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Home My WebLink AboutNC0038377_J15060059 Report_20150902+ DUKE Analytical Laboratory 1 of59 ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report J15060059 MAYO STEAM - AB GW ASSESSMENT SOIL Tim Hunsucker, Jerry Wylie, Kathy Webb, John Toepfer Margaret Galvin -Karr MXG4644(101161) 2015.07.06 08:34:32 Q I�FCK-04'00' Margaret Galvin -Karr Phone: 980-875-5219 Date: Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 7/6/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: 2 of 59 Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015016946 MAYO STEAM 31-May-15 10:30 AM Erin Black ABMW-2BR-EB 2015016947 MAYO STEAM 31-May-15 11:15 AM Erin Black ABMW-2BR (45.0-45.5) 2015016948 MAYO STEAM 31-May-15 4:15 PM Erin Black ABMW-2BR (57.5-58.0) 3 Total Samples 3 of 59 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes❑ No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 66 Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately Reviewed By: Margaret Galvin -Karr Date: 7/6/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060059 Site: ABMW-2BR-EB Collection Date: 31-May-15 10:30 AM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015016946 Matrix: SOIL 4 of 59 Method Analysis Date/Time Analyst Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060059 Site: ABMW-2BR (45.0-45.5) Collection Date: 31-Mav-15 11:15 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 5 of 59 Sample #: 2015016947 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060059 Site: ABMW-2BR (57.5-58.0) Collection Date: 31-May-15 4:15 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 6 of 59 Sample #: 2015016948 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE -- Additional Information -- SPLP sulfate blank is 2.3 mg/L. Associated sample results are less than 10 times this number and are therefore suspect. MG-K 7/6/15 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kic&fie. Suite 100 Huntersville, INC 28078 (704)875-9092 July 03, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J 15060059 Pace Project No.: 92252534 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on June 02, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Mary Ann Ogle, Duke Energy Rodney Wilke, Duke Energy p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 52 lacmnalyfica( www.pacelabs.com Pace Analytical Services, Inc. 9800 Kinf.W. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060059 Pace Project No.: 92252534 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21-A Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 North Carolina Drinking Water Certification #: 37712 Florida/NELAP Certification #: E87648 North Carolina Wastewater Certification #: 40 Massachusetts Certification #: M-NC030 South Carolina Certification #: 99030001 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Kig,8y&je. Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Project: J15060059 Pace Project No.: 92252534 Asheville Certification IDs West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ff�i�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: J15060059 Pace Project No.: 92252534 Lab ID Sample ID Matrix Date Collected Date Received 92252534001 2015016946 Water 05/31/1510:30 06/02/15 16:30 92252534002 2015016947 Solid 05/31/1511:15 06/02/15 16:30 92252534003 2015016948 Solid 05/31/1516:15 06/02/15 16:30 92252534004 2015016947 SPLP Water 05/31/15 11:15 06/02/15 16:30 92252534005 2015016948 SPLP Water 05/31/15 16:15 06/02/15 16:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 fflinl c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: J15060059 92252534 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92252534001 2015016946 EPA 6020A RJS 24 PASI-M EPA 7470A LMW 1 PASI-M 92252534002 2015016947 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G 92252534003 2015016948 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500-CI-E SER 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 TJJ 6 PASI-G 92252534004 2015016947 SPLP EPA 6020A RJS 24 PASI-M EPA 7470A LMW 1 PASI-M 92252534005 2015016948 SPLP EPA 6020A RJS 24 PASI-M EPA 7470A LMW 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060059 Pace Project No.: 92252534 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92252534001 2015016946 EPA 6020A Aluminum 3.8J ug/L 10.0 06/10/15 11:43 EPA 6020A Calcium 19.5J ug/L 40.0 06/10/15 11:43 EPA 6020A Cobalt 0.26J ug/L 0.50 06/10/15 11:43 EPA 6020A Iron 18.OJ ug/L 50.0 06/10/15 11:43 EPA 6020A Magnesium 3.5J ug/L 10.0 06/10/15 11:43 EPA 6020A Manganese 0.37J ug/L 0.50 06/10/15 11:43 92252534002 2015016947 EPA 6010 Aluminum 6900 mg/kg 30.0 06/10/15 15:18 M1 EPA 6010 Barium 92.2 mg/kg 3.0 06/10/15 15:18 M1 EPA 6010 Beryllium 0.44 mg/kg 0.30 06/10/15 15:18 EPA 6010 Calcium 1640 mg/kg 150 06/10/15 15:18 EPA 6010 Chromium 8.0 mg/kg 1.5 06/10/15 15:18 EPA 6010 Copper 72.7 mg/kg 1.5 06/10/15 15:18 M1 EPA 6010 Iron 18300 mg/kg 12.0 06/10/15 15:18 M1 EPA 6010 Magnesium 4170 mg/kg 150 06/10/15 15:18 EPA 6010 Manganese 579 mg/kg 1.5 06/10/15 15:18 M1 EPA 6010 Nickel 4.8 mg/kg 1.5 06/10/15 15:18 EPA 6010 Potassium 329 mg/kg 300 06/10/15 15:18 EPA 6010 Sodium 353 mg/kg 300 06/10/15 15:18 EPA 6010 Strontium 23.2 mg/kg 3.0 06/10/15 15:18 EPA 6010 Zinc 39.8 mg/kg 6.0 06/10/15 15:18 EPA 6020 Cobalt 6.OJ mg/kg 6.0 06/10/15 10:58 M6 EPA 6020 Lead 3.1J mg/kg 6.0 06/10/15 10:58 EPA 6020 Vanadium 30.3 mg/kg 6.0 06/10/15 10:58 M6 ASTM D2974-87 Percent Moisture 14.2 % 0.10 06/10/15 08:15 EPA 9045 pH at 25 Degrees C 7.8 Std. Units 0.10 06/10/15 12:30 EPA 300.0 Sulfate 3.1 mg/L 2.3 06/16/15 16:28 B EPA 9060 RSD% 8.2 % 06/25/15 10:20 92252534003 2015016948 EPA 6010 Aluminum 20200 mg/kg 25.5 06/10/15 15:30 EPA 6010 Barium 41.2 mg/kg 2.6 06/10/15 15:30 EPA 6010 Beryllium 0.26 mg/kg 0.26 06/10/15 15:30 EPA 6010 Calcium 7340 mg/kg 128 06/10/15 15:30 EPA 6010 Chromium 56.7 mg/kg 1.3 06/10/15 15:30 EPA 6010 Copper 81.7 mg/kg 1.3 06/10/15 15:30 EPA 6010 Iron 43400 mg/kg 10.2 06/10/15 15:30 EPA 6010 Magnesium 17600 mg/kg 128 06/10/15 15:30 EPA 6010 Manganese 782 mg/kg 1.3 06/10/15 15:30 EPA 6010 Nickel 53.5 mg/kg 1.3 06/10/15 15:30 EPA 6010 Potassium 360 mg/kg 255 06/10/15 15:30 EPA 6010 Sodium 303 mg/kg 255 06/10/15 15:30 EPA 6010 Strontium 49.4 mg/kg 2.6 06/10/15 15:30 EPA 6010 Zinc 102 mg/kg 5.1 06/10/15 15:30 EPA 6020 Cobalt 37.4 mg/kg 5.1 06/10/15 11:05 EPA 6020 Vanadium 84.9 mg/kg 5.1 06/10/15 11:05 ASTM D2974-87 Percent Moisture 4.9 % 0.10 06/10/15 08:15 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060059 Pace Project No.: 92252534 Lab Sample ID Client Sample ID Method Parameters SUMMARY OF DETECTION Result Units Report Limit Analyzed 92252534003 2015016948 EPA 9045 pH at 25 Degrees C 7.4 Std. Units 0.10 06/10/15 12:30 EPA 300.0 Sulfate 2.4 mg/L 2.1 06/16/15 16:42 B EPA 9060 RSD% 5.2 % 06/25/15 10:43 92252534004 2015016947 SPLP EPA 6020A Aluminum 20000 ug/L 10.0 07/01/15 01:23 EPA 6020A Arsenic 6.1 ug/L 0.50 07/01/15 01:23 EPA 6020A Barium 542 ug/L 3.0 07/02/15 09:06 EPA 6020A Beryllium 1.3 ug/L 0.20 07/01/15 01:23 EPA 6020A Boron 65.9 ug/L 5.0 07/01/15 01:23 EPA 6020A Cadmium 0.085 ug/L 0.080 07/01/15 01:23 EPA 6020A Calcium 5660 ug/L 40.0 07/01/15 01:23 EPA 6020A Chromium 15.6 ug/L 0.50 07/01/15 01:23 EPA 6020A Cobalt 12.0 ug/L 0.50 07/01/15 01:23 EPA 6020A Copper 171 ug/L 1.0 07/01/15 01:23 EPA 6020A Iron 34200 ug/L 500 07/02/15 09:06 EPA 6020A Lead 5.6 ug/L 0.10 07/01/15 01:23 EPA 6020A Magnesium 10500 ug/L 10.0 07/01/15 01:23 EPA 6020A Manganese 1240 ug/L 5.0 07/02/15 09:06 EPA 6020A Molybdenum 2.7 ug/L 0.50 07/01/15 01:23 EPA 6020A Nickel 12.0 ug/L 0.50 07/01/15 01:23 EPA 6020A Potassium 1520 ug/L 50.0 07/01/15 01:23 EPA 6020A Selenium 7.5 ug/L 0.50 07/01/15 01:23 EPA 6020A Sodium 5580 ug/L 50.0 07/01/15 01:23 EPA 6020A Strontium 101 ug/L 0.50 07/01/15 01:23 EPA 6020A Thallium 0.037J ug/L 0.10 07/01/15 01:23 EPA 6020A Vanadium 69.0 ug/L 1.0 07/01/15 01:23 EPA 6020A Zinc 199 ug/L 5.0 07/01/15 01:23 92252534005 2015016948 SPLP EPA 6020A Aluminum 17200 ug/L 10.0 07/01/15 01:28 EPA 6020A Arsenic 0.35J ug/L 0.50 07/01/15 01:28 EPA 6020A Barium 291 ug/L 0.30 07/01/15 01:28 EPA 6020A Beryllium 0.27 ug/L 0.20 07/01/15 01:28 EPA 6020A Boron 49.7 ug/L 5.0 07/01/15 01:28 EPA 6020A Cadmium 0.0591 ug/L 0.080 07/01/15 01:28 EPA 6020A Calcium 5840 ug/L 40.0 07/01/15 01:28 EPA 6020A Chromium 58.9 ug/L 0.50 07/01/15 01:28 EPA 6020A Cobalt 39.4 ug/L 0.50 07/01/15 01:28 EPA 6020A Copper 66.0 ug/L 1.0 07/01/15 01:28 EPA 6020A Iron 40200 ug/L 250 07/02/15 09:10 EPA 6020A Lead 0.97 ug/L 0.10 07/01/15 01:28 EPA 6020A Magnesium 12900 ug/L 10.0 07/01/15 01:28 EPA 6020A Manganese 912 ug/L 2.5 07/02/15 09:10 EPA 6020A Molybdenum 1.2 ug/L 0.50 07/01/15 01:28 EPA 6020A Nickel 48.6 ug/L 0.50 07/01/15 01:28 EPA 6020A Potassium 590 ug/L 50.0 07/01/15 01:28 EPA 6020A Sodium 4130 ug/L 50.0 07/01/15 01:28 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 fflic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060059 Pace Project No.: 92252534 Lab Sample ID Client Sample ID Method Parameters 92252534005 2015016948 SPLP EPA 6020A Strontium EPA 6020A Vanadium EPA 6020A Zinc SUMMARY OF DETECTION Result UnitE 53.0 ug/L 114 ug/L 176 ug/L REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Report Limit Analyzed Qualifiers 0.50 07/01/15 01:28 1.0 07/01/15 01:28 5.0 07/01/15 01:28 Page 8 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060059 Pace Project No.: 92252534 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: July 03, 2015 General Information: 2 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24583 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92252534002 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1235380) • Aluminum • Barium • Iron • Manganese • MSD (Lab ID: 1235381) • Aluminum • Barium • Copper • Iron • Manganese Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ff�i�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060059 Pace Project No.: 92252534 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: July 03, 2015 Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICP / 15013 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli .8y& je. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060059 Pace Project No.: 92252534 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: July 03, 2015 General Information: 2 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24584 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92252534002 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1235384) • Antimony • Cadmium • Vanadium • MSD (Lab ID: 1235385) • Antimony • Cadmium • Cobalt • Selenium • Vanadium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffiigc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060059 Pace Project No.: 92252534 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: July 03, 2015 Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICPM / 9967 Analyte Comments: QC Batch: MPRP/24584 N2: The lab does not hold TNI accreditation for this parameter. •2015016947 (Lab ID:92252534002) • Antimony •2015016948 (Lab ID:92252534003) • Antimony • BLANK (Lab ID: 1235382) • Antimony • LCS (Lab ID: 1235383) • Antimony • MS (Lab ID: 1235384) • Antimony • MSD (Lab ID: 1235385) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060059 Pace Project No.: 92252534 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: July 03, 2015 General Information: 3 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/55040 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92252908015 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1989131) • Aluminum • MSD (Lab ID: 1989132) • Aluminum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060059 Pace Project No.: 92252534 Method: EPA 7470A Description: 7470A Mercury Client: Duke Energy Date: July 03, 2015 General Information: 3 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�nic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060059 Pace Project No.: 92252534 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: July 03, 2015 General Information: 2 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K2'8y&j.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060059 Pace Project No.: 92252534 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: July 03, 2015 General Information: 2 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KS'8y&j.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060059 Pace Project No.: 92252534 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: July 03, 2015 General Information: 2 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/23324 B: Analyte was detected in the associated method blank. • BLANK for HBN 268289 [WETA/233 (Lab ID: 1485896) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K4'8y&j.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060059 Pace Project No.: 92252534 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: July 03, 2015 General Information: 2 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 111: Analysis conducted outside the EPA method holding time. •2015016947 (Lab ID:92252534002) •2015016948 (Lab ID:92252534003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060059 Pace Project No.: 92252534 Method: SM 4500-CI-E Description: 4500 Chloride, SPLP Client: Duke Energy Date: July 03, 2015 General Information: 2 samples were analyzed for SM 4500-CI-E. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WETA/23354 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92252532003 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1487999) • Chloride • MSD (Lab ID: 1488000) • Chloride Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060059 Pace Project No.: 92252534 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: July 03, 2015 General Information: 2 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/47029 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015016947 (Lab ID:92252534002) • Chloride • Sulfate •2015016948 (Lab ID:92252534003) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060059 Pace Project No.: 92252534 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: July 03, 2015 General Information: 2 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 113: Sample was received or analysis requested beyond the recognized method holding time. •2015016947 (Lab ID:92252534002) •2015016948 (Lab ID:92252534003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/47028 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015016947 (Lab ID:92252534002) • Nitrate as N •2015016948 (Lab ID:92252534003) • Nitrate as N REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPgc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060059 Pace Project No.: 92252534 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: July 03, 2015 General Information: 2 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060059 Pace Project No.: 92252534 Sample: 2015016946 Lab ID: 92252534001 Collected: 05/31/15 10:30 Received: 06/02/15 16:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\�i,I=11 l[99�� 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 07/03/2015 08:29 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 3.8J ug/L 10.0 3.0 1 06/10/15 08:50 06/10/15 11:43 7429-90-5 ND ug/L 0.50 0.15 1 06/10/15 08:50 06/10/15 11:43 7440-36-0 ND ug/L 0.50 0.11 1 06/10/15 08:50 06/10/15 11:43 7440-38-2 ND ug/L 0.30 0.081 1 06/10/15 08:50 06/10/15 11:43 7440-39-3 ND ug/L 0.20 0.067 1 06/10/15 08:50 06/10/15 11:43 7440-41-7 ND ug/L 5.0 1.1 1 06/10/15 08:50 06/10/15 11:43 7440-42-8 ND ug/L 0.080 0.024 1 06/10/15 08:50 06/10/15 11:43 7440-43-9 19.5J ug/L 40.0 16.0 1 06/10/15 08:50 06/10/15 11:43 7440-70-2 ND ug/L 0.50 0.17 1 06/10/15 08:50 06/10/15 11:43 7440-47-3 0.26J ug/L 0.50 0.13 1 06/10/15 08:50 06/10/15 11:43 7440-48-4 ND ug/L 1.0 0.21 1 06/10/15 08:50 06/10/15 11:43 7440-50-8 18.OJ ug/L 50.0 13.7 1 06/10/15 08:50 06/10/15 11:43 7439-89-6 ND ug/L 0.10 0.046 1 06/10/15 08:50 06/10/15 11:43 7439-92-1 3.5J ug/L 10.0 3.2 1 06/10/15 08:50 06/10/15 11:43 7439-95-4 0.37J ug/L 0.50 0.24 1 06/10/15 08:50 06/10/15 11:43 7439-96-5 ND ug/L 0.50 0.094 1 06/10/15 08:50 06/10/15 11:43 7439-98-7 ND ug/L 0.50 0.16 1 06/10/15 08:50 06/10/15 11:43 7440-02-0 ND ug/L 50.0 11.7 1 06/10/15 08:50 06/10/15 11:43 7440-09-7 ND ug/L 0.50 0.20 1 06/10/15 08:50 06/10/15 11:43 7782-49-2 ND ug/L 50.0 16.3 1 06/10/15 08:50 06/10/15 11:43 7440-23-5 ND ug/L 0.50 0.13 1 06/10/15 08:50 06/10/15 11:43 7440-24-6 ND ug/L 0.10 0.015 1 06/10/15 08:50 06/10/15 11:43 7440-28-0 ND ug/L 1.0 0.28 1 06/10/15 08:50 06/10/15 11:43 7440-62-2 ND ug/L 5.0 2.4 1 06/10/15 08:50 06/10/15 11:43 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 06/05/15 08:05 06/05/15 14:05 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060059 Pace Project No.: 92252534 Sample: 2015016947 Lab ID: 92252534002 Collected: 05/31/15 11:15 Received: 06/02/15 16:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 07/03/2015 08:29 AM Analytical Method: EPA 6010 Preparation Method: EPA 3050 6900 mg/kg 30.0 15.0 5 06/08/1516:08 06/10/1515:18 7429-90-5 M1 92.2 mg/kg 3.0 1.5 5 06/08/1516:08 06/10/1515:18 7440-39-3 M1 0.44 mg/kg 0.30 0.15 5 06/08/1516:08 06/10/1515:18 7440-41-7 ND mg/kg 15.0 7.5 5 06/08/1516:08 06/10/1515:18 7440-42-8 1640 mg/kg 150 75.1 5 06/08/1516:08 06/10/1515:18 7440-70-2 8.0 mg/kg 1.5 0.75 5 06/08/1516:08 06/10/1515:18 7440-47-3 72.7 mg/kg 1.5 0.75 5 06/08/1516:08 06/10/1515:18 7440-50-8 M1 18300 mg/kg 12.0 6.0 5 06/08/1516:08 06/10/1515:18 7439-89-6 M1 4170 mg/kg 150 75.1 5 06/08/1516:08 06/10/1515:18 7439-95-4 579 mg/kg 1.5 0.75 5 06/08/1516:08 06/10/1515:18 7439-96-5 M1 ND mg/kg 3.0 1.5 5 06/08/1516:08 06/10/1515:18 7439-98-7 4.8 mg/kg 1.5 0.75 5 06/08/1516:08 06/10/1515:18 7440-02-0 329 mg/kg 300 150 5 06/08/1516:08 06/10/1515:18 7440-09-7 353 mg/kg 300 150 5 06/08/1516:08 06/10/1515:18 7440-23-5 23.2 mg/kg 3.0 1.5 5 06/08/1516:08 06/10/1515:18 7440-24-6 39.8 mg/kg 6.0 3.0 5 06/08/1516:08 06/10/1515:18 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 6.0 3.0 100 06/08/1516:08 06/10/1510:58 7440-36-0 M6,N2 ND mg/kg 6.0 3.0 100 06/08/1516:08 06/10/1510:58 7440-38-2 ND mg/kg 0.72 0.36 100 06/08/1516:08 06/10/1510:58 7440-43-9 M6 6.01 mg/kg 6.0 3.0 100 06/08/1516:08 06/10/1510:58 7440-48-4 M6 3.1J mg/kg 6.0 3.0 100 06/08/1516:08 06/10/1510:58 7439-92-1 ND mg/kg 6.0 3.0 100 06/08/1516:08 06/10/1510:58 7782-49-2 M6 ND mg/kg 6.0 3.0 100 06/08/1516:08 06/10/1510:58 7440-28-0 30.3 mg/kg 6.0 3.0 100 06/08/1516:08 06/10/1510:58 7440-62-2 M6 Analytical Method: EPA 7471 Preparation Method: EPA 7471 ND mg/kg 0.0096 0.0048 1 06/08/1516:22 06/09/1512:20 7439-97-6 Analytical Method: ASTM D2974-87 14.2 % 0.10 0.10 1 06/10/15 08:15 Analytical Method: EPA 9045 7.8 Std. Units 0.10 0.10 1 06/10/15 12:30 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 06/04/15 02:10 3.1 mg/L 2.3 1.2 1 06/16/1516:28 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 06/04/15 02:10 ND mg/L 0.23 0.23 1 06/18/1517:12 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 06/04/15 02:10 ND mg/L 5.8 2.9 1 06/18/15 04:55 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 �nic&y&Je. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060059 Pace Project No.: 92252534 Sample: 2015016947 Lab ID: 92252534002 Collected: 05/31/15 11:15 Received: 06/02/15 16:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 289 145 5 06/06/1512:16 16887-00-6 D3 Sulfate ND mg/kg 289 145 5 06/06/1512:16 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 28.9 14.5 5 06/06/15 12:16 14797-55-8 D3,1-13 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 700 350 1 06/25/15 10:20 7440-44-0 Total Organic Carbon ND mg/kg 699 350 1 06/25/15 10:27 7440-44-0 Total Organic Carbon ND mg/kg 694 347 1 06/25/15 10:32 7440-44-0 Total Organic Carbon ND mg/kg 704 352 1 06/25/15 10:38 7440-44-0 Mean Total Organic Carbon ND mg/kg 699 350 1 06/25/15 10:20 7440-44-0 Surrogates RSD% 8.2 % 1 06/25/15 10:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 25 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060059 Pace Project No.: 92252534 Sample: 2015016948 Lab ID: 92252534003 Collected: 05/31/15 16:15 Received: 06/02/15 16:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 07/03/2015 08:29 AM Analytical Method: EPA 6010 Preparation Method: EPA 3050 20200 mg/kg 25.5 12.8 5 06/08/1516:08 06/10/1515:30 7429-90-5 41.2 mg/kg 2.6 1.3 5 06/08/1516:08 06/10/1515:30 7440-39-3 0.26 mg/kg 0.26 0.13 5 06/08/1516:08 06/10/1515:30 7440-41-7 ND mg/kg 12.8 6.4 5 06/08/1516:08 06/10/1515:30 7440-42-8 7340 mg/kg 128 63.8 5 06/08/1516:08 06/10/1515:30 7440-70-2 56.7 mg/kg 1.3 0.64 5 06/08/1516:08 06/10/1515:30 7440-47-3 81.7 mg/kg 1.3 0.64 5 06/08/1516:08 06/10/1515:30 7440-50-8 43400 mg/kg 10.2 5.1 5 06/08/1516:08 06/10/1515:30 7439-89-6 17600 mg/kg 128 63.8 5 06/08/1516:08 06/10/1515:30 7439-95-4 782 mg/kg 1.3 0.64 5 06/08/1516:08 06/10/1515:30 7439-96-5 ND mg/kg 2.6 1.3 5 06/08/1516:08 06/10/1515:30 7439-98-7 53.5 mg/kg 1.3 0.64 5 06/08/1516:08 06/10/1515:30 7440-02-0 360 mg/kg 255 128 5 06/08/1516:08 06/10/1515:30 7440-09-7 303 mg/kg 255 128 5 06/08/1516:08 06/10/1515:30 7440-23-5 49.4 mg/kg 2.6 1.3 5 06/08/1516:08 06/10/1515:30 7440-24-6 102 mg/kg 5.1 2.6 5 06/08/1516:08 06/10/1515:30 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 5.1 2.6 100 06/08/1516:08 06/10/1511:05 7440-36-0 ND mg/kg 5.1 2.6 100 06/08/1516:08 06/10/1511:05 7440-38-2 ND mg/kg 0.61 0.31 100 06/08/1516:08 06/10/1511:05 7440-43-9 37.4 mg/kg 5.1 2.6 100 06/08/1516:08 06/10/1511:05 7440-48-4 ND mg/kg 5.1 2.6 100 06/08/1516:08 06/10/1511:05 7439-92-1 ND mg/kg 5.1 2.6 100 06/08/1516:08 06/10/1511:05 7782-49-2 ND mg/kg 5.1 2.6 100 06/08/1516:08 06/10/1511:05 7440-28-0 84.9 mg/kg 5.1 2.6 100 06/08/1516:08 06/10/1511:05 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 ND mg/kg 0.0087 0.0043 1 06/08/1516:22 06/09/1512:26 7439-97-6 Analytical Method: ASTM D2974-87 4.9 % 0.10 0.10 1 06/10/15 08:15 Analytical Method: EPA 9045 7.4 Std. Units 0.10 0.10 1 06/10/15 12:30 N2 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 06/04/15 02:10 2.4 mg/L 2.1 1.1 1 06/16/1516:42 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 06/04/15 02:10 ND mg/L 0.21 0.21 1 06/18/1517:14 H1 Analytical Method: SM 4500-CI-E Leachate Method/Date: EPA 1312; 06/04/15 02:10 ND mg/L 5.3 2.6 1 06/18/15 05:00 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 t S,8y&J.. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060059 Pace Project No.: 92252534 Sample: 2015016948 Lab ID: 92252534003 Collected: 05/31/15 16:15 Received: 06/02/15 16:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 263 131 5 06/06/1512:38 16887-00-6 D3 Sulfate ND mg/kg 263 131 5 06/06/1512:38 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 26.3 13.1 5 06/06/15 12:38 14797-55-8 D3,1-13 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 635 318 1 06/25/15 10:43 7440-44-0 Total Organic Carbon ND mg/kg 632 316 1 06/25/15 10:49 7440-44-0 Total Organic Carbon ND mg/kg 634 317 1 06/25/15 10:54 7440-44-0 Total Organic Carbon ND mg/kg 635 317 1 06/25/15 11:00 7440-44-0 Mean Total Organic Carbon ND mg/kg 634 317 1 06/25/15 10:43 7440-44-0 Surrogates RSD% 5.2 % 1 06/25/15 10:43 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 27 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K4'8y&J.. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060059 Pace Project No.: 92252534 Sample: 2015016947 SPLP Lab ID: 92252534004 Collected: 05/31/15 11:15 Received: 06/02/15 16:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 07/03/2015 08:29 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 20000 ug/L 10.0 3.0 1 06/29/15 10:21 07/01/15 01:23 7429-90-5 ND ug/L 0.50 0.15 1 06/29/15 10:21 07/01/15 01:23 7440-36-0 6.1 ug/L 0.50 0.11 1 06/29/15 10:21 07/01/15 01:23 7440-38-2 542 ug/L 3.0 0.81 10 06/29/15 10:21 07/02/15 09:06 7440-39-3 1.3 ug/L 0.20 0.067 1 06/29/15 10:21 07/01/15 01:23 7440-41-7 65.9 ug/L 5.0 1.1 1 06/29/15 10:21 07/01/15 01:23 7440-42-8 0.085 ug/L 0.080 0.024 1 06/29/15 10:21 07/01/15 01:23 7440-43-9 5660 ug/L 40.0 16.0 1 06/29/15 10:21 07/01/15 01:23 7440-70-2 15.6 ug/L 0.50 0.17 1 06/29/15 10:21 07/01/15 01:23 7440-47-3 12.0 ug/L 0.50 0.13 1 06/29/15 10:21 07/01/15 01:23 7440-48-4 171 ug/L 1.0 0.21 1 06/29/15 10:21 07/01/15 01:23 7440-50-8 34200 ug/L 500 137 10 06/29/15 10:21 07/02/15 09:06 7439-89-6 5.6 ug/L 0.10 0.046 1 06/29/15 10:21 07/01/15 01:23 7439-92-1 10500 ug/L 10.0 3.2 1 06/29/15 10:21 07/01/15 01:23 7439-95-4 1240 ug/L 5.0 2.4 10 06/29/15 10:21 07/02/15 09:06 7439-96-5 2.7 ug/L 0.50 0.094 1 06/29/15 10:21 07/01/15 01:23 7439-98-7 12.0 ug/L 0.50 0.16 1 06/29/15 10:21 07/01/15 01:23 7440-02-0 1520 ug/L 50.0 11.7 1 06/29/15 10:21 07/01/15 01:23 7440-09-7 7.5 ug/L 0.50 0.20 1 06/29/15 10:21 07/01/15 01:23 7782-49-2 5580 ug/L 50.0 16.3 1 06/29/15 10:21 07/01/15 01:23 7440-23-5 101 ug/L 0.50 0.13 1 06/29/15 10:21 07/01/15 01:23 7440-24-6 0.037J ug/L 0.10 0.015 1 06/29/15 10:21 07/01/15 01:23 7440-28-0 69.0 ug/L 1.0 0.28 1 06/29/15 10:21 07/01/15 01:23 7440-62-2 199 ug/L 5.0 2.4 1 06/29/15 10:21 07/01/15 01:23 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 06/29/1514:30 07/01/1518:10 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 28 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K3�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: J15060059 Pace Project No.: 92252534 Sample: 2015016948 SPLP Lab ID: 92252534005 Collected: 05/31/15 16:15 Received: 06/02/15 16:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 07/03/2015 08:29 AM Analytical Method: EPA 6020A Preparation Method: EPA 3020 17200 ug/L 10.0 3.0 1 06/29/15 10:21 07/01/15 01:28 7429-90-5 ND ug/L 0.50 0.15 1 06/29/15 10:21 07/01/15 01:28 7440-36-0 0.35J ug/L 0.50 0.11 1 06/29/15 10:21 07/01/15 01:28 7440-38-2 291 ug/L 0.30 0.081 1 06/29/15 10:21 07/01/15 01:28 7440-39-3 0.27 ug/L 0.20 0.067 1 06/29/15 10:21 07/01/15 01:28 7440-41-7 49.7 ug/L 5.0 1.1 1 06/29/15 10:21 07/01/15 01:28 7440-42-8 0.059J ug/L 0.080 0.024 1 06/29/15 10:21 07/01/15 01:28 7440-43-9 5840 ug/L 40.0 16.0 1 06/29/15 10:21 07/01/15 01:28 7440-70-2 58.9 ug/L 0.50 0.17 1 06/29/15 10:21 07/01/15 01:28 7440-47-3 39.4 ug/L 0.50 0.13 1 06/29/15 10:21 07/01/15 01:28 7440-48-4 66.0 ug/L 1.0 0.21 1 06/29/15 10:21 07/01/15 01:28 7440-50-8 40200 ug/L 250 68.5 5 06/29/15 10:21 07/02/15 09:10 7439-89-6 0.97 ug/L 0.10 0.046 1 06/29/15 10:21 07/01/15 01:28 7439-92-1 12900 ug/L 10.0 3.2 1 06/29/15 10:21 07/01/15 01:28 7439-95-4 912 ug/L 2.5 1.2 5 06/29/15 10:21 07/02/15 09:10 7439-96-5 1.2 ug/L 0.50 0.094 1 06/29/15 10:21 07/01/15 01:28 7439-98-7 48.6 ug/L 0.50 0.16 1 06/29/15 10:21 07/01/15 01:28 7440-02-0 590 ug/L 50.0 11.7 1 06/29/15 10:21 07/01/15 01:28 7440-09-7 ND ug/L 0.50 0.20 1 06/29/15 10:21 07/01/15 01:28 7782-49-2 4130 ug/L 50.0 16.3 1 06/29/15 10:21 07/01/15 01:28 7440-23-5 53.0 ug/L 0.50 0.13 1 06/29/15 10:21 07/01/15 01:28 7440-24-6 ND ug/L 0.10 0.015 1 06/29/15 10:21 07/01/15 01:28 7440-28-0 114 ug/L 1.0 0.28 1 06/29/15 10:21 07/01/15 01:28 7440-62-2 176 ug/L 5.0 2.4 1 06/29/15 10:21 07/01/15 01:28 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 06/29/1514:30 07/01/1518:13 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 29 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060059 Pace Project No.: 92252534 QC Batch: MERP/13774 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92252534001 METHOD BLANK: 1985612 Matrix: Water Associated Lab Samples: 92252534001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 06/05/1513:29 LABORATORY CONTROL SAMPLE: 1985613 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.3 105 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1985614 1985615 MS MSD 92246833005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L 0.77 5 5 5.4 5.3 93 91 80-120 1 20 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 30 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060059 Pace Project No.: 92252534 QC Batch: MERP/14018 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92252534004, 92252534005 METHOD BLANK: 2006739 Matrix: Water Associated Lab Samples: 92252534004, 92252534005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 07/01/1517:33 LABORATORY CONTROL SAMPLE: 2006740 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 4.9 97 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2007452 2007453 MS MSD 92255755005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 5.2 5.3 103 105 80-120 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 31 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�gc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060059 Pace Project No.: 92252534 QC Batch: MERP/5828 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92252534002, 92252534003 METHOD BLANK: 1235386 Matrix: Solid Associated Lab Samples: 92252534002, 92252534003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0078 06/09/1512:15 LABORATORY CONTROL SAMPLE: 1235387 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .079 0.080 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1235388 1235389 MS MSD 92252534002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg ND .0932 .0944 0.092 0.093 97 96 80-120 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 32 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060059 Pace Project No.: 92252534 QC Batch: MPRP/24583 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92252534002, 92252534003 METHOD BLANK: 1235378 Associated Lab Samples: 92252534002, 92252534003 Parameter Units Aluminum mg/kg Barium mg/kg Beryllium mg/kg Boron mg/kg Calcium mg/kg Chromium mg/kg Copper mg/kg Iron mg/kg Magnesium mg/kg Manganese mg/kg Molybdenum mg/kg Nickel mg/kg Potassium mg/kg Sodium mg/kg Strontium mg/kg Zinc mg/kg Matrix: Solid Blank Result Reporting Limit Analyzed ND 5.2 06/10/1515:10 ND 0.52 06/10/1515:10 ND 0.052 06/10/1515:10 ND 2.6 06/10/1515:10 ND 26.0 06/10/1515:10 ND 0.26 06/10/1515:10 ND 0.26 06/10/1515:10 ND 2.1 06/10/1515:10 ND 26.0 06/10/1515:10 ND 0.26 06/10/1515:10 ND 0.52 06/10/1515:10 ND 0.26 06/10/1515:10 ND 52.0 06/10/1515:10 ND 52.0 06/10/1515:10 ND 0.52 06/10/1515:10 ND 1.0 06/10/1515:10 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1235379 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 128 135 105 80-120 Barium mg/kg 12.8 13.8 107 80-120 Beryllium mg/kg 1.3 1.4 105 80-120 Boron mg/kg 128 134 105 80-120 Calcium mg/kg 641 686 107 80-120 Chromium mg/kg 12.8 13.4 104 80-120 Copper mg/kg 12.8 13.3 104 80-120 Iron mg/kg 128 135 105 80-120 Magnesium mg/kg 641 680 106 80-120 Manganese mg/kg 12.8 13.7 107 80-120 Molybdenum mg/kg 12.8 13.0 102 80-120 Nickel mg/kg 12.8 13.5 105 80-120 Potassium mg/kg 641 685 107 80-120 Sodium mg/kg 641 709 111 80-120 Strontium mg/kg 12.8 13.5 106 80-120 Zinc mg/kg 64.1 67.3 105 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 33 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060059 Pace Project No.: 92252534 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1235380 1235381 MS MSD 92252534002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 6900 148 141 8160 8260 852 964 75-125 1 20 M1 Barium mg/kg 92.2 14.8 14.1 92.6 92.4 3 2 75-125 0 20 M1 Beryllium mg/kg 0.44 1.52 1.4 1.8 1.8 92 96 75-125 1 20 Boron mg/kg ND 148 141 136 130 92 93 75-125 5 20 Calcium mg/kg 1640 740 704 2330 2200 93 79 75-125 6 20 Chromium mg/kg 8.0 14.8 14.1 20.6 21.5 85 96 75-125 4 20 Copper mg/kg 72.7 14.8 14.1 86.9 90.7 96 129 75-125 4 20 M1 Iron mg/kg 18300 148 141 17400 18500 -605 133 75-125 6 20 M1 Magnesium mg/kg 4170 740 704 4840 4710 91 77 75-125 3 20 Manganese mg/kg 579 14.8 14.1 496 507 -558 -509 75-125 2 20 M1 Molybdenum mg/kg ND 14.8 14.1 13.2 12.7 88 89 75-125 4 20 Nickel mg/kg 4.8 14.8 14.1 19.2 19.0 97 101 75-125 1 20 Potassium mg/kg 329 740 704 1010 1010 92 97 75-125 1 20 Sodium mg/kg 353 740 704 1070 1090 96 104 75-125 2 20 Strontium mg/kg 23.2 14.8 14.1 36.9 36.3 93 93 75-125 2 20 Zinc mg/kg 39.8 74 70.4 112 108 97 97 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 34 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 1inlc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060059 Pace Project No.: 92252534 QC Batch: MPRP/24584 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92252534002, 92252534003 METHOD BLANK: 1235382 Matrix: Solid Associated Lab Samples: 92252534002, 92252534003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.050 06/10/1510:54 N2 Arsenic mg/kg ND 0.050 06/10/1510:54 Cadmium mg/kg ND 0.0060 06/10/1510:54 Cobalt mg/kg ND 0.050 06/10/1510:54 Lead mg/kg ND 0.050 06/10/1510:54 Selenium mg/kg ND 0.050 06/10/1510:54 Thallium mg/kg ND 0.050 06/10/1510:54 Vanadium mg/kg ND 0.050 06/10/1510:54 LABORATORY CONTROL SAMPLE: 1235383 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony mg/kg 2.5 2.7 108 80-120 N2 Arsenic mg/kg 2.5 2.7 105 80-120 Cadmium mg/kg .25 0.27 106 80-120 Cobalt mg/kg 2.5 2.7 106 80-120 Lead mg/kg 2.5 2.7 107 80-120 Selenium mg/kg 2.5 2.7 107 80-120 Thallium mg/kg 2.5 2.7 107 80-120 Vanadium mg/kg 2.5 2.7 106 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1235384 1235385 MS MSD 92252534002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 2.8 2.8 ND ND 64 56 75-125 20 M6, N2 Arsenic mg/kg ND 2.8 2.8 3.9J 4.OJ 94 95 75-125 20 Cadmium mg/kg ND .28 .28 ND ND 61 55 75-125 20 M6 Cobalt mg/kg 6.OJ 2.8 2.8 8.8 7.9 101 69 75-125 11 20 M6 Lead mg/kg 3.1J 2.8 2.8 5AJ 5.3J 82 77 75-125 20 Selenium mg/kg ND 2.8 2.8 4.3J 3.9J 86 70 75-125 20 M6 Thallium mg/kg ND 2.8 2.8 2.8J ND 95 93 75-125 20 Vanadium mg/kg 30.3 2.8 2.8 34.3 31.8 140 53 75-125 7 20 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 35 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060059 Pace Project No.: 92252534 QC Batch: MPRP/55040 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92252534001 METHOD BLANK: 1989129 Associated Lab Samples: 92252534001 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 06/10/1511:38 ND 0.50 06/10/1511:38 ND 0.50 06/10/1511:38 ND 0.30 06/10/1511:38 ND 0.20 06/10/1511:38 ND 5.0 06/10/1511:38 ND 0.080 06/10/1511:38 ND 40.0 06/10/1511:38 ND 0.50 06/10/1511:38 ND 0.50 06/10/1511:38 ND 1.0 06/10/1511:38 ND 50.0 06/10/1511:38 ND 0.10 06/10/1511:38 ND 10.0 06/10/1511:38 ND 0.50 06/10/1511:38 ND 0.50 06/10/1511:38 ND 0.50 06/10/1511:38 ND 50.0 06/10/1511:38 ND 0.50 06/10/1511:38 ND 50.0 06/10/1511:38 ND 0.50 06/10/1511:38 ND 0.10 06/10/1511:38 ND 1.0 06/10/1511:38 ND 5.0 06/10/1511:38 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1989130 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 79.7 100 80-120 Antimony ug/L 80 76.7 96 80-120 Arsenic ug/L 80 76.8 96 80-120 Barium ug/L 80 76.7 96 80-120 Beryllium ug/L 80 83.0 104 80-120 Boron ug/L 80 74.6 93 80-120 Cadmium ug/L 80 79.6 99 80-120 Calcium ug/L 1000 1010 101 80-120 Chromium ug/L 80 78.6 98 80-120 Cobalt ug/L 80 76.6 96 80-120 Copper ug/L 80 77.4 97 80-120 Iron ug/L 1000 1000 100 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 36 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060059 Pace Project No.: 92252534 LABORATORY CONTROL SAMPLE: 1989130 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 77.3 97 80-120 Magnesium ug/L 1000 976 98 80-120 Manganese ug/L 80 77.8 97 80-120 Molybdenum ug/L 80 76.9 96 80-120 Nickel ug/L 80 76.2 95 80-120 Potassium ug/L 1000 945 94 80-120 Selenium ug/L 80 77.6 97 80-120 Sodium ug/L 1000 965 96 80-120 Strontium ug/L 80 76.7 96 80-120 Thallium ug/L 80 81.6 102 80-120 Vanadium ug/L 80 78.2 98 80-120 Zinc ug/L 80 78.2 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1989131 1989132 MS MSD 92252908015 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 103 80 80 212 208 136 132 75-125 2 20 M1 Antimony ug/L ND 80 80 77.2 77.2 96 96 75-125 0 20 Arsenic ug/L ND 80 80 75.9 75.8 95 95 75-125 0 20 Barium ug/L 2.3 80 80 79.8 79.2 97 96 75-125 1 20 Beryllium ug/L ND 80 80 82.2 81.1 103 101 75-125 1 20 Boron ug/L 1.91 80 80 81.2 75.1 99 92 75-125 8 20 Cadmium ug/L ND 80 80 79.8 80.4 100 101 75-125 1 20 Calcium ug/L 148 1000 1000 1170 1060 102 92 75-125 9 20 Chromium ug/L 0.58 80 80 80.4 80.5 100 100 75-125 0 20 Cobalt ug/L ND 80 80 77.0 77.0 96 96 75-125 0 20 Copper ug/L 2.2 80 80 80.2 80.2 97 98 75-125 0 20 Iron ug/L 199 1000 1000 1210 1210 101 101 75-125 0 20 Lead ug/L 0.14 80 80 77.6 77.4 97 97 75-125 0 20 Magnesium ug/L 44.4 1000 1000 1030 1030 99 98 75-125 0 20 Manganese ug/L 4.2 80 80 83.9 82.1 100 97 75-125 2 20 Molybdenum ug/L 0.32J 80 80 76.8 77.6 96 97 75-125 1 20 Nickel ug/L 0.60 80 80 77.2 76.6 96 95 75-125 1 20 Potassium ug/L 172 1000 1000 1150 1130 98 96 75-125 2 20 Selenium ug/L ND 80 80 77.5 78.6 97 98 75-125 1 20 Sodium ug/L 293 1000 1000 1260 1270 96 98 75-125 1 20 Strontium ug/L 0.55 80 80 76.7 78.4 95 97 75-125 2 20 Thallium ug/L ND 80 80 81.7 81.4 102 102 75-125 0 20 Vanadium ug/L ND 80 80 79.0 78.0 99 97 75-125 1 20 Zinc ug/L 3.5J 80 80 81.9 82.6 98 99 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 37 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060059 Pace Project No.: 92252534 QC Batch: MPRP/55571 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92252534004, 92252534005 METHOD BLANK: 2006731 Associated Lab Samples: 92252534004, 92252534005 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 07/01/15 00:15 ND 0.50 07/01/15 00:15 ND 0.50 07/01/15 00:15 ND 0.30 07/01/15 00:15 ND 0.20 07/01/15 00:15 ND 5.0 07/01/15 00:15 ND 0.080 07/01/15 00:15 ND 40.0 07/02/15 07:11 ND 0.50 07/01/15 00:15 ND 0.50 07/01/15 00:15 ND 1.0 07/02/15 07:11 ND 50.0 07/01/15 00:15 ND 0.10 07/01/15 00:15 ND 10.0 07/01/15 00:15 ND 0.50 07/01/15 00:15 ND 0.50 07/01/15 00:15 ND 0.50 07/01/15 00:15 ND 50.0 07/01/15 00:15 ND 0.50 07/01/15 00:15 ND 50.0 07/01/15 00:15 ND 0.50 07/01/15 00:15 ND 0.10 07/01/15 00:15 ND 1.0 07/01/15 00:15 ND 5.0 07/01/15 00:15 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 2006732 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 76.1 95 80-120 Antimony ug/L 80 76.2 95 80-120 Arsenic ug/L 80 77.5 97 80-120 Barium ug/L 80 79.1 99 80-120 Beryllium ug/L 80 82.0 103 80-120 Boron ug/L 80 87.1 109 80-120 Cadmium ug/L 80 77.9 97 80-120 Calcium ug/L 1000 1030 103 80-120 Chromium ug/L 80 78.1 98 80-120 Cobalt ug/L 80 78.4 98 80-120 Copper ug/L 80 77.4 97 80-120 Iron ug/L 1000 976 98 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 38 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060059 Pace Project No.: 92252534 LABORATORY CONTROL SAMPLE: 2006732 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 77.0 96 80-120 Magnesium ug/L 1000 964 96 80-120 Manganese ug/L 80 78.4 98 80-120 Molybdenum ug/L 80 76.8 96 80-120 Nickel ug/L 80 78.2 98 80-120 Potassium ug/L 1000 979 98 80-120 Selenium ug/L 80 78.2 98 80-120 Sodium ug/L 1000 994 99 80-120 Strontium ug/L 80 77.3 97 80-120 Thallium ug/L 80 76.6 96 80-120 Vanadium ug/L 80 78.6 98 80-120 Zinc ug/L 80 77.2 97 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2007450 2007451 MS MSD 92255755020 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 5.6J 80 80 94.1 93.8 111 110 75-125 0 20 Antimony ug/L ND 80 80 78.5 76.7 98 96 75-125 2 20 Arsenic ug/L ND 80 80 81.1 77.9 101 97 75-125 4 20 Barium ug/L 0.26J 80 80 80.8 79.3 101 99 75-125 2 20 Beryllium ug/L ND 80 80 79.8 80.6 100 101 75-125 1 20 Boron ug/L ND 80 80 84.4 81.9 104 101 75-125 3 20 Cadmium ug/L ND 80 80 80.7 79.4 101 99 75-125 2 20 Calcium ug/L 76.6 1000 1000 1100 1090 103 101 75-125 2 20 Chromium ug/L ND 80 80 81.2 79.1 101 99 75-125 3 20 Cobalt ug/L ND 80 80 82.2 78.6 103 98 75-125 4 20 Copper ug/L 0.32J 80 80 81.9 78.9 102 98 75-125 4 20 Iron ug/L 14.7J 1000 1000 1030 996 101 98 75-125 3 20 Lead ug/L ND 80 80 79.3 77.2 99 97 75-125 3 20 Magnesium ug/L 7.9J 1000 1000 1030 1000 102 99 75-125 3 20 Manganese ug/L 0.42J 80 80 81.6 80.2 102 100 75-125 2 20 Molybdenum ug/L ND 80 80 80.0 78.7 100 98 75-125 2 20 Nickel ug/L ND 80 80 84.0 80.4 105 100 75-125 4 20 Potassium ug/L 18.5J 1000 1000 1050 1030 104 101 75-125 3 20 Selenium ug/L ND 80 80 82.1 78.6 103 98 75-125 4 20 Sodium ug/L 31.9J 1000 1000 1070 1010 104 97 75-125 6 20 Strontium ug/L 0.50 80 80 80.6 79.8 100 99 75-125 1 20 Thallium ug/L ND 80 80 81.1 79.2 101 99 75-125 2 20 Vanadium ug/L ND 80 80 82.0 79.4 102 99 75-125 3 20 Zinc ug/L 8.0 80 80 92.6 83.4 106 94 75-125 10 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 39 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060059 Pace Project No.: 92252534 QC Batch: PMST/3629 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92252534002, 92252534003 SAMPLE DUPLICATE: 1237772 35190066001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 5.1 4.0 23 10 D6 SAMPLE DUPLICATE: 1237773 35191549001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 21.5 20.1 7 10 SAMPLE DUPLICATE: 1237774 35191958002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 20.2 20.2 0 10 SAMPLE DUPLICATE: 1237775 35192020007 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 24.1 22.6 6 10 SAMPLE DUPLICATE: 1237776 35192120002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 12.4 10.2 19 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 40 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060059 Pace Project No.: 92252534 QC Batch: WET/37953 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92252534002, 92252534003 SAMPLE DUPLICATE: 1478381 92253145001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 5.9 5.8 0 10 SAMPLE DUPLICATE: 1478382 92252534003 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 7.4 7.4 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 41 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Iigc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060059 Pace Project No.: 92252534 QC Batch: WETA/23324 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92252534002, 92252534003 METHOD BLANK: 1485896 Matrix: Water Associated Lab Samples: 92252534002, 92252534003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L 2.3 2.0 06/16/1515:20 LABORATORY CONTROL SAMPLE: 1485897 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 19.6 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1485898 1485899 MS MSD 92252532003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 6.3 20 20 26.0 26.2 98 99 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 42 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060059 Pace Project No.: 92252534 QC Batch: WETA/23372 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92252534002, 92252534003 METHOD BLANK: 1488925 Matrix: Water Associated Lab Samples: 92252534002, 92252534003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L 0.14 0.020 06/18/15 17:00 Z2 LABORATORY CONTROL SAMPLE: 1488926 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.5 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1488927 1488928 MS MSD 92252532003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L ND 2.5 2.5 2.6 2.6 98 97 90-110 1 10 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 43 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060059 Pace Project No.: 92252534 QC Batch: WETA/23354 Analysis Method: SM 4500-CI-E QC Batch Method: SM 4500-CI-E Analysis Description: 4500 Chloride Associated Lab Samples: 92252534002, 92252534003 METHOD BLANK: 1487997 Matrix: Water Associated Lab Samples: 92252534002, 92252534003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 06/18/15 04:51 LABORATORY CONTROL SAMPLE: 1487998 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 19.8 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1487999 1488000 MS MSD 92252532003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 20 20 17.3 17.4 86 86 90-110 0 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 44 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 1j ni c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060059 Pace Project No.: 92252534 QC Batch: WETA/47029 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92252534002, 92252534003 METHOD BLANK: 1233607 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.8 06/06/15 06:55 Sulfate mg/kg ND 49.8 06/06/15 06:55 LABORATORY CONTROL SAMPLE: 1233608 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1233610 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1233609 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 496 510 103 80-120 496 507 102 80-120 92252369001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 1310 1240 76 80-120 M 1 ND 1310 1300 84 80-120 92252369001 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 45 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060059 Pace Project No.: 92252534 QC Batch: WETA/47028 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92252534002, 92252534003 METHOD BLANK: 1233603 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 06/06/15 06:55 LABORATORY CONTROL SAMPLE: 1233604 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 49.6 52.7 106 80-120 MATRIX SPIKE SAMPLE: 1233606 92252369001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 131 123 92 80-120 H3 SAMPLE DUPLICATE: 1233605 92252369001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 46 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: J15060059 Pace Project No.: 92252534 QC Batch: WETA/29146 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92252534002, 92252534003 METHOD BLANK: 1180915 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 06/25/15 07:35 LABORATORY CONTROL SAMPLE: 1180916 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 111000 93 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1180917 1180918 MS MSD 92252370001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 13100 10700 10700 23800 22800 100 90 50-150 5 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 47 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 14'8y&J.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: J15060059 Pace Project No.: 92252534 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: ICP/15013 Ill Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. Batch: ICPM/9967 III Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H1 Analysis conducted outside the EPA method holding time. H1 Analysis conducted outside the recognized method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 48 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 Ijigc&y&J.. Suite 100 Huntersville, INC 28078 (704)875-9092 QUALIFIERS Project: J15060059 Pace Project No.: 92252534 ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TIN accreditation for this parameter. Z2 Analyte present in the associated method blank above the detection limit. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/03/2015 08:29 AM without the written consent of Pace Analytical Services, Inc.. Page 49 of 52 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 16'8y&J.. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15060059 Pace Project No.: 92252534 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92252534002 2015016947 EPA 3050 MPRP/24583 EPA 6010 92252534003 2015016948 EPA 3050 MPRP/24583 EPA 6010 92252534002 2015016947 EPA 3050 MPRP/24584 EPA 6020 92252534003 2015016948 EPA 3050 MPRP/24584 EPA 6020 92252534001 2015016946 EPA 3020 MPRP/55040 EPA 6020A 92252534004 2015016947 SPLP EPA 3020 MPRP/55571 EPA 6020A 92252534005 2015016948 SPLP EPA 3020 MPRP/55571 EPA 6020A 92252534001 2015016946 EPA 7470A MERP/13774 EPA 7470A 92252534004 2015016947 SPLP EPA 7470A MERP/14018 EPA 7470A 92252534005 2015016948 SPLP EPA 7470A MERP/14018 EPA 7470A 92252534002 2015016947 EPA 7471 MERP/5828 EPA 7471 92252534003 2015016948 EPA 7471 MERP/5828 EPA 7471 92252534002 2015016947 ASTM D2974-87 PMST/3629 92252534003 2015016948 ASTM D2974-87 PMST/3629 92252534002 2015016947 EPA 9045 WET/37953 92252534003 2015016948 EPA 9045 WET/37953 92252534002 2015016947 EPA 300.0 WETA/23324 92252534003 2015016948 EPA 300.0 WETA/23324 92252534002 2015016947 EPA 353.2 WETA/23372 92252534003 2015016948 EPA 353.2 WETA/23372 92252534002 2015016947 SM 4500-CI-E WETA/23354 92252534003 2015016948 SM 4500-CI-E WETA/23354 92252534002 2015016947 EPA 9056 WETA/47029 92252534003 2015016948 EPA 9056 WETA/47029 92252534002 2015016947 EPA 9056 WETA/47028 92252534003 2015016948 EPA 9056 WETA/47028 92252534002 2015016947 EPA 9060 WETA/29146 92252534002 2015016947 EPA 9060 WETA/29147 92252534003 2015016948 EPA 9060 WETA/29146 92252534003 2015016948 EPA 9060 WETA/29147 Date: 07/03/2015 08:29 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch ICP/15013 ICP/15013 ICPM/9967 ICPM/9967 ICPM/24731 ICPM/25109 ICPM/25109 MERC/16024 MERC/16364 MERC/16364 MERC/5813 MERC/5813 Page 50 of 52 ��I'?CoAnalyflcaf' I I IGI IL I+1g111 G. Condition Upon Recei Document Number: F-CH R-CS-003-rev.16 "LlUUIIICIIL IICVIJOU IVIOy IV, GV IV Page 1 of 2* Issuing Authority: 5 Pace Huntersviile Qualitv(�ice Client name: * Page 2 of 2 is for Internal Use Only Courier: ❑ Fed Ex ❑ UPS❑ USPS❑ Client❑ Commercial Pace Other Custody Seal on Cooler/Box Present: ❑ yes ❑ono Seals intact: ❑ yes ❑ no Packing Material: ❑ Bubble 1❑p ❑"`Bubble Bags g ❑ oclNon" e ❑ Other Thermometer Used: IR Gun T1401 Type of t Blue None _0-6mpies on ice, cooling process has begun Temp Correction Factor T1401 No Correction I .tom+' Corrected Cooler Temp.: °C Temp should be above freezing to 0°C Biological Tissue is Frozen: Yes No NIA g Comments: Date a� Ir� i Is f arson examining conk t.- Chain of Custody Present: Yes ❑No ❑N/A 1. Chain of Custody Filled Out: Tres ❑No ❑NIA 2. Chain of Custody Relinquished: Ys ❑No ❑NIA 3. Sampler Blame & Signature on COC: ❑Y❑No ❑NIA 4. Samples Arrived within Hold Time: CYes ❑No 0N1A 5. Short Hold Time Analysis (<72hr): ❑Yes qNo ❑N1A 6. Rush Turn Around Time Requested: ❑Yes 4No ❑NIA 7. Sufficient Volume: Q� es ❑No ❑NIA $, Correct Containers Used: -Pace Containers Used: OYes ❑No ❑Yes Of(o ❑NIA ❑NIA 9. Containers Intact: Yes ❑No ❑NIA 10. Filtered volume received for Dissolved tests ❑Yes ONO ❑N/A 11. Sample Labels match COC: -Includes date/time/ID/Analysis Matrix: byes ❑ o ❑NIA 12. All containers needing preservation have been checked. All containers needing preservation are found to be in compliance with EPA recommendation. exceptions: VOA, conform, TOC, 0&G, WI-DRO (water) gYes ❑No ❑ El ❑Yes ❑No ❑NIA ©N!A 13. '- Samples checked for dechlorination: ❑Yes ❑No 01\11A 14. Headspace in VOA Vials{ >6mm): ❑Yes ❑No ❑ lA 15. Trip Blank Present: Trip Blank Custody Seals Present Pace Trip Blank Lot # (if purchased): - - Dyes ❑No ❑Yes ❑No ❑Nn ❑NIA 16. - - - - - Client Notification/ Resolution: Field Data Required? Y 1 N Person Contacted: Daterrime: Comments/ Resolution: SCURF Review. Date; 1 41211s" SRF Review: Date: - /,- Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( 1.e out of hold, incorrect preservative, out of temp, incorrect containers) WOlt:92252534 11111111111111111111111 Page 51 of 52 d = a M1 3 j N O 5'j n c +D y � A fe 0 [l ya M o o la o 0 n � �+ O n � �tr � 3 0 4 R A n CI n ^ a _x 1 O `po n� m w en n m� 3 m c ri t o� �x x a is V .. u a .. • M i i ijj' \�� u N II Customer to complete appropriate columns to right Customer MU51 Complete N n m n v 1- S. CL n Iw d 0 o 's .�. i m 7 . n Le v n c Ia 0 n On C n o $ a 0, e " O e n ° D 6 of 0 O N N 7 n v, 3 a or Ti a +D Y w n N m o. N p n m o a O =� w a e m K 8 n a e z a �c Sg o � m 58 c9 1 1 1 F I i 3 I 1 a, all *3 NN�flO cr pin ICU z� y 13: ib N i"lry m 0ID biz i� o ;,a CA 1 a`1 Mio a 2 i yin i i C ! .............! Vi _.o _ _.1 � ! v G ! I in 1 I Z l v iD i iZ DiD yir O �iN i d! riN to oil o@ i D i7 1 Q I = 3 Cim 2 0 o�-a 3 rto � 3 1 m v v Page 52 of 52 u jUKE - - _ _CHAIN E CUSTODY RECORD A14D ANALYSIS REQUEST FORM Synterra EDD 4' AnaCy# Cal Labl�ratary Si�hv#cd�sY Analytical Laboratory Use Only,of", ^ I N1aII L`44kA M3A2 {BVPISring]9g�) _..___ i'44fk6rdir .._____ ,�.._._._.-.•,'y,.•'•.eA_•L•`..—,'•_•�• �-�•••, ary.1 oti e 133]9 MaQprs Fwry Rd '- -C7 Ji, SOIL � i DISTRIBUTION ENERGY Y Hunhirgyllls, N.C. 2007'8 1 { - '� _ .8anr Inatin Frw ORIC INAL CIF tAR h h4co ae as J-T jEdiU) ars-saaa yy j A ,(J COPY to (,L. 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