the filter free of growth? Is the air scour operational? Is the scouring acceptable? Is the clear well free of excessive solids and filter media? Yes No NA NE ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ Yes No NA NE Down flow ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ Comment: Two of four filters were online due to low flow. Filters are backwashed once per da Disinfection - UV Yes No NA NE Are extra UV bulbs available on site? 0 ❑ ❑ ❑ Are UV bulbs clean? 0 ❑ ❑ ❑ Is UV intensity adequate? ■ ❑ ❑ ❑ Is transmittance at or above designed level? ■ ❑ ❑ ❑ Is there a backup system on site? 0 ❑ ❑ ❑ Is effluent clear and free of solids? 0 ❑ ❑ ❑ Comment: Two banks of UV in series, each with three modules. The UV units were being serviced by a contractor at the time of insDection Disinfection -Liquid Yes No NA NE Is there adequate reserve supply of disinfectant? ❑ ❑ ■ ❑ (Sodium Hypochlorite) Is pump feed system operational? ❑ ❑ ■ ❑ Is bulk storage tank containment area adequate? (free of leaks/open drains) ❑ ❑ 0 ❑ Is the level of chlorine residual acceptable? ❑ ❑ ■ ❑ Is the contact chamber free of growth, or sludge buildup? ❑ ❑ ■ ❑ Is there chlorine residual prior to de -chlorination? ❑ ❑ 0 ❑ Comment: Backup system has not been used in the past years. Page# 5 Permit: NC0020559 Owner -Facility: Inspection Date: 06/07/2023 Inspection Type: Henderson Water Reclamation Facility Compliance Evaluation De -chlorination Yes No NA NE Type of system ? Liquid Is the feed ratio proportional to chlorine amount (1 to 1)? ❑ ❑ ❑ Is storage appropriate for cylinders? ❑ ❑ 0 ❑ # Is de -chlorination substance stored away from chlorine containers? ❑ ❑ 0 ❑ Are the tablets the proper size and type? ❑ ❑ 0 ❑ Comment: Backup system has not been used in the past years. Are tablet de -chlorinators operational? ❑ ❑ ❑ Number of tubes in use? Comment: Aerobic Digester Yes No NA NE Is the capacity adequate? 0 ❑ ❑ ❑ Is the mixing adequate? 0 ❑ ❑ ❑ Is the site free of excessive foaming in the tank? ■ ❑ ❑ ❑ # Is the odor acceptable? 0 ❑ ❑ ❑ # Is tankage available for properly waste sludge? 0 ❑ ❑ ❑ Comment: The digester was about 3/4 full at the time of inspection. The one million gallon sludge holding tank has not been used in the past year. Pumps-RAS-WAS Yes No NA NE Are pumps in place? 0 ❑ ❑ ❑ Are pumps operational? 0 ❑ ❑ ❑ Are there adequate spare parts and supplies on site? ■ ❑ ❑ ❑ Comment: Three RAS-WAS pumps Solids Handling Equipment Is the equipment operational? Is the chemical feed equipment operational? Is storage adequate? Is the site free of high level of solids in filtrate from filter presses or vacuum filters? Is the site free of sludge buildup on belts and/or rollers of filter press? Is the site free of excessive moisture in belt filter press sludge cake? The facility has an approved sludge management plan? Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ Page# 6 Permit: NCO020559 Inspection Date: 06/07/2023 Solids Handling Equipment Owner -Facility: Henderson Water Reclamation Facility Inspection Type: Compliance Evaluation Comment: Screw thickener was in operation at the time of inspection Effluent Pipe Is right of way to the outfall properly maintained? Are the receiving water free of foam other than trace amounts and other debris? If effluent (diffuser pipes are required) are they operating properly? Comment: Chemical Feed Is containment adequate? Is storage adequate? Are backup pumps available? Is the site free of excessive leaking? Yes No NA NE Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ ❑ ❑ ■ ❑ Yes No NA NE ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ Comment: Facility does not feed chemicals to sustain treatment processes (except that polymers are fed to wasted sludge before being dewatered by the screw thickener Standby Power Is automatically activated standby power available? Is the generator tested by interrupting primary power source? Is the generator tested under load? Was generator tested & operational during the inspection? Do the generator(s) have adequate capacity to operate the entire wastewater site? Is there an emergency agreement with a fuel vendor for extended run on back-up power? Is the generator fuel level monitored? Comment: The generator is tested twice per month Laboratory Are field parameters performed by certified personnel or laboratory? Are all other parameters(excluding field parameters) performed by a certified lab? # Is the facility using a contract lab? # Is proper temperature set for sample storage (kept at less than or equal to 6.0 degrees Celsius)? Incubator (Fecal Coliform) set to 44.5 degrees Celsius+/- 0.2 degrees? Yes No NA NE ■ ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ ■ ❑ ❑ ❑ Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ ■ ❑ ❑ ❑ Page# 7 Permit: NCO020559 Owner -Facility: Henderson Water Reclamation Facility Inspection Date: 06/07/2023 Inspection Type: Compliance Evaluation Laboratory Yes No NA NE Incubator (BOD) set to 20.0 degrees Celsius +/- 1.0 degrees? 0 ❑ ❑ ❑ Comment: Influent Sampling Yes No NA NE # Is composite sampling flow proportional? 0 ❑ ❑ ❑ Is sample collected above side streams? 0 ❑ ❑ ❑ Is proper volume collected? ■ ❑ ❑ ❑ Is the tubing clean? 0 ❑ ❑ ❑ # Is proper temperature set for sample storage (kept at less than or equal to 6.0 0 ❑ ❑ ❑ degrees Celsius)? Is sampling performed according to the permit? 0 ❑ ❑ ❑ Comment: Effluent Sampling Yes No NA NE Is composite sampling flow proportional? 0 ❑ ❑ ❑ Is sample collected below all treatment units? 0 ❑ ❑ ❑ Is proper volume collected? ■ ❑ ❑ ❑ Is the tubing clean? 0 ❑ ❑ ❑ # Is proper temperature set for sample storage (kept at less than or equal to 6.0 ■ ❑ ❑ ❑ degrees Celsius)? Is the facility sampling performed as required by the permit (frequency, sampling type ■ ❑ ❑ ❑ representative)? Comment: Upstream / Downstream Sampling Yes No NA NE Is the facility sampling performed as required by the permit (frequency, sampling type, 0 ❑ ❑ ❑ and sampling location)? Comment: Nutrient Removal Yes No NA NE # Is total nitrogen removal required? M ❑ ❑ ❑ # Is total phosphorous removal required? 0 ❑ ❑ ❑ Type Biological # Is chemical feed required to sustain process? ❑ 0 ❑ ❑ Is nutrient removal process operating properly? M ❑ ❑ ❑ Page# 8 Permit: NCO020559 Owner -Facility: Henderson Water Reclamation Facility Inspection Date: 06/07/2023 Inspection Type: Compliance Evaluation Nutrient Removal Yes No NA NE Comment: Chemical feed is not needed to sustain process Flow Measurement - Influent Yes No NA NE # Is flow meter used for reporting? ■ ❑ ❑ ❑ Is flow meter calibrated annually? ❑ ■ ❑ ❑ Is the flow meter operational? ■ ❑ ❑ ❑ (If units are separated) Does the chart recorder match the flow meter? ❑ ❑ ■ ❑ Comment: Flow meter was last calibrated on 2/2/2022 Flow Measurement - Effluent Yes No NA NE # Is flow meter used for reporting? ■ ❑ ❑ ❑ Is flow meter calibrated annually? ❑ ■ ❑ ❑ Is the flow meter operational? ■ ❑ ❑ ❑ (If units are separated) Does the chart recorder match the flow meter? ❑ ❑ ■ ❑ Comment: Flow meter was last calibrated on 2/2/2022 Record Keeping Yes No NA NE Are records kept and maintained as required by the permit? ■ ❑ ❑ ❑ Is all required information readily available, complete and current? ■ ❑ ❑ ❑ Are all records maintained for 3 years (lab. reg. required 5 years)? ■ ❑ ❑ ❑ Are analytical results consistent with data reported on DMRs? ■ ❑ ❑ ❑ Is the chain -of -custody complete? ■ ❑ ❑ ❑ Dates, times and location of sampling ■ Name of individual performing the sampling ■ Results of analysis and calibration ■ Dates of analysis ■ Name of person performing analyses ■ Transported COCs ■ Are DMRs complete: do they include all permit parameters? ■ ❑ ❑ ❑ Has the facility submitted its annual compliance report to users and DWQ? ■ ❑ ❑ ❑ (If the facility is = or > 5 MGD permitted flow) Do they operate 24/7 with a certified ❑ ❑ ■ ❑ operator on each shift? Is the ORC visitation log available and current? ❑ ■ ❑ ❑ Page# 9 Permit: NCO020559 Inspection Date: 06/07/2023 Owner -Facility: Henderson Water Reclamation Facility Inspection Type: Compliance Evaluation Record Keeping Is the ORC certified at grade equal to or higher than the facility classification? Is the backup operator certified at one grade less or greater than the facility classification? Is a copy of the current NPDES permit available on site? Facility has copy of previous year's Annual Report on file for review? Comment: ORC and backup ORC need to keep a visitation log Yes No NA NE ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ ■ ❑ ❑ ❑ Page# 10 United States Environmental Protection Agency Form Approved. EPA Washington, D.C. 20460 OMB No. 2040-0057 Water Compliance Inspection Report Approval expires 8-31-98 Section A: National Data System Coding (i.e., PCS) Transaction Code NPDES yr/mo/day Inspection Type Inspector Fac Type 1 IN 2 u 3 I NC0020559 111 121 21/08/24 I17 18 L D I 19 I s I 201 211IIIII 111111III II III III1 I I IIIII IIIIIIIII II r6 Inspection Work Days Facility Self -Monitoring Evaluation Rating B1 QA ---------------------- Reserved ------------------- 67 I 72 I n, I 73 � I 74 79 I I I I I I I80 70 I I 71 I LL -1 I I LJ Section B: Facility Data Name and Location of Facility Inspected (For Industrial Users discharging to POTW, also include Entry Time/Date Permit Effective Date POTW name and NPDES permit Number) 10:OOAM 21/08/24 19/08/01 Henderson Water Reclamation Facility 1646 W Andrews Ave Exit Time/Date Permit Expiration Date Henderson NC 275362555 12:OOPM 21/08/24 23/03/31 Name(s) of Onsite Representative(s)/Titles(s)/Phone and Fax Number(s) Other Facility Data Darrel P Johnson//252-431-6085 / Name, Address of Responsible Official/Title/Phone and Fax Number Contacted Terrell Blackmon,PO Box 1434 Henderson NC 275361434/City Manager/252-430-5701 / No Section C: Areas Evaluated During Inspection (Check only those areas evaluated) Pretreatment Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) (See attachment summary) Name(s) and Signature(s) of Inspector(s) Agency/Office/Phone and Fax Numbers Date Cheng Zhang DWR/RRO WQ/919-791-4200/ Signature of Management Q A Reviewer Agency/Office/Phone and Fax Numbers Date EPA Form 3560-3 (Rev 9-94) Previous editions are obsolete. Page# NPDES yr/mo/day Inspection Type NCO020559 I11 12I 21/08/24 117 18 1 p I Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) Page# Permit: NC0020559 Inspection Date: 08/24/2021 Owner -Facility: Henderson Water Reclamation Facility Inspection Type: Pretreatment Compliance Yes No NA NE Page# NH3/TRC WLA Calculations Henderson WRF Permit No. NC0020559 Prepared By: Gary Perlmutter Enter Design Flow (MGD): 4.14 Enter s7Q10 (cfs): 0.2 Enter w7Q10 (cfs): 0.4 Total Residual Chlorine (TRC) Ammonia (Summer) Daily Maximum Limit (ug/1) Monthly Average Limit (mg NH3-N/1) s7Q10 (CFS) 0.2 s7Q10 (CFS) 0.2 DESIGN FLOW (MGD) 4.14 DESIGN FLOW (MGD) 4.14 DESIGN FLOW (CFS) 6.417 DESIGN FLOW (CFS) 6.417 STREAM STD (UG/L) 17.0 STREAM STD (MG/L) 1.0 Upstream Bkgd (ug/1) 0 Upstream Bkgd (mg/1) 0.22 IWC (%) 96.98 IWC (%) 96.98 Allowable Conc. (ug/1) 18 Allowable Conc. (mg/1) 1.0 Ammonia (Winter) Monthly Average Limit (mg NH3-N/1) Fecal Coliform w7Q10 (CFS) 0.4 Monthly Average Limit: 200/100ml DESIGN FLOW (MGD) 4.14 (If DF >331; Monitor) DESIGN FLOW (CFS) 6.417 (If DF<331; Limit) STREAM STD (MG/L) 1.8 Dilution Factor (DF) 1.03 Upstream Bkgd (mg/1) 0.22 IWC (%) 94.13 Allowable Conc. (mg/1) 1.9 Total Residual Chlorine 1. Cap Daily Max limit at 28 ug/I to protect for acute toxicity Ammonia (as NH3-N) 1. If Allowable Conc > 35 mg/l, Monitor Only 2. Monthly Avg limit x 3 = Weekly Avg limit (Municipals); capped at 35 mg/I 3. Monthly Avg limit x 5 = Daily Max limit (Non-Munis); capped at 35 mg/I Fecal Coliform 1. Monthly Avg limit x 2 = 400/100 ml = Weekly Avg limit (Municipals) = Daily Max limit (Non -Muni) NH3/TRC WLA Calculations Henderson WRF Permit No. NC0020559 Prepared By: Gary Perlmutter Enter Design Flow (MGD): 6 Enter s7Q10 (cfs): 0.2 Enter w7Q10 (cfs): 0.4 Total Residual Chlorine (TRC) Daily Maximum Limit (ug/1) Ammonia (Summer) Monthly Average Limit (mg NH3-N/1) s7Q10 (CFS) 0.2 s7Q10 (CFS) 0.2 DESIGN FLOW (MGD) 6 DESIGN FLOW (MGD) 6 DESIGN FLOW (CFS) 9.3 DESIGN FLOW (CFS) 9.3 STREAM STD (UG/L) 17.0 STREAM STD (MG/L) 1.0 Upstream Bkgd (ug/1) 0 Upstream Bkgd (mg/1) 0.22 IWC (%) 97.89 IWC (%) 97.89 Allowable Conc. (ug/1) 17 Allowable Conc. (mg/1) 1.0 Ammonia (Winter) Monthly Average Limit (mg NH3-N/1) Fecal Coliform w7Q10 (CFS) 0.4 Monthly Average Limit: 200/100mi DESIGN FLOW (MGD) 6 (If DF >331; Monitor) DESIGN FLOW (CFS) 9.3 (If DF<331; Limit) STREAM STD (MG/L) 1.8 Dilution Factor (DF) 1.02 Upstream Bkgd (mg/1) 0.22 IWC (%) 95.88 Allowable Conc. (mg/1) 1.9 Total Residual Chlorine 1. Cap Daily Max limit at 28 ug/l to protect for acute toxicity Ammonia (as NH3-N) 1. If Allowable Conc > 35 mg/l, Monitor Only 2. Monthly Avg limit x 3 = Weekly Avg limit (Municipals); capped at 35 mg/I 3. Monthly Avg limit x 5 = Daily Max limit (Non-Munis); capped at 35 mg/l Fecal Coliform 1. Monthly Avg limit x 2 = 400/100 ml = Weekly Avg limit (Municipals) = Daily Max limit (Non -Muni) Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 REQUIRED DATA ENTRY Table 1. Proiect Information Facility Name WWTP/WTP Class NPDES Permit Outfall Flow, Qw (MGD) Receiving Stream HUC Number Stream Class ❑ CHECK IF HQW OR ORW WQS Henderson WRF Grade IV NCO020559 001 4.140 Nutbush Creek 03010102 C ❑ Apply WS Hardness WQC 7Q10s (cfs) 7Q10w (cfs) 30Q2 (cfs) QA (cfs) 1Q10s (cfs) 0.20 0.40 0.50 3.50 0.17 _Effluent Hardness Upstream Hardness Combined Hardness Chronic Combined Hardness Acute 51 mg/L (Avg) 67.17 mg/L (Avg) I ------- 51.49 mg/L I 51.42 mg/L — — — — - 'Fe rmittee-submitted DMRs and PPAs. Data Source(s) ❑ CHECK TO APPLY MODEL Par01 Par02 Par03 Par04 Par05 Par06111111 Par07 Par08 Par09 Par10 Par11 Par12 Par13 Par14 Par15 Par16 Par17 Par18 Par19 Par20 Par21 Par22 Par23 Par24 Table 2. Parameters of Concern Name w4s Type Chronic ModIer Acute PQL Units Arsenic Aquactic Life C 150 FW 340 ug/L Arsenic Human Health Water Supply C 10 HH/WS N/A ug/L Beryllium Aquatic Life NC 6.5 FW 65 ug/L Cadmium Aquatic Life NC 1.0184 FW 6.0785 ug/L Chlorides Aquatic Life NC 230 FW Chlorinated Phenolic Compounds Water Supply NC 1 A ug/L Total Phenolic Compounds Aquatic Life NC 300 A ug/L Chromium III Aquatic Life NC 212.7536 FW 1633.7075 ug/L Chromium VI Aquatic Life NC 11 FW 16 pg/L Chromium, Total Aquatic Life NC N/A FW N/A pg/L Copper Aquatic Life NC 14.6110 FW 20.6585 ug/L Cyanide Aquatic Life NC 5 FW 22 10 ug/L Fluoride Aquatic Life NC 1,800 FW ug/L Lead Aquatic Life NC 6.5970 FW 169.0311 ug/L Mercury Aquatic Life NC 12 FW 0.5 ng/L Molybdenum Human Health NC 2000 HH ug/L Nickel Aquatic Life NC 68.6058 FW 616.9605 pg/L Nickel Water Supply NC 25.0000 WS N/A pg/L Selenium Aquatic Life NC 5 FW 56 ug/L Silver Aquatic Life NC 0.06 FW 1.0245 ug/L Zinc Aquatic Life NC 233.7499 FW 231.5808 ug/L 20559 Freshwater RPA 2023, input 10/13/2023 H1 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 REASONABLE POTENTIAL ANALYSIS H2 Use "PASTE SPECIAL Use "PASTE SPECIAL Effluent Hardness Values" then "COPY• Upstream Hardness Values" then "COPY" . Maximum data . Maximum data points = 58 points = 58 Date Data BDL=1/2DL 3/12/2019 52 52 3/13/2019 52 52 3/14/2019 56 56 3/15/2019 60 60 3/18/2019 64 64 7/11/2019 52 52 8/7/2019 56 56 10/10/2019 52 52 1/9/2020 56 56 4/23/2020 56 56 7/16/2020 60 60 10/8/2020 44 44 1/14/2021 52 52 2/18/2021 52 52 3/11/2021 64 64 4/8/2021 64 64 5/5/2021 56 56 6/9/2021 40 40 7/15/2021 44 44 8/4/2021 40 40 9/8/2021 44 44 10/7/2021 48 48 11 /3/2021 44 44 12/1/2021 48 48 1/13/2022 44 44 4/7/2022 44 44 7/14/2022 40 40 7/21/2022 40 40 10/5/2022 60 60 1/10/2023 48 48 4/5/2023 48 48 7/5/2023 52 52 Results Std Dev. 7.3966 Mean 51.0000 C.V. 0.1450 n 32 10th Per value 40.40 mg/L Average Value 51.00 mg/L Max. Value 64.00 mg/L Date Data BDL=1/2DL Results 1 3/12/2019 58 58 Std Dev. 18.1124 2 3/13/2019 72 72 Mean 67.1739 3 3/14/2019 76 76 C.V. 0.2696 4 3/15/2019 80 80 n 23 5 3/18/2019 80 80 10th Per value 52.80 mg/L 6 7/9/2019 64 64 Average Value 67.17 mg/L 7 8/6/2019 82 82 Max. Value 84.00 mg/L 8 10/1/2019 72 72 9 1/7/2020 68 68 10 4/7/2020 80 80 11 7/7/2020 84 84 12 10/6/2020 84 84 13 1/5/2021 52 52 14 4/6/2021 76 76 15 7/6/2021 72 72 16 10/20/2021 76 76 17 1/6/2022 60 60 18 4/5/2022 1 1 19 7/12/2022 44 44 20 10/12/2022 80 80 21 1/10/2023 56 56 22 4/4/2023 68 68 23 7/18/2023 60 60 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 20559 Freshwater RPA 2023, data -3- 10/13/2023 REASONABLE POTENTIAL ANALYSIS Par01 & Par02 Date Data 1 4/11/2019 < 2 7/11/2019 < 3 8/7/2019 < 4 10/10/2019 < 5 1 /9/2020 < 6 4/23/2020 < 7 7/16/2020 < 8 10/8/2020 < 9 1/14/2021 < 10 2/18/2021 < 11 3/11/2021 < 12 4/8/2021 < 13 5/5/2021 < 14 6/9/2021 < 15 7/15/2021 < 16 8/4/2021 < 17 9/8/2021 < 18 10/7/2021 < 19 11 /3/2021 < 20 12/1/2021 < 21 1/13/2022 < 22 4/7/2022 < 23 7/14/2022 < 24 7/21/2022 < 25 4/5/2023 < 26 7/5/2023 < 27 28 29 30 . 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Arsenic BDL=1/2DL Results 2 1 Std Dev. 2 1 Mean 2 1 C.V. 2 1 n 2 1 2 1 Mult Factor = 2 1 Max. Value 2 1 Max. Fred Cw 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 Use "PASTE SPECIAL Par03 Values" then "COPY" . Maximum data points = 58 1.0000 0.0000 26 1.00 1.0 ug/L 1.0 ug/L Use "PASTE SPECIAL Beryllium Values" then "COPY" . Maximum data points = 58 Date Data BDL=1/2DL Results 1 1/9/2020 < 0.5 0.25 Std Dev. 2.7424 2 4/8/2021 < 0.5 0.25 Mean 1.8333 3 7/21/2022 < 10 5 C.V. (default) 0.6000 4 n 3 5 6 Mult Factor = 3.00 7 Max. Value 5.00 ug/L 8 Max. Fred Cw 15.00 ug/L 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 -4- 20559 Freshwater RPA 2023, data 10/13/2023 REASONABLE POTENTIAL ANALYSIS Par04 Cadmium Date Data BDL=1/2DL Results 1 4/11/2019 < 0.15 0.075 Std Dev. 2 7/11/2019 < 0.15 0.075 Mean 3 8/7/2019 < 0.15 0.075 C.V. 4 10/10/2019 < 0.15 0.075 n 5 1 /9/2020 < 0.15 0.075 6 4/23/2020 < 0.15 0.075 Mult Factor = 7 7/16/2020 < 0.15 0.075 Max. Value 8 10/8/2020 < 0.15 0.075 Max. Fred Cw 9 1/14/2021 < 0.15 0.075 10 2/18/2021 < 0.15 0.075 11 3/11/2021 < 0.15 0.075 12 4/8/2021 < 0.15 0.075 13 5/5/2021 < 0.15 0.075 14 6/9/2021 < 0.15 0.075 15 7/15/2021 < 0.15 0.075 16 8/4/2021 < 0.15 0.075 17 9/8/2021 < 0.15 0.075 18 10/7/2021 < 0.15 0.075 19 11 /3/2021 < 0.15 0.075 20 12/1/2021 < 0.15 0.075 21 1/13/2022 < 0.15 0.075 22 4/7/2022 < 0.15 0.075 23 7/14/2022 < 0.15 0.075 24 7/21/2022 < 0.15 0.075 25 10/5/2022 < 0.15 0.075 26 1/10/2023 < 0.15 0.075 27 4/5/2023 < 0.15 0.075 28 7/5/2023 < 0.15 0.075 29 3 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Pdr05 Values" then "COPY" . Maximum data points = 58 0.0750 0.0000 28 1.00 0.075 ug/L 0.075 ug/L 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Chlorides Date Data BDL=1/2DL Results Std Dev. Mean C.V. n Mult Factor = Max. Value Max. Fred Cw Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 NO DATA NO DATA 0 N/A N/A mg/L N/A mg/L -5- 20559 Freshwater RPA 2023, data 10/13/2023 REASONABLE POTENTIAL ANALYSIS Par06 Chlorinated Phenolic Compounds Use "PASTE SPECIAL valves" imthenum •copydata . Max Par07 Total Phenolic Compounds points = 58 Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results 1 Std Dev. NO DATA 1 1/9/2020 11 11 Std Dev. 2 Mean NO DATA 2 4/8/2021 < 10 5 Mean 3 C.V. NO DATA 3 7/21/2022 19 19 C.V. (default) 4 n 0 4 n 5 5 6 Mult Factor = N/A 6 Mult Factor = 7 Max. Value N/A ug/L 7 Max. Value 8 Max. Fred Cw N/A ug/L 8 Max. Fred Cw 9 9 10 10 11 11 12 12 13 13 14 14 15 15 16 16 17 17 18 18 19 19 20 20 21 21 22 22 23 23 24 24 25 25 26 26 27 27 28 28 29 29 30 30 31 31 32 32 33 33 34 34 35 35 36 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 11.6667 0.6000 3 3.00 19.0 ug/L 57.0 ug/L 20559 Freshwater RPA 2023, data -6- 10/13/2023 REASONABLE POTENTIAL ANALYSIS Par08 Chromium III Date Data BDL=1/2DL Results 1 Std Dev. 2 Mean 3 C.V. 4 n 5 6 Mult Factor = 7 Max. Value 8 Max. Fred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Pdr09 Use "PASTE SPECIAL Values" then "COPY" Chromium VI . Maximum data points = 58 Date Data BDL=1/2DL Results NO DATA 1 Std Dev. NO DATA 2 Mean NO DATA 3 C.V. 0 4 n 5 N/A 6 Mult Factor = N/A Ng/L 7 Max. Value N/A Ng/L 8 Max. Fred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY' . Maximum data points = 58 NO DATA NO DATA NO DATA 0 N/A N/A Ng/L N/A Ng/L 20559 Freshwater RPA 2023, data -7- 10/13/2023 Par10 Date Data 1 4/11/2019 < 2 7/11/2019 < 3 8/7/2019 < 4 10/10/2019 < 5 1 /9/2020 < 6 4/23/2020 < 7 7/16/2020 < 8 10/8/2020 < 9 1/14/2021 < 10 2/18/2021 < 11 3/11/2021 < 12 4/8/2021 < 13 5/5/2021 < 14 6/9/2021 < 15 7/15/2021 < 16 8/4/2021 < 17 9/8/2021 < 18 10/7/2021 < 19 11 /3/2021 < 20 12/1/2021 < 21 1/13/2022 < 22 4/7/2022 < 23 7/14/2022 < 24 7/21/2022 < 25 4/5/2023 < 26 7/5/2023 < 27 28 29 30 . 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 REASONABLE POTENTIAL ANALYSIS Pall Use "PASTE SPECIAL Use "PASTE SPECIAL Chromium, Total Values" then "COPY" Copper Values" then "COPY" . Maximum data . Maximum data points = 58 points = 58 BDL=1/2DL Results 2 1 Std Dev. 2 1 Mean 2 1 C.V. 2 1 n 2 1 2 1 Mult Factor = 2 1 Max. Value 2 1 Max. Fred Cw 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 1.0000 0.0000 26 1.00 1.0 Ng/L 1.0 Ng/L Date Data BDL=1/2DL Results 1 4/11/2019 2 2 Std Dev. 0.8400 2 7/11/2019 3 3 Mean 1.6653 3 8/7/2019 3 3 C.V. 0.5044 4 9/4/2019 4 4 n 49 5 10/10/2019 3 3 6 11/6/2019 3 3 Mult Factor = 1.04 7 12/4/2019 2 2 Max. Value 4.00 ug/L 8 1/9/2020 2 2 Max. Fred Cw 4.16 ug/L 9 2/5/2020 2 2 10 3/4/2020 2 2 11 4/23/2020 2 2 12 5/6/2020 < 2 1 13 6/3/2020 < 2 1 14 7/16/2020 2 2 15 8/5/2020 2 2 16 9/2/2020 3 3 17 10/8/2020 < 2 1 18 11/4/2020 < 2 1 19 12/2/2020 < 2 1 20 1/14/2021 < 2 1 21 2/18/2021 < 2 1 22 3/11/2021 2 2 23 4/8/2021 < 2 1 24 5/5/2021 < 2 1 25 6/9/2021 < 2 1 26 7/15/2021 < 2 1 27 8/4/2021 < 2 1 28 9/8/2021 < 2 1 < 2 1 F10/7/2021 11/3/2021 < 2 1 12/1/2021 < 2 1 32 1/13/2022 < 2 1 33 2/2/2022 < 2 1 34 3/2/2022 < 2 1 35 4/7/2022 2.6 2.6 36 5/4/2022 2 2 37 6/8/2022 2 2 38 7/14/2022 < 2 1 39 7/21/2022 < 2 1 40 10/5/2022 < 2 1 41 11/2/2022 < 2 1 42 12/7/2022 3 3 43 1/10/2023 2 2 44 2/8/2023 3 3 45 3/8/2023 3 3 46 4/5/2023 < 2 1 47 5/3/2023 < 2 1 48 6/7/2023 < 2 1 49 7/5/2023 < 2 1 50 51 52 53 54 55 56 57 58 20559 Freshwater RPA 2023, data -8- 10/13/2023 REASONABLE POTENTIAL ANALYSIS Par12 Par13 Use "PASTE SPECIAL Use "PASTE SPECIAL Cyanide Values" then "COPY• Fluoride Values" then "COPY" . Maximum data . Maximum data points = 58 points = 58 Date Data BDL=1/2DL Results Date Data BDL=1/2DL Results 1 1/9/2020 7 5 Std Dev. 0.0000 1 Std Dev. NO DATA 2 4/8/2021 < 5 5 Mean 5.00 2 Mean NO DATA 3 7/21/2022 < 5 5 C.V. (default) 0.6000 3 C.V. NO DATA 4 n 3 4 n 0 5 5 6 Mult Factor = 3.00 6 Mult Factor = N/A 7 Max. Value 5.0 ug/L 7 Max. Value N/A ug/L 8 Max. Fred Cw 15.0 ug/L 8 Max. Fred Cw N/A ug/L 9 9 10 10 11 11 12 12 13 13 14 14 15 15 16 16 17 17 18 18 19 19 20 20 21 21 22 22 23 23 24 24 25 25 26 26 27 27 28 28 29 29 30 30 31 31 32 32 33 33 34 34 35 35 36 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 58 20559 Freshwater RPA 2023, data -9- 10/13/2023 REASONABLE POTENTIAL ANALYSIS Par14 Lead Date BDL=1/2DL Results 1 4/11/2019 < 0.5 0.25 Std Dev. 2 7/11/2019 < 0.5 0.25 Mean 3 8/7/2019 < 0.5 0.25 C.V. 4 10/10/2019 < 0.5 0.25 n 5 1/9/2020 < 0.5 0.25 6 4/23/2020 < 0.5 0.25 Mult Factor = 7 7/16/2020 < 0.5 0.25 Max. Value 8 10/8/2020 < 0.5 0.25 Max. Fred Cw 9 1/14/2021 < 0.5 0.25 10 2/18/2021 < 0.5 0.25 11 3/11/2021 < 0.5 0.25 12 4/8/2021 < 0.5 0.25 13 5/5/2021 < 0.5 0.25 14 6/9/2021 < 0.5 0.25 15 7/15/2021 < 0.5 0.25 16 8/4/2021 < 0.5 0.25 17 9/8/2021 < 0.5 0.25 18 10/7/2021 < 0.5 0.25 19 11/3/2021 < 0.5 0.25 20 12/1/2021 < 0.5 0.25 21 1/13/2022 < 0.5 0.25 22 4/7/2022 < 0.5 0.25 23 7/14/2022 < 0.5 0.25 24 7/21/2022 < 0.5 0.25 25 4/5/2023 < 0.5 0.25 26 7/5/2023 < 0.5 0.25 27 28 29 30 . 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Par15 Values" then "COPY" . Maximum data points = 58 0.2500 0.0000 26 1.00 0.250 ug/L 0.250 ug/L 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Mercury Values" then "COPY" . Maximum data points = 58 Date Data BDL=1/2DL Results Std Dev. NO DATA Mean NO DATA C.V. NO DATA n 0 Mult Factor = N/A Max. Value N/A ng/L Max. Fred Cw N/A ng/L -10- 20559 Freshwater RPA 2023, data 10/13/2023 REASONABLE POTENTIAL ANALYSIS Par16 Date Data 1 4/11/2019 2 7/11/2019 3 8/7/2019 4 10/10/2019 5 1 /9/2020 < 6 4/23/2020 < 7 7/16/2020 < 8 10/8/2020 < 9 1/14/2021 < 10 2/18/2021 < 11 3/11/2021 < 12 4/8/2021 13 5/5/2021 < 14 6/9/2021 15 7/15/2021 < 16 8/4/2021 < 17 9/8/2021 < 18 10/7/2021 < 19 11 /3/2021 < 20 12/1/2021 < 21 1/13/2022 < 22 4/7/2022 < 23 7/14/2022 24 7/21/2022 < 25 4/5/2023 < 26 7/5/2023 < 27 28 29 30 . 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Molybdenum BDL=1/2DL Results 4 4 Std Dev. 6 6 Mean 3 3 C.V. 2 2 n 2 1 2 1 Mult Factor = 2 1 Max. Value 2 1 Max. Fred Cw 2 1 2 1 2 1 9 9 2 1 2 2 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 3 3 2 1 2 1 2 1 Use "PASTE SPECIAL Par17 & Pdr18 Values" then "COPY" Nickel . Maximum data points = 58 1.8462 1.0242 26 1.42 9.0 ug/L 12.8 ug/L Date Data BDL=1/2DL Results 1 4/11/2019 2.4 2.4 Std Dev. 2 7/11/2019 4.5 4.5 Mean 3 8/7/2019 3.9 3.9 C.V. 4 10/10/2019 4.6 4.6 n 5 1 /9/2020 2 2 6 4/23/2020 2.6 2.6 Mult Factor = 7 7/16/2020 4.1 4.1 Max. Value 8 10/8/2020 3.5 3.5 Max. Fred Cw 9 1/14/2021 3.1 3.1 10 2/18/2021 2.6 2.6 11 3/11/2021 6.6 6.6 12 4/8/2021 8.5 8.5 13 5/5/2021 4.6 4.6 14 6/9/2021 5 5 15 7/15/2021 4.2 4.2 16 8/4/2021 4.5 4.5 17 9/8/2021 4.6 4.6 18 10/7/2021 4.5 4.5 19 11 /3/2021 5 5 20 12/1/2021 2.9 2.9 21 1/13/2022 3 3 22 4/7/2022 2.7 2.7 23 7/14/2022 3.5 3.5 24 7/21/2022 3 3 25 4/5/2023 2.5 2.5 26 5/3/2023 2.4 2.4 27 6/7/2023 3.7 3.7 28 7/5/2023 4.3 4.3 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values " then "COPY" . Maximum data points = 58 3.8857 0.3579 28 1.14 8.5 Ng/L 9.7 Ng/L 20559 Freshwater RPA 2023, data 11 - 10/13/2023 REASONABLE POTENTIAL ANALYSIS Par19 Date Data 1 4/11/2019 < 2 7/11/2019 < 3 8/7/2019 < 4 10/10/2019 < 5 1 /9/2020 < 6 4/23/2020 < 7 7/16/2020 < 8 10/8/2020 < 9 1/14/2021 < 10 2/18/2021 < 11 3/11/2021 < 12 4/8/2021 < 13 5/5/2021 < 14 6/9/2021 < 15 7/15/2021 < 16 8/4/2021 < 17 9/8/2021 < 18 10/7/2021 < 19 11 /3/2021 < 20 12/1/2021 < 21 1/13/2022 < 22 4/7/2022 < 23 7/14/2022 < 24 7/21/2022 < 25 10/5/2022 < 26 1/10/2023 < 27 4/5/2023 < 28 7/5/2023 < 29 3 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Selenium BDL=1/2DL Results 0.5 Std Dev. 0.5 Mean 0.5 C.V. 0.5 n 0.5 0.5 Mult Factor = 0.5 Max. Value 0.5 Max. Fred Cw 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Use "PASTE SPECIAL Par20 Values" then "COPY" . Maximum data points = 58 0.5000 0.0000 28 1.00 0.5 ug/L 0.5 ug/L Use "PASTE SPECIAL Silver Values" then "COPY" . Maximum data points = 58 Date Data BDL=1/2DL Results 1 4/11/2019 < 0.5 0.25 Std Dev. 0.4252 2 7/11/2019 < 0.5 0.25 Mean 0.3304 3 8/7/2019 < 0.5 0.25 C.V. 1.2871 4 10/10/2019 < 0.5 0.25 n 28 5 1/9/2020 < 0.5 0.25 6 4/23/2020 < 0.5 0.25 Mult Factor = 1.44 7 7/16/2020 < 0.5 0.25 Max. Value 2.500 ug/L 8 10/8/2020 < 0.5 0.25 Max. Fred Cw 3.600 ug/L 9 1/14/2021 < 0.5 0.25 10 2/18/2021 < 0.5 0.25 11 3/11/2021 < 0.5 0.25 12 4/8/2021 < 0.5 0.25 13 5/5/2021 < 0.5 0.25 14 6/9/2021 < 0.5 0.25 15 7/15/2021 < 0.5 0.25 16 8/4/2021 < 0.5 0.25 17 9/8/2021 < 0.5 0.25 18 10/7/2021 < 0.5 0.25 19 11/3/2021 < 0.5 0.25 20 12/1/2021 < 0.5 0.25 21 1/13/2022 < 0.5 0.25 22 4/7/2022 < 0.5 0.25 23 7/14/2022 < 0.5 0.25 24 7/21/2022 < 0.5 0.25 25 10/5/2022 < 0.5 0.25 26 1/10/2023 < 5 2.5 27 4/5/2023 < 0.5 0.25 28 7/5/2023 < 0.5 0.25 290 0.31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 -12- 20559 Freshwater RPA 2023, data 10/13/2023 REASONABLE POTENTIAL ANALYSIS Par21 Zinc Date Data BDL=1/2DL Results 1 1/6/2021 275 275 Std Dev. 2 1/14/2021 518 518 Mean 3 1/20/2021 263 263 C.V. 4 1/27/2021 258 258 n 5 2/3/2021 296 296 6 2/10/2021 205 205 Mult Factor = 7 2/18/2021 128 128 Max. Value 8 2/24/2021 96 96 Max. Fred Cw 9 3/3/2021 195 195 10 3/11/2021 193 193 11 3/17/2021 170 170 12 3/24/2021 159 159 13 3/31/2021 150 150 14 4/8/2021 145 145 15 4/14/2021 121 121 16 4/21/2021 166 166 17 4/28/2021 151 151 18 5/5/2021 139 139 19 5/12/2021 190 190 20 5/19/2021 245 245 21 5/26/2021 181 181 22 6/2/2021 183 183 23 6/9/2021 194 194 24 6/16/2021 178 178 25 6/23/2021 187 187 26 6/30/2021 179 179 27 7/7/2021 256 256 28 7/15/2021 194 194 29 7/21/2021 220 220 30 7/28/2021 184 184 31 8/4/2021 168 168 32 8/11/2021 206 206 33 8/18/2021 276 276 34 8/25/2021 164 164 35 9/1/2021 151 151 36 9/8/2021 157 157 37 9/15/2021 149 149 38 9/22/2021 132 132 39 9/29/2021 130 130 40 10/7/2021 121 121 41 10/13/2021 117 117 42 10/20/2021 108 108 43 10/27/2021 88 88 44 11/3/2021 83 83 45 12/1 /2021 127 127 46 1/13/2022 120 120 47 4/7/2022 73 73 48 7/14/2022 43 43 49 7/21/2022 29 29 50 4/5/2023 35 35 51 52 7/5/2023 31 31 53 54 55 56 57 58 Use "PASTE SPECIAL Par22 Values" then "COPY" . Maximum data points = 58 167.1961 0.4813 51 1.03 518.0 ug/L 533.5 ug/L 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL O Values" then "COPY" . Maximum data points = 58 Date Data BDL=1/2DL Results Std Dev. NO DATA Mean NO DATA C.V. NO DATA n 0 Mult Factor = N/A Max. Value N/A Max. Fred Cw N/A -13- 20559 Freshwater RPA 2023, data 10/13/2023 Henderson WRF - Outfall 001 NCO020559 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators Qw = 4.14 MGD MAXIMUM Qw (MGD) = 4.1400 1Q10S (cfs) = 0.17 7Q10S (cfs) = 0.20 7Q10W (cfs) = 0.40 30Q2 (cfs) = 0.50 Avg. Stream Flow, QA (cfs) = 3.50 Receiving Stream: Nutbush Creek HUC 03010102 DATA POINTS = 58 WWTP/WTP Class: Grade IV IWC% @ 1Q10S = 97.41915895 IWC% @ 7Q10S = 96.97748224 IWC% @ 7Q10W = 94.13231627 IWC% @ 30Q2 = 92.7714327 rW%C @ QA = 64.70706867 Stream Class: C COMBINED HARDNESS (mg/L) Acute = 51.42 mg/L Chronic = 51.49 mg/L PARAMETER NC STANDARDS OR EPA CRITERIA Y) REASONABLE POTENTIAL RESULTS RECOMMENDED ACTION TYPE J a z Applied Chronic Acute n # Det. Max Pred Cw Allowable Cw Standard Acute (FW): 349.0 Arsenic C 150 FW(7Q10s) 340 ug L - - - - 26 0 1.0 Chronic (FW): 154.7 Max MDL = 2 Arsenic C 10 HH/WS(Qavg) ug/L NO DETECTS Chronic (HH): 15.5 No detects - no monitoring or limits required Max MDL = 2 Acute: 66.72 Beryllium NC 6.5 FW(7Q10s) 65 ug L 3 0 15.00 Note: n 5 9 C.V. (default) Chronic: 6.70 No detects - no monitoring or limits required Limited data set NO DETECTS Max MDL = 10 Acute: 6.240 Cadmium NC 1.0184 FW(7Q10s) 6.0785 ug/L 28 0 0.075 Chronic: 1.050 No detects - no monitoring or limits required NO DETECTS Max MDL = 0.15 Acute: NO WQS Chlorides NC 230 FW(7Q10s) mg;L 0 0 N/A Chronic:----- 237.2 Acute: NO WQS Chlorinated Phenolic Compounds NC 1 A(30Q2) ug/L 0 0 N/A ------------------------------ Chronic:----- 1.1 Acute: NO WQS Total Phenolic Compounds NC 300 A(30Q2) ug/L 3 2 57.0 Note: n 5 9 C.V. (default) Chronic: 323.4 No RP for limited dataset (n<8 samples). No Limited data set No value > Allowable Cw monitoring or limits required Acute: 1,677.0 Chromium III NC 212.7536 FW(7Q10s) 1633.7075 µg/L 0 0 N/A Chronic:----- 219.4 Acute: 16.4 Chromium VI NC 11 FW(7Q10s) 16 µg L 0 0 N/A Chronic:----- 11.3 ------------------------------ Chromium, Total NC µg/L 26 0 1.0 Max reported value = 1 No detects - no monitoring or limits required NO DETECTS Max MDL = 2 20559 Freshwater RPA 2023, rpa Page 14 of 15 10/13/2023 Henderson WRF - Outfall 001 NCO020559 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators Qw = 4.14 MGD Acute: 21.21 Copper NC 14.6110 FW(7Q10s) 20.6585 ug/L 49 22 4.16 Chronic: 15.07 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute: 22.6 Cyanide NC 5 FW(7QlOs) 22 10 ug/L 3 1 15.0 Note: n < 9 C.V. (default) Chronic: 5.2 All values < 10 considered compliant; no monitoring Limited data set No value > Allowable Cw or limits required Acute: NO WQS Fluoride NC 1800 FW(7Q10s) ug/L 0 0 N/A Chronic:-----1,856.1 ----------------------------- Acute: 173.509 Lead NC 6.5970 FW(7QIOs) 169.0311 ug/L 26 0 0.250 Chronic: 6.803 No detects - no monitoring or limits required NO DETECTS Max MDL = 0.5 Acute: NO WQS Mercury NC 12 FW(7Q10s) 0.5 ng/L 0 0 N/A --- ------------------------- Chronic:----- 12.4 Acute: NO WQS Molybdenum NC 2000 HH(7QlOs) ug/L 26 7 12.8 Chronic: 2,062.3 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute (FW): 633.3 Nickel NC 68.6058 FW(7Q10s) 616.9605 µg/L 28 28 9.7 Chronic (FW): 70.7 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw ------------------------------ Monitoring required Nickel NC 25.0000 WS(7Q10s) µg/L Chronic (WS): 25.8 No value > Allowable Cw Acute: 57.5 Selenium NC 5 FW(7Q10s) 56 ug/L 28 0 0.5 _ _ _ _ _ _ _ _ Chronic: 5.2 _ _ _ _ _ _ _ _ _ _ _ _ No detects - no monitoring or limits required NO DETECTS Max MDL = 1 Acute: 1.052 Silver NC 0.06 FW(7Q10s) 1.0245 ug/L 28 0 3.600 Chronic: 0.062 All data < 0.5 ug/L except for one value of 5.8 ug/L on NO DETECTS Max MDL = 5 6/7/2021 Acute: 237.7 Zinc NC 233.7499 FW(7QIOs) 231.5808 ug/L 51 51 533.5 Chronic: 241.0 RP shown - apply Monthly Monitoring with Limit 8 values > Allowable Cw Acute: 0 0 N/A Acute: 0 0 N/A Chronic: 20559 Freshwater RPA 2023, rpa Page 15 of 15 10/13/2023 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 REQUIRED DATA ENTRY Table 1. Proiect Information Facility Name WWTP/WTP Class NPDES Permit Outfall Flow, Qw (MGD) Receiving Stream HUC Number Stream Class ❑ CHECK IF HQW OR ORW WQS Henderson WRF Grade IV NCO020559 001 6.000 Nutbush Creek 03010102 C ❑ Apply WS Hardness WQC 7Q10s (cfs) 7Q10w (cfs) 30Q2 (cfs) QA (cfs) 1Q10s (cfs) 0.20 0.40 0.50 3.50 0.17 JL _Effluent Hardness Upstream Hardness Combined Hardness Chronic Combined Hardness Acute 51 mg/L (Avg) 67.17 mg/L (Avg) I ------- 51.34 mg/L I 51.29 mg/L — — — — - 'Fe rmittee-submitted DMRs and PPAs. Data Source(s) ❑ CHECK TO APPLY MODEL Par01 Par02 Par03 Par04 Par05 Par06111111 Par07 Par08 Par09 Par10 Par11 Par12 Par13 Par14 Par15 Par16 Par17 Par18 Par19 Par20 Par21 Par22 Par23 Par24 Table 2. Parameters of Concern Name w4s Type Chronic ModIer Acute PQL Units Arsenic Aquactic Life C 150 FW 340 ug/L Arsenic Human Health Water Supply C 10 HH/WS N/A ug/L Beryllium Aquatic Life NC 6.5 FW 65 ug/L Cadmium Aquatic Life NC 1.0162 FW 6.0654 ug/L Chlorides Aquatic Life NC 230 FW Chlorinated Phenolic Compounds Water Supply NC 1 A ug/L Total Phenolic Compounds Aquatic Life NC 300 A ug/L Chromium III Aquatic Life NC 212.2514 FW 1630.3999 ug/L Chromium VI Aquatic Life NC 11 FW 16 pg/L Chromium, Total Aquatic Life NC N/A FW N/A pg/L Copper Aquatic Life NC 14.5750 FW 20.6104 ug/L Cyanide Aquatic Life NC 5 FW 22 10 ug/L Fluoride Aquatic Life NC 1,800 FW ug/L Lead Aquatic Life NC 6.5760 FW 168.5679 ug/L Mercury Aquatic Life NC 12 FW 0.5 ng/L Molybdenum Human Health NC 2000 HH ug/L Nickel Aquatic Life NC 68.4385 FW 615.6702 pg/L Nickel Water Supply NC 25.0000 WS N/A pg/L Selenium Aquatic Life NC 5 FW 56 ug/L Silver Aquatic Life NC 0.06 FW 1.0202 ug/L Zinc Aquatic Life NC 233.1791 FW 231.0957 ug/L 20559 Freshwater RPA 2023, input 10/13/2023 Henderson WRF - Outfall 001 NCO020559 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators Qw = 6 MGD MAXIMUM Qw (MGD) = 6.0000 1Q10S (cfs) = 0.17 7Q10S (cfs) = 0.20 7Q10W (cfs) = 0.40 30Q2 (cfs) = 0.50 Avg. Stream Flow, QA (cfs) = 3.50 Receiving Stream: Nutbush Creek HUC 03010102 DATA POINTS = 58 WWTP/WTP Class: Grade IV IWC% @ 1Q10S = 98.20485744 IWC% @ 7Q10S = 97.89473684 IWC% @ 7Q10W = 95.87628866 IWC% @ 30Q2 = 94.89795918 rW%C @ QA = 72.65625 Stream Class: C COMBINED HARDNESS (mg/L) Acute = 51.29 mg/L Chronic = 51.34 mg/L PARAMETER NC STANDARDS OR EPA CRITERIA Y) REASONABLE POTENTIAL RESULTS RECOMMENDED ACTION TYPE J a z Applied Chronic Acute n # Det. Max Pred Cw Allowable Cw Standard Acute (FW): 346.2 Arsenic C 150 FW(7Q10s) 340 ug L - - - - 26 0 1.0 Chronic (FW): 153.2 Max MDL = 2 Arsenic C 10 HH/WS(Qavg) ug/L NO DETECTS Chronic (HH): 13.8 No detects - no monitoring or limits required Max MDL = 2 Acute: 66.19 Beryllium NC 6.5 FW(7Q10s) 65 ug L 3 0 15.00 Note: n 5 9 C.V. (default) Chronic: 6.64 No detects - no monitoring or limits required Limited data set NO DETECTS Max MDL = 10 Acute: 6.176 Cadmium NC 1.0162 FW(7Q10s) 6.0654 ug/L 28 0 0.075 Chronic: 1.038 No detects - no monitoring or limits required NO DETECTS Max MDL = 0.15 Acute: NO WQS Chlorides NC 230 FW(7Q10s) mg;L 0 0 N/A Chronic:----- 234.9 Acute: NO WQS Chlorinated Phenolic Compounds NC 1 A(30Q2) ug/L 0 0 N/A ------------------------------ Chronic:----- 1.1 Acute: NO WQS Total Phenolic Compounds NC 300 A(30Q2) ug/L 3 2 57.0 Note: n 5 9 C.V. (default) Chronic: 316.1 No RP for limited dataset (n<g samples). No Limited data set No value > Allowable Cw monitoring or limits required Acute: 1,660.2 Chromium III NC 212.2514 FW(7Q10s) 1630.3999 µg/L 0 0 N/A Chronic:----- 216.8 Acute: 16.3 Chromium VI NC 11 FW(7Q10s) 16 µg L 0 0 N/A Chronic:----- 11.2 ------------------------------ Chromium, Total NC µg/L 26 0 1.0 Max reported value = 1 No detects - no monitoring or limits required NO DETECTS Max MDL = 2 20559 Freshwater RPA 2023, rpa Page 2 of 3 10/13/2023 Henderson WRF - Outfall 001 NCO020559 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators Qw = 6 MGD Acute: 20.99 Copper NC 14.5750 FW(7Q10s) 20.6104 ug/L 49 22 4.16 Chronic: 14.89 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute: 22.4 Cyanide NC 5 FW(7QlOs) 22 10 ug/L 3 1 15.0 Note: n < 9 C.V. (default) Chronic: 5.1 All values < 10 considered compliant; no monitoring Limited data set No value > Allowable Cw or limits required Acute: NO WQS Fluoride NC 1800 FW(7Q10s) ug/L 0 0 N/A Chronic:-----1,838.7 ----------------------------- Acute: 171.649 Lead NC 6.5760 FW(7QIOs) 168.5679 ug/L 26 0 0.250 Chronic: 6.717 No detects - no monitoring or limits required NO DETECTS Max MDL = 0.5 Acute: NO WQS Mercury NC 12 FW(7Q10s) 0.5 ng/L 0 0 N/A --- ------------------------- Chronic:----- 12.3 Acute: NO WQS Molybdenum NC 2000 HH(7QlOs) ug/L 26 7 12.8 Chronic: 2,043.0 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw Monitoring required Acute (FW): 626.9 Nickel NC 68.4385 FW(7Q10s) 615.6702 µg/L 28 28 9.7 Chronic (FW): 69.9 No RP, Predicted Max < 50% of Allowable Cw - No No value > Allowable Cw ------------------------------ Monitoring required Nickel NC 25.0000 WS(7Q10s) µg/L Chronic (WS): 25.5 No value > Allowable Cw Acute: 57.0 Selenium NC 5 FW(7Q10s) 56 ug/L 28 0 0.5 _ _ _ _ _ _ _ _ Chronic: 5.1 _ _ _ _ _ _ _ _ _ _ _ _ No detects - no monitoring or limits required NO DETECTS Max MDL = 1 Acute: 1.039 Silver NC 0.06 FW(7Q10s) 1.0202 ug/L 28 0 3.600 Chronic: 0.061 All data < 0.5 ug/L except for one value of 5.8 ug/L on NO DETECTS Max MDL = 5 6/7/2021 Acute: 235.3 Zinc NC 233.1791 FW(7QIOs) 231.0957 ug/L 51 51 533.5 Chronic: 238.2 RP shown - apply Monthly Monitoring with Limit 8 values > Allowable Cw Acute: 0 0 N/A Acute: 0 0 N/A Chronic: 20559 Freshwater RPA 2023, rpa Page 3 of 3 10/13/2023 Permit No. NC0020559 NPDES Implementation of Instream Dissolved Metals Standards - Freshwater Standards The NC 2007-2015 Water Quality Standard (WQS) Triennial Review was approved by the NC Environmental Management Commission (EMC) on November 13, 2014. The US EPA subsequently approved the WQS revisions on April 6, 2016, with some exceptions. Therefore, metal limits in draft permits out to public notice after April 6, 2016 must be calculated to protect the new standards - as approved. Table 1. NC Dissolved Metals Water Q ality Standards/A uatic Life Protection Parameter Acute FW, µg/1 (Dissolved) Chronic FW, µg/1 (Dissolved) Acute SW, µg/1 (Dissolved) Chronic SW, µg/1 (Dissolved) Arsenic 340 150 69 36 Beryllium 65 6.5 --- --- Cadmium Calculation Calculation 40 8.8 Chromium III Calculation Calculation --- --- Chromium VI 16 11 1100 50 Copper Calculation Calculation 4.8 3.1 Lead Calculation Calculation 210 8.1 Nickel Calculation Calculation 74 8.2 Silver Calculation 0.06 1.9 0.1 Zinc Calculation Calculation 90 81 Table 1 Notes: 1. FW= Freshwater, SW= Saltwater 2. Calculation = Hardness dependent standard 3. Only the aquatic life standards listed above are expressed in dissolved form. Aquatic life standards for Mercury and selenium are still expressed as Total Recoverable Metals due to bioaccumulative concerns (as are all human health standards for all metals). It is still necessary to evaluate total recoverable aquatic life and human health standards listed in 15A NCAC 213.0200 (e.g., arsenic at 10 µg/1 for human health protection; cyanide at 5 µg/L and fluoride at 1.8 mg/L for aquatic life protection). Table 2. Dissolved Freshwater Standards for Hardness -Dependent Metals The Water Effects Ratio (WER) is equal to one unless determined otherwise under 15A NCAC 02B .0211 Subparagraph (11)(d) Metal NC Dissolved Standard, µg/I Cadmium, Acute WER*{1.136672-[1n hardness] (0. 04183 8)) • e^{0.9151 [In hardness]-3.1485) Cadmium, Acute Trout waters WER*{1.136672-[ln hardness](0.041838)} • e^{0.9151[ln hardness] -3.623 6) Cadmium, Chronic WER*{1.101672-[ln hardness](0.041838)} • e^{0.7998[ln hardness]-4A45l) Chromium III, Acute WER*0.316 e^{0.8190[ln hardness]+3.7256} Chromium III, Chronic WER*0.860 e^{0.8190[ln hardness]+0.6848} Copper, Acute WER*0.960 e^{0.9422[ln hardness]-1.700) Copper, Chronic WER*0.960 e^{0.8545[ln hardness]-1.702) Lead, Acute WER*{1.46203-[ln hardness](0.145712)) • e^{1.273[ln hardness]-1.460) Lead, Chronic WER*{1.46203-[ln hardness](0.145712)) • e^{1.273[ln hardness]-4.705) Nickel, Acute WER*0.998 e^{0.8460[ln hardness]+2.255) Nickel, Chronic WER*0.997 e^{0.8460[ln hardness]+0.0584) Page 1 of 4 Permit No. NCO020559 Silver, Acute WER*0.85 • eA0.72[ln hardness]-6.59} Silver, Chronic Not applicable Zinc, Acute WER*0.978 e^{0.8473[ln hardness]+0.884} Zinc, Chronic WER*0.986 e^{0.8473[ln hardness]+0.884} General Information on the Reasonable Potential Analysis (RPA) The RPA process itself did not change as the result of the new metals standards. However, application of the dissolved and hardness -dependent standards requires additional consideration in order to establish the numeric standard for each metal of concern of each individual discharge. The hardness -based standards require some knowledge of the effluent and instream (upstream) hardness and so must be calculated case -by -case for each discharge. Metals limits must be expressed as `total recoverable' metals in accordance with 40 CFR 122.45(c). The discharge -specific standards must be converted to the equivalent total values for use in the RPA calculations. We will generally rely on default translator values developed for each metal (more on that below), but it is also possible to consider case -specific translators developed in accordance with established methodology. RPA Permitting Guidance/WOBELs for Hardness -Dependent Metals - Freshwater The RPA is designed to predict the maximum likely effluent concentrations for each metal of concern, based on recent effluent data, and calculate the allowable effluent concentrations, based on applicable standards and the critical low -flow values for the receiving stream. If the maximum predicted value is greater than the maximum allowed value (chronic or acute), the discharge has reasonable potential to exceed the standard, which warrants a permit limit in most cases. If monitoring for a particular pollutant indicates that the pollutant is not present (i.e. consistently below detection level), then the Division may remove the monitoring requirement in the reissued permit. To perform a RPA on the Freshwater hardness -dependent metals the Permit Writer compiles the following information: • Critical low flow of the receiving stream, 7Q10 (the spreadsheet automatically calculates the 1 Q 10 using the formula 1 Q 10 = 0.843 (s7Q 10, cfs) 0.993 • Effluent hardness and upstream hardness, site -specific data is preferred • Permitted flow • Receiving stream classification 2. In order to establish the numeric standard for each hardness -dependent metal of concern and for each individual discharge, the Permit Writer must first determine what effluent and instream (upstream) hardness values to use in the equations. The permit writer reviews DMR's, Effluent Pollutant Scans, and Toxicity Test results for any hardness data and contacts the Permittee to see if any additional data is available for instream hardness values, upstream of the discharge. If no hardness data is available, the permit writer may choose to do an initial evaluation using a default hardness of 25 mg/L (CaCO3 or (Ca + Mg)). Minimum and maximum limits on the hardness value used for water quality calculations are 25 mg/L and 400 mg/L, respectively. If the use of a default hardness value results in a hardness -dependent metal showing reasonable potential, the permit writer contacts the Permittee and requests 5 site -specific effluent and upstream hardness samples over a period of one week. The RPA is rerun using the new data. Page 2 of 4 Permit No. NCO020559 The overall hardness value used in the water quality calculations is calculated as follows: Combined Hardness (chronic) _ (Permitted Flow, cfs *Avfz. Effluent Hardness, mg/L)+s7Q10, cfs *Avg. Upstream Hardness, mg/L) (Permitted Flow, cfs + s7Q 10, cfs) The Combined Hardness for acute is the same but the calculation uses the 1 Q 10 flow. 3. The permit writer converts the numeric standard for each metal of concern to a total recoverable metal, using the EPA Default Partition Coefficients (DPCs) or site -specific translators, if any have been developed using federally approved methodology. EPA default partition coefficients or the "Fraction Dissolved" converts the value for dissolved metal at laboratory conditions to total recoverable metal at in -stream ambient conditions. This factor is calculated using the linear partition coefficients found in The Metals Translator: Guidance for Calculating a Total Recoverable Permit Limit from a Dissolved Criterion (EPA 823-B-96-007, June 1996) and the equation: Cdiss = 1 Ctotal 1 + { [Kpo] [ss('+a)] [10-6] } Where: ss = in -stream suspended solids concentration [mg/1], minimum of 10 mg/L used, and Kpo and a = constants that express the equilibrium relationship between dissolved and adsorbed forms of metals. A list of constants used for each hardness -dependent metal can also be found in the RPA program under a sheet labeled DPCs. 4. The numeric standard for each metal of concern is divided by the default partition coefficient (or site -specific translator) to obtain a Total Recoverable Metal at ambient conditions. In some cases, where an EPA default partition coefficient translator does not exist (ie. silver), the dissolved numeric standard for each metal of concern is divided by the EPA conversion factor to obtain a Total Recoverable Metal at ambient conditions. This method presumes that the metal is dissolved to the same extent as it was during EPA's criteria development for metals. For more information on conversion factors see the June, 1996 EPA Translator Guidance Document. 5. The RPA spreadsheet uses a mass balance equation to determine the total allowable concentration (permit limits) for each pollutant using the following equation: Ca = (s7Q 10 + Qw) (Cwgs)(s7Q 10) (Cb) Qw Where: Ca = allowable effluent concentration (µg/L or mg/L) Cwqs = NC Water Quality Standard or federal criteria (µg/L or mg/L) Cb = background concentration: assume zero for all toxicants except NH3* (µg/L or mg/L) Qw = permitted effluent flow (cfs, match s7Q 10) s7Q 10 = summer low flow used to protect aquatic life from chronic toxicity and human health through the consumption of water, fish, and shellfish from noncarcinogens (cfs) * Discussions are on -going with EPA on how best to address background concentrations Flows other than s7Q 10 may be incorporated as applicable: 1 Q 10 = used in the equation to protect aquatic life from acute toxicity Page 3 of 4 Permit No. NC0020559 QA = used in the equation to protect human health through the consumption of water, fish, and shellfish from carcinogens 30Q2 = used in the equation to protect aesthetic quality 6. The permit writer enters the most recent 2-3 years of effluent data for each pollutant of concern. Data entered must have been taken within four and one-half years prior to the date of the permit application (40 CFR 122.21). The RPA spreadsheet estimates the 95th percentile upper concentration of each pollutant. The Predicted Max concentrations are compared to the Total allowable concentrations to determine if a permit limit is necessary. If the predicted max exceeds the acute or chronic Total allowable concentrations, the discharge is considered to show reasonable potential to violate the water quality standard, and a permit limit (Total allowable concentration) is included in the permit in accordance with the U.S. EPA Technical Support Document for Water Quality -Based Toxics Control published in 1991. 7. When appropriate, permit writers develop facility specific compliance schedules in accordance with the EPA Headquarters Memo dated May 10, 2007 from James Hanlon to Alexis Strauss on 40 CFR 122.47 Compliance Schedule Requirements. The Total Chromium NC WQS was removed and replaced with trivalent chromium and hexavalent chromium Water Quality Standards. As a cost savings measure, total chromium data results may be used as a conservative surrogate in cases where there are no analytical results based on chromium III or VI. In these cases, the projected maximum concentration (95th %) for total chromium will be compared against water quality standards for chromium III and chromium VI. 9. Effluent hardness sampling and instream hardness sampling, upstream of the discharge, are inserted into all permits with facilities monitoring for hardness -dependent metals to ensure the accuracy of the permit limits and to build a more robust hardness dataset. 10. Hardness and flow values used in the Reasonable Potential Analysis for this permit included: Parameter Value Comments (Data Source) Average Effluent Hardness, mg/L 51.00 Permittee submitted DMRs (Total as CaCO3) Average Upstream Hardness, mg/L 67.17 Permittee submitted DMRs (Total as CaCO3) 7Q10 summer (cfs) 0.2 Reported in previous permit Fact Sheet 1 Q 10 (cfs) 0.17 Calculated in RPA spreadsheet Permitted Flow (MGD) 6.0 Design flow Date: October 4, 2023 Permit Writer: Gary Perlmutter Page 4 of 4 10/13/23 WQS = 12 ng/L Facility Name Henderson WRF / NC0020559 /Permit No. Total Mercury 1631E PQL = 0.5 ng/L Date Modifier Data Entry Value MERCURY WQBEL/TBEL EVALUATION V:2013-6 No Limit Required MMP Required 7Q10s = 0.200 cfs WQBEL = 12.37 ng/L Permitted Flow = 4.140 47 ng/L 10/7/20 1.14 1.14 1.1 ng/L - Annual Average for 2020 1/14/21 1.46 1.46 2/17/21 < 1 0.5 3/11/21 1.73 1.73 4/8/21 < 1 0.5 5/5/21 3.27 3.27 6/9/21 6.44 6.44 7/15/21 < 1 0.5 8/19/21 < 1 0.5 9/8/21 5.01 5.01 10/7/21 < 1 0.5 11/3/21 < 1 0.5 12/1/21 < 1 0.5 1.8 ng/L - Annual Average for 2021 1/13/22 < 1 0.5 4/7/22 < 1 0.5 7/21/22 < 1 0.5 0.5 ng/L - Annual Average for 2022 4/26/23 < 1 0.5 0.5 ng/L - Annual Average for 2023 10/13/23 WQS = 12 ng/L Facility Name Henderson WRF / NC0020559 /Permit No. Total Mercury 1631E PQL = 0.5 ng/L Date Modifier Data Entry Value MERCURY WQBEL/TBEL EVALUATION V:2013-6 No Limit Required MMP Required 7Q10s = 0.200 cfs WQBEL = 12.26 ng/L Permitted Flow = 6.000 47 ng/L 10/7/20 1.14 1.14 1.1 ng/L - Annual Average for 2020 1/14/21 1.46 1.46 2/17/21 < 1 0.5 3/11/21 1.73 1.73 4/8/21 < 1 0.5 5/5/21 3.27 3.27 6/9/21 6.44 6.44 7/15/21 < 1 0.5 8/19/21 < 1 0.5 9/8/21 5.01 5.01 10/7/21 < 1 0.5 11/3/21 < 1 0.5 12/1/21 < 1 0.5 1.8 ng/L - Annual Average for 2021 1/13/22 < 1 0.5 4/7/22 < 1 0.5 7/21/22 < 1 0.5 0.5 ng/L - Annual Average for 2022 4/26/23 < 1 0.5 0.5 ng/L - Annual Average for 2023