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Home My WebLink AboutNC0038377_J15060206 Report_20150902+ DUKE Analytical Laboratory 1 of64 ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J15060206 MAYO STEAM - AB GW ASSESSMENT SOIL Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer Margaret Galvin -Karr MXG4644 (101161) - 2015.07.06 15:01:21 RGY�-04'00' Margaret Galvin -Karr Phone: 980-875-5219 Date: Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 7/6/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Collection Sample ID Plant/Station Date and Time 2015017618 2015017619 2015017620 2015017621 4 Total Samples Collected By Sample Description MAYO STEAM 02-Jun-15 9:35 AM Erin Black ABMW-1-EB MAYO STEAM 02-Jun-15 10:01 AM Erin Black ABMW-1(1.0-1.5) MAYO STEAM 02-Jun-15 11:30 AM Erin Black ABMW-1(11.5-12.0) MAYO STEAM 02-Jun-15 11:20 AM Erin Black AVMW-1(13.0-13.5) 2 of 64 3 of 64 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes❑ No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 66 Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately Reviewed By: Margaret Galvin -Karr Date: 7/6/2015 Certificate of Laboratory Analysis 4 of 64 This report shall not be reproduced, except in full. Order # J15060206 Site: ABMW-1-EB Collection Date: 02-Jun-15 9:35 AM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015017618 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060206 Site: ABMW-1(1.0-1.5) Collection Date: 02-Jun-15 10:01 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 5 of 64 Sample #: 2015017619 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060206 Site: ABMW-1(11.5-12.0) Collection Date: 02-Jun-15 11:30 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 6 of 64 Sample #: 2015017620 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060206 Site: AVMW-1(13.0-13.5) Collection Date: 02-Jun-15 11:20 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 7 of 64 Sample #: 2015017621 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kigc&y&e. Suite 100 Huntersville, INC 28078 (704)875-9092 July 06, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 15060206 Pace Project No.: 92253195 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on June 05, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Mary Ann Ogle, Duke Energy Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 56 lacmnalyfica( www.pacelabs.com Pace Analytical Services, Inc. 9800 Kinf&e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060206 Pace Project No.: 92253195 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21-A Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 North Carolina Wastewater Certification #: 12 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060206 Pace Project No.: 92253195 Charlotte Certification IDs Kentucky UST Certification #: 84 West Virginia Certification #: 357 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 VirginiaNELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ff�in� c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J15060206 Pace Project No.: 92253195 Lab ID Sample ID Matrix Date Collected Date Received 92253195001 2015017618 Water 06/02/15 09:35 06/05/15 14:45 92253195002 2015017619 Solid 06/02/1510:01 06/05/15 14:45 92253195003 2015017620 Solid 06/02/1511:30 06/05/15 14:45 92253195004 2015017621 Solid 06/02/1511:20 06/05/15 14:45 92253195005 2015017619 SPLP Water 06/02/15 10:01 06/05/15 14:45 92253195006 2015017620 SPLP Water 06/02/15 11:30 06/05/15 14:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J15060206 92253195 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92253195001 2015017618 EPA 6020A TT3 24 PASI-M EPA 7470A LMW 1 PASI-M 92253195002 2015017619 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 SLJ 1 PASI-C EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 Modified TJJ 4 PASI-G 92253195003 2015017620 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 SLJ 1 PASI-C EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 Modified TJJ 4 PASI-G 92253195004 2015017621 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 SLJ 1 PASI-C EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 Modified TJJ 4 PASI-G 92253195005 2015017619 SPLP EPA 6020A RJS 24 PASI-M EPA 7470A LMW 1 PASI-M 92253195006 2015017620 SPLP EPA 6020A RJS 24 PASI-M EPA 7470A LMW 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060206 Pace Project No.: 92253195 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92253195001 2015017618 EPA 6020A Aluminum 13.9 ug/L 10.0 06/10/15 16:56 EPA 6020A Barium 0.22J ug/L 0.30 06/10/15 16:56 EPA 6020A Cadmium 0.031 J ug/L 0.080 06/10/15 16:56 EPA 6020A Calcium 70.1 ug/L 40.0 06/10/15 16:56 EPA 6020A Chromium 0.26J ug/L 0.50 06/10/15 16:56 EPA 6020A Copper 0.77J ug/L 1.0 06/10/15 16:56 EPA 6020A Iron 22.2J ug/L 50.0 06/10/15 16:56 EPA 6020A Lead 0.0951 ug/L 0.10 06/10/15 16:56 EPA 6020A Magnesium 7.5J ug/L 10.0 06/10/15 16:56 EPA 6020A Manganese 0.34J ug/L 0.50 06/10/15 16:56 EPA 6020A Potassium 16.1 J ug/L 50.0 06/11 /15 07:54 EPA 6020A Sodium 45.5J ug/L 50.0 06/10/15 16:56 EPA 6020A Strontium 0.17J ug/L 0.50 06/10/15 16:56 EPA 6020A Zinc 5.5 ug/L 5.0 06/10/15 16:56 92253195002 2015017619 EPA 6010 Aluminum 6960 mg/kg 43.3 06/15/15 01:23 EPA 6010 Barium 150 mg/kg 4.3 06/15/15 01:23 EPA 6010 Beryllium 2.1 mg/kg 0.43 06/15/15 01:23 EPA 6010 Boron 27.4 mg/kg 21.7 06/15/15 01:23 EPA 6010 Calcium 2070 mg/kg 217 06/15/15 01:23 EPA 6010 Chromium 25.0 mg/kg 2.2 06/15/15 01:23 EPA 6010 Copper 37.9 mg/kg 2.2 06/15/15 01:23 EPA 6010 Iron 2240 mg/kg 17.3 06/15/15 01:23 EPA 6010 Magnesium 561 mg/kg 217 06/15/15 01:23 EPA 6010 Manganese 18.4 mg/kg 2.2 06/15/15 01:23 EPA 6010 Nickel 14.3 mg/kg 2.2 06/15/15 01:23 EPA 6010 Potassium 1010 mg/kg 433 06/15/15 01:23 EPA 6010 Strontium 71.8 mg/kg 4.3 06/15/15 01:23 EPA 6010 Zinc 18.8 mg/kg 8.7 06/15/15 01:23 EPA 6020 Arsenic 16.6 mg/kg 8.7 06/13/15 16:20 EPA 6020 Cobalt 7.6J mg/kg 8.7 06/13/15 16:20 EPA 6020 Lead 13.0 mg/kg 8.7 06/13/15 16:20 EPA 6020 Vanadium 39.3 mg/kg 8.7 06/13/15 16:20 ASTM D2974-87 Percent Moisture 40.8 % 0.10 07/06/15 09:45 EPA 9045 pH at 25 Degrees C 10.4 Std. Units 0.10 06/14/15 15:00 EPA 300.0 Sulfate 19.9 mg/L 3.4 06/16/15 17:22 B EPA 9060 Modified RPD% 17.2 % 0.10 06/27/15 17:22 EPA 9060 Modified Total Organic Carbon 77800 mg/kg 5940 06/27/15 17:22 EPA 9060 Modified Total Organic Carbon 92400 mg/kg 6070 06/27/15 17:28 EPA 9060 Modified Mean Total Organic Carbon 85100 mg/kg 6000 06/27/15 17:22 92253195003 2015017620 EPA 6010 Aluminum 7960 mg/kg 39.2 06/15/15 01:39 EPA 6010 Barium 152 mg/kg 3.9 06/15/15 01:39 EPA 6010 Beryllium 1.9 mg/kg 0.39 06/15/15 01:39 EPA 6010 Boron 27.4 mg/kg 19.6 06/15/15 01:39 EPA 6010 Calcium 2260 mg/kg 196 06/15/15 01:39 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffl %fir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060206 Pace Project No.: 92253195 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92253195003 2015017620 EPA 6010 Chromium 26.9 mg/kg 2.0 06/15/15 01:39 EPA 6010 Copper 34.6 mg/kg 2.0 06/15/15 01:39 EPA 6010 Iron 2710 mg/kg 15.7 06/15/15 01:39 EPA 6010 Magnesium 712 mg/kg 196 06/15/15 01:39 EPA 6010 Manganese 31.3 mg/kg 2.0 06/15/15 01:39 EPA 6010 Nickel 14.6 mg/kg 2.0 06/15/15 01:39 EPA 6010 Potassium 1100 mg/kg 392 06/15/15 01:39 EPA 6010 Strontium 111 mg/kg 3.9 06/15/15 01:39 EPA 6010 Zinc 21.9 mg/kg 7.8 06/15/15 01:39 EPA 6020 Arsenic 26.2 mg/kg 7.8 06/13/15 16:25 EPA 6020 Cobalt 8.3 mg/kg 7.8 06/13/15 16:25 EPA 6020 Lead 13.5 mg/kg 7.8 06/13/15 16:25 EPA 6020 Vanadium 46.2 mg/kg 7.8 06/13/15 16:25 ASTM D2974-87 Percent Moisture 34.7 % 0.10 07/06/15 09:45 EPA 9045 pH at 25 Degrees C 8.2 Std. Units 0.10 06/14/15 15:00 EPA 300.0 Sulfate 4.1 mg/L 3.1 06/16/15 18:03 B EPA 9060 Modified RPD% 10.2 % 0.10 06/27/15 17:58 EPA 9060 Modified Total Organic Carbon 46700 mg/kg 3680 06/27/15 17:58 EPA 9060 Modified Total Organic Carbon 51700 mg/kg 3700 06/27/15 18:05 EPA 9060 Modified Mean Total Organic Carbon 49200 mg/kg 3690 06/27/15 17:58 92253195004 2015017621 EPA 6010 Aluminum 7090 mg/kg 30.9 06/15/15 01:44 EPA 6010 Barium 53.8 mg/kg 3.1 06/15/15 01:44 EPA 6010 Beryllium 0.23J mg/kg 0.31 06/15/15 01:44 EPA 6010 Calcium 410 mg/kg 155 06/15/15 01:44 EPA 6010 Chromium 3.7 mg/kg 1.5 06/15/15 01:44 EPA 6010 Copper 4.1 mg/kg 1.5 06/15/15 01:44 EPA 6010 Iron 8770 mg/kg 12.4 06/15/15 01:44 EPA 6010 Magnesium 1190 mg/kg 155 06/15/15 01:44 EPA 6010 Manganese 92.2 mg/kg 1.5 06/15/15 01:44 EPA 6010 Nickel 1 AJ mg/kg 1.5 06/15/15 01:44 EPA 6010 Potassium 1350 mg/kg 309 06/15/15 01:44 EPA 6010 Strontium 10.8 mg/kg 3.1 06/15/15 01:44 EPA 6010 Zinc 12.7 mg/kg 6.2 06/15/15 01:44 EPA 6020 Vanadium 11.9 mg/kg 6.2 06/13/15 16:28 EPA 7471 Mercury 0.011 mg/kg 0.010 06/16/15 12:42 ASTM D2974-87 Percent Moisture 19.7 % 0.10 07/06/15 09:45 EPA 9045 pH at 25 Degrees C 4.9 Std. Units 0.10 06/14/15 15:00 EPA 9060 Modified RPD% 27.8 % 0.10 06/28/15 08:56 EPA 9060 Modified Total Organic Carbon 6520 mg/kg 744 06/28/15 08:56 EPA 9060 Modified Total Organic Carbon 4930 mg/kg 751 06/28/15 09:03 EPA 9060 Modified Mean Total Organic Carbon 5730 mg/kg 747 06/28/15 08:56 92253195005 2015017619 SPLP EPA 6020A Aluminum 234 ug/L 10.0 07/01/15 01:10 EPA 6020A Antimony 2.0 ug/L 0.50 07/01/15 01:10 EPA 6020A Arsenic 39.6 ug/L 0.50 07/01/15 01:10 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060206 Pace Project No.: 92253195 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92253195005 2015017619 SPLP EPA 6020A Barium 37.1 ug/L 0.30 07/01/15 01:10 EPA 6020A Boron 659 ug/L 25.0 07/02/15 08:42 EPA 6020A Calcium 23100 ug/L 200 07/02/15 08:42 EPA 6020A Chromium 18.3 ug/L 0.50 07/01/15 01:10 EPA 6020A Copper 0.65J ug/L 1.0 07/01/15 01:10 EPA 6020A Iron 24.3J ug/L 50.0 07/01/15 01:10 EPA 6020A Lead 0.16 ug/L 0.10 07/01/15 01:10 EPA 6020A Magnesium 58.0 ug/L 10.0 07/01/15 01:10 EPA 6020A Manganese 2.6 ug/L 0.50 07/01/15 01:10 EPA 6020A Molybdenum 8.0 ug/L 0.50 07/01/15 01:10 EPA 6020A Nickel 0.26J ug/L 0.50 07/01/15 01:10 EPA 6020A Potassium 98.8 ug/L 50.0 07/01/15 01:10 EPA 6020A Selenium 0.55 ug/L 0.50 07/01/15 01:10 EPA 6020A Sodium 1180 ug/L 50.0 07/01/15 01:10 EPA 6020A Strontium 150 ug/L 0.50 07/01/15 01:10 EPA 6020A Vanadium 120 ug/L 1.0 07/01/15 01:10 EPA 6020A Zinc 6.0 ug/L 5.0 07/01/15 01:10 92253195006 2015017620 SPLP EPA 6020A Aluminum 921 ug/L 10.0 07/01/15 01:14 EPA 6020A Antimony 4.6 ug/L 0.50 07/01/15 01:14 EPA 6020A Arsenic 143 ug/L 0.50 07/01/15 01:14 EPA 6020A Barium 149 ug/L 0.30 07/01/15 01:14 EPA 6020A Beryllium 0.45 ug/L 0.20 07/01/15 01:14 EPA 6020A Boron 155 ug/L 5.0 07/01/15 01:14 EPA 6020A Cadmium 0.074J ug/L 0.080 07/01/15 01:14 EPA 6020A Calcium 6460 ug/L 40.0 07/01/15 01:14 EPA 6020A Chromium 15.7 ug/L 0.50 07/01/15 01:14 EPA 6020A Cobalt 0.83 ug/L 0.50 07/01/15 01:14 EPA 6020A Copper 10.8 ug/L 1.0 07/01/15 01:14 EPA 6020A Iron 302 ug/L 50.0 07/01/15 01:14 EPA 6020A Lead 1.9 ug/L 0.10 07/01/15 01:14 EPA 6020A Magnesium 1580 ug/L 10.0 07/01/15 01:14 EPA 6020A Manganese 8.1 ug/L 0.50 07/01/15 01:14 EPA 6020A Molybdenum 4.4 ug/L 0.50 07/01/15 01:14 EPA 6020A Nickel 2.6 ug/L 0.50 07/01/15 01:14 EPA 6020A Potassium 304 ug/L 50.0 07/01/15 01:14 EPA 6020A Selenium 0.96 ug/L 0.50 07/01/15 01:14 EPA 6020A Sodium 1620 ug/L 50.0 07/01/15 01:14 EPA 6020A Strontium 192 ug/L 0.50 07/01/15 01:14 EPA 6020A Thallium 0.31 ug/L 0.10 07/01/15 01:14 EPA 6020A Vanadium 107 ug/L 1.0 07/01/15 01:14 EPA 6020A Zinc 10.6 ug/L 5.0 07/01/15 01:14 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffl %fir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060206 Pace Project No.: 92253195 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: July 06, 2015 General Information: 3 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24673 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92253145025 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1240561) • Aluminum • Barium • Beryllium • Calcium • Iron • Magnesium • Manganese • Molybdenum • Nickel • Potassium • Strontium • Zinc • MSD (Lab ID: 1240563) • Aluminum • Barium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ff�ic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060206 Pace Project No.: 92253195 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: July 06, 2015 QC Batch: MPRP/24673 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92253145025 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • Beryllium • Calcium • Iron • Magnesium • Manganese • Molybdenum • Nickel • Potassium • Strontium • Zinc Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICP / 15063 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffl %fir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060206 Pace Project No.: 92253195 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: July 06, 2015 General Information: 3 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24674 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92253145025 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1240566) • Antimony • Cadmium • Cobalt • Selenium • Vanadium • MSD (Lab ID: 1240567) • Antimony • Cadmium • Cobalt • Lead • Selenium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060206 Pace Project No.: 92253195 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: July 06, 2015 Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICPM / 10002 Analyte Comments: QC Batch: MPRP/24674 N2: The lab does not hold TNI accreditation for this parameter. •2015017619 (Lab ID:92253195002) • Antimony •2015017620 (Lab ID:92253195003) • Antimony •2015017621 (Lab ID:92253195004) • Antimony • BLANK (Lab ID: 1240564) • Antimony • LCS (Lab ID: 1240565) • Antimony • MS (Lab ID: 1240566) • Antimony • MSD (Lab ID: 1240567) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP %fir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060206 Pace Project No.: 92253195 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: July 06, 2015 General Information: 3 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/55069 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92253161011 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1989762) • Aluminum • MSD (Lab ID: 1989763) • Aluminum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�nic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060206 Pace Project No.: 92253195 Method: EPA 7470A Description: 7470A Mercury Client: Duke Energy Date: July 06, 2015 General Information: 3 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060206 Pace Project No.: 92253195 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: July 06, 2015 General Information: 3 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060206 Pace Project No.: 92253195 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: July 06, 2015 General Information: 3 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. QC Batch: WET/38033 D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. • DUP (Lab ID: 1481715) • pH at 25 Degrees C • DUP (Lab ID: 1481716) • pH at 25 Degrees C Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060206 Pace Project No.: 92253195 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: July 06, 2015 General Information: 2 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/23324 B: Analyte was detected in the associated method blank. • BLANK for HBN 268289 [WETA/233 (Lab ID: 1485896) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060206 Pace Project No.: 92253195 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: July 06, 2015 General Information: 2 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 111: Analysis conducted outside the EPA method holding time. •2015017619 (Lab ID:92253195002) •2015017620 (Lab ID:92253195003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K� %fir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060206 Pace Project No.: 92253195 Method: SM 4500-CI-E Description: 4500 Chloride, SPLP Client: Duke Energy Date: July 06, 2015 General Information: 2 samples were analyzed for SM 4500-CI-E. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WETA/23354 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92252532003 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1487999) • Chloride • MSD (Lab ID: 1488000) • Chloride Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060206 Pace Project No.: 92253195 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: July 06, 2015 General Information: 3 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/47190 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015017619 (Lab ID:92253195002) • Chloride • Sulfate •2015017620 (Lab ID:92253195003) • Chloride • Sulfate •2015017621 (Lab ID:92253195004) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPgc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060206 Pace Project No.: 92253195 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: July 06, 2015 General Information: 3 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 113: Sample was received or analysis requested beyond the recognized method holding time. •2015017619 (Lab ID:92253195002) •2015017620 (Lab ID:92253195003) •2015017621 (Lab ID:92253195004) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060206 Pace Project No.: 92253195 Method: EPA 9060 Modified Description: Total Organic Carbon Client: Duke Energy Date: July 06, 2015 General Information: 3 samples were analyzed for EPA 9060 Modified. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3 %fir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060206 Pace Project No.: 92253195 Sample: 2015017618 Lab ID: 92253195001 Collected: 06/02/15 09:35 Received: 06/05/15 14:45 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\��,I=11a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 07/06/2015 01:32 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 13.9 ug/L 10.0 3.0 1 06/10/15 09:24 06/10/15 16:56 7429-90-5 ND ug/L 0.50 0.15 1 06/10/15 09:24 06/10/15 16:56 7440-36-0 ND ug/L 0.50 0.11 1 06/10/15 09:24 06/10/15 16:56 7440-38-2 0.22J ug/L 0.30 0.081 1 06/10/15 09:24 06/10/15 16:56 7440-39-3 ND ug/L 0.20 0.067 1 06/10/15 09:24 06/10/15 16:56 7440-41-7 ND ug/L 5.0 1.1 1 06/10/15 09:24 06/10/15 16:56 7440-42-8 0.031J ug/L 0.080 0.024 1 06/10/15 09:24 06/10/15 16:56 7440-43-9 70.1 ug/L 40.0 16.0 1 06/10/15 09:24 06/10/15 16:56 7440-70-2 0.26J ug/L 0.50 0.17 1 06/10/15 09:24 06/10/15 16:56 7440-47-3 ND ug/L 0.50 0.13 1 06/10/15 09:24 06/10/15 16:56 7440-48-4 0.77J ug/L 1.0 0.21 1 06/10/15 09:24 06/10/15 16:56 7440-50-8 22.2J ug/L 50.0 13.7 1 06/10/15 09:24 06/10/15 16:56 7439-89-6 0.095J ug/L 0.10 0.046 1 06/10/15 09:24 06/10/15 16:56 7439-92-1 7.5J ug/L 10.0 3.2 1 06/10/15 09:24 06/10/15 16:56 7439-95-4 0.34J ug/L 0.50 0.24 1 06/10/15 09:24 06/10/15 16:56 7439-96-5 ND ug/L 0.50 0.094 1 06/10/15 09:24 06/10/15 16:56 7439-98-7 ND ug/L 0.50 0.16 1 06/10/15 09:24 06/10/15 16:56 7440-02-0 16.1J ug/L 50.0 11.7 1 06/10/15 09:24 06/11/15 07:54 7440-09-7 ND ug/L 0.50 0.20 1 06/10/15 09:24 06/10/15 16:56 7782-49-2 45.5J ug/L 50.0 16.3 1 06/10/15 09:24 06/10/15 16:56 7440-23-5 0.17J ug/L 0.50 0.13 1 06/10/15 09:24 06/10/15 16:56 7440-24-6 ND ug/L 0.10 0.015 1 06/10/15 09:24 06/10/15 16:56 7440-28-0 ND ug/L 1.0 0.28 1 06/10/15 09:24 06/10/15 16:56 7440-62-2 5.5 ug/L 5.0 2.4 1 06/10/15 09:24 06/10/15 16:56 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 06/10/1510:30 06/10/1514:31 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3nic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060206 Pace Project No.: 92253195 Sample: 2015017619 Lab ID: 92253195002 Collected: 06/02/15 10:01 Received: 06/05/15 14:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 07/06/2015 01:32 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 6960 mg/kg 43.3 21.7 5 06/12/15 16:16 06/15/15 01:23 7429-90-5 150 mg/kg 4.3 2.2 5 06/12/15 16:16 06/15/15 01:23 7440-39-3 2.1 mg/kg 0.43 0.22 5 06/12/15 16:16 06/15/15 01:23 7440-41-7 27.4 mg/kg 21.7 10.8 5 06/12/15 16:16 06/15/15 01:23 7440-42-8 2070 mg/kg 217 108 5 06/12/15 16:16 06/15/15 01:23 7440-70-2 25.0 mg/kg 2.2 1.1 5 06/12/15 16:16 06/15/15 01:23 7440-47-3 37.9 mg/kg 2.2 1.1 5 06/12/15 16:16 06/15/15 01:23 7440-50-8 2240 mg/kg 17.3 8.7 5 06/12/15 16:16 06/15/15 01:23 7439-89-6 561 mg/kg 217 108 5 06/12/15 16:16 06/15/15 01:23 7439-95-4 18.4 mg/kg 2.2 1.1 5 06/12/15 16:16 06/15/15 01:23 7439-96-5 ND mg/kg 4.3 2.2 5 06/12/15 16:16 06/15/15 01:23 7439-98-7 14.3 mg/kg 2.2 1.1 5 06/12/15 16:16 06/15/15 01:23 7440-02-0 1010 mg/kg 433 217 5 06/12/15 16:16 06/15/15 01:23 7440-09-7 ND mg/kg 433 217 5 06/12/15 16:16 06/15/15 01:23 7440-23-5 71.8 mg/kg 4.3 2.2 5 06/12/15 16:16 06/15/15 01:23 7440-24-6 18.8 mg/kg 8.7 4.3 5 06/12/15 16:16 06/15/15 01:23 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 8.7 4.3 100 06/12/15 16:16 06/13/1516:20 7440-36-0 16.6 mg/kg 8.7 4.3 100 06/12/15 16:16 06/13/1516:20 7440-38-2 ND mg/kg 1.0 0.52 100 06/12/15 16:16 06/13/1516:20 7440-43-9 7.6J mg/kg 8.7 4.3 100 06/12/15 16:16 06/13/1516:20 7440-48-4 13.0 mg/kg 8.7 4.3 100 06/12/15 16:16 06/13/1516:20 7439-92-1 ND mg/kg 8.7 4.3 100 06/12/15 16:16 06/13/1516:20 7782-49-2 ND mg/kg 8.7 4.3 100 06/12/15 16:16 06/13/1516:20 7440-28-0 39.3 mg/kg 8.7 4.3 100 06/12/15 16:16 06/13/1516:20 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 ND mg/kg 0.014 0.0068 1 06/12/1516:30 06/16/1512:31 7439-97-6 Analytical Method: ASTM D2974-87 40.8 % 0.10 0.10 1 07/06/15 09:45 Analytical Method: EPA 9045 10.4 Std. Units 0.10 0.10 1 06/14/15 15:00 N2 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 06/08/15 00:00 19.9 mg/L 3.4 1.7 1 06/16/1517:22 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 06/08/15 00:00 ND mg/L 0.34 0.34 1 06/18/1517:17 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 06/08/15 00:00 ND mg/L 8.4 4.2 1 06/18/15 05:02 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060206 Pace Project No.: 92253195 Sample: 2015017619 Lab ID: 92253195002 Collected: 06/02/15 10:01 Received: 06/05/15 14:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 425 213 5 06/11/15 05:04 16887-00-6 D3 Sulfate ND mg/kg 425 213 5 06/11/15 05:04 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 42.5 21.3 5 06/11/15 05:04 14797-55-8 H3 Total Organic Carbon Analytical Method: EPA 9060 Modified Surrogates RPD% 17.2 % 0.10 0.10 1 06/27/15 17:22 Total Organic Carbon 77800 mg/kg 5940 2970 1 06/27/15 17:22 7440-44-0 Total Organic Carbon 92400 mg/kg 6070 3030 1 06/27/15 17:28 7440-44-0 Mean Total Organic Carbon 85100 mg/kg 6000 3000 1 06/27/15 17:22 7440-44-0 Date: 07/06/2015 01:32 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060206 Pace Project No.: 92253195 Sample: 2015017620 Lab ID: 92253195003 Collected: 06/02/15 11:30 Received: 06/05/15 14:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 07/06/2015 01:32 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 7960 mg/kg 39.2 19.6 5 06/12/15 16:16 06/15/15 01:39 7429-90-5 152 mg/kg 3.9 2.0 5 06/12/15 16:16 06/15/15 01:39 7440-39-3 1.9 mg/kg 0.39 0.20 5 06/12/15 16:16 06/15/15 01:39 7440-41-7 27.4 mg/kg 19.6 9.8 5 06/12/15 16:16 06/15/15 01:39 7440-42-8 2260 mg/kg 196 98.1 5 06/12/15 16:16 06/15/15 01:39 7440-70-2 26.9 mg/kg 2.0 0.98 5 06/12/15 16:16 06/15/15 01:39 7440-47-3 34.6 mg/kg 2.0 0.98 5 06/12/15 16:16 06/15/15 01:39 7440-50-8 2710 mg/kg 15.7 7.8 5 06/12/15 16:16 06/15/15 01:39 7439-89-6 712 mg/kg 196 98.1 5 06/12/15 16:16 06/15/15 01:39 7439-95-4 31.3 mg/kg 2.0 0.98 5 06/12/15 16:16 06/15/15 01:39 7439-96-5 ND mg/kg 3.9 2.0 5 06/12/15 16:16 06/15/15 01:39 7439-98-7 14.6 mg/kg 2.0 0.98 5 06/12/15 16:16 06/15/15 01:39 7440-02-0 1100 mg/kg 392 196 5 06/12/15 16:16 06/15/15 01:39 7440-09-7 ND mg/kg 392 196 5 06/12/15 16:16 06/15/15 01:39 7440-23-5 111 mg/kg 3.9 2.0 5 06/12/15 16:16 06/15/15 01:39 7440-24-6 21.9 mg/kg 7.8 3.9 5 06/12/15 16:16 06/15/15 01:39 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 7.8 3.9 100 06/12/15 16:16 06/13/1516:25 7440-36-0 26.2 mg/kg 7.8 3.9 100 06/12/15 16:16 06/13/1516:25 7440-38-2 ND mg/kg 0.94 0.47 100 06/12/15 16:16 06/13/1516:25 7440-43-9 8.3 mg/kg 7.8 3.9 100 06/12/15 16:16 06/13/1516:25 7440-48-4 13.5 mg/kg 7.8 3.9 100 06/12/15 16:16 06/13/1516:25 7439-92-1 ND mg/kg 7.8 3.9 100 06/12/15 16:16 06/13/1516:25 7782-49-2 ND mg/kg 7.8 3.9 100 06/12/15 16:16 06/13/1516:25 7440-28-0 46.2 mg/kg 7.8 3.9 100 06/12/15 16:16 06/13/1516:25 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 ND mg/kg 0.013 0.0064 1 06/12/1516:30 06/16/1512:39 7439-97-6 Analytical Method: ASTM D2974-87 34.7 % 0.10 0.10 1 07/06/15 09:45 Analytical Method: EPA 9045 8.2 Std. Units 0.10 0.10 1 06/14/15 15:00 N2 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 06/08/15 00:00 4.1 mg/L 3.1 1.5 1 06/16/1518:03 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 06/08/15 00:00 ND mg/L 0.31 0.31 1 06/18/1517:18 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 06/08/15 00:00 ND mg/L 7.7 3.8 1 06/19/15 05:18 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060206 Pace Project No.: 92253195 Sample: 2015017620 Lab ID: 92253195003 Collected: 06/02/15 11:30 Received: 06/05/15 14:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 381 191 5 06/11/15 05:25 16887-00-6 D3 Sulfate ND mg/kg 381 191 5 06/11/15 05:25 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 38.1 19.1 5 06/11/15 05:25 14797-55-8 H3 Total Organic Carbon Analytical Method: EPA 9060 Modified Surrogates RPD% 10.2 % 0.10 0.10 1 06/27/15 17:58 Total Organic Carbon 46700 mg/kg 3680 1840 1 06/27/15 17:58 7440-44-0 Total Organic Carbon 51700 mg/kg 3700 1850 1 06/27/15 18:05 7440-44-0 Mean Total Organic Carbon 49200 mg/kg 3690 1840 1 06/27/15 17:58 7440-44-0 Date: 07/06/2015 01:32 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K� %fir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060206 Pace Project No.: 92253195 Sample: 2015017621 Lab ID: 92253195004 Collected: 06/02/15 11:20 Received: 06/05/15 14:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 7090 mg/kg 30.9 15.5 5 06/12/15 16:16 06/15/15 01:44 7429-90-5 Barium 53.8 mg/kg 3.1 1.5 5 06/12/15 16:16 06/15/15 01:44 7440-39-3 Beryllium 0.23J mg/kg 0.31 0.15 5 06/12/15 16:16 06/15/15 01:44 7440-41-7 Boron ND mg/kg 15.5 7.7 5 06/12/15 16:16 06/15/15 01:44 7440-42-8 Calcium 410 mg/kg 155 77.4 5 06/12/15 16:16 06/15/15 01:44 7440-70-2 Chromium 3.7 mg/kg 1.5 0.77 5 06/12/15 16:16 06/15/15 01:44 7440-47-3 Copper 4.1 mg/kg 1.5 0.77 5 06/12/15 16:16 06/15/15 01:44 7440-50-8 Iron 8770 mg/kg 12.4 6.2 5 06/12/15 16:16 06/15/15 01:44 7439-89-6 Magnesium 1190 mg/kg 155 77.4 5 06/12/15 16:16 06/15/15 01:44 7439-95-4 Manganese 92.2 mg/kg 1.5 0.77 5 06/12/15 16:16 06/15/15 01:44 7439-96-5 Molybdenum ND mg/kg 3.1 1.5 5 06/12/15 16:16 06/15/15 01:44 7439-98-7 Nickel 1.4J mg/kg 1.5 0.77 5 06/12/15 16:16 06/15/15 01:44 7440-02-0 Potassium 1350 mg/kg 309 155 5 06/12/15 16:16 06/15/15 01:44 7440-09-7 Sodium ND mg/kg 309 155 5 06/12/15 16:16 06/15/15 01:44 7440-23-5 Strontium 10.8 mg/kg 3.1 1.5 5 06/12/15 16:16 06/15/15 01:44 7440-24-6 Zinc 12.7 mg/kg 6.2 3.1 5 06/12/15 16:16 06/15/15 01:44 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 6.2 3.1 100 06/12/15 16:16 06/13/1516:28 7440-36-0 N2 Arsenic ND mg/kg 6.2 3.1 100 06/12/15 16:16 06/13/1516:28 7440-38-2 Cadmium ND mg/kg 0.74 0.37 100 06/12/15 16:16 06/13/1516:28 7440-43-9 Cobalt ND mg/kg 6.2 3.1 100 06/12/15 16:16 06/13/1516:28 7440-48-4 Lead ND mg/kg 6.2 3.1 100 06/12/15 16:16 06/13/1516:28 7439-92-1 Selenium ND mg/kg 6.2 3.1 100 06/12/15 16:16 06/13/1516:28 7782-49-2 Thallium ND mg/kg 6.2 3.1 100 06/12/15 16:16 06/13/1516:28 7440-28-0 Vanadium 11.9 mg/kg 6.2 3.1 100 06/12/15 16:16 06/13/1516:28 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.011 mg/kg 0.010 0.0050 1 06/12/1516:30 06/16/1512:42 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 19.7 % 0.10 0.10 1 07/06/15 09:45 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 4.9 Std. Units 0.10 0.10 1 06/14/15 15:00 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 316 158 5 06/11/15 05:47 16887-00-6 D3 Sulfate ND mg/kg 316 158 5 06/11/15 05:47 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 31.6 15.8 5 06/11/15 05:47 14797-55-8 H3 Date: 07/06/2015 01:32 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 28 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K� %fir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060206 Pace Project No.: 92253195 Sample: 2015017621 Lab ID: 92253195004 Collected: 06/02/15 11:20 Received: 06/05/15 14:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Analytical Method: EPA 9060 Modified Surrogates RPD% 27.8 % 0.10 0.10 1 06/28/15 08:56 Total Organic Carbon 6520 mg/kg 744 372 1 06/28/15 08:56 7440-44-0 Total Organic Carbon 4930 mg/kg 751 375 1 06/28/15 09:03 7440-44-0 Mean Total Organic Carbon 5730 mg/kg 747 374 1 06/28/15 08:56 7440-44-0 Date: 07/06/2015 01:32 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 29 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060206 Pace Project No.: 92253195 Sample: 2015017619 SPLP Lab ID: 92253195005 Collected: 06/02/15 10:01 Received: 06/05/15 14:45 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 07/06/2015 01:32 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 234 ug/L 10.0 3.0 1 06/29/15 10:21 07/01/15 01:10 7429-90-5 2.0 ug/L 0.50 0.15 1 06/29/15 10:21 07/01/15 01:10 7440-36-0 39.6 ug/L 0.50 0.11 1 06/29/15 10:21 07/01/15 01:10 7440-38-2 37.1 ug/L 0.30 0.081 1 06/29/15 10:21 07/01/15 01:10 7440-39-3 ND ug/L 0.20 0.067 1 06/29/15 10:21 07/01/15 01:10 7440-41-7 659 ug/L 25.0 5.6 5 06/29/15 10:21 07/02/15 08:42 7440-42-8 ND ug/L 0.080 0.024 1 06/29/15 10:21 07/01/15 01:10 7440-43-9 23100 ug/L 200 80.0 5 06/29/15 10:21 07/02/15 08:42 7440-70-2 18.3 ug/L 0.50 0.17 1 06/29/15 10:21 07/01/15 01:10 7440-47-3 ND ug/L 0.50 0.13 1 06/29/15 10:21 07/01/15 01:10 7440-48-4 0.65J ug/L 1.0 0.21 1 06/29/15 10:21 07/01/15 01:10 7440-50-8 24.3J ug/L 50.0 13.7 1 06/29/15 10:21 07/01/15 01:10 7439-89-6 0.16 ug/L 0.10 0.046 1 06/29/15 10:21 07/01/15 01:10 7439-92-1 58.0 ug/L 10.0 3.2 1 06/29/15 10:21 07/01/15 01:10 7439-95-4 2.6 ug/L 0.50 0.24 1 06/29/15 10:21 07/01/15 01:10 7439-96-5 8.0 ug/L 0.50 0.094 1 06/29/15 10:21 07/01/15 01:10 7439-98-7 0.26J ug/L 0.50 0.16 1 06/29/15 10:21 07/01/15 01:10 7440-02-0 98.8 ug/L 50.0 11.7 1 06/29/15 10:21 07/01/15 01:10 7440-09-7 0.55 ug/L 0.50 0.20 1 06/29/15 10:21 07/01/15 01:10 7782-49-2 1180 ug/L 50.0 16.3 1 06/29/15 10:21 07/01/15 01:10 7440-23-5 150 ug/L 0.50 0.13 1 06/29/15 10:21 07/01/15 01:10 7440-24-6 ND ug/L 0.10 0.015 1 06/29/15 10:21 07/01/15 01:10 7440-28-0 120 ug/L 1.0 0.28 1 06/29/15 10:21 07/01/15 01:10 7440-62-2 6.0 ug/L 5.0 2.4 1 06/29/15 10:21 07/01/15 01:10 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 06/29/1514:30 07/01/1518:03 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 30 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3 %fir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060206 Pace Project No.: 92253195 Sample: 2015017620 SPLP Lab ID: 92253195006 Collected: 06/02/15 11:30 Received: 06/05/15 14:45 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 07/06/2015 01:32 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 921 ug/L 10.0 3.0 1 06/29/15 10:21 07/01/15 01:14 7429-90-5 4.6 ug/L 0.50 0.15 1 06/29/15 10:21 07/01/15 01:14 7440-36-0 143 ug/L 0.50 0.11 1 06/29/15 10:21 07/01/15 01:14 7440-38-2 149 ug/L 0.30 0.081 1 06/29/15 10:21 07/01/15 01:14 7440-39-3 0.45 ug/L 0.20 0.067 1 06/29/15 10:21 07/01/15 01:14 7440-41-7 155 ug/L 5.0 1.1 1 06/29/15 10:21 07/01/15 01:14 7440-42-8 0.074J ug/L 0.080 0.024 1 06/29/15 10:21 07/01/15 01:14 7440-43-9 6460 ug/L 40.0 16.0 1 06/29/15 10:21 07/01/15 01:14 7440-70-2 15.7 ug/L 0.50 0.17 1 06/29/15 10:21 07/01/15 01:14 7440-47-3 0.83 ug/L 0.50 0.13 1 06/29/15 10:21 07/01/15 01:14 7440-48-4 10.8 ug/L 1.0 0.21 1 06/29/15 10:21 07/01/15 01:14 7440-50-8 302 ug/L 50.0 13.7 1 06/29/15 10:21 07/01/15 01:14 7439-89-6 1.9 ug/L 0.10 0.046 1 06/29/15 10:21 07/01/15 01:14 7439-92-1 1580 ug/L 10.0 3.2 1 06/29/15 10:21 07/01/15 01:14 7439-95-4 8.1 ug/L 0.50 0.24 1 06/29/15 10:21 07/01/15 01:14 7439-96-5 4.4 ug/L 0.50 0.094 1 06/29/15 10:21 07/01/15 01:14 7439-98-7 2.6 ug/L 0.50 0.16 1 06/29/15 10:21 07/01/15 01:14 7440-02-0 304 ug/L 50.0 11.7 1 06/29/15 10:21 07/01/15 01:14 7440-09-7 0.96 ug/L 0.50 0.20 1 06/29/15 10:21 07/01/15 01:14 7782-49-2 1620 ug/L 50.0 16.3 1 06/29/15 10:21 07/01/15 01:14 7440-23-5 192 ug/L 0.50 0.13 1 06/29/15 10:21 07/01/15 01:14 7440-24-6 0.31 ug/L 0.10 0.015 1 06/29/15 10:21 07/01/15 01:14 7440-28-0 107 ug/L 1.0 0.28 1 06/29/15 10:21 07/01/15 01:14 7440-62-2 10.6 ug/L 5.0 2.4 1 06/29/15 10:21 07/01/15 01:14 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 06/29/1514:30 07/01/1518:06 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 31 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K� %fir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060206 Pace Project No.: 92253195 QC Batch: MERP/13814 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92253195001 METHOD BLANK: 1989756 Matrix: Water Associated Lab Samples: 92253195001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 06/10/1514:06 LABORATORY CONTROL SAMPLE: 1989757 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.0 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1989758 1989759 MS MSD 92253195001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 5.5 5.3 110 106 80-120 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2015 01:32 PM without the written consent of Pace Analytical Services, Inc.. Page 32 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060206 Pace Project No.: 92253195 QC Batch: MERP/14018 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92253195005, 92253195006 METHOD BLANK: 2006739 Matrix: Water Associated Lab Samples: 92253195005, 92253195006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 07/01/1517:33 LABORATORY CONTROL SAMPLE: 2006740 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 4.9 97 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2007452 2007453 MS MSD 92255755005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 5.2 5.3 103 105 80-120 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2015 01:32 PM without the written consent of Pace Analytical Services, Inc.. Page 33 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 1inlc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060206 Pace Project No.: 92253195 QC Batch: MERP/5849 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92253195002, 92253195003, 92253195004 METHOD BLANK: 1240633 Matrix: Solid Associated Lab Samples: 92253195002, 92253195003, 92253195004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0078 06/16/1512:20 LABORATORY CONTROL SAMPLE: 1240634 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .078 0.084 108 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1240635 1240636 MS MSD 92253145025 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg ND .0954 .093 0.10 0.097 106 105 80-120 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2015 01:32 PM without the written consent of Pace Analytical Services, Inc.. Page 34 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060206 Pace Project No.: 92253195 QC Batch: MPRP/24673 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92253195002, 92253195003, 92253195004 METHOD BLANK: 1240559 Matrix: Associated Lab Samples: 92253195002, 92253195003, 92253195004 Blank Parameter Units Result Solid Reporting Limit Analyzed Aluminum mg/kg ND 4.9 06/15/15 00:48 Barium mg/kg ND 0.49 06/15/15 00:48 Beryllium mg/kg ND 0.049 06/15/15 00:48 Boron mg/kg ND 2.4 06/15/15 00:48 Calcium mg/kg ND 24.4 06/15/15 00:48 Chromium mg/kg ND 0.24 06/15/15 00:48 Copper mg/kg ND 0.24 06/15/15 00:48 Iron mg/kg 1.51 1.9 06/15/15 00:48 Magnesium mg/kg ND 24.4 06/15/15 00:48 Manganese mg/kg ND 0.24 06/15/15 00:48 Molybdenum mg/kg ND 0.49 06/15/15 00:48 Nickel mg/kg ND 0.24 06/15/15 00:48 Potassium mg/kg ND 48.7 06/15/15 00:48 Sodium mg/kg ND 48.7 06/15/15 00:48 Strontium mg/kg ND 0.49 06/15/15 00:48 Zinc mg/kg ND 0.97 06/15/15 00:48 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1240560 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 128 126 99 80-120 Barium mg/kg 12.8 12.9 101 80-120 Beryllium mg/kg 1.3 1.3 101 80-120 Boron mg/kg 128 124 97 80-120 Calcium mg/kg 639 644 101 80-120 Chromium mg/kg 12.8 12.7 100 80-120 Copper mg/kg 12.8 12.2 95 80-120 Iron mg/kg 128 128 100 80-120 Magnesium mg/kg 639 641 100 80-120 Manganese mg/kg 12.8 12.6 98 80-120 Molybdenum mg/kg 12.8 12.4 97 80-120 Nickel mg/kg 12.8 12.8 100 80-120 Potassium mg/kg 639 645 101 80-120 Sodium mg/kg 639 669 105 80-120 Strontium mg/kg 12.8 12.5 98 80-120 Zinc mg/kg 63.9 63.0 99 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2015 01:32 PM without the written consent of Pace Analytical Services, Inc.. Page 35 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 I� %fir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060206 Pace Project No.: 92253195 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1240561 1240563 MS MSD 92253145025 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 17900 158 146 15800 15200 -1320 -1830 75-125 4 20 M1 Barium mg/kg 260 15.8 14.6 316 280 355 134 75-125 12 20 M1 Beryllium mg/kg 1.9 1.57 1.45 2.8 2.8 61 65 75-125 0 20 M1 Boron mg/kg ND 158 146 124 115 79 78 75-125 8 20 Calcium mg/kg 3320 790 733 3470 3330 20 2 75-125 4 20 M1 Chromium mg/kg 14.9 15.8 14.6 26.9 27.4 75 85 75-125 2 20 Copper mg/kg 8.6 15.8 14.6 22.7 20.2 89 79 75-125 11 20 Iron mg/kg 25800 158 146 18700 18800 -4470 -4740 75-125 1 20 M1 Magnesium mg/kg 14000 790 733 11300 10700 -342 -451 75-125 5 20 M1 Manganese mg/kg 694 15.8 14.6 599 574 -600 -817 75-125 4 20 M1 Molybdenum mg/kg ND 15.8 14.6 11.6 10.9 73 74 75-125 6 20 M1 Nickel mg/kg 10.8 15.8 14.6 21.1 20.3 65 65 75-125 4 20 M1 Potassium mg/kg 11800 790 733 10500 10100 -164 -237 75-125 4 20 M1 Sodium mg/kg ND 790 733 823 768 93 93 75-125 7 20 Strontium mg/kg 22.8 15.8 14.6 32.0 30.2 58 50 75-125 6 20 M1 Zinc mg/kg 125 79 73.3 155 151 38 35 75-125 3 20 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2015 01:32 PM without the written consent of Pace Analytical Services, Inc.. Page 36 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 I� %fir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060206 Pace Project No.: 92253195 QC Batch: MPRP/24674 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92253195002, 92253195003, 92253195004 METHOD BLANK: 1240564 Matrix: Solid Associated Lab Samples: 92253195002, 92253195003, 92253195004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.050 06/13/1516:08 N2 Arsenic mg/kg ND 0.050 06/13/1516:08 Cadmium mg/kg ND 0.0060 06/13/1516:08 Cobalt mg/kg ND 0.050 06/13/1516:08 Lead mg/kg ND 0.050 06/13/1516:08 Selenium mg/kg ND 0.050 06/13/1516:08 Thallium mg/kg ND 0.050 06/13/1516:08 Vanadium mg/kg ND 0.050 06/13/1516:08 LABORATORY CONTROL SAMPLE: Parameter 1240565 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.6 2.5 96 80-120 N2 Arsenic mg/kg 2.6 2.6 102 80-120 Cadmium mg/kg .26 0.25 99 80-120 Cobalt mg/kg 2.6 2.6 101 80-120 Lead mg/kg 2.6 2.6 101 80-120 Selenium mg/kg 2.6 2.5 96 80-120 Thallium mg/kg 2.6 2.7 104 80-120 Vanadium mg/kg 2.6 2.6 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1240566 1240567 MS MSD 92253145025 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 3.14 3.14 ND ND 52 57 75-125 20 M6, N2 Arsenic mg/kg ND 3.14 3.14 3.2J ND 82 79 75-125 20 Cadmium mg/kg ND .314 .314 ND ND 51 41 75-125 20 M6 Cobalt mg/kg 7.5 3.14 3.14 9.5 9.6 64 67 75-125 1 20 M6 Lead mg/kg ND 3.14 3.14 5.9J 4.5J 118 74 75-125 20 M6 Selenium mg/kg ND 3.14 3.14 ND ND 63 49 75-125 20 M6 Thallium mg/kg ND 3.14 3.14 3.3J 3AJ 91 93 75-125 20 Vanadium mg/kg 84.5 3.14 3.14 86.0 88.0 48 115 75-125 2 20 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2015 01:32 PM without the written consent of Pace Analytical Services, Inc.. Page 37 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 I� %fir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060206 Pace Project No.: 92253195 QC Batch: MPRP/55069 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92253195001 METHOD BLANK: 1989760 Associated Lab Samples: 92253195001 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 06/10/1516:43 ND 0.50 06/10/1516:43 ND 0.50 06/10/1516:43 ND 0.30 06/10/1516:43 ND 0.20 06/10/1516:43 ND 5.0 06/10/1516:43 ND 0.080 06/10/1516:43 ND 40.0 06/10/1516:43 ND 0.50 06/10/1516:43 ND 0.50 06/10/1516:43 ND 1.0 06/10/1516:43 ND 50.0 06/10/1516:43 ND 0.10 06/10/1516:43 ND 10.0 06/10/1516:43 ND 0.50 06/10/1516:43 ND 0.50 06/10/1516:43 ND 0.50 06/10/1516:43 ND 50.0 06/11/15 07:45 ND 0.50 06/10/1516:43 ND 50.0 06/10/1516:43 ND 0.50 06/10/1516:43 ND 0.10 06/10/1516:43 ND 1.0 06/10/1516:43 ND 5.0 06/10/1516:43 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1989761 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 77.9 97 80-120 Antimony ug/L 80 76.4 96 80-120 Arsenic ug/L 80 77.6 97 80-120 Barium ug/L 80 81.3 102 80-120 Beryllium ug/L 80 80.8 101 80-120 Boron ug/L 80 78.3 98 80-120 Cadmium ug/L 80 77.2 96 80-120 Calcium ug/L 1000 955 95 80-120 Chromium ug/L 80 79.4 99 80-120 Cobalt ug/L 80 84.9 106 80-120 Copper ug/L 80 81.3 102 80-120 Iron ug/L 1000 1030 103 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2015 01:32 PM without the written consent of Pace Analytical Services, Inc.. Page 38 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 I� %fir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060206 Pace Project No.: 92253195 LABORATORY CONTROL SAMPLE: 1989761 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 78.1 98 80-120 Magnesium ug/L 1000 985 98 80-120 Manganese ug/L 80 75.2 94 80-120 Molybdenum ug/L 80 77.2 97 80-120 Nickel ug/L 80 78.9 99 80-120 Potassium ug/L 1000 1020 102 80-120 Selenium ug/L 80 78.9 99 80-120 Sodium ug/L 1000 1010 101 80-120 Strontium ug/L 80 75.3 94 80-120 Thallium ug/L 80 82.9 104 80-120 Vanadium ug/L 80 77.2 96 80-120 Zinc ug/L 80 80.8 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1989762 1989763 MS MSD 92253161011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 173 80 80 333 345 200 215 75-125 4 20 M1 Antimony ug/L ND 80 80 76.3 76.2 95 95 75-125 0 20 Arsenic ug/L ND 80 80 79.7 78.9 100 99 75-125 1 20 Barium ug/L 1.2 80 80 77.8 77.6 96 95 75-125 0 20 Beryllium ug/L ND 80 80 82.9 80.1 104 100 75-125 3 20 Boron ug/L ND 80 80 76.6 74.2 96 93 75-125 3 20 Cadmium ug/L ND 80 80 78.1 78.0 98 98 75-125 0 20 Calcium ug/L 168 1000 1000 1180 1170 102 100 75-125 2 20 Chromium ug/L 1.9 80 80 80.9 81.0 99 99 75-125 0 20 Cobalt ug/L ND 80 80 78.1 77.8 97 97 75-125 0 20 Copper ug/L 1.2 80 80 82.0 82.2 101 101 75-125 0 20 Iron ug/L 333 1000 1000 1420 1420 109 109 75-125 0 20 Lead ug/L 0.053J 80 80 78.4 77.7 98 97 75-125 1 20 Magnesium ug/L 42.1 1000 1000 1050 1020 100 98 75-125 3 20 Manganese ug/L 5.3 80 80 80.8 80.4 94 94 75-125 0 20 Molybdenum ug/L 0.39J 80 80 77.2 78.7 96 98 75-125 2 20 Nickel ug/L 0.32J 80 80 79.7 79.1 99 98 75-125 1 20 Potassium ug/L 39.OJ 1000 1000 1010 1040 98 100 75-125 2 20 Selenium ug/L ND 80 80 83.5 78.3 104 98 75-125 6 20 Sodium ug/L 33.9J 1000 1000 928 915 89 88 75-125 1 20 Strontium ug/L 1.2 80 80 77.6 76.7 96 94 75-125 1 20 Thallium ug/L ND 80 80 83.9 82.8 105 103 75-125 1 20 Vanadium ug/L ND 80 80 76.5 77.2 95 96 75-125 1 20 Zinc ug/L ND 80 80 84.9 80.9 104 99 75-125 5 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2015 01:32 PM without the written consent of Pace Analytical Services, Inc.. Page 39 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060206 Pace Project No.: 92253195 QC Batch: MPRP/55571 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92253195005, 92253195006 METHOD BLANK: 2006731 Associated Lab Samples: 92253195005, 92253195006 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 07/01/15 00:15 ND 0.50 07/01/15 00:15 ND 0.50 07/01/15 00:15 ND 0.30 07/01/15 00:15 ND 0.20 07/01/15 00:15 ND 5.0 07/01/15 00:15 ND 0.080 07/01/15 00:15 ND 40.0 07/02/15 07:11 ND 0.50 07/01/15 00:15 ND 0.50 07/01/15 00:15 ND 1.0 07/02/15 07:11 ND 50.0 07/01/15 00:15 ND 0.10 07/01/15 00:15 ND 10.0 07/01/15 00:15 ND 0.50 07/01/15 00:15 ND 0.50 07/01/15 00:15 ND 0.50 07/01/15 00:15 ND 50.0 07/01/15 00:15 ND 0.50 07/01/15 00:15 ND 50.0 07/01/15 00:15 ND 0.50 07/01/15 00:15 ND 0.10 07/01/15 00:15 ND 1.0 07/01/15 00:15 ND 5.0 07/01/15 00:15 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 2006732 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 76.1 95 80-120 Antimony ug/L 80 76.2 95 80-120 Arsenic ug/L 80 77.5 97 80-120 Barium ug/L 80 79.1 99 80-120 Beryllium ug/L 80 82.0 103 80-120 Boron ug/L 80 87.1 109 80-120 Cadmium ug/L 80 77.9 97 80-120 Calcium ug/L 1000 1030 103 80-120 Chromium ug/L 80 78.1 98 80-120 Cobalt ug/L 80 78.4 98 80-120 Copper ug/L 80 77.4 97 80-120 Iron ug/L 1000 976 98 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2015 01:32 PM without the written consent of Pace Analytical Services, Inc.. Page 40 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 I� %fir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060206 Pace Project No.: 92253195 LABORATORY CONTROL SAMPLE: 2006732 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 77.0 96 80-120 Magnesium ug/L 1000 964 96 80-120 Manganese ug/L 80 78.4 98 80-120 Molybdenum ug/L 80 76.8 96 80-120 Nickel ug/L 80 78.2 98 80-120 Potassium ug/L 1000 979 98 80-120 Selenium ug/L 80 78.2 98 80-120 Sodium ug/L 1000 994 99 80-120 Strontium ug/L 80 77.3 97 80-120 Thallium ug/L 80 76.6 96 80-120 Vanadium ug/L 80 78.6 98 80-120 Zinc ug/L 80 77.2 97 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2007450 2007451 MS MSD 92255755020 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 5.6J 80 80 94.1 93.8 111 110 75-125 0 20 Antimony ug/L ND 80 80 78.5 76.7 98 96 75-125 2 20 Arsenic ug/L ND 80 80 81.1 77.9 101 97 75-125 4 20 Barium ug/L 0.26J 80 80 80.8 79.3 101 99 75-125 2 20 Beryllium ug/L ND 80 80 79.8 80.6 100 101 75-125 1 20 Boron ug/L ND 80 80 84.4 81.9 104 101 75-125 3 20 Cadmium ug/L ND 80 80 80.7 79.4 101 99 75-125 2 20 Calcium ug/L 76.6 1000 1000 1100 1090 103 101 75-125 2 20 Chromium ug/L ND 80 80 81.2 79.1 101 99 75-125 3 20 Cobalt ug/L ND 80 80 82.2 78.6 103 98 75-125 4 20 Copper ug/L 0.32J 80 80 81.9 78.9 102 98 75-125 4 20 Iron ug/L 14.7J 1000 1000 1030 996 101 98 75-125 3 20 Lead ug/L ND 80 80 79.3 77.2 99 97 75-125 3 20 Magnesium ug/L 7.9J 1000 1000 1030 1000 102 99 75-125 3 20 Manganese ug/L 0.42J 80 80 81.6 80.2 102 100 75-125 2 20 Molybdenum ug/L ND 80 80 80.0 78.7 100 98 75-125 2 20 Nickel ug/L ND 80 80 84.0 80.4 105 100 75-125 4 20 Potassium ug/L 18.5J 1000 1000 1050 1030 104 101 75-125 3 20 Selenium ug/L ND 80 80 82.1 78.6 103 98 75-125 4 20 Sodium ug/L 31.9J 1000 1000 1070 1010 104 97 75-125 6 20 Strontium ug/L 0.50 80 80 80.6 79.8 100 99 75-125 1 20 Thallium ug/L ND 80 80 81.1 79.2 101 99 75-125 2 20 Vanadium ug/L ND 80 80 82.0 79.4 102 99 75-125 3 20 Zinc ug/L 8.0 80 80 92.6 83.4 106 94 75-125 10 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2015 01:32 PM without the written consent of Pace Analytical Services, Inc.. Page 41 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 I� %fir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060206 Pace Project No.: 92253195 QC Batch: PMST/7948 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92253195002, 92253195003, 92253195004 SAMPLE DUPLICATE: 1478682 92251982001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 31.7 26.1 19 25 SAMPLE DUPLICATE: 1478683 92253195004 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 19.7 19.4 2 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2015 01:32 PM without the written consent of Pace Analytical Services, Inc.. Page 42 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Ij %fir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060206 Pace Project No.: 92253195 QC Batch: WET/38033 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92253195002, 92253195003, 92253195004 SAMPLE DUPLICATE: 1481715 92253352003 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 7.2 7.0 3 10 D6 SAMPLE DUPLICATE: 1481716 92253161005 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 5.4 5.0 8 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2015 01:32 PM without the written consent of Pace Analytical Services, Inc.. Page 43 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 1j nl c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060206 Pace Project No.: 92253195 QC Batch: WETA/23324 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92253195002, 92253195003 METHOD BLANK: 1485896 Matrix: Water Associated Lab Samples: 92253195002, 92253195003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L 2.3 2.0 06/16/1515:20 LABORATORY CONTROL SAMPLE: 1485897 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 19.6 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1485898 1485899 MS MSD 92252532003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 6.3 20 20 26.0 26.2 98 99 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2015 01:32 PM without the written consent of Pace Analytical Services, Inc.. Page 44 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060206 Pace Project No.: 92253195 QC Batch: WETA/23372 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92253195002, 92253195003 METHOD BLANK: 1488925 Matrix: Water Associated Lab Samples: 92253195002, 92253195003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L 0.14 0.020 06/18/15 17:00 Z2 LABORATORY CONTROL SAMPLE: 1488926 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.5 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1488927 1488928 MS MSD 92252532003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L ND 2.5 2.5 2.6 2.6 98 97 90-110 1 10 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2015 01:32 PM without the written consent of Pace Analytical Services, Inc.. Page 45 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060206 Pace Project No.: 92253195 QC Batch: WETA/23354 Analysis Method: SM 4500-CI-E QC Batch Method: SM 4500-CI-E Analysis Description: 4500 Chloride Associated Lab Samples: 92253195002 METHOD BLANK: 1487997 Matrix: Water Associated Lab Samples: 92253195002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 06/18/15 04:51 LABORATORY CONTROL SAMPLE: 1487998 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 19.8 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1487999 1488000 MS MSD 92252532003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 20 20 17.3 17.4 86 86 90-110 0 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2015 01:32 PM without the written consent of Pace Analytical Services, Inc.. Page 46 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Ijc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060206 Pace Project No.: 92253195 QC Batch: WETA/23374 Analysis Method: SM 4500-CI-E QC Batch Method: SM 4500-CI-E Analysis Description: 4500 Chloride Associated Lab Samples: 92253195003 METHOD BLANK: 1489297 Matrix: Water Associated Lab Samples: 92253195003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 06/19/15 05:16 LABORATORY CONTROL SAMPLE: 1489298 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 20.3 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1489299 1489300 MS MSD 92253890015 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 45.6 45.6 49.6 49.7 109 109 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1489301 1489302 MS MSD 92254310001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 28.1 28.1 29.5 29.4 101 101 90-110 0 10 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2015 01:32 PM without the written consent of Pace Analytical Services, Inc.. Page 47 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060206 Pace Project No.: 92253195 QC Batch: WETA/47190 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92253195002, 92253195003, 92253195004 METHOD BLANK: 1238041 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.9 06/11/15 08:38 Sulfate mg/kg ND 49.9 06/11/15 08:38 LABORATORY CONTROL SAMPLE: 1238042 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1238044 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1238043 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 502 472 94 80-120 502 470 94 80-120 92253145022 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 653 576 88 80-120 ND 653 656 85 80-120 92253145022 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2015 01:32 PM without the written consent of Pace Analytical Services, Inc.. Page 48 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060206 Pace Project No.: 92253195 QC Batch: WETA/47192 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92253195002, 92253195003, 92253195004 METHOD BLANK: 1238051 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 06/11/15 08:38 LABORATORY CONTROL SAMPLE: 1238052 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 50.2 49.4 98 80-120 MATRIX SPIKE SAMPLE: 1238054 92253145022 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 65.3 60.8 91 80-120 H3 SAMPLE DUPLICATE: 1238053 92253145022 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2015 01:32 PM without the written consent of Pace Analytical Services, Inc.. Page 49 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Ijc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060206 Pace Project No.: 92253195 QC Batch: WETA/29243 Analysis Method: EPA 9060 Modified QC Batch Method: EPA 9060 Modified Analysis Description: 9060 TOC Average Associated Lab Samples: 92253195002, 92253195003, 92253195004 METHOD BLANK: 1184234 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 06/27/15 16:37 LABORATORY CONTROL SAMPLE: 1184235 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 116000 96 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1184236 1184237 MS MSD 92253195003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 49200 37200 37200 95100 93500 123 119 50-150 2 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1184238 1184239 MS MSD 92253195002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 85100 62800 61900 149000 147000 102 100 50-150 2 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2015 01:32 PM without the written consent of Pace Analytical Services, Inc.. Page 50 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Ij %fir&e. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J15060206 Pace Project No.: 92253195 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: ICPM/10002 Ill Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. Batch: ICP/15063 Ill Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H1 Analysis conducted outside the EPA method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2015 01:32 PM without the written consent of Pace Analytical Services, Inc.. Page 51 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Ij %fir&e. Suite 100 Huntersville, INC 28078 (704)875-9092 QUALIFIERS Project: J15060206 Pace Project No.: 92253195 ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TIN accreditation for this parameter. Z2 Analyte present in the associated method blank above the detection limit. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2015 01:32 PM without the written consent of Pace Analytical Services, Inc.. Page 52 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: J15060206 92253195 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92253195002 2015017619 EPA 3050 MPRP/24673 EPA 6010 ICP/15063 92253195003 2015017620 EPA 3050 MPRP/24673 EPA 6010 ICP/15063 92253195004 2015017621 EPA 3050 MPRP/24673 EPA 6010 1CP/15063 92253195002 2015017619 EPA 3050 MPRP/24674 EPA 6020 ICPM/10002 92253195003 2015017620 EPA 3050 MPRP/24674 EPA 6020 ICPM/10002 92253195004 2015017621 EPA 3050 MPRP/24674 EPA 6020 ICPM/10002 92253195001 2015017618 EPA 3020 MPRP/55069 EPA 6020A ICPM/24739 92253195005 2015017619 SPLP EPA 3020 MPRP/55571 EPA 6020A ICPM/25109 92253195006 2015017620 SPLP EPA 3020 MPRP/55571 EPA 6020A ICPM/25109 92253195001 2015017618 EPA 7470A MERP/13814 EPA 7470A MERC/16086 92253195005 2015017619 SPLP EPA 7470A MERP/14018 EPA 7470A MERC/16364 92253195006 2015017620 SPLP EPA 7470A MERP/14018 EPA 7470A MERC/16364 92253195002 2015017619 EPA 7471 MERP/5849 EPA 7471 MERC/5838 92253195003 2015017620 EPA 7471 MERP/5849 EPA 7471 MERC/5838 92253195004 2015017621 EPA 7471 MERP/5849 EPA 7471 MERC/5838 92253195002 2015017619 ASTM D2974-87 PMST/7948 92253195003 2015017620 ASTM D2974-87 PMST/7948 92253195004 2015017621 ASTM D2974-87 PMST/7948 92253195002 2015017619 EPA 9045 WET/38033 92253195003 2015017620 EPA 9045 WET/38033 92253195004 2015017621 EPA 9045 WET/38033 92253195002 2015017619 EPA 300.0 WETA/23324 92253195003 2015017620 EPA 300.0 WETA/23324 92253195002 2015017619 EPA 353.2 WETA/23372 92253195003 2015017620 EPA 353.2 WETA/23372 92253195002 2015017619 SM 4500-CI-E WETA/23354 92253195003 2015017620 SM 4500-CI-E WETA/23374 92253195002 2015017619 EPA 9056 WETA/47190 92253195003 2015017620 EPA 9056 WETA/47190 92253195004 2015017621 EPA 9056 WETA/47190 92253195002 2015017619 EPA 9056 WETA/47192 92253195003 2015017620 EPA 9056 WETA/47192 92253195004 2015017621 EPA 9056 WETA/47192 92253195002 2015017619 EPA 9060 Modified WETA/29243 92253195002 2015017619 EPA 9060 Modified WETA/29249 92253195003 2015017620 EPA 9060 Modified WETA/29243 92253195003 2015017620 EPA 9060 Modified WETA/29249 92253195004 2015017621 EPA 9060 Modified WETA/29243 92253195004 2015017621 EPA 9060 Modified WETA/29249 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2015 01:32 PM without the written consent of Pace Analytical Services, Inc.. Page 53 of 56 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 1�nlc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15060206 Pace Project No.: 92253195 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/06/2015 01:32 PM without the written consent of Pace Analytical Services, Inc.. Page 54 of 56 Document Name: aceAnalytical' Sample Condition Upon Receil Document Number: F-CHR-CS-003-rev.16 Document rtevisea: may i o, `u i a UR Page 1 of 2* Issuing Authority: 62 of 64 Pace Huntersville Quality Office Client Name:_ 12, r,,e— nor/ . Page 2 of 2 Is for Internal Use Only Courier: ❑Fed Ex ❑ UPS[] LISPS❑ Client❑ C ercial❑ PcQlOther�' Custody Seal on Cooler/Box Present: ❑ no Seals intact: Elyes ❑ no ti Packing Material; ❑ Bubble VDp Bubble Bags ❑ None ❑ Other Thermometer Used: IR Gun�1� Type of Ice: 6e .-4lue None Samples on ice, cooling process has begun r.....- n..- Fs ,., ram. #— TIAn4 hie (nrrar_finn Corrected Cooler Ternp.: °C Biological Tissue is Frazee: Yes No Nr Temp should be above freezing to WC Comments: Date and Initials of person examining contents: r Chain,of Custody Present: 2te;IdN. ❑NIA 1. Chain of Custody Filled Out: llyes o El NIA 2. Chain of Custody Relinquished: 2<es o ❑NIA 3. Sampler Name & Signature on COC: es o ❑NIA 4. Samples Arrived within Hold Time: es ❑No N/A 5. Short Hold Time Analysis (<72hr): Dyes Na eZNA 6. Rush Turn Around Time Requested: Dyes o ❑NIA 7. Sufficient Volume: Ofs J2,95 ❑NIA 8. Correct Containers Used: es ❑No NIA -Pace Containers Used: ❑Yes o ❑NIA 9. Containers Intact: es ❑No ❑NIA Filtered volume received for Dissolved tests ❑Yes No EM61A 11. Sample Labels match COC: es ❑No ❑N/A -includes date/time/ID/Analysis Matrix: 12. b ❑N1A All containers needing preservation have been checked. 7.,0 All containers needing preservation are found to be in o ❑ IA compliance with EPA recommendation. exceptions: VOA, coliforra, TOC, O&G, W -DRO (water) Dyes ❑ o 13. Samples checked for dechlorination: Dyes ❑No G r 14. Headspace in VOA Vials (>6mm): Dyes ❑No dN!P, 15. Trip Blank Present: Dyes ❑No Trip Blank Custody Seals Present ❑Yes ❑No t/A Pace Trip -Blank Lot # if purchased): 16. Client Notification/ Resolution: Person Contacted: Comments/ Resolution: Date/Time: SRF Review: ► Date: 1 tp Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DBHNR Certification Office (Le out of hold, incorrect preservative, out of temp, incorrect containers) Field Data Required? Y 1 N 5319�iiiiiiii�iiii Page 55 of 56 Cl- 2 i 63 of 64 Customer must omp ele _ N Cuslomer to complete appropriate columns to right m S , 14. = a c t P P m a a Y 1 t, �+ O 1 _ Y N Q � O v ra m 3 w u u o j G 4 Y 0 o o qz 3 a n > o n �1 7 a O ^ c C C O D0 CL w s m Y P = a 0 + a v o ID G) w C : N �. E.5 N am cr n ° �^ O p 181 13, a a rG 0 O t S K o a 5 n a N o P n A O gw m o a mg o< e /• O a Q. b r n. o 4 v * - A n q T M _ c' � -0 -0 Q pia 0 � \ y, !m N K 3 ro CD I i oo {moo `�• 1-\0 y Ir j O 1 0 Ma 1 - is p e L'4 i Z o� Aza sN—� i❑ i� 19 o O I6A ai 5 5 u u C1 Z iia fComp. ►<, K Grab Req ire A -1 CD i EA Total Metals , Anions,; pH n 1-iW 1- 8 oz jar SPACE,) 5 o i l G .Id f/,/s @ i ti j A r r �TOC 4- 4 oz jar 4 3 C i M (PACE) I 0 m 1 (/) SPLP - Total Metals ''—i T! N N and Anions j 2 - 8 oz jars (PACE) 5 ; O 1 i� Sediment specific 1 tests 2 •8 oz Jar (ACCESS i ANALYTICAL) 5 M�'A44 1 _,ii=, OX. (A s _ �ous C Di m M C z�- p Page 56 of 56 2OTolal of Containers CHAIN OF CUSTODY RECORDANALYSIS REQUEST FORM � - loly i;Ldrv- am i----_.-------.-N_a_,_.:,__ --A-----D __............... ._. Analytical Laborato UsOn efat., DUKE Mail soda MGiiS►3 1Sulldlr19 i&OSI 1.1339 Haorrs Farry Rd wwtOr lrr 7 ff 1L — ': ENERGY.Y Hunieramil s. tr. C` 2107E `ir ea beet ll s.m t In*rin From _ 1990I 974-9245 ; � fJ � 1 � � fix: 98G B73 4yr9°� ,._•-------- ,.�. __�__._____,o,.._._•_.,.--1 �.. � _ SAMPLE PRCBRl4M C,r04rYI 'rYsHleT � 7IPrp}rgr r� - �kiS C�rpt�nriwat�r ASstsssment - $041 pJFtiur�r toe: iWinAor Qmer_ i marg } a ip{ Pace _ � Tenn s C. #J Hirt 41FeN lift: ,t PQ 1142081 `°Pr_:.1 H ' AB fsNl i reeert'tirner S 1w 4jEurFn®qunit 'flFn#JECt K+; u rII Oral" unit i IiUjlxlrr 117 When specific ac cuuntiog has been eetab1i61rad MW is not Indicated ■b4ue 1Ye need the ftAlwalim2: 11 Eaiter carrwi accorirrt7ng In all 6 orcoun*N fleld5 above, Of 21 Pra,Itdo Corr v asccautl ray for pneratlna Un1t and Process ID. I LAB L-SE OWY I I i Matrlx Boll, 3ralmeM, AmhI "Sample Description or ID (rl9 MAIN -ti _ i!'r �J } i o. i - i r �, I i I I I 1 1 ... y F11R�IlnriulrMd @}' Uatsltim■ '/ Rrll++9undi4d by Oam)r..m■ r - Cb _- iYaYalTrrne tryOW&-. Al, Sb. As, Ba, Be, B. Cd, Ca, Cr, Co, CU. Fa, Pb, My, Ml Anions: CO. Nitrate-N, SO4 Sediment SplRe flC Parametem �.G Lt �, ter, P S {•f `tfLl u =lee =Nona j 617 c• In u} ustu rte Ctam a >rll ,� C eo A fcrariat� arm. UrC LU w a �s A PreiservativCs when used rnurl Its -_- yy s� C1. V H _ CL _ 0 N l added with ln 15 minufeg 9t sarrljkle 0fib co � collection i'--' •� a In Q1 N (A "Coll$Gtloll lraforLU maii t7 —. c .tea `� r C] H d � 5 .5 (J -j O.am SS nQal/ure O 2 ~ � i--' �' CL L r LW) ICI iv '; o 1� ,,yTTlma y 'i I k 1120 M=- AA-Z. ev: LtxTefnma frv— Mt. K, Se, Na, Sr, 71, V, Yrt, Mercury, PH lids CEC, PariieleSize iNSlriburtion RedoaPntential Syr terra EDD ORI€,Ia io LA.B COPY ltt C 111 N r $rl W0Lj 5 V.Requested Turnaround la a®rs �s •r fs�xa T -iB W