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HomeMy WebLinkAboutNC0038377_J15070341report_20150902Lab DUI E Analytical Laboratory APagel1aof 177 ENERGY Order Number: Project Name: Customer Name(s): Customer Address: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J15070341 MAYO STEAM - AB GW ASSESSMENT WATER Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer Lab Contact: Mary Ann Ogle Phone: 980-875-5274 mary.ogle@duke- Report Authorized By: f%p 9f energy.com Date: 7/18/2015 (Signature) (/ ✓ 2015.07.18 14:16:41-04'00' Mary Ann Ogle Program Comments: Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Analytical Lab Page 2 of 17 Sample ID Plant/Station 2015022933 2015022934 2 Total Samples Collection Date and Time Collected By Sample Description MAYO STEAM 07-Jul-15 10:05 AM illegible CW-2 MAYO STEAM 07-Jul-15 9:47 AM illegible CW-2D Analytical Lab Page 3 of 17 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals 0 Yes ❑ No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes 0 No All laboratory QA/QC requirements are acceptable. 0 Yes ❑ No Report Sections Included: E%-'] Job Summary Report ❑� Sample Identification Technical Validation of Data Package ❑� Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report ❑d Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries ❑� Chain of Custody ❑� Electronic Data Deliverable (EDD) Sent Separately Reviewed By: Mary Ann Ogle Date: 7/18/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15070341 Site: CW-2 Collection Date: 07-Jul-15 10:05 AM Analyte Result Units Qualifiers RDL DF RADIOLOGICAL - (Analysis Performed by GEL) Vendor Parameter Complete Sample #: 2015022933 Matrix: GW WW Analytical Lab Page 4 of 17 Method Analysis Date/Time Analyst Vendor Method v GEL Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15070341 Site: CW-2D Collection Date: 07-Jul-15 9:47 AM Analyte Result Units Qualifiers RDL DF RADIOLOGICAL - (Analysis Performed by GEL) Vendor Parameter Complete Sample #: 2015022934 Matrix: GW WW Analytical Lab Page 5 of 17 Method Analysis Date/Time Analyst Vendor Method v GEL ® Laboratories LLc nalytical Lab ,_, age 6 of 17 a member of The GEL Group IN'. P4 Box 30712 Charleston. SC 29417 2040 Sange Road Chad eston.SC29407 P 843556.8171 F 843.76Gi.1178 gel.com July 17, 2015 Mary Ann Ogle Duke Energy Analytical Laboratory 13339 Hagers Ferry Road Mail Code: MGO3A2 Huntersville, North Carolina 28078 Re: AB GW Assessment Water Work Order: 376975 SDG: J15070341 Dear Mary: GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received on July 10, 2015. This original data report has been prepared and reviewed in accordance with GEL's standard operating procedures. Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time. We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at (843) 556-8171, ext. 4443. Sincerely, 'Le En�Trrent for Lindsay Fabra Project Manager Purchase Order: 1142110 Enclosures Pa Analytical Lab Page 7 of 17 GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Report for DUP0002 Duke Energy Client SDG: J15070341 GEL Work Order: 376975 The Qualifiers in this report are defined as follows: * A quality control analyte recovery is outside of specified acceptance criteria ** Analyte is a Tracer compound ** Analyte is a surrogate compound J Value is estimated U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD. Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the Certificate of Analysis. The designation ND, if present, appears in the result column when the analyte concentration is not detected above the limit as defined in the 'U' qualifier above. This data report has been prepared and reviewed in accordance with GEL Laboratories LLC standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra. Reviewed by Page 2 of 11 Analytical Lab GEL LABORATORIES LLC Page 8 of 17 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Duke Energy Analytical Laboratory Address : 13339 Hagers Ferry Road Mail Code: MG03A2 Huntersville, North Carolina 28078 Contact: Mary Ann Ogle Project: AB GW Assessment Water Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector: 2015022933 376975001 Water 07-JUL-15 10:05 10-JUL-15 Client Report Date: July 17, 2015 Project: DUKE00225 Client ID: DUP0002 Parameter Qualifier Result DL RL Units DF Analyst Date Time Batch Method Metals Analysis-ICP-MS SW846 3010A/6020A Liquid "As Received" Uranium-238 0.000257 0.000067 0.0002 ug/mL 1 PRB 07/17/15 1019 1491995 1 Uranium-233 U 0.00 0.00001 0.00005 ug/mL 1 SKJ 07/17/15 0846 1491995 2 Uranium-234 U 0.00 0.00001 0.00005 ug/mL 1 Uranium-236 U 1.00E-06 0.00001 0.00005 ug/mL 1 Rad Gas Flow Proportional Counting GFPC, Ra228, Liquid "As Received" Radium-228 U 1.06 1.37 3.00 pCi/L AXM6 07/16/15 1125 1491968 3 Rad Radium-226 Lucas Cell, Ra226, liquid "As Received" Radium-226 1.61 0.868 1.00 pCi/L CXP3 07/16/15 0730 1492045 4 The following Prep Methods were performed: Method Description Analyst Date Time Prep Batch SW846 3010A SW 846 3010 Acid Digestion JP1 07/14/15 1710 1491994 The following Analytical Methods were performed: Method Description Analyst Comments 1 SW846 3010A/6020A 2 SW846 3010A/6020A 3 EPA 904,0/SW846 9320 Modified 4 EPA 903.1 Modified Surrogate/Tracer Recovery Test Result Nominal Recovery% Acceptable Limits Barium-133 Tracer GFPC, Ra228, Liquid "As Received" 92.7 (15%-125%) Notes: Page 3 of 11 Analytical Lab GEL LABORATORIES LLC Page 9 of 17 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Duke Energy Analytical Laboratory Address : 13339 Hagers Ferry Road Mail Code: MG03A2 Huntersville, North Carolina 28078 Contact: Mary Ann Ogle Project: AB GW Assessment Water Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector: 2015022934 376975002 Water 07-JUL-15 09:47 10-JUL-15 Client Report Date: July 17, 2015 Project: DUKE00225 Client ID: DUP0002 Parameter Qualifier Result DL RL Units DF Analyst Date Time Batch Method Metals Analysis-ICP-MS SW846 3010A/6020A Liquid "As Received" Uranium-238 0.000354 0.000067 0.0002 ug/mL 1 PRB 07/17/15 1021 1491995 1 Uranium-233 U 0.00 0.00001 0.00005 ug/mL 1 SKJ 07/17/15 0847 1491995 2 Uranium-234 U 0.00 0.00001 0.00005 ug/mL 1 Uranium-236 U 1.00E-06 0.00001 0.00005 ug/mL 1 Rad Gas Flow Proportional Counting GFPC, Ra228, Liquid "As Received" Radium-228 U 1.57 1.72 3.00 pCi/L AXM6 07/16/15 1248 1491968 3 Rad Radium-226 Lucas Cell, Ra226, liquid "As Received" Radium-226 0.792 0.640 1.00 pCi/L CXP3 07/16/15 0730 1492045 4 The following Prep Methods were performed: Method Description Analyst Date Time Prep Batch SW846 3010A SW 846 3010 Acid Digestion JP1 07/14/15 1710 1491994 The following Analytical Methods were performed: Method Description Analyst Comments 1 SW846 3010A/6020A 2 SW846 3010A/6020A 3 EPA 904,0/SW846 9320 Modified 4 EPA 903.1 Modified Surrogate/Tracer Recovery Test Result Nominal Recovery% Acceptable Limits Barium-133 Tracer GFPC, Ra228, Liquid "As Received" 95.3 (15%-125%) Notes: Page 4 of 11 Analytical Lab Page 10 of 17 GEL LABORATORIES LLC 2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com QC Summary Duke Energy Analytical Laboratory 13339 Hagers Ferry Road Mail Code: MG03A2 Huntersville, North Carolina Contact: Mary Ann Ogle Workorder: 376975 Report Date: July 17, 2015 Page 1 of 3 Parmname NOM Sample Qual QC Units RPD%o REC% Range Anlst Date Time Metals Analysis - ICPMS Batch 1491995 QC1203352380 376974001 DUP Uranium-233 U ND U ND ug/mL N/A SKJ 07/17/15 08:38 Uranium-234 U ND U ND ug/mL N/A Uranium-236 U ND U ND ug/mL N/A Uranium-238 0.000504 0.00144 ug/mL 96.0*^ (+/-0.0002) PRB 07/17/1510:10 QC1203352378 LCS Uranium-238 0.0496 0.0446 ug/mL 89.8 (80%-120%) 07/17/15 09:56 QC1203352379 LCS Uranium-233 0.0005 0.000509 ug/mL 102 (80%-120%) SKJ 07/17/15 08:35 Uranium-234 0.00055 0.000534 ug/mL 97.1 (80%-120%) Uranium-236 0.005 0.00555 ug/mL 111 (80%-120%) QC1203352377 MB Uranium-233 U ND ug/mL 07/17/15 08:34 Uranium-234 U ND ug/mL Uranium-236 U ND ug/mL Uranium-238 U ND ug/mL PRB 07/17/15 09:54 QC1203352381 376974001 MS Uranium-238 0.0496 0.000504 0.0486 ug/mL 96.8 (75%-125%) 07/17/1510:15 QC1203352382 376974001 MS Uranium-233 0.0005 U ND 0.000486 ug/mL 97.2 (75%-125%) SKJ 07/17/15 08:39 Uranium-234 0.00055 U ND 0.000521 ug/mL 94.7 (75%-125%) Uranium-236 0.005 U ND 0.00542 ug/mL 108 (75%-125%) QC1203352383 376974001 SD1LT Uranium-233 U ND U ND ug/L N/A 07/17/15 08:41 Page 5 of 11 Analytical Lab Page 11 of 17 GEL LABORATORIES LLC 2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 376975 Page 2 of 3 Parmname NOM Sample Qual QC Units RPD% REC% Range Anlst Date Time Metals Analysis - ICPMS Batch 1491995 Uranium-234 U ND U ND ug/L N/A Uranium-236 U ND U ND ug/L N/A (0%-10%) SKJ 07/17/15 08:41 Uranium-238 0.504 J 0.117 ug/L 16.1 (0%-10%) PRB 07/17/1510:16 Rad Gas Flow Batch 1491968 QC1203352289 376974002 DUP Radium-228 1.41 U -0.336 pCi/L 325* (0%- 100%) AXM6 07/16/15 11:27 QC1203352290 LCS Radium-228 30.5 33.5 pCi/L 110 (75%-125%) 07/16/1511:25 QC1203352288 MB Radium-228 U 0.638 pCi/L 07/16/1511:27 Rad Ra-226 Batch 1492045 QC1203352518 376974001 DUP Radium-226 0.719 1.27 pCi/L 55.1 (0% - 100%) CXP3 07/16/15 08:00 QC1203352520 LCS Radium-226 24.7 23.6 pCi/L 95.5 (75%-125%) 07/16/15 08:00 QC1203352517 MB Radium-226 0.489 pCi/L 07/16/15 08:00 QC1203352519 376974001 MS Radium-226 124 0.719 129 DCi/L 103 (75%-125%) 07/16/15 08:00 Notes: The Qualifiers in this report are defined as follows: ** Analyte is a Tracer compound < Result is less than value reported > Result is greater than value reported BD Results are either below the MDC or tracer recovery is low E %difference of sample and SD is >10%. Sample concentration must meet flagging criteria FA Failed analysis. FB Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed invalid for reporting to regulatory agencies H Analytical holding time was exceeded Page 6of11 Analytical Lab Page 12 of 17 GEL LABORATORIES LLC 2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 376975 Parmname NOM Sample Qual QC Units RPD% REC'% Range Anlst J Value is estimated K Analyte present. Reported value may be biased high. Actual value is expected to be lower. L Analyte present. Reported value may be biased low. Actual value is expected to be higher. M M if above MDC and less than LLD M REMP Result > MDC/CL and < RDL N Metals --The Matrix spike sample recovery is not within specified control limits N/A RPD or %Recovery limits do not apply. N1 See case narrative ND Analyte concentration is not detected above the detection limit NJ Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Q One or more quality control criteria have not been met. Refer to the applicable narrative or DER. R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD. UI Gamma Spectroscopy --Uncertain identification UJ Gamma Spectroscopy --Uncertain identification UL Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias. X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y Other specific qualifiers were required to properly define the results. Consult case narrative. ^ RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry. h Preparation or preservation holding time was exceeded Page 3 of 3 Date Time N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike cone. by a factor of 4 or more or %RPD not applicable. ^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the RL is used to evaluate the DUP result. * Indicates that a Quality Control parameter was not within specifications. For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations. Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the QC Summary. Page 7 of 11 21-181 103 fn IsiO.(.pt A gtiv 'COO '£OOH'9•,WV `� „ VTJ .t xeuol(j - N £ON 'YOS •t'J r.. .- �- �- �- �- �- �- e- «- � • rn � Ir -------------- t H Elm a' ?t c1r) m to (((; ai$P aV C�CJ� OZ a! baa ��J,� a z x = s d„t dutoa Lt r2r >11 ' 6 t1 O j C L' L 0 i a)a Ui O sj m � r m i -E ,h 1 Q V Li 0 o It qNj i iA i ct 0), to U.. i m 1 O ! ! It1n I ttt� ";=e; : j c 1V'o 1 J! It t}IOU 0 p q a i y o i i Gi i'•-'y `C Vui uj LLJ }C tom_ �r 'S..r�.. ♦.�.. ..+'�w � �..� ._..� .�.. ..... .. _.. .._.. .. _. _ _ .;1�sn'µFx. Page 8 of 11 Analytical Lab Page 14 of 17 Laboratories -LG SAMPLE RECEIPT & REVIEW FORM Client: 'Du tc SDGIAWCOC/Work Order* Received By: Date Received: Suspected Hazard information Ig *If Net Counts > 100cpm on samples not marked "radioactive", contact the Radiation Safety Group for further investigation. COC/Samples, marked as radioactive? A,- Maximum Net Counts Observed* (Observed Counts - Area Background Counts): Classified Radioactive It or 111 by RSO? 1,41fyes, Were swipes taken of sample containers < action levels? COC/Samples marked containing PCBs? &I - Package, COC, and/or Samples marked as W , beryllium or asbestos containing? If yes, samples are to be segregated as Safety Controlled Samples, and opened by the GEL Safety Group. Shipped as a DOT Hazardous? .,"Hazard Class Shipped: LJTN#: Samples identified as Foreign Soil? Sample Receipt Criteria Z Comments/Qualifiers (Required for Non -Conforming Items) Shipping containers received intact Circle Applicable: I and sealed? Seals broken Damaged container Leaking container Other (describe) 2 Samples requiring cold preservation Preservation Method:4 'gce�ba�g—s Bluc ice Dryiee None Other(describe) in Celsius within (0 S 6 deg, C)?* er., eratures are recorded 2a Daily check performed and passed on Temperature Device Serial N: Secondary Temperature Device Serial It (If Applicable): x/--, IR temperature gun? Chain of custody documents included 3 with shipment? Circle Applicable: 4 Sample containers intact and seated? Seals broken Damaged container Faking container Other (describe) Samples requiring chemical Sample ID's, containers affected and observed pit: 5 preservation at proper pH? If Preservation added, lot#: Do Low Level Perchlorate samples Sample ID's and containers affected: 6 (EPA 6850) have headspace as 1 required? VOA vials free of headspace (defined Sample ID's and containers affected: 7 as < 6mni bubble)? (if yes, immediately deliver to Volatiles laboratory) 8 Are Encore containers present? Samples received within holding ID's and tests affected: 9 time? I Sample ID's on COC match ID's on Sample ID's and containers affected: 10 bottles? Date & time on COC match date & Sample ID's affected: 11 time on bottles? Number of containers received match Sample ID's affected: 12 number indicated on COC? Are sample containers identifiable as 13 GEL provided? 14 COC form is properly signed in relinquished/received sections? Circle Appiwable: FedEx Air FedEx Ground UPS Field Services Courier < fOthS,�- 15 Carrier and tracking number. I] I Comments (Use Continuation Form if needed): A PM (or PMA) review: Initial"*--, Date 15� page _4_ of __C_ GL-CHL-SR-001 Rev 1 kwol ! 10 i Page 9 of 11 Analytical Lab Page 15 of 17 List of current GEL Certifications as of 17 July 2015 State Certification Alaska UST-110 Arkansas 88-0651 CLIA 42DO904046 California 2940 Interim Colorado SC00012 Connecticut PH-0169 Delaware SC000122013-10 DoD ELAP/ ISO17025 A2LA 2567.01 Florida NELAP E87156 Foreign Soils Permit P330-12-00283, P330-12-00284 Georgia SC00012 Georgia SDWA 967 Hawaii SC000122013-10 Idaho Chemistry SC00012 Idaho Radiochemistry SC00012 Illinois NELAP 200029 Indiana C—SC-01 Kansas NELAP E-10332 Kentucky SDWA 90129 Kentucky Wastewater 90129 Louisiana NELAP 03046 (A133904) Louisiana SDWA LA150001 Maryland 270 Massachusetts M—SCO 12 Michigan 9976 Mississippi SC000122013-10 Nebraska NE—OS-26-13 Nevada SC000122014-1 New Hampshire NELAP 2054 New Jersey NELAP SCO02 New Mexico SC00012 New York NELAP 11501 North Carolina 233 North Carolina SDWA 45709 Oklahoma 9904 Pennsylvania NELAP 68-00485 Plant Material Permit PDEP-12-00260 S.Carolina Radchem 10120002 South Carolina Chemistry 10120001 Tennessee TN 02934 Texas NELAP T104704235-15-10 Utah NELAP SC000122015-17 Vermont VT87156 Virginia NELAP 460202 Washington C780 West Virginia 997404 Page 10 of 11 Analytical Lab Page 16 of 17 GEL Laboratories LLC Form GEL -DER DER Report No.: 1430817 Revision No.: 1 DATA EXCEPTION REPORT Mo.Day Yr. Division: Quality Criteria: Type: 17-JUL-15 Industrial Specifications Process Instrument Type: Test / Method: Matrix Type: Client Code: ICP/MS SW846 3010A/6020A Liquid DUKE Batch ID: Sample Numbers: 1491995 See Below Potentially affected work order(s)(SDG):376974(J15070340),376975(J15070341),376977(J15070278) Application Issues: Failed RPD for DUP Specification and Requirements DER Disposition: Exception Description: 1. Failed RPD for DUP: 1. Not all the applicable analyte RPD values were within the acceptance criteria. QC 1203352380DUP 1203352380 (2015022931DUP) Uranium-238 [96.0" (0.0%-20.0%)]. Originator's Name: Samantha Jacobs 17-JUL-15 Data Validator/Group Leader: Paul Boyd 17-JUL-15 Page 11 of 11 i/ _ - _), -y-iLC11U L."LJ. Legacy Progress Work Being_ Performed By Duke Analytical La! o tigg 1 ! oek D'dar WdWI — 8ampba Nc_ DUKE Mail Coal MG03UhOrQry 1 - ww Dripinatlny ��_ Mail Cosa IiAGOSR2 (Building 7408) ! i ' ��,, oH_ ! ..y., at, D1IGINA 1to1LA C. Rd ! N HuntersvFlle, N. C. 28078 (ems) i 'I eajea By vate SAMPLE vrtocvuw ! Hunte Hailers N. i �� � Ground Water i ORIGINAL to LAB, COPY to CLIENT � 87,-,,4, Fax: 1980) 376-4M9 labcustomer4kduke- — 1 1 % NPDES 11�� -) enal yy.com ---J i t>a ar T 1 V _ _ _ _ _ _ _ _ _ _ _. —._ _ _ _. _ _ _ _ 11proFac[ Na„s p hen. No: GEL t�IQ i{�G3nt:�St1 Pon( �7w RCRA WuM W 1 Cooler Tamp C _v— �J V i �� - - IFFac Mo: i6PreSQ1Y.:,- John Toepfer, Tim Hunsucker .. P© 1142110 H L a=H, -----------------•------------------------------------------------ 3 Progress Accounting (To be completed by client) O-None 3 4 4 M m .� 4 15FFrq-t 10. Projssr - 1 I..pol(; CUStorner to 20000005 Ocurgpwn: ~ Metals Prep - aJBr►cleRcrauel complete all appropriate TRM c Ialra.►w- SO400 j areas. I_ ICp=AI, Ba B. tl _ - -- ---------------------- J ------ _----------------------------- Cr, Cu, Fe, ,.::), z o ._.._..----.._.._.--•---•-.._.._.._.._.._.._.._..-.._.._.._..-..._.._.._.-_.._.._.._..-.._.._--_.._..-----.-.._.•-.._.._.._..------........_.,_ ! Duke Accountin To be completed b lab /Duke Accounting) Mn, Nl, Zn IMS=Sb,AS, col i Q ale t�+e s�oc.raw+euac not ID �".Cc� - '..........-----.._... ------ -., ,-----.------------------ --.._.._.._.-_.._.....---.. +e Inforrnatlon asB IJF ONLY XCEL-0 Se, T!LL,...._Coltection - and Hg 245.1 p Y is k.IMS Labomtory Sample ID Sample Descrl Lion or ID Date Tirna s nature '� 0-1 I 1 1 1 - i CW4 jI ♦ 1 7 i 1 . 773 1 1 1 rYA 1 Gw—�.D Lf �dy4 l` lonl TAin j 1 1 1 1 22Requested Turnaround 14 Day/7 t •7 Days 48 Fir Analytical Lab Page 17 of 17